MATERIAL SAFETY DATA SHEET

Fanfar e ® 2EC Page 1 of 5

7

- 31

- 08 1. IDENTIFICATION

Product name: Fanfare ® 2EC Chemical name of active ingredient(s): Bifenthrin: 2 methyl[1,1'

- biphenyl]

- 3

- yl)methyl 3

- (2

- chloro

3,3,3

- trifluoro

- 1

- propenyl)

- 2,2

- dimethyl

cyclopropanecarboxylate

Manufacturer: Makhteshim Agan of North Americ a , Inc. 4515 Falls of Neuse Road, Suite 300 Raleigh, NC 27609

Phone: 919

- 256

- 9300 For fire, spill, and/or leak emergencies,

contact Infotrac: Phone: 1

- 800

- 535

- 5053

For medical emergencies and health and safety inquiries, contact Prosar: Phone: 1

- 877

- 250

- 9291

2. COMPOSITION/INFORMATION ON INGREDIENTS

COMMON NAME CAS NO. % OSHA / PEL ACIGH

/ TLV OTHER NTP/IARC/OSHA

(Carcinogenicity)

Bifenthrin 82657

- 04

- 3 25.1 NA NA NA NA Inert ingredients including: 74.9

Aromatic hydrocarbons 64742

- 94

- 5 100 ppm NA NA NA

NA=Not available

3. HAZARDS IDENTIFICATIONS

PHYSICAL PROPERTIES Appearance: Amber liquid

Odor: Aromatic hydrocarbons

EMERGENCY OVERVIEW Warning. May be fatal if swallowed. Causes substantial but temporary eye injury. Do not get in eyes or o n clothing. Wear protective eyewear (goggles, face shield, or safety glasses). Harmful if absorbed through skin. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or usi ng tobacco. Remove and wash contaminated clothing before reuse.

POTENTIAL HEALTH EFFECTS: Eye: Causes severe eye irritation

. Skin: Harmful if absorbed through the skin. Causes moderate skin irritation. Avoid contact with skin, eyes, or clothing.

Inhalati on : Harmful if inhaled; a void breathing vapor or spray mist. Ingestion : May be fatal if swallowed.

SYMPTOMS OF ACUTE EXPOSURE Large doses may cause incoordination, tremor, salivation, vomiting, diarrhea and irritability to sound and

touch.

4.FIRST AID MEA SURES

FIRST AID

• Immediately c all a poison control center or doctor.

• Do not induce vomiting unless told to do so by a poison control center or

doctor.

• Do not give any liquid to the person. IF SWALLOWED:

• Do not give anything by mouth to an unconscious person.

• Hold eye open and rinse slowly and gently with water for 15

- 20 minutes. IF IN EYES:

• Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.MATERIAL SAFETY DATA SHEET

Fanfar e ® 2EC Page 2 of 5

7

- 31

- 08 • Call a poison control center or doctor for treatment advi ce.

• Take off contaminated clothing.

• Rinse skin immediately with plenty of water for 15

- 20 minutes. IF ON SKIN OR
CLOTHING:

• Call a poison control center or doctor for treatment advice.

• Move person to fresh air.

• If person is not breathing , call 911 or an ambulance, then give artificial respiration, preferably mouth

- to

- mouth if possible. IF INHALED:

• Call a poison control center or doctor for further treatment advice.
Have the product container or label with you when calling a poison control center o r doctor or going for treatment. You may also contact 1

- 877

- 250

- 9291 for emergency medical treatment information.
NOTE TO PHYSICIAN: This product is a pyrethroid. If large amounts have been ingested, the stomach

and intestines should be evacuated. Treatmen t is symptomatic and supportive. Digestible fats, oils, or alcohol may increase absorption and should be avoided. This product contains a petroleum distillate ;

v omiting may cause aspiration pneumonia

.

5. FIRE FIGHTING MEASURES

FLASH POINT: 65 ° C (149 ° F ) ( Pensky

- Martens Closed Cup )
FLAMMABLE LIMITS : LFL /UFL : Not available

EXTINGUISHING MEDIA: Foam, CO 2 , dry chemical
FIRE & EXPLOSION HAZARDS: Moderately combustible. Found not to be explosive. Do not use or store near heat or open flame.

FIRE

- FIGHTING PRO CEDURES: Isolate fire area. Do not breathe smoke, gases or vapors generated.

FIRE

- FIGHTING EQUIPMENT: Wear self

- contained breathing apparatus and full

- protective clothing.
HAZARDOUS DECOMPOSITION PRODUCTS: None known.

6. ACCIDENTAL RELEASE MEASURES

ACTION TO TAKE FOR SPILLS/LEAKS: Clean up spills immediately, using precautions described in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering.

Keep material out of lakes, streams, ponds and sewer drains. To confine spill: If liquid, dike surrounding area or absorb with sand, cat litter or commercial clay; if dry material, cover to prevent dispersal. Place damaged package in a holding container. Identify contents.

Do not allow material to run off into soil, drainage syste ms, or bodies of water. Notify and consult with proper regulatory authorities.

7. HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING : Carefully open containers. After partial use, replace lids and close tightly. Do not put concentrate or dilute mat erial into food or drink containers. Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal.

PRECAUTIONS TO BE TAKEN IN STORAGE: Do not allow product to freeze. Do not store below 40 ° F ( 4 ° C). If crystals are observ ed, warm material to above 60 ° F ( 16 ° C) by placing container in warm location. Shake or roll periodically to redissolve solids. Keep out of reach of children and animals. Store in original container only. Store in cool, dry place and avoid excessi ve heat. Do not contaminate other pesticides , fertilizers, water, food, or feed by storage or disposal.

STORAGE TEMPERATURE (MIN/MAX): Do not store below 40 ° F (4 ° C)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PE RSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS
PRODUCT.

FOR COMMERCIAL APPLICATIONS AND/OR ON

- FARM APPLICATIONS CONSULT THE PRODUCT

LABEL.MATERIAL SAFETY DATA SHEET

Fanfar e ® 2EC Page 3 of 5

7

- 31

- 08 EYE PROTECTION: Protective eyewear

.

SKIN PROTECTION: Long

- sleeved shirt and long pants. Shoes plus socks.

HAND PROTECTION: Chemical

- resistant gloves , such as barrier laminate, nitrile rubber, neoprene rubber, or Viton

.

RESPIRATOR REQUIREMENTS: Not required

– Use normal safety precautions.

ADDITIONAL PROTECTIVE MEASURES: Disca rd clothing and other absorbent materials that have been drenched or heavily contaminated with this product’s concentrate. Do not reuse them. Follow manufacturer’s instructions for cleaning and maintaining PPE. If no such instructions for washables, use

de tergent and hot water. Keep and wash PPE separately from other laundry.

USER SAFETY RECOMMENDATIONS:

Users should: • Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. • Remove clothing immediately if pesticide gets inside . Then wash thoroughly and put on clean clothing.

EXPOSURE GUIDELINES: Refer to Section 2.

ENGINEERING CONTROLS: Use adequate ventilation to minimize airborne concentrations of this

material.

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Amber liquid

ODOR : Aromatic hydrocarbon
FLASH POINT: 65°C (149° F) ( Pensky

- Martens Closed Cup ) pH: 5.77

VISCOSITY: 4.415(20 ° C) & 2.739 (40 ° C)
MISCIBILITY: Product is miscible in oil
SOLUBILITY IN WATER: Soluble

DENSITY

: 0.976 g/ml
OXIDIZING OR REDUCIN G ACTIVITY : Compatib le with water, 10% monoammon i um phosphate solution, iron powder and Kerosene. Incompatible with 10% potassium permanganate solution

10. STABILITY AND REACTIVITY

STABILITY: Stable under normal use and storage conditions.
CONDITIONS TO AVOID: Excessive heat and fire.

POLYMERIZATION: Will not occur.

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY/IRRIT ATION STUDIES Acute Oral LD50 (Rat): 149.6 mg/kg Acute Dermal LD50 (Rabbit): > 2

, 000 mg/kg Acute Inhalation LC50 (Rat): > 2.06 mg/L (4 hrs.) Eye Irritation (Rabbit): Severely irritating
Skin Irritation (Rabbit): Moderately irritating Dermal Sensitization (Guinea Pig): Not a contact sensitizer

MUTAGENIC POTENTIAL:

Bifenthrin: None observed.

TERATOGENIC EFFECTS:

Bifenthrin: None observed.

12. ECOLOGICAL INFORMATION

ENVIRONMENTAL HAZARDS: This pesticide is extremely toxic to fish and aquatic invertebrates. Use with care when applying in areas adjacent to any body of water. Do not apply directly to water, to areasMATERIAL SAFETY DATA SHEET

Fanfar e ® 2EC Page 4 of 5

7

- 31

- 08 where surface water is present, or to intertidal area s below the mean high water mark. Do not make applications when weather conditions favor drift from treated areas. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. Do not contaminate water when disposing of eq uipment washwaters. This product is highly toxic to bees exposed to direct treatment or residues on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weeds while bees are actively visiting the treatment area.

ECOT OXICOLOGY: Bifenthrin is very highly toxic to fish, crustaceans and aquatic animals

. Care should be taken to avoid contamination of the aquatic environment. LC 50 : 0.00015 mg/L (rainbow trout), 0.00035 mg/L (bluegill), 0.0016 mg/L (daphnia).

Bifenthrin is moderately toxic to many species of bird.

LC 50 : 1,280 ppm (mallard duck) ; 4,450 ppm (bobwhite quail).

LD 50 : 2,150 mg/kg (mallard duck) ; 1,800 mg/kg (bobwhite quail),

Bifenthrin is toxic to bees.

13. DISPOSAL CONSIDERATIONS

PESTICIDE DISPOSAL: Pestici de wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agenc y, or the Hazardous Waste representative of the nearest EPA Regional Office for guidance.

CONTAINER DISPOSAL: Dispose of product containers, waste containers, and residues according to label instructions and local, state, and federal health and environment al regulations.

14. TRANSPORT INFORMATION

DOT CLASSIFICATION: UN 3352, Pyrethroid pesticides, liquid, toxic, 6.1, PGIII

NOTE: Combination packages with inner packagings less than 4 liters (1.057 gallons) may be reclassified as a Consumer Commodity (ORM

- D). These packages cannot be shipped by air freight.

NOTE: Consumer Commodity (ORM

- D) classification is for domestic surface/ground shipments only (4x1

- gallon and 4x1

- quart packages). Air shipments remain regulated.

INTERNATIONAL TRANSPORTATION: IMO (vessel): UN 3352, Pyrethroid pesticides, liquid, toxic (bifenthrin), 6.1, PGIII, Marine Pollutant

IATA (air): UN 3352, Pyrethroid pesticides, liquid, toxic (bifenthrin), 6.1, PGIII

15. REGULATORY INFORMATION

SARA TITLE III CLASSIFICATION:
Section 302: Not applicable.
Section 311/312: Acute health hazard (immediate)

Chronic health hazard (delayed)
Section 313: Bifenthrin (CAS # 82657

- 04

- 3) 25 .1 %

CA PROPOSITION 65: Not applicable
CERCLA RQ: Not applicable

RCRA CLASSIFICATION: U nder RCRA, it is the respon sibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be

classified as a hazardous waste.

TSCA STATUS:

The ingredients of this product are listed on the TSCA inventor y or exempt.

16. OTHER INFORMATION

HAZARD RATINGS NFPA HMISMATERIAL SAFETY DATA SHEET

Fanfar e ® 2EC Page 5 of 5

7

- 31

- 08 HEALTH: 2 2 0 MINIMAL

FLAMMABILITY: 1 1 1 SLIGHT
REACTIVITY: 0 0 2 MODERATE

3 HIGH

4 SEVERE

MSDS Date : 7

- 31

- 08; Supercedes version s dated: 3

- 14

- 08 and 5

- 24

- 04

. Changes made to Section 13

and 14

. The information herein is given in good faith, but no warrant, express or implied, is made. Consult

Makhteshim Agan of North America, Inc. for further information.