### TS- EMLA50 /60/70/80 

## Attachment #1 Material Safety Data SheetRecommended Use Asphalt Emulsifier Company Emergency Phone Number OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) Product Code(s) Chemical Emergency Phone Number Potential Health Effects CANUTEC (Canadian Transportation) : (613) 996-6666 CHEMTREC (US Transportation) : (800) 424-9300 Principle Routes of Exposure Eye Contact. Skin Contact. Inhalation. Ingestion. Product Name
Acute toxicity 

### 2. HAZARDS IDENTIFICATION Eyes Avoid contact with eyes. Risk of serious damage to eyes. Skin Avoid contact with skin. Contact causes severe skin irritation and possible burns. May cause sensitization by skin contact. Inhalation Avoid breathing vapors or mists. Aspiration into lungs can produce severe lung damage. Irritating to respiratory system. Corrosive by inhalation. UN/ID No

Ingestion Ingestion may cause serious damage to mouth, throat, and stomach. May be harmful if swallowed. May cause uptake in target organs with no visable symptoms. May cause lung damage if swallowed. Aspiration may cause pulmonary edema and pneumonitis. UN2735 Emergency Contact 

### 1. PRODUCT AND COMPANY IDENTIFICATION E-mail Manufacturer 

## Emergency Overview Corrosive. Vapors may be irritating to eyes, nose, throat, and lungs. May cause sensitization by skin contact. May cause allergic respiratory reaction. May be harmful if swallowed, inhaled, or absorbed through skin. Contains components that may cause target organ damage, based on laboratory animal data. Do not mix with nitrites; product may form suspected cancer-causing nitrosamines.

_____________________________________________________________________________________________ Appearance: Amber viscous liquid Revision Date: 11-Apr-2012

Odor: Ammoniacal 

### Page 1 / 8 Issuing Date: 11-Apr-2012 

# Material Safety Data Sheet
Physical State: Not Applicable Version: 1

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012 Prolonged exposure may cause chronic effects. Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible persons. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen.


### 5. FIRE-FIGHTING MEASURES Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Do not rub affected area. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Flammable Properties Not flammable Environmental hazard

Flash Point > 300 °F / > 149 °C Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Remove and wash contaminated clothing before re-use. Consult a physician. Allergic symptoms may develop within 12 hours after exposure. In the case of skin irritation or allergic reactions see a physician. Method closed cup See Section 12 for additional Ecological Information. Aggravated Medical Conditions
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon dioxide (CO 2 ). Alcohol-resistant foam. Dry chemical. Chemical Name Inhalation Move to fresh air in case of accidental inhalation of vapors or decomposition products. Get medical attention immediately if symptoms occur. CAS-No
Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire. Weight % Respiratory disorders. Skin disorders. Call a doctor immediately if allergic signs, particularly in the respiratory tract, are observed.

Hazardous Combustion Products Carbon monoxide (CO). Carbon dioxide (CO 2 ). Nitrogen oxides (NOx). Sulfur oxides. Hydrocarbons. Decomposes in a fire giving off toxic fumes and dense clouds of smoke. Ingestion Do NOT induce vomiting. Call a physician or Poison Control Center immediately. Rinse mouth. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion. Smallest quantities reaching the lungs through swallowing or subsequent vomiting may result in lung edema or pneumonia. Fatty Amidoamine Mixture Proprietary
Explosion Data 100
Sensitivity to Mechanical Impact None. Chronic Effects
Notes to Physician Sensitivity to Static Discharge None. Treat symptomatically. 

### 4. FIRST AID MEASURES

_____________________________________________________________________________________________ 

### 3. COMPOSITION/INFORMATION ON INGREDIENTS
Protection of First-aiders 

### Page 2 / 8 Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

Methods for Containment Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). Prevent material from entering surface waters, drains or sewers, and soil. Spills of material which could reach surface waters must be reported to the United States Coast Guard National Response Center's toll free phone number (800) 424-8802. Methods for Cleaning Up Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. May cause sensitization by inhalation and skin contact. Heating of containers may cause pressure rise, with risk of bursting. Avoid prolonged contact with rags or other porous materials - may spontaneously combust. Always store rags used for wiping purposes that may have contacted this product in an appropriate metal container.


### 7. HANDLING AND STORAGE 6. ACCIDENTAL RELEASE MEASURES Protective Equipment and Precautions for Firefighters
Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. In case of insufficient ventilation, wear suitable respiratory equipment. Wear personal protective equipment. Refer to Section 8. Remove contaminated clothing and shoes. Do not puncture or incinerate. If spilled, take caution, as material can cause surfaces to become very slippery. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. There is a hazard associated with rags, paper or any other material used to remove spills which become soaked with product. Avoid accumulation of these: they are to be disposed off safely after use. Never pierce, drill, grind, cut, saw or weld any empty container. Personal Precautions Technical Measures/Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from direct sunlight. Keep away from heat and sources of ignition. Store in accordance with local regulations. Store away from incompatible materials (see section 10). Store in original container. Do not re-use empty containers. Keep away from food, drink and animal feedingstuffs. No action shall be taken involving any personal risk or without suitable training. Evacuate non-essential personnel. Do not touch or walk through spilled material. Avoid breathing vapors or mists. Ensure adequate ventilation. For personal protection see section 8. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Environmental Precautions Do not allow material to contaminate ground water system. Try to prevent the material from entering drains or water courses. Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Specific hazards arising from the chemical Flammability 1 Personal protection X HMIS



### _____________________________________________________________________________________________ Flammability 1 Physical and chemical hazards - Stability 1



### Page 3 / 8 Health Hazard 2 Physical Hazard 1 NFPA Health Hazard 2

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012 Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. 9.2 Other information Density VALUE 7.90 lbs/gal @ 25 C / 77 F; 7.84 lbs/gal @ 49 C / 120 F Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. 

### 10. STABILITY AND REACTIVITY Engineering Measures Showers Eyewash stations Ventilation systems Stability Stable under recommended storage conditions. Hygiene Measures Incompatible Products Oxidizing or reducing agents. Metals. Acids. Combustible materials. May react with nitrites to form suspected cancer causing nitrosamines. Avoid prolonged contact with rags or other porous materials - may spontaneously combust. Always store rags used for wiping purposes that may have contacted this product in an appropriate metal container. Handle in accordance with good industrial hygiene and safety practice.
Conditions to Avoid Extremes of temperature and direct sunlight. Excessive heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to air. Storage near to reactive materials. 

### 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Other Exposure Guidelines Personal Protective Equipment
Hazardous Decomposition Products None known based on information supplied. 

### 9. PHYSICAL AND CHEMICAL PROPERTIES Hazardous Polymerization Hazardous polymerization does not occur. If user operations generate mist, use ventilation to keep exposure to airborne contaminants below the applicable exposure limits. Refer to the current exposure limits for oil mist, diethylenetriamine, triethylenetetramine, and tetraethylenepentamine. Exposure Guidelines



### 11. TOXICOLOGICAL INFORMATION 9.1 Information on Basic Physical and Chemical Properties Eye/Face Protection Tightly fitting safety goggles. If splashes are likely to occur, wear: Goggles, Face-shield. Avoid contact with eyes. Skin and Body Protection Appearance: Specific Gravity 0.95 Amber viscous liquid pH Flash Point > 149 °C / > 300 °F 25 C / 77 F Not applicable Odor: Ammoniacal



### _____________________________________________________________________________________________ Remarks • Methods Viscosity, dynamic 825 cps closed cup 

### Page 4 / 8 Property No information available Values 25 C / 77 F

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

No information available. Inhalation Corrosive to nose, throat and respiratory tract. Avoid breathing vapors or mists. May be harmful if inhaled. Aspiration into lungs can produce severe lung damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. There is no data available for this product. Developmental Toxicity No information available. Skin Contact Avoid contact with skin. Contact causes severe skin irritation and possible burns. May be absorbed through the skin in harmful amounts. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Chronic Effects Prolonged exposure may cause chronic effects. Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible persons. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. 

### Teratogenicity No information available. This material should only be handled by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals. It should be borne in mind that the toxocological and physiological properties of this compound is not well defined. May be harmful by inhalation, ingestion, or skin absorption.
Target Organ Effects Kidney. Respiratory system. Liver. Skin. Eyes. Carcinogenicity Contains no ingredient listed as a carcinogen. Acute toxicity



### 12. ECOLOGICAL INFORMATION Ingestion May be harmful if swallowed. Can burn mouth, throat, and stomach. May cause uptake in target organs with no visable symptoms. May cause lung damage if swallowed. Ecotoxicity The environmental impact of this product has not been fully investigated. When spilled, this product may act as an oil, causing a film, sheen, emulsion, or sludge at or beneath the surface of a body of water. This product contains a chemical which is listed as a marine pollutant according to DOT. This product itself is not currently regulated as a marine pollutant per US DOT regulation. Eye Contact Sensitization May cause sensitization of susceptible persons. 

### 13. DISPOSAL CONSIDERATIONS Avoid contact with eyes. Vapor may cause irritation. May cause irreversible damage to eyes.



### _____________________________________________________________________________________________ Germ Cell Mutagenicity No information available. Product Information



### Page 5 / 8 Chronic Effects Reproductive toxicity

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

TSCA - Not listed on the TSCA Inventory. R&D Exemption use only. Commercial use is prohibited. - Waste Disposal Methods

DSL DOT
NDSL EINECS - This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. 

### 14. TRANSPORT INFORMATION
ELINCS - IATA ENCS - Proper shipping name
IECSC - Proper shipping name KECL - UN2735; Amines, Liquid, Corrosive, N.O.S. (Polyethylene Polyamines, n-Alkyl Polypropylene Polyamines); 8; PG III UN2735; Amines, Liquid, Corrosive, N.O.S. (Polyethylene Polyamines, n-Alkyl Polypropylene Polyamines); 8; PG III
PICCS - Contaminated packaging

AICS - Do not re-use empty containers. IMDG Hazard class

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory 8

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Proper shipping name UN2735; Amines, Liquid, Corrosive, N.O.S. (Polyethylene Polyamines, n-Alkyl Polypropylene Polyamines); 8; PG III EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances UN/ID No

KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances UN2735

AICS - Australian Inventory of Chemical Substances 

### U.S. Federal Regulations Packing Group III 

### 15. REGULATORY INFORMATION

_____________________________________________________________________________________________ International Inventories Page 6 / 8 Emergency Response Guide Number 153

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012 Fire Hazard No This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. 

### U.S. State Regulations WHMIS Hazard Class D2B Toxic materials E Corrosive material Sudden Release of Pressure Hazard No Acute Health Hazard California Proposition 65 This product does not contain any Proposition 65 chemicals. Yes Reactive Hazard No


### 16. OTHER INFORMATION U.S. State Right-to-Know Regulations SARA 311/312 Hazard Categories This product does not contain any substances regulated by state right-to-know regulations Prepared By Issuing Date: 11-Apr-2012 Chronic Health Hazard

Revision Date: 11-Apr-2012 Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). 

### International Regulations
Revision Note No information available. Yes



### _____________________________________________________________________________________________ Canada 

### Page 7 / 8 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012 Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.



### Page 8 / 8 _____________________________________________________________________________________________ End of Material Safety Data Sheet