November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City: State: TX Zip Code: 75244

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments owned): 3000

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City: State: TX Zip Code: 77503

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 146

Dallas

5005 LBJ Freeway, Suite 2200

Occidental Chemical Corporation

281-884-4047

tyrone_barren@oxy.com

Oxy Vinyls, LP (Pasadena Plant)

4403 Pasadena Freeway

Pasadena

Tyrone Barren
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

Form C-1-c Supplemental Questions

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 39900 liters/hour

 liters

Process Unit ID: U-1202

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

Process Equipment ID: C-397

Wastewater Feed Rate (lb/hr): 87700 Not Available liters/hour (max design)

Feed Temperature (°F): 140 liters (max design)

Feed Inlet Pressure (psia): 15.2

Liquid Loading Rate (liters/m2): Not Available

Steam Feed Rate (lb/hr): 6000

Steam to Feed Ratio (kg steam/liter of wastewater): 0.068

Operating Temperature (°F): 206

Operating Pressure (psig): 0.5

Total Number of Stages: 1

Overall Calculated Tray Efficiency: Not Available

Stripping Factor: Not Available

Flow configuration (countercurrent, cocurrent): Countercurrent

Number of Actual Trays: 15

Column Height (meters): 9.04

Year Equipment Installed: 1977

Equipment Currently Regulated Under (cite regulations): 40 CFR 61, Subpart F, 40 CFR 61, Subpart V, 30 TAC 116

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if 

necessary below.
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

C-1023 A Incinerator Absorber Water Effluent W-1043 0 108000 104000 Measured 365 C-1023 Incinerator Absorber WWT Biological Wastewater Treatment Unit Yes

C-1023 B Incinerator Absorber Water Effluent W-1043 0 108000 104000 Measured 365 C-1023 Incinerator Absorber WWT Biological Wastewater Treatment Unit Yes

C-1024 IncineratorScrubber Effluent W-1046 0 43000 43000 Measured 365 C-1024 Incinerator Scrubber WWT Biological Wastewater Treatment Unit Yes

U-307 Dryer 1 CEW W-312 0 235000 201000 Measured 365 U-307 Dryer 1 Centrifuge WWT Biological Wastewater Treatment Unit Yes

U-407 Dryer 2 CEW W-412 0 251000 222000 Measured 365 U-407 Dryer 2 Centrifuge WWT Biological Wastewater Treatment Unit Yes

U-507 Dryer 3 CEW W-512 0 234000 210000 Measured 365 U-507 Dryer 3 Centrifuge WWT Biological Wastewater Treatment Unit Yes

U-607 Dryer 4 CEW W-612 0 210000 184000 Estimated 365 U-607 Dryer 4 Centrifuge WWT Biological Wastewater Treatment Unit Yes

U-707 Dryer 5 CEW W-712 0 250000 207000 Estimated 365 U-707 Dryer 5 Centrifuge WWT Biological Wastewater Treatment Unit Yes

U-807 Dryer 6 CEW W-812 0 260000 210000 Estimated 365 U-807 Dryer 6 Centrifuge WWT Biological Wastewater Treatment Unit Yes

U-907 Dryer 7 CEW W-912 0 336000 261000 Measured 365 U-907 Dryer 7 Centrifuges WWT Biological Wastewater Treatment Unit Yes

Catalyst Bottle Wash Water from Solution Prep Oily Water Sump W-1236 0 2000 1000 Estimated 365 U-1222 Catalyst Bottle Washing Station WWT Biological Wastewater Treatment Unit Yes

OxyVinyls believes that W-1236 is maintenace wastewater

Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

U-1202 U-1207 Steam Stripping Continuous W1222 0 212000 178000 Measured 365 WWT Oxy Vinyls Wastewater Treatment Plant Yes

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

Flow Rate 

Determination 

Method

14

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 

below)

Associated Destination 

Information

(Refer to Table 3 below)

Operating Days 

Per Year

Type of Process 

Wastewater 

Treatment System

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

2

Originating PVC Process 

Equipment ID

Operating Days Per 

Year

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process 

equipment and its destination?

Originating PVC Process 

Equipment Description

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

PVC Process 

Wastewater 

Stream ID

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination Information
Table 3. PVC Process Wastewater Destination Codes Table

Code

Wastewater treatment system WWT Provide name of the wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall

Discharge to POTW, no treatment POTWRAW Provide name of POTW

Discharge to PrOTW, no treatment PrOTWRAW Provide name of PrOTW

Zero discharge or alternative disposal method ZEROALT Describe method

Recycle to process RECYC Describe where in the process the stream is recycled

Other OTHER Describe

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System

2 3 4 5 6 7

Min Max Average

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

Operating Days 

Per Year

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

1

Destination Description Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

01/14/13 01/15/13

1/15/2013 - 1/19/2013 1/15/2013 - 1/19/2013 1/17/2013 - 1/31/2013

PAS PVC WW Stripper Day 7 PAS PVC WW Stripper Day 8 PAS PVC WW Stripper Day 9

130047-8 130047-9 130047-10

CAS No. HAP Analysis Method Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

107211 Ethylene glycol SW-846-8015C 10 Non-detect 10 Non-detect 10 Non-detect

67561 Methanol SW-846-8015C 674 783 623

75070 Acetaldehyde SW-846-8315A 4.11 4.26 3.63

50000 Formaldehyde SW-846-8315A 0.075 Non-detect 0.075 Non-detect 0.15 Non-detect

51285 2,4-dinitrophenol SW-846-8270D 0.7 Non-detect 0.7 Non-detect 0.35 Non-detect

98862 Acetophenone SW-846-8270D 7.54 7.8 6.53

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.5 Non-detect 0.5 Non-detect 0.25 Non-detect

123319 Hydroquinone SW-846-8270D R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.5 Non-detect

108952 Phenol SW-846-8270D 0.1 Non-detect 0.1 Non-detect 0.05 Non-detect

79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

106990 1,3-butadiene SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

540841 2,2,4-trimethylpentane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

71432 Benzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

108907 Chlorobenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

67663 Chloroform SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

126998 Chloroprene SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

98828 Cumene SW-846-8260B 0.001 Non-detect 0.002 J-estimated sample result 0.011 J-estimated sample result

75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.068 J-estimated sample result

100414 Ethylbenzene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.01 J-estimated sample result

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

74873 Methyl chloride (Chloromethane) SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

75092 Methylene chloride SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

110543 n-Hexane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

108883 Toluene SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

79005 1,1,2-Trichloroethane SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

108054 Vinyl acetate SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

593602 Vinyl bromide SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

75014 Vinyl chloride EPA Method 107 0.097 0.011 0.018

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

1330207 Xylenes (isomers and mixtures) SW-846-8260B 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

No Reading

180

01/13/13

No Reading 170

180 175

Measured Measured Measured

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date -->

suspension suspension suspension

Page 1 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 01/16/13 01/17/13 01/18/13

1/17/2013 - 1/31/2013 1/18/2013 - 2/1/2013 1/21/2013 - 2/1/2013

PAS PVC WW Stripper Day 10 PAS PVC WW Stripper Day 11 PAS PVC WW Stripper Day 12

130047-11 130047-12 130047-13

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

530 519 649

4.79 5.78 4.62

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

7.38 7.13 3.99

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.5 Non-detect 0.5 Non-detect 0.5 Non-detect

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 J-estimated sample result 0.005 J-estimated sample result 0.001 Non-detect

0.004 J-estimated sample result 0.004 J-estimated sample result 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.019 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.003 J-estimated sample result 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.047 0.010 Non-detect 0.010 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.003 J-estimated sample result 0.002 Non-detect

168 143

178 186

Measured Measured

158

182

Measured

suspension suspension suspension

Page 2 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 01/19/13 01/20/13 01/21/13

1/21/2013 - 1/30/2013 1/22/2013 - 2/5/2013 1/23/2013 - 2/5/2013

PAS PVC WW Stripper Day 13 PAS PVC WW Stripper Day 14 PAS PVC WW Stripper Day 15

130047-14 130047-16 130047-17

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

557 745 916

3.94 5.22 7.41

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

5.08 5.47 5.28

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.010 Non-detect 0.328 0.082

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

suspension

Measured

181 177 171

150 152 149

Measured Measured

suspension suspension

Page 3 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 01/22/13 01/23/13 01/24/13

1/23/2013 - 2/5/2013 1/24/2013 - 2/8/2013 1/25/2013 - 2/13/2013

PAS PVC WW Stripper Day 16 PAS PVC WW Stripper Day 17 PAS PVC WW Stripper Day 18

130047-18 130213-1 130213-2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

673 663 548

5.93 8.15 4.43

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

5.42 4.72 6.22

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.005 J-estimated sample result 0.002 J-estimated sample result

0.001 Non-detect 0.068 J-estimated sample result 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.009 J-estimated sample result 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.003 J-estimated sample result 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.010 Non-detect 0.224 0.010 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

162 157

150

Measured Measured

152

suspension

Measured

170

156

suspension suspension

Page 4 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 01/25/13 01/26/13 01/27/13

1/26/2013 - 2/8/2013 1/29/2013 - 2/9/2013 1/29/2013 - 2/14/2013

PAS PVC WW Stripper Day 19 PAS PVC WW Stripper Day 20 PAS PVC WW Stripper Day 21

130213-3 130213-5 130213-6

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

722 697 722

5.78 3.88 4.7

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

5.76 7.21 7.22

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 J-estimated sample result 0.001 Non-detect 0.004 J-estimated sample result

0.001 Non-detect 0.001 Non-detect 0.002 J-estimated sample result

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.150 0.090 0.024

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

177 176 172

156 153 150

Measured Measured Measured

suspension suspension suspension

Page 5 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 01/28/13 01/29/13 01/30/13

1/31/2013 - 2/14/2013 1/31/2013 - 2/17/2013 1/31/2013 - 2/17/2013

PAS PVC WW Stripper Day 22 PAS PVC WW Stripper Day 23 PAS PVC WW Stripper Day 24

130213-7 130213-8 130213-9

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

832 621 787

5.65 4.41 5.18

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

3.94 7.66 4.52

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 J-estimated sample result 0.001 Non-detect 0.002 J-estimated sample result

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.015 0.010 Non-detect 0.010 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

175 175

suspension

152

Measured Measured Measured

171

154 149

suspension suspension

Page 6 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 01/31/13 02/01/13 02/02/13

1/31/2013 - 2/17/2013 2/4/2013 - 2/17/2013 2/4/2013 - 2/18/2013

PAS PVC WW Stripper Day 25 PAS PVC WW Stripper Day 26 PAS PVC WW Stripper Day 27

130213-10 130213-11 130213-12

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

587 791 780

4.14 5.38 5.41

0.15 Non-detect 0.15 Non-detect 0.247 J-estimated sample result

0.35 Non-detect 0.35 Non-detect 0.7 Non-detect

7.71 5.43 11

0.25 Non-detect 0.25 Non-detect 0.5 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.1 Non-detect

0.002 J-estimated sample result 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.005 J-estimated sample result 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.006 J-estimated sample result

0.002 J-estimated sample result 0.001 Non-detect 0.03 J-estimated sample result

0.001 Non-detect 0.001 Non-detect 0.033 J-estimated sample result

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.016 J-estimated sample result

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.004 J-estimated sample result 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.010 Non-detect 0.010 Non-detect 0.906

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

172 170

suspension suspension suspension

172

Measured Measured Measured

152 155 153

Page 7 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 02/03/13 02/04/13 02/05/13

2/4/2013 - 2/17/2013 2/4/2013 - 2/11/2013 2/5/2013 - 2/17/2013

PAS PVC WW Stripper Day 28 PAS PVC WW Stripper Day 29 PAS PVC WW Stripper Day 30

130213-13 130213-14 130213-16

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

736 689 787

6.09 6.02 7.44

0.15 Non-detect 0.216 J-estimated sample result 0.15 Non-detect

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

9.54 5.84 5.9

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 J-estimated sample result 0.003 J-estimated sample result 0.001 J-estimated sample result

0.002 J-estimated sample result 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.036 0.010 Non-detect 0.010 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

Measured Measured

160

170 165

suspension suspension suspension

165

159 156

Measured

Page 8 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 02/06/13 02/07/13 02/08/13

2/6/2013 - 2/17/2013 2/8/2013 - 2/18/2013 2/8/2013 - 2/18/2013

PAS PVC WW Stripper Day 31 PAS PVC WW Stripper Day 32 PAS PVC WW Stripper Day 33

130213-17 130213-18 130213-19

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

932 932 856

7.23 6.95 6.2

0.15 Non-detect 0.15 Non-detect 0.203 J-estimated sample result

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

8.42 7.01 7.64

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 J-estimated sample result 0.001 J-estimated sample result 0.001 J-estimated sample result

0.003 J-estimated sample result 0.003 J-estimated sample result 0.001 J-estimated sample result

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 J-estimated sample result 0.002 J-estimated sample result 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.017 0.017 0.029

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

Measured

160

Measured Measured

153 153

155 155

suspension suspension suspension

155

Page 9 of 10
Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

Flow Rate Determination Method -->

Sample Date --> 02/09/13 02/10/13 02/11/13

2/12/2013 - 2/18/2013 2/12/2013 - 2/18/2013 2/12/2013 - 2/18/2013

PAS PVC WW Stripper Day 34 PAS PVC WW Stripper Day 35 PAS PVC WW Stripper Day 36

130213-21 130213-22 130213-23

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect

1020 1000 1060

5.05 5.3 4.82

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.35 Non-detect 0.35 Non-detect 0.35 Non-detect

6.91 5.05 6.98

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

R

result rejected due to poor analyte efficiency

R

result rejected due to poor analyte efficiency

0.5 Non-detect

0.05 Non-detect 0.05 Non-detect 0.05 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 J-estimated sample result 0.002 J-estimated sample result 0.001 J-estimated sample result

0.001 Non-detect 0.001 J-estimated sample result 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 J-estimated sample result 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.013 0.021 0.010 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

suspension suspension suspension

Measured

177 175

162 154

Measured Measured

175

160

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