MONTREAL PROTOCOL 

ON SUBSTANCES THAT DEPLETE 

THE OZONE LAYER 

UNEP 

REPORT OF THE

TECHNOLOGY AND ECONOMIC ASSESSMENT PANEL

MAY 2011 

VOLUME 1 

PROGRESS REPORT

UNEP 

MAY 2011 REPORT OF THE

TECHNOLOGY AND ECONOMIC

ASSESSMENT PANEL

VOLUME 1 

PROGRESS REPORT
iv May 2010 TEAP Progress Report 

Montreal Protocol 

On Substances that Deplete the Ozone Layer 

Report of the 

UNEP Technology and Economic Assessment Panel 

May 2011 

VOLUME 1 

PROGRESS REPORT

The text of this report is composed in Times New Roman. 

Co-ordination: Technology and Economic Assessment Panel 

Composition of the report: Lambert Kuijpers and Meg Seki (UNEP) 

Layout and formatting: Ozone Secretariat (UNEP) 

 Lambert Kuijpers (UNEP TEAP) 

Date: May 2011 

Under certain conditions, printed copies of this report are available from: 

UNITED NATIONS ENVIRONMENT PROGRAMME 

Ozone Secretariat, P.O. Box 30552, Nairobi, Kenya 

This document is also available in portable document format from the UNEP Ozone 

Secretariat's website: 

http://www.unep.org/ozone/teap/Reports/TEAP_Reports/

No copyright involved. This publication may be freely copied, abstracted and cited, with 

acknowledgement of the source of the material. 

ISBN: 978-9966-20-004-4
May 2010 TEAP Progress Report v

Disclaimer 

The United Nations Environment Programme (UNEP), the Technology and Economic Assessment 

Panel (TEAP) Co-chairs and members, the Technical Options Committees Co-chairs and members, the 

TEAP Task Forces Co-chairs and members, and the companies and organisations that employ them do 

not endorse the performance, worker safety, or environmental acceptability of any of the technical 

options discussed. Every industrial operation requires consideration of worker safety and proper 

disposal of contaminants and waste products. Moreover, as work continues - including additional 

toxicity evaluation - more information on health, environmental and safety effects of alternatives and 

replacements will become available for use in selecting among the options discussed in this document. 

UNEP, the TEAP Co-chairs and members, the Technical Options Committees Co-chairs and members, 

and the TEAP Task Forces Co-chairs and members, in furnishing or distributing this information, do 

not make any warranty or representation, either express or implied, with respect to the accuracy, 

completeness, or utility; nor do they assume any liability of any kind whatsoever resulting from the use 

or reliance upon any information, material, or procedure contained herein, including but not limited to 

any claims regarding health, safety, environmental effect or fate, efficacy, or performance, made by the 

source of information. 

Mention of any company, association, or product in this document is for information purposes only and 

does not constitute a recommendation of any such company, association, or product, either express or 

implied by UNEP, the Technology and Economic Assessment Panel Co-chairs or members, the 

Technical and Economic Options Committee Co-chairs or members, the TEAP Task Forces Co-chairs 

or members or the companies or organisations that employ them. 

Acknowledgements 

The Technology and Economic Assessment Panel, its Technical Options Committees and the Task 

Forces Co-chairs and members acknowledges with thanks the outstanding contributions from all of the 

individuals and organisations that provided support to Panel, Committees and Task Forces Co-chairs 

and members. The opinions expressed are those of the Panel, the Committees and Task Forces and do 

not necessarily reflect the reviews of any sponsoring or supporting organisation. 

The TEAP thanks UNEP Reginal Office Europe in Geneva, Switzerland, for hosting the TEAP 

meeting, 8-12 May 2011, where this report was discussed and reviewed.

TEAP May 2011 Progress Report vii

Foreword 

The TEAP 2011 Progress Report 

The May 2011 TEAP Progress Report consists of two volumes: 

Volume 1 TOC Progress Reports, EUN and CUN Reports and several Task Force 

Reports. This report is the Volume 1 report. 

This Volume 1 May 2011 TEAP Progress Report starts with an Introduction, which mentions 

that this TEAP Progress Report updates previous reports and presents good news on technical 

innovation in every sector. 

It also contains an evaluation of the Essential Use Nominations followed by the Medtical 

Technical Options Committee Progress Report. 

These are followed by the Chemicals Technical Options Committee Progress Report and the 

Task Force report that responds to the request made by Parties in Decision XXII/10. 

Next one will find two more Progress Reports, one of the Halons Technical Options 

Committee and one of the Methyl Bromide Technical Options Committee; the latter is 

followed by the CUN evaluation report by the same Technical Options Committee. 

In the last part of the Progress Report the report of the Task Force on decision XXII/22 is 

given. Two short chapters on TEAP operation and TEAP recusal complete this report. As a 

last piece of information, the TEAP and TOC Membership lists are given as an Annex, status 

May 2011. 

Volume 2 Task Force Report for the Funding Requirement for the Replenishment of the 

Multilateral Fund for the triennium 2012-2014. 

The separate Volume 2 of the TEAP Progress Report contains the report of the Task Force 

responding to Decision XXII/3 on the funding requirement for the replenishment of the 

Multilateral Fund for the triennium 2012-2014. 

In this Volume 2 report the Executive Summary has been placed upfront, followed by a 

number of chapters on data, cost effectiveness, methodologies, etc. Chapters 8 and 9 give 

information on the estimated funding requirement for the triennium 2012-2014 and indicative 

funding requirement amounts for the two triennia beyond. 

The UNEP Technology and Economic Assessment Panel: 

Stephen O. Andersen, co-chair USA Marta Pizano COL 

Lambert Kuijpers, co-chair NL Ian Porter AUS 

Marta Pizano, co-chair COL Miguel Quintero COL 

Paul Ashford UK Ian Rae AUS 

Mohamed Besri MOR Helen Tope AUS 

David Catchpole UK Dan Verdonik USA 

Biao Jiang PRC Ashley Woodcock UK 

Bella Maranion USA Masaaki Yamabe J 

Michelle Marcotte CDN Shiqiu Zhang PRC 

Roberto Peixoto BRA 

TEAP May 2011 Progress Report ix

UNEP 

MAY 2011 REPORT OF THE

TECHNOLOGY AND ECONOMIC

ASSESSMENT PANEL

VOLUME 1 

PROGRESS REPORT

TABLE OF CONTENTS ....................................................................................................................... PAGE 

FOREWORD.................................................................................................................................................VII

1 HIGHLIGHTS OF TECHNICAL SUCCESS........................................................................1

1.1 HIGHLIGHTS OF TECHNICAL SUCCESS ON PROTECTING STRATOSPHERIC OZONE 

AND CLIMATE...............................................................................................................................1

1.2 TECHNOLOGY ISSUES NEEDING RESOLUTION..............................................................................3

1.2.1 Phaseout from CFCs in MDIs .....................................................................................................3

1.2.2 Use or Destruction of Stockpiles .................................................................................................3

2 ESSENTIAL USES....................................................................................................................5

2.1 EXECUTIVE SUMMARY OF ESSENTIAL USE NOMINATIONS FOR METERED DOSE 

INHALERS .....................................................................................................................................5

2.2 ESSENTIAL USE NOMINATIONS FOR METERED DOSE INHALERS .................................................8

2.2.1 Criteria for Review of Essential Use Nominations for MDIs.....................................................8

2.2.2 Review of Nominations ................................................................................................................8

2.2.3 Observations ................................................................................................................................8

2.2.4 Affordability of CFC-free Inhalers..............................................................................................9

2.2.5 Company size and product demand...........................................................................................10

2.2.7 Slow processes are delaying transition.....................................................................................12

2.2.8 Exported products......................................................................................................................13

2.2.9 Anti-cholinergics........................................................................................................................14

2.2.10 Sodium cromoglycate.................................................................................................................14

2.2.11 Combination products ...............................................................................................................14

2.2.12 New CFC MDI products being launched after 2010................................................................15

2.2.13 Stockpiles ...................................................................................................................................15

2.2.14 Bangladesh................................................................................................................................15

2.2.15 People's Republic of China........................................................................................................18

2.2.16 Pakistan......................................................................................................................................25

2.2.17 Russian Federation....................................................................................................................27

2.3 REPORTING ACCOUNTING FRAMEWORKS FOR ESSENTIAL USE EXEMPTIONS AND 

ISSUES FOR COUNTRIES IN THE FINAL STAGES OF TRANSITION ..................................................29

2.3.1 Argentina....................................................................................................................................29

2.3.2 Egypt ..........................................................................................................................................30

2.3.3 European Union.........................................................................................................................30

2.3.4 India ...........................................................................................................................................30

2.3.5 Iran.............................................................................................................................................31

2.3.6 Syria ...........................................................................................................................................31

2.3.7 United States ..............................................................................................................................31

3 MEDICAL TECHNICAL OPTIONS COMMITTEE PROGRESS REPORT ...............33

3.1 EXECUTIVE SUMMARY ...............................................................................................................33

3.2 GLOBAL USE OF CFCS FOR MDIS ..............................................................................................34

3.3 CFC STOCKPILES ........................................................................................................................35

3.4 CFC PRODUCTION ......................................................................................................................38
x TEAP May 2011 Progress Report

3.5 ESTIMATED FUTURE CFC USAGE FOR MDIS..............................................................................38

3.6 TRANSITION AWAY FROM THE USE OF CFC MDIS.....................................................................40

3.6.1 Transition strategies ..................................................................................................................40

3.6.2 Progress reports on transition strategies under Decision XII/2 ..............................................42

3.7 GLOBAL DATABASE IN RESPONSE TO DECISION XIV/5..............................................................42

3.8 EXPORT MANUFACTURING TRANSITION PLANS IN RESPONSE TO DECISION 

XVIII/16.....................................................................................................................................43

4 CHEMICALS TECHNICAL OPTIONS COMMITTEE (CTOC) PROGRESS 

REPORT...................................................................................................................................45

4.1 EXECUTIVE SUMMARY ...............................................................................................................45

4.2 INTRODUCTION ...........................................................................................................................48

4.3 PROCESS AGENTS .......................................................................................................................48

4.3.1 Revision of Table A....................................................................................................................48

4.3.2 Revision of Table B....................................................................................................................50

4.3.3 Alternatives to Process Agents ..................................................................................................51

4.3.4 Information on process agents uses in the European Union....................................................51

4.4 LABORATORY AND ANALYTICAL USES......................................................................................51

4.4.1 Analyses for which there are no non-ODS alternatives ...........................................................51

4.4.2 National and international standards .......................................................................................52

4.4.3 Reporting to the Ozone Secretariat...........................................................................................53

4.4.4 Possible exemptions...................................................................................................................54

4.5 REVIEWS OF ESSENTIAL USE NOMINATIONS .............................................................................54

4.5.1 Essential Use Nomination of CFC-113 for Aerospace Industries by the Russian 

Federation..................................................................................................................................54

4.5.2 Essential Use Nomination of solvent use of BCM for polymeric flame retardants 

by Jordan....................................................................................................................................56

4.6 SOLVENTS AND UPDATE OF N-PB ..............................................................................................58

4.6.1 Solvent update............................................................................................................................58

4.6.2 n-Propyl Bromide (n-PB) Update .............................................................................................59

4.7 CARBON TETRACHLORIDE (CTC) EMISSIONS AND OPPORTUNITIES FOR 

REDUCTION ................................................................................................................................59

4.8 FEEDSTOCKS...............................................................................................................................61

4.8.1 Montreal Protocol definitions ...................................................................................................61

4.8.2 Where they are used...................................................................................................................61

4.8.3 Estimated emissions of ODS......................................................................................................62

4.9 DESTRUCTION TECHNOLOGIES...................................................................................................62

4.9.1 Necessity of new criteria of the destruction technologies.........................................................63

4.9.2 Recent literature ........................................................................................................................63

4.9.3 Destruction projects in Article 5 Parties...................................................................................63

5 TEAP TASK FORCE RESPONSE TO DECISION XXII/10............................................65

5.1 CONTEXT AND CONTENT OF DECISION XXII/10........................................................................65

5.2 TASK FORCE COMPOSITION........................................................................................................66

5.3 PERFORMANCE CRITERIA ...........................................................................................................68

5.3.1 Destruction and Removal Efficiency (DRE) vs. Destruction Efficiency (DE) .........................68

5.3.2 Destruction and Removal Efficiency in Perspective.................................................................69

5.3.3 The Case for moving the dioxin/furan limits for ODS ..............................................................69

5.3.4 Destruction and Removal Efficiency for Methyl Bromide........................................................70

5.3.5 Specific concerns about brominated dioxins/furans.................................................................70

5.3.6 Conclusions on Performance Criteria ......................................................................................71

5.4 EVALUATION OF EMERGING TECHNOLOGIES.............................................................................71

5.4.1 Generic technologies vs. specific (proprietary) technologies ..................................................71

5.4.2 Status of previous ‘high potential’ technologies.......................................................................71

5.4.3 Assessment of Each Technology................................................................................................72

5.5 DEVELOPMENT OF VERIFICATION CRITERIA..............................................................................74
TEAP May 2011 Progress Report xi

5.5.1 Maximising Destruction or Quantifying Destruction? .............................................................74

5.5.2 Status of Code of Good Housekeeping......................................................................................77

5.5.3 Further Verification Needs for Quantifying Destruction .........................................................78

5.5.4 Use of a Voluntary Annex for Verification Purposes................................................................79

5.6 POSSIBLE TEXT FOR A VOLUNTARY ANNEX TO THE CODE ........................................................79

6 HTOC PROGRESS REPORT...............................................................................................83

6.1 ALTERNATIVE AGENTS ..............................................................................................................83

6.2 HALON 1301 USE AS A FEEDSTOCK ...........................................................................................83

6.3 HALON RECOVERY AND RECYCLING IN ARTICLE 5 COUNTRIES ...............................................83

6.4 CONTAMINATED RECYCLED HALONS ........................................................................................84

6.5 UPDATE ON THE RESPONSE TO DECISION XXI/7 .......................................................................84

7 MBTOC PROGRESS REPORT............................................................................................87

7.1 QUARANTINE AND PRE-SHIPMENT (QPS)...................................................................................87

7.1.1 Consumption of methyl bromide for QPS .................................................................................87

7.1.2 International Plant Protection Convention...............................................................................88

7.1.3 Report of the CPM Informal Working Group on Strategic Planning ......................................89

7.1.4 IPPC Standard setting, topics and priorities ............................................................................89

7.1.5 Technical Panels and Expert Working Groups.........................................................................89

7.1.6 IPPC Strategic Framework 2012-2019.....................................................................................92

7.1.7 Legislative updates and clarifications.......................................................................................94

7.1.8 Procedures to find alternatives .................................................................................................96

7.2 SOILS ........................................................................................................................................101

7.2.1 Scope of the report...................................................................................................................101

7.2.2 Chemical alternatives for soil fumigation...............................................................................101

7.2.3 Non chemical alternatives in the soil sector ...........................................................................102

7.2.4 Remaining challenges..............................................................................................................103

7.2.5 References ................................................................................................................................104

7.3 ECONOMIC ISSUES RELATING TO MB PHASE-OUT....................................................................106

7.3.1 Components of an assessment of financial feasibility.............................................................106

7.3.2 Estimating the components for assessing financial feasibility ...............................................107

7.3.3 Default values ..........................................................................................................................108

7.3.4 References ................................................................................................................................108

7.4 STRUCTURES AND COMMODITIES ............................................................................................108

7.4.1 Regulatory News......................................................................................................................109

7.4.2 Special review on achieving control of pest eggs by sulfuryl fluoride - key 

messages resulting from the review of SF efficacy against pest eggs ....................................110

7.4.3 References ................................................................................................................................115

8 2011 EVALUATIONS OF CRITICAL USE NOMINATIONS FOR METHYL 

BROMIDE AND RELATED MATTERS – INTERIM REPORT ..................................137

8.1 SCOPE OF THE REPORT .............................................................................................................137

8.2 CRITICAL USE NOMINATIONS FOR METHYL BROMIDE............................................................138

8.2.1. Mandate ...................................................................................................................................138

8.2.2. Fulfilment of Decision IX/6 .....................................................................................................138

8.2.3 Consideration of Stocks - Decision Ex.1/4 (9f).......................................................................139

8.2.4. Reporting of MB Consumption for Critical Use - Decision XVII/9 .......................................141

8.2.5 Trends in Methyl Bromide Use for CUEs since 2005.............................................................142

8.2.6 Evaluations of CUNs – 2011 round for 2013 exemptions ......................................................147

8.2.7 Critical Use Nominations Review ...........................................................................................148

8.2.8 Disclosure of Interest...............................................................................................................148

8.3 ARTICLE 5 ISSUES .....................................................................................................................149

8.4. MBTOC-SOILS: FINAL EVALUATIONS OF 2011 CRITICAL USE NOMINATIONS FOR 

PREPLANT SOIL USE OF METHYL BROMIDE ............................................................................150

8.4.1 Minority Reports......................................................................................................................150
xii TEAP May 2011 Progress Report

8.4.2 Summary of interim recommendations....................................................................................150

8.4.3. Issues related to CUN Assessment for Preplant Soil Use.......................................................152

8.4.4. Standard presumptions used in assessment of nominated quantities.....................................154

8.4.5. Adjustments for standard dosage rates using MB/Pic formulations......................................156

8.4.6. Use/Emission reduction technologies - Low permeability barrier films and 

dosage reduction......................................................................................................................156

8.5 MINORITY REPORTS .................................................................................................................157

8.5.1. Minority Report 1: United States of America nomination for the use of methyl 

bromide for strawberry fruit production in California in 2013 .............................................157

8.5.2 Minority Report 2: United States of America nomination for the use of methyl 

bromide for tomato, pepper, cucurbit and eggplant production in the USA..........................159

8.5.3 Minority Report 3: Nomination submitted by Canada for the use of methyl 

bromide for the production of strawberry runners on Prince Edward Island .......................160

8.6. REPORT PRESENTED AFTER THE TEAP DECISION ON THE US STRAWBERRY CUN

BY SOME MEMBERS WHO SUPPORTED THE MAJORITY POSITION AFTER THE 

MBTOC MEETING....................................................................................................................175

8. 7. INTERIM CUN REPORT – ISSUES SPECIFIC TO MBTOC-STRUCTURES AND 

COMMODITIES ..........................................................................................................................176

8.7.1. Standard Dosage Presumptions and Adjustments for standard dosage rates .......................178

8.7.2. Details of evaluations ..............................................................................................................178

8.8. REFERENCES .............................................................................................................................189

ANNEX 1 TO CHAPTER 8. DECISION IX/6............................................................................................194

ANNEX II TO CHAPTER 8 DECISION XVI/4 .........................................................................................195

ANNEX III TO CHAPTER 8 - PART A: HISTORICAL TREND IN MB PREPLANT SOIL 

NOMINATIONS AND EXEMPTIONS ............................................................................................196

ANNEX IV TO CHAPTER 8 – PART B: HISTORICAL TREND IN MB STRUCTURAL AND 

COMMODITY NOMINATIONS AND EXEMPTIONS.......................................................................202

9 RESPONSE TO DECISION XXII/22 – MEMBERSHIP CHANGES ON THE 

ASSESSMENT PANELS......................................................................................................209

9.1 EXECUTIVE SUMMARY..............................................................................................................209

9.2 INTRODUCTION .........................................................................................................................210

9.2.1 Mandate and scope of the report.............................................................................................210

9.2.2 Organization of work...............................................................................................................211

9.3 ON SIZE AND BALANCE.............................................................................................................211

9.3.1 Balance in the TOCs...............................................................................................................212

9.3.2 Balance and membership in TSBs...........................................................................................213

9.4 MATRICES OF GAPS AND AVAILABLE EXPERTISE .....................................................................213

9.4.1 Current matrix of needed expertise.........................................................................................213

9.4.2 Update to matrix of needed expertise......................................................................................214

9.4.3 Matrices of current capabilities ..............................................................................................215

9.4.4 Updated matrix of current capabilities...................................................................................218

9.5 GUIDELINES FOR NOMINATIONS ...............................................................................................218

9.5.1 TEAP expert members. ............................................................................................................218

9.5.2 Co-chairs of TOCs...................................................................................................................218

9.5.3 TOC members ..........................................................................................................................219

9.5.4 Nomination Information ..........................................................................................................219

9.6 SUMMARY AND FINDINGS ........................................................................................................220

10 TEAP OPERATING PROCEDURES ................................................................................223

11 TEAP GUIDELINES ON RECUSAL.................................................................................225

ANNEX TEAP TOC MEMBERSHIP LIST STATUS MAY 2011.................................................229
TEAP May 2011 Progress Report 1

1 Highlights of Technical Success 

Stratospheric ozone depletion and climate change are intricately coupled. Ozone absorbs UV 

radiation and is a greenhouse gas (GHG). Stratospheric ozone influences surface climate and 

GHGs influence stratospheric ozone. Ozone-depleting substances (ODSs) not only destroy 

stratospheric ozone but are potent GHGs. Furthermore, hydrofluorocarbons (HFCs) that are 

chemical substitutes for some ODSs can also be potent GHGs. Hence, ozone layer and 

climate protection should be considered together in decisions to select new technology. 

The Montreal Protocol is working because control measures have created incentives for new 

technology, because enterprises and organizations have worked hard to implement new 

technology and because the Multilateral Fund (MLF) has been replenished to finance the 

agreed incremental costs of the transition for Article 5(1) Parties. 

With implementation of each new phase of technology, the Montreal Protocol has succeeded 

in reducing the production, use, and emissions of ODSs that are also potent greenhouse gases. 

Through these efforts, the world has avoided significant economic, environmental and health 

consequences of increases in ultraviolet radiation and climate change. 

Under the Montreal Protocol HCFCs were considered low-ODP “transitional substances” to 

replace high-ODP CFCs in circumstances when environmentally superior alternatives were 

not available. HFCs were developed as zero ODP alternatives but, in effect, have emerged as 

“transitional substances” in applications where new technology now offers low- or no-GWP 

options. A new irony faced by the Montreal Protocol is that HFCs are controlled in the basket 

of gases of the Kyoto Protocol and are increasingly regulated by many countries including 

Australia, the European Union, Japan, and the United States. These regulations include 

import taxes and or deposits on the manufacture or import of HFCs that are used to finance 

the cost of end-of-life (EoL) due to ODS and GHG destruction, phase-out of HFCs used in 

vehicle air conditioning, and prohibitions on HFC use. The challenge is to phase out HCFCs 

while avoiding high-GWP HFCs and while achieving high energy efficiency using 

technology that is safe and environmentally acceptable. It is called “leapfrogging” when the 

transition goes directly from HCFCs to low-GWP options. 

1.1 Highlights of Technical Success on Protecting Stratospheric 

Ozone and Climate 

This TEAP Progress Report updates previous reports and presents good news on technical 

innovation in every sector: 

Nominations for Essential Use Exemptions (EUEs) for Metered Dose Inhalers (MDIs) are 

declining rapidly, with nominations from only four countries for a total of about 800 tonnes 

recommended for 2012; a reduction of about 65 percent from 2010. 

Nominations for Critical Use Exemptions (CUEs) for 2013 (submitted in 2011) total only 

about 750 tonnes from four countries; an approximate 50% reduction in amount of MB 

requested compared to 2010 round with just 20 nominations. 

Nominations for preplant soil use were reduced from 27 to 13 with Israel and Japan no longer 

seeking CUEs. 

Plant nurseries are proving the most difficult area for MB phaseout for preplant soil uses, but 

only in 3 non-A5 countries (Australia, Canada and USA). 
2 TEAP May 2011 Progress Report

Stocks of MB in the USA have reduced dramatically but still significantly exceed annual MB 

requests for CUNs of MB. 

Process Agent uses allowed by the Montreal Protocol declined from 41 to 14; a net 

elimination of 27 processes worldwide. 

Changes to the applicable Annexes to the Chicago Convention on International Civil Aviation 

mandating the use of halon alternatives on board newly produced aircraft in the lavatory trash 

receptacles and handheld extinguishers, and in engine nacelles, and auxiliary power units in 

new designs are now imminent. A final decision is scheduled for 13 June 2011. 

A new purity specification for halon 1211 was approved that increases the level of confidence 

in relying on recycled halon 1211 in handheld extinguishers onboard aircraft. 

Low-GWP options continue to be commercialized for all applications with few uses still 

depending on HCFCs and high-GWP HFCs. 

• Low-GWP refrigerants and foam blowing agents are being rapidly announced and 

commercialized by companies with operations in both developed and developing 

countries. 

• Motor vehicle manufacturers and suppliers in Europe, Japan and the United States 

have endorsed HFC-1234yf as the refrigerant-of-choice to replace HFC-134a in 

mobile air conditioning (MACs). 

• HFC-152a and HFC-1234yf are listed under the US EPA (EPA) Significant New 

Alternatives Program (SNAP) as acceptable replacements in mobile air 

conditioning and EPA has announced that plans to remove (Un-SNAP) HFC-134a 

from the list of acceptable replacements. 

• New technology is also being commercialized to contain refrigerants and to 

recover and destroy ODSs and HFCs from banks contained in foam and 

refrigeration and air conditioning equipment. 

MB use for structures and commodities continues to decline in response to very positive 

results of research, registration, and adoption of alternatives. 

• Australia is committed to phasing out MB for its packaged rice by the end of 

2014.MBTOC is assisting Australia in determining how to kill the eggs of key rice 

insect pests with a new review of the published scientific literature, which is 

included in the 2011 Progress Report. 

• Canada did not renew its CUN for pasta facilities, which is evidence that 

alternatives for that sector have succeeded. 

• Israel completed adoption of alternatives for fresh dates and for the first time did 

not submit a postharvest CUN. 

• Japan has committed to the phase out of MB for fresh chestnuts in 2014 using 

methyl iodide identified an alternative through its research program and is now 

training its farmers and commercializing methyl iodide. 

• The US has very significantly decreased the MB quantities requested in almost all 

its postharvest CUNs and this year did not send a CUN for food processing 

facilities. 

MBTOC believes that adoption of sulfuryl fluoride alone or heat treatment allowed the US 

food processing sector to move away from methyl bromide. 
TEAP May 2011 Progress Report 3

1.2 Technology Issues Needing Resolution 

1.2.1 Phaseout from CFCs in MDIs 

There are two areas of concern remaining in the phase-out of CFCs from MDIs. Unable to 

phaseout by the 1996 non-Article 5 deadline, the Russian Federation has faced many delays 

and now projects phase-out by the end of 2013, despite the availability of affordable imported 

products. China, now the largest consumer of CFCs in MDIs, looks likely to continue until at 

least 2014, with total phase-out planned for 2016. 

Eighty-eight percent of global methyl bromide (MB) controlled uses have been phased out. 

However, increased use of MB for QPS uses not controlled by the Montreal Protocol is 

offsetting gains made by reductions in controlled uses for soils, structures and commodities. 

 Some of this increase is due to preplant soil use in propagation nursery sectors. TEAP 

estimates that currently available alternatives and substitutes could replace approximately 

22% to 33% of total QPS consumption. 

1.2.2 Use or Destruction of Stockpiles 

Stockpiles are the result of 1) ODS manufactured before the scheduled phaseout date and held 

as an investment or as a hedge against shortage; 2) ODS recovered from use and set aside for 

future use; 3) ODS inventory at a facility at the time of transition to ODS-free or transitional 

HCFC technology; 4) ODS granted under a EUE or CUE exemption but not necessary for the 

essential or critical use; or 5) ODS illegally produced or imported and held for illegal sale. 

The largest ODS stockpiles are managed by military organizations, private halon banks, and 

chemical and chemical reprocessing companies for use in applications they consider 

important or profitable. 

Under the Montreal Protocol, unwanted legal stockpiles, including ODS granted under an 

EUE or CUE, can be used for any domestic purpose and stockpiles granted under and EUE 

can be exported to another Party to satisfy a new EUE. Domestic regulations sometimes tax 

or restrict the use of stockpiles or compel collection and destruction, but it has been the 

experience worldwide that regulations that require the ODS owner to finance destruction 

frequently result in venting to the atmosphere. When MLF fails to finance the redeployment 

or destruction of ODS remaining at a facility after transition, there is a temptation to vent 

when no profitable market can be found and lack of financing can result in stocks leaking 

away from storage. 

It is important during the final stages of the phase-out of CFC MDIs that CFC stockpiles 

accumulated under essential use provisions are managed properly. 

It would be ironic if Parties who demanded excess EUE inventory to avoid shortages in CFCMDIs were to use those stockpiles for ordinary emissive uses, further depleting the ozone 

layer, with consequences to human health such as skin cancer, cataracts, and suppression of 

the human immune system. 

It would be consistent with the spirit and letter of the Montreal Protocol if ODS approved for 

essential use were only used for the purposes approved by Parties or destroyed and that all 

unwanted or unneeded ODS were collected and destroyed. 

TEAP May 2011 Progress Report 5

2 Essential Uses 

2.1 Executive Summary of Essential Use Nominations for Metered 

Dose Inhalers 

MTOC received 4 essential use nominations requesting a total of 877.34 tonnes of CFCs for 

the manufacture of metered dose inhalers (MDIs) in 2012, and 125 tonnes for 2013: 3 

nominations were from Article 5 countries (Bangladesh, China, Pakistan); and 1 was from a 

non-Article 5 country (Russian Federation). 

Table 2-1 summarises the recommendations of the Technology and Economic Assessment 

Panel (TEAP) and its Medical Technical Options Committee (MTOC) on nominations for 

essential use production exemptions for chlorofluorocarbons (CFCs) for MDIs. 

Recommendations are made in accordance with Decision XV/5(3), which requests TEAP and 

its MTOC to make recommendations on nominations for essential use exemptions for CFCs 

for MDIs with reference to the active ingredient of the metered-dose inhalers in which the 

CFCs will be used and the intended market for sale or distribution. Recommendations are for 

a total of 792.81 tonnes of CFCs for the manufacture of MDIs in 2012. 

Table 2-1: Recommendations for essential use nominations 

Party 2012 Active Ingredients Intended 

Markets 

Bangladesh 24.67 tonnes Ciclesonide, ipratropium, 

ipratropium/salbutamol, salmeterol and 

tiotropium 

Bangladesh 

528.14 tonnes Beclomethasone, 

beclomethasone/clenbuterol/ipratropium, 

budesonide, cromoglycate, datura metel 

extract/clenbuterol, dimethicone; 

ephedra, gingko, sophora flavescens and 

radix scutellariae; 

ipratropium/salbutamol, isoprenaline, 

isoprenaline/guaifenesin, procaterol, 

salbutamol, salmeterol 

China China 

3.9 tonnes Cromoglycate Cuba 

Pakistan 24.1 tonnes Beclomethasone, 

beclomethasone/salbutamol, 

fluticasone/salmeterol, salbutamol, 

salmeterol, triamcinolone acetonide 

Pakistan 

Russian 

Federation 

212 tonnes Salbutamol Russian 

Federation 

MTOC thanks the Ozone Secretariat for providing meeting venue sponsorship for the MTOC 

meeting held in Buenos Aires, Argentina, 20-22 March 2011. MTOC member, Dr Jorge 

Caneva, and the Ozone Program Office of Argentina (OPROZ) provided a range of 

organisational assistance. 
6 TEAP May 2011 Progress Report

In 2009, the first year of the essential use process for Article 5 countries, MTOC reviewed 

nominations from eight Article 5 countries. It is very encouraging to note that two years on, 

Argentina, Egypt, Iran, India and Syria did not nominate for essential uses of CFCs for MDIs 

for 2012. There have been significant reductions from about 2,400 tonnes of authorised 

essential use CFCs in 2010 to about 880 tonnes of CFCs nominated for 2012. 

Looking to the future, two major areas of concern remain. The first is Russia, a non-Article 5 

country where there have been repeated assurances that phase-out would have been 

completed by 2008. The use of CFCs in domestically produced MDIs is now projected to be 

required until 2013, despite the availability of affordable imported products from a number of 

manufacturers. The second is China, now the largest consumer of CFCs in MDIs, where 

consumption of greater than 500 tonnes per annum looks likely to continue until at least 2014, 

with total phase-out planned for 2016. 

MTOC accepts the need to protect the patients with limited economic means. With the 

production of a wide range of generic CFC-free inhalers at very low cost in Bangladesh, India 

and other Article 5 countries the argument of affordability is no longer valid. Pricing policies, 

tariffs, import taxes and restrictions have been implemented, which have the effect of 

protecting local industry, favouring locally made CFC MDIs, and discouraging the use of 

affordable imported CFC-free alternatives. Parties may wish to consider domestic policies 

(pricing, import and drug approvals) that will expedite the rapid transition to CFC-free 

inhalers, with the priority of protecting the health of patients. 

MTOC notes that some essential use nominations for 2012 include companies that are seeking 

small amounts of CFCs, in several cases in China less than 1 tonne. Parties may wish to 

consider the advantages of consolidating their MDI operations in enterprises that are 

sufficiently large to cope with the requirements of CFC-free inhaler production, and cease 

making nominations for manufacturers where there is no intention to continue MDI 

manufacture in an HFC form. MTOC will consider again next year any essential use 

nominations submitted to ensure that companies requesting CFCs are diligently undertaking 

research and development themselves or in collaboration with other companies. In the 

absence of demonstrated evidence of research and development activity, MTOC is unlikely to 

recommend the relevant portion of that nomination. 

Slow regulatory approval processes (which in China are reported to take up to 4 or more 

years) and slow funding procurement processes (for the Russian Federation) have been cited 

as reasons for delays in the introduction of CFC-free alternatives. Parties are strongly 

encouraged to fast-track administrative processes to speed up the transition to CFC-free 

alternatives to meet their obligations under the Montreal Protocol. 

One nomination (China) included significant CFC quantities to manufacture MDIs intended 

for export to other Article 5 countries. This nomination did not adequately demonstrate that 

these CFC MDIs were essential in the intended export markets or demonstrate that importing 

Parties had provided their prior informed consent for the import of the CFC MDIs in 2012. 

MTOC does not have the information from importing Parties to substantiate that these uses 

are essential, except for import of cromoglycate into Cuba where no CFC-free alternative is 

currently available for use in Cuba. However, MTOC considers that for all countries that 

import MDIs (except China, Pakistan, and Russia), there is now a complete range of 

affordable alternatives for salbutamol and beclomethasone. Consequently, MTOC is unable 

to recommend any of the CFC quantities nominated to manufacture MDIs for beta-agonists 

and inhaled corticosteroids for intended export markets. Parties may also wish to consider 

domestic regulations to ban the import or export of any beta-agonist and/or inhaled 

corticosteroid CFC MDI. 
TEAP May 2011 Progress Report 7

It is technically difficult to formulate anti-cholinergic drugs, such as ipratropium bromide and 

tiotropium bromide, as HFC MDIs. A limited range of CFC-free inhalers is currently 

available in this category. MTOC has recommended the nominated quantities for ipratropium 

and tiotropium and their combinations for Bangladesh and Pakistan for 2012. However, 

China’s own criteria in its transition strategy for anti-cholinergics (category D) appear to have 

been satisfied with more than one CFC-free alternative available. Consequently, MTOC 

considers that anti-cholinergics no longer meet the criteria for essential use in China where 

adequate affordable alternatives appear to be available. Furthermore, MTOC believes that 

adequate supplies of CFC-free inhalers containing anti-cholinergic drugs will become 

available worldwide in 2012 and it is unlikely that CFC inhalers for anti-cholinergics or their 

combinations will be considered essential in future years. 

A range of alternative HFC MDI (e.g. Intal and Cromal-5 HFC MDIs) and DPI formulations 

(e.g. Jing Wei’s sodium cromoglycate DPI or Intal Spincaps DPI) to sodium cromoglycate 

CFC MDI is available. Cuba has requested to import from China a small quantity of sodium 

cromoglycate CFC MDIs in 2012. MTOC is uncertain whether CFC-free alternatives are 

approved for use in Cuba. Consequently, MTOC has recommended the quantity of CFC for 

sodium cromoglycate CFC MDIs intended for export from China for 2012 only. One year 

will give time for Cuba to complete approvals for import of the globally available CFC-free 

alternatives. As soon as Cuba achieves the import of CFC-free alternatives, import of sodium 

cromoglycate CFC MDIs from China should be phased out. The criteria for China’s 

transition strategy appear to have been satisfied for sodium cromoglycate (category C) use 

within China, although further information is needed by MTOC to confirm its nonessentiality. MTOC requests additional information about CFC-free alternatives to sodium 

cromoglycate in China and the essentiality of the CFC MDI formulation. In future years, 

MTOC is likely to recommend that CFCs are not essential for sodium cromoglycate MDIs 

given the global availability of suitable CFC-free alternatives. 

For 2010 and 2011 nominations, MTOC considered the CFCs requested for combination 

products with anti-cholinergics to be essential for the nominations received from Article 5 

countries. MTOC considered this again and has recommended combination products with 

anti-cholinergics for 2012. However, due to the availability of CFC-free alternatives, 

combined with the widespread availability of affordable separate inhalers, MTOC has limited 

the CFC quantity to the same approved for 2011 and is unlikely to consider combination 

products with anti-cholinergics essential in future years. In the case of Bangladesh, MTOC 

was unable to recommend as essential the CFC quantities requested for the combination 

product with fluticasone/salmeterol due to the availability of CFC-free alternatives in 2012. 

MTOC has become aware of a new salbutamol CFC MDI product registered in Pakistan in 

2007 and launched in late 2010. MTOC also became aware of a new fluticasone/salmeterol 

CFC MDI that launched in Bangladesh during 2010. In China, it appears that four companies 

that have requested CFCs for 2012 had no CFC consumption in 2010, and three had CFC 

consumption only in 2011. In the past, MTOC has been unable to recommend as essential 

any new CFC MDIs not in the marketplace in 2009. A new product launched in 2010, when 

alternative CFC and CFC-free inhalers are already available, might not be considered 

essential under Decision IV/25. Parties may wish to consider domestic regulations to ban the 

launch or sale of new CFC MDI products in Article 5 countries, even if already approved but 

not launched. 

Of the Parties that provided accounting frameworks for 2010, there were stocks of 

pharmaceutical-grade CFCs of about 1,930 tonnes at the end of 2010. Sizeable or significant 

stocks were reported in China, India, and the United States. India also reported a small 

surplus of non-pharmaceutical grade CFCs resulting from the production of pharmaceuticalgrade CFCs. Small or negligible stocks were reported in Argentina, Pakistan and Russia. 
8 TEAP May 2011 Progress Report

Iran reported that it had completely depleted its stockpile. The European Union reported a 

small stockpile at the end of 2009. Further discussion on stockpiles and stockpile 

management is elaborated in the following sub-sections of section 3.2 and section 3.3. 

2.2 Essential Use Nominations for Metered Dose Inhalers 

2.2.1 Criteria for Review of Essential Use Nominations for MDIs 

Decision IV/25 of the 4th Meeting and subsequent Decisions V/18, VII/28, VIII/9, VIII/10, 

XII/2, XIV/5, XV/5, XVI/12, XVIII/16, XX/3, XXI/4 and XXII/4 have set the criteria and the 

process for the assessment of essential use nominations for MDIs for Parties not operating 

under paragraph 1 of Article 5 and Parties operating under paragraph 1 of Article 5 of the 

Protocol. Other essential use decisions relevant to these Parties are Decisions XVII/5, 

XVIII/7 and XIX/13. 

2.2.2 Review of Nominations 

The review of essential use nominations by the MTOC was conducted as follows. 

Three members of the MTOC independently reviewed each nomination, preparing an 

assessment. Further information was requested of nominating Parties where necessary. The 

MTOC considered the assessments, made recommendation decisions and prepared a 

consensus report at its meeting in Buenos Aires, Argentina, 20-22 March 2011. Members 

disclosed any potential conflict of interests ahead of the discussion. Where necessary, 

members were recused from the decision-making process of the nomination relevant to any 

potential conflict of interest. Annually listed disclosures of members indicate specific 

interests and any relevant actions taken such as recusal. 

Nominations were assessed according to the guidelines for essential use contained within the 

Handbook on Essential Use Nominations (TEAP, 2009) and subsequent Decisions of the 

Parties. Recommendations are made in accordance with Decision XV/5(3), which requests 

TEAP and its TOC to make recommendations on nominations for essential use exemptions 

for CFCs for MDIs with reference to the active ingredient of the metered-dose inhalers in 

which the CFCs will be used and the intended market for sale or distribution. 

Concurrent with the evaluation undertaken by the MTOC, copies of all nominations are 

provided to the Technology and Economic Assessment Panel (TEAP). The TEAP and its 

TOCs can consult with other individuals or organisations to assist in the review and to prepare 

TEAP recommendations for the Parties. 

2.2.3 Observations 

MTOC received 4 essential use nominations requesting a total of 877.34 tonnes of CFCs for 

the manufacture of metered dose inhalers (MDIs) in 2012, and 125 tonnes for 2013: 3 

nominations were from Article 5 countries (Bangladesh, China, Pakistan); and 1 was from a 

non-Article 5 country (Russian Federation). MTOC recommendations are for a total of 

792.81 tonnes of CFCs for the manufacture of MDIs in 2012. 

In 2009, the first year of the essential use process for Article 5 countries, MTOC reviewed 

nominations from eight Article 5 countries. It is very encouraging to note that two years on, 

Argentina, Egypt, Iran, India and Syria did not nominate for essential uses of CFCs for MDIs 

for 2012. There have been significant reductions from about 2,400 tonnes of authorised 

essential use CFCs in 2010 to about 880 tonnes of CFCs nominated for 2012. Furthermore, 

this is the last year of nomination for Bangladesh. All of these Parties are to be commended 

for their efforts to successfully phase-out CFCs. 
TEAP May 2011 Progress Report 9

Looking to the future, two major areas of concern remain. The first is Russia; a non-Article 5 

country where there have been repeated assurances that phase-out would have been 

completed by 2008. The use of CFCs in domestically produced MDIs is now projected to be 

required until 2013, despite the availability of affordable imported products from a number of 

manufacturers. The second is China, now the largest consumer of CFCs in medical products, 

where consumption of greater than 500 tonnes per annum looks likely to continue until at 

least 2014, with total phase-out planned for 2016. 

There has been substantial progress in the development and registration of affordable CFCfree MDIs, especially those manufactured by Article 5 countries. With economies of scale, 

and a range of different brands from local manufacturers, HFC MDIs have become more 

competitively priced compared to CFC MDIs. Despite this, some Parties that locally produce 

CFC MDIs are asking for more time for their pharmaceutical companies to complete the 

transition. Some of these Parties are clearly lagging in their transition process, but they still 

request special treatment for their industries. The main reasons for these requests are the 

claims that: 

• Locally made CFC MDIs are much cheaper than ozone-friendly imported products. 

• Research and development and regulatory approval processes take time and 

significant resources. 

• Production of medication to treat asthma/COPD is a sovereignty issue. 

2.2.4 Affordability of CFC-free Inhalers 

MTOC accepts the need to protect the patients with limited economic means. With the 

production of a wide range of generic CFC-free inhalers at very low cost in Bangladesh, India 

and other Article 5 countries the argument of affordability is no longer valid. 

MTOC has previously reported that price differences between locally made and imported 

products can be a result of external variables such as: 

• Trade barriers, including higher tariffs, difficult registration procedures, restrictions to 

market penetration, and government procurement and reimbursement policies; 

• Local circumstances such as geographical location; 

• Local policies such as pricing of a raw material. 

In other cases, national policies like sales price control of the CFC inhalers may prevent the 

local manufacturer from receiving the revenues required to develop the new CFC free 

technology. 

The conditions mentioned above, even if they exist, do not justify the continued use of CFC 

MDIs. Furthermore, the continued production of CFC inhalers is counter-productive for the 

global phase-out of CFC MDIs for the following reasons: 

• Creates the false impression that CFC phase-out may not actually occur and 

discourages change in the Parties where they are still produced. 

• Allows for the continued export of CFC MDIs to other Parties, delaying their 

transition as well. 

• Allows the continued production of medical grade CFCs, and, as a consequence of 

the manufacturing process, also allows production of CFCs that are not medical grade 

at the beginning and end of each manufacturing run. There are no uses authorised for 
10 TEAP May 2011 Progress Report

this material. Furthermore, there is a risk that these non-medical grade materials may 

not be disposed of properly. 

• Allows some companies to defer research and development activities to facilitate 

transition, which is a disincentive for those companies that have already transitioned, 

in some cases entirely at their own expense. 

Pricing policies, tariffs, import taxes and restrictions have been implemented, which have the 

effect of protecting local industry, favouring locally made CFC MDIs, and discouraging the 

use of affordable imported CFC-free alternatives. Parties may wish to consider domestic 

policies (pricing, import and drug approvals) that will expedite the rapid transition to CFCfree inhalers, with the priority of protecting the health of patients. 

2.2.5 Company Size and Product Demand 

The definition of essentiality for purposes of the Montreal Protocol is based in part on the 

idea that production and consumption of CFCs for essential uses is necessary for the 

functioning of society. 

In those countries where the Multilateral Fund (MLF) is funding phase-out projects for 

different companies, it is likely that conditions for non-essentiality could be met before all the 

projects have been completed. Therefore essentiality should not be linked to the completion 

of all phase-out projects but rather to the satisfaction of essential use criteria. 

MTOC notes that some essential use nominations for 2012 include companies that are seeking 

small amounts of CFCs, in several cases in China1

 less than 1 tonne. These small volume 

consumptions will result in the production of around 50,000 MDI inhalers per year in each 

case. It is likely that these small volume operations will have high operating costs, higher 

losses of material, and few resources for research and development. It is technically and 

economically difficult for low volume consuming companies to undertake the necessary 

research and development, especially clinical trials, and investment in new production lines. 

It is especially challenging to convert low volume products where the investment of funds and 

technical expertise may not be available or justified. 

The manufacture of DPIs and MDIs requires exacting quality control to assure that patients 

will receive always the proper dose in particles of the right size. Production of CFC-free 

MDIs is even more demanding than the production of CFC MDIs; the difficulties that delayed 

the initial introduction of HFC MDIs were the result of different physical properties, 

compatibility and stability issues, and the need for costly trials. It is possible that small 

companies with consumptions of a few tonnes of propellant will not have the resources to 

produce CFC-free MDIs competitively. 

In China, rationalisation of production to fewer companies and fewer products is likely to 

occur. Nonetheless, these companies continue to request CFCs, and China continues to 

nominate CFCs for these companies. The criteria for including CFC quantities within a 

nomination require nominating Parties to exclude companies that are not diligently 

undertaking research and development. China has indicated that it expects some of the 

companies currently included in its nomination to cease MDI production. Future nominations 

should not include some of these small factories if they never intend to reformulate their CFC 

MDIs. 

 

1 In China, out of 21 domestic CFC MDI manufacturers, 13 have requested less than 10 tonnes for 2012. Another 

7 have requested between 10-80 tonnes, and one company has requested 280 tonnes. 
TEAP May 2011 Progress Report 11

Some companies have been successful in transition, even without MLF-funding of conversion 

projects. Market leaders in HFC MDIs should not be penalised for fast transition by 

competing against lower priced CFC MDIs in the same markets. These circumstances also 

arose in non-Article 5 countries, and this was an important factor in delaying salbutamol CFC 

MDI transition. 

There is the risk that those remaining Parties still nominating essential uses of CFCs, where 

there are companies with big differences in size, might try to adjust the pace of the transition 

to that of the smaller enterprises. Such an adjustment would be at the expense of the larger 

factories that have more resources. The Montreal Protocol has considered the plight of SMEs 

in many sectors that have used ODPs, but despite attempts to help CFC users regardless of 

size, the phase-out of CFCs has generally resulted in the adoption of the newer technologies 

by companies that are the stronger and the more technologically skilled of their sector. 

Parties may wish to consider the advantages of consolidating their MDI operations in 

enterprises that are sufficiently large to cope with the requirements of CFC-free inhaler 

production, and cease making nominations for manufacturers where there is no intention to 

continue MDI manufacture in an HFC form. 

Furthermore, the concept of therapeutic equivalence (such as within the group of inhaled 

corticosteroids where one corticosteroid has similar therapeutic benefits to another) implies 

that not all moieties that were formulated as CFC MDIs need to be reformulated as HFC 

MDIs to complete the CFC phase-out. The experience with phase-out shows that in some 

cases, reformulation may not be commercially viable or technically possible, while in other 

cases, it was possible to reformulate a moiety as a DPI, but not as an MDI. 

There are a number of decisions by Parties relating to active research and development by 

companies seeking production of essential use CFCs to manufacture MDIs. 

Decision VIII/10 states: 

“That Parties will request companies applying for MDI essential-use exemptions to 

demonstrate ongoing research and development of alternatives to CFC MDIs with all due 

diligence and/or collaborate with other companies in such efforts and, with each future 

request, to report in confidence to the nominating Party whether and to what extent resources 

are deployed to this end and progress is being made on such research and development, and 

what licence applications if any have been submitted to health authorities for non-CFC 

alternatives;” 

Decisions XVIII/7 (and subsequent modifications made by Decision XX/3) supplements 

Decision VIII/10 and the requirements for Parties nominating essential-uses by specifying: 

“That Parties will request companies applying for metered-dose inhaler essential use 

exemptions to demonstrate that they are making efforts, with all due diligence, on research 

and development with respect to chlorofluorocarbon-free alternatives to their products and 

are diligently seeking approval of their chlorofluorocarbon-free alternatives in their domestic 

and export markets aimed at transitioning those markets away from the chlorofluorocarbon 

products;” 

Decision XIX/13, which further supplements Decision XVIII/7, specifies: 

“That Parties will request each company, consistent with paragraph 1 of decision VIII/10, to 

notify the relevant authority, for each metered-dose inhaler product for which the production 

of CFCs is requested, of: 
12 TEAP May 2011 Progress Report

(a) The company’s commitment to the reformulation of the concerned products; 

(b) The timetable in which each reformulation process may be completed; 

(c) Evidence that the company is diligently seeking approval of any chlorofluorocarbon-free 

alternative(s) in its domestic and export markets and transitioning those markets away from 

its chlorofluorocarbon products;” 

MTOC will consider again next year any essential use nominations submitted to ensure that 

companies requesting CFCs are diligently undertaking research and development themselves 

or in collaboration with other companies. In the absence of demonstrated evidence of 

research and development activity, MTOC is unlikely to recommend the relevant portion of 

that nomination. 

2.2.7 Slow Processes are Delaying Transition 

Different countries have different regulatory approaches to the approval of CFC-free inhalers, 

resulting in more rapid transition in some countries than in others. Slow regulatory approval 

processes (which in China are reported to take up to 4 or more years) and slow funding 

procurement processes (for the Russian Federation) have been cited as reasons for delays in 

the introduction of CFC-free alternatives. These processes, which are within the control of 

individual Parties and implementing agencies associated with the Montreal Protocol, appear 

to be frustrating the transition and stifling companies that have the technology to transition. 

China has explained that its Drug Registration Management Regulation requires that any 

company that would like to submit a registration application for HFC MDIs should follow the 

requirements for a new drug (or a dosage form). Therefore, the process of registering a new 

HFC MDI product is expected to proceed as follows: 

1. After completing pre-clinical studies (including pharmaceutical, pharmacology and 

safety) for HFC MDIs, the company can submit its application for clinical trial. 

2. The Department of Drug registration of SFDA reviews the application dossier and 

issues a clinical trial licence to the applicants meeting all requirements. 

3. MDI manufacturers conduct clinical trials and submit clinical reports and summaries 

to SFDA. 

4. After reviewing the clinical dossier, a manufacturing licence will be issued to the 

company meeting all requirements. 

According to the “standard time” required for drug registration in the regulations, China 

states that it will take at least 3 to 4 years for manufacturers to finish all the steps of drug 

registration and then launch their products, even if the research and development process goes 

smoothly and the submitted dossiers meet requirements. China explains this is why two 

salbutamol HFC MDIs submitted for registration in 2010 will not get to market in China until 

2014. This period has already been calculated under the premise of a “fast track” registration 

process. SFDA is now establishing how to implement “fast track” approval for HFC MDIs. 

In China, two domestic enterprises have salbutamol HFC MDIs currently in the registration 

process. One of these is the largest MDI producer in China, Jing Wei, which has completed 

some clinical trials and has production capacity of 36 million cans, more than China’s current 

MDI use. Faster regulatory approval than currently proposed could mean that Jing Wei 

salbutamol HFC MDIs are on the market sooner. MTOC understands that Jing Wei plans to 

market the first salbutamol HFC MDI product by 2012, so that at least one locally made 

salbutamol HFC MDI could be marketed in China within about the next 12 months. MTOC 
TEAP May 2011 Progress Report 13

is also aware that Jing Wei already manufactures under contract and exports salbutamol and 

beclomethasone HFC MDIs at British Pharmaceutical standards. 

Parties are strongly encouraged to fast-track administrative processes to speed up the 

transition to CFC-free alternatives to meet their obligations under the Montreal Protocol. 

2.2.8 Exported Products 

MTOC has noted the wide availability in Article 5 countries of technically suitable 

alternatives to CFC MDIs. However, availability by itself has not prompted transition largely 

due to lack of affordability of these alternatives. CFC-free inhaler products sourced from 

manufacturers in Article 5 countries are now substantially increasing the range of affordable 

alternatives. 

One nomination (China) included significant CFC quantities to manufacture MDIs intended 

for export to other Article 5 countries. This nomination did not adequately demonstrate that 

these CFC MDIs were essential in the intended export markets or demonstrate that importing 

Parties had provided their prior informed consent for the import of the CFC MDIs in 2012. 

MTOC does not have the information from importing Parties to substantiate that these uses 

are essential, except for import of cromoglycate into Cuba where no CFC-free alternative is 

currently available for use in Cuba. MTOC is also aware that one company, Jing Wei, 

already manufactures under contract and exports salbutamol and beclomethasone HFC MDIs 

at British Pharmaceutical standards. It is not clear whether importing Parties are specifically 

requesting the import of CFC MDIs despite the alternatives available, whether they simply 

import the cheapest available product even if it contains CFCs, or whether they are unable to 

switch to alternatives because of a lack of regulatory approval of the alternatives. There is an 

opportunity for importing Parties to help drive the global phase-out of CFCs through 

judicious sourcing of CFC-free alternatives and actively declaring non-essentiality. 

MTOC considers that in most developing countries there is an adequate range of technically 

satisfactory and affordable CFC-free alternatives for beta-agonist (in particular, salbutamol) 

and inhaled corticosteroid (in particular, beclomethasone) CFC MDIs. Furthermore, MTOC 

considers that for all countries that import MDIs (except China, Pakistan, and Russia), there is 

now a complete range of affordable alternatives for salbutamol and beclomethasone. 

Consequently, MTOC is unable to recommend any of the CFC quantities nominated to 

manufacture MDIs for beta-agonists and inhaled corticosteroids for intended export markets. 

There are some Parties where beta-agonist and/or inhaled corticosteroid CFC MDIs may still 

be needed for use in their own countries in 2012: China, Pakistan and the Russian Federation. 

CFCs for MDIs in these therapeutic categories are recommended for these markets for 2012 

while the conversion to CFC-free alternatives is underway and HFC MDI capacity is 

increasing. However, these Parties should also consider importing the wide range of 

affordable alternatives that are available now. 

MTOC was not provided evidence that salbutamol and/or beclomethasone CFC MDIs are 

essential in any importing countries in 2012. However, any importing Parties with difficulty 

in sourcing affordable CFC-free inhalers could potentially access them through the Asthma 

Drug Facility (an independent non-profit organisation managed by the International Union 

against Tuberculosis and Lung Disease www.globaladf.org). Parties may also wish to 

consider domestic regulations to ban the export and import of any beta-agonist and/or inhaled 

corticosteroid CFC MDI. 
14 TEAP May 2011 Progress Report

2.2.9 Anti-cholinergics 

It is technically difficult to formulate anti-cholinergic drugs, such as ipratropium bromide and 

tiotropium bromide, as HFC MDIs. A limited range of CFC-free inhalers is currently 

available in this category. New CFC-free inhalers (DPIs and HFC MDIs manufactured in 

both non-Article 5 and Article 5 countries) for tiotropium and ipratropium (and combinations 

with other moieties) are beginning to become available. However, in the case of Bangladesh 

and Pakistan, MTOC remains uncertain that there is an adequate range of affordable CFC-free 

alternatives to consider the CFC MDIs for these drugs to be non-essential. However, in 

Bangladesh there is a unit dose DPI formulation of tiotropium. MTOC has recommended the 

nominated quantities for ipratropium and tiotropium and their combinations for Bangladesh 

and Pakistan for 2012. 

However, China’s own criteria in its transition strategy for anti-cholinergics (category D) 

appear to have been satisfied with more than one CFC-free alternative available. 

Consequently, MTOC considers that anti-cholinergics no longer meet the criteria for essential 

use in China where adequate affordable alternatives appear to be available. 

MTOC believes that adequate supplies of CFC-free inhalers containing anti-cholinergic drugs 

will become available worldwide in 2012 and it is unlikely that CFC inhalers for anticholinergics or their combinations will be considered essential in future years. 

2.2.10 Sodium Cromoglycate 

A range of alternative HFC MDI (e.g. Intal and Cromal-5 HFC MDIs) and DPI formulations 

(e.g. Jing Wei’s sodium cromoglycate DPI or Intal Spincaps DPI) to sodium cromoglycate 

CFC MDI is available. Furthermore, many countries no longer use sodium cromoglycate 

MDI due to the availability of more effective drug therapies and the technical difficulty in 

reformulation of the CFC MDI. 

Cuba has requested to import from China a small quantity of sodium cromoglycate CFC 

MDIs in 2012. MTOC is uncertain whether CFC-free alternatives are approved for use in 

Cuba. Consequently, MTOC has recommended the quantity of CFC for sodium 

cromoglycate CFC MDIs intended for export from China for 2012 only. One year will give 

time for Cuba to complete approvals for import of the globally available CFC-free 

alternatives. As soon as Cuba achieves the import of CFC-free alternatives, import of sodium 

cromoglycate CFC MDIs from China should be phased out. 

The criteria for China’s transition strategy appear to have been satisfied for sodium 

cromoglycate (category C) use within China, although further information is needed by 

MTOC to confirm its non-essentiality. MTOC requests additional information about CFCfree alternatives to sodium cromoglycate in China and the essentiality of the CFC MDI 

formulation. 

In future years, MTOC is likely to recommend that CFCs are not essential for sodium 

cromoglycate MDIs given the global availability of suitable CFC-free alternatives. 

2.2.11 Combination Products 

There are increasing numbers of combination products becoming available in Article 5 

country markets. In previous years, MTOC had indicated that it does not consider 

combination products to be essential where there are the same active ingredients available in 

the separate CFC-free inhalers. However, subsequently, evidence suggested that the 

combination of active ingredients in a single inhaler is beneficial, with improved compliance 

and clinical benefit, sometimes combined with a decrease in cost for patients compared to the 
TEAP May 2011 Progress Report 15

drugs delivered in separate inhalers. As a result of this evidence, for 2010 and 2011 

nominations, MTOC considered the CFCs requested for combination products with anticholinergics to be essential for the nominations received from Article 5 countries. MTOC 

considered this again and has recommended combination products with anti-cholinergics for 

2012. However, due to the availability of CFC-free alternatives, combined with the 

widespread availability of affordable separate inhalers, MTOC has limited the CFC quantity 

to the same approved for 2011 and is unlikely to consider combination products with anticholinergics essential in future years. 

In the case of Bangladesh, MTOC was unable to recommend as essential the CFC quantities 

requested for the combination product with fluticasone/salmeterol due to the availability of 

CFC-free alternatives in 2012. 

2.2.12 New CFC MDI Products being Launched after 2010 

MTOC has become aware of a new salbutamol CFC MDI product registered in Pakistan in 

2007 and launched in late 2010. In the past, MTOC has been unable to recommend as 

essential any new CFC MDIs not in the marketplace in 2009. A new product launched in 

2010, when alternative CFC and CFC-free inhalers are already available, might not be 

considered essential under Decision IV/25. Nonetheless, without knowledge of the situation 

of this new product in Pakistan, MTOC has already considered and recommended CFC 

quantities for this product in nominations for 2010 and 2011 and Parties have already 

authorised these quantities based on patient needs. Given the commitment made by Pakistan 

to phase-out CFC MDIs by the end of 2012, MTOC recommends these CFC quantities for 

2012. 

MTOC also became aware of a new fluticasone/salmeterol CFC MDI that launched in 

Bangladesh during 2010, although no CFC quantities were requested for this product for 

2012. 

In China, it appears that four companies that have requested CFCs for 2012 had no CFC 

consumption in 2010, and three had CFC consumption only in 2011. This anomalous pattern 

suggests new CFC MDI product launches or new manufacturing enterprises entering the 

market after 2010. 

Parties may wish to consider domestic regulations to ban the launch or sale of new CFC MDI 

products in Article 5 countries, even if already approved but not launched. 

2.2.13 Stockpiles 

Of the Parties that provided accounting frameworks for 2010, there were stocks of 

pharmaceutical-grade CFCs of about 1,930 tonnes at the end of 2010. Sizeable or significant 

stocks were reported in China, India, and the United States. India also reported a small 

surplus of non-pharmaceutical grade CFCs resulting from the production of pharmaceuticalgrade CFCs. Small or negligible stocks were reported in Argentina, Pakistan and Russia. 

Iran reported that it had completely depleted its stockpile. The European Union (EU) 

reported a small stockpile at the end of 2009. Further discussion on stockpiles and stockpile 

management is elaborated in the following sub-sections of section 2.2, in section 3.3 and 3.4. 

2.2.14 Bangladesh 

Year Quantity nominated 

2012 40.35 tonnes 
16 TEAP May 2011 Progress Report

Specific Use: MDIs for asthma and COPD 

Nominated quantities, active ingredients and intended markets for which the 

nomination applies: 

Active Ingredient Intended market Quantity (Tonnes)

Ciclesonide Bangladesh 0.48 

Fluticasone/Salmeterol Bangladesh 9.59 

Ipratropium Bangladesh 1.14 

Ipratropium/ Salbutamol Bangladesh 27.41 

Salmeterol Bangladesh 1.10 

Tiotropium Bangladesh 0.63 

Total 40.35 

Recommendation: 

Recommend 24.67 tonnes of CFCs for MDIs for use in Bangladesh for active 

ingredients ciclesonide, ipratropium, ipratropium/salbutamol, salmeterol and 

tiotropium. 

Unable to recommend CFCs for MDIs for active ingredients 

fluticasone/salmeterol. 

Comments 

Bangladesh developed an initial National Transition Strategy in 1995. CFC-free 

MDIs have been introduced starting in late 2006 and it appears their adoption has 

continued to grow. Currently, three companies manufacture HFC MDIs while 

two companies manufacture DPI inhalers. In general, the pricing of these 

alternatives is comparable to their CFC counterparts and this fact should help 

with continued transition. 

In the 2010 update to its Transition Strategy, Bangladesh stated that it would 

phase out CFC use completely by 2012, four years earlier than was originally 

proposed in the 2009 nomination. This development has been aided by the MLFfunded plant conversion projects. Good progress has resulted in the availability 

of multiple HFC products for salbutamol and beclomethasone, together with new 

CFC-free products for other moieties. Bangladesh has stated that the current 

nomination for 2012 will be its final nomination for essential uses of CFCs in 

MDIs. Bangladesh is commended for its proactive and diligent pursuit of 

transition from CFC MDI products. 

For 2012, Bangladesh has nominated a total of 40.35 tonnes of CFC for use in 

MDIs. The nominated CFCs are for the manufacture of MDIs for domestic 

consumption only, as Bangladesh does not export CFC MDIs. Transition is 

actively underway. Accordingly, there is no CFC nomination for manufacture of 

either salbutamol or beclomethasone MDIs for 2012. 

Of the 156.7 tonnes of CFCs authorised for essential uses in Bangladesh in 2010, 

only 48.0 tonnes were acquired and 44.6 tonnes used, in part due to transition 
TEAP May 2011 Progress Report 17

making faster progress than had been anticipated. With an initial stockpile of 4.5 

tonnes, this resulted in 7.8 tonnes of CFCs on hand at the end of 2010. MTOC 

recommended 38.7 tonnes and Parties authorised 57 tonnes CFCs for essential 

uses for 2011. Given that the 2011 authorised allowance exceeds the 2010 

consumption by 13 tonnes, that transition is proceeding for other moieties, and 

that there are 8 tonnes of stock in hand, it would appear there is more than enough 

CFCs available for essential uses in 2011. Furthermore, the nomination for 2012 

is only 4 tonnes less than consumption in 2010 despite expected transition to 

CFC-free MDIs for salbutamol and beclomethasone by 2012. 

The continued manufacture of CFC MDIs beyond 2010, where multiple HFC or 

DPI alternatives already exist, competes with the CFC-free alternatives and slows 

the transition. MTOC learned that a salmeterol/fluticasone CFC MDI product 

was launched in 2010, although no CFC quantities were requested for this 

product for 2012. 

There are multiple non-CFC alternatives on the market in Bangladesh for 

budesonide and salmeterol/fluticasone, and single sources of manufacture of 

salbutamol/ipratropium and salmeterol. There are as yet no CFC-free alternatives 

for ipratropium (expected later in 2011) and ciclesonide, although there is a unit 

dose DPI formulation of tiotropium. Most of the CFC-free products are 

manufactured locally. Consequently, MTOC is unable to recommend the 

nominated CFC quantity for salmeterol/fluticasone because there are HFC MDI 

products available from two manufacturers and DPI products available from 3 

manufacturers. 

HFC MDIs for the manufacture of ipratropium/salbutamol MDIs from one 

manufacturer have now been on the market for over 12 months without 

significant issues. However, the quantity of CFCs requested for this combination 

product by the remaining two manufacturers is 6 tonnes greater for 2012 (27.41 

tonnes) than 2011 (21.32 tonnes). Any increase in patients’ need can be met from 

the available HFC MDIs, at a price that is only 10 percent higher than the 

available CFC MDIs. Therefore MTOC recommends only 21.32 tonnes CFCs 

for salbutamol/ipratropium, the same quantity as nominated in 2011 by the 

remaining two manufacturers for these CFC MDI products. 

It is very important that Bangladesh continues efforts to educate patients, 

pharmacists and prescribers on what to expect as transition completes. This will 

help to ensure that demand for CFC MDIs diminish to a point where it is no 

longer economically feasible to manufacture and sell them. 

In conclusion, MTOC recommends the following quantities for essential use in 

2012: 
18 TEAP May 2011 Progress Report

Recommended quantities in accordance with Decision XV/5(3): 

Active Ingredient Intended market Quantity (Tonnes)

Ciclesonide Bangladesh 0.48 

Fluticasone/Salmeterol Bangladesh 0.0 

Ipratropium Bangladesh 1.14 

Ipratropium/Salbutamol Bangladesh 21.32 

Salmeterol Bangladesh 1.10 

Tiotropium Bangladesh 0.63 

Total 24.67 

2.2.15 People's Republic of China 

Year Quantity nominated 

2012 562.89 tonnes 

Specific Use: MDIs for asthma and COPD, and acute pulmonary oedema. 

Nominated quantities, active ingredients and intended markets for which the 

nomination applies: 

Active Ingredients China Export Total 

Beclomethasone 54.77 *5.75 60.52 

Beclomethasone/clenbuterol/ipratropium 0.7 0 0.7 

Budesonide 11.16 0 11.16 

Cromoglycate 6.58 **3.90 10.48 

Datura metel extract/clenbuterol 2.0 0 2.0 

Dimethicone 0.20 0 0.20 

Ephedra, ginkgo, sophora flavescens, radix 

scutellariae 

7.00 0 7.00 

Ipratropium 8.50 0 8.50 

Ipratropium /salbutamol 0.74 0 0.74 

Isoprenaline 45.88 0 45.88 

Isoprenaline/guaifenesin 3.96 0 3.96 

Procaterol 1.45 0 1.45 

Salbutamol 393.68 ***16.60 410.28 

Salmeterol 0.02 0 0.02 

Total 536.64 26.25 562.89 

* Intended markets Burma, Cambodia, Nigeria, Sudan, Turkmenistan. 

** Intended market Cuba. 

*** Intended markets Burma, Cambodia, Chile, Ethiopia, Kenya, Mali, Mozambique, Nigeria, 

Peru, Sierra Leone, Sudan, Turkmenistan. 
TEAP May 2011 Progress Report 19

Recommendation: 

Recommend 532.04 tonnes CFCs for MDIs intended for China for the active 

ingredients beclomethasone, beclomethasone/clenbuterol/ipratropium, 

budesonide, cromoglycate, datura metel extract/clenbuterol, dimethicone; 

ephedra, gingko, sophora flavescens and radix scutellariae; 

ipratropium/salbutamol, isoprenaline, isoprenaline/guaifenesin, procaterol, 

salbutamol, salmeterol, and intended for export to Cuba for the active ingredient 

cromoglycate. 

Unable to recommend CFCs for MDIs intended for China for the active 

ingredient ipratropium. 

Unable to recommend CFCs for MDIs intended for export to Burma, Cambodia, 

Chile, Ethiopia, Kenya, Mali, Mozambique, Nigeria, Peru, Sierra Leone, Sudan, 

Turkmenistan for the active ingredients beclomethasone and salbutamol. 

Comments 

China has made a detailed nomination using the 2005 (rather than the 2009) 

Handbook on Essential Use Nominations2

. The nomination is for 553.69 tonnes 

of CFCs for MDIs for asthma and COPD, and 200 kg and 9 tonnes, respectively, 

for dimethicone to treat pulmonary oedema and for Chinese traditional medicines. 

Asthma and COPD

The nomination elaborates that there are 20 million patients with asthma and 50 

million patients with COPD in China. The nomination is for an identical range of 

active ingredients compared to 2010, except that the nomination for ciclesonide 

has been withdrawn. The nominated volume is for a total of 562.89 tonnes of 

CFCs. Of this, 536.64 tonnes is for domestic use in China, and 26.25 tonnes is 

for export of CFC MDIs. The volume of CFCs requested for 2012 is more than a 

threefold increase compared with estimated consumption in 2004. However, 

requested CFC quantities appear to have peaked in 2011 (809.91 tonnes). The 

2012 nomination is markedly lower (562.89 tonnes), due to a lower request both 

for export markets and for domestic consumption. This appears at odds with the 

stated increase in treatment rate claimed by China in the nomination. 

In 2010, the total amount of domestically produced inhalers (MDIs and DPIs) 

was about 24 million inhalers, mainly containing salbutamol. In comparison, the 

amount of imported inhalers (MDIs and DPIs) was 10.3 million. These imported 

inhalers accounted for 30 percent of total consumption. The imported inhalers 

included 6.3 million HFC MDI inhalers, of which GSK’s VentolinTM was about 5 

million inhalers. In addition, imported DPIs amounted to 4 million inhalers, of 

which the GSK salmeterol/fluticasone combination comprised 2.8 million 

inhalers, with the remainder split equally among tiotropium, budesonide and 

formoterol/budesonide combination. 

The China nomination identifies 21 domestic CFC MDI manufacturers. Of these, 

one (Jing Wei) has requested about half the total requested CFC quantity for 

China, eight have requested between 10-80 tonnes, and the remaining twelve 

 

2

 http://ozone.unep.org/Assessment_Panels/TEAP/Reports/TEAP_Reports/EUN-Handbook2009.pdf 
20 TEAP May 2011 Progress Report

have requested less than 10 tonnes each. It is unlikely that the large number of 

small to medium sized manufacturers of MDIs in China will be carrying out 

active research and development of CFC-free inhalers. In addition, China has 

indicated itself that the transition of many manufacturers to CFC-free inhalers is 

not likely to be economically viable. The nomination also suggests that four 

companies may begin manufacture of CFC MDIs for the first time in 2011 or 

2012. However, China has indicated that no product included in the nomination 

was approved after December 31, 2008, according to Decision XII/2 (2 bis.). 

MTOC questions whether small to medium sized enterprises (SMEs) that are 

unlikely to make the transition to CFC-free inhalers should be authorized 

essential use CFCs. CFC use by these companies may simply continue 

unnecessarily for years until other manufacturers with greater manufacturing and 

research capacity successfully complete transition. With adequate notice, larger 

manufacturers could build market and distribution networks to areas that SMEs 

currently supply. In future years, MTOC will need much greater justification of 

whether the requests for CFCs from these numerous low-volume consuming 

SMEs meet the essential use criteria along with clear, demonstrated evidence of 

on-going active research and development in order to recommend CFC quantities. 

MTOC understands that Jing Wei have four manufacturing lines with a total 

installed capacity to produce 36 million inhalers per year, more than China’s 

current MDI use. Jing Wei has manufacturing lines capable of producing both 

salbutamol CFC and HFC MDIs. MTOC is also aware that Jing Wei already 

manufactures under contract and exports salbutamol and beclomethasone HFC 

MDIs at British Pharmaceutical standards. 

China has a transition strategy based on drug categories, with a plan of action for 

phase-out of salbutamol that has been submitted to the Ozone Secretariat. The 

nomination states there will be a complete phase-out of CFC MDIs by December 

31, 2016, and that China will cease making nominations by December 31, 2015. 

China states that the salbutamol CFC MDI phase-out will be completed by 

December 31, 2015, but that CFC and HFC MDIs should co-exist during a 

transition period of one year. The nomination states that some patients “may not 

adopt CFC-free MDIs” and “a small amount of CFC exemption use may still be 

required” after December 31, 2016. For other drug categories, the nomination 

states that there will be a similar one-year transition period when both CFC and 

CFC-free MDIs should co-exist, also ending on December 31, 2016. 

China has stated that salbutamol CFC MDIs will remain essential until four 

different CFC-free MDIs from four different domestic enterprises are available in 

an adequate range of doses. MTOC has considered these criteria carefully: 

• Regulatory approval – The nomination states that, as yet, no suitable 

CFC-free MDIs are available in China from domestic manufacturers. 

Two applications for salbutamol HFC MDIs have been submitted for 

registration to the SFDA in 2010 and are anticipated to be on the market 

in 2014. China has explained that its registration process may take up to 

4 years. Due to this long regulatory period, MTOC is concerned that 

only two domestic manufacturers of salbutamol may be able to achieve 

transition by the specified phase-out date. Thus China may not be able to 

achieve its own criteria for phase-out of salbutamol CFC MDIs, requiring 

four separate domestic enterprises. 
TEAP May 2011 Progress Report 21

• Research and development – Research and development is progressing 

for 2 salbutamol HFC formulations by 2 separate companies. However, 

it is highly unlikely that all of the remaining 19 MDI manufacturers are 

conducting active research and development on reformulation. 

• Affordability – The Chinese Essential Drugs Lists (NEDL and EDL) 

determine the maximum price of salbutamol MDIs in China. An EDL, 

published in August 2009 as a cross-Ministry agreement, gives more 

people access to basic medicines at reduced prices (by 28-60 percent). 

MTOC understands that the price cap for the only imported salbutamol 

HFC MDI is comparable to that for CFC MDIs. Domestic products are 

marketed at lower prices than imported products, but the price gap has 

narrowed. Nevertheless, sales of the imported salbutamol HFC MDI (21 

percent of all inhalers) have been accelerating since its inclusion under 

the EDL. 

• Dry powder inhalers – A number of imported DPIs are currently 

available in China. In addition, the nomination indicates that there is a 

small supply of domestically produced salbutamol DPIs. Neither a list of 

domestic manufacturers nor production volumes are specified. The 

nomination also indicates the availability of domestically produced 

beclomethasone DPIs, but no manufacturer details or production volumes 

are provided. The nomination states that domestic manufacturers are 

undertaking research and development on DPI formulations for 

procaterol, salmeterol and tiotropium. 

Patients with asthma and COPD require a range of affordable salbutamol CFCfree inhalers for safe phase-out of CFC MDIs. China has proposed that four 

domestically produced salbutamol HFC MDIs should be available prior to phaseout. To reach the total of four enterprises with salbutamol HFC MDIs for phaseout of salbutamol CFC MDIs may take a further five years (4 years for regulatory 

approval and one year of co-marketing). As of March 2011, there are only two 

enterprises that have submitted regulatory packages to the SFDA. The phase-out 

criteria for salbutamol CFC MDIs may not be achievable by China’s own phaseout date of December 31, 2015. 

While the current status of product registration applications from domestic 

manufacturers is unclear, MTOC believes that a range of affordable salbutamol 

CFC-free inhalers may be available sooner, through a combination of domestic 

manufacturing and affordable imports. MTOC believes that China’s transition 

strategy criteria for salbutamol CFC MDI phase-out need not be limited to 4 

domestic producers. Instead, the criteria should simply be for 4 affordable 

inhalers from any source (including imports). DPIs could also provide a suitable 

alternative for many patients. 

In China, two domestic enterprises have salbutamol HFC MDIs currently in the 

registration process. One of these is the largest MDI producer in China, Jing 

Wei, which has completed some clinical trials and has production capacity of 36 

million cans, more than China’s current MDI use. Faster regulatory approval 

than currently proposed could mean that Jing Wei salbutamol HFC MDIs are on 

the market sooner. At MTOC’s 2010 meeting, Jing Wei and another company 

Nuokang indicated that they might be able to phase out salbutamol CFC MDIs 

earlier than scheduled in China’s national strategy provided there was a 

favourable fast-track regulatory approval process. MTOC understands that Jing 

Wei plans to market the first salbutamol HFC MDI product by 2012, so that at 
22 TEAP May 2011 Progress Report

least one locally made salbutamol HFC MDI could be marketed in China within 

about the next 12 months. In addition, one imported salbutamol HFC MDI 

already has significant market share (about 20 percent) and its price is capped at 

the same maximum price as domestic salbutamol CFC MDIs. DPIs may be 

available and could provide a suitable alternative for patients3

. MTOC believes 

that these developments (two domestic and one imported salbutamol HFC MDI, 

and possible DPI alternatives) would provide an adequate range of affordable 

alternatives for early and safe phase-out of salbutamol CFC MDIs in China. 

In addition to salbutamol, China has requested CFCs for MDIs in 2012 for 

another nine moieties for asthma and COPD (excluding Traditional Chinese 

Medicines that are addressed further below). These include CFCs for MDIs 

containing inhaled corticosteroids (beclomethasone and budesonide; 67 tonnes), 

beta-agonists (isoprenaline and procaterol; 51 tonnes), and anti-cholinergics 

(ipratropium; 8 tonnes) and their combinations. Under the China transition 

strategy, all of the CFC MDIs for these moieties will become non-essential when 

one alternative CFC-free MDI becomes available, except for beclomethasone that 

requires two CFC-free alternatives. 

The China phase-out strategy is also determined by category. In category A 

(beta-agonists), phase-out is proposed when five CFC-free MDIs become 

available (4 salbutamol and one other). For Category B (inhaled corticosteroids), 

phase-out is proposed when two beclomethasone CFC-free MDIs become 

available along with two other moieties. For categories C, D and E, a single 

CFC-free inhaler in an adequate range of doses will trigger phase-out for the 

category. In category F (combinations), phase-out can occur once the separate 

moieties are available on the market in CFC-free inhalers. 

There is already a substantial range of imported CFC-free inhalers in all of these 

categories, which may provide suitable and affordable alternatives. 

For category B, two HFC MDIs are available for fluticasone (one in combination 

with salmeterol) and four DPIs are available containing an inhaled corticosteroid 

(fluticasone alone, and in combination with salmeterol; and budesonide alone, 

and in combination with formoterol). These are significantly more expensive 

than locally produced CFC MDIs containing inhaled corticosteroids. To date, 

one locally made budesonide HFC MDI has been submitted for registration to the 

SFDA in 2010. There have been no registration applications for beclomethasone 

HFC MDIs as yet, although a locally made beclomethasone DPI is available. 

For category C, China states that a locally made DPI alternative for sodium 

cromoglycate is available. 

For category D, an imported ipratropium bromide HFC MDI is dominant in the 

market (about 1 million inhalers). Ipratropium bromide CFC MDIs are also made 

in small numbers by two local enterprises (about 20,000 inhalers). These 

products are sold at the same price as the imported HFC MDI (IMS4

 data; 

 

3

 Shanghai Sine Tianping Pharmaceutical Co.Ltd produces a salbutamol DPI. It can produce 60 

million capsules (single dose) per year, but only produces 6 million capsules per year due to its 

limited market. Jing Wei also produces a salbutamol DPI (200mcg dose), although its capacity and 

production are unknown. 

4

 IMS Health is an international company that supplies the pharmaceutical industry with sales data. 
TEAP May 2011 Progress Report 23

47 RMB). An imported DPI for tiotropium (and possibly also a locally made 

DPI) is also available. 

MTOC concludes that phase-out of CFC MDIs for inhaled corticosteroids is still 

in its early stages, and the relative role of imports is unclear, in particular in terms 

of affordability. In contrast, MTOC considers that anti-cholinergics (category D) 

no longer meet the criteria for essential use in China. The criteria for China’s 

transition strategy for category D appear to have been satisfied. Consequently, 

MTOC is unable to recommend the CFC quantities requested for ipratropium. 

Non-essentiality appears also to apply to sodium cromoglycate (category C) 

although further information is needed. MTOC requests additional information 

about CFC-free alternatives to sodium cromoglycate in China and the essentiality 

of the CFC MDI formulation. In future years, MTOC is unlikely to recommend 

CFCs for sodium cromoglycate MDIs given the global availability of CFC-free 

alternatives. 

Exports

The China nomination provides a detailed analysis of its proposed export markets 

for 2012. The requested CFCs for MDI exports constitute about 5 percent of 

China’s total nominated quantity for 2012. The nomination states it will not 

export to countries that have declared non-essentiality. It provides an intended 

list of 13 Article 5 countries for exports in 2012 (Burma, Cambodia, Chile, Cuba, 

Ethiopia, Kenya, Mali, Mozambique, Nigeria, Peru, Sierra Leone, Sudan, 

Turkmenistan). MTOC understands that the one manufacturer, Jing Wei, makes 

90 percent of China’s CFC MDI exports. 

Cuba has requested to import a small quantity of sodium cromoglycate CFC 

MDIs from China in 2012. Many countries no longer use cromoglycate MDI due 

to the availability of more effective therapies and the technical difficulty in 

reformulation of the CFC MDI. MTOC notes that alternative sodium 

cromoglycate HFC MDI (e.g. Intal and Cromal-5 HFC MDIs) and DPI 

formulations (e.g. Jing Wei’s sodium cromoglycate DPI or Intal Spincaps DPI) 

may be available for import to Cuba. However, MTOC is uncertain whether 

these or other CFC-free alternatives are currently approved for use in Cuba. 

Consequently, MTOC has recommended the quantity of CFC for sodium 

cromoglycate CFC MDIs intended for export from China for 2012 only. One 

year will give time for Cuba to complete approvals for import of the globally 

available CFC-free alternatives. As soon as Cuba achieves the import of CFCfree alternatives, import of sodium cromoglycate CFC MDIs from China should 

be phased out. 

Except for cromoglycate CFC MDIs intended for export to Cuba, MTOC does 

not believe that the remaining nominated volumes for export meet the criteria for 

essentiality, and is unable to recommend these quantities for export. MTOC 

believes that there is a complete range of affordable CFC-free alternatives 

available worldwide for all importing countries. MTOC considers that there is 

probably no essential requirement for export of CFC MDIs from China for 2012 

and beyond and that continued export of CFC MDIs is detrimental to the 

transition to CFC-free inhalers in all importing countries. MTOC was not 

provided evidence in the China nomination that importing countries still consider 

CFC MDIs essential in 2012. 
24 TEAP May 2011 Progress Report

Stockpiles

The nomination describes in detail the CFC inventory management process in 

2010. At end of 2010, the total stockpile held by MDI manufacturers in China 

was 65.24 tonnes. Furthermore, the only bulk CFC manufacturer in China held 

inventory of 865.49 tonnes of pharmaceutical-grade CFCs. Thus, the total 2010 

year-end stockpile in China was 930.73 tonnes. This corresponds to about 18 

months of actual use. The nomination states that China will not issue a CFC 

production quota to the CFC manufacturer for 2011 unless the inventory is 

inadequate. MTOC commends China for plans to manage its stockpile down to 

no more than 12 months of actual use through licensing of bulk CFC 

manufacture. 

Dimethicone and Traditional Chinese Medications

The nomination includes a request for 200 kg CFCs for dimethicone, which is an 

anti-foaming agent used in pulmonary oedema in China. MTOC is unaware that 

dimethicone is used elsewhere for this indication. China has mentioned the 

technical difficulty of reformulation and substitution of dimethicone CFC MDI 

due to its chemical properties and those of HFCs compared with CFCs. China 

has determined to make the use of this product non-essential in 2016. 

The nomination also includes a request for 9 tonnes CFCs for Chinese Traditional 

Medicines (TCM). China has mentioned the technical difficulty of reformulation 

and substitution of TCM CFC MDIs, and has stated that substitution is unlikely to 

be completed. China has decided that the date for non-essential use of TCM CFC 

MDIs is currently determined to be 2016. 

In previous years, MTOC has requested published scientific information and 

outcomes of the Chinese re-evaluation of the therapeutic benefits of these 

medications. MTOC understands from the nomination that this re-evaluation is 

still in process. MTOC anticipates this information would be provided in any 

future nomination to assess the on-going essentiality of these medications. 

MTOC may be unable to recommend future CFC quantities for dimethicone and 

Chinese Traditional Medicines without adequate additional information on 

essentiality. 

The nominated quantities of CFCs for essential uses in domestic and export 

markets for the nominated active ingredients in 2011 (metric tonnes) are: 
TEAP May 2011 Progress Report 25

Recommended Quantities in Accordance with Decision XV/5(3): 

Active Ingredients China Export Total 

Beclomethasone 54.77 0 54.77 

Beclomethasone/clenbuterol/ipratropium 0.7 0 0.7 

Budesonide 11.16 0 11.16 

Cromoglycate 6.58 3.9 10.48 

Datura metel extract/clenbuterol 2.0 0 2.0 

Dimethicone 0.20 0 0.20 

Ephedra, ginkgo, sophora flavescens, radix 

scutellariae 

7.00 0 7.00 

Ipratropium 0 0 0.00 

Ipratropium/salbutamol 0.74 0 0.74 

Isoprenaline 45.88 0 45.88 

Isoprenaline/guaifenesin 3.96 0 3.96 

Procaterol 1.45 0 1.45 

Salbutamol 393.68 0 393.68 

Salmeterol 0.02 0 0.02 

Total 528.14 3.90 532.04 

2.2.16 Pakistan 

Year Quantity nominated 

2012 24.1 tonnes 

Specific Use: MDIs for asthma and COPD 

Nominated quantities, active ingredients and intended markets for which the 

nomination applies: 

Active Ingredient Intended Market Quantity (Tonnes) 

Beclomethasone Pakistan 1.0 

Beclomethasone/Salbutamol Pakistan 14.1 

Fluticasone/Salmeterol Pakistan 1.0 

Salbutamol Pakistan 7.5 

Salmeterol Pakistan 0.2 

Triamcinolone Acetonide Pakistan 0.3 

Total 24.1 
26 TEAP May 2011 Progress Report

Recommendation: Recommend 24.1 tonnes CFCs for MDIs for intended use in 

Pakistan for the active ingredients beclomethasone, beclomethasone/salbutamol, 

fluticasone/salmeterol, salbutamol, salmeterol, triamcinolone acetonide. 

Comments 

This nomination should be the final request for essential use CFCs by Pakistan, 

according to the country ́s phase-out strategy. For 2012, Pakistan has nominated 

24.1 tonnes CFCs, which is a reduction of about 40 percent from 39.6 tonnes 

CFCs authorised for 2011. There is an expected reduction in consumption of 

CFCs for all moieties and combination products, except triamcinolone acetonide. 

CFCs for ipratropium MDIs are no longer included. 

Of the three local producers, GlaxoSmithKline, which historically was the largest 

local CFC MDI manufacturer, has been importing HFC MDIs, and is expected to 

start local production of salbutamol HFC MDIs in the second quarter of 2012. 

The second largest MDI manufacturer, Macter International Ltd., has requested 

20 tonnes for 2012, which is a reduction of 16 tonnes from its request for 2011. 

This company will have to fund its own conversion to CFC-free inhalers because 

it did not qualify for funding from the Multilateral Fund. The third producer, 

Zafa Pharmaceutical Laboratories Ltd., has increased its nomination from 3.6 

tonnes to 4.1 tonnes. In Decision 56/49, the Executive Committee of the 

Multilateral Fund approved an investment project for Zafa. 

The production of MDIs in Pakistan is solely for domestic consumption. The 

nomination does not mention the phase-out date of 2012, which according to the 

National Strategy is the phase-out date. However, the company without MLF 

funding, Macter, has indicated to MTOC that it is on track for conversion by 

December 2012. 

Introduction of locally made salbutamol CFC-free inhalers could be hindered by 

imports of inexpensive CFC MDIs from China, for instance CFC MDIs 

manufactured by Jewim Pharmaceuticals (Shandong) Co Ltd. (otherwise known 

as Jing Wei) are currently imported into Pakistan. CFC-free inhalers are also 

imported into Pakistan. MTOC has received information that the following 

moieties are available in Pakistan either as DPIs or as CFC-free MDIs: 

beclomethasone, budesonide, fluticasone, formoterol, ipratropium, salbutamol, 

and salmeterol; and the combination products: salbutamol/beclomethasone, 

budesonide/formoterol, ipratropium/salbutamol, fluticasone/salmeterol, 

tiotropium/formoterol. According to the nomination these products are more 

expensive than the CFC MDI products made locally. However, MTOC is aware 

that dry powder inhaler capsules for use with two devices (Revolizer and 

Rotahaler) are now available in a range of locally made medications, including 

for salbutamol. Dry powder inhaler sales in Pakistan showed an appreciable 

growth rate of 307 percent in 2010. According to IMS data, about 46,000 

patients were shifted to dry powder inhalers during 2010. These devices are 

reportedly providing the advantage of increased compliance by and cost 

effectiveness for patients in Pakistan. These locally made CFC-free inhalers 

provide an expanding alternative to CFC MDIs. 

The salbutamol CFC MDI produced by Macter was registered and briefly 

launched in February 2007 to complete regulatory obligations. However it was 

not launched commercially until 2010. Essential use requests for this product 

were made within nominations for the years 2010, 2011 and now for 2012. Its 
TEAP May 2011 Progress Report 27

introduction in the market has taken place while GSK has been substituting its 

salbutamol CFC-free MDI (currently imported but soon to be locally made) for 

its salbutamol CFC MDI. 

A press report (The Express Tribune, 11 February 2011) on the shortage of 

inhalers and nebulizers for asthma in Pakistan came to the attention of MTOC. 

While the report highlights the shortage of inhalers in general, it also quotes 

pharmacy retailers and some patients being aware of both the earlier (CFC-based) 

brands as well as the newer (CFC-free based) brands. The report also indicates 

that many patients are psychologically attached to the brands with which they are 

familiar. 

On consulting with the implementing agencies for the Pakistan MDI project 

(UNDP and UNEP), MTOC was assured that such issues and challenges had been 

foreseen and were to be expected during the transition period, not only in 

Pakistan but also other countries. The agencies indicated they were working 

closely with government, industry and other stakeholders to find ways to 

minimize the impacts of such challenges on cost-effective availability of inhalers 

during the transition period. MTOC also learned that local companies are 

conducting extensive education campaigns. 

The accounting framework of Pakistan for the year 2010 indicates that Macter 

and Zafa together used slightly less (34.6 tonnes) than the amount of CFCs 

authorised by the Parties (34.9 tonnes). No CFCs were acquired in 2010, with 

only stock held at the start of 2010 used for the manufacture of MDIs. A small 

stockpile of 2.5 tonnes remained at the end of 2010. 

2.2.17 Russian Federation 

Year Quantity nominated 

2012 250.0 tonnes 

2013 125.0 tonnes 

Specific Use: MDIs for asthma and COPD 

Nominated quantities, active ingredients and intended markets for which the 

nomination applies: 

Year Active Ingredient Intended market Quantity 

(Tonnes) 

2012 Salbutamol Russian Federation 250.0 

2013 Salbutamol Russian Federation 125.0 

Recommendation: 

Recommend 212 tonnes CFCs for MDIs for intended use in the Russian 

Federation for the active ingredient salbutamol for 2012. 

Unable to recommend CFCs for MDIs requested for 2013. 
28 TEAP May 2011 Progress Report

Comments 

The Russian Federation nomination requests 250 tonnes CFCs for the 

manufacture of salbutamol CFC MDIs for domestic use only, which is 2 tonnes 

more than the 248 tonnes nominated for 2011, and an 18 percent increase over the 

212 tonnes nominated for 2010 and authorised by Parties for 2010 and 2011. The 

majority of patients continue to use locally produced CFC MDIs owing to their 

wider availability, low cost and popularity. The combined production volume for 

locally made salbutamol CFC MDIs increased from 4.1 to 7.6 million units 

between 2008 and 2010. 

CFCs are requested for two Russian pharmaceutical companies, which together 

with UNIDO took initiatives in 2009-10 to develop a GEF-funded project to 

complete the phase out of CFCs in MDIs. The Russian Federation stated in 2010 

that the phase-out could be achieved by the end of 2012 if GEF funds became 

available on time. Although the two companies have submitted documents for 

registration of salbutamol CFC-free MDIs, the implementation of the conversion 

project, specifically the appropriation of funding for equipment and provision of 

technology assistance, has been further delayed. This has led them to adjust the 

timeline to mid-2013. 

Negotiations between UNIDO and GEF about a grant for preparation of the 

UNIDO/GEF Project, “Phase-out of CFC consumption in the Manufacture of 

Aerosol Metered Dose Inhalers (MDIs) in the Russian Federation”, has been 

completed successfully and on the 15th of March, 2011, UNIDO received 

notification from GEF about appropriation of those funds. In June 2011 it is 

envisaged that preparation of the project proposals for submission to the GEF 

Secretariat will be completed. It is planned that the UNIDO/GEF Project would 

be approved during the autumn meeting of the GEF Council, and the 

UNIDO/GEF Project started at the beginning of 2012 and finished in the second 

part of 2013. 

Despite the recent successful appropriation of funds, there has otherwise been 

little demonstrated progress in manufacturing transition in the last 12 months. At 

present, Russian companies are carrying out testing of the technological 

parameters of production of CFC-free products on laboratory equipment for 

subsequent use in process lines, which they plan to acquire during the 

UNIDO/GEF Project. Parties authorised an essential use exemption for 212 

tonnes for the Russian Federation for each of the years 2010 and 2011. 

Considering the patient perspective, MTOC is recommending the same quantity 

(212 tonnes) for 2012, instead of the nominated 250 tonnes. The increased 

demand for salbutamol MDIs could be fulfilled by the currently available 

imported CFC-free MDIs, which are similarly priced at equipotent dose. 

A bilateral Russia/United States Government workshop on Exchange of 

Experience in Implementation of Transition to CFC-free MDI Production was 

held in Moscow in late September 2010. Options for future cooperation were 

discussed for the Russian conversion of production of MDIs to the use of HFCs. 

After signing a contract for the supply of equipment and obtaining a list of 

technical specifications and parameters, the two Russian companies plan to 

communicate with relevant members of the US working group on specific issues 

relating to commissioning. This will be aimed at minimising errors and 

optimising time in starting new production of HFC MDIs. Given the equipment 

and technology used by US companies are not fundamentally different from those 
TEAP May 2011 Progress Report 29

to be introduced by Russian enterprises, such assistance is expected to be 

extremely useful. 

MTOC is unable to recommend the nomination for 2013. The phase-out date for 

the Russian Federation was initially established as 2008. In recent years the 

argument of lack of finance has been repeatedly offered to justify new 

nominations. A delayed funding process with UNIDO and the GEF has more 

recently frustrated timely transition in the Russian Federation. There is a clear 

opportunity for the Russian Federation Government and the two companies to 

take the initiative to accelerate the phase-out process and thereby fulfil their 

environmental commitments under the Montreal Protocol. If conversion is not 

achieved within 2012, MTOC believes that the Russian Federation should 

broaden the importation and distribution of affordable, imported salbutamol CFCfree inhalers to meet the demand of Russian patients with asthma and COPD. 

2.3 Reporting Accounting Frameworks for Essential Use 

Exemptions and Issues for Countries in the Final Stages of 

Transition 

The following section describes information provided in reporting accounting frameworks by 

Parties with authorised essential use exemptions for 2010 that are not nominating essential 

uses for 2012. It also elaborates some remaining issues for these countries in the final stages 

of transition. The reporting accounting frameworks of Parties nominating essential uses for 

2012, and associated issues, are summarised in the preceding sections. 

2.3.1 Argentina 

Parties authorised 178 tonnes of essential use CFCs for the manufacture of MDIs in Argentina 

for 2010. Argentina’s accounting framework for 2010 was received on 25th January 2011. 

Argentina reports that no CFCs were acquired during 2010 for essential uses. With a 

stockpile of 90 tonnes entering the year, Argentina has used its stockpile to manufacture 

MDIs in 2010. Final data from MDI manufacturers on usage and the remaining stockpile at 

the end of 2010 were not available at the time of submission. Apparently there were some 

CFC supply issues for Argentinian MDI manufacturers that would ordinarily import CFCs. 

Argentina has an authorised essential use exemption of 107.2 tonnes for 2011. During its 

March 2011 meeting held in Buenos Aires, Argentina, MTOC met with a small selection 

(Atlas, Denver, Pablo Cassara, and 3M Argentina) of local MDI manufacturers and 

representatives of the Secretaria de Ambiente y Desarrollo Sustentable. Argentina is pleased 

to report there has been significant progress in the transition from CFC MDIs to CFC-free 

inhalers. There is now significant HFC MDI production capacity, with a range of alternative 

CFC-free inhalers available in the market and also in the pipeline. Atlas has developed HFC 

inhalers, without any previous manufacture of CFC MDIs, with its salbutamol HFC MDI 

approved during 2010. Denver Farma ceased production of CFC MDIs at the end of 2010, 

with its salbutamol HFC MDI launched in July 2010. 3M Argentina has developed a range of 

HFC formulations: it is ready to license generic HFC inhalers (salbutamol, 

salbutamol/beclomethasone, fluticasone, fluticasone/salmeterol, budesonide) to developing 

markets. 

Pablo Cassara manufactures a number of HFC MDI products in a range of active ingredients. 

Pablo Cassara continues to develop isobutane-propelled salbutamol MDIs as a climate and 

ozone friendly alternative to CFC MDIs. It is hoping to submit its formulation for approval to 

regulatory authorities by the 2nd half of 2012. Pablo Cassara is not anticipating the need for 

any long-term clinical studies. However, MTOC members are of the opinion that toxicology 
30 TEAP May 2011 Progress Report

and clinical studies (in combination with each active ingredient) will be needed, at least 

outside Argentina, because no full human toxicological studies have ever been performed on 

isobutane. Pablo Cassara has also developed a formulation for salbutamol HFC MDIs. 

Given the scarcity of CFC supply in Argentina, and commendable progress in the 

manufacture of CFC-free inhalers, it is unlikely that there will be significant continued 

essential use requirements in Argentina. 

2.3.2 Egypt 

Parties authorised 227.4 tonnes of essential use CFCs for the manufacture of MDIs in Egypt 

for 2010. However, no accounting framework has been reported for authorised essential uses 

in 2010. 

2.3.3 European Union 

Parties authorised 22 tonnes of essential use CFCs for the manufacture of MDIs in the 

European Union for 2009. The European Union’s accounting framework for 2009 was 

received on 22nd February 2011. The European Union has also updated the accounting 

framework for 2008, and outlined plans for the remaining surplus. 

For 2009, the European Union reports that about 14 tonnes of pharmaceutical-grade CFCs 

were acquired in 2009 under its essential use exemption. With about 115 tonnes of stockpile 

entering 2009, the European Union reports that about 79.5 tonnes were used to manufacture 

MDIs, of which 74.4 tonnes were contained in exported products. With about 3 tonnes 

destroyed in 2009, a stockpile of about 46.4 tonnes remained at the end of 2009. 

The European Union has completed transition and has not had any authorised essential use 

exemptions since 2009. In a letter dated February 2011, the European Union has indicated 

the likely fate of the surplus: some are to be destroyed; some “will be used for the production 

of MDIs and parts thereof”; some were sold for a non-MDI use of which nothing is known of 

the intended use except that the purchaser is a known user of CFC for process agent uses; no 

information is available for some; and some was unaccounted for on stock inventory. 

Further discussion on CFCs stockpiles and the deployment of surplus is presented in section 

3.3. 

2.3.4 India 

Parties authorised 343.6 tonnes of essential use CFCs for the manufacture of MDIs in India 

for 2010. India’s accounting framework for 2010 was received on 25th March 2011. India 

reports that about 293 tonnes of pharmaceutical-grade CFCs were manufactured in 2010 

under its essential use exemption, along with about 24.4 tonnes of non-pharmaceutical grade 

CFCs manufactured during the start-up of the production run. Of the 293 tonnes, India 

reports that 2.24 tonnes of bulk CFCs were exported to Iran under its essential use exemption. 

MTOC notes that this quantity also appears in the accounting framework for Iran. 

Of the 290.7 tonnes of CFCs produced for domestic requirements, only 94.9 tonnes were used 

for MDI manufacture in India. India reports that none of these CFCs were used to 

manufacture MDIs intended for exports. No CFCs were destroyed in 2010. With a small 

stockpile of about 6 tonnes entering the year, by the end of 2010 India had a stockpile of 

about 201.9 tonnes of pharmaceutical-grade CFCs, plus 24.4 tonnes of non-pharmaceutical 

grade CFCs. 
TEAP May 2011 Progress Report 31

India’s nomination for 2011 was withdrawn and transition has been completed, meaning that 

a stockpile remains that is surplus to requirements in India. Further discussion on CFCs 

stockpiles and the deployment of surplus is presented in section 3.3. 

2.3.5 Iran 

Parties authorised 105 tonnes of essential use CFCs for the manufacture of MDIs in Iran for 

2010. The Iran accounting framework for 2010 was received on 16th March 2011. Iran 

reports that 2.24 tonnes of pharmaceutical-grade CFCs were imported from India under Iran’s 

essential use exemption for 2010. Iran reports that a license for the import of about 18.7 

tonnes of CFCs was issued in 2009 under the pre-essential use quota system, and delivered in 

January 2010. This provided stock of 18.7 tonnes at the start of 2010. Iran used the entire 

20.96 tonnes of available pharmaceutical-grade CFCs for the manufacture of MDIs in 2010, 

with no stockpile remaining. No CFCs were destroyed in 2010. 

2.3.6 Syria 

Parties authorised 44.68 tonnes of essential use CFCs for the manufacture of MDIs in Syria 

for 2010. However, no accounting framework has been reported for authorised essential uses 

in 2010. 

2.3.7 United States 

Parties authorised 92 tonnes of essential use CFCs for the manufacture of MDIs in the United 

States for 2010. The United States does not have any authorised essential uses for 2011. The 

United States’ accounting framework for 2010 was received on 19th March 2011. Of the 92 

tonnes of CFCs authorised as essential uses by the Parties, the United States allocated 30 

tonnes to MDI manufacturers for CFC production under its internal legal processes, all of 

which was acquired. With a reported stockpile of 525 tonnes entering the year, the United 

States had 555 tonnes available for use in 2010. The United States reported that 358 tonnes 

of CFCs were used for the manufacture of MDIs in 2010 and 28 tonnes were destroyed, with 

remaining stockpile of 169 tonnes at the end of 2010 reported in its accounting framework. 

Some of the surplus reported in the accounting framework was manufactured pre-1996. In 

addition, the United States has reported separately under Decision XXII/4(4) that stockpiles 

of 624.637 tonnes of pharmaceutical-grade CFCs are potentially available for export to 

Parties with essential-use exemptions in 2011. The United States has advised that this 

stockpile quantity, held by Honeywell, is separate to the stockpile reported in its accounting 

framework, held by individual MDI manufacturing companies. Therefore, the United States 

has a total stockpile of about 793.6 tonnes of CFCs. Further discussion on CFCs stockpiles 

and the deployment of surplus is presented in section 3.3. 

TEAP May 2011 Progress Report 33

3 Medical Technical Options Committee Progress Report 

3.1 Executive Summary 

The Medical Technical Options Committee (MTOC) thanks the Ozone Secretariat for 

providing meeting venue sponsorship for the MTOC meeting held in Buenos Aires, 20-22 

March 2011. MTOC member, Dr Jorge Caneva, and the Ozone Program Office of Argentina 

(OPROZ) provided a range of organisational assistance. 

The global use of CFCs to manufacture MDIs in 2010 is estimated to be less than 1,600 

tonnes. Article 5 countries that provided accounting frameworks used about 768 tonnes, and 

the Russian Federation and the United States used about 570 tonnes, of CFCs for the 

manufacture of MDIs in 2010. Parties reported about 1,931 tonnes of pharmaceutical-grade 

CFCs in stockpiles at the end of 2010. The United States reported that about 625 tonnes of 

pharmaceutical-grade CFCs are available for export under commercial agreement with 

holders of those stocks. In addition, the United States also reported 169 tonnes of CFCs held 

by individual MDI manufacturing companies in its accounting framework. India reported 

stockpile of about 202 tonnes of pharmaceutical-grade CFCs, and about 24 tonnes of nonpharmaceutical grade CFCs at the end of 2010. 

Production of pharmaceutical-grade CFCs is now limited to a few sources. It is likely that, 

other than for China and the Russian Federation, all other essential use CFCs will need to be 

acquired from available stockpile for 2011. Furthermore, CFCs can potentially be supplied 

from stockpile for the total remaining essential use requirements (190 tonnes) for countries 

excluding China and the Russian Federation. This depends on, inter alia, Parties’ decisions 

regarding essential use exemptions for 2012, whether stockpile is acquired under commercial 

arrangements, and also whether the CFC mix and specifications of the stockpile meets the 

needs of the MDI manufacturers. However, it should be possible to complete the phase-out of 

CFC MDIs in countries without access to CFC production sources with careful management 

of existing global CFC stockpiles. 

Remaining CFC surplus should also be considered for some of the remaining essential use 

requirements in China and the Russian Federation to avoid the need for unnecessary new 

production and costly destruction of surplus. Any new source of supply of CFCs will require 

that CFC MDI producers validate the suitability of the newly sourced propellant in each 

specific MDI product. Parties may wish to encourage the transfer of stockpiles and to avoid 

future production of CFCs that is surplus to actual needs. A cautious approach to CFC 

production is advisable since transition is moving quickly. 

TEAP and its MTOC believes that it is important during the final stages of the phase-out of 

CFC MDIs that stockpiles of CFCs are utilised only in uses authorised through an essential 

use exemption, in preference to newly produced CFCs, and appropriately destroyed if not 

utilised in uses authorised under an essential use exemption. Parties may wish to clarify in a 

decision that CFCs produced under Decision IV/25, or remaining pre-1996 or -2010 phaseout CFCs that were not utilised for essential uses in subsequent years in preference to 

production of new CFCs, are only authorised for uses specified in essential use exemptions 

and otherwise, if not utilised, need to be destroyed. Such a decision might clarify obligations 

for Parties with surplus CFCs. 

Technically satisfactory alternatives to CFC MDIs to treat asthma and COPD are available in 

almost all countries worldwide. MTOC has noted previously the wide availability in Article 5 

countries of technically suitable CFC-free alternatives to CFC MDIs manufactured by 

multinational companies in developed countries. CFC-free inhalers manufactured in 

developing countries are now substantially increasing the range of affordable alternatives. 
34 TEAP May 2011 Progress Report

3.2 Global Use of CFCs for MDIs 

The global use of CFCs to manufacture MDIs in 2010 was about 1,340 tonnes, excluding 

Egypt and Syria, for which accounting frameworks were not received. Taking potential 

consumption in these countries into account, global consumption in 2010 is estimated to be 

less than 1,600 tonnes. 

Figure 3-1 and Table 3-1 show the use of chlorofluorocarbons (CFCs) for the manufacture of 

MDIs for asthma and COPD in Article 5 and non-Article 5 countries for essential uses. 

Article 5 countries that provided accounting frameworks used about 768 tonnes of CFCs for 

the manufacture of MDIs in 2010, a remarkable reduction of 55 percent from 1,700 tonnes in 

2009. Most countries reduced consumption significantly between 2009 and 2010, except 

China for which consumption remained about the same. 

The Russian Federation and the United States used about 570 tonnes of CFCs for the 

manufacture of MDIs in 2010, a reduction of only 2 percent from 2009. The United States 

increased its production of CFC MDIs in 2010 by 6 percent. 

Despite the 2010 trends in China, Russia and the United States, there has otherwise been 

significant global progress in the transition of CFC MDIs to CFC-free inhalers in 2010. 

Substantial capacity to manufacture CFC-free inhalers is expected by 2011-2012. 

Figure 3-1: Quantities of CFCs for MDI manufacture in Article 5 and non-Article 5 

countries 
TEAP May 2011 Progress Report 35

Table 3-1: Quantities (in tonnes) of CFCs for MDI manufacture in Article 5 and nonArticle 5 countries 

Year of 

Essential 

Use 

Amount Exempted/ 

Nominated for year 

of Essential Use 

Used for Essential 

Use 

On Hand End of 

Year 

1996 12,987.20 8,241.13 7,129.59 

1997 13,548.00 8,904.99 8,515.24 

1998 11,720.18 8,013.60 7,656.63 

1999 9,442.13 7,906.35 5,653.95 

2000 8,364.95 6,062.75 5,433.32 

2001 6,126.53 6,121.62 4,402.59 

2002 6,714.75 4,751.92 4,133.71 

2003 6,641.55 4,261.91 3,570.27 

2004 5,443.12 2,840.82 2,460.10 

2005 3,321.10 2,735.40 3,671.01 

2006 2,039.00 2,107.10 2,916.08 

2007 1,778.00 1,220.90 1,946.68 

2008 797.00 796.10 1,022.18 

2009 552.00 772.54 **1,590.16 

*2010 2,399.78 1,338.29 **1,930.56 

2011 1,099.95 - - 

* In the year 2010, Article 5 countries with essential use authorisations are newly included, which explains 

in part the sudden jump in quantities for all three categories, amount exempted, used and stockpiled. Use 

and stockpile are not reflected for Egypt or Syria because no accounting frameworks were received for 

these countries. 

** For the years 2009 and 2010, separately reported stockpile (1,017.148 tonnes and 624.637 tonnes 

respectively) held by Honeywell in the United States is included, in addition to stocks held by individual 

MDI companies reported in the accounting frameworks. 

3.3 CFC Stockpiles 

Table 3-1 presents historical stockpiles reported by Parties with essential use exemptions 

under accounting frameworks. Of the Parties that provided accounting frameworks for 2010, 

there were stocks of pharmaceutical-grade CFCs of about 1,930 tonnes at the end of 2010. 

Decision XXI/4 and XXII/4 encouraged Parties with stockpiles of pharmaceutical-grade 

CFCs potentially available for export to notify the Ozone Secretariat by 31st December 2009 

and 2010 respectively. As a result, at the end of 2009 Parties reported that there were about 

1,017 tonnes of pharmaceutical-grade CFCs (about 225 tonnes CFC-11, 425 tonnes CFC-12, 

367 tonnes CFC-114) available in stockpiles in the United States and 301 tonnes of 

pharmaceutical-grade CFC-12 available in Venezuela. At the end of 2010, no further 

information is available on stockpiles in Venezuela, and the United States reported stockpiles 

of 624.637 tonnes (about 155 tonnes CFC-11, 349 tonnes CFC-12, 121 tonnes CFC-114). 

These stockpiles are available for export under commercial agreement with holders of those 

stocks. Regulatory processes for exporting CFCs from the United States’ stockpiles for 

essential uses are not complicated. The United States has advised that this stockpile quantity, 

held by Honeywell, is separate to the stockpile of 169 tonnes reported in its accounting 

framework held by individual MDI manufacturing companies. 
36 TEAP May 2011 Progress Report

Any remaining essential use stockpiles in the European Union are not available for export due 

to regulations prohibiting the production and export of CFCs from 1st January 2010. The 

European Union has reported in its accounting framework stockpile of about 46 tonnes at the 

end of 2009. The European Union has completed transition and has not had any authorised 

essential use exemptions for MDIs since 2009. In a letter dated February 2011, the European 

Union has indicated the likely fate of the surplus: some are to be destroyed; some “will be 

used for the production of MDIs and parts thereof”; some were sold for a non-MDI use of 

which nothing is known of the intended use except that the purchaser is a known user of CFC 

for process agent uses; no information is available for some; and some was unaccounted for 

on stock inventory. 

India has also reported in its accounting framework stockpile of about 202 tonnes of 

pharmaceutical-grade CFCs, and 24.402 tonnes of non-pharmaceutical grade CFCs, available 

at the end of 2010. 

The European Union, India and the United States do not have any authorised essential use 

exemptions for 2011 or later. At the end of 2010, total CFC stockpiles in these Parties was 

about 1,020 tonnes. 

TEAP and its TOCs has reported previously that there may be two remaining1

 options to 

resolve post-1996 and post-2010 surplus accumulated under the essential use provisions of 

the Montreal Protocol: 

1. Transfer the surplus CFCs to an essential use authorised by Parties; and/or 

2. Destruction of the surplus CFCs in processes approved by the Montreal Protocol. 

TEAP and its MTOC have also reported previously on the status of pre- and post-1996 

stockpiles in non-Article 5 countries2

. TEAP and its MTOC concluded that it might not be 

significant that CFCs were produced prior to the 1996 phase-out because of the way these 

stockpiles have been maintained under the essential use process. Under essential use 

requirements, it is assumed that any company that had received an essential use allowance 

would have been required to use existing pre-1996 stock first. TEAP and its MTOC believes 

that if a company used an essential use quantity while in possession of pre-1996 material, 

then any pre-1996 surplus remaining at the end of a company’s production of MDIs under 

essential use exemption should be treated as having been produced post-1996. Under this 

interpretation, the deployment of the pre-1996 surplus would also need to abide by the 

provisions of the Montreal Protocol that might apply to post-1996 surplus (as outlined above). 

The same interpretation is relevant for pre- and post-2010 stockpiles in Article 5 countries. 

The letter from the European Union raises the issue of whether or not CFCs accumulated 

under the essential use provisions can or cannot be used for process agent or feedstock uses. 

Article 2 of the Montreal Protocol mandates the phase-out of production and "consumption" 

of substances that deplete the ozone layer. "Consumption" is defined as production plus 

imports minus exports. Article 2 also authorises the Parties by decision to permit such 

 

1 In its 2005 Progress Report, TEAP also reported a third option of transfer to an Article 5 country for basic 

domestic needs (with prior consent and accounting), which is no longer available as an option. UNEP May 2005 

Report of the Technology and Economic Assessment Panel, pg. 35, 

http://ozone.unep.org/Assessment_Panels/TEAP/Reports/TEAP_Reports/teap_progress_report_May2005.pdf.

2

 UNEP May 2005 Report of the Technology and Economic Assessment Panel, pg. 35, 

http://ozone.unep.org/Assessment_Panels/TEAP/Reports/TEAP_Reports/teap_progress_report_May2005.pdf. 
TEAP May 2011 Progress Report 37

production and "consumption" as may be necessary for those uses decided by the Parties to 

satisfy the essential use criteria. 

Under Decision IV/25, production and consumption for essential uses after the Protocol’s 

production phase-out is very specific. It is only permitted against an authorisation granted by 

the Parties to an individual Party, which is then passed on to an individual company by a 

national mechanism/regulation. This has applied to MDIs, solvents and halons, since only 

these uses have been specified as essential uses for the purposes of production and 

consumption in decisions of the Parties. There is also the global exemption for laboratory and 

analytical uses. 

CFC production and consumption for feedstock and process agents is treated differently to 

CFC production and consumption for essential uses under the Protocol. In Decision VII/30, 

Parties decided that quantities of controlled substances being produced and imported/exported 

for use as feedstock in the manufacture of other chemicals would not be taken into account in 

the calculation of production or consumption of controlled substances. In Decision X/14, 

Parties decided that quantities of controlled substances being produced and imported for use 

as process agents would also not be taken into account in the calculation of production and 

consumption of controlled substances. They are not essential uses, but have been deemed to 

be non-emissive uses or uses where emissions are insignificant. 

Taken together, TEAP and its MTOC might interpret these decisions to mean that Parties did 

not intend that CFCs produced under the essential use provisions were authorised for any uses 

other than those for which the exemption was given, and were not authorised for use as 

feedstock or process agents. Furthermore, TEAP and its MTOC has operated under the 

assumption that Parties intended CFCs authorised under essential use exemptions to be used 

in the uses for which the exemption was given, and has made every effort to estimate 

accurately CFC requirements for MDIs subject to essential use nominations for any particular 

year. 

Alternatively, there are some environmental and economic advantages to deployment of 

CFCs, produced under an essential use exemption authorised for MDI manufacture but 

surplus to requirements, being used in process agent or feedstock applications. This could 

avoid unnecessary new CFC production, feasibly lowering impacts on the ozone layer and the 

costs of CFC acquisition for feedstock or process agent uses. On the other hand, opening this 

as an avenue for deployment of surplus CFCs, produced under an authorised essential use 

exemption for MDIs, might create a perverse incentive for over-estimation and production of 

CFCs under the essential use provisions. Technical assessment of nominations under the 

essential use process might be expected to avoid this outcome. There may be only a few 

process agent or feedstock uses for CFC-11 and -12, but possibly more uses for CFC-114. 

Nonetheless, TEAP and its MTOC believes that it is important during the final stages of the 

phase-out of CFC MDIs that stockpiles of CFCs are utilised only in uses authorised through 

an essential use exemption, and otherwise appropriately destroyed. Parties may wish to 

clarify in a decision that CFCs produced under Decision IV/25, or remaining pre-1996 or -

2010 phase-out CFCs that were not utilised for essential uses in subsequent years in 

preference to production of new CFCs, are only authorised for uses specified in essential use 

exemptions or otherwise destroyed, rather than diverted to process agent or feedstock use. 

Such a decision might clarify obligations for Parties with surplus CFCs. 

Parties may also wish to recall that Decision VIII/9 (9) states: “...to request each of the 

Parties that have had essential-use exemptions granted for previous years, to submit their 

report in the approved format by 31 January of each year”, meaning that Parties are required 

to report stockpile management annually. This allows Parties to track the deployment of 

stockpiles of essential use CFCs through transfer, use, or destruction until depleted to zero. 
38 TEAP May 2011 Progress Report

This should include reporting of quantities of non-pharmaceutical-grade CFCs manufactured 

as a result of production of pharmaceutical-grade CFCs. 

3.4 CFC Production 

Production of pharmaceutical-grade CFCs is now limited to a few sources. Honeywell, in the 

United States, has a swing plant producing HCFC-22 that can also produce CFCs. However, 

regulatory processes to allow export of newly produced CFCs would likely take more than a 

year to complete. China and India both have production facilities capable of manufacturing 

pharmaceutical-grade CFCs but they are subject to MLF production phase-out agreements. 

Under its existing CFC production phase-out agreement, China is allowed to manufacture 

pharmaceutical-grade CFCs for authorised essential uses for itself and for export to the 

Russian Federation only. Decision XXI/4 requested the Executive Committee to consider 

reviewing both of the CFC production phase-out agreements with China and India with a 

view to allowing production of pharmaceutical-grade CFCs to meet authorised levels of CFC 

production for essential uses. The 60th Executive Committee Meeting, April 12-15, 2010, 

decided to modify the production sector agreements for China and India to allow the 

production for export of pharmaceutical-grade CFCs for 2010, with an annual review, for the 

purposes of meeting essential use requirements of other countries provided that the exporting 

countries had specified reporting and verification systems in place. No request has been made 

to review these agreements for 2011. Therefore it is likely that, other than for China and the 

Russian Federation, all other essential use CFCs will need to be acquired from available 

stockpile for 2011. 

Any new source of supply of CFCs will require that CFC MDI producers validate the 

suitability of the newly sourced propellant in each specific MDI product. Validation takes 

time to complete, and in some cases would require the approval of health authorities. Total 

time to register a new source can take up to 6 months. 

3.5 Estimated Future CFC Usage for MDIs 

Table 3-2 and Figure 3-2 show estimated future global CFC usage for MDI manufacture. 

CFC usage for 2010 is based mainly on quantities reported by Parties in accounting 

frameworks. MTOC estimates that less than 1,100 tonnes of pharmaceutical-grade CFCs 

might be required in 2011 to supply CFCs for essential MDI uses, although not all of this 

quantity is likely to be needed. Excluding China and the Russian Federation, less than 140 

tonnes of pharmaceutical-grade CFCs is likely to be required to supply CFCs for essential 

MDI uses in Parties without access to CFC production sources (Argentina, Bangladesh, 

Pakistan) in 2011. If Parties approve MTOC’s recommendations for essential use quantities 

of CFCs at the 23nd Meeting of the Parties, less than 50 tonnes of pharmaceutical-grade CFCs 

might be required in 2012 to supply CFCs for essential MDI uses in countries excluding 

China and the Russian Federation. For 2013 onwards, the estimated CFC consumption for 

essential MDI uses in countries other than China and the Russian Federation might be zero 

tonnes. 

For the total remaining essential use requirements (190 tonnes) for countries other than China 

and the Russian Federation, CFCs can potentially be supplied from stockpile quantities. This 

depends on, inter alia, Parties’ decisions regarding essential use exemptions for 2012, 

whether stockpile is acquired under commercial arrangements, and also whether the CFC mix 

and specifications of the stockpile meets the needs of the MDI manufacturers. However, it 

should be possible to complete the phase-out of CFC MDIs in countries without access to 

CFC production sources with careful management of existing global CFC stockpiles. 
TEAP May 2011 Progress Report 39

Table 3-2: Estimated CFC usage for MDI manufacture by Parties, 2010- 2014+3

Country 2010 2011 2012 2013 2014 + Total 

Algeria 11 8 0 0 0 19

Argentina 90 45 0 0 0 135

Bangladesh 45 57 25 0 0 142

China 528 741 528 400 345 2,577

Colombia - - - - - 0

Cuba - - - - - 0

Egypt 227 0 0 0 0 227

India 95 0 0 0 0 95

Indonesia - - - - - 0

Iran 21 0 0 0 0 21

Mexico - - - - - 0

Pakistan 35 40 24 0 0 98

Russia 212 212 212 0 0 636

Syria 45 0 0 0 0 45

United 

States 

358 0 0 0 0 358

Uruguay - - - - - 0

Venezuela - - - - - 0

Total 1,666 1,103 789 400 345 4,353

Remaining CFC stockpiles should also be considered for some of the remaining essential use 

requirements in China and the Russian Federation to avoid the need for unnecessary new 

production and costly destruction of surplus. 

Parties may wish to encourage the transfer of stockpiles to avoid future production of CFCs 

that are surplus to actual needs. A cautious approach to CFC production is advisable since 

transition is moving quickly. 

Some changes to the accounting framework were considered by MTOC to help track 

production and/or import of newly produced CFC, existing stockpile, and other production 

and stockpile issues. New columns in the accounting framework were considered to report 

the export of bulk CFCs, whether the exported CFCs were newly produced or from stockpile, 

and the country to which they were exported. However, TEAP and its MTOC have not 

elaborated a changed framework given the advanced stage of the phase-out process for MDIs. 

 

3

 Black font is actual use reported by Parties; red font is essential use quantity authorized by Parties; blue font is an 

estimate made by MTOC. For 2010, usage data are based on exempted quantities, actual consumption reported in 

accounting frameworks or estimates provided by countries in 2011 essential use nominations. For 2011, usage 

data are based on exempted quantities or estimations made by MTOC. For 2012, MTOC estimates are based on 

essential use quantities recommended by MTOC and does not pre-judge decisions taken by Parties. For 2013 

onwards, estimated usage does not take into account whether use meets the essential use criteria. 
40 TEAP May 2011 Progress Report

Figure 3-2: Estimated CFC usage4

 for MDIs for Parties, 2010-2014+

3.6 Transition Away from the Use of CFC MDIs 

Technically satisfactory alternatives to CFC MDIs to treat asthma and COPD are available in 

almost all countries worldwide. For a number of years, MTOC has noted the wide 

availability in Article 5 countries of technically suitable CFC-free inhalers manufactured by 

multinational companies in developed countries. CFC-free inhalers manufactured in 

developing countries are now substantially increasing the range of affordable alternatives. 

Further information about the range of alternatives available worldwide are contained in the 

2010 MTOC Assessment Report5

. 

3.6.1 Transition Strategies 

In response to Decision XII/2, transition strategies developed by seven Parties are listed on 

the Ozone Secretariat’s web site. Pursuant to Decision XV/5(4), plans of action regarding the 

phase-out of the domestic use of salbutamol CFC MDIs from the European Community, the 

Russian Federation and the United States are also listed on the Ozone Secretariat’s web site6

. 

For Article 5 countries, Decisions IX/19(5bis) and XV/5(4bis) set out requirements for the 

development of national transition strategies and preliminary plans of action for the phase-out 

of salbutamol CFC MDIs respectively. 

 

4

 For 2010, usage data are based on exempted quantities, actual consumption reported in accounting frameworks or 

estimates provided by countries in 2011 essential use nominations. For 2011, usage data are based on exempted 

quantities or estimations made by MTOC. For 2012, MTOC estimates are based on essential use quantities 

recommended by MTOC and does not pre-judge decisions taken by Parties. For 2013 onwards, estimated usage 

does not take into account whether use meets the essential use criteria. 

5 http://ozone.unep.org/Assessment_Panels/TEAP/Reports/MTOC/MTOC-Assessment-Report-2010.pdf

6 http://ozone.unep.org/Exemption_Information/Essential_Use_Nominations/index.shtml 
TEAP May 2011 Progress Report 41

Decision IX/19(5bis) states: 

“To require Parties operating under paragraph 1 of Article 5 submitting essential-use 

nominations for chlorofluorocarbons for metered-dose inhalers for the treatment of 

asthma and chronic obstructive pulmonary disease to present to the Ozone 

Secretariat an initial national or regional transition strategy by 31 January 2010 for 

circulation to all Parties. Where possible, Parties operating under paragraph 1 of 

Article 5 are encouraged to develop and submit to the Secretariat an initial transition 

strategy by 31 January 2009. In preparing a transition strategy, Parties operating 

under paragraph 1 of Article 5 should take into consideration the availability and 

price of treatments for asthma and chronic obstructive pulmonary disease in 

countries currently importing chlorofluorocarbon-containing metered-dose inhalers;” 

Decision XV/5(4bis) states: 

“That no quantity of chlorofluorocarbons for essential uses shall be authorized after 

the commencement of the Twenty-First Meeting of the Parties if the nominating Party 

operating under paragraph 1 of Article 5 has not submitted to the Ozone Secretariat, 

in time for consideration by the Parties at the twenty-ninth meeting of the Open-ended 

Working Group, a preliminary plan of action regarding the phase-out of the domestic 

use of chlorofluorocarbon containing metered-dose inhalers where the sole active 

ingredient is salbutamol;” 

Furthermore, Decision XVII/5(3bis) requests nominating Article 5 countries to submit a date 

to the Ozone Secretariat prior to the Twenty-Second Meeting of the Parties, by which time a 

regulation or regulations to determine the non-essentiality of the vast majority of 

chlorofluorocarbons for metered-dose inhalers where the active ingredient is not solely 

salbutamol will have been proposed. Decision XV/5(6) requests Parties to submit to the 

Ozone Secretariat specific dates by which time they will cease making nominations for 

essential use nominations for CFCs for MDI where the active ingredient is not solely 

salbutamol. 

This report provides an overview of the national strategies submitted to the MTOC for its 

review at its 2011 meeting. MTOC has noted, from its experience reviewing Essential Use 

Nominations, that Parties engaged in transition from CFC MDI to CFC-free alternatives 

encounter challenges and struggles of various kinds that could result in changes to dates, 

alteration in project timelines, and product availability. Despite this, MTOC believes that a 

well-articulated national transition strategy can provide the necessary road map for a country 

to accomplish the transition. 

In 2011, an update to China’s transition strategy was submitted to the Ozone Secretariat, 

which, among other things, elaborates the date by which the non-essentiality of the vast 

majority of non-salbutamol CFC MDIs will be proposed and specific dates by which time 

they will cease making essential use nominations. This updated strategy is summarised in 

Chapter 2 on Essential Use Nominations. 

Argentina has not yet submitted its national transition strategy. However, Argentina is 

demonstrating significant commendable progress in phasing out CFC MDIs, and it is unlikely 

that there will be significant continued essential use requirements in Argentina. Section 3 of 

Chapter 2 provides a summary of Argentina’s progress. 
42 TEAP May 2011 Progress Report

Further recent information on transition strategies is contained in the 2010 MTOC Assessment 

Report7

. 

3.6.2 Progress Reports on Transition Strategies under Decision XII/2 

Under Decision XII/2, Parties are required to report to the Secretariat by 31 January each year 

on progress made in transition to CFC-free MDIs. In 2011, progress reports about progress 

made with implementation of national transition strategies were received within essential use 

nominations. 

Article 5 countries that develop their own national transition strategy should provide it to the 

Secretariat, to be posted on its website, and then report each year on progress in transition, in 

accordance with Decisions XX/3 and XII/2. 

3.7 Global Database in Response to Decision XIV/5 

Under Decision XIV/5, all Parties are requested to submit information on CFC and CFC-free 

alternatives to the Secretariat by 28 February each year. In 2011, a report was received from 

Canada8

. Canada reported that it imported about 5.57 million DPIs, 2,500 CFC MDIs and 9.2 

million HFC MDIs in 2010 from either the United Kingdom or the United States. The source 

of the small number of imported CFC MDIs is not clear from the information provided but 

might indicate minor cross-border movement of redundant technology. 

Twenty-two Article 5 countries have submitted data pursuant to Decision XIV/5 since its 

inception, but much of the data is up to 10 years old and no longer relevant to today’s 

markets. These Parties are Argentina, Belize, Bosnia and Herzegovina, Brazil, China, Costa 

Rica, Croatia, Cuba, Eritrea, Georgia, Guyana, India, Indonesia, Jamaica, Malaysia, 

Mauritius, Namibia, Oman, Singapore, South Africa, Sri Lanka, and Uruguay. The Ozone 

Secretariat agreed to send a letter in 2010 to remind Parties of their obligation to report 

annually under Decision XIV/5. However, other than Canada, no other Party provided its 

annual update. 

It is important that Article 5 countries collect their own data on CFC and CFC-free inhaler use 

annually and provide it to the Secretariat by 28 February each year, to be posted on its 

website, in accordance with Decision XIV/5. Decision XII/2(3) also requests Parties, 

including Article 5 countries, to notify the Ozone Secretariat of any MDI products determined 

to be non-essential, and for nominating Parties to take this information into consideration. 

The Ozone Secretariat website only has information for the European Community. 

Collection of such data would aid in the development and implementation of effective 

transition plans within each country and in the determination of any essential use nominations 

for Article 5 countries. 

Parties may wish to recall Decision XII/2(3) to notify the Ozone Secretariat of any MDI 

products determined to be non-essential. 

 

7 http://ozone.unep.org/Assessment_Panels/TEAP/Reports/MTOC/MTOC-Assessment-Report-2010.pdf 

8 http://ozone.unep.org/Exemption_Information/Essential_Use_Nominations/index.shtml 
TEAP May 2011 Progress Report 43

3.8 Export Manufacturing Transition Plans in Response to 

Decision XVIII/16 

Decision XVIII/16(7) requests: 

“...each Party receiving essential-use exemptions for the production or import of 

chlorofluorocarbons to manufacture metered-dose inhalers for export to Parties 

operating under paragraph 1 of Article 5 to submit to each importing Party a detailed 

export manufacturing transition plan for each manufacturer where the exports of an 

active ingredient to that Party exceed 10 metric tonnes, specifying the actions that each 

manufacturer is taking and will take to transition its exports to chlorofluorocarbon-free 

metered-dose inhalers as expeditiously as possible in a manner that does not put 

patients at risk;” 

Paragraph 10 of that Decision requests each Party to submit a report summarising the export 

manufacturing transition plans as part of the Party’s essential use nomination, and paragraph 

11 requests the TEAP to consider such reports in its assessments of essential use nominations. 

No export manufacturing transition plan has been submitted under this Decision because the 

threshold has not been exceeded (10 metric tonnes of CFCs for an active ingredient for 

exports to a Party). 

TEAP May 2011 Progress Report 45

4 Chemicals Technical Options Committee (CTOC) Progress 

Report 

4.1 Executive Summary 

The CTOC met on March 1-3, 2011 in Bangkok, Thailand. The agenda of the meeting covered issues 

requested by the Parties, including process agents, laboratory and analytical uses, CTC issues and 

destruction technologies, in addition to two essential uses nominations; one from the Russian 

Federation on CFC-113 for aerospace industries and the other from Jordan on bromochloromethane 

(BCM) for polymeric flame retardants. 

Process Agents 

The Table A in decision XXII/8 contains 41 ODS uses registered as process agents. Based on 

information provided by the Parties through the Ozone Secretariat, and the report of the status on 

process agent applications in Article 5 Parties submitted by the Executive Committee under decision 

XXI/3(5), the CTOC recommends removing 27 process agent uses from the Table A, which are no 

longer operational. (See Table 4-1) Table 4-1 also involves a list of parties operating process agent 

uses according to the request under decision XXII/8(4). 

Table 4-2 summarises the status of ODS emissions from process agent uses in Table B of decision 

X/14 based on the information submitted from EC, USA, Switzerland, Israel and China to the Ozone 

Secretariat under decision X/14(4). Ninety three parties so far confirmed that they do not have process 

agent uses. 

Information about process agent uses was derived from the report of the MLF ExCom in response to 

Decision XXI/3. 

Laboratory and Analytical Uses 

Decision XXI/6 requested the TEAP/CTOC to complete the report as requested under decision 

XIX/18 and to provide it for the OEWG-30, by following the preliminary report prepared in 2010 and 

substantial information provided in 2009. 

The 2009 CTOC Progress Report provided an extensive list of laboratory and analytical procedures 

for which it believes that alternatives to the use of ODS are available, and the list is still effective and 

was included in the prologue of Decision XXI/6. 

It was noted in the 2010 Progress report that there were biomedical procedures in which small 

quantities of CTC had long been used as a toxicant, and also noted that biomedical research material 

is routinely destroyed by incineration and so CTC used in such procedures was unlikely to be emitted. 

However, Macedonia was advised about CTC use in analytical procedures to remove lipids that might 

interfere with the assay from other laboratories that alternative (non-ODS) solvents could be used and 

that commercial analytical kits that avoided the use of CTC were available. As is often the case with 

other uses of CTC in analytical work, the use of an alternative requires parallel investigations to 

ensure comparability, and (in the case of the kits) adoption of more expensive methods. 

With the assistance of the Ozone Secretariat, the CTOC has made contact with two major standardsetting bodies, ASTM International and the European Standards organisation (CEN), with a view to 

stimulating the preparation of standard methods not involving ODS. CTOC noted that ASTM 

International has the matter of non-ODS alternatives under investigation and is providing copies of 

standard methods to a CTOC co-chair so that alternative methods can be considered. The CTOC 

continues to work with the organizations with a view to developing a list of procedures for which 

agreement could be reached that some new standards were necessary. 
46 TEAP May 2011 Progress Report

If preparation of a handbook on laboratory and analytical uses were to be commissioned it would 

assist countries to make appropriate choices and so prove to be of great value. Parties may wish to 

allocate funding for the preparation of such a handbook. Meanwhile, Parties may wish to require 

reporting of the quantities of any ODSs so used in Article 5 Parties, as suggested above, so that 

assistance can be provided to those with the greatest need. 

The reasons that non-ODS methods are not adopted in Article 5 Parties are: (a) adherence to standard 

methods for which there are no non-ODS alternatives, and (b) the cost of implementing new methods, 

including training. Only in the few cases where an international standard exists and there is no nonODS alternative should it be necessary to persist with the use of ODS. The CTOC also advises that 

costs of transition should be sustainable, although the cost of alternative substances may be higher 

than those of the ODS they replace. 

EUE of CFC-113 for Aerospace Industries by the Russian Federation 

The Russian Federation submitted a new request for Essential Use Exemptions of 100 metric tonnes 

of CFC-113 for manufacturing the missile and space equipments in the year 2012, to the Ozone 

Secretariat on January 25, 2011. 

The required amounts of CFC-113 are 20 metric tonnes higher than the forecasted 80 metric tonnes as 

was seen in the TEAP May 2010 Progress Report. The CTOC asked the Russian Federation why it is 

necessary to maintain the consumption of CFC-113 at a level of 100 metric tons for the period 2012 – 

2013 in spite of the continuing efforts to reduce the use of CFC-113. The CTOC noted that there are 

objective reasons to expand the Russian national space program before 2015 in terms of reliability and 

failure-free performance of the Russian space equipment and hardware. The Russian space industry 

has authorized the increase of the number of manned missions to ensure safe and reliable operation of 

the International Space Station (ISS) and to provide support for the Global Navigation Satellite 

System GLONASS in addition to the unexpected launch failure of satellites. (e.g. 

http://www.insidegnss.com/node/2464) 

The CTOC acknowledged the research development of the Russian Federation to reduce essential use 

of CFC-113, but the comparison of the research results reported in this nomination with those 

reported in 2010 shows rather slow progress in developing appropriate alternatives to CFC-113. The 

CTOC recommends acceleration. 

After substantial review and discussion, the CTOC recommends the Essential Use Exemptions for 

100 metric tonnes of CFC-113 in 2012 for the Russian Federation. 

EUE of Bromochloromethane (BCM) as a Solvent for Polymeric Fire Retardants by Jordan 

Jordan has submitted an Essential Use Nomination for the use of bromochloromethane (BCM) as a 

solvent in the bromination of polystyrene to produce brominated polystyrene which is advantageously 

used as a polymeric flame retardant. It facilitates recycling and reprocessing of plastics such as highimpact polystyrene and acrylonitrile-butadiene-styrene resins containing this flame retardant. The 

special efficacy of BCM as a reaction solvent has been claimed in several patent applications. But 

investigation of any possible solvents is continuing and alternatives could be adopted if found 

suitable. 

The information provided by Jordan covers the essential nature of the use, both as to the desirability 

of producing brominated polystyrene and need for BCM as a solvent. The details of the process are 

presented, from which it is clear that much of the BCM is recycled and that emission controls will be 

in place. 
TEAP May 2011 Progress Report 47

However, in view of the existence of other methods for the production of brominated polystyrene, the 

CTOC is unable to recommend the Essential Use Exemption by Jordan for the use of 

bromochloromethane in producing brominated polystyrene. 

Solvents and Update of n-PB 

The elimination of HCFC and high GWP-HFC solvents still leaves many options available and they 

have found various levels of acceptance. However, no single option seems well suited to replace 

HCFCs and HFCs completely. HFEs with low or moderate GWP are expected as one of the options to 

replace high-GWP HFC solvents, even though HFEs are mostly expensive solvents. Their growth 

may be high when expressed by percentage, but quantities per chemical and in total are expected to 

remain relatively small. 

Decision XIII/7 has requested the TEAP to report annually on n-PB use and emissions (para3) 

together with requests to Parties to inform industry and users about the concerns the use and 

emissions of n-PB and the potential threat that these might be pose to the ozone layer (para 1) and to 

urge industry and users to consider limiting the use of n-PB to applications where more economically 

feasible and environmentally friendly alternatives are not available, and to urge them also to take 

care to minimize exposure and emissions during use and disposal (para2). Only limited action has 

been taken so Parties may wish to reconsider the practicality of the request to the TEAP under 

Decision XIII/7. 

Carbon Tetrachloride (CTC) Emissions and Opportunities for Reduction 

The discrepancy between ‘bottom up’ estimates and ‘top down’ estimates has been left unsolved in 

spite of year-by-year reconsideration of possible emissions from industrial and natural sources of CTC 

and the revision of its atmospheric lifetime by the Scientific Assessment Panel (SAP). 

Some data was added from EC PRTR (Pollution Release and Transfer Release) last year indicating 

previously unreported emissions of CTC from industrial facilities. The quantities revealed by the EC 

study cannot explain the current discrepancy, but do suggest that further work in other jurisdictions 

could reveal sources not reporting to the Ozone Secretariat. 

It is likely that chemical manufacture using CTC as a feedstock would also result in accounting for 

CTC emissions. As noted in Chapter 7 of this report, better information will be needed and Parties 

may wish to consider requiring more thorough reporting of feedstock uses of CTC and the emissions 

there from. 

The MLF ExCom produced a separate report on CTC emissions as part of its report under decision 

XXI/3 on process agent uses. 

Feedstocks 

Common feedstock applications have been updated, but the quantities of emissions from those 

feedstock remain uncertain, because no reported global uses of ODS feedstock exist. 

In order to obtain the level of feedstock uses of ODS, and actual or estimated emissions arising from 

these uses, Parties may wish to consider requiring the reporting of all feedstock uses of 

ODS. Disclosure of confidential information can usually be avoided by aggregation at country level. 

Destruction Technologies 

The CTOC has reviewed proposals for new technologies using information provided by the 

proponents. In some cases the information was subject to commercial confidentiality. The CTOC 

prepared a preliminary report which was provided to the XXII/10 TEAP Task Force. 
48 TEAP May 2011 Progress Report

The destruction technologies for methyl bromide in the agricultural field are quite different from those 

of industrial products such as refrigerants. The CTOC believes that it is necessary to develop new 

criteria for the destruction technologies for methyl bromide, since the criteria in 1992 were established 

for ODS in industrial products and not for dispersed uses such as agricultural processes. 

There are a number of in-country projects to link recovery of ODS with destruction according to the 

following information from UNDP, and their progress is summarise din this CTOC report. 

4.2 Introduction 

The CTOC met on March 1-3, 2011 in the United Nations Conference Centre (UNESCAP) Bangkok, 

Thailand where the meeting was kindly hosted by Atul Bagai and Charuwan Tintukasiri of UNEP 

ROAP. Their extraordinary courtesy was highly appreciated. Eleven out of sixteen CTOC members 

participated in the meeting. Attending members were five from Article 5 Parties (two from China, and 

one each from India, Kuwait and Tanzania) and six from non-Article 5 Parties (two from Japan, and 

one each from Australia, the Netherlands, the Russian Federation, and the USA). 

The agenda of the meeting covered issues requested by the Parties, including process agents, 

laboratory and analytical uses, n-PB, CTC issues and destruction technologies. Furthermore, the 

CTOC reviewed two essential use nominations; one from the Russian Federation on solvent use of 

CFC-113 for aerospace industries for 2011, and the other from Jordan on solvent use of BCM for 

polymeric flame retardants. The CTOC also discussed and updated ODS feedstock uses. 

4.3 Process Agents 

The Parties have requested that TEAP undertake a periodic review of process agent uses in a variety 

of aspects, including revisions of Table A (a list of process agent uses) and Table B (make up and 

emissions of ODS as process agent uses) under the following decisions. 

- Decision XXII/8 has requested the TEAP to review progress made reducing process agent 

uses and to make any additional recommendations to parties on further actions to reduce uses 

and emissions of process agents starting in 2011 and every other year thereafter. 

- Decision XXI/3(5) has requested the TEAP and the Executive Committee of the Multilateral 

Fund to prepare a joint report on progress with phasing out process agent applications. 

- Decision XVII/6(6) has requested the TEAP and the Executive Committee to report to the 

Open-ended Working Group starting in 2007 and every other year thereafter on the progress 

made in reducing emissions of ODS process agent uses 

- Decision XVII/6(7) and XVII/6(8) have requested the TEAP to review the information 

submitted by Parties regarding ODS process agent uses and to report and make 

recommendations to the Parties at MOP-20 in 2008 and every other year thereafter, on 

process agent use exemptions to revise Table A of decision X/14, and to recommend any 

reductions to the make-up and maximum emissions with respect to Table B. 

4.3.1 Revision of Table A 

Based on information of process agent uses provided by Parties and also provided by the ExCom 

under the decision XXI/3, 27 process agent uses are no longer operational and can be removed from 

Table A (see annex 1). In Table 4-1 an overview is given of which Parties are still operating process 

agent uses according to the request under decision XXII/8(4). 
TEAP May 2011 Progress Report 49

Table 4-1: A revised Table A on process agent uses listing operating Parties 

Process Agent 

Application 

Substance Decision 

XXII/8 

No. 

Parties Recommend 

by CTOC 

removing 

from Table A 

Elimination of NCl3 in chlor-alkali production CTC 1 

 EU, 

Israel and 

US 

No 

Chlorine gas recovery by tail gas absorption in chloralkali production CTC 2 EU and 

US 

No 

Production of chlorinated rubber CTC 3 EU No 

Production of Endosulfan CTC 4 India Yes 

Production of chlorosulfonated polyolefin (CSM) CTC 5 China 

and US 

No 

Production Aramid polymer (PPTA) CTC 6 EU No 

Production of synthetic fibre sheet CFC-11 7 US No 

Production of chlorinated paraffin CTC 8 EU- Yes 

Photochemical synthesis of 

perfluoropolyetherpolyperoxide precursors of Zperfluoropolyethers and difunctional derivatives CFC-12 9 

EU No 

Preparation of perfluoropolyether diols with high 

functionality CFC-113 10 EU No 

Production of Cyclodime CTC 11 EU No 

Production of chlorinated polypropene CTC 12 China No 

Production of chlorinated ethylene vinyl acetate 

(CEVA) 

CTC 13 China No 

Production of methyl isocyanate derivatives CTC 14 China No 

Production of 3-phenoxy benzaldehyde CTC 15 China Yes 

Production of 2-chloro-5-methylpyridine CTC 16 China Yes 

Production of Imidacloprid CTC 17 China Yes 

Production of Buprofenzin CTC 18 China Yes 

Production of Oxadiazon CTC 19 China Yes 

Production of chloradized N-methylaniline CTC 20 China Yes 

Production of 1,3- dichlorobenzothiazole CTC 21 China Yes 

Bromination of a styrenic polymer BCM 22 US No 

Synthesis of 2,4-dichlorophenoxyacetic acid (2,4-D) CTC 23 US Yes 

Synthesis of di(-2-ethylhexyl) peroxidedicarbonate 

(DEHPC) CTC 24 US Yes 

Production of high modulus polyethylene fibre CFC-113 25 US No 

Production of vinyl chloride monomer CTC 26 US Yes 

Production of Sultamicillin BCM 27 - Yes 

Production of Prallethrin CTC 28 China Yes 

Production of o-nitrobenzaldehyde CTC 29 China Yes 

Production of 3-methyl-2-thiophenecarboxaldehyde CTC 30 China Yes 

Production of 2-thiophenecarboxaldehyde CTC 31 China Yes 

Production of 2-thiophene ethanol CTC 32 China Yes 

Production of 3,5-dinitrobenzoyl chloride (3,5-

DNBC) CTC 33 China Yes 

Production of 1,2-benzisothiazol-3-ketone CTC 34 China Yes 

Production of m-nitrobenzaldehyde CTC 35 China Yes 

Production of Tichlopidine CTC 36 China Yes 

Production of p-nitro benzyl alcohol CTC 37 China Yes 
50 TEAP May 2011 Progress Report

Process Agent 

Application 

Substance Decision 

XXII/8 

No. 

Parties Recommend 

by CTOC 

removing 

from Table A 

Production of Tolclofos methyl CTC 38 China Yes 

Production of polyvinylidene fluoride (PVdF) CTC 39 China Yes 

Production of tetrafluorobenzoylethyl acetate CTC 40 China Yes 

Production of 4-bromophenol CTC 41 China Yes 

In China, 47 production lines that have used CTC as a process agent are no longer in operation. 

(UNEP/OzL.Pro/ExCom/62/Inf.2/Rev.1 16 March 2011) Accordingly, 27 process agent uses can be deleted from 

Table A, leaving just 14 process agent uses approved by the Parties.

4.3.2 Revision of Table B 

To date, information of ODS emissions from process agent uses in Table B has been less than 

complete. Information of process agent applications from the Russian Federation and Israel are not 

known but use and emissions are included in Table B. A better standard of reporting of emissions 

needs to be achieved so that Table B gives a reliable picture of emissions arising from process agent 

uses. The reported data are summarized in Table 4-2. 

As of 1 March 2011, ninety three Parties have confirmed that they do not have process agent uses 

according to information provided by the Ozone Secretariat.a)

Table 4-2: A revised Table B (metric tonnes) 

Party Make up or 

consumption 

2009 

Maximum 

make up or 

consumption 

Emissions 

2009 

Maximum 

emissions 

European Union 669 1083 1.6 17 

United States of America No data 2300 47.1 181 

Russian Federation No data 800 No data 17 

Israel 2.4 3.5 0 0 

Brazil 0 2.2b 0 2.2b 

China 313 1103 No data 1103 

Total 982 5292 49 1320 

a) Afghanistan, Andorra, Argentina, Armenia, Australia, Austria, Bahamas, Bahrain, Bangladesh, Barbados, Belarus, Belize, Botswana, Bulgaria, Burkina Faso, 

Cambodia, Canada, Cape Verde, Chad, Comoros, Congo, Costa Rica, Croatia, Cuba, Cyprus, D.R. Congo, Dominican Republic, Egypt, Estonia, Finland, 

Ghana, Grenada, Guyana, Holy See, Hungary, Iran, Ireland, Italy, Jamaica, Japan, Kenya, Kiribati, Kyrgyz Republic, Lebanon, Lesotho, Liberia, Liechtenstein, 

Lithuania, Macedonia, Madagascar, Malaysia, Maldives, Malta, Mexico, Moldova, Monaco, Montenegro, Morocco, Myanmar, New Zealand, Niger, Nigeria, 

Oman, Pakistan, Panama, Papua New Guinea, Paraguay, Republic of Korea, Saint Lucia, Sao Tome & Principe, Senegal, Serbia, Singapore, Slovakia, Slovenia, 

Spain, Sri Lanka, Sri Lanka, St. Vincent & the Grenadines, Sweden, Switzerland, Syria, Tajikistan, Tanzania, Togo, Trinidad & Tobago, Turkey, Turkmenistan, 

Tuvalu, Uruguay, Uzbekistan, Vietnam and Zimbabwe. 

b)In accordance with decision 54/36 of the Executive Committee of the Multilateral Fund, the annual make-up or consumption and maximum emissions for 

Brazil will be 2.2 metric tonnes up to and including 2013 and zero thereafter 
TEAP May 2011 Progress Report 51

4.3.3 Alternatives to Process Agents 

Of the cases reviewed by the CTOC, especially those in which CTC is used as process agent, there are 

only a few in which the reasons for using CTC rather than an alternative are described in detail. It 

seems likely that no investigations of alternatives have been made, and that CTC is used because that 

was the solvent used in laboratory work that led to patents and industrial processes. Owing to the 

chemical engineering considerations of a plant’s design, once a process has begun operation, changing 

to an alternative solvent can be difficult. Therefore an established plant may well be solvent specific 

and changing the solvent may be difficult even from an economical point of view. 

4.3.4 Information on Pprocess Agents Uses in the European Union 

A new decision in the EU came into force on 18 June 2010 that allocated make up quantities for the 

eight facilities that have permitted process agent uses. 

Regarding CTC emissions in the EU, there are 16 facilities that reported CTC emissions (with a 

threshold of 100 kg) in 2008. A total of 63 metric tonnes was emitted, including the process agent use 

facilities that emitted CTC in 2008 as part of a total of 1.6 metric tonnes ODS (CTC and CFC-12, EU 

report on the use of ODS as process agent). (Ref. http://prtr.ec.europa.eu/PollutantReleases.aspx)

4.4 Laboratory and Analytical Uses 

This report completes the CTOC response to Decision XXI/6, following the preliminary report 

prepared in 2010 and substantial information provided in 2009. 

4.4.1 Analyses for which there are no Non-ODS Alternatives 

Clause 5(a) of Decision XXI/6 requested a list of laboratory and analytical uses of ODS including 

those uses where no alternatives exist. The case studies presented in the 2009 Progress Report showed 

that most laboratory and analytical uses of ODS in non-Article 5 Parties had ceased. There have been 

no changes to the extensive list of procedures in the 2009 Progress Report where alternatives were 

identified by the CTOC for almost all uses and this list was included in the prologue of Decision 

XXI/6. 

There are laboratory uses in both non-Article 5 and Article 5 Parties that are essentially consumptive 

in nature – in other words, uses in which the ODS takes part in a chemical reaction and is thereby 

transformed to non-ODS substance. Since no alternatives are available, these uses are likely to 

continue. There is a parallel with feedstock uses that take place on an industrial scale. The ODS most 

commonly used in these laboratory procedures are carbon tetrachloride (CTC) and methyl bromide. 

The CTOC has drawn attention to another laboratory use of CTC as a specialized solvent for reactions 

involving N-bromosuccinimide, and noted that despite some investigations by researchers, no 

alternative has been identified. 

In the 2010 report, the CTOC requested information from Article 5 Parties where procedures removed 

from the global exemption by the Parties in earlier decisions might still be in use, but no information 

was forthcoming. The intention of the request was to enable CTOC members to assist laboratories in 

such countries to identify and adopt alternatives. Some work of this kind has already been reported to 

the Parties and it has been found that contact through Ozone Officers is the appropriate way to make 

the necessary connections. 

It was noted in the 2010 Progress Report that there were biomedical procedures in which small 

quantities of CTC had long been used as a toxicant. Although the procedures are not formally 

designated as such, their longevity means that they are effectively ‘standard methods’. It was also 

noted that biomedical research material is routinely destroyed by incineration and so CTC used in 

such procedures was unlikely to be emitted. However, not all biomedical procedures are of this type. 

Macedonia advised about CTC use in analytical procedures to remove lipids that might interfere with 
52 TEAP May 2011 Progress Report

the assay. Advice was received from other laboratories that alternative (non-ODS) solvents could be 

used and that commercial analytical kits that avoided the use of CTC were available. Quality control 

is important in laboratories, taking in robustness of analytical methods, confirmation of positive 

results and avoidance of false positives. As is often the case with other uses of CTC in analytical 

work, the use of an alternative requires parallel investigations to ensure comparability, and (in the 

case of the kits) adoption of more expensive methods. 

4.4.2 National and International Standards 

Clause 5(b) of Decision XXI/6 requested the TEAP/CTOC to identify the international and national 

standards that require the use of ODS and to indicate the corresponding alternative standard methods 

not mandating the use of ODS. Considerable information about alternative methods has been provided 

in the last two Progress Reports. Alternative standard methods exist for a number of procedures, as 

detailed in the 2009 Progress Report. The analysis of oil, grease and petroleum hydrocarbons in water, 

soils and air by infrared spectroscopy is described in a number of standard methods designated by 

national and international bodies. The use of the non-ODS solvent S-316 to replace CTC and CFC113 used in older methods is specified in standard method ASTM D7066-04. As regards the use of 

butane to replace CTC in measurements of adsorptivity of activated carbon, the standard method 

ASTM D3467-04 (2009) specifies the use of CTC, but ASTM D5228-92 (2005) uses butane and 

ASTM D5742-95 (2005) provides a correlation between results obtained with CTC and with butane. 

ASTM methods are thoroughly tested before release and provide assurance to users that reliable 

results will be obtained. The correlation standard enables results obtained by the new standard method 

to be related to those obtained by the old method, so the historical record of results is preserved. 

With the assistance of the Ozone Secretariat (see Clause 4 of Decision XXI/6), the CTOC has made 

contact with two major standard-setting bodies, ASTM International and the European Standards 

organisation (CEN), with a view to stimulating the preparation of standard methods not involving 

ODS. In general, requests for the development of new standards come from users, although in the 

European case requests from the EC can also be received. ASTM International has the matter of nonODS alternatives under investigation, and is providing copies of Standard Methods to a CTOC cochair so that the uses of ODS can be appraised and alternatives suggested. The CTOC continues to 

work with the organizations with a view to developing a list of procedures for which agreement could 

be reached that some new standards were necessary. For example, as a result of CTOC investigations 

some alternatives have been shown to work well in analyses and new standard methods could be 

based on them. Examples are oil, grease and petroleum hydrocarbon determinations by infrared, 

iodometric titrations, and iodine and bromine index determinations. 

Clause 5(c) of Decision XXI/6 requests TEAP/CTOC to consider the technical and economical 

availability of those alternatives in Article-5 and non-Article-5 parties as well as to ensure that the 

alternative methods show similar or better statistical properties (for example accuracy or detection 

limits). Standard methods, often termed ‘norms’, are in place in a number of countries and since these 

are legislated on a national basis, alternatives can be devised and implemented without the need for 

international standard-setting bodies to be involved. This was the subject of the request to all Parties 

in Clause 3 of decision XXI/6, to urge their national standards-setting organisations to identify and 

review those standards which mandate the sue of ODS in laboratory and analytical procedures with a 

view to adopting, where possible, ODS-free laboratory and analytical products and processes. The 

task of gathering information globally is beyond the resources of advisory committees, but the 

TEAP/CTOC would be able to provide better advice to the Parties if Parties had this information. It is 

noted that Clause 7 of Decision XXI/6 allowed Article 5 Parties to deviate from the existing 

laboratory and analytical use bans in individual cases, where a Party considers this justified by 31 

December 2010. 
TEAP May 2011 Progress Report 53

4.4.3 Reporting to the Ozone Secretariat 

Clause 9 of Decision XXI/6 requested Parties to continue to investigate domestically the possibility of 

replacing ODS in those laboratory and analytical uses listed in the report by the TEAP and to make 

this information available to the Ozone Secretariat by 30 April 2010. Only three reports were received 

- those of the European Commission (EC), Australia and Lithuania. 

In 2009 the EC authorised (nationally allocated) the use of 190 ODP tonnes of ODS for laboratory 

and analytical purposes but only 59 tonnes was actually authorised for use, mostly CTC (35.8 ODP 

tonnes) and CFCs (23.2 ODP tonnes) (52.8 and 47.1 metric tonnes, respectively). The figures include 

some ODS that was exported for laboratory and analytical uses and so overstates actual consumption 

in the European Union. The EC provided information about a number of standard methods and 

alternatives, and suggested that the CTOC should determine the applicability of the latter. The EC 

drew attention to the fact that methods formerly used in non-Article 5 Parties may still be in use, or 

being considered for introduction, in Article 5 Parties, and so should be included in the compilation. 

The task suggested for the CTOC, amounting to the production of a laboratory and analytical uses 

handbook, is beyond the capacity of the CTOC. However, if preparation of such a handbook were to 

be commissioned it would assist countries to make appropriate choices and so prove to be of great 

value. Parties may wish to allocate funding for the preparation of such a handbook. The EC report was 

of great value and Parties may therefore wish to consider requiring reports from all Parties, say every 

few years, that include quantities of ODS used in laboratory and analytical procedures, the ODS 

procedures that are followed, the alternatives under consideration, and the time to phase-out. 

Australia reported that CTC had been imported from Europe in 2008 for use as a specialty solvent in 

reactions involving N-bromosuccinimide, a use to which the CTOC has previously drawn attention as 

one for which no alternative has yet been found. Australia reported on-going experiments with 

alternatives. Bromochloromethane was also imported for a consumptive use, preparation of acetals, 

which has also been identified in earlier CTOC reports. Trials have been conducted with non-ODS 

reagents but none has proved satisfactory. 

Lithuania provided a very detailed report. Information about laboratory and analytical uses of ODS 

had been sought from stakeholders, including the national standardisation body. They had also been 

provided with information from the TEAP. The Lithuanian Ministry of Environment reported that ‘the 

results of the recently undertaken survey poorly reflect the situation in industry. In our opinion, the 

Lithuanian industry might use ODS to perform some analyses mentioned in the TEAP report, but the 

industry showed disinterest and lukewarmly participated in the survey’. It was noted that that use of 

ODS for analysing hydrocarbons (oil and grease) in water has been banned in Lithuania already for 

several years. This has caused problems for industries where hydrocarbon analysis is required, but 

alternative methods not involving ODS are required by Lithuanian law. ODS, probably not exceeding 

a few hundred grams a year in any one case, are still used in a number of other analyses for which the 

TEAP has identified non-ODS alternatives, as well as some other procedures for which alternatives 

need to be sought and some such as calibrations and consumptive sues for which no alternatives exist. 

Lithuanian use of ODS is governed by European Council and Parliament Regulation (EB) 1005/2009, 

covering a range of ODS. 

The CTOC is aware of another questionnaire, sent to countries in the Arabian Gulf Region, which did 

not elicit information from possible users of ODS. The reasons for the poor response are not known, 

but could include those identified by Lithuania, namely, no use of ODS or reluctance to move to new 

methods. Many laboratories have been unwilling to replace standard methods (either international or 

local standards) with other methods because they are not able to guarantee the accuracy of such 

analyses without doing some comparisons of old and new methods, which takes time and costs 

money. This accounts for a good deal of the inertia in the laboratory analytical sector. Even when 

new standards are developed, nationally or internationally, each user laboratory will want to conduct 

trials before confirming adoption of the new methods. An additional consideration is that, when only 
54 TEAP May 2011 Progress Report

small quantities of ODS are involved, which is often the case, they are subsumed in Basic Domestic 

Needs and do not receive scrutiny from officers acting at national level. 

The CTOC will continue to work with UNEP and the Ozone Officers as instructed by Parties in 

Decision XXI/6(9), but if Parties wish to accelerate the phase-out of laboratory and analytical uses of 

ODS they may wish to require reporting of the quantities of any ODSs so used in Article 5 countries, 

as suggested above, so that assistance can be provided to those with the greatest need. 

4.4.4 Possible Exemptions 

Clause 6 of Decision XXI/6 requests TEAP while continuing in its work as described in paragraph 5, 

to evaluate the availability of alternatives for those uses already banned under the global exemption 

in Parties operating under Article 5(1), considering technical and economic aspects... (and) ...

present its findings and recommendations whether exemptions would be required for parties 

operating under Article 5(1) for any of the uses already banned. It will be evident from the earlier 

sections of this report that the reasons that non-ODS methods are not adopted in Article 5 countries 

are: (a) adherence to standard methods for which there are no non-ODS alternatives, and (b) the cost 

of implementing new methods, including training. As to the first of these, where purely national 

standards are involved, then it is within the power and capability (since skilled staff exist and methods 

are available in the scientific literature) of countries to adopt the necessary procedures. Only in the 

few cases where an international standard exists and there is no non-ODS alternative should it be 

necessary to persist with the use of ODS. In the second instance, The CTOC advises that costs of 

transition should be sustainable, although the cost of alternative substances may be higher than those 

of the ODS they replace. As suggested above, Parties may wish to require reporting of time horizons 

for the phase-out of ODS in laboratory and analytical procedures. 

4.5 Reviews of Essential Use Nominations 

4.5.1 Essential Use Nomination of CFC-113 for Aerospace Industries by the 

Russian Federation 

4.5.1.1 Introduction 

Decision XXI/5 in MOP-22 approved an essential use exemption of 100 metric tonnes of CFC-113 in 

2011 for applications in the missile and aerospace industries in the Russian Federation, taking into 

consideration the TEAP/CTOC findings that no appropriate alternatives to CFC-113 currently exists 

for its use in the aerospace industries in the Russian Federation and that the search for its alternatives 

continues, as confirmed in the TEAP May 2010 Progress Report Vol.2 (p57-59) 

On 25 January 2011, The Ministry of National Resources and Environment of the Russian Federation 

sent a new request for Essential Use Exemptions of 100 metric tonnes of CFC-113 for manufacturing 

the missile and space equipments in the year 2012 to the Ozone Secretariat. 

4.5.1.2 The CTOC Comments on EUE of CFC-113 in 2012 by the Russian Federation 

The Russian Federation had been successful in reducing the annual consumption of CFC-113 in the 

missile and space industry from 241 metric tonnes in 2001 to 100 metric tonnes in 2010 as shown in 

the Illustration 2 (TEAP May 2010 Progress Report Vol.2, p59). However, the Russian industry has 

found no solvents comparable to CFC-113 from viewpoints of cleaning efficiency, versatility and 

compatibility with structural materials. 

The new request by the Russian Federation for an Essential Use Exemption for 100 metric tonnes of 

CFC-113 in the year 2012, which is 20 metric tonnes higher than that forecasted in the TEAP May 

2010 Progress Report, describes and explains in detail why this application is urgent for health and 

safety or vital for society; what efforts have been made to investigate currently available alternatives, 

and why they are insufficient or unsuitable for the purpose; and also efforts to minimize the emissions 
TEAP May 2011 Progress Report 55

of CFC-113. The CTOC asked the Russian Federation why it is necessary to maintain the 

consumption of CFC-113 at a level of 100 metric tonnes for the period 2012 – 2013 in spite of the 

continuing efforts to reduce the use of CFC-113. The CTOC noted that there are objective reasons to 

expand the Russian national space program before 2015 in terms of reliability and failure-free 

performance of the Russian space equipment and hardware. The Russian space industry has to 

increase the number of manned missions to ensure safe and reliable operation of the International 

Space Station (ISS) and to provide support for the Global Navigation Satellite System GLONASS in 

addition to the unexpected launch failure of satellites. (e.g. http://www.insidegnss.com/node/2464) 

Unique physicochemical properties, high processing and operational characteristics of CFC-113 

ensure the required cleanliness levels of parts and assembly units, high tightness levels of the missile 

and space equipment. Faultless and reliable operation in those applications, and consequently, the life 

and health of spacecraft crews, personnel and communities in the launching area depend on proper 

selection of the cleaning solvent for those parts and equipment. In particular, failures of gyro 

instruments of the launch vehicle or space vehicle control system can lead to fatal situations and 

insufficient liquid-propellant rocket systems, which use liquid oxygen as an oxidizer, can result 

explosions during launching. 

So far, tested candidates of solvents for replacement of CFC-113 have covered ozone-safe organic 

solvents, chlorocarbons solvents, aqueous detergents, transitional HCFC solvents (HCFC-122, HCFC122a, HCFC-141b and HCFC-225) and fluorocarbons. However, none of these candidates could meet 

the requirements for the replacement of CFC-113. 

In order to minimize emissions of CFC-113, recirculation and stock accumulation have been 

attempted, however the recycled and accumulated stock of CFC-113 is not available in sufficient 

quality for the expected application. Also, due to ultra-high requirements for the content of the main 

product, the recycled application of CFC-113 is limited. 

The Russian new nomination satisfies, in principle, the following criteria to qualify as “Essential” 

under the decision IV/25. 

1. It is necessary for the health, safety or critical for the functioning of the society. 

2. There are no available technically and economically feasible alternatives or substitutes that 

are acceptable from the standpoint of environment and health. 

3. An action has been attempted to minimize emission of CFC-113. 

4.5.1.3 Conclusions 

The CTOC acknowledged the research development of Russian Federation to reduce essential use of 

CFC-113, but the comparison of the research results reported in this nomination with those reported in 

2010 shows rather slow progress in developing appropriate alternatives to CFC-113. The new 

proposed schedule of CFC-113 essential usage by the Russian Federation shows a significant delay in 

reducing CFC-113. The previous future schedule shown in TEAP May 2010 Progress Report Vol.2, 

page 59 forecasted the usage at 80 metric tonnes in 2012, 50 metric tonnes in 2013 and 35 metric 

tonnes in 2014 respectively, and the revised future schedule shown in figure 5-1 seems to be delayed 

by at least 2 years. 

The CTOC recommends the acceleration of efforts to introduce appropriate alternatives, to investigate 

materials incompatible with alternatives, and the adoption of newly designed equipment to complete 

the phase-out of CFC-113 within an accelerated time schedule. Parties that are partners or customers 

of Russian space projects may wish to consider the advantage of cooperation in implementing ozonesafe alternatives. 

After substantial review and discussion, the CTOC recommends the Essential Use Exemptions for 

100 metric tonnes of CFC-113 in 2012 for the Russian Federation. 
56 TEAP May 2011 Progress Report

Figure 4-1: The Phase-out Schedule given by the Russian Federation 

4.5.2 Essential Use Nomination of solvent use of BCM for polymeric flame 

retardants by Jordan 

4.5.2.1 Introduction 

Jordan has submitted an Essential Use Nomination for the use of bromochloromethane (BCM) as a 

solvent in the bromination of polystyrene to produce brominated polystyrene which is marketed as a 

flame retardant. Use by the Jordan Bromine Company Limited, a joint venture between Jordan’s Arab 

Potash Company and Albemarle Holdings Company Limited (USA), is proposed to commence in 

2013. BCM has solvent properties that make it especially suitable for this use, and is largely 

recovered after use, so had the process been started prior to 30 June 1999 then this application would 

have been made for Process Agent status. Use of BCM for such a chemical reaction in the US has 

been accorded Process Agent Status (see #22 in Table A of Decision XXII/8). 

Jordan provided information in response to the questions in the form provided for submission of 

Essential Use Nominations. 

4.5.2.2 Essentiality 

The ‘gateway’ question is ‘why is this use necessary for the health and/or safety or critical for the 

functioning society?’, in response to which the following information was provided. Brominated 

flame retardants save lives by increasing the fire safety of products and materials. The costs 

associated with loss of human life and property damage due to fires are staggering. In the United 

States alone, fires kill more than 3,000 people (52% of them children under the age of 5) each year 

and injure more than 20,000, with property damage exceeding $11 million annually. In the absence of 

flame retarded materials, these figures would likely be significantly higher. However, despite the 

benefits of flame retardants, many types of small-molecule flame retardants have been voluntarily 

withdrawn or banned (notably under the Stockholm Convention) because of concerns over 

bioaccumulation and potential harm to human health or the environment. Other current smallmolecule flame retardants are under scrutiny and could also be banned. Therefore, replacement 

molecules that are equally effective at meeting regulatory fire safety requirements, but that lack the 

human health and environmental concerns are desperately needed. Polymeric flame retardants have 

these attributes and have been widely accepted by regulatory agencies. The brominated polystyrene 

prepared by bromination in BCM has superior properties, including low levels of impurities, high 

bromine content (bromine being the active element in fire suppression) and good thermal stability, 

which facilitates recycling and reprocessing of plastics such as high-impact polystyrene and 
TEAP May 2011 Progress Report 57

acrylonitrile-butadiene-styrene resins containing this flame retardant with less waste and fewer 

emissions. 

4.5.2.3 Alternatives 

The claims for special efficacy of BCM as reaction solvent are contained in several US patents held 

by the Albemarle Company (especially US 5,767,203 and US 5,916,978). Alternative solvents that 

have been investigated include dichloromethane, dibromomethane, 1,2-dichloroethane, 1,2-

dibromoethane and even elemental bromine. None produces brominated polystyrene with properties 

approaching that formed in BCM. Aromatic, olefinic, protic and basic solvents are unsuitable because 

they are attacked by bromine, aluminium chloride (catalyst in the bromination reaction) or HBr (by 

product). Alkanes, ethers and fluorocarbons do not possess sufficient solvent power for this reaction. 

Investigations into possible solvents are continuing and alternatives could be adopted if found 

suitable. 

4.5.2.4 Minimizing Use and Emissions 

Most of the BCM solvent is recovered after the reaction and, after purification, is reused. New 

material is sourced from the United States. A code of Good Housekeeping (Manufacture) is to be 

followed, and Jordan provided information on the following aspects: pre-delivery, arrival at facility, 

unloading, testing and verification, storage and stock control, quantity measurement, facility design, 

maintenance, quality control and quality assurance, training and control equipment. 

4.5.2.5 Quantity 

Since this is a new industry, the following annual figures are estimates based on the operation of other 

facilities working at this scale. In 2013 the usage (= makeup) figure would be 62Mt, but as production 

of brominated polystyrene grows from 20,000 Mt to 40,000 Mt over five years, this would increase to 

132 Mt made up as follows: 

Operation BCM Mt (tonnes) 

Emissions – point source (8), fugitive (12) 20 

Remaining in spent carbon 2 

Decomposed (conversion to CH2Br2) 30 

Solvent in final product 80 

Total 132 

Two entries in the table merit further comment. Air emissions throughout the process are controlled 

by best-available technology and equipment, including regenerative carbon beds, liquid scrubbers and 

chilled condensers (note that the boiling point of BCM is 68o

C). At end-of-life, when carbon beds 

need to be replaced, they retain small amounts of BCM which is destroyed when the carbon is 

incinerated. The second comment concerns an unusual feature of this reaction, the conversion of a 

small proportion of the solvent, through replacement of chlorine with bromine, to dibromomethane 

(CH2Br2) which is recovered and sold. It is not a controlled substance under the Montreal Protocol. 

4.5.2.6 Conclusions 

The information provided by Jordan covers the essential nature of the use, both as to the desirability 

of producing brominated polystyrene and need for BCM as solvent. The details of the process are 

presented, from which it is clear that much of the BCM is recycled and that emission controls will be 

in place. 

Jordan has given no indication of the time for which this EUE will be necessary but the submission 

envisages the period 2013-2018. 
58 TEAP May 2011 Progress Report

With the banning of small-molecule brominated flame retardants under the Stockholm Convention, 

there is increased interest in the use of polymeric flame retardants. A recent announcement from Dow 

Chemical tells commercial interests in their newly-invented brominated polymer which is not, 

according to commercial sources, brominated polystyrene. 

The case for an Essential Use Exemption for the used of BCM by Jordan rests on the importance of 

the proposed product, brominated polystyrene, to the fire protection industry. This compound is 

produced by two other manufacturers, Albemarle (using BCM under a Process Agent exemption) and 

Israel Chemicals Limited (ICL). The process used by ICL is confidential but the company has 

notified the CTOC that BCM is not used. Searches of the literature have disclosed methods using 

chlorinated solvents such as methylene chloride or 1,2-dichloroethane, or excess bromine. 

Given the existence of these alternatives, the CTOC is unable to recommend the Essential Use 

Exemption by Jordan for the use of bromochloromethane in producing brominated polystyrene. 

4.6 Solvents and Update of n-PB 

4.6.1 Solvent Update 

As stated in the 2010 CTOC Assessment Report (Chapter 4. Solvents, pp13-16), most of the ODS 

solvents had been replaced by not-in-kind technologies and some in-kind alternatives have been 

introduced advantageously in precision and electronics cleaning. 

Among the in-kind alternatives, HCFC-141b has been conveniently used in Article 5 countries and its 

use in small and medium-size customers will be expected to be replaced by not-in-kind alternatives 

such as chlorocarbons and hydrocarbons. Sizable amounts of HCFC-225 solvent have been used in 

niche applications including military and aerospace industries where no other alternatives are 

available in non-Article 5 Parties. The other in-kind alternatives in solvent applications include some 

HFC and HFE (hydrofluoroethers), which are expensive and their uses are mostly limited in nonArticle 5 Parties. 

The elimination of these HCFC and high GWP-HFC solvents still leaves many options available and 

they have found various levels of acceptance. However, no single option seems well suited to replace 

HCFCs and HFCs completely. HFEs with low or moderate GWP are expected as one of the options to 

replace high-GWP HFC solvents, even though HFEs are mostly expensive solvents. Their growth 

may be high when it is expressed by percentage, but quantities per chemical and in total are expected 

to remain relatively small. 

Some new HFE solvents have been introduced in the non-Article 5 market and are summarised in 

Table 4-3. 
TEAP May 2011 Progress Report 59

Table 4-3: HFE solvents recently commercialized 

Code Number HFE-64-13S1 HFE-77-12 HFE-347pc-f2 

Product Name Novec 7300 Novec 7600 AE-3000 

Chemical Structure C6F13OCH3 C3HF6CH(CH3)OC3HF6 CF3CH2OCF2CHF2

Boiling Point () 98 131 56 

KB value 5 9.5 13 

Flammability Non-flammable Non flammable Non flammable 

GWP (100yrs) 210 700 580 

Atmospheric 

Lifetime (yrs) 

3.8 9 7.1 

Furthermore, unsaturated fluorochemicals with zero ODP and ultra lower GWP are said to be under 

development for the replacement of high GWP-HFC and low or moderate GWP HFE solvents. 

4.6.2 n-Propyl Bromide (n-PB) Update 

The CTOC reported repeatedly the difficulties of obtaining complete and accurate data on production 

and uses of n-PB because n-PB is not classified or registered as a controlled substance nor registered 

as a hazardous air pollutant. Responding to this issue, one representative commented in the 30-OEWG 

(UNEP/OzL.Pro.WE1/30/7, para29) that from January 1, 2010 n-PB had to be reported under the new 

European Union Regulation on ozone-depleting substances. The CTOC noticed a new registration of 

n-PB for REACH (EC No. 203-45-0), but it has not been successful in obtaining production and 

consumption data from the REACH Inventory. 

On the other hand, the SAP reported nothing new for the behavior of n-PB as a very short-lived 

substance but a calculation of its lifetime as 41 days instead of formerly reported 34 days (2010 SAP 

Assessment Report, Table 1-4, pp38). 

Decision XIII/7 has requested the TEAP to report annually on n-PB use and emissions (para3) 

together with requests to Parties to inform industry and users about the concerns on the use and 

emissions of n-PB and the potential threat that these might pose to the ozone layer (para1) and to 

urge industry and users to consider limiting the use of n-PB to applications where more economically 

feasible and environmentally friendly alternatives are not available, and to urge them also to take 

care to minimize exposure and emissions during use and disposal (para2). Action has been taken on 

the latter part of para2, for example, the approval of n-PB for selected applications as a substitute for 

CFC-113 and methyl chloroform in metals, electronics and precision cleaning under the SNAP in US 

EPA as well as its registration under the REACH in EU. 

Having considered the current status, Parties may wish to reconsider the practicality of the request to 

TEAP under Decision XIII/7. 

4.7 Carbon Tetrachloride (CTC) Emissions and Opportunities for 

Reduction 

For some years now the CTOC and TEAP members have attempted to reconcile differences between 

the estimates of emissions of carbon tetrachloride (CTC; CCl4) provided by consideration of known or 

estimated usage of this chemical and the associated emissions (‘bottom up’ estimates), and estimates 

derived from the observed stratospheric concentrations of CTC and the lifetime calculated by the 

Science Assessment Panel (‘top down’ estimates). 
60 TEAP May 2011 Progress Report

Both estimates were subject to reconsideration. After consideration of bulk uses of CTC, no evidence 

of substantial sources for release of CTC from natural sources such as oceans and volcanoes, and from 

pollutant releases from landfills, drinking water disinfection and contaminated groundwater was 

found. We were left to conclude that, if releases were indeed much greater than our ‘bottom up’ 

estimates, then there must be other – and quite substantial – sources of CTC emissions. These could 

be production and consumption that had not been reported to the Ozone Secretariat, but discussions 

with Parties suggested that there were no such sources, at least on the scale required to ‘balance the 

books’. 

As for the ‘top down’ estimates, attention was focused on the atmospheric lifetime ascribed to CTC. If 

this were substantially longer than the accepted figure of about 28 years, and perhaps as long as 44 

years as was sometimes suggested, then smaller emissions would suffice to maintain the observed 

stratospheric concentration and the difference in estimates would be within the limits of error for such 

estimation techniques. The Science Assessment Panel addressed this issue in their 2010 Assessment 

Report, noting that ‘Although the size of this discrepancy is sensitive to uncertainties in our 

knowledge of how long CCl4 persists in the atmosphere (its “lifetime”), the variability cannot be 

explained by lifetime uncertainties. Errors in reporting, errors in the analysis of reported data, and/or 

unknown sources are likely responsible for the year-to-year discrepancies’. The SAP (in its 2010 

Assessment Report in section 1.2.1.3, Box 1-2 and Fig 1-5) gave consideration to lifetimes in the 

range 23-33 years and summarised the attempts to reconcile the estimates. 

During the last year some data from the EC Pollution Release and Transfer Register, indicating 

previously unreported emissions of CTC from industrial facilities, has added new information that 

needs to be taken in to account. In 2008 the releases to air totaled 62.63 tonnes, mostly from industrial 

scale production of basic organic chemicals in France, Netherlands and UK. Releases to water totaled 

less than 1 tonne. While the largest emitters were organic chemical producers and urban waste-water 

treatment plants, there were significant amounts from production of inorganic chemicals, fertilizers 

and biocides and from disposal of hazardous wastes. Some of these industrial facilities use CTC as a 

process agent and the emissions from their operations would be accounted for in EC reporting to the 

Ozone Secretariat. However, other emissions came from facilities in which elemental chlorine was 

produced or used. CTC as a by-product in production, for example, of chloroform (feedstock for 

production of HCFC-22) is well understood and the by-product may be recycled or marketed as a 

valuable industrial chemical. In addition, the fact that chlorine is an extremely powerful chemical 

reagent is often not appreciated, and any industrial procedure that uses chlorine in association with 

organic chemicals is likely to produce at least some CTC. An example is the chlorination of carbon 

monoxide to produce phosgene (COCl2), which is used on a large scale in production of isocyanates, 

the precursors of polyurethanes. 

The quantities revealed by the EC study do not suggest that such emissions are on the scale required 

to eliminate the current discrepancy but do suggest that further work in other jurisdictions could 

reveal sources not reporting to the Ozone Secretariat. 

Other information from the EC, reported in December 2009, shows that CTC production declined 

steadily from 18,633 tonnes in 2004 to 15,763 tonnes in 2008, and that in 2008 there was no import or 

export of this chemical. Sales within the EU amounted to only 862 tonnes, suggesting that most CTC 

was used as feedstock by the producers. This is also likely to be the case in other countries. 

It is likely that chemical manufacture using CTC as feedstock would also result in CTC emissions. As 

noted in this report, better information is needed and Parties may wish to consider requiring reporting 

of feedstock uses of CTC and emissions arising from them. 

The Executive Committee of the Multilateral Fund responded to Decision XXI/3 by producing a 

separate report (ExCom/62/Inf.2) concentrating on process agent uses of CTCs including information 

on CTC emissions from those uses. 
TEAP May 2011 Progress Report 61

4.8 Feedstocks 

Carbon tetrachloride (CTC), trichloroethane, chlorofluorocarbons (CFCs) and 

hydrochlorofluorocarbons (HCFCs), all ozone depleting substances, serve as chemical building blocks 

in the preparation of other chemicals. They allow incorporation of fluorine atoms into molecule 

structures and in all known uses there are no other technologically and economically viable alternative 

routes at this time. Their use in chemical reactions provides cost-effective manufacture of refrigerants, 

blowing agents, solvents, polymers, pharmaceuticals, agricultural chemicals, etc. to benefit society. 

As raw materials, they are converted to other products except for de minimus residues. As a result, 

their environmental impact is minimal. These could be residual levels in the ultimate product (which 

are typically miniscule) or by fugitive leaks in the production, storage and/or transport processes. 

4.8.1 Montreal Protocol Definitions 

The Montreal Protocol defines “Production” as: “the amount of controlled substances produced, 

minus the amount destroyed by technologies to be approved by the Parties and minus the amount 

entirely used as feedstock in the manufacture of other chemicals. The amount recycled and reused is 

not to be considered as Production.” Based on this definition, substances controlled by the Montreal 

Protocol are not subject to phase-out regulations while being used in feedstock applications. 

Therefore, it is expected that production of some of these controlled substances will continue for the 

foreseeable future until either the products derived from these feedstocks are no longer needed or 

when alternative economically attractive synthetic technologies are commercialized. 

4.8.2 Where they are Used 

CTC, CFCs and HCFCs can be feedstocks by being fed directly into the process as a raw material 

stream, as production as an intermediate in the synthesis of another product or as a by-product during 

manufacture of other desired products. Losses can occur during production, storage, transport, if 

necessary, and transfers. Intermediates are normally stored and used at the same site and so fugitive 

leaks are somewhat lower in this case. 

Common feedstock applications include, but are not limited to the following: 

- Conversion of HCFC-21 in the synthesis of HCFC-225 which finds application as a 

solvent 

- Conversion of CFC-113 to chlorotrifluoroethylene. The latter is subsequently 

polymerized to polychlorotrifluoroethylene, a barrier resin used in moisture-resistant 

packaging. 

- Conversion of CFC-113 and CFC-113a to HFC-134a and HFC-125. As this is the route 

to much of the HFC volumes, it is a high volume use. 

- Conversion of HCFC-22 to tetrafluoroethylene (TFE). TFE forms the building block of 

many fluoropolymers both by homopolymerization and copolymerization. This is a very 

high volume use. TFE is also a feedstock for producing HFC-125. Work has been done 

for decades to identify and develop a commercial direct route to TFE without success. 

- Conversion of 1,1,1- trichloroethane as a feedstock in the production of HCFC-141b and 

HCFC-142b. This can continue until 2040 at high volume for emissive uses of these 

products and can continue long-term for uses related to conversion to polymers as noted 

below. 

- Conversion of HCFC-142b to vinylidene fluoride which is polymerized to polyvinylidene 

fluoride or to copolymers. These are specialty elastomers. This feedstock use of HCFC142b is not subject to phase-out and is likely to continue long term. 

- Conversion of carbon tetrachloride (CTC) to CFC-11, CFC-12, etc. This has historically 

been a very high volume application. However, as the phase-out of CFC production is 

now limited to only a few essential uses, e.g., limited amounts of propellant production 

for metered dose inhalers, volume of CTC required for this application has been 

dramatically reduced. 
62 TEAP May 2011 Progress Report

- Conversion of CTC to chlorocarbons which, in turn, are used as feedstocks in production 

of HFC-245fa and other fluorochemicals. 

- Reaction of CTC with 2-chloropropene to eventually lead to production of HFC-365mfc. 

- CTC is used in reaction with vinylidene chloride for preparation of HFC-236fa with 

production volumes under 1 million pounds annually. 

- By-product CTC can be produced in the manufacture of chloroform which is a feedstock 

used in production of HCFC-22, a long-term high volume operation. 

- Conversion of HCFC-123, HFC-123a and HFC-133a in manufacture of pharmaceuticals 

which is a long term use not subject to phase-out. 

- Conversion of HCFC-123 in the production of HFC-125. While this usually occurs as an 

intermediate, it is possible that this could be done using HCFC-123 as a starting material. 

We are not aware of using HCFC-123 as a starting material at this time. 

- HCFC-124 can be used as a feedstock to prepare HFC-125. 

- Halon-1301 in the manufacture of pharmaceuticals and pesticide (Fipronil) 

- CTC in the synthesis of synthetic pyrethroids. 

4.8.3 Estimated Emissions of ODS 

In earlier CTOC reports, efforts were made to estimate emissions likely from use of ODSs as 

feedstocks. In the 2010 CTOC Assessment Report and also in the Progress Report, this was estimated 

as total emissions of 4450 metric tonnes representing about 1600 ODP tonnes. Although parties are 

required under Article 7 of the Montreal Protocol to report ODS production for feedstock uses, 

reported global uses of ODS feedstocks do not exist and the basis for estimates are anecdotal. This 

created serious disagreement concerning both the data and sources. Much of the estimated levels were 

based on proprietary unpublished market information which, by necessity, was aggregated for 

competitive reasons. Further, until such time as parties are required to report such feedstock volumes 

by use, estimates of emissions will be uncertain and subject to disagreement. 

Further complicating such efforts are how to properly estimate levels of emissions during feedstock 

use from storage facilities, transfers, transportation, fugitive losses, etc. No commonly accepted 

guidelines are in place which has resulted in non-productive disagreements. 

In order that a better understanding may be gained of the feedstock uses of ODS and actual or 

estimated emissions arising from these uses, Parties may wish to consider requiring reporting of all 

feedstock uses of ODS. Disclosure of confidential information can usually be avoided by aggregation 

at country level. Where possible, annual quantities for each type of use should be given but at 

minimum there should be reporting of the nature of all feedstock uses. 

4.9 Destruction Technologies 

The TEAP Task Force on destruction technologies that reported in April 2002 described a number of 

technologies as being suitable for destruction of ODS in bulk or in foams. It established criteria for 

destruction and recovery efficiency (DRE) for dilute and concentrated ODS, for dioxin/furan 

emissions, and a number of other practical matters associated with the operation of destruction 

facilities. A number of facilities have been installed using these technologies, and subject to local 

regulations and legislation, but no comprehensive list of these facilities is available. 

The Task Force also recommended investigation of technologies that convert ODS into useful 

compounds via chemical reactions, and these have been slow to appear but the first few are reported 

below. They begin, of course, with destruction of the ODS but then instead of the end products being 

fluoride, chloride, or bromide salts, there is recovery of useful hydrogen fluoride or an organic 

fluorochemical for which there are potential or actual uses. 

The CTOC has reviewed proposals for new technologies using information provided by the 

proponents. Information was be provided to the XXII/10 TEAP Task Force. No cost information was 

provided in the submissions. Proposals were received from SGL CARBON GmbH, LESNI A/S, 
TEAP May 2011 Progress Report 63

ASADA Corporation, Midwest Refrigerants LLC, University of Newcastle (Australia), SRL Plasma, 

and Nordiko Quarantine Systems Pty Ltd (the last two being concerned with destruction of methyl 

bromide). 

4.9.1 Necessity of New Criteria of the Destruction Technologies 

The destruction technologies in the agricultural field are quite different from those in the industrial 

products such as refrigerants. Recently, however, new technologies for the destruction of methyl 

bromide in the agricultural field have appeared. 

The destruction efficiencies of methyl bromide in the above mentioned Nordiko Pty Ltd are lower 

than the suggested minimum standards of DRE 99.99% for concentrated sources and DRE 99.5% for 

dilute sources such as ODS in foams which were set in the ad-hoc Technical Committee in 1992. In 

addition, it took a long period (16 months) for the destruction of methyl bromide on activated carbon. 

Despite of these difficulties, new criteria for destruction technologies are necessary since the criteria 

in 1992 were established for ODS in industrial products and not for the dispersed uses such as 

agricultural processes. The CTOC recommends re-consideration of the criteria. 

4.9.2 Recent Literature 

A recent publication (R. Xuan, D.J. Ashworth, L. Luo and S.R. Yates, ‘Reactive Films for Mitigating 

Methyl Bromide Emissions from Fumigated Soil’, Environmental Science and Technology, 2011, 

electronic version accessible at DOI: 10.1021/es103713k) has described the use of reactive films for 

preventing or minimizing the emission of methyl bromide from field applications. A layer of the 

active ingredient, dry ammonium thiosulfate, is sandwiched between a lower, permeable, film and an 

upper virtually-impermeable film. Methyl bromide is destroyed through reaction with the thiosulfate. 

No commercial applications of this technology have yet been reported. 

4.9.3 Destruction Projects in Article 5 Parties 

Reverse manufacturing of ODS-containing equipment and material at a number of scales is within the 

capability of many countries. Difficulties that attend transboundary movements of waste mean that 

there is no plan (that CTOC is aware of) for a regional destruction facility but there are a number of 

in-country projects to link recovery of ODS with destruction. Decisions between export and incountry destruction are likely to be influenced by the cost and availability of smaller-scale destruction 

equipment such as some of the above examples. 

Brazil had a relatively advanced commercial hazardous waste management infrastructure, and the 

MLF approved a project to develop a fully functioning system of ‘end of life’ (EOL) management 

including environmentally sound and verifiable ODS destruction capability. After screening of a 

number of potentially available destruction facilities (7 incineration and 1 plasma arc), UNDP and the 

Brazil Ministry of Environment are conducting an assessment to evaluate the actual requirements that 

are in place and the potential adaptations those facilities may require to destroy ODS. At one there 

was already reverse manufacturing of domestic refrigerators which had resulted in a declared stock of 

12 tonnes of CFC-12 through manual and semi-automatic process from the national operator. Two 

automatic reverse manufacturing facilities were also established in the latter part of 2010, handling 

refrigeration circuits and foams, and is expected that each one will have destruction capability 

although information about the destruction technology is not yet available. The projects have 

received bilateral funding from the Government of Germany and funding from a Swiss Foundation, 

respectively. Assessments may need to be done to verify if the estimated capacity of the three plants 

are to exceed the market needs in the short term. Also, verification of the interest of those companies 

to receive ODS from third parties (e.g. independent refrigerators de-manufacturers through manual 

processes and EOL chillers containing CFCs) is needed. In the longer term, they also must be 

consulted on their interest/or availability to destroy HCFCs - the successors to the ODS currently 
64 TEAP May 2011 Progress Report

being recovered and destroyed, CFC-11 and CFC-12 from Commercial Refrigeration and AC, since 

those plants were primarily designed for the management of EOL domestic refrigerators. 

UNDP Ghana in collaboration with the Environment Protection Agency (EPA), Energy Commission 

of Ghana, and the center for Rural and Industrial research (CRIR) has developed an overarching 

strategy to provide climate and ozone benefits through the Integrated Plan for Energy Efficiency, 

Climate Mitigation and ODS Reductions for the Refrigeration Sector, the last of these three projects 

having MLF support. Waste ODS would be transported from refrigerator servicing and dismantling 

centres (to be set up with MLF and GEF funding, respectively) and transported overseas for 

destruction. The ExCom will give further attention to this at its 63rd meeting (April 2011). 

The MLF Executive Committee has approved funding for UNDP for a preparatory study in India for 

demonstration of a sustainable technological, financial and management model for disposal of ODS. 

The project proposes to maximize cross-convention synergies by including work on e-waste, shipbreaking, energy efficiency, and equipment replacement programmes. Processes for destruction and 

safe disposal of recovered ODSs from refrigeration and air-conditioning equipment, disposal waste 

stream, chillers, ship breaking activities etc., are expected to be operationalized through this project. 

A destruction project in Cuba, funded by the MLF and implemented by UNDP, seeks to develop an 

efficient and cost-effective logistic framework for the transport, storage and destruction of ODS in a 

cement kiln in Cuba. Since 2006, the Government of Cuba has expended over US $700 million on 

decommissioning of 2,757,000 refrigerators and 276,000 air-conditioning units aged between 20 and 

60 years. A stockpile of 133 tonnes of waste ODS awaits destruction. At its 62nd meeting, December 

2010, the ExCom approved funding of US $525,200 for destruction of 43.5 metric tonnes of ODS 

waste in the ODS Waste Management Pilot project in Cuba. 

The World Bank’s 2009-2011 Business Plan for Montreal Protocol operations lists a global study of 

financing of ODS destruction, and pilot ODS destruction projects in Mexico (UNIDO has produced a 

concept plan), Indonesia (a previous project there was funded by Japan) and the Philippines. 
TEAP May 2011 Progress Report 65

5 TEAP Task Force Response to Decision XXII/10 

5.1 Context and Content of Decision XXII/10 

The Montreal Protocol allows remanufacture of ODSs to replace a portion of ODS destroyed under 

specific conditions (within the same year as destruction, within the same group of substances, etc.). 

This creates the necessity to determine the portion of ODS delivered to a destruction facility that is 

actually destroyed in order to know how much can be remanufactured, if the Party were to choose to 

remanufacture. In practice, however, Parties have typically not remanufactured ODS to offset 

quantities destroyed, choosing instead to further protect stratospheric ozone and climate with 

destruction. Thus, the list of Approved Destruction Technologies has been more concerned with 

destruction efficiency and concerns about safety and atmospheric by-products than with quantification 

of ODS destroyed. 

It is also significant that considerable work on destruction technologies has taken place to support the 

development of market-based strategies to pay for destruction of greenhouse gases in the Kyoto 

basket. New protocols similarly incentivize the destruction of ODS that are also greenhouse gases. 

The Technology and Economic Assessment Panel, its TOCs and Task Forces have assessed existing 

and emerging technologies and have made recommendations for technologies to be added to the list of 

approved destruction technologies, since 1992. The first major assessment on destruction was 

published in the 2002 TEAP Progress Report as a separate volume. This work screened in 16 

technologies before confirming 11 for destruction of concentrated CFC destruction (5 of which were 

also confirmed suitable for halons) and 1 for the destruction of CFCs in foams. Four more 

technologies were judged as having ‘high potential’ for both CFCs and halons (these were AC 

Plasma, CO2 Plasma, Gas Phase Chemical Reduction and Solvated Electron Decomposition), while 6 

of the technologies already confirmed for CFCs were judged to have high potential for halons. Most 

importantly, 29 technologies were ‘screened out’ as not being appropriate. The next request for an 

update of the list was in Decision XVI/15 and an update on Destruction Technologies was included as 

Section 6.9 of the 2005 TEAP Progress Report as a consequence. This decision did not request an 

update of the Approved Technologies List, therefore the four ‘high potential’ emerging technologies 

were not addressed for further consideration by the Parties. The current Approved Technologies List, 

as contained in the 2009 Handbook of the Montreal Protocol, therefore remains unchanged from the 

list developed in 2002. 

Further discussion of destruction technologies was included in Section 4.7 of the 2010 TEAP Progress 

Report, partially in response to clause 3 in Decision XXI/2, which was worded: 

3. To request the Technology and Economic Assessment Panel to review those destruction 

technologies identified in its 2002 report as having high potential and any other 

technologies and to report back to the 30th meeting of the Open-ended Working Group on 

these technologies and their commercial and technical availability. 

This assessment documented the emergence of national regulations to govern the destruction of ODS, 

often based on the criteria set out in the 2002 TEAP Progress Report. It noted, however, that the 

breadth of destruction technologies being practiced at that time was already ‘far wider’ than the 

Approved Technologies List, partially because of the influence of progress in destruction of POPs 

under the Stockholm Convention and the introduction of Resource Conservation & Recovery Act 

(RCRA) requirements and Maximum Achievable Control Technology (MACT) standards in the USA. 

However, the TEAP (through its CTOC) did not explicitly advocate any further additions to the 

Approved Technologies List. An additional section in the 2010 TEAP Assessment Report highlighted 

a series of ‘emerging technologies’. These were described in the 2010 Report in Table 4-4, which is 

reproduced below for ease of reference: 
66 TEAP May 2011 Progress Report

Organisation Nation Fluorocarbons 

Destroyed Evaluation 

Lesni A/S Denmark CFCs, HFCs Destruction of dilute fluorocarbons by 

catalytic cracking 

Midwest 

Refrigerants, LLC 

United States of 

America 

CFCs, HCFCs, HFCs, 

PFCs, Halons 

Transformation of fluorocarbons by 

pyrolytic conversion 

SGL Carbon 

GmbH 

Germany HCFCs, HFCs, CCl4 Destruction of concentrated sources by a 

porous reactor 

University of 

Newcastle 

Australia Halons, CFCs Transformation of fluorocarbons to 

fluorinated vinyl monomers 

SRL Plasma Pty 

Ltd 

Australia Methyl bromide Applicability of present destruction 

technologies to methyl bromide 

 

Decision XXII/10 now focuses on the review of Destruction and Removal Efficiency (DRE) criteria 

in general and consideration of the minimum DRE criterion for methyl bromide destruction. In 

addition, the TEAP has been asked to review the list of ‘existing and emerging technologies’ in the 

context of these criteria and provide an evaluation of their performance and commercial/technical 

availability. DRE is currently viewed as the appropriate metric for measuring the efficiency of ODS 

destruction. In order to ensure that the emerging technology assessment reviews the most recent 

developments, a call for new submissions was made – to be received no later than 1st February 2011. 

The full operative text of Decision is as follows: 

1. To request the Panel and the relevant technical options committees, in consultation with 

other relevant experts, for consideration at the thirty-first meeting of the Open-ended 

Working Group and with a view to possible inclusion in the Montreal Protocol handbook: 

a. To evaluate and recommend the appropriate destruction and removal efficiency for 

methyl bromide and to update the destruction and removal efficiency for any other 

substance already listed in annex II to the report of the Fifteenth Meeting of the 

Parties; 

b. To review the list of destruction technologies adopted by parties taking into 

account emerging technologies identified in its 2010 Progress Report and any 

other developments in this sector, and to provide an evaluation of their 

performance and commercial and technical availability; 

c. To develop criteria that should be used to verify the destruction of ozone-depleting 

substances at facilities that use approved ozone-depleting-substance destruction 

technologies, taking into account the recommended destruction and removal 

efficiencies for the relevant substance; 

2. To invite submissions to the Ozone Secretariat by 1 February 2011 of data relevant to the 

tasks set out in paragraph 1 above; 

In response to paragraph 2 of the current decision, the Ozone Secretariat has not only received further 

inputs from the five emerging technology proponents listed in 2010, but also from the ASADA 

Corporation in Japan and Nordiko Quarantine Systems PTL Limited in Australia, 

5.2 Task Force Composition 

The Chemicals Technical Options Committee (CTOC) had taken the lead on the destruction 

technologies issue since 2005 and had reviewed the subject periodically since then. However, the 

number of destruction experts on the Committee was limited. Accordingly, the burden of this work 

had fallen on a relatively small number of individuals and did not include experts in all aspects of 

destruction. 
TEAP May 2011 Progress Report 67

In view of the specificity of Decision XXII/10, TEAP decided to form a specific Task Force cochaired by one of the existing CTOC co-chairs (Ian Rae), but also involving some foam expertise in 

the form of an FTOC co-chair (Paul Ashford), who had previously dealt with the coverage of ODS 

destruction from dilute sources in both the TEAP Task Force on Destruction Technologies (2002) and 

the Foams End-of-Life Task Force in 2005. Other Task Force members were selected on a basis of 

expertise and availability. 

The main focus of the decision was on destruction criteria and it was felt necessary to strengthen the 

expertise in this area by involving Rick Cooke, who has experience from the Stockholm Convention 

on Persistent Organic Pollutants and the Global Environment Facility as well as Montreal Protocol 

demonstration projects. In addition, Dr Koichi Mizuno, from the CTOC, provided continuity with 

earlier assessments and to bring his substantial experience to the Task Force. Finally, it was deemed 

as valuable to have a member on the Task Force responsible for the oversight of existing destruction 

facilities in developing countries. Ms Cristina Poli of CETESB in Brazil, which is the agency of the 

State Government responsible for the control, supervision, monitoring and licensing of pollution 

generating activities, with the aim of preserving and recovering the quality of air, water and soil, was 

therefore invited onto the Committee. 

The Task Force was further strengthened by the presence of Ms Bella Maranion of the United States 

Environmental Protection Agency who oversees the regulation of ODS destruction in the United 

States and who, along with other Task Force members, had been part of the Advisory Workgroup to 

the Climate Action Reserve in California on the development of its International Protocol., 

Clause 1(c) of the decision addresses the need for criteria for the verification of destruction at 

facilities that use ODS destruction technologies. This need arises from the fact that the Climate Action 

Reserve, amongst others, has been nervous about ensuring environmentally-sound destruction outside 

of the United States of America. In turn, this provided a barrier to the use of local destruction facilities 

in Article 5 countries. With this in mind, TEAP invited four experts in the field of project verification 

to join the Task Force: they were Syd Partridge from the Reserve itself, Tim Kidman (SAIC), Kristian 

Bruning (Climate Wedge) and, representing the management of appliances, Christoph Becker (RAL 

Standards). 

The full membership is summarised in the table below: 

Member Affiliation Nationality 

Ian Rae (co-chair) University of Melbourne Australia 

Paul Ashford (co-chair) Caleb Management Services (consultancy) UK 

Christoph Becker RAL Standards Germany 

Kristian Bruning Climate Wedge Finland 

Rick Cooke Man-West Environmental Group Canada 

Tim Kidman SAIC USA 

Bella Maranion US Environmental Protection Agency USA 

Koichi Mizuno National Institute of Advanced Industrial 

Science and Technology (AIST) Japan 

Syd Partridge Climate Action Reserve USA 

Cristina Poli CETESB Brazil 
68 TEAP May 2011 Progress Report

Although methyl bromide destruction was an element of the brief to the Task Force, it was considered 

that the existing destruction expertise on the Task Force would be sufficient to assess specific issues 

related to the substance. However, it was noted that close liaison with the Methyl Bromide Technical 

Options Committee (MBTOC) would be an important aspect of this work. 

The Task Force did not physically meet to conduct its business, but communicated primarily by email. Bella Maranion, Paul Ashford and Ian Rae took advantage of the opportunity to meet during the 

TEAP meeting in Geneva in May 2011 in order to discuss the structuring and content of the report. 

The opportunity was also taken to liaise informally with MBTOC members in the margins of the 

TEAP meeting on issues of significance to Decision XXII/10. 

5.3 Performance Criteria 

5.3.1 Destruction and Removal Efficiency (DRE) vs. Destruction Efficiency 

(DE) 

The 2002 TEAP Task Force Report on Destruction Technologies (TFDT) noted that there was a clear 

distinction between Destruction and Removal Efficiency (DRE) and Destruction Efficiency (DE) with 

Destruction Efficiency being the more comprehensive measure of the efficiency of destruction in that 

it not only considers losses in the stack gas, but also losses from other sources such as fly ash, 

scrubber water and bottom ash. In this respect, it aims at getting closer to a full mass balance. 

The decision in the 2002 TFDT Report to stay with DRE as the criterion for deriving the list of 

Approved Technologies was based mostly on the availability of data. Accordingly, it was viewed as 

appropriate to remain with this measure in order to cover as many technologies as possible. Since 

then, Destruction Efficiency has become a more prevalent measure of destruction performance when 

documenting POPs destruction under the Stockholm and Basel Conventions. A current proposal from 

the Scientific Technical Advisory Panel of the GEF recommends the use of Destruction Efficiency 

(DE) before quoting a Destruction and Removal Efficiency (GEF/C.40/Inf. 16). 

Inevitably, the DE is lower than the DRE because it encompasses more potential losses. However, the 

GEF Scientific and Technical Advisory Committee (STAP) highlights that Best Available 

Technology (BAT) should be able to achieve DRE of 99.9999% and DE of 99.99% and that these 

should be used as ‘working benchmarks’. This means that the current criterion for destruction within 

the Montreal Protocol of 99.99% DRE is fairly modest. 

Under the Clean Air Act in the United States, the stratospheric ozone regulation (40 CFR Part 82 

Subpart A) specifies minimum performance in terms of Destruction Efficiency rather than Destruction 

and Removal Efficiency and set a minimum performance of 98%. However, the International Protocol 

developed by the Climate Action Reserve holds to the Montreal Protocol approach of specifying a 

DRE of 99.99%. 

The opportunity therefore exists for the Montreal Protocol to re-visit its specification of destruction 

criteria and could now consider the possibility of specifying the more comprehensive performance 

indicator of Destruction Efficiency. However, if this criterion was left at a value of 99.99%, it would 

effectively be an increase in the requirements for destruction over the current position. An alternative 

would be to consider a lower threshold, noting that the current US minimum requirement is set at 

98%. For gaseous materials such as ODS, the difference between DRE and DE would not be expected 

to be so substantial. Accordingly, a figure of 99% or 99.5% for DE would seem to be more 

appropriate. Such proposals could be the basis for wider consultation within the Parties of the 

Montreal Protocol. 

However, counter-arguments to a change include the fact that DE is primarily used to trace losses of 

hazardous bi-products in water and soil. Since ODSs are volatile and are not generally deemed as 

hazardous outside of their ozone impacts, the adoption of DE would not provide a particular 
TEAP May 2011 Progress Report 69

advantage and would entail additional cost. The improvement in the quantification of ODS destroyed 

would also be marginal. Conversely, if destruction is extended to methyl bromide, there might be 

advantage in being able to trace other sources of loss from destruction facilities, in view of its toxic 

nature (see Section 5.4). 

In summary, the Task Force is not proposing a specific change at this time, but believes it important 

for Parties to keep this wider perspective in mind for future decisions related to destruction. 

5.3.2 Destruction and Removal Efficiency in Perspective 

As the shift in ODS destruction moves from surplus ODS stockpiled from manufacture to recovery 

and destruction of ODS at end-of-life (E-o-L), the losses occurring in the collection and recovery 

stages have become the subject of greater focus. Although these losses can still be relatively low for 

concentrated sources derstroyed in sophisticated facilities, it is likely that considerable losses 

(sometimes in excess of 5%) can occur in recovery of some refrigerants and foam blowing agents 

prior to the destruction step. Section 5 of this report also picks up on the management of dilute 

sources, where re-concentration can also lead to additional losses. 

Under these circumstances, a case can be made to avoid setting criteria for destruction that are 

dwarfed by losses from other sources. Therefore, there does remain a solid basis for retaining a DRE 

of 99.99% rather than 99.9999%, for example. Indeed, some argue that a DRE of 99.9% would also 

provide sufficient margins of safety in view of the fact that these minor emissions are not 

environmentally significant when compared with losses in collection and recovery. 

The STAP also highlights in its recent paper the fact that striving for the highest destruction criteria 

can have a damaging effect of the cost effectiveness of destruction and notes that this can limit the 

amount of destruction that occurs to the wider detriment of the environment. In particular, it is viewed 

that the criteria for developing countries should be no more stringent than those already applied in 

developed countries. 

Applying these principles to the destruction of ODS, the Task Force believes that there is a reasoned 

case for reducing the DRE to 99.9% but recognises that this would open up the need to review all of 

the technologies that were ‘screened out’ in 2002 to see if they would have qualified under the revised 

criteria. In addition, if there is a decision as a result of the discussion in Section 5.1 to move to the 

more comprehensive Destruction Efficiency (DE) measure, then it would certainly be counterproductive to have to re-visit the ‘screened out’ technologies twice. A critical aspect of any decision 

to adjust criteria is that any changes maintain appropriate levels of environmental prudence while 

maximizing the opportunity to recover and destroy ODS in the field. 

5.3.3 The Case for Moving the Dioxin/Furan Limits for ODS 

Apart from the efficiency of destruction considered in the previous two sections, there is a need to 

ensure that the breakdown products themselves do not cause an increased risk to the environment. The 

likely components of such a breakdown in the case of ODS are polychlorinated dibenzo-p-dioxins and 

polychlorinated dibenzofurans (PCDD/PCDF). The screening criteria in the 2002 TFDT Report were 

set at 0.2ng ITEQ/Nm3

 (toxicity equivalency factor) for concentrated sources. Since there are 75 types 

of PCCD and 135 types of PCDF, the purpose of the ITEQ approach is to aggregate individual 

toxicities and concentrations in such a way as to set an overall limit. Accordingly, a more toxic 

substance will contribute to reaching the aggregated threshold more quickly than a less toxic 

substance. 

Even in the 2002 Report, there were comments to the effect that 0.2 ng ITEQ Nm3

 was a compromise 

between more stringent requirements in developed countries (<1 ng ITEQ Nm3

) and possibly higher 

figures in developing countries. To put this into context, however, it should be noted that the figure 
70 TEAP May 2011 Progress Report

put forward by the Technical Advisory Committee in the 1992 report was 5 times higher at 1.0 ng 

ITEQ Nm3

. 

The Task Force is currently of the view that a limit of 0.1 ng ITEQ Nm3 would be closer to the 

industry norm, but notes that there may be some existing ‘screened in’ technologies that might not 

satisfy this criterion. As can be seen in Section 4, there is one technology that has been operational in 

Denmark, Sweden and the UK for several years and operates to a limit of 0.2 ng ITEQ Nm3

. 

In conclusion, the Task Force recommends a move to 0.1 ng ITEQ Nm3

 and suggests that this should 

be done via a consultation process through the regulatory authorities of the Parties in order to 

determine the impact prior to a definitive decision. 

5.3.4 Destruction and Removal Efficiency for Methyl Bromide 

Since the primary use of methyl bromide is as a toxic fumigant, it clearly has a human health hazard 

profile that needs to be managed. However, this has been achieved successfully in the diverse world 

of agriculture and is therefore not seen to provide any insurmountable handling challenges to the 

chemical destruction sector. The main hazard characteristics of methyl bromide can be summarised 

as: 

• Toxic and Corrosive through ingestion, inhalation and skin contact 

• Strong irritant 

• Potential mutagen 

Methyl bromide has been reported historically to be the most difficult ODS to destroy by 

incineration1

, having a Class 1 Thermal Stability Index (Ranking 31-33). Nonetheless, significant 

quantities of methyl bromide have been destroyed historically. The 2010 Progress Report highlighted 

a table that indicated the destruction of over 13,000 tonnes of methyl bromide in the United States 

alone between 1991 and 2003. Further investigation has revealed that a number of destruction 

technologies were used during that period, but the major ones were rotary kiln incineration, 

conventional thermal incineration (called a fume/vapour system by some facilities) and catalytic 

oxidisers. Little information is available on the levels of destruction achieved. 

Having reviewed the limited data available, the Task Force sees no reason why the Destruction and 

Removal Efficiency (DRE) should be set at an initial figure that differs from that used for other ODS 

(99.99%). However, as with ODS, the opportunity exists to round this down in due course to a DRE 

of 99.9% or switch across to a more comprehensive DE measure. Since this decision will not be made 

immediately, there is an opportunity to solicit more information from the destruction sector on methyl 

bromide destruction experiences. However, with the on-going refinement of destruction technologies, 

there is unlikely to be any insurmountable to the achievement of DREs in excess of 99.99%. 

5.3.5 Specific Concerns about Brominated Dioxins/Furans 

A more significant issue for methyl bromide destruction is the avoidance of hazardous bi-products as 

part of the destruction step. In the case of methyl bromide, these will be primarily polybrominated 

dibenzo-p-dioxins and polybrominated dibenzofurans (PBDD/PBDF). In 1998, an expert group 

recommended the use of the aggregated TEF approach for these compounds and further recommended 

the adoption of the same limits as for PCDDs and PCDFs2

. However, these recommendations have 

not yet been fully adopted into the TEF scheme. 

 

1

 B. Dellinger and P.H. Taylor, “Handbook: Guidance on setting permit conditions and reporting trial burn 

results, Appendix D” US EPA/625/6-89/019, (1989) 

2

 http://www.inchem.org/documents/ehc/ehc/ehc205.htm 
TEAP May 2011 Progress Report 71

In the light of this background, the Task Force recommends a limit of 0.1ng TEQ Nm3

 in order to 

align with the likely eventual adoption within the TEF scheme. 

5.3.6 Conclusions on Performance Criteria 

The review conducted by the Task Force has uncovered a number of aspects that would drive towards 

a change in the current performance criteria. However, the predicting the full consequences of such 

changes to existing, high potential and emerging technologies will need further consultation with the 

destruction industry. The Task Force would therefore propose an on-going consultation, possibly via 

the Parties to their national agencies, to seek feedback on the following: 

• A change from a performance criterion set on the basis of DRE to one based on DE 

• A setting of the DRE at 99.9% or DE at 99% or 99.5% 

• The decrease of PCDD/PCDF limits to 0.1 ng ITEQ Nm3

• The value of PBDD/PBDF limits to be set at 0.1 ng TEQ Nm3

• The DRE for methyl bromide to be set initially at 99.99% but to mirror on-going changes 

proposed for other ODS. 

5.4 Evaluation of Emerging Technologies 

5.4.1 Generic Technologies vs. Specific (proprietary) Technologies 

One of the challenges associated with the assessment of destruction technologies for approval under 

the Montreal Protocol is deciding what constitutes a technology. The 2002 TFDT Report identified 45 

distinct technologies and only ‘screened in’ 16 of these. 12 were approved by Parties at that point and 

four were characterised by TEAP as having ‘high potential’. The remainder were ‘screened out’. As 

noted in Section 3, any changes in performance criteria will require re-appraisal of the whole set of 45 

technologies previously screened in and out. 

In the 2010 Progress Report, the CTOC had highlighted a list of 5 emerging technologies. A further 

two technologies related to methyl bromide have also been added since that time and are assessed in 

this report. These are primarily proprietary technologies put forward by individual legal entities. 

Intellectually, this creates the challenge of deciding whether these specific technologies are sub-sets 

of technologies previously reviewed, whether ‘screened in’ or ‘screened out’. Without this wider 

analysis, there is a risk that a specific ‘emerging’ technology could be ‘screened in’ or ‘approved’ 

while the wider generic technology could have been previously ‘screened out’. The Task Force 

considered that each application for approval should be treated on its own merits, and that decisions 

should not be swayed by previous evaluations. This avoids the risk of misappropriation of the 

technology. It may be a separate (future) step in the management of the Approved Technology List to 

go back through and identify duplications and over-laps. Parties are invited to consider and comment 

on this approach. 

5.4.2 Status of Previous ‘High Potential’ Technologies 

The 2002 Report of the TFDT identified four technologies that were of ‘high potential’. These were: 

• AC Plasma 

• CO2 Plasma 

• Gas Phase Chemical Reduction 

• Solvated Electron Decomposition 

The Task Force has reviewed AC Plasma and CO2 Plasma technologies and has concluded that they 

remain suited to low vapour pressure liquid and gaseous streams and therefore of high potential for 
72 TEAP May 2011 Progress Report

ODS destruction. However, the published literature is limited on their actual use for ODS (particularly 

for CO2 Plasma), so it is not yet clear whether they can be added to the Approved Technology List. 

Parties may wish to consider a call for further information via the Ozone Secretariat. 

In the case of Gas Phase Chemical Reduction and Solvated Electron Decomposition, however, these 

technologies are less suited to ODS unless a level of pre-treatment takes place. This could make 

assessment of destruction efficiencies more challenging. There is also some question mark about the 

widespread commercial adoption of these technologies, placing some further doubt on the earlier 

optimism. Nevertheless, it is viewed as premature to ‘screen out’ these processes until more 

experience is gained. 

5.4.3 Assessment of Each Technology 

The following table summarises the information received on the seven emerging technologies 

reviewed by the Task Force: 

Proponent Technology Feed rate of ODS

Against criteria

99.99% DRE

Dioxins < 0.1 ng ITEQ m-3

Comment

SGL Carbon GmbH

Refrigerant gas, air and fuel in 

porous reactor at high temp for 

short time.

2 -10 kg/h for HCFC-22 

and HFC-134a; 60 kg/h 

for CCl4

99.99% DRE (but 95% for 

dilute sources); dioxins 

< 0.1 ng m-3

Already operated at Frankfurt Main 

by Akzo; pilot plant at TU 

Bergakademie, Freiberg.

Lesni A/S

Catalytic destruction of 

fluorocarbons and hydrocarbons 

vapour from foams at modest 

temperatures.

60 kg/h for CFC-11, 

CFC-12, HFC-134a and 

pentane

>99.9% DRE; dioxins 0.2 ng 

Nm-3 (0.5 ng Nm-3 for dilute 

gases).

Operated for 7 years in Sweden, 

Denmark, and UK.

ASADA Corporation Plasma destruction, small scale 

Typically, 2 kg/h for 

HCFC-22, HFC-134a, 1 

kg/h for CFC-12

DRE >99.99%; dioxins < 

0.000002 ng-ITEQ m-3

Operated at Matsuzaka-city, Mie 

prefecture and at Giacomino, 

Argentina.

Midwest Refrigerants LLC Thermal conversion of ODS with 

hydrogen and carbon dioxide.

In a pilot plant, 5.4 –

7.3 kg/h (12 – 16 

lbs/h) for CFC-12

DRE >99.99% reported;

2,3,7,8-PCDD 0.0095 ng m-3

reported

Halogens recovered as salable

hydrogen halides or halide salts.

Further process definition 

provided since 2010

Newcastle, Australia

Thermal conversion of 

fluorocarbons to vinylidene 

chloride (described in two US 

patents).

Feed rate achieved for 

both halons and CFCs 

was 1.5 kg/hr

Conversion of reactant halons

and CFCs was 99.99% at 1173 

K (900 degree C)

Catalytic reactions of 

fluorocarbons with hydrocarbons 

(natural gas) in a semi-scale 

reactor; 

SRL Plasma Plasma destruction of methyl 

bromide 31 kg over 100 minutes

DRE >99.5% claimed but 2-

3% of MB recovered; may 

meet dioxin criterion if bromodioxins have ITEQ similar to 

chlorinated.

Trial processed 

Nordiko Quarantine 

Systems Pty Ltd

Adsorption of methyl bromide on 

activated carbon and subsequent 

destruction by chemical, biological 

or thermal means.

Not quantitative 

amount of methyl 

bromide reported

DRE of 96.02%. claimed for 

methyl bromide adsorbed on 

activated carbon in an ambient 

conditions for 16 months 

The technical adequacy of the initial submissions received varied significantly and much of the data 

contained in this table was accumulated through a number of bilateral communications between Task 

Force members and the technology proponents. This was not always a very efficient process and some 

technology holders struggled to provide the information required. 

One conclusion from this is that there may be a case for developing a specific ‘pro forma’ for 

information submissions in future. This could be made available on the Ozone Secretariat website for 

ease of access, with periodic ‘calls’ for submission. 

5.4.3.1 SGL Carbon 

The technology application submitted by SGL Carbon GmbH has been described as a process by 

which ODS, air and fuel are combined for a short period in a porous reactor. Generically, this is 

understood to be a thermal oxidation reactor which would broadly qualify under the ‘screened in’ 

incineration technologies already Approved. However, there may be proprietary nuances to the 

technology which take it slightly outside of the current definitional boundaries. 

A pilot plant operates at Frankfurt Main and has a feed rate which is above the minimum required for 

eligibility. The performance achieved is as listed in the table and meets the current criteria specified. 

Therefore the Task Force recommends adding this technology to the list of Approved Technologies 
TEAP May 2011 Progress Report 73

immediately, although it may be subsumed in an existing category as and when the review referred to 

in Section 5.1 is undertaken. (Recommended for Approval) 

5.4.3.2 Lesni A/S 

This technology is described as the catalytic destruction of fluorocarbons from foams at modest 

temperatures. As such, it may fall under the wider category of ‘Gas phase catalytic dehalogenation’ 

but, as with the SGL technology, this can be resolved in a subsequent review. The DRE claimed for 

the technology is 99.9% which, under current criteria does not qualify. Additionally, the Dioxins 

performance of 0.2 ng ITEQ Nm3

 is now considered below the international norm form for ODS 

destruction processes. However, the Task Force notes that this technology has been operated for 7 

years under the purview of the Swedish, Danish and UK authorities. 

The Task Force would wish Parties to consider the treatment of such cases within a fluid situation for 

performance criteria (see Section 5.3). However, the Task Force does not feel empowered to approve 

the technology under the current circumstances, although it accepts its high potential. (High 

Potential) 

5.4.3.3 ASADA 

The ASADA portable plasma destruction plant has the advantage of being transportable to the place 

of need. Issues surrounding the requirements for continuity of power supply have been raised and 

addressed, leading to a general conclusion that the plant is operable in most circumstances. Plants are 

already reported to be operating in Japan and Argentina. 

 The capacity of these plants can be as low as 1 kg/hour for some ODS (e.g. CFC-12). However, this 

is equivalent to the minimum feed rate defined by the TFDT in 2002 as a ‘screen in’ criterion. Whilst 

this low throughput might have an impact on the economics, the Task Force does not view this as a 

basis for exclusion of the technology. 

The destruction performance is consistent with other approved plasma technologies and the Task 

Force recommends it for Approved Technologies List (Recommended for Approval) 

5.4.3.4 Midwest Refrigerants 

This technology provides a novel approach to the destruction of ODS and involves the thermal 

reaction of ODS with hydrogen and carbon dioxide. The process results in an irreversible 

transformation and the performance criteria currently in place for ODS destruction are met, although 

there was initially some concern within the Task Force concerning the process flow adopted and the 

level of analytical verification. However, this has subsequently been resolved. Since the process is 

targeted to create hydrogen halides and/or halide salts as saleable bi-products of the destruction 

process, the normal screening criterion related to maximum HCl or HF levels in the stack gases do not 

really apply. 

The Task Force believes that this represents a significant additional technology option and, although it 

is still in its semi-commercial stage, recommends its inclusion in the Approved Technologies List. 

(Recommended for Approval) 

5.4.3.5 University of Newcastle 

As with Midwest Refrigerants, this technology is strictly a transformation process. However, the Task 

Force points out that all destruction processes are, in fact, transformation processes, with the only 

difference being whether there is a specific use for product (in this case vinylidene fluoride) into 

which the ODS has been transformed. The critical aspect of any transformation process from a Task 

Force perspective is whether the transformation is irreversible or not. Clearly, it would not be 

appropriate to sanction technologies in which the permanence of the transformation was not assured. 
74 TEAP May 2011 Progress Report

Being a transformative process, however, does not mean that it should be subject to lower 

performance thresholds than other destruction technologies. In this instance, a conversion factor of 

99.99% has been reported for both CFCs and halon. Whether this is viewed strictly as a DE or a DRE, 

the level of conversion is sufficient to meet the criteria set for inclusion as an Approved Technology, 

and accordingly is recommended for approval. (Recommended for Approval) 

5.4.3.6 SRL Plasma 

This is the first of two technologies submitted specifically to address the destruction of methyl 

bromide. In principle, the Task Force sees no reason why plasma technology of the type operated by 

SRL Plasma would not be suitable for methyl bromide destruction. However, although the DRE is 

quoted as 99.5%, there seems to be a contradiction in the fact that 2-3% is recovered from the waste 

stream. The Task Force suspects that the flow rate used for the trials may have been too high (31 kg 

over 100 minutes) to achieve full destruction and that slower rates might be more effective. This is 

equally borne out by the observation in Section 5.4 that methyl bromide is more thermally stable than 

other ODS. 

The Task Force has concluded that there is insufficient information on SRL Plasma to recommend 

approval, but notes the high potential that it represents. (High Potential) 

5.4.3.7 Nordiko 

The technology is described as the adsorption of methyl bromide on activated carbon and subsequent 

destruction by chemical, biological or thermal means. Since the technology is not linked with any 

specific destruction technology, the Task Force does not believe that this current submission can be 

considered within the scope of an assessment of destruction technologies. The technology, as 

described, relates more to a collection and recovery methodology which clearly performs well in 

achieving a recovery rate of 96.02% over an extended period (16 months). Currently, there is no 

approved performance criterion for collection and recovery of methyl bromide. The closest parameter 

under consideration is the Recovery and Destruction Efficiency (RDE) used as a benchmark for 

recovering ODS from foams, either in dilute form or by re-concentrating. With these points in mind, 

the Task Force is ‘unable to assess’ this submission based on the data available. (Unable to Assess) 

5.5 Development of Verification Criteria 

5.5.1 Maximising Destruction or Quantifying Destruction? 

In the early years of the Montreal Protocol, the primary purpose of Approved Destruction 

Technologies was to act as a vehicle for destroying ozone depleting substances in order to omit these 

materials from declared national consumption, where consumption is defined as follows: 

 Consumption = Production + Imports – Exports – Quantity Destroyed 

The provision allowed for the remanufacture of ODS to offset that destroyed in a facility approved by 

the Parties, if accomplished in the same year and if the ODS remanufactured were in the same ODS 

group. As noted earlier however, Parties have typically not remanufactured ODS to offset quantities 

destroyed, choosing instead to further protect stratospheric ozone and climate with destruction. 

Implicit in this mechanism was an underlying assumption that Parties would be destroying unwanted 

stockpiles rather than gathering ozone depleting at end of life for destruction to prevent emissions. It 

was largely assumed that any ODS collected from the field was more likely to be reclaimed or 

recycled than destroyed at a time when these substances also had a market value of their own. 

Since most stockpiles already existed, there was no significant collection step and certainly not one 

that would be likely to result in substantial emissions prior to destruction. There was also no particular 

challenge in quantification of materials destroyed. The focus was therefore on the destruction 
TEAP May 2011 Progress Report 75

technology used and the efficiency of that process – both in terms of level of destruction (at least 

99.99%) achieved and levels of trace pollutants that might result. 

In the 2002 TEAP Task Force Report on Collection, Recovery & Storage (TFCRS), the discussion 

had already begun to move towards consideration of the ‘banks’ of ozone depleting substances in use 

(i.e. ‘already consumed’ in Montreal Protocol language) and ways in which emissions could be 

avoided or, at least, minimised at the point at which equipment and products were being 

decommissioned in order to maximise destruction. This necessarily required consideration of the 

losses that might be incurred during the collection, recovery and storage stages prior to destruction, 

unless the recovery and destruction would lead to new production. 

For refrigerants and halons, it was noted that the ODS were generally contained and, with the use of 

appropriate equipment and/or practices, could be aggregated into significant quantities for destruction. 

This was not the case for blowing agents in foams, where the blowing agent was distributed in 

discrete pockets throughout the foam and, in some instances, might even be partially dissolved in the 

polymer matrix itself. Recognising this reality, it was concluded that the destruction of ODS in foams 

could be addressed either by extracting the blowing agent to the extent possible prior to reconcentrating it for destruction by Approved Destruction Technologies or, could be destroyed along 

with the foam itself through an appropriate incineration process. This led to the inclusion of 

Municipal Solid Waste Incinerators (MSWI) in the list of Approved Technologies for diffuse sources 

(intact foams) following positive reports of destruction efficiencies from work conducted by the foam 

industry in Europe during the 1990s (e.g. the Tamara Project). Later Rotary Kiln Incineration was 

added to the List following positive evidence in support of this technology from Japan and elsewhere. 

The destruction of ODS directly within foams typically results in lower destruction efficiencies 

because of the non-homogeneous nature of the substrate and its distribution through the product. 

Accordingly, a Destruction and Removal Efficiency (DRE) of 95% was deemed reasonable for such 

direct incineration processes. Where blowing agent was extracted from foams prior to destruction, it 

was recognised that there would be losses in the physical handling of foams through the process. In 

addition, there would be residual level of blowing agent remaining in the polymer matrix after 

extraction. These various points of loss would lead to lower recovery yields even if the final 

Approved Destruction Technology resulted in a 99.99% DRE. In addition, for both categories of 

destruction there would be some losses in foam decommissioning and collection. The TEAP Task 

Force on Foam End-of-Life Issues provided further insight into these issues and concluded that it was 

necessary to introduce an additional parameter called Recovery and Destruction Efficiency (RDE), 

which accounted for all losses from the point of product decommissioning to the final destruction of 

the blowing agent. Therefore RDE was defined as: 

RDE (%) = 

Blowing Agent in foam 

immediately prior to 

decommissioning

Blowing Agent in foam 

Immediately prior to __ [Losses in Segregation and/or Mechanical , 

 Decommissioning Recovery and/or Incineration] 

___________________________________________________ 

 This was the first step towards the assessment of losses in ODS destruction from foams as 

summarised in the following: 
76 TEAP May 2011 Progress Report

 Product Type Recovery 

Method 

Losses in 

segregation 

Losses in 

other preincineration 

steps 

Losses in 

incineration 

Recovery & 

Destruction 

Efficiency 

(RDE) 

General 

Building Foam 

Mechanical 

Recovery 

2-8% 0.5% <0.1% >90% 

General 

Building Foam 

Direct Foam 

Incineration 

2-8% 

Not 

Applicable 

<0.1% >90% 

Sandwich 

Panels 

Mechanical 

Recovery Not Applicable <5% <0.1% >94% 

Sandwich 

Panels 

Direct Foam 

Incineration Not Applicable 

Not 

Applicable <0.1% >99% 

Appliance 

Foam 

Mechanical 

Recovery Not Applicable <5% <0.1% >94% 

Appliance 

Foam 

Direct Foam 

Incineration 

Manual 

(no ODS capture) 

5-25% 

Not 

Applicable 

<0.1% <95% 

Appliance 

Foam 

Direct Foam 

Incineration 

Manual 

(with ODS capture) 

0.5-4% 

Not 

Applicable 

<0.1% >95% 

The initial inference, as recorded in the Foams End-of-Life Task Force Report (2005), was that an 

RDE of 85% or 90% could be set as a minimum recovery and destruction level. The updated table 

above would indicate that a decision to opt for a minimum RDE of 90% could rule out some manual 

separation practices with appliances in non-enclosed facilities. This may be a desired outcome in 

regions where better alternatives can be afforded, but may not be appropriate in all regions and 

circumstances. 

However, whichever route is chosen it should be noted that all of these approaches are targeted at 

maximising destruction rather than measuring destroyed amounts. In particular, the direct incineration 

of foams would not provide a quantitative assessment of ODS destroyed, since there would be no 

input flow measure of the type required for the determination of DRE when concentrated ODS are 

destroyed. 

The lack of quantification was of little consequence in the end-of-life scenario until it became clear 

that destroyed ODS could become a source of co-funding as a result of the carbon equivalent value in 

protecting the climate. This was particularly significant because of the high global warming potentials 

of most CFCs, HCFCs and other ODSs. As carbon projects began to be considered in earnest for ODS 

recovery and destruction, there was a need to consider the protocols for quantification. Organisations 

such as the Voluntary Carbon Standard (VCS) and the Climate Action Reserve (CAR) either have 

developed, or are in the process of developing such protocols, with CAR taking this through to a full 

methodology3

 although only for the recovery of blowing agents/refrigerants prior to incineration. 

CAR concluded that the challenges associated with the quantification of blowing agent in in-tact foam 

were too great at this stage to extend the methodology to this aspect. In order to quantify emissions 

savings achieved by the projects in question, these protocols also needed to take due account of the 

baseline emissions that would otherwise occurred in the waste stream. Any quantitative or qualitative 

adjustments to minimum emission thresholds or monitoring procedures adopted by the Parties will 

 

3 Climate Action Reserve: Article 5 Ozone Depleting Substances Project Protocol, Version 1 (February 2010) 
TEAP May 2011 Progress Report 77

likely have a direct impact on the requirements set by these methodologies. In particular, ambitious 

RDE minimum thresholds can have a significant impact on monitoring costs. 

For CAR, in particular, there was some concern that the ability to apply its methodology 

internationally would depend, first and foremost, on the level of confidence in the performance of the 

destruction facilities themselves (i.e. the reliability of the certificate of destruction). As a secondary 

point, it would also be necessary to have confidence in the availability of data on the baseline 

emissions and procedures practiced in collection and recovery, as well as confidence in data on 

external energy consumed by the destruction project. However, these would ultimately be factors 

influencing the quantity of credits available, with conservative assumptions being taken in the absence 

of information. 

In the short term, CAR’s concern on the verification of performance of destruction facilities led to the 

decision to restrict the destruction step to operations in the United States of America or its territories, 

so that the management of destruction could be covered under the US Clean Air Act (US EPA rule 40 

CFR 82). In order to extend the application of the CAR Protocol beyond the boundaries of the USA, 

there would be a need to assure verification against criteria set out in Section 5.3 of this report. This 

therefore focused attention on the Code of Good Housekeeping that had been previously developed 

under the Montreal Protocol and included in the Montreal Protocol Handbook. 

Finally, it should be highlighted that recovery and destruction of ODS under carbon schemes by 

nature increases incentives to maximizing RDE as losses reduce the amount of material available for 

destruction. Beyond given RDE and DRE thresholds, an ODS carbon project only generates credits 

against measured destruction. A focus on Code of Good Housekeeping as a measure to maximize or 

verify RDE and DRE would create an indirect project eligibility criteria. Further work would be 

required to assess any impact on supply of projects. 

5.5.2 Status of Code of Good Housekeeping 

The Code of Good Housekeeping was first prepared by the Ad-hoc Technical Advisory Committee in 

May 1992 and was incorporated into the Montreal Protocol provisions via Decision IV/11 at the 

Fourth Meeting of the Parties later in the same year. The primary purpose of the Code was explicitly 

described ‘to ensure that environmental releases of ozone depleting substances through all media are 

minimised’. However, in seeking to achieve this, it advocated important quantification measures. 

Following the preparation of the 2002 TEAP Task Force Report on Destruction Technologies, the 

Code of Good Housekeeping was updated in the 2003 TEAP Progress Report to include the new list 

of Approved Technologies and also to provide a broader coverage of the handling of issues 

surrounding the management of dilute sources (foams). In the process of this update, a level of 

concern developed amongst Parties over the use of the word ‘standards’ in the draft text. It was 

recognised that a distinction needed to be drawn between the ‘technical capability’ of a process and its 

measured day-to-day performance, which could be either side of a mean value. The primary rationale 

for this change was that the TEAP, TOCs and Task Forces are not standards setting bodies and there 

is a need to allow some flexibility for Governments and other standards setting authorities to select 

minimum standards that reflected the variations around the mean values associated with technical 

capability. For this reason the text of the Code is non-prescriptive in its entirety. Whilst this serves to 

provide Governments with the comfort needed, it acts against the idea of using the Code of Good 

Housekeeping itself as a verification tool. 

As noted earlier, the Code also straddles the dual challenges of both minimising emissions and 

quantifying destruction. The following table highlights the main activities covered in the current Code 

and their impact on both maximising and quantifying destruction: 
78 TEAP May 2011 Progress Report

Procedure Minimise Emissions Quantify Destruction 

 

1. Pre-delivery Yes* No 

2. Arrival at the facility Yes Yes 

3. Unloading from delivery vehicle Yes No 

4. Testing and verification Yes Yes 

5. Storage and stock control Yes Yes 

6. Measuring quantities destroyed No Yes 

7. Facility design Yes No 

8. Maintenance Yes No 

9. Quality control and Quality Assurance Yes Yes 

10.Training Yes Yes 

11.Code of transportation Yes No** 

12.Monitoring Yes Yes 

13.Measurement of ODS No Yes 

14.Control Systems Yes Yes 

15.Performance measurements Yes Yes 

16.Suggested substances for declaration Yes No 

* by establishing detailed ‘chain of custody’ and appropriate practices 

**unless a quantitative declaration is required from the customer 

5.5.3 Further Verification Needs for Quantifying Destruction 

The basic quantification of the ODS destroyed is, of course, achieved at the destruction facility. Many 

would argue that ‘some destruction is better than no destruction’ and there is a case for this line of 

argument based on the alternative of ‘no destruction’. However, for a reputable organisation such as 

CAR or VCS, it would be important not to be associated with projects that were poor in their chains 

of custody, since this would cast doubt on both the validity of any baseline calculations and the duty 

of care exercised in minimising emissions in the supply chain to the destruction facility. 

This said, the means of satisfying any project verifier of chain of custody issues is likely to remain 

qualitative rather than quantitative unless a decision is taken to introduce minimum Recovery and 

Destruction Efficiencies or something similar. 

In conclusion, the focus of concern for those developing project protocols and methodologies is to be 

sure that destruction occurs appropriately and that quantities of destroyed ODS are known by product 

type either on their own, in blends or in products. These are all items that can be achieved by applying 

the Good Housekeeping practices described in the Code, but the ability to verify that those practices 

have been observed requires something stronger. Effectively, if verification is to be achieved, there 

needs to be the opportunity to audit the paper trail retrospectively and/or carry out spot checks on 

physical deliveries. In order to fulfil normal verification procedures, these audits would typically be 

carried out by third party auditors or verifiers. A possible text for such requirements is set out in the 

draft Voluntary Annex attached to this section. 
TEAP May 2011 Progress Report 79

5.5.4 Use of a Voluntary Annex for Verification Purposes 

The purpose of a Voluntary Annex to the Code is to provide a separation between the Code of Good 

Housekeeping statements on ‘technical capability’ and the verification procedures necessary to ensure 

minimum standards of verified destruction are achieved. The rationale for making the Annex 

voluntary is to allow for destruction facilities anywhere in the world to actively participate in 

destruction projects under the Climate Action Reserve (CAR), Voluntary Carbon Standard (VCS) and 

other relevant destruction protocols that either already exist or may emerge in the future. The criteria 

in either instance are no different from those contained in the Code of Good Housekeeping. The 

purpose of such a Voluntary Annex is simply to strengthen the verification procedures by shifting the 

burden of proof to the destruction facilities and project proponents themselves. 

It should be stressed that Section 5.6 that follows is only an outline of how such a Voluntary Annex 

might look and is not intended as a formal proposal from TEAP or its Task Force. This is made 

available for possible discussion by Parties at the thirty first Open Ended Working Group Meeting and 

any further inter-sessional work deemed appropriate ahead of the twenty second Meeting of the 

Parties. 

5.6 Possible Text for a Voluntary Annex to the Code 

Compliance with this Voluntary Annex offers destruction and other reversible transformation 

facilities around the world a route to pre-qualify for participation in ODS destruction projects that 

are eligible under selected ODS protocols. These include, but are not limited to, the protocols of the 

Climate Action Reserve and the Voluntary Carbon Standard. 

The Code of Good Housekeeping contains a list of Approved Destruction Technologies which qualify 

according to their respective technical capabilities. However, in order not to limit the autonomy of 

Parties to set their own national minimum performance criteria, no minimum standard is prescribed. 

To comply with this Annex, the destruction facility needs to positively demonstrate performance and 

practices that ensure that the technical capabilities of the technology are consistently achieved. The 

requirements are listed under the following five headings: 

Chain of Custody 

The destruction facility shall put measures in place to ensure that verifiable, written declarations of 

quantified ODS content are provided by customers on all shipments arriving at the facility, where the 

ODS is in a pure form, in blends (including contaminated sources) or in products containing ODS. To 

determine the actual weight of the ODS content, the following information shall be recorded: gross 

weight of each container, tare weight of the container, weight of the contents, type of scale used 

(including calibration history and scaling error) and the date of weighing. Information on the mode of 

transport and distances shipped should also be made available. 

Because recovered ODS may contain a wide range of contaminants such as oil, water, other 

substances, the destruction facility shall address any up-front preparation of material for destruction 

that may be necessary because of these unknowns 

The destruction facility shall be capable of handling the likely variation in container sizes and be able 

to introduce the ODS contents into the feed stream of the destruction facility. NOTE: Some cylinders 

do not have dual port valves: if liquid product is to be removed in lieu of vapour, the cylinder must be 

inverted. 

Analysis of the contents of each shipment shall be available for retrospective inspection or audit and 

records shall be kept available for a minimum of [5] years following the processing of the said 

shipment. 
80 TEAP May 2011 Progress Report

Access shall be given to provide for the conduct of ‘spot checks’ on shipments as received by the 

destruction facility. A spot check shall take place at least once in every six months. 

Customers shall be encouraged to assist project developers in establishing the baseline emissions 

scenario for the waste stream in question, although the project developer shall retain ultimate 

responsibility for the presentation of the baseline scenario within a project preparation document 

(PPD). 

Estimates of emissions in the chain of custody shall be made for each shipment based on best practice 

at the time and shall be documented by the project developer. 

Where shipments have crossed national borders, the project developer shall be responsible 

documenting compliance with all cross-border regulations (e.g. the Basel Convention, where relevant) 

and this shall be open to verification by the project verifier. 

The destruction facility shall provide a means of removing any waste/bi-product created during the 

destruction process, including the transfer of the waste/bi-product to a licensed disposal site and 

disposal of empty non-reusable containers. 

Destruction Criteria 

The destruction facility shall ensure that its plants meet the performance criteria set out in the 

Approved Technologies List or the national minimum standard, whichever is the more stringent, and 

shall organise third party independent verification of this at least once in every [three] years. These 

criteria will include both relevant DRE values and maximum International Toxic Equivalency 

Quotient (ITEQs) of relevant classes of pollutants. The outputs shall be reviewed by the project 

verifier. 

Where a rigorous national minimum standard for destruction facilities may not exist or where 

compliance and enforcement of such a standard is poor or questionable, the destruction facility may 

conduct a destruction trial analysis: a specified quantity of the received ODS contents shall be 

processed into the destruction system over a sufficient duration period for destruction/conversion to 

take place and to evaluate the feasibility of using the technology; process streams are sampled before, 

during, and after processing and analysed to demonstrate the destruction of ODS; the fate of fluorine 

and chlorine in the system is determined; and confirmation is made that no reformation of chlorinated 

and fluorinated Volatile Organic Compounds (VOCs) occurred. An independent laboratory will 

oversee the trial destruction process to ensure collection of relevant process data, will review all data 

output during the process, and may collect samples for off-site laboratory analysis. 

The destruction facility shall also permit the conduct of ‘spot checks’ on these criteria by a competent 

authority or Third Party Auditor in their jurisdiction within [one] week of notification. 

The means of demonstrating compliance shall be through the development and implementation of a 

suitable Monitoring and Operations Plan, as currently defined in the CAR protocol. 

Detailed records of energy use within the destruction facility shall be maintained for a minimum of 

[3] years and provide information on quantity, fuel type and calorific value (e.g. from fuel purchase 

receipts, electricity bills etc.) 

The minimum DRE shall be commensurate with the form of ODS being processed (concentrated 

versus dilute) and shall be confirmed by the project verifier. 
TEAP May 2011 Progress Report 81

Avoidance of Fugitive Emissions 

The Destruction Efficiency (DE) for concentrated sources shall be no less than [98%] 

For dilute sources such as foams, the Recovery and Destruction Efficiency RDE shall be no less than 

[85%] 

As appropriate, the destruction facility shall ensure that the DE and/or RDE is assessed at least once 

in every [three] years for routine shipments. 

For shipments arriving from new sources or containing new products, the first shipment shall have an 

assessment of the relevant criterion. This shall be repeated at least [one] further time within the first 

[ten] such shipments. 

Destruction facilities will take all reasonable care to minimise on-site emissions in accordance with 

the principles set out in the Code of Good Housekeeping and the measures so taken shall be overseen 

by the project verifier. 

Measurement and Recording of Quantities

Estimates of emissions in the chain of custody shall be made for each shipment based on best practice 

at the time. Actual measurements or justification for use of an overall emissions factor may be 

provided to meet this requirement. Likely point sources of emissions in the chain of custody include at 

recovery, decanting (if needed), consolidation / transfer to storage tank, transport, handling, and 

storage. 

From the assessment of the chain of custody information, the fugitive losses on site and the relevant 

destruction and removal efficiencies, the destruction facility shall derive its estimate of destroyed 

ODS for each shipment. This will be supported by physical measurements at the two points 

highlighted in the Code of Good Housekeeping. 

The quantities of destroyed ODS shall be recorded by type and, as appropriate, provided to the project 

verifier in order that they can then be weighted by their global warming potentials (SAR?) to 

determine the carbon equivalent emissions avoided. 

Records shall be kept for a period [five] years or for the period stated in the relevant project 

documents, whichever is the greater. 

Qualifications for Project Verifiers and other Third Party Auditors 

All Project Verifiers operating under this Annex shall be companies or individuals with at least [two] 

years’ experience in the verification of carbon projects and the project leaders shall carry appropriate 

professional qualifications. 

All Third Party Auditors covering the technical performance of destruction facilities under this Annex 

shall have at least [five] years’ experience in auditing similar destruction facilities and the project 

leaders shall carry appropriate professional qualifications. 

In keeping with the concept of pre-qualification, nothing in this Annex guarantees the acceptance of a 

destruction facility for a specific project. Protocol developers will be fully within their rights to set 

more stringent criteria as circumstances dictate and may also require specific demonstrations on the 

particular ODS to be destroyed. 

 

TEAP May 2011 Progress Report 83

6 HTOC Progress Report 

The Halons Technical Options Committee (HTOC) does not plan to meet in 2011 unless issues are 

raised at the 31st meeting of the Open Ended Working Group that would necessitate a meeting. The 

Committee’s next meeting will most likely be in the first quarter of 2012. The following is the update 

for 2011. 

6.1 Alternative Agents 

Testing of the new alternative agents/technologies mentioned in the 2010 HTOC Assessment report 

continues. 

Water mist technologies continue to evolve. Recently commercialised innovations include: new 

atomisation technology using two-fluid system (air and water) to create ultrafine mist with spray 

features that are adjustable by changing the flow ratio of water to air, and water mist combined with 

nitrogen to gain extinguishing benefits of both inert gas and water mist. 

Development continues on the use of pyrotechnic products to generate nitrogen or mixtures of 

nitrogen and water vapour, with little particulate content, for use in total flooding fire extinguishing 

applications. 

One chemical manufacturer is developing unsaturated HFC compounds for various uses including as 

total flooding fire extinguishing agents. The molecules of these chemicals have short atmospheric 

lifetimes and, therefore, low values of GWP. 

The development and testing of the unsaturated hydrobromofluorocarbon (HBFC) 3,3,3-trifluoro-2-

bromo-prop-1-ene for use as a halon 1211 replacement in the aviation industry continues. 

A second fluoroketone is under development aimed at replacing halon 1211 (and possibly halon 2402) 

in streaming applications. 

Phosphorous tribromide, PBr3, is an effective fire extinguishant in part due to its bromine content but 

it poses little risk to stratospheric ozone. The agent decomposes rapidly in the atmosphere and it has 

been commercialised for use as a fire extinguishant in one small aircraft engine application. 

A novel non-corrosive and low toxicity water-based agent that employs multiple salts to achieve a 

very low freezing point (-70°C) without the use of glycols has been introduced. It goes under the trade 

name of Aquagreen XT, and has excellent fire extinguishing effectiveness that includes film-forming 

capability. Initial commercial applications are as fixed local application systems in industrial vehicles 

such as mining and forestry, but it could have military applications as well. 

6.2 Halon 1301 Use as a Feedstock 

Halon 1301 (CF3Br) continues to be produced in China and France for use as a feedstock in the 

manufacture of the pesticide Fipronil. The total halon production quantities in these countries are 

unknown to the Committee but have been increasing annually in China since 2005. 

6.3 Halon Recovery and Recycling in Article 5 Countries 

In India, currently the military and offshore oil platforms have the major demand for halons, although 

a small quantity of halons (about 1 MT) is in use for the servicing of civil aircraft. However, the major 

airlines are sourcing halon and having equipment serviced abroad. The main sources of halon 1301 

within India come from shipbreaking and industry decommissioning. In the past year, shipbreaking 

has yielded approximately 25 MT of halon 1301 and 10 MT of halon 2402. The decommissioning of 

industrial systems, e.g., from the power sector, is picking up, but the lack of suitable recycling 
84 TEAP May 2011 Progress Report

facilities and testing laboratories is hampering progress. Of concern is the fact that halon 1301 is 

recovered by private fire industry companies who are then selling the halon to end users without 

proper purification and testing. Halon 1211 is now in short supply, similar to the previously reported 

situation with halon 2402. 

In China, halons recovered from decommissioned equipment are now classified as a hazardous waste. 

Recovery and recycling therefore require a hazardous waste management license. The companies who 

were supposed to collect and recycle the halons do not have such a license and appear to have limited 

interest in handling hazardous wastes. This has hampered efforts to export the halon to other Parties. 

6.4 Contaminated Recycled Halons 

Over the past year, the HTOC has been working closely with ASTM International (formerly known as 

the American Society for Testing and Materials) to fast track a halon 1211 Standard for use by 

recyclers and testing laboratories. This Standard, D7673, is now available and the HTOC recommends 

strict adherence to this and other international halon specifications/standards to avoid the potential 

risks from reduced fire extinguishing performance or increased agent toxicity from contaminated 

recycled halons. 

6.5 Update on the Response to Decision XXI/7 

The HTOC continues to work with the International Civil Aviation Organization (ICAO) on requiring 

the phase-out of the use of halons on new aircraft. On 16 November 2010, the ICAO Air Navigation 

Commission (ANC) considered proposals that were supported by the HTOC to amend their Chicago 

convention Annex 6 — Operation of Aircraft, Part I — International Commercial Air Transport — 

Aeroplanes, Part II — International General Aviation — Aeroplanes and Part III — International 

Operations — Helicopters and Annex 8 — Airworthiness of Aircraft to establish requirements and 

timeframes for the replacement of halon fire extinguishing agents. The proposal included language 

supporting the use of alternatives that cause the least amount of impact to the environment while 

performing the specific fire protection applications for which the equipment was designed. 

The ANC agreed that the proposals should be transmitted to ICAO Member States and appropriate 

international organizations for comment. State letter AN 3/25.1-10/75, dated 

17 December 2010 was sent with a due date for replies of 1 March 2011. 

By 1 March 2011, 45 replies had been received from 42 States (including eight Council Member 

States), and three international organizations. By 1 May 2011, 57 replies had been received from 54 

States (including 16 Council Member States), and three international organizations. 

The vast majority of replies indicated broad support for the proposed amendment. However, China 

and the Russian Federation provided Disagreement with Comments, known as “DC” in the ICAO 

process. 

The comments from the Russian Federation in their DC indicate that they have concerns that requiring 

the mandatory introduction of halon alternatives in new aircraft within the specified timeframes would 

have a large financial impact on the industry and that considerable time would be needed to 

implement the requirements. They proposed reducing the requirement from a mandate to a 

recommended practice only. In previous meetings and discussions at ICAO in which the Russian 

Federation representative was present, the Stakeholders group, which includes ICAO Member States, 

HTOC, Industry and Industry Association representatives came to the conclusion that the 

recommended practice approach was not the best approach and that the financial burden and 

timeframes recommended were manageable. 

On 2 May 2011, the HTOC co-chair met with the ICAO Secretariat and the ANC member from the 

Russian Federation to assist in resolving their concerns. The HTOC has offered its co-chair from the 
TEAP May 2011 Progress Report 85

Russian Federation to provide assistance within the Russian Federation to explain the HTOC position 

and provide additional information as needed. The HTOC has also informed the ANC member from 

China, through the ICAO Secretariat, that they have a member of HTOC from their Civil Aviation 

Authority who would be a good internal resource to assist them with information and coordination of 

any future questions. 

The ANC met on 3 May 2011 to take up the comments and decide upon the final path forward. An 

HTOC co-chair was invited by the ICAO Secretary General staff and participated in the meeting. The 

ICAO Secretariat concurred with moving forward as originally proposed. The DCs from the Russian 

Federation and China were not found to be persuasive and the ANC agreed as follows. 

• the proposed amendments to Annex 6, Parts I, II and III as contained in Appendix B to State 

letter AN 3/25.1-10/75 and as modified by action taken to resolve comments received to date 

will go forward to the Council for approval; 

• the proposed amendments to Annex 8 as contained in Appendix C to State letter AN 3/25.1-

10/75 and as modified by action to resolve the comments received to date will go forward to 

the Council for approval; 

• the proposed amendments to Annex 6, Parts I, II and III should become applicable on 15 

December 2011; 

• the proposed amendment to Annex 8 should become applicable on [date of adoption + 3 

years]; and instruct the Secretary regarding the preparation of the draft report to Council. 

Agreement by the Council is the final step in mandating the replacement of halons in civil aviation. 

The Council is scheduled to meet the week of 13 June 2011. An HTOC co-chair has been invited by 

the ICAO Secretary General staff and will attend the meeting to participate in the discussions to 

support moving forward on the resolution as proposed. Final results of the Council meeting and 

overall ICAO progress will be included in the TEAP / HTOC update during the Open-ended Working 

Group in August 2011.

TEAP May 2011 Progress Report 87

7 MBTOC Progress Report 

Since MBTOC recently published its 2010 Assessment Report, this report focuses only on those areas 

where there are new developments, and areas where further analysis is relevant at this time. 

7.1 Quarantine and Pre-shipment (QPS) 

This section provides and update on consumption of methyl bromide for QPS, information on recent 

developments in the International Plant Protection Convention (IPPC) on phytosanitary activities 

relevant to the methyl bromide phase out, examples of recent legislative changes and clarifications, 

examples of alternatives to methyl bromide being used and a summary of R&D to find alternatives to 

methyl bromide for key uses. 

7.1.1 Consumption of Methyl Bromide for QPS 

The consumption of methyl bromide for QPS showed increased consumption reported by Parties from 

“Asia” and “Western Europe and Others” groupings (Fig. 7-1). 

Figure 7-1: Consumption of methyl bromide for QPS from 1999 to 2009 according 

to regional groupings 

The “Western Europe and Others” Group comprises 29 entities including 16 States in the European 

Union, 9 Parties (Australia, New Zealand, European Union, Holy See, Iceland, Norway, Switzerland, 

USA) and 4 principalities. The trend downwards from 2006 to 2008 in this Group was reversed in 

2009 mainly by the USA that reported a 73% increase in methyl bromide consumed for QPS. 

The “Asia” Group comprises 56 Parties including China, Republic of Korea and Israel. In 2009 

compared to the consumption reported in 2008, the Republic of Korea doubled its consumption and 

Israel increased its consumption 15-fold, which were the main reasons for the reversal of the 

downward trend from 2007 to 2008. China’s continued export trade during the global crisis in 2009 

did not result in an increase in methyl bromide for QPS as China reported a decrease in 2009 

compared to 2008. 
88 TEAP May 2011 Progress Report

The overall trend in QPS consumption for non-Article 5 and Article 5 Parties that reported methyl 

bromide consumption for QPS is shown in Figure 7-2. The global trend shows a general increase over 

the past 10 years in MB consumed for QPS in Article 5 Parties (blue line), and a general decrease 

over the same period in non-Article 5 Parties (red line). The consumption of MB for QPS in 2009 

was about the same in Article 5 Parties and non-Article 5 Parties (blue and red lines). 

The global consumption (green line) showed an increase in methyl bromide consumed for QPS in 

2009 compared to 2008, due to an increased consumption in non-Article 5 Parties. There were 27 

non-A5 Parties that reported QPS consumption between 1999 and 2008. Of these, 16 Parties (59%) 

have reported every year and 6 (22%) 6-10 times in this period. The frequency of reporting by the 

majority of the non-A5 Parties that consume methyl bromide for QPS provided confidence in the 

trend lines shown in Figure 7-2. 

Figure 7-2: Consumption of methyl bromide for QPS from 1999 to 2009 in Article 5 (blue), 

non-Article 5 (red) and for all Parties (green) 

7.1.2 International Plant Protection Convention 

The IPPC is an international agreement that aims to protect cultivated and wild plants by preventing 

the introduction and spread of pests mainly during trade of commodities. The IPPC supports the 

development of International Standards for Phytosanitary Measures (ISPMs), which are the 

standards, guidelines and recommendations recognized as the basis for phytosanitary measures. Some 

of these standards include procedures that can replace or avoid the use of MB for use in quarantine. 

The Commission on Phytosanitary Measures (CPM) governs the implementation of the IPPC. The 

CPM meets annually and provides a forum for the discussion of international plant protection issues 

and sets the annual programme of work for the IPPC. The sixth session of the CPM (CPM-6) was 

held in Rome 14-16 March 2011. There were three documents on the CPM agenda that aimed to 

reduce or eliminate the consumption of methyl bromide1

, which were therefore also relevant to the 

Montreal Protocol: 

 

1

 Documents for the meeting are stored on https://www.ippc.int/index.php?id=13330&L=0
TEAP May 2011 Progress Report 89

• Report of the CPM Informal Working Group on Strategic Planning 

• IPPC Standard setting, topics and priorities 

• IPPC Strategic Framework 2012-2019 

7.1.3 Report of the CPM Informal Working Group on Strategic Planning 

Despite staff and financial resource constraints, the IPPC set as a high priority the establishment of 

standards for “...plants for planting, new ISPM 15 treatments that are alternatives to methyl bromide, 

international movement of wood, soil and growing media...”2. These are also topics that are relevant 

to the Parties to the Montreal Protocol. Standards for these activities that contain options to not use 

methyl bromide will increase the possibility of using alternatives and reduce the consumption of 

methyl bromide. 

7.1.4 IPPC Standard Setting, Topics and Priorities 

Standards are established according to formal procedures that involve work undertaken by Technical 

Panels and Expert Working Groups. The IPPC follows five steps to adopt a new or a revised 

standard, which is summarised in Figure 7-1. It typically takes 4-5 years from “start to adoption” of a 

standard. 

The outcome of their work is considered in formal consultations with relevant organisations and the 

CPM. So far these procedures have resulted in 

34 ISPMs that have been adopted. 

7.1.5 Technical Panels and 

Expert Working 

Groups 

Five Technical Panels and one Joint Panel are 

undertaking work that aims to provide 

information that can lead to new or revised 

ISPMs: 

• Technical Panel on Phytosanitary 

Treatments (TPPT) 

• Fruit fly treatments (20) based on heat 

and cold treatments 

• Irradiation treatments (3 species) and 

one generic dose for all insects except 

lepidopteran species in the host 

• Treatments for soil and growing media in association with plants 

• Technical Panel on forest quarantine (TPFQ, 7 topics) 

• Joint Panel on treatments for wood packaging material (TPPT / TPFQ, 5 treatments) 

• Technical Panel on the Glossary of Phytosanitary Terms (TPG, 35 terms under consideration) 

• Technical Panel on pest free areas and systems approaches for fruit flies (TPFF, 5 topics) 

 

2

 CPM 2011/INF/7: Summary Report of the 12th Meeting of the CPM Informal Working Group on Strategic 

Planning and Technical Assistance. 

Figure 7-3: Steps to revise or develop a 

standard 
90 TEAP May 2011 Progress Report

• Technical Panel that develops Diagnostic Protocols for specific pests (TPDP, 31 topics 

divided into Bacteria, Fungi, Insects and mites, Nematodes, and Plants) 

In addition to the Panels, there are 25 Expert Working Groups that specialise in the development of 

documents to address a wide range of pest control measures and practices. Altogether there are 146 

specifications under development by the Panels and Expert Working Groups that could lead to new or 

revised standards3

 (see Table 7-1 below for examples of five specifications under development). 

Standards adopted by the CPM may result in a decrease in the use of methyl bromide if the standards 

that result from this work include MB-free options and if they are adopted for post-harvest pest 

control by countries. The standards are voluntary and can be useful guidance for Parties wishing to 

establish a phytosanitary agreement for new trade, or for establishing the appropriate protocols for 

existing trade. The level of risk mitigation varies according to the requirements of the importing 

country, and may be less than the level recommended in the standard. The activities toward 

development of the standard specifications undertaken by the Technical Panels and the Expert 

Working Groups that are most relevant to Montreal Protocol are summarised below. 

Technical Panels on Forest Quarantine / Phytosanitary Treatments 

The TPPT/TPFQ has examined additional treatments for ISPM-15, which is the Standard describing 

phytosanitary measures that reduce the risk of introduction and spread of quarantine pests associated 

with the movement in international trade of wood packaging material. The TPPT/TPFQ: 

Submitted a draft ISPM to the Standards Committee in November 2010 for the separate use of 

microwave irradiation and sulfuryl fluoride for disinfesting wood packaging material; 

Submitted a revised version of ISPM-15 for Country Consultation in June 2010, which is projected 

for adoption by the CPM in 2012. This contains revised and expanded guidelines for heat treatment, a 

correction of an inconsistency between the text on methyl bromide and the Annex in ISPM-15, and 

provision for sulfuryl fluoride and microwave irradiation treatments as alternatives to heat and methyl 

bromide-based treatments. Annex 1 is projected for adoption by the CPM in 2013; and 

Requested further information on the following proposed treatments for wood packaging material: 

methyl isothiocyanate and sulfuryl fluoride (Ecotwin mixture); Hydrogen cyanide; and methyl iodide. 

All of these treatments have been given “high priority” because of the need to add other treatments to 

ISPM-15. ISPM-15 specifies the use of debarked wood heated to a minimum temperature of 56°C 

continuously for at least 30 minutes. Alternatively, methyl bromide can be used according to the 

treatment schedule provided in ISPM-15. However, National Plant Protection Organisations (NPPOs) 

are required by the IPPC to take into account a previous CPM Recommendation “Replacement or 

reduction of the use of methyl bromide as a phytosanitary measure (2008)”, which encourages NPPOs 

to promote the use of heat rather than use methyl bromide for WPM. The work of the joint 

TPPT/TPFQ panels on alternatives to methyl bromide and heat for wood packaging material is 

summarised in Table 7-1

 

3

 CPM 2011/6: IPPC Standard setting topics and priorities 
TEAP May 2011 Progress Report 91

Table 7-1: Work being undertaken by the joint TPPT/TPFQ Panels 

Process Priority Wood packaging material 

treatment s

Body Added to work 

pgm

Status

Special High Microwave irradiation of wood 

packaging material (WPM) 

TPPT (TPFQ) SC 1-5 

November 2010 

Draft ISPM to SC for 

Member Consultation

Special High Sulfuryl fluoride fumigation of 

WPM 

TPPT (TPFQ) SC 1-5 

November 2010 

Draft ISPM to SC for 

Member Consultation

Special High MITC and SF (Ecotwin mixture) 

fumigation for Bursaphelenchus 

xylophilus, Coleoptera: 

Cerambycidae, and Coleoptera: 

Scolytinae of WPM

TPPT (TPFQ) SC 1-5 

November 2010

Additional data 

requested from 

submitter

Special High HCN treatment of WPM TPPT (TPFQ) SC 1-5 

November 2010

Additional data 

requested from 

submitter

Special High MI fumigation for 

Bursaphelenchus xylophilus and 

Coleoptera: Cerambycidae of 

WPM

TPPT (TPFQ) SC 1-5 

November 2010

Additional data 

requested from 

submitter

Source: IPPC 2011. 

Despite the widespread implementation of heat treatment facilities in Article 5 and non-Article 5 

countries, some of them have not installed heat treatment facilities1 and they do not have access to 

non-wood packaging material2. Therefore, alternatives to heat and methyl bromide in ISPM-15 are 

needed in a revised ISPM-15 standard as soon as possible. 

Additionally, alternative treatments to methyl bromide are needed for treating wood packing material 

in shipping containers that are already loaded with goods, and that have been stamped with the ISPM15 compliance mark in anticipation of a successful heat treatment. Stamping before treatment is 

allowable under some interpretations of the ISPM-15 standard. 

Technical Panel Working on the “Glossary of Phytosanitary Terms” 

The Technical Panel that is working on the Glossary of Phytosanitary Terms (TPG) is considering 

revisions to 34 phytosanitary terms e.g., host susceptibility, pest freedom. One of TPG’s areas of 

work is particularly relevant to the Montreal Protocol, as it concerns an examination of the 

“Terminology of the Montreal Protocol in relation to the Glossary of Phytosanitary Terms”. The 

TPG has compared the definitions used in the Montreal Protocol with those used in the Glossary of 

Phytosanitary Terms by the Parties to the IPPC. The TPG reported on the degree of overlap between 

the Montreal Protocol and the Glossary terms, and noted definitions that had insufficient or no overlap 

in the terminology used by the IPPC and the Montreal Protocol e.g. pre-shipment. The work 

undertaken by the TPG on Terminology of the Montreal Protocol is under consideration as an Annex 

to ISPM-5 “Glossary of Phytosanitary Terms”. A draft was circulated to the Standards Committee 

for Member Consultation. The Ozone Secretariat, with input from the MBTOC, reviewed the draft 

and provided comments. Member consultation on the draft terms is expected to begin in June 2011. 

During that consultation, the Parties to the Montreal Protocol will be able to provide comments at the 

national level through their Convention contact points. The Ozone Secretariat will keep the Parties 

 

1

 TEAP. 2009. QPS Task Force Report. A5 facilities Pp 84 ; Non-A5 Pp 52. See also page 99 of TEAP 2010 

Progress Report; There are more than 6,000 certified heat treatment facilities deployed globally (Dec XXI/10 2009) 2

 TEAP. 2009. QPS Task Force Report. Pp 75-76. 
92 TEAP May 2011 Progress Report

informed of the process3.. A revised ISPM-5 is projected for adoption by the CPM in 2013. The 

implications of this work on the definitions of QPS used in the Montreal Protocol, and any actions 

that the Parties to the Montreal Protocol may wish to consider as a result of the work, were not 

discussed in the reports circulated by the IPPC for Country Consultations. 

Technical Panel on Phytosanitary Treatments 

The TPPT is considering twenty treatments to control fruit flies using heat (vapour, high temperature 

forced air) and cold storage conditions. All of them have been given high priority for development. 

However, additional data have been requested for nineteen of them and only one has been completed 

as a draft ISPM that has been sent to the Standards Committee. Fruit flies are not typically controlled 

with methyl bromide and therefore ISPM treatments for fruit fly control will generally have little 

impact. 

Other treatments under development include irradiation treatments. These have progressed further 

than the heat and cold treatments, as two have been recommended for adoption by the CPM in 2011, 

and one has been transmitted for Country Consultation and for adoption in 2012. The ISPM under 

development as a generic irradiation dose for all insects except lepidopteran species in the host 

requires additional data before it can be submitted for the consideration of the Standards Committee. 

All of the work on these irradiation treatments has been given high priority for development. In some 

instances, irradiation treatments may be an alternative to QPS MB treatments. 

The TPPT is considering the development of an ISPM for “treatments for soil and growing media in 

association with plants”. In the Montreal Protocol, treatments to control soil pests associated with soil 

on nursery plants to meet certification standards accounted for about 25% of the total QPS 

consumption reported by non-Article 5 Parties4. Because the high consumption of methyl bromide 

for QPS for soil and growing media in association with plants, the Parties to the Montreal Protocol 

may wish to invite the IPPC to consider raising the priority to from ‘normal’ to ‘high’ for this aspect 

of the work of the TPPT. 

Expert Working Group Examining Actions to Minimise the Risk of Quarantine Pests in Stored 

Products 

An Expert Working Group is examining actions that can be taken to minimise the risk of quarantine 

pests associated with stored products in international trade. Their work is expected to contribute 

toward an ISPM on this topic. Specifications with comments have been submitted to the Standards 

Committee. The projected adoption date for the ISPM entitled “International Movement of Grain” 

has not been determined. In 2009, there was substantial global consumption of methyl bromide for 

grain disinfestation of about 12% (1300 tonnes) annually5

. 

7.1.6 IPPC Strategic Framework 2012-2019 

Parties at the CPM were invited to discuss and tentatively agree the 8-year IPPC Strategic Framework 

2012-2019, and to provide guidance on 4-year Medium Term Plan and 2-year Programme of Work 

and Budget that are included in the IPPC Strategic Framework.6

 The IPPC Strategic Framework 

replaces the current Business Plan, which expires in 2011. As the IPPC Strategic Framework contains 

information relevant to the use of methyl bromide used for pest control, the main parts of the 

Framework relevant to the Montreal Protocol are summarised. The IPPC’s strategic objectives for 

2012–2019 are to: 

 

3

 UNEP/OzL.Pro.WG.31/2; paragraphs 34 and 35. 

4

 MBTOC. 2010. Assessment Report, Section 6.13.2: Treatment of soil with methyl bromide to control pests 

in propagated plants. Page 257. 5

 TEAP. 2009. QPS Task Force Report, Table 4-6, page 40. 

6

 IPPC. 2011. IPPC: Strategic Framework 2012-2019. Agenda Item 13.5 of the Provisional Agenda for CPM6. CPM 2011/18. 
TEAP May 2011 Progress Report 93

• Protect sustainable agriculture and enhance global food security through the prevention of 

pest spread 

• Protect the environment, forests and biodiversity against plant pests 

• Create economic and trade development opportunities through the promotion of harmonised, 

scientifically-based phytosanitary measures 

• Develop phytosanitary capacity for members to accomplish A, B & C. 

A vast range of plant pests and diseases threaten global food production (including animal feed), the 

culture of forests and the wild flora of the natural environment. If pests can be prevented from 

establishing in an area, the resources used in prevention are invariably significantly lower than those 

needed for long-term control, containment, eradication (if possible) after introduction. The regulatory 

policy challenges to prevent pest establishment are shaped by global trade; environment and natural 

resources (including climate change); demographic trends; and food security. The IPPC: 

Acknowledged a reduction in international trade in the past few years due to the global financial 

crisis, but predicted that countries would emerge from the global downturn and exports would 

increase as governments seek a broader economic growth strategy; 

Noted that “...the ozone damaging effects of methyl bromide are now well known and documented, 

and alternative phytosanitary measures are encouraged (see IPPC Recommendation7

)...”; 

Predicted that population growth of middle class consumers in developing countries would generally 

be greater than those in developed countries, which would lead to more import and export of goods 

and increased risk to the environment from potential pest incursions; 

Considered that the availability of, and access to, adequate food supplies is a food security issue for 

many countries. Food security was affected by climate change, plant pests (including invasive 

species), trade, food aid, new production technologies and rural development; 

Noted that developing countries aimed to reduce dependence on food aid by increasing exports of 

locally produced food, which may require capacity development, technical assistance and trade 

promotion to reduce the risk of pests being accidentally shipped with the exports. 

Many of these challenges might be met by methyl bromide in the short term. The IPPC saw a role 

for NPPOs to address these policy challenges by concentrating their efforts on reviewing existing 

policies to meet the changing environment and risks. The IPPC cited the measures in place for methyl 

bromide in the Montreal Protocol, which required NPPOs to use combinations of alternative pest 

management measures and systems approaches for pest control. These approaches were being used 

more widely to “...counter increasing public opposition to traditional pesticide-based means of 

dealing with pest outbreaks and to allow countries to meet their obligations under the Montreal 

Protocol. These have increased the costs faced by governments in ensuring an equivalent level of 

phytosanitary protection provided by traditional, but environmentally damaging, treatments”. 

NPPOs safeguard agriculture, environment and natural resources from the negative impacts of pests, 

and thereby contribute to enhanced food security and open up trade opportunities for countries. The 

ISPMs provide the framework for the effective operation of an NPPO e.g. the establishment and 

operation of an import regulatory system, how to conduct pest risk analysis, and guidelines for 

surveillance, pest status and pest eradication. 

 

7

 “Replacement or reduction of the Use of Methyl Bromide as a Phytosanitary Measure” adopted as a 

Recommendation for the Implementation of the IPPC at CPM-3. UNEP/OzL.Pro.WG.1/28/INF/4
94 TEAP May 2011 Progress Report

Quarantine use is currently exempted from any control measures. However, TEAP periodically 

provides information to the Parties that may result in their re-evaluation of the exemption. Thus, the 

quarantine exemption could be modified or even eliminated in the future8

. The work of the IPPC 

would be an important factor in any decision taken by the Parties on QPS. The Parties to the 

Montreal Protocol can be kept abreast of the ongoing work of the IPPC according to previous 

Decisions9

 of the Parties that requested the Ozone Secretariat to strengthen cooperation and 

coordination with the IPPC Secretariat. 

7.1.7 Legislative Updates and Clarifications 

Brazil 

The Government of Brazil has confirmed their intention of ceasing all uses of MB for QPS purposes 

by 31 December 201510. (Controlled uses have been phased out entirely as of 2007). Brazil has 

achieved significant reductions in MB used for pre-shipment, and presently, over 70% of wood 

packaging materials (ISPM 15) are being treated with heat. Some quarantine uses still pose challenges 

for replacement with alternatives but research is underway in this respect. Brazil is also undertaking a 

more detailed analysis of amounts of MB used at present for QPS. 

Canada 

The government of Canada has declared that none of the nominations submitted to the Montreal 

Protocol in 2011 for strawberry runner production constitutes QPS in Canada, either for domestic or 

for export purposes11. The fumigation of strawberry plantlets does not fall under the definition of 

pre-shipment application because the soil is fumigated more than 21 days from shipment. Therefore, 

the treatment neither qualifies with the definition of pre-shipment as defined in the Montreal Protocol 

that requires shipment in less than 21 days after fumigation with methyl bromide, nor with Canada’s 

Ozone-depleting Substances Regulations (1998). The pests that are targeted by the fumigation are not 

pests identified by Canada as quarantine pests. 

The soil is fumigated in the context of normal agricultural practice to meet provincial phytosanitary 

requirements and industry-sponsored certification programmes which are quality assurance driven. 

The runner plants are produced under a quality management programme as the plants are intended to 

be used for berry crop production. The methyl bromide is used to aid production of healthy plants, as 

free as practicable from the endemic pest complement. Presently, these pests are not targeted for 

quarantine management or eradication programmes in Canada. For these reasons, Canada believes 

the nominations are consistent with the criteria governing critical use nominations and not QPS. 

European Union 

The European Union prohibits all uses of methyl bromide including those used for QPS from 19 

March 2010, in accordance with Regulation (EC) No 1005/2009 on ozone depleting substances which 

came into force12 on 1 January 2010. The prohibition in that Regulation was consistent with two 

earlier legislative measures in the EU that prohibited the use of methyl bromide as a biocide from 1 

September 2006, and Decision 2008/753/EC which prohibited the use of methyl bromide as a plant 

protection product under 91/414/EEC from 18 March 2010. Only substances that are listed in Annex 

1 of 91/414/EEC can be used in the EU, and since methyl bromide was not included it could not be 

used. Methyl bromide was prohibited because of its harmful effects on human health and in particular 

its effects on bystanders and on consumers. 

 

8

 Ragsdale and Vick. 2001. Pesticide Outlook, December 2001, p.248 

9

 Decisions XVII/15 (2005), XVIII/14 (2006) and Decision XX/6 (2008). 10 Oficio e nota técnica MAPA Protocolo de Montreal. Ministério da Agricultura, pécuaria é 

Abastecimento, Brasilia, Brasil, Nov 2010. 11 Canada. 2011. Nomination for methyl bromide CDN01_CUN13_Soil_Strawberry_Runners_PEI.doc 

12 Article 12(1) in Regulation (EC) No 1005/2009 on Substances that Deplete the Ozone Layer. 
TEAP May 2011 Progress Report 95

The prohibition on the use of methyl bromide was re-confirmed in February 2011 when the European 

Union decided to not accept a proposal to amend Annex I of Directive 91/414/EEC to allow the use 

methyl bromide for the treatment of wood packaging material in sea containers. The proposal was not 

accepted because the applicant did not address all of the concerns with its use, especially those related 

to the harmful effects on human health and in particular its effects on bystanders and on consumers13. 

Regulation (EC) No 1005/2009 allows the Commission to authorise the temporary production, placing 

on the market and emergency use of methyl bromide where unexpected outbreaks of particular pests 

or diseases14. The placing on the market and use of methyl bromide must also be exempted under 

Directive 91/414/EEC and Directive 98/8/EC. The Commission has not authorised any emergency 

uses of methyl bromide for QPS since methyl bromide was prohibited for all uses in March 2010. 

Japan 

The Japanese plant protection authority has published a revised plant quarantine regulation that 

establishes a new quarantine pest list and appropriate quarantine measures based on the pest risk 

analysis15. The risk of new quarantine pests is considered to be higher as a result of increased imports 

of plant products, trade partner and rapid international distribution. In addition, quarantine measures 

with scientific pest risk analysis are internationally required. The revised plant quarantine regulation: 

Lists 724 species quarantine pests. Interim quarantine pests that are undergoing pest risk analysis 

constitute 238 families of harmful animals and 362 genera and 2 taxa of harmful plants; nonquarantine pests are 194 kinds of animals and plants, including new 17 species. Most of these new 

species are scale insects, aphids and others that are normally fumigated with HCN and not methyl 

bromide. 

Excludes from the list pests that are widely distributed in Japan and considered not harmful. 

Requires enforcement of the regulation by the introduction of thorough quarantine measures, such as 

re-examination of imports from prohibited areas that might include banned plants, and/or requiring 

quarantine measures before export for quarantine pests that are difficult to detect on import e.g., 

inspection at cultivation area, heat treatment and precise identification. 

Generally, the increase in the number of non-quarantine pests as a result of the new regulation is 

expected to reduce the need for methyl bromide for QPS compared to the previous regulation. The 

revised plant quarantine regulation will come into force in September 2011. 

New Zealand 

Following a two year re-assessment of the controls on the use of methyl bromide for QPS, New 

Zealand’s Environmental Risk Management Authority (ERMA) decided in late 2010 to continue to 

permit the use of methyl bromide for the QPS treatment of imports and exports16. ERMA considered 

that a ban on methyl bromide was inappropriate because of a lack of alternatives for specific uses on 

imports and exports. Exports of unprocessed logs from New Zealand were expected to triple in the 

next 5 years17, which could increase the use of methyl bromide used for QPS. 

Continued use of methyl bromide in New Zealand was made conditional on putting in place practices 

to manage the indirect effects of methyl bromide on human health and the environment, including the 

requirement to install recapture equipment on fumigation facilities by 2020; setting non-occupational 

by-stander Tolerable Exposure Limits to methyl bromide for 24h (0.333 ppm) and 1h (1 ppm) 

 

13 Commission Decision 2011/120/EU of 21 February 2011. 

14 Article 12(3) of Regulation (EC) No 1005/2009 on Substances that Deplete the Ozone Layer 

15 MAFF-Japan. Nov 2010. http://www.maff.go.jp/j/syouan/keneki/kikaku/minaoshi-an.html In Japanese. 16 ERMA. 2010. Methyl bromide reassessment. HRC08002 Decision 28 October 2010. 17 OzoNews 2 November 2010. Article No. 6. 
96 TEAP May 2011 Progress Report

exposures; requiring reports of the concentration of methyl bromide in the air close to fumigation 

facilities; and imposing minimum buffer zones of 10-100 meters, depending on the quantity of methyl 

bromide being applied. 

ERMA strongly recommended further research on both methyl bromide recapture technology and 

alternatives to methyl bromide. Following ERMA’s recommendation, New Zealand committed to 

expenditure of US$1.85 million from government and industry sources from 2011 to 2016 on research 

that aims to meet phytosanitary requirements by either capturing methyl bromide or developing a 

replacement. “New Zealand hopes to significantly reduce the environmental harm from the use of 

methyl bromide by 2015”18. In the meantime methyl bromide was needed to meet the phytosanitary 

requirements of importing countries for New Zealand timber exports worth $2.2 billion a year. 

7.1.8 Procedures to Find Alternatives 

MBTOC has reported uses in the past where Parties have reported that alternatives to methyl bromide 

for QPS were not yet available19. Research and developed was reported to be underway to identify 

alternatives to replace methyl bromide for specific uses e.g., HCN for wood packaging material; or to 

develop practical treatments for those that had been identified e.g. sulfuryl fluoride treatment of food 

facilities; or to put in place a not-in-kind alternative e.g. non-wood pallets that cannot be infested by 

pests20. 

The availability of non-MB treatments for specific QPS uses may not be immediately apparent. A 

systematic search may be needed to find an alternative treatment that involves examination of 

alternatives in use, such as those located in the USDA-APHIS-PPQ Treatment Manual, Biosecurity 

Australia, Biosecurity New Zealand, Japan MAFF, European Plant Protection Organisation (EPPO), 

TEAP and MBTOC reports, proceedings of conferences, publications, unpublished studies and 

industry reports. Local pesticide registration databases may need to be examined to see if the 

treatment is authorised for use in the country where the treatment is to be carried out. 

As the procedures for finding an alternative may be generally useful to Parties, MBTOC has chosen to 

illustrate them using three examples. A summary of the search steps and the databases involved are 

provided in Table 7-4. 

Rice Seed 

Many countries require the seeds for rice for planting to be free of the nematode Aphelenchoides 

besseyi. It can exist in a dormant state in the seed. When the seed is planted, the nematodes become 

active and move to the growing points of leaves and stems where they feed externally. A. besseyi is 

present in Asia, America, Africa, Italy and others (MBTOC, 2002), and is classed as a quarantine pest 

by many quarantine authorities around the world. Contradictory information has been published on 

whether or not the pest is present in a particular country. Treatment of seed against seed-borne 

nematodes has been identified in the past as a use of methyl bromide without alternatives19. 

If A. besseyi is confirmed to not be present in the importing country, the first option is to obtain seed 

that has been certified as nematode free. Certified seed is normally available commercially from a 

range of suppliers. Some quarantine authorities prohibit the import of rice seed unless it is certified as 

free from A. besseyi. Importation of seed that is not certified free could result in the competent 

authority rejecting the consignment on entry, which means that it could be returned to the sender or 

destroyed. 

 

18 NZ News UK. 1 February 2011. Methyl bromide research funding welcomed. NZ Env. Minister Dr Nick Smith. 19 TEAP. QPS Task Force Report. Uses of methyl bromide where alternatives are not available, pp 76-79 

20 TEAP. QPS Task Force Report. Section 6.2.5.3 Not-in-kind alternatives for WPM, pp 75 
TEAP May 2011 Progress Report 97

Alternatively, imported non-certified seed could be disinfested with an alternative to methyl bromide. 

Methyl bromide is to be avoided as it is both ozone-depleting and can damage the germination of rice 

seeds at the required rates. A disinfestation treatment should be carefully selected that controls the 

pest with the least impact on germination. 

As a result of this search, a range of hot water treatments were found effective for controlling A. 

besseyi: Hot water immersion at 132.8°F (56°C) for 15 minutes is an approved quarantine treatment 

in the US21; Soaking in cold water for 24h, followed by immersion in hot water at 51-53°C for 15 

minutes22; Soaking in cold water for 3h, followed by hot water immersion at 52-57°C for 15 minutes, 

then dried to 14% moisture content23; Immersed at 40°C for 15-30 minutes, followed by 57°C for 10-

15 minutes24. The temperature and exposure times need to be precisely controlled to kill the 

nematode with minimal impact on rice seed germination. The level of risk mitigation may vary 

between treatments and be more or less acceptable to the importing country, according to the 

importance that the importing county attaches to rice production. 

Apart from heat treatments, soaking the seed in the fungicide Thiabendazole was also reported to 

control A. besseyi25. This treatment was not approved by competent authorities or rice organisations, 

and some countries may not authorise the use of a fungicide to control a nematode. 

This example illustrates the importance of avoiding the need for any treatment by importing seed that 

is certified to be free of the pathogen. Seed certified free of nematodes, as well as heat treatment and 

possibly Thiabendazole, are alternatives to methyl bromide. 

Military Vehicles 

Military vehicles are sometimes moved from one country to another for warfare or local security. 

When imported back to the country of origin following a tour of duty, disinfestation may be required 

to prevent quarantine pests being accidentally imported along with the vehicles. Detecting pests on 

military equipment can be challenging as the equipment contains many places where pests can hide. 

Spiders are particularly problematic pests because they can be quarantine pest that may also pose a 

risk to human health. Military vehicles imported into some countries can be infested with spiders of 

the genus Latrodectus, called widow spiders. The injection of neurotoxic venom from the female 

widow spider is particularly harmful to humans because of its unusually large venom glands. 

Different species of widow spiders can be found on every continent of the world except Antarctica. 

They are classified as a quarantine pest when a species of Latrodectus is accidentally imported to a 

country where it is not normally found. 

In this case, new military vehicles used for troop transport were imported into a country. On 

inspection they were found to be infested with widow spiders that were classified as a quarantine pest. 

Treatment with methyl bromide was not a preferred option for several reasons: methyl bromide is an 

ODS; spiders are tolerant of methyl bromide and require significantly more methyl bromide than most 

lepidopteran pests; and methyl bromide damages natural rubber-based materials which was an 

important component of the vehicles. 

Non-MB treatment options were considered, including the application of 1% SO2 / 6% CO2 mixture at 

> 16°C for 30 minutes. This is an approved treatment on grapes imported by New Zealand from the 

 

21 USDA-APHIS Treatment Manual 2011, Section 5-6-18, Treatment T559-2 

22 IRRI 1988, p.110. IRRI is the International Rice Research Institute 23 CGIAR 2010, p.2. CGIAR is an international agricultural research organisation 

24 EMBRAPA, the national agricultural research organisation of Brazil , based on Tenente et al 2006,p.241-242 25 Vuong & Rodriguez 1970 cited in Fortuner & Williams 1975, p.12 
98 TEAP May 2011 Progress Report

USA26. However, it was not an approved treatment for military vehicles infested with spiders, and 

therefore it was not immediately available for use. 

SF was also considered as another option as the lethal accumulated dose had been determined 

experimentally for the black widow spider L. hesperus27. However, this treatment was not recognised 

as an approved treatment in the importing country for military vehicles. 

Heat treatment can be an acceptable disinfestation treatment since the military vehicles are usually 

constructed to operate in adverse climatic conditions where the temperatures can exceed 55°C, which 

is the minimum temperature required for the rapid heat treatment. However, heat treatment facilities 

were not considered suitable as they were not large enough to treat the number of vehicles in the time 

available. 

Thirty candidate pesticides were screened for their potential to control the widow spider, their 

registration status, ease of use, environmental and human safety, and suitability for use on the 

vehicles. From this list, alpha-cypermethrin met these criteria and was selected for the treatment of 

the widow spiders in military vehicles. It also has a record of being used for the spot treatment of 

pests in stores, warehouses, industrial buildings, houses, apartment buildings, greenhouses and 

laboratories; on ships, railcars, buses, trucks and aircraft; and in non-food areas such as schools, 

nursing homes, hospitals, restaurants, hotels and in food processing plants28. 

This example illustrates that the use of methyl bromide was not necessary as a suitable pesticide was 

registered and available to control a spider pest on new military vehicles. 

Cotton Exports 

The cotton boll weevil (Anthonomus grandis) is recognized as a quarantine pest of cotton 

internationally. In many countries A. grandis is on the list of harmful organisms, such as EPPO’s “A1 

List” of pests where it is recommended for regulation as a quarantine pest. Certain plants or plant 

products that are associated with the cotton boll weevil are restricted, which aims to prevent the 

introduction into, and whose spread within, protected areas or zones. 

A country that wanted to import raw cotton requested the exporting country to apply a methyl 

bromide treatment, in compliance with the importing country’s regulation or policy, prior to exporting 

the cotton. The exporting country, however, showed the results of an EPPO survey conducted in 2006 

that showed A. grandis was not present. 

Typically, procedures acceptable to the importing country must be in place and carried out annually to 

demonstrate freedom from a pest. Although such procedures were not in place, and on the basis of 

the results of the survey carried out several years previously, the exporting country questioned the 

need for the treatment since the target of the restriction (A. grandis) did not appear to be present. 

Even if the pest was absent, the importing country still required the treatment with methyl bromide as 

this was a phytosanitary measure that governed the import of cotton. However, the exporting country 

was not able to use methyl bromide because it had been banned due to concerns with its harmful 

effects on human health. 

Normally, under these circumstances both countries would need to negotiate the terms and conditions 

for market access. The time needed to reach a successful agreement, and the conditions of any 

 

26 NZ Biosecurity. 2008. Import Health Standard. Procedures for the Management of Regulated Spiders Associated 

with the Importation of California Table Grapes (Vitis vinifera). 27 Thoms, E.M., and R.H. Scheffrahn. 1994. Control of pests by fumigation with Vikane gas fumigant (sulfuryl 

fluoride). Down to Earth, 49 (2): 23-30. 28 US-EPA. 1989. Pesticide Fact Sheet Number 199: Cypermethrin. US EPA, Office of Pesticide Programs, 

Registration Div., Washington, DC 
TEAP May 2011 Progress Report 99

agreement, were unlikely to be determined in the short term. In the meantime, the cotton was treated 

with phosphine and exported to other countries in order to avoid financial hardship for the cotton 

exporters and growers. Phosphine had been approved or recommended as a quarantine treatment for 

A. grandis in bulk cotton by the EPPO, the FAO and USDA-APHIS. EPPO had approved phosphine 

at a dosage of 1.3 gm-3 at >10°C for 72h29. FAO recommended methyl bromide or phosphine 

fumigation for raw cotton from countries where A. grandis occurs

30. USDA-APHIS had approved the 

use of phosphine at 1.27 gm-3 at 50°F for 72h as a quarantine treatment for A. grandis31. Approved 

treatments that did not use methyl bromide have been available for more than 8 years. 

This example shows that the conditions for exports based on area freedom from a quarantine pest 

requires an agreement on the protocol to demonstrate ongoing area freedom, such as surveys, 

reporting and records32. The time to agree the protocol and to change the importing phytosanitary 

requirement from methyl bromide to an alternative can take several years. Annual surveys to 

demonstrate area freedom can be an additional cost that the government or the industry are not willing 

to meet, and therefore a fumigation or other treatment at the port of exit can be more cost effective. 

In the meantime, an approved phosphine treatment was used to allow trade in cotton with other 

countries. 

Summary of Suggested Search Procedures 

The procedures that could be used to search for suitable alternatives require a search for them 

globally, in the region and in the relevant country. Various legislative checks would be made to 

“filter out” alternatives that were not applicable. The steps involved in the search are summarised in 

Table 7-2, with hyperlinks to the relevant documents. 

 

29 EPPO (1998) Phytosanitary procedure. Fumigation of cotton and cotton products to control Anthonomus

grandis. PM 3/47 (1), amendment of 1998. European Plant Protection Organisation, Paris. 3pp. Available as a 

current EPPO Standard PM 3/47 (1), http://archives.eppo.org/EPPOStandards/procedures.htm 30 FAO 1983 cited in EPPO 1997, p.4 

31 APHIS (2009) PPQ Treatment Manual, Plant Protection and Quarantine, Animal and Plant Health Inspection 

Service, United States Department of Agriculture. Treatment No. T301-d-1-2 32 IPPC. 2007. ISPM No. 29: Recognition of pest free areas and areas of low pest prevalence 
100 TEAP May 2011 Progress Report

Table 7-2: Suggested steps to find alternatives to methyl bromide 

1) Search for existing alternatives by commodity / pest species on: 

a. The USDA-APHIS-PPQ Treatment Manual 

b. Treatments in other country databases e.g. Australia, New Zealand, Japan

c. EPPO standards 

d. IPPC International Standards 

e. TEAP Reports, MBTOC-QPS subcommittee reports 

f. CABI Crop Protection Compendium (global module) for pest distribution, if 

relevant 

g. Conferences on alternatives in the US

h. Publications, unpublished studies, and industry data 

2) Check to see if the treatment is authorised for use in the country where the treatment is being 

carried out 

3) Compile summary workbook of relevant information from above, including the sources of 

the information and date 

4) Determine the relevant category of pest or action of the treatment: 

DE – Desiccant

HB – Herbicide

OT - Other treatment

AC - Acaricide

IN – Insecticide

RO – Rodenticide

BA - Bactericide

MO – Molluscicide

ST - Soil treatment

FU - Fungicide

NE – Nematicide

SY – Synergist

5) Determine conditions of use for a proposed treatment according to: 

a. Treatment schedule (see (1) above) 

b. Technology (see (1) above) 

c. Manufacturer specifications e.g. Degesch, Dow Agro Sciences, Bayer 

d. Researcher files e.g. USDA-ARS 

e. Conference references e.g. EU conferences on alternatives to methyl bromide; US 

conferences (MBAO) and stored product conferences (e.g. CAF) 

f. From published and unpublished literature 

g. From pest control companies 

6) Determine plant or human health impacts of the leading treatments: 

h. Identify treatments that have the least impact on the environment and human health 

i. Hyperlink and / or download any PowerPoint documents or information that could 

be helpful for end users such as technical bulletins, brochures, farm-notes, seminars 

etc
TEAP May 2011 Progress Report 101

7.2 Soils 

7.2.1 Scope of the Report 

The MBTOC 2010 Assessment Report has been recently published and is accessible at the Ozone 

Secretariat website http://ozone.unep.org/Assessment_Panels/TEAP/Reports/MBTOC/MBTOCAssesment-Report-2010.pdf. This report focuses mainly on assessment of alternatives to methyl 

bromide, (MB) for the remaining Critical Uses and those alternatives adopted through Multi Lateral 

Fund (MLF) projects to achieve reductions of MB and/or phase out in A5 Parties. The acceptance of 

new alternatives continues to increase as new products, such as methyl iodide or iodomethane (IM) 

and dimethyl disulphide (DMDS) expand registration and growers become more used to others 

practices, i.e. the 3 way system in the USA. 

Since the last report, several Parties, Israel and Japan, no longer submit Critical Use Nominations. The 

US has not submitted a nomination for sweet potatoes or forest nurseries. 

The recently 2010 Assessment Report contains a full analysis of the technical and economic 

feasibility of alternatives to replace MB. It also contains sections on the commercial adoption of 

alternatives and potential alternative treatments to MB as a soil fumigant. It shows trends in MB 

production and consumption in both Article 5 and non-Article 5 Parties; estimated levels of emissions 

of MB to the atmosphere, and strategies to reduce those emissions. In addition, the report gives a 

review of economic issues relating to MB phase-out. In light of the above, this progress report will 

describe briefly the remaining challenges and will give a short update of chemical and non chemical 

alternatives technically and economically feasible at a large scale 

7.2.2 Chemical Alternatives for Soil Fumigation 

Chloropicrin (Pic), is a key alternative which is being used alone or in combination with other 

fumigants to effectively control soilborne fungi and some insects. It has limited activity against 

weeds (Ajwa et al. 2003). Recent results with new virtually or totally impermeable films (VIF, TIF) 

are proving an effective strategy to reduce dosage rates and avoid off gassing issues (Chow 2009). 

The increased use of Pic and other alternatives, eg 1,3-Dichloropropene has proved successful in 

many countries to sustainably control diseases in the absence of methyl bromide. In the US, Israel 

and Spain, some increases in infestation with Macrophomina phaseolina and Fusarium oxysporum

have been observed. Further studies are required to determine if this is due to the ineffectiveness of 

the fumigants or related to changes to strip treatment and drip fumigation. Regulatory constraints 

continue to limit Pic use in some countries that already phased out MB. 

1,3-Dichloropropene (1,3-D) is used as a nematicide and also provides effective control of insects and 

suppresses some weeds and pathogenic fungi (Ajwa et al 2003). 1,3-D as a single application is not 

very effective in controlling fungi or bacteria. However when combined with Pic it has been a key 

alternative to MB in almost all countries. As with Pic, 1,3-D can be combined virtually or totally 

impermeable films (VIF, TIF) to help reduce dosage rates and improve efficacy (Chow 2009). 

Fumigants that are based on the generation of methyl isothiocyanate (MITC), e.g. dazomet, metam 

sodium and metam potassium, are generally only fully effective against a wide range of arthropods, 

soilborne fungi, and weeds, when combined with other methods but are less effective against bacteria 

and root-knot nematodes. The use and knowledge of their application is continually improving. 

Methyl iodide (MI) has been recently tested on a wide range of crops by drip and shank-injected and 

found to be highly effective at controlling a wide range of soilborne pathogenic fungi, nematodes, and 

weeds (Browne et al. 2006, Fennimore et al. 2008, Schneider et al. 2008, 2009, Yakabe et al. 2010). . 

MI is now registered in all the United States except Washington and New York for 27 crops including 

ornamentals, peppers, strawberries, tomatoes, stone fruits, nut crops, vine crops (including table and 

wine grapes), turf, conifer trees and nursery crops. MI is a key alternative with efficacy similar to MB 
102 TEAP May 2011 Progress Report

and is only limited for uptake for the remaining uses of MB because of lack of registration and 

regulations on dosage rates, buffer zones and economics. Present regulations in California on dosage 

rates and buffer zones may limit the areas where methyl iodide can presently be adopted. In spite of 

this the US has accepted MI as a key alternative for the remaining critical uses. Australia is hopeful 

of achieving registration for use in strawberry runners to offset the use of MB for the last remaining 

critical use in soils and Canada has been urged to consider evaluation of the product also for the 

remaining strawberry runner use. 

Dimethyl disulfide (DMDS), which has been registered in some countries, including the US, appears 

to be highly efficient against various nematodes, including Meloidogyne spp.(Santos et al 2009), 

especially when combined with Pic. DMDS efficacy can be enhanced when combined with VIF or 

TIF films (Chow 2009). 

In the EU, all alternative fumigants (Pic, 1,3 D, metham K and metham Na, dazomet) were revised 

after MB ban according the regulation 91/414/CE. Only dazomet is now included in the 91/414/CE 

annex I list of registered pesticides. 1,3 D is not included and its use is questionable, being subjected 

to specific authorizations country by country for emergency uses. Metham Na and K are also not 

included and their use is possible until December 2014 only for specific essential uses in each 

country. Inclusion of Pic in annex I list is still pending, and the final decision is expected in late 2011. 

Contrary to the MB phase out process, the revision of EU uses of MB alternative fumigants has been 

undertaken without considering the possible technical substitution with alternative solutions. 

7.2.3 Non Chemical Alternatives in the Soil Sector 

Resistant Cultivars 

The use of resistant cultivars to control soilborne pathogens is considered as the best alternative to 

MB for some specific crops e.g. tomato, pepper, eggplant. Cultivars with resistance to diseases, rootknot nematodes, bacteria, viruses and Orobanche spp. have been developed (Devran and Sogut, 2010, 

Quesada-Ocampo and Hausbeck, 2010, Dor et al. 2009, Wu et al. 2009) .The major limitations to use 

of resistant varieties include the appearance of new pests and disease, new races of known diseases 

that overcome resistance genes, presence of a diverse range of nematodes and pathogens in the same 

field, presence of high population levels of pathogens that can override resistance, and environmental 

conditions, which may limit the level of resistance (Besri 1993; Takken and Rep 2010; Tanyolaç and 

Akkale 2010). 

Grafting 

Grafting has been used with great success to control a wide spectrum of vegetable diseases (Bausher, 

2009; Louws, 2009). In addition to reductions in disease severity grafting also provides yield 

increases, improved fruit quality, growth promotion, extended production periods and crop longevity, 

more efficient fertilizer use, reductions in the number of plants required per hectare, tolerances to soil 

salinity, low temperature and flooding (Bausher et al., 2007; Davis et al., 2008;; Maršić and Jakše 

2010). In the USA, grafting is still mostly limited to greenhouses and organic producers, but many 

research projects are underway to establish the technology on a wider scale, particularly in the open 

fields (Bausher 2008, 2009, Kubota et al., 2008 a,b; Rivard et al. 2009; Freeman et al. 2009; Louws 

2009). The best performance seen with grafted plants has been obtained when they are used as a 

component of an IPM program combining non chemical and chemical alternatives (Besri 2008; Davis 

et al., 2008; Kokalis-Burelle et al., 2008; Lin et al., 2008; Rivard et al., 2009). In this regard, preplant soil fumigation with specific nematicides (1,3 D) combined with grafting is widely used to 

control root knot nematodes and soilborne diseases. Presently the major concern with respect to 

grafting is the enhanced risk of spreading diseases throughout grafting handling procedure. 

Substrates 

Substrates are widely employed for growing healthy and high-quality plants, particularly in protected 

agriculture (Kazaz and Yilmaz, 2009). Although initial investment is generally high, increased 
TEAP May 2011 Progress Report 103

productivity and yield due to higher planting densities and often better quality of produce, offsets any 

extra costs (Savas and Passam, 2002; Caballero and De Miguel 2002;). A number of countries have 

now developed substrate systems that are cost effective because they employ materials that are locally 

available. The use of substrates has less potential to replace MB for large-scale open field operations 

because of limited availability of suitable local materials. Constraints on soilless culture may include 

lack of identification of suitable local substrates, and the vulnerability of the system to pathogen 

attack, the need for large amounts of water in open systems and the complexity of closed and semiclosed systems needing recirculation of nutrient solutions. 

Steaming 

Use of steam has continued to increase as an alternative to MB in intensive, protected, high-value 

cropping systems such as flowers and vegetables (Runia 2000; O'Neill and Green 2009). Steam has 

replaced the use of MB for sterilization of substrates in a number of areas (Barel 2005). Cost and 

energy souces are the main limiting factors for this technique. 

Hot water 

New more effective hot water treatments have gained acceptance for use in Japan. Hot water is 

applied for the cultivation of tomato, melon, strawberry, spinach, sweet pea and carnation (Nishi 

2000, 2002, Uematsu et al., 2003). This technology however, is not expanded to countries other than 

Japan. 

Solarization 

The effectiveness of soil solarization in controlling many diseases in a variety of annual crops has 

been shown under a variety of conditions, soils and agricultural systems in many countries (Katan 

1981, Stapleton 2000). Control of certain soil pathogens in solarized soil was improved by combining 

this method with reduced dosages of fumigants e.g. MB, metam sodium, formalin (Stapleton 2000, 

Chellimi and Miruso 2006). 

Biofumigation 

Spain switched a significant area to biofumigation and biosolarization as the main non-chemical 

alternative to MB (Bello et al 2007). The combination of biofumigation and soil solarisation 

(biosolarisation) has been found to be synergistic in improving the efficacy of both procedures and 

thereby reducing the time required for solarization and the rates of amendment needed for 

biofumigation (Bello et al 2007). 

7.2.4 Remaining Challenges 

The key alternatives, Pic, 1,3-D and MI all have regulations, which have potential to affect their 

uptake for the remaining uses of MB. MBTOC continues to urge Parties to consider review of these 

regulations to ensure they serve the best interests of the Montreal Protocol and human safety. 

Use of methods which avoid the need for MB (substrates, soilless culture, grafting, resistant varieties) 

continue to expand worldwide to grow crops once produced with MB and these technologies get more 

cost effective every year. Continual review of these technologies is required to support evaluation of 

Critical Use nominations. 

Nursery uses are the most significant remaining use for methyl bromide worldwide and more studies 

are required to determine the risk imposed by use of alternatives in these industries. Until these are 

conducted growers are apprehensive about switching to alternatives. 

MB continues to be classified differently for nursery applications by several Parties despite the target 

pests and crops being similar in several countries. Canada supplied a useful summary of their 
104 TEAP May 2011 Progress Report

interpretation of this use which has been included in the QPS report. MBTOC continues to urge 

Parties to review the status of these uses. 

Emergence of new or re-emergence of previously controlled pathogens in fields that have used MB 

alternatives for a few years. Examples include Macrophomina on strawberry and morning glory and 

nutgrass in nurseries, Orobanche species in greenhouse tomato and pepper crops in Israel. 

Furthermore, root knot nematodes have emerged after the phase-out of MB in regions in Israel of 

which this pathogen did not exist. 

7.2.5 References 

Ajwa H A, Klose S, Nelson S D, Minuto A, Gullino M L, Lamberti F, Lopez Aranda J M. (2003). 

Alternatives to methyl bromide in strawberry production in the United States of America and the Mediterranean 

Region. Phytopathol. Mediterr. 42, 220-244. 

Barel, M. (2005). Report on UNDP Project Mission in Bolivia, 19-22 April 2005. Project No. UNDP BOL/02/G62-

11606. Report to National Ozone Unit, Bolivia. 

Bausher MG, Kokalis-Burelle N, Rosskopf E N. (2007). Evaluation of rootstocks for management of Meloidogyne 

incognita on grafted bell pepper. In: International Research Conference on Methyl Bromide Alternatives and 

Emissions Reductions, October 29 November 1, 2007, San Diego, California, 112,1-3. 

Bausher, M.G., (2009). Tomato rootstock performance to natural populations of root-knot nematode . In: 

International Research Conference on methyl bromide alternatives and emissions reductions, November 9-13, San 

Diego, California, 44-1. 

Bello, A., Díez Rojo, M.A., López-Pérez, J.A., González López M.R., Robertson, L., Torres, J.M., de Cara, M., 

Tello, J., Zanón, M.J., Font, I., Jordá, C., Guerrero, M.M., Ros, C., and Lacasa, A. (2007). The use of 

biofumigation in Spain. Ed R. Labrada, Technical Workshop on non-chemical alternatives to replace 

methyl bromide as a soil fumigant, Budapest, Hungary, 26-28 June 2007. 79-86. 

Besri M. (1993). Effects of salinity on plant disease development. In: H. Lieth and A. Al Masoom (eds). Towards the 

Rational Use of High Salinity Tolerant Plants. Kluwer Academic Publishers 2, 67-74. 

Besri, M. (2008). Cucurbits grafting as alternative to methyl bromide for cucurbits production in Morocco. 

Proceedings MBAO Conference, Orlando (FL) 2009, 60,1-5. 

Browne, G.T., Connell, J.H., Schneider, S.M. (2006). Almond replant disease and its management with alternative 

pre-plant soil fumigation treatments and rootstocks. Plant Disease, 90 (7), pp. 869-876. 

Caballero, P and De Miguel, M.D. (2002). Costes e intensificación en la hortofruti-cúltura Mediterránea. In: JM 

Garca (ed.). La Agricultura Mediterránea en el Siglo XXI. Instituto Cajamar, Almería. pp. 222-244. 

Chellemi, D.O; Mirusso, J (2006). Optimizing soil disinfestation procedures for fresh market tomato and pepper 

production. Plant Disease 90: 668-674 

Chow, E. (2009). An update on the development of TIF mulching films. Proc. 2009 Annual International Research 

Conference on Methyl Bromide Alternatives and Emissions Reductions. 

http://www.mbao.org/2009/Proceedings/050ChowEMBAO2009.pdf 

Davis, A.R., Perkins-Veazie, P., Hassell, R., Levi, A., King, S.R., and Zhang, X. (2008). Grafting effects on vegetable 

quality. HortScience, 43 1670-1672. 

Devran, Z., and Sogut, M.A. (2010). Occurrence of virulent root-knot nematode populations on tomatoes bearing 

the Mi gene in protected vegetable-growing areas of Turkey. Phytoparasitica 38, 245-251. 

Dor, E., Alperin, B., Wininger, S., Ben-Dor, B., Somvanshi, V.S., Koltai, H., Kapulnik, Y., and Hershenhorn, J. 

(2009). Characterization of a novel tomato mutant resistant to the weedy parasites Orobanche and 

Phelipanche spp. Euphytica, 171, 371-380. 

Fennimore, S.A., Haar, M.J., Goodhue, R.E., Winterbottom, C.Q. (2008). Weed control in strawberry runner plant 

nurseries with methyl bromide alternative fumigants. HortScience, 43 (5), pp. 1495-1500. 

Freeman J., Rideout, S., and Wimer, A., (2009). Performance of grafted tomato seedlings in open field production. 

International Research Conference on Methyl Bromide Alternatives and Emissions Reduction , Nov 10 – 13, San 

Diego, CA ,MBAO 45-1; 45-2. 
TEAP May 2011 Progress Report 105

Katan, J. (1981). Soil solarization. Annual Rev. Phytopathol 19:211-236 

Kazaz, S and S. Yilmaz. (2009). Effects of zeolite-peat mixture on yield and some quality parameters of carnation 

grown in soilless culture. 7th I nternational Symposium on Chemical and non-Chemical Soil and 

Substrate Disinfestation SD 2009. p.104. 

King, S. R., Davis, A. R., Liu, W., and Levi, A. (2008). Grafting for disease resistance. Hortscience 43, 1673-1676. 

Kokalis-Burelle, N., Rosskopf, E.N., Bausher, M.G., McCollum, G., and Kubota, C. (2008). Alternative fumigants 

and grafting for tomato and double cropped muskmelon production in Florida. In: International 

Research Conference on methyl bromide alternatives and emissions reductions, November 11-14, 2008, Orlando, 

Florida. 63-1; 63-2. 

Kubota, C., McClure, M.A., Kokalis-Burelle, N., Bausher, M.G., and Rosskopf, E.N. (2008a). Vegetable grafting: 

History, use, and current technology status in North America HortScience, 43, 1664-1669. 

Kubota, C., McClure, M.A., Olsen, M., and Tronstad, R. (2008b). A multidisciplinary project for introducing 

vegetable grafting in the USA. In: International Research Conference on methyl bromide alternatives and emissions 

reductions, November 11-14, 2008, Orlando, Florida. 64-1; 64-2. 

Lin, C., Hsu, S.T., Tzeng K.C., and Wang, J.F. (2008). Application of a preliminary screen to select locally adapted 

resistant rootstock and soil amendment for integrated management of tomato bacterial wilt in 

Taiwan. Plant Disease, 92, 909-916. 

Louws, F. (2009). Grafting tomato with interspecific rootstocks provides effective management for southern blight 

and root knot nematodes. Annual International Research Conference on Methyl Bromide 

Alternatives and Emissions Reduction, Nov 10–13, San Diego, CA ,40. 

Maršić, N.K., and Jakše, M. (2010). Growth and yield of grafted cucumber (Cucumis sativus L.) on different soilless 

substrates. Journal of Food, Agriculture and Environment 8, 654-658 

Nishi, K. (2000) Soil Sterilization with Hot Water Injection, A New Control Measure for . Soilborne Diseases, 

Nematodes and Weeds. PSJ Soilborne Disease Workshop No.20 October, 2000. 

Nishi, K. (2002) Hot water treatment with the principle and record of practical use. Edited by Japan Protected 

Horticulture Association (2002). 

O'Neill, T.M., and Green, K.R. (2009). Evaluation of some pre-plant soil treatment and chemical disinfectants form 

control of Fusarium wilt diseases in protectes cut flowers. 7th International Symposium on Chemical and 

non- Chemical Soil and Substrate Disinfestation SD, p. 62. 

Quesada-Ocampo, L.M., and Hausbeck, M.K. (2010). Resistance in tomato and wild relatives to crown and root rot 

caused by Phytophthora capsici. Phytopathology 100. 619-627. 

Rivard, C.L., O’Connell, S., Peet, M.M., and Louws, F.J. (2009). Grafting tomato with inter-specific rootstock to 

manage diseases caused by Sclerotium rolfsii and root-knot nematodes In: International Research 

Conference on methyl bromide alternatives and emissions reductions, November 9-13, San Diego, 

California, 40-1, 40-3. 

Runia, W.T. (2000). Steaming methods for soils and substrates. Acta Horticulturae, 532, 115-123. 

Santos, B.M., Gilreath, J.P., López-Aranda, J.M., Miranda, L., Soria, C., Medina, J.J. (2009). Comparing methyl 

bromide alternatives for strawberry in Florida and Spain. Journal of Agronomy, 6 (1), pp. 225-227. 

Savvas, D. and Passam, H. (eds.) (2002). Hydroponic production of vegetablesand ornamentals. Embryo Publications, 

Athens, Greece, 463 pp. 

Schneider, S.M., Ajwa, H.A., Trout, T.J., Gao, S. (2008). Nematode control from shank- and drip-applied fumigant 

alternatives to methyl bromide. HortScience, 43 (6), pp. 1826-1832. 

Schneider, S.M., Hanson, B.D., Gerik, J.S., Shrestha, A., Trout, T.J., Gao, S. (2009). Comparison of shank-and dripapplied methyl bromide alternatives in Perennial crop field nurseries. HortTechnology, 19 (2), pp. 331-

339. 

Stapleton J.J. (2000). Soil solarization in various agricultural production systems. Crop Protection 19, 837-841. 

Takken, F., and Rep, M. (2010). The arms race between tomato and Fusarium oxysporum. 

Molecular Plant Pathology, 11, 309-314 
106 TEAP May 2011 Progress Report

Tanyolaç, B., and Akkale, C. (2010). Screening of resistance genes to fusarium root rot and fusarium wilt diseases in 

F3 family lines of tomato (Lycopersicon esculentum) using RAPD and CAPs markers. African Journal of 

Biotechnology, 9, 2727-2730 

Uematsu,S., Nishi,K, Kita,N. (2003) “Hot water soil sterilization begins in Japan” Farming Japan, 37, 35 -41. 

Wu, W-W., Shen, H-L., and Yang, W-C. (2009). Sources for heat-stable resistance to southern root-knot nematode 

(Meloidogyne incognita) in Solanum lycopersicum. Agricultural Sciences in China. 8, 697-702. 

Yakabe, L.E., MacDonald, J.D. (2010). Soil treatments for the potential elimination of Phytophthora ramorum in 

ornamental nursery beds. Plant Disease, 94 (3), pp. 320-324. 

7.3 Economic Issues Relating to MB Phase-out 

During CUN evaluations, MBTOC assesses the economic feasibility of alternatives available to the 

Party (Decision IX/6), because an alternative may be considered technically feasible, but may not be 

economically feasible. In its assessment report MBTOC provided a detailed summary of this 

information, but a further summary is provided here to assist Parties with future assessment of the 

economic feasibility of alternatives to methyl bromide. 

Measurement of the economic implications of the use of methyl bromide or an alternative can in most 

cases be done satisfactorily by means of a partial budget analysis, which is a practical quantitative 

decision tool used to compare alternative production practices. It is partial because the analysis 

considers only a part of a larger enterprise. 

More than one alternative can be analyzed with partial budgeting. The key information for the 

analysis is the impact on output and the changes in variable costs (see below). Physical output is not 

deterministic, especially in primary agriculture where yields are affected by exogenous factors such as 

the weather and soil fertility. Furthermore, soil pest pressure is dynamic and the efficacy of 

disinfestations is variable. Partial budgeting analysis can address biological factors in a reduced form 

manner by conducting sensitivity analysis by varying the assumed yield differences. The analyses can 

also examine the sensitivity of results to different prices for variable inputs like labour. The stochastic 

output prices need not be modelled unless the alternatives affect the quality of the crop or the timing 

of the harvest and thus the realized price. 

Other circumstances that need special attention include: 

Where there is a single treatment followed by a multi-year stream of marketable output, which 

necessitates economic discounting, and hence the careful selection of the discount rate, which should 

be based on the producer’s time preference and opportunity cost of funds. 

Disinfestation in multiple-output production or processing systems, where the economic analysis has 

to account for the beneficial effect of the disinfestation on the other outputs. 

7.3.1 Components of an Assessment of Financial Feasibility 

In assessing financial feasibility, the calculation of each of the following key components is done for: 

(i) the firm operating with methyl bromide and (ii) the firm operating with each of the next best 

technically feasible alternatives for each use: 

Gross revenue measures the earnings of the firm; broadly the quantity of the product sold times the 

average selling price per unit. Where gross revenue is not expected to change as a result of the 

adoption of an alternative it is not necessary to consider it. 

Variable costs are those costs of production that vary with the amount produced, e.g. fumigation 

costs; broadly the quantity of the input used times the cost per unit of input. Borrowing costs for 

capital equipment and remuneration to the owner are excluded. 
TEAP May 2011 Progress Report 107

Fixed costs are those costs that do not vary with the amount produced, e.g. property taxes and 

insurance premiums. Fixed costs may be difficult to deal with in situations where firms produce more 

than one product, as they then have to be allocated to different products produced by the firm. 

Capital costs are classified as fixed costs; e.g. investment in new machinery. Capital includes a time 

element as it generates revenues over more than one production cycle and its costs are spread over 

time through interest on borrowing. Where transition to an alternative involves investment in capital 

equipment, the costs of such equipment should be spread over the economic life of the asset. 

The gross margin is what remains from gross revenue after subtracting certain variable costs. The 

process of calculating the gross margin is conventionally referred to as partial budgeting because it 

does not include fixed and capital costs. 

It is sometimes necessary to measure a margin above specified costs, for example where certain 

capital costs or even fixed costs change as a result of the adoption of an alternative. 

Net Revenue (or Net Returns) is what remains from gross revenue after subtracting variable, fixed and 

capital costs. 

7.3.2 Estimating the Components for Assessing Financial Feasibility 

A responsible financial assessment requires sufficient data to construct a partial budget for the current 

use (in this case production with methyl bromide) as well as for the next best technically feasible 

alternative. 

However, enterprise budgets in agriculture are difficult to construct because of: 

• The diversity of firms in terms of size, age and geographic location, etc.; 

• The diversity of conditions that can affect input use as well as gross revenue; 

Changes introduced as a result of the adoption of the next best alternative, such as increased risk of 

loss in production, increased variability in yields or efficacy, missed market windows, the creation of 

new markets (e.g. organics), etc.; 

Because of this diversity, it is important that the presentation of the budgets be accompanied by 

explicit statements of the way in which each figure was calculated. Examples of well constructed 

enterprise budgets can be found at the UC-Davis Department of Agricultural and Resource 

Economics33. 

In all these cases, it is not always possible to provide proprietary information on individual firms. 

Hence, data should be provided for either a ‘typical’ or an average enterprise, i.e. one that shares 

similar physical, economic, etc. characteristics as the firm(s) in question. 

The information regarding financial feasibility must be assessed for internal consistency, 

completeness, and reasonableness. Because there are virtually no published sources on the financial 

feasibility of the adoption of methyl bromide alternatives, MBTOC is largely dependent on the Parties 

to provide objective sources. To this end, the work of MBTOC will be made easier if the data that is 

provided has been verified by a third party, e.g. via banks that serve the clients in question, 

government agencies such as extension services, and farmer study groups, etc. 

In terms of financial feasibility, the following considerations apply: 

 

33 http://coststudies.ucdavis.edu/current.php
108 TEAP May 2011 Progress Report

Alternatives that result in significant negative gross margins are not financially feasible. 

In the event that the gross revenues are higher and costs are lower (a situation which is unlikely as 

initial profit gains are generally short term and likely to be offset by increased supply over time), the 

alternative is financially feasible. 

In the unlikely event that changes in costs and revenues are absolutely equal, the alternative is 

financially feasible because of the environmental benefits accruing. 

When costs and revenues increase or decrease simultaneously, the result is ambiguous, and there is a 

need to define default values. 

All other effects on the economics of the business are assumed to remain unchanged (e.g. high fuel 

prices, changes in the commodity price), unless explicitly stated otherwise in the analysis. 

7.3.3 Default Values 

Financial feasibility criteria are needed for those cases where gross margin declines but remains 

positive. Thus, Parties asserting that methyl bromide alternatives are not financially feasible should 

explain why projected impacts are of sufficient magnitude to support their claim. 

MBTOC has adopted the default assumption that alternatives leading to decreases in gross margins 

(or in a margin above specified costs where appropriate) of more than around 15 to 20 percent or 

more are not financially feasible. 

7.3.4 References 

Adam, B.D., Bonjour, E.L.,and Criswell, J.T., 2010. Cost comparison of Methyl Bromide and Sulfuryl Fluoride 

(ProFume®) for fumigating food processing facilities, warehouses, and cocoa beans. 10th 

International Working Conference on Stored Product Protection 

Ferrer, Myra Clarisse R., Esendugue Greg Fonsah, Cesar L. Escalante and Stanley Culpepper, 2010. Profitability 

Efficiency Analysis of Methyl Bromide Fumigants and Mulch Systems Alternatives for Pepper 

Production in Georgia. Selected Paper prepared for presentation at the Southern Agricultural 

Economics Association Annual Meeting, Orlando, FL, February 6-9, 2010 

Jenson, Emily A, Frank H. Arthur and James R. Nechols, 2010. Efficacy of an esfenvalerate plusmethoprene 

aerosol for the control of eggs and fifth instars of Plodia interpunctella (Lepidoptera: Pyralidae). 

Insect Science Vol 17: 21–28 

Wang, Qingren, Waldemar Klassen, Edward A. Evans, Yungcong Li and Merlyn Codallo, 2010. Combination of 

Organic and Plastic Mulches to Improve the Yield and Quality of Winter Fresh Market Bell Peppers 

(Capsicum annuum L.).Tropical Research and Education Center, University of Florida, 18905 SW 

280th Street, Homestead, FL 33031 

7.4 Structures and Commodities 

The 2011 MBTOC Assessment Report includes a chapter on use of alternatives to methyl bromide in 

control of pests in structures and commodities . In that chapter Parties will find new writing and 

analysis of the research on pest control in food processing structures and commodities. Almost all the 

200 references that were cited have been published since 2006.. 

This section of the TEAP May 2011 Progress Report, contributed by the MBTOC Structures and 

Commodities subgroup (MBTOC SC) includes two sections: 

A regulatory news update and; 

A special review on achieving control of pest eggs by sulfuryl fluoride. 
TEAP May 2011 Progress Report 109

Parties, MBTOC, CUN applicants and researchers continue to note inconsistencies in observed 

efficacy of sulfuryl fluoride (SF) in practice. This is of concern as fumigation with SF is one of the 

pest control adopted by some parties as the principal alternative to methyl bromide in some major 

postharvest and structural uses. The lack of full effectiveness of SF against eggs of pests is mentioned 

in several critical use nominations. To assist in understanding, and hopefully resolving, this problem, 

MBTOC SC prepared a Special Review, given below (Section 7.4.2) of reported laboratory studies on 

SF in controlling eggs of stored product insect pests. This review provided a basis for analysis of the 

lack of full control of pests by SF in some commercial fumigations . 

As a result of its review, MBTOC concludes that: 

-- the target dosage rate of SF, typically a ct-product of 1500 g h m-3 over 24h at 26C, is insufficient 

to fully control eggs of some common species of stored product insect pest 

-- many common pests will be fully controlled (all developmental stages including eggs) to 

commercial levels under these conditions. 

It is important to achieve a high degree of kill of infestations, including the egg stage, under situations 

where resistance development may be a risk. 

MBTOC noted that the actual ct-product experienced by pests, including their eggs, may be less than 

the free space ct-product under conditions where there are significant barriers to gas distribution, such 

as packaging materials. 

The review and analysis reported here merits further examination and testing by researchers and 

refinement by pest control fumigators, but at this point, we believe the information could act as a 

guide to improving the efficacy of SF fumigations as methyl bromide replacements. 

7.4.1 Regulatory News 

Since the last Progress Report there have been few changes in registration and other regulatory news 

of interest to Parties. Neither Australia nor Canada have expanded their registrations for sulfuryl 

fluoride (SF), which applicants are reported to be awaiting. 

MBTOC notes the uncertainty caused by the recent US EPA proposed regulation on sulfuryl fluoride, 

which has been brought about as part of a range of actions to reduce the incidence of fluoride in the 

diet of some sub-sectors of the US population, particularly children. 

The lengthy US proposed regulation discusses both the health assessment of the residues resulting 

from the use of SF in structures and commodities, as well as the legal basis and issues which resulted 

in the proposal to phase out its use. Excerpting short sections of this lengthy regulation can lead 

misunderstandings so Parties may want to review the entire regulation at: EPA. 2011. Sulfuryl 

Fluoride; Proposed Order Granting Objections to Tolerances and Denying Request for a Stay. Federal 

Register Vol. 76 No 12 Page 3444. 

Fluoride presence in the diet is largely regional, the result of naturally occurring fluoride (from soils 

impacting water), from fluoride additions to drinking water, and to a much lesser extent from fluoride 

residues resulting from the use of SF as a fumigant. Australia then addressed this issue and re-assured 

its public that fluoride presence was not a problem in Australian diets and therefore its approval of SF 

for control of structural and commodity pests would not change as a result of the US proposed 

regulation. MBTOC notes that Canada has not established a tolerance for SF contact with foods in 

Canada. 

In further regulatory news, as explained in the text box for Japanese fresh chestnuts, Japan is 

progressing in the necessary logistical and training requirements following its registration of methyl 
110 TEAP May 2011 Progress Report

iodide for control of chestnut pests. As part of their CUN of 2011, Japan presented a full phase out 

plan for the use of MB in chestnuts by 2015. 

7.4.2 Special Review on Achieving Control of Pest Eggs by Sulfuryl Fluoride 

- Key Messages Resulting From the Review of SF Efficacy against Pest 

Eggs 

Fumigations which target only 95% efficacy in killing pest eggs can quickly result in severe reemergence of infestation and can, eventually after repeated fumigations, result in pest resistance to the 

fumigant. Therefore, MBTOC is of the opinion that, where there is risk of resistance development 

(e.g. with repeated treatments of infested premises) fumigations should be conducted to achieve a 

very high level of kill (>99%) of all pest life stages, including eggs. 

Because of varied mortality responses (including by the tolerant egg stage) to SF, , identification of 

the pests of concern before the fumigation is required to select treatment parameters necessary to 

achieve full efficacy. 

Knowledge gained from the pest identification, when coupled with the data shown in the review 

tables in the Appendix, can be used to determine the treatment parameters necessary for egg mortality. 

Crucial factors for limiting egg tolerance are temperature and length of exposure, and level of 

concentration, which operate differently on different species. Other important factors affecting 

response to SF include the developmental period of the embryo, the structure of the egg shell and 

other compounds of the egg. 

Achieving an effective treatment may require a combination of concentration and time and elevated 

temperature, which is not currently found elsewhere. 

The dosage/mortality values determined in laboratory studies may be used as a basis of commercial 

dosage recommendations, with allowance for the various inefficiencies and deviations from ideal 

systems that occur in practice. Reichmuth (2010b) proposed a factor of three times for conversion of 

laboratory-derived values to commercial applications. 

7.4.2.1. Reasons Why MBTOC SC Conducted this Special Review Project 

As noted in the Australia rice CUN text box, in the Canada Mills CUN and in MBTOC’s 2010 

Assessment Report review of the effectiveness of SF as a methyl bromide replacement, some 

researchers and food processing companies have reported inadequate control of pest eggs with SF and 

difficulties understanding the research in that field. In many situations, pest control methods, used as a 

single control measure, are not considered to be adequately effective if they do not control the eggs as 

the facility or commodity will become noticeably infested again from survivors within very few 

weeks. 

Some commercial recommendations for the use of SF in food processing structures and commodities 

target a 95% kill of pests. It is the opinion of MBTOC members that fumigations with less than 99% 

efficacy of killing pest eggs are undesirable because of selection for resistance under situations where 

the SF fumigant is the sole control measure used and repeated exposures are likely. 

The reason for this is that survivors of such repeated unsuccessful fumigations will eventually become 

resistant to the fumigant -- and the fumigant will not longer be useful, including as a methyl bromide 

replacement. On the other hand, if other subsequent, additional control measures including IPM 

processes (e.g. a second fumigation, cooling, heating or further processing) were to be used in 

addition to the SF fumigation, and if a resulting additive kill-effect could be validated to 99%, then a 

95% kill of all stages, with 'complete' kill of adults, may be sufficient both technically and 

commercially. Additionally we note that increasing the temperature and/or duration of the fumigation 

for a particular dosage will also help to increase effectiveness of the fumigation. 
TEAP May 2011 Progress Report 111

MBTOC notes, however, that in the absence of MB, it is likely that SF will be used repeatedly as a 

postharvest fumigant in many applications without achieving full control, thus setting the conditions 

for pest resistance (i.e., if the treatment(s) are not effective to >99%). Since eggs tend to be much 

more tolerant than other developmental stages to SF, it is critical that the conditions leading to >99% 

mortality of eggs is understood if control to >99% efficacy is to be achieved. 

Australia’s rice CUN applicant and North American flour millers have said they have been unable to 

show efficacy of SF to control eggs under their treatment conditions. Australia has indicated its 

intention to phase out MB use for rice in 2015, largely by switching to phosphine, but since the use of 

SF would require fewer logistical changes, they have also been examining it. 

MBTOC wishes assist Parties in correct use of SF and at the same time we were concerned about 

ongoing inconsistency in reports of efficacy of SF fumigations in controlling pest eggs. We believed 

that much research had been done that might be helpful to Parties whose applicants continue to 

struggle to find efficacious fumigations. 

7.4.2.2. Method Used for MBTOC’s Special Review of Efficacy of SF against Eggs 

Given the problems outlined above, , several MBTOC members, led by Dr. Christoph Reichmuth 

(Germany) collated all available data on the fumigation of eggs of stored product insects and 

especially those occurring in rice and flour mills, the situations of particular concern where SF is a 

potential or actual methyl bromide replacement 

From an extensive data set from published laboratory studies on SF effects on insect pests, MBTOC 

decided to include in its review only those data points which showed efficacy of at least 99%. 

Quarantine treatments may require effectiveness much greater than 99% mortality, and so were 

excluded from this analysis. 

Additionally, to ensure MBTOC-SC had the most up to date research and to ensure the Committee’s 

analysis correctly reflected current knowledge, MBTOC-SC also sought data from a scientist whose 

work focuses on pest control in food processing structures and commodities (Dr. Spencer Walse of 

USDA’s Parlier Research Lab.). MBTOC appreciates the unpublished data submitted by Dr. Walse. 

The data collected for this special review and forming the basis for the conclusions are given in the 

four tables below (Tables 7-3 to 7-6). 

Table 7-3 summarises published mortality data and lethal responses of eggs of 28 economically 

important insects and mites following fumigation with sulfuryl fluoride. Additional information on the 

pests can be obtained from Reichmuth et al., (2007) and in the cited references. This table provides 

Parties access to research data on specific pest species where control of pest eggs was >99%. 

Table 7-4 presents a bar graph of the reported minimum and maximum ct-products required for 99% 

efficacy of control of eggs by various pest species. 

Table 7-5 presents unpublished data from US Department of Agriculture’s Parlier Laboratory in 

California, including information on pests associated with Pre-shipment treatments at the 

comparatively low temperature of 15.6°C. They confirm the range of other data in the main table and 

the very high dosages that are required to control the eggs of the dried fruit beetle, Carpophilus 

hemipterus. MBTOC notes that Dr. Walse’s work is focused on pests of dried fruit and dates, that 

may be of interest to Parties considering treatment of these commodities with SF as a methyl bromide 

alternative. 

Table 7-6 sorts pest species into groups that are probably, possibly or unlikely to be controlled at 

1,500 g h m-3 at at 26.7°C (80°F) and 24 h exposure. This ct-product is maximum rate that is allowed 

under the registration of SF as a pesticide (‘label’ rate) for control of all developmental stages of 
112 TEAP May 2011 Progress Report

stored product pest, such as specified in the ‘Fumiguide’, a proprietary guide to the use of SF as a 

postharvest and structural fumigant. This rate is targeted at 95% mortality. 

7.4.2.3 Assessment of the Data Available 

In assessing the data revealed in the tables, MBTOC has prepared some summary comments. 

(1) The ct-products given in Table 1 were sufficient to kill >99% of the eggs in the test. Where 

available, the mortality rate corresponding to the ct-value is given. In some studies, the steps of 

concentration increase between tests were large, so that the actual value for achieving 99% mortality 

is not well defined, but lies between two limiting values. The higher value is used in the table, but 

may be an overestimate of the true value for 99% mortality. 

Some authors calculated LD95 and spoke of “complete control”, whereas others presented CTPs that 

were lethal to all eggs in the test (no survivors or no development to adults). The costs that were often 

included in the papers but not included in this table, showed that in most cases much higher CTPs will 

be needed to avoid even one surviving egg that may lead to claims in the food chain. 

7.4.2.4. Historical Background to the Use of SF and to Its Efficacy on Eggs 

Sulfuryl fluoride (SF) was registered for stored product protection in 2004 as ProFume® by the 

DowAgroscience company (Buckley and Drinkall, 2010). This company undertook a large effort to 

investigate the necessary CTPs and dosages for control of many pest insects and mites that can infest 

stored food products and other material. SF has also been registered for control of termites (Miekle et 

al., 1963) and wood pest insects(Williams and Sprenkel, 1990) under the name Vikane®.. SF has 

been used for termite control for about 50 years (Kenaga, 1975). SF has been independently 

developed in China as a grain fumigant and methyl bromide alternative. 

From the very first introduction of this compound for pest control in the US it was obvious that eggs 

of arthropods were the most tolerant developmental stage and that they could not be killed for many 

species at dosage rates that eliminated the adult stage. Also a strong dependency of the lethal dosages 

on temperature became soon very evident. This can clearly also be seen from Table 1 when 

comparing the CTPs for eggs of one species at different given temperatures with higher temperatures 

leading to lower CTPs for control. Explanations for these dependencies have been suggested by 

Meikle et al. (1963) and Outram (1967a; 1967b). Uptake of SF by eggs compared to other developing 

stages and adults is much less pronounced and seems to be linked to the properties of the egg shell 

membranes. On the other hand, the lethal effect seems to be linked to physiological processes that are 

reduced at lower temperatures. 

The registration of SF for fumigating food processing structures and commodities by 

DowAgroscience was accompanied by the introduction of a proprietary computer program 

(Fumiguide®) to optimise SF fumigation efficiency under particular situations. Inputs to the 

Fumiguide include many scientific and technical factors that describe an effective fumigation, 

including species, stage, temperature, exposure period, loss rate of SF due to expected leaks on the 

base of a gas tightness test, wind speed, and commodity to be treated. All this information has to be 

introduced by the fumigator to obtain the necessary amount of SF that should be applied in a 

particular fumigation. In certain cases the guide even gives the top up quantity of additional gas 

required to achieve the set ct-product, based on gas concentration measurements and identified losses 

of gas during the treatment. In some countries the Fumiguide is not publicly available, but linked to 

licencing of SF use by the registrant. 

During many fumigations after 2004 in the US, it was found by practitioners and scientists that mostly 

all the pests were controlled, provided the recommendations of the Fumiguide were followed. The 

temperature range of the current Fumiguide is limited to temperatures above 20°C and below 40°C. 
TEAP May 2011 Progress Report 113

7.4.2.6. Discussion of Results of MBTOC Review 

As with other fumigants, there is a wide range of sensitivity to SF fumigant with different pest species 

and developmental stage with some insect species tolerating much higher exposures than others.. The 

eggs themselves develop through different stages that differ markedly in uptake of gas and ct-products 

that can give high mortality. (see Table 7-3 where response of eggs with different age are 

summarised). The different stages have been prepared in the laboratory by waiting various hours after 

egg laying before introducing them into a test fumigation. The development of the embryo differs in 

these eggs of different ages and also the structure of the egg shell and other components of the egg. 

The kinetics of these processes are strongly dependent on temperature. 

Crucial factors for limiting egg tolerance are temperature and length of exposure, which operate 

obviously differently on different species. For example ct-products (CTPs) of about 800, 600 and 300 

g h m-3 killed 95% of eggs of Rhyzopertha dominica at 20°C, 25°C and 30oC, respectively. At 30oC, 

the CTP required for complete kill of eggs fell steadily from 300 g h/m3 as the exposure time was 

lengthened from 20h, only 155 g h m-3 being required over a 120 h exposure. The table also shows 

that even for tolerant species such as Ahasverus advena at 20oC, length of exposure is the key to 

reducing the dosage levels required for control to the practically feasible level of 1500 g h m-3. In 

other words, with this species, the CTP depends strongly on exposure time and not so strongly on 

concentration of SF during the treatment. 

For Acanthoscelides obtectus the effect of a longer exposure can be seen at all temperatures, together 

with the effect of temperature itself (Table 7-3). For other species, however, e.g. Sitophilus granarius

and Ephestia kuehniella , concentration may appear more important than the time component of the 

ct-product at a temperature of 25oC, but below 15 g m-3 exposure times longer than two or three days 

are needed to give the necessary ct-product for control. 

As with phosphine, there appears to be a strong dependence on exposure period related to the time 

taken for eggs to develop from a tolerant to susceptible stage. Thus for R. dominica where eggs can 

take 11 days to hatch at 25oC, increasing exposure times from one to five days have little effect on 

reducing the ct-product for control. At 30oC, the eggs develop quickly enough to become susceptible 

in 5 days. For A. obtectus and A. advena with eggs starting to hatch a week after oviposition at 20oC, 

increasing the exposure to four or seven days greatly affects tolerance at this temperature. The length 

of the phase of high tolerance in the egg stage (varying between species so some are more tolerant 

than others) is a fixed proportion of the total egg development time and so is temperature dependent. 

Development continues during exposure to SF until a susceptible stage is reached. If gas is still 

present, the egg succumbs. 

For use of SF in control of insects that occur in rice storage in Australia, e.g. Tribolium castaneum 

and Sitophilus oryzae, necessary basic information for the dosage can be derived from Table 7-3. 

Unfortunately, T. castaneum belongs to the very few species that eggs are pronouncedly more tolerant 

than eggs of most other species. The maximum ct-product that is recommended by the Fumiguide® 

(1500 g h m- 3) does not guarantee the complete control of all eggs present, at least not at 20°C. 

Reichmuth (2007, 2010a, 2010b) has tried to demonstrate the limitations of not killing all the present 

eggs of a pest species in the context of the speed of rebound time of infestation after a fumigation. 

The speed of rebound depends on temperature. Typically common stored product pests lay 40 to 200 

eggs per female. With a 99% kill of adult females, the remaining female can lay eggs that can then 

develop into the same level of infestation as before the treatment. Generation times can be a few 

weeks or months depending on species and temperature. A goal of, for instance, control of only 95% 

is totally insufficient within the food industry where zero tolerance of insects in food is the rule. It is a 

weak argument to say that new infestation will occur the very moment after the mill or other object of 

fumigation has been aerated and reopened. The client and government inspectors regulating the mill 
114 TEAP May 2011 Progress Report

or food-processing facility will expect that there will be actually or nearly no surviving pest insects 

and stages following a SF fumigation. 

Also Schaub (2010) dealt with the financial and economic aspects of fumigation in stored product 

protection. It is known that in practice, gas leaks, temperature sinks of 10°C, residual flour of 10 cm 

thick layers may occur. The avoidance of all these factors that can jeopardize the success of a 

fumigation is nearly impossible. 

A fumigation plan which targets or results in less that 99 % control is bad fumigation practice and 

may result in survivors that are more tolerant than the regular field strains. Campbell et al. (2010) 

dealt with the question of rebound of pest populations, considering field conditions. Harzer et al. 

(2010b) presented more detailed information on the field fumigations, which led to the results in 

Harzer et al. (2010a), quoted in Table 7-3. Ciesla and Ducom (2009), quoted in Table 7-3, also 

subsequently gave also more detailed information (Ciesla and Ducom, 2010). 

Reichmuth and Klementz 2010b) compared the selection of the appropriate dosage for practical 

fumigation for methyl bromide and sulfuryl fluoride treatments. It was accepted as a reasonable, 

conservative approach to multiply the lethal dosage determined in the laboratory with a factor of 

about three to obtain the practical dosage. With MB, for example, 20 g m-3 is an accepted 

concentration for space fumigations, even though in the lab a concentration of only 5 g m-3 results in 

complete control for most species and stages over the same exposure time. However, with SF, as 

shown in Table 7-3, the theoretical values from the laboratory were converted into the recommended 

commercial dosing in the field mostly without giving some tolerance practical imperfections typically 

encountered, as previously discussed (Section 7.4.2.5). Reichmuth (2010b) proposed a factor of three 

for this conversion. 

Another possibility to overcome the increased tolerance of the egg stage in using SF for insect pest 

control is the combination with other fumigants. Xiaoping et al. (2008), Ling et al. (2008), Guogang et 

al. (2008) proposed the combination with carbon dioxide (see also Table 7-3), whereas Reichmuth 

and Klementz (2010b) showed data on the very effective combination of SF with hydrogen cyanide 

(HCN). Of course, the combined use of heat or elevated temperature and SF offer an opportunity to 

economise on use of SF and still kill all eggs and other stages present. The use of supplemental heat 

to achieve sufficient egg kill in SF fumigations has been recommended by MBTOC since its 2008 

Progress Report. This technique may also be applicable with packed food. 

Dr. Spencer Walse, USDA, (personal communication) confirmed the range of the necessary ctproducts to control egg stages (especially the one day old eggs) of the dried fruit beetle with about 

4500 ghm-3 being necessary even at 25°C. According to his unpublished experimental results, the ctproducts for LD50 he observed are slightly higher than those described by Flingelli et al. (2011) 

especially at the highest experimental temperature. 

Additional Comments on Interrelationship of Packaging and SF Efficacy, of Particular Relevance to 

the Australia Rice CUN 

Some infestable stored foodstuffs are typically fumigated after packaging. There is an 

interrelationship between the permeability of the packaging and the efficacy of SF fumigation. 

In particular, the Australian rice CUN for 2012, and previously, arises, in part, because the applicant 

wishes to fumigate its product after packaging, at a point where the packed material leaves its 

premises, as part of their quality assurance programto ensure retailers and consumers do not receive 

infested rice. The rice packaging used in Australia is punctured with holes. This packaging method 

prevents the package from ‘ballooning’ with air during filling and prevents bursting during 

subsequent handling. From the perspective of disinfestation, the use of punctured packages is a twoedged sword. Insects may be able to re-infest fumigated packages through the holes if they are larger 
TEAP May 2011 Progress Report 115

than 0.1 mm in diameter. But on the other hand, packages without holes may be fairly gas tight and 

insects inside sealed packages may be protected from exposure to the fumigant to some extent. 

The Australian rice industry should ensure the correct identification of the pests and developmental 

stages of concern to their product; evaluate the SF efficacy such as using data from the tables 1 and 4 

below and the information on the permeability of plastic packaging to determine dosages that may be 

suitable to ensure complete control of all egg stages that might be present in the rice. 

Some authors (Osbrink et al., 1988; Scheffrahn et al., 1990) described the permeation of SF through 

different plastic membranes. Scheffrahn et al., (1990) describes most of what is needed to know on 

pack permeability to SF and its low rate of permeation compared with methyl bromide through plastic 

films. On the basis of data from Scheffrahn et al., (1990), a 24 hour exposure to SF is unlikely to give 

lethal (ovicidal) concentrations within an intact laminate bag of rice. This conclusion is based on the 

likely diffusion and permeation of SF through plastic laminates that are used to package possibly 

infested processed rice in Australia. The influence of the pinholes is undefined and probably quite 

variable. 

It may be useful for the Australian applicant to consider the quoted references. 

Furthermore, it should now be possible to determine the likely SF and fluorine ion (F-) residues that 

may be formed in the course of an effective fumigation with SF. 

7.4.3 References 

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China, Sichuan Publishing House of Science & Technology, Oct. 1999, Chengdu Province, P. R. 

China, Vol. 1, pp. 406-408. 

Tsai, W.-T., Mason, L.J., Chayaprasert, W., Maier, D.E., Ileleji, K.E. (2011). Investigation of fumigant efficacy in 

flour mills under real-world fumigation conditions. Journal of stored Products Research vol. 47, 

doi:10.1016/j.jspr.2010.10.006. 

Williams, L.H., Sprenkel, R.J. (1990). Ovicidal activity of sulfuryl fluoride to anobiid and lyctid beetle eggs of various 

ages. Journal of entomological Science 25, 366-375. 

Xiaoping, Y., Yuxin, Ch., Guaogan, X., Juan, Z., Jiade, S., Guangli, Sh, Shengjie, J., Jialiang, W. (2008). Mortality of 

three stored product pests exposed to sulfuryl fluoride in laboratory and field tests. In: Daolin, G. et 

al. (Eds.), Proceedings of the 8th International conference on Controlled Atmosphere and 

Fumigation, 21-26 September 2008, Chendu, Sichuan Publishing Houise of Science and Technology, 

Chengdu, pp. 191-195. 
TEAP May 2011 Progress Report 

Table 7-3: ct-products for sulfuryl fluoride giving >99% mortality of eggs of various stored product pests, given in published lab

results at different temperatures and exposure periods. 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Ahasverus advena All 20 4656 1.67 Ahasverus advena All 20 3072 4 Ahasverus advena All 20 1966 7 Acanthoscelides obtectus All 20 1070 1 Acanthoscelides obtectus All 20 605 4 Acanthoscelides obtectus All 25 763 1 Acanthoscelides obtectus All 25 379 2 Acanthoscelides obtectus All 30 480 1 Acanthoscelides obtectus All 30 259 2 Attagenus piceus 2 26.7 1216 0.66 76 Acarus siro All 25 >669 Corcyra cephalonica 3 27 377 3 5.24 Corcyra cephalonica All 27 503 5 4.19 Corcyra cephalonica All 27 503 4 5.24 Corcyra cephalonica All 27 449 3 6.24 Cryptolestes ferrugineus (PH3 resistant) all st 15 720 1 30 
120 TEAP May 2011 Progress Report

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Cryptolestes ferrugineus (PH3 resistant) all st \ 15 1440 2 20 Cryptolestes ferrugineus (PH3 resistant) all st 15 720 3 30 Cryptolestes ferrugineus (PH3 resistant) all st 20 720 1 30 Cryptolestes ferrugineus (PH3 resistant) all st 20 720 3 10 Cryptolestes ferrugineus all 25 480 1 20 Cryptolestes ferrugineus all 25 960 2 20 Cryptolestes ferrugineus Allst 25 720 3 10 Cryptolestes ferrugineus (PH3 resistant) all st 25 720 1 30 Cryptolestes ferrugineus (PH3 resistant) all st r 25 960 2 20 Cryptolestes ferrugineus (PH3 resistant) all st 25 720 3 10 Cryptolestes ferrugineus all 15 1440 3 20 Cryptolestes ferrugineus all 15 720 1 30 Cryptolestes ferrugineus all 15 960 2 30 Cryptolestes ferrugineus (PH3 resistant) all st 20 960 2 20 
TEAP May 2011 Progress Report 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Carpophilus hemipterus 2 15 4320 (99) 1 180 Carpophilus hemipterus 2 20 2400 1 100 Carpophilus hemipterus 1 25 4320 1 180 Carpophilus hemipterus 2 25 1920 1 80 Cryptolestes turcicus 25 784 Ephestia cautella 1 15 2160 1 90 Ephestia cautella 2 15 4560 1 190 Ephestia cautella 3 15 4560 1 190 Ephestia cautella 1 20 1440 1 60 Ephestia cautella 2 20 3360 1 140 Ephestia cautella 3 20 3360 1 140 Ephestia cautella 1 25 1440 1 60 
122 TEAP May 2011 Progress Report

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Ephestia cautella 2 25 2160 1 90 Ephestia cautella 3 25 2160 1 90 Ephestia cautella 1 30 480 1 20 Ephestia cautella 2 30 720 1 30 Ephestia cautella 3 30 720 1 30 Ephestia elutella All 25 474 22 21.3 Ephestia elutella All 25 557 48 11.4 Ephestia elutella 1-4 15 465 (99) 0.75-2 11.6 Ephestia elutella 1-4 15 1078 (99) 0.75-2 21.3 Ephestia elutella 1-4 20 683 (99) 0.75-2 11.6 Ephestia elutella 1-4 20 624 (99) 0.75-2 21.3 Ephestia elutella 1-4 25 559 (99) 0.75-2 11.6 Ephestia elutella 1-4 25 475 (99) 0.75-2 21.3 Ephestia kuehniella 1 15 3214 (99) 2133 (P 99) 2 Ephestia kuehniella 2 15 7485 (99) 9293 (P 99) 25 
TEAP May 2011 Progress Report 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Ephestia kuehniella 2 15 3741(99) 3471 (P 99) 43 Ephestia kuehniella 2 15 5149 (99) 3958 (P 99) 2 Ephestia kuehniella 3 15 6710 (99) 3975 (P 99) 2 Ephestia kuehniella 4 15 6294 (99) 2991 (P 99) 2 Ephestia kuehniella 4 15 3088 (99) 4846 (P 99) 25 Ephestia kuehniella 1 25 554 (99) 20 Ephestia kuehniella 2 25 937 (99) 1058 (P 99) 1 Ephestia kuehniella 2 25 1078 (99) 930 (P 99) 20 Ephestia kuehniella 3 25 795 (99) 651 (P 99) 1 Ephestia kuehniella 3 25 830 (99) 596 (P 99) 20 Ephestia kuehniella 1 15 2736 Ephestia kuehniella 1 15 3214 (99 h) Ephestia kuehniella 2 15 3301 
124 TEAP May 2011 Progress Report

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Ephestia kuehniella 2 15 4524 (99 h) Ephestia kuehniella 3 15 2736 Ephestia kuehniella 3 15 6710 (99 h) Ephestia kuehniella 4 15 2736 Ephestia kuehniella 4 15 6294 (99 h) Ephestia kuehniella 1 25 473 Ephestia kuehniella 1 25 452 (99 h) Ephestia kuehniella 2 25 912 Ephestia kuehniella 3 25 667 (99 h) Ephestia kuehniella 20 1680 2 35 Ephestia kuehniella 20 2520 3 35 Ephestia kuehniella All 20 1688 2 35 Ephestia kuehniella All 20 1688 2 35 Ephestia kuehniella All 20 842 3 11.7 Ephestia kuehniella 1 20 480 1 Ephestia kuehniella 1 20 960 2 Ephestia kuehniella 1 20 720 3 Ephestia kuehniella 2 20 480 1 
TEAP May 2011 Progress Report 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Ephestia kuehniella 2 20 960 2 Ephestia kuehniella 2 20 720 3 Ephestia kuehniella 3 20 1440 2 Ephestia kuehniella 3 20 1440 3 Ephestia kuehniella 4 20 1440 2 Ephestia kuehniella 4 20 720 3 Ephestia kuehniella All 22-40 1860-2255 (99.4) 1.5-2 Liposcelis bostrichophila 25 1000 Lyctus brunneus 1 470 (97.7) Oryzaephilus mercator all st 15 >720 1 >30 Oryzaephilus mercator all st 15 1440 2 30 Oryzaephilus mercator all st 15 720 3 10 Oryzaephilus mercator all st 20 >720 1 >30 Oryzaephilus mercator all st 20 1440 2 30 Oryzaephilus mercator all st 20 720 3 10 Oryzaephilus mercator all st 25 720 1 30 Oryzaephilus mercator all st 25 1440 2 30 
126 TEAP May 2011 Progress Report

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Oryzaephilus mercator all st 25 720 3 10 Oryzaephilus surinamensis 20 636 1 26.5 Oryzaephilus surinamensis 20 1272 2 26.5 Oryzaephilus surinamensis 20 958 3 13.3 Oryzaephilus surinamensis All 20 319 1 13.3 Oryzaephilus surinamensis All 20 638 2 13.3 Oryzaephilus surinamensis All 20 958 3 13.3 Oryzaephilus surinamensis All 22-40 1860-2255 (100-99.1) 1.5-2 Plodia interpunctella 20 564 1 23.5 Plodia interpunctella 20 562 2 11.7 Plodia interpunctella 20 842 3 11.7 Plodia interpunctella 28-31 1100-1500 av: 1353 0.93 Plodia interpunctella All 20 281 1 11.7 Plodia interpunctella All 20 562 2 11.7 Plodia interpunctella All 20 842 3 11.7 Plodia interpunctella (G) 1 25 269 1 11.2 Plodia interpunctella (US) 1 25 269 (99.6) 1 11.2 
TEAP May 2011 Progress Report 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Plodia interpunctella (G) 1 25 239 2 4.97 Plodia interpunctella (US) 1 25 365 2 7.6 Plodia interpunctella (G) 1 25 979 3 13.6 Plodia interpunctella (US) 1 25 979 3 13.6 Plodia interpunctella (G) 2-4 25 192 1 8 Plodia interpunctella (US) 2-4 25 192 1 8 Plodia interpunctella (G) 2-4 25 365 2 7.6 Plodia interpunctella (US) 2-4 25 490 2 10.2 Plodia interpunctella (G) 2-4 25 979 3 13.6 Plodia interpunctella (US) 2-4 25 979 3 13.6 Plodia interpunctella All 22-40 1860-2255 1.5-2 Plodia interpunctella 1 30 227 2 5 Plodia interpunctella 2 30 640 2 15 Plodia interpunctella 3 30 1180 (98.8) 2 25 Plodia interpunctella All 25 814 2 Plodia interpunctella All 25 854 (99) 2 
128 TEAP May 2011 Progress Report

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Rhyzopertha dominica All 20 912 0.83 Rhyzopertha dominica All 20 762 2.42 Rhyzopertha dominica All 20 912 5 Rhyzopertha dominica All 25 656 0.83 Rhyzopertha dominica All 25 525 2.42 Rhyzopertha dominica All 25 638 5 Rhyzopertha dominica All 30 415 0.83 Rhyzopertha dominica All 30 304 5 Rhyzopertha dominica All 30 155 5 Rhyzopertha dominica 28-31 1100-1500 av: 1353 0.93 Rhyzopertha dominica 26.7 219 0.66 13.7 Rhyzopertha dominica All 23-27 1920 2 40 Rhyzopertha dominica All 23-27 1440 2 30 Rhyzopertha dominica All 23-27 1680 7 10 Rhyzopertha dominica All 23-27 840 (98.6) 7 5 Rhyzopertha dominica 19.3; min 12 4277 (d)+ CO2 5.94+14.25 CO2 Sitotroga cerealella 2 26.7 90 0.66 5.6 Sitophilus granarius 25 966 
TEAP May 2011 Progress Report 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Sitophilus granarius 20 840 1 35 Sitophilus granarius 20 1680 2 35 Sitophilus granarius 20 1339 3 19 Sitophilus granarius All 20 840 1 35 Sitophilus granarius All 20 1680 2 35 Sitophilus granarius All 20 1339 3 18.6 Sitophilus oryzae All 28-31 1100-1500 av: 1353 0.93 Sitophilus oryzae All 23-27 1920 2 40 Sitophilus oryzae All 23-27 1440 2 30 Sitophilus oryzae 19.3; min 12 4277 (d) + CO2 5.94+ 14.25 CO2 Stegobium paniceum All 20 437 1 18.2 Stegobium paniceum All 20 874 2 18.2 Stegobium paniceum All 20 1310 3 18.2 Stegobium paniceum All 28-31 1100-1500 av: 1353 0.93 Tribolium castaneum All 25 3030 (99 h) Tribolium castaneum 25 1869 (99 e) Tribolium castaneum 30 3958 (99 h) Tribolium castaneum 30 1243 (99 e) 
130 TEAP May 2011 Progress Report

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Tribolium castaneum 25 1669 Tribolium castaneum 31 633-1134 Tribolium castaneum 28 1154 (99) Tribolium castaneum 28-31 

1100-1500 Av: 1353 

0.93 

Tribolium castaneum 22-32 663-1191 (89-92) Tribolium castaneum All 20 960 + HCN (100) 2 20 + 1.5 HCN Tribolium castaneum All 20 72 (HCN) (85) 2 1.5 HCN Tribolium castaneum All 22-40 1860-2255 (98.8) 1.5-2 Tribolium castaneum 25 1157 (99.8) 2 Tribolium castaneum 19.3; min 12 4277 (d) + CO2 5.94+ 14.25 CO2 Tribolium confusum 25 813 (99) Tribolium confusum 25 780 Tribolium confusum All 25 941 2 
TEAP May 2011 Progress Report 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Tribolium confusum 25 672 Tribolium confusum 21 853-1345 Tribolium confusum 26 1192 Tribolium confusum 28 1154 Tribolium confusum 31 633-1134 Tribolium confusum 32 1133 Tribolium confusum 22 1016 Tribolium confusum 20 319 1 13.3 Tribolium confusum 20 638 2 13.3 Tribolium confusum 20 958 3 13.3 Tribolium confusum 28-31 1100-1500 av: 1353 0.93 Trogoderma inclusum 20 437 1 18.2 18.2 Trogoderma inclusum 20 562 2 11.7 Trogoderma inclusum 20 1310 3 18.2 Tenebrio molitor All 22-40 1860-2255 (99.5) 1.5-2 
132 TEAP May 2011 Progress Report

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Trogoderma variabile 25 936 (100) Trogoderma variabile 25 1419 (99 h) Trogoderma versicolor All 20 437 1 18.2 Trogoderma versicolor All 20 562 2 11.7 Trogoderma versicolor All 20 1310 3 18.2 Species and strain Field trials 

Egg age in days Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF dosage in (g m-3 

Ephestia kuehniella Unspecified 28-31 1100-1500av:1353 0.93 49.7-67 Ephestia kuehniella Unspecified 25 1125 1 46.9 Plodia interpunctella Unspecified 25 1503 1 62.5 Plodia interpunctella 1-3 33-37 612-1014 A1 (99.5 e) 1 26-42 Plodia interpunctella 1-3 30-40 520-670 A3 (94.7 h; 100.0 e) 0.94 23-30 Plodia interpunctella 1-3 - 455-713 C3 (99.7 h; 99.7 e) 0.75 25-40 Plodia interpunctella 1-3 25-30 873-1346 D3 (74.3 h; 100.0 e) 1 36-56 Sitophilus granarius Unspecified 25 1503 1 62.5 Sitophilus zeamais All 19-20 92 + 441 (CO2) 0.25 

15.38+ 73.58 (CO2) 
TEAP May 2011 Progress Report 

Species and strain Laboratory tests 

Egg age (days) Temperature (°C) Ct-product for>99% 

mortality ( g h m-3) 

Exposure period (days). in days 

SF concentration (g m

Sitophilus zeamais All 11-15.5 3840 + 41472 (CO2) 16 10 + 108 (CO2) Sitophilus zeamais All 12-19 1680 + 38976 (CO2) 14 5 + 116 (CO2) Sitophilus zeamais All 11-15 1152 + 44160 (CO2) 16 3 + 115 (CO2) Sitophilus zeamais All 12-18 1008 + 40622 (CO2) 14 3 + 121 (CO2) Sitophilus zeamais All 13-14 2400 10 10 Tribolium castaneum 1-3 32-37 427-554 A2 (99 e) 0.98 18-24 Tribolium castaneum 1-3 30-40 520-670 A3 (96.3 h;100.0 e) 0.94 23-30 Tribolium castaneum 1-3 30-36 507-907 B1 (99.3 h) 0.98 22-39 Tribolium castaneum 1-3 29-34 775-986 B2 (94.3 h; 99 e) 0.93 35-45 Tribolium castaneum 1-3 - 455-713 C3 (98.7 h; 100.0 e) 0.75 25-40 Tribolium confusum 25 1125 1 46.9 

Abbreviations: h = hatch; e = emergence; 100 = ct for no survivors; av = average; P 99 = calculated with probit analysis for LD99; d = ct based on dosage, no explicit indication of gas losses, t1⁄2 (500 Pa - 250 Pa) =4US = US strain; all = all egg ages; all st = all developing stages; A1-A3, B1, B2, C3, D2 and D3 different fumigated flour mills 
134 TEAP May 2011 Progress Report

Table 7-4: Lowest and highest reported ct-products in the literature for the complete control of eggs 

of the listed pest insects depending on temperature, egg age and concentration during fumigation 

with SF (all exposure periods). 

 

0 1000 2000 3000 4000 5000 6000 7000 8000

Trogode rm a ve rsicolor

Trogode rm a inclusum

Tribolium ca sta ne um

Stegobium paniceum

Sitophilus ze a m a is

Sitophilus gra na rius

Plodia interpunctella

Oryza e philus m e rca tor

Liposce lis bostrichophila

Ephe stia e lute lla

Cryptole ste s turcicus

Corcyra cephalonica

Atta ge nus pice us

Aca rus siro

ct product in gh/m 3

max

min

ct product
May 2011 TEAP Progress Report 135

Table 7-5: Sulfuryl fluoride ovicidal efficacy data for non-quarantine pestsof stored 

products (Dr Spencer Walse, personal communication, USDA-ARS Parlier, 2009-present) 

Mortality data corrected for control mortality. 

Species Egg age 

(days) 

Temperature( °C) ct-product giving stated 

% mortality (g h m-3) 

Exposure 

(days) 

Number of 

specimens in test 

Plodia interpunctella 0-3 15.6 468 (50) 1 

Plodia interpunctella 0-3 15.6 1567.2 (99) 1 

Plodia interpunctella 0-3 15.6 3736.8 (P9) 1 

4720 

Plodia interpunctella 0-3 21.1 266.4 (50) 1 

Plodia interpunctella 0-3 21.1 873.6 (99) 1 

Plodia interpunctella 0-3 21.1 2056.8 (P9) 1 

2400 

Plodia interpunctella 0-3 26.7 129.6 (50) 1 

Plodia interpunctella 0-3 26.7 559.2 (99) 1 

Plodia interpunctella 0-3 26.7 1610.4 (P9) 1 

3000 

Tribolium castaneum 0-2 15.6 799.2 (50) 1 

Tribolium castaneum 0-2 15.6 3050.4 (99) 1 

Tribolium castaneum 0-2 15.6 7992 (P9) 1 

3758 

Tribolium castaneum 0-2 21.1 909.6 (50) 1 

Tribolium castaneum 0-2 21.1 2424 (99) 1 

Tribolium castaneum 0-2 21.1 4908 (P9) 1 

2696 

Tribolium castaneum 0-2 26.7 607.2 (50) 1 

Tribolium castaneum 0-2 26.7 1416 (99) 1 

Tribolium castaneum 0-2 26.7 2604 (P9) 1 

1800 
136 May 2011 TEAP Progress Report 

Table 7-6: Grouping of pest species by probable, possible and unlikely control of eggs by 

sulfuryl fluoride at 1500 g h m-3 at 26.7°C .) 

PROBABLE EGG CONTROL AT 1500 g h m-3 and 26.7°C 

Species: common 

name 

Species: scientific name ct-product ( g h 

m-3) giving 

99% mortality 

Reference 

Rust-red grain beetle Cryptolestes ferrugineus ~720 Baltaci et. al (2008) 

Merchant grain beetle Oryzaephilus mercator ~720 Baltaci et. al (2008) 

Warehouse moth Ephestia elutella ~500 Baltaci et. al (2006) 

Rice moth Corcyra cephalonica ~500 Barakat et al, (2009) 

Psocid Liposcelis bostrichophila 1000 Bell et. al, (2003) 

Grain beetle Cryptolestes turcicus 780 Bell et. al, (2003) 

Flour mite Acarus siro 700 Bell et. al, (2003) 

Warehouse beetle Trogoderma variabile ~1000 Bell et. al, (1999) 

POSSIBLE EGG CONTROL AT 1500 g h m-3 and 26.7°C 

Mediterranean flour 

moth 

Ephestia kuehniella 500-1300 Baltaci et al (2006); Drinkall et al 

(2003) ; Ducon et al (2003); 

Reichmuth and Klementz (2008a) 

Indian meal moth Plodia interpunctella 1000-1300 Drinkall et al (2003) ; Ducon et al 

(2003); 

Confused flour beetle Tribolium confusum 600-1300 Bell et al (1999); Cisela and 

Ducom (2009); Drinkall et al 

(2003) 

Rice weevil Sitophilus oryzae 1300 Drinkall et al (2003) 

Lesser grain borer Rhyzopertha dominica 1300 Drinkall et al (2003) 

Drugstore beetle Stegobium paniceum 1300 Drinkall et al (2003) 

UNLIKELY EGG CONTROL AT 1500 g h m-3 and 26.7°C F 

Almond moth Ephestia cautella 1400 Akan and Ferizli (2010) 

Granary weevil Sitophilus granaries 1000-1500 Ducon et al (2003); Reichmuth 

and Klementz (2008a) 

Red flour beetle Tribolium castaneum 1500-1850 Drinkall et al (2003) ; Ducon et al 

(2003); Reichmuth and Klementz 

(2008a) 

Dried fruit beetle Carpophilus hemipterus ~4500 Karakoyun and Emekei (2010) 
May 2011 TEAP Progress Report 137

8 2011 Evaluations of Critical Use Nominations for Methyl 

Bromide and Related Matters – Interim Report 

8.1 Scope of the Report 

This 2011 interim report provides evaluations by MBTOC of Critical Use Nominations 

(CUNs) submitted for methyl bromide (MB) in 2012 and 2013 by the Parties in accordance 

with Decision IX/6 (Annex I, MOP16). CUNs were submitted to the Ozone Secretariat by the 

Parties, in accordance with Decision XVI/4 (Annex II of this report). Parties are encouraged 

to ensure any CUN is submitted in accordance with the timetable shown in paragraph 1 of 

Annex I, Decision XVI/4. 

This interim report also provides information from Parties on stocks (in accordance with 

Decision Ex.1/4 (9f)), partial information on actual MB consumption for critical uses (in 

accordance with Decision XVII/9), apparent adoption rates of alternatives, as evidenced by 

trend lines on reduction of MB CUNs (in accordance with Decisions XIX/9, XX/5). It is 

noted that trend lines on adoption do not necessarily indicate true adoption rates for 

alternatives, as the use of stocks of MB that may have been available to the same sector or 

areas of production may have increased or fallen within the sector due to a range of 

circumstances. 

MBTOC’s has recently completed the 2010 Assessment Report 

(http://ozone.unep.org/Assessment_Panels/TEAP/Reports/MBTOC/MBTOC-AssesmentReport-2010.pdf). The MBTOC Progress Report in this TEAP report contains the most recent 

information on registration issues affecting the availability of alternatives for preplant and 

post harvest uses (in accordance with Decision Ex. 1/4 (9i) and (9j)), consideration of 

national, sub national and local regulations and laws on the use of MB alternatives (in 

accordance with Decision XX/5) and summaries of emission control, research and appropriate 

efforts (in accordance with Decision XXI/11, para 9). 

Standard presumptions used in the 2011 round were the same as those used in the 2010 

evaluations of the CUNs. MBTOC-Soils (MBTOC-S) has updated references to substantiate 

its standard presumptions for MB dosage rates cited in previous reports, and no further 

updates have been provided in this report. These standard presumptions are subject to 

continual review. However, any changes proposed by MBTOC are required to be approved 

by the Party’s in the MOP preceding the year of assessment based on a draft Decision 

presented to the MOP in accordance with paragraph 2 in Annex 1 to the report of MOP16. 

MBTOC-S has initial responsibility for issues concerning MB and its alternatives for preplant soil uses and for the preparation of a Progress Report on alternatives to methyl bromide 

for these uses. MBTOC-Structures and Commodities (MBTOC-SC) has initial responsibility 

for issues concerning MB uses and alternatives for structural and commodity treatments and 

for the preparation of a Progress Report on alternatives to methyl bromide for these uses. 

MBTOC QPS has initial responsibility for issues concerning MB and its alternatives for QPS 

uses and for the preparation of a Progress Report on alternatives to methyl bromide for these 

uses. 

Evaluations of CUNs for the soil and structural treatments were evaluated and the results of 

the evaluations are reported separately below. Outcomes from deliberations by the three 

MBTOC subcommittees were discussed in plenary with all of the MBTOC members present 

at the meeting in Turkey with the aim of reaching consensus on the draft evaluations by the 

whole committee. Discussions on the last day in plenary reviewed all nominations and 

focused on nominations where there were difficulties in arriving at a recommendation. 
138 May 2011 TEAP Progress Report 

8.2 Critical Use Nominations for Methyl Bromide 

8.2.1. Mandate 

Under Article 2H of the Montreal Protocol on the production and consumption (defined as 

production plus imports minus exports) of MB required it to be not consumed in Parties not 

operating under Article 5(1) of the Protocol after 1 January 2005. However, the Parties 

agreed to a provision enabling exemptions for those uses of MB that qualify as critical. 

Parties established criteria, under Decision IX/6 (see Annex 1 of this report) of the Protocol, 

which all critical uses need to meet in order to qualify for an exemption. TEAP and its 

MBTOC provided guidance to the Parties’ decisions on critical use exemptions in accordance 

with Decisions IX/6 and Annex I of Decision XVI/4. 

8.2.2. Fulfilment of Decision IX/6 

Decision XVI/2 and Decision XXI/11 directed MBTOC to indicate whether all CUNs fully 

met the requirements of Decision IX/6. When the requirements of Decision IX/6 are met, 

MBTOC can recommend critical uses of MB. Where some of the conditions are not fully met, 

MBTOC can recommend a decreased amount depending on its technical and economic 

evaluation, or determine the CUN as “unable to assess” and request further information from 

the Party. When the information is submitted, MBTOC is required to re-assess the 

nomination, following the procedures defined in Annex 1 of the Sixteenth Meeting of the 

Parties 

Several Parties presented Phase Out Plans for MB for specific nominations. For example, 

Japan to eliminate the use of MB for fresh chestnuts and Australia to eliminate the use of MB 

on packaged rice. 

MBTOC recommended less methyl bromide that requested in a CUN when a technically and 

economically feasible alternative was considered to be available or, in a few cases, when the 

Party failed to show that there was no technically and economically feasible alternative. In 

this round of CUNs, as in previous rounds, MBTOC considered all information provided by 

the Parties, including answers to questions requested by MBTOC, up to the date of the 

evaluation. 

Now that technically and economically feasible alternatives have been identified for most 

applications, regulations on the use of these alternatives determine their availability to the end 

users. In addition, comparative information on the economic feasibility/infeasibility of the 

use of alternatives compared to MB is critical to the outcomes of present and future CUNs. 

Without information on the economic feasibility of MB alternatives and pertinent regulations 

from the nominating Parties, further CUNs may not be assessable, as MBTOC will be unable 

to analyse the impact of national, subnational and local regulations and laws as required in 

Decision XX/5. In many cases, MBTOC has proposed that existing commercially and 

economically feasible alternatives should be used. Where these are not available, MBTOC 

has suggested research that could lead to commercial alternatives to replace MB. MBTOC has 

also shown how regulatory issues can hinder or promote the phase out of MB, and has 

directed Parties attention toward such issues.Parties are encouraged to review the section in 

the Progress Report concerning economic analysis as guidance to improving the economic 

information in the CUNs. 

Paragraph 20 of Annex 1 in Decision XVI/4, Parties specifically requested that, in cases 

where a nomination relies on the economic criteria of Decision IX/6, MBTOC’s report should 

explicitly state the central basis for the Parties economic argument relating to CUNs. 

However, there were relatively few nominations reviewed in 2011 that contained economic 

arguments as criteria for critical uses. Parties are encouraged to review the section in the 
May 2011 TEAP Progress Report 139

Progress Report concerning economic analysis as guidance to providing any economic 

information in future CUNs. 

8.2.3 Consideration of Stocks - Decision Ex.1/4 (9f) 

One criterion for granting a critical use is that MB “is not available in sufficient quantity and 

quality from existing stocks of banked or recycled methyl bromide” (paragraph 1 (b) (ii) of 

Decision IX/6). Parties nominating critical use exemptions are requested under decision 

Ex.I/4(9f) to submit an accounting framework with the information on stocks. MBTOC has 

not reduced its recommended amount of methyl bromide in consideration of stocks held by 

the Party and has instead relied on Parties to take this into consideration when approving the 

amounts recommended by TEAP for each nomination. To assist the Parties with their 

consideration of stocks, and in accordance with Decision XVIII/13(7), a summary of the data 

on stocks as reported by the Parties in the first year for accounting in 2006, and then reports 

submitted in 2008 to 2011 are summarized in Tables 8-1 to 8-4 below. 

Efficient functioning of commerce requires a certain level of available stocks and additional 

stocks to respond to emergencies. Additionally, stocks may be held on behalf of other Parties 

or for exempt uses (feedstock and QPS uses). The correct or optimal level of stocks for 

virtually every input to production is not zero. In addition, stocks are privately owned and 

may not be readily available for critical uses, or there may be national regulations preventing 

the transfer of stocks. Despite these restrictions, Parties may wish to ensure that stocks are 

used wherever possible in order to minimize the quantity of MB that need to be produced 

each year for critical uses. 

Table 8-1: Quantities of MB (metric tonnes) ‘on hand’ at the beginning and end of 2005, 

as first reported by Parties in 2006/2007 under Decision XVI/6. 

Quantity of MB as reported by Parties (metric tonnes) 

Party 

Critical use 

exemptions 

authorized 

by MOP for 

2005 

Amount on 

hand at 

start of 

2005 

Quantity 

acquired for 

CUEs in 2005 

(production 

+imports) 

Amount 

available 

for use in 

2005 

Quantity 

used for 

CUEs in 

2005 

Amount 

on hand at 

the end of 

2005 

Australia 146.6 0 114.912 114.912 114.912 0 

Canada 61.792 0 48.858 48.858 45.146 3.712 

EU 4 392.812 216.198 2 435.319 2 651.517 2 530.099 121.023 

Israel 1 089.306 16.358 1 072.35 1 088.708 1 088.708 0 

Japan 748 0 594.995 594.995 546.861 48.134 

New 

Zealand 

50 6.9 40.5 47.4 44.58 2.81 

USA(a) 9 552.879 7 613 not reported 7 170 443 

(a) Additional information on stocks was reported on US EPA website, September 2006: MB inventory held 

by USA companies: 2004 = 12,994 tonnes; 2005 = 9,974 tonnes. 
140 May 2011 TEAP Progress Report 

Table 8-2: Quantities of MB ‘on hand’ at the beginning and end of 2008, as reported by 

Parties in 2009 under Decision XVI/6. 

Quantity of MB as reported by Parties (metric tonnes) 

Party Critical use 

exemptions

authorized 

by MOP for 

2008 

Amount 

onhand at 

start of 

2008 

Quantity 

acquired for 

CUEs in 2008 

(production 

+imports) 

Amount 

available 

for use in 

2008 

Quantity 

used for 

CUEs in 

2008 

Amount 

on hand 

at the 

end of 

2008 

Australia 48.450 0 41.037 41.037 41.037 0 

Canada 42.19 0.348 32.937 33.285 31.281 1.997 

EU 245.146 6.409 206.146 212.555 212.463 0.092 

Israel 

Japan 443.775 24.467 392.994 417.461 409.937 7.524 

USA 5 336 1 730 

6458(a) 

3 036 9464 4 083 5381(b) 

269(c) 

(a) Amount of pre-2005 stocks; (b) Includes the pre-2005 stocks; (c). Amount of unused allocation for 

CUEs which will be reduced from following years production

Table 8-3: Quantities of MB ‘on hand’ at the beginning and end of 2009, as reported by 

Parties in 2010 under Decision XVI/6. 

Quantity of MB as reported by Parties (metric tonnes) 

Party Critical use 

exemption 

authorized 

by MOP for 

2009 

Amount on 

hand at 

start of 

2009 

Quantity 

acquired for 

CUEs in 2009 

(production 

+imports) 

Amount 

available 

for use in 

2009 

Quantity 

used for 

CUEs in 

2009 

Amount 

on hand 

at the 

end of 

2009 

Australia 37.61 0 33.278 33.278 33.278 0 

Canada 39.1 1.997 30.276 30.276 23.8 6.38 

Israel Not Reported 

Japan 305.380 11.882 278.616 290.498 286.532 3.966 

USA 2,276 4,273(a) 2,274 6,547 2,215 

1,135(d) 

3,063 (b) 

59 (c) 

(a) Amount of pre-2005 stocks 

(b) Includes the pre-2005 stocks 

(c).Amount of unused allocation for CUEs which will be reduced from following years production 

(d) Stocks used for CUE uses in 2009 
May 2011 TEAP Progress Report 141

Table 8-4: Quantities of MB ‘on hand’ at the beginning and end of 2010, as reported by 

Parties in 2011 under Decision XVI/6. 

Quantity of MB as reported by Parties (metric tonnes) 

Party Critical use 

exemption 

authorized 

by MOP for 

2010 

Amount on 

hand at 

start of 

2010 

Quantity 

acquired for 

CUEs in 2010 

(production 

+imports) 

Amount 

available 

for use in 

2010 

Quantity 

used for 

CUEs in 

2010 

Amount 

on hand 

at the 

end of 

2010 

Australia 36.44 0 34.167 34.167 34.167 0 

Canada 33.277 6.38 23.456 29.836 25.254 3.4 

Japan 267 8.82 248.67 257.49 251.159 6.331 

USA 1,956 3,063 (a) 1,955 5,018 1,955 

613 (d) 

1,803(b) 

(a) Amount of pre-2005 stocks available at the start of 2010 

(b) Amount of pre-2005 stocks available at the end of 2010. 

(d) Stocks used for CUE uses in 2010 

In 2006, the US predicted that pre 2005 stocks for preplant soil uses would be exhausted by 

2009, yet pre 2005 stocks are still available. It is noted that the stocks recently reported by the 

United States (about 1,800 tonnes) were approximately three times the quantity nominated by 

the US for 2013 (about 604 tonnes) and suggests Parties may wish to review this information 

in the light of the Decision IX/6 1(b)(ii) that “...permits production only if methyl bromide is 

not available in sufficient quantity and quality from existing stocks...”. 

It is noted that stocks are privately held in the United States and market forces determine 

when and at what price stocks are used. It is also notes that the US has made allowances for 

some of the use of these stocks as critical allowances for CUNs when licensing critical uses of 

methyl bromide and suggests that Parties may wish to seek clarification on how the remaining 

stocks will be apportioned. 

8.2.4. Reporting of MB Consumption for Critical Use - Decision 

XVII/9 

Decision XVII/9(10) of the 17th MOP requests TEAP and its MBTOC to “report for 

2005 and annually thereafter, for each agreed critical use category, the amount of 

methyl bromide nominated by a Party, the amount of the agreed critical use and 

either: 

(a) The amount licensed, permitted or authorised; or 

(b) The amount used 

Since the start of the CUN reviews in 2003, MBTOC has provided the amounts of MB 

nominated and agreed for each critical use (Annexes III and IV). Australia, Canada, Japan 

and the United States that submitted nominations for 2012 and/or 2013 did not supply data 

under Form 2 of the accounting framework as it was not accepted by the Parties (refer p. 65 of 

the Handbook on Critical Use Nominations (version 6 of December 2007). The data reported 

here for (a) and (b) above is therefore incomplete. Some Parties record part of the information 

under their own local reporting requirements. 
142 May 2011 TEAP Progress Report 

8.2.5 Trends in Methyl Bromide Use for CUEs since 2005 

The nominated amounts and the apparent rate of reduction in MB or adoption of alternatives 

achieved by Parties are shown in Table 8-5, as well as Figures 8-1 and 8-2. It is noted that for 

those countries that have pre-2005 stocks of MB that are being drawn down, the reductions in 

CUEs from year to year cannot be taken directly as evidence of alternative adoption since pre2005 stocks may have been used in the same sectors. Table 14-6 and 14-7 in particular show 

the amounts nominated by Parties for preplant soil uses and those recommended for ‘Critical 

Use’ in either 2012 or 2013. 

Decision XVII/9 requires TEAP to show trends in the phase out of the critical uses of MB by 

the Parties. As part of the requirements of Decision XVII/9, trends in phase out by Parties are 

shown below. Since 2005, there has been a progressive trend in the reduction of methyl 

bromide for CUNs by all Parties for preplant soil uses and post harvest uses, although this has 

occurred at different rates. Figs 8-1 and 8- 2 show the trends in the reduction in amounts 

approved/nominated by Parties for ‘Critical Use’ from 2005 to 2013 for some key uses. The 

complete trends in phase out of MB by country, as indicated by change in CUE, are shown in 

Annexes III and IV. 
May 2011 TEAP Progress Report 143

Figure 8-1: Amounts of MB exempted for CUE uses in selected preplant soil industries 

from 2005 to 2012. Solid lines indicate the trend in CUE methyl bromide approved by 

the Parties. Dashed lines indicate quantity of MB nominated by the Parties in 2013. ( See 

table 9 -7 for exact quantities nominated by the Party for 2013)

Cucurbits and Melons

0

200

400

600

800

1000

1200

1400

2005 2006 2007 2008 2009 2010 2011 2012 2013

Year

metric tonnes

Israel

Japan

USA

 

Cutflowers

0

50

100

150

200

250

300

350

400

2005 2006 2007 2008 2009 2010 2011 2012 2013

Year

metric tonnes

Australia

Belgium

France

Greece

Israel

Italy

Portugal

Spain

USA

Strawberry Fruit

0

500

1000

1500

2000

2500

2005 2006 2007 2008 2009 2010 2011 2012 2013

Year

metric tonnes

Australia France Israel Italy New Zealand Spain UK USA

Tomatoes

0

500

1000

1500

2000

2500

3000

3500

2005 2006 2007 2008 2009 2010 2011 2012 2013

Year

metric tonnes

Belgium Greece

Italy USA

Orchard Replant

0

100

200

300

400

500

600

700

800

2005 2006 2007 2008 2009 2010 2011 2012 2013

Year

metric tonnes

France

USA

Peppers and Eggplant

0

200

400

600

800

1000

1200

1400

2005 2006 2007 2008 2009 2010 2011 2012 2013

Year

metric tonnes

Belgium

France

Italy

Japan

Spain

USA
144 May 2011 TEAP Progress Report 

Figure 8-2: Amounts of MB exempted for CUE uses in the strawberry nursery sector 

from 2005 to 2013. Solid lines indicate the trends in CUE methyl bromide approved by 

the Parties. Dashed lines indicate quantity of MB nominated by the Party in 2013. 

Strawberry Nursery

0

50

100

150

200

250

2005 2006 2007 2008 2009 2010 2011 2012

metric tonnes

Australia

Belgium

Canada

France

Israel

Italy

New Zealand

Poland

Spain

USA (a)

• Additional amounts of MB (Estimated 460 t) are exempted under QPS regulations in 

the USA (TEAP 2010). 

.
May 2011 TEAP Progress Report 145

Figure 8-3: Amounts of MB exempted for CUE uses in mills and food processing facilities 

from 2008 to 2012. Solid lines indicate trend in CUE methyl bromide. Dashed lines 

indicate quantity of MB recommended by MBTOC for 2013. Chart uses Log 10 scale. 

Note that a number of countries (Belgium, France, Germany, Greece, Israel, Italy, UK) have 

phased out MB for use in mills and food processing as of 200 
May 2011 TEAP Progress Report 

146 Table 8-5: Summary of Critical Use Nominations and Exemptions 

 Quantities Nominated Quantities Approved 

2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 

(1ExMOP 

and 

16MOP) 

2006 

(16MOP+ 

2ExMOP+ 

17MOP) 

2007 

(17MOP + 

18MOP)

2008 

(18MOP

+ 

19MOP)

2009 

(19MOP)

201

(20MO

+ 

21MO

Australia 206.950 81.250 52.145 52.900 38.990 37.610 35.450 34.660 32.164 146.600 75.100 48.517 48.450 37.610 36Canada 61.992 53.897 46.745 42.241 39.115 35.080 19.368

+3.529

16.281 13.444 61.792 53.897 52.874 36.112 39.020 30

+3

European Community1 5754.361 4213.47 1239.873 245.00 0 0 0 0 0 4392.812 3536.755 689.142 245.146 0 Israel 1117.156 1081.506 1236.517 952.845 699.448 383.700 232.247 0 0 1089.306 880.295 966.715 860.580 610.854 290Japan 748.000 741.400 651.700 589.600 508.900 288.500 249.420 221.104 3.317 748.000 741.400 636.172 443.775 305.380 267New Zealand 53.085 53.085 32.573 0 0 0 0 0 0 50.000 42.000 18.234 0 0 Switzerland 8.700 7.000 0 0 0 0 0 0 0 8.700 7.000 0 0 0 USA 10753.997 9386.229 7417.999 6415.153 4958.034 3299.490 2388.128 1181.779+ 

6.270

656.366 9552.879 8081.753 6749.060 5355.976 4261.974 3232

+2

TOTALS 18704.241 15617.837 10677.552 8297.739 6244.487 4044.380 2928.142 1460.094 705.291 16050.089 13418.200 9160.714 6990.039 5,254.838 3572

* Not yet available. 1 Members of the European Community which had CUNs/CUEs included: 

2005 – Belgium, France, Germany, Greece, Italy, Netherlands, Poland, Portugal, Spain, and the United Kingdom. 2006 – Belgium, France, Germany, Greece, Ireland, Italy, Latvia, Malta, Netherlands, Poland, Portugal, Spain, and the United Kingdom. 

2007 – France, Greece, Ireland, Italy, Netherlands, Poland, Spain, and the United Kingdom 2008 – Poland, Spain
May 2011 TEAP Progress Report 147

8.2.6 Evaluations of CUNs – 2011 Round for 2013 Exemptions 

All three sub-committees of MBTOC met in Antalya, Turkey from 14 – 18 March 2011 to 

evaluate the requests for methyl bromide and to propose draft recommendations on the quantity 

of methyl bromide eligible for critical uses, to update reports, discuss issues of registration of 

alternatives and other matters. MBTOC sincerely appreciated the welcome and hospitality of 

the West Mediterranean Agricultural Research Institute (BATEM, Antalya) and the Ministry of 

Agriculture. MBTOC thanks BATEM and Professor Suat Yilmaz and his team for the 

organization of the meeting. The two MBTOC economists attended the meeting. 

The meetings were held as required in accordance with the time schedule for the consideration 

of CUNs provided in Annex I referred to in Decision XVI/4. Consensus decisions were made 

in subcommittees, and comments made by members were considered in the final 

recommendations. The results of the draft recommendations on the critical uses of methyl 

bromide proposed by the MBTOC-S and MBTOC-SC subcommittees were discussed in plenary 

as well as to some extent after the meeting via email. 

During the meeting MBTOC-Soils held bilateral meetings with the US delegation and 

separately with the Californian Strawberry Commission. MBTOC-SC held a bilateral with the 

US delegation. Arysta LifeSciences also presented to MBTOC-Soils and MBTOC-SC. All of 

the MBTOC-QPS members also attended the plenary presentations. 

Australia, Canada, Japan, and the USA submitted nominations for either preplant soil use and/or 

post harvest use in 2013. These Parties have submitted nominations in previous CUN years. 

Twenty nominations were submitted in this round which was 16 fewer than submitted in the last 

round (Table 8-6). Amounts of 7.445 t and 7.537 t was nominated in 2012 and 2013 

respectively for research in the USA in both the preplant soil and post harvest sectors. During 

the MBTOC meeting in Antalya, Party advised that the amounts for cured pork research were 

reduced from 1.220 t to 0.045 t for both years. The total nominated amount for all countries for 

2013 was 705.291 t and this represented a 52% reduction to that nominated in 2010 for 2012. 

The interim recommendation for 2013 was 655.979 t, ie. 93% of that nominated (Table 8-6). 

For the preplant soils CUNs, Australia and Canada submitted similar amounts to the previous 

rounds highlighting difficulties with phase out of MB for the strawberry nursery sector. In the 

USA almost all sectors were making significant progress towards phase out in this round 

although restrictions on the use of alternatives in California were affecting progress towards 

phase out in the strawberry fruit sector. 

In Structures and Commodities, Parties continued to show progress in reducing the quantity of 

methyl bromide requested in the CUNs. The reduction was most likely the result of continuing 

efforts by Parties to resolve the inter-related issues of treatment logistics, costs, trade demands 

and effectiveness of alternatives. Canada nominated amounts for mills in 2013, but did not 

nominate for pasta processing facilities. Additionally, Australia and Japan submitted Phase Out 

Plans stating they will not submit CUNs in 2015. 

MBTOC has sometimes recommended quantities of MB for 2012 or 2013 which are less those 

nominated. The grounds used for these recommendations are given in detail after the relevant 

CUNs in Tables 8-13 and 8-14. The adjustments for preplant soils use may in part be to 

account for presumptions given in Tables 8-10 and 8-11. 

In general and as result of the review of the CUNs, they were submitted due to the following 

issues: regulatory restrictions that did not allow partial or full use of alternatives, difficulties in 

the scale-up of alternatives, alternatives considered uneconomical and to a much smaller degree, 

the technical unavailability of alternatives. In structures and commodities CUNs noted that the 

US Environmental Protection Agency has proposed phasing out the use of sulfuryl fluoride for 
148 May 2011 TEAP Progress Report 

postharvest uses. This situation is discussed further in the 2010 Assessment Report and in the 

Progress Report. Sulfuryl fluoride, phosphine and controlled atmospheres are the leading 

alternatives for structural and commodity pest control. Additionally, MBTOC-SC notes that 

some Parties continue to struggle with the ability to adapt previously identified alternatives to 

their circumstances. 

In paragraph 20 of Annex 1 referred to in Decision XVI/4, Parties specifically requested that 

MBTOC explicitly state the specific basis for the Party’s economic statement relating to CUNs. 

Tables 8-13 and 8-14 provide this information for each CUN. This information was prepared by 

MBTOC economists. Parties are encouraged to review the section in the MBTOC Progress 

Report (TEAP 2011) concerning economic analysis as guidance to providing any economic 

information in future CUNs. 

8.2.7 Critical Use Nominations Review 

In considering the CUNs submitted in 2011, as in previous rounds , both MBTOC 

subcommittees applied the standards contained in Annex I of the final report of 16 MOP, and, 

where relevant, the standard presumptions given below. In particular MBTOC sought to provide 

consistent treatment of CUNs within and between Parties while at the same time taking local 

circumstances into consideration. Unless otherwise indicated, the most recent CUE approved by 

the Parties for a particular CUN was used as baseline for consideration of continuing 

nominations. 

In evaluating the CUNs for soil treatments, MBTOC assumed that a technically feasible 

alternative to MB would need to provide sufficient pest and/or weed control for continued 

production of that crop to existing market standards. 

For commodity and structural applications, it was assumed that technically and economically 

feasible alternatives would provide disinfestation to a level that met the objectives of a MB 

treatment, e.g. meeting infestation standards in finished product from a mill, while ensuring the 

costs were economically feasible in the context of that nomination, to the extent that could be 

determined. 

Consistent with Article 4(1) of the the Terms of Reference for TEAP as they apply to technical 

options committees, three Minority Reports were submitted by some MBTOC members after 

the March meeting in Turkey. TEAP considered the technical justifications provided in each 

Minority Report at its April meeting in Geneva Switzerland. In the first case that concerned 

strawberry fruit production in California, TEAP partly agreed with the Minority Report, and 

was able to recommend that portion of the nomination where there was no dissent after the 

assessment by MBTOC. The Party was invited to submit additional information for MBTOC’s 

assessment, in the event that a greater amount of methyl bromide was required than the amount 

recommended by TEAP. In the second case that concerned vegetable production in the US, 

TEAP accepted the majority MBTOC recommendations and invited the Party to provide further 

information by 15 July 2011for final MBTOC’s assessment; and in the third case that concerned 

strawberry runner production in Canada, TEAP disagreed with the Minority View and 

recommended methyl bromide for that use. 

8.2.8 Disclosure of Interest 

As in the past, each MBTOC member submitted a disclosure of interest form relating 

specifically to their level of national, regional or enterprise involvement for the 2011 CUN 

process, according to a standardised format developed by TEAP. The Disclosure of Interest 

declarations can be found on the internet at 

http://ozone.unep.org/Assessment_Panels/TEAP/index.shtml. As in previous rounds, some 
May 2011 TEAP Progress Report 149

members withdrew from a particular CUN assessment or only provided technical advice on 

request for those nominations where a potential conflict of interest was declared. 

8.3 Article 5 issues 

Methyl bromide is due to be fully phased out in A5 Parties by Jan 1 2015, 10 years after full 

phaseout by non-A5 Parties. In both cases, uses for feedstock and QPS are exempted from 

phase out under the control measures described in Article 2H. There is also provision for 

exemption from phase out for uses deemed ‘critical’ according to Article 2H, as complying with 

Decision IX/6. 

Presently, nearly 80% of the controlled consumption in A5 Parties has been phased out, well 

ahead of the 2015 deadline. This has been achieved largely as a result of investment projects 

implemented by the Montreal Protocol agencies, with MLF funding. Almost all remaining MB 

consuming Parties have agreements in place with the MLF for full phaseout of methyl bromide 

by 2015 at the latest, very often earlier. These are usually accompanied with legislation to ban 

further consumption of MB for controlled uses, and funding to support ongoing implementation 

of alternatives therefore promoting the sustainability of the phase out. 

Article 5 Parties may choose to submit nominations for Critical Use Exemptions (CUEs) for 

remaining uses they consider appropriate for year 2015 and possibly subsequently. The first 

CUNs by non-A5 Parties were made in 2003 for CUEs to be in force in 2005. If a similar 

advanced submission period is to be followed, some A5 Parties may choose to submit CUNs in 

2013 for assessment by MBTOC for potential use as 2015 CUEs. 

MBTOC is mindful of the difficult and complex process that occurred during the first round of 

CUNs in 2003. TEAP urges Parties to consider the requirements for CUNs in due time as set 

out in the ‘Handbook on Critical Use Nominations’ 

(http://ozone.unep.org/Assessment_Panels/TEAP/Reports/MBTOC/Handbook%20CUNversion5-27Nov06.pdf). 
150 May 2011 TEAP Progress Report 

8.4. MBTOC-Soils: Final Evaluations of 2011 Critical Use 

Nominations for Preplant Soil Use of Methyl Bromide 

In addition to organization and welcome to the meeting in Antalya, MBTOC-S thanks the 

Government of Turkey, Department of Agriculture, for organization and conduct of the field 

tour on Wednesday 16th March. 

8.4.1 Minority Reports 

Three signed Minority Reports with technical justification were submitted by MBTOC 

members on nominations from the United States and Canada in March, 2011 as shown below. 

The full text of the minority reports is shown in Section 4.5. 

Minority Report 1: United States of America nomination for the use of methyl bromide for 

strawberry fruit production in California in 2013. 

Minority Report 2: United States of America nomination for the use of methyl bromide for 

tomato, pepper, cucurbit and eggplant production in the USA. 

Minority Report 3: Nomination by Canada for the use of methyl bromide for the use of methyl 

bromide for the production of strawberry runners on Prince Edward Island. 

At the May meeting in Geneva, TEAP by consensus agreed to the following positions in 

conjunction with the text provided in the recommendation boxes shown in Table 8-11. 

• TEAP partly agreed with the Minority Report 1. TEAP was able to recommend that 

portion of the recommendation that was not in disagreement by MBTOC, but unable to 

recommend any further amount of MB up to that nominated until further substantiation 

is provided by the Party as shown in the full summary of the recommendation (Table 9 

-11). 

• TEAP concurred with the interim recommendation proposed by the MBTOC majority 

on vegetables produced in the US. TEAP invited the Party to provide substantiation of 

the recent failure of alternatives on each nomination for cucurbits, eggplants, peppers 

and tomatoes by July 15, 2011. 

• With respect to Minority Report 3, TEAP concurred with the MBTOC majority. 

8.4.2 Summary of Interim Recommendations 

In the 2011 round, 13 CUNs were submitted for preplant soil uses, 1 for 2012 and 12 for 2013. 

This compared to 27 nominations submitted in the past round in 2010 as Japan and Israel no 

longer submitted CUNs. USA did not submit a nomination for forest nurseries and sweet potato 

slips, both of which had been submitted in previous rounds, but did submit a new nomination 

for research uses in 2012 and 2013. 

MBTOC-S acknowledged the substantial reductions made by USA for 2013 in the 2011 CUNs. 

Further acknowledgement goes to Israel and Japan who supported their action plans to phase 

out MB in Israel by the end of 2011 and for Japan by the end of 2012. 

The nominated amounts were for 6.111 tonnes in 2012 and 661.677 tonnes in 2013. The 

interim recommended amounts totaled 577.242 t for 2013 (Table 8-6 and 8-7). MBTOC was 

unable to assess the USA research nomination for 2012 and 2013 because insufficient details 

were provided to support the use (see Table 8-11). Interim recommendations on 8 of the 11 

remaining nominations were made. However, the final quantity depends on the US providing 

further information by July 15, 2011 for MBTOC assessment on the vegetable and strawberry 
May 2011 TEAP Progress Report 151

nominations (Table 8-13). The US ornamentals nomination was reduced as alternatives were 

considered suitable for a portion of the nomination. 

Table 8-6: Summary of MBTOC-S nominations and interim recommendations for 2012 and 

2013 by country for CUNs received in 2011 for preplant soil use of MB (tonnes)

CUE approved at 22nd 

MOP 

CUN Submitted in 2011 MBTOC-S Interim 

Recommendation 

Country 

2012 2012 2013 2012 2013 

Australia 29.760 29.760 [29.760] 

Canada 5.261 5.596 [5.261] 

Israel 0 

Japan 216.120 0 

USA 941.967 620.118 [542.221] 

USA Research 

(New) 

6.111 6.203 [Unable] [Unable] 

Total 1193.108 6.111 661.677 [577.242] 

Table 8 -7: Summary of the interim recommendations by MBTOC-S (in square brackets) for 

CUE’s for preplant uses of MB (tonnes) for 2012 and 2013 submitted in the 2011 round. 

Years 

Country and Sector 2012 2013 

1. Australia 

1. Strawberry runners [29.760] 

2. Canada 

1. Strawberry runners [5.261] 

3. USA 

1. Cucurbits 

 2. Eggplants (field) 

 3. Nurseries stock: fruits, nuts & flowers 

4. Orchard replant 

5. Ornamentals 

6. Pepper (field) 

7. Strawberry (field) 

8. Strawberry runners 

 9. Tomatoes (field) 

 10. Research [Unable] 

 [11.899] 

 [1.381] 

[0.541] 

[6.230] 

 [40.818] 

 [5.673] 

 [461.186] 

 [3.752] 

[10.741] 

[Unable] 

TOTAL [Unable] [577.242]
152 May 2011 TEAP Progress Report 

8.4.3. Issues Related to CUN Assessment for Preplant Soil Use 

Key issues which influenced assessment and the need for MB for preplant use of MB in the 

2010 round were: 

i) Increased adoption and registration of methyl iodide (MI or iodomethane) with barier 

films in most states of the USA (not California) which has continued since mid 2008 

which has led to commercial adoption on large scale areas in the US and substantial 

reduction in the US nominations in SE and Florida. 

ii) Registration of methyl iodide in California in December 2010, which allowed for a 21 

% reduction by the US for the strawberry fruit nomination. 

iii) Continued and progressive acceptance of a 3 way fumigant strategy (1,3-

dichloropropene, metham sodium, Pic) as being effective for nutsedge and pathogen 

control in USA. 

iv) Changing regulations on key alternatives, particularly 1,3-D township caps and buffer 

zones on 1,3-D, metham sodium and Pic used alone or in mixtures. 

v) Introduction of a new formulation of 1,3-D/Pic (Picchlor 60) in the USA which 

increased affected the use of 1,3-D in areas affected by township caps. 

vi) Effect of restrictions on use of high rates of Pic (greater than 200 kg/ha (20 g/m2

)) in 

some counties of California. 

vii) Lack of acceptance in specific sectors that alternatives exist, e.g. nursery industries and 

the classification by one Party of these uses under the QPS exemption. 

viii) Movement of quantities of MB from CUE classification to an exempt ‘QPS’ status in 

some sectors (eg. US Forest nurseries). 

In this round, the US indicated it no longer sought nominations for the forest nursery or sweet 

potato sectors. It was unclear whether this was due to uptake of alternatives or reclassification 

to QPS. Israel and Japan no longer sought any methyl bromide under critical use for preplant 

soil use, thus honoring their phase out notified to the Parties in 2010. 

In the 2010 round, MBTOC also used adoption data of alternatives in specific regions where it 

was available, such as the Californian Department of Pesticide Regulation –Pesticide Use 

Report data to help with assessment, particularly the largest strawberry fruit nomination. 

MBTOC continues to urge Parties to consider review of regulations covering the registration, 

use and adoption of alternatives, particularly review of barrier films to reduce dosage rates of 

MB and the alternatives, and associated emissions. As in the previous round, Parties found 

alternatives more difficult to adopt for propagation materials, such as strawberry runners and 

nurseries. There is a lack of research studies to develop and demonstrate effectiveness of 

alternatives in these sectors. This lack of research effort leads MBTOC to conclude that several 

of the CUNs do not to fully satisfy the requirements of Decision IX/6 and urges Parties to 

increase studies in these sectors. The impact of current reviews of volatile organic compound 

(VOC) emissions in California (http://www.epa.gov/iaq/voc.html) may also have a major 

impact on the use of MB and alternatives. 

MBTOC also notes that a large proportion of MB has been nominated for uses where 

regulations or legislation prevent reductions of MB dosage. For many uses, the mandatory use 

of MB is specified at a high dosage for either treatment of certified propagation material or 

because regulations prevent use of barrier films which otherwise could have reduced the MB 

dosage rate. Also regulations on the use of alternatives are preventing their uptake for a 

substantial proportion of the remaining CUNs for preplant soil use. For instance, current 

restrictions on dose rate for methyl iodide in California prevent MBTOC accepting it as a 
May 2011 TEAP Progress Report 153

suitable alternative for nursery uses. MBTOC urges the Parties to align their local policies and 

regulations with internationally accepted methodologies and to allow use of MB alternatives. 

8.4.3.1. Registration of alternatives for preplant uses - Decision Ex I/4 (9i) and (9j) 

Decision Ex. I/4 (9i) requires MBTOC “To report annually on the status of re-registration and 

review of methyl bromide uses for the applications reflected in the critical-use exemptions, 

including any information on health effects and environmental acceptability”. Further, Decision 

Ex I/4 (9j) requires MBTOC “To report annually on the status of registration of alternatives 

and substitutes for methyl bromide, with particular emphasis on possible regulatory actions 

that will increase or decrease dependence on methyl bromide”.

Iodomethane (MI) is registered for more than 28 crops in all US states except Washington and 

New York and this has greatly assisted phase out of MB in SE States of the USA including 

field-grown ornamentals, peppers, strawberries and tomatoes. In California approval was 

granted for iodomethane in December 2010, however use rates approved may be restrictive for 

certain uses according to the Party. MI has also gained registration in a number of Article 5 

countries and non Article 5 countries, such as New Zealand and Japan and this has assisted 

phase out of MB for preplant uses in these countries. Registration of MI is pending in Australia 

and this alternative is indicated by the Party to be a main alternative which could assist phase 

out for MB in strawberry runners. To ensure that the mitigation measures for MI will be 

consistent with the measures being required for the other fumigants, the label requirements are 

presently being reexamined in the USA. 1,3-dichloropropene, may be subject to similar 

provisions when the soil fumigants are evaluated together again in 2013. 

The EU has further reported that registration for 1,3-D and other alternatives including 

chloropicrin, dazomet and metham sodium are under review. A grace period for the registration 

of 1,3-D became due on 20 March 2009 and was extended, but its future registration is 

uncertain. 

A number of other chemicals which may be alternatives to MB are being considered for 

impending registration in specific countries recently, including dimethyl disulphide (DMDS) in 

Europe and the USA. 

8.4.3.2. Update on rates of adoption of alternatives for preplant uses - Decision 

XIX/9 

As of the 2010 round, Decision XIX/9 para. 3 requests: ‘ the Technology and Economic 

Assessment Panel to ensure that recent findings with regard to the adoption rate of alternatives 

are annually updated and reported to the Parties in its first report of each year and inform the 

work of the Panel’. 

Previous reports (see references in Table 8-11, Porter et al., 2006, MBTOC 2011) show that 

technical alternatives exist for almost all uses requesting CUNs, but the uptake of alternatives 

varied between countries, crops and the pest pressure. In general, similar alternatives are being 

adopted by the same sectors in a number of countries, although the rate of adoption has varied 

depending on regulatory restrictions on use, differences in registration rates between countries 

and other market forces. In this round as in previous rounds of CUNs, MBTOC has recognised 

that a limited period of time is needed to allow the market penetration of alternatives, based on 

logistical, training, imports of alternatives and other information provided in the nomination by 

the Party (paragraph 35 in Annex 1 of the 16th Meeting of the Parties). 

Figures 8-1 to 8-4 in this report show the apparent reduction rates for MB use achieved by 

many Parties in a number of key sectors. As noted above, true reduction and adoption rates may 

vary from the rate of change of CUN/CUE because of factors such as use of stocks (some 

Parties uses stocks and freshly produced methyl bromide from CUEs) or transfer MB between 
154 May 2011 TEAP Progress Report 

categories of use. The CUN reviews presented in Table 8-11 also provide detail of some of the 

key alternatives that Parties have and should consider to further replace MB for the remaining 

uses. 

Further guidance from the Parties, particularly Australia, Canada and the US of expected rates 

of adoption of alternatives following registration, in accordance with paragraphs 34-35 of 

Annex 1 of the MOP16, as this information would assist MBTOC in evaluation of CUNs in 

future. 

8. 4.3.3. Sustainable Alternatives for Preplant Uses 

For preplant soil uses of MB, the regulatory restrictions on 1,3-dichloropropene and Pic are 

preventing further adoption of these products in the USA, particularly California and this is 

putting pressure on industries to retain MB. 

MBTOC urges Parties to consider the long term sustainability of treatments adopted as 

alternatives to MB, to continue to adopt environmentally sustainable and safe chemical and 

non-chemical alternatives for the short to medium term and to develop sustainable IPM or nonchemical approaches for the longer term. Decision IX/6 1(a)(ii) refers to alternatives that are 

‘acceptable from the standpoint of environment and health’. MBTOC has consistently 

interpreted this to mean alternatives that are registered or allowed by the relevant regulatory 

authorities in individual CUN regions, without reference to the sustainability of the alternative. 

In the past, MBTOC visited flower growers in Southern Spain who have successfully adopted 

biodisinfestation as an efficient and sustainable alternative to MB. 

8.4.4. Standard Presumptions Used in Assessment of Nominated 

Quantities. 

The tables below (Tables 8-8 and 8-9) provide the standard presumptions applied by MBTOC-S 

for this round of CUNs. These standard presumptions were first proposed in the MBTOC report 

of October 2005 and were presented to the Parties at 17th MOP. Studies and reports to support 

them have been provided in previous reports and were revised for some sectors after 

consideration by the Parties at the 19th MOP. The rates and practices adopted by MBTOC as 

standard presumptions are based on maximum rates considered acceptable by published 

literature and actual commercial practice. 

As in the evaluations in previous years, MBTOC considered reductions to quantities of MB in 

particular nominations to a standard rate per treated area where technical evidence supported its 

use. As a special case, MBTOC continues to accept a maximum rate of 200 kg/ ha (20 g/m2

) 

with high Pic-containing mixtures with barrier films for certified nursery production, unless 

regulations prescribed lower or higher rates. However, studies have indicated that rates of 200 

kg/ha (20g/m2

) or less of MB: Pic 50:50 were effective with barrier films for production of 

‘certified’ nursery material. 

The indicative rates used by MBTOC were maximum guideline rates, for the purpose of 

calculation only. MBTOC recognises that the actual rate appropriate for a specific use may vary 

with local circumstances, soil conditions and the target pest situation. Some nominations were 

based on rates lower than these indicative rates. 
May 2011 TEAP Progress Report 155

Table 8-8: Standard presumptions used in assessment of CUNs for the 2009 and later 

assessments – soil treatments. 

Comment CUN adjustment Exceptions 

1. Dosage rates Maximum guideline rates for 

MB:Pic 98:2 are 25 to 35 g/m2 with 

barrier films (VIF or equivalent); 

for mixtures of MB/Pic are 12.5 to 

17.5 g MB/m2

 for pathogens and 

nutsedge respectively, under barrier 

films depending on the sector. All 

rates are on a ‘per treated hectare’ 

basis. 

Amount adjusted to maximum 

guideline rates. Maximum rates 

set dependent on formulation 

and soil type and film 

availability. 

Higher rates accepted if 

specified under national 

legislation or where the Party 

had justified otherwise. 

2. Barrier films All treatments to be carried out 

under low permeability barrier film 

(e.g. VIF, TIF) 

Nomination reduced 

proportionately to conform to 

barrier film use. 

Where barrier film 

prohibited or restricted by 

legislative or regulatory 

reasons 

3. MB/Pic 

Formulation: 

Pathogen control 

Unless otherwise specified, MB/Pic 

50:50 (or similar) was considered 

to be the standard effective 

formulation for pathogen control, 

as a transitional strategy to replace 

MB/Pic 98:2. 

Nominated amount adjusted for 

use with MB/Pic 50:50 (or 

similar). 

Where MB/Pic 50:50 is not 

registered, or Pic (Pic) is not 

registered 

4. MB/Pic 

Formulation: 

Weeds/nutsedge 

ass control 

Unless otherwise specified, MB/Pic 

67:33 (or similar) was used as the 

standard effective formulation for 

control of resistant (tolerant) 

weeds, as a transitional strategy to 

replace MB/Pic 98:2. 

Nominated amount adjusted for 

use with MB/Pic 67:33 (or 

similar). 

Where Pic or Pic-containing 

mixtures are not registered 

5. Strip vs. 

Broadacre 

Fumigation with MB and mixtures 

to be carried out under strip 

Where rates were shown in 

broadacre hectares, the CUN 

was adjusted to the MB rate 

relative to strip treatment (i.e. 

treated area). If not specified, 

the area under strip treatment 

was considered to represent 67% 

of the total area. 

Where strip treatment 

was not feasible e.g. 

some protected 

cultivation, emission 

regulations on MB, or 

open field production 

of high health 

propagative material 

Table 8-9: Maximum dosage rates for preplant soil use of MB by sector used in the 2009 and 

later assessments (standard presumptions).

Maximum MB Dosage Rate (g/m2) in MB/Pic mixtures (67:33, 50:50) 

Film Type considered effective for:

Strawberries and 

Vegetables 

Nurseries* Orchard Replant Ornamentals 

Barrier films - 

Pathogens 

12.5 15 15 15 

Barrier films - 

Nutsedge 

15.0 17.5 17.5 17.5 

No Barrier films 

– Pathogens 

20 20 20 20 

No Barrier films - 

Nut sedge 

26 26 26 26 

* Maximum rate unless certification specifies otherwise 
156 May 2011 TEAP Progress Report 

8.4.5. Adjustments for Standard Dosage Rates Using MB/Pic 

Formulations 

One key transitional strategy to reduce MB dosage has been the adoption of MB/Pic 

formulations with lower concentrations of MB (e.g. MB/Pic 50:50, 45:55 or less). These 

formulations are considered to be equally as effective in controlling soilborne pathogens as 

formulations containing higher quantities of MB (e.g. 98:2, 67:33) (e. g. Porter 2006;Melgarejo 

et al., 2001; Santos et al., 2007; Hamill et al., 2004; Hanson et al., 2006). Parties are urged to 

consider even lower dosage rates of MB for the remaining CUNs. This includes rates as low as 

75 kg/ha (7.5 g/m2

) with mixtures of 30:70 or 33:67 mixtures (at 250 kg/ha or 25 g/m2) or 100 

kg/ha (10 g/m2

) of MB in 250 kg/ha (25 g/m2) of 50:50 MB/Pic mixtures in conjunction with 

barrier films (Table 8-10). 

Table 8-10: Actual dosage rates applied during preplant fumigation when different rates and 

formulations of MB/Pic mixtures are applied with and without barrier films. Rates of 

application reflect standard commercial applications rates. 

MB/Pic formulation (dose of MB in g/m2 Commercial ) 

application rates 

of formulation 98:2 67:33 50:50 30:70 

A. With Standard Polyethylene Films 

400 39.2 26.8 20.0 12.0 

350 34.3 23.5 17.5 10.5 

300 29.4 20.1 15.0 9.0 

B. With Low Permeability Barrier Films (LPBF) 

250 24.5 16.8 12.5 7.5 

200 19.6 13.4 10.0* 6.0 

175 17.2 11.8 8.8 5.3 

* Note: Trials from 1996 to 2008 (Annex III) show that a dosage of 10g/m2 (e.g. MB/Pic 50:50 at 

200kg/ha with LP Barrier Films) is technically feasible for many situations and equivalent to the 

standard dosage of >20g/m2 using standard PE films 

8.4.6. Use/Emission Reduction Technologies - Low Permeability Barrier 

Films and Dosage Reduction 

Decision XXI/11 (para 9) requested further reporting on Decision IX/6 to ensure Parties 

adopted emissions controls where possible. For preplant soil use, this includes the use of 

barrier films and lowest effective dose of MB with mixtures of chloropicrin. Other methods 

include deep shanking and use of ammonium thiosulphate and different irrigation technologies 

(Yates et al., 2007, Yates et al., 2009). These latter technologies have not been reported or 

adopted widely by Parties and need to be evaluated more widely for future CUN uses. 

 In southeast USA the reported use of barrier films in vegetable crops has expanded to over 

20,000 hectares and it is also exclusively used with the alternative MI to assist its effectiveness 

at low dosage rates (Allan, pers. comm., 2008; Chism, pers.comm, 2009). An exception to the 

adoption of barrier films is in the State of California in the USA where a regulation currently 

prevents use of barrier films with MB (California Code of Regulations Title 3 Section 6450(e)), 

but not with the alternatives. Barrier films are consistently improving the performance of 

alternatives at lower dosage rates. 
May 2011 TEAP Progress Report 157

Figure 8-4: Reductions in the critical uses of methyl 

bromide approved and proposed 

3,434 ha at 196 kg/ha = 673 tonnes of methyl bromide in 2012

Approved by Parties

2,713 ha at 170 kg/ha = 461 

tonnes of methyl bromide

in 2013

MINORITY EVALUATION

3,128 ha at 170 kg/ha = 531 

tonnes of methyl bromide

in 2013

US Proposal

9% reduction 

not agreed

21% reduction 

agreed

8.5 Minority Reports 

8.5.1. Minority Report 1: United States of America Nomination for the 

Use of Methyl Bromide for Strawberry Fruit Production in 

California in 2013 

Signed by: Janny Vos, Cao Aocheng, Antonio Bello, Suat Yilmaz, Alejandro Valeiro, Tom 

Batchelor, Raquel Ghini 

In 2011, the US nominated 531.737 tonnes of methyl bromide for the treatment of 4,406 ha in 

2013 at an application rate of 170 kg/ha1

. At the meeting in Turkey in March 2011, the US 

delegation in a meeting with MBTOC corrected the area to be treated from 4,406 ha to 3,128 

ha. The nominated amount of 531.737 tonnes and treatment rate of 170 kg/ha remained the 

same. 

MBTOC’s recommendation for 

the 2010 nomination for 2012 that 

was approved by the Parties was 

based on 3,434 ha at an application 

rate of 196 kg/ha. MBTOC 

encouraged the Party to reduce this 

application rate as lower rates 

were considered feasible. This 

recommendation was the result of 

MBTOC’s Soils Sub-committee 

meeting in the strawberry growing 

region of San José (California) in 

September 2010. The MBTOC 

Soils meeting was specifically held 

in that location last year to see 

firsthand the strawberry 

production in California and to 

fully understand the concerns of 

growers. 

The signatories of this Minority Report hold firmly to the view that the MB-treated area in 2013 

should be calculated on the basis of the approved area in 2012, namely 3,434 ha. A 21% 

reduction should therefore result in a MB-treated area of no more than 2,713 ha in 2013, as this 

is 21% less than the area proposed for treatment in 2012 of 3,434 ha. This area of 2,713 ha 

would result in a recommendation by MBTOC of 461.186 tonnes of methyl bromide at the rate 

of 170 kg/ha (see summary of these figures in 8-4). 

The California Strawberry Commission (CSC) also presented information to MBTOC at the 

meeting in Turkey. The CSC advised MBTOC that it was “in dispute” with the US nomination 

of 531.737 tonnes1

, as it believed the nominated amount for California in 2013 should be 

685.896 tonnes of methyl bromide2

. This larger quantity was more than the amount approved 

by the Parties for producing strawberry fruit in California in 2012. An increased quantity 

would be inconsistent with paragraph 7 of Decision ExI/3 that says, “...Parties should aim to 

significantly and progressively reduce their production and consumption of methyl bromide for 

critical-use exemptions...”, and inconsistent with previous annual reductions (8-5). 

 

1

 USA. 2011. Nomination for critical uses. USA_CUN13_SOIL_Strawberry_Fruit_Open_Field—CA. 

2

 California Strawberry Commission. 2011. 2013 CUE application. MBTOC meeting in Turkey March 2011. 

Slide 4. 3

 CSC. 2011. 2013 CUE application. MBTOC meeting in Antalya Turkey March 2011. Slide 15. 
158 May 2011 TEAP Progress Report 

Figure 8-5: Use of methyl bromide for strawberry fruit production in California districts 

(bar graph), compared with methyl bromide approved by the Parties (solid line) and 

proposed (dotted and dashed lines) 

0

500,000

1,000,000

1,500,000

2,000,000

2,500,000

Methyl bromide (kg)

Oxnard

Orange/San Diego

Santa Maria

Watsonville/Salinas

MB CUE (California allocation)

CUN2013

MBTOC minority recommendation

Sources: California DPR - Pesticide Use Report database (MB use till 2009), TEAP reports (MB 

CUE for California), CUN2013 and the minority recommendation 

At the 2010 meeting in Turkey, MBTOC asked the US delegation to resolve the inconsistencies 

between the US nominated amount and the CSC amount and to correct the errors in estimating 

the area to be treated with methyl bromide in the nomination. The US 2011 nomination for 

2013 did not provide any reasons for the inconsistencies and errors in their nomination. 

The CSC stated that further information would be available in June 2011 on the availability of a 

key alternative, and that such information would be made available to MBTOC at that time. 

8.5.1.1. Reasons for “unable to assess” the US critical use nomination for 

strawberry fruit in California 

MBTOC is required to “...categorize the nomination as ‘unable to assess’ if there is insufficient 

information to make an assessment, and clearly explain what information was missing”3

. 

Consistent with paragraph 4 of Section 2.4 in Decision XVI/4, the “...the Party may be 

requested via the Ozone Secretariat to submit further information”. 

The signatories of this Minority Report considered the US nomination for strawberry fruit 

“Unable to Assess” as: 

• The information provided by the US delegation was not consistent between the 

nomination and the information provided at the meeting with MBTOC; 

 

4

 Annex to Decision XVI/4 (Annex I of MOP16 report). 
May 2011 TEAP Progress Report 159

• There was disagreement between the California Strawberry Commission and the US 

government on the area eligible for methyl bromide and the quantity of methyl bromide 

to nominate as a critical use; 

• The majority recommended 70 tonnes more methyl bromide4

 than would otherwise be 

recommended following the spreadsheet calculations developed to satisfy the criteria in 

Decision IX/6; and 

• Further information on the availability of an alternative will be forthcoming from the 

nominating Party in June 2011. 

The signatories of this minority report respectfully request TEAP to categorise the nomination 

as “unable to assess” in this TEAP Progress Report until such time that the nominating Party 

submits further information for subsequent assessment by MBTOC. 

8.5.2 Minority Report 2: United States of America Nomination for the 

Use of Methyl Bromide for Tomato, Pepper, Cucurbit and 

Eggplant Production in the USA 

Signed by: Tom Batchelor, Antonio Bello, Janny Vos 

The US submitted four nominations for 10.741, 5.673, 11.890 and 1.381 tonnes of methyl 

bromide for critical uses for the production of tomato, pepper, cucurbit and eggplant 

respectively5

. The total nominated was 29.685 tonnes. 

MBTOC’s majority recommendation of methyl bromide for critical uses in 2013 for these four 

crops was inconsistent with paragraph 1(a)(ii) of Decision IX/6. This paragraph requires 

methyl bromide to qualify as critical only when “...there are no technically and economically 

feasible alternatives or substitutes available to the user that are acceptable from the standpoint 

of environment and health and are suitable to the crops and circumstances of the nomination5

”. 

As evidence of alternatives being available, one of the US members of MBTOC presented a 

paper at an international conference in Morocco6

 held several days before the MBTOC meeting 

in Turkey that stated that “...30 tonnes of methyl bromide nominated by the US in 2013 for 

tomato, pepper, cucurbit and eggplant is less than 1% of the amount approved by the Parties for 

use on these crops in 2005”7

. Therefore alternatives to methyl bromide are available for this 

use as more than 99% of the methyl bromide that was used in 2005 for the production of these 

four crops would be replaced by an alternative in 2013. The paper citing the availability of 

many alternatives for these crops is consistent with previous MBTOC reports7

. In addition, the 

US agreed at the meeting with MBTOC to supply further information by 15 July 2011 in 

support of this nomination. 

The signatories of this Minority Report request TEAP to consider the US nomination for 

tomato, pepper, cucurbit and eggplant “Unable to Assess” as: 

• The recommendation was not compliant with Decision IX/66

; 

• The Party agreed to send further information in July 2011. 

 

4

 5 May 2011 TEAP Progress Report 

5 Decision IX/6. 1997. Critical use exemptions for methyl bromide. UNEP Ozone Secretariat website. 6 Schneider, S. 2011. Vegetable production without methyl bromide in the USA: Current situation, 

constraints and perspectives. Proceedings of International Symposium on “Vegetable Production without 

methyl bromide: A challenge for developed and developing countries”. Agadir, 10-11 March 2011. Project 

MP/MOR/08/004/17-51. In publication. 7

 For example, MBTOC. 2010. Assessment Report. Section 4.4.4: Vegetables / Solanaceous crops and 

cucurbits. Pp93-96. 
160 May 2011 TEAP Progress Report 

The signatories of this Minority Report respectfully request TEAP to categorise the nomination 

as “unable to assess” in this TEAP Progress Report until such time that the nominating Party 

submits further information for subsequent assessment by MBTOC. 

8.5.3 Minority Report 3: Nomination Submitted by Canada for the Use 

of Methyl Bromide for the Production of Strawberry Runners on 

Prince Edward Island 

Signed by Tom Batchelor, Janny Vos, Antonio Bello 

Canada submitted a nomination for 5.261 tonnes of methyl bromide for critical uses for the 

production of strawberry runners on Prince Edward Island. 

The quantity of methyl bromide nominated for 2013 is the same amount approved by the Parties 

for use in 2011 as well as 2012. The quantity of methyl bromide is not reducing each year, as 

required by paragraph 7 of Decision ExI/3 that says “...Parties should aim to significantly and 

progressively reduce their production and consumption of methyl bromide for critical-use 

exemptions...”. 

The MBTOC Soils subcommittee determined that the Party is not undertaking research as 

required by paragraph 1(b)(iii) of Decision IX/6 that says “...Parties must demonstrate that 

research programmes are in place to develop and deploy alternatives and substitutes”. The 

company has been testing organic production with different varieties and has found one variety 

that compared favorably to conventional production using methyl bromide. It was not clear 

why this one variety had not been put into production as a way to produce runners free of 

methyl bromide. The organic production testing ceased in 2009 and research has not continued 

after this date. 

Chloropicrin is registered in Canada but the PEI authorities have denied a permit for its use 

until groundwater testing has been conducted. The Party has not undertaken ground water 

testing that was planned by the Party to commence in 2008. MBTOC Soils subcommittee 

determined that the Party had demonstrated “insufficient effort” to evaluate, commercialize and 

secure national regulatory approval of alternatives and substitutes, as required by paragraph 

1(b)(iii) of Decision IX/6. 

According to paragraph 1(b) of Dec IX/6, MBTOC is required to recommend methyl bromide 

for consumption only if the proposed critical uses show, inter alia, that research programmes are 

in place and that appropriate effort is being made to substitute methyl bromide. 

The signatories of this Minority Report respectfully request TEAP to categorise the nomination 

as “Not recommended” in this TEAP Progress Report. 
May 2011 TEAP Progress Report 

Table 8-11: Final evaluations of CUNs for preplant soil use submitted in 2011 for 2012 or 2013 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117 

CUE for 20128

CUN for 2012 (addtl or new) 

CUN for 2013 

Strawberry runners 

Australia 35.750 37.500 35.750 35.750 29.790 29.790 29.790 29.760 - 29.760 

MBTOC comments 2011: MBTOC recommends a CUE of 29.760 tonnes for 2013. There has only been minor reductions made in last 5 CUEs submitted and no re

regulated by certification rules. The Party states that the key pests affecting strawberry runner production are fungi (Phytophthora, Pythium, Rhizoctonia and Verticillium s

arvensis, Agrostis tenuis, Raphanus spp., Poa annua, Cyperus spp). The Party also states that MB:Pic 50:50 at a MB dose of 25 g/m2 is 

certification standards. Although this quantity exceeds MBTOC’s standard presumption of 20 g/m2, the lower rate is unregistered. The Pa

a reduced rate of 18.75 g/m2 resulted in unsatisfactory results in the second year of testing. The Party initiated another 2-year study using 

kg/ha [20g/m2] and the standard rate MB/Pic (50/50) at 500 kg/ha [ie. MB at 25g/m2]. Yields from the plot treated with MB/PIC [20g/m2] w

from the standard rate. Two additional commercial trials were initiated in 2010/2011 using the lower rate of 20g/m2 as APVMA requires 2 yapproving a reduced rate. The Party states that the most promising alternative, MI/Pic, has been demonstrated in commercial scale field efficacy to MB:Pic. The registrant has indicated that additional data has been requested by APVMA which will be submitted this year and in late 2011. While more data has been submitted to support the registration of EDN, the Party indicates that the registration status is still alternative, 1,3-D:Pic, is considered ineffective due to phytotoxicity and doubling of plant back times in the heavy and wet soil conditions in The Party also indicates that the Victorian Strawberry Certification Authority (VSICA) completed the second year of a 2-year development systems for production of foundation stock strawberry runners. Results indicated that the productivity of the soil-less system is similar to tproduction in MB:Pic fumigated soils, and the economics of the soil-less system compares favourably with the current method of productioestablish a commercial facility by 2012 which, if successful, would eliminate VSICA’s need for MB for foundation stock in 2011/2012. MBTOC requires that the Party: (1) report the results with reduced rates of 20 g/m2 of MB with its next CUN submission as well as the de

the reduced rates; (2) provide a comprehensive update of the registration status of MI and EDN, (3) provide the results from the new trials as well as a comprehensive plan for commercialization and (4) since the production of 60,000 foundation generation has been found to be Party needs to provide the economic analysis that supports their assertion that any further expansion is not economically feasible. Althouresults of extensive research results with highly promising alternatives MBTOC expects significant adoption of these in any future nominatMBTOC comments on economics 2011: The nomination was not based on economic arguments 
162 May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117 

CUE for 20128

CUN for 2012 (addtl or new) 

CUN for 2013 

Comments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i) Emission control: no, but standard films are claimed by the Party to perform the same as VIF in the cold tempera

typical for strawberry runner production. 

• Dec. IX/6 b(iii) Research program: ongoing research is being conducted in (a) supporting reduced application rates of MB:Pic, 

registration of MI; unknown for EDN; (c) use of recaptured MB & Pic; 

• Dec. IX/6 b(iii) Appropriate effort: research effort is adequate but commercialization may be confronted with regulatory obstac

Strawberry runners (PEI) 

Canada 6.840 6.840 7.995 7.462 7.462 7.462 5.261 5.261 - 5.596 

MBTOC comments 2011: MBTOC recommends a reduced CUE of 5.261 tonnes for this use in 2013. In 2012 the requested amount was 5.261 t. In this round, the 

nomination had been reduced by 25%, but as it increased, MBTOC only recommends the quantity approved in 2012. The CUN for 2013 

for MB of 20 g/m2, and MBTOC acknowledges the Party’s reduction in the absence of formal registration for this dose rate. The Party has attempted to replace MB with 1,3-D, but 1,3-D was banned for use in Prince Edward Island in January 2003 due to ground Chloropicrin (PIC 100) has been registered by PMRA, but the PEI authorities have denied a permit for its use until further groundwater tesMI registrant has not applied for registration in Canada. The company has been testing organic production from 2006 - 2009 with different that they obtained significant reductions in yield ranging from 40% to 70%. Only one variety using the organic production system compareproduction. While MB:Pic 67:33 at 500 kg/ha is the only use rate registered for strawberry runners, which exceeds MBTOC’s standard pregrower petitioned PMRA to use a lower rate under barrier films. PMRA, in the absence of a formal label amendment, granted permission tthe grower’s own risk and liability. In 2008 the grower tested two plots totalling 2.4 ha using 25% & 30% lower rates under barrier films anin 2009. The results were comparable using the reduced rates with barrier films. The CUN for 2013 is based entirely on a reduced rate for entire area to be fumigated. For future submissions, MBTOC suggests actions for the Party to (1) complete the necessary ground water studies to obtain the PIC 100 

by the Party to commence in 2008 and (2) test the adoption of soiless cultures for at least part of the production cycle, 3) provide an updaother key alternatives (especially methyl iodide/chloropicrin). MBTOC requests greater substantiation of effort (ie trial data) be provided to nominations as required in Decision IX/6.MBTOC comments on economics 2011: The nomination was not based on economic arguments.
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Comments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i) Emission reduction: Yes, uses barrier films with reduced application rate of MB conforming to MBTOC’s presumptions 

• Dec. IX/6 b(iii) Research program: No recent research; previous focus has been on organic production testing; registrant for Midas h

registration application materials at this time. 

• Dec. IX/6 b(iii) Appropriate effort: The Party has not demonstrated an active research program on its most critical issue since it has b

assistance to do the necessary GW testing required by PEI authorities before approving the use of PIC100 in PEI.
164 May 2011 TEAP Progress Report 

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United Cucurbits 1187.800 747.839 592.891 486.757 407.091 302.974 195.698 59.500 - 11.899 States 

MBTOC comments 2011: MBTOC recommends a CUE of 11.899 tonnes for this use in 2013, provided the Party submits further explanation on the specific issues t

alternatives by July 15th, 2011 recognizing that the nominated amount represents an almost complete phase-out in this industry. The USG 

withdraw this nominated sector at the OEWG. If the US proposes an increased amount, MBTOC will need to reassess. From this amountsquash, 0.657 tonnes for Georgia cucumber; 2.415 tonnes for Georgia melon; and 7.665 t for the Southeast region and 0.348 t for Mardel The Party states that the major disease problems addressed by grafting in cucurbits include fusarium wilt (Thies et al., 2008), the main pro

Rootstocks resistant or tolerant to Fusarium oxysporum are available for melon, watermelon and cucumber (Blestos, 2005; Crinó et al., 20

factor limiting grafting in the US. However, the cost of grafting vegetables has decreased dramatically internationally since the mid-1990s. metallized tarps has shown to be as efficacious as MB (Hausbeck and Cortright, 2007; Olson and Kreger, 2007), but this fumigant is not rthe producing company does not pursue its registration (Brilleman, pers.com. March 2011). In Georgia, fumigant combinations using 1,3-Dsodium (TELPICVAP) were as effective as methyl bromide for controlling Meloidogyne incognita, Pythium irregulare, Rhizoctonia solani a

squash crops (Desaeger et al., 2008). A study suggests that - as in bell pepper- in cucumber, squash and zucchini crops TELPICVAP and or black polyethylene mulch (metal) could give the highest net revenue per acre making it the most profitable fumigant and mulch option if (Ferrer et al., 2010) MBTOC acknowledges the substantial reduction made by the Party of 80% from 2012. Past reductions have been based on a transition to D + chloropicrin, followed by chloropicrin alone, followed by metam-sodium, that shows good results against key cucurbit pests in spring sMBTOC continues to stress the need of considering also non chemical methods within an integrated pest management strategy. MBTOC key herbicide to control the most important crops ́ weeds, there is a controversy about potential phytotoxic effects of halosulfuron on cucuof studies show that, even though this could be partially true, some windows could be found to use halosulfuron in a way and timing to conimpacts on yields and quality of fruits (Brandenberger et al., 2005; Norsworthy et al., 2007; Trader et al., 2007; Macrae et al.,2008; Sosno

et al., 2009). MBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic arguments Comments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i) Emission reduction: Rates consistent with use of barrier films are used in the application. The amount used was 
May 2011 TEAP Progress Report 

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• Dec. IX/6 b(iii) Research program: The Party states that several studies are been conducted in recent years and many continu

that studies done in southern U.S. tomato and pepper production systems are also included in the list above, because these systU.S. cucurbit production in terms of soil environment, key pests, etc. 

• Dec. IX/6 b(iii) Appropriate effort: The party has shown efforts by the reduction of 70% from its last nomination. The current no

specific cases such as Karst soils 

United Eggplant 76.721 82.167 85.363 66.018 48.691 32.820 19.725 6.904 - 1.381 States 

MBTOC comments 2011: MBTOC recommends 1.381 tonnes for this use for 2013, provided the Party submits further explanation on the specific issues that have a

July 15th, 2011. Of this amount, 0.769 t are for Georgia and 0.612 t are for Florida. If substantiation is not provided, MBTOC does not reco

USG may either support or withdraw this nominated sector at the OEWG. If the US proposes an increased amount, MBTOC will need to The Party has made an 80 % reduction in MB use from the amount approved by the Party’s for 2012 (6.904 t). The US nomination is only for those areas where the alternatives are still under extensive evaluation and pest pressure (nutsedge, nemat

The Party is projecting rates of 125 kg/ha both for pathogens and for nutsedge. The Party states that the treatment, known as the “UGA 3successive soil fumigations, beginning with 1,3-D + Pic application, followed by a Pic application, followed by a metham-sodium or metham(Culpepper, 2007) is an alternative for MB in spring crops. For summer and fall crops, this system needs further development for use in anutsedge pressure. In addition, metham sodium and metham potassium in the fall require longer waiting periods for planting than MB. Demarket windows. A further constraint to adoption of the UGA-3 WAY is that 1,3-D is restricted in areas of Karst topography where ground leaching from 1,3-D. This research is on-going, however specific studies conducted or in progress since the last nomination were not cited states that dimethyl disulfide (DMDS) plus Pic are also feasible alternatives, but this combination does not effectively control certain grassTrials will continue with this alternative. An application to register DMDS is under consideration at USEPA. MI is not registered for eggplaonly for those areas where the alternatives are still under extensive evaluation and pest pressure (nutsedge, nematodes and P. capsici) is a 50:50 formulation (MB/Pic) is widely used in Florida but does not provide information about the formulation used in Georgia. MBTOC acknowledges the substantial reduction by the Party for uptake of alternatives, particularly the use of the 3 way system and the cchloropicrin. MBTOC considers that further reductions in MB amount may be possible with changes to formulations of 30:70 used in combcommercially feasible. MBTOC considers that the Party should develop non chemical alternatives e.g. grafting, biofumigation, soil less cuin many countries and regions with similar climate and pest (Besri, 2008). It is important to note that MB is not used in any other non A5 cno indication in the nomination that research in these areas is continuing. 
166 May 2011 TEAP Progress Report 

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MBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic argumentsComments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i)- Emission Reduction: There is no information in the nomination about the use of VIF or equivalent film, however, the 

consistent with the use of VIF. 

• Dec. IX/6-b(iii)-Research Program: This research is on-going, however specific studies conducted or in progress since the last nom

CUN. 

• Dec. IX/6-b(iii)-Appropriate Efforts: It appears that the party is making an appropriate effort to replace MB with alternatives such as 

Iodide. More effort to implement grafting, resistant root stocks, etc. may facilitate the phase out of MB in areas where regulatory consof the chemical alternatives. 

Nurseries stock (fruit, nut, flower) 

United 45.800 64.528 28.275 51.102 25.326 17.363 7.955 1.591 - 0.541 States 

MBTOC comments 2011: MBTOC recommends 0.541 tonnes of MB for this use in 2013. This represents a reduction of 66% from previous amounts. The Party states that the requested amount is for those crops that require certification but do not move across controlled boundaries e.g. c

preferred alternatives such as 1,3-D due to township caps or on specific soil conditions. The treatment for crops such as fruit and nut trees required to meet certification standards for a crop that is in the ground for two years. Some portions of the crops in this sector are now proalternatives are used wherever possible. The target pest for certification is nematodes, but control of soilborne pathogens and weeds also 

MBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic argumentsComments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i) Emission reduction: Yes. Barrier films cannot be used for this nomination in California, but rates conform to the s

• Dec. IX/6 b(iii) Research program: Yes, An area wide program is evaluating the key alternatives, including methyl iodide/Pic. 

• Dec. IX/6 b(iii) Appropriate effort: A range of alternatives are being considered and commercialized.
May 2011 TEAP Progress Report 

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Orchard replant 

United 706.176 527.600 405.400 393.720 292.756 215.800 183.232 18.324 - 6.230 States 

MBTOC comments 2011: MBTOC recommends 6.230 tonnes for this use in 2013. This includes 4.318 t for stone fruit, 0.213 t for raisins, 0.627 t for walnuts, 0.564 

wine grapes. The CUN is for orchard/vineyard replant disorder of unknown etiology for a portion of replant sites in California where alternaavailable (1,3-D) or where the data on the effectiveness of lower rates of methyl iodide (MI which is currently registered in California) are seffectiveness is not yet known. The Party states that alternatives are not available because of regulatory restrictions or physical characteristics such as unacceptable soil topography. The CUN is for heavy soils or soils which cannot be effectively treated to a sufficient depth to effectively use the reduced rateCalifornia. Regulatory constraints (maximum labelled rates) prevent the use of 1,3-D at the rates needed for effective kill of old roots and deeper soil. Although methyl iodide has been registered in California since December 2010 for replant, successful trials have only been rethan registered (Browne et. al., 2010; Schneider et. al, 2005). Trials at the registered, lower, rates have been initiated. The best alternathave been identified are 1,3-D or 1,3-D with chloropicrin, and/or metam-sodium, especially in coarse-textured soils. Under certain soil and than 12% to 1.5 meters) 1,3-D is an effective management tool for replant problems and is currently used to replant the majority of orcharMBTOC acknowledges that the CUN is for a substantially smaller amount that is 34 % of the previously approved CUN. The Party confirm

formulation is used for California stone fruit, raisin grapes, and wine grapes, and now as well for almond and walnut at a dose rate of 20g/

MBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic arguments.Comments requested in Dec. XX1/11 (para 9)  Dec. IX/6 b(i) Emission reduction: No, high barrier films cannot be used in California due to regulatory constraints. Rates constandard presumptions without barrier films. Rates conform to the standard presumptions with barrier films.  Dec IX/6 b(iii) Research program: Yes, research effort have been conducted on alternatives.  Dec. IX/6 b(iii) Appropriate effort: Substantial reduction indicates appropriate efforts. 
168 May 2011 TEAP Progress Report 

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United States 

Ornamentals 154.000 148.483 137.835 138.538 107.136 84.617 64.307 48.164 - 48.164 MBTOC comments 2011: MBTOC recommends a reduced amount of 40.818 tonnes for this use in 2013. This includes 39.907 t for California and 0.911 t for Florida

The Party states that the nomination is for a large number of species, mostly grown in the field. In Florida, the main species using 

snapdragon. Additional species using MB in California include alstroemeria, carnations, delphinium, gerbera, chrysanthemums, pomponsseveral types of cut flower, foliage, and bulb crops grown each year and often several species are grown in the same field simultaneoudiseases (e.g., Fusarium spp., Pythium spp., Phytophthora spp., and Rhizoctonia spp.), plant parasitic nematodes (e.g., root knot, roo

weeds (e.g. Cyperus spp., Portulaca, Ambrosia and others), and previous crop propagules. Methyl iodide (MI) is now registered in Califo

data as to efficacy at the reduced rates on the California label. MI has been registered since 2009 in Florida and some data as to its effica

some concerns on its applicability for widespread use on certain soil conditions (Kokalis-Burelle et al., 2010; Rosskopf et al., 2010 ab). T

potential cultivar sensitivity and this requires more research with the many cultivars and flower crops produced. MBTOC considers other alternatives are available in Florida, such as 1,3-D/Pic and solarization sometimes combined with chemicals 

McSorley et al., 2008). Steaming systems and application methods were evaluated in California and provided pest control statistica

bromide (Gilbert et al., 2009; Rainbolt et al., 2010). MBTOC has reduced the nomination by 15% for California and 25% for Florimplementation of substrates, steam and uptake and improvement in MI technologies by 2013 and the registration time (and rate) for MI. MBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic arguments.Comments requested in Dec. XX1/11 (para 9) 

• Dec. IX/6 b(i) Emission reduction: Yes, for part of the nomination. Barrier films are currently used in Florida. Barrier films 

California due to regulatory constraints. Rates conform to the standard presumptions with barrier films.

• Dec. IX/6 b(iii) Research program: Yes, research efforts have been conducted on alternatives. 

• Dec. IX/6 b(iii) Appropriate effort: The nomination indicates significant efforts have been made to switch to alternatives. Su

indicates appropriate efforts particularly in Florida. In California, efforts have been made within the constraints imposed by regula
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United States 

Peppers (field) 

1094.782 1243.542 1106.753 756.339 548.984 463.282 206.234 28.366 - 5.67

MBTOC comments 2011: MBTOC recommends 5.673 tonnes for this use in 2013, provided the Party submits further explanation on the specific issues that have ar

July 15th, 2011. If substantiation is not provided, MBTOC does not recommend this nomination. The USG may either support or withdraw 

OEWG. If the US proposes an increased amount, MBTOC will need to reassess the nomination. Of the recommended amount, 0.068 t is for the Southeast, 0.189 t is for Georgia and 5.415 t is for Florida. The Party has made an 80 % reduction in MB use from the amount approved by the Party’s for 2012. MBTOC acknowledges the substanfor uptake of alternatives. The Party did not submit a CUN for Michigan for 2013. The Party is projecting rates of 125 kg/ha (12.5 g/m2) for 

nutsedge. In addition, the party states that the treatment, known as the “UGA 3-WAY”, consisting of three successive soil fumigations, begapplication, followed by a Pic application, followed by a metham-sodium or metham-potassium application (Culpepper, 2007a), is an alterncrops. For Georgia fall crops, this system needs further development for use in areas with moderate to high nutsedge pressure. 1,3-D is rtopography where ground water is vulnerable to leaching from 1,3-D. In addition, metham sodium and 1,3-D in the fall require longer waitMB. Delays could result in missed market windows. Midas, a mixture of MI and Pic, has received state-level approval in 47 US states (CaNew York are the exceptions at this time). However, the Party states that some time will be necessary before Midas achieves a full adopt

to the widely use of MI are : (1) the cost of MI formulations which is higher than MB, (2) growers and researchers will need time to evalualocal production conditions covered by this nominations, and (3) growers and applicators will need to make some equipment modifications rates typical with less expensive MI application rates and to avoid the corrosion of some metals that can occur with MI (Sumner 2005, Nol

MBTOC considers that further reductions in MB amount is possible with changes to formulations of 50:50 MB/Pic or less (e.g. to 30:70) usbarrier films, MBTOC considers that the Party should also develop some non chemical alternatives e.g. grafting, biofumigation, soil less cused in many countries and regions with similar climate and pest. It is important to note that MB is not used in other non Article 5 countrie

MBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic argumentsComments requested in Dec. XX1/11 (para 9) 

• Dec. IX/6 b(i) Emission Reduction: There is no information in the nomination about the use of VIF or equivalent film, howeve

indicate that there is an active program of research into the use of various barrier films and the rates (125 kg/ha) are consistent w

and MBTOC’s standard presumptions 

• Dec. IX/6 b(iii) Research Program: Yes, equivalent research is on-going in similar sectors, 
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• Dec. IX/6 b(iii) Appropriate Efforts: It appears that the Party is making an appropriate effort to replace MB with alternatives suc

and Methyl Iodide. More effort to implement grafting, resistant root stocks, etc. may facilitate the phase out of MB in areas wheprevent the use of some of the chemical alternatives

Strawberry (field) 

2052.846 1730.828 1476.019 1349.575 1269.32 1007.47

7 

United 812.709 678.004 - 531.737 States 

MBTOC comments 2011  After reviewing the MBTOC report, including the text of the minority report, TEAP made a recommendation for a reduced amount of 461.1

fruit in California for 2013 and that the Party provide further substantiation of why the 70.551 tonnes (or part there of) can not use alternatiMBTOC. The amount approved is part of the nominated amount of 531.76 t by the Party. After TEAPs Decision, a report was written by majority to restate their position on the recommendation (see below) - this report was not reviewed by TEAP. MBTOC reiterates its previous suggestions in 2010 that shank injection of 1,3-D/Pic may result in improved disease control compared to drecognise that township cap regulations impose a penalty on shank injection. MBTOC continues to urge the Party to reconsider the evidenregulation. Regulations in California also prohibit the use of VIF films with MB application, and therefore discourage reduction of MB dose control through use of VIF. PUR use data for 2009 indicate that MB:Pic 57:43 formulations are used on 73% of the MB fumigated acreageformulations are used on 5% of the California use area. The Party has adopted a dose rate of 170 kg MB/ha in its CUN for 2013. MBTOC 

170 kg/ha as MBTOC encourages wider use of 50:50 formulations, which still allow for complying with regulatory restrictions on Pic use. TMI/Pic in California was completed successfully in December 2010, however MI/Pic use is restricted by buffer zones and other restrictionsto adoption of MI, as cited by the California Strawberry Commission (CSC) that alluded to actions by environmental groups and market stanature of the MI registration in California, and observations of phytotoxicity. MBTOC requests the Party to confirm the area of critical needbreakdown of that unable to use 1,3-D or Pic or their mixtures and those unable to use methyl bromide in any future nominations. MBTOC to develop an action plan for California, particularly addressing the restrictions on the use of alternatives adopted elsewhere in the USA, areductions to effectively progress the transition to MB alternatives. MBTOC notes and commends the withdrawal of MB for this use in Florida and Eastern USA, where full transition to alternatives has been Majority position At the March meeting of MBTOC in Turkey, a majority view (15 of 24 committee members present) supported nomination by the Party of 5

2013 which is a 21% reduction (for methyl iodide uptake) based on the 673.085 tonnes MB approved at the MOP in 2010 for use in 2012. 2013, as corrected in the bilateral with the U.S. government, is 3,128 ha which is a 21% reduction of the area estimated: 170 kg/ha x 3.12MBTOC has accepted, in 2010, a dose rate of 196 kg/ha in California, however encouraged the Party to reduce its dose rate to 170 Kg/ha 
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MBTOC acknowledges this effort in the dose reduction. The majority considers that in the past, there has been variability in the area of land treated with methyl bromide as farmers lease land anwithin regions and counties and therefore it is difficult to identify the exact area to be treated. Analysis and models to predict with precision do not exist and MBTOC has relied on historical data to predict future trends. As the Party is making a good transition to a new alternative Party reduction. The Party proposed a transition of 21% from the 2012 CUE amount of 673.085. The nomination is therefore based on a an area of 3,128 ha which was a 21% reduction of 3959 ha. Further elaboration of the rationale for the majority recommendation of 531.76 tonnes appears immediately following this table.Minority position The minority position was signed by seven members. The minority recommended that the nomination was 'Unable to Assess' and that the should be based on the nominated dosage rate of the Party at 170 kg/ha and a 21% reduction of the critical area of 3.434 ha (for methyl iothe area used by MBTOC last year to determine the 2012 CUE and approved by the MOP. Also, that a decision not be made until the Pathat cannot use alternatives, particularly 1,3-D or Pic and their mixtures, as determined by MBTOC is incorrect. The critical area in 2010 wminority just as in past opportunities, using information from the Californian Pesticide Use Reports and information on restrictions provided D and Pic. This information was discussed and given to the Parties during bilateral discussions in 2011. TEAP recommendation At the May meeting in 2011, and after listening to the majority and minority points of views, TEAP agreed to support a part of the nominatequestioned by the majority and the minority positions of MBTOC (ie 461.186 t). The additional amount, 70.551 tonnes requires, further suarea not able to use the alternatives (1,3-D and Pic and their combinations) as provided by MBTOC to the Party. The Party is invited to pr15 July 2011 for further evaluation by MBTOC for any amount above the minority recommendation up to the nominated amount.' MBTOC comments on economics 2011: CUN includes a partial budget for the use of iodomethane by California strawberry producers, in addition to Pic+MB and 1,3D+Pic as in th

shows that the gross margin (termed net revenue in the CUN) declines from $688 per hectare using methyl bromide to a loss of $3889 pe

iodomethane, $8614 using Pic+MB, and $8042 using 1,3D+Pic, the latter two as a result of a yield loss of 15% and 14% respectively. MBaccuracy of the data, but notes that UC Davis estimates the return to strawberry production in California as $6700 per acre, or more than (http://coststudies.ucdavis.edu/current.php).

Comments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i) Emission reduction: In California VIF is not used; 
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• Dec. IX/6 b(iii) Research program: Yes, there is an ongoing research program, which the CUN refers to; • Dec. IX/6 b(iii) Appropriate efforts: In California there is varying effort in the different production districts. 

Strawberry runners 

54.988 56.291 4.483 8.838 7.944 4.690+ 

2.018 

United 6.036 3.752 - 3.752 States 

MBTOC comments 2011: MBTOC recommends 3.752 tonnes for this use in 2013, This CUE recommendation is based on an area of approximately 19 ha at a rate 

The Party stated that the amount applied for is lower than those required by the nematode certification program which specifies rates of 2

sandy and clay loam soils according to the of California Dept of Agriculture Nursery Inspection Procedures Manual No. 7. Studies in otheshown that MI in combination with Pic and metham has given equivalent effectiveness for nematodes at rates of 336 kg/ha. Methyl iodide nursery certification purposes, but the present rates required for certification (26 g/m2) are greater than those presently registered in Califo

proportion (99%) of the hectares are exempted under QPS. The key pests previously stated as affecting strawberry runners are weeds (pfungi (Rhizoctonia and Pythium spp in SE, Phytophthora,Verticillium in California), nematodes (root-knot, sting in CA). Alternatives evaluathe past several years showed that 1,3-D/chloropicrin, 1,3-D/chloropicrin + metam-sodium, 1,3-D and metam-sodium, and dazomet as a fD/chloropicrin or chloropicrin (Fennimore et al., 2008b) were very effective. These formulations have been shown to give similar pathogen 

meet requirements of certification (Kabir et al., 2005; Fennimore et al. 2007, 2008; MBAO). However, regulations in California on the use 

restrict key alternatives used in some locations. MBTOC acknowledges that trials are now underway to evaluate efficacy of the lower registered rates for certified nursery use and approvanominations to update on trials with these products. Transition rates to MI have not been considered by the Party for this CUE. The CUN duse. MBTOC requests that a full review of trials with feasible alternatives (especially MI/Pic) be provided with future nominations as requiMBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic argumentsComments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i) Emission control: Yes in Florida and Eastern states, with use of VIF; No in California where VIF is not used; Rate• Dec. IX/6 b(iii) Research program: Yes, ongoing research is being conducted showing that MI/Pic especially is effective, but it i

suitable for certification in California. 

• Dec. IX/6 b(iii) Appropriate effort: No, trials have not been provided showing use of MI/Pic at lower rates. MI has qualified for c

however it is not yet registered at suitable rates.
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Tomatoes (field) 

United 2876.046 2476.365 2065.246 1406.484 1003.876 737.584 292.751 54.423 - 10.741 States 

MBTOC comments 2011: MBTOC recommends an amount of 10.741 tonnes for this use in 2013, provided the Party submits further explanation on the specific issu

alternatives by July 15th, 2011. If substantiation is not provided, MBTOC does not recommend this nomination. The USG may either suppo

nominated sector at the OEWG. If the US proposes an increased amount, MBTOC will need to reassess. Of the nominated amount, 0.1 t is for Maryland, 0.129 t for Virginia, 1.633 t for SE, 0.776 t for Georgia, and 8.331 t for Florida. The Party has projected a significant transition to alternatives, about an 80 % reduction in MB use from the amount approved by the Partytonnes). The UGA 3-WAY has been shown to be effective for tomatoes in Georgia. However, the use of any alternative strategies involvinregulatory restrictions in areas with karst topography. Plant back timing is also a constraint in some regions as it affects market timing. In 

for more research to determine the fumigant rates and mulch combinations needed for pest control and crop safety where there is heavy pof MI and Pic, is registered in the tomato nominated states. This product has shown good efficacy against key tomato pests, including nuttomatoes (Olsen 2008). Midas has received state-level approval in US states, except in Washington, and New York. DMDS has a FederaFlorida and California and has demonstrated effectiveness, however there are still some technical and application issues to be resolved uTreatments with DMDS plus chloropicrin and/or metam-sodium are not significantly different from methyl bromide + chloropicrin. However impairment to its widespread adoption.Grafting is widely used in many countries and regions with similar climate and pest (Besri 2008). M2008, Kubota 2008, Louws 2009, Bausher 2009) provides evidence that root stocks e.g. ‘Big Power’, ‘Beaufort’, and ‘Maxifort’ can be utilizpathogens. Freeman et al. (2009) reported that although grafted plants add significantly to input costs at current prices, the net economic infestations are high. It is important to note that MB is not used any more in developed countries (e.g. European countries , Australia, Japadeveloping countries (e.g. Morocco, Lebanon, Turkey) on tomato. MBTOC acknowledges the substantial reduction by the Party for uptake of alternatives, particularly the use of the “UGA 3-WAY”, consistinfumigations, beginning with 1,3-D + Pic application, followed by a Pic application, followed by a metam-sodium or metam-potassium appliuse of methyl iodide (Culpepper, 2007, Gilreath et al. 2006, Noling et al. 2006). MBTOC considers present issues with MI amd DMDS to MBTOC comments on economics 2011: The same economic information is provided as in the previous year. CUN is not based on economic arguments.Comments requested in Dec. XX1/11 (para 9)

• Dec. IX/6 b(i)- Emission Reduction: No, there is no information in the nomination about the use of VIF or equivalent film, howe

program of research into the use of various barrier films. 
174 May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117 

CUE for 20128

CUN for 2012 (addtl or new) 

CUN for 2013 

• Dec. IX/6-b(iii)-Research Program: Yes, the research is on-going, however specific studies conducted or in progress since the 

cited in the nomination 

• Dec. IX/6-b(iii)-Appropriate Efforts: The Party made large reductions. Adoption of chemical and non chemical alternatives m

MB in areas where regulatory constraints prevent the use of some of the chemical alternatives. 

United Research 6.111 6.203 States 

MBTOC comments 2011: 

MBTOC was unable to recommend this nomination in total at this time. Decision XVII/9 (7) states that Parties should endeavour to source stocks. At present rate of drawdown of about 1200 tonnes annually (US Accounting Framework for 2009, 2010), pre-2005 stocks should b2011. The nomination of 7.445 and 7.537 tonnes for 2012 and 2013 respectively covers three distinct areas of MB-related research: (1) redeveloping or improving QPS procedures involving use of methyl bromide, (2) research directed at gathering full scale performance and emethyl bromide and other fumigants, to meet regulatory requirements and approval processes, and (3) research on alternatives where meperformance benchmark during development and approval of alternatives. In several particular nominated uses, the quantity nominated fonomination for the use itself. Parties may wish to consider quantities for research used for category (1), development of QPS treatments, be considered as exempt from same way as QPS treatments themselves. MBTOC recommends that uses in category (2) be approved as a CUE, provided that best end

source the required quantities from stocks and that these have been unsuccessful. MBTOC recommends that quantities nominated in cate

provided that best endeavours have been used to source the required quantities from stocks and that these have been unsuccessful, and in cases where the need to benchmark performance of potential alternatives is specifically required to eet regulatory and registration requthis is not so, MBTOC suggests that an alternative benchmark be used to assess comparative effectiveness. The Party has submitted research plans in one case (Cured Pork CUN) to explain the nominated quantities. This part of this CUN has bee

nomination and is considered separately in the Structures and Commodities text boxes. MBTOC seeks detail on the plans in the other secconfirmation of the quantities requested, how these are allocated to the various categories of use, and the background to the regulatory neperformance benchmark in each use. This should enable MBTOC to finalise its recommendations for this complex nomination. 

11ExMOP and 16MOP; 216MOP+2ExMOP+17MOP; 3MOP17+MOP18; 4MOP18+MOP19; 5MOP19+MOP20; 6MOP20+MOP21; 7MOP21+MO
May 2011 TEAP Progress Report 175

8.6. Report Presented after the TEAP Decision on the US 

Strawberry CUN by Some Members who Supported the 

Majority Position after the MBTOC Meeting 

Signed by: Abraham Gamliel, Jim Schaub, Ken Vick, Sally Schneider, Peter Caulkins, George 

Lazarovits, Andrea Minuto, Chris Bell, Nick Vink, Akio Tateya, Darka Hamel 

TEAP Statement

Section 8.6 is a signed statement by the majority segment of voting MBTOC members in 

response to the signed minority report concerning the US strawberry CUN and 

recommendations of TEAP itself. This statement was submitted after the TEAP meeting where 

TEAP made recommendations on this CUN and TEAP members did not review the statement. 

Therefore the views expressed by the segment of voting MBTOC members reflects the opinion of 

the signatories and not necessarily the views of other MBTOC or TEAP members. 

The strawberry textbox in the Oct 2010 TEAP report notes that the Party nominated 751.596 

tonnes for an area of 4421 ha treated at 170 kg/ha for California in use year 2012 and this is 

shown in the CUN, as well. Later in the same textbox, there is language that says that MBTOC 

has accepted a dose rate of 196 kg/ha in California. This could be text left over from previous 

years, as higher rates were nominated in earlier years. It is unlikely that MBTOC would 

recommend a higher rate than the Party had nominated, and thus is reasonable to assume a use 

rate of 170 kg/ha. MBTOC recommended and the Parties approved 90% of the nominated 

amount, so a reasonable estimate of the area using the 170 kg/ha nominated rate and the 

approved amount for California of 673.085 tonnes would be 3,959 ha. The area stated for use 

in 2013, as corrected in the bilateral with the U.S. government, is 3,128 ha which is a 21% 

reduction of the area estimated. When multiplied by 170 kg/ha, the result is 531.760 ha, 

essentially the amount nominated. This is the most likely scenario, since the CUNs for both 

2012 and 2013 nominated a use rate of 170 kg/ha. 

If indeed MBTOC approved, and the Party used, a use rate of 196 kg/ha instead of the 170 

kg/ha that was nominated, the approved amount of 673.085 tonnes could be used to treat 3,434 

ha. A 21% reduction from 3,434 ha is 2,713 ha. If this reduced area is then multiplied by 196 

kg/ha would give 531,748 tonnes, which is again the nominated amount. 

Absent specific information from the party or documentation in a textbox, an inconsistent 

interpretation would be to use 196 kg/ha for one part of the calculation, then use 170 kg/ha for 

the other part; i.e. to ignore the part of the 2010 textbox that said the Party nominated a use rate 

of 170 kg/ha and choose instead the part of the textbox that said MBTOC accepted 196 kg/ha 

when calculating the estimated treatment area for 2012, and then use then choose the 170 kg/ha 

rate for the calculation of the 2013 recommendation. 

 It should be noted that the vast majority of the strawberry growers rent lands where they grow 

strawberries and these rental choices are not constrained to counties or townships. Therefore, to

attempt this precision for the strawberry CUE is not practical. Analysis and models to predict 

with precision the location of production do not exist. Hence, the recommendation along 

previous years never identified specific hectares for strawberry production and their locations 

The underlying approach used by the Party and accepted by the majority included: 

− Calculate area to be treated in 2012 based on amount approved (673.085t) and use rate 

(170 kg/ha) 

− Apply transition to alternatives (21% for uptake of methyl iodide) to calculated area 

− Calculate amount based on reduced area and consistent use rate. 
176 May 2011 TEAP Progress Report 

These calculations are shown in the table below. 

Consistent – 

Reflects Use 

Rate from 

Party 

Alternate Use 

Rate, but 

consistent 

Inconsistent 

2012 Amt Approved 673.085 tonnes 673.085 673.085

2012 Use rate 170 kg/ha 196 kg/ha 196 kg/ha

Calculated 2012 ha 3,959 ha 3,434 ha 3,434 ha

21% Reduction of 2012 ha 3,128 2,713 ha 2,713 ha

2013 Use Rate 170 kg/ha 196 kg/ha 170 kg/ha

Calculated Amount 

Recommended 531.760 tonnes 531.748 tonnes 461.210 tonnes

% Reduction from 2012 

Amount Approved 21% 21% 32%

The Party proposed a transition of 21% from the 2012 CUE of 673.085. The nomination is 

based on a dose rate of 170 kg/ha and an area of 3128 ha which was 21% reduction of 3959 ha. 

8. 7. Interim CUN Report – Issues Specific to MBTOC-Structures 

and Commodities 

MBTOC Structures and Commodities (SC) met at Antalya, Turkey in March 2011. At the kind 

invitation of the Government of Turkey, Ministry of Agriculture, and the Western 

Mediterranean Agricultural Research Centre (BATEM), MBTOC SC and QPS jointly 

conducted a field trip to view quarantine proceedures for of dried fruits, nuts and packaging 

materials in the main growing and export region of Izmir. We also visited two grower 

cooperatives engaged in export of dried fruit and nuts to learn about their use of MB and 

alternatives for quarantine and preshipment uses. 

The earthquake and tsunami in Japan occurred just before the MBTOC meeting. MBTOC was 

very concerned but can report, with relief, that its two Japanese members were safe and even 

able to attend the MBTOC meeting. 

MBTOC SC assessed the 2011 CUNs and prepared the Progress Report. A short bilateral 

meeting was held with United States to discuss questions about the CUNs and to improve 

understanding of recent proposed regulatory changes which might affect the future use of 

sulfuryl fluoride. Additionally, MBTOC SC met with Arysta LifeScience to understand 

requirements of the safe use of methyl iodide for postharvest disinfestation of chestnuts in 

Japan. 

Parties continue to make progress on some CUNs, reducing many MB uses by continuing to 

resolve the inter-related issues of treatment logistics, costs, trade demands and effectiveness of 

alternatives. 

Last year, MBTOC noted a concern that progress in adopting alternatives had stalled. This year 

there was a complete change; all Parties nominated very significant decreases in MB use. To 

illustrate this change, last year the Government of the United States informed MBTOC that no 

further adoption of alternatives seemed possible for dried fruit and nut sector. To assist further 
May 2011 TEAP Progress Report 177

adoption of alternatives, MBTOC discussed alternatives in its text box and provided a review of 

research on alternatives for dates included in the US CUN. Perhaps for this reason, this year, the 

USG nominated a 66% decrease in its commodity CUN. Australia and Japan both nominated 

decreases in their CUNs for rice and chestnuts respectively, and in addition committed to new 

phase out plans which committed to zero MB use by 2015. 

This year the Government of Canada did not submit a critical use nomination for pasta 

facilities. MBTOC believes the Party and its applicant have conducted tests of heat treatment 

and sulfuryl fluoride treatment, perhaps making sufficient adaptations to have allowed adoption 

of alternatives in this sector. This sector may have achieved phase out of MB use and if so, 

MBTOC congratulates the Government of Canada. 

As well this year, the Government of the United States did not submit a critical use nomination 

for those food processing facilities formerly included in the CUN of the National Pest 

Management Association (NPMA). In its final report in 2010, MBTOC discussed the then 

recent change in regulatory interpretation by the US Environmental Protection Agency which 

was able to result in the applicant withdrawing its CUN. MBTOC congratulates the United 

States for its ability to resolve a regulatory issue which then led to phase out of MB in the food 

processing sectors included in the former NPMA CUN. 

The use of methyl bromide in Canadian and American grain and cereal milling continues to 

decrease, largely through the adoption of heat treatment and sulfuryl fluoride treatment (SF). 

Although millers in both countries have adopted both types of treatments, millers in Canada 

have tended to adopt heat more than they have adopted SF, whereas millers in the US have 

tended to adopt SF more than they have adopted heat treatment. Depending on possible 

regulatory changes pertaining to SF use in the future, this may be significant. 

MBTOC notes the uncertainty caused by the recent US EPA proposed regulation, which has 

been brought about as part of a range of actions to reduce the incidence of fluoride in the diet of 

some sectors of the US population. The regulation proposes to eventually eliminate food contact 

by the fumigant sulfuryl fluoride.. MBTOC continues to watch this situation with interest. This 

matter was discussed in the Assessment report and is further discussed in the MBTOC SC 

Progress Report. 

The US decreased its CUN for regional cured pork in storages in spite of a lack of effective and 

registered alternatives, largely through IPM improvements. There is an ongoing research project 

to test alternatives. This year MBTOC learned about the scale-up of phosphine research as a 

possible alternative for pests of this commodity. MBTOC notes that phosphine efficacy has yet 

to be demonstrated on commercial scale for the mites which are sometimes pests of this 

commodity. The planned research may find ways to combine phosphine treatment with other 

methods to achieve effective pest control. 

Although IPM is not a common programme in meat processing facilities, which are usually 

more concerned with control of microorganisms, perhaps in this instance, research to develop 

and evaluate specific IPM methods for meat processing may contribute to achieving effective 

control. 

This year, the US submitted a CUN for MB to support various research projects. The CUN 

included some soils research and also research on regional cured pork. Later correspondence 

with the US corrected the amount nominated for cured pork and provided more information 

about the intended research use of MB. 
178 May 2011 TEAP Progress Report 

8.7.1. Standard Dosage Presumptions and Adjustments for Standard 

Dosage Rates 

MBTOC assessed CUNs for appropriate MB dosage rates and deployment of MB emission/use 

reduction technologies, such as appropriate sealing techniques. 

Decision IX/6 requires that critical uses should be permitted only if ‘all technically and 

economically feasible steps have been taken to minimise the critical use and any associated 

emission of methyl bromide’. Decision Ex.II/1 also mentions emission minimisation 

techniques, requesting Parties “...to ensure, wherever methyl bromide is authorised for criticaluse exemptions, the use of emission minimisation techniques that improve gastightness or the 

use equipment that captures, destroys and/or reuses the methyl bromide and other techniques 

that promote environmental protection, whenever technically and economically feasible.” 

With the beginning of the CUN process in 2005, MBTOC published its standard presumptions 

for structures (20g m-3) and indicated that the European Plant Protection Organization’s (EPPO) 

published dosage rates for commodities should be considered standard best practice for 

fumigation world wide. Since that time all Parties submitting CUNs stated their adherence to 

those practices. The EPPO dosage rates for commodity treatment vary by commodity, sorption 

rate and environmental conditions. They can be found in annexes to the MBTOC 2006 

Assessment Report (MBTOC, 2007). Where possible, reduced dosages, combined with longer 

exposure periods, can reduce MB consumption, while maintaining efficacy. (MBTOC 2007). 

8.7.2. Details of Evaluations 

Parties have submitted seven CUNs for the use of MB in structures and commodities in 2011. 

In addition, one aspect of the US research CUN was for cured pork; it was separated from the 

research CUN and is responded to here. The text box for the remaining aspects of the CUN is 

located in the MBTOC Soils report. This year all CUNs were for one year – 2013. 

MBTOC was unable to assess the CUN for cured pork because commercial scale trials with 

phosphine are planned or are being conducted. If there was to be a successful outcome of those 

trials, the use of phosphine might eliminate the need for methyl bromide.. MBTOC has 

recommended 0.045 tonnes of MB to enable the research to be done. Phosphine is registered 

but there are no published commercial-scale results showing efficacy for the pests of this 

commodity. If MBTOC receives research results by mid-August, then MBTOC will be able to 

re-evaluate this CUN by conference call and email in September. Therefore the final evaluation 

for this CUN will be found in the October MBTOC report. 

The total MB volume nominated in 2011 for non-QPS post-harvest uses, including research, 

was 43.47 tonnes. 

Of nominations in 2011 for 2013, MBTOC recommended 39.74 tonnes (Table 8-12) 

Table 8-13 provides the MBTOC-SC interim recommendations for the CUNs submitted. 
May 2011 TEAP Progress Report 179

Table 8-12: Summary of the interim recommendations by MBTOC-SC (in square brackets) 

for CUE’s for postharvest uses of MB (tonnes) for 2013 submitted in the 2010 round. 

Years 

Country and Sector 2013 

Australia. Packaged rice [2.374] 

Canada. Mills [7.848] 

Japan. Fresh Chestnuts [3.317] 

USA 

1. Commodities 

2. Mills and Food Processing Structures 

3. Cured Pork 

4. Research in Cured Pork Alternatives* 

5. Research in Post harvest Emissions and 

QPS (Unable to Assess) 

(*See also US Research CUN in Soils)

[0.822] 

[25.334] 

[Unable] 

[0.045] 

[Unable]

TOTAL [39.74] 
180 May 2011 TEAP Progress Report 

Table 8-13: Final evaluations of CUNs for structures and commodities submitted in 2011 for 2012 or 2013 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

Australia Rice 6.150 6.150 .205 9.200 7.820 6.650 4.87 3.653 - 

MBTOC comments 2011: MBTOC recommends 2.374 tonnes of MB, the amount nominated by the Party, for use on packaged rice in 2013. This represents decrease over the amount of MB granted by the Parties for this use in 2012. MBTOC had until that point noted that the Australian adopted alternatives in spite of the availability and use of technically effective alternatives in Australia and worldwide. MBTOC nottreatment of packaged rice with sulfuryl fluoride, one of the alternatives in use elsewhere, is not registered in Australia. The Party pursuing the adoption of phosphine. In mid-2010, Australia submitted a new CUN and phase out plan nominating a 25% reduction also for each following year with the result that in 2015, there would be no further MB CUN nomination. The Party indicated that rrice harvested or the continuation of drought, this phase out plan would be required of its rice applicant. MBTOC continues to note the applicant has adopted alternatives, but with the recent improvement of water availability in the growing region, rice harvests foimprove significantly and that therefore it seems likely that alternatives will be adopted. The Party has noted some difficulties in achieving the level of technical efficacy required by its applicant; MBTOC has volunteered summary of research of efficacy of sulfuryl fluoride for the pest species of concern. MBTOC’s summary of pertinent research of inParty with similar concern can be found in the MBTOC/TEAP Progress Report of May 2011. Emission Reduction: Yes. The applicant now sends the majority of its MB-fumigated rice through MB recapture equipment. Research Program. Trials with sulfuryl fluoride are ongoing; the applicant says further work is needed to see if results can be imhowever, that there is already extensive research available on the efficacy of SF against the pests of concern and has provided a Report. A research project in 2009 was interrupted due to the unfortunate death of the scientist in charge. Appropriate effort. As with all postharvest registration issues, neither the applicant nor the Party mandated with Montreal Protoc

over pesticide registration. This applicant has not made appropriate efforts to adopt alternatives, since no alternatives have been of technically effective and affordable alternatives being available. MBTOC agrees with the Party that its new phase out plan will ladopting alternatives soon as harvest quantities are expected to increase and MB availability has decreased.MBTOC comments on economics 2011: Applicant argues that phosphine fumigation, following milling but before packaging, is the best technical and economical alternativto transition to phosphine 
May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

Mills 47 

(included 

mills and 

pasta) 

Canada 34.774 30.167 28.650 26.913 22.878 14.107 11.020 - 

MBTOC comments 2011: MBTOC recommends 7.848 tonnes, the amount nominated by the Party for use in mills in 2013. This is an approximate 29% dec

granted by the Parties for 2012. The Party advises that mills that are producers of durum semolina or have integrated/contiguous that are particularly large structures are the remaining methyl bromide users. The CUN states that the amount requested is only sof 7-8 of the 17-18 mills in the application, so most mills would not be fumigated in 2013. As per Canadian regulation, mills which 

necessary, share some of the total CUN amount granted so that is why more mills are listed than will actually be fumigated. The 2

one less mill than in 2010, due to adoption to alternative treatments such as heat. Evaluation of alternatives to methyl bromide in progress include: heat treatments; the just recently registered ECO2Fume formula 

phosphine mixed in gas cylinders), sulfuryl fluoride (SF) (but only if there is no food contact); plus integrated pest management prcombination with heat treatments and fumigations with the aforementioned alternative fumigants. Current research is directed towards practical trials with heat and other IPM upgrades, and SF. The results of current trials on a pindicated poorer than expected efficacy, probably because adequate temperatures are not being maintained and the vulnerability maintenance in windy conditions. Additionally, SF, at the applied dose, has been found to be less effective for the eggs of red flouflour beetle. This is significant because red flour beetle is the pest of most concern in Canadian mills yet confused flour beetle is tspecies in trials. For all alternatives, the recent tightening of food safety regulations in Canada has increased the pressure to raise the already high to eliminate pests. Mills have to operate according to a “Required efficacy” standard which in Canada means no live insects, incluproduct fractions leaving the mill for customer destinations. There is intensifying regulatory pressure in North America to improve human pathogens, contaminants and stored product pests from food ingredients and processed foods. The Party advised MBTOC that a number of mills are acquiring heat treatment equipment in 2010 and 2011 with the expectation use by 2012. Other mills are still having difficulty in achieving the required efficacy through use of alternatives. Until problems can adoption of SF will be delayed, even if registration is eventually extended beyond empty structures. There is registration of SF fowidening of this registration originally expected in the summer of 2009 was not achieved as of March 2011. 
182 May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

Heat treatments may also be somewhat less successful than conventional MB fumigations, particularly as the size of the structure each structure act as “heat sinks” that absorb large amounts of heat, rendering them difficult to heat to the temperature and for thlife stages of insect pests. Complete evaluation of the heating requirements for any single milling facility is a process of trial and eone that takes time to complete. The CUN summarizes that, treatment with SF or the heat and phosphine combination treatment (phosphine, heat and carbon dioxpopulations in flour mills for over 18 weeks. In the nine treatments, only once did the next fumigation need to be scheduled earlier Emission control. The majority of mills are now not even fumigated annually, which reduces emissions. Ongoing research – Excellent research multi-mill, multi-stakeholder research program in past with several full reports submitted 

SF and elevated temperature, phosphine + CO2, etc). Research has not been reported in past two years; MBTOC is not convincefield is absolutely necessary. When mills are not MB fumigated, they are being heat treated and all are now in enhanced IPM. Appropriate effort in the CUN? Full registration of SF has not been achieved; there is still no food tolerance for F residues from action has been delayed for several years and hinders ability to fully adopt SF as an alternative treatment. Neither the millers nor registration. In spite of delay in achieving full registration, the mills are continuing to make progress. MBTOC comments on economics 2011: CUN states that the transition to heat treatment or enabling structural modifications such as replacement of wooden floors and exinsulation to reduce insect harbourage, which require capital investment, is negatively affected by the economic downturn. Howevout is to permit a gradual economic adjustment in the absence of federal or provincial government financial assistance programs. 

Japan Chestnuts 7.100 6.800 6.500 6.300 5.800 5.400 5.35 3.489 - 

MBTOC comments 2011: MBTOC recommends 3.317 tonnes of MB, the amount nominated by the Party for fresh chestnuts in 2013. This is a 5% reduction 

granted by the Party for this use in 2012. As a result of its research program, Japan determined that methyl iodide (MI) would be an effective alternative to the use of MB in registered in 2009 and an MRL for methyl iodide residues in food was later established (0.5ppm), which allowed for the use of MInot result in the immediate commercial availability of the fumigant. The registrant of MI in Japan has a product stewardship prograstringent and modern application methods for MI than are required for MB, which was an older process. The registrant had to first systems to make the fumigant available for its different applications. The registrant then investigated current fumigation practises training in the safe use of the fumigant according to multinational standards of fumigation practise. 
May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

The additional stringency has resulted in the requirements for the building of better containment fumigation chambers, among othstringent requirements for the safe use of MI, plus the training requirement, have resulted in the need for more time to complete thestablishing technically effective methods to use MI in fumigation consistent with their requirements for 2 hour fumigation times reharvest. The CUN notes that Japan will have completely transitioned this use to MI by the end of 2014. The amount of MB requested by thphase out plan leading to zero use of methyl bromide in 2015. MBTOC asks if Japan has established an MRL for iodide. Emission reduction. To date regular reductions in MB use through logistical improvements. Consolidation of fumigation loads al

Research program in past 12 months. Extensive research program has been completed, no further research needed other than MI can be achieved, and that is optional. There is established efficacy of MI for this purpose in Japan and it has been registered. Appropriate effort? Registration for methyl iodide proceeded as per normal and was registered after appropriate review. Now exchange logistics and treatment facilities to allow the safe use of methyl iodide as per multi-national fumigation standards. MBTOC comments on economics 2011: The nomination was not based on economic arguments. 

United Commodities 89.166 87.719 78.983 58.921 45.623 19.242 5.000 2.419 - 

States 

MBTOC comments 2011: MBTOC recommends 0.822 tonnes, the amount nominated by the Party for MB treatment of dried fruit, walnuts and dates in 2013

reduction over the amount granted by the Parties for use in 2012. The USG has nominated a very challenging decrease in MB usMBTOC supports. If it were to be provided, a phase out plan would inform MBTOC and Parties of the continued timing of its transMBTOC notes that logistical improvements and investments may be needed which could lead to the adoption of cold storage for tdried fruits which could assist this sector to phase out of MB entirely. We would expect that any further commodities CUN would nthey should be protected from post-process re-infestation with treatments other than MB. Additionally, MBTOC notes that controlled atmosphere treatment would provide an effective non-chemical treatment for all the comay find the section on controlled atmosphere treatment and associated tables found in the Structures and Commodities Chapter Report to be helpful in understanding controlled atmosphere. Transition to controlled atmosphere might be additionally useful give
184 May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

Protection Agency regulation which proposes to phase out the use of SF for food contact. This is particularly significant given that prepared before the announcement of the proposed regulation, reports that the sector is moving to SF. If the US government phafoods, it may delay the transition to alternatives, since the use of SF has assisted this transition. Emissions reduction. This sector has very considerably reduced use of MB, and therefore emissions. Fumigation takes place in enclosures. Research effort. Research on dates is ongoing but focused on the use of sulfuryl fluoride. The US Environmental Protection Age

the use of SF for foods and so MBTOC does not know if this proposed regulation will affect research or adoption of alternatives. Appropriate effort. Several alternatives are already registered. Also controlled atmosphere could be used. MBTOC comments on economics 2011: Walnuts: The CUN provides a detailed financial analysis in the form of a partial budget of the cost of fumigating walnuts with met

fluoride, and with phosphine. SF results in an increase in gross margin because the price per unit is lower, even though the dosagPhosphine requires capital investment in fumigation chambers in the first year because of the longer fumigation time and the danwindow, but thereafter is cheaper to use as the unit cost is lower than that of methyl bromide. The full cost of the fumigation chamyear. Dried fruit: The CUN shows that treatment with SF results in a higher gross margin, and that treatment with phosphine, while res

in the first year because of the need to provide fumigation chambers, will in later years also lead to a higher gross margin. Dates: SF is the only technically feasible alternative in dates, and the CUN shows that its use results in an increase in gross marg

The CUN is not based on economic arguments, but on the need for a phase-out period. 
May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

Mills and 

processors 

United 483.000 461.758 401.889 348.237 291.418 291.418 173.023 74.510 - 2

States 

MBTOC comments 2011 MBTOC recommends 25.334 tonnes, the amount recommended by the Party for use in food processing structures in 2013. This r

the amount granted by the Parties in 2012. This CUN includes amounts for three sectors and the recommendation is divided as fofor pet food facilities .004665 t; for mills 18.201 t. The USG has nominated a very challenging decrease in MB use for this sector, were to be provided, a phase out plan would inform MBTOC and Parties of the continued timing of its transition to alternatives.This nomination is for facilities, or portions of facilities, that are unsuitable for the alternatives, or where the alternatives are not ecrequesting methyl bromide for this sector to allow time for the industry to purchase equipment, modify structures, and/or practice The lethal effects of sulfuryl fluoride (SF) are highly dependent upon temperature. The Party reported that, should a facility need ftemperatures, this chemical may not be a cost-effective solution because of the requirement to use supplemental heat and additiohigher dosages to kill the eggs of structural pests than for other life stages. Phosphine, although it is used in combination with he

mills, can be corrosive to many metals that are present in facilities, especially in the computers and other electronic process contrThere is some confusion as to the commodities that may be directly fumigated with SF. According to the SF label in the US, pet fapproved for direct treatment. If not on the label the commodity can not be treated, leaving the question of incidental fumigation iSF. This “incidental” fumigation of commodities inside a food processing structure has resulted in problems with label interpretatiothat all pet food products would need to be removed from treatment areas or sufficiently protected to prevent the formation of resithe pet food products. This is also a factor for mills that produce mixes with multiple ingredients (e.g. cake mixes, muffin mixes, eThe industry reports that complete removal of non-sulfuryl fluoride treatable ingredients and product from the target facility would challenges, including multiple forklifts and forklift drivers, plus rented truck trailers onto which the ingredients could be loaded. Thremoved from the facility, most likely to available space in the parking lot. This process that would add labor and trailer rental coswith additional downtime needed to accomplish the ingredient removal task. Heat is dependent on several parameters: the structural composition, as different building components expand and contract at difdesign/layout factors, which affect the ability to evenly distribute heated air; and the availability of convenient and economical souconstructed primarily from wood, which the CUN reports comprise about 25 percent of the flour mills in the U.S., may not be able warping of the wood. Some areas of each structure act as “heat sinks” that absorb large amounts of heat, rendering them difficult and for the duration required to kill all life stages of insect pests. In addition, heat may not be a viable option for structures where food products or commodities are also present. There is also a high initial investment to purchase explosion-proof heaters, modifeducate personal on heat treatments. 
186 May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

In spite of the availability of heat treatment methods, the US structural sector has largely relied on transition to SF as it reduced Mregistration of SF remains unchanged in the US for the uses in this nomination. Greater transition to the use of heat treatment miEnvironmental Protection Agency regulation which proposes to eventually phase out the use of SF for food processing structuresout the use of SF for food processing structures, it may delay the transition to alternatives, since the use of SF has assisted this trEmission reduction. The sector has widely adopted SF which requires greater attention to sealing and so if MB is also used em

Research effort: No new research reported, but research is not needed. Instead trials and adaptation of known methods are nee

Appropriate effort. As with all postharvest registration issues, neither the applicant nor the Party mandated with Montreal Protoc

over pesticide registration. Many of the companies formerly associated with this CUN have switched to alternatives and/or decreaMBTOC comments on economics 2011: Pet food facilities: The CUN provides a partial budget that shows that heat treatment in the first year will result in a decline in the 

the years after the initial investment the result will be an increase in the gross margin of 0.02%. In the budget provided, the capitainvestment. Mills and other food processors: The CUN identifies SF and heat treatment as the best technical alternatives, and provides a peconomic impact of these two alternatives. In the case of heat treatment, the capital costs are again charged to the first year. The of 0.01% in gross margin, while heat treatment, taking into account the capital costs, results in a decline of 0.13%. Once the capitgross margin increases by 0.14%. The CUN is not based on economic arguments, but on the need for a phase-out period. 

Cured pork 67.907 40.854 18.998 19.669 18.998 4.465 3.73 3.730 - 

United 

States 

MBTOC comments 2011: MBTOC is unable to assess this CUN pending the receipt of the results of large scale trials to be conducted in spring and summe

had nominated 3.730 tonnes, the amount nominated by the Party, for use in cured pork sector in 2013. This is the same amount guse in 2012. See also the US research CUN text box following. The CUN reported that investigators achieved 100 % mortality of all life stages of red legged ham beetles and ham mites with 48 

1000 ppm of phosphine, respectively (Phillips, 2009). In addition, residual phosphine concentrations in dry cured hams that were 
May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

ppm were below 0.01 ppm, the legal residual limit in stored food products (Sekhon, et al. 2009b; Sekhon et al., 2010c), and consudetect differences between control and phosphine fumigated samples at 1000 ppm (Sekhon et al. 2009b; Sekhon et al., 2010c). be considered a potential alternative to methyl bromide for controlling arthropod pests of southern dry cured hams. Further testing with a greater number of mites has indicated that a greater concentration of phosphine (>1000 ppm) is likely necesinfestations. In addition, commercial applications of phosphine are planned for 2010-2011 to determine the efficacy of using phosCUN noted that the effectiveness of phosphine will be evaluated in upcoming years through the use of both bioassays (with ham in a simulated dry cured ham aging room. Other portions of this upcoming research include the economical analysis of using phomethyl bromide, if it is effective at eradicating mites. Additional items that will be researched in the future (if funding is obtained) infumigations on the sensory quality and residual concentration of phosphine in ham, and the effectiveness of using phosphine in dprocessors have indicated that they would be willing to help evaluate the efficacy of phosphine (at controlling ham mite infestationresearch project, which truly demonstrates the willingness of the industry to do everything that they can to help determine if potenbromide exist. The USG has indicated in correspondence that phosphine is registered for use on processed meats, which would include cured pDegesch America Phostoxin® (aluminium phosphide) and Fumicel® (magnesium phosphide) labels in the US lists processed medo not exceed 0.01ppm. The Horn Diluphos Fosfoquim label also lists processed meats with the same maximum residue limits. CA could be used but since the ham storage structures also require disinfestations, then adoption of CA would require a fast investorage facilities. Emissions reduction. Over the years the applicants have made facility improvements to improve gastighness, but this is a tradit

some of the facilities are older and unusual. The research program continues to work with the applicants to improve gastightnessimprovements which reduce the need for fumigation and result in decreased use of MB. This work needs to continue. Research effort. Excellent research effort to date and still ongoing. Now researching phosphine effectiveness on commercial scauniversity research program is ongoing and full reports of research have been made available to MBTOC. Appropriate effort. As with all postharvest registration issues, neither the applicant nor the Party mandated with Montreal Protoc

over pesticide registration. Phosphine is registered for use on processed meats such as cured pork. MBTOC comments on economics 2011: CUN states that an economic analysis was not conducted because there are no technically feasible alternatives. 
188 May 2011 TEAP Progress Report 

Country Industry CUE for 

20051

CUE for 20062

CUE for 20073

CUE for 20084

CUE for 20095

CUE for 20106

CUE for 20117

CUE for 20128

CUN for 2012 (Addtl or new) 

CUN 2013 

Researchcured pork 

element 

 0.045 

United 

States 

MBTOC comments 2011: The USG submitted a Research CUN, which included aspects of research on soils, QPS and one postharvest commodity – cured 

desegregated this CUN so that the postharvest element is dealt with by MBTOC-SC. Accordingly, MBTOC recommends a maxim

the USG to conduct research on alternatives to control pests in cured pork in 2012, provided that best endeavours have been usequantities from stocks and that these have been unsuccessful (Decision XVII/9, para 7). The CUN also nominated MB for researcevaluate the necessity for further MB for research in a later year if the CUN is resubmitted. The USG CUN for research amounts otonnes of MB for use in cured pork research in 2012. During MBTOC’s bilateral meeting with the USG, this amount was noted as correspondence to 0.045 tonnes. Separately, MBTOC assessed the amount needed to provide controls for commercial scale trialdetermined that 0.045 tonnes of MB should be ample, given the dosages required for pest control, and given the possibility of failneed to repeat a trial. MBTOC comments on economics 2011: The nomination was not based on economic arguments 

 Research: 

Emission reduction and QPS 

 0.114 0.11

MBTOC comments 2011: The US also nominated 0.114 tonnes for postharvest emissions control and QPS research. That aspect of the US research CUN 

further information from the Party on the intended use. 

11ExMOP and 16MOP; 216MOP+2ExMOP+17MOP; 3MOP17+MOP18; 4MOP18+MOP19; 5MOP19+MOP20; 6MOP20+MOP21; 7MO
May 2011 TEAP Progress Report 189

8.8. References 

Bausher, M.G., (2009). Tomato rootstock performance to natural populations of root-knot nematode . In: 

International Research Conference on methyl bromide alternatives and emissions reductions, 

November 9-13, San Diego, California, 44-1 

Besri, M. (2008). Cucurbits grafting as alternative to Methyl Bromide for cucurbits production in Morocco. 

In: 2008 Annual International Research Conference on Methyl Bromide Alternatives and 

Emissions Reductions, Orlando, Florida, November 11 – 14. 

Blestos, F.A. (2005). Use of grafting and calcium cyanamide as alternatives to methyl bromide soil fumigation 

and their effects on growth, yield, quality and Fusarium wilt control in melon.; Journal of 

Phytopathology 153 (3): 155-161.

Browne, G. B. Lampinen, D. Doll, B. Holtz, S. Upadhyaya, L. Schmidt, D. Wang, S. Fennimore, B. Hanson, 

S. Gao, K. Klonsky, and S. Johnson.2010. Integrated Pre-plant Alternatives to Methyl Bromide 

for Almonds and Other Stone Fruits. Annual International Research Conference on Methyl 

Bromide Alternatives. Pp 28:1-4.

Burelle, N.K, E.M. Rosskopf, M.G. Bausher, G. McCollum. (2008). Alternative fumigants and grafting for 

tomato and double-cropped muskmelon production in Florida 2008. Annual International 

Research Conference on Methyl Bromide Alternatives and Emissions Reduction. 

(http://www.mbao.org/) 

Crinò, P., Lo Bianco, C., Rouphael, Y., Colla, G., Saccardo, F., Paratore, A. (2007). Evaluation of rootstock 

resistance to Fusarium wilt and gummy stem blight and effect on yield and quality of a grafted 

'inodorus' melon. HortScience 42(3): 521-525. 

Culpepper, A.S. (2007). Impact of mulch type on rate of methyl bromide needed to control nutsedge. 

Methyl bromide CUE data generated in Georgia (Fall, 2006 – Spring, 2007), Appendix 4. 

Culpepper, A.S., P. Sumner, D. Langston, K. Rucker, G. Beard, J. Mayfied, T. Webster, and W. Upchurch, 

(2007). Can Georgia growers replace methyl bromide? MBAO Conference, San Diego, 

California, 2007. http://mbao.org/2007/PDF/Preplant/PP4/Culpepper(20).pdf

Culpepper, A.S., P. Sumner, D. Langston, K. Rucker, G. Beard, J. Mayfied, T. Webster, and W. Upchurch. 

2008. DMDS or the 3-Way: Which is more effective in Georgia? MBAO conference, Orlando, 

Florida, 2008. http://mbao.org/2008/007Culpepper.pdf

Desaeger, J.A., Seebold, K.W., Csinos, A.S. (2008). Effect of application timing and method on efficacy and 

phytotoxicity of 1,3-D, chloropicrin and metham-sodium combinations in squash plasticulture. 

Pest Management Science 64(3): 230-238. 

Díez-Rojo, M.A., JA López-Pérez, P Urbano Terrón, and A Bello Pérez. (2010). Biodesinfección de Suelos 

y Manejo Agronómico (Soil Biodisinfection and Agromic Management). Ministerio de Medio 

Ambiente, Medio Rural y Marino (MARM), Madrid, 407 pp. http://www.marm.es/es/calidady-evaluacion-ambiental/publicaciones/libro_de_biodesinfecci%C3%B3n_tcm7-156245.pdf

Fennimore, S., A. Spataru and N. Leslie (2008). Steam and heat for soil disinfestations. In: 2008 Annual 

International Research Conference on Methyl Bromide Alternatives and Emissions 

Reductions, Orlando, Florida, November 11 – 14, 2008. 

Fennimore, S, H. Ajwa, S. Shem-Tov, K. Subbarao, F. Martin, G. Browne, S. Klose (2007). Facilitating 

adoption of alternatives to methyl to methyl bromide in California strawberries . In: 

Proceedings of Annual International Research Conference on Methyl Bromide Alternatives 

and Emissions Reductions, San Diego, CA, USA. 

Fields, PG. (2007). Evaluation of Alternatives to Methyl Bromide for Use in Structural Fumigation of 

Canadian Pasta Manufacturing Facilities 2007/2008. Agriculture and Agri-Food Canada and 

the Canadian National Millers Association. 

Freeman, J., S. Rideout, A. Wimer., (2009). Performance of grafted tomato seedlings in open field production 

. Annual International Research Conference on Methyl Bromide Alternatives and Emissions 

Reduction , Nov 10 – 13, San Diego, CA ,MBAO 45-1; 45-2. 
190 May 2011 TEAP Progress Report 

Gilbert, C., S. Fennimore, K. Subbarao, B. Hanson, C. Rainbolt, R Goodhue, J. B. Weber and J. Samtani 

(2009). Systems to disinfest soil with heat for strawberry and flower production. In: Annual 

International Research Conference on Methyl Bromide Alternatives and Emissions 

Reductions, San Diego, California, November 10 – 13, 2009. 

Gilreath, J.P. B.M. Santos, J.D. Busacca, J.E. Eger Jr., J.M. Mirusso, P.R. Gilreath. (2006). Validation 

Broadcast Application of Telone C-35 Complemented with Chloropicrin and Herbicides in 

Commercial Tomato Farms. Crop Prot. 25:79-82. 

Hamill, J. E., Dickson, D. W., T-Ou, L., Allen, L. H., Burelle, N. K. and Mendes, M. L. (2004). Reduced 

rates of MBR and C35 under LDPE and VIF for control of soil pests and pathogens. In: 

Annual International Research Conference on Methyl Bromide Alternatives and Emissions 

Reductions 31 October - 3 November, 2004, Orlando, Florida, USA, pp. 2-1. 

Hanson, B., J. Gerik and S. Schneider (2006). Evaluation of reduced Methyl Bromide rates and alternative 

fumigants in field grown perennial crop nurseries. In: Annual International Research 

Conference on Methyl Bromide Alternatives and Emissions Reductions, Orlando, Florida, 

USA, 2006. 

Hausbeck, M. and B. Cortright (2007). Managing melon soil-borne pathogens in Michigan with MBR 

alternatives. Annual International Research Conference on Methyl Bromide Alternatives and 

Emission Reductions. October 29- November 1, 2007. San Diego, California. 

Kabir et al. (2005). Alternatives to MB for strawberry runner plant production. HortScience 40:1709-1715. 

Kokalis-Burelle, N.; Rosskopf, E. N.; Albamo, J. P.; Holzinger, J. (2010). Effects of Midas on nematodes in 

commercial floriculture production in Florida, Journal of Nematology 42(1):17–21. 

Kubota, C. (2008). Use of grafted seedlings for vegetable production in North America .Acta Horticulturae

770, pp. 21-28. 

Louws, F. (2009). Grafting tomato with interspecific rootstocks provides effective management for southern 

blight and root knot nematodes. Annual International Research Conference on Methyl 

Bromide Alternatives and Emissions Reduction , Nov 10 – 13, San Diego, CA , 40 

Macrae, A., Culpepper A. S., Batts R., Lewis K. (2008). Seeded Watermelon and Weed Response to 

Halosulfuron Applied Preemergence and Postemergence. Weed Technology: January 2008, 

Vol. 22, No. 1, pp. 86-90. 

MBTOC, (2007). 2006 Assessment Report of the Methyl Bromide Technical Options Committee. UNEP, 

Nairobi 482 pp. 

McSorley, R., K.H. Wang and N. Kokallis-Burelle, (2006a). Solarization as an alternative to Methyl Bromide 

in Florida floriculture. In: Annual International Research Conference on Methyl Bromide 

Alternatives and Emissions Reductions, November 6-9, 2006 Orlando, Florida, USA-337. 

2004. 

McSorley, R., K-H. Wang and S.K. Saha, (2006b). Can solarization match methyl bromide fumigation in sites 

colonized by fungi? Phytopathology 96(6), suppl., p. S187. 

McSorley, R., Koon-Hui Wang and E.N. Rosskopf (2008). Methyl Bromide alternatives for floriculture 

production in a problem site. In: Annual International Research Conference on Methyl 

Bromide Alternatives and Emissions Reductions, Orlando, Florida, November 11 – 14, 2008. 

Melgarejo, P., A. De Cal, T. Salto, M. L. Martínez-Beringola, A. Martínez-Treceno, E. Bardon, J. Palacios, M. 

Becerril, J.J. Medina, J., Gálvez and J.M. López-Aranda, (2001). Three Years of Results on 

Chemical Alternatives To Methyl Bromide For Strawberry Nurseries in Spain. Annual 

International Research Conference on Methyl Bromide Alternatives and Emissions Reduction 

2001. 5-9 November, 2001, San Diego, California, USA pp. 93-1. 

Noling, J.W., J.P. Gilreath and D.A. Botts. (2006). Chapter 23. Alternatives to methyl bromide soil 

fumigation for Florida vegetable production. In: Olson, SM. et al. 2006. Vegetable Production 

Handbook for Florida. University of Florida, Institute of Food and Agricultural Sciences 

(IFAS) Extension. 

Noling, J.W., J.P. Gilreath, D.A. Botts. (2006). Chapter 23. Alternatives to methyl bromide soil fumigation 

for Florida vegetable production. In: Olson, SM. et al. 2006. Vegetable Production Handbook 

for Florida. University of Florida, Institute of Food and Agricultural Sciences (IFAS) 

Extension. 
May 2011 TEAP Progress Report 191

Olsen, B. (2008). Midas soil fumigant. Proc. Annual Int. Res. Conf. on Methyl Bromide Alternatives and 

Emissions Reductions. Available on the web at 

http://mbao.org/2008/Proceedings/mbrpro08.html. 

Phillips, T.W,. Hasan, M.M., Aikens, M.J., Schilling, M.W. (2008). Efficacy of sulfuryl fluoride to control ham 

mites and red-legged ham beetles. Annual International Research Conference on Methyl 

Bromide Alternatives and Emission Reduction, Orlando, FL, November 11th-14th, USA. 

Phillips, T.W. (2009). Personal Communication. 

Porter, I.J., L. Trinder and D. Partington. (2006). Special Report Validating the Yield Performance of 

Alternatives to Methyl Bromide for Preplant fumigation. TEAP/MBTOC Special Report, 

UNEP Nairobi, May 2006 97pp. 

Rainbold, C.M., Hanson, B.; S.A. Fennimore, and J.S. Gerik, (2010). Steam disinfestation as a methyl 

bromide alternative in California cut flower nurseries. Proceedings of the annual international 

research conference on methyl bromide alternatives and emissions reductions. Orlando, 

Florida, November 2 – 5, 2010. 

Rosskopf, E.N., N. Kokalis-Burelle, D.M. Butler, J. Holzinger, S. Fennimore. (2010b). Evalution of steam 

for nematode and weed control in cut flower production in Florida. Proceedings of the 

Annual International Research Conference on Methyl Bromide Alternatives and Emissions 

Reductions. Orlando, Florida, November 2 – 5, 2010. 

Rosskopf, E.N., N. Kokalis-Burelle, E. Nissen, O. Nissen, R. Hartman, R. McSorley, E. Skvarch, T.J. 

Swaford, C. Owens, S. Brooks, and K. Register. (2010a). Evaluation of currently available 

alternatives to methyl bromide for ornamental crop production in Florida. Proceedings of the 

Annual International Research Conference on Methyl Bromide Alternatives and Emissions 

Reductions. Orlando, Florida, November 2 – 5, 2010. 

Santos, B.M., J.P. Gilreath, J.M. López-Aranda, L. Miranda, C. Soria, and J.J. Medina. (2007). Comparing 

Methyl Bromide alternatives for strawberry in Florida and Spain. Journal of Agronomy 6(1): 

225 – 227. 

Schneider, S., T. Trout, and H. Ajwa. (2005). Field Evaluations of Methyl Bromide Alternatives for Vineyard 

Replant. Annual International Research Conference on Methyl Bromide Alternatives. Pp 45:1-

6. 

Sekhon, R.K., Schilling, M.W., Phillips, Hasan, M.M., Aikens, M.J, Mikel, W.B. (2009). Chemical 

Composition of Dry Cured Hams Fumigated with Carbon Dioxide. Annual International 

Research Conference on Methyl Bromide Alternatives and Emission Reduction, San Diego, 

CA, November 10th-13th 

Sekhon, R.K., Schilling, M.W., Phillips, Hasan, M.M., Aikens, M.J, Mikel, W.B. (2009). Chemical composition 

of dry cured hams fumigated with phosphine. Annual International Research Conference on 

Methyl Bromide Alternatives and Emission Reduction, San Diego, CA, November 10th-13th 

Sekhon, R.K., Schilling, M.W., Phillips, T.W., Hasan, M.M., Aikens, M.J. Mikel, W.B. (2010a). Sulfuryl 

fluoride fumigation effects on the safety, volatile composition, and sensory quality of dry cured 

ham. Meat Science. 84(3):505-511. 

Sekhon, R.K., Schilling, M.W., Phillips, T.W., Hasan, M.M., Aikens, M.J., Nannapaneni, R., Mikel, W.B. 

(2010). Effects of carbon dioxide and ozone treatments on the volatile composition and 

sensory quality of dry cured ham. J. Food Science. 75(5):452-458. 

Sekhon, R.K., Schilling, M.W., Phillips, T.W., Hasan, M.M., Aikens, M.J., Corzo, A. Mikel, W.B. (2010). 

Effects of phosphine and methyl bromide fumigation on the volatile flavor profile and sensory 

quality of dry cured ham. Meat Science. 86(2):411-417. 

Sosnoskie, L.M., Davis A.L., and Culpepper, A.S. (2008); Response of Seeded and Transplanted Summer 

Squash to S-Metolachlor Applied at Planting and Postemergence; Weed Technology: April 

2008, Vol. 22, No. 2, pp. 253-256. 

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192 May 2011 TEAP Progress Report 

Thies, J.A., Ariss, J., Kousik, C.S., Hassell, R. (2008). Grafting - a tool for managing root-knot 

nematodes in watermelon? Phytopathology 98:S156.

Yates et al (2007). Film permeability measurements in support of USDA-ARS area wide research. Methyl 

Bromide Alternatives Organization conference. Orlando San Diego, November 2007

Yates, S, Papierknik S., Chellemi D, Wang D, Gao S, Hanson B, Ajwa H, Browne G, Kluepfel D. (2009). 

Update of film permeability measurements for USDA-ARS area-wide research project. In 

‘Annual International Research Conference on MB Alternatives and Emissions 

Reductions’Nov 10-13,San Diego, 2009.
May 2011 TEAP Progress Report 193

Chapter 8 - Common Acronyms 

1,3-D 1,3- Dichloropropene 

CUE Critical Use Exemption 

CUN Critical Use Nomination 

DOI Disclosure of Interest 

EPA Environmental Protection Agency 

EPPO European Plant Protection Organisation 

EU European Union 

MI Methyl iodide (or Iodomethane) 

IPM Integrated Pest Management 

IPPC International Plant Protection Convention 

ISPM International Standard Phytosanitary Measure 

LPBF Low Permeability Barrier Film (including VIF films) 

MB Methyl Bromide 

MBTOC Methyl Bromide Technical Options Committee 

MBTOC-SC Methyl Bromide Technical Options Committee Structures and

 Commodities Subcommittee 

MBTOC-S Methyl Bromide Technical Options Soils Subcommittee 

MBTOC-QPS Methyl Bromide Technical oprtions Quarantine and Preshipment

 Subcommittee 

MITC Methyl isothiocyanate 

MOP Meeting of the Parties 

MS Metham sodium 

OEWG Open Ended Working Group 

Pic Chloropicrin 

QPS Quarantine and Pre-shipment 

SF Sulfuryl fluoride 

TEAP Technology and Economic Assessment Panel 

TIF Totally impermeable films 

VIF Virtually Impermeable Film 
194 May 2011 TEAP Progress Report 

ANNEX 1 TO CHAPTER 8. Decision IX/6 

1. To apply the following criteria and procedure in assessing a critical methyl 

bromide use for the purposes of control measures in Article 2 of the Protocol: 

(a) That a use of methyl bromide should qualify as “critical” only if the nominating Party 

determines that: 

(i) The specific use is critical because the lack of availability of methyl bromide for 

that use would result in a significant market disruption; and 

(ii) There are no technically and economically feasible alternatives or substitutes 

available to the user that are acceptable from the standpoint of environment and 

health and are suitable to the crops and circumstances of the nomination; 

(b) That production and consumption, if any, of methyl bromide for critical uses should 

be permitted only if: 

(i) All technically and economically feasible steps have been taken to minimise the 

critical use and any associated emission of methyl bromide; 

(ii) Methyl bromide is not available in sufficient quantity and quality from existing 

stocks of banked or recycled methyl bromide, also bearing in mind the 

developing countries’ need for methyl bromide; 

(iii) It is demonstrated that an appropriate effort is being made to evaluate, 

commercialise and secure national regulatory approval of alternatives and 

substitutes, taking into consideration the circumstances of the particular 

nomination and the special needs of Article 5 Parties, including lack of financial 

and expert resources, institutional capacity, and information. Non-Article 5 

Parties must demonstrate that research programmes are in place to develop and 

deploy alternatives and substitutes. Article 5 Parties must demonstrate that 

feasible alternatives shall be adopted as soon as they are confirmed as suitable 

to the Party’s specific conditions and/or that they have applied to the 

Multilateral Fund or other sources for assistance in identifying, evaluating, 

adapting and demonstrating such options; 

2. To request the Technology and Economic Assessment Panel to review nominations 

and make recommendations based on the criteria established in paragraphs 1 (a) (ii) and 1 (b) 

of the present decision; 

3. That the present decision will apply to Parties operating under Article 5 and 

Parties not so operating only after the phase-out date applicable to those Parties. 

Para. 2 of Decision IX/6 does not assign TEAP the responsibility for determining the existence 

of “significant market disruption” specified in paragraph 1(a)(i). 

TEAP assigned its Methyl Bromide Technical Options Committee (MBTOC) to determine 

whether there are no technically and economically feasible alternatives or substitutes available 

to the user that are acceptable from the standpoint of environment and health and are suitable 

to the crops and circumstances of the nomination, and to address the criteria listed in Decision 

IX/6 1(b).
May 2011 TEAP Progress Report 195

ANNEX II TO CHAPTER 8. Decision XVI/4 

Review of the working procedures and terms of reference of the Methyl Bromide 

Technical Options Committee

Report of the Sixteenth Meeting of the Parties to the Montreal Protocol (Annex I), Prague, 22–26 

November 2004), paragraph 15. 

A. Working procedures of the Methyl Bromide Technical Options Committee relating 

to the evaluation of nominations for critical uses of methyl bromide 

15. An annual work plan will enhance the transparency of, and insight in, the operations 

of MBTOC. Such a plan should indicate, among other things: 

(a) Key events for a given year; 

(b) Envisaged meeting dates of MBTOC, including the stage in the nomination and 

evaluation process to which the respective meetings relate; 

(c) Tasks to be accomplished at each meeting, including appropriate delegation of 

such tasks; 

(d) Timing of interim and final reports; 

(e) Clear references to the timelines relating to nominations; 

(f) Information related to financial needs, while noting that financial 

considerations would still be reviewed solely in the context of the review of the 

Secretariat’s budget; 

(g) Changes in the composition of MBTOC, pursuant to the criteria for selection; 

(h) Summary report of MBTOC activities over the previous year, including matters 

that MBTOC did not manage to complete, the reasons for this and plans to 

address these unfinished matters; 

(i) Matrix with existing and needed skills and expertise; and 

(j) Any new or revised standards or presumptions that MBTOC seeks to apply in 

its future assessment of critical-use nominations, for approval by the Meeting 

of the Parties. 
196 May 2011 TEAP Progress Report 

ANNEX III TO CHAPTER 8 - Part A: Historical Trend in MB Preplant Soil Nominations and Exemptions List of nominated (2005 – 2012 in part) and exempted (2005 – 2011 in part) amounts of MB granted by Parties under the CUE p

commodity. 

Party Industry Total CUN MB Quantities Total CUE MB Quantities

2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Australia Almonds 1.900 2.100 1.900 2.100 Australia Rice 9.200 2.374 

consumer packs 

12.300 12.300 10.225 

1.8 

9.2 7.82 5.66 3.653 6.150 6.150 9.205 9.200 

Belgium Artefacts and 

structures 

0.600 0.307 0.590 0.307 

Belgium Antique 

structure & furniture 

0.750 0.199 0.319 0.199 

Belgium Churches, 

monuments and ships' quarters 

0.150 0.059 0.150 0.059 

Belgium Electronic 

equipment 

0.100 0.035 0.100 0.035 

Belgium Empty silo 0.050 0.043 0.050 0.043 Belgium Flour mill 

see mills below 

0.125 0.072 See 

mills below 

0.072 

Belgium Flour mills 10.000 4.170 9.515 4.170 Belgium Mills 0.200 0.200 0.200 0.200 Belgium Food 

processing facilities 

0.300 0.300 0.300 0.300 
May 2011 TEAP Progress Report 

Party Industry Total CUN MB Quantities Total CUE MB Quantities

2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Belgium Food 

Processing premises 

0.030 0.030 0.030 0.030 

Belgium Food storage 

(dry) structure 

0.120 0.120 0.120 0 

Belgium Old 

buildings 

7.000 0 .306 1.150 0.306 

Belgium Old 

buildings and objects 

0.450 0.282 0 0.282 

Belgium Woodworkin

g premises 

0.300 0.101 0.300 0.101 

Canada Flour mills 47.200 34.774 30.167 28.650 26.913 22.878 14.107 11.020 7.848 (a)47 34.774 30.167 28.65 Canada Pasta 

manufacturing facilities 

(a) 10.457 6.757 6.067 4.740 4.740 2.084 (a) 10.457 6.757 6.067 

Canada Commodities 0.068 France Seeds sold 

by PLANSPG company 

0.135 0.135 0.100 0.135 0.135 0.096 

France Mills 55.000 40.000 8.000 40.000 35.000 8.000 France Rice 

consumer packs 

2.000 2.000 2.000 2.000 

France Chestnuts 2.000 2.000 1.800 2.000 2.000 1.800 Germany Artefacts 0.250 0.100 0.250 0.100 
198 May 2011 TEAP Progress Report 

Party Industry Total CUN MB Quantities Total CUE MB Quantities

2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Germany Mills and 

Processors 

45.000 19.350 45.000 19.350 

Greece Dried fruit 4.280 3.081 0.900 4.280 3.081 0.450 Greece Mills and 

Processors 

23.000 16.000 1.340 23.000 15.445 1.340 

Greece Rice and legumes 2.355 2.355 Ireland Mills 0.888 0.611 0.888 Israel Artefacts 0.650 0.650 0.600 0.650 0.6500 Israel Dates (post 

harvest) 

3.444 3.444 2.200 1.800 2.100 3.444 2.755 2.200 1.800 

Israel Flour mills 

(machinery & storage) 

2.140 1.490 1.490 0.800 0.300 2.140 1.490 1.040 0.312 

Israel Furniture– 

imported 

1.4220 1.4220 2.0420 1.4220 0 

Italy Artefacts 5.500 5.500 5.000 5.225 0 5.000 Italy Mills and 

Processors 

160.000 130.000 25.000 160.00

0 

65.000 25.000 

Japan Chestnuts 7.100 6.500 6.500 6.300 5.800 5.400 5.350 3.489 3.317 7.100 6.800 6.500 6.300 Latvia Grains 2.502 2.502 Netherlands Strawberry runners post 

harvest 

0.120 0.120 0.120 0 0.120 

Poland Medicinal 

herbs & dried mushrooms as dry commodities 

4.000 3.560 1.800 0.500 4.100 3.560 1.800 1.800 

Poland Coffee, 

cocoa beans 

(a) 2.160 2.000 0.500 2.160 1.420 1.420 

Spain Rice 50.000 42.065 
May 2011 TEAP Progress Report 

Party Industry Total CUN MB Quantities Total CUE MB Quantities

2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Switzerland Mills & 

Processors 

8.700 7.000 8.700 7.000 

UK Aircraft 0.165 0.165 UK Mills and 

Processors 

47.130 10.195 4.509 47.130 10.195 4.509 

UK Cereal processing plants 8.131 3.480 (a) 8.131 UK Cheese 

stores 

1.640 1.248 1.248 1.640 1.248 1.248 

UK Dried 

commodities (rice, fruits and nuts) Whitworths 

 2.400 1.256 2.400 1.256 

UK Herbs and 

spices 

0.035 0.037 0.030 0.035 0.037 

UK Mills and 

Processors (biscuits) 

2.525 1.787 0.479 2.525 1.787 

UK Spices 

structural equip. 

1.728 1.728 0 0.479 

UK Spices stored 0.030 0.030 0 UK Structures 

buildings (herbs and spices) 

3.000 1.872 0.908 3.000 1.872 0.908 
200 May 2011 TEAP Progress Report 

Party Industry Total CUN MB Quantities Total CUE MB Quantities

2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

UK Structures, 

processors and storage (Whitworths) 

1.100 0.880 0.257 1.100 0.880 0.257 

UK Tobacco 

equipment 

0.523 0.050 

UK Woven 

baskets 

0.770 0.770 

USA Dried fruit 

and nuts (walnuts, pistachios, dried fruit and dates and dried beans) 

89.166 87.719 91.299 67.699 58.912 19.242 10.041 2.419 0.822 89.166 87.719 78.983 58.921 

USA Dry 

commodities/ structures (cocoa beans) 

61.519 61.519 64.028 52.256 51.002 61.519 55.367 64.082 53.188 

USA Dry 

commodities/ structures (processed foods, herbs and spices, dried milk and cheese processing facilities) NPMA 

83.344 83.344 85.801 72.693 66.777 37.778 17.365 0.200 83.344 69.118 82.771 69.208 
May 2011 TEAP Progress Report 

Party Industry Total CUN MB Quantities Total CUE MB Quantities

2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

USA Smokehouse 

hams (Dry cure pork products) (building and product) 

136.304 135.742 40.854 19.669 19.699 4.465 3.730 3.730 3.730 67.907 81.708 18.998 19.699 

USA Mills and 

Processors 

536.328 505.982 401.889 362.952 291.418 173.023 135.299 74.51 25.334 483.000 461.758 401.889 348.237 

USA Research 0.159 0.159 
202 May 2011 TEAP Progress Report 

ANNEX IV TO CHAPTER 8 – Part B: Historical Trend in MB Structural and Commodity Nominations and ExeList of nominated (2005 – 2012 in part) and exempted (2005 – 2011 in part) amounts of MB granted by Parties under the CUE p

commodity. 

Total CUN MB Quantities Total CUE Quantities Party Industry 2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Australia Cut Flowers – field 40.000 22.350 18.375 22.350 Australia Cut flowers – protected 20.000 10.425 Australia 

Cut flowers, bulbs – protected Vic 

7.000 7.000 6.170 6.150 7.000 7.000 3.598 3.500 

Australia Strawberry Fruit 90.000 67.000 Australia Strawberry 

runners 

35.750 37.500 35.750 35.750 29.790 29.790 29.790 29.790 29.760 35.750 37.500 35.750 35.75

Belgium Asparagus 0.630 0.225 0.630 0.225 Belgium Chicory 0.600 0.180 0.180 0.180 Belgium Chrysanthemums 1.800 0.720 1.120 Belgium Cucumber 0.610 0.545 0.610 0.545 Belgium Cut flowers – other 6.110 1.956 4.000 1.956 Belgium Cut flowers – roses 1.640 Belgium Endive (sep from lettuce) 1.650 1.650 Belgium Leek & onion seeds 1.220 0.155 0.660 
May 2011 TEAP Progress Report 

Total CUN MB Quantities Total CUE Quantities Party Industry 2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Belgium Lettuce(& endive) 42.250 22.425 25.190 Belgium Nursery Not Predictable 0.384 0.900 0.384 Belgium Orchard pome & berry 1.350 0.621 1.350 0.621 Belgium Ornamental plants 5.660 0.000 Belgium Pepper & egg plant 5.270 1.350 3.000 1.350 Belgium Strawberry runners 3.400 0.900 3.400 0.900 Belgium Tomato (protected) 17.170 4.500 5.700 4.500 Belgium Tree nursery 0.230 0.155 0.230 0.155 Canada Strawberry runners (PEI) 14.792 6.840 7.995 7.462 7.462 7.462 5.261 5.261 5.596 (a)14.792 6.840 7.995 7.462 Canada Strawberry runners (Quebec) 1.826 1.826 (a) 1.826 1.826 Canada Strawberry runners (Ontario) 6.129 6.129 France Carrots 10.000 8.000 5.000 8.000 8.000 1.400 France Cucumber 85 revised to 60 60.000 15.000 60.000 60.000 12.500 France Cut-flowers 75.000 60.250 12.000 60.000 52.000 9.600 France Forest tree 

nursery 

10.000 10.000 1.500 10.000 10.000 1.500 

France Melon 10.000 10.000 7.500 6.000 
204 May 2011 TEAP Progress Report 

Total CUN MB Quantities Total CUE Quantities Party Industry 2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

France 

Nursery: orchard, raspberry 

5.000 5.000 2.000 5.000 5.000 2.000 

France Orchard replant 25.000 25.000 7.500 25.000 25.000 7.000 France Pepper 

Incl in.tomato cun 

27.500 6.000 27.500 6.000 

France Strawberry fruit 90.000 86.000 34.000 90.000 86.000 France Strawberry 

runners 

40.000 4.000 35.000 40.000 40.000 28.000 

France 

Tomato (and eggplant for 2005 only) 

150(all solanaceous) 

60.500 33.250 125.000 48.400 

France Eggplant 27.500 33.250 48.400 Greece Cucurbits 30.000 19.200 30.000 19.200 Greece Cut flowers 14.000 6.000 14.000 6.000 Greece Tomatoes 180.000 73.600 156.000 73.600 Israel Broomrape 250.000 250.000 125.000 12.500 12.500 250.000 250.0Israel Cucumber - protected new 2007 25.000 18.750 18.750 12.500 25.000 18.75Israel Cut flowers – open field 77.000 67.000 80.755 53.345 42.777 42.554 23.292 77.000 67.000 74.540 44.75Israel Cut flowers – protected 303.000 303.000 321.330 163.400 113.821 72.266 52.955 303.000 240.000 220.185 114.4Israel Fruit tree nurseries 50.000 45.000 10.000 50.000 45.000 7.500 Israel Melon – protected & field 148.000 142.000 140.000 87.500 87.500 87.500 35.000 125.650 99.400 105.000 87.50
May 2011 TEAP Progress Report 

Total CUN MB Quantities Total CUE Quantities Party Industry 2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Israel Potato 239.000 231.000 137.500 93.750 75.000 239.000 165.000 137.500 93.75Israel Seed production 56.000 50.000 22.400 56.000 28.000 Israel Strawberries – fruit (Sharon) 196.000 196.000 176.200 64.125 52.250 47.500 28.500 196.000 196.000 93.000 105.9Israel 

Strawberries – fruit (Sharon & Ghaza) 

 

Israel Strawberry runners (Sharon) 35.000 35.000 20.000 15.800 13.570 13.500 35.000 35.000 28.000 31.90Israel 

Strawberry runners and fruit Ghaza 

 87.875 67.500 67.500 34.000 

Israel 

Strawberry runners (Sharon & Ghaza) 

 

Israel Tomatoes 90.000 22.750 Israel Sweet potato 95.000 20.000 20.000 111.5Italy Cut flowers (protected) 250.000 250.000 30.000 250.000 187.000 30.000 Italy Eggplant (protected) 280.000 200.000 15.000 194.000 156.000 Italy Melon (protected) 180.000 135.000 10.000 131.000 131.000 10.000 Italy Pepper (protected) 220.000 160.000 67.000 160.000 130.000 67.000 
206 May 2011 TEAP Progress Report 

Total CUN MB Quantities Total CUE Quantities Party Industry 2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Italy Strawberry Fruit (Protected) 510.000 400.000 35.000 407.000 320.000 Italy Strawberry Runners 100.000 120.000 35.000 120.000 120.000 35.000 Italy Tomato (protected) 1300.000 1030.00 418.000 871.000 697.000 80.000 Japan Cucumber 88.300 88.800 72.400 68.600 61.400 34.100 29.120 26.162 88.300 88.800 72.400 51.45Japan Ginger – field 119.400 119.400 112.200 112.100 102.200 53.400 47.450 42.235 119.400 119.400 109.701 84.07Japan Ginger – protected 22.900 22.900 14.800 14.800 12.900 8.300 7.770 6.558 22.900 22.900 14.471 11.10Japan Melon 194.100 203.900 182.200 182.200 168.000 90.800 77.600 67.936 194.100 203.900 182.200 136.6Japan Peppers (green and hot) 189.900 200.700 169.400 162.300 134.400 81.100 68.260 61.101 187.200 200.700 156.700 121.7Japan Watermelon 126.300 96.200 94.200 43.300 23.700 15.400 13.870 12.075 129.000 98.900 94.200 32.47Malta Cucumber 0.096 0.127 Malta Eggplant 0.128 0.170 Malta Strawberry 0.160 0.212 Malta Tomatoes 0.475 0.594 New Zealand Nursery material 1.085 1.085 0 New Zealand Strawberry fruit 42.000 42.000 24.78 42.000 34.000 12.000 New Zealand 

Strawberry runners 

10.000 10.000 5.720 8.000 8.000 6.234 

Poland Strawberry Runners 40.000 40.000 25.000 12.000 40.000 40.000 24.500 Portugal Cut flowers 130.000 8.750 50.000 8.750 
May 2011 TEAP Progress Report 

Total CUN MB Quantities Total CUE Quantities Party Industry 2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

Spain Cut Flowers – Cadiz 53.000 53.000 35.000 53.000 42.000 

17 15.000 43.490 

Spain Cut Flowers – Catalonia 20.000 18.600 12.840 (+Andaluci

a) 

20.000 (+Andaluci

a) 

Spain Pepper 200.000 155.000 45.000 200.000 155.000 45.000 Spain Strawberry Fruit 556.000 499.290 80.000 556.000 499.290 0.0796 Spain Strawberry Runners 230.000 230.000 230.000 215.000 230.000 230.000 230.000 UK Cut flowers 7.560 6.050 UK Ornamental tree 

nursery 

12.000 6.000 6.000 6.000 

UK 

Strawberry (& raspberry in 2005) 

80.000 63.600 68.000 54.500 

UK Raspberry 

nursery 

 4.400 4.400 54.500 

USA Chrys. Cuttings/roses 29.412 29.412 0 USA Cucurbits – field 1187.8 747.839 598.927 588.949 411.757 340.405 218.032 59.500 11.899 1187.800 747.839 592.891 486.7USA Eggplant – field 76.761 101.245 96.48 79.546 62.789 34.732 21.561 6.904 1.381 76.721 82.167 85.363 66.01USA Forest nursery seedlings 192.515 157.694 152.629 133.140 125.758 120.853 106.043 192.515 157.694 122.032 131.2USA Ginger 9.2 9.2 0 
208 May 2011 TEAP Progress Report 

Total CUN MB Quantities Total CUE Quantities Party Industry 2005 2006 2007 2008 2009 2010 2011 2012 2013 2005 2006 2007 2008 

USA Orchard replant 706.176 827.994 405.415 405.666 314.007 226.021 203.591 18.324 6.230 706.176 527.600 405.400 393.7USA Ornamentals 210.949 162.817 149.965 138.538 137.776 95.204 70.178 48.164 48.164 154.000 148.483 137.835 138.5USA 

Nursery stock - fruit trees, raspberries, roses 

45.789 64.528 12.684 51.102 27.663 17.954 7.955 1.591 0.541 45.800 64.528 28.275 51.10

USA Peppers – field 1094.782 1498.53 1151.751 919.006 783.821 463.282 212.775 28.366 1094.782 1243.542 1106.753 756.3USA Strawberry fruit – field 2468.873 1918.40 1733.901 1604.669 1336.754 1103.422 1023.471 753.974 531.737 2052.846 1730.828 1476.019 1349.USA Strawberry 

runners 

54.988 56.291 4.483 8.838 8.837 7.381 7.381 3.752 3.752 54.988 56.291 4.483 8.838 

USA Tomato – field 2876.046 2844.985 2334.047 1840.1 1406.484 994.582 336.191 54.423 10.741 737.584 2476.365 2065.246 1406.USA Turfgrass 352.194 131.600 78.040 52.189 0 131.600 78.04 0 USA Sweet potato 224.528 18.144 18.144 18.144 14.515 8.709 18.14USA Research 6.111 6.203 
May 2011 TEAP Progress Report 209

9 Response to Decision XXII/22 – Membership Changes on 

the Assessment Panels 

9.1 Executive Summary 

Decision XXII/22 requested TEAP to draw up guidelines for the nomination of experts by the 

Parties, and to consider the need for balance and appropriate expertise when appointing 

members to Technical Options Committees (TOCs), task forces and other temporary 

subsidiary technical bodies (TSBs) in accordance with the TEAP terms of reference (TOR). 

To address this task, TEAP set up a balanced task force (TF) of eight members, which 

included members of all TOCs plus two TEAP senior experts. 

The TF recommends that “balance” should be considered for Article 5 versus non-Article 5 

membership and also include the need for adequate regional distribution. TOC members are 

chosen by the TOC Co-chairs in consultation with TEAP. TOC Co-chairs are continually 

looking for new members to round out expertise and balance by adding, removing or altering 

membership as assessment needs change. Parties are one important source of nominations 

but are not the only source. TOC Co-chairs also look for qualified candidates through 

recommendations of existing TOC members, including those from other TOCs, of persons 

they have worked with in the recent past, professional and academic organizations, and 

others. 

TSB members are assigned by TEAP. In this regard they are similar to TOC members in that 

the Parties do not confirm appointment. However, unlike TOC members, it is possible that an 

assigned TSB Co-chair who was not a member of TEAP becomes a temporary member of 

TEAP. Task Force Co-chairs and other Temporary TEAP members are appointed to the 

TEAP by consensus, typically for one year or less. 

When anticipated recurring expertise is needed within TEAP that does not come from the 

TOC Co-chairs, the TEAP solicits nominations for additional expert members while staying 

within the Parties’ direction to maintain TEAP at 18 – 22 members. 

Currently, the TEAP and TOC call for experts is managed through updates of a simple matrix 

that is publicized through the Ozone Secretariat website and which is regularly updated by 

TEAP. The TF recognized that this matrix does not provide sufficient information on the 

nomination or selection process for new members so that Parties can make appropriate and 

timely nominations of needed expertise. 

The TF identified specific improvements to a Matrix of Needed Capabilities and Matrix of 

Current Capabilities, including harmonizing the current matrices used by TEAP and TOCs, as 

well as proposed timelines for regular review and updates of these matrices. If agreed to by 

the Parties, a searchable database for the TEAP website, TEAP/TOC Roster of Expertise, 

could be developed if financed and managed by the Ozone Secretariat. 

The TF further recommended that the TEAP consider creating a standard Nominations Form 

or at least standardize the nomination content to assist the Parties in collecting and providing 

the necessary information that TOC Co-chairs would use in making appointments, and which 

TEAP would use in recommending appointment for Parties’ consideration and confirmation. 

For this purpose, the TF compiled a list of relevant information that is needed for the 

preliminary assessment of a nomination and the Parties are requested to consider whether or 

not TEAP should develop a standard nomination form. 
210 May 2011 TEAP Progress Report 

9.2 Introduction 

9.2.1 Mandate and Scope of the Report 

Decision XXII/22 requested the Technology and Economic Assessment Panel (TEAP) and its 

Technical Options Committees (TOCs) to, 

 “...draw up guidelines for the nomination of experts by the parties, in accordance 

with section 2.9 of the terms of reference of the Technology and Economic 

Assessment Panel, for presentation to the parties prior to the thirty-first meeting of 

the Open-Ended Working Group;” 

and 

 “... to consider the need for balance and appropriate expertise when appointing 

members of the technical options committees, task forces and other subsidiary groups 

in accordance with sections 2.1, 2.5 and 2.8 of the terms of reference of the Panel;” 

The sections of the terms of reference of TEAP (found in Annex V of the report of the Eighth 

Meeting of the Parties, as amended by Decision XVIII/19, and included in the Handbook for 

the Montreal Protocol on Substances that Deplete the Ozone Layer (Eighth edition, 2009)) 

cited in the above decision are as follows: 

2.1 Size and Balance 

The membership size of the TEAP should be about 18-22 to allow it to function 

effectively. It should consist of the Co-chairs of the TEAP, the Co-chairs of all the 

TOCs and 4-6 Senior Experts for specific expertise or geographical balance not 

covered by the TEAP Co-chairs or TOC Co-chairs. Each TOC should have two 

or, if appropriate, three Co-chairs. The positions of TOC Co-chairs as well as of 

the Senior Experts must be filled to promote a geographical and expertise 

balance. The overall goal is to achieve a representation of about 50 per cent for 

Article 5(1) Parties in the TEAP and TOCs.

2.5 Appointment of Members of TOCs 

Each TOC should have about 20-35 members. The TOC members are appointed 

by the TOC Co-chairs in consultation with the TEAP.

2.8. Subsidiary Bodies 

Temporary Subsidiary Technical Bodies (TSBs) can be appointed by the 

TEAP/TOCs to report on specific issues of limited duration. The TEAP/TOCs 

may appoint and dissolve, subject to review by the Parties, such subsidiary 

bodies of technical experts when they are no longer necessary. The Code of 

Conduct must be followed by the members of TSBs to avoid conflict of interests in 

the performance of their duties. For issues which cannot be handled by the 

existing TOCs and are of substantial and continuing nature TEAP should request 

the establishment by the Parties of a new TOC.

2.9. Guidelines for Nominations 

The TEAP/TOCs will draw up guidelines for nominating experts by the Parties. 

The TEAP/TOCs will publicize a matrix of expertise available and the expertise 

gap in the TEAP/TOCs so as to facilitate submission of appropriate nominations 

by the Parties. 

 
May 2011 TEAP Progress Report 211

Based on the four paragraphs cited above, this report provides the following: 1) an overview 

and discussion of TEAP’s process to meet the need for balance in appointing members to 

TOCs and TSBs – the TEAP considered the appointment by Parties of members of TEAP 

beyond the scope of the request in Decision XXII/22 - and 2) guidelines for Parties for 

nominating experts to TEAP, TOCs and TSBs, along with a framework for an expanded 

matrix showing current and needed expertise, that is yet to be developed. 

9.2.2 Organization of Work 

In response to Decision XXII/22, TEAP set up a balanced task force (TF) of eight members, 

which included members of all TOCs plus two TEAP senior experts, as follows: 

Co-chairs 

Marta Pizano (A5) MBTOC (and TEAP Co-chair) 

Dan Verdonik HTOC (non-A5) 

Members

Paul Ashford FTOC (non-A5) 

Bella Maranion TEAP Senior Expert (non-A5) 

Roberto Peixoto RTOC (A5) 

Helen Tope MTOC (non-A5) 

Maasaki Yamabe CTOC (non-A5) 

Shiqiu Zhang TEAP Senior Expert (A5) 

Task Force work was conducted primarily by electronic communication. Drafts were then 

circulated to all TEAP members, and discussed and reviewed during the TEAP meeting held 

in Geneva, May 8-12, 2011. When addressing the assigned tasks, the TF considered the 

existing TEAP Terms of Reference (TOR), and supplemental information collected or 

developed by TEAP in its efforts to develop an internal standard operating procedure (SOP) 

over the past two years. 

9.3 On Size and Balance 

TOR paragraph 2.1 requires that TEAP has between 18 and 22 members. Currently (2011), 

the TEAP has 20 members: 3 TEAP Co-chairs, two of which are TOC Co-chairs and one that 

is a Senior Expert member; two additional Senior Expert members and 15 additional TOC 

Co-chairs. 

Decision XXII/22 requested TEAP to consider the need for balance and appropriate expertise 

when appointing members of TOCs, TF and other temporary subsidiary technical bodies 

(TSBs) in accordance with sections 2.1, 2.5 and 2.8 of the TEAP TOR. As Parties, not 

TEAP, must confirm the appointment of a member to TEAP, no discussion is included in this 

report on how TEAP balance is achieved. The exceptions to this are that both temporary TOC 

Co-chairs and TSB Co-chairs who if not already members of TEAP become temporary 

members of TEAP while they are TSB Co-chairs; and this specific case will be addressed in 

section 9.3.2 below. 

The TF recognizes that there are many different ways possible to represent the present 

balance of the TEAP and its TOCs. The TF discussed the different possibilities including 

whether or not to include gender in defining balance. The TEAP recommends that “balance” 

should be considered for Article 5 versus non-Article 5 and within that overall major balance, 

also a need for adequate regional distribution. The current representation of balance for 

TEAP and its TOCs is provided in Table 9-1. 
212 May 2011 TEAP Progress Report 

Table 9-1: Regional Distribution of TEAP and TOCs as of 2011 

Regional Distribution** 

 NonA5 A5 CEIT

* 

NAM SAM E AF MEA EE A O 

TEAP**

* 

 12 7 1 4 4 4 1 1 3 3 

TOCs 

CTOC 8 7 1 3 1 1 2 1 1 6 1 

FTOC 13 5 6 2 5 1 3 1 

HTOC 11 8 2 4 1 6 1 2 2 5 

MTOC 18 11 7 3 8 1 1 7 2 

MBTOC 24 15 1 8 4 11 4 2 1 5 3 

RTOC 18 7 5 3 13 1 3 

 TOC 

Total 

91 53 4 33 14 44 10 6 4 29 8 

* CEIT – Formerly known as Countries with Economies in Transition. 

** NAM: North America, SAM: South America, E: Europe, AF: Africa, MEA: Middle East Asia, EE: Eastern 

Europe, A: Asia, and O: Oceania 

*** TEAP Members (as of 2011): Co-chairs: Stephen O. Andersen, Lambert Kuijpers, 

Marta Pizano; Senior Expert Members: Bella Maranion, Shiqiu Zhang; TOC Co-chairs: 

CTOC: Ian Rae, Masaaki Yamabe, Jiang Biao; FTOC: Paul Ashford, Miguel Quintero; 

HTOC: Dave Catchpole, Sergey Kopylov; Daniel Verdonik; MTOC: Jose Pons, Helen 

Tope, Ashley Woodcock; MBTOC: Mohamed Besri, Michelle Marcotte, Marta Pizano, Ian 

Porter; RTOC: Lambert Kuijpers, Roberto Peixoto. 

9.3.1 Balance in the TOCs 

The TOCs members are chosen by the TOC Co-chairs in consultation with TEAP, per 

paragraph 2.5 of the TOR. TOC Co-chairs are continually reviewing the need for or looking 

for new members to round out expertise and balance. This can happen throughout the year, 

particularly when existing members retire from a TOC. More commonly this review of TOC 

membership balance is done at the completion of a TEAP progress report cycle or a report on 

a particular decision. At a broader level, the TOC Co-chairs look to refresh their TOC 

membership in preparation for an upcoming assessment, typically a four-year cycle, by 

adding, removing or altering required expertise, as assessment needs change. Throughout this 

process, the TOC Co-chairs are very mindful of balance between Article 5 and non-Article 5 

Parties and the need for geographic balance as well. 

TOC Co-chairs do not limit themselves in where they look for new members. Parties are an 

important source of nominations but are not the only source. TOC Co-chairs also look for 

qualified candidates through recommendations of existing TOC members, including those 

from other TOCs, recommendations from persons they have worked with in the recent past, 

professional and academic organizations, and others. In appointing new members, the TOC 

Co-chairs strive for balance while maintaining the technical expertise required in order to 

meet the needs of the Parties. 
May 2011 TEAP Progress Report 213

9.3.2 Balance and Membership in TSBs 

TSB members are appointed by TEAP. In this regard they are similar to TOC members in 

that the Parties do not confirm appointments. A TSB Co-chair who is not currently a member 

of TEAP becomes a temporary member of TEAP for the period of the TSB assignment. 

As with the TOC make-up, TEAP also considers balance for appointment of TSB members. 

For example, the membership of the Decision XXII/22 TF was assigned by the TEAP to have 

as balanced a membership as possible. The TF consists of three Article 5 members and five 

non-Article 5 members. There are two members from North America, two from South 

America, two from Asia, one from Europe and one from Oceania. Beyond this, the TEAP 

achieved, in this case, gender balance with four male and four female members. 

The appointment of TSB Co-chairs and members typically comes from within TEAP. 

When anticipated recurring expertise is needed within TEAP that is not currently 

available within its membership, TEAP solicits nominations for additional expert 

members while striving to maintain TEAP at 18 – 22 members. When the current 

TEAP membership does not have the expertise required for a one-time TSB, then the 

TEAP Co-chairs may recommend to the TEAP membership that a non-TEAP 

member may be assigned as a TSB Co-chair and hence becomes a temporary TEAP 

member. TEAP members will consider balance in appointing a temporary member 

and TSB Co-chair, however, the expertise required to meet the needs of the Parties is 

the deciding factor. Task Force Co-chairs and other Temporary TEAP members are 

appointed to the TEAP by consensus, typically for one year or less. 

9.4 Matrices of Gaps and Available Expertise 

9.4.1 Current Matrix of Needed Expertise 

Currently, the TEAP and TOC call for experts is managed through updates of a simple matrix 

that is publicized through the Ozone Secretariat website at 

http://ozone.unep.org/Assessment_Panels/TEAP/TEAP-Nominations.shtml. 

This matrix is updated regularly by TEAP. Table 9-2 is an update of the matrix that currently 

appears on the website. 
214 May 2011 TEAP Progress Report 

Table 9-2: TEAP current openings for qualified experts 

Body Required Expertise Position(s)

TEAP Senior Expert member with cross-cutting experience in 

engineering, economics, market transformation, and data 

analysis

Member

Methyl 

Bromide TOC

Quarantine and pre-shipment 

Certification of nursery plant materials related to movement 

of plant pathogens across state and international boundaries 

Risk, assessment 

International conventions (i.e. IPPC) 

Member from A5 

particularly for QPS

Halons TOC Aviation Fire Protection specialists 

Military 

Fire protection experts from Europe and A5

 Member

Foams TOC Experts in implementing HFC, HC and other alternatives to 

CFC and HCFC foam with knowledge of activities in 

Eastern Europe, Africa, South & Central Asia and the 

Middle East

Member

Refrigeration 

TOC

Experts in low-GWP alternatives to HCFC and HFC 

refrigeration and AC with knowledge of applications 

Non-A5 experts in transport and large sized refrigeration 

Experts from the Middle East region

 Member

Medical 

Products TOC

Experts not currently required.

Chemicals 

TOC

Experts in destruction technologies 

Experts in industrial chemistry or chemical engineering

Member 

Members from A5 

and non-A5

In addition to the above matrix of needed expertise, the TEAP page of the Ozone Secretariat 

website provides limited background information on TEAP, a brief overview of general 

qualifications and responsibilities of TEAP, TOC, and Task Force members, and directs 

interested Parties to contact the TEAP Co-chairs for further information. 

9.4.2 Update to Matrix of Needed Expertise 

The TF recognizes that the current matrix of expertise needed as presented on the Ozone 

Secretariat website, may not provide sufficient information so that Parties can make 

appropriate and timely nominations of experts. The current webpage also does not provide 

specific guidance on the nomination or selection process for new members. 

The TF believes the following information may be helpful to Parties in improving this matrix, 

and the present nomination and selection procedures for experts to TEAP and TOCs: 

3⁄4 More descriptive information on the required expertise may be needed for either a 

nominator or nominee to consider if the combination of education, work and related 

experience of the nominee would be a good fit for the TEAP or TOC position. 
May 2011 TEAP Progress Report 215

3⁄4 A more user-friendly website may be needed, with more background and practical 

information about TEAP or TOC membership. This information would be provided 

through links to documents that already exist such as the TEAP Terms of Reference. 

New documents could also be developed such as the following: TEAP Origin and 

Evolution, Description of TEAP Positions, Roles and Responsibilities (for positions 

of TEAP Co-chairs, TOC Co-chairs, Senior Expert Members, TOC and TSB 

Members), typical time commitments for members for meetings and reports, 

voluntary (unpaid) nature of the assignment (Article 5 travel and accommodation are 

funded by the Ozone Secretariat, but those of non-Article 5 members are not), and 

language requirement (meetings are conducted and reports are written in English). 

The TEAP/TOC Co-chairs will develop more detailed descriptions for each of the experts and 

expertise needed for which they are seeking nominations. Depending on the position and 

requirements of TEAP or the relevant TOC, certain academic qualifications, work experience, 

or skills may be preferred over others when nominees are evaluated. This “selection 

guidance” can be included in the detailed descriptions. 

9.4.3 Matrices of Current Capabilities 

Currently, TEAP and TOC have varying processes for tracking the expertise contained within 

each group’s membership. Tables 9-3, 9-4, and 9-5 provide examples of the current 

capabilities of members of TEAP, MBTOC’s QPS Subcommittee and CTOC, respectively. 
216 May 2011 TEAP Progress Report 

Table 9-3: Qualifications for 2011 TEAP members 

TEAP Member Highest 

Degree 

Degree 

Subjects 

Employment 

History 

Current 

Employment 

Stephen O. Andersen PhD Economics 

Agriculture 

Government 

University 

NGO 

Industry 

Consultant 

NGO 

Paul Ashford BSc Chemistry Industry Consultant 

Mohamed Besri PhD Plant Pathology Government 

University 

Agricultural 

Institute 

Biao Jiang PhD Chemistry Government 

Industry 

Chemical 

Institute 

David Catchpole BA 

(Hons) 

Mathematics Industry Consultant 

Sergey Kopylov PhD Chemistry 

Engineering 

Government 

Industry 

Fire Protection 

Institute 

Lambert Kuijpers PhD Physics Industry 

University 

University 

Bella Maranion BSc Biology, 

Electrical Engr 

Government Government 

Michelle Marcotte BA Home Economics, 

Food & Nutrition 

Education 

Association 

Industry 

Consultant 

Roberto de A. Peixoto PhD Mechanical 

Engineering 

University Technology 

Institute 

Marta Pizano MSc Plant Pathology Industry 

Trade Association 

Consultant 

Jose Pons Pons MSc Engineering Manufacturing 

industry 

Manufacturing 

Industry 

Ian Porter PhD Plant Pathology Government 

University 

Government 

Institute 

Miguel Quintero MSc Chemistry Industry 

University 

University 

Ian D. Rae PhD Chemistry University University 

Helen Tope PhD Chemistry Government Consultant 

Ashley Woodcock MD Medicine Medicine Hospital 

Daniel Verdonik Eng.Sc.

D 

Chemical 

Metallurgy 

Government 

Industry 

Consultant 

Masaaki Yamabe MSc Chemistry Industry 

Government 

National 

Institute 

Shiqiu Zhang PhD Economics University University 
May 2011 TEAP Progress Report 217

Table 9-4: Example 1 - MBTOC QPS subcommittee Members - October 2010 

Name Gender Affiliation Expertise Length of 

service 

Country A5/non 

A5 

status 

Co-chair

1. Marta 

Pizano 

F Consultant MB alternatives, 

particularly 

horticulture (preplant soils uses) 

(MSc) 

> 10 years Colombia A5 

Members 

2. Jonathan 

Banks 

M Consultant QPS, stored grains, 

fumigation 

technologies, 

recapture systems 

(PhD) 

>10 years Australia Non A5 

3. Tom 

Batchelor 

M Touchdown 

Consulting 

Technical issues on 

QPS (PhD) 

1-5 years 

or >10 

years* 

Belgium Non A5 

4. Ken 

Glassey 

M MAF, New 

Zealand 

(Government 

research) 

Phytosanitary 

quarantine 

treatments, 

biosecurity 

1-5 years New 

Zealand 

Non A5 

5. Takashi 

Misumi 

M MAFF 

(Government 

research) 

Quarantine 

Disinfestation 

Technologies 

5- 10 

years 

Japan Non A5 

6. David 

Okioga 

M Kenya Ozone 

Office 

(Government) 

Plant quarantine 

services, MB alts 

(PhD) 

>10 years Kenya A5 

7. Ian Porter M Consultant and 

Department of 

Victorian 

Primary 

Industries 

(Government) 

Researcher, soils MB 

use and alts, 

particularly fungal 

pathogens and IPM 

(PhD) 

>10 years Australia Non-A5 

8. Ken Vick M Consultant Research in MB 

alternatives, for soil, 

structures and 

commodities 

including QPS. 

Entomologist (PhD) 

>10 years USA Non A5 

9. Eduardo 

Willink 

M Estación 

Experimental 

Agroindustrial 

Obispo 

Colombrés 

(Government 

research) 

Quarantine 

treatments, systems 

approach and pest 

host status 

1-5 years Argentina A5 

TOTALS F 1 

M 8 

 A5 = 3 

Non A5 

= 6 

Source: MBTOC CUN Final report Sept 2010 

*Dr Batchelor was a member of MBTOC between 1992 and 2002. He was appointed to MBTOC again in 2009 
218 May 2011 TEAP Progress Report 

Table 9-5: Example 2 - The expertise required for the CTOC members 

Chemistry Chemical 

Engineering 

Experience on 

Industry / 

Government 

Experience 

on regulation 

Knowledge / 

Experience on 

International 

Organization 

Process Agent Essential Essential Essential Not Relevant Not Relevant 

Lab. & 

Analytical 

uses 

Essential Desirable Desirable Essential Essential 

Feedstock Essential Essential Essential Not Relevant Not Relevant 

EUN Essential Essential Essential Essential Desirable 

CTC Essential Essential Essential Desirable Desirable 

Solv./ n-PB Essential Essential Essential Essential Not Relevant 

Destruction Essential Essential Essential Essential Desirable 

9.4.4 Updated Matrix of Current Capabilities 

The TF believes that it would be helpful to standardize and improve the differing matrices 

listing current capabilities. The information on current and historical TEAP/TOC experts and 

expertise, based on information TEAP has already compiled, could be made into a searchable 

database, such as a TEAP/TOC Roster of Expertise. This would be a complex task that would 

need to be significantly aided by the Ozone Secretariat, which has the means and resources to 

do so. The database would be searchable by one or a combination of different search fields 

(e.g., degrees and fields of study and/or experience, ODS sector, regional experience (e.g., 

A5, or specific regionssuch as Asia or Africa), government / military / industry / academia 

affiliations, years of experience, years of TEAP/TOC affiliation, relevant publications, etc.). 

This would require standardizing information reported by TEAP/TOC members so that their 

expertise could be compiled into this database. Again, if the Parties consider this to be a good 

option, TEAP would need financial and management assistance from the Ozone Secretariat to 

complete this task. 

9.5 Guidelines for Nominations 

9.5.1 TEAP Expert Members. 

The TEAP is limited by the TOR to 18 – 22 members. When the TEAP has less than 22 

members, the TEAP can include the additional expertise that would benefit the Parties in the 

Matrix of Required Capabilities. If the vacancy is the result of losing one or more TEAP 

Expert members, TEAP can also update the Matrix of Current Capabilities. These updates 

can be made on an annual basis and will be included in the TEAP progress report beginning 

in 2012. This timing would allow Parties to make nominations, coordinate with TEAP at the 

OEWG and/or MOP and confirm new TEAP members per the TOR. 

9.5.2 Co-chairs of TOCs 

The TOR indicates that TOCs should have 2 or sometimes 3 Co-chairs. Parties nominate and 

appoint TOC Co-chairs, according to TEAP TOR paragraph 2.3. When a TOC needs one or 

more Co-chairs, the TOC will notify the TEAP, who will include the needs in the Matrix of 
May 2011 TEAP Progress Report 219

Required Capabilities. If the vacancy is the result of losing one or more TOC Co-chairs, the 

TEAP will also update the Matrix of Current Capabilities. This can be done on an annual 

basis and will be included in the TEAP progress report beginning in 2012. This timing will 

allow Parties to make nominations, coordinate with TEAP at the OEWG and/or MOP and 

confirm new TEAP members per the TOR. 

9.5.3 TOC Members 

The TOC Co-chairs appoint TOC members in coordination with TEAP. When a TOC needs 

additional expertise, TOC Co-chairs, in coordination with TEAP, and the Ozone Secretariat as 

necessary, can update the Matrix of Required Capabilities. It is typical that this would follow 

the same general timeframe as for TEAP needs but since the TOC collectively have many 

more members, the need to replace retiring members can happen at any time during the year. 

The TOC Co-chairs can review and update, if needed, the Matrix of Required Capabilities 

and the Matrix of Current Capabilities on semi-annual July 1 and January 1 basis, at least, 

beginning in 2012. 

In preparation for Assessment Reports, some TOCs may choose to refresh or restructure their 

TOCs and potentially could ask significant numbers or even all of its members to retire 

essentially dissolving their TOC and then reforming the TOC to maximize flexibility in 

achieving the required expertise and overall balance. Other TOCs may have much reduced 

needs to dissolve TOCs and may ask selected members to retire. The decision remains with 

the TOC Co-chairs who, in coordination with TEAP, and the Ozone Secretariat as needed, 

will update the Matrix of Required Capabilities and the Matrix of Current Capabilities based 

on their decisions on the level of TOC renewal, turnover and continuity. In this case, the 

matrices will be updated no later than July 1st of the year before the Assessment Report is to 

be completed (e.g., July 1st 2013 if the Assessment will be completed by end 2014.) 

9.5.4 Nomination Information 

The TEAP and its TF recommended creating a standard Nominations Form or at least 

standardizing the nomination content, to assist the Parties in collecting and providing the 

necessary information about nominees that TOC Co-chairs would use in making 

appointments of TOC members. The TF compiled the following list of relevant information 

that is needed for the preliminary assessment of a nomination independent of whether or not 

the Parties would like TEAP to develop a standard nomination form. 

3⁄4 Cover letter. The nomination should explain how the nominee’s experience, 

qualifications and competence match the position for which you are seeking to be 

nominated. 

3⁄4 Formal education and other qualifications. An advanced academic degree is desirable 

but not necessary when a combination of experience and specialization may offer 

sufficient qualification. 

3⁄4 Employment and other relevant work experience as an expert. This would include 

Montreal Protocol experience, for example positions held and products developed, 

and where; policy and regulatory experience on a national or international level; 

academic, government, consultancy or industry experience related to ODS phase-out 

which could relate to a specific region; direct experience with ODS transition in 

sectors of use, including evaluation of alternatives and their commercial adoption by 

previous ODS users, design and/or manufacturing of equipment using ODS 

alternatives, international experience and description of any work performed in an 

international group/environment; experience in a multidisciplinary environment, 

preferably but not necessarily in an international context; communication skills based 
220 May 2011 TEAP Progress Report 

on teaching experience, public presentations, active participation in meetings, 

publications, preparation of reports. 

3⁄4 Past performance conducting similar or related work. This criterion seeks to 

evaluate, when possible, the applicant’s ability to successfully complete and/or 

manage similar work. For example, the applicant’s ability to prepare a report, and/or 

participate on a committee, work to manage diverse and opposing views, resolve 

conflict, and meet deadlines. Information provided by the applicant and also relevant 

information from other sources will be considered. 

3⁄4 English Language Proficiency: Good command of the English language is required. 

The TEAP and its TOCs work and write only in English as per TEAP TOR paragraph 

3.1. Nominees and their nominators need to consider the ability of any potential 

nominee to converse in English on both technical and programmatic issues. 

3⁄4 Relevant professional references. This may include, for example, recommendations 

by colleagues or peers, or performance when working with implementing agencies 

and others. 

3⁄4 Relevant publications. These may include those that support the applicant’s 

experience and / or qualifications.

Additional information or qualifications that would aid the selection process include but are 

not limited to: 

3⁄4 Professional memberships and / or awards

3⁄4 The country and / or world region (i.e., Africa, Latin America) where the nominee is 

situated or has experience. 

3⁄4 Source of funding or support for position. Article 5 candidates receive funding for 

travel and accommodation from the Ozone Secretariat, but non-Article 5 members do 

not. Lack of funding can make participation difficult or even impossible. 

The workload on TEAP and TOCs can be extensive. TEAP members are expected to 

participate in at least three meetings per year: TEAP meeting, the Open-ende Working Group 

(OEWG) and the Meeting of the Parties (MOP). TEAP members that are TOC Co-chairs 

would typically have one or more TOC meetings per year depending up workload for an 

Assessment year and /or the need to make recommendations on Essential Use Nominations or 

Critical Use Nominations. Members from Article 5 Parties have their travel funded by the 

Ozone Secretariat. 

In addition to the travel requirements, there is also extensive workload in between meetings. 

This is especially the case during the months before completing reports, which are due 

annually 6 weeks before the OEWG and at the end of an Assessment year. The need to 

participate in TFs or other TSBs adds further to this workload. 

9.6 Summary and Findings 

To respond to Decision XXII/22, TEAP convened a TF to review the existing information and 

processes for nominations of experts by Parties and to review how balance and appropriate 

expertise is realized within the TOCs, TFs, and other TSBs. The findings of the TF are 

summarized below: 

3⁄4 The TF identified the need for TEAP/TOC Co-chairs to develop more detailed 

descriptions for each of the experts and expertise required for which they are seeking 

nominations for members; 
May 2011 TEAP Progress Report 221

3⁄4 The TF recognized that there are many different ways possible to represent the 

present balance of the TEAP and its TOCs, including whether or not to include 

gender in defining balance. When considering balance, the TEAP recommends that 

“balance” should be considered for Article 5 versus non-Article 5 and within that 

overall major balance, the need for adequate regional distribution as well. 

3⁄4 The TF identified specific improvements to a Matrix of Needed Capabilities and a 

Matrix of Current Capabilities, including harmonizing the current matrices used by 

TEAP and TOCs, as well as proposed timelines for the regular review and updates of 

these matrices 

3⁄4 If agreed to by the Parties, a searchable database for the TEAP website, TEAP/TOC 

Roster of Expertise, could be developed if financed and managed by the Ozone 

Secretariat 

3⁄4 The TF recommended that the TEAP consider creating a standard Nominations Form 

or at least standardizing the nomination content to assist the Parties in collecting and 

providing the necessary information that TOC Co-chairs would use in making 

appointments, and which TEAP would use in recommending appointment for Parties’ 

consideration and confirmation. 

The TF compiled a list of relevant information that is needed for the preliminary assessment 

of a nomination and the Parties are requested to consider whether or not TEAP should 

develop a standard nomination form. 

May 2011 TEAP Progress Report 223

10 TEAP Operating Procedures 

TEAP actions to improve its procedures on disclosure of interest, recusal of members, and 

minority views. 

In the first 20 years of TEAP, TOC, and Temporary Subsidiary Bodies (TSBs) operation 

(1989 through 2009), there were fewer than five minority statements, with a total of three 

minority reports – two from MBTOC members and one from a TEAP member. An additional 

minority report was submitted by a MBTOC member in the 2010 TEAP Progress Report. In 

the 2011 TEAP Progress Report there were three formal minority reports from MBTOC 

members. In addition, minority views were reported in the 2010 FTOC Assessment Report. 

The minority views reported by FTOC in its 2010 Assessment (published in May 2011) 

involved the use of methyl formate as a foam blowing agent. The technical and economic 

performance of methyl formate foam was also the subject of correspondence to UNDP cosigned as from the Global Fluorocarbon Producers Forum (GFPF) Issues Managers 

Committee and the European Diisocyanate & Polyol Producers Association (ISOPA). The 

connection to TEAP is that the expert writing the UNDP report was a member of the FTOC 

and among those with minority views on methyl formate in the 2010 FTOC Assessment 

Report. 

In response to the three MBTOC minority reports, the minority FTOC views on methyl 

formate in the FTOC report, and the GFPA/ISOPA correspondence TEAP took the following 

actions: 

1. Confirmed that GFPA/ISOPA was mistaken in suggesting that the FTOC had 

commented as a body on the UNDP report on methyl formate, although a few FTOC 

members, acting in their own capacity and not representing the FTOC, had 

commented; 

2. Co-ordinated with the Ozone Secretariat in reiterating to TEAP members that work 

instructions come only from the TEAP terms of reference and periodic Decisions of 

Parties (and do not come from the MLF Executive Committee or staff, Implementing 

Agencies, or other bodies); 

3. Requested the MBTOC to explain the sequence of events and complications leading 

to minority reports and to suggest any changes in future TEAP operating procedures; 

4. Requested the FTOC to explain the sequence of events and complications leading to 

minority views and to suggest any changes in future TEAP operating procedures; 

5. With the Ozone Secretariat, TEAP will review reports of the MBTOC and FTOC and 

take any additional steps, as necessary; 

6. Instructed the FTOC Co-Chairs to request the resignation of any members that 

violated TEAP Terms of Reference in circulating confidential draft reports or who 

disclosed internal deliberations of the FTOC and to report back to TEAP and the 

Ozone Secretariat; 

7. Instructed TEAP members to redouble efforts to update and assure completeness of 

disclosures of interest and requested the Ozone Secretariat to improve the UNEP 

Ozone Secretariat Website to track the date of postings; 

8. Asked the MBTOC to organize its 2012 MBTOC meeting agenda to allow members 

of each subcommittee to attend discussions on each topic necessary to contribute to 

an informed decision and to consider other strategies to support achieving consensus 

on CUEs and other important topics; 
224 May 2011 TEAP Progress Report 

9. Developed guidelines on recusal when a TEAP/TOC member has a direct interest in 

the outcome, particularly in cases of Essential Use Nominations EUNs, Critical Use 

Nominations (CUNs), Process Agents Review, and specification of technical 

performance; and 

10. Developed guidelines on the importance of consensus and, where appropriate, on how 

to properly include minority views. 
May 2011 TEAP Progress Report 225

11 TEAP Guidelines on Recusal 

These guidelines apply to all members of the Technology and Economic Assessment Panel 

(TEAP) and its Subsidiary and Temporary Subsidiary Bodies (including Technical Options 

Committees (TOCs) & Task Forces. 

Members’ Interests

TEAP, TOC, and TSB Expert Members’ Interests 

Financial Interests: 

Working for a government, company, or environmental non-governmental 

organization (NGO) with financial interest in the outcome of TEAP reports or 

recommendations 

Ownership, intellectual property, or investment in enterprises profiting from 

ODSs or their alternatives and substitutes 

Private Enterprise Interests 

Research grants or operating grants directly related to actions of the Montreal 

Protocol, including environmental NGOs, universities, and standards 

organizations receiving funding to support action under the Montreal 

Protocol 

Professional Interests: 

Rewards from participation in global efforts to protect ozone & climate, early 

knowledge of next-generation technology, inside information on treaty and 

regulatory incentives, and the opportunity to work with other experts most 

involved in new technology 

Not All Interests are a Conflict with the Montreal Protocol 

It is the interest of Parties to have the experts most involved in ODS-free and low-GWP 

technology as members of TEAP, TOCs, and TSBs. Therefore, disclosing interests in 

compliance with the TEAP TOR does not in itself indicate an actual Conflict of Interest. 

Members and co-chairs of TEAP, TOCs and subsidiary bodies seek to avoid the appearance 

of conflicts of interest by recusal in topics, discussions, and deliberations where there is a 

direct financial interest or significant private enterprise or professional interest that may 

unduly influence participation. 

Disclosure of Interests 

TEAP, TOC, and TSB members are required to disclose any interest that may be seen as 

influencing their actions, including, but are not limited to, the following: 

• Part time, full time, or contract employment for the Party nominating Critical or 

Essential Uses, 

• Paid or unpaid advice to the Party or affected companies on Critical or Essential Use 

nominations, 
226 May 2011 TEAP Progress Report 

• Part time, full time or contracted employment for a company, industry association, 

or other business, or environmental, consumer or other NGO that has a professional, 

institutional or financial interest in the outcome of the TEAP, TOC, and TSB 

findings, 

• Part time, full time or contracted employment for a government or government 

agency or institution that has an interest in the outcome of the deliberations, 

• Immediate family financial interests including stocks, grants, salary, contractual / 

working arrangement, travel re-imbursement, promises of employment or any other 

situation of value, 

• Personal and/or professional interest affected by TEAP/TOC/TSB outcomes 

(reputation of the member, immediate family, employer, or financer), 

• Income or contract funding from the Multilateral Fund or its implementing agencies, 

and 

• Direct or indirect assistance to others seeking MLF funding, including paid or unpaid 

employment as an independent assessor, reviewer, or advisor. 

Recusal Guidelines 

Recusal can be defined as “to disqualify from specific participation for good reason.” 

The purpose of recusal is to avoid the appearance or consequences of a conflict of interest. 

Interests subject to recusal include: 

Financial interest (if outcome impacts profit, wage, dividend, bonus, promotion, etc.), 

Political Advocacy interest (if member instructed or rewarded for outcome), 

Other consumer-, environmental-, or industry-NGO Advocacy Interest (if member 

instructed or rewarded for outcome, or NGO (consumer, environmental, or industry) 

benefits professionally, institutionally, or financially from the outcome). 

Interests that are not subject to recusal if no direct financial interest include: 

 Professional ethics and codes of conduct (e.g. Hippocratic Oath) 

 Rights of free speech and professional judgment 

Appearance of a conflict of interest occurs when a member or immediate family member has 

a direct financial or other interest in the outcome of a decision or finding, or the member’s or 

immediate family member’s employer, consumer, environmental, or industry NGO affiliation 

has an interest (financial or otherwise) in the outcome of a decision or finding, and an 

interested party would have good reason to question the objectivity and fairness of their 

involvement. 

Recusal is only necessary for actions such as those listed below that have direct financial or 

other impact for the member or the organization that the member is affiliated with. 
May 2011 TEAP Progress Report 227

The TEAP/TOC actions with likely impact on direct financial or other interests include: 

9 Process Agent and Feedstock declaration 

9 Listing of approved Destruction Technology 

9 Essential Use Exemption (EUE) 

9 Critical Use Exemption (CUE) 

9 Finding on the technical performance & market potential of technology subject to 

intellectual property rights 

Self-Recusal: 

When the member believes there may be the appearance of a conflict of interest and 

prefers not to participate in decision-making. 

Self-recusal can be reconsidered and withdrawn, at which time the member can fully 

participate. 

Request for Recusal by Co-Chairs: 

TEAP and TOC Co-Chairs can request recusal of members by consensus or simple majority. 

1. If there is no-degree of separation from applicant interest: the recused member 

can answer questions, cannot participate in discussions and cannot participate in 

consensus or ballot findings and recommendations. 

Examples of no-degree of separation: 

o Is employed by an applicant: 

 Holds a position of responsibility, 

 Involved or consults in the application for an exemption, 

 Will implement the outcome of the decision, such as for essential or 

critical uses, or 

 Process or product is under member’s direct control, ownership, or 

marketing; 

o Provided advice, for personal or professional gain (financial, commercial, 

political, etc.), to an applicant on the application within the last 4 years; 

o Has a current financial interest, e.g. shares or bonds under the direct control 

of the member, in a commercial entity with an interest in the outcome; 

o Participated in the preparation of the application as part of duties for a third 

party with an interest in the outcome; 

o Employment affected by TEAP/TOC findings or recommendations 

2. If there is no degree of separation from competitive interest: the recused member

can answer questions, cannot participate in discussions and cannot participate in 

consensus or ballot findings and recommendations. 

Examples of no-degree of separation: 

o Has a financial interest in the denial or approval of the application; 

o Works for a commercial entity that stands to benefit by denial or approval; 

o Has current proprietary interest in a substance, technology or process (e.g. 

ownership of a patent) subject to the application; 

o Works for a consumer, environmental, or industrial NGO that stands to 

benefit financially, professionally, or politically by denial or approval. 
228 May 2011 TEAP Progress Report 

3. If there is one degree of separation from the applicant: the recused member can

answer questions, can participate in discussion, but cannot participate in 

consensus or ballot findings and recommendations. 

Examples of one-degree of separation: 

o Application developed by someone who has influence over (financial, 

political, professional etc.) the TEAP/TOC member or someone who reports 

to the member; 

o Organization preparing the application also sponsors the member’s travel. 

4. If there is one degree of separation from interest of a Party: the recused member 

can answer questions, can participate in discussions, but cannot participate in 

consensus or ballot findings and recommendations. 

o Works for, advises, or receives financial assistance from the competent 

authority forwarding the application and was substantially associated with the 

processing of the application; 

o Manages or conducts research directly related to the specific proposed critical 

or essential use (on either the proposed use or an alternative) that is funded by 

organizations with an interest in the application. 

In any case of recusal by self or chairs, all other members of the relevant body (TEAP and/or 

TOC) must immediately disclose any financial or other interest in the topic of the recusal. 
May 2011 TEAP Progress Report 229

Annex TEAP TOC Membership List Status May 2011 

The disclosure of interest (DOI) of each member can be found on the Ozone Secretariat website 

at: http://ozone.unep.org/Assessment_Panels/TEAP/toc-members-disclosures.shtml. The 

disclosures are updated whenever necessary. 

Technology and Economic Assessment Panel (TEAP) 

Co-chairs Affiliation Country 

Stephen O. Andersen Institute for Governance and Sustainable Development USA 

Lambert Kuijpers Technical University Eindhoven Netherlands 

Marta Pizano Consultant Colombia 

Senior Expert Members Affiliation Country 

Bella Maranion U.S. EPA USA 

Shiqiu Zhang Center of Environmental Sciences, Peking University China 

TOC Chairs Affiliation Country 

Paul Ashford Caleb Management Services UK 

Mohamed Besri Institut Agronomique et Vétérinaire Hassan II Morocco 

Biao Jiang Shanghai Institute of Organic Chemistry China 

David Catchpole Petrotechnical Resources Alaska UK 

Sergey Kopylov All Russian Research Institute for Fire Protection Russian Federation 

Michelle Marcotte Marcotte Consulting LLC and Marcotte Consulting Inc Canada 

Roberto de A. Peixoto Maua Institute (IMT), Sao Paulo Brazil 

Jose Pons-Pons Spray Quimica Venezuela 

Ian Porter Department of Primary Industries Australia 

Miguel Quintero Consultant Colombia 

Ian D. Rae University of Melbourne Australia 

Helen Tope Energyinter Consultancy Australia 

Ashley Woodcock Wythenshawe Hospital Manchester UK 

Daniel Verdonik Hughes Associates USA 

Masaaki Yamabe National Inst. Advanced Industrial Science and Technology Japan 

TEAP Chemicals Technical Options Committee (CTOC)

Co-chairs Affiliation Country 

Biao Jiang Shanghai Institute of Organic Chemistry China 

Ian D. Rae University of Melbourne Australia 

Masaaki Yamabe National Inst. Advanced Industrial Science and Technology Japan 

 

Members Affiliation Country 

D. D. Arora The Energy and Research Institute India 

Steven Bernhardt Honeywell USA 

Olga Blinova Russian Scientific Center for Applied Chemistry Russia 

Jianxin Hu College of Environmental Sciences & Engineering, Peking 

University 

China 

Michael Kishimba University of Dar-es-Salaam Tanzania 

Abid Merchant Consultant USA 

Koichi Mizuno National Inst. Advanced Industrial Science and Technology Japan 

Keichi Ohnishi Asahi Glass Japan 

Claudia Paratori Coordinator Ozone Programme -CONAMA Chile 

Hans Porre Teijin Aramids Netherlands 

John Stemniski Consultant USA 

Fatemah Al-Shatti Kuwait Petroleum Corporation Kuwait 

Nee Sun Choong Kwet 

Yive (Robert) 

University of Mauritius Mauritius 
230 May 2011 TEAP Progress Report 

TEAP Flexible and Rigid Foams Technical Options Committee (FTOC) 

Co-chairs Affiliation Country 

Paul Ashford Caleb Management Services UK 

Miguel Quintero Consultant Colombia 

Members Affiliation Country 

Terry Arrmitt Hennecke UK 

Chris Bloom Dow USA 

Row Chowdhury Australia Urethane Systems Australia 

Kyoshi Hara JUFA Japan 

Mike Hayslett Maytag/AHAM USA 

Mike Jeffs Consultant UK

Candido Lomba ABRIPUR Brazil 

Yehia Lotfi Technocom Egypt 

Christoph Meurer Solvay Germany 

Francesca Pignagnoli Dow Europe Italy 

Ulrich Schmidt Haltermann Germany 

Enshang Sheng Huntsman Co China 

Helen Walter-Terrinoni DuPont USA 

Tom Werkema Arkema USA 

Dave Williams Honeywell USA 

Allen Zhang Owens Corning China 

TEAP Halons Technical Options Committee (HTOC) 

Co-chairs Affiliation Country 

David V. Catchpole Petrotechnical Resources Alaska UK 

Sergey Kopylov All Russian Research Institute for Fire Protection Russian Federation 

Daniel P. Verdonik Hughes Associates USA 

 

Members 

Tareq K. Al-Awad King Abdullah II Design & Development Bureau Jordan 

Jamal Alfuzaie Kuwait Fire Department Kuwait 

Seunghwan (Charles) Choi Hanju Chemical Co., Ltd. South Korea 

Michelle M. Collins Consultant- EECO International USA 

Salomon Gomez Tecnofuego Venezuela 

Andrew Greig Protection Projects Inc South Africa 

Zhou Kaixuan CAAC-AAD PR China 

H. S. Kaprwan Consultant – Retired India 

Nikolai Kopylov All Russian Research Institute for Fire Protection Russian Federation 

David Liddy United Kingdom Ministry of Defence UK 

John J. O’Sullivan Bureau Veriitas UK 

Emma Palumbo Safety Hi-tech srl Italy 

Erik Pedersen Consultant – World Bank Denmark 

Donald Thomson Mantoba Hydro & MOPIA Canada 

Caroline Vuillin European Aviation Safety Agency France 

Robert T. Wickham Consultant-Wickham Associates USA 

Mitsuru Yagi Nohmi Bosai Ltd & Fire and Environment Prot. Network Japan 

Yong Meng Wah Singapore Civil Defence Force Singapore 

 

Consulting Experts 

Thomas Cortina Halon Alternatives Research Corporation USA 

Matsuo Ishiyama Nohmi Bosai Ltd & Fire and Environment Prot. Network Japan 

Steve McCormick United States Army USA 

John G. Owens 3M Company USA 

Mark L. Robin DuPont USA 

Joseph A. Senecal Kidde-Fenwal USA 

Ronald S. Sheinson United States Naval Research Laboratory – Retired USA 

Ronald Sibley Defense Supply Center, Richmond USA 
May 2011 TEAP Progress Report 231

TEAP Medical Technical Options Committee (MTOC) 

Co-chairs Affiliation Country 

Jose Pons Pons Spray Quimica Venezuela 

Helen Tope Energy International Australia Australia 

Ashley Woodcock University Hospital of South Manchester UK 

Members Affiliation Country 

Emmanuel Addo-Yobo Kwame Nkrumah University of Science and Technology Ghana 

Paul Atkins Oriel Therapeutics Inc. USA 

Sidney Braman Rhode Island Hospital USA 

Nick Campbell Arkema SA France 

Hisbello Campos Centro de Referencia Prof. Helio Fraga, Ministry of Health Brazil 

Jorge Caneva Favaloro Foundation Argentina 

Christer Carling Private Consultant Sweden 

Guiliang Chen Shanghai Institute for Food and Drug Control China 

Davide Dalle Fusine Chiesi Farmaceutici Italy 

Charles Hancock Charles O. Hancock Associates USA 

Eamonn Hoxey Johnson & Johnson UK 

Javaid Khan The Aga Khan University Pakistan 

Katharine Knobil GlaxoSmithKline USA 

Suzanne Leung 3M USA 

Nasser Mazhari Sina Darou Laboratories Company Iran 

Gerald McDonnell STERIS UK 

Hideo Mori Private Consultant Japan 

Tunde Otulana Aerovance Inc. USA 

John Pritchard Philips Home Healthcare Solutions UK 

Rabbur Reza Beximco Pharmaceuticals Bangladesh 

Raj Singh The Chest Centre India 

Roland Stechert Boehringer Ingelheim Germany 

Ping Wang Chinese Pharmacopoeia Commission China 

Adam Wanner University of Miami USA 

Kristine Whorlow National Asthma Council Australia Australia 

You Yizhong Journal of Aerosol Communication China 
232 May 2011 TEAP Progress Report 

TEAP Methyl Bromide Technical Options Committee (MBTOC) 

Co-chairs Affiliation Country 

Mohamed Besri Institut Agronomique et Vétérinaire Hassan II Morocco 

Michelle Marcotte Marcotte Consulting Canada 

Marta Pizano Consultant –Hortitecnia Ltda Colombia 

Ian Porter Department of Primary Industries Australia 

 

Members Affiliation Country 

Jonathan Banks Consultant Australia 

Tom Batchelor Touchdown Consulting Belgium 

Chris Bell Consultant UK 

Antonio Bello Centro de Ciencias Medioambientales Spain 

Fred Bergwerff Eco2, Netherlands The Netherlands 

Aocheng Cao Chinese Academy of Agricultural Sciences China 

Peter Caulkins US Environmental Protection Agency USA 

Ricardo Deang Consultant Philippines 

Patrick Ducom Consultant France 

Abraham Gamliel Agricultural Research Organisation Israel 

Raquel Ghini EMBRAPA Brasil 

Ken Glassey MAFF - NZ New Zealand 

Eduardo Gonzalez Fumigator Philippines 

Darka Hamel Inst. For Plant Protection in Ag. And Forestry Croatia 

George Lazarovits A & L Biologicals Canada 

Andrea Minuto CERSAA, Albenga Italy 

Takashi Misumi MAFF - Japan Japan 

David Okioga Ministry of Environment and Natural Resources Kenya 

Christoph Reichmuth BBAGermany Germany 

Jordi Riudavets IRTA – Department of Plant Protection Spain 

John Sansone SCC Products USA 

Jim Schaub US Department of Agriculture USA 

Sally Schneider US Department of Agriculture USA 

JL Staphorst Plant Protection Research Institute South Africa 

Akio Tateya Japan Fumigation Technology Association Japan 

Robert Taylor Consultant UK 

Alejandro Valeiro Department of Agriculture Argentina 

Ken Vick Consultant USA 

Nick Vink University of Stellenbosch South Africa 

Janny Vos CABI International The Netherlands 

Chris Watson IGROX UK 

Jim Wells Environmental Solutions Group USA 

Eduardo Willink Ministerio de Agricultura Argentina 

Suat Yilmaz BATEM Horticulture Research Station Turkey 
May 2011 TEAP Progress Report 233

TEAP Refrigeration, Air Conditioning and Heat Pumps Technical Options Committee 

(RTOC) 

Co-chair Affiliation Country 

Lambert Kuijpers Technical University Eindhoven Netherlands 

Roberto de A. Peixoto Maua Institute, IMT, Sao Paulo Brazil 

 

Members Affiliation Country 

Radhey S. Agarwal IIT New Delhi India 

James M. Calm Engineering Consultant USA 

Radim Cermak Ingersoll Rand Czech Republic 

Guangming Chen Inst. For Refrigeration and Cryogenic Eng., Shanghai China 

Denis Clodic Ecole des Mines France 

Daniel Colbourne Consultant UK 

Sukumar Devotta Consultant India 

Martin Dieryckx Daikin Europe Belgium 

Dennis Dorman Trane USA 

Kenneth E. Hickman Consultant USA 

William Hill Consultant USA 

Martien Janssen Re/genT Netherlands 

Makoto Kaibara Panasonic, Research and Technology Japan 

Michael Kauffeld Fachhochschule Karlsruhe Germany 

Fred Keller Consultant USA 

Jürgen Köhler University of Braunschweig Germany 

Holger König Heat AG, Vienna Germany 

Edward J. McInerney Consultant USA 

Petter Nekså SINTEF Energy Research Norway 

Horace Nelson Manufacturer Jamaica 

Alexander C. Pachai Johnson Controls Denmark 

Andy Pearson Star Refrigeration Glasgow UK 

Per Henrik Pedersen Danish Technological Institute Denmark 

Sulkan Suladze Consultant Georgia 

Paulo Vodianitskaia Consultant Brazil