# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions**

Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information**

Parent Company

Name:

Address:

City: State: TX Zip Code: 75244

Country: USA

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): 3000

**PVC Production Facility General Information**

Facility Name:

Facility Address:

Facility City: State: TX Zip Code: 77503

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 146 Dallas 5005 LBJ Freeway, Suite 2200 Occidental Chemical Corporation

281-884-4047

tyrone_barren@oxy.com Oxy Vinyls, LP (Pasadena Plant)

4403 Pasadena Freeway

Pasadena

Tyrone Barren

# November 8, 2012 CAA Section 114 - Poly **viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**Form C-1-c Supplemental Questions FORM C-1-c**  **PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER** Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 39900 liters/hour liters Process Unit ID: U-1202 If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: Process Equipment ID: C-397 Wastewater Feed Rate (lb/hr): 87700 Not Available liters/hour (max design) Feed Temperature (°F): 140 liters (max design) Feed Inlet Pressure (psia): 15.2 Liquid Loading Rate (liters/m2): Not Available Steam Feed Rate (lb/hr): 6000 Steam to Feed Ratio (kg steam/liter of wastewater): 0.068 Operating Temperature (°F): 206 Operating Pressure (psig): 0.5 Total Number of Stages: 1 Overall Calculated Tray Efficiency: Not Available Stripping Factor: Not Available Flow configuration (countercurrent, cocurrent): Countercurrent Number of Actual Trays: 15 Column Height (meters): 9.04

Year Equipment Installed: 1977 Equipment Currently Regulated Under (cite regulations): 40 CFR 61, Subpart F, 40 CFR 61, Subpart V, 30 TAC 116 1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Stream Information**

**Instructions**

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3 4**  **5 6**  **7 8**  **9 10**  **11 12**  **13**

**Min Max**  **Average** C-1023 A Incinerator Absorber W ater Effluent W- 1043 0 108000 104000 Measured 365 C-1023 Incinerator Absorber WWT Biological W astewater Treatment Unit Yes C-1023 B Incinerator Absorber W ater Effluent W- 1043 0 108000 104000 Measured 365 C-1023 Incinerator Absorber WWT Biological W astewater Treatment Unit Yes C-1024 IncineratorScrubber Effluent W- 1046 0 43000 43000 Measured 365 C-1024 Incinerator Scrubber WWT Biological W astewater Treatment Unit Yes U-307 Dryer 1 CEW W-312 0 235000 201000 Measured 365 U-307 Dryer 1 Centrifuge WWT Biological W astewater Treatment Unit Yes U-407 Dryer 2 CEW W-412 0 251000 222000 Measured 365 U-407 Dryer 2 Centrifuge WWT Biological W astewater Treatment Unit Yes U-507 Dryer 3 CEW W-512 0 234000 210000 Measured 365 U-507 Dryer 3 Centrifuge WWT Biological W astewater Treatment Unit Yes U-607 Dryer 4 CEW W-612 0 210000 184000 Estimated 365 U-607 Dryer 4 Centrifuge WWT Biological W astewater Treatment Unit Yes U-707 Dryer 5 CEW W-712 0 250000 207000 Estimated 365 U-707 Dryer 5 Centrifuge WWT Biological W astewater Treatment Unit Yes U-807 Dryer 6 CEW W-812 0 260000 210000 Estimated 365 U-807 Dryer 6 Centrifuge WWT Biological W astewater Treatment Unit Yes U-907 Dryer 7 CEW W-912 0 336000 261000 Measured 365 U-907 Dryer 7 Centrifuges WWT Biological W astewater Treatment Unit Yes

Catalyst Bottle W ash W ater from Solution Prep Oily W ater Sump W- 1236 0 2000 1000 Estimated 365 U-1222 Catalyst Bottle W ashing Station WWT Biological W astewater Treatment Unit Yes

OxyVinyls believes that W -1236 is maintenace wastewater

**Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System 1**  **2 3**  **4 5**  **6 7**  **8 9**  **10 11**  **12 13** 

**Min Max**  **Average** U-1202 U-1207 Steam Stripping Continuous W1 222 0 212000 178000 Measured 365 WWT Oxy Vinyls W astewater Treatment Plant Yes **PVC Process Wastewater Stream Flow Rate**

**(gallons per day)**

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system**  **PVC Process Wastewater**  **Treatment System ID**  **PVC Process Unit ID**  **PVC Process Wastewater**  **Stream ID Is this** 
**process wastewater**  **treatment system batch**  **or continuous operation?**  **Flow Rate Determination**  **Method**

**14**

**PVC Process Wastewater Stream**  **Destination Code**

(Refer to Table 3 below) **Associated Destination Information** 

(Refer to Table 3 below) **Operating Days Per Year**  **Ty pe of Process**  **Wastewater Treatment System**  **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day) Flow Rate**  **Determination Method**  **2**

**Originating PVC Process Equipment ID**  **Operating Days Per Year**  **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process**  **equipment and its destination? Originating PVC Process**  **Equipment Description PVC Process**  **Unit ID Name of PVC Process Wastewater Stream**  **PVC Process Wastewater**  **Stream ID PVC Process Wastewater Stream**  **Destination Code**

(Refer to Table 3 below) **Associated Destination Information Table 3. PVC Process Wastewater Destination Codes Table**  **Code**
Wastewater treatment system WWT Provide name of the wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall Discharge to POTW , no treatment POTW RAW Provide name of POTW Discharge to PrOTW , no treatment PrOTW RAW Provide name of PrOTW Zero discharge or alternative disposal method ZEROALT Describe method Recycle to process RECYC Describe where in the process the stream is recycled Other OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System**
**2 3**  **4 5**  **6 7** 

**Min Max**  **Average Flow Rate**  **Determination Method**  **PVC Process Wastewater**  **Treatment System ID**  **Operating Days Per Year**  **Process Wastewater Stream Flow Rate**

**(gallons per day) Source of Process Wastewater Stream** 

**1 Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**  **Destination Description Instructions** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 01/14/13 01/15/13

1/15/2013 - 1/19/2013 1/15/2013 - 1/19/2013 1/17/2013 - 1/31/2013 PAS PVC WW Stripper Day 7 PAS PVC WW Stripper Day 8 PAS PVC WW Stripper Day 9 130047-8 130047-9 130047-10

**CAS No. HAP**  **Analysis Method Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

107211 Ethylene glycol SW-846-8015C 10 Non-detect 10 Non-detect 10 Non-detect 67561 Methanol SW-846-8015C 674 783 623 75070 Acetaldehyde SW-846-8315A 4.11 4.26 3.63 50000 Formaldehyde SW-846-8315A 0.075 Non-detect 0.075 Non-detect 0.15 Non-detect 51285 2,4-dinitrophenol SW-846-8270D 0.7 Non-detect 0.7 Non-detect 0.35 Non-detect 98862 Acetophenone SW-846-8270D 7.54 7.8 6.53 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.5 Non-detect 0.5 Non-detect 0.25 Non-detect

123319 Hydroquinone SW-846-8270D R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency 0.5 Non-detect 108952 Phenol SW-846-8270D 0.1 Non-detect 0.1 Non-detect 0.05 Non-detect 79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 106990 1,3-butadiene SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 540841 2,2,4-trimethylpentane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 71432 Benzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 108907 Chlorobenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 67663 Chloroform SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 126998 Chloroprene SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 98828 Cumene SW-846-8260B 0.001 Non-detect 0.002 J-estimated sample result 0.011 J-estimated sample result 75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.068 J-estimated sample result 100414 Ethylbenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.01 J-estimated sample result 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 74873 Methyl chloride (Chloromethane) SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 75092 Methylene chloride SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 110543 n-Hexane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 108883 Toluene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 79005 1,1,2-Trichloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 108054 Vinyl acetate SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 593602 Vinyl bromide SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 75014 Vinyl chloride EPA Method 107 0.097 0.011 0.018 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 1330207 Xylenes (isomers and mixtures) SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect No Reading 180 01/13/13

No Reading 170 180 175 Measured Measured Measured

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** suspension suspension suspension



### Page 1 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 01/16/13 01/17/13 01/18/13

1/17/2013 - 1/31/2013 1/18/2013 - 2/1/2013 1/21/2013 - 2/1/2013 PAS PVC WW Stripper Day 10 PAS PVC WW Stripper Day 11 PAS PVC WW Stripper Day 12 130047-11 130047-12 130047-13 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 530 519 649 4.79 5.78 4.62 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 7.38 7.13 3.99 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.5 Non-detect 0.5 Non-detect 0.5 Non-detect 0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 J-estimated sample result 0.005 J-estimated sample result 0.001 Non-detect 0.004 J-estimated sample result 0.004 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.019 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.003 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.047 0.010 Non-detect 0.010 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.003 J-estimated sample result 0.002 Non-detect 168 143 178 186 Measured Measured 158 182 Measured suspension suspension suspension



### Page 2 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 01/19/13 01/20/13 01/21/13

1/21/2013 - 1/30/2013 1/22/2013 - 2/5/2013 1/23/2013 - 2/5/2013 PAS PVC WW Stripper Day 13 PAS PVC WW Stripper Day 14 PAS PVC WW Stripper Day 15 130047-14 130047-16 130047-17 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 557 745 916 3.94 5.22 7.41 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 5.08 5.47 5.28 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.010 Non-detect 0.328 0.082 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect suspension

Measured 181 177 171

150 152 149 Measured Measured suspension suspension



### Page 3 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 01/22/13 01/23/13 01/24/13

1/23/2013 - 2/5/2013 1/24/2013 - 2/8/2013 1/25/2013 - 2/13/2013 PAS PVC WW Stripper Day 16 PAS PVC WW Stripper Day 17 PAS PVC WW Stripper Day 18 130047-18 130213-1 130213-2 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 673 663 548 5.93 8.15 4.43 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 5.42 4.72 6.22 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.005 J-estimated sample result 0.002 J-estimated sample result 0.001 Non-detect 0.068 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.009 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.003 J-estimated sample result 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.010 Non-detect 0.224 0.010 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 162 157

150 Measured Measured 152 suspension

Measured 170

156 suspension suspension



### Page 4 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 01/25/13 01/26/13 01/27/13

1/26/2013 - 2/8/2013 1/29/2013 - 2/9/2013 1/29/2013 - 2/14/2013 PAS PVC WW Stripper Day 19 PAS PVC WW Stripper Day 20 PAS PVC WW Stripper Day 21 130213-3 130213-5 130213-6 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 722 697 722 5.78 3.88 4.7 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 5.76 7.21 7.22 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 J-estimated sample result 0.001 Non-detect 0.004 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.002 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.150 0.090 0.024 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 177 176 172

156 153 150 Measured Measured Measured suspension suspension suspension



### Page 5 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 01/28/13 01/29/13 01/30/13

1/31/2013 - 2/14/2013 1/31/2013 - 2/17/2013 1/31/2013 - 2/17/2013 PAS PVC WW Stripper Day 22 PAS PVC WW Stripper Day 23 PAS PVC WW Stripper Day 24 130213-7 130213-8 130213-9 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 832 621 787 5.65 4.41 5.18 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 3.94 7.66 4.52 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 J-estimated sample result 0.001 Non-detect 0.002 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.015 0.010 Non-detect 0.010 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 175 175 suspension

152 Measured Measured Measured 171

154 149 suspension suspension



### Page 6 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 01/31/13 02/01/13 02/02/13

1/31/2013 - 2/17/2013 2/4/2013 - 2/17/2013 2/4/2013 - 2/18/2013 PAS PVC WW Stripper Day 25 PAS PVC WW Stripper Day 26 PAS PVC WW Stripper Day 27 130213-10 130213-11 130213-12 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 587 791 780 4.14 5.38 5.41 0.15 Non-detect 0.15 Non-detect 0.247 J-estimated sample result 0.35 Non-detect 0.35 Non-detect 0.7 Non-detect 7.71 5.43 11 0.25 Non-detect 0.25 Non-detect 0.5 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.1 Non-detect 0.002 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.005 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.006 J-estimated sample result 0.002 J-estimated sample result 0.001 Non-detect 0.03 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.033 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.016 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.010 Non-detect 0.010 Non-detect 0.906 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 170 172 suspension suspension suspension 172 Measured Measured Measured 152 155 153



### Page 7 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 02/03/13 02/04/13 02/05/13

2/4/2013 - 2/17/2013 2/4/2013 - 2/11/2013 2/5/2013 - 2/17/2013 PAS PVC WW Stripper Day 28 PAS PVC WW Stripper Day 29 PAS PVC WW Stripper Day 30 130213-13 130213-14 130213-16 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 736 689 787 6.09 6.02 7.44 0.15 Non-detect 0.216 J-estimated sample result 0.15 Non-detect 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 9.54 5.84 5.9 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 J-estimated sample result 0.003 J-estimated sample result 0.001 J-estimated sample result 0.002 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.036 0.010 Non-detect 0.010 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect Measured Measured 160 170 165 suspension suspension suspension 165

156 159 Measured



### Page 8 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 02/06/13 02/07/13 02/08/13

2/6/2013 - 2/17/2013 2/8/2013 - 2/18/2013 2/8/2013 - 2/18/2013 PAS PVC WW Stripper Day 31 PAS PVC WW Stripper Day 32 PAS PVC WW Stripper Day 33 130213-17 130213-18 130213-19 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 932 932 856 7.23 6.95 6.2 0.15 Non-detect 0.15 Non-detect 0.203 J-estimated sample result 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 8.42 7.01 7.64 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 J-estimated sample result 0.001 J-estimated sample result 0.001 J-estimated sample result 0.003 J-estimated sample result 0.003 J-estimated sample result 0.001 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 J-estimated sample result 0.002 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.017 0.017 0.029 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

Measured 160 Measured Measured 153 153

155 155 suspension suspension suspension 155



### Page 9 of 10**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Resin Ty** **pe (suspension, dispersion, bulk, etc.) -->**

**Flow Rate Determination Method -->**

**Sample Date -->** 02/09/13 02/10/13 02/11/13

2/12/2013 - 2/18/2013 2/12/2013 - 2/18/2013 2/12/2013 - 2/18/2013 PAS PVC WW Stripper Day 34 PAS PVC WW Stripper Day 35 PAS PVC WW Stripper Day 36 130213-21 130213-22 130213-23 **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 1020 1000 1060 5.05 5.3 4.82 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.35 Non-detect 0.35 Non-detect 0.35 Non-detect 6.91 5.05 6.98 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R result rejected due to poor analyte efficiency R result rejected due to poor analyte efficiency 0.5 Non-detect 0.05 Non-detect 0.05 Non-detect 0.05 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 J-estimated sample result 0.002 J-estimated sample result 0.001 J-estimated sample result 0.001 Non-detect 0.001 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 J-estimated sample result 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.013 0.021 0.010 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect suspension suspension suspension

Measured 177 175

162 154 Measured Measured 175

160



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