.1

# IlIAdvance Environmental

.Associates,

# U.C
. April 11, 2001 Mr. Donald E. Sulton, P.E. Manager, PermitSection Bureau ofAir. Illinois Environmental Protection Agency 1021 North GrandAvenue East Springfield, IL 62794-9276 RE: Showing Compliance with 35 lAC 215 SubpartK. CrownlineBoats 11884 Country Club Road West Frankfort, IIIinois 62896 Source ID No.

- 055070AAU Dear Mr. Sutton: 300 S. SecondStreet St. Chorles, MO 63301 (636) 916·4800 Fox(636) 916-3717 E-Mail: AEA@AclvonceEnvironmento/.com

(

. i

\ ,1 As we discussed during ourphone conversation on April 4, 2001, AdvanceEnvironmental Associates, LLC (AEA) is currently assisting Crownline Boats, Inc. 'tohelp finalize iheirTitle V operating permitby working closely with Mr. NathanFrank, thereview engineerassigned to write theirpermit. Uponreviewing the draftTitleVpermit, we discovered asignificantproblem with respect to demonstrating on-going compliance with the "Use ofOrganicMaterial" regulation, i.e., 35 lAC 215 SubpartK. The rule statesthat, " nopersonshallcause orallow the discharge of more than 

### 3.6kg/hr (8Ib/hrJ of organic materialinto the atmospherefrom any e;'ission source, except ". Theproblem with the operatingpermit as now written is how the term "emissionsource" is defined inreference to demonstrating compliancewith this rule. In this regard, we·have.become ratherfrustrated trying to obtain a cons·istent and appropriate determination from the Illinois EPA on exactly how this rule shouldlie applied to theboat manufacturing.operations at CrownlineBoats, Inc. inWest Frankfort, :illinois.-Ourfrustration stems from two facts. The first is thatthere appears to be no clear cutdefinition inthe illinois rules ofthe term "emission source" as usedinthe contextof35 lAC 215 SubpartK ("the 8 lb/hr rule"). The second is from ourrepeated attempts to havethis clarifiedby the IEPA only to be given conflicting definitions from three different IEPA engineers for the tenn "emissions source"

. in this rule.

To help resolve the issue ofproperly defining the term "emissionsource" forpurposes of applying the.8lblhrrule to fiberglass boatbuilding, we would like to suggestadefinition thatis both based onthe specificboatbuilding activities at CrownlineBoats and on whatwebelieve to be the intent ofthe rule. To do so, we believe it is important to-tirst describe theboatbuilding process at Crownline Boats, The CrownlineBoats production processes include the following production areas (insequence): 1) Prototype Shop

- boatmolddevelopment; 2) GelcoatApplication Area

- gelcoatcoating is appliedto the pre-formedboatmolds (single applicationpermold);Mr. DonaldE. Sutton, P.E. April 11, 2001 'Page 2of3 3) LaminationArea

- glass fibers, polyesterresin and catalyst are applied

# to thebOat mold (multiple applications permold, 

### Le., 2 to 3 "skins" perboathull depending on model and size); 4) Grind andTrim Area

- cutexcess material from the fiberglass part/smooth rough surfacesllaminate floor support structure and floorto hull;

. 5) Woodworking Area- construction ofseatframes, interior cabinets, wood decks, etc. 6)

.Upholstery Area- assembles the seats and.othervinyl fabric products required in.the boats 7) FinalAssembly Area

- hulls and decks are assembled to complete the boat structure, all mechanical equipment is installed and all otherequipmentinstalled to finish boat;

. . . 8) Shipping

- finished boatis cleaned, inspected, engine tested andboat is preparedfor

. shipment. Please note that the areas shown inboldtypeface representthose areas where the majority of YOM-containing materials are used (e.g., gelcoats, resins, etc.) Ofthe above-listed steps, three ofthese areas (gelcoat, lamination, and grind & trim) release the majority ofYOM to atmosphere. These are discussed in greaterdetailbelow.

. The boat manufacturing process involves the "building" ofeachboaiin several steps using gelcoat andfiberglass reinforcedresin materials that contain organic materials. Eachboat model built consists oftwo primary parts (thehull and the deck). and one secondary part (the flooring structure. The "building" ofeachhull and deckinvolves several steps. Both the hull and·deckfor eachboatmodel are builtby first applying alayer ofgelcoat material to

# a mold ofthe respective part, followed bycuring and then the application oflaminate (fiberglass reinforced resin) material in two to three layers, or "skins". The size oftheboat determines whethertwo orthree skins mustbe applied. Each skin mustbe allowedto cure or "set" before the nextlayer canbe applied. The flooring. structure is then builtinto the boat hull by manually applying laminatematerialover the fiberglass cloth-covered floorpieces. Theflooring resin is then allowed to setbefore the boat is ready for final assembly Goining ofthe deckto theboathull). The s,teps described above constitute the boatbuildingprocess, which averages approximately 22hours to complete. This is the typical time frame that is needed to build the boat "structure"before itis ready for finishing (addition ofengine, steering, seats, and othermechanical components and accessories). It represents the time from the start ofgelcoat appiication to aboaimold (hull ordeck) to the time when the boatis ready for finishing. This time frame includes bothfuetime for application of

.gelcoats and resins and the time to allow these materials to properly cure. The 22 hours required forthe above-describedboatbuildingprocess to be completedlargely consists of (1) the time for both applying the**VOM~containing** materials (gelcoat andresin) and (2) the time needed for these materials to properly cure. The curing step is important

### ~ith**~espect** to the release ofYOM in that apartofthe YOM (styrene and othervolatile organics) is released during application (approximately 70% perNMMAdata) and thebalance during the curing period. However, otherfactors enterinto the total actual timerequiredto complete the boat structure. That is, Crownline makes a variety ofboatmodels and sizes depending on customer demand (sales). Therefore, any combination ofboatmodels and sizes canbeproducedduring

. any given day. From startto finish (boatready to be shipped) itCan take up to as long as 3 calendardays to build acompleteboat. The range ofboat. sizes producedis 18 to29 feet in length. There are many instances where a deckmay be gelcoated and then sit for several hours before lamination is started orthe time between application ofresin skins may vary. The dailyMr. DonaldE. Sutton, P.E. April 11, 2001 Page 3 of3 sequences and time frames depend on such variables as production schedule (whichtypically varies daily) andthe availability ofthe various work crews. Based on the foregoing discussion, we believe that the "process" ofbuilding the

### strucrdTe ofan . individual boat (as described above) is well suited for the definition of "emission source". We believe this is appropriate in thatthe boat "buildingprocess" consists ofboth application and curing time. Therefore, the hourly YOM emissions shouldbe computed onthe basis ofthe total time for the completion ofall activities required to build any givenboat structure (including gelcoat and resin application and curing time forbuilding ofthe hull, deck andfloor suucrure of the boat), Le., approximately 22hours. Accordingly, the 8 lb/hrrule wouldthenbe applied to the amount ofYOM emitted perhour, averaged overthe entire term ofthe process (approximately 22 hours). We believe this meets the intent ofthe rule in thatthe rule was intended for continuous operations, i.e., for operations thatemit YOM continuously (e.g., 24 hours/day).**Sinc~** the process ofbuilding the structure ofaboat involves individual steps (during which time Va!;! emissions vary significantly from hour to hourper boatbeing built), webelieve itis reasonable and appropriate to apply the 8lb/hrrule to the averageYOM emissions value computed from the entiretime it takes to build a givenboat (e.g.,. overthe period of approximately 22 hours)

.. Furthermore, the rule was intendedto limit the total amount ofYOM emittedfrom asourcefor purposes ofpreventing ozone formation. In this regard, the individual hourly rate ofVOy! emissions is not imponantto protectagainst ozone formation; the total amount is, however. Finally, we believe it is important to considerthe fact that Crownline Boats will reduce its YOM emissions when it complies withtheproposed BoatManufacturing MACT Standard. We would ask thatyou give our suggested approach to applying the 8lb/hrrule, as descnbed above, your serious consideration. If youhave any otherquestions, please contactme in Sr. Charles, Missouri at 636-916-4800. Sincerely,

Andrew

### J. Polcyn 

### President

cc: DavidMcKenzie

- Crownline Boats

# Appendix 6 Development ofEquations ForExtrapolating NMMAEmission Factors to Calculate Styrene and Methyl Methacrylate (MMA) Emissions From the Application ofGelcoats and Resins to Boat Hulls And Decks Considering Varying Boat Length

..and OtherVariables

# Appendix 6

Development ofEquations For ExtrapolatingNMMA Emission Factors to Calculate Styrene and Methyl Methacrylate (MlVlA} Emissions Fromthe Application ofGelcoats and Resins to BoatHulls. and Decks ConsideringVarying Boat Length and OtherVariables Preface: The NM:MA emission factors forresin and gel coat applicationto boathulls arebased ontestdata for two boat lengths ofi8 feet and28 feet. To derive emissionfactors forthe application ofresin and gelcoat to boats hulls ofotherlengths (between 18 and 28 feet, or greaterthan28 feet) an equation canbe easily developedusing these two datapoints. However, theNM:MA emission factors for application ofresin and gelcoat to boatdecks werebased ontest datalimitedto onlya singleboat length of18 feet. Sincetwo points are requiredin orderto create an equationfor purposes ofinterpolating orextrapolating emissionfactors forboat decks ofvarying lengths, the secondpoint (emission factor for a28 footboatdeck) hadto be artificially derivedby assuming that therate atwhich emissions increase from resin and gelco'at applicationto an 18 foot versus a 28 footboat deckis the same as therate atwhich emissions increase for resinand gel coat applicationbetween an 18 foot and a 28 foot boathulL By assuming that the slopefrom the graph createdbyplotting the emissions for an 18 foot versus a 28 foot hull is the same as the slope of the graph for application ofresm. and gelcoatto boatdecks, the emissionvalue for a 28 footboat canbe derived. This is referredto as the "point/slope" methodofderivipg an equationfrom a singlepoint and aknown slope ofthe corresponding graph.



# - . Similarly, the·NMMA emissionfactors were developed from test datathatwasJimitedto onlytwo values ofstyrene contentinresins. Consequently, another set ofequations hadto be developedto take this variable factor into accountin orderto derive emission factors forresins ofvarying styrep.e content. Finally, yet another setofequations hadto be developedto take into account different application methods (airatomized versus lowpressure, non-atomized, orflow coat-type ofapplication). The tables, graphs and equations thatfollow demonstrate the detailed step-by-step procedureused to derive the various equations necessaryto properlyt4einto account all ofthe variables (boat length, hulls vs. decks, varying styrene andMMA contents andmethod ofapplication) that affect the extrapolation ofemissionfactors from the limitednumberofdatapoints uponwhich the NMMA factors arebased.

## Exhibit 1a ofAttachment 6 Extrapolation of Emission Factors for Gelcoat Application

Table1. Styrene Emissions Data from Table2-1, NMMA Baseline Emissions Report Styrene Emissions As Percent ofAvailable 

### , Description Styrene, P , . The NMMA report**show~d** only one emissLan value for 

### 18 ft 

### Hull 46.4% application to decks. This was for an 18 foot deck. Two '. data points are required to" develop an emission factor 

### 28 ft 

### Hull 50.4% equation based on boat length. The value of46.3% fOF the 28 foot deck was derived by assuming the increase in the amount of emissions from an 18 foot deckto a2810at deck 

### 18 ft 

### Deck 42.3% is similarto that of an 18 foot hull to a28 foot hull. That is, 

### 28 ft 

### Deck 46.3%'- the slopes of the line connecting the data points for hulls was the same as that for decks and asecond emission

. data point for28 foot decks was obtained. Sse Figure 1 below. 

### Table 2 Coordinates for Graph (Shown in Figure 1) Boat Percent Emitted, P Lenath, BL Hulls

.Decks 18 46.4

. 42.3 28 50.4 46.3
Figure 1. Graph for Deriving Extrapolated Emission Factors to· Calculate Styrene Emissions from Gelcoat • Application for Boat Hulls and Decks at Variable Lengths.

--Hulls 

### -II-: Decks

30 26 28 Decks 

### y= OAx + 35.1
24 22 .18 20 HuJls y = OAx + 39.2

42 41**+--~--~-~-~~-~-~-___j** 16 51 

### -r-----'------------, 50 <ll

- C. 49 .0 • 48 

# "'


# ... > 47 

# « E '0 UJ 46

... Q) 45 <: <: 44

... ;., Q)

..... 43 

### c. VJ



### Boat Length, BL

Appendix 6

- Page 1 Crownline Boats, Inc VVestFrankfort,IL

## Exhibit 1a of Appendix 6 (continued)
! 

### Table3. MMA EmissionsDatafrom Table2-1 NMMA Baseline Emissions Report , 

### MMA Emissions As Percent ofAvailable , 

### Description MMA , Jne NMMA report showed only one emission value for 

### 18 ft Hull 73.2% application to decks. This was for an 18 foot deck. Two data points are required to develop an emission factor 

### 28 ft Hull 78.6% equation based on boat length. The \lalue of 81 ;0% for the 28 foot deck was derived by assuming the increase in the amount of emissiof]s from an 18 foot deck to a 28"foot deck 

### 18ft Deck 75.6% is similarto that of an 18 foot hull to a 28 foot hull. Tha"t is, 

### 28 ft Deck 81.0%

.... the slope of the lines connecting the data points for hulls was the same as that fordecks and a second emission cata point for 28 foot decks was Obtained. See Figure 2 :.eJow. 

### Table 4. Coordinates for Graph (Shown i

. Boat Percent Emitted, P Length,BL Hulls Decks 18 73.2 75.6 28 78.6 81.0 n Figure 2)

Figure 2.

. Graph for Deriving Extrapolated Emission Factors to Calculate MMA Emissions from GelcoatApplication for Boat Hulls and Decks at Variable Lengths.

-+-:- Hulls ---llI- Decks

30 (28, 81.0)

Hulls y

### =O.54x + 63.48
18 20 22 24 26 .28 Boat Length, BL (18,73.2) Decks 

### y= O.54x + 65.88 83 -,------------------, 82 81 80 ell 

# :c a. 79 

# '" = .,j 78**·~.B77 «~**  - E 76 

### .:: w 75 t: 74 73 

### a. 72 71**+---,-----,---~-__,__-_,_-_,.----1** 16

Appendix 6 - Page 2 Crownline Boats, Inc WestFrankfort, IL

## Exhibit 1b ofAppendix 6 Demonstration of How Emission Equations Shown in Figures 1 and 2 Were Derived.

The equations shown in Figures 1 and 2 were derived using the slope intercept method of deriving an equation from two data points. An example ofthis method ofderivation is shown below: Example:

. Styrene Emissions from the application of Gelcoat on Hulls

- 

### Boat Percent Length, 

### BL Emitted, P x 

## y ·18 •. 46.4 28 50.4 Derive the slope ofthe function, m. Given: y = mx 

### + 

### b

m 

### = (50.4
- 46.4)/(28-18) 

### = 0.4 Use a single data point and the slope, m, to 

### derive the y-intercept, b.

b

# =46.4
- 0.4(18)

# =39.2 Therefore, 

### P = O.4BL + 39.2 Table 5 Summary of Equations Developed from Figures 1 and 2. Styrene MMA Equation for Hulls: Percent Emitted Equation for Hulls: Percent Emitted P = O.4BL 

### + 39.2 P

# = O.54BL 

### + 63.48

- 

### Equation for Decks: Percent Emitted Equ'ation for Decks: Percent Emitted

. 

### P= O.4BL 

### + 35.1 P

# = O.54BL 

### + 65.88 Where: P = Percent ofAvailable Emitted BL = Boat Length (feet) Appendix 6
. Page 3 Crownline Boats, Inc WestFrankfort, IL

## Exhibit 2a of Appendix 6 Data Used for Extrapolation Method of Deriving Styrene Emission Equations for Resin Application (Atomized Spray and Flow Coat) Table 6. Emissions Data from Table2-1, NMMA Baseline Emissions Report Using 42% Available Styrene Resin Atomized Spray Emissions As Percent ofAvailable Description Styrene

18 ft Hull 20.7% 28 ft Hull 23.3% 18 ft Deck 21.1% 28 ft Deck 23.7%1 Using 42% Available Styrene Resin 

# . . 

## . Flow Coat Emissions As Percent ofAvailable Description Styrene

18 ft Hull 11.4% 28 ftHull 14

..0%2

. 18 ft Deck 13.4% 28 ft Deck 16.0%2 Using 35% Available Styrene Resin Flow Coat Emissions As Percent ofAvailable Description Styrene

18 ft Hull 10.8% 28 ft Hull 13.3%2



# . 18 ft Deck 11.9% 28 ft Deck 14.4%2 Using 35% Available**~tyrene** 

### Resin Atomized Spray

. 

### Emissions As Percent ofAvailable Description .Styrene

18 ft Hull 14.8% 28 ft Hull 17.3% 18 ft Deck 12.9% 28 ft Deck 15.4%1 (1) The NMMA report showed only one emission value for application of Resin to decks. This was for an 18foot deck. Two data points are required to develop an emission faetro equation based on boat length. The values 23.7 and 15.4 were derived from existing data for hulls by assuming the increase in the amount of emissions from an 18 foot**dec~** to a 28 footdeck is similarto that of an 18 foot hull to a 28 foot hull. That is, the slopes of the line connecting the data points for hulls were the same as those fordecks and a second emission data point for 28 foot decks was obtained using the point-slope method

.. (2) The NMMA report showed only one emission value for application of Resin to decks and one for the application of Resin to hulls. These were for an 18 foot deck and for an 18 foot hull. Two data points are required to develop an emission factor equation based on bQat length. The required values for 28 foot decks and "hulls were derived by assuming the increases in the amount of emissions from an 18 foot deck to a 28 foot deck and from an 18 foot hull to a28 foot hull for. flow coat application are similarto that for atomized spray. That is, the slopes ofthe lines connecting the data points for atomized spraywere the same. as the slope forflow coat application and the second emission data points for 28 foot decks and hulls was obtained using the point-slope method.

Appendix 6 - Page 4 Crownline Boats, Inc WestFrankfort, JL

## Exhibit 2b ofAppendix 6 Styrene Emissions from Resin Application Using Atomized Spray

Table 7 Coordinates for Graph
- 42% Resin, Atomized Spray(Shown in Figure 3) Boat Percent Emitted, P Length, BL Hulls Decks 

### 18 20.7 21.1 28 23.3 23.7

- 

### Figure 3. Graph for Deriving Extrapolated Emission Factors to

. . 

### Calculate Styrene Emissions from 42% Styrene Resin
- Atomized SprayApplication for Boat Hulls and Decks at Variable Lengths. 25.,..------------------,**~a.** 24



# - :: al 23 

# "'- >;::: 

# « E 

## '0 W 22

- OJ 

# " " E 21.



### .... » OJ

- 

### a. 

### rn 20 Decks 

### y

### =O.26x + 16.42

Hulls y 

### =O.26x 

### + 16.02 

### --+- Hulls -'lii--- Decks

19 -'-- ......J Boat Length, BL



### Equation for Hulls: Percent Emitted (P) 

### Equation for Decks: Percent Emitted (P) 

### P 

## =0.26BL + 16.02 P 

## =0.26BL + 16.42
These Equations are derived using linear regression; or the slope inter.cept method of deriving an equatibn from.two data points. An example ofthis derivation is presented In Exhibit 1b.

Appendix 6 - Page 5 CrownlineBoals, Inc WeslFrankfort, IL

## Exhibit 2b of

## Appendix 6 (continued)

Table 8 Coordinates for Graph
- 35% Resin, Atomized Spray (Shown in Figure 4) Boat Percent Emitted,P Lenqth, BL Hulls Decks 18 14.8 12.9 28 17.3 15.4 Figure 4. Graph for Deriving Extrapolated Emission Factors to Calculate Styrene Emissions from 35% Styrene Resin - Atomized Spray Application for Boat Hulls and Decks at Variable Lengths.. 18 Hulls ",. 17 Y= 0.25x + 10.3 -0- .c •**~"C** .- 

# '" 10_ 16 

### >- ::: 

### <t 

### E -w 15 o '" 

# - " " '" '"

.... 14**~Z" ~lIJ**  13 12 -+-Hulls --Decks

Decks 

### y= 0.25x + 8.4
Boat Length, BL



### Equation for Hulls: Percent Emitted Equation for Decks: Percent Emitted 

### P

# =0.25BL 

### + 10.3 

### P = 0.25BL 

### + 8.4
These Equations are derived using linear regression, orthe slope intercept method of deriving an equation from two data points. An example of this derivation is presented in Exhibit 1"

.

Appendix 6

- Page 6 Crownline Boats, Inc WestFrankfort, IL

## Exhibit 2b of Appendix 6 (continued) Table 9. Summary of Equations forAtomized SprayApplication of Resins Developed from Figures 3 and 4 Presented as Functions of Boat Length. 35% Styrene Resin Equation for Hulls: Percent Emitted 

### P 

## =0.25BL 

### + 10.3

42% Styrene Resin Equation for Hulls: Percent Emitted 

### P

# = 0.26BL 

### + 16.02

. 

### EHuation for Decks: Percent Emitted 

### P

# =0.25BL 

### + 8.4

Equation for Decks: Percent Emitted 

### P

## =0.26BL + 

### 16.42

In order to obtain a Percent Styrene Emitted equation as a function not only of Boat Length, (BL), but also of the Styrene' content of the Resin used, (ST%), a second set of equations are derived using the slope-intercept method. These equations are derived using the existing equations (listed above) as the values for 

### Y1 and yz and the Styrene. content percentages 35% and 42% as X 1 

### and Xz. Hulls
- Atomized Percent Percent Styrene, ST% Emitted, P x) (y) 35 0.25BL 

### + 10.3 42 0.26BL 

### + 16.02

. Given: y

# =mx + b Decks
- Atomized Percent Percent Styrene, ST% Emitted, 

## P (x) 

### (y)

. 

### 35 0.25BL 

### + 8.4 42 0.26BL + 16.42 (Same procedure as for Hulls)

m

# =((0.26BL 

### + 16.02)
- (0.25BL 

### + 10.3»/(42-35)

m

# =**(0~01** 

### BL 

### + 5.72)/7 b 

### = yz - mxz 

### = (0.26 

### + 16.02)
- ((0.01 BL 

### + 5.72)/7)(42) b

# =0.2BL
- 18.3 P

# =(((0.01 BL + 5.72)/7)ST% + (0.2BL-18.3» Appendix 6

-Page 7 CroWIilineBoats, Inc WestFrankfort, IL

## Exhibit 2c ofAppendix 6 Styrene Emissions from Resin Application Using Flow Coat

Table 10 Coordinates for Graph
- 42% Resin, Flow Coat (Shown in Figure 5) Boat Percent Emitted, P Length, BL Hulls Decks 18 11.4 ' 13.4 28 14.0 16.0 

### ! 

### I '
Figure 5. , Graph for Deriving Extrapolated Emission Factors to Calculate Styrene Emissions from 42% Styrene Resin
- Flow Coat Application'for Boat Hulls arid Decks at Variable Lengths.
16.5 

### .5!!c.. .l:l' Ol • 15.5 _"0 "co 

### > :!= 14.5 

# « E '0 W 13.5

..... Q> t: t: Q> 12.5 u 

### >-


# ........ en 11.5 , Decks 

### y 

### = 0.26x + 

### 8.72

Hulls 

### y

# =0.26x 

### + 6.72 --+- Hulls -ii-Decks

10.5 -'- _J 

### Boat Length, BL

Equation for Hulls: Percent Emitted Equation for Decks: Percent Emitted

. 

### P 

### = O.26BL 

### + 6.72 P

# = O.26BL 

### + 8.72
These Equations are derived using linear regression, orthe slope intercept method of deriving an equation from two data points. An example ofthis derivation is presented in Exhibit 1,

Appendix 6 - Page 8 Crownline Boats, Inc WestFrankfort, 1L

## Exhibit 2c ofAppendix 6 (continued)

Table 11 Coordinates for Graph
- 42% Resin, Flow Coat (Shown in Figure 6) Boat -Percent Emitted, P Length, BL Hulls Decks 18 10.8 11.9 28 13.3 14.4 Figure 6. Graph for Deriving 'Extrapolated Emission Factors to Calculate Styrene Emissions from 35% Styrene Resin
- Flow Coat Application for Boat Hulls and Decks at Variable Lengths. 15**~c..** 14 ..c • "'"0 

## == QJ 

# '"

# - 13**>~** c( 

### E 'C;" LU 12 

# - '" 

# " 

# " ., 

# '" " '- 11 '- >. 

# .,- a. Ul 10 9 Decks y = a.25x+ 7.4

--HuJls --Decks HuJls 

### y= a.25x+ 6.3

Boat Length, BL

- 

### Equation for Hulls: Percent Emitted Equation for Decks: Percent Emitted P

# =O.25BL 

### + 6.3 

### p= O.25BL +7.4
These Equations are derived using linear regression, orthe slope intercept method of deriving an equation from two data points. An example ofthis derivation is presented in Exhibit 1.

Appendix 6 - Page 9 Crownline Boats, Inc WestFrankfort, IL

## Exhibit 2c ofAppendix 6 (continued) Table 12. Summary of Equations for Flow Coat Application of Resins Developed from Figures 5 and 6 Presented as Functions of Boat Length. 35% Styrene Resin

. Equation for Hulls:Percent Emitted 

### P = 

### O.25BL 

### + 6.3

42% Styrene Resin Equation for Hulls: Percent Emitted 

### P

# =O.26BL 

### + 6.72

. I 

### . squatioll for Decks: Percent Emitted 

### P

# =O.25BL + 

### 7.4

Equation for Decks: Percent Emitted 

### P

# = O.26BL 

### + 8.72

I . 

### In order to obtain a Percent Styrene Emitted equation as a function not only of Boat Length, (BL), but also of the Styrene content of the Resin used, (ST%), a'second set of equations are derived using the slope-intercept method. These equations are derived using the existing equations (listed above) as the values for y, and yz and the Styrene content percentages 35% and 42% as X1 and Xz. Hulls
- Atomized Percent Percent Styrene, ST% Emitted, P' x) y) 

### 35 0.25BL + 6.3 42 0.26BL + 6.72 Given: y = mx +b Decks
- Atomized Percent Percent Styrene, ST% Emitted, P x) ( ). 

### 35 0.25BL + 7.4 42· 0.26BL + 8.72 (Same procedure as for Hulls)

I . 

# I m 

### = ((0.26BL + 6.72)
- (0.25BL + 6.3))/(42-35)
m = (0.01 BL + 0.42)/7 b

# = yz - mxz

# = (0.26 + 6.72)
- ((0.01 BL + 0.42)/7)(42) b 

### = 0.2BL
- 4.2. P 

### = (((0.01 BL + 0.42)/7)ST% + (0.2BL-4.2)) Appendix 6 -Page 10 CrownlineBoats, Inc WestFrankfort, IL

## Exhibit 2d ofAppendix 6 Summary of Emissions Equations Derived for Resin Application

Table 13 Equations for the Percent of Styrene Emitted from the Use of Resin Atomized Spray Flow Coat . 

### Equation for Hulls: Percent Emitted Equafion for Hulls: Percent Emitted P

# = «O.01BL

### + 5.72)/7)ST% 

### + (0.2BL -18.3) P

# = ((0.01 BL 

### + 0.42)/7)ST% 

### + (0.2BL 

### +4.2)

. 

### Equation for Decks: Percent Emitted Equation for Decks: Percent Emitted
I· 

### P

# = ((0.01 BL 

### + 8.02)/7)ST% 

### + (0.2BL ·31.7) P

# = ((0.01 BL 

### + 1.32)/7)ST% 

### + (0.2BL 

### + 0.8) Where: P 

### = Percent ofAvailable Emitted BL 

### = Boat Length (feet)

.. ST% 

### = Percent ofAvailable Styrene in the Resin

Appendix 6 - Page 11 Cro'\\'nlineBoats, Inc WestFrankfort,IL

## Exhibit 3 of Appendix 6 YOM Emissions From Plant Gelcoat and Resin Application Operations Pre-MACT Scenario· Using production data and material usage data for 2003
- assuming production and material use forAugust -Decemberwere the same as for July 2003
- an annual. YOM emission value was calculated. This annual 

### V0t0 emission value was calculated assuming Crownline was operating like they were priorto making changes to comply with MACT. That is, the following assumptions were made: 1. The production resin was42% styrene instead ofthe low styrene 33.5%, 2. The Spraycore 1800 and 2000 were the high styrene versions, 3. The J:11oonstone and opal gelcoats were the high YOM content versions, and 4. All resins were applied using atomized spray. Table 14 Boat Production Resin and Gelcoat Use, and YOM Emissions. , 

### Other Resin Gelcoat Materials Total Amount YOM Amount YOM YOM YOM, Boats Used· Emissions Used Emissions Emissions Emissions Month Produced 1 

### (tons) (tons)2 (tons) (tons)3 (tons)4 (tons) January 361 190.9 9.90 25.3 5.39 3.97 19.26 February 355 187.1 9.73 32.4 6.72 3.72 20.17

.March 375 251.3 12.75 36.6 7.64 3.38 23.77 April 374 198.4 9.76 38.6 8.08' 5.43 23.27 May 473 291.8 14.01 36.0 7.46 4.33· 25.80 June 390 .186.1 9.19 39.7 8.41 2.81 20.41

July 354 198.0 9.32
. 22.4 4.62 4.75 18.69 August5 

### 354 198.0 9.32 22.4 ·4.62 4.75 18.69 September5 

### 354 198.0 9.32· 22.4 4.62 4.75· 18.69 OctoberS 354· 198.0 9.32 22.4 4.62 4.75 18.69 November5 

### 354 198.0 9.32

. ·22.4 4.62· 4.75 18.69· December" 354 198

..0 9.32 22.4 4.62 4.75 18.69

.Annual 4452· 2493.6 121.26 343.2
. 71.42 52.14 244.82 (1) Represents the total.number of boats sold. Does not Include boats partiallythrough the production process. Boats are only counted when they are finished and sold. (2) VOM emissions from Resin use .are calculated using the mix of Qoat models built. styrene content ofthe resins used and the emission factor equation deveioped in Exhibit 2 ofthis appendix. ' (3) VOM emissions from Gelcoat use are calculated using the mix of boat models built; styrene content of the geHcoats used and the emission factor equation developed in Exhibit 1 of this appendix. (4) VOM emissions from the use of Other materials are emissions from products such as adhesives, foams. caulks. putties, waxes, iacquers and solvents. These emissions assume 100% of the VOM content is emitted. (5) Boat production and material use for the months Aug-Dec are assumed to be the same as that of July 2003,



### \ Appendix 6

- Page 12

## Exhibit 4 ofAppendix 6 YOM Emissions From Plant Gelcoat and Resin Application Operations MACT Standard Compliance Scenario Using production data and material usage data for 

### 2003

- assuming production and material use for August -December were the same as for July 

### 2003.- an annual VOM emission value was calculated. This annual**VO~** 

### emission value was calculated using production methods and material use that has allowed them to comply with he MACT point value system. That is, the following changes were made priorto 

### 2003: 1. The production resin is 

### 33.5%

- low styrene resin, 

### 2. The Spraycore 

### 1800 and 

### 2000 are the low styrene versions, 

### 3. The moonstone and opal gelcoats are the low VOM content versions, and 

### 4. All resins are applied using flow coat application. Table 

### 15 Boat Production Resin and Gelcoat Use and YOM Emissions , , 

### Other Resin Gelcoat Materials Total Amount VOM·
.Amount YOM YOM YOM

. 

### Boats Used Emissions Used Emissions Emissions Emissions Month Prbduced1 

### (tons) (tons)2 (tons) (tons)3 (tons)4 (tons) January 

### 361 190.9 6.60 25.3 5.34 3.97 15.91 February 

### 355 187.1 6.43 32.4 6.71 3.72 16.86

. March' 

### 375 251.3 8.65
. 36.6 6.17 3.38 18.20

April. 

### 374 198.4

. 7.20 38.6 6.58 5.43 19.21 May 

### 473 291.8 10.56 36.0 5.87 4.33 20.76 June 

### 390 ·186.1 7.41 39.7 6.89 2.81 17.11

July 

### 354 198.0

. 6.87 22.4 3.67 4.75 15.29 AugustS 

### 354 198.0 6.87 22.4 3.67 4.75 15.29 eptember5 

### 354 198.0 6.87 22.4 3.67 4:75

. 15.29

October5 

### 354 198.0 6.87 22.4 3.67 4.75 15.29 \lovember5 

### 354 198.0 6.87 22.4 3.67 4.75 15.29 )ecember" 

### 354. 198.0 6.87 22.4 3.67 4.75 15.29 Annual 

### 4452 2493.6 88.07 343.2 59.58 52.14 199.79 (1) Represents the total. n.umberof boats sold. Does not Include boats partiallythrough the production process. Boats are only counted when they are finished and sold. (2) VOM emissions from Resin use are calculated using the mix ofboat modeis built, styrene content of the resins used and the emission factor equation deveioped in Exhibit 2 ofthis appendix.'

. . (3) YOM emissions from Geicoat use are calcuiated using the mix of boat modeis buiit, styrene content ofthe geicoats used and the emission factor equation deveioped in Exhibit 1 of this appendix. (4) VOM emissions from the use of Other materials are emissions from products such as adhesives,foams, cauiks; putties, waxes, iacquers and soivents. These.emissions assUme 100% ofthe VOM contentis emitted. (5) Boatproduction and materiai use forthe mon1hs Aug·Dec are assumed to be the same as that of Juiy2003.
Appendix 6 - Page 13

## Exhibit 5 ofAppendix 6 YOM Emissions From Plant Gelcoat and Resin Application Operations 8lb/hr Compliance Scenario To make a boat less than 25 feet in length requires the application of 5 skins of resin and/or gelcoat. To make a boat of 25 feet or greater requires**th~** 

### application of 7 skins of resin or gei coat. For the scenarios shown in Exhibits 3 and 4, Crownline produced .". 

### 4,452 boats, 4,054 boatsless than 25 feet long <;lnd 398 boats that were 25 feet or longer. Assuming it takes one hour·to apply a skin and limiting YOM emissions during resin and gelcoat application to 8Ibs/hr, the annual YOM emissions from resin and gelcoat use for this scenario are calculated as follows. Boat Length less than 25feet VOM Emissions = (4054 boats/yr) x (5 skins/boat) x (1 hr/skin) x (8 Ibs VOMlhr) x (0.005 tons VOM/lb VOM) VOM Emissions = 81.08 tons VOM 

### Boat Length 25 feet or greater VOM Emissions = (398boats/yr) x (7 skins/boat) x (1 hr/skin) x (8 Ibs VO,M/hr) x (0.005 tons VOMllb VOM) VOM Emissions = 11.14 tons VOM 

### Total YOM emissions from resin and gelcoat use is the sum of 81.08 and 11.14 which equals92.22 tons ofYOM emissions. To obtain the total annual amount ofYOM emissions from the plant, the YOM emissions from the use of other materials (adhesives, foams, caulks, putties, waxes, lacquers aDd

...";,,,,;.,;, solvents) is added tothe YOM emissions from the use of resin and gelcoat. The amount ofYOM emissions from other materials is 52.14 tons ofYOM and is found in Tables 14 and 15 in Exhibits 3 and 4 ofthis appendix. Therefore, the total YOM emissions for this scenario becomes, 92.22 

### + 52.14 

### = 144.36 tons. Total YOM Emissions

# =144.36 tons.

Appendix 6 - Page 14

# .Appendix 7 

# YOM Emission Calculations from Caulking, Adhesive and Lacquer OperationsTable 1 CrownLine'Adhesive/Caulk/Lacquer Usage 4563 580H ,90014 62216 90009 90016 900!?9 90015 Adhesive Caulk
.Caulk Caulk Caulk Caulk Adhesive Head.liner/ Adhesive Adthane Adhesive Silicone Lacquer Silicone

Carpet Foam White Bla'ck Black White Gray·
. Clear Gallons Gallons Tubes Tubes Tubes Tubes
. Gallons Tubes 180 BR 1.50 0.00 0.60 2.00 4.80 0.00 0.75 0.00 180 CD 1.50 0.00 0.60 0.00 4.80 0.00 0.75 0.00 192 BR 2.30 0.00 0.90 2.50 0.00 0.00 1.00 0,00 202 SR 2.60 0.00 1.20 2.50 0.50 0.00 0.00 0.00 205 BR 2.30 0.00 0.90 2.50 0.00 0.00 1.00 0.00 205CC 2.30 0.30 0.90 2.60 0.00 0.00 1.00 0.00 212 DB 2.10 0.20 0.90 10.00 0.00 0.00 2.50 0.00 215 CC 2.60 1.00 1.20 8.00 0.00 0.00 2.50 0.00 225 SR 2.60 0.00

. 1.20 2.50 0.50 0.00 0,00 0.00 230 BR 2.10 0.00 0.90 8.00 0.00 0.00 3.00 0.00 230CC 3.60 0.00 1.20 8.50 0,00 1,00 1.25 0,00 238DS 2.10 0.20 0.90 10.00 0.00 0.00 3.00 0.00 239 DB 2.10 0.20 0.90 0.00 19.20 0.00 3.00 0.00

. 242 CR' 3.40**1.~O** 1.80 4.00 0.00 .'

. 0.00 1.25 0,50 262 CR 3.10 1.50 1.80 4.00 0.00 2.50 4.00 , 0.50 266 BR 3.60 0.00 1.70 4:00 0.00 1.00 1.25 0.00 266 CC 2.40
. 1.20 1.20 9.00 0.00. 4.00 1.25 

# .
. 2.00 288 SR 3.60 0.00 2.00 12.00 0.00 1.00 6.00

.. 0.00 290CR 3.10 1.50 2.10 6.00 0.00 2.50 0.00 0.50 Total 48.90 7.30 22.90**~8.10** 29.80 12.00 33.50 3.50Table 2 Line Adheslve/CaulkiL _._.-., 

## -- --.**~_** 

## ........._ ... 4563 580H ' 90014 62216 90009 90016 90059 90015

.. Adhesive Caulk Caulk Caulk Caulk Caulk Adhesive Headliner! Adhesive Adthane Adhesive Silicone Lacquer Silicone

Carpet Foam White . Black' Black White Gray ,Clear

. Ib/gal , Ib/gal Ib/gal Ib/gal Ib/gal Ib/gal Ib/gal Ib/gal 180 BR 6.95 7.12 0.39 0.39 0.39 8.00

. 180 CD .6.95 7.12. 0.39 0.39 .0.39 8.00 192 BR 6.95 7.12 0.39 0.39 0.39 8.00 202 BR 6.95 7.12 0.39 0.39 , 0.39 8.00 205 BR 6.95 7.12 0.39 0.39 0.39 8.00 205CC 6.95 7.12 0.39 0.39 0.39 8.00 212 DB. 6.95 7.12 0.39 0.39 0.39 8.00 

### -. '" 215 CC 6.95 7.12 0.39 0:39.· 0.39 8.od 225BR 6.95 7.12 0.39 , 0.39 0.39

. .8.00 230 BR 6.95 7.12 0.39 0.39 .0.39 8.00 230CC 6.95 7,12 0.39 0.39 0.39 8.00 238 DB 6.95 7.12 0.39 0.39 ,0.39 8.00 239 DB 6.95
. 7.1.2 0.39 0.39 0.39 8.00 .' ·242 CR
. 6.95 7.12

. 0:39 0.39 0:39 8.00

262CR 6.95 7.12 0.39 0.39 0.39 8.00 266 BR 6.95 7.12 0.39 0.39 0.39

. 8.00 266CC 6.95 7.12 0.39 0.39 0.39 8.00 288 BR 6.95 7.12 0.39 0.39 0.39 8.00 290CR 6.95 7.12 0.39 ,0.39 0.39 8.00 TotalVOMC Table 3 Line Adhesive!CaulkiL C 

## _._.... ace uer -........... 4563 580H 90014 62216 90009 90016 90059 90015 Adhesive, Caulk Caulk Caulk Caulk Caulk Adhesive Headliner! Adhesive Adthane Adhesive Silicone Lacquer 'Silicone ,Carpet Foam White Black Black White Gray Clear Fraction Fraction Fraction Fraction Fraction Fraction Fraction Fraction 180 BR 0.64 0.55 0.00 0.00 0.00 0.71 180 CD 0.64 0.55 0.00 0.00 0.00

. 0.71 . , 192 BR 0.64 0.55 0.00 0.00 0.00 0.71 202 BR 0.64 0.55 0.00 0.00 0.00 0.71 205BR 0.64 0.55 0.00 0.00 0.00 0.71 205 CC' 0.64 0.55 0.00 0.00
. 0.00 0.71 212 DB 0.64 0.55 0.00 0,00

. 0.00 0.71 . , 215.CC 0.64 0.55 0.00 0·00 0.00 0.71 225 BR 0.64 0.55 0.00 0.00 0.00 0.71 230 BR 0.64 0.55 0.00 .0.00 0.00 0.71 230 CC 0.64 0.55 0.00 0.00 0.00 0.71 238 DB 0.64 0.55 0.00 0.00 0.00 0.71 239 DB 0.64 0.55 0.00 0.00 ,0.00 0.71 242CR 0.64 0.55 0.00 0.00 0.00 0.71

. 262 CR 0.64 0.5.5 0.00 0.00 0.00 0.71

266 BR 0.64 0.55 0.00 0.00 0.00 0.71 266 CC 0.64 . 0.55 0.00 0.00 0.00 0.71 288 BR 0.64 0.55 0.00 0.00 0.00 0.71 290CR 0.64 0.55 0.00 0.00 0.00 0.71 TotalTable 4 CrownLine Adhesive/CaulkfLacquerVOM Emissions· Priorto MACT Compliance

4563 

### I 580H ' 90014 62216 90009 90016 90059 90015 Adhesive Caulk Caulk Caulk Caulk Caulk Adhesive Headliner! Adhesive Adthane Adhesive Silicone Lacquer Silicone

Carpet. Foam· White Black Black White Gray Clear 'Ib/hr Ib/hr Ib/hr Ib/hr

. Ib/hr Ib/hr Ib/hr Ib/hr 180 BR 6.62 0.00 0.23 0.78 1.87 0.00 4.26 0.00 180 CD 6.62 0.00 0.23 0.00 1.87 0.00 4.26 .0.00 192 BR

### ¥.~il'J.~J~ 0.00 0.35 0.98 0.00 0.00 5.68 0'.00
•**,~~~** i!' • ., .... 202 BR

### I!!tI'B$i\~.!!~~ 0.00 0.47 0.98 0.20 0.00 0.00 0.00 205 BR**~lfJi\ilil~ll!lt;1'~lI1!Q** 0.00 0.35 0.98 0.00 0.00 5.68 0.00**l.~L** ..i:E

. i'l!l ,l· " 205CC**Iilli\fJlW~lillI:!!1!IDIl** 1.17 ,0.35 1.01 0.00 0.00 5.68 0.00 I'll , _ '" ,d 212 DB

### .A1fJi~~ 0.78 0.35 3.90 0.00 0.00**li\liilr;\~1ii&'2J:l** _0.00 (:it. r" .•"." 215 CC 

### fj!**'!i1~%** 3.92 0.47

. 3

..12 0.00 0.00**~.l\\!t1:a'l2~** 0.00 

### ,u ,-I
.. ,.".-i'.""""·"" 225BR " ijj;' '"

### ltI~!lr 0.00 0.47 0.98 0.20 0.00 0.00 O.QO , 

### ....**~.",** . 230 SR 

# ....**',.~** 0.00 0.35 3.12 0.00 0.00 

### IJI\!!filJ1j1¥7Ji!3:!t 0.00 230CC r 

### ." ,'","§1 0.00 0.47
. 3.32 0.00 0.00 7.10 0.00 238 DB

### ~IllilW 

## g ,0.78 0.35 3.90 0.00 0.00**I!Mi1f,~;ft~]):l\** 0.00 239 DB

### ~til 

## '. ' \il: j 0.78 0.35 0.00 7.49 0.00 

## 'i\!'l!1'1.'G!ll' 0.00**!'t~ ~~**  .. ..**:,~;** 242CR**~11!l\~.· '~[!1lNJ**  4.70 0;70 1.56 0.00 0.00 7.10 0.00 262CR 

# &".**·~l£~** 5.87 0.70 1.56 0.00 0.00**i'lli~~a'~'2** 0.00 ">fl•..**.,.~,;** •. ;:"'-

...

## 266BR~.m~ 0.00 0.66 1.56 0.00 0.00 7.10 0.00 266 CC 

## ,.!Ill**"~~~** 4.70 0.47 3.51 0.00 0.00 7.10 0.00 288 SR**~~l\ U~~IPJ!im**  0.00 0.78 4.68 '0.00 0.00

## ~'1~Q6 0.00 290 CR**WM~~~JmThW-$J1f~** 5.87 0.82 2.34 0.00 0.00 0.00 0.00

-------- Total , ,Out of ComplianceTable 5 CrownLine Adhesive/Caulk/Lacquer VOM Emissions .After MACT Compliance

4563 

### I 580H ' 90014 62216 90009 90016 90059 90015 Adhesive Caulk Caulk Caulk Caulk Caulk Adhesive Headlinerl Adhesive Adthane Adhesive' Silicone Lacquer Silicone

Carpet Foam White Black Black i White .Gray Clear

Ib/hr Ib/hr Ib/hr Ib/hr Ib/hr Ib/hr Ib/hr Ib/hr 180 BR 6.62 0.00 0.23 0.78 1.87 0.00 4.26 0.06) 180CD 6.62

. 0.00 0.23 0.00 1.87 0.00 4.26 0.00 192 BR 

## itil1!>'iiil.1ili1tQ.\1ieJ 0.00 0.35 0.98 0.00 0.00 5.68 0.00 '."**,,~** ..l

..;r 202 BR**~*J1fl!l~~~llJ!!l~** 0.00 0.47 0.98 0.20 0.00 0.00 0.001 in .•• d 205 BR 

## lI\!!lJi**"'(ljjjl~** 0.00 0.35

. 0.98 0.00 0.00 5.68 0.00 (. iv'

. 'ib ' 205CC**~!~i!l!" "l!\l:lt~j!l**  1.17 0.35 1.01 0.00 0.00 5.68 0.00**.~** kli ., . III I
... 212 DB

# -~ 0.78 0.35 3.90 0.00 0.00

### &l'~l~Q - 0..00 '"'. <t _".**.~,J ~,~"** **~15** CC

### L~l!Mmt4~ 3.92 0.47 3:12 0.00 0.00**~'ifrlj)ij.l** . 0.00 ;C'il' 11**~j~.1** 

### ..t,gQ 225 BR

# 1.1I11l:!~ 0.00 0.47 0.98 0.20 0.00 0.00 ·0.00 230 BR 

## 1:'-' .'**.,g~jj** 0.00 0.35 3.12 0.00 

### O.do**~'f~.'!lZ'tiJ!l:** 0.00**l,t§i,~** _**~L** ... : 230CC 

# Ill.**Jt~~~** 0.00 ' 0.47 3.32 0.00 0.00 7.10 0.00 238 DB

### ~11f"5l:~ 0.78 0.35 3.90 0.00 0.00**lGI'Il$JliIfl~\1llt** 0.00 $f; • , ... 239 DB 

# If 0.78 0.35 0.00 7.49 0.00**il1!l!,~111IJQlf** 

### . 0.001 ' 

# ... \0} 1\.1**,,,.;~,'** 242CR**~..** 

### .." On! 4.70 0.70 1.56 0.00 0.00 7.10 0.001

" "**,'~** :iI..**,~~** , 262CR 

## I\IIl**,.~** 

## ';**1~;l[S** 5.87 0.70 1.56 0.00 ,0.00

### 1t1!\l~~~.~mg 0.00 266 BR 

## 11\Jl1l'**!Il~g** 0.00 0.66 1.56 0.00 0.00 7.10 0.00**~,.~.~. ~,.**  266 CC 

## CO" l!!O!IlJ!1!il\J" 4.70 0.47 3.51 0.00 ' 0.00 7.10 0.001**:~~wj~~** . 288 BR**lJffMpl¥W~ ,:!t1~!!:i~**  0.00 0.78 4.68 0.00 0.00**f,~'}~~t?·ta!J~.o8** 0.001 ".,,,,1;>';**.'''',,~** 290CR**~~Wj);~;\\'ii!j31e6** 5.87 0.82 2.34 

### p,OO .0.00 0,00 0,00 ,.'

..... """-'" ._. 'v, Total
, IOut of Compliance

### Sample Calculations for YOM Emissions from Crownline Finishing Operations This Appendix shows the results ofthe YOM calculations for the finishing operations. In final assembly hulls and decks are assembled to complete the boat. The decks are first moved to deck rigging where carpet, headline and upholstered parts are attached to the

. decks. Meanwhile, the hulls are moved to the carpet area where carpet is installed in the

boat. From the carpet area, the hulls then move to engine assembly. After engine assembly, the finished decks from deck rigging are attached to the hulls, caulked and then moved to 

### final assembly. The boats are then fitted with interiors and miscellaneous hardware. The'following caulkings, adhesives and lacquers are used in the final assembly:



## • • • • • 4563 Solvent Based Carpet Adhesive 580H Headliner-Foam Solvent Based A.dhesive 62216, 90014, 90009 Caulk Adhesive (Adthane 1800) 90059 Lacquer Silicone Caulk As shown inTable 1, each adhesive, caulk, or lacquer is given ingallons or tubes. To calculate the YOM emissions, the density ofthe.material is required. AEA was provided with the MSDSs for each chemical and the density was determined from this. The MSDSs have been included in this Appendix. The densities are listed inTable 2. Each caulking tube is 10.1 fluid ounces which converts to 0.079 gallons. Since the Adthane 1800 MSDS does not proVide the YOM contentby wei&ht, AEA contacted the manufacturerfor the YOM content. They reported thatAdthane 1800 has aYOM density of47 gIL or 0.39 lb/gal.

YOM Emission Calculations (for all materials used

### exc~pt Adthane 1800) For all ofthe materials except the Adthane 1800 CaulkAdhesive, the calculations are as follows: VOMij 

# =Ui,j X 

### D x VC Where VOMi;j YOM emission rate for material i in lblhrforboat modelj 

### Ui,j 

### = amount ofmaterial i used perboat modelj 

### (lb) D = 

### density ofmaterial i VCi

## =current YOM content for material i taken from MSDS and expressed as

# a

, fraction by weight

i 

### = material (i,e" 4563 Solvent-based CarpetAdhesive) 

### j 

# =boat model number

### Example: YOM Emissions ofcarpet adhesive from Modell92BR VOM45OJ. 192BR

## =2.3 x 6.95 x 0.64

## = 10.23 lblhr

YOM Emissions Calculations for 

### Adthane f800

For the Adthane 1800 caulk, the calculations are as follows: VOMj = 

### V j x VOMD Where VOMj 

## =YOM emission rate for material in lblhrforboat model j 

### V

j amount ofmaterial used perboatmodelj 

### (Ib) VOMD

# =YOM density ofmaterial

# =0.39 lb/gal j = 

### boat model number
Example: YOM Emissions ofAdthane 1800 from Model 192BR VOM6ZZ16.

### 19ZB~= 2.5 x 0.39 = 

### 0.975 lblhr

# q 00

# ('-I 2.2/1" 

## 90009' I /

F040S-D2, Ver A, Mars 2000 Created 05/1209:08 AM Modified 09/0511:14 AM 

# Product: 1800 MATERIAL SAFETY DATA SHEET

SUPPLIER ADCHEM ADHESJVES INC. 2670, PAULUS STREET SAINT-LAURENT (QC) H4S IGI
2696, SLOUGH ST., , MlSSISSAUGA (ONT.) UT IG3 EMERGENCY 24 HOURS EMERGENGY TELEPHONE NUMBER (514) 337-7534

(905) 405-9346

(613) 996-6666



# , I SECTIONI IDENTIFICATION AND USE 

# I**~-----** rPRODUCT NUMBER 

### 1800 PRODUCT NAME 

### ADTHANE PRODUCT USE


# -

, CHEMICAL NAMEIFAMILY 

### Polyurethane Sealant

SECTION

### n REPORTABLE INGREDIENTS 

# I -------'
INGREDIENTS ' CAS NUMBER % HAZARD

Xylene, mixed 1330-20-7 5 +/- 3%, Xn;R isomers, pure 10-20-121-38 Distillates (petroleum), hydrotreated light 64742-47-8 <2% Xn;R65 diphenylroethane -4,4' -<!i-isocyanate 77-58-7 <0.7% Xn;R 20-36/37/38/42 

# I

### Mixture

## I Pasty

# I
Not applicablej Various colors/light

## I IpH AS IS IpHYSICALFORM SECTION ill PHYSICALDATA IpURE MATERlAL OR MIXTURE

INITIAL BOll.INGPOINT 

### , 137°C MELTING POINT 

### Undetermined 

# I 

# I

Insoluble

# I !SOLUBll.ITY IN WATER SPECIFIC GRAVITY (WATER=!) VOLATll.ES 

## t% WfW) EVAPORATION RATE VAPOUR DENSITY (AIR-I) 

### I.I7@20°C VAPOUR PRESSURE (MM)

SECTION N FIREAND EXPLOSION DATA



## I

. I . AUTO-IGNITION TEMPERATURE 

### 4SSOC FLASH POINT 

### 40-55°C UPPEREXPLOSIVE LIMIT ('/0) 

### 8 LOWEREXPLOSIVE LIMIT (%) 

### I SENSITIVE TO STATIC DISCHARGE 

### Not available SENSITIVE TO MECHANICAL IMPACT

. > 

### Not available EXTINGUISH MEDIA 

### Carbon dioxide, Foam, fire-extinguishing powder. SPECIALFIREFIGHTINGPROCEDURES 

### Forsafety reasons unsuitable extinguishin§ agents: Wearwith fulljet. In case offire, th( following canbereleased: Carbon monoxid( (CO), Nitrogen oxides (NOx). 

### In certalnfin conditions, traces ofothertoxicgases cannot b( excluded, e.g.: Hydrogen cyanide (HCN), Isocyanates. Wear self-contained respiratof)

. . protective device. FIRE OR EXPLOSIVE IlAZARD 

### product is not explosive. However, fOtnlation ofexplosive air/vapormixtures are possible. HA.ZARDOUS COMBUSTION PRODUCTSSECTION V HEALTH EFFECTS DATA

Information pertaining to particular dangers for man and environment: 'Contains isocyanates.
SHORT TERM EFFECTS OF EXPOSURE ROUTE OF ENTRY 

### , ,

. ACUTE EFFECTS-INGESTION

. ACUTE EFFECTS-SKIN ABSORPTION -c ACUTE EFFECTS-INHALATION ACUTE EFFECTS-EYE OVEREXPOSURE SYMPTOMS' 

### Drowsiness, headache, dizziness, nausea.

,. ' LONG TERM EFFECTS OFEXPOSURE /EFFECTS OFCHRONICEXPOSURE
L-

### ---=--:--:-::::---:-::-:-:--:~------------ll SPECIALHEALTS EFFECTS 

# ICARCINOGENICITY ITARGET ORGANS 

# I SECTION VI FIRSTAID MEASURES 

# I
peneral information: Immediately remove any clothing soiled by the product. INGESTION SKIN CONTACT 

### Immediately washwith.water and soap and rinse thoroughly

.. INHALATION 

### Supply fresh 

### air. Ifrequired,provide artificial respiration. Keep patient warm. Consult a physician 

### ifsymptoms persist. EYE CONTACT 

### Rinse opened eye for several minutes under running water. Then consult aphysician.

, "

.SECTION VII RECOMMENDATIONS FOR PERSONAL PROTECTIVE EQUIPMENT '. . '. ' CONDITIONS UNDERWHICH PPE REQ'D
NOTE: 

### Avoid close orlong term contact with the skin. Wash hands before breaks and at theI 

# I end ofwork. Do not eat, drink, smoke while working. Do not inhale gases/fumes/aerosols. Pregnantwomen should avoid inhalation or skin contact. EYE PROTECTION REQUIREMENTS 

### Splashgoggles 

# IGLOVE REQUIREMENTS 

# I Protective gloves

# I

WASH REQUIREMENTS RESPIRATOR REQUIREMENTS 

### Use suitable respiratory protective device in cas ofinsufficient ventilation. IENGINEERING CONTROLS REQUIRES

SECTION

## vm REACTIVITY DATA
STABll.,JTY 

### No decomposition ifused according to specifications. INCOMPATIBILITIES 

### Reacts with alcohols, amines, aqueous acids and alkalis. Reacts with waterforming carbon dioxide. Dangerofreceptacles bursting because ofvapor overpressure. ICONDITIONS TO AVOID HAZARDOUS DECOMPOSITIONPRODUCTS 

### No dangerous decomposition products known. 

# I I

. 

# I

I HAZARDOUS POLYMERIZATION

SECTION IX SPILLAND LEAKPROCEDURES
SPILL AND LEAKPROCEDURES 

### Ensure adequate ventilation. Keep away from ignition sources. do not allow productto reach sewage system or any water course. Pickup mechanically. Send for recovery ordisposal in suitablereceptacles. Do not close them (reaction with water forming carbon dioxide). WASTE DISPOSALMETHODS 

### Incinerator for hazardous water or authorized dump. Disposal must be made accordingto official regulations. OTHERPRECAUTIONS 

# I SECTION X HANDLING AND STORAGEPRECAUTIONS

### ~---------...,.---~-ISTORAGE TEMPERATURE HANDLING/STORAGE 

# IOTHER PRECAUTIONS ISPECIAL COMMENTS 

### Ensure good ventilation/exhaustion at the workplace. Provide ventilation for receptacl.es. Keep receptacle tigbtly sealed. Store in dry conditions. Store in a cool place

.

. Keep ignition sources away - Do not smoke.

# I

, I

ACUTE TOXICITY

. SECTION XI TOXICOLOGICAL INFORMATION 

### Xylene, mixed isomers, pure. Oral: LD50: 8700 mg/kg (rat) Dermal: LD50:

2000 mglkg (rbt) Inhalation: LD50/4!:J: 6350 mgll (rat) Primary irritant effect: On the skin: No irritant

. effect. Onthe eye: Irritating effect. Sensitization: Sensitizing effectthrough inhalationis possible with prolonged exposure. 

# I

___-'- S_E_C_TI-'-O_N-XlI=::-RE-::-cG::ooU:=LA=T.,..O'"'R-:Y=IN=F-O-RMA--T-I-O_N 

# -Il T.D.G. INFORMATION /SHIPPING NAME 

# I Not regulated

# I

# ·Ii-=-~-·L-'~-·c-~~~-:-E:-R--·----'-------·I --;,---,:-1 .PACKAGING GROUP.

. WHMIS INFORMATION 

# I CLASS 

## I . Not controlled

# I

### .i

# I 

# I ) SECTION XII TECHNICAL CONTACT
CREATION DATE: 04/13/1999 EXPJRATION DATE:04/13/2002 FOR TECHNICAL INFORMATiON, CONTACT:



### , ADCHEM ADHESIVES INC. 2670. PAULUS STREET VILLE SAINT-LAURENT (QC) H4S IGI (514) 337-7534 2696. SLOUGH ST.. MISSISSAUGA (ONT.) !AT IGJ (905) 405-9346 IMPORTANT 

### The infonnation given and therecomrnendations made herein applyto ourproducts alone and not combinewith otherproducts. This information is based on our research and on data from reliable sources and is believed to be accurate. No guaranty ofaccuracy is made. It 

### is the purchaser's or the user's responsibility before using any product to verifY this dataundertheir own operating conditions and to determine whetherthe product is suitable for theirpurposes.



# ,II
I

. ;



# I .I 

# J

I

### MSDS Print Date: 04/06/2001 MATERIAL SAFETY DATA SHEET Page 4 of 10

-------------------------------------------------------------------------- 

### PRODUCT ID: 4563 TRADE- NAME: FLAMMABLE WHISPER SPRA**--------------------------------------------~---"------------------------** 

### irritation persists. Launder contaminated clothing before reuse. 

# .

- 

### INHALATION: Remove individual to fresh air. If breathing is difficult administer oxygen. If breathing has stopped begin -artificial**respirat~on.** 

### Seek immediate medical attention.' INGESTION: Do not induce vomiting. Seek immediate medical attention. NOTE TO PHYSICIAN: Any treatment that might be required for overexposure should be 'directed at- the control of symptoms and the clinical condition.**---------------------------~--------------~----------- ---------------------**  

### SECTION 5

- FIRE FIGHTING MEASURES

--------------------------------------------------------------------------- 

### FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: Material is extremely flammable, highly volatile and readily gives off vapors which are heavier than air and may travel along the ground or may be moved by ventilation and ignited by pilot lights, other flames, sparks, heaters, smoking, electric motors, static discharge, or other ignition sources at locations distant from material handling point. Avoid open flames and other ignition sources in storage and in use, especially in spray applications. This product should not be used where inadequate ventilation is likely or where vapor concentrations may become flammable.

- ; i

%- 

### Volume in Air %- 

### Volume in Air Liquid Flammable Seta 1.0 

### 12.8 IB DOT: 5.0- 

### F Lower Upper

399.0 F -' 

### Flammability Classification Flashpoint Flammabl€/Explosive Limits. Auto-ignition Temperature
.**-~TINGUISHING** 

### MEDIA:

Dry chemical, carbon dioxide, foam, water spray or fog, and vaporizing

., liquid type extinguishing agents may all be suitable for extinguishing fires involving this type of product, depending on the size or potential

- size of the fire and circumstances related to the situation. 

# t-

### ------------------------------------------------------------------- 

### [MSDS Print Date: 04/06/2001 I • 

### MATERIAL SAFETY DATA SHEET 

### I Page 5 of 10

---------------------------------------------------------------------- 

### Dry chemical, carbon dioxide, and "multipurpose" foams are recommended. Water may be an ineffective extinguishing agent unless used under favorable conditions by experienced fire fighters trained in fighting all types of flammable liquid fires. PRODUCT ID: 4563 TRADE NAME: FLAMMABLE WHISPER SPRA

FIRE-FIGHTING PROCEDURES AND EQUIPMENTS: !

. 

### Wear a selt-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective**equipment~**

I 

### Water maybe used to keep fire-exposed containers cool to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Avoid spreading burning liquids with water used for cooling purposes. Fire protection and fire response strategy should be planned through consultation with local fire protection authorities or appropriate specialists.**-------------------------------~---------------------- -----------------**  

### SECTION 6 - ACCIDENTAL RELEASE MEASURES**,----------------------~-~----------------------------- ----------------------**  I 

### 'CONTAINMENT AND CLEAN-UP: Eliminate all ignition sources such as flames (including pilot lights), electrical sparks, etc. Stop spill at source. Contain spilled liquid with sand, earth, vermiculite or other inert absorbent material. This material isa water pollutant and should be prevented from contaminating**.~** 

### soil or from entering sewage and drainage systems and other bodies of 

### J' water. If run-off occurs notify authorities as required. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Depending on the size of the spill, pump or vacuum transer spilled product to clean container for recovery and transfer contaminated absorbent to appropriately marked waste container for disposal.

---------------------------------------------------,-------_._--------------- 

### SECTION 7

- HANDLING AND STORAGE

### I------------------~-----~---------------------_·_----**-----------------------** ,HANDLING: 

# I Handle with reasonable care. Avoid breathing vapors and spray mist.**Avo~d** 

### eye contact and repeated or prolonged skin contact. When opening containers, remove top slowly to relieve any pressure build-up. When dispensing from container, follow acceptable' static grounding/bonding procedures for flammable liquids. Do not transfer product to unmarked container. Keep out of the reach of children. For industrial use only. Containers of**thi~** 

### material may be hazardous when emptied.**Becau~e** 

### emptied containers retain product residues (vapor, liquid and/or solid),**~ll** 

### hazard precautions given in the data sheet must be observed. All five gallon pails and larger metai containers including tank cars and tank trucks should be grounded and/or bonded when material is transferred. Empty drums should be completely drained and properly

### MSDS Print Date: 04/06i2001 

### MATERIAL SAFETY DATA SHEET Page 6 of 10

-----------------------------------------------------------------------

---------------------------------------------------------------------- 

### returned to a drum reconditioner or properly disposed of

. Hydrocarbon solvents are basically non-conductors of electricity and can become electrostatically charged during mixing, filtering, or pumping at high flow rates. If this charge reaches a sufficiently high level,. sparks can form that ,may ignite. the vapors of flammable .liquids.**.~** 

# • PRODUCT ID: 4563 TRADE NAME: FLAMMABLE WHISPER SPRA



### , WARNING! sudden release of hot organic chemical vapors or'mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignition without the presence of obvious ignition sources. Published "autoigintion" or "ignition" temperature values cannot be treated as safe operating temperatures in**chemica~** 

### processes without analysis of the actual process conditions. Any proposed use of this product in**~levated** 

### temperature processes or in spray applications should be thoroughly evaluated to assure that safe operating conditions are established and maintained. STORAGE: Keep product containers cool, dry,' and away from sources of ignition. ,Use and store this product with adequate ventilation. Keep product ,containers tightly closed when not in**~se.**



### Product may corrode, degrade, or otherwise react with some metals and plastics upon prolonged contact. Consult with equipment supplier for proper construction materials for storage tanks, mixers, fittings, pipes and other storage and handling equipment. SPECIAL COMMENTS: Practice safe working procedures and good personal hygiene. Use protective equipment when necessary. Wash. thoroughly after handling and before eating, drinking, smoking, or using toilet facilities.**---------------~-------------------------------------- ---------------------**  

### SECTION 8'- EXPOSURE**CONT~OLS,** 

### PERSONAL PROTECTION
--------------------------------------------.------------------------------- 

### EYE PROTECTION: Chemical splash goggles are advised. Consult with safety representative. Readily accessible eyewash stations and safety showers in work areas are recommended. SKIN PROTECTION: The use of chemical resistant gloves is recommended (consult with safety equipment supplier). If necessary, wear impervious clothing and boots. RESPIRATORY PROTECTION: 

# If the TLV or PEL for the product or any component is exceeded in the workplace air (see Section 2), a ,NIOSH/OSHA approved respirator is advised. Engineering controls should be implemented to reduce exposure.

### ~NGINEERING CONTROLS:

### MSDS Print Date: 04/06/2001**~~TERIAL** 

### SAFETY DATA SHEET Page 7 of 10
PRODUCT ID: 4563 --------------------------------------------------------------------------- 

### TRADE NAME: FLAMMABLE WHISPER SPRA

# -~~~~id~-~~ffi~i~~~-~~~h~~i~~l-(~~~~~~l-~~d/~~-l~~~l-~~h~~~~)-~~~~il~~i~~ , to maintain exposure below exposure limit (s)

.



# I
----------------------------------------------------------------------- SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

------------------------------------------------------------------------ 

### physical State Color Vapor Pressure Vapor Density

. Boiling Range
. Water Solubility Specific Gravity Density

. VOC (less

.water and exempt solvent) VOC (less water and exempt solvent) Evaporation Rate Volatile (% 

### Wt)

. Volatile (% 

### Vol)

. 'Static Electricity Explosion ,. Liquid Light·Amber 182.00 mrnHg @ 

### 68F 4.90 Air = 

### 1 Lower 133.0 F Higher 342.0 F Appreciable .835 6
.. 9517. LB/GL

3.583 LB/GL 429.35 GM/L 7.700 (n-Butyl Acetate 63.4902 70.1026 Yes 1)**-----------~------------------------------------------ ----------------**  

### SECTION 10

- STABILITY AND REACTIVITY

-

## - - - - --

# -- - - - -

## -- - -

## -- - - - - - - - - - -

## -- - - 

## - - 

## - - - - - - - - - - -

## -- - - - - 

## - - - - - - - - - - - - - - - - - 

## - - - -'

. . 

### (INCOMPATIBILITIES:

, Avoid contact with: Strong acids (mineral acids) Strong oxidizing agents DECOMPOSITION: I 

### Hazardous combustion and decomposition produG-ts: Carbon monoxide and carbon dioxide Acrid (choking) smoke and fumes Various hydrocarbons Other unidentified organic compounds and toxic substances CONDITIONS TO AVOID: II 

### Avoid exposure to heat, sparks, open flames, and other ignition sources which induce combustion and/or thermal decomposition

.

. POLYMERIZATION: 

# I Product will not undergo hazardous polymerization. ISTABILITY: 

# i Stable under normal conditions of temperature and pressure.

### MSDS Print Date: 04/06/2001 

### MATERIAL SAFETY DATA SHEET Page 8 of 10

------------------------------------------------------------------ --------- 

### PRODUCT ID: 4563 

### TRADE NAME: FLAMMABLE WHISPER SPRA



## -- - - - - - 

## - - - - - - - - - - - - - - 

## - - - - 

## - - - - - - - - 

## - - - --- 

## - - - 

## - - " " 

## - - - - - - - - - - 

## - - - - - - - - - - - - - 

## - - - - 

## -**---------------------------------~-------------------- --------------------**  

# t SECTION 11

- 

### TOXICOLOGICAL INFORMATION

---------------------7----------------------------------------------------_ 

### No data for product.**----------------------------------------~----------~-- ---------------------**  

### SECTION 12

- 

### ECOLOGICAL INFORMATION**----------------------------------------~~------------ -----------------.----**  

### ECOTOXICOLOGlCAL INFORMATION: AQUATIC TOXICITY: No information is available for product. DO NOT DISCHARGE TO STREAMS, LAKES, PONDS OR SEWERS.

- ENVIRONMENTAL FATE: No data for product.**-----------------------------------------------------~----------~----------** 

### SECTION 13

- 

### DISPOSAL CONSIDERATIONS**---------------------------~--------------------------------~--------------**



### --------------------------------------------------------------------------- .( 

### WASTE DISPOSAL: Do not flush to sewer. Dispose of in accordance with all applicable federal, state or provincial, and local-1awp and regulations. RCRA hazardoup material 40 

### CFR PART 260 

### et.seg. 

# l-------------------------------------------------------------------------"- 1 SECTION 14

- 

### TRANSPORT INFORMATION
DOT HAZARD CLASS: 3 DOT PACKAGING GROUP: 2**--------_._----------------------------------~----~-----------------------~-** 

### SECTION 15

- 

### REGULATORY INFORMATION**------------------------------------------------------ -----------~---------**  

### FEDEPJili REGULATIONS: TSCA (U.S. Toxic Substances Control Act) Status: The intentional ingredients of this product are listed.**Sk~** 

### 313 

### INFORMATION, This product contains NONE of the substances subject to the reporting requirements of Section 313 

### of Title III of the Superfund Amendments and Reauthorization Act of 1986 

### and 40 

### CFR Part 372 

### in guantitiepgreater than the "de minimis" level. ' STATE REGULATIONS: The following statement is made in order to comply with the California Safe Drinking Water and Toxic_ Enforcement Act of 1986:



### ..,

# WARNI~G: This product contains a chemical(s) known to the state of California to cause cancer.

### 10 9 of Page MSDS Print Date: 04/06/2001 MATERIAL SAFETY DATA SHEET I
--------

_ 

### PRODUCT ID: 4563 TRADE NAME: FLAMMABLE WHISPER SPRA

# -~~~~~~-~~~~-~~~~~~:-~~~:~~~~-~-~~~~~~~:~~;-~~~~~-:~-:~~-~:::~-~~------
, California to cause birth defects and/or other reproductive harm.



### , I 

### INTERNATIONAL REGULATIONS: No data available for product. i 

### ----------------------------------------,---------------------------------- 

### SECTION 16

- OTHER INFORMATION**--------------------~--------------------------------- ---------------------**  

### Regulatory Manager. MSDS Prepared by. MSDS Print Date
. MSDS Revision Number MSDS Revision Date. joseph Salib Dennis Sanders 04/06/2001 1 

### 12/12/2000 HMIS Information: Health- '1 Flammability- 3 Reactivity- 0 Personal Protective Equipment- 

## ** ",.safety glasses and impervious gloves are recommended as a MINIMUM. It is the responsibility of the user to determine the personal protective equipment appropriate for each use of the product

.

. ,3CLAIMER OF WARRANTY AND OTHER COMMENTS: This document, has been prepared in accordance with the requirements

, of the OSHA Hazard Communication Standard 29 CFR 1910.1200. The information contained herein is, to the best of 

### our knowledge and belief, accurate. However, because the conditions of handling and use are beyond 

### our control, we make no guarantee of results, and assume no liability for damages incurred by the use of**thi~** 

### material. It is the responsibility of the user to comply with all federal, state, and local laws and regulations. The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and to develop work practice procedures for a safe work environment.
, 

### i 

### iABBREVIATIONS: ACGIH: OSHA: NIOSH: IARC: NTP, 

### TLV: PEL: TWA: STEL: ppm: mg/cum: American Conference of Governmental 

### & Industrial Hygienists. Occupational Safety 

### & Health Administration National Institute for Occupational Safety and Health International Agency for Research on Cancer National Toxicology Program Threshold Limit Value (ACGIH) Permissible Exposure Limit (OSHA) Time Weighted Average Short Term Exposure Limit parts per million milligrams per cubic meter of'air

### MSD.S Pri.nt Date: 04/06/2001 MATERIAL SAFETY DATA SHEET Page 10 of 10

------------------------------------------------------------------------



### ... , PRODUCT ID: 4563 TRADE NAME: FLAMMABLE WHISPER SPRA



## - 

## - - - - 

## - - - - - - - - - 

## - 

## - - - 

## - - - 

## - - - - 

## - - - - - - - - - - - 

## - - - 

## - - --- 

## - - - - 

## - - - - 

## -- 

## - - - 

## - - - 

## - - - - - 

## - - - - - - - -

N/D NOt Determined

• N/A: Not Applicable HMIS: Hazardous Materials Identification Systemfj 

## 2001 I**~~:!~Fl'i.W!!~,** .

,. 1:r1"ft.-,.;H't"f.H·Hf.HHH+ii H HfHfl:f,HHt**~H:HHi:f!it ;-Ht-I.:1:HHi::H:Hf~Ht-.:h·.Ht**  '.

# ~'l:f~(~ ..:""E'·; b':NIN;

# ~_O,CiT~!~G~:: iNC. qdC,j-'E';:: 23e,l:**h('~ i.:'\'12~·**  uri**'1~:** El**~2;'F::: O:~**  73(,.}:, ;(,f**C'l'·;(lii.~** i**,~":',:** (40::';**.:.~,~** -:7:**~?: ~,:;E'**  ";2":':cy :':-. ::?:f: :**-E.0(~-;':.;~-92·.e~,**



### ----**INGR~DrE~T** 

### ---- .I**-""~R!H~ DfS[RJP7IO:~1**  PCGIH 

### OSHA 

# , V' TL\J;:WPJ**~'tL VAPO~:** **::AS~** 

### WI,**~:PM** 

### PPM LEL**PRE~:.** 

### TOLUENE 

### REsm ,qESIN t'HTHALATE ESTER**iSORUTy~** ACETATE ME'il-!YL '\'-P.NYL XE"TONE E'lH'/L HLCDHGJ..**ME:TP~Ol..** 

### 2-PRDPP.NDL. /1e5-86-2 

### , 47. t,j I J**(~13.** 0\.1/ 203,**l1~/** 

## , e/ 22,0 

### , 

# .. /9N'4-70-ij 2. 53 INOT ESTINOT 

### ESTl / /'?0f.4-70-0 .I 3. 42 

### /NOT ESTINOT 

### ES1/ I IE.B:<15-4s

...e, 

### , 2. :',0:, 

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### ,**I1t0-:l~-6** i i2.**5~** ./ 

### 15e,. eel**!5~t ~0/**  I fE'.3 ! i / I N/A

.... 1;**~,-43-€** ! l.**~s** / 5e"**~0/ 10~.00/**  1. 

## " 2. 1 

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# " 5.40 ! I**e:e,~·,** 00i1000. e0/ 14.0 ft.?-5E.-l ;. 1:, ! 2i?lG,00l 20.0. e0! E .•0./ 

## %.e /E,7-63-f; i 2.5:: !**~e0,00!** .40e,.**~,rJ/** 2. 5/ 32.8 L£;;E ,**l'\~** ;: CHRo.¥:ATE .{W'

147.2 Low-**723.~:** ,r: 

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## I 

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### EXPlOSION**P~ZAP.D** 

### 9ATP. 

### ==============

,**~. ::-;lfl;~c:c;;:i:y** **;::c.i's:~:·:·;::(·** .. : Llr·:·=:E**::=:;,";~,,:;i;'.~** 

### Tti:;**4l~.** '? E:-:pl·:,s:,::{! L;veJ: _:::we"**:...!;'~ET r;c.:;j;~;;:.jizity** **~::.;:; j:h.:~;:**  i;r:::-:,",**~er:.~:;:·:tt'·;:: SPECjH~**  Fi**~~FI5n;:** 1-:;:**:'~C;CE[:U'~~:. u~~·**  NI["::H**5pr·(;"·!~j** i:. j :**~-~':~'~** 

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### TIRE AND**Er.P~DS;[~** 

### HAZARDS**B~!'r;l** ni:**~iay** pl"')QilCe-**::'~:** ee: ::,f r::;**r::'~En** ,:"t':':: cart,,)!;,**?{eY~1'** use I'leic**i~lg** crcut.tiYiQ t:.:,rcr: {<T:,**':'~' r:~;:~"**  ch-:;ms**~,;-:a:;~:-** pY·,:,CUCT. car, ignite Explc<slvEly. Va.8ors at'€'_heavi2r ;nul c,ir' ari',j r-,:;}' :r'a

...:E';' along**t.h~·** grc<ur,d**-:'!'~** r;ray bE**1~(tve6** ty**'l~nti12t:.,:<;,,:** 2Y;::'**l~r:HE'::** 

### by ?:!-:,t 1i£Ms! ;parks,**heater~: Sliiok!r;9~**  f!E;;';:-"--**~K,t::,~~s= c'~**  ';:2::C**:~~::M2~'2€ ~~5tar:~** **f;"'I):~ h~.n6lirlg**  p.:,ir:t.



### ======================**S~CT:a~** v - 

### RECCT1VITY DRTA 

### ========================

r,'-.;C[(f;C';;-IBH.:Y**;~TE"P.~A~S** ':'[; C;\jOIVi**S~''-.)r:~, L'~:** **h~~;** i**r;~** ager:ts:**s~.rN;~** .; 1\-\2.1 i**y:~:::.~** st**.-~:,r;g** I:";: r,E'l"'t;: ac1cs.**~~IHRD8~; DECQ~~r.S;7;ON**  

### OR**8Y)RODL~:S Oxidc.~i(;7:**  may**PP;)u'iJC~** C5;-'O'.:,r. c.;';[i**r:i~:'('g2r: (i}:irie~**  .•**t*f.ft*~**f~rt+~fti***f*f.~ff~f~fiir.ffi~~*T.T.ftf~f.f.~*fff.f*ff~*f.rff****f~~T.ff.ti** ,==='::========== SECTION VI

- :-'::HLTri**h"~lHRO D~;g**  ========================= I**~iALAT!DN ~E;:LT~** **B!S~:S** AND**S'(~::'TD~:f' i}.~**  EOG"SURE**~);ceSSiVE i"(;r,2-ia~**  iUr ::,f v2;,,::n ·:'B_ '::'a'-,=E-**r;.3=,z~** ar,d**i'e~~:il'ato~--y 1n'itation~** 

di:zlr'i?ssJ**Ii:::ak:·:~:-:.: f~::;-:J~:** **~"6;,;:.ea! -;~a;:'at~if~,** **pc:'~s:b:i? 1~:~;:-C';'l5d')!lS!res-=:**  c:flC**E--,;~-r, 2~)":**  ..,,i.:.t E:;'" Eye c,:.ntad :::-,2";**caL!~?** !rdt03.t:::,:·,:**;~·Ed:';:::-~:.:Ec:r·ir:g: :;~:iT1**  cc,rrtact C2T' cause redr,es.s,:**diy.':es:.~** 0' rash. aht**t~ur~'-2C** 'Ii 0;,i '::1':. 

### ,**:~..:G~S!ION H~A;.":"~** **~:rs~~~:** ;L;!£:**sy~C'n];,:\g** GF**::-;J~JS-Uf.:~** ;'r'dY caU32**"'::""i~';~:'"if~** r.i!ljS'?-=:l**-:i2:-':'f1:e2~ a':"l~:**  £.:str·c,iTltE::;.tir:Q} trdtat·ic,rr.

322**2.b::'v~** iN' c:t'lt!:'**h2.~cir·d:;.** :"o;--=: ;l2nt ·:'·;;r-ei-:p('S'.l"i'2 :)f s,)lvE-nts is suspec-ted ::rf**c.:;~::iri£** :ivE>r'! kic:'";ey: h:r:f 6r:d**cerrt~'al :"~l,~"'CI),JS** **SYSt:E~1** da.::".a9E. Z;"JterltioYiai l.tiS:J:'E by dEl ibEl:-.:t=--:y**CCq~:'~:';:~"ati,;;;** '='1"(. i;-:hali'i:g sc,lve7lts may ::e harmf:Jt**.':;~'** fa.t::. OSHA REGH_ATED? f'k.'

i

# ~RGEJ~CY AND

# ~tRST Aio

# P~OC~~JR~S

irhalatiN;; Itk,ve "'itt:ll: tc:**f:-~;i-, air'~**  aid**t't>eat~rirr91** ca11'**p~;ysic:iarlo** Eye' [(,ntact: F>:.sr. Eye=, irr:r:iElciately**r:it~· ~ar9~**  ar.';OuTlts -:,f water- fe-r**a~** l?2.st 15**min1!t~** a'(ld**c~ll** physi:-iarr. S!i.1r, C«7rt-act:**~2rri')Vi? :::·,)r:t.;.r~i"a:~d_clc,-;(:i!:~~**  flash area i!lllrlEdiately with sc,ap c,:'"rC**~.Ii3~e~'.** Sec phy'=.ician**~f** ::,rit3tic",,; pErsi;.ts. j';rgestiur::**[1~':r,~:;** C,t·· 2 g16S5::':- c,f ;';':;:;i:t**t~,** dilrltE. D,) NOT induce**:/c'~1Hi';rg. C::';';~.i.;lt;,** **p~:!'s-itian c:~'**  p::,i;.:or, :::"::;'rtr(,:**C-~Ylte-i"** iklfl1ediac21y,

5m'S Tn 9E IRKEN IN CASE**,~AiE:1I.';L** IS'**itc:_EJ~S£D** DR S:tILLED**=~::ak** up**spi!~~.** }.;:th**}'('~i't** matEr:,;l: i.E.: S37,d: arrd sCl"'ape- up -,.:ith YrCIl":- :-parkir;g tct(,ls.**p,~t.** i r. c:c,\

..**e-~'e-d** r.1eta:1 c-c,r;;aini;t TN' disposaL 

### WRSTE DISPOSAL MoTHDD DisposE i71 e:r'cOtOarrcE l'dh· lcv.:a!r**stat~:** 2":'!0 fe-der'sl**y~gulatir<l"!s.** 3tc,rE in**ti~~;ti'f** tl:::s;G C-':'·(it.a:f:er-;;.**r~e=~;** a,ia'! fr-Cl:il s-par·ks!**ey.CEssi'v'~** heat! e,r Cl!J2rt**nam~'~' Tr-ansfc~'**  Oe;WE2i"r**c·c'r,ta.i;:..:r~** ti-,a; haVE**~eE'r.** electric-a:};;**~:·o:mded. S;;-~**  OSHH1 f"? CFR: p:",t**l3~:V.**

## ·' 

# -
• • p '. 'l: i 1:1:**Hf.H*HHfH*f~H** H t Hr.H H'* H *HfHf.HH**f~** i**~HJ:.j,** fH tHHH**::-H~** 1''''H

## ***=~.** i r. C::'l;ti:ct• Re-iEaSE p;--·2:;.:=.'..:r"2 ('1' r::'Ylt2 ?,e;" ';**~,y:::.** 

## . Styo,S ?"(l:" :;;:e j:: i<',,':;**·~dii.;;:e.::** 2!"·eas.,**WE.~.:-j ::·::,r;T.dji~jr;;tf"~** **;:.'j:)~>:i'·:Q** Gei::,n:**~'er.;s.o;,** 

## v(·**.,~)t** Ql'';'i. -;: j.jE:**pur;=~!lr-E:** c·;" r-€,;.tse.**c,)r;tc1irlE'~";.** [i.:.? 

### :·t ,'SS .C'··'E':'S\:···.; t·:**ft;,:;t~,. :======~==========**  

### SECil0N 

### ViII

-**CGN~ROL M~P.SUR£S**  

### , 

## ========================**~~BP!RKTD~Y** 

### PROTECTiON .is,;**NESAn~IQ:3;";** ap;'-(;':Ed**r·~s~i,.a** t,:::---. C:::me**~f;E-T** ;-c,r;**~.~~** t./vapt r'E':pi**~~at,:,:· C'h~Mictil** **j'eSpil'~tCor. ~Vt**  PROTECTION.**U~::·** .s.ol.ashproof 90991E';. :::,j"**fdC~ s~lie}C:.** **==========~====== S[CTI[~~**  

### X**SE'~ilO~** Jij i0Klr Sheroicals 

## =================

47.63 weigMt f.**i~8-SB-3** OJ: 5: ?'.:,dur:-t C\:]'jtcin: th;· fo]; c.wing t::.xic ChefjliC",:ds**s1Jb~iEct** it: the**:"E'p,:rr'~lr;g** r"equ1 l'err.e-flt·=, !:)f seetin:"; '313 of**th~** tfilFrgi:7ri2j' Pll1f17;ir'Q**CY~::; ~,)mlll!.;r;i~1** **R.i~ht-T')-!':fIO::: A('~**  of l'3BS arid (oT 40 Ct:R 372:**"'.~THP.NO!...** . 1,15**T~t** INFDRMATION CmnAINED HERt:!N IS**Hi~ORMHT!ON** RECEIVED ,=RDtf, DUR RAI-i f:p'TERIHL SUP;:'Ll£RS" t1NV OTt-IF: SDURCE5 RM] 

### IS 8ELIEVED TO BE RELIABLE. THIS DPTA IS NOT TO BE**TA~EN ~;**  

### A**WPRR~~TY** 

### OR**REPRtSENTAT!~~ t~R**  

### WY1Cn THEA80YE

-, 

## 1

# I MSDS Print Date: 03/05/2001 Page ):>UTj. 

### 1 of 10

----------------------------------------------------------------------- . 

### SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

--------------------------------------------------------------------------**~EMICAL** 

### PRODUCT IDENTIFICATION: :-.... PRODUCT ID.
.

. PRODUCT CLASS

. . TRADE NAME

... MSDS prepared. for: CROWN LINE BOATS-. INC 11884 ·COUNTRY CLUB RD. WEST FRANKFORT Attn: IL 62896

CONTACT TELEPHONE MANUFACTURER NAME ADDRESS

. TELEPHONE EMERGENCY EMERGENCY IDENTIFICATION: IMPERIAL ADHESIVES, INC 6315 WIEHE ROAD CINCINNATI OH**4S2~7** 

### 513-351-1300 CHEMTREC 1-800-424-9300**-----------~------~--------------------------------~-- ---------------------**  

### SECTION 2 C 

### COMPOSITION, INFORMATION ON INGREDIENTS

---------------------------------------------------------------------------



### 400 ppm 500 ppm 500 ppm 85 ppm 440 ppm 15-min TWA 1 Heptane CAS# 142-82-5 PCT BY WT: 20-30 I 

### EXPOSURE LIMIT: ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA NIOSH REL-TWA NIOSH REL-CEILING VAPOR PRESSURE: 40.000 MMHG @ 

### 68F LEL 1.10

2 Mineral Spirits CAS# 8052-41-3 Aliphatic Hydrocarbons iStuddard**T}~e)**



### PCT BY WT: 5-10 VAPOR PRESSURE: 2.000 MMHG @ 

### 68F LEL 1.00 EXPOSURE LIMIT: ACGIH TLV-TWA 100 ppm OSHA pBL-TWA 500 ppm NIOSH REL-TWA 350 mg/cum NIOSH REL-CEILING 1800 mg/cum lS-min TWA _._-----------------------------------'-------------------------------------- 

### 3 Acetone Cll,S# 67-64-1 

# I PCT BY WT: 

### 20-30

EXPOSURE LTMIT: ACGIH TLV-TWA 

## lL. ACGIH TLV-STEL

,. OSHA PEL-TWA NIOSH REL-TWA 

# I VAPOR PRESSURE: 500 ppm 750 ppm 1000 ppm 250 ppm 182.000MMHG @ 

### 68F LEL 2.60

### MSDS print**Dat~:** 

### 03/05/2001 MATERIAL SAFETY DATA SHEET Page 2 of 10

.... 

## - - - -'-
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 

### PRODUCT ID: 580H TRADE NAME: FLAMMABLE WHISPER SPRA**-----------------------------------------~------------ ------------------** 



## - - - - - - - - -.- - 

## -- - - - - - - - - - - - 

## - - 

## -- - - - - - - - - - - - - 

## - - - - - - - - - - - 

## - - - - - - - - - 

## - - - - - - - 

## - - - - 

## ---

- 4 Diacetone Alcohol

. CAS# 123-42-2 PCT BY WT: 1-5 EXPOSURE LIMIT: ACGIH TLV-TWA OSHA PEL-TWA NIOSH REL-TWA VAPOR PRESSURE, 50 ppm 50 ppm 50 ppm .800 MMHG @ 

### 68F LEL 1. 

### 80

--------------------------------------------------------------------------- ***-************************************************************************ 

### This product contains nb 

### reportable carcinogens or suspected carcinogens.

-**********************************~************************************************



### --------------------------------------------------------------------------- 

### SECTION 3 - HAZARDS IDENTIFICATION

--------------------------------------------------------------------------- 

### EMERGENCY OVERVIEW: DANGER! Extremely flammable liquid and vapors. Vapors can cause flash fire. Keep away from heat, sparks, flames, and other sourcea of ignition (e.g. static electricity, pilot lights, mechanical/electrical equipment)

. Can cause eye, skin, and respiratory tract irritation. Overexposure can cause**c~ntral** 

### nervous system depression. Aspiration hazard if swallowed. Can enter lungs and cause damage. Use ventilation adequate to keep**~exposures** 

### below legal and recommended exposure limits (see**sec~ion** 

### 2). Avoid contact with eyes, skin, and clothing. Do not- taste or swallow. Wash thoroughly after handling. Toxic fumes are released in fire situations. Contain spilled liquid to prevent contamination of soil, surface water**o~** 

### ground water. POTENTIAL HEALTH EFFECTS: For short term overexposure EYE:

Can caUse irritation. Symptoms may include stinging, burning, tearing, redness, and swelling. SKIN:

Can cause irritation. Symptoms may include redness, burning, drying, inflammation (dermatitis), and burns. Material may be absorbed through the skin from prolonged contact. INHALATION:

Can cause irritation of nose, throat, airways

..High concentrations may cause central nervous system depression with symptoms of dizziness, headache, nausea, confusion. INGESTION:

Can cause irritation of the mouth, throat, and gastrointestinal tract. Symptoms may include abdominal pain, nausea, vomiting, diarrhea. Aspiration of material into the lungs may cause chemical pneumonitis

### MSDS Print Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 3 of 10**-~----'----------------------------------------------- -------------------**  

### PRODUCT ID: 580H TRADE NAME: FLAMMABLE WHISPER SPRA which can be fatal. -------------------------------------------------------------------------- 

### TARGET ORGAN/CHRONIC EFFECTS: For repeated overexposure



### I

.

I 

### Reports have associated repeated and prolonged occupational overexposure to organic solvents with various neurotoxic effects including permanent brain and nervous system damage. SymRtoms include loss of memory, loss of intellectual ability and loss of coordination. Chronic skin exposure to solvents may cause similar effects. Intentional misuse by deliberately concentrating and inhaling the contents of this product may be harmful or fatal. Acetone shortens the time of onset or worsens the liver and kidney**damag~** 

### induced by other chemicals. Overexposure to acetone has been suggested as a cause of the following effects in laboratory animals, and may aggravate pre"existing disorders of these organs in hUmans: mild, reversible liver effects, mild reversible kidney effects.

. Acetone has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain. Overexposure to diacetone alcohol has.been suggested as a cause of the following effects in laboratory animals: liver abnormalities, anemia, kidney damage.

. Pre-existing disorders of the following organs (or organ systems) may be aggravated by exposure to diacetone alcohol: liver, kidney, and any pre-existing condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. Overexposure to mineral spirits CAS# 8052-41-3 has been suggested as a cause of central.nervous system effects in humans. CARCINOGENICITY: Based on the available information, this product is not expected to be carcinogenic in humans. This product contains no components in quantities greater than or equal to.0.1% by weight that are listed as proven or suspect carcinogens by IARC, NTP, or OSHA. PRIMARY ROUTE(S) OF ENTRY: Inhalation, eye contact, skin contact
SECTION 4 - FIRST AID MEASURES
EYE CONTACT: Flush eyes gently with water for at least 15 minutes while holding eyelids apart. Consult physician.

# ~KIN CONTACT: Wash exposed skin area with soap and water. Consult physican if

### MSDS p'rint Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 4 of 10 ---"----------------------------------------------------------------------- 

### PRODUCT ID: 580H TRADE NAME: FLAMMABLE WHISPER SPRA
--------------------------------------------------------------.-----------



### irritation persists. Launder contaminated clothing before reuse. INHALATION: Remove individual to fresh air. If breathing is difficult administer ,oxygen. If breathing has stopped begin artificial respiration. Seek

immediate medical attention. INGESTION: Do hot induce vomiting. Seek immediate' medical attention. NOTE TO PHYSICIAN: Any treatment that might be required for overexposure should be directed at the control of symptoms and the clinical condition.

--------------------------------------------------------------------- 

### SECTION 5 - FIRE FIGHTING MEASURES

------------------------------------------------------------------------ 

### FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL: Material is extremely flammable, highly volatile and readily gives off vapors which are heavier than air and may travel along the ground or may be moved by ventilation and ignited by pi1o.t lights, other flames, sparks, heaters, smoking, electric motors, static discharge, or other ignition sources at locations distant from material handling point. Avoid open flames and other ignition sources in storage and in use, especially in spray applications. This product should not be used where inadequate ventilation is likely or where vapor concentrations may become flammable. The solids portipn of the product (if applicable), is combustible and will decompose during combustion or under pyrolysis conditions giving off toxic fumes.

. Closed containers may burst due to pressure build-up if exposed to temperatures at or near the boiling point of the**product~** 

### Closed containers may rupture explosively, with product ignition, if exposed to extreme heat or fire. Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Flammabili ty Classification lB DOT: Flammable Liquid Flashpoint 5.0- F Seta Flammable/Explosive Limits. Lower 1.0 % 

### Volume in Air Upper 12.8 % 

### Volume in Air Auto-ignition Temperature 399.0 F EXTINGUISHING MEDIA: Dry chemical" carbon dioxide, foam, water spray or fog, and vaporizing

........ liquid type extinguishing agents may all be suitable for extinguishing fires involving this type of product, depending on the size or potential size of the fire and circumstances related to the situation.

### MSDS Print Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 5 of 10

----------------------------------------------------------------------- 

### PRODUCT ID: 580H TRADE NAME: FLAMMABLE WHISPER SPRA I**---------------------------~-------------------------- -------------------**  

### Dry chemical, carbon dioxide, and "multipurpose" foams are recommended. Water may be an ineffective extinguishing agent unless used under favorable conditions by experienced fire fighters trained in fighting all types of flammable liquid fires. FIRE-FIGHTING 'PROCEDURES AND EQUIPMENTS: Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode,with appropriate turn-out gear and chemical resistant personal protective equipment: Water may be used to keep fire-exposed containers cool to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Avoid. spreading burning liquids with water used for cooling purposes. Fire protection and fire response strategy should be planned through consultation with local fire protection authorities or appropriate specialists.**-----------~------------------------------------------ ---------.------------**  

### SECTION 6 - ACCIDENTAL RELEASE MEASURES
CONTAINMENT AND CLEAN-UP: Eliminate all ignition sources such as flames (including pilot lights), electrical sparks, etc. Stop spill at. source. Contain spilled liquid with sand, earth, vermiculite or other inert absorbent material. This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and other bodies of water. If runoff occurs notify authorities as required. i
I 

### Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Depending on the size of the spill, pump or vacuum transer spilled produ4t to clean container for recovery and transfer contaminated absorbent·. to appropriately marked waste container for disposal.
SECTION 7 - HANDLING AND STORAGE**----------------------~------------------------------- ---------------------**  

### HANDLING:

. Handle with reasonable care. Avoid breathing vapors and spray mist. Avoid eye contact and repeated or prolonged skin contact. When opening containers, remove top slowly to relieve any pressure build-up. When dispensing ·from container, follow acceptable static grounding/bonding procedures for flammable liquids. Do not transfer product to unmarked container. For industrial use only.

. Containers of this material may be hazardous when emptied. Because emptied containers retain product residues (vapor, liquid and/or solid), all hazard precautions given in the data sheet must be observed. All five gallon pails and larger metal contaiDers including tank cars and tank trucks should be grounded and/or bonded when material is transferred. Empty drums should be completely drained and properly

### MSDS Print Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 6 of, 10

--------------------------------------------------------------------------- 

### PRODUCT ID: 580H TRADE NAME: FLAMMABLE WHISPER SPRA

-------------------------------------------------------------------- 

### returned to a drum reconditioner or properly disposed of. Hydrocarbon solvents are basically non-conductors of electricity and can become ,electrostatically charged during mixing, filtering, or pumping at high flow rates. If this charge reaches a sufficiently high level, sparks can form that may ignite the vapors. of flammaDle liquids. WARNING! Sudden release of hot organfc chemical vapors or mists from process equipment operating at elevat'ed temperature and pressure, or sudden ingress of air into vacuum equipment; may result in ignition' without the presence of obvious ignition sources. Published "autoigintion" or "ignition" temperature values cannot be treated as safe operating temperatures in chemical processes without, analysis of the actual process conditions. ' Any proposed use of this product in elevated temperature processes or in spray applications should be thoroughly evaluated to assure that safe operating conditions are established and maintained. STORAGE: Keep product containers cool, dry, and away from sources of ignition. Use and store this product with adequate ventilation. Keep product containers tightly closed when not in use. Product may corrode, degrade, or otherwise react with some metals and plastics upon prolonged contact. Consult with equipment supplier for proper 'construction materials for storage tanks, mixers, fittings, pipes and other storage and handling equipment. SPECIAL COMMENTS; Practice safe working procedures ,and good personal hygiene. Use protective equipment when necessary. Wash th9roughly after handling and before eating, drinking, smoking, or using toilet facilities.**------------------------------------------------------ -------------------~--**  

### SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION
EYE ,PROTECTION: Chemical splash goggles are advised. Consult with safety representative. Readily accessible eyewash stations and safety showers in work areas are recommended. SKIN PROTECTION: The use of chemical resistant gloves is recommended (consult with safety equipment supplier). If necessary, wear impervious clothing and boots. RESPIRATORY PROTECTION: If the TLV or PEL for the product or any component is exceeded in the workplace air (see Section 2), a NIOSH/OSHA approved respirator is advised. Engineering controls should be implemented to reduce exposure. ENGINEERING CONTROLS;

### MSDS Print Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 7 of 10

------------------------------------------------------------------------- 

### PRODUCT ID: 580H TRADE NAME: FLAMMABLE WHISPER SPRA

-------------------------------------------------------------------- 

### Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below ·exposure limit (s)

..**-------------~---------------------------------------- -----------------**  

### SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

----------------------------------------------------------------------- 

### physical State Color Vapor Pressure Vapor Density

. Boiling Range
. Water Solubility Specific Gravity Density

. VOC (less water and exempt solvent) VOC (less water and exempt solvent) Evaporation Rate volatile (% 

### Wt)

.... Volatile 

### (% Vol)

. '"

. Static Electricity Explosion " 

### Liquid Light Amber

. 182.00 mrnHg @ 

### 68F 4.90 Air = 

### 1 Lower 133.0 F Higher. 342.0 F Appreciable .856 7.1230 LB/GL

3.048

. LB/GL 365.24 GM/L 7.700 (n-Butyl Acetate = 

### 1) 55.0002 62.2281 Yes**~---------------------------------------~------------- ---------------------**  

### , ; 

## I 

# '- SECTION 10

- STABILITY AND REACTIVITY

--------------------------------------------------------------------------

. I 

### INCOMPATIBILITIES: Avoid contact with:

Strong acids (mineral acids) Strong oxidizing agents DECOMPOSITION: Hazardous combustion and decomposition products:

Carbon monoxide and carbon dioxide Acrid (choking) smoke and fumes Various hydrocarbons Other unidentified organic compounds and toxic substances CONDITIONS TO AVOID: Avoid exposure to heat, sparks, open flames, and other ignition sources which induce combustion· and/or thermal decomposition

. POLYMERIZATION: Product will not undergo hazardous polymerization. STABILITY: Stable under normal conditions of temperature and pressure..

### MSDS Print Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 8 of 10

------------------------------------------------------------------- 

### PRODUCT ID: 580H TRADE NAME: FLAMMABLE WhISPER SPRA

# ~-====================================================**======================** SECTION 11- TOXICOLOGICAL INFORMATION

------------------------------------------------------------------------ 

### No data for product.

--------------------------------------------------------------------------- 

### SECTION 12

-**ECOLOG~CAL** 

### INFORMATION

--------------------------------------------------------------------------- 

### ECOTOXICOLOGlCAL INFORMATION, AQUATIC TOXICITY: No information is available for product. DO NOT DISCHARGE TO STREAMS, LAKES, PONDS OR SEWERS. ENVIRONMENTAL FATE: No data for product.

------------------------------------------------------------------------ 

### SECTION 13

- DISPOSAL CONSIDERATIONS**----------------------------------------------~------- ---------------------**  

### WASTE DISPOSAL:

- Do not flush to sewer. Dispose of in accordance with all applicable federal, state or provincial, and local laws and regulations. RCRA hazardous material 40 CFR PART 260 et.seq.

-------------_.------------------------------------------------------------- 

### SECTION 14

- TRANSPORT INFORMATION**------------------------------------------------------ ----~----------------**  

### DOT HAZARD CLASS: 3 DOT PACKAGING GROUP: 2-**---------------------------------------------------~-- ---------------------**  

### SECTION 15

- REGULATORY INFORMATION
FEDERAL REGULATIONS: TSCA (U.S. Toxic Substances Control Act) Status: The intentional ingredients of this product are'listed. SARA 313 INFORMATION: This product contains NONE of the substances subject to the reporting requirements of Section'313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 in quantities

. greater than the "de minimis" level. STATE REGULATIONS: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: WARNING: This product contains a chemical(s) known to the state of California to cause cancer.

### MSDS Print Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 9 of 10**-~---------------------------------------------------- ------------------** 



### -------------------------------------------------------------------------- 

### WARNING: This product contains a chemical(s) known to the state of California to cause birth defects and/or other reproductive harm. 

### , 

## , PRODUCT ID: 580H TRADE NAME: FL.l\

. .'!NABLE WHISPER SPRA

INTERNATIONAL REGULATIONS: No data available for product.



### ,

--------------------------------------------------------------------------- 

### SECTION 16- OTHER INFORMATION**------------~-------~---------------~----------------- ------------------**  

### Regulatory Manager. MSDS prepared by. MSDS Print Date
. MSDS Revision Number MSDS Revision Date. Joseph Salib Dennis Sanders' 03/05/2001 1 

### 12/12/2000 HMIS Information: Health- 1 Flammability- 3 Reactivity- 0 Personal Protective Equipment- 

### **

, ** Safety glasses and impervious gloves are recommended as a MINIMUM. It is the responsibility of the user to determine the personal protective equipment appropriate for each use of the product. j 

### \.**~SCLAIMER** 

### OF WARRANTY 

### AND OTHER COMMENTS: This document has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. The information contained herein is, to the best of our knowledge and belief, accurate. However, because the conditions of handling and use**ar~** 

### beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of**th~s** 

### material. It is the responsibility of the user to comply with all federal, state, and local laws and regulations. The responsibility to provide a 

### safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions'required in an individual operation to instruct employees and to develop work practice procedures for a safe work environment. ABBREVIATIONS:

I I 

### ACGIH: OSHA: NIOSH: IARC: NTP: TLV: PEL: TWA: STEL: ppm: mg/cum: American Conference of Governmental 

### & Industrial Hygienists. Occupational Safety 

### & Health Administration National Institute for Occupational Safety and Health International Agency for Research on' Cancer National Toxicology Program Threshold Limit Value (ACGIH) Permissible Exposure Limit (OSHA) Time Weighted Average Short Term Exposure Limit parts per million milligrams per cubic meter of air

### MsbS Print Date: 03/05/2001 MATERIAL SAFETY DATA SHEET Page 10 of 10

------------------------------------------------------------------------ 

### PRODUCT ID: 580H**T~~E** 

### NAME: FLAMMABLE WHISPER SPRA l .------------------------------------------------------------------------- 

### N/D

- Not Determined N/A: Not Applicable HMIS: Hazardous Materials Identification System

# Appendix 8 

# YOM Emission Calculations from Small PartsProiecl: Page:

_ Prepared by: ---,- - Dole:

_ Clienl: Scope 1.0.:

_ 

# riflAdvance Environmental Associates, 

# LL 

# C Checkedby: Dole:



### "

# ~Sl~ -t-41f0

# ~U\..**~?** 

# i:**S+")I-c~L**

# 1~ \v'7-+

# k~iar'**,{~,**



# -

\g**t=~** 

## D.u).. 3'-' f2. 

## F=t..



# .In:,...**~\;"** 

## 25

# g 

# f8t+-**\~?7K** :L0

## Fit

.**I~.** 

## :3?'7.i?.

# p,~~L~~J.J;..~;· . .,:

### ~.4 

## :: 

# b

### Veal

# =amount ofcatalyst used on an individual part (Ib) N1am

## =number ofparts to be laminated in 1 hour

## =l.part/hr Vee,t

### = current YOM content ofthe catalyst expressed as a fraction EFcat 

### = VOM emission factor in the catalystexpressed as a fraction
Example: 192BR w/Liner Box foot star/port VOMlam 

### = (I7 

### x 1 x 0.35 x 0.099) x (0.6 x 1 x 0.03 x 1) 

### = 0.611b/hr To see how EF,e, was determined refer to attached handwritten calculation sheet. EFeatis 100% ofthe 3% YOM in the catalyst. In other words, all ofthe 3% is emitted from the catalyst. This data was taken from the catalyst MSDS.

### Sample Calculations for YOM Emissions from, Crownline Small Parts

The table lists adescription ofeach part that is treated in the gelcoat" and lamination areas. Each part listed is associated with a specific.boat model. Crownline has provided the part number and the material usage amount. Each part canbe sprayed with gelcoator resin within 1 hour. The following equation was used to calculate the YOM emissions for gelcoat and resin:

Gelcoat: VOMgel 

### = Uge1 X 

### N gel x VCgel X 

### EFgel Where VOMgel 

### = YOM emission rate for gelcoat in lb/hr ' Ugel 

### = amount ofgelcoatused on anindividual part (ib) Ngel 

### = numberofparts to be gelcoated in 1 hour

### = 1 part/hr VCgel 

### = current styrene content in the gelcoat expressed as a,fraction EFgel 

### = YOM emission factor in the gelcoatexpressed as a fraction determined using data from the NMMA Table 2-5

.. Example: 192BR 

### wILinerBox foot star/port VOMgel = 

### 0.1 

## it 1 x-0.33 x 0.375 

### = 0.0121b/hr

, , 

### To see how EFgel was determinedreferto attached

### handw~itten calculation sheet.

Lamination:
VOM1am= 

### (Ures' x N,es x VCres x EFres) 

### + (Ueal x Neal x VCeal X 

### EFead Where VOMlam

## =YOM emission rate for lamination in lblhr Ures 

### = amount ofresin used on an individual part (Ib) N1am 

### = number ofparts to be laminated in 1 hour 

### = 1 part/hr VCres 

### = current styrene content in the resin expressed as'a fraction EFres 

### = YOM emission factor in the resin expressed as afraction determined using data from theNMMA Table.2-5 (using procedure from March 14, 2001 letterAppendix 11CrownLln" SmlJ1 Part Uuo"ln Pound' of 1.11;'\10<1.1:I MACT Comptlanc" Scenll10 VOU Content VOU Emtul"n FlICt"r VOU Ernlutons Uadel O-.scrtplton Part No. O"teo.t fl.

...ln C"",,,,**Appllc..tlon~me** O"lcell'l 

# ..." Cr..al)'S1 O.tcOIl'l Rssln C.w", O"lcu:!. fl..stn

.. Cn.aJy'l"t 192 9A wtt.in"" S';";m Pladorm <J5S< 6.25 ".00 0.83 1.00 0.33 0"" O.OJ 0.375 0.099 I o.a '-. 192 BAwl\.in"" MotOr**Bo~** 

# "'" '.00 6:1.00 1.<Cl 1.00 0.33 o..JS O.OJ 0..375 0.099 I 1.0 

## ,., 192 BA wA..iner Box 1001 stlflport 

# "". 0.10 17.00 0.60 1.00 0.33 o..JS O.OJ 0.375 0.099 I 0.0 0.6 192 BA wll.ioer Ud. Fuel Tank 61179 '.00 27.00 0.6< '.00 0.3::J-. 0"" '.OJ 0.375 0.099 

## , 0; In U2SubtoW 11-" 1.(7.00 3." 1.00 0.33 0"" 0." 0.375 0.099 1 U 

## " 20S 8A LShape S<Jndedr.. S93S6 12.00 79.00 

## ,.20 1.00 0.33 "-" O.OJ 0..375 0.099 I 15 '.a 20S BA LSl\apl Dash. Port Side 59357 9.75 60.00 1.J3 1.00 0.33 

## '"" oro 0..375 0.099 I 1.1 I.' 20S BA LShape Ud.l.addfl( s'm 2.SO 17.00 0." , 1.00 0.33 o..JS o.OJ 0..375 0.099 I 0' 0.6 20S CC Supe< Sport Ud.l..addfl( 

# .- ,.so H.oo 0." 1.00 0.33 0"" o.OJ 0'75 0.099 I 0' 0.6**2~SubtoW** 25.75 '''.00 413 1.00 0.33 o..JS 

## ." 0..375 0.099 1 J.2 

## " 21208 Lid, I.lIdder 

## ""'" ,.so 17.00 0.'" 1.00 0.33 o..JS O.OJ 0..375 0.099 I 0' 0.6 21208 Ud.L..addfl( <1SSJ 1.75 17.00 0.38 1.00 0.33 0"" '.OJ 0..375 0.099 I 02 0.6 21208 door. Head Hatch 59060 '.00 16.00 0.<5 1.00 0.33 o..JS OOJ 0.375 0.099 I 02 0.6 21208 Seal Base 61182 '.00 <6.00 I." 1.00 0.33 0"" O.OJ 0.375 0.099 

## , 1.1 1.6 212 Subtoul 15.25 ".00 

### .. 1.00 0.33 0.35 0." 0.315 0.099. I u JA 215 CC Supe<' Sport J.lQlor**Bo~** 

# "'" a.oo 6:1.00 1.53 1.00 0.33 

## '"" O.OJ 0..375 0.099 I 1.0 '2 215CCSuperSIlO'1 H.m 59607 "'.00 62.00 1.59 1.00 0.33 o..JS '.OJ 00375 0.099 I 1.7

. 22 215 CC SuperSport Doot. Cabin 

## """ 7.so ".00 O.BB 1.00 0.33 0"" O.OJ 0.375 0.099 I 

## ,. " 215 Subt"tIl ".so 103.00 400 1.00 0.33 0"" 

## ." 00375 0.099 I 3.7 5.' 2:lO BA L·$J\aped Two Lid. Ladder 

# """ 1.75 17.00 0." ·'.00 0.33 o..JS om 0.375 0.099 I 02 0.8· 2:lO BA L·s/I3ped Two Lid,'Ladder "'70 '.00 17.00 OAS 1.00 0.33 0"" '.OJ 0.375 0.099 

## , 02 0.6 230 BA L·s:/l.Iped Two Door, Head Hatch 

## "'" '.70 ".00 0.61 1.00 0.33 0"" O.OJ 0.375 0.099 

## , 0; 0.9 2:lO BA L'$/I3pedTwo Head comp Linfl( 59697 9.00 71.00 1.65 1.00 0.33 0"" O.OJ 00375 0.099 I 1.1 '.5 2JO CC SuperSport Lid. Fuel Tank S93S6 3.00 31.00 0.70 1.00 0.33 0"" O.OJ 0.375 0.099 I 0.' 1.1 2:lO CC $upeo' Spocl 

## COO"'. S93S6 7.67 65.00 ,;" 1.00 0.33 0"" O.OJ 0..375 0.099 I 0.9 1.9 2:Xl CC Super Sport H"m 

# """ 12.90 65.00 1.53 1.00 0.33 0"" oro 0.375 0.099 

## , '-6 

## ,., 2JO CC Super Sport Lid. Ladder 59<72 

# ,

# ... 17.00 0.'" 1.00 0.33 0"" O.OJ 0..375 0.099 

## , 0' 0.6 2:JC1 Subto,,", <= 

## "'.00 7.12 1.00 0.33 0"" 

## ." 0.J75 0.099 I 5' 10.5 

### "'06 Ud. L.add¥ <1560 1.75 17.00 0.38 1.00 0.33 o..JS OOJ 0'" 0.099 I p2 0.6 

### "'06 Door. Head Hatd\ 59060 '.00 16.00 0.<5 1.00· 0.33 0"" O.OJ 0'" 0.099 I 02 0.6 

### "'06 Seal Ba$(I 61182 9.00 ".00 1." 1.00 0.33 0"" O.OJ 0.375 0.099 I 1.1 1.6 23aSub'toul 12.75 79.00 US 1.00 0.33 0"" 0" 00375 0.099 I 1.' 

## ,

# . 2J9 08 L..ShapedTwo Lid. Ladder 

# """ ·1.75 . 17.00 0." 1.00 0.33 0"" O.OJ 0.375 0.099 I 02 0.6 moo l.shaped Two Ud.l.lIdd"" <1570**~OO** 17.00 0.,(5 1.00 0.33 .0"" O.OJ 0.375 0.099 I 02 

## ,. moo LsII3pedTwo Door. HeadHillCh 

## "'" '70 ".00 .0.61 1.00 0.33 "-" O.OJ 0.375 0.099 I 05**O~** moo LshapGd Two seat Base 59612 6.BO '76.00 ,.69 1.00 0.33 0"" O.OJ 0..375 0.099 I 

## '" '.7 2:l9 08 Lshaped Two Head ComP Liner 59697 9.00 71.00 1.65 1.00 0.33 0"" O.OJ 0.375 0.099 I 1.1 '.5 m "'''''''' 

## ,= "".00 479 1.00 0.33 0"" 

## ." 0.375 0.099 I 

# .... 7'**2~2** Cfl 2C02 Base 50 Ud, Ladder <1570**~OO** 17.00**0.~5** 1.00 0.33 "-" O.OJ 0.375 0.099 ; 02 0.6**2~2** CR 2002 B.ue 50 $howfl(w/slnk ,(3571 9.00 6<.00**1~1** 1.00 0.33 "-" O.OJ 0..375 0.099 

## , 1.1 U**2~2** CA 2C02 Base 50 Showef W/lionom 

## "''' 1<'" 90.00 2.16 ,.00 0.33 0"" O.OJ 0..375 0.099 I 

# ,. 32 2.(2 CR 2C02 Basa 50 Mator Hatch 59613 6.00 79.00 1.75 1.00 0.33 o..JS O.OJ 00375 0.099 I 0.7 

## ,. 2.(2 CA 2002 Base Bo H"m 59610 1.(.00 65.00 1.90 1.00 0.33 o.>i O.OJ 00375 0.099 I 1.7 

## ,., 2.(2 SubtoUl ".>< 314.00 ,.,7 1.00 0.33 0"" OOJ 0..375

. 0.099 I 5.' 11.1 262·CA Base Boat MOlor Hateh 59613 6.00 79.00 I." 1.00 OJJ "-" O.OJ 0.375 0.099 I 0.7 '.a 262 CR Base Boal H"m "'10 1.(.00 65.00 1.90 1.00 0.33 "-" O.OJ 0..375 0.099 I 1.7 

## " 262cR Base Boal ShQwfl(Wkink ·596t5 11'>< 93.00 2.1B 1.00 0.33 "-" 0.03 0.375 0.099 I I.' 3' 262 CA Base 60al ShoWer wlbOaorn "'16 17.70 '20.00**~..,** 1.00 0.33 0"" oro 00375 0.099 I 22 <2 262 CR Base Boal Top. Shower J.4arble 59619 NA 3.00 026 1.00 0.33 "-" O.OJ 00375 0.099 

## , EVALUEI 0.1 zst Subtotal 

## "'

# ... "'.00 1.93 ,.00 .0.33 "-" OoJ 0..375 0.099 1 '.1**1~7** 266 BA Super Spa1 Ud. And'>« S1«aoe 

## "''' 2.SO 16.00 026 1.00 0.33 "-" 003
. 0.375 0.099 I 0' 0.6 266 BA Super SIlO'1 Ud. Laddfl( <JS52 2.SO 19.00 0." 1.00 0.33 0"" "OJ 0..375 0.099 I 0' 0.7 266 CC withU<wr Lid. Andler SIor.Jge 205<J 2.:H 20.00 0." 1.00 0.33 o..JS O.OJ 0.375 0.099 I 0' 0.7 266 CCwilh Uner LId. FuelTani: 2OS7O '.00 J2.50. 0." 1.00 0.33 "-" O.OJ 0..375 0.099 I 

## ,. 1.1 266CCwittlL..'oet Ud.Ud<ler "'16 '.00 17.00 0." 1.00 0.33 "-" O.OJ 0..375 0.099 I 02 0.' 266CC withL..lrwlt H_ 

# "'" a." S2.SO 

# ,,, 1.00 OJJ "-" 0.03 0..375 0.099 I 1.0 U 266CCwithl..Joer Ud, SId1.Dck1lf 

# "'"**~'"** R70 0.38 1.00 0.33 "-" O.OJ 0.375 0.099 I 0' O. 266 CC with L.inef sB31Basa 

# """**1~'"** 

## ".00 1.82 1.00 0.33 0"" o.oJ 0= 0.099 I**1~ ~7**  266 CC with Uoer w_ 600"**~OO** 12.60 0.:10 1.00 0.33 "-" O.OJ 0.375 0.099 I 02 0.' 266 CC with Uner w_ 

# """ 1-" 10.75**0~7** 1.00 0.33 o..JS O.OJ 0'" 0.099 I 02 0.' 2&lI Subtatal 

## .,.., 270

... 'M 1.00 0.33 

## '"" OOJ 0..375 0.099 1 '.0 

# .., ",aR Lid, Ladder "'70 2.<Xl 17.00 0." 1.00 0.33 "-" O.OJ 0.375 0.099 I 02 0.6 

### "'BR Door, Head Hatch 59060 2.<Xl 16.00 0" 1.00 0.33 o.J5 O.OJ 0..375 0.099 I 02 0.6 

### "'BR 

# ......"". 

# "'" 16.50 92.., ,.S:! 1.00 0.33 "-" O.OJ 0.375 0.099 I '.0 3' 

### "'BR Door. Head 593

.. 

# ,.

## ., 30.00 o.s9 1.00 0.33 "-" O.OJ 0.375 0.099 I 0.' 1.1 "'BR HeadCompl..Joer 59J65 15.3-4 91.40 '23 '.00 0.33 o.J5 O.OJ 0..375

# - I 13 22 

### "'BR H_ 59J65 11.00 sa.ao 1.6< 1.00 0.33 "-" O.OJ 0..375 0.099 I I.' '.1 

### "'BR Door,Sidel Entry 59367 '.70 

# . ., 026 ,.00 0.33 "-" O.OJ 0..375 0.099 

# , " 0' 21!!$ubtcrtlll 

# ..... 31(,00. 

## ..,. 1.00 0.33 "-" CO2 0.375 0.099 I 

# ... 11.1 290 CA Base boat Lid. Laddot 

## ""'" 2.SO 17.00 0." 1.00 0.33 0-'5 O.OJ 0..375 0.099 I 0' 0.6 29J CA Base boal 

## .......,- 

# """ 12.50 125.00 2.Bl 1.00 0.33 "-" O.OJ 0,375 0.099 I**1~** 

## ••• m CA Base boat H_ 61317 18.70 B9.25**~13** 1.00 0.33 0"" O.OJ 0..375 0.099 I 

# " 

# ,

# .. 200CA Basil bo<n J.4otol'Hatch 61318 B.2O**91.~** ,.0< 1.00 0.33 "-" O.OJ 0'75 0099 I 

## '" 32 290 CR Base boat Ud. Ladder 61319 2.<Xl 19.00 0.<5 1.00 0.33 0"" om 0.375 0.099 I 02 0.7 200 CA Sasll boal Shower WaS 61321

. 7'>< 101.90 

## ,.20 1.00 0.33 0"" O.OJ 0.375 .099 I 

# " ,. 290 SLjbtoul 51.2.( "'-" 10.03 .1.00 0.33 0"" OOJ 0.'" 0.099 I 

# ., 14' lBOBA No 01

..... Sml11 partJ; lBOCC No OIQS SmaIJ Pwts

# Appendix 9 . Detailed InfornlationAbout

# VEe TechnologyGenmar Technology· Virtual Engineered Composites (VECJ Page.l of 2

LARSON ;:"".'.,'.-: ,C"l).STRON

### ~,:~HATTERAS**~~5-** TR1UJ,lPH LUND NOVA RANGER T ROIA.H

GENMAR (OMPANIES GEL COATS I R.OPLENE I VEe: HULL**DESIC~~S** ROBOTICS Virtual Engineered Composites: The Future of Fiberglass Manufacturing Through a commitment to building**bi~h-quality** boats using innovative and 'revolutionary technology, Ge(lmar Incorporating a new cutting-edge fiberglass' construction process that is expected to set new standards in the ooat·building industry. It's called Virtual Engineered Composites (VEe'"") and it replaces the traditional fiberglass production method, which is labor-intensive, expensive, slow .and produces regulated air emissions.
Genmar is systematically implementing**V.E~** te.chnology into its fiberglass boat manufacturing facilities becauseit's'an environmentally friendly 'and automated process that increases the**dur~bility** and structural integrity of boats, while increasing production efficiencies an-d producing fewer regulated air emissions than the traditional " fiberglass lamination process. VEC is used predominately forproducinr; hulls, but will be used for other fiberglass parts as well, including decking, stringers·and smaller components. VEC involves a complex computerized system that " manages the entire injection

molding process, including all equipment operations and the curing of reSIns. It controls the key elements of the process to eliminate inconsistencies in the finished producl Manufacturing facilities that have VEe cells are dig"ally connected to a VEC Solutions Genter, which is a

._ remote facIlity that houses

technical experts who monitor the :A.-:;<A**~"::4** :::;s:**~.ti ~~** **e:.~** technology and are available for assistance. ( TECHNOLOGY QUAlJTY 1 PARTNERSHIPS

"**"'T1~** furttrt' nf

foo-urbuild;{(¥ dt:pt'rrcJs Qrrrlre
(/C'1.'(:/r;l'(fJc'{1! til

rtt'll' ({INI Jm(lfT,lt'('d**U{UHlffi~~t{lrilrx** h·(·hu(llug(l.'s. ,. (Iwi l) Jac()b5

parts.

# 'a~.·I.~(:.!i:'?~;.#~'7~:'~~_v...:~J~~**b~~~t~ ~~~~** **~~\~{~~Sm~ld '·'"~tfg.;:~::;g**  system that allows Genmar to

, "" ',_
- - produce a variety of parts

, economically. This system uses a thin composite skin in the shape 01 the part to be produced
- that's mounted on a water·filled pressure vessel, creating a Iowpressure, ciosed·mold process. The composite skins can be

- rapidly fabricated and are easily

- changed, which lowers the time

and**~st** of producing prototype

Extensive 'on-water endurance and laboratory testing shows that VEC-produced fiberglass hulls perform at least as well as hulls produced using the traditional open-faced molding process. VEC parts"qre also stranger, lighter and take less time to prod**uc~.**

9/17/01Article Archives Pagelof3 

# FeaturE 

# O/l/\ TltlfIrlNDUSTRY 

# £J.--/11**1~/NTERNA1IONA1'**



# . ONLINE Click here to get back to the homeoage. Email this Article to a Colleague 

### , 

### Genmar looking for VEe 

### partners Opportunities In Europe and Australia? Ke)'word Search of Boo.ting Industry Online's Archh'e!i:

# I :.



# .. . 

# .. ".
, ' . . 

### "-il·.-iMiililiiiliiillii

Teh high cost associated with the Introduction of Its new boat manufacturing processes has spurred Genmar Holdings, Inc. to look for new ways to recoup the Investment. ByJohn. JKettlewel! News and ArticleTopics WORLDWIDE Archives .En;';iron'ment Expo Business In Brief

... International Distribulion Interne-t--

-- ----. Maililfa:cturing & fabrication.

. Marinas & Yards**Ma~nance** Market Outlook Regulatory Review Retail Update Technology Trends

. The more than US$30 million cost associated with the Introduction ofIts more environmen friendly and more effident ticat manufacturing processes has spurred US-based Genmar Inc. to look for new ways to recoup the investment Inducted In that search are plans to license the technology to other tioatbullding companle possibly create tioatbulldlng centers in Europe.
The search for a,large reduction in styt-ene emissions and the quest for reduced labOr in a production setting is driving the development ofGenmar's virtual engineered composites ( technology.

"**Howev~,** most boatbuilding companies are either too small to take advantage ofthe syst 

# I**.~lit .~**  are alreaely wedded to other processes that would be too expensive to scrap. As a result, 

### 1._.

# ;:rl.:I.~l.i.:.[_,**;~,;.;;'** _;;;..,;, ..;,;

.•.,..;..... '

......_.__,;, Genmar's plans may be harder to realize than·the company hopes.

, Irwin L Jacobs, chalnnan ofGenmar, belleves thatVEe will become the standard for the I and he plans to license the technology out to other companies.

. Site Menu



### , Home Article Archives Online Buyer's Guide New Products Calendar Classifieds Bulletin Board Web Links Advertising About Us Poll Archives Register Subscribe 

# Monarcb 

# Marineh Even IfVEC was not protected by its 31 patents, it Is unlikely many companies would be a affend the investment This has lead some to speculate that Genmar plans 00 produdng hulls and ded<s for othe companies, but Genmar seniorVice President George. SuUivan says that is notthe case.

. Genmar 15 sending mixed signals on plans to begin tiullding in Europe. Sullivan says Genm

been considering other locations around the**WOrl~,** but locations outside Europe are more However, Jacobs says, "We'll be In Europe sooner, rather than later.- And the compai)Y has utilized European manufacturing expertise in the col15truction ofthe VEC plant Italian company Belottl supplied the six-axis, computer-controlled router that tr and ded<si and drills holes.
Retumon invesbnent based on efficiency This Month's Issue:. When Genmar unwrapped its new 8,83S-square-metre VEe boatbullding plant (see Boaon Industry Intemaoonal July 2000), the fadlity represented a total investment of more than

____ ,-_,_, "T_..l_ •. r"_LL"J111')**~J1"'U'l1**Article Archives

Charter industry may sail into danger Fewer shows, more cooperation Change happens Advertising important during a downturn Sign up today for a FREE subscription to 

# B:Jj.7711JS fHDusruINru.NATI01i r 1 t'age L. or j

million, including about US$12 million for the factory alone, This level of investment is far greater than the cost to get an open-mold boatbuilding oper going, which is more typical ofboat companies around the world. Genmar hopes to recoup some ofthis investment through increased manufacturing efficie new plant will soon be making as many as 10,000**~Iastron** and larson boats, with an ave labor time savings of about 60 percent less than using traqitional manufacturing processe . With two VEe "cells" creating hulls and decks every 40 minutes, and a computer-controlle assembly line moving boats along every 22 minutes, the current'factory can complete abo 30 boats each day

... Though Genmar has made an agreement not to layoffany employees, eventually, ,throug retirement and attrition, the work force necessary to build aset number of boats will shrin Steve Kubisen, president of Pennsylvania-based VEC Technology Inc" the subsidiary Gen formed to develop the new technology. Genmar currently employs about 6,400 people in plants.

. Non-!JS markets are different One fador in its future decisions about Europe, pointed out byJacobs, is that the VEC ass line process is suitable for producing large numbers of identical smaller boats, which is th of the US market. Larger boats, which are frequently customized, can't be built on a moving assembly line, s time sailings in building the small number of. hulls produced becomes a much smaller prop the whoJe time spent on the yacht. Therefore, the cost savings for a big boat built with VE not be significant. ' Also, there are no companies in Europe produdng large numbers ofsmaller boats, as is d the United States. Large-volume European boatbuilders measure production in hundreds not tens ofthousands. The same situation applies in Australia and New Zealand, though Wesley Moxey, managin director ofThe Riviera Group, manUfacturers of Rivieras, Mariners and Australian-builtWe says Genmar's technology will have a big impact on the production ofsmaller boats. The main obstacle to adopting VEC in**Au~lia** is the high cost ofentry, S9YS Moxey, but production savings could do for the boatbuilding indUstry what it has done for the cost of manufacturing consumer electronics. Also, the cost ofVEC technology itselfwill decrease and more companies adopt it. Until Genmarcan develop a market for large quantities ofsmaller boats in Europe and Au appears likely most VEC manufacturing will remain in North AmeriCa.
- Genmar has several new technologies coming soon that will continue to improve efficienc reduce styrene emissions. Jacobs,says the company is so far ahea,d of the c0rt:\petition, it i running a race against itself for the lead in boatbuilding technology. \Vithin six months to a year, Genmar plans on switching ITom traditional gelcoat in the VE to atype of "film" that will not emit,volatile organic compounds (VOC). Traditional gelcoat be applied by handheld equipment when tne mold is open, allowing high levels of VOCS to emitted. Tnis film technology will lowerthe total VOC emissions from aVEe plant to the point wher factories can be built anywhere, even in the middle of populated areas, says Jacobs. And Jacobs is predicting further efficiendes wil1 mean eventually as many as 20,000 boats will be built from a standard 8,83S·square-metre VEC plant. Traditional boatbuilding not dead

7117/OtArticle Archives Page 3 of 3

Other companies mass-producing boats, like canada-based Bombardier Recreational Prod continue to refine more traditional technology to reduce emissions.
Rock Lambert, vice president and general managerof Bombardiers Sea-Doe sport boat di says the company believES its styrene control systems will be adequate for any foreseeabl Environmental Protection Agency limits that may be imposed.
The Illinois manufacturing fadlity for Sea-Doe sport boats and some personal watercraft ( utilizes a traditional, open-mold type of construction,-but the molds are in sealed chamber special filters and ventilators. The exhausted air is indnerated.
Sea-Doo is produdng l!p to 48 boats a day from one plant, putting it into the mass-produ category that might seem appropriate for VEe. The boats are sold in 70 countries around _d

. .
But Lambert says the company can't see dear advantages for the VEe system, particularly Sea-Doo is already producing large numbers of boats successfully and meeting styrene e goals. Sea-Doo has already m2de a large investment in cleaning, up its traditional open·mold pro and a change to VEC would mean a massive investment in plant and retraining. 

### , However, Lambert does .acknowledge that the company is constantly testing and reviewin technologies. Low·styrer.e resins and g"el coats may be needed in the future, depending a regulatory developments.
With a change to VEC appearing to be toe costly for both small boatbuilders and large op Genmar may find the Futur= for marketing this technology lies mainly outside the boatbuil industry.
For related information, please visit**~..!,poating:i.DQ!:!-gIY,<;:.9m"** and ,use the following key an article search: VE.C, Genmar, boatbuilding. "AllContenl Copyrighl 2001 National Trade Publications Inc. Click Here lor details on OW Privacy Policy This si'..e besl viewed with:**NETSCA~_.iZ** or**~emelli~elp!~r** .

7117101Genmar Technology' Virtual Engineered Composiles (VEC) Page ,t of 2

GEL COATS I**ROPLcr~E** 1VEe: HULL**DESIG~~5** ROBOTICS

Imrm·ll't'd

. UfWlI!!i1ctUrTIfX rC'(.·hufli/JXIl:$. ' {rwin**JaC(l~ HT1~**  /llfll11,' rtf NiwbuiMilig (kpt.·rrds UfJ {lie ('fl'arJo"and**i1e~/upmC'1l1** {if r1C'u' (md 

# r TECHNOLOGY Q\JJ\UTY PARTNERSHIPS Virtual i:ngineered Composites: The Future of Fiberglass Manufacturing

Genmar is systematically**~rtlplementing \(~G** **!~nol9:gy** into Its fiberglass boat manufacturing laCllities because it's an environmentally friendly and**·~automated** process that increases the durability and suuctural

. integrity of boats, white increasing production effICiencies and producing lewer regulated air emissions than the uaditionaI
.- ,- fiberglass laminaUon process..VEe Is used predominately lor producinQ huns. blrt will be used lor otherfiberglass parts as well, including decking, stringers and smaller components. .' Through a commitment to building**Ai~h-quality** boats using innovative and revolutionary technology, Genmar**i~** Incorporating a new cutting·edge fiberglass construction process that is expected to set new standards in the boat·building indusUy. It's called Virtual Engineered Composites (VEC'N) and it replaces the traditional fiberglass production method, which is**labor~intellSive.** expensive, slow and produces,regulated air emissions.

VEC involves a complex computerized system that mana,ges the entire injection mdlding process, including all equipment operations and the curing of resllls. It controls the key elements of the process to eliminate inconSIstencies in the finished product. Manufacturing lacmties that have VEC cells are digitally connected to a VEC Solutions Center, which is a remote facl1tty that houses technical experts who monitor the ;,::;"A.

... =::s:**r~** e::..-:a. .' technology and are available for assistance. NOVA RANGER TROJAN. TRIUI,IRH

LUND

GENMAR COMPANIES 

## I i

parts. 

## 1!!!1I!!5!!!'

# e= The VEC process involves a .**,,~~:'** patented 1ow:COst flexible mold**:~*~** system that allows Genmar to

.._. - produce a variety 01 parts economically

...This system uses a thin composrte skin
- in the shapeof the part to be produced
- that's mounted on a water·filled pressure vessel. creating a low· pressure. closecf..mold process.

. The composite skins can be

. 'rapidly fabricated and are easily changed. which lowers the lime

. and.cost 01 producing prototypa



# I Extensive**on~water** endurance and laboratory testlng shows that· VEC-produced fiberglass hulls perform at least as

### wen as.hulls produced using the traditional open-faced molding process. VEC parts are also stronger, lighter and take less time tp produce.**_~** __"'_L'.

__.__ 9/17/01Article Archives

Kc.,'wurd Search orBoating Industry Online's

# Arch~\.c ...

# :I'

. ".

News and**Art~.c1e** .Topics 

# Dn!\TIfl!:it.INDUST.RY

.**~III.** INTERNArIONAl" 

## M,;am"'Ua 

# DNLINE Click here to get back to the homeoage. . Ernaillhis Article [0 aColleague 

### ·Genmar looking for VEe partners OppOrtunities In Europe and Australia? Teh high cost associated with the Inrroduction of

. Its new boat manufacturing processes has

spurred Genmar Holdings, Inc. to look for new ways to recoup the Invesbnent. .. ByJohn J**Kerlle~ll** WORLDWIDE· Page 1 of J 

# FeaturE

Archives EnVironment F:xpo Business Cn Brief... International Distribution Internet M'ii1ii1acturing &Fabrication Marinas & Yards Marine Finance Markel Outlook Regulatory Review

. Retail Update

Technology Trends. The more than US$30 million cost associated with the introduct:lon of its more environmen frlendly and more effiCient boat manufacturing processes has spurred US-based Genmar Inc. to lookfor neNways to recoup the investment

. Induded In thatsearch are plans to license the technology to other boatbulldlng companle

.. possibly create.boatbuilding centers In Europe.

The'seanch for alarge reduction in styrene emissions and the quest for reduced labor in a production setting is driving the development ofGenmar's vfrtual engineered compcsltes ( technology.

. 

# IHowever, mostboatbuilding cOmpanies are either too small to take advantage of the syst

# -:~i".:h==r**~e~~~~I= ~o~~:r:~~~WO~~d**  ::n:n0::,e to soap. As a resul,

____:::.. ;..;....... ..1 Irwln L Jacobs, chairman of Genmar, believes·that VEe will become the standard for the i and he planstolicense the technologyoutto other companJes. Site Menu' Home Article Archives Online Buyer's Guide New Products Calendar Classifieds Bulletin Board Web Links Advertising About Us Poll Archives Register

. Subscribe 

# Monarch

# Marin~ This Month's Issue: Even IfVEewas net protected by its 31 p,;tents, It is unlikely many companies would be a afford the Investment

. This has lead someto speculate that Genmar plans on produdng hulis and dedcs for othe companies, butGenmarsenior Vice PresIdent Gecrge Sullivan says.that Is not the case. Genmaris ",rdng mixed slgnals on planS to begin building in Europe. Sullivan says Genm been considering other locations aroundthe world, but locations outside Europe are more However, Jacobssays, "We'll be In Europe sooner, rather than later:

. And the COll'4"lny has utilized European manufacturing expertise In the construction ofthe



### VEe plant Italian company Belotti supplied the siX-axis, computer-mntrolled router that tr and dedcs, and dtiIIs holes.

. Return on**~nvestment** based on**effi~ency** When Genmarunwrapped Its new B,B3S-square-metre VEe boatbullding plant (see Beatin Industry lnternalional July 2000), the fadlity repreSented a total Investment of more thanArticle Archives

Charter industry may sail into danger Fewer shows, more cooperation Change happens Advertising important during a downtum Sign up today for a FREE sUbscription to 

# BCYi77111S**rxDCJS!~r** !HrUNA

## ~'rXtl!P t'age 2 ofJ

million, induding about US$12 million for the factory alone.
This level of investment is far greater than the cost to get an open-mold boatbuilding oper going, which is more typical of. boat companies around the world.

. Genmar hopes to recoup some of this investment through increased manufacturing efflcie new plant will soon be making as many as 10,000 Glastron and Larson boats, with an ave labor time savings of about 60 percent less than using traditional manufacturing processe With two VEC "cells" creating hulls and decks every 40 minutes, and a computer-controlle assembly line moving boats along every 22 minutes, the current factory can comple.te abo 30 boats each day. ' ' Though Genmar has made an agreement not to layoff any employees, eventuallY"throug retirement and attrition, the work force necessary to build a set numberof boats will shrin Steve KU.bisen, president of Pennsylvania-based VEC Technology Inc., the subsidiary Gen formed to develop the new technology. Genmar currently employs about 6,400 people in plants. Non-US markets are different
One factor in its future decisions about Europe, pointed out by Jacobs, is that the VEC ass line process is suitable for produdng large numbers of identical smaller boats, which is ttl of the' us markel Larger boats, which are frequently customized, can't be built on a moving assembly line s ome Savings in building the small number of hulls produced becomes a much smaller**pr~p** the whole time spent on the yacht. Therefore, the cost savings for a big boat built with VE not be significant. AlsO, there are no companies in Europe produdng large numbers ofsmaller boats, as is d the United States. Large-volume European boatbuilders measure production in hundreds not tens of thousands.
The same situation ap'plies in Australia and New Zealand, though Wesley Moxey, managin director ofThe Riviera Group, manufacturers of Rivieras, Mariners and Australian-built We says Genmar's**te~nology** will have a big impact on the productron of smaller boats.
The main obstacle to adopting VEC in AustrRlia is the high cost of entry, says Moxey, but p'roduction savings could do for the boatbuild.ing industry what it has done for the cost of manufacturing consumer electronics. Also, the cost ofVEC technology itselfwill decrease and more companies adopt it.
Until Genmar can-develop a market for large quantiDes of smaller boats in Europe and Au appears likely most VEC manufacturing will remain in North America. Genmar has several new technologies coming soon that will continue to improve efficienc reduce styrene emissions. Jacobs says the company is so far ahead ofthe competition, it i running a race against itself for the iead in boatbuiiding technology.
Within six months to a year, Genmar plans on switching from traditional gelcoat in the VE to a type of "film' that will not**emi~** voiatiie organic compounds (VOC). Tradiiional geicoat be applied by handheid equipmentwhen the moid is open, aHowing high levels ofVOCS to emitted.
This film technoiogy wiH iower the total VOC emissions from a VEC plant to the point wher factories can be' built anywhere, even in the middle of populated areas, says Jacobs.
And Jacobs is predicting further effidendes will mean eventually as many as20,000 boats wHi be built from a standard 8,83S-square-metre VEC planl
Traditional boatbuilding not dead

7/17/01Article Archives Page J of 3

Other companies mass-producing boats, like canada-based Bombardier Recreational Prod continue to refine more traditional technology to reduce emissions. 'Rock Lambert, vice president and general**man~ger** of Bombardier's Sea-Doo sport boat di says the company believes its styrene control systems will be adequate for any foreseeabl Environmental Protection Agency limits that may be. imposed. The Illinois manufacturing facility for Sea-Doc sport boats and some personal watercraft ( utilizes a traditional, open-mold type of construction, but the molds are in sealed chamber spedal filters an'd ventilators. The exhausted air is indnerated

.

.

## , Sea-Doc is produdngl up to 48 boats a day from one plant, putting it into the mass-produ category that might seem appropriate for VEe. The boats are sold in 70 countries around world.

, But Lambert says the company can't see dearadvantages for the VEe system, particularly Sea-Ooo is already produdng large numbers of boats successfully and meeting styrene e goals. Sea-Doo has already made a large investment in deaning up its traditional open-mold pro and achange to VEe would mean a massive investment in plant and retraining_ However, Lambert does acknowledge that the company is constantly testing and reviewin technologies. Low-styrene resins and gel coats may be needed in the future, depending a regulatory develop.ments.

. With a change to VEe appearing to be too costly for both small boatbuilders and large op Genmar may find the future for marketing this technology lies mainly outside the boatbuil industry. For related information, please visit**WY:fN.boat!D.9:(ru;I.Y..~t[Y,C:Q.rrJ"** and use the following key an article search: VEe, Genmar, boatbuilding.**N~~~~~~~~~~inc.** Click. Here for dowls on our PrivaCY Policy ThiS site bestviewed with: !:'l_ETSCAPE_4.7 or lntemel**EX?~£f~~** ,

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