WISCONSIN DEPT. OF NATURAL RESOURCES 

### State of Wisconsin DEPARTMENT OF NATURAL RESOURCES 101 S. Webster Street Box 7921 Madison WI 53707-7921 Scott Walker, Governor Cathy Stepp, Secretary Telephone 608-266-2621 FAX 608-267-3579 TTY Access via relay - 711



### January 24, 2011

Ms. Susan Hedman Regional Administrator - R19J USEPA - Region 5 77 W. Jackson Blvd. Chicago IL 60604

Subject: Wisconsin Infrastructure SIP Components Confirmation

Dear Ms. Hedman:

I am writing to confirm that the State of Wisconsin continues to retain the resources and authorities necessary to evaluate air ambient air quality, develop plans to attain new and existing ambient air quality standards, meet the applicable requirements of the new source review (NSR) program and to effectively enforce all applicable requirements. Specifically, the Wisconsin Department of Natural Resources (WI-DNR) has the authority and resources to implement and satisfactorily complete the requirements listed below as set forth in Section 110 of the Clean Air Act (CAA) for the 1997 and 2006 National Ambient Air Quality Standards (NAAQS), and therefore meets the current applicable requirements of Section 110 of the CAA for 8-hour ozone, PM-2.5, and PM-10.

The State Implementation Plan (SIP) elements listed below are required under Section 110(a). Section 110(a)(1) provides the procedural and timing requirements for SIPs. Section 110(a)(2) lists the basic or infrastructure elements that all individual SIPs must contain. Following each element is a discussion of WI-DNR's ability to fulfill the requirement. In regard to the 8-hour ozone Section 110 infrastructure SIP elements, this transmittal confirms those portions of the federally-approved 1-hour air quality state planning provisions noted in 58 FR 34225 - June 24, 1993.

EPA guidance on the Section 110(a) infrastructure affirmations and required components (Oct 2, 2007 and Sep 25, 2009 — William T. Harnett) addresses the following elements at the core of the overall ambient air quality management structure: 1. Emission limits and other control measures 2. Ambient air quality monitorinWdata system 3. Program for enforcement of control measures 4. Interstate [pollutant] transport 5. Adequate [authority and] resources 6. Stationary source monitoring system 7. Emergency power 8. Future SIP revisions 9. Consultation with government officials 10. Public notification 11. PSD and visibility protection 12. Air quality modeling/data 13. Permitting fees 14. Consultation/participation by affected local entities

### Page 2



## Required Section 110 SIP Elements (per EPA guidance)

EPA Guidance: The SIP elements listed below are required under section 110(a)(1) and (2). Section 110(a)(1) provides the procedural and timing requirements for SIPs. Section 110(a)(2) lists the basic or "infrastructure" elements that all SIPs must contain. We note that this list in not intended to constitute an interpretation of these provisions, or a change of past practice with respect to these provisions, merely a brief description of the required elements.



### Wisconsin response: Wisconsin Statute Chapter 285 embodies the primary air pollution regulation requirements and authorities of the state. Subchapter II of 285, Wis. Stats., delineates the general duties and authorities of the WI-DNR as the primary agency for air quality management within the state and as the designated authority to implement the state responsibilities of the federal Clean Air Act and associated State Implementation Plans. Prior Wisconsin Legislative Fiscal Bureau Reports regarding Wisconsin Air Management Programs notes an ongoing commitment of the state within its Air Management Programs to include these fourteen general SIP components. Beyond the general authority noted by Ch. 285 Wis. Stats., the individual responses that follow indicate specific authorities related to the discrete SIP provisions.



## 1. Emission limits and other control measures

EPA Guidance: Emission limits and other control measures — Section 110(a)(2)(A) requires SIPs to include enforceable emission limits and other control measures, means or techniques, schedules for compliance and other related matters. EPA notes that the specific nonattainment area plan requirements of section 110(a)(2)(I) are subject to the timing requirements of section 172, not the timing requirement of section 110(a)(1), and also that SIPs to meet this section are not covered by the Consent Decree.



### Wisconsin response: WI-DNR continues to monitor, update and implement necessary and required revisions to Wisconsin's SIP in the form of emission limits and other control measures in order to meet federal and state ambient air quality standards including 8-hour ozone, PM-2.5 and PM-10. Authority for this effort is established generally for the Bureau of Air Management under ss. 285.11 through 285.19, Wis. Stats. Authorities related to specific pollutants, including the establishment of ambient air quality standards and increments, identification of nonattainment areas, air resource allocations and various performance and emissions standards, are contained in ss. 285.21 through 285.29, Wis. Stats.



## 2. Ambient air quality monitoring/data system EPA Guidance : Ambient air quality monitoring/data system — Section 110(a)(2)(B) requires SIPs to include provisions to provide for establishment and operation of ambient air quality monitors, collecting and analyzing ambient air quality data, and making these data available to EPA upon request.



### Wisconsin response: WI-DNR continues to operate an extensive air monitoring network. The data is used after full quality assuranceto determine compliance with the federal and state NAAQS. Wisconsin's most recently adopted and EPAapproved annual network plan for 2011 was signed and submitted on June 25, 2010. In addition, WI-DNR actively participated in the recent development of a five-year regional network assessment for Region 5 states dated July 1, 2010. Authority for the monitoring efforts exists under the general WI-DNR air pollution duties in s. 285.H, Wis. Stats. Funding for the monitoring network comes from a variety of sources with EPA providing a major share under its Section 103 and 105 grant programs supporting federal monitoring requirements specified in 40 C.F.R Part 58.10.



## 3. Program for enforcement of control measures EPA Guidance: Program for enforcement of control measures — Section 110(a)(2)(C) requires States to include a program providing for enforcement of all SIP measures and the regulation of construction of new or modified sources to meet prevention of significant deterioration (PSD) and nonaffainment NSR requirements.

### Page 3

Wisconsin response: The WI-DNR Air Management and Environmental Enforcement Programs work together to assure compliance with air program SIP provisions and related administrative code and permit requirements. Authority to enforce violations and to assess penalties is contained in ss. 285.83 and 285.87, Wis. Stats. WDNR follows a stepped enforcement process to address violations in proportion to their seriousness. The enforcement responses range from issuance of a Letter of Inquiry (the state counterpart of an EPA 114 request) where additional information is needed to confirm or assess the significance of a violation, up through referral to the Wisconsin Department of Justice for civil or criminal enforcement as appropriate. The EnPPA (Environmental Performance Partnership Agreement) between the Air Program and EPA Region 5 addresses implementation of the EPA HPV (High Priotity Violation) policy. The process for prosecution of violations is also addressed in an Air Program Compliance and Enforcement Memorandum of Understanding betvveen EPA Region 5 and the WDNR Air Management Program. Consistent with the provisions of this MOU, the two agencies conduct monthly compliance and enforcement conference calls to discuss program issues and specific cases. WI-DNR retains the authority to develop enforcement mechanisms and supporting fee structures related to the State's prevention of significant deterioration (PSD) and nonattainment NSR construction and operating permits programs under s. 285.11, s. 285.13, s. 285.17, s. 285.19 and ss. 285.60 through 285.69, Wis. Stats.



## 4. Interstate [pollutant] transport

EPA Guidance: Interstate Transport — Section 110(a)(2)(D) requires SIPs to include provisions prohibiting any source or other type of emissions activity in one State from contributing significantly to nonattainment, or interfering with maintenance, of the NAAQS in another State, or from interfering with measures required to prevent significant deterioration of air quality or to protect visibility in another state. EPA has already issued CAR to assist States in developing SIPs to meet this requirement for purposes of the 8-hour Ozone and PM-2.5 NAAQS, and has issued separate guidance to all states on how to comply with each prong of this statutory provision.



### Wisconsin response: WI-DNR has adopted and implemented the various major programs related to interstate transport of pollution as noted necessary by EPA — most recently in NR 432 for the state portions of the Clean Air Interstate Rule (CAIR). The agency developed CAIR implementation programs after 2005 to address interstate transport of ozone and PM-2.5 precursors. When EPA finalizes the replacement to the second phase of CAIR, in the form of a final CATR regulation, WI-DNR has the authority to develop refined control requirements to address that federal program — either adopting the Federal Implementation Plan (FIP) directly or through development of an approvable substitute regulation embodying a more unique state program. Wisconsin has entered into agreements and working relationships with the surrounding states of Illinois, Indiana, Michigan and Minnesota to address a continuing assessment and control strategy program development to ensure multi-state nonattainment areas meet required clean air timelines. Together these regulations and cooperative agreements address CAA and EPA concerns over the interstate transport of emissions of regulated pollutants. Wisconsin Statutes ss. 285.11, 285.13 and 285.15 address circumstances where interstate transport reduction agreements between states are needed to resolve SIP development of cross-boundary nonattainment areas.



## 5. Adequate resources EPA Guidance: Adequate resources — Section 110(a)(2)(E) requires States to provide for adequate personnel, funding, and legal authority under State law to carry out its SIP, and related issues.



### Wisconsin response: The amount of funding and personnel granted to the WI-DNR is handled through the State of Wisconsin's biennial budget process. The WI-DNR Air Program has several funding sources, including program revenue (fees paid by businesses), tax revenue and grants (federal and state). There are separate accounts affiliated with the different funding sources to ensure the funding and related personnel are used for the intended purpose. The primary federal grant the WI-DNR Air Program receives is the Section 105 Air Pollution Control Grant. It is an annual grant that includes extensive review by EPA prior to award. In addition, the WI-DNR and EPA negotiatePage 4



### priorities and grant commitments under the Environmental Performance Partnership Agreement (EnPPA), which is a two year agreement itemizing performance measure and outcomes across the various funding sources and grants. The current EnPPA remains in effect until September 30, 2011. Wisconsin's basic air management program duties and authorities are ensured under s. 285.11, Wis. Stats.



## 6. Stationary source monitoring system EPA Guidance: Stationary source monitoring system — Section 110(a)(2)(F) requires States to establish a system to monitor emissions from stationary sources and to submit periodic emission reports.



### Wisconsin response: WI-DNR requires regulated sources to submit various reports, dependant on applicable requirements and the type of permit issued, to the Bureau of Air Management Compliance Team. Reports are prioritized through the Bureau Air Leaders structure regarding frequency and relative thoroughness of review. Frequency and requirements for review are incorporated as part of Wis. Adm. Codes NR 438 and 439. Emission reports are now submitted following a federally mandated Compliance Assurance Monitoring (CAM) reporting structure. Over the last several years Wisconsin has crafted a strong and integrated set of net-based monitoring, reporting, permits and compliance databases that have substantially strengthened the integrity of each of its component units. Basic authority for this effort is provided in s. 285.65, Wis. Stats.



## 7. Emergency power

EPA Guidance: Emergency power— Section 110(a)(2)(G) requires States to provide for authority to address activities causing imminent and substantial endangerment to public health, including contingency plans to implement the emergency episode provisions in their SIPs.



### Wisconsin response: Wisconsin Statute s. 285.85 requires the Agency to act upon a finding that episode or emergency conditions exist. This language authorizes the Department to seek immediate injunctive relief in circumstances of 

### substantial danger to the environment or to the public health of 

### persons. WI-DNR will further revise the PM-2.5 SIP when EPA promulgates Emergency Episode guidance which addresses priority classifications and significant harm levels. A recent review of monitoring to date (since the first federal method monitors started functioning in Wisconsin) for PM-2.5 has yet to exceed the EPA's current functional emergency episode threshold metric of 140 ug/m3 over a 24-hr period.



## 8. Future SIP revisions

EPA Guidance: Future SIP revisions — Section 110(a)(2)(H) requires States to have the authority to revise their SIPs in response to changes in the NAAQS, availability of improved methods for attaining the NAAQS, or in response to an EPA finding that the SIP is substantially inadequate.



### Wisconsin response: 

### Wisconsin Statutes s. 285.11(6) provides the agency the authority to develop all rules, limits and regulations necessary to meet ambient air quality standards as they evolve and to respond to any EPA findings of inadequacy with the overall Wisconsin SIP and air management programs.



## 9. Consultation with government officials EPA Guidance: Consultation with govemment officials — Section 110(a)(2)(J) requires States to provide a process for consultation with local governments and Federal Land Managers carrying out NAAQS implementation requirements pursuant to section 121 relating to consultation.



### Wisconsin response: Wisconsin DNR follows a coordinated administrative process in the authorization, approval for notice and adoption via its Natural Resources Board in order to move forward all SIP revisions involving implementation and control program or control measure adoption. That coordinated development process ensures that other

### Page 5

potentially fiscally impacted public entities are identified and allowed to become engaged in the development process. The agency pursues formal MOA processes in all conformity and transportation system activities that might impact local transportation projects, regional projects and planning, and federal funding sources outside EPA. The Bureau of Air Management has effectively used formal stakeholder structures in the development and refinement of all major SIP revisions, especially in regard to regional pollutants such as those critical to ozone, haze and PM-2.5. Wisconsin actively engaged Federal Land Managers (FLMs) and states with Class I areas impacted by Wisconsin source area emissions in regard to regional haze reduction planning. WI-DNR is given the authority in s. 285.13(5), Wis. Stats., to "advise, consult, contract and cooperate with other agencies of the state, local governments, industries, other states, interstate or inter-local agencies, and the federal government, and with interested persons or groups" during the entire process of SIP revision development and implementation and for other elements regarding air management for which the agency is the officially-charged agency.



## 10. Public notification EPA Guidance: Consultation with government officials — Section 110(a)(2)(J) further requires States to notify the public if NAAQS are exceeded in an area and to enhance public awareness of measures that can be taken to prevent exceedances.



### Wisconsin response: WI-DNR maintains an active monitoring netvvork for multiple criteria pollutants (those with NAAQS) and routinely forecasts air pollutant concentrations. As provided for under s. 285.11, Wis. Stats., public notice is provided at levels associated with the extent of the monitored problem ranging from a simple advisory to alert levels actively participating in regional air quality forecasts and EPA's AIRNOW air quality data outreach program. WI-DNR maintains an active multi-media outreach effort through a variety of partners to ensure adequate public notice and to advise the public on simple means to reduce immediate exposure.



## 11. PSD and Visibility protection EPA Guidance: PSD and visibility protection — Section 110(a)(2)(J) also requires States to meet applicable requirements of Part C related to prevention of significant deterioration and visibility protection.



### Wisconsin response:WI-DNR is addressing both the ongoing review of new major sources and major modifications under a SIPapproved PSD new source review program and through the development of a 'visibility improvement (haze reduction) SIP revision that includes the formal adoption of Wisconsin's BART program into the SIP. PSD is generally authorized under s. 285.11, Wis. Stats., with specific performance, emission standards (including for BART), permitting and fee structure authorities under ss.285.27 and 285.60-285.69, Wis. Stats.



## 12. Air quality modeling data EPA Guidance: Air quality modeling/data — Section 110(a)(2)(K) requires that SIPs provide for performing air quality modeling for predicting effects on air quality of emissions from any NAAQS pollutant and submission of such data to EPA upon request.



### Wisconsin response: WI-DNR maintains a capability to perform modeling of the air quality impacts of emissions of all criteria pollutants including ozone and PM-2.5 among others and including both source-oriented and more regionally directed complex photochemical grid models. WI-DNR works with LADCO, EPA and the other Lake Michigan states to perform regional modeling of ozone and PM-2.5 from consistent emissions inventory and meteorology platforms in order to support coordinated and non-competing SIP development for Wisconsin and nearby nonattainment areas and to address interstate pollutant transport and visibility impact assessments. As required by the Clean Air Act, Wisconsin also requires source-specific modeling for PSD-NSR assessment and permitting for the construction of major and some minor sources. These authorities reside under ss. 285.11, 285.13 and 285.6°- 285.69, Wis. Stats.

### mcerely

elby, Jr. — Director eau of Air Manageme



### Cc: Sue Bangert AD/8 Pat Stevens — AD/8 Cheryl Nevvton USEPA Region 5 Page 6



## 13. Permitting fees EPA Guidance: Permitting Fees — Section 110(a)(2)(L) requires SIPs to require each major stationary source to pay permitting fees to cover the cost of reviewing, approving, implementing and enforcing a permit.



### Wisconsin response: Major stationary sources receive permits under the WI-DNR Title 5 and New Source Review (NSR) programs. The Title 5 program is funded by emission fees paid by the sources and the level of funding, or fees assessed, are included in the State of Wisconsin biennial budget process. The NSR program is funded by permitting fees that vary based on the type and complexity of the permit. These fees were revised effective January 1, 2011. Authority is established under s. 285.69, Wis. Stats.



## 14. Consultation/participation by affected local entities EPA Guidance: Consultation/participation by affected local entities — Section 110(a)(2)(M) requires States to provide for consultation and participation in SIP development by local political subdivisions affected by the SIP.



### Wisconsin response: In addition to the consultative authorities and responsibilities noted in response to element 9 addressing Section (a)(2)(J) regarding intergovernmental consultation, WI-DNR follows formal public hearing processes in the development and adoption of all forrnal SIP revisions that entail new or revised control programs or strategies/targets. As part of its program development approach, the agency actively engages potentially impacted stakeholders and other interested parties including local governmental entities. To ensure this process is active and inclusive, the agency is required to adopt all formal emission control programs and strategies as rules following the state's formal regulatory processes of notice prior to adoption, and, for any SIP revision not related to a single source, to provide the standing Committees of the state legislature with jurisdiction over environmental matters a 60 day review period which effectively ensures local entities have been engaged in the program development process. The Department is obligated to respond to inquiries by the committee Chairs within 15 days under s. 285.14, Wis. Stats.

Based on the information noted here, I believe that Wisconsin-DNR meets or exceeds all of the necessary CAA Section 110 infrastructure needs in regard to 8-hour ozone, regional haze and particulate matter in the form of PM-2.5 and PM-10 and that the authorities in place continue to satisfy those requirements of the CAA. If you have any questions, please feel free to contact Joe Hoch, Regional Pollutants and Mobile Sources Section Chief, Bureau of Air Management at 608-267-7543 or Joseph.Hoch@Wisconsin.gov

.

### State of Wisconsin

DEPARTMENT OF NATURAL RESOURCES 101 S. Webster Street Box 7921 Madison WI 53707-7921 Scott Walker, Governor Cathy Stepp, Secretary Telephone 608-266-2621 FAX 608-267-3579 TTY Access via relay - 711



### March 28, 2011

Cheryl L. Newton, Director Air and Radiation Division U.S. Environmental Protection Agency, Region 5 77 West Jackson Boulevard Mail Code: A-18J Chicago IL 60604-3507

Subject: Wisconsin Infrastructure State Implementation Plan (SIP) Clarifications for the 1997 8-Hour Ozone (0 3 ) National Ambient Air Quality Standard (NAAQS) and the 2006 24-Hour Fine Particulate Matter (PM 2

. 5 ) NAAQS.

Dear Ms. Newton:

The Wisconsin Department of Natural Resources (WDNR) submitted a confirmation of Clean Air Act (CAA) Section 110 infrastructure SIP components to the U.S. Environmental Protection Agency (EPA) on January 24, 2011. The purpose of this letter is to provide important clarifications related to greenhouse gases (GHG) and the use of coarse particulate matter (PM 10 ) as a surrogate for PM2.5.

The U.S. EPA published the "Narrowing Rule" in the Federal Register 

### on December 30, 2010 (75 FR 82536). The U.S. EPA narrowed its approval of state-specific Prevention of Significant Deterioration (PSD) rules to the extent that those rules required major source permits for sources emitting less than specified thresholds (e.g., 75,000 tons per year (tpy) of carbon dioxide equivalent ("CO2e")). To avoid any unnecessary confusion, we want to be clear that by our letter of January 24th, we are requesting a finding that Wisconsin's SIP is sufficient to meet the requirements of CAA Section 110(a)(2)(C) and (J) that is based, in pertinent part, on a PSD program that reflects the elevated thresholds of the Narrowing Rule.

The U.S. EPA promulgated the PM 2

. 5 NAAQS in 1997. Shortly thereafter, the U.S. EPA issued a guidance document entitled "Interim Implementation for the New Source Review (NSR) Requirements for PM2.5." (John S. Seitz, U.S. EPA, October 23, 1997) ("Seitz Memo"). The Seitz Memo recognized that there were "significant technical difficulties" that exist with respect to PM 2

. 5 implementation and that due to these difficulties "EPA believes that PM,0 may properly be used as a surrogate for PM 2

. 5 in meeting NSR requirements until these difficulties are resolved." The grace period for use of PM 10as a surrogate for PM 2

. 5ends on May 16, 2011.

Wisconsin has discontinued the use of PM 10 as a surrogate for PM 2

. 5 for all NSR requirements. Wisconsin had always implemented this as policy so there is no administrative rule(s) that need to be revised to account for sun setting its use. NSR staff has been instructed that the surrogate policy is no longer to be used and peer review by both the WDNR and U.S. EPA Region 5 staff serve as a check to ensure that it does not occur.

Thank you for your cooperation on these clarifications regarding our infrastructure SIP components. If you have any questions or need additional information, please contact Joseph Hoch, Regional Pollutant and Mobile Source Section Chief, at 608-267-7543 or ipsQh.hoch@wisconsin.gov

.

dnr.wi.gov wisconsin.gov 

## Naturally 

# WISCONSIN 1 ‘111r,PRINTED ON RECYCLED PAPER

### Page 2

Sincerely,

H. Melby, Jr. — D

. au of Air Manage

John Summerha . EPA, Region 5 John Mooney — U.S. EPA, Region 5 Michael Leslie — U.S. EPA, Region 5 Margaret Hoefer — LS/8 Joseph Hoch — AM/7 Andy Stewart — AM/7UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 77 WEST JACKSON BOULEVARD· CHICAGO, IL 60604-3590



### Bill Baumann, Acting Bureau Director Air Bureau Wisconsin Department of Natural Resources lO 1 South Webster Street P.O. Box 7921 REPLY TO THE ATTENTION OF: .-. 4} \,:; ""j\' } .-'



### Madi(j.··;

### ~1iss(~sin 53707-7921

Dear

# ¥~mann,

Thank 

# t

u for your March 7, 20 ll request for a Clean Data Determination for the 2006 24- hour Fine Particulate Matter (PM2.5) National Ambient Air Quality Standard (NAAQS) for the Milwaukee-Racine Nonattainment Area. The Region has reviewed your request and has determined that two PM2.5 monitors within the nonattainment area, which were violating the standard for 2007-2009 design value period, were erroneously approved for discontinuation at the beginning of 2010. Those monitors were the Virginia Street Fire Station PM2.5 monitor (AQS 

### Site ID: 550790043) and the Fire Department Headquarters PM2.5 monitor on Wells Street (AQS 

### Site ID: 550790099). The Region has, therefore, used a series of statistical tests to determine if those two monitors would likely have met the NAAQS if they had continued collecting data through 20l0 for the 2008-2010 design value period.

Our analysis results show that the Virginia Street Fire Station PM2.5 monitor, had it continued operating, would very likely have shown attainment of the NAAQS. The monitor also has similar concentrations to the two remaining sites within the County of Milwaukee, which are the Wisconsin Department of Natural Resources (WDNR) Southeast Regional**Head~uarters** 

### PM2.5 monitor (AQS 

### Site ID: 550790026) and the Health Center PM2.5 monitor on 16 1 

### Street (AQS 

### Site /D: 550790010). The Region believes that allowing this monitor to remain shut down would not compromise the requirements of 40 CFR Part 58 Appendix D.

Our analysis results show that the Fire Department Headquarters PM2.5 monitor on Wells Street, had it continued operating, also would very likely have shown attainment of the NAAQS. However, this monitor appears to measure a more unique air mass than the Virginia Street Fire Station PM2.5 monitor. Additionally, people live next door to the Fire Department Headquarters PM2.5 monitor on Wells Street, which qualifies the site as population oriented and would help the nonattainment area's PM2.5 network meet the monitoring requirements of 40 CFR Part 58 Appendix D. 

### The Region, therefore, is requiring that the Fire Department Headquarters**P~U.S** 

### monitor on Wells Street be re-established and restart operation by January 1, 2012.

Pursuant to your request, we intend to publish rulemaking in the Federal Register proposing to approve your Clean Data Determination request, thereby determining that the Milwaukee-Racine Nonattainment Area is meeting the 24-hour PM2.5 NAAQS. In 

### describing our rationale for

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### proposing this determination, we plan to provide detailed discussion of our analysis of air quality

at the discontinued monitor locations. Our final rulemaking would then reflect consideration of any public comments we receive.

If you have any questions regarding the monitoring data or statistical analysis, please contact Michael Rizzo, at 312-353-8641. If you questions regarding the PM2.5 redesignation process, please contact Gilberta Alvarez at 312-886-6143.

Sincerely,WISCONSIN OEM OF NATURAL RESOURCES



### Sincerely,

ohn elby, Jr. — Direct Bureau f Air Manageme

d nr.wi .go 

### v wisconsin.gov 

## Naturally 

# WISCONSIN PAPER State of Wisconsin DEPARTMENT OF NATURAL RESOURCES 101 S. Webster Street Box 7921 Madison WI 53707-7921 Scott Walker, Governor Cathy Stepp, Secretary Telephone 608-266-2621 FAX 608-267-3579 TTY Access via relay - 711



### March 7, 2011

Mr. John Mooney, Acting Chief of Air Programs Branch U.S. Environmental Protection Agency, Region 5 77 West Jackson Boulevard Mail Code: AR-18J Chicago IL 60604

Subject: Clean Data Determination for the 2006 24-hour Fine Particulate Matter (PM 2

. 5 ) National

Ambient Air Quality Standard (NAAQS)

Dear Mr. Mooney:

The Wisconsin Department of Natural Resources (WDNR) herby requests the U.S. Environmental Protection Agency (EPA) make a determination that the Milwaukee-Racine nonattainment area has attained the 2006 24- hour PM2. 5 NAAQS and publish that determination in the Federal Register. This request is based on recent measured attainment statewide from Federal Reference Method (FRM) PM 2

. 5 monitors from 2008 through 2010.

Based upon fully quality assured, quality controlled, FRM PM 2

. 5 monitoring data, 98 th percentile 24-hour PM2. 5 concentrations and derived design values are presented in the attachment to this correspondence. All PM2.5 monitors in Wisconsin measured attainment of the 24-hour PM 2

. 5 NAAQS for this period with resulting design values of 31.7 — 33.0 lag/m 3 within the nonattainment area and 16.9 — 35.3 gg/m 3 statewide. Notably, attainment levels have been achieved throughout the state well in advance of the December 2014 statutory deadline.

It is our understanding that a clean data determination by the U.S. EPA for the 2006 24-hour PM 2

. 5 NAAQS suspends the requirement for the WDNR to submit an attainment demonstration and associated reasonably available control measures, reasonable further progress plans, contingency measures, and other planning items related to attainment of the PM 2

. 5 NAAQS, in accordance with 40 CFR 51.1004. The WDNR also understands that the suspension of these planning requirements can be rescinded if the U.S. EPA subsequently issues a finding that the area is no longer attaining the NAAQS.

The measured improvements in PM 2

. 5 air quality are due to a variety of state and federally enforceable control programs implemented to reduce emissions of PM2. 5 and its precursor pollutants. The WDNR will work collaboratively with the U.S. EPA to develop a redesignation request for the Milwaukee-Racine nonattainment area over the next several months that further quantifies the achieved emission reductions.

Thank you for considering this request. If you have any questions or need additional information, please contact Joseph Hoch, Regional Pollutant and Mobile Source Section Chief, at 608-267-7543.

### ATTACHMENT

Su 

### mmary of PM 2S Monitoring Data

All PM2. 5 monitors in 

### Wisconsin measured attainment of the 24-hour PM 2

. 5 NAAQS for the period 2008 through 2010. During this period, the design values ranged from 31.7 - 33.0 1.1g/m 3 within the nonattainment area and 16.9 - 35.3 p.g/m 3 statewide. The following table summarizes the 24-hour PM2.5 98 th percentile concentrations and resulting design values for the period 2008 through 2010.

Table 1. Statewide 24-Hour PM25 98 6 Percentile Concentrations and Design Values from 2008 - 2010

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.. 34.6 36.4 35.1 35.3 Appleton 550870009 1 30.5 33.5 36.6 33.5 Milw-DNR SERHQ 550790026 1 27.5 39.0 32.6 33.0 Potosi 550430009 1 35.2 33.0 30.2 32.8 Waukesha 551330027 2 29.9 32.8 35.9 32.8 Milw

- 16th CHC 550790010 2 27.5 39.1 30.9 32.5 LaCrosse 550630012 1 29.2 39.5 28.7 32.4 Milw

- FAA/College Ave. 550790058 1 26.9 33.0 35.3 31.7 Madison 550250047 1 32.0 32.1 29.5 Perkinstown 551198001 1 33.0 25.3 32.5 30.2 Manitowoc 550710007 1 24.7 33.6 29.5 29.2 Devils Lake 551110007 1 24.4 37.8 24.9 29.0 Mayville / Horicon 550270007 1 24.7 32.3 29.9 28.9 Harrington Beach 550890009 1 26.3 31.5 27.6 28.4 Somerset 551091002 1 24.2 33.9 27.0 28.3 Chiwaukee 550590019 1 25.8 34.7 23.3 27.9 Trout Lake 551250001 1 21.2 24.5 20.9 22.2 Potawatomi 550410007 1 15.2 20.4 22.1 19.2 Bad River 550030010 1 16.0 17.6 17.3 16.9

I Design Values were developed in accordance with 40 CFR 50 Appendix N Monitors located in the Milwaukee-Racine nonattainment area are identified by bold text. FRM - Federal Reference Method



### Based on this data, the WDNR believes a clean data determination for the Milwaukee-Racine nonattainment area is both reasonable and justified at this time. The WDNR will continue to operate a federally approved FRM PM2.5 monitoring network in this area to track continued attainment of the 2006 24-hour PM 2

. 5 NAAQS.

### 1 

## Appendix 3

An Analysis of Characteristics and Precursors to Ambient PM 2.5 

## Levels in Southeastern Wisconsin for Purposes of Designing Emission Inventories for Inclusion in a Request for Redesignation to Attainment PM 2.5 

## Nonattainment Counties of Milw aukee, Waukesha and Racine

Bureau of Air Management Wisconsin Department of Natural Resources August 2011

(Updated in May 2012 to address ammonia pollution)

--------------- --------------- --------------- --------------- -------------

Table of Contents Section Page

1 Purpose of Report 2

2 Overview: PM 2.5 

### nonattainment designations and request to redesignate to attainment 2

3 Overview: Requirements on evalua ting concentration levels of PM 2.5 

### and gaseous PM 2.5 

### precursors for PM 2.5 

### SIP revisions 4

4 Data analysis overview 5

5 Measurement data 6

5.1 FRM PM 2.5 

### data 6 5.2 Speciated PM 2.5 

### data 6 5.3 VOC measurement data 7 5.4 NOx measurement data 8 5.5 Meteorological data 8

6 Evaluating characteristics of PM 2.5 

### in Milwaukee and Waukesha Counties 10

6.1 Month of year distributions - average FRM PM 2.5 

### concentrations 10 6.2 Month of Year – Average speciated PM 2.5 

### concentrations 10 6.3 Speciated PM 2.5 

### distributions vs. increasing ambient temperature 14 6.4 Speciated PM 2.5 

### distributions vs. increasing daily temperature difference 16 6.5 Speciated PM 2.5 

### distributions vs. increasing relative humidity 16 6.6 Analysis of FRM and organic carbon PM 2.5 

### and its gaseous precursors 18 6.7 Analysis of nitrate and FRM PM 2.5 

### and NOx 20 6.8 Winter Nitrate Study: Ammonia’s modeled influence on nitrate PM 2.5 

### levels in SE Wis 24

7 Summary 25 8 Proposed recommendations 26 9 References 27

### 2 1 Purpose of Report

The purpose of this report is to provide a technical demonstration to identify certain long-term (2001 through 2009, 2010) characteristics, distributions and profiles in me asured fine particulates (i.e. those particles with an aerodynamic diameters less than 2.5 microns [“PM 2.5 

### ”]) and some of their precursors in southeastern Wisconsin.

Evaluating these long-term behaviors and features of PM 2.5 

### and precursors in southeastern Wisconsin will help in assessing which (if any) additional emission inventori es need to be constructed as part of the Wisconsin Department of Natural Resources (WDNR)’s requ est for the redesignation to attainment for PM 2.5 

### nonattainment counties in southeastern Wisconsin as part of the state implementation plan (SIP) for PM 2.5 

### .

2 Overview: PM 2.5 

### nonattainment designations and requ est to redesignate to attainment

On November 13, 2009 (74 FR 58688) the U.S. Environmental Protection Agency (EPA) designated the Wisconsin counties of Milwaukee, Racine and Waukesha (Figure 1) as being in nonattainment of the year 2006 24-hour PM 2.5 

### National Ambient Air Quality Standard (NAAQS). This designation was part of the U.S. EPA’s national rulemaking in which numerous other regions in the country were also designated as not attaining a PM 2.5 

### NAAQS.

This rulemaking, which was done in accordance with Sec tion 107(d) of the Federal Clean Air Act (CAA), was based upon the Agency’s review of PM 2.5 

### measurements collected during the three year period 2006-2008.

The PM 2.5 

### measurements collected at monitoring sites in Milwaukee and Waukesha Counties during 2008-2010 show that all sites have attained all PM 2.5 

### NAAQS during this three year period. There never has been any PM 2.5 

### monitoring conducted in Racine County.

Consequently, the Wisconsin Department of Natural R esources (WDNR) is in the process of drafting a request that the U.S. EPA redesignate Milwaukee, Racine and Waukesha Counties (Figure 1) as attaining the year 2006 24-hour PM 2.5 

### NAAQS.

The U.S. EPA has established guidance and requirements that any state must follow in submitting a redesignation request.

Under section 172(c)(3) of the federal Clean Air Act (CAA) , any state seeking a redesignation to attainment is required to submit a comprehensive, accurate and current inventory of actual (base year / attainment year) emissions. Additionally, under secti on 175A of the CAA, the state must submit a maintenance plan that demonstrates continued attainment for at least 10 years af ter approval of a redesignation. This maintenance plan must include a maintenance inventory.

Eight years after the redesignation, a revised maintenance plan for the next ten years must be submitted to the U.S. EPA. In order to address the possibility of future NAAQS violations, the maintenance plan must contain contingency measures.

### 3 Figure 1

Wisconsin Nonattainment Counties

And FRM PM 2.5 

### Monitoring Sites (Milwaukee, Waukesha and Racine)

2006 24-Hour PM 2.5 

### NAAQS

### 4 3 Overview: Requirements on evaluating concentration levels of PM 2.5 

### and gaseous PM 2.5 

### precursors for PM 2.5 

### SIP revisions (e.g., redesignation requests)

On April 25, 2007 the U.S. EPA promulgated many re quirements and guidance notes regarding provisions for implementation of PM 2.5 

### NAAQS – as part of the Agency’s Clean Air Fine Particle Implementation Rule (72 FR 50586). These requirements are codified in 40 CFR 51 subpart Z (“provisions for implementation of PM 2.5 

### NAAQS“).

Among these PM 2.5 

### SIP requirements is addressing pollutants contributing to PM 2.5 

### concentrations. Section 40 CFR 51.1002(c) requires that

“The State implementation plan [SIP] must identify and evaluate sources of PM 2.5 

### direct emissions and PM 2.5 

### attainment plan precursors in accordance with §§ 51.1009 and 51.101 0. After January 1, 2011, for purposes of establishing emissions limits under 51 .1009 and 51.1010, States must establish such limits taking into consideration the condensable fraction of direct PM 2.5 

### emissions”

“(1) The State must address sulfur dioxide [SO 2 

### ] as a PM 2.5 

### attainment plan precursor and evaluate sources of SO 2 

### emissions in the State for control measures.”

“(2)-(4) The State must address any of the followi ng gaseous precursors: NOx [oxides of nitrogen], volatile organic compounds [VOCs], and ammonia [NH 3 

### ] as PM 2.5 

### attainment plan precursors and evaluate their emission sources in the State for c ontrol measures, unless the State and the U.S. EPA provide an appropriate technical demonstration fo r a specific area showing that these emissions from sources in the State do not significantly contribute to PM 2.5 

### concentrations in the nonattainment area.”

“(5) The State must submit a demonstration to reverse any presumption in this rule for a PM 2.5 

### precursor with respect to a particular nonattainme nt area, if the administrative record related to development of its SIP shows that the presumption is not technically justified for that area.”

Since 2001 in southeastern Wisconsin, the WDNR has co llected a sizable archive of measurements of both unspeciated (bulk) and speciated PM 2.5 

### compounds (e.g., SO 4 

### , NO 3 

### and OC), as well most of their gaseous precursors (SO 2 

### , NOx and VOCs). Consequently, this study contains analyses of the long-term trends (2001-2009) in the characteristics and relationshi ps between the above-mentioned precursors and PM 2.5 

### species.

However, there is one gaseous PM 2.5 

### precursor (ammonia [NH 3 

### ]) for which EPA regulations [40 CFR 51.1002(c )(4)] note should be investigated for potential impact on PM 2.5 

### levels. Ammonia aids in the formation of NO 3 

### PM 2.5 

### , as well as ammonium (NH 4 

### ) PM 2.5 

### . However, the WDNR has almost no ambient NH 3 

### , measurements, especially in southeastern Wisconsin. Consequently, there is no analysis possible of the long-term characteristics of NH 3 

### concentrations as they relate to NO 3 

### levels in southeastern Wisconsin.

However, the Illinois State Water Supply (ISWS) did collect daily 24 hour-averaged NH 3 

### measurements during January – March 2009 at the WDNR monitoring sit es in Mayville (ID # 550270070 )and Milwaukee SERHQ (ID# 550790026). The ISWS conducted this NH 3 

### sampling as part of a LADCO-sponsored study to evaluate the science of nitrate PM 2.5 

### levels during the winter in southeastern Wisconsin (i.e., the “Winter Nitrate Study” [WNS], Stanier, et. al, 2010). The WDNR and several contractors (including ISWS) monitored a total of 25 parameters as part of the WNS field meas urement program during January-March 2009.

Using the WNS measurements, researchers from the Un iversity of Iowa cond ucted a detailed modeling analysis of what processes appear to assist in producing relative high NO 3 

### levels in southeastern Wisconsin during the winter months (Stanier, et. al, 2010). These results, especially as they involve NH 3 

### concentrations are discussed in Section 6.8.

### 5 4 Data analysis overview

Addressing the requirements listed in 40 CFR 51.1002(c)(2 ) and (3) forms the heart of this study -- as they pertain to the WDNR drafting a request that the U. S. EPA redesignate Milwaukee, Racine and Waukesha Counties to attainment of the year 2006 24-hour PM 2.5 

### NAAQS. Specifically, for the long-term (2001-2009) period in Wisconsin’s PM 2.5 

### nonattainment counties - this analysis looks at the characteristics and distributions of the following pollutants:

a) PM 2.5 

### (measured according to EPA’s federal reference method [FRM]),

b) Major speciated PM 2.5 

### ions, and

c) The gaseous PM 2.5 

### precursors VOCs and NOx - how their concentr ation levels relate to the targeted PM 2.5 

### ions and FRM PM 2.5 

### . Meteorological conditions are known to gr eatly influence ambient levels of PM 2.5 

### , especially those formed as secondary particles from gaseous precursors (Dam burg 2007, LADCO 2009). Consequently, some of the graphical assessments illustrate how varying profiles of several meteorological metrics (e.g., average daily temperature, average daily relative humidity) relate to PM 2.5 

### levels.

The results of these analyses will provide a technical demonstration that helps answer the following questions regarding emission inventor ies for this redesignation request:

a) How should the emissions inventories be configur ed on a temporal basis? Based on annual activity levels? Or targeted to those portion(s) of the calendar when the ambient PM 2.5 

### levels are most dominant?

b) Which gaseous precursor(s) demonstrate to make contributions to secondary (condensable) PM 2.5 

### levels that are sufficiently large such that their emissi ons must be taken into account as part of the PM 2.5 

### SIP?

With regards to part (b) – this assess ment will address the influence of the PM 2.5 

### precursor pollutants VOCs and NOx. There are little, if any ambient ammonia (NH 3 

### ) measurement data available for southeastern Wisconsin. Consequently, NH 3 

### is not evaluated for this study.

### 6 5 Measurement data

The geographical focus of this study of PM 2.5 

### and PM 2.5 

### precursor measurements for purposes of assessing which emission inventories need to be constructed is the PM 2.5 

### nonattainment area in Wisconsin (i.e., the Counties of Milwaukee, Waukesha and Racine [Figure 1] ). Note, there have never been any measurements of any PM 2.5 

### and PM 2.5 

### precursors collected in Racine County.

5.1 FRM PM 2.5 

### data

One of the questions that need answering in this study is how the emissions inventories should be configured on a temporal basis. Should the emissions be established for annual activities and throughputs? Or should they be derived for the calendar season of greatest PM 2.5 

### impact? (e.g., winter months). In order to evaluate this question all of the validated 24 hour, filter-based FRM PM 2.5 

### measurements collected in both Milwaukee and Waukesha Counties during Janua ry 1999 – December 2010 were analyzed. The WDNR commenced FRM PM 2.5 

### monitoring in Wisconsin in January 1999.

At varying times during January 1999 – December 2010 the WDNR has operated a total of 7 FRM PM 2.5 

### monitoring sites in Milwaukee County, as follows:

Site Name Site ID #

16th St. Health Center 550790010 (a) DNR SER HQ 550790026 (a) Virginia St. Fire Station 550790043 Craig School 550790050 County Zoo 550790051 College Ave. 550790058 (a) Fed Aviation Adm. Bldg 550790059 Wells St. Fire Station 550790099

-------------------- (a) Active site as of July 2011. All other monitoring sites have been discontinued.

The WDNR, during the same 12 year period, maintained two FRM PM 2.5 

### monitoring sites in Waukesha County:

Site Name Site ID #

Cleveland Ave 551330027(a) Barstow St 551330034

----------------------------------- (a) Active site as of July 2011. The Barsto w site has been discontinued.

5.2 Speciated PM 2.5 

### data

Since 2001 the WDNR, at the Milwaukee-DNR SERHQ a nd Waukesha-Cleveland sit es, has also collected a second series of 24-hour, filter-based PM 2.5 

### mass samples using a different instrument and filter system from the FRM equipment. (i.e., the Speciation Air Sampling System [SASS]). In turn, these SASS PM 2.5 

### mass samples have been laboratory-analyzed for many different types of PM 2.5 

### species that comprise the total PM 2.5 

### mass.

Based upon the lab analysis of the PM 2.5 

### mass collected on these speciation filters, the large majority of PM 2.5 

### mass has been identified as pertaining to four PM 2.5 

### species, as follows:

### 7 - Sulfates (SO 4 

### ), most which are formed from the atmospheri c chemical processes involving the gaseous PM 2.5 

### precursor sulfur dioxide (SO 2 

### ).

- Organic carbon (OC), most which is formed from the atmospheric chemical processes involving heavier volatile organic compounds (VOCs) – largely in the aromatics species group.

- Nitrates (NO 3 

### ), most which are formed from the atmospheri c chemical processes involving the gaseous PM 2.5 

### precursors oxides of nitrogen (NOx) and ammonia (NH 3 

### ).

The U.S. EPA guidance for PM 2.5 

### SIPs already requires that the st ates need to compile and assess SO 2 

### emission inventories for their contribution to PM 2.5 

### levels (mostly via SO 4 

### ).

However, the U.S. EPA requirements [40 CFR 51.1002( c)] note that states should also evaluate how the PM 2.5 

### precursors VOCs, NOx and NH 3 

### may influence PM 2.5 

### levels in their PM 2.5 

### nonattainment. Any of these precursors which are estimated to “si gnificantly contribute” (EPA language) to PM 2.5 

### levels in the PM 2.5 

### nonattainment area – emission inventories for the precursor(s) need to be compiled.

For this study, WDNR’s large measurement arch ive of both VOCs and NOx allows for a long-term assessment on how OC PM 2.5 

### levels relate to VOC concentrations, and also compare NO 3 

### PM 2.5 

### concentrations to NOx levels in Wisconsin’s PM 2.5 

### nonattainment area. The data sets of both VOC and NOx measurements collected in southeastern Wiscons in that were analyzed for these comparisons are described in the following two sections.

As noted in Section 3, there is almost a complete absence of NH 3 

### measurements in southeastern Wisconsin, which includes Wisconsin’s PM 2.5 

### nonattainment counties of Milwaukee, Waukesha and Racine. Consequently, the influence of NH 3 

### on NO 3 

### levels in this area is derived from a modeling analysis conducted as part of the 2010 Winter Nitrate Study (Stanier, et. al, 2010). A discussion of this analysis is contained in Section 6.8.

5.3 VOC measurement data

The purpose of evaluating VOC measur ements as they relate to PM 2.5 

### concentrations is that one of the largest PM 2.5 

### component species is organic carbon (OC) (Wis DNR, 2003). Some OC PM 2.5 

### is formed as a primary pollutant directly emitted into the atmosphere.

However, the large majority of OC PM 2.5 

### is formed in the atmosphere as a secondary organic aerosol (SOA) (Grosjean and Seinfeld, 1989). The ability of a given VOC species to produce these condensable SOA products depends on its atmospheric abundance, reactivity, oxidant availability and vo latility of its products (NARSTO, 2001). Of note is that the large majority of VOC sp ecies do not form SOA under atmospheric conditions due to the typically high vapor pressure of their products.

The SOA particles are formed mostly as a result of certain atmospheric chemistry processes involving a synthesis of sunlight, heat and moisture which tran sform some of the heavier (i.e., lower vapor pressure) VOCs (mostly from the aromatics group) to yield conde nsable particulates (Grosjean and Seinfeld, 1989).

Consequently, the two categories of ambient VOC concentrations that are analyzed in this PM 2.5 

### study are total VOCs (i.e., total nonmethane organic carbon [TNMOCs]) and the aromatic species.

The only ambient speciated VOC measurement data collected in Wisconsin’s PM 2.5 

### nonattainment area have been at the Milwaukee DNR SERHQ site, located approximately 2 miles north of the Milwaukee downtown and 2 miles east of Lake Michigan (Figure 1).

There have been two types of speciated VOC measurement data collected at the SER site:

### 8 a) Lab analysis of integrated 24 hour air sampl es collected in stainless steel canisters – once every 6 th 

### calendar day, year around. The “VOC canister” data base used in this study is for the period 2001 – 2009.

b) Continuous analysis of ambient air streamed in to an automated gas chromatograph (“autoGC”) during the months of June-July-August for the years 2001-2 007. The VOC concentrations derived from this continuous sampling were synthesized into hourly averag ed and then into calendar day (24-hour) levels.

The WDNR Air Monitoring Section has evaluated how “canister” and “autoGC” 24-hour averaged VOC measurements compare for same day sampling. Th eir findings concluded that the overall differences between the two VOC measurement methods were suffi ciently minimal. Consequently, the WDNR ruled that both VOC data bases could be used interchangeably in the same analysis.

Consequently, the data base of validated 24-hour VOC (i.e., TNMOC, aromatic species) established for this study was derived as of 1) VOC concentrations from for all canister-based samples (year-around collection), and 2) the 24-hour averaged VOC data from the autoGC on those dates that were not already witness to canister sampling.

This resulting data base of 24-hour averaged TNMO C and aromatic VOCs concentrations is used in comparison with the same day 24-hour FRM and OC PM 2.5 

### measurements at Milwaukee-SER during 2001- 2009.

5.4 NOx measurement data

The purpose of evaluating NOx measurements as they relate to PM 2.5 

### concentrations is that one of the largest PM 2.5 

### component species is nitrate (NO 3 

### ). Some nitrates are formed as a primary pollutant directly emitted into the atmosphere.

However, the large majority of NO 3 

### PM 2.5 

### is formed in the atmosphere as secondary fine particulates (Damberg, 2007).

The only ambient NOx measurement data collected in Wisconsin’s PM 2.5 

### nonattainment area have been at the Milwaukee DNR SERHQ site. The NOx data base used in this study consist of 24-hour (calendar day) averaged values that have been aggreg ated from validated hourly-averaged NOx.

This resulting data base of 24-hour averaged NOx concen trations is used in comparison with the same day 24-hour FRM and NO 3 

### PM 2.5 

### measurements at Milwaukee-SER during 2001-2009.

5.5 Meteorological data

The concentration levels of PM 2.5 

### and its major precursors can be greatly influenced by varying meteorological conditions (LADCO, 2009). Consequently, there are graphs constructed for this study that profile changes in FRM PM 2.5 

### , OC and NO 3 

### PM 2.5 

### and their precursor concentrations.

The source of all meteorological data employed in th is study was the weather measurements taken at the National Weather Service (NWS) station located at M ilwaukee Mitchell Field Airport (“MKE”). The MKE site is located approximately 3 miles west of Lake Mi chigan and approximately 10 miles directly south of the WDNR monitoring site at the Milwaukee-DNR SERHQ office.

Many of the graphs that contain air pollution data from Milwaukee-SER site also display MKE meteorological data. Both the SER and MKE sites are approximately the same distance west of the Lake Michigan, which can greatly modify weather patterns on the east side of Milwaukee. Consequently, it is

### 9 believed that the MKE meteorological data are ade quately representative of the meteorology at the SER site.

The MKE NWS meteorological data were used because th ey are more complete and subject to more quality assurance than the meteorological measurements taken at Milwaukee-DNR SERHQ.

### 10 6 Evaluating characteristics of PM 2.5 

### in Milwaukee and Waukesha Counties

6.1 Month of year distributions - average FRM PM 2.5 

### concentrations

Figures 2 and 3 display county-wide, collective mont h-of-year metrics - both the average daily FRM PM 2.5 

### concentrations and the percentage of daily FRM PM 2.5 

### concentrations greater than 30 ug/m3 for all validated FRM PM 2.5 

### monitoring conducted during January 1999 – December 2010 in Milwaukee and Waukesha Counties, respectively.

Both graphs display the same general patterns. Tho se patterns are that the highest monthly average PM 2.5 

### levels and the greatest occurrence of high site-PM 2.5 

### days (i.e., defined as > 30ug/m3) during January 1999 – December 2010 are noticeably skewed to the colder months of November – March. Using Milwaukee County PM 2.5 

### data, the collective average month-of-year PM 2.5 

### concentration for November – March (15.0 ug/m3) is 26% higher than for the remaining seven months (11.8 ug/ m3). Furthermore, the collective average percentage rate of high PM 2.5 

### days for November – March (6.68%) is more than twice the rate of high PM 2.5 

### site-days during the other seven months (2.97%).

There is a weak secondary maximum in these PM 2.5 

### statistics during July-August. The graphs show that the lowest monthly PM 2.5 

### levels typically occur during the meteorologi cally transitional spring (March-April) and autumn (September-October) seasons. For Waukesha County - a very similar evaluation of annual distribution in FRM PM 2.5 

### can be derived from applying the same metrics.

Figures 2 and 3 reveal that both the long-term (1999-2010) PM 2.5 

### levels are highest and the exceedances of the 24-hour PM 2.5 

### NAAQS are most likely during the colder months of December – February in southeastern Wisconsin. These characteristics suggest that the focus of PM 2.5 

### SIP work, including emissions inventory development might be most effective if directed towards PM 2.5 

### -related activity levels and throughput during December-February.

Reid, et.al. (2011) have already compiled winter time em issions inventories (“average January weekday”, years 2005 and 2008) for the pollutants NOx, VOCs and carbon monoxide (CO) for several sites in the upper Midwest, including the vicinity of the Milwauk ee DNR SERHQ site. These emission inventories were constructed from inventory components developed by the Lake Michigan Air Directors Consortium (LADCO). Of note is that summertime emissions inventories were also compiled as part of this study.

6.2 Month of Year – Average speciated PM 2.5 

### concentrations

Figures 4 is similar to Figure 2 in that it displays collective month-of-year average daily PM 2.5 

### concentrations collected in Milwaukee during the past decade. However, Figures 4, as well as Figure 5, is derived from the 24- hour speciated PM 2.5 

### measurements collected at the Milwaukee-SE R site during January 2001 (when speciation PM 2.5 

### monitoring started) through December 2009. Figures 4 and 5 show composite month-of-year stacked bar graphs of the daily average concentrations and percenta ge fractions of FRM values, respectively for the four major PM 2.5 

### species (organic carbon [OC], nitrate [NO 3 

### ], sulfate [SO 4 

### ] and ammonium [NH 4 

### ]) that together comprise 90%+ of the PM 2.5 

### mass collected on filters in Wisconsin.

These graphs show that OC is generally the single largest speciated PM 2.5 

### component, expressing a slight bias towards higher values during the warmer months of June – August. Furthermore, Figure 5 reveals that the OC comprises almost half the total PM 2.5 

### mass during May-August. Damberg (2007) notes that OC exhibits higher mass in the summer when photochemical activity is highest (i.e., peak solar radiation and temperature). This results in generating sizable amounts of secondary orga nic aerosols (SOA) from the heavier volatile organic compounds (VOCs) that have lower vapor pressures. These VOCs are classified as aromatics (e.g., toluene, xylene). Man-made sources of aromatic gases incl ude mobile sources, petrochemical manufacturing and solvents (Damberg, 2007).

### 11 The next largest overall PM 2.5 

### constituent is nitrate (NO 3 

### ), at least when this pollutant is significantly highest during the colder months. According to Husar (1999) a nd Blanchard and Tanenbaum (2003), the formation of NO 3 

### PM 2.5 

### is favored by the availability of gaseous ammonia (NH 3 

### ) and nitric acid (HNO 3 

### ) along with low temperatures, and high relative humidity. Figures 4 and 5 corroborate that nitrate’s properties of being semivolatile and not stable in higher temperatures lead to NO 3 

### levels that are typically higher during winter months and significantly lower in summer (Husar, 1999).

### 12

### 13

### 14 Overall, the 3rd largest overall PM 2.5 

### component is sulfate (SO 4 

### ). Figures 4 and 5 reveal that the distribution in sulfate’s concentrations throughout a 12-month period is similar to OC in that its monthly average concentrations also peak during the summer months – only much more dramatically. Sulfate, like OC, is mostly formed as a secondary aerosol through oxidation (for sulfate through SO 2 

### – via either gas-phase photochemistry with the hydroxyl radical [OH - 

### ]) in the presence of sunlight or a queous-phase oxidation in presence of cloud droplets (Seinfeld and Pandis, 1998). The SO 4 

### production is substantially ma ximized during days of warm weather and high solar radiation (Husar, 1999).

Ammonium (NH 4 

### ) is the remaining major PM 2.5 

### constituent of any sizable mass. Ammonium is formed largely from the gaseous precursor ammonia (NH 3 

### ), which mostly comes from oxides of nitrogen (NOx) emissions being oxidized in the presence of the hydroxyl radical (OH - 

### ) (Seinfeld and Pandis, 1998). Ammonium is actually part of the products when NH 3 

### reacts with either sulfuric acid (H 2 

### SO 4 

### ) or nitric acid (HNO 3 

### ) to form either ammonium sulfate (NH 4 

### SO 4 

### ) or ammonium nitrate (NH 4 

### NO 3 

### ), respectively (Damberg, 2007). Ammonium sulfate formation is preferential under most conditions, t hough ammonium nitrate is favored by low temperature and high humidity.

Similar to NO 3 

### , Figures 4 and 5 show that ambient NH 4 

### levels at Milwaukee SER exhibit a seasonal trend of the highest monthly values occurring during the colder months (November – March) and the lowest concentrations during the warmer period (April – October). Howe ver, the spread in the range of monthly NH 4 

### is much less than for NO 3 

### . 6.3 Speciated PM 2.5 

### distributions vs. increasing ambient temperature

Figure 6 shows how NO 3 

### , NH 4 

### , SO 4 

### and OC PM 2.5 

### at Milwaukee DNR SERHQ varied with increasing daily average ambient temperature, as measured at Milwauk ee Mitchell Airport’s National Weather Service [NWS] office [MKE] during 2001-2009.

As expected, the average NO 3 

### profile exhibits a generally inverse relationship – substantially decreasing concentrations with increasing temperatures (i.e., a minimum of 0.6 ug/m3 at temperatures > 85 F). As noted by Stanier, et.al (2009) nitrate is semi-volatile secondary aerosol (formed from a highly complex set of processes involving nitric acid [HNO 3 

### ] and ammonium) that can evaporat e in warmer environments.

However, it is noteworthy that the peak daily average NO 3 

### concentrations (mean: 5.6 ug/m3) were not during the coldest temperatures but in the 30-35 F range. This suggests that other factors (e.g., high relative humidity) may have played an important secondary role in nitr ate formation. Husar (1999) makes reference to high humidity assisting NO 3 

### formation.

Ammonium (NH 4 

### ) levels were a bit more uniform with respect to increasing daily average temperature (i.e., ranging from 1.3 to 2.5 ug/m3). There also was no real NH 4 

### trend with respect to temperature. The peak NH 4 

### (2.5 ug/m3 for 80-85 F) was followed by a re latively low 1.5 ug/m3 for temperatures > 85 F.

Also as expected - the average SO 4 

### profile exhibits a generally direct correlation with ambient temperature. Sulfates are largely a product of both photochemical and in-cloud oxidation involving sulfur dioxide (SO 2 

### ) (US EPA, 2003). These processes are optimized during warmer weather periods.

There is a significant rise in SO 4 

### concentrations with increasing temperatures (i.e., a minimum of 1.3 ug/m3 at temperatures < 15 F, peaking at 6.6 ug/m3 for th e 80-85 F bin). The distribution in OC vs. increasing temperatures generally followed a similar, but less dramatic trend to that for SO 4 

### . Namely, OC levels averaged approximately 3.4 ug/mg for temperatures under 55 F a nd above 5.1 ug/m3 when daily average temperatures were > 75 F.

### 15

### 16 Figure 7 is similar to Figure 6 except that Milwaukee-SER PM 2.5 

### species’ percentage fraction profiles of FRM PM 2.5 

### are normalized against bins of in creasing MKE daily average temperatur es. This graph generally validates most of the Figures 6 features. Namely, the profiles’ percentage fractions for NO 3 

### and SO 4 

### PM 2.5 

### relative to increasing temperature largely follo w the same for the speciated PM 2.5 

### concentrations (Figure 6). The NO 3 

### fraction is substantially much higher during the colder months (< 40 F: 27% average) than during the warm months (> 65 F: 8% average). Conversely, SO 4 

### exhibited lower average percentage fractions for temperatures < 30 F (16%), much higher fractions (28%) for temperatures > 70 F.

Across the temperature spectrum the distribution percentage fractions for NH 4 

### (9 - 15%) and OC (31 – 5%) are both relatively less variable, more uniform than for either NO 3 

### or SO 4 

### . This indicates that NH 4 

### and OC contributions to overall PM 2.5 

### mass are less influenced by surface temperature fluctuations than are SO 4 

### and NO 3 

### . 6.4 Speciated PM 2.5 

### distributions vs. increasing daily temperature difference (observed minus climate average).

There is a more noticeable pattern when comparing Milwaukee SER’s speciated PM 2.5 

### to the differences between MKE’s daily average temperature and its daily climatological average (30 years [1971-2000]) (WSCO, 2009) (Figure 8). Namely, all four targeted PM 2.5 

### species (NO 3 

### , SO 4 

### , NH 4 

### and OC) had relatively lower daily average concentrations on days well below climate normal temperatures (< -16 F departure), steadily and sizably increasing to relatively very warm days (> + 20 F departure).

Steadily increasing PM 2.5 

### associated with days witnessing climatologically warm temperatures was also noted for the Wisconsin’s highest FRM PM 2.5 

### days (WDNR, 2009). This earlier PM 2.5 

### study indicated that a positive correlation between high PM 2.5 

### and climatologically warm days appear s to be part of a more complex meteorological scenario which also includes relatively hi gh atmospheric moisture (i.e., relative humidity) and winds with a noticeable southerly wind component.

Figure 9 is similar to Figure 8 except that Milwaukee-SER PM 2.5 

### species’ percentage fraction profiles of FRM PM 2.5 

### are normalized against bins of increasing differen ces between MKE’s daily average temperature and its daily climatological average. The individual percentage fraction profiles for SO 4 

### , NO 3 

### , OC and NH 4 

### are each largely similar, save for their behavior during the largest negative temperature differences.

6.5 Speciated PM 2.5 

### distributions vs. increasing relative humidity

There is a generally continual increase in the average concentrations of PM 2.5 

### species NO 3 

### , SO 4 

### and NH 4 

### at Milwaukee-SER as a function of increasing daily averag e relative humidity (RH) at MKE (Figure 10). Higher PM 2.5 

### associated with days that have elevated RH is similarly evident for Wisconsin’s 50 highest PM 2.5 

### days (WDNR 2009). Organic carbon PM 2.5 

### is different from the other species in that there is little variation (min: 3.2 ug/m3, max: 4.1 ug/m3) across the range of RH bins.

Seinfeld and Pandis (1998) noted that the presence of water vapor makes it more efficient to photochemically oxidize gaseous SO 2 

### into SO 4 

### . Pathak, et.al. (2009) stated that there can be a significant production of secondary aerosols, especially during the summer due, in part, to a "large water vapor content."

Figure 11 is similar to Figure 10 except that Milwaukee-SER PM 2.5 

### species’ percentage fraction profiles of FRM PM 2.5 

### are normalized against bins of in creasing MKE daily average relative hum idity. The profiles’ percentage fractions for NO 3 

### and NH 4 

### PM 2.5 

### generally get larger with respect to higher relative humidity. This follows the same trend for the speciated PM 2.5 

### concentrations (Figure 10).

### 17

### 18 Organic carbon‘s relative fraction contribution to FRM PM 2.5 

### is inverse to that for NO 3 

### and NH 4 

### . The OC percentage fraction is greatest (58%) for the lowest rela tive humidity bin (< 40 %) and smallest (25%) for the highest relative humidity (> 90%). Varadarajan (2007) did a study of PM 2.5 

### in Ohio, which also revealed that OC had a negative relation to increasing relative humidity.

Sulfate’s percentage fraction of FRM PM 2.5 

### (18-26%) is sizable but fairly uniform across the relative humidity spectrum. Robinson, et.al. (2002) evaluated the hygroscopic growth of fresh sulfur-based particles by comparing size distributions measured at different leve ls of relative humidity during nucleation events in the Pittsburgh (PA) Air Quality Study. They found neglig ible to modest hygroscopic growth across relative humidity levels ranging from 10 to 55%.

6.6 Analysis of FRM and organic carbon PM 2.5 

### and OC’s gaseous precursors

As noted in previous sections, organic carbon is typically the single largest PM 2.5 

### constituent (by mass) collected on speciation filters in Wisconsin. Furthermor e, the large majority of OC is formed in the atmosphere as secondary organic aerosols (SOA) (Grosjean and Seinfeld, 1989). These SOAs are produced from complicated atmospheric chemistry processes involving a synthesis of sunlight, heat and moisture which transform some of the heavier VOCs (called aromatics) to yield condensable particulates (Grosjean and Seinfeld, 1989).

Section 5.3 provides an overview of the measurem ents of ambient VOCs (also referred to as total nonmethane organic carbon [TNMOC]), focusing on aromatic species collected at the Milwaukee DNR SERHQ monitoring site.

The following discussion and associated graphs d escribe some long term (2001-2009) relationships between concentrations of ambient VOCs (especially aromatics) and OC at the Milwaukee DNR SERHQ monitoring site.

Figure 12 displays SER’s collective month-of-year median daily concentrations of TNMOCs, aromatics and OC during 2001 - 2009. Consistent with the OC portion of Figure 4 – OC levels peak during the summer months. (July: 5.0 ug/m3). The profile of aromatic VOCs fo llows an approximately similar pattern. Namely, peak monthly-averages are highest during the summer (but not di rectly in July). The TNMOCs also generally crest during the summer. However, TNMOCs also exhibits a strong secondary maximum during the winter months.

Figure 13 shows how average OC and FRM PM 2.5 

### track against increasing average 24-hour TNMOC concentrations during 2001-2009. Fr om this graph, there is a respectable correlation between increasing TNMOCs and increasing both FRM and OC PM 2.5 

### through the TNMOC bin 105-120 ppbC. This correlation is temporarily reversed for TNMOC levels between 120–150 ppbC, only to resume for the next highest TNMOC bin (150-165 ppbC).

Figure 14 is similar to Figure 13, the only difference bei ng that bins of average arom atic concentrations replace TNMOCs as the independent (x-axis) metric . The profiles of average OC and FRM PM 2.5 

### tracking with respect to increasing average 24-hour aromatic levels during 2001-200 9 is quite similar to tracking of TNMOCs (Figure 13). There appears to be an adequate correlation between increasing aromatics and increasing both FRM and OC PM 2.5 

### through the lower half of the aromatics distribution (18-21 ppbC bin). Aroma tic concentrations above 21 ppbC yield generally flat profiles for both FRM and OC.

### 19

### 20 Figure 15 tracks SER’s OC PM 2.5 

### levels as well as its 24-hour-averaged TN MOCs and aromatic concentrations with respect to MKE’s increasing daily average ambient temperature during 2001-2009.

In general, all three pollutants exhibit little coherency for temperatures below 40 F. However, starting from the temperature bin of 40-45 degrees Fahrenheit (F), the TNMOCs and aromatic VOCs are generally increasing with rising temperatures. The OC values follow a similar pattern of growing with higher temperatures, but are commencing for the temperature bin 35-40 F.

Explaining factors that contribute to increasing OC with respect to warmer temperatures is difficult because of the highly nonlinear chemistry of secondary organic aeros ol (SOA) formation, which dominates OC. There is also the smaller fraction of primary OC that is emitted di rectly. As pointed out by Cabada (2004), much of the SOA mass can result from long-range transport, not local chemistry. However, ambient temperature has been shown to sizably influence SOA production rates, based upon reaction chamber studies (Warren, et.al., 2009).

6.7 Analysis of nitrate and FRM PM 2.5 

### and NOx

Figure 16 displays SER’s collective month-of-year average concentrations of 1) median of the daily average 1- hr NOx and 2) same-day daily average NO 3 

### PM 2.5 

### during 2001–2009. The NOx levels display a pattern of being considerably highest during the coldest months (November-F ebruary: 24 ppb average), which is twice the levels during the summer months. Since the NOx emissions do not demonstrate a seasonal bias – and boundary layer heights do not appear to be seasonally dependent, -photoch emistry must play a dominant role in determining seasonal NOx levels (Hayden, et.al., 2003).

The profile of nitrate concentrations are well correlated with NOx levels. Average NO 3 

### is substantially biased higher towards the colder months. (5 ug/m3 average durin g December-February). This is consistent with the NO 3 

### portion of Figure 4. The seed of most nitrate form ation is in gaseous precursor NOx. Gas-phase species nitric acid (HNO 3 

### ) is derived from the oxidation of NOx, which is also favored during the colder weather. NO 3 

### is then produced from equilibrium reactions between HNO 3 

### , and ammonia (NH 3 

### ) (Blanchard and Tanenbaum, 2003). The equilibrium favors the condensed phase at lower temperatures and higher humidities.

Additionally, nitrate is semi-volatile and not stable in higher temperatures (Husar, 199 9). Consequently, all of the above-described charac teristics lead to NO 3 

### concentrations being generally much higher during colder winter months, significantly lower in summer.

Figure 17 highlights how average NO 3 

### and its average percentage fraction of overall FRM PM 2.5 

### levels track with respect to increasing average daily median 1-hou r NOx at Milwaukee-SER during June 2001 – December 2009. This graph reflects the similar NO 3 

### | NOx characteristics to those disp layed in Figure 16. For increasing NOx concentrations (at least up to 35 ppb), there is a strong positive correlation of substantial, steady increases in both average NO 3 

### levels (min. 0.5 ppb to max. 7.0 ppb) and NO 3 

### ’s percentage fraction of the overall FRM PM 2.5 

### values (min. 8.2% to max. 29.2%). For NOx concentrations above 40 ppb, both the NO 3 

### concentrations and NO 3 

### /FRM percentage fractions plateau at very high levels.

Figure 18 shows how SER’s average daily median 1-hour NOx and average daily NO 3 

### trend with respect to increasing MKE’s average daily temperature during June 2001 – December 2009. As expected from both Figures 6 and 16, these pollutants appear to have genera lly negative correlations with increasing temperature at least through the 60-65 F temperature bin. Above 65 F the NO 3 

### and NOx levels have only minor changes.

### 21

### 22

### 23

### 24 6.8 Winter Nitrate Study: Ammonia’s modeled influence on nitrate PM 2.5 

### levels in southeastern Wisconsin

As noted in Section 3, there is almost a complete absence of NH 3 

### measurements in southeastern Wisconsin, which includes Wisconsin’s PM 2.5 

### nonattainment counties of Milwaukee, Waukesha and Racine. Consequently, the influence of NH 3 

### on NO 3 

### levels in this area is derived from a modeling analysis conducted as part of the 2010 Winter Nitrate Study (Stanier, et. al, 2010).

Ammonia (NH 3 

### ) is a gaseous byproduct emitted from agricultural operations such as manure storage, spreading and fertilizer applications. In the atmosphere NH 3 

### reacts with sulfuric acid (H 2 

### SO 4 

### ) and nitric acid (HNO 3 

### ) to form ammonium sulfate (NH 4 

### SO 4 

### ) and ammonium nitrate (NH 4 

### NO 3 

### ) PM 2.5 

### , respectively (Kenski, 2006).

Preliminary analyses by Stanier, et.al. (2010) indicate th at “..local sources of NOx (e.g., nearby highways) are important for the [highly-urbanized] Milw aukee, and that regional sources of NH 3 

### affect both Milwaukee and [rural] Mayville. Stanier and his group further noted th at "During episodes, total nitrate concentrations were about doubled over average concentrations at Milwaukee and tripled at Mayville [where ammonia has a greater presence]." One of their summary conclusions was that "T otal ammonia and total nitrate (and, by extension, NOx) influence episode intensity. Controls of ammonia or nitrate are likely to decrease episode concentrations."

### 25 7 Summary

As stated in Section 1, a primary purpose of this study is to identify long-term characteristics, distributions and profiles in measured PM 2.5 

### and some of PM 2.5 

### gaseous precursors (TNMOCs, aromatic VOCs, NOx) in southeastern Wisconsin. This assessment, which is re quired under sections 40 CFR 51.1002(2) and (3) of the federal Clean Air Act, is needed in order to assess if NOx and / or VOC emission inventories need to be constructed as part of the WDNR’s request for redesignating to attainment for the PM 2.5 

### nonattainment counties in southeastern Wisconsin (Figure 1).

Section 6 details the findings from analyzing these long-term relationships of PM 2.5 

### and PM 2.5 

### precursors in southeastern Wisconsin. Of the many points identified in this study, the following are probably most pertinent to the purpose of the overall study:

 

### Figure 2: The collective average month-of-year PM 2.5 

### concentration at FRM sites in Milwaukee County for November – March 1999-2011 is 15.0 ug/m3, whic h is 26% higher than for the remaining seven months (11.8 ug/m3). For these same sites and time period - the collective average percentage rate of high PM 2.5 

### days (site-days > 30ug/m3) for November – Marc h (6.68%) is more than twice the rate of high PM 2.5 

### site-days during the other seven months (2.97%).

 

### Figures 4 and 5: Organic carbon (OC) is generally the single largest speciated PM 2.5 

### component, with a slight bias towards higher values during the warmer m onths of June – August and comprises almost half the total PM 2.5 

### mass during May - August.

 

### Figure 12: Milwaukee SER’s OC levels peak during the summer months. (July: 5.0 ug/m3). The profile of both TNMOCs and aromatic VOCs also show peak monthly-averages during the summer. However, TNMOCs also exhibits a strong secondary maximum during the winter months.

 

### Figure 13 and 14: There is a respectable correlation between both increasing TNMOCs (Figure 13) as well as aromatic VOCs (Figure 14) and rising levels of both FRM and OC PM 2.5 

### .

 

### Figure 16: SER’s NOx levels are considerably highest during the coldest months (November - February: 24 ppb average), which is twice the levels during the summer months.

 

### Figures 15 and 16: Nitrate concentrations are we ll correlated with NOx levels. The average NO 3 

### is also substantially biased higher towards the colder months (5 ug/m3 average during December-February).

 

### Figure 17: With increasing NOx concentrations, there is a strong positive correlation of substantial, steady increases in both average NO 3 

### levels (min. 0.5 ppb to max. 7.0 ppb) and NO 3 

### ’s percentage fraction of the overall FRM PM 2.5 

### values (min. 8.2% to max. 29.2%).

As noted in several previous sections, there is only a negligible archive of ammonia (NH 3 

### ) measurements in southeastern Wisconsin. Consequently, an assessment of this PM 2.5 

### precursor’s role in influencing PM 2.5 

### levels in Wisconsin’s PM 2.5 

### nonattainment was derived from a recent study on the science of high nitrate PM 2.5 

### levels during winter months in southeastern Wisconsin (i .e., the WNS report [Stanier, et.al., 2010]).

Based upon Stanier’s thermodynamic modeling with a limited (3 months) measurement data set, it was estimated that ammonia has a highly complex relationship to nitrate PM 2.5 

### levels during the winter in southeastern Wisconsin. In genera l, the modeling showed higher NH 3 

### concentrations were associated with higher nitrate levels – more so at th e rural WNS site (Mayville), less so at the urbanized Milwaukee WNS site.

### 26 8 Proposed Recommendations

Exceedances of the 24-hour PM 2.5 

### NAAQS can occur during any time of the year in Wisconsin. However, Figures 2 and 3 demonstrate that PM 2.5 

### has a modest tendency to be highest, along with the best potential to exceed the standard, during November-March in Milwa ukee and Waukesha counties. From these analyses, it is evident that both organic carbon (OC) and nitrate (NO 3 

### ) comprise a substantial fraction of the PM 2.5 

### mass measured in southeastern Wisconsin’s PM 2.5 

### nonattainment area (Figure 1).

These characteristics suggest that the focus of PM 2.5 

### SIP work, including emissions inventory development might be most effective if directed towards PM 2.5 

### -related activity levels and throughput during DecemberFebruary. This three month period is generally defined as the “meteorological winter” in the upper Midwest of the United States.

Based upon these assessments - at this time it could be pr actical to consider the following options on developing emission inventories (EI) for the WDNR’s request to redesignate to attainment the PM 2.5 

### nonattainment counties of Milwaukee, Waukesha and Racine as part of the state implementation plan (SIP) for PM 2.5 

### :

 

### Construct additional emission inventories for the PM 2.5 

### precursors VOCs and NOx, which are shown in this study to yield substantial contri butions to the formation of secondary PM 2.5 

### aerosols (organic carbon [OC] and nitrates [NO 3 

### ]) in southeastern Wisconsin. This demonstration was completed per the requirements contained in 40 CFR 51.1004(c) ("Pollutan ts contributing to fine particle concentrations")

 

### Construct emission inventories for all major PM 2.5 

### -related pollutants (i.e., direct PM 2.5 

### , SO 2 

### , NOx and VOCs). These inventories should target activity levels and throughputs representative of that portion of the calendar when PM 2.5 

### levels are seasonally highest (i.e., an average winter day).

 

### Results from thermodynamic modeling conducted as part of the Winter Nitrate Study (WNS, Stanier, et.al.,2010) indicated that ammonia greatly enhances the production of nitrate PM 2.5 

### during winters in southeastern Wisconsin.

### 27 9 References

Blanchard, C.L. and S. Tanenbaum, 2003: Trends In Ambient NOx AND Particulate Nitrate Concentrations In California, 1980-2000. Final Report CRC Project No. A-43c. Prepared for the Coordinating Research Council, Inc. 111 pp, June.

Cabada, J.C., S.N. Pandis, R. Subramanian, A. Robi nson, A. Polidori and B Turpin, 2004: Estimating the secondary organic aerosol contribution to PM 2.5 

### using EC tracer method. Aerosol Sci & Tech

. 38(S1): 140–155.

Damberg, R., 2007: Policies for Addressing PM 2.5 

### Precursor Emissions. Presentation at US EPA Workshop on PM2.5 Implementation and Area Designation Process for the 2006 PM 2.5 

### Standards. June 20-21, 2007 Chicago, Illinois June 20.

Hayden, K.L., K. L. Hayden, K. G. Anlauf, D. R. H astie and J. W. Bottenheim, 2003: Partitioning of reactive atmospheric nitrogen oxides at an elevated site in southern Quebec, Canada. J. Geophys. Res.108 :4603-4619.

Husar, R., 1999: PM Formation in the Atmosphere . Washington Univ., St. Louis, MO. Web page. http://capita.wustl.edu/pmfine/Workbook/PM Topics_PPT/Pm25Formation/sld001.htm

Kenski, D., 2006: PM2.5 Chemistry and Formation. Presentation at the Northeast Ohio Areawide Coordinating Agency (NOACA), 30 Nov, 23 slides. Available at www.noaca.org/LADCOfpfor.ppt

LADCO (Lake Michigan Air Directors Consortium), 2009: Conceptual Model of PM2.5 Episodes in the Midwest . LADCO PM Data Analysis Workgroup, 40 pp, January.

NARSTO (North American Research of Stra tospheric and Tropospheric Ozone) 2001: NARSTO Assessment of the Atmospheric Science on Particulate Matter. Academic Press, NY, NY.

Pathak, R.K., W.S. Wu, and T. Wang, 2009: Summertime PM2.5 ionic species in four major cities of China: nitrate formation in an ammonia-deficient atmosphere. Atmos. Chem. Phys. 9 :1711–1722

Reid, S., E. Pollard Y. Du, J. Stilley, 2011: A Top-Down Emissions Inventory Evaluation for the Upper Midwest . Sonoma Technology, Inc. Petaluma, CA, Prep ared for National Renewable Energy Laboratory (NREL Contract # AFA-9-99135-0). Final Report 149 pp, May 31.

Robinson, A.L., A. Khlystov, B. Witti g, C.I. Davidson, and S.N. Pandis, 2002: Characteristics and sources of PM2.5 in the Pittsburgh Region. Carnegie Mellon Univ. 14 pp. Available at http://www.netl.doe.gov/publications/proceedings/02/air_q3/CMU.pdf

Seinfeld, J.H. and S.N Pandis, 1998: Atmospheric Chemistry and Physics . Wiley-Interscience, 1325 pp.

Stanier C., A. Bender, G. Carmichael,A . Beranek-Collins, M. Brown, T. Hollo way, A. Jamroensan, S.R. Lee, P. Marrapu, A. Pettibone, S. Sousan, and S. Spak, 2009: Understanding Episodes of High Airborne Particulate Matter in Iowa . Prepared for the Bi-State State Regional Commission. U. Iowa 121 pp, Feb.

Stanier, C., J. Baek, G. Carmichael, S.R. Lee, J. Ols on, N. Riemer, T. Rohlf, S. Sousan and S. Spak, 2010: Episodic Air Pollution in Wisconsin (LADCO Wint er Nitrate Study) and Georgia (SEARCH Network) During Jan-Mar 2009 - Phase I Report . Prepared for the Lake Michigan Air Directors Consortium (LADCO), Oct, 144 pp.

Tai, A.P., Mickley, L.J. Jacob, D.J., 2010: Correlations between fi ne particulate matter and meteorological variables in the U.S.: Implications for sensitivity of PM 2.5 

### to climate change. Atmos. Env. 44 :3976-3984.

### 28 Varadarajan, C., 2007: Development of a Source-Meteorology- Receptor (SMR) Approach using Fine Particulate Intermittent Monitored Con centration Data for Urban Areas in Ohio . Ph.D Dissertation, Civil Engineering, Univ. of Toledo, Civil Engineering. Pages 115p. Available at www.ohiolink.edu/etd/view .cgi?acc_num=toledo1197655960

Warren, B., R.L. Austin and D.R. Cocker, 2009: Te mperature dependence of secondary organic aerosol, Atmos. Environ. 43 :3548–3555.

### APPENDIX 4: 2006 AND 2010 POINT SOURCE EMISSIONS CALCULATIONS

2005 Point Source Emissions FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241004610 Milwaukee NOx 5.383 1.47E-02 241005600 Milwaukee NOx 5.359 1.47E-02 241005710 Milwaukee NOx 19.368 5.31E-02 241006260 Milwaukee NOx 17.330 4.75E-02 241006370 Milwaukee NOx 31.288 8.57E-02 241006810 Milwaukee NOx 4.681 1.28E-02 241006920 Milwaukee NOx 67.520 1.85E-01 241007030 Milwaukee NOx 44.891 1.23E-01 241007690 Milwaukee NOx 4,649.559 1.27E+01 241007800 Milwaukee NOx 3,893.653 1.07E+01 241008130 Milwaukee NOx 9.244 2.53E-02 241008240 Milwaukee NOx 25.935 7.11E-02 241008680 Milwaukee NOx 17.975 4.92E-02 241009670 Milwaukee NOx 21.821 5.98E-02 241010770 Milwaukee NOx 6.142 1.68E-02 241010990 Milwaukee NOx 2.009 5.50E-03 241011100 Milwaukee NOx 34.604 9.48E-02 241011760 Milwaukee NOx 23.039 6.31E-02 241011870 Milwaukee NOx 31.556 8.65E-02 241012200 Milwaukee NOx 9.634 2.64E-02 241012310 Milwaukee NOx 13.470 3.69E-02 241012970 Milwaukee NOx 62.000 1.70E-01 241013080 Milwaukee NOx 3.345 9.17E-03 241014180 Milwaukee NOx 0.774 2.12E-03 241014620 Milwaukee NOx 14.401 3.95E-02 241015390 Milwaukee NOx 7.780 2.13E-02 241016710 Milwaukee NOx 2.932 8.03E-03 241017040 Milwaukee NOx 0.542 1.48E-03 241017370 Milwaukee NOx 0.451 1.24E-03 241017590 Milwaukee NOx 0.488 1.34E-03 241017920 Milwaukee NOx 0.961 2.63E-03 241018140 Milwaukee NOx 1.385 3.79E-03 241019350 Milwaukee NOx 2.790 7.64E-03 241019900 Milwaukee NOx 34.369 9.42E-02 241020780 Milwaukee NOx 1.295 3.55E-03 241021880 Milwaukee NOx 4.059 1.11E-02 241023640 Milwaukee NOx 41.460 1.14E-01 241024190 Milwaukee NOx 7.089 1.94E-02 241024300 Milwaukee NOx 13.436 3.68E-02 241025070 Milwaukee NOx 1.843 5.05E-03 241025290 Milwaukee NOx 2.616 7.17E-03 241025510 Milwaukee NOx 2.606 7.14E-03 241026060 Milwaukee NOx 0.662 1.81E-03 241026500 Milwaukee NOx 1.252 3.43E-03 241027050 Milwaukee NOx 325.606 8.92E-01 241027160 Milwaukee NOx 6.076 1.66E-02 241027380 Milwaukee NOx 3.050 8.36E-03 241027600 Milwaukee NOx 1.841 5.04E-03FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241027930 Milwaukee NOx 7.964 2.18E-02 241028810 Milwaukee NOx 11.882 3.26E-02 241028920 Milwaukee NOx 2.177 5.96E-03 241029030 Milwaukee NOx 9.698 2.66E-02 241029140 Milwaukee NOx 13.930 3.82E-02 241029250 Milwaukee NOx 249.337 6.83E-01 241029470 Milwaukee NOx 0.111 3.04E-04 241029690 Milwaukee NOx 0.906 2.48E-03 241029800 Milwaukee NOx 1.155 3.17E-03 241031120 Milwaukee NOx 13.854 3.80E-02 241031340 Milwaukee NOx 9.382 2.57E-02 241031450 Milwaukee NOx 0.847 2.32E-03 241032440 Milwaukee NOx 0.042 1.16E-04 241032770 Milwaukee NOx 4.356 1.19E-02 241033210 Milwaukee NOx 6.976 1.91E-02 241033430 Milwaukee NOx 1.535 4.20E-03 241033650 Milwaukee NOx 1.225 3.36E-03 241034200 Milwaukee NOx 0.025 6.89E-05 241036840 Milwaukee NOx 0.428 1.17E-03 241036950 Milwaukee NOx 1.914 5.24E-03 241038820 Milwaukee NOx 3.474 9.52E-03 241040690 Milwaukee NOx 1.161 3.18E-03 241041900 Milwaukee NOx 1.810 4.96E-03 241042670 Milwaukee NOx 1.145 3.14E-03 241045420 Milwaukee NOx 0.850 2.33E-03 241045750 Milwaukee NOx 15.592 4.27E-02 241047730 Milwaukee NOx 0.471 1.29E-03 241052680 Milwaukee NOx 4.738 1.30E-02 241053010 Milwaukee NOx 0.783 2.14E-03 241053450 Milwaukee NOx 4.188 1.15E-02 241054330 Milwaukee NOx 0.253 6.92E-04 241055870 Milwaukee NOx 3.741 1.02E-02 241063570 Milwaukee NOx 3.609 9.89E-03 241094370 Milwaukee NOx 0.565 1.55E-03 241094700 Milwaukee NOx 1.188 3.25E-03 241095910 Milwaukee NOx 3.746 1.03E-02 241116700 Milwaukee NOx 2.165 5.93E-03 241167630 Milwaukee NOx 0.680 1.86E-03 241168070 Milwaukee NOx 0.435 1.19E-03 241168180 Milwaukee NOx 7.242 1.98E-02 241168510 Milwaukee NOx 2.646 7.25E-03 241168620 Milwaukee NOx 25.524 6.99E-02 241189520 Milwaukee NOx 0.658 1.80E-03 241202170 Milwaukee NOx 1.458 3.99E-03 241213720 Milwaukee NOx 1.050 2.88E-03 241222410 Milwaukee NOx 0.635 1.74E-03 241225710 Milwaukee NOx 0.080 2.19E-04 241228350 Milwaukee NOx 360.091 9.87E-01 241231760 Milwaukee NOx 0.290 7.95E-04 241232640 Milwaukee NOx 0.056 1.53E-04 241234840 Milwaukee NOx 0.082 2.23E-04 241235940 Milwaukee NOx 0.434 1.19E-03FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241251670 Milwaukee NOx 0.850 2.33E-03 241256290 Milwaukee NOx 0.089 2.44E-04 241256730 Milwaukee NOx 0.690 1.89E-03 241266740 Milwaukee NOx 1.232 3.38E-03 241270810 Milwaukee NOx 0.124 3.41E-04 241276750 Milwaukee NOx 0.444 1.22E-03 241308870 Milwaukee NOx 0.180 4.93E-04 241316020 Milwaukee NOx 0.213 5.83E-04 241321960 Milwaukee NOx 0.001 1.76E-06 241334060 Milwaukee NOx 0.823 2.26E-03 241355400 Milwaukee NOx 5.687 1.56E-02 241371350 Milwaukee NOx 1.104 3.03E-03 241372120 Milwaukee NOx 0.942 2.58E-03 241413810 Milwaukee NOx 0.466 1.28E-03 241442630 Milwaukee NOx 0.585 1.60E-03 241450440 Milwaukee NOx 6.451 1.77E-02 241454290 Milwaukee NOx 1.101 3.02E-03 241454400 Milwaukee NOx 1.529 4.19E-03 241455500 Milwaukee NOx 1.031 2.82E-03 241459790 Milwaukee NOx 0.419 1.15E-03 241472770 Milwaukee NOx 2.199 6.02E-03 241480910 Milwaukee NOx 0.502 1.38E-03 241514570 Milwaukee NOx 0.323 8.86E-04 241670660 Milwaukee NOx 0.609 1.67E-03 241672090 Milwaukee NOx 0.635 1.74E-03 241709930 Milwaukee NOx 0.244 6.69E-04 241723240 Milwaukee NOx 4.466 1.22E-02 241751950 Milwaukee NOx 2.800 7.67E-03 241757340 Milwaukee NOx 5.597 1.53E-02 241779450 Milwaukee NOx 0.621 1.70E-03 241832360 Milwaukee NOx 1.800 4.93E-03 241879550 Milwaukee NOx 1.365 3.74E-03 241961610 Milwaukee NOx 1.800 4.93E-03 241964580 Milwaukee NOx 0.742 2.03E-03 252004280 Milwaukee NOx 5.774 1.58E-02 252004940 Milwaukee NOx 2.591 7.10E-03 252005380 Racine NOx 10.360 2.84E-02 252005820 Racine NOx 6.271 1.72E-02 252005930 Racine NOx 106.620 2.92E-01 252006370 Racine NOx 45.781 1.25E-01 252007030 Racine NOx 0.670 1.84E-03 252007140 Racine NOx 3.053 8.36E-03 252007580 Racine NOx 0.286 7.84E-04 252007690 Racine NOx 3.471 9.51E-03 252008460 Racine NOx 2.937 8.05E-03 252009780 Racine NOx 0.586 1.60E-03 252011870 Racine NOx 7.678 2.10E-02 252012090 Racine NOx 7.233 1.98E-02 252013190 Racine NOx 2.489 6.82E-03 252013630 Racine NOx 1.567 4.29E-03 252019900 Racine NOx 6.923 1.90E-02 252041130 Racine NOx 2.579 7.06E-03FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 252070500 Racine NOx 0.153 4.19E-04 252075340 Racine NOx 0.494 1.35E-03 252076990 Racine NOx 3.552 9.73E-03 252077760 Racine NOx 0.222 6.07E-04 252080070 Racine NOx 0.215 5.89E-04 252091070 Racine NOx 0.465 1.27E-03 252103940 Racine NOx 7.379 2.02E-02 252126380 Racine NOx 0.536 1.47E-03 252135950 Racine NOx 0.786 2.15E-03 252194140 Racine NOx 11.989 3.28E-02 252229670 Racine NOx 0.150 4.12E-04 252236380 Racine NOx 3.936 1.08E-02 268005100 Waukesha NOx 1.054 2.89E-03 268005430 Waukesha NOx 10.944 3.00E-02 268005870 Waukesha NOx 3.745 1.03E-02 268006310 Waukesha NOx 0.032 8.80E-05 268006750 Waukesha NOx 11.293 3.09E-02 268006970 Waukesha NOx 12.521 3.43E-02 268007080 Waukesha NOx 2.367 6.49E-03 268007740 Waukesha NOx 1.771 4.85E-03 268008400 Waukesha NOx 12.800 3.51E-02 268008510 Waukesha NOx 2.400 6.58E-03 268008730 Waukesha NOx 4.428 1.21E-02 268009500 Waukesha NOx 1.888 5.17E-03 268010710 Waukesha NOx 1.863 5.10E-03 268012030 Waukesha NOx 3.885 1.06E-02 268012250 Waukesha NOx 2.274 6.23E-03 268012360 Waukesha NOx 1.015 2.78E-03 268012580 Waukesha NOx 0.175 4.79E-04 268012910 Waukesha NOx 6.602 1.81E-02 268013240 Waukesha NOx 1.641 4.49E-03 268014560 Waukesha NOx 0.156 4.27E-04 268014670 Waukesha NOx 27.868 7.63E-02 268014780 Waukesha NOx 0.210 5.75E-04 268015330 Waukesha NOx 2.854 7.82E-03 268016100 Waukesha NOx 2.735 7.49E-03 268016210 Waukesha NOx 2.630 7.20E-03 268023580 Waukesha NOx 2.145 5.88E-03 268028200 Waukesha NOx 6.419 1.76E-02 268028420 Waukesha NOx 1.240 3.40E-03 268082650 Waukesha NOx 5.568 1.53E-02 268088700 Waukesha NOx 2.814 7.71E-03 268088920 Waukesha NOx 8.236 2.26E-02 268089140 Waukesha NOx 2.866 7.85E-03 268107620 Waukesha NOx 0.557 1.52E-03 268142270 Waukesha NOx 0.499 1.37E-03 268144250 Waukesha NOx 1.357 3.72E-03 268152500 Waukesha NOx 0.585 1.60E-03FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 268152610 Waukesha NOx 0.490 1.34E-03 268154260 Waukesha NOx 0.196 5.37E-04 268154370 Waukesha NOx 1.350 3.70E-03 268157890 Waukesha NOx 5.315 1.46E-02 268158660 Waukesha NOx 0.459 1.26E-03 268161410 Waukesha NOx 0.917 2.51E-03 268164160 Waukesha NOx 0.224 6.14E-04 268165370 Waukesha NOx 0.167 4.58E-04 268168560 Waukesha NOx 2.548 6.98E-03 268171310 Waukesha NOx 1.952 5.35E-03 268173290 Waukesha NOx 0.004 1.21E-05 268175270 Waukesha NOx 0.560 1.53E-03 268180660 Waukesha NOx 0.064 1.76E-04 268183080 Waukesha NOx 13.959 3.82E-02 268185610 Waukesha NOx 4.933 1.35E-02 268186160 Waukesha NOx 0.000 4.32E-07 268198370 Waukesha NOx 0.006 1.69E-05 268203430 Waukesha NOx 0.396 1.09E-03 268204090 Waukesha NOx 0.544 1.49E-03 268213880 Waukesha NOx 0.059 1.60E-04 268218170 Waukesha NOx 0.494 1.35E-03 268219490 Waukesha NOx 0.406 1.11E-03 268221360 Waukesha NOx 4.692 1.29E-02 268221910 Waukesha NOx 0.410 1.12E-03 268227850 Waukesha NOx 0.404 1.11E-03 268228070 Waukesha NOx 0.900 2.47E-03 268239290 Waukesha NOx 0.164 4.49E-04 268244130 Waukesha NOx 12.596 3.45E-02 268255790 Waukesha NOx 1.374 3.76E-03 268257220 Waukesha NOx 5.349 1.47E-02 268262060 Waukesha NOx 0.167 4.57E-04 268266020 Waukesha NOx 0.045 1.23E-04 268270420 Waukesha NOx 0.091 2.49E-04 268270750 Waukesha NOx 0.116 3.18E-04 268289450 Waukesha NOx 0.304 8.32E-04 268290550 Waukesha NOx 1.562 4.28E-03 268342470 Waukesha NOx 0.253 6.93E-04 268376900 Waukesha NOx 1.109 3.04E-03 268404730 Waukesha NOx 0.983 2.69E-03 268414850 Waukesha NOx 0.271 7.42E-04 268423870 Waukesha NOx 0.891 2.44E-03 268457970 Waukesha NOx 52.498 1.44E-01 268463800 Waukesha NOx 2.093 5.73E-03 268523970 Waukesha NOx 4.140 1.13E-02 268525070 Waukesha NOx 1.105 3.03E-03 268544540 Waukesha NOx 0.228 6.23E-04 341003300 Waukesha NOx 0.099 2.72E-04FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 341018810 Waukesha NOx 0.330 9.04E-04 341024310 Waukesha NOx 1.027 2.81E-03 341075460 Waukesha NOx 4.607 1.26E-02 341076780 Waukesha NOx 0.281 7.70E-04 341092510 Waukesha NOx 4.803 1.32E-02 241004610 Milwaukee PM25 0.724 1.98E-03 241005600 Milwaukee PM25 0.144 3.95E-04 241005710 Milwaukee PM25 30.692 8.41E-02 241006260 Milwaukee PM25 66.865 1.83E-01 241006370 Milwaukee PM25 2.409 6.60E-03 241006810 Milwaukee PM25 0.509 1.39E-03 241006920 Milwaukee PM25 2.096 5.74E-03 241007030 Milwaukee PM25 3.757 1.03E-02 241007690 Milwaukee PM25 17.493 4.79E-02 241007800 Milwaukee PM25 8.113 2.22E-02 241008130 Milwaukee PM25 1.266 3.47E-03 241008240 Milwaukee PM25 1.869 5.12E-03 241008350 Milwaukee PM25 1.852 5.07E-03 241008680 Milwaukee PM25 1.618 4.43E-03 241009670 Milwaukee PM25 1.450 3.97E-03 241010770 Milwaukee PM25 3.413 9.35E-03 241010990 Milwaukee PM25 0.053 1.47E-04 241011100 Milwaukee PM25 1.699 4.66E-03 241011760 Milwaukee PM25 2.005 5.49E-03 241011870 Milwaukee PM25 7.061 1.93E-02 241012200 Milwaukee PM25 1.086 2.97E-03 241012310 Milwaukee PM25 13.447 3.68E-02 241012970 Milwaukee PM25 1.671 4.58E-03 241013080 Milwaukee PM25 0.147 4.03E-04 241014180 Milwaukee PM25 0.184 5.04E-04 241014620 Milwaukee PM25 1.093 2.99E-03 241015390 Milwaukee PM25 10.484 2.87E-02 241016710 Milwaukee PM25 0.402 1.10E-03 241017040 Milwaukee PM25 0.041 1.13E-04 241017370 Milwaukee PM25 0.015 3.98E-05 241017590 Milwaukee PM25 0.215 5.88E-04 241017920 Milwaukee PM25 0.029 7.90E-05 241018140 Milwaukee PM25 0.042 1.14E-04 241019350 Milwaukee PM25 0.304 8.33E-04 241019900 Milwaukee PM25 1.901 5.21E-03 241020780 Milwaukee PM25 0.100 2.74E-04 241021880 Milwaukee PM25 4.107 1.13E-02 241023640 Milwaukee PM25 2.804 7.68E-03 241024190 Milwaukee PM25 0.536 1.47E-03 241024300 Milwaukee PM25 1.617 4.43E-03 241025070 Milwaukee PM25 0.184 5.03E-04 241025290 Milwaukee PM25 0.354 9.70E-04FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241025510 Milwaukee PM25 0.234 6.41E-04 241026060 Milwaukee PM25 0.020 5.44E-05 241027050 Milwaukee PM25 26.130 7.16E-02 241027160 Milwaukee PM25 6.816 1.87E-02 241027380 Milwaukee PM25 0.418 1.14E-03 241027600 Milwaukee PM25 0.417 1.14E-03 241027930 Milwaukee PM25 0.157 4.31E-04 241028810 Milwaukee PM25 0.697 1.91E-03 241028920 Milwaukee PM25 0.034 9.29E-05 241029030 Milwaukee PM25 0.269 7.38E-04 241029140 Milwaukee PM25 0.378 1.04E-03 241029250 Milwaukee PM25 34.622 9.49E-02 241029690 Milwaukee PM25 0.013 3.59E-05 241029800 Milwaukee PM25 17.363 4.76E-02 241031120 Milwaukee PM25 1.894 5.19E-03 241031340 Milwaukee PM25 0.885 2.42E-03 241031450 Milwaukee PM25 0.084 2.31E-04 241032440 Milwaukee PM25 0.001 3.49E-06 241032770 Milwaukee PM25 1.629 4.46E-03 241033210 Milwaukee PM25 0.914 2.50E-03 241033430 Milwaukee PM25 0.184 5.05E-04 241033650 Milwaukee PM25 0.037 1.00E-04 241034200 Milwaukee PM25 0.020 5.39E-05 241036840 Milwaukee PM25 0.051 1.41E-04 241036950 Milwaukee PM25 1.604 4.40E-03 241037280 Milwaukee PM25 0.000 3.60E-08 241038820 Milwaukee PM25 0.328 8.99E-04 241040690 Milwaukee PM25 0.159 4.36E-04 241041900 Milwaukee PM25 0.248 6.79E-04 241042670 Milwaukee PM25 0.137 3.76E-04 241045420 Milwaukee PM25 0.116 3.19E-04 241045750 Milwaukee PM25 0.563 1.54E-03 241047730 Milwaukee PM25 0.032 8.65E-05 241052680 Milwaukee PM25 0.358 9.80E-04 241053010 Milwaukee PM25 0.250 6.84E-04 241054330 Milwaukee PM25 0.030 8.30E-05 241055870 Milwaukee PM25 0.284 7.78E-04 241063570 Milwaukee PM25 1.542 4.22E-03 241091400 Milwaukee PM25 1.493 4.09E-03 241094370 Milwaukee PM25 0.017 4.78E-05 241094700 Milwaukee PM25 3.374 9.24E-03 241095910 Milwaukee PM25 1.522 4.17E-03 241116700 Milwaukee PM25 0.065 1.78E-04 241167630 Milwaukee PM25 0.093 2.55E-04 241168070 Milwaukee PM25 0.033 9.06E-05 241168180 Milwaukee PM25 0.707 1.94E-03 241168510 Milwaukee PM25 0.197 5.40E-04FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241168620 Milwaukee PM25 16.610 4.55E-02 241189520 Milwaukee PM25 0.020 5.41E-05 241202170 Milwaukee PM25 0.129 3.53E-04 241222410 Milwaukee PM25 0.076 2.09E-04 241225710 Milwaukee PM25 0.001 3.90E-06 241228350 Milwaukee PM25 2.047 5.61E-03 241231760 Milwaukee PM25 0.035 9.53E-05 241234840 Milwaukee PM25 0.060 1.65E-04 241235940 Milwaukee PM25 0.033 9.05E-05 241256290 Milwaukee PM25 0.011 2.93E-05 241256730 Milwaukee PM25 0.000 4.03E-08 241266740 Milwaukee PM25 0.135 3.71E-04 241270810 Milwaukee PM25 0.016 4.45E-05 241276750 Milwaukee PM25 0.053 1.46E-04 241308870 Milwaukee PM25 0.001 1.64E-06 241316020 Milwaukee PM25 0.016 4.43E-05 241321960 Milwaukee PM25 0.077 2.11E-04 241334060 Milwaukee PM25 0.063 1.71E-04 241335160 Milwaukee PM25 3.750 1.03E-02 241355400 Milwaukee PM25 0.250 6.84E-04 241362660 Milwaukee PM25 0.017 4.64E-05 241371350 Milwaukee PM25 0.084 2.30E-04 241372120 Milwaukee PM25 3.736 1.02E-02 241413810 Milwaukee PM25 0.014 3.83E-05 241442630 Milwaukee PM25 0.230 6.31E-04 241450440 Milwaukee PM25 0.476 1.30E-03 241454290 Milwaukee PM25 0.081 2.21E-04 241454400 Milwaukee PM25 0.116 3.18E-04 241455500 Milwaukee PM25 0.092 2.53E-04 241459790 Milwaukee PM25 0.050 1.38E-04 241472770 Milwaukee PM25 43.815 1.20E-01 241480910 Milwaukee PM25 0.060 1.65E-04 241514570 Milwaukee PM25 0.028 7.59E-05 241670660 Milwaukee PM25 0.046 1.27E-04 241672090 Milwaukee PM25 0.054 1.47E-04 241723240 Milwaukee PM25 0.339 9.30E-04 241751950 Milwaukee PM25 0.384 1.05E-03 241757340 Milwaukee PM25 0.409 1.12E-03 241832360 Milwaukee PM25 0.054 1.48E-04 241879550 Milwaukee PM25 0.041 1.12E-04 241961610 Milwaukee PM25 0.207 5.68E-04 241961720 Milwaukee PM25 0.001 2.12E-06 241964580 Milwaukee PM25 0.015 4.16E-05 341003300 Waukesha PM25 0.007 2.03E-05 341005280 Waukesha PM25 7.983 2.19E-02 341018810 Waukesha PM25 0.025 6.87E-05 341024310 Waukesha PM25 0.562 1.54E-03FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 341062260 Waukesha PM25 0.022 6.16E-05 341075460 Waukesha PM25 0.314 8.61E-04 341076780 Waukesha PM25 0.021 5.85E-05 341092510 Waukesha PM25 0.527 1.44E-03 252004280 Racine PM25 2.520 6.90E-03 252004940 Racine PM25 1.601 4.39E-03 252005380 Racine PM25 4.087 1.12E-02 252005820 Racine PM25 0.477 1.31E-03 252005930 Racine PM25 57.258 1.57E-01 252006370 Racine PM25 1.382 3.79E-03 252007030 Racine PM25 0.051 1.39E-04 252007140 Racine PM25 0.338 9.26E-04 252007580 Racine PM25 0.009 2.35E-05 252007690 Racine PM25 0.264 7.23E-04 252008460 Racine PM25 0.325 8.90E-04 252009780 Racine PM25 0.060 1.64E-04 252011870 Racine PM25 1.258 3.45E-03 252012090 Racine PM25 0.458 1.25E-03 252013190 Racine PM25 0.288 7.90E-04 252013630 Racine PM25 0.129 3.54E-04 252019900 Racine PM25 0.526 1.44E-03 252041130 Racine PM25 0.851 2.33E-03 252070500 Racine PM25 0.018 5.03E-05 252075340 Racine PM25 0.015 4.06E-05 252076990 Racine PM25 0.000 1.77E-07 252077760 Racine PM25 0.006 1.71E-05 252078200 Racine PM25 0.200 5.47E-04 252080070 Racine PM25 0.016 4.48E-05 252091070 Racine PM25 0.014 3.82E-05 252103940 Racine PM25 0.542 1.48E-03 252126380 Racine PM25 0.016 4.40E-05 252135950 Racine PM25 0.079 2.16E-04 252147060 Racine PM25 0.816 2.24E-03 252194140 Racine PM25 0.740 2.03E-03 252194910 Racine PM25 0.055 1.50E-04 252224830 Racine PM25 2.829 7.75E-03 252229670 Racine PM25 0.005 1.24E-05 252236380 Racine PM25 1.454 3.98E-03 268005100 Waukesha PM25 0.126 3.47E-04 268005430 Waukesha PM25 22.824 6.25E-02 268005650 Waukesha PM25 3.324 9.11E-03 268005870 Waukesha PM25 0.285 7.80E-04 268006310 Waukesha PM25 0.103 2.83E-04 268006750 Waukesha PM25 0.803 2.20E-03 268006970 Waukesha PM25 3.237 8.87E-03 268007080 Waukesha PM25 1.150 3.15E-03 268007740 Waukesha PM25 0.135 3.69E-04FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 268008400 Waukesha PM25 0.205 5.60E-04 268008510 Waukesha PM25 0.164 4.48E-04 268008730 Waukesha PM25 1.003 2.75E-03 268009500 Waukesha PM25 1.760 4.82E-03 268010710 Waukesha PM25 0.002 5.10E-06 268012030 Waukesha PM25 1.935 5.30E-03 268012250 Waukesha PM25 0.066 1.81E-04 268012360 Waukesha PM25 0.013 3.60E-05 268012580 Waukesha PM25 0.021 5.75E-05 268012910 Waukesha PM25 0.476 1.30E-03 268013240 Waukesha PM25 0.288 7.90E-04 268014120 Waukesha PM25 1.098 3.01E-03 268014560 Waukesha PM25 0.008 2.27E-05 268014670 Waukesha PM25 0.600 1.64E-03 268014780 Waukesha PM25 0.006 1.73E-05 268015330 Waukesha PM25 0.261 7.15E-04 268016100 Waukesha PM25 0.213 5.85E-04 268016210 Waukesha PM25 0.017 4.67E-05 268023580 Waukesha PM25 0.257 7.05E-04 268028200 Waukesha PM25 0.493 1.35E-03 268028420 Waukesha PM25 0.071 1.94E-04 268082650 Waukesha PM25 0.204 5.58E-04 268088700 Waukesha PM25 0.458 1.26E-03 268088920 Waukesha PM25 9.323 2.55E-02 268089140 Waukesha PM25 1.161 3.18E-03 268107620 Waukesha PM25 0.017 4.57E-05 268142270 Waukesha PM25 0.060 1.64E-04 268144250 Waukesha PM25 0.008 2.27E-05 268152500 Waukesha PM25 0.000 4.01E-08 268152610 Waukesha PM25 0.000 3.35E-08 268154260 Waukesha PM25 0.005 1.34E-05 268154370 Waukesha PM25 0.975 2.67E-03 268157890 Waukesha PM25 0.096 2.64E-04 268158660 Waukesha PM25 0.007 1.96E-05 268161410 Waukesha PM25 0.110 3.01E-04 268164160 Waukesha PM25 0.002 6.58E-06 268165370 Waukesha PM25 0.020 5.50E-05 268168560 Waukesha PM25 0.303 8.29E-04 268170320 Waukesha PM25 0.000 7.26E-08 268171310 Waukesha PM25 0.120 3.29E-04 268173290 Waukesha PM25 0.000 1.28E-07 268175270 Waukesha PM25 0.067 1.84E-04 268180660 Waukesha PM25 0.430 1.18E-03 268183080 Waukesha PM25 0.280 7.68E-04 268185610 Waukesha PM25 0.538 1.47E-03 268186160 Waukesha PM25 0.000 1.29E-08 268198370 Waukesha PM25 1.730 4.74E-03FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 268203430 Waukesha PM25 0.030 8.25E-05 268204090 Waukesha PM25 0.005 1.28E-05 268213880 Waukesha PM25 0.002 4.81E-06 268218170 Waukesha PM25 0.059 1.62E-04 268219490 Waukesha PM25 1.206 3.30E-03 268221910 Waukesha PM25 0.031 8.55E-05 268227850 Waukesha PM25 0.031 8.40E-05 268228070 Waukesha PM25 0.108 2.96E-04 268239290 Waukesha PM25 0.022 6.15E-05 268255790 Waukesha PM25 0.103 2.81E-04 268257220 Waukesha PM25 0.597 1.64E-03 268262060 Waukesha PM25 0.020 5.49E-05 268266020 Waukesha PM25 0.001 3.70E-06 268270750 Waukesha PM25 0.003 9.55E-06 268289450 Waukesha PM25 0.614 1.68E-03 268290550 Waukesha PM25 0.160 4.39E-04 268299130 Waukesha PM25 1.971 5.40E-03 268353800 Waukesha PM25 0.000 1.59E-08 268376900 Waukesha PM25 0.956 2.62E-03 268404730 Waukesha PM25 0.076 2.07E-04 268414850 Waukesha PM25 0.008 2.23E-05 268423870 Waukesha PM25 0.052 1.43E-04 268457970 Waukesha PM25 0.392 1.07E-03 268463800 Waukesha PM25 2.249 6.16E-03 268523970 Waukesha PM25 0.761 2.08E-03 268525070 Waukesha PM25 0.084 2.30E-04 268544540 Waukesha PM25 0.006 1.77E-05 241004610 Milwaukee SO2 0.034 9.31E-05 241005600 Milwaukee SO2 0.044 1.21E-04 241005710 Milwaukee SO2 2.358 6.46E-03 241006260 Milwaukee SO2 11.733 3.21E-02 241006370 Milwaukee SO2 54.643 1.50E-01 241006810 Milwaukee SO2 0.023 6.43E-05 241006920 Milwaukee SO2 0.402 1.10E-03 241007030 Milwaukee SO2 2.468 6.76E-03 241007690 Milwaukee SO2 12,902.614 3.53E+01 241007800 Milwaukee SO2 8,483.158 2.32E+01 241008130 Milwaukee SO2 0.120 3.28E-04 241008240 Milwaukee SO2 0.144 3.93E-04 241008680 Milwaukee SO2 1.244 3.41E-03 241009670 Milwaukee SO2 0.118 3.23E-04 241010770 Milwaukee SO2 0.037 1.01E-04 241010990 Milwaukee SO2 0.303 8.29E-04 241011100 Milwaukee SO2 95.890 2.63E-01 241011760 Milwaukee SO2 32.553 8.92E-02 241011870 Milwaukee SO2 1.171 3.21E-03 241012200 Milwaukee SO2 0.058 1.58E-04FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241012310 Milwaukee SO2 3.680 1.01E-02 241012970 Milwaukee SO2 0.216 5.90E-04 241013080 Milwaukee SO2 0.020 5.50E-05 241014180 Milwaukee SO2 0.015 3.98E-05 241014620 Milwaukee SO2 0.090 2.48E-04 241015390 Milwaukee SO2 0.730 2.00E-03 241016710 Milwaukee SO2 0.018 4.82E-05 241017040 Milwaukee SO2 0.003 8.91E-06 241017370 Milwaukee SO2 0.003 7.41E-06 241017590 Milwaukee SO2 0.003 8.02E-06 241017920 Milwaukee SO2 0.006 1.58E-05 241018140 Milwaukee SO2 0.008 2.28E-05 241019350 Milwaukee SO2 0.021 5.81E-05 241019900 Milwaukee SO2 0.298 8.18E-04 241020780 Milwaukee SO2 0.017 4.55E-05 241021880 Milwaukee SO2 0.445 1.22E-03 241023640 Milwaukee SO2 0.233 6.38E-04 241024190 Milwaukee SO2 0.071 1.95E-04 241024300 Milwaukee SO2 0.216 5.92E-04 241025070 Milwaukee SO2 0.112 3.06E-04 241025290 Milwaukee SO2 0.016 4.30E-05 241025510 Milwaukee SO2 0.016 4.28E-05 241026060 Milwaukee SO2 0.004 1.09E-05 241026500 Milwaukee SO2 0.008 2.06E-05 241027050 Milwaukee SO2 484.337 1.33E+00 241027160 Milwaukee SO2 0.002 5.38E-06 241027380 Milwaukee SO2 0.018 5.01E-05 241027600 Milwaukee SO2 12.388 3.39E-02 241027930 Milwaukee SO2 0.048 1.31E-04 241028810 Milwaukee SO2 0.472 1.29E-03 241028920 Milwaukee SO2 0.013 3.58E-05 241029030 Milwaukee SO2 0.069 1.90E-04 241029140 Milwaukee SO2 0.030 8.18E-05 241029250 Milwaukee SO2 0.501 1.37E-03 241029470 Milwaukee SO2 0.001 1.82E-06 241029690 Milwaukee SO2 1.534 4.20E-03 241029800 Milwaukee SO2 4.631 1.27E-02 241031120 Milwaukee SO2 0.083 2.27E-04 241031340 Milwaukee SO2 0.068 1.87E-04 241031450 Milwaukee SO2 0.288 7.90E-04 241032440 Milwaukee SO2 0.000 6.98E-07 241032770 Milwaukee SO2 0.029 7.84E-05 241033210 Milwaukee SO2 0.046 1.26E-04 241033430 Milwaukee SO2 0.009 2.52E-05 241033650 Milwaukee SO2 0.008 2.09E-05 241034200 Milwaukee SO2 0.001 1.75E-06 241036840 Milwaukee SO2 0.003 7.04E-06FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241036950 Milwaukee SO2 0.011 2.89E-05 241038820 Milwaukee SO2 0.021 5.71E-05 241040690 Milwaukee SO2 0.007 1.91E-05 241041900 Milwaukee SO2 0.011 2.98E-05 241042670 Milwaukee SO2 0.007 1.88E-05 241045420 Milwaukee SO2 0.005 1.40E-05 241045750 Milwaukee SO2 0.375 1.03E-03 241047730 Milwaukee SO2 0.010 2.82E-05 241052680 Milwaukee SO2 0.169 4.63E-04 241053010 Milwaukee SO2 0.022 5.98E-05 241053450 Milwaukee SO2 0.018 4.91E-05 241054330 Milwaukee SO2 0.002 4.15E-06 241055870 Milwaukee SO2 0.023 6.32E-05 241063570 Milwaukee SO2 0.017 4.59E-05 241094370 Milwaukee SO2 0.002 6.63E-06 241094700 Milwaukee SO2 0.007 1.95E-05 241095910 Milwaukee SO2 0.163 4.46E-04 241116700 Milwaukee SO2 0.013 3.56E-05 241167630 Milwaukee SO2 0.006 1.55E-05 241168180 Milwaukee SO2 0.050 1.36E-04 241168510 Milwaukee SO2 0.033 9.12E-05 241189520 Milwaukee SO2 0.004 1.08E-05 241202170 Milwaukee SO2 0.009 2.40E-05 241213720 Milwaukee SO2 0.006 1.73E-05 241222410 Milwaukee SO2 0.004 1.04E-05 241225710 Milwaukee SO2 0.000 9.39E-07 241228350 Milwaukee SO2 1.852 5.07E-03 241231760 Milwaukee SO2 0.002 4.77E-06 241232640 Milwaukee SO2 0.000 9.21E-07 241234840 Milwaukee SO2 0.000 1.34E-06 241235940 Milwaukee SO2 0.003 7.14E-06 241251670 Milwaukee SO2 0.005 1.40E-05 241256290 Milwaukee SO2 0.001 1.46E-06 241256730 Milwaukee SO2 0.004 1.13E-05 241266740 Milwaukee SO2 0.007 1.79E-05 241270810 Milwaukee SO2 0.001 2.91E-06 241276750 Milwaukee SO2 0.003 7.29E-06 241308870 Milwaukee SO2 0.001 2.96E-06 241316020 Milwaukee SO2 0.001 3.50E-06 241321960 Milwaukee SO2 0.004 1.06E-05 241334060 Milwaukee SO2 0.005 1.35E-05 241355400 Milwaukee SO2 2.850 7.81E-03 241362660 Milwaukee SO2 0.004 1.12E-05 241371350 Milwaukee SO2 0.007 1.82E-05 241372120 Milwaukee SO2 0.032 8.70E-05 241413810 Milwaukee SO2 0.003 7.66E-06 241442630 Milwaukee SO2 0.018 4.92E-05FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241450440 Milwaukee SO2 0.151 4.14E-04 241454290 Milwaukee SO2 0.007 1.81E-05 241454400 Milwaukee SO2 0.009 2.51E-05 241459790 Milwaukee SO2 0.003 6.89E-06 241472770 Milwaukee SO2 2.856 7.82E-03 241480910 Milwaukee SO2 0.003 8.25E-06 241514570 Milwaukee SO2 0.001 3.80E-06 241670660 Milwaukee SO2 0.004 1.00E-05 241672090 Milwaukee SO2 0.004 1.04E-05 241709930 Milwaukee SO2 0.001 4.02E-06 241723240 Milwaukee SO2 0.027 7.34E-05 241751950 Milwaukee SO2 0.017 4.60E-05 241757340 Milwaukee SO2 0.034 9.20E-05 241832360 Milwaukee SO2 0.011 2.96E-05 241879550 Milwaukee SO2 0.008 2.24E-05 241961610 Milwaukee SO2 0.011 2.96E-05 241964580 Milwaukee SO2 0.004 1.11E-05 341003300 Waukesha SO2 0.001 1.60E-06 341018810 Waukesha SO2 0.002 5.42E-06 341024310 Waukesha SO2 0.006 1.69E-05 341075460 Waukesha SO2 0.028 7.57E-05 341076780 Waukesha SO2 0.002 4.62E-06 341092510 Waukesha SO2 0.232 6.36E-04 252004280 Milwaukee SO2 0.575 1.57E-03 252004940 Milwaukee SO2 0.666 1.82E-03 252005380 Racine SO2 9.060 2.48E-02 252005820 Racine SO2 0.162 4.43E-04 252005930 Racine SO2 232.779 6.38E-01 252006370 Racine SO2 0.686 1.88E-03 252007030 Racine SO2 0.004 1.10E-05 252007140 Racine SO2 0.090 2.47E-04 252007580 Racine SO2 0.002 4.70E-06 252007690 Racine SO2 0.021 5.71E-05 252008460 Racine SO2 0.049 1.34E-04 252009780 Racine SO2 0.007 1.81E-05 252011870 Racine SO2 0.046 1.26E-04 252012090 Racine SO2 0.172 4.72E-04 252013190 Racine SO2 3.292 9.02E-03 252013630 Racine SO2 0.009 2.58E-05 252019900 Racine SO2 0.047 1.28E-04 252041130 Racine SO2 0.018 4.81E-05 252070500 Racine SO2 0.001 2.52E-06 252075340 Racine SO2 0.003 8.12E-06 252076990 Racine SO2 1.015 2.78E-03 252077760 Racine SO2 0.001 3.64E-06 252080070 Racine SO2 0.001 3.53E-06 252091070 Racine SO2 0.003 7.64E-06FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 252103940 Racine SO2 0.068 1.86E-04 252126380 Racine SO2 0.003 8.81E-06 252135950 Racine SO2 0.009 2.55E-05 252194140 Racine SO2 0.705 1.93E-03 252229670 Racine SO2 0.001 2.47E-06 252236380 Racine SO2 0.128 3.51E-04 268005100 Waukesha SO2 0.006 1.73E-05 268005430 Waukesha SO2 1.592 4.36E-03 268005870 Waukesha SO2 0.022 6.16E-05 268006310 Waukesha SO2 0.039 1.06E-04 268006750 Waukesha SO2 0.119 3.25E-04 268006970 Waukesha SO2 0.812 2.23E-03 268007080 Waukesha SO2 1.352 3.70E-03 268007740 Waukesha SO2 0.011 2.91E-05 268008400 Waukesha SO2 0.077 2.10E-04 268008510 Waukesha SO2 0.014 3.95E-05 268008730 Waukesha SO2 0.230 6.31E-04 268009500 Waukesha SO2 0.132 3.62E-04 268010710 Waukesha SO2 0.011 3.06E-05 268012030 Waukesha SO2 0.076 2.09E-04 268012250 Waukesha SO2 0.014 3.74E-05 268012360 Waukesha SO2 0.006 1.67E-05 268012580 Waukesha SO2 0.001 2.88E-06 268012910 Waukesha SO2 8.098 2.22E-02 268013240 Waukesha SO2 0.193 5.29E-04 268014560 Waukesha SO2 0.001 2.56E-06 268014670 Waukesha SO2 0.463 1.27E-03 268014780 Waukesha SO2 0.001 3.45E-06 268015330 Waukesha SO2 0.017 4.69E-05 268016100 Waukesha SO2 0.016 4.50E-05 268016210 Waukesha SO2 0.016 4.32E-05 268023580 Waukesha SO2 0.013 3.53E-05 268028200 Waukesha SO2 6.436 1.76E-02 268028420 Waukesha SO2 5.305 1.45E-02 268082650 Waukesha SO2 0.024 6.54E-05 268088700 Waukesha SO2 0.331 9.07E-04 268088920 Waukesha SO2 2.872 7.87E-03 268089140 Waukesha SO2 0.000 1.40E-07 268107620 Waukesha SO2 0.003 9.15E-06 268142270 Waukesha SO2 0.003 8.21E-06 268144250 Waukesha SO2 0.006 1.72E-05 268152500 Waukesha SO2 0.317 8.69E-04 268152610 Waukesha SO2 0.215 5.89E-04 268154260 Waukesha SO2 0.001 3.22E-06 268154370 Waukesha SO2 0.008 2.22E-05 268157890 Waukesha SO2 0.015 4.15E-05 268158660 Waukesha SO2 0.002 6.56E-06FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 268161410 Waukesha SO2 0.005 1.51E-05 268164160 Waukesha SO2 0.000 1.32E-06 268165370 Waukesha SO2 0.001 2.75E-06 268168560 Waukesha SO2 5.467 1.50E-02 268170320 Waukesha SO2 0.000 1.75E-08 268171310 Waukesha SO2 0.048 1.33E-04 268173290 Waukesha SO2 0.000 7.28E-08 268175270 Waukesha SO2 0.003 9.21E-06 268180660 Waukesha SO2 0.000 1.06E-06 268183080 Waukesha SO2 0.084 2.29E-04 268185610 Waukesha SO2 9.119 2.50E-02 268186160 Waukesha SO2 0.000 2.59E-09 268198370 Waukesha SO2 0.012 3.39E-05 268203430 Waukesha SO2 0.002 6.51E-06 268204090 Waukesha SO2 0.004 9.84E-06 268213880 Waukesha SO2 0.000 9.62E-07 268218170 Waukesha SO2 0.003 8.12E-06 268219490 Waukesha SO2 0.044 1.20E-04 268221910 Waukesha SO2 0.002 6.75E-06 268227850 Waukesha SO2 0.002 6.63E-06 268228070 Waukesha SO2 0.005 1.48E-05 268239290 Waukesha SO2 0.001 2.69E-06 268244130 Waukesha SO2 7.849 2.15E-02 268255790 Waukesha SO2 0.085 2.33E-04 268257220 Waukesha SO2 4.199 1.15E-02 268262060 Waukesha SO2 0.001 2.74E-06 268266020 Waukesha SO2 0.000 7.40E-07 268270420 Waukesha SO2 0.001 1.49E-06 268270750 Waukesha SO2 0.001 1.91E-06 268289450 Waukesha SO2 0.020 5.47E-05 268290550 Waukesha SO2 0.010 2.65E-05 268376900 Waukesha SO2 0.073 2.00E-04 268404730 Waukesha SO2 0.006 1.62E-05 268414850 Waukesha SO2 0.002 4.45E-06 268423870 Waukesha SO2 0.005 1.34E-05 268457970 Waukesha SO2 0.128 3.50E-04 268463800 Waukesha SO2 0.138 3.77E-04 268523970 Waukesha SO2 0.039 1.06E-04 268525070 Waukesha SO2 0.007 1.82E-05 268544540 Waukesha SO2 0.001 3.74E-06 241004610 Milwaukee VOC 0.311 8.52E-04 241005490 Milwaukee VOC 4.863 1.33E-02 241005600 Milwaukee VOC 2.400 6.57E-03 241005710 Milwaukee VOC 30.894 8.46E-02 241006260 Milwaukee VOC 126.611 3.47E-01 241006370 Milwaukee VOC 53.502 1.47E-01 241006810 Milwaukee VOC 9.806 2.69E-02FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241006920 Milwaukee VOC 10.041 2.75E-02 241007030 Milwaukee VOC 122.860 3.37E-01 241007690 Milwaukee VOC 114.873 3.15E-01 241007800 Milwaukee VOC 27.471 7.53E-02 241008130 Milwaukee VOC 7.583 2.08E-02 241008240 Milwaukee VOC 4.275 1.17E-02 241008680 Milwaukee VOC 45.339 1.24E-01 241009670 Milwaukee VOC 5.412 1.48E-02 241010770 Milwaukee VOC 5.923 1.62E-02 241010990 Milwaukee VOC 13.150 3.60E-02 241011100 Milwaukee VOC 1.836 5.03E-03 241011760 Milwaukee VOC 18.201 4.99E-02 241011870 Milwaukee VOC 28.286 7.75E-02 241012200 Milwaukee VOC 11.954 3.28E-02 241012310 Milwaukee VOC 51.514 1.41E-01 241012970 Milwaukee VOC 10.306 2.82E-02 241013080 Milwaukee VOC 0.184 5.04E-04 241014180 Milwaukee VOC 3.553 9.74E-03 241014620 Milwaukee VOC 427.502 1.17E+00 241015390 Milwaukee VOC 30.708 8.41E-02 241016710 Milwaukee VOC 0.189 5.19E-04 241017040 Milwaukee VOC 2.310 6.33E-03 241017370 Milwaukee VOC 2.967 8.13E-03 241017590 Milwaukee VOC 28.258 7.74E-02 241017700 Milwaukee VOC 8.075 2.21E-02 241017920 Milwaukee VOC 24.347 6.67E-02 241018140 Milwaukee VOC 5.802 1.59E-02 241019350 Milwaukee VOC 5.231 1.43E-02 241019460 Milwaukee VOC 13.323 3.65E-02 241019900 Milwaukee VOC 2.655 7.27E-03 241020780 Milwaukee VOC 15.694 4.30E-02 241021220 Milwaukee VOC 56.165 1.54E-01 241021880 Milwaukee VOC 15.657 4.29E-02 241023640 Milwaukee VOC 32.178 8.82E-02 241024190 Milwaukee VOC 0.453 1.24E-03 241024300 Milwaukee VOC 1.454 3.98E-03 241025070 Milwaukee VOC 0.732 2.01E-03 241025290 Milwaukee VOC 1.102 3.02E-03 241025510 Milwaukee VOC 0.138 3.78E-04 241026060 Milwaukee VOC 0.871 2.39E-03 241026500 Milwaukee VOC 15.986 4.38E-02 241027050 Milwaukee VOC 2.260 6.19E-03 241027160 Milwaukee VOC 0.119 3.25E-04 241027380 Milwaukee VOC 0.168 4.60E-04 241027600 Milwaukee VOC 34.896 9.56E-02 241027930 Milwaukee VOC 0.426 1.17E-03 241028810 Milwaukee VOC 88.873 2.43E-01FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241028920 Milwaukee VOC 57.280 1.57E-01 241029030 Milwaukee VOC 33.219 9.10E-02 241029140 Milwaukee VOC 0.274 7.50E-04 241029250 Milwaukee VOC 45.751 1.25E-01 241029470 Milwaukee VOC 0.028 7.78E-05 241029690 Milwaukee VOC 0.223 6.11E-04 241029800 Milwaukee VOC 48.579 1.33E-01 241031120 Milwaukee VOC 0.760 2.08E-03 241031340 Milwaukee VOC 102.247 2.80E-01 241031450 Milwaukee VOC 0.148 4.05E-04 241032440 Milwaukee VOC 4.266 1.17E-02 241032770 Milwaukee VOC 19.222 5.27E-02 241033210 Milwaukee VOC 0.376 1.03E-03 241033430 Milwaukee VOC 42.387 1.16E-01 241033650 Milwaukee VOC 2.340 6.41E-03 241033760 Milwaukee VOC 8.554 2.34E-02 241034200 Milwaukee VOC 5.084 1.39E-02 241034420 Milwaukee VOC 2.382 6.53E-03 241036840 Milwaukee VOC 0.696 1.91E-03 241036950 Milwaukee VOC 0.097 2.65E-04 241037280 Milwaukee VOC 0.130 3.56E-04 241038820 Milwaukee VOC 4.050 1.11E-02 241040690 Milwaukee VOC 15.996 4.38E-02 241041130 Milwaukee VOC 37.700 1.03E-01 241041900 Milwaukee VOC 0.813 2.23E-03 241042670 Milwaukee VOC 7.500 2.05E-02 241043880 Milwaukee VOC 3.663 1.00E-02 241045420 Milwaukee VOC 0.047 1.28E-04 241045750 Milwaukee VOC 0.683 1.87E-03 241046410 Milwaukee VOC 0.245 6.70E-04 241047730 Milwaukee VOC 3.597 9.86E-03 241049160 Milwaukee VOC 3.884 1.06E-02 241049710 Milwaukee VOC 8.479 2.32E-02 241052680 Milwaukee VOC 4.275 1.17E-02 241053010 Milwaukee VOC 0.582 1.59E-03 241053450 Milwaukee VOC 0.596 1.63E-03 241053560 Milwaukee VOC 1.890 5.18E-03 241054330 Milwaukee VOC 1.514 4.15E-03 241055870 Milwaukee VOC 0.206 5.63E-04 241063570 Milwaukee VOC 57.067 1.56E-01 241078640 Milwaukee VOC 11.974 3.28E-02 241079300 Milwaukee VOC 1.643 4.50E-03 241094370 Milwaukee VOC 11.997 3.29E-02 241094700 Milwaukee VOC 4.761 1.30E-02 241095910 Milwaukee VOC 0.202 5.54E-04 241116700 Milwaukee VOC 10.560 2.89E-02 241164770 Milwaukee VOC 18.070 4.95E-02FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241167630 Milwaukee VOC 0.039 1.07E-04 241168070 Milwaukee VOC 1.083 2.97E-03 241168180 Milwaukee VOC 0.399 1.09E-03 241168510 Milwaukee VOC 1.275 3.49E-03 241168620 Milwaukee VOC 0.319 8.75E-04 241174560 Milwaukee VOC 20.198 5.53E-02 241189520 Milwaukee VOC 4.548 1.25E-02 241197990 Milwaukee VOC 3.014 8.26E-03 241202170 Milwaukee VOC 0.270 7.40E-04 241213720 Milwaukee VOC 3.940 1.08E-02 241222410 Milwaukee VOC 0.486 1.33E-03 241225710 Milwaukee VOC 10.770 2.95E-02 241227910 Milwaukee VOC 4.951 1.36E-02 241228350 Milwaukee VOC 18.033 4.94E-02 241231760 Milwaukee VOC 0.016 4.37E-05 241232640 Milwaukee VOC 4.069 1.11E-02 241234840 Milwaukee VOC 3.243 8.89E-03 241235940 Milwaukee VOC 3.606 9.88E-03 241245180 Milwaukee VOC 21.204 5.81E-02 241251670 Milwaukee VOC 1.887 5.17E-03 241256290 Milwaukee VOC 4.410 1.21E-02 241256730 Milwaukee VOC 5.687 1.56E-02 241266740 Milwaukee VOC 13.891 3.81E-02 241270810 Milwaukee VOC 16.326 4.47E-02 241276750 Milwaukee VOC 33.487 9.17E-02 241308870 Milwaukee VOC 7.458 2.04E-02 241309090 Milwaukee VOC 14.578 3.99E-02 241316020 Milwaukee VOC 9.362 2.56E-02 241318330 Milwaukee VOC 1.634 4.48E-03 241321850 Milwaukee VOC 4.132 1.13E-02 241321960 Milwaukee VOC 0.035 9.68E-05 241325590 Milwaukee VOC 10.455 2.86E-02 241334060 Milwaukee VOC 13.164 3.61E-02 241355400 Milwaukee VOC 0.057 1.55E-04 241362660 Milwaukee VOC 4.403 1.21E-02 241371350 Milwaukee VOC 0.345 9.46E-04 241372120 Milwaukee VOC 4.617 1.26E-02 241413810 Milwaukee VOC 6.082 1.67E-02 241428550 Milwaukee VOC 17.275 4.73E-02 241435260 Milwaukee VOC 16.512 4.52E-02 241442630 Milwaukee VOC 21.255 5.82E-02 241450440 Milwaukee VOC 0.347 9.51E-04 241454290 Milwaukee VOC 26.392 7.23E-02 241454400 Milwaukee VOC 0.084 2.30E-04 241455500 Milwaukee VOC 5.757 1.58E-02 241459790 Milwaukee VOC 0.641 1.75E-03 241472770 Milwaukee VOC 0.280 7.68E-04FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 241473650 Milwaukee VOC 5.405 1.48E-02 241480910 Milwaukee VOC 5.023 1.38E-02 241514570 Milwaukee VOC 4.906 1.34E-02 241536350 Milwaukee VOC 0.434 1.19E-03 241670660 Milwaukee VOC 18.923 5.18E-02 241672090 Milwaukee VOC 0.035 9.57E-05 241684630 Milwaukee VOC 8.569 2.35E-02 241709930 Milwaukee VOC 5.227 1.43E-02 241714000 Milwaukee VOC 17.276 4.73E-02 241723240 Milwaukee VOC 12.330 3.38E-02 241723460 Milwaukee VOC 1.432 3.92E-03 241741940 Milwaukee VOC 8.611 2.36E-02 241751950 Milwaukee VOC 3.822 1.05E-02 241757340 Milwaukee VOC 41.068 1.13E-01 241805300 Milwaukee VOC 5.584 1.53E-02 241832360 Milwaukee VOC 1.830 5.01E-03 241879550 Milwaukee VOC 1.435 3.93E-03 241916180 Milwaukee VOC 2.220 6.08E-03 241961610 Milwaukee VOC 0.095 2.61E-04 241961720 Milwaukee VOC 14.101 3.86E-02 241964580 Milwaukee VOC 6.213 1.70E-02 241967440 Milwaukee VOC 1.829 5.01E-03 341003300 Waukesha VOC 7.088 1.94E-02 341018810 Waukesha VOC 6.131 1.68E-02 341024310 Waukesha VOC 17.245 4.72E-02 341027170 Waukesha VOC 7.004 1.92E-02 341037290 Waukesha VOC 8.995 2.46E-02 341039270 Waukesha VOC 7.849 2.15E-02 341062260 Waukesha VOC 9.256 2.54E-02 341075460 Waukesha VOC 9.800 2.69E-02 341076780 Waukesha VOC 0.826 2.26E-03 341092510 Waukesha VOC 0.836 2.29E-03 252004280 Milwaukee VOC 0.174 4.78E-04 252004720 Milwaukee VOC 1.635 4.48E-03 252004940 Racine VOC 37.638 1.03E-01 252005380 Racine VOC 17.450 4.78E-02 252005820 Racine VOC 0.343 9.39E-04 252005930 Racine VOC 26.726 7.32E-02 252006370 Racine VOC 187.968 5.15E-01 252007030 Racine VOC 0.037 1.01E-04 252007140 Racine VOC 2.875 7.88E-03 252007580 Racine VOC 0.351 9.62E-04 252007690 Racine VOC 8.268 2.27E-02 252008460 Racine VOC 4.772 1.31E-02 252009780 Racine VOC 16.336 4.48E-02 252011870 Racine VOC 3.524 9.66E-03 252012090 Racine VOC 2.151 5.89E-03FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 252013190 Racine VOC 0.025 6.82E-05 252013630 Racine VOC 16.277 4.46E-02 252019900 Racine VOC 0.381 1.04E-03 252041130 Racine VOC 8.906 2.44E-02 252070500 Racine VOC 5.201 1.42E-02 252075340 Racine VOC 5.131 1.41E-02 252076990 Racine VOC 1.162 3.18E-03 252077760 Racine VOC 3.008 8.24E-03 252078200 Racine VOC 0.866 2.37E-03 252080070 Racine VOC 4.940 1.35E-02 252081390 Racine VOC 3.588 9.83E-03 252091070 Racine VOC 2.665 7.30E-03 252103940 Racine VOC 0.399 1.09E-03 252109550 Racine VOC 5.098 1.40E-02 252111530 Racine VOC 0.045 1.24E-04 252126380 Racine VOC 4.328 1.19E-02 252128580 Racine VOC 1.099 3.01E-03 252135950 Racine VOC 0.834 2.28E-03 252173680 Racine VOC 11.730 3.21E-02 252194140 Racine VOC 27.126 7.43E-02 252195350 Racine VOC 0.684 1.87E-03 252229670 Racine VOC 5.819 1.59E-02 252236380 Racine VOC 9.773 2.68E-02 252236490 Racine VOC 1.612 4.42E-03 252237260 Racine VOC 0.272 7.45E-04 268005100 Waukesha VOC 0.058 1.59E-04 268005430 Waukesha VOC 105.537 2.89E-01 268005870 Waukesha VOC 0.206 5.64E-04 268006310 Waukesha VOC 4.029 1.10E-02 268006750 Waukesha VOC 13.022 3.57E-02 268006970 Waukesha VOC 1.224 3.35E-03 268007080 Waukesha VOC 2.084 5.71E-03 268007410 Waukesha VOC 1.381 3.78E-03 268007740 Waukesha VOC 29.497 8.08E-02 268008400 Waukesha VOC 61.958 1.70E-01 268008510 Waukesha VOC 75.299 2.06E-01 268008620 Waukesha VOC 28.070 7.69E-02 268008730 Waukesha VOC 0.332 9.11E-04 268009500 Waukesha VOC 5.455 1.49E-02 268010710 Waukesha VOC 13.141 3.60E-02 268011150 Waukesha VOC 14.462 3.96E-02 268012030 Waukesha VOC 38.663 1.06E-01 268012250 Waukesha VOC 12.951 3.55E-02 268012360 Waukesha VOC 37.170 1.02E-01 268012580 Waukesha VOC 6.487 1.78E-02 268012800 Waukesha VOC 8.302 2.27E-02 268012910 Waukesha VOC 0.068 1.86E-04FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 268014560 Waukesha VOC 6.098 1.67E-02 268014670 Waukesha VOC 21.552 5.90E-02 268014780 Waukesha VOC 3.006 8.24E-03 268015330 Waukesha VOC 2.778 7.61E-03 268016100 Waukesha VOC 59.419 1.63E-01 268016210 Waukesha VOC 31.096 8.52E-02 268017200 Waukesha VOC 12.709 3.48E-02 268017640 Waukesha VOC 9.755 2.67E-02 268023580 Waukesha VOC 0.118 3.23E-04 268028200 Waukesha VOC 0.064 1.76E-04 268028420 Waukesha VOC 1.166 3.19E-03 268082650 Waukesha VOC 25.973 7.12E-02 268088920 Waukesha VOC 24.936 6.83E-02 268089140 Waukesha VOC 0.052 1.42E-04 268107620 Waukesha VOC 5.377 1.47E-02 268142270 Waukesha VOC 8.096 2.22E-02 268144250 Waukesha VOC 0.036 9.94E-05 268148210 Waukesha VOC 0.829 2.27E-03 268152500 Waukesha VOC 0.714 1.96E-03 268152610 Waukesha VOC 0.502 1.38E-03 268154260 Waukesha VOC 1.993 5.46E-03 268154370 Waukesha VOC 0.072 1.96E-04 268155250 Waukesha VOC 27.705 7.59E-02 268157890 Waukesha VOC 0.105 2.88E-04 268158110 Waukesha VOC 4.702 1.29E-02 268158660 Waukesha VOC 12.934 3.54E-02 268161410 Waukesha VOC 6.229 1.71E-02 268164160 Waukesha VOC 4.826 1.32E-02 268165150 Waukesha VOC 21.328 5.84E-02 268165370 Waukesha VOC 2.305 6.31E-03 268168560 Waukesha VOC 0.025 6.98E-05 268170320 Waukesha VOC 2.186 5.99E-03 268170760 Waukesha VOC 5.744 1.57E-02 268171310 Waukesha VOC 7.446 2.04E-02 268173290 Waukesha VOC 9.848 2.70E-02 268175270 Waukesha VOC 9.022 2.47E-02 268175490 Waukesha VOC 4.182 1.15E-02 268180660 Waukesha VOC 2.980 8.16E-03 268183080 Waukesha VOC 138.431 3.79E-01 268185610 Waukesha VOC 0.055 1.49E-04 268186160 Waukesha VOC 25.239 6.91E-02 268198370 Waukesha VOC 9.430 2.58E-02 268203430 Waukesha VOC 10.315 2.83E-02 268204090 Waukesha VOC 2.352 6.45E-03 268213880 Waukesha VOC 1.953 5.35E-03 268218170 Waukesha VOC 4.752 1.30E-02 268219490 Waukesha VOC 23.840 6.53E-02FID COUNTY POLLUTANT 2005(TONS) 2005(TPWD) 268221360 Waukesha VOC 22.705 6.22E-02 268221910 Waukesha VOC 3.400 9.32E-03 268227850 Waukesha VOC 8.171 2.24E-02 268228070 Waukesha VOC 12.370 3.39E-02 268238190 Waukesha VOC 2.811 7.70E-03 268239290 Waukesha VOC 42.975 1.18E-01 268244130 Waukesha VOC 7.774 2.13E-02 268255790 Waukesha VOC 0.110 3.01E-04 268257220 Waukesha VOC 6.590 1.81E-02 268257990 Waukesha VOC 6.587 1.80E-02 268262060 Waukesha VOC 2.888 7.91E-03 268266020 Waukesha VOC 1.656 4.54E-03 268270420 Waukesha VOC 4.826 1.32E-02 268270750 Waukesha VOC 19.261 5.28E-02 268284280 Waukesha VOC 1.502 4.11E-03 268289450 Waukesha VOC 0.025 6.79E-05 268290440 Waukesha VOC 4.101 1.12E-02 268290550 Waukesha VOC 5.843 1.60E-02 268298250 Waukesha VOC 10.457 2.86E-02 268306280 Waukesha VOC 20.846 5.71E-02 268312770 Waukesha VOC 6.900 1.89E-02 268337080 Waukesha VOC 1.674 4.59E-03 268342470 Waukesha VOC 10.403 2.85E-02 268376900 Waukesha VOC 0.091 2.48E-04 268382620 Waukesha VOC 8.772 2.40E-02 268393620 Waukesha VOC 3.076 8.43E-03 268404730 Waukesha VOC 11.187 3.06E-02 268414850 Waukesha VOC 10.611 2.91E-02 268423870 Waukesha VOC 18.193 4.98E-02 268457970 Waukesha VOC 7.638 2.09E-02 268463800 Waukesha VOC 0.171 4.68E-04 268504390 Waukesha VOC 5.476 1.50E-02 268523970 Waukesha VOC 0.417 1.14E-03 268525070 Waukesha VOC 3.276 8.97E-03 268529360 Waukesha VOC 3.335 9.14E-03 268534310 Waukesha VOC 6.135 1.68E-02 268544540 Waukesha VOC 0.775 2.12E-03 268574020 Waukesha VOC 1.312 3.59E-03 268576770 Waukesha VOC 0.500 1.37E-03 368011050 Waukesha VOC 11.713 3.21E-02

### 2008 Point Source Emissions

FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241005600 Milwaukee NOx 3.611 9.89E-03 241005710 Milwaukee NOx 22.057 6.04E-02 241006260 Milwaukee NOx 21.050 5.77E-02 241006370 Milwaukee NOx 2.455 6.73E-03 241006810 Milwaukee NOx 3.463 9.49E-03 241006920 Milwaukee NOx 98.535 2.70E-01 241007030 Milwaukee NOx 44.694 1.22E-01 241007690 Milwaukee NOx 4,979.441 1.36E+01 241007800 Milwaukee NOx 3,106.287 8.51E+00 241008130 Milwaukee NOx 9.910 2.72E-02 241008240 Milwaukee NOx 36.588 1.00E-01 241008680 Milwaukee NOx 19.522 5.35E-02 241009670 Milwaukee NOx 22.940 6.28E-02 241010770 Milwaukee NOx 9.439 2.59E-02 241010990 Milwaukee NOx 1.845 5.05E-03 241011100 Milwaukee NOx 50.637 1.39E-01 241011760 Milwaukee NOx 13.968 3.83E-02 241011870 Milwaukee NOx 20.557 5.63E-02 241012200 Milwaukee NOx 6.374 1.75E-02 241012310 Milwaukee NOx 10.607 2.91E-02 241013080 Milwaukee NOx 3.615 9.90E-03 241014180 Milwaukee NOx 1.991 5.45E-03 241014620 Milwaukee NOx 15.818 4.33E-02 241015390 Milwaukee NOx 6.231 1.71E-02 241016710 Milwaukee NOx 1.033 2.83E-03 241017040 Milwaukee NOx 0.000 3.22E-07 241017370 Milwaukee NOx 0.600 1.64E-03 241017590 Milwaukee NOx 0.416 1.14E-03 241017920 Milwaukee NOx 0.825 2.26E-03 241019350 Milwaukee NOx 2.550 6.99E-03 241019900 Milwaukee NOx 38.533 1.06E-01 241020780 Milwaukee NOx 1.663 4.56E-03 241021220 Milwaukee NOx 2.969 8.13E-03 241021880 Milwaukee NOx 1.905 5.22E-03 241023640 Milwaukee NOx 41.364 1.13E-01 241024190 Milwaukee NOx 7.865 2.15E-02 241024300 Milwaukee NOx 11.038 3.02E-02 241025070 Milwaukee NOx 2.289 6.27E-03 241025290 Milwaukee NOx 2.762 7.57E-03 241025510 Milwaukee NOx 2.567 7.03E-03 241026060 Milwaukee NOx 0.623 1.71E-03 241026500 Milwaukee NOx 0.852 2.33E-03 241027050 Milwaukee NOx 393.748 1.08E+00 241027160 Milwaukee NOx 9.175 2.51E-02 241027380 Milwaukee NOx 2.446 6.70E-03 241027930 Milwaukee NOx 9.064 2.48E-02FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241028810 Milwaukee NOx 11.631 3.19E-02 241029030 Milwaukee NOx 6.984 1.91E-02 241029140 Milwaukee NOx 3.835 1.05E-02 241029250 Milwaukee NOx 141.567 3.88E-01 241029470 Milwaukee NOx 0.183 5.01E-04 241029800 Milwaukee NOx 1.626 4.45E-03 241031120 Milwaukee NOx 14.954 4.10E-02 241031450 Milwaukee NOx 1.278 3.50E-03 241032770 Milwaukee NOx 5.307 1.45E-02 241033210 Milwaukee NOx 8.737 2.39E-02 241033430 Milwaukee NOx 1.492 4.09E-03 241033650 Milwaukee NOx 0.866 2.37E-03 241034200 Milwaukee NOx 0.256 7.01E-04 241036840 Milwaukee NOx 0.208 5.68E-04 241036950 Milwaukee NOx 2.034 5.57E-03 241038820 Milwaukee NOx 4.236 1.16E-02 241040690 Milwaukee NOx 1.088 2.98E-03 241041900 Milwaukee NOx 1.626 4.46E-03 241042670 Milwaukee NOx 1.236 3.39E-03 241045420 Milwaukee NOx 2.338 6.40E-03 241045750 Milwaukee NOx 13.471 3.69E-02 241047730 Milwaukee NOx 2.061 5.65E-03 241052680 Milwaukee NOx 4.718 1.29E-02 241053010 Milwaukee NOx 0.222 6.07E-04 241053450 Milwaukee NOx 2.726 7.47E-03 241054330 Milwaukee NOx 0.249 6.83E-04 241055870 Milwaukee NOx 4.051 1.11E-02 241063570 Milwaukee NOx 2.739 7.50E-03 241094370 Milwaukee NOx 0.589 1.61E-03 241094700 Milwaukee NOx 1.256 3.44E-03 241095910 Milwaukee NOx 3.724 1.02E-02 241116700 Milwaukee NOx 1.898 5.20E-03 241164770 Milwaukee NOx 0.738 2.02E-03 241167630 Milwaukee NOx 0.560 1.53E-03 241168070 Milwaukee NOx 1.674 4.59E-03 241168180 Milwaukee NOx 8.105 2.22E-02 241168510 Milwaukee NOx 2.856 7.82E-03 241168620 Milwaukee NOx 97.030 2.66E-01 241189520 Milwaukee NOx 0.882 2.42E-03 241202170 Milwaukee NOx 1.286 3.52E-03 241213720 Milwaukee NOx 1.002 2.74E-03 241222410 Milwaukee NOx 0.790 2.16E-03 241222850 Milwaukee NOx 0.188 5.16E-04 241225710 Milwaukee NOx 0.008 2.19E-05 241227910 Milwaukee NOx 0.078 2.13E-04 241228350 Milwaukee NOx 335.036 9.18E-01 241231760 Milwaukee NOx 0.307 8.41E-04FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241235940 Milwaukee NOx 0.465 1.27E-03 241245180 Milwaukee NOx 0.645 1.77E-03 241251670 Milwaukee NOx 1.001 2.74E-03 241254310 Milwaukee NOx 2.367 6.48E-03 241256730 Milwaukee NOx 0.745 2.04E-03 241266740 Milwaukee NOx 1.499 4.11E-03 241276750 Milwaukee NOx 0.642 1.76E-03 241305790 Milwaukee NOx 0.205 5.61E-04 241308870 Milwaukee NOx 0.175 4.79E-04 241316020 Milwaukee NOx 0.219 5.99E-04 241321960 Milwaukee NOx 0.001 1.84E-06 241334060 Milwaukee NOx 1.339 3.67E-03 241355400 Milwaukee NOx 5.164 1.41E-02 241362660 Milwaukee NOx 0.838 2.29E-03 241370140 Milwaukee NOx 0.772 2.12E-03 241371350 Milwaukee NOx 1.167 3.20E-03 241372120 Milwaukee NOx 0.490 1.34E-03 241413810 Milwaukee NOx 0.433 1.19E-03 241442630 Milwaukee NOx 0.478 1.31E-03 241450440 Milwaukee NOx 6.153 1.69E-02 241454290 Milwaukee NOx 0.868 2.38E-03 241455500 Milwaukee NOx 1.378 3.78E-03 241480910 Milwaukee NOx 0.572 1.57E-03 241514570 Milwaukee NOx 0.473 1.30E-03 241672090 Milwaukee NOx 1.565 4.29E-03 241709930 Milwaukee NOx 0.200 5.49E-04 241723240 Milwaukee NOx 7.037 1.93E-02 241757340 Milwaukee NOx 3.139 8.60E-03 241789350 Milwaukee NOx 0.753 2.06E-03 241832360 Milwaukee NOx 2.371 6.50E-03 241879550 Milwaukee NOx 1.537 4.21E-03 241961610 Milwaukee NOx 6.401 1.75E-02 241964580 Milwaukee NOx 0.982 2.69E-03 341003300 Waukesha NOx 0.152 4.18E-04 341005280 Waukesha NOx 0.815 2.23E-03 341024310 Waukesha NOx 1.046 2.87E-03 341024420 Waukesha NOx 4.954 1.36E-02 341076780 Waukesha NOx 0.238 6.51E-04 341092510 Waukesha NOx 4.862 1.33E-02 252004280 Racine NOx 5.013 1.37E-02 252004940 Racine NOx 2.907 7.96E-03 252005380 Racine NOx 19.276 5.28E-02 252005820 Racine NOx 6.131 1.68E-02 252005930 Racine NOx 205.316 5.63E-01 252006370 Racine NOx 43.215 1.18E-01 252007030 Racine NOx 0.614 1.68E-03 252007140 Racine NOx 4.993 1.37E-02FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 252007690 Racine NOx 4.299 1.18E-02 252008460 Racine NOx 3.265 8.94E-03 252009780 Racine NOx 1.050 2.88E-03 252011870 Racine NOx 10.562 2.89E-02 252012090 Racine NOx 7.626 2.09E-02 252013190 Racine NOx 0.044 1.21E-04 252013630 Racine NOx 1.803 4.94E-03 252019900 Racine NOx 8.034 2.20E-02 252041130 Racine NOx 2.748 7.53E-03 252075340 Racine NOx 0.768 2.10E-03 252076990 Racine NOx 2.794 7.65E-03 252077760 Racine NOx 0.320 8.75E-04 252078200 Racine NOx 0.191 5.22E-04 252080070 Racine NOx 0.441 1.21E-03 252086120 Racine NOx 0.542 1.48E-03 252091070 Racine NOx 0.519 1.42E-03 252103940 Racine NOx 8.381 2.30E-02 252126380 Racine NOx 0.272 7.45E-04 252135950 Racine NOx 1.509 4.13E-03 252194140 Racine NOx 10.215 2.80E-02 252229670 Racine NOx 0.171 4.67E-04 252236380 Racine NOx 4.211 1.15E-02 252237260 Racine NOx 2.551 6.99E-03 241472770 Milwaukee NOx 6.885 1.89E-02 268005100 Waukesha NOx 1.380 3.78E-03 268005430 Waukesha NOx 4.644 1.27E-02 268006310 Waukesha NOx 0.018 4.97E-05 268006750 Waukesha NOx 85.826 2.35E-01 268006970 Waukesha NOx 13.415 3.68E-02 268007080 Waukesha NOx 3.505 9.60E-03 268008400 Waukesha NOx 9.850 2.70E-02 268008510 Waukesha NOx 1.565 4.29E-03 268008620 Waukesha NOx 0.440 1.21E-03 268008730 Waukesha NOx 4.282 1.17E-02 268009500 Waukesha NOx 1.600 4.38E-03 268010710 Waukesha NOx 2.019 5.53E-03 268012030 Waukesha NOx 4.295 1.18E-02 268012250 Waukesha NOx 2.354 6.45E-03 268012360 Waukesha NOx 1.964 5.38E-03 268012580 Waukesha NOx 0.159 4.34E-04 268012800 Waukesha NOx 0.847 2.32E-03 268012910 Waukesha NOx 6.009 1.65E-02 268014560 Waukesha NOx 0.169 4.64E-04 268014670 Waukesha NOx 24.961 6.84E-02 268014780 Waukesha NOx 0.145 3.97E-04 268015330 Waukesha NOx 2.693 7.38E-03 268016100 Waukesha NOx 2.478 6.79E-03FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 268016210 Waukesha NOx 0.775 2.12E-03 268017200 Waukesha NOx 0.773 2.12E-03 268028200 Waukesha NOx 3.330 9.12E-03 268028420 Waukesha NOx 3.577 9.80E-03 268088700 Waukesha NOx 3.546 9.72E-03 268088920 Waukesha NOx 1.974 5.41E-03 268089140 Waukesha NOx 4.075 1.12E-02 268090240 Waukesha NOx 0.782 2.14E-03 268107620 Waukesha NOx 0.603 1.65E-03 268142270 Waukesha NOx 0.915 2.51E-03 268144250 Waukesha NOx 1.738 4.76E-03 268152500 Waukesha NOx 0.522 1.43E-03 268152610 Waukesha NOx 0.453 1.24E-03 268154260 Waukesha NOx 0.123 3.38E-04 268154370 Waukesha NOx 2.392 6.55E-03 268157890 Waukesha NOx 3.461 9.48E-03 268159210 Waukesha NOx 2.278 6.24E-03 268162730 Waukesha NOx 0.584 1.60E-03 268164160 Waukesha NOx 0.080 2.19E-04 268165370 Waukesha NOx 0.191 5.23E-04 268168560 Waukesha NOx 3.414 9.35E-03 268170320 Waukesha NOx 0.001 3.10E-06 268171310 Waukesha NOx 2.152 5.90E-03 268173290 Waukesha NOx 0.004 1.03E-05 268175270 Waukesha NOx 0.687 1.88E-03 268180660 Waukesha NOx 0.079 2.16E-04 268183080 Waukesha NOx 10.018 2.74E-02 268183190 Waukesha NOx 0.682 1.87E-03 268185610 Waukesha NOx 5.003 1.37E-02 268186160 Waukesha NOx 0.016 4.49E-05 268198370 Waukesha NOx 1.643 4.50E-03 268203430 Waukesha NOx 0.465 1.27E-03 268204090 Waukesha NOx 0.794 2.18E-03 268213880 Waukesha NOx 0.047 1.29E-04 268218170 Waukesha NOx 0.497 1.36E-03 268219490 Waukesha NOx 0.539 1.48E-03 268221360 Waukesha NOx 4.690 1.28E-02 268221910 Waukesha NOx 0.367 1.01E-03 268227850 Waukesha NOx 0.401 1.10E-03 268228070 Waukesha NOx 0.900 2.47E-03 268239290 Waukesha NOx 0.156 4.28E-04 268244130 Waukesha NOx 17.596 4.82E-02 268257220 Waukesha NOx 5.804 1.59E-02 268266020 Waukesha NOx 0.077 2.10E-04 268270420 Waukesha NOx 0.114 3.13E-04 268270750 Waukesha NOx 0.165 4.51E-04 268297590 Waukesha NOx 0.092 2.52E-04FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 268353800 Waukesha NOx 17.648 4.84E-02 268404730 Waukesha NOx 1.113 3.05E-03 268414850 Waukesha NOx 0.233 6.38E-04 268423870 Waukesha NOx 1.936 5.30E-03 268457970 Waukesha NOx 65.274 1.79E-01 268463800 Waukesha NOx 1.567 4.29E-03 268504390 Waukesha NOx 0.163 4.47E-04 268523970 Waukesha NOx 4.230 1.16E-02 268565440 Waukesha NOx 3.529 9.67E-03 268572040 Waukesha NOx 0.209 5.73E-04 268574020 Waukesha NOx 0.450 1.23E-03 268594920 Waukesha NOx 0.016 4.28E-05 268600750 Waukesha NOx 0.412 1.13E-03 268601630 Waukesha NOx 0.052 1.42E-04 368011050 Waukesha NOx 0.000 2.69E-08 241005600 Milwaukee PM25 0.013 3.46E-05 241005710 Milwaukee PM25 3.739 1.02E-02 241006260 Milwaukee PM25 6.450 1.77E-02 241006370 Milwaukee PM25 0.316 8.66E-04 241006810 Milwaukee PM25 0.064 1.76E-04 241006920 Milwaukee PM25 0.286 7.84E-04 241007030 Milwaukee PM25 0.355 9.72E-04 241007690 Milwaukee PM25 13.234 3.63E-02 241007800 Milwaukee PM25 6.942 1.90E-02 241008130 Milwaukee PM25 0.075 2.05E-04 241008240 Milwaukee PM25 0.127 3.47E-04 241008350 Milwaukee PM25 0.444 1.22E-03 241008680 Milwaukee PM25 3.111 8.52E-03 241009670 Milwaukee PM25 0.812 2.22E-03 241010770 Milwaukee PM25 0.379 1.04E-03 241010990 Milwaukee PM25 0.003 7.86E-06 241011100 Milwaukee PM25 0.920 2.52E-03 241011760 Milwaukee PM25 0.164 4.50E-04 241011870 Milwaukee PM25 0.925 2.53E-03 241012200 Milwaukee PM25 0.075 2.06E-04 241012310 Milwaukee PM25 1.641 4.50E-03 241013080 Milwaukee PM25 0.049 1.34E-04 241014180 Milwaukee PM25 0.015 4.14E-05 241014620 Milwaukee PM25 0.134 3.68E-04 241015390 Milwaukee PM25 0.837 2.29E-03 241016710 Milwaukee PM25 0.008 2.08E-05 241017040 Milwaukee PM25 0.000 2.45E-09 241017370 Milwaukee PM25 0.002 5.03E-06 241017590 Milwaukee PM25 0.004 1.14E-05 241017920 Milwaukee PM25 0.007 1.97E-05 241019350 Milwaukee PM25 0.300 8.21E-04 241019900 Milwaukee PM25 0.219 6.01E-04FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241020780 Milwaukee PM25 0.004 1.22E-05 241021220 Milwaukee PM25 0.533 1.46E-03 241021880 Milwaukee PM25 0.260 7.11E-04 241023640 Milwaukee PM25 0.288 7.89E-04 241024190 Milwaukee PM25 0.059 1.63E-04 241024300 Milwaukee PM25 0.113 3.09E-04 241025070 Milwaukee PM25 0.017 4.79E-05 241025290 Milwaukee PM25 0.018 5.01E-05 241025510 Milwaukee PM25 0.354 9.69E-04 241026060 Milwaukee PM25 0.002 5.12E-06 241026500 Milwaukee PM25 0.002 5.12E-06 241027050 Milwaukee PM25 0.884 2.42E-03 241027160 Milwaukee PM25 2.798 7.67E-03 241027380 Milwaukee PM25 0.019 5.09E-05 241027930 Milwaukee PM25 0.018 4.84E-05 241028810 Milwaukee PM25 0.161 4.42E-04 241029030 Milwaukee PM25 0.015 4.12E-05 241029140 Milwaukee PM25 0.029 7.99E-05 241029250 Milwaukee PM25 2.389 6.55E-03 241029470 Milwaukee PM25 0.076 2.09E-04 241029800 Milwaukee PM25 2.997 8.21E-03 241030240 Milwaukee PM25 0.000 6.61E-07 241031120 Milwaukee PM25 0.111 3.03E-04 241031450 Milwaukee PM25 0.024 6.51E-05 241032770 Milwaukee PM25 0.235 6.43E-04 241033210 Milwaukee PM25 0.064 1.75E-04 241033430 Milwaukee PM25 0.011 3.11E-05 241033650 Milwaukee PM25 0.068 1.85E-04 241034200 Milwaukee PM25 0.002 6.48E-06 241036840 Milwaukee PM25 0.010 2.87E-05 241036950 Milwaukee PM25 0.120 3.28E-04 241037280 Milwaukee PM25 0.000 1.60E-07 241038820 Milwaukee PM25 0.029 7.82E-05 241040690 Milwaukee PM25 0.015 4.08E-05 241041240 Milwaukee PM25 0.003 6.93E-06 241041900 Milwaukee PM25 0.012 3.39E-05 241045420 Milwaukee PM25 0.018 4.87E-05 241045750 Milwaukee PM25 0.040 1.09E-04 241047730 Milwaukee PM25 0.004 1.02E-05 241052680 Milwaukee PM25 0.036 9.86E-05 241053010 Milwaukee PM25 0.092 2.51E-04 241053450 Milwaukee PM25 0.021 5.68E-05 241054330 Milwaukee PM25 0.000 1.37E-09 241055870 Milwaukee PM25 0.031 8.44E-05 241063570 Milwaukee PM25 0.292 7.99E-04 241091400 Milwaukee PM25 0.076 2.08E-04 241094370 Milwaukee PM25 0.003 8.76E-06FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241094700 Milwaukee PM25 0.000 1.09E-06 241095910 Milwaukee PM25 0.113 3.08E-04 241116700 Milwaukee PM25 0.006 1.56E-05 241164770 Milwaukee PM25 0.000 2.18E-07 241165210 Milwaukee PM25 0.128 3.51E-04 241167630 Milwaukee PM25 0.004 1.17E-05 241168070 Milwaukee PM25 0.000 2.28E-07 241168180 Milwaukee PM25 0.062 1.69E-04 241168510 Milwaukee PM25 0.132 3.62E-04 241168620 Milwaukee PM25 4.542 1.24E-02 241189520 Milwaukee PM25 0.048 1.32E-04 241202170 Milwaukee PM25 0.003 8.03E-06 241213720 Milwaukee PM25 0.011 3.09E-05 241222410 Milwaukee PM25 0.000 3.22E-07 241222850 Milwaukee PM25 0.161 4.41E-04 241225710 Milwaukee PM25 0.000 1.19E-07 241227910 Milwaukee PM25 0.001 1.62E-06 241228350 Milwaukee PM25 0.116 3.18E-04 241231760 Milwaukee PM25 0.001 2.52E-06 241235940 Milwaukee PM25 0.004 9.68E-06 241251670 Milwaukee PM25 0.003 8.23E-06 241254310 Milwaukee PM25 0.018 4.93E-05 241256730 Milwaukee PM25 0.009 2.45E-05 241266740 Milwaukee PM25 0.005 1.41E-05 241288520 Milwaukee PM25 0.012 3.27E-05 241305790 Milwaukee PM25 0.002 5.24E-06 241308870 Milwaukee PM25 0.405 1.11E-03 241316020 Milwaukee PM25 0.002 4.55E-06 241321960 Milwaukee PM25 0.254 6.96E-04 241334060 Milwaukee PM25 0.008 2.22E-05 241335160 Milwaukee PM25 0.628 1.72E-03 241355400 Milwaukee PM25 0.348 9.53E-04 241362660 Milwaukee PM25 0.006 1.74E-05 241370140 Milwaukee PM25 0.024 6.59E-05 241371350 Milwaukee PM25 0.009 2.43E-05 241372120 Milwaukee PM25 0.254 6.96E-04 241413810 Milwaukee PM25 0.004 1.03E-05 241442630 Milwaukee PM25 0.021 5.83E-05 241450440 Milwaukee PM25 0.040 1.11E-04 241454290 Milwaukee PM25 0.002 4.78E-06 241455500 Milwaukee PM25 0.028 7.69E-05 241514570 Milwaukee PM25 0.004 1.11E-05 241672090 Milwaukee PM25 0.006 1.73E-05 241709930 Milwaukee PM25 0.001 1.65E-06 241723240 Milwaukee PM25 0.050 1.36E-04 241757340 Milwaukee PM25 0.009 2.58E-05 241789350 Milwaukee PM25 0.009 2.45E-05FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241832360 Milwaukee PM25 0.021 5.65E-05 241879550 Milwaukee PM25 0.001 2.67E-06 241961610 Milwaukee PM25 0.074 2.02E-04 241964580 Milwaukee PM25 0.086 2.37E-04 341003300 Waukesha PM25 0.001 3.06E-06 341005280 Waukesha PM25 0.513 1.41E-03 341024310 Waukesha PM25 0.084 2.30E-04 341024420 Waukesha PM25 0.038 1.03E-04 341037290 Waukesha PM25 0.000 6.85E-09 341076780 Waukesha PM25 0.002 4.95E-06 341092510 Waukesha PM25 0.042 1.14E-04 341112860 Waukesha PM25 0.000 9.59E-10 252004280 Racine PM25 0.870 2.38E-03 252004940 Racine PM25 0.232 6.36E-04 252005380 Racine PM25 1.289 3.53E-03 252005820 Racine PM25 0.047 1.28E-04 252005930 Racine PM25 6.550 1.79E-02 252006370 Racine PM25 0.604 1.65E-03 252007030 Racine PM25 0.005 1.28E-05 252007140 Racine PM25 0.036 9.96E-05 252007690 Racine PM25 0.033 8.95E-05 252008460 Racine PM25 1.601 4.39E-03 252009780 Racine PM25 0.004 1.12E-05 252011870 Racine PM25 0.025 6.90E-05 252012090 Racine PM25 0.019 5.11E-05 252013190 Racine PM25 0.001 3.09E-06 252013630 Racine PM25 0.016 4.38E-05 252019900 Racine PM25 0.061 1.68E-04 252041130 Racine PM25 0.598 1.64E-03 252075340 Racine PM25 0.007 1.83E-05 252076990 Racine PM25 0.065 1.77E-04 252077760 Racine PM25 0.003 7.25E-06 252078200 Racine PM25 0.004 1.18E-05 252080070 Racine PM25 0.003 9.18E-06 252086120 Racine PM25 0.004 1.13E-05 252091070 Racine PM25 0.005 1.24E-05 252103940 Racine PM25 0.061 1.66E-04 252126380 Racine PM25 0.001 4.04E-06 252135950 Racine PM25 0.011 3.14E-05 252147060 Racine PM25 0.104 2.85E-04 252194140 Racine PM25 0.074 2.03E-04 252194910 Racine PM25 0.007 1.80E-05 252195350 Racine PM25 0.001 1.52E-06 252224830 Racine PM25 0.876 2.40E-03 252229670 Racine PM25 0.001 4.07E-06 252236380 Racine PM25 1.271 3.48E-03 252237260 Racine PM25 0.012 3.28E-05FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241472770 Milwaukee PM25 0.106 2.91E-04 268005430 Waukesha PM25 1.686 4.62E-03 268005650 Waukesha PM25 0.673 1.84E-03 268006310 Waukesha PM25 0.145 3.97E-04 268006750 Waukesha PM25 0.128 3.50E-04 268006970 Waukesha PM25 1.074 2.94E-03 268007080 Waukesha PM25 0.125 3.42E-04 268008400 Waukesha PM25 0.074 2.04E-04 268008510 Waukesha PM25 0.012 3.26E-05 268008620 Waukesha PM25 0.003 9.16E-06 268008730 Waukesha PM25 0.242 6.62E-04 268009500 Waukesha PM25 0.180 4.94E-04 268010710 Waukesha PM25 0.015 4.16E-05 268012030 Waukesha PM25 0.265 7.27E-04 268012250 Waukesha PM25 0.013 3.68E-05 268012360 Waukesha PM25 0.006 1.61E-05 268012580 Waukesha PM25 0.021 5.72E-05 268012800 Waukesha PM25 0.006 1.76E-05 268012910 Waukesha PM25 0.668 1.83E-03 268014120 Waukesha PM25 0.293 8.03E-04 268014560 Waukesha PM25 0.001 2.89E-06 268014670 Waukesha PM25 0.096 2.62E-04 268014780 Waukesha PM25 0.001 3.46E-06 268015330 Waukesha PM25 0.034 9.29E-05 268016100 Waukesha PM25 0.012 3.30E-05 268016210 Waukesha PM25 0.006 1.66E-05 268017200 Waukesha PM25 0.007 1.82E-05 268028200 Waukesha PM25 0.413 1.13E-03 268028420 Waukesha PM25 0.277 7.59E-04 268088700 Waukesha PM25 0.569 1.56E-03 268088920 Waukesha PM25 0.625 1.71E-03 268089140 Waukesha PM25 0.371 1.02E-03 268090240 Waukesha PM25 0.005 1.51E-05 268107620 Waukesha PM25 0.005 1.44E-05 268142270 Waukesha PM25 0.003 7.52E-06 268144250 Waukesha PM25 0.003 8.38E-06 268152500 Waukesha PM25 0.022 6.08E-05 268152610 Waukesha PM25 0.019 5.27E-05 268154260 Waukesha PM25 0.000 1.01E-06 268154370 Waukesha PM25 0.350 9.59E-04 268157890 Waukesha PM25 0.007 1.93E-05 268159210 Waukesha PM25 0.023 6.28E-05 268162730 Waukesha PM25 0.004 1.21E-05 268164160 Waukesha PM25 0.001 1.67E-06 268168560 Waukesha PM25 0.596 1.63E-03 268170320 Waukesha PM25 0.000 2.36E-08 268171310 Waukesha PM25 0.010 2.67E-05FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 268173290 Waukesha PM25 0.000 3.11E-08 268180660 Waukesha PM25 0.106 2.90E-04 268183080 Waukesha PM25 0.027 7.28E-05 268183190 Waukesha PM25 0.002 5.60E-06 268185610 Waukesha PM25 0.592 1.62E-03 268186160 Waukesha PM25 0.000 1.35E-07 268198260 Waukesha PM25 0.061 1.66E-04 268198370 Waukesha PM25 0.091 2.49E-04 268203430 Waukesha PM25 0.004 9.69E-06 268204090 Waukesha PM25 0.003 8.47E-06 268213880 Waukesha PM25 0.000 3.86E-07 268218170 Waukesha PM25 0.001 4.08E-06 268219490 Waukesha PM25 0.211 5.79E-04 268221360 Waukesha PM25 0.064 1.76E-04 268221910 Waukesha PM25 0.003 7.67E-06 268227850 Waukesha PM25 0.003 8.34E-06 268228070 Waukesha PM25 0.003 8.75E-06 268239290 Waukesha PM25 0.001 3.25E-06 268257220 Waukesha PM25 0.051 1.39E-04 268266020 Waukesha PM25 0.001 1.83E-06 268270420 Waukesha PM25 0.000 9.40E-07 268270750 Waukesha PM25 0.000 1.24E-06 268297590 Waukesha PM25 0.004 1.03E-05 268299130 Waukesha PM25 0.171 4.69E-04 268353800 Waukesha PM25 0.907 2.48E-03 268404730 Waukesha PM25 0.007 1.87E-05 268414850 Waukesha PM25 0.001 1.91E-06 268423870 Waukesha PM25 0.014 3.88E-05 268457970 Waukesha PM25 0.067 1.82E-04 268463800 Waukesha PM25 0.540 1.48E-03 268504390 Waukesha PM25 0.001 3.89E-06 268523970 Waukesha PM25 0.055 1.51E-04 268560380 Waukesha PM25 0.098 2.68E-04 268565440 Waukesha PM25 0.015 4.03E-05 268572040 Waukesha PM25 0.002 5.00E-06 268574020 Waukesha PM25 0.001 3.69E-06 268594920 Waukesha PM25 0.000 5.14E-07 268600750 Waukesha PM25 0.001 2.30E-06 268601630 Waukesha PM25 0.000 1.24E-06 241005600 Milwaukee SO2 0.032 8.71E-05 241005710 Milwaukee SO2 2.628 7.20E-03 241006260 Milwaukee SO2 34.622 9.49E-02 241006370 Milwaukee SO2 4.546 1.25E-02 241006810 Milwaukee SO2 4.097 1.12E-02 241006920 Milwaukee SO2 0.366 1.00E-03 241007030 Milwaukee SO2 0.250 6.84E-04 241007690 Milwaukee SO2 14,471.271 3.96E+01FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241007800 Milwaukee SO2 6,886.133 1.89E+01 241008130 Milwaukee SO2 0.083 2.27E-04 241008240 Milwaukee SO2 2.455 6.73E-03 241008680 Milwaukee SO2 0.017 4.64E-05 241009670 Milwaukee SO2 0.284 7.79E-04 241010770 Milwaukee SO2 0.042 1.14E-04 241010990 Milwaukee SO2 0.008 2.17E-05 241011100 Milwaukee SO2 87.770 2.40E-01 241011760 Milwaukee SO2 0.151 4.13E-04 241011870 Milwaukee SO2 0.916 2.51E-03 241012200 Milwaukee SO2 0.038 1.05E-04 241012310 Milwaukee SO2 2.660 7.29E-03 241013080 Milwaukee SO2 0.022 5.95E-05 241014180 Milwaukee SO2 0.001 3.59E-06 241014620 Milwaukee SO2 0.104 2.86E-04 241015390 Milwaukee SO2 0.213 5.85E-04 241017370 Milwaukee SO2 0.004 9.86E-06 241017590 Milwaukee SO2 0.002 6.83E-06 241017920 Milwaukee SO2 0.005 1.36E-05 241019350 Milwaukee SO2 0.066 1.82E-04 241019900 Milwaukee SO2 7.169 1.96E-02 241020780 Milwaukee SO2 0.011 2.97E-05 241021220 Milwaukee SO2 0.013 3.55E-05 241021880 Milwaukee SO2 0.171 4.69E-04 241023640 Milwaukee SO2 0.233 6.39E-04 241024190 Milwaukee SO2 0.099 2.71E-04 241024300 Milwaukee SO2 0.219 6.00E-04 241025070 Milwaukee SO2 0.085 2.33E-04 241025290 Milwaukee SO2 0.002 5.85E-06 241025510 Milwaukee SO2 0.015 4.22E-05 241026060 Milwaukee SO2 0.004 1.02E-05 241026500 Milwaukee SO2 0.005 1.40E-05 241027050 Milwaukee SO2 607.873 1.67E+00 241027160 Milwaukee SO2 24.656 6.76E-02 241027930 Milwaukee SO2 0.042 1.15E-04 241028810 Milwaukee SO2 0.068 1.86E-04 241029030 Milwaukee SO2 0.064 1.75E-04 241029140 Milwaukee SO2 0.023 6.30E-05 241029250 Milwaukee SO2 0.586 1.61E-03 241029470 Milwaukee SO2 0.001 2.15E-06 241029800 Milwaukee SO2 4.830 1.32E-02 241031120 Milwaukee SO2 0.359 9.85E-04 241031450 Milwaukee SO2 0.453 1.24E-03 241032770 Milwaukee SO2 0.047 1.29E-04 241033210 Milwaukee SO2 0.059 1.61E-04 241033430 Milwaukee SO2 0.009 2.45E-05 241033650 Milwaukee SO2 0.005 1.28E-05FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241034200 Milwaukee SO2 0.012 3.27E-05 241036840 Milwaukee SO2 0.001 3.41E-06 241036950 Milwaukee SO2 0.010 2.68E-05 241038820 Milwaukee SO2 0.010 2.79E-05 241040690 Milwaukee SO2 0.007 1.79E-05 241041900 Milwaukee SO2 0.027 7.53E-05 241042670 Milwaukee SO2 0.007 2.03E-05 241045420 Milwaukee SO2 0.014 3.84E-05 241045750 Milwaukee SO2 2.904 7.96E-03 241047730 Milwaukee SO2 0.151 4.14E-04 241052680 Milwaukee SO2 0.017 4.58E-05 241053010 Milwaukee SO2 0.082 2.24E-04 241053450 Milwaukee SO2 0.016 4.48E-05 241054330 Milwaukee SO2 0.001 4.10E-06 241055870 Milwaukee SO2 0.024 6.66E-05 241063570 Milwaukee SO2 0.016 4.50E-05 241094370 Milwaukee SO2 0.003 6.91E-06 241094700 Milwaukee SO2 0.008 2.06E-05 241095910 Milwaukee SO2 0.030 8.23E-05 241116700 Milwaukee SO2 0.011 3.12E-05 241164770 Milwaukee SO2 0.000 7.26E-08 241167630 Milwaukee SO2 0.000 1.23E-07 241168180 Milwaukee SO2 0.060 1.65E-04 241168510 Milwaukee SO2 0.020 5.61E-05 241168620 Milwaukee SO2 6.220 1.70E-02 241189520 Milwaukee SO2 0.004 1.04E-05 241202170 Milwaukee SO2 0.008 2.11E-05 241213720 Milwaukee SO2 0.006 1.65E-05 241222410 Milwaukee SO2 0.171 4.70E-04 241222850 Milwaukee SO2 0.001 3.10E-06 241225710 Milwaukee SO2 0.000 9.45E-08 241227910 Milwaukee SO2 0.000 1.28E-06 241228350 Milwaukee SO2 1.516 4.15E-03 241231760 Milwaukee SO2 0.002 5.05E-06 241235940 Milwaukee SO2 0.003 7.64E-06 241245180 Milwaukee SO2 0.004 1.06E-05 241251670 Milwaukee SO2 0.006 1.65E-05 241256730 Milwaukee SO2 0.004 1.22E-05 241266740 Milwaukee SO2 1.034 2.83E-03 241276750 Milwaukee SO2 0.004 1.05E-05 241305790 Milwaukee SO2 0.001 3.37E-06 241308870 Milwaukee SO2 0.001 2.88E-06 241316020 Milwaukee SO2 0.001 3.59E-06 241321960 Milwaukee SO2 0.004 1.10E-05 241334060 Milwaukee SO2 0.008 2.20E-05 241355400 Milwaukee SO2 5.986 1.64E-02 241362660 Milwaukee SO2 0.005 1.38E-05FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241370140 Milwaukee SO2 0.004 9.89E-06 241371350 Milwaukee SO2 0.000 9.12E-07 241372120 Milwaukee SO2 3.532 9.68E-03 241413810 Milwaukee SO2 0.003 7.11E-06 241442630 Milwaukee SO2 0.010 2.81E-05 241450440 Milwaukee SO2 0.049 1.35E-04 241454290 Milwaukee SO2 0.005 1.43E-05 241455500 Milwaukee SO2 0.008 2.27E-05 241480910 Milwaukee SO2 0.003 9.40E-06 241514570 Milwaukee SO2 0.002 5.56E-06 241672090 Milwaukee SO2 0.004 1.21E-05 241709930 Milwaukee SO2 0.001 3.29E-06 241723240 Milwaukee SO2 0.042 1.16E-04 241757340 Milwaukee SO2 0.019 5.16E-05 241789350 Milwaukee SO2 0.006 1.60E-05 241832360 Milwaukee SO2 0.014 3.90E-05 241879550 Milwaukee SO2 0.009 2.53E-05 241961610 Milwaukee SO2 0.038 1.05E-04 241964580 Milwaukee SO2 0.005 1.47E-05 341003300 Waukesha SO2 0.001 2.53E-06 341005280 Waukesha SO2 0.005 1.34E-05 341024310 Waukesha SO2 0.006 1.72E-05 341024420 Waukesha SO2 0.030 8.14E-05 341076780 Waukesha SO2 0.001 3.90E-06 341092510 Waukesha SO2 0.301 8.24E-04 252004280 Milwaukee SO2 0.471 1.29E-03 252004940 Milwaukee SO2 0.659 1.81E-03 252005380 Milwaukee SO2 8.902 2.44E-02 252005820 Milwaukee SO2 0.191 5.23E-04 252005930 Racine SO2 187.468 5.14E-01 252006370 Racine SO2 0.624 1.71E-03 252007140 Racine SO2 0.192 5.27E-04 252007690 Racine SO2 0.026 7.07E-05 252008460 Racine SO2 0.033 8.93E-05 252009780 Racine SO2 0.006 1.73E-05 252011870 Racine SO2 0.042 1.15E-04 252012090 Racine SO2 0.186 5.11E-04 252013190 Racine SO2 0.015 4.16E-05 252013630 Racine SO2 0.011 2.96E-05 252019900 Racine SO2 0.055 1.50E-04 252041130 Racine SO2 0.222 6.08E-04 252075340 Racine SO2 0.005 1.26E-05 252076990 Racine SO2 0.648 1.77E-03 252077760 Racine SO2 0.002 5.25E-06 252078200 Racine SO2 0.001 3.13E-06 252080070 Racine SO2 0.003 7.25E-06 252086120 Racine SO2 0.003 8.91E-06FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 252091070 Racine SO2 0.003 8.53E-06 252103940 Racine SO2 0.032 8.84E-05 252126380 Racine SO2 0.001 3.19E-06 252135950 Racine SO2 0.009 2.48E-05 252194140 Racine SO2 0.608 1.67E-03 252229670 Racine SO2 0.001 2.80E-06 252236380 Racine SO2 0.133 3.65E-04 252237260 Racine SO2 0.015 4.19E-05 241472770 Milwaukee SO2 0.001 3.23E-06 268005100 Waukesha SO2 0.008 2.27E-05 268005430 Waukesha SO2 0.673 1.85E-03 268006310 Waukesha SO2 0.031 8.51E-05 268006750 Waukesha SO2 0.369 1.01E-03 268006970 Waukesha SO2 1.123 3.08E-03 268007080 Waukesha SO2 1.195 3.28E-03 268008400 Waukesha SO2 0.059 1.62E-04 268008510 Waukesha SO2 0.009 2.57E-05 268008620 Waukesha SO2 0.003 7.23E-06 268008730 Waukesha SO2 0.259 7.11E-04 268009500 Waukesha SO2 0.094 2.58E-04 268010710 Waukesha SO2 0.012 3.29E-05 268012030 Waukesha SO2 0.012 3.23E-05 268012250 Waukesha SO2 0.014 3.87E-05 268012360 Waukesha SO2 0.012 3.23E-05 268012580 Waukesha SO2 0.001 2.61E-06 268012800 Waukesha SO2 0.005 1.39E-05 268012910 Waukesha SO2 4.814 1.32E-02 268014560 Waukesha SO2 0.001 2.78E-06 268014670 Waukesha SO2 0.795 2.18E-03 268014780 Waukesha SO2 0.001 2.38E-06 268015330 Waukesha SO2 0.016 4.43E-05 268016100 Waukesha SO2 0.005 1.47E-05 268016210 Waukesha SO2 0.005 1.27E-05 268017200 Waukesha SO2 0.008 2.25E-05 268028200 Waukesha SO2 1.991 5.45E-03 268028420 Waukesha SO2 12.066 3.31E-02 268088700 Waukesha SO2 0.417 1.14E-03 268088920 Waukesha SO2 2.775 7.60E-03 268089140 Waukesha SO2 0.232 6.36E-04 268090240 Waukesha SO2 0.134 3.66E-04 268107620 Waukesha SO2 0.004 9.91E-06 268142270 Waukesha SO2 0.005 1.50E-05 268144250 Waukesha SO2 0.008 2.21E-05 268152500 Waukesha SO2 0.283 7.76E-04 268152610 Waukesha SO2 0.199 5.45E-04 268154260 Waukesha SO2 0.001 2.03E-06 268154370 Waukesha SO2 0.014 3.93E-05FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 268157890 Waukesha SO2 0.007 2.03E-05 268159210 Waukesha SO2 0.014 3.75E-05 268162730 Waukesha SO2 0.004 9.59E-06 268164160 Waukesha SO2 0.000 1.32E-06 268165370 Waukesha SO2 0.001 3.14E-06 268168560 Waukesha SO2 4.775 1.31E-02 268170320 Waukesha SO2 0.000 1.92E-08 268171310 Waukesha SO2 0.042 1.16E-04 268173290 Waukesha SO2 0.000 6.16E-08 268175270 Waukesha SO2 0.004 1.13E-05 268180660 Waukesha SO2 0.000 1.29E-06 268183080 Waukesha SO2 0.060 1.65E-04 268183190 Waukesha SO2 0.004 1.12E-05 268185610 Waukesha SO2 3.667 1.00E-02 268186160 Waukesha SO2 0.000 2.68E-07 268198370 Waukesha SO2 0.055 1.49E-04 268203430 Waukesha SO2 0.003 7.65E-06 268204090 Waukesha SO2 0.005 1.31E-05 268213880 Waukesha SO2 0.000 7.73E-07 268218170 Waukesha SO2 0.003 8.16E-06 268219490 Waukesha SO2 0.045 1.23E-04 268221360 Waukesha SO2 0.023 6.40E-05 268221910 Waukesha SO2 0.002 5.48E-06 268227850 Waukesha SO2 0.002 6.58E-06 268228070 Waukesha SO2 0.005 1.48E-05 268239290 Waukesha SO2 0.001 2.56E-06 268244130 Waukesha SO2 15.599 4.27E-02 268257220 Waukesha SO2 4.765 1.31E-02 268266020 Waukesha SO2 0.000 1.26E-06 268270420 Waukesha SO2 0.001 1.88E-06 268270750 Waukesha SO2 0.001 2.93E-06 268297590 Waukesha SO2 0.001 1.51E-06 268353800 Waukesha SO2 1.088 2.98E-03 268404730 Waukesha SO2 0.007 1.83E-05 268414850 Waukesha SO2 0.001 3.83E-06 268423870 Waukesha SO2 0.011 3.07E-05 268457970 Waukesha SO2 0.248 6.79E-04 268463800 Waukesha SO2 0.103 2.82E-04 268504390 Waukesha SO2 0.001 2.68E-06 268523970 Waukesha SO2 0.028 7.71E-05 268565440 Waukesha SO2 0.021 5.72E-05 268572040 Waukesha SO2 0.299 8.20E-04 268574020 Waukesha SO2 0.003 7.39E-06 268594920 Waukesha SO2 0.000 2.58E-07 268600750 Waukesha SO2 0.006 1.57E-05 268601630 Waukesha SO2 0.000 8.53E-07 368011050 Waukesha SO2 0.000 3.23E-07FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241005490 Milwaukee VOC 2.149 5.89E-03 241005600 Milwaukee VOC 1.013 2.78E-03 241005710 Milwaukee VOC 40.544 1.11E-01 241006260 Milwaukee VOC 93.410 2.56E-01 241006370 Milwaukee VOC 4.630 1.27E-02 241006810 Milwaukee VOC 8.050 2.21E-02 241006920 Milwaukee VOC 14.374 3.94E-02 241007030 Milwaukee VOC 109.941 3.01E-01 241007690 Milwaukee VOC 118.681 3.25E-01 241007800 Milwaukee VOC 26.798 7.34E-02 241008130 Milwaukee VOC 9.696 2.66E-02 241008240 Milwaukee VOC 11.723 3.21E-02 241008680 Milwaukee VOC 37.774 1.03E-01 241009670 Milwaukee VOC 4.687 1.28E-02 241010770 Milwaukee VOC 4.215 1.15E-02 241010990 Milwaukee VOC 14.115 3.87E-02 241011100 Milwaukee VOC 1.039 2.85E-03 241011760 Milwaukee VOC 12.921 3.54E-02 241011870 Milwaukee VOC 19.005 5.21E-02 241012200 Milwaukee VOC 4.979 1.36E-02 241012310 Milwaukee VOC 33.918 9.29E-02 241013080 Milwaukee VOC 12.452 3.41E-02 241014180 Milwaukee VOC 5.892 1.61E-02 241014620 Milwaukee VOC 235.492 6.45E-01 241015280 Milwaukee VOC 0.421 1.15E-03 241015390 Milwaukee VOC 22.934 6.28E-02 241016710 Milwaukee VOC 0.064 1.75E-04 241017040 Milwaukee VOC 2.274 6.23E-03 241017370 Milwaukee VOC 1.948 5.34E-03 241017590 Milwaukee VOC 3.230 8.85E-03 241017700 Milwaukee VOC 9.909 2.71E-02 241017920 Milwaukee VOC 14.095 3.86E-02 241019350 Milwaukee VOC 9.468 2.59E-02 241019460 Milwaukee VOC 14.017 3.84E-02 241019900 Milwaukee VOC 2.910 7.97E-03 241020780 Milwaukee VOC 12.747 3.49E-02 241021220 Milwaukee VOC 68.856 1.89E-01 241021880 Milwaukee VOC 7.382 2.02E-02 241023640 Milwaukee VOC 32.018 8.77E-02 241024190 Milwaukee VOC 0.504 1.38E-03 241024300 Milwaukee VOC 1.545 4.23E-03 241025070 Milwaukee VOC 0.580 1.59E-03 241025290 Milwaukee VOC 0.778 2.13E-03 241025510 Milwaukee VOC 0.136 3.73E-04 241026060 Milwaukee VOC 0.372 1.02E-03 241026500 Milwaukee VOC 5.410 1.48E-02 241027050 Milwaukee VOC 2.809 7.70E-03FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241027160 Milwaukee VOC 0.285 7.81E-04 241027380 Milwaukee VOC 0.135 3.69E-04 241027930 Milwaukee VOC 0.245 6.71E-04 241028810 Milwaukee VOC 84.423 2.31E-01 241029030 Milwaukee VOC 41.123 1.13E-01 241029140 Milwaukee VOC 0.211 5.78E-04 241029250 Milwaukee VOC 66.919 1.83E-01 241029470 Milwaukee VOC 0.004 1.00E-05 241029800 Milwaukee VOC 37.469 1.03E-01 241031120 Milwaukee VOC 0.785 2.15E-03 241031450 Milwaukee VOC 0.048 1.31E-04 241032440 Milwaukee VOC 0.000 0.00E+00 241032770 Milwaukee VOC 20.694 5.67E-02 241033210 Milwaukee VOC 0.456 1.25E-03 241033430 Milwaukee VOC 26.925 7.38E-02 241033650 Milwaukee VOC 0.040 1.09E-04 241033760 Milwaukee VOC 5.368 1.47E-02 241034200 Milwaukee VOC 1.963 5.38E-03 241036840 Milwaukee VOC 1.271 3.48E-03 241036950 Milwaukee VOC 0.099 2.73E-04 241037280 Milwaukee VOC 0.629 1.72E-03 241038820 Milwaukee VOC 4.202 1.15E-02 241040690 Milwaukee VOC 14.181 3.89E-02 241041130 Milwaukee VOC 24.275 6.65E-02 241041900 Milwaukee VOC 0.109 3.00E-04 241042670 Milwaukee VOC 0.068 1.86E-04 241043880 Milwaukee VOC 6.908 1.89E-02 241045420 Milwaukee VOC 0.129 3.52E-04 241045750 Milwaukee VOC 0.404 1.11E-03 241047730 Milwaukee VOC 3.813 1.04E-02 241049160 Milwaukee VOC 4.237 1.16E-02 241052680 Milwaukee VOC 5.715 1.57E-02 241053010 Milwaukee VOC 2.688 7.36E-03 241053450 Milwaukee VOC 0.214 5.87E-04 241053560 Milwaukee VOC 9.515 2.61E-02 241054330 Milwaukee VOC 1.700 4.66E-03 241055870 Milwaukee VOC 0.223 6.10E-04 241063570 Milwaukee VOC 20.897 5.73E-02 241078640 Milwaukee VOC 21.990 6.02E-02 241094370 Milwaukee VOC 9.874 2.71E-02 241094700 Milwaukee VOC 1.273 3.49E-03 241095910 Milwaukee VOC 0.206 5.65E-04 241116700 Milwaukee VOC 19.103 5.23E-02 241164770 Milwaukee VOC 23.424 6.42E-02 241167630 Milwaukee VOC 0.031 8.45E-05 241168070 Milwaukee VOC 1.044 2.86E-03 241168180 Milwaukee VOC 0.447 1.23E-03FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241168510 Milwaukee VOC 1.245 3.41E-03 241168620 Milwaukee VOC 6.993 1.92E-02 241174560 Milwaukee VOC 18.541 5.08E-02 241189520 Milwaukee VOC 0.095 2.60E-04 241197990 Milwaukee VOC 5.530 1.52E-02 241202170 Milwaukee VOC 0.543 1.49E-03 241213720 Milwaukee VOC 2.534 6.94E-03 241222410 Milwaukee VOC 1.308 3.58E-03 241222850 Milwaukee VOC 1.271 3.48E-03 241225710 Milwaukee VOC 1.368 3.75E-03 241227910 Milwaukee VOC 6.955 1.91E-02 241228350 Milwaukee VOC 16.493 4.52E-02 241231760 Milwaukee VOC 0.016 4.46E-05 241232640 Milwaukee VOC 3.062 8.39E-03 241235940 Milwaukee VOC 3.638 9.97E-03 241245180 Milwaukee VOC 18.592 5.09E-02 241251670 Milwaukee VOC 2.297 6.29E-03 241254310 Milwaukee VOC 0.130 3.57E-04 241256730 Milwaukee VOC 4.062 1.11E-02 241266740 Milwaukee VOC 35.592 9.75E-02 241276750 Milwaukee VOC 28.853 7.91E-02 241305790 Milwaukee VOC 0.011 3.09E-05 241308870 Milwaukee VOC 6.538 1.79E-02 241309090 Milwaukee VOC 20.046 5.49E-02 241316020 Milwaukee VOC 12.800 3.51E-02 241318330 Milwaukee VOC 1.399 3.83E-03 241321850 Milwaukee VOC 2.669 7.31E-03 241321960 Milwaukee VOC 0.037 1.01E-04 241325590 Milwaukee VOC 24.424 6.69E-02 241334060 Milwaukee VOC 5.836 1.60E-02 241355400 Milwaukee VOC 0.065 1.78E-04 241362660 Milwaukee VOC 3.726 1.02E-02 241370140 Milwaukee VOC 4.003 1.10E-02 241371350 Milwaukee VOC 0.064 1.76E-04 241372120 Milwaukee VOC 8.664 2.37E-02 241413810 Milwaukee VOC 4.653 1.27E-02 241428550 Milwaukee VOC 6.164 1.69E-02 241435260 Milwaukee VOC 28.555 7.82E-02 241442630 Milwaukee VOC 22.195 6.08E-02 241450440 Milwaukee VOC 0.307 8.41E-04 241454290 Milwaukee VOC 5.855 1.60E-02 241455500 Milwaukee VOC 20.253 5.55E-02 241473650 Milwaukee VOC 2.791 7.65E-03 241480910 Milwaukee VOC 3.386 9.28E-03 241514570 Milwaukee VOC 3.308 9.06E-03 241672090 Milwaukee VOC 0.086 2.36E-04 241684630 Milwaukee VOC 1.849 5.07E-03FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 241709930 Milwaukee VOC 1.287 3.53E-03 241714000 Milwaukee VOC 11.136 3.05E-02 241723240 Milwaukee VOC 14.142 3.87E-02 241741940 Milwaukee VOC 4.268 1.17E-02 241757340 Milwaukee VOC 31.664 8.68E-02 241789350 Milwaukee VOC 2.062 5.65E-03 241805300 Milwaukee VOC 7.968 2.18E-02 241832360 Milwaukee VOC 2.385 6.54E-03 241879550 Milwaukee VOC 1.134 3.11E-03 241916180 Milwaukee VOC 2.930 8.03E-03 241961610 Milwaukee VOC 0.647 1.77E-03 241961720 Milwaukee VOC 4.750 1.30E-02 241964580 Milwaukee VOC 8.368 2.29E-02 241967440 Milwaukee VOC 3.656 1.00E-02 341003300 Waukesha VOC 3.568 9.78E-03 341005280 Waukesha VOC 0.045 1.23E-04 341024310 Waukesha VOC 21.682 5.94E-02 341024420 Waukesha VOC 10.690 2.93E-02 341027170 Waukesha VOC 0.593 1.62E-03 341037290 Waukesha VOC 3.575 9.79E-03 341039270 Waukesha VOC 5.005 1.37E-02 341062260 Waukesha VOC 4.057 1.11E-02 341076780 Waukesha VOC 1.025 2.81E-03 341092510 Waukesha VOC 1.020 2.79E-03 341112860 Waukesha VOC 1.874 5.13E-03 252004280 Milwaukee VOC 0.198 5.42E-04 252004940 Milwaukee VOC 28.068 7.69E-02 252005380 Milwaukee VOC 18.398 5.04E-02 252005820 Milwaukee VOC 0.334 9.16E-04 252005930 Milwaukee VOC 27.134 7.43E-02 252006370 Milwaukee VOC 171.282 4.69E-01 252007030 Milwaukee VOC 0.043 1.18E-04 252007140 Milwaukee VOC 1.528 4.19E-03 252007690 Milwaukee VOC 22.063 6.04E-02 252008460 Milwaukee VOC 17.691 4.85E-02 252009780 Milwaukee VOC 14.486 3.97E-02 252011870 Milwaukee VOC 2.379 6.52E-03 252012090 Milwaukee VOC 1.272 3.48E-03 252013190 Milwaukee VOC 0.001 1.52E-06 252013630 Milwaukee VOC 13.717 3.76E-02 252014510 Milwaukee VOC 1.417 3.88E-03 252016270 Milwaukee VOC 1.410 3.86E-03 252019900 Milwaukee VOC 0.441 1.21E-03 252041130 Milwaukee VOC 9.906 2.71E-02 252075340 Milwaukee VOC 9.398 2.57E-02 252076990 Milwaukee VOC 4.552 1.25E-02 252077760 Milwaukee VOC 4.347 1.19E-02FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 252078200 Racine VOC 0.685 1.88E-03 252080070 Racine VOC 6.393 1.75E-02 252081390 Racine VOC 1.451 3.98E-03 252086120 Racine VOC 7.303 2.00E-02 252091070 Racine VOC 0.027 7.53E-05 252103940 Racine VOC 0.440 1.21E-03 252109550 Racine VOC 7.855 2.15E-02 252126380 Racine VOC 3.586 9.82E-03 252135950 Racine VOC 0.145 3.99E-04 252173680 Racine VOC 15.484 4.24E-02 252194140 Racine VOC 18.610 5.10E-02 252195350 Racine VOC 1.176 3.22E-03 252229670 Racine VOC 5.497 1.51E-02 252236380 Racine VOC 7.774 2.13E-02 252236490 Racine VOC 0.227 6.23E-04 252237260 Racine VOC 0.108 2.95E-04 252237810 Racine VOC 6.656 1.82E-02 252248700 Racine VOC 5.734 1.57E-02 252253760 Waukesha VOC 0.378 1.04E-03 241472770 Milwaukee VOC 6.714 1.84E-02 268000480 Waukesha VOC 0.917 2.51E-03 268005100 Waukesha VOC 0.076 2.08E-04 268005430 Waukesha VOC 33.269 9.11E-02 268006310 Waukesha VOC 7.452 2.04E-02 268006750 Waukesha VOC 13.006 3.56E-02 268006970 Waukesha VOC 1.328 3.64E-03 268007080 Waukesha VOC 6.577 1.80E-02 268007410 Waukesha VOC 8.646 2.37E-02 268008400 Waukesha VOC 76.677 2.10E-01 268008510 Waukesha VOC 71.364 1.96E-01 268008620 Waukesha VOC 46.974 1.29E-01 268008730 Waukesha VOC 0.197 5.40E-04 268009170 Waukesha VOC 1.790 4.90E-03 268009500 Waukesha VOC 2.359 6.46E-03 268010710 Waukesha VOC 10.273 2.81E-02 268011150 Waukesha VOC 4.514 1.24E-02 268012030 Waukesha VOC 21.431 5.87E-02 268012250 Waukesha VOC 7.474 2.05E-02 268012360 Waukesha VOC 35.821 9.81E-02 268012580 Waukesha VOC 6.456 1.77E-02 268012800 Waukesha VOC 6.590 1.81E-02 268012910 Waukesha VOC 0.187 5.11E-04 268014560 Waukesha VOC 11.167 3.06E-02 268014670 Waukesha VOC 12.804 3.51E-02 268014780 Waukesha VOC 4.666 1.28E-02 268015330 Waukesha VOC 3.946 1.08E-02 268016100 Waukesha VOC 31.583 8.65E-02FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 268016210 Waukesha VOC 23.180 6.35E-02 268017200 Waukesha VOC 13.945 3.82E-02 268017640 Waukesha VOC 4.436 1.22E-02 268028200 Waukesha VOC 0.124 3.39E-04 268028420 Waukesha VOC 0.072 1.96E-04 268088920 Waukesha VOC 7.914 2.17E-02 268089140 Waukesha VOC 0.072 1.96E-04 268090240 Waukesha VOC 0.061 1.68E-04 268107620 Waukesha VOC 3.850 1.05E-02 268142270 Waukesha VOC 5.857 1.60E-02 268144250 Waukesha VOC 0.046 1.27E-04 268152500 Waukesha VOC 0.972 2.66E-03 268152610 Waukesha VOC 0.474 1.30E-03 268154260 Waukesha VOC 0.350 9.60E-04 268154370 Waukesha VOC 0.127 3.47E-04 268155250 Waukesha VOC 26.288 7.20E-02 268157450 Waukesha VOC 5.037 1.38E-02 268157890 Waukesha VOC 0.068 1.87E-04 268158110 Waukesha VOC 2.797 7.66E-03 268158660 Waukesha VOC 7.389 2.02E-02 268159210 Waukesha VOC 0.125 3.43E-04 268162730 Waukesha VOC 36.121 9.90E-02 268164160 Waukesha VOC 2.334 6.39E-03 268165150 Waukesha VOC 3.880 1.06E-02 268165370 Waukesha VOC 1.587 4.35E-03 268168560 Waukesha VOC 0.043 1.18E-04 268170320 Waukesha VOC 3.071 8.41E-03 268170760 Waukesha VOC 6.342 1.74E-02 268171310 Waukesha VOC 5.174 1.42E-02 268173290 Waukesha VOC 9.418 2.58E-02 268175270 Waukesha VOC 8.596 2.36E-02 268175490 Waukesha VOC 2.183 5.98E-03 268180660 Waukesha VOC 2.562 7.02E-03 268183080 Waukesha VOC 73.709 2.02E-01 268183190 Waukesha VOC 6.676 1.83E-02 268185610 Waukesha VOC 0.166 4.55E-04 268186160 Waukesha VOC 41.438 1.14E-01 268198370 Waukesha VOC 4.876 1.34E-02 268203430 Waukesha VOC 7.412 2.03E-02 268204090 Waukesha VOC 3.530 9.67E-03 268213880 Waukesha VOC 1.202 3.29E-03 268218170 Waukesha VOC 6.374 1.75E-02 268219490 Waukesha VOC 4.770 1.31E-02 268221360 Waukesha VOC 20.987 5.75E-02 268221910 Waukesha VOC 3.170 8.69E-03 268227850 Waukesha VOC 7.078 1.94E-02 268228070 Waukesha VOC 5.673 1.55E-02FID COUNTY POLLUTANT 2008(TONS) 2008(TPWD) 268238190 Waukesha VOC 2.870 7.86E-03 268239290 Waukesha VOC 15.615 4.28E-02 268244130 Waukesha VOC 20.130 5.52E-02 268257220 Waukesha VOC 7.125 1.95E-02 268257990 Waukesha VOC 3.991 1.09E-02 268266020 Waukesha VOC 1.007 2.76E-03 268270420 Waukesha VOC 5.946 1.63E-02 268270750 Waukesha VOC 2.534 6.94E-03 268280210 Waukesha VOC 0.048 1.31E-04 268284280 Waukesha VOC 6.347 1.74E-02 268290440 Waukesha VOC 8.456 2.32E-02 268297590 Waukesha VOC 8.861 2.43E-02 268298250 Waukesha VOC 18.350 5.03E-02 268306280 Waukesha VOC 10.441 2.86E-02 268312770 Waukesha VOC 7.791 2.13E-02 268337080 Waukesha VOC 8.401 2.30E-02 268342470 Waukesha VOC 11.322 3.10E-02 268353800 Waukesha VOC 1.408 3.86E-03 268382620 Waukesha VOC 10.037 2.75E-02 268393620 Waukesha VOC 1.402 3.84E-03 268404730 Waukesha VOC 9.333 2.56E-02 268414850 Waukesha VOC 6.195 1.70E-02 268423870 Waukesha VOC 13.923 3.81E-02 268457970 Waukesha VOC 7.756 2.13E-02 268463800 Waukesha VOC 0.128 3.50E-04 268504390 Waukesha VOC 6.147 1.68E-02 268523970 Waukesha VOC 1.945 5.33E-03 268529360 Waukesha VOC 2.222 6.09E-03 268560380 Waukesha VOC 75.150 2.06E-01 268565440 Waukesha VOC 0.000 8.08E-08 268572040 Waukesha VOC 0.005 1.39E-05 268574020 Waukesha VOC 5.766 1.58E-02 268589860 Waukesha VOC 12.284 3.37E-02 268594920 Waukesha VOC 3.519 9.64E-03 268600750 Waukesha VOC 0.020 5.57E-05 268601630 Waukesha VOC 2.528 6.93E-03 268606690 Waukesha VOC 2.442 6.69E-03 368011050 Waukesha VOC 2.523 6.91E-032006(est) 2010(est) 2006(est) 2010(est) 2006(est) 2010(est) 2006(est) 2010(est) Milwaukee 55079 27.82 27.62 0.76 0.02 60.63 61.20 6.76 4.23 Racine 55101 0.78 1.19 0.16 0.00 0.64 0.46 1.19 1.22 Waukesha 55133 0.84 1.17 0.13 0.00 0.16 0.16 3.41 2.67 SO2 (TPWD) VOC (TPWD) Estimated 2006 and 2010 Point Emissions

COUNTY FIPS ID NOx (TPWD) PM25 (TPWD)

Calculations for 2006 and 2010 Point Inventories (NOx) County 2005 Pt 2008 Pt 2006(est) 2010(est) 2010 (mod)* Milwaukee 28.29 26.88 27.82 25.93 27.62 Racine 0.68 0.99 0.78 1.19 1.19 Waukesha 0.76 1.01 0.84 1.17 1.17 * 2010 estimate is modified to include 2010 actual emissions from W E Energies - Elm Road (FID 241219440), which did not operate in 2008.

Calculations for 2006 and 2010 Point Inventories (PM2.5) County 2005 Pt 2008 Pt 2006(est) 2010(est) 2010 ( mod ) * Milwaukee 1.06 0.17 0.76 0.00 0.02 Racine 0.22 0.04 0.16 0.00 0.00 Waukesha 0.18 0.03 0.13 0.00 0.00 * 2010 estimate is modified to include 2010 actual emissions from W E Energies - Elm Road (FID 241219440), which did not operate in 2008.

Calculations for 2006 and 2010 Point Inventories (SO2) County 2005 Pt 2008 Pt 2006(est) 2010(est) 2010 (mod)* Milwaukee 60.57 60.74 60.63 60.84 61.20 Racine 0.68 0.55 0.64 0.46 0.46 Waukesha 0.15 0.16 0.16 0.16 0.16 * 2010 estimate is modified to include 2010 actual emissions from W E Energies - Elm Road (FID 241219440), which did not operate in 2008.

Calculations for 2006 and 2010 Point Inventories (VOC) County 2005 Pt 2008 Pt 2006(est) 2010(est) 2010 (mod)* Milwaukee 7.39 5.50 6.76 4.23 4.23 Racine 1.18 1.20 1.19 1.22 1.22 Waukesha 3.59 3.04 3.41 2.67 2.67 * 2010 estimate is modified to include 2010 actual emissions from W E Energies - Elm Road (FID 241219440), which did not operate in 2008.EGU Point Calculations: WE Energies - Elm Road (FID 241219440)

FIPS ID FID DVID SCC POLLUTANT 2006 (TONS) 2010 (TONS) 2006 (TPWD) 2010 (TPWD) 55079 241219440 1 1-01-002-22 NOx 0 462.40 0 1.267 55079 241219440 2 1-01-002-22 NOx 0 153.30 0 0.420 55079 241219440 1 1-01-002-22 PM25 0 5.01 0 0.014 55079 241219440 2 1-01-002-22 PM25 0 1.81 0 0.005 55079 241219440 1 1-01-002-22 SO2 0 84.30 0 0.231 55079 241219440 2 1-01-002-22 SO2 0 46.40 0 0.127 55079 241219440 1 1-01-002-22 VOC 0 0.12 0 0.000 55079 241219440 2 1-01-002-22 VOC 0 0.04 0 0.000 Notes: 1) AP-42 emission factors used to estimate PM2.5 and VOC emissions (W DNR staff applied ESP, Baghouse and W etFGD control technogies to emission factors). 2) We Energies - Elm Road 2010 NOx and SO2 emissions taken from USEPA's Acid Rain database.APPENDIX 5: 2006, 2010, 2020 AND2025 AREA SOURCE EMISSIONSSCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2102004001 55079 NOx 1.19E-011.00 1.00 0.86 0.821.19E-01 1.18E-01 1.02E-01 9.76E-022102004001 55079 NOx 3.81E-041.00 1.00 0.86 0.823.82E-04 3.79E-04 3.28E-04 3.13E-042102004002 55079 NOx 7.71E-011.00 1.00 0.86 0.827.74E-01 7.68E-01 6.64E-01 6.33E-012102004002 55079 NOx 2.47E-031.00 1.00 0.86 0.822.48E-03 2.46E-03 2.13E-03 2.03E-032102005000 55079 NOx 8.57E-05 0.98 0.99 0.85 0.84 8.37E-05 8.49E-05 7.31E-05 7.18E-052102005000 55079 NOx 2.67E-02 0.98 0.99 0.85 0.84 2.61E-02 2.65E-02 2.28E-02 2.24E-022102006000 55079 NOx 9.86E-04 0.98 1.04 1.02 1.07 9.67E-04 1.02E-03 1.01E-03 1.05E-032102006000 55079 NOx 3.08E-01 0.98 1.04 1.02 1.07 3.02E-01 3.19E-01 3.16E-01 3.29E-012102008000 55079 NOx 2.01E-04 0.96 1.06 1.18 1.25 1.92E-04 2.12E-04 2.38E-04 2.52E-042102008000 55079 NOx 6.28E-02 0.96 1.06 1.18 1.25 6.00E-02 6.63E-02 7.43E-02 7.86E-022102011000 55079 NOx 2.51E-06 0.98 0.98 0.89 0.89 2.47E-06 2.47E-06 2.24E-06 2.25E-062102011000 55079 NOx 7.85E-04 0.98 0.98 0.89 0.89 7.70E-04 7.72E-04 6.99E-04 7.01E-042103002000 55079 NOx 4.84E-04 1.02 0.99 0.85 0.82 4.91E-04 4.79E-04 4.12E-04 3.97E-042103002000 55079 NOx 2.52E-01 1.02 0.99 0.85 0.82 2.56E-01 2.49E-01 2.14E-01 2.06E-012103004001 55079 NOx 2.56E-011.00 1.00 0.86 0.822.57E-01 2.55E-01 2.20E-01 2.10E-012103004001 55079 NOx 4.92E-041.00 1.00 0.86 0.824.94E-04 4.90E-04 4.24E-04 4.04E-042103004002 55079 NOx 2.86E+001.00 1.00 0.86 0.822.87E+00 2.85E+00 2.46E+00 2.35E+002103004002 55079 NOx 5.49E-031.00 1.00 0.86 0.825.52E-03 5.47E-03 4.73E-03 4.51E-032103005000 55079 NOx 3.87E-07 0.99 1.03 0.88 0.86 3.84E-07 3.96E-07 3.41E-07 3.32E-072103005000 55079 NOx 2.01E-04 0.99 1.03 0.88 0.86 2.00E-04 2.06E-04 1.77E-04 1.73E-042103006000 55079 NOx 4.68E-03 0.99 1.01 0.89 0.90 4.63E-03 4.71E-03 4.14E-03 4.21E-032103006000 55079 NOx 2.43E+00 0.99 1.01 0.89 0.90 2.41E+00 2.45E+00 2.16E+00 2.19E+002103007000 55079 NOx 2.32E-04 0.98 1.00 0.88 0.86 2.28E-04 2.33E-04 2.04E-04 2.00E-042103007000 55079 NOx 1.21E-01 0.98 1.00 0.88 0.86 1.19E-01 1.21E-01 1.06E-01 1.04E-012103008000 55079 NOx 2.98E-05 1.00 1.00 0.87 0.84 2.98E-05 2.98E-05 2.59E-05 2.50E-052103008000 55079 NOx 1.55E-02 1.00 1.00 0.87 0.84 1.55E-02 1.55E-02 1.35E-02 1.30E-022103011000 55079 NOx 4.61E-06 0.98 1.00 0.89 0.89 4.51E-06 4.59E-06 4.10E-06 4.09E-062103011000 55079 NOx 2.40E-03 0.98 1.00 0.89 0.89 2.35E-03 2.39E-03 2.13E-03 2.13E-03SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2104004000 55079 NOX 2.35E-05 1.01 0.98 0.75 0.65 2.38E-05 2.31E-05 1.77E-05 1.54E-052104004000 55079 NOx 2.44E-01 1.01 0.98 0.75 0.65 2.47E-01 2.40E-01 1.83E-01 1.60E-012104006000 55079 NOX 3.15E-03 0.98 1.01 0.90 0.88 3.10E-03 3.20E-03 2.85E-03 2.78E-032104006000 55079 NOx 4.10E+00 0.98 1.01 0.90 0.88 4.03E+00 4.16E+00 3.70E+00 3.61E+002104007000 55079 NOX 5.88E-05 0.98 1.01 0.94 0.93 5.74E-05 5.96E-05 5.56E-05 5.47E-052104007000 55079 NOx 7.65E-02 0.98 1.01 0.94 0.93 7.47E-02 7.74E-02 7.22E-02 7.12E-022104008100 55079 NOX 2.68E-021.00 1.00 0.86 0.822.69E-02 2.67E-02 2.31E-02 2.20E-022104008210 55079 NOX 5.34E-021.00 1.00 0.86 0.825.36E-02 5.32E-02 4.60E-02 4.39E-022104008220 55079 NOX 1.40E-021.00 1.00 0.86 0.821.40E-02 1.39E-02 1.20E-02 1.15E-022104008230 55079 NOX 4.08E-031.00 1.00 0.86 0.824.10E-03 4.06E-03 3.52E-03 3.35E-032104008310 55079 NOX 3.36E-021.00 1.00 0.86 0.823.38E-02 3.35E-02 2.90E-02 2.76E-022104008320 55079 NOX 8.78E-031.00 1.00 0.86 0.828.81E-03 8.74E-03 7.56E-03 7.21E-032104008330 55079 NOX 2.56E-031.00 1.00 0.86 0.822.57E-03 2.55E-03 2.21E-03 2.10E-032104008400 55079 NOX 2.78E-021.00 1.00 0.86 0.822.79E-02 2.77E-02 2.40E-02 2.28E-022104008510 55079 NOX 6.22E-021.00 1.00 0.86 0.826.25E-02 6.20E-02 5.36E-02 5.11E-022104008610 55079 NOX 3.60E-011.00 1.00 0.86 0.823.62E-01 3.59E-01 3.10E-01 2.96E-012104009000 55079 NOX 1.43E-02 1.00 1.00 0.88 0.85 1.42E-02 1.43E-02 1.26E-02 1.21E-022104011000 55079 NOX 1.50E-07 0.98 1.01 0.90 0.88 1.47E-07 1.51E-07 1.35E-07 1.32E-072104011000 55079 NOx 1.55E-03 0.98 1.01 0.90 0.88 1.53E-03 1.56E-03 1.40E-03 1.37E-032610000100 55079 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55079 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55079 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55079 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002810030000 55079 NOX 4.98E-04 0.94 1.04 1.01 1.02 4.68E-04 5.16E-04 5.04E-04 5.09E-042810030000 55079 NOX 1.37E-06 0.94 1.04 1.01 1.02 1.28E-06 1.42E-06 1.38E-06 1.40E-062102004001 55101 NOx 4.00E-020.99 1.01 0.92 0.903.97E-02 4.04E-02 3.67E-02 3.61E-022102004001 55101 NOx 1.28E-040.99 1.01 0.92 0.901.27E-04 1.30E-04 1.18E-04 1.16E-042102004002 55101 NOx 2.60E-010.99 1.01 0.92 0.902.57E-01 2.62E-01 2.38E-01 2.34E-012102004002 55101 NOx 8.33E-040.99 1.01 0.92 0.908.25E-04 8.40E-04 7.64E-04 7.51E-042102005000 55101 NOx 2.89E-05 0.98 0.99 0.85 0.84 2.82E-05 2.86E-05 2.46E-05 2.42E-05SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2102005000 55101 NOx 9.01E-03 0.98 0.99 0.85 0.84 8.80E-03 8.93E-03 7.68E-03 7.55E-032102006000 55101 NOx 3.32E-04 0.98 1.04 1.02 1.07 3.26E-04 3.45E-04 3.41E-04 3.55E-042102006000 55101 NOx 1.04E-01 0.98 1.04 1.02 1.07 1.02E-01 1.08E-01 1.06E-01 1.11E-012102008000 55101 NOx 6.78E-05 0.96 1.06 1.18 1.25 6.48E-05 7.16E-05 8.02E-05 8.48E-052102008000 55101 NOx 2.12E-02 0.96 1.06 1.18 1.25 2.02E-02 2.23E-02 2.50E-02 2.65E-022102011000 55101 NOx 8.47E-07 0.98 0.98 0.89 0.89 8.31E-07 8.33E-07 7.55E-07 7.57E-072102011000 55101 NOx 2.64E-04 0.98 0.98 0.89 0.89 2.59E-04 2.60E-04 2.36E-04 2.36E-042103002000 55101 NOx 6.35E-05 1.02 0.99 0.85 0.82 6.45E-05 6.28E-05 5.41E-05 5.20E-052103002000 55101 NOx 3.30E-02 1.02 0.99 0.85 0.82 3.35E-02 3.27E-02 2.81E-02 2.71E-022103004001 55101 NOx 3.36E-020.99 1.01 0.92 0.903.33E-02 3.39E-02 3.08E-02 3.03E-022103004001 55101 NOx 6.45E-050.99 1.01 0.92 0.906.39E-05 6.51E-05 5.92E-05 5.82E-052103004002 55101 NOx 3.75E-010.99 1.01 0.92 0.903.71E-01 3.78E-01 3.44E-01 3.38E-012103004002 55101 NOx 7.21E-040.99 1.01 0.92 0.907.14E-04 7.28E-04 6.61E-04 6.50E-042103005000 55101 NOx 5.07E-08 0.99 1.03 0.88 0.86 5.04E-08 5.20E-08 4.48E-08 4.36E-082103005000 55101 NOx 2.64E-05 0.99 1.03 0.88 0.86 2.62E-05 2.70E-05 2.33E-05 2.27E-052103006000 55101 NOx 6.13E-04 0.99 1.01 0.89 0.90 6.07E-04 6.17E-04 5.44E-04 5.52E-042103006000 55101 NOx 3.19E-01 0.99 1.01 0.89 0.90 3.16E-01 3.21E-01 2.83E-01 2.87E-012103007000 55101 NOx 3.05E-05 0.98 1.00 0.88 0.86 2.99E-05 3.05E-05 2.67E-05 2.63E-052103007000 55101 NOx 1.58E-02 0.98 1.00 0.88 0.86 1.56E-02 1.59E-02 1.39E-02 1.37E-022103008000 55101 NOx 3.91E-06 1.00 1.00 0.87 0.84 3.91E-06 3.91E-06 3.40E-06 3.28E-062103008000 55101 NOx 2.03E-03 1.00 1.00 0.87 0.84 2.03E-03 2.03E-03 1.77E-03 1.71E-032103011000 55101 NOx 6.05E-07 0.98 1.00 0.89 0.89 5.92E-07 6.03E-07 5.38E-07 5.37E-072103011000 55101 NOx 3.15E-04 0.98 1.00 0.89 0.89 3.08E-04 3.13E-04 2.80E-04 2.79E-042104004000 55101 NOX 4.98E-06 1.01 0.98 0.75 0.65 5.03E-06 4.89E-06 3.74E-06 3.26E-062104004000 55101 NOx 5.17E-02 1.01 0.98 0.75 0.65 5.22E-02 5.08E-02 3.88E-02 3.38E-022104006000 55101 NOX 5.69E-04 0.98 1.01 0.90 0.88 5.60E-04 5.77E-04 5.14E-04 5.01E-042104006000 55101 NOx 7.39E-01 0.98 1.01 0.90 0.88 7.27E-01 7.50E-01 6.68E-01 6.51E-012104007000 55101 NOX 2.43E-05 0.98 1.01 0.94 0.93 2.37E-05 2.46E-05 2.29E-05 2.26E-052104007000 55101 NOx 3.16E-02 0.98 1.01 0.94 0.93 3.08E-02 3.20E-02 2.98E-02 2.94E-022104008100 55101 NOX 1.61E-020.99 1.01 0.92 0.901.60E-02 1.63E-02 1.48E-02 1.45E-02SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2104008210 55101 NOX 1.08E-020.99 1.01 0.92 0.901.07E-02 1.09E-02 9.88E-03 9.71E-032104008220 55101 NOX 3.71E-030.99 1.01 0.92 0.903.67E-03 3.74E-03 3.40E-03 3.34E-032104008230 55101 NOX 1.05E-030.99 1.01 0.92 0.901.04E-03 1.06E-03 9.65E-04 9.49E-042104008310 55101 NOX 4.72E-020.99 1.01 0.92 0.904.68E-02 4.77E-02 4.33E-02 4.26E-022104008320 55101 NOX 1.22E-020.99 1.01 0.92 0.901.20E-02 1.23E-02 1.12E-02 1.10E-022104008330 55101 NOX 1.18E-020.99 1.01 0.92 0.901.17E-02 1.19E-02 1.08E-02 1.06E-022104008400 55101 NOX 1.19E-020.99 1.01 0.92 0.901.18E-02 1.20E-02 1.09E-02 1.07E-022104008510 55101 NOX 2.70E-020.99 1.01 0.92 0.902.68E-02 2.73E-02 2.48E-02 2.44E-022104008610 55101 NOX 6.37E-020.99 1.01 0.92 0.906.31E-02 6.43E-02 5.85E-02 5.75E-022104008700 55101 NOX 2.76E-020.99 1.01 0.92 0.902.73E-02 2.78E-02 2.53E-02 2.49E-022104009000 55101 NOX 4.35E-04 1.00 1.00 0.88 0.85 4.33E-04 4.35E-04 3.83E-04 3.69E-042104011000 55101 NOX 3.17E-08 0.98 1.01 0.90 0.88 3.11E-08 3.18E-08 2.85E-08 2.79E-082104011000 55101 NOx 3.29E-04 0.98 1.01 0.90 0.88 3.23E-04 3.31E-04 2.96E-04 2.90E-042610000100 55101 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55101 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55101 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55101 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002810030000 55101 NOX 4.83E-04 0.94 1.04 1.01 1.02 4.53E-04 5.00E-04 4.88E-04 4.93E-042810030000 55101 NOX 1.33E-06 0.94 1.04 1.01 1.02 1.24E-06 1.37E-06 1.34E-06 1.35E-062102004001 55133 NOx 1.26E-010.99 1.01 0.95 0.941.24E-01 1.27E-01 1.19E-01 1.19E-012102004001 55133 NOx 4.03E-040.99 1.01 0.95 0.943.97E-04 4.09E-04 3.82E-04 3.80E-042102004002 55133 NOx 8.15E-010.99 1.01 0.95 0.948.03E-01 8.27E-01 7.73E-01 7.70E-012102004002 55133 NOx 2.61E-030.99 1.01 0.95 0.942.57E-03 2.65E-03 2.48E-03 2.47E-032102005000 55133 NOx 9.06E-05 0.98 0.99 0.85 0.84 8.85E-05 8.98E-05 7.72E-05 7.59E-052102005000 55133 NOx 2.83E-02 0.98 0.99 0.85 0.84 2.76E-02 2.80E-02 2.41E-02 2.37E-022102006000 55133 NOx 1.04E-03 0.98 1.04 1.02 1.07 1.02E-03 1.08E-03 1.07E-03 1.11E-032102006000 55133 NOx 3.26E-01 0.98 1.04 1.02 1.07 3.19E-01 3.37E-01 3.34E-01 3.47E-012102008000 55133 NOx 2.13E-04 0.96 1.06 1.18 1.25 2.03E-04 2.25E-04 2.52E-04 2.66E-042102008000 55133 NOx 6.64E-02 0.96 1.06 1.18 1.25 6.35E-02 7.01E-02 7.85E-02 8.31E-022102011000 55133 NOx 2.66E-06 0.98 0.98 0.89 0.89 2.61E-06 2.61E-06 2.37E-06 2.38E-06SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2102011000 55133 NOx 8.30E-04 0.98 0.98 0.89 0.89 8.14E-04 8.16E-04 7.39E-04 7.42E-042103002000 55133 NOx 2.04E-04 1.02 0.99 0.85 0.82 2.07E-04 2.02E-04 1.74E-04 1.67E-042103002000 55133 NOx 1.06E-01 1.02 0.99 0.85 0.82 1.08E-01 1.05E-01 9.04E-02 8.69E-022103004001 55133 NOx 1.08E-010.99 1.01 0.95 0.941.06E-01 1.09E-01 1.02E-01 1.02E-012103004001 55133 NOx 2.07E-040.99 1.01 0.95 0.942.04E-04 2.10E-04 1.97E-04 1.96E-042103004002 55133 NOx 1.20E+000.99 1.01 0.95 0.941.19E+00 1.22E+00 1.14E+00 1.14E+002103004002 55133 NOx 2.32E-030.99 1.01 0.95 0.942.28E-03 2.35E-03 2.20E-03 2.19E-032103005000 55133 NOx 1.63E-07 0.99 1.03 0.88 0.86 1.62E-07 1.67E-07 1.44E-07 1.40E-072103005000 55133 NOx 8.47E-05 0.99 1.03 0.88 0.86 8.42E-05 8.69E-05 7.48E-05 7.29E-052103006000 55133 NOx 1.97E-03 0.99 1.01 0.89 0.90 1.95E-03 1.98E-03 1.75E-03 1.77E-032103006000 55133 NOx 1.02E+00 0.99 1.01 0.89 0.90 1.02E+00 1.03E+00 9.09E-01 9.22E-012103007000 55133 NOx 9.79E-05 0.98 1.00 0.88 0.86 9.62E-05 9.80E-05 8.59E-05 8.44E-052103007000 55133 NOx 5.09E-02 0.98 1.00 0.88 0.86 5.00E-02 5.10E-02 4.47E-02 4.39E-022103008000 55133 NOx 1.26E-05 1.00 1.00 0.87 0.84 1.26E-05 1.26E-05 1.09E-05 1.05E-052103008000 55133 NOx 6.53E-03 1.00 1.00 0.87 0.84 6.53E-03 6.53E-03 5.68E-03 5.48E-032103011000 55133 NOx 1.94E-06 0.98 1.00 0.89 0.89 1.90E-06 1.94E-06 1.73E-06 1.73E-062103011000 55133 NOx 1.01E-03 0.98 1.00 0.89 0.89 9.90E-04 1.01E-03 8.99E-04 8.98E-042104004000 55133 NOX 1.32E-05 1.01 0.98 0.75 0.65 1.33E-05 1.29E-05 9.88E-06 8.61E-062104004000 55133 NOx 1.37E-01 1.01 0.98 0.75 0.65 1.38E-01 1.34E-01 1.03E-01 8.94E-022104006000 55133 NOX 1.09E-03 0.98 1.01 0.90 0.88 1.08E-03 1.11E-03 9.88E-04 9.63E-042104006000 55133 NOx 1.42E+00 0.98 1.01 0.90 0.88 1.40E+00 1.44E+00 1.28E+00 1.25E+002104007000 55133 NOX 2.65E-05 0.98 1.01 0.94 0.93 2.59E-05 2.69E-05 2.51E-05 2.47E-052104007000 55133 NOx 3.45E-02 0.98 1.01 0.94 0.93 3.37E-02 3.49E-02 3.26E-02 3.21E-022104008100 55133 NOX 9.80E-030.99 1.01 0.95 0.949.66E-03 9.95E-03 9.30E-03 9.26E-032104008210 55133 NOX 1.95E-020.99 1.01 0.95 0.941.92E-02 1.98E-02 1.85E-02 1.84E-022104008220 55133 NOX 5.10E-030.99 1.01 0.95 0.945.02E-03 5.17E-03 4.84E-03 4.82E-032104008230 55133 NOX 1.49E-030.99 1.01 0.95 0.941.47E-03 1.51E-03 1.41E-03 1.41E-032104008310 55133 NOX 1.23E-020.99 1.01 0.95 0.941.21E-02 1.25E-02 1.16E-02 1.16E-022104008320 55133 NOX 3.21E-030.99 1.01 0.95 0.943.16E-03 3.25E-03 3.04E-03 3.03E-032104008330 55133 NOX 9.39E-040.99 1.01 0.95 0.949.25E-04 9.53E-04 8.91E-04 8.87E-04SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2104008400 55133 NOX 1.08E-020.99 1.01 0.95 0.941.06E-02 1.09E-02 1.02E-02 1.02E-022104008510 55133 NOX 2.25E-020.99 1.01 0.95 0.942.21E-02 2.28E-02 2.13E-02 2.12E-022104008610 55133 NOX 1.31E-010.99 1.01 0.95 0.941.30E-01 1.33E-01 1.25E-01 1.24E-012104009000 55133 NOX 5.54E-03 1.00 1.00 0.88 0.85 5.52E-03 5.54E-03 4.87E-03 4.69E-032104011000 55133 NOX 8.37E-08 0.98 1.01 0.90 0.88 8.23E-08 8.41E-08 7.53E-08 7.37E-082104011000 55133 NOx 8.69E-04 0.98 1.01 0.90 0.88 8.54E-04 8.74E-04 7.82E-04 7.65E-042610000100 55133 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55133 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55133 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55133 NOX 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002810030000 55133 NOX 6.24E-04 0.94 1.04 1.01 1.02 5.86E-04 6.46E-04 6.31E-04 6.37E-042810030000 55133 NOX 1.71E-06 0.94 1.04 1.01 1.02 1.61E-06 1.78E-06 1.73E-06 1.75E-062104008100 55079 PM25 2.44E-011.00 1.00 0.86 0.822.45E-01 2.43E-01 2.10E-01 2.00E-012104008210 55079 PM25 5.84E-011.00 1.00 0.86 0.825.86E-01 5.82E-01 5.03E-01 4.79E-012104008220 55079 PM25 1.20E-011.00 1.00 0.86 0.821.20E-01 1.19E-01 1.03E-01 9.85E-022104008230 55079 PM25 4.16E-021.00 1.00 0.86 0.824.18E-02 4.14E-02 3.59E-02 3.42E-022104008310 55079 PM25 3.67E-011.00 1.00 0.86 0.823.69E-01 3.66E-01 3.17E-01 3.02E-012104008320 55079 PM25 7.55E-021.00 1.00 0.86 0.827.58E-02 7.52E-02 6.50E-02 6.20E-022104008330 55079 PM25 2.61E-021.00 1.00 0.86 0.822.62E-02 2.60E-02 2.25E-02 2.15E-022104008400 55079 PM25 2.24E-021.00 1.00 0.86 0.822.25E-02 2.23E-02 1.93E-02 1.84E-022104008510 55079 PM25 9.33E-011.00 1.00 0.86 0.829.36E-01 9.29E-01 8.03E-01 7.66E-012104008610 55079 PM25 5.40E+001.00 1.00 0.86 0.825.42E+00 5.38E+00 4.65E+00 4.43E+002104009000 55079 PM25 5.28E-02 1.00 1.00 0.88 0.85 5.25E-02 5.27E-02 4.64E-02 4.47E-022294000000 55079 PM25 7.70E-01 0.99 1.01 0.97 1.00 7.61E-01 7.80E-01 7.48E-01 7.67E-012296000000 55079 PM25 0.00E+00 0.97 1.03 1.03 1.05 0.00E+00 0.00E+00 0.00E+00 0.00E+002302002100 55079 PM25 6.30E-02 0.97 1.03 1.03 1.05 6.14E-02 6.48E-02 6.46E-02 6.62E-022302002200 55079 PM25 4.46E-01 0.97 1.03 1.03 1.05 4.35E-01 4.59E-01 4.57E-01 4.68E-012302003100 55079 PM25 1.02E-01 0.97 1.03 1.03 1.05 9.97E-02 1.05E-01 1.05E-01 1.07E-012302003200 55079 PM25 7.72E-03 0.97 1.03 1.03 1.05 7.52E-03 7.94E-03 7.91E-03 8.11E-032311010000 55079 PM25 8.89E-03 0.98 1.02 1.05 1.09 8.73E-03 9.06E-03 9.31E-03 9.70E-032311020000 55079 PM25 5.72E-01 0.98 1.02 1.05 1.09 5.62E-01 5.83E-01 5.99E-01 6.25E-012311030000 55079 PM25 9.97E-02 0.98 1.02 1.05 1.09 9.79E-02 1.02E-01 1.04E-01 1.09E-01SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2610000100 55079 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55079 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55079 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55079 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002104008100 55101 PM25 1.46E-010.99 1.01 0.92 0.901.45E-01 1.48E-01 1.34E-01 1.32E-012104008210 55101 PM25 1.18E-010.99 1.01 0.92 0.901.17E-01 1.19E-01 1.08E-01 1.06E-012104008220 55101 PM25 3.19E-020.99 1.01 0.92 0.903.16E-02 3.22E-02 2.92E-02 2.87E-022104008230 55101 PM25 1.07E-020.99 1.01 0.92 0.901.06E-02 1.08E-02 9.85E-03 9.68E-032104008310 55101 PM25 5.16E-010.99 1.01 0.92 0.905.11E-01 5.21E-01 4.74E-01 4.66E-012104008320 55101 PM25 1.04E-010.99 1.01 0.92 0.901.04E-01 1.05E-01 9.59E-02 9.42E-022104008330 55101 PM25 1.20E-010.99 1.01 0.92 0.901.19E-01 1.21E-01 1.10E-01 1.08E-012104008400 55101 PM25 9.58E-030.99 1.01 0.92 0.909.49E-03 9.66E-03 8.79E-03 8.64E-032104008510 55101 PM25 4.05E-010.99 1.01 0.92 0.904.01E-01 4.08E-01 3.71E-01 3.65E-012104008610 55101 PM25 9.55E-010.99 1.01 0.92 0.909.46E-01 9.64E-01 8.76E-01 8.61E-012104008700 55101 PM25 2.50E-010.99 1.01 0.92 0.902.48E-01 2.53E-01 2.30E-01 2.26E-012104009000 55101 PM25 1.61E-03 1.00 1.00 0.88 0.85 1.60E-03 1.61E-03 1.41E-03 1.36E-032294000000 55101 PM25 2.55E-01 0.99 1.01 0.97 1.00 2.52E-01 2.58E-01 2.48E-01 2.54E-012296000000 55101 PM25 1.94E-01 0.97 1.03 1.03 1.05 1.89E-01 2.00E-01 1.99E-01 2.04E-012302002100 55101 PM25 1.32E-02 0.97 1.03 1.03 1.05 1.29E-02 1.36E-02 1.35E-02 1.39E-022302002200 55101 PM25 9.33E-02 0.97 1.03 1.03 1.05 9.09E-02 9.60E-02 9.57E-02 9.80E-022302003100 55101 PM25 2.14E-02 0.97 1.03 1.03 1.05 2.09E-02 2.20E-02 2.20E-02 2.25E-022302003200 55101 PM25 1.62E-03 0.97 1.03 1.03 1.05 1.57E-03 1.66E-03 1.66E-03 1.70E-032311010000 55101 PM25 7.84E-03 0.98 1.02 1.05 1.09 7.70E-03 7.99E-03 8.21E-03 8.55E-032311020000 55101 PM25 2.29E-01 0.98 1.02 1.05 1.09 2.25E-01 2.34E-01 2.40E-01 2.50E-012311030000 55101 PM25 1.28E-01 0.98 1.02 1.05 1.09 1.25E-01 1.30E-01 1.34E-01 1.39E-012610000100 55101 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55101 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55101 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55101 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002104008100 55133 PM25 8.90E-020.99 1.01 0.95 0.948.77E-02 9.03E-02 8.44E-02 8.41E-022104008210 55133 PM25 2.13E-010.99 1.01 0.95 0.942.10E-01 2.16E-01 2.02E-01 2.01E-012104008220 55133 PM25 4.38E-020.99 1.01 0.95 0.944.32E-02 4.45E-02 4.16E-02 4.14E-022104008230 55133 PM25 1.52E-020.99 1.01 0.95 0.941.50E-02 1.54E-02 1.44E-02 1.44E-022104008310 55133 PM25 1.34E-010.99 1.01 0.95 0.941.32E-01 1.36E-01 1.27E-01 1.27E-01SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2104008320 55133 PM25 2.76E-020.99 1.01 0.95 0.942.72E-02 2.80E-02 2.62E-02 2.60E-022104008330 55133 PM25 9.57E-030.99 1.01 0.95 0.949.43E-03 9.72E-03 9.08E-03 9.05E-032104008400 55133 PM25 8.67E-030.99 1.01 0.95 0.948.55E-03 8.80E-03 8.23E-03 8.20E-032104008510 55133 PM25 3.37E-010.99 1.01 0.95 0.943.32E-01 3.42E-01 3.19E-01 3.18E-012104008610 55133 PM25 1.97E+000.99 1.01 0.95 0.941.94E+00 2.00E+00 1.87E+00 1.86E+002104009000 55133 PM25 2.05E-02 1.00 1.00 0.88 0.85 2.04E-02 2.05E-02 1.80E-02 1.73E-022294000000 55133 PM25 5.63E-01 0.99 1.01 0.97 1.00 5.56E-01 5.70E-01 5.47E-01 5.61E-012296000000 55133 PM25 3.60E-01 0.97 1.03 1.03 1.05 3.51E-01 3.71E-01 3.69E-01 3.78E-012302002100 55133 PM25 2.52E-02 0.97 1.03 1.03 1.05 2.45E-02 2.59E-02 2.58E-02 2.64E-022302002200 55133 PM25 1.78E-01 0.97 1.03 1.03 1.05 1.74E-01 1.83E-01 1.83E-01 1.87E-012302003100 55133 PM25 4.08E-02 0.97 1.03 1.03 1.05 3.98E-02 4.20E-02 4.19E-02 4.29E-022302003200 55133 PM25 3.08E-03 0.97 1.03 1.03 1.05 3.00E-03 3.17E-03 3.16E-03 3.24E-032311010000 55133 PM25 1.47E-02 0.98 1.02 1.05 1.09 1.44E-02 1.50E-02 1.54E-02 1.60E-022311020000 55133 PM25 9.08E-01 0.98 1.02 1.05 1.09 8.92E-01 9.25E-01 9.51E-01 9.91E-012311030000 55133 PM25 2.42E-01 0.98 1.02 1.05 1.09 2.38E-01 2.47E-01 2.53E-01 2.64E-012610000100 55133 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55133 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55133 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55133 PM25 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002102004001 55079 SO2 1.93E-011.00 1.00 0.86 0.821.93E-01 1.92E-01 1.66E-01 1.58E-012102004002 55079 SO2 5.07E-021.00 1.00 0.86 0.825.09E-02 5.05E-02 4.37E-02 4.16E-022102005000 55079 SO2 1.71E-01 0.98 0.99 0.85 0.84 1.67E-01 1.69E-01 1.45E-01 1.43E-012102006000 55079 SO2 1.85E-03 0.98 1.04 1.02 1.07 1.81E-03 1.91E-03 1.89E-03 1.97E-032102008000 55079 SO2 7.14E-03 0.96 1.06 1.18 1.25 6.82E-03 7.53E-03 8.44E-03 8.93E-032102011000 55079 SO2 1.27E-06 0.98 0.98 0.89 0.89 1.25E-06 1.25E-06 1.13E-06 1.14E-062103002000 55079 SO2 6.60E-01 1.02 0.99 0.85 0.82 6.70E-01 6.52E-01 5.62E-01 5.40E-012103004001 55079 SO2 2.17E-011.00 1.00 0.86 0.822.17E-01 2.16E-01 1.87E-01 1.78E-012103004002 55079 SO2 1.88E-011.00 1.00 0.86 0.821.89E-01 1.87E-01 1.62E-01 1.54E-012103005000 55079 SO2 5.51E-04 0.99 1.03 0.88 0.86 5.48E-04 5.65E-04 4.86E-04 4.74E-042103006000 55079 SO2 1.46E-02 0.99 1.01 0.89 0.90 1.44E-02 1.47E-02 1.29E-02 1.31E-022103007000 55079 SO2 7.24E-04 0.98 1.00 0.88 0.86 7.12E-04 7.26E-04 6.36E-04 6.25E-042103008000 55079 SO2 1.76E-03 1.00 1.00 0.87 0.84 1.76E-03 1.76E-03 1.53E-03 1.48E-032103011000 55079 SO2 5.69E-04 0.98 1.00 0.89 0.89 5.57E-04 5.66E-04 5.05E-04 5.05E-042104004000 55079 SO2 5.78E-01 1.01 0.98 0.75 0.65 5.84E-01 5.68E-01 4.34E-01 3.79E-01SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2104006000 55079 SO2 2.62E-02 0.98 1.01 0.90 0.88 2.57E-02 2.65E-02 2.36E-02 2.30E-022104007000 55079 SO2 3.25E-04 0.98 1.01 0.94 0.93 3.17E-04 3.29E-04 3.07E-04 3.02E-042104008100 55079 SO2 4.13E-031.00 1.00 0.86 0.824.15E-03 4.11E-03 3.56E-03 3.39E-032104008210 55079 SO2 7.63E-031.00 1.00 0.86 0.827.66E-03 7.60E-03 6.58E-03 6.27E-032104008220 55079 SO2 2.45E-031.00 1.00 0.86 0.822.46E-03 2.44E-03 2.11E-03 2.01E-032104008230 55079 SO2 8.16E-041.00 1.00 0.86 0.828.19E-04 8.13E-04 7.03E-04 6.70E-042104008310 55079 SO2 4.80E-031.00 1.00 0.86 0.824.82E-03 4.78E-03 4.14E-03 3.94E-032104008320 55079 SO2 1.54E-031.00 1.00 0.86 0.821.55E-03 1.53E-03 1.33E-03 1.26E-032104008330 55079 SO2 5.13E-041.00 1.00 0.86 0.825.15E-04 5.11E-04 4.42E-04 4.21E-042104008400 55079 SO2 2.34E-031.00 1.00 0.86 0.822.35E-03 2.33E-03 2.02E-03 1.92E-032104008510 55079 SO2 6.86E-021.00 1.00 0.86 0.826.89E-02 6.83E-02 5.91E-02 5.63E-022104008610 55079 SO2 3.97E-011.00 1.00 0.86 0.823.99E-01 3.95E-01 3.42E-01 3.26E-012104011000 55079 SO2 3.68E-03 0.98 1.01 0.90 0.88 3.62E-03 3.70E-03 3.31E-03 3.24E-032610000100 55079 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55079 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55079 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002102004001 55101 SO2 6.49E-020.99 1.01 0.92 0.906.43E-02 6.55E-02 5.96E-02 5.86E-022102004002 55101 SO2 1.71E-020.99 1.01 0.92 0.901.69E-02 1.72E-02 1.57E-02 1.54E-022102005000 55101 SO2 5.75E-02 0.98 0.99 0.85 0.84 5.61E-02 5.70E-02 4.90E-02 4.82E-022102006000 55101 SO2 6.23E-04 0.98 1.04 1.02 1.07 6.11E-04 6.45E-04 6.38E-04 6.65E-042102008000 55101 SO2 2.40E-03 0.96 1.06 1.18 1.25 2.30E-03 2.54E-03 2.84E-03 3.01E-032102011000 55101 SO2 4.29E-07 0.98 0.98 0.89 0.89 4.21E-07 4.22E-07 3.82E-07 3.83E-072103002000 55101 SO2 8.65E-02 1.02 0.99 0.85 0.82 8.79E-02 8.56E-02 7.37E-02 7.09E-022103004001 55101 SO2 2.84E-020.99 1.01 0.92 0.902.81E-02 2.87E-02 2.61E-02 2.56E-022103004002 55101 SO2 2.46E-020.99 1.01 0.92 0.902.44E-02 2.49E-02 2.26E-02 2.22E-022103005000 55101 SO2 7.23E-05 0.99 1.03 0.88 0.86 7.18E-05 7.41E-05 6.38E-05 6.22E-052103006000 55101 SO2 1.91E-03 0.99 1.01 0.89 0.90 1.90E-03 1.93E-03 1.70E-03 1.72E-032103007000 55101 SO2 9.50E-05 0.98 1.00 0.88 0.86 9.34E-05 9.52E-05 8.35E-05 8.19E-052103008000 55101 SO2 2.31E-04 1.00 1.00 0.87 0.84 2.31E-04 2.31E-04 2.01E-04 1.94E-042103011000 55101 SO2 7.46E-05 0.98 1.00 0.89 0.89 7.30E-05 7.43E-05 6.63E-05 6.62E-052104004000 55101 SO2 1.22E-01 1.01 0.98 0.75 0.65 1.24E-01 1.20E-01 9.19E-02 8.01E-022104006000 55101 SO2 4.72E-03 0.98 1.01 0.90 0.88 4.64E-03 4.78E-03 4.26E-03 4.16E-032104007000 55101 SO2 1.34E-04 0.98 1.01 0.94 0.93 1.31E-04 1.36E-04 1.27E-04 1.25E-042104008100 55101 SO2 2.48E-030.99 1.01 0.92 0.902.46E-03 2.50E-03 2.27E-03 2.24E-03SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2104008210 55101 SO2 1.54E-030.99 1.01 0.92 0.901.52E-03 1.55E-03 1.41E-03 1.39E-032104008220 55101 SO2 6.50E-040.99 1.01 0.92 0.906.44E-04 6.56E-04 5.97E-04 5.86E-042104008230 55101 SO2 2.10E-040.99 1.01 0.92 0.902.08E-04 2.12E-04 1.93E-04 1.90E-042104008310 55101 SO2 6.75E-030.99 1.01 0.92 0.906.68E-03 6.81E-03 6.19E-03 6.09E-032104008320 55101 SO2 2.13E-030.99 1.01 0.92 0.902.11E-03 2.15E-03 1.96E-03 1.92E-032104008330 55101 SO2 2.36E-030.99 1.01 0.92 0.902.34E-03 2.38E-03 2.16E-03 2.13E-032104008400 55101 SO2 1.00E-030.99 1.01 0.92 0.909.92E-04 1.01E-03 9.19E-04 9.03E-042104008510 55101 SO2 2.98E-020.99 1.01 0.92 0.902.95E-02 3.00E-02 2.73E-02 2.68E-022104008610 55101 SO2 7.02E-020.99 1.01 0.92 0.906.96E-02 7.09E-02 6.45E-02 6.34E-022104008700 55101 SO2 4.24E-030.99 1.01 0.92 0.904.20E-03 4.28E-03 3.89E-03 3.83E-032104011000 55101 SO2 7.78E-04 0.98 1.01 0.90 0.88 7.65E-04 7.82E-04 7.00E-04 6.85E-042610000100 55101 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55101 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55101 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002102004001 55133 SO2 2.04E-010.99 1.01 0.95 0.942.01E-01 2.07E-01 1.93E-01 1.92E-012102004002 55133 SO2 5.36E-020.99 1.01 0.95 0.945.28E-02 5.44E-02 5.08E-02 5.06E-022102005000 55133 SO2 1.80E-01 0.98 0.99 0.85 0.84 1.76E-01 1.79E-01 1.54E-01 1.51E-012102006000 55133 SO2 1.95E-03 0.98 1.04 1.02 1.07 1.92E-03 2.02E-03 2.00E-03 2.08E-032102008000 55133 SO2 7.54E-03 0.96 1.06 1.18 1.25 7.21E-03 7.96E-03 8.92E-03 9.44E-032102011000 55133 SO2 1.35E-06 0.98 0.98 0.89 0.89 1.32E-06 1.32E-06 1.20E-06 1.20E-062103002000 55133 SO2 2.78E-01 1.02 0.99 0.85 0.82 2.82E-01 2.75E-01 2.37E-01 2.28E-012103004001 55133 SO2 9.13E-020.99 1.01 0.95 0.948.99E-02 9.26E-02 8.66E-02 8.63E-022103004002 55133 SO2 7.92E-020.99 1.01 0.95 0.947.80E-02 8.03E-02 7.51E-02 7.48E-022103005000 55133 SO2 2.32E-04 0.99 1.03 0.88 0.86 2.31E-04 2.38E-04 2.05E-04 2.00E-042103006000 55133 SO2 6.15E-03 0.99 1.01 0.89 0.90 6.09E-03 6.19E-03 5.45E-03 5.53E-032103007000 55133 SO2 3.05E-04 0.98 1.00 0.88 0.86 3.00E-04 3.06E-04 2.68E-04 2.63E-042103008000 55133 SO2 7.42E-04 1.00 1.00 0.87 0.84 7.42E-04 7.42E-04 6.45E-04 6.23E-042103011000 55133 SO2 2.40E-04 0.98 1.00 0.89 0.89 2.35E-04 2.39E-04 2.13E-04 2.13E-042104004000 55133 SO2 3.23E-01 1.01 0.98 0.75 0.65 3.26E-01 3.17E-01 2.43E-01 2.12E-012104006000 55133 SO2 9.07E-03 0.98 1.01 0.90 0.88 8.93E-03 9.20E-03 8.20E-03 7.99E-032104007000 55133 SO2 1.47E-04 0.98 1.01 0.94 0.93 1.43E-04 1.48E-04 1.38E-04 1.36E-042104008100 55133 SO2 1.51E-030.99 1.01 0.95 0.941.49E-03 1.53E-03 1.43E-03 1.42E-032104008210 55133 SO2 2.79E-030.99 1.01 0.95 0.942.75E-03 2.83E-03 2.64E-03 2.63E-032104008220 55133 SO2 8.94E-040.99 1.01 0.95 0.948.81E-04 9.08E-04 8.49E-04 8.45E-04SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2104008230 55133 SO2 2.98E-040.99 1.01 0.95 0.942.94E-04 3.02E-04 2.83E-04 2.81E-042104008310 55133 SO2 1.75E-030.99 1.01 0.95 0.941.73E-03 1.78E-03 1.66E-03 1.66E-032104008320 55133 SO2 5.62E-040.99 1.01 0.95 0.945.54E-04 5.71E-04 5.34E-04 5.31E-042104008330 55133 SO2 1.88E-040.99 1.01 0.95 0.941.85E-04 1.91E-04 1.78E-04 1.77E-042104008400 55133 SO2 9.07E-040.99 1.01 0.95 0.948.94E-04 9.21E-04 8.61E-04 8.57E-042104008510 55133 SO2 2.48E-020.99 1.01 0.95 0.942.44E-02 2.51E-02 2.35E-02 2.34E-022104008610 55133 SO2 1.45E-010.99 1.01 0.95 0.941.43E-01 1.47E-01 1.38E-01 1.37E-012104011000 55133 SO2 2.06E-03 0.98 1.01 0.90 0.88 2.02E-03 2.07E-03 1.85E-03 1.81E-032610000100 55133 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55133 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55133 SO2 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002102004001 55079 VOC 1.19E-031.00 1.00 0.86 0.821.19E-03 1.18E-03 1.02E-03 9.76E-042102004001 55079 VOC 3.81E-061.00 1.00 0.86 0.823.82E-06 3.79E-06 3.28E-06 3.13E-062102004002 55079 VOC 6.94E-041.00 1.00 0.86 0.826.97E-04 6.92E-04 5.98E-04 5.70E-042102004002 55079 VOC 2.23E-061.00 1.00 0.86 0.822.23E-06 2.22E-06 1.92E-06 1.83E-062102005000 55079 VOC 4.36E-07 0.98 0.99 0.85 0.84 4.26E-07 4.32E-07 3.72E-07 3.66E-072102005000 55079 VOC 1.36E-04 0.98 0.99 0.85 0.84 1.33E-04 1.35E-04 1.16E-04 1.14E-042102006000 55079 VOC 5.43E-05 0.98 1.04 1.02 1.07 5.32E-05 5.62E-05 5.56E-05 5.79E-052102006000 55079 VOC 1.69E-02 0.98 1.04 1.02 1.07 1.66E-02 1.76E-02 1.74E-02 1.81E-022102008000 55079 VOC 1.55E-05 0.96 1.06 1.18 1.25 1.49E-05 1.64E-05 1.84E-05 1.95E-052102008000 55079 VOC 4.85E-03 0.96 1.06 1.18 1.25 4.64E-03 5.12E-03 5.74E-03 6.07E-032102011000 55079 VOC 2.48E-08 0.98 0.98 0.89 0.89 2.43E-08 2.43E-08 2.21E-08 2.21E-082102011000 55079 VOC 7.73E-06 0.98 0.98 0.89 0.89 7.58E-06 7.60E-06 6.89E-06 6.91E-062103002000 55079 VOC 2.20E-06 1.02 0.99 0.85 0.82 2.23E-06 2.18E-06 1.87E-06 1.80E-062103002000 55079 VOC 1.14E-03 1.02 0.99 0.85 0.82 1.16E-03 1.13E-03 9.74E-04 9.37E-042103004001 55079 VOC 4.92E-061.00 1.00 0.86 0.824.94E-06 4.90E-06 4.24E-06 4.04E-062103004001 55079 VOC 2.56E-031.00 1.00 0.86 0.822.57E-03 2.55E-03 2.20E-03 2.10E-032103004002 55079 VOC 2.49E-031.00 1.00 0.86 0.822.50E-03 2.48E-03 2.14E-03 2.04E-032103004002 55079 VOC 4.79E-061.00 1.00 0.86 0.824.80E-06 4.77E-06 4.12E-06 3.93E-062103005000 55079 VOC 7.94E-09 0.99 1.03 0.88 0.86 7.89E-09 8.15E-09 7.01E-09 6.83E-092103005000 55079 VOC 4.13E-06 0.99 1.03 0.88 0.86 4.10E-06 4.24E-06 3.64E-06 3.55E-062103006000 55079 VOC 2.57E-04 0.99 1.01 0.89 0.90 2.55E-04 2.59E-04 2.28E-04 2.31E-042103006000 55079 VOC 1.34E-01 0.99 1.01 0.89 0.90 1.32E-01 1.35E-01 1.19E-01 1.20E-012103007000 55079 VOC 1.28E-05 0.98 1.00 0.88 0.86 1.25E-05 1.28E-05 1.12E-05 1.10E-05SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2103007000 55079 VOC 6.64E-03 0.98 1.00 0.88 0.86 6.52E-03 6.65E-03 5.83E-03 5.73E-032103008000 55079 VOC 2.30E-06 1.00 1.00 0.87 0.84 2.30E-06 2.30E-06 2.00E-06 1.93E-062103008000 55079 VOC 1.20E-03 1.00 1.00 0.87 0.84 1.20E-03 1.20E-03 1.04E-03 1.01E-032103011000 55079 VOC 4.54E-08 0.98 1.00 0.89 0.89 4.45E-08 4.52E-08 4.04E-08 4.03E-082103011000 55079 VOC 2.36E-05 0.98 1.00 0.89 0.89 2.31E-05 2.35E-05 2.10E-05 2.10E-052104004000 55079 VOC 9.15E-07 1.01 0.98 0.75 0.65 9.24E-07 8.99E-07 6.87E-07 5.99E-072104004000 55079 VOC 9.50E-03 1.01 0.98 0.75 0.65 9.59E-03 9.33E-03 7.13E-03 6.22E-032104006000 55079 VOC 1.85E-04 0.98 1.01 0.90 0.88 1.82E-04 1.87E-04 1.67E-04 1.62E-042104006000 55079 VOC 2.40E-01 0.98 1.01 0.90 0.88 2.36E-01 2.43E-01 2.17E-01 2.11E-012104007000 55079 VOC 2.29E-06 0.98 1.01 0.94 0.93 2.24E-06 2.32E-06 2.16E-06 2.13E-062104007000 55079 VOC 2.98E-03 0.98 1.01 0.94 0.93 2.91E-03 3.01E-03 2.81E-03 2.77E-032104008100 55079 VOC 1.95E-011.00 1.00 0.86 0.821.96E-01 1.94E-01 1.68E-01 1.60E-012104008210 55079 VOC 1.01E+001.00 1.00 0.86 0.821.02E+00 1.01E+00 8.71E-01 8.30E-012104008220 55079 VOC 7.34E-021.00 1.00 0.86 0.827.37E-02 7.31E-02 6.33E-02 6.03E-022104008230 55079 VOC 3.06E-021.00 1.00 0.86 0.823.07E-02 3.05E-02 2.64E-02 2.51E-022104008310 55079 VOC 6.36E-011.00 1.00 0.86 0.826.39E-01 6.34E-01 5.48E-01 5.23E-012104008320 55079 VOC 4.62E-021.00 1.00 0.86 0.824.64E-02 4.60E-02 3.98E-02 3.79E-022104008330 55079 VOC 1.92E-021.00 1.00 0.86 0.821.93E-02 1.91E-02 1.66E-02 1.58E-022104008400 55079 VOC 3.00E-041.00 1.00 0.86 0.823.01E-04 2.99E-04 2.59E-04 2.46E-042104008510 55079 VOC 3.99E-011.00 1.00 0.86 0.824.00E-01 3.97E-01 3.44E-01 3.27E-012104008610 55079 VOC 2.31E+001.00 1.00 0.86 0.822.32E+00 2.30E+00 1.99E+00 1.90E+002104009000 55079 VOC 7.35E-02 1.00 1.00 0.88 0.85 7.32E-02 7.35E-02 6.46E-02 6.23E-022104011000 55079 VOC 5.82E-09 0.98 1.01 0.90 0.88 5.72E-09 5.85E-09 5.24E-09 5.13E-092104011000 55079 VOC 6.04E-05 0.98 1.01 0.90 0.88 5.94E-05 6.08E-05 5.44E-05 5.32E-052302002100 55079 VOC 1.57E-02 0.97 1.03 1.03 1.05 1.53E-02 1.62E-02 1.61E-02 1.65E-022302002200 55079 VOC 5.42E-02 0.97 1.03 1.03 1.05 5.28E-02 5.57E-02 5.55E-02 5.69E-022302003000 55079 VOC 1.65E-02 0.97 1.03 1.03 1.05 1.60E-02 1.69E-02 1.69E-02 1.73E-022302003100 55079 VOC 7.76E-03 0.97 1.03 1.03 1.05 7.56E-03 7.98E-03 7.96E-03 8.15E-032302003200 55079 VOC 3.02E-04 0.97 1.03 1.03 1.05 2.95E-04 3.11E-04 3.10E-04 3.18E-042401001000 55079 VOC 3.94E+00 0.96 1.04 1.08 1.11 3.78E+00 4.12E+00 4.24E+00 4.37E+002401005000 55079 VOC 6.15E-01 0.97 1.03 1.05 1.10 5.96E-01 6.32E-01 6.48E-01 6.80E-012401005000 55079 VOC 2.37E-03 0.97 1.03 1.05 1.10 2.29E-03 2.43E-03 2.49E-03 2.61E-032401008000 55079 VOC 3.56E-03 1.00 1.00 0.83 0.76 3.55E-03 3.57E-03 2.94E-03 2.71E-032401008000 55079 VOC 1.86E-05 1.00 1.00 0.83 0.76 1.86E-05 1.87E-05 1.54E-05 1.42E-05SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2401020000 55079 VOC 2.18E-01 0.98 0.98 1.08 1.26 2.12E-01 2.14E-01 2.36E-01 2.75E-012401020000 55079 VOC 8.38E-04 0.98 0.98 1.08 1.26 8.17E-04 8.22E-04 9.09E-04 1.06E-032401025000 55079 VOC 2.68E-01 0.98 0.98 1.08 1.26 2.61E-01 2.63E-01 2.90E-01 3.38E-012401025000 55079 VOC 1.03E-03 0.98 0.98 1.08 1.26 1.00E-03 1.01E-03 1.12E-03 1.30E-032401030000 55079 VOC 8.38E-02 1.04 0.96 0.94 1.01 8.70E-02 8.04E-02 7.89E-02 8.45E-022401030000 55079 VOC 3.22E-04 1.04 0.96 0.94 1.01 3.34E-04 3.09E-04 3.03E-04 3.25E-042401040000 55079 VOC 6.78E-01 0.97 1.01 1.09 1.19 6.60E-01 6.88E-01 7.36E-01 8.07E-012401040000 55079 VOC 2.61E-03 0.97 1.01 1.09 1.19 2.54E-03 2.65E-03 2.83E-03 3.11E-032401045000 55079 VOC 9.44E-01 0.97 1.01 1.09 1.19 9.19E-01 9.58E-01 1.03E+00 1.12E+002401045000 55079 VOC 3.63E-03 0.97 1.01 1.09 1.19 3.53E-03 3.69E-03 3.94E-03 4.33E-032401055000 55079 VOC 5.26E-01 0.86 1.14 1.62 1.94 4.55E-01 6.00E-01 8.53E-01 1.02E+002401055000 55079 VOC 2.02E-03 0.86 1.14 1.62 1.94 1.75E-03 2.31E-03 3.28E-03 3.92E-032401060000 55079 VOC 5.51E-02 0.98 0.99 1.08 1.23 5.40E-02 5.47E-02 5.94E-02 6.77E-022401060000 55079 VOC 2.12E-04 0.98 0.99 1.08 1.23 2.08E-04 2.10E-04 2.28E-04 2.60E-042401065000 55079 VOC 3.23E-03 0.98 0.99 1.08 1.23 3.16E-03 3.20E-03 3.48E-03 3.96E-032401065000 55079 VOC 1.24E-05 0.98 0.99 1.08 1.23 1.22E-05 1.23E-05 1.34E-05 1.52E-052401070000 55079 VOC 4.33E-01 0.95 1.04 1.12 1.24 4.10E-01 4.49E-01 4.86E-01 5.38E-012401070000 55079 VOC 1.66E-03 0.95 1.04 1.12 1.24 1.58E-03 1.73E-03 1.87E-03 2.07E-032401075000 55079 VOC 0.00E+00 0.97 1.00 1.00 1.08 0.00E+00 0.00E+00 0.00E+00 0.00E+002401075000 55079 VOC 0.00E+00 0.97 1.00 1.00 1.08 0.00E+00 0.00E+00 0.00E+00 0.00E+002401080000 55079 VOC 7.23E-03 0.97 1.00 1.00 1.08 7.05E-03 7.20E-03 7.24E-03 7.81E-032401080000 55079 VOC 2.78E-05 0.97 1.00 1.00 1.08 2.71E-05 2.77E-05 2.79E-05 3.00E-052401085000 55079 VOC 3.12E-02 0.96 1.04 1.12 1.20 2.99E-02 3.25E-02 3.49E-02 3.76E-022401085000 55079 VOC 1.20E-04 0.96 1.04 1.12 1.20 1.15E-04 1.25E-04 1.34E-04 1.44E-042401090000 55079 VOC 3.19E-01 0.97 1.02 1.05 1.13 3.08E-01 3.24E-01 3.33E-01 3.61E-012401090000 55079 VOC 1.23E-03 0.97 1.02 1.05 1.13 1.19E-03 1.25E-03 1.28E-03 1.39E-032401100000 55079 VOC 1.44E+00 0.93 1.07 1.30 1.48 1.33E+00 1.54E+00 1.87E+00 2.13E+002401200000 55079 VOC 9.14E-03 1.00 0.99 1.00 1.07 9.12E-03 9.08E-03 9.15E-03 9.74E-032415000000 55079 VOC 2.09E+00 0.98 1.00 1.04 1.15 2.05E+00 2.08E+00 2.17E+00 2.40E+002415000000 55079 VOC 6.69E-03 0.98 1.00 1.04 1.15 6.58E-03 6.67E-03 6.96E-03 7.69E-032425000000 55079 VOC 8.50E+00 1.02 0.97 0.97 1.04 8.66E+00 8.26E+00 8.25E+00 8.87E+002425000000 55079 VOC 2.72E-02 1.02 0.97 0.97 1.04 2.77E-02 2.65E-02 2.64E-02 2.84E-022460100000 55079 VOC 2.48E+00 0.99 1.01 0.97 1.00 2.45E+00 2.51E+00 2.41E+00 2.47E+002460200000 55079 VOC 2.35E+00 0.99 1.01 0.97 1.00 2.32E+00 2.38E+00 2.28E+00 2.34E+00SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2460400000 55079 VOC 1.78E+00 0.99 1.01 0.97 1.00 1.75E+00 1.80E+00 1.72E+00 1.77E+002460500000 55079 VOC 1.24E+00 0.99 1.01 0.97 1.00 1.23E+00 1.26E+00 1.20E+00 1.24E+002460600000 55079 VOC 7.44E-01 0.99 1.01 0.97 1.00 7.35E-01 7.54E-01 7.23E-01 7.41E-012460800000 55079 VOC 2.32E+00 0.99 1.01 0.97 1.00 2.30E+00 2.35E+00 2.26E+00 2.31E+002460900000 55079 VOC 9.14E-02 0.99 1.01 0.97 1.00 9.03E-02 9.25E-02 8.87E-02 9.10E-022461021000 55079 VOC 9.04E-01 0.95 1.05 1.16 1.25 8.55E-01 9.52E-01 1.05E+00 1.13E+002461022000 55079 VOC 2.18E-01 0.95 1.05 1.16 1.25 2.07E-01 2.30E-01 2.54E-01 2.74E-012461800000 55079 VOC 1.11E-02 0.99 1.01 0.97 1.00 1.09E-02 1.12E-02 1.07E-02 1.10E-022461800000 55079 VOC 5.21E-05 0.99 1.01 0.97 1.00 5.15E-05 5.28E-05 5.06E-05 5.19E-052501011011 55079 VOC 3.96E-011.00 1.00 0.86 0.823.97E-01 3.94E-01 3.41E-01 3.25E-012501011012 55079 VOC 7.72E-011.00 1.00 0.86 0.827.75E-01 7.69E-01 6.65E-01 6.34E-012501011013 55079 VOC 9.92E-021.00 1.00 0.86 0.829.96E-02 9.88E-02 8.54E-02 8.14E-022501011014 55079 VOC 2.96E-021.00 1.00 0.86 0.822.97E-02 2.95E-02 2.55E-02 2.43E-022501011015 55079 VOC 2.72E-031.00 1.00 0.86 0.822.73E-03 2.71E-03 2.34E-03 2.23E-032501012011 55079 VOC 1.26E-021.00 1.00 0.86 0.821.27E-02 1.26E-02 1.09E-02 1.04E-022501012012 55079 VOC 2.47E-021.00 1.00 0.86 0.822.48E-02 2.46E-02 2.13E-02 2.03E-022501012013 55079 VOC 1.35E-011.00 1.00 0.86 0.821.36E-01 1.35E-01 1.17E-01 1.11E-012501012014 55079 VOC 5.70E-021.00 1.00 0.86 0.825.73E-02 5.68E-02 4.91E-02 4.68E-022501012015 55079 VOC 5.24E-031.00 1.00 0.86 0.825.26E-03 5.21E-03 4.51E-03 4.30E-032501050120 55079 VOC 2.70E-01 1.00 1.00 0.83 0.76 2.70E-01 2.71E-01 2.24E-01 2.06E-012501050120 55079 VOC 8.67E-04 1.00 1.00 0.83 0.76 8.65E-04 8.70E-04 7.18E-04 6.61E-042501055120 55079 VOC 0.00E+001.00 1.00 0.86 0.820.00E+00 0.00E+00 0.00E+00 0.00E+002501055120 55079 VOC 0.00E+001.00 1.00 0.86 0.820.00E+00 0.00E+00 0.00E+00 0.00E+002501060050 55079 VOC 8.49E-01 1.00 1.00 0.83 0.76 8.48E-01 8.53E-01 7.03E-01 6.47E-012501060050 55079 VOC 2.71E-03 1.00 1.00 0.83 0.76 2.71E-03 2.72E-03 2.25E-03 2.07E-032501060100 55079 VOC 6.54E-01 1.00 1.00 0.83 0.76 6.53E-01 6.56E-01 5.42E-01 4.98E-012501060100 55079 VOC 1.71E-03 1.00 1.00 0.83 0.76 1.71E-03 1.72E-03 1.42E-03 1.30E-032501060201 55079 VOC 7.31E-02 1.00 1.00 0.83 0.76 7.29E-02 7.33E-02 6.05E-02 5.57E-022501060201 55079 VOC 2.18E-04 1.00 1.00 0.83 0.76 2.18E-04 2.19E-04 1.81E-04 1.66E-042501080050 55079 VOC 1.24E-01 0.93 1.07 1.19 1.28 1.16E-01 1.33E-01 1.48E-01 1.59E-012501080050 55079 VOC 3.98E-04 0.93 1.07 1.19 1.28 3.71E-04 4.25E-04 4.73E-04 5.10E-042501080100 55079 VOC 2.68E-02 0.93 1.07 1.19 1.28 2.50E-02 2.87E-02 3.19E-02 3.43E-022501080100 55079 VOC 7.36E-05 0.93 1.07 1.19 1.28 6.86E-05 7.87E-05 8.75E-05 9.44E-052505030120 55079 VOC 2.68E-02 1.00 1.00 0.83 0.76 2.68E-02 2.69E-02 2.22E-02 2.05E-02SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2505030120 55079 VOC 9.36E-05 1.00 1.00 0.83 0.76 9.34E-05 9.40E-05 7.75E-05 7.13E-052610000100 55079 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55079 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55079 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55079 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002630010000 55079 VOC 1.24E-02 0.95 1.04 1.19 1.34 1.18E-02 1.29E-02 1.48E-02 1.66E-022630010000 55079 VOC 5.57E-05 0.95 1.04 1.19 1.34 5.30E-05 5.81E-05 6.65E-05 7.46E-052630020000 55079 VOC 0.00E+00 0.98 1.02 1.04 1.08 0.00E+00 0.00E+00 0.00E+00 0.00E+002630020000 55079 VOC 0.00E+00 0.98 1.02 1.04 1.08 0.00E+00 0.00E+00 0.00E+00 0.00E+002640000000 55079 VOC 2.99E-06 0.98 1.02 1.04 1.08 2.91E-06 3.05E-06 3.10E-06 3.24E-062640000000 55079 VOC 8.22E-09 0.98 1.02 1.04 1.08 8.02E-09 8.40E-09 8.54E-09 8.92E-092810030000 55079 VOC 3.92E-03 0.94 1.04 1.01 1.02 3.67E-03 4.06E-03 3.96E-03 4.00E-032810030000 55079 VOC 1.08E-05 0.94 1.04 1.01 1.02 1.01E-05 1.11E-05 1.09E-05 1.10E-052102004001 55101 VOC 4.00E-040.99 1.01 0.92 0.903.97E-04 4.04E-04 3.67E-04 3.61E-042102004001 55101 VOC 1.28E-060.99 1.01 0.92 0.901.27E-06 1.30E-06 1.18E-06 1.16E-062102004002 55101 VOC 2.34E-040.99 1.01 0.92 0.902.32E-04 2.36E-04 2.15E-04 2.11E-042102004002 55101 VOC 7.50E-070.99 1.01 0.92 0.907.43E-07 7.57E-07 6.88E-07 6.76E-072102005000 55101 VOC 1.47E-07 0.98 0.99 0.85 0.84 1.44E-07 1.46E-07 1.25E-07 1.23E-072102005000 55101 VOC 4.59E-05 0.98 0.99 0.85 0.84 4.48E-05 4.55E-05 3.91E-05 3.85E-052102006000 55101 VOC 1.83E-05 0.98 1.04 1.02 1.07 1.79E-05 1.90E-05 1.87E-05 1.95E-052102006000 55101 VOC 5.71E-03 0.98 1.04 1.02 1.07 5.60E-03 5.92E-03 5.85E-03 6.09E-032102008000 55101 VOC 5.24E-06 0.96 1.06 1.18 1.25 5.01E-06 5.53E-06 6.20E-06 6.56E-062102008000 55101 VOC 1.64E-03 0.96 1.06 1.18 1.25 1.56E-03 1.73E-03 1.93E-03 2.05E-032102011000 55101 VOC 8.35E-09 0.98 0.98 0.89 0.89 8.19E-09 8.21E-09 7.44E-09 7.46E-092102011000 55101 VOC 2.60E-06 0.98 0.98 0.89 0.89 2.56E-06 2.56E-06 2.32E-06 2.33E-062103002000 55101 VOC 2.89E-07 1.02 0.99 0.85 0.82 2.93E-07 2.86E-07 2.46E-07 2.37E-072103002000 55101 VOC 1.50E-04 1.02 0.99 0.85 0.82 1.52E-04 1.48E-04 1.28E-04 1.23E-042103004001 55101 VOC 6.45E-070.99 1.01 0.92 0.906.39E-07 6.51E-07 5.92E-07 5.82E-072103004001 55101 VOC 3.36E-040.99 1.01 0.92 0.903.33E-04 3.39E-04 3.08E-04 3.03E-042103004002 55101 VOC 3.26E-040.99 1.01 0.92 0.903.23E-04 3.29E-04 3.00E-04 2.94E-042103004002 55101 VOC 6.28E-070.99 1.01 0.92 0.906.22E-07 6.34E-07 5.76E-07 5.66E-072103005000 55101 VOC 1.04E-09 0.99 1.03 0.88 0.86 1.04E-09 1.07E-09 9.20E-10 8.96E-102103005000 55101 VOC 5.42E-07 0.99 1.03 0.88 0.86 5.38E-07 5.56E-07 4.78E-07 4.66E-072103006000 55101 VOC 3.37E-05 0.99 1.01 0.89 0.90 3.34E-05 3.40E-05 2.99E-05 3.04E-05SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2103006000 55101 VOC 1.75E-02 0.99 1.01 0.89 0.90 1.74E-02 1.77E-02 1.56E-02 1.58E-022103007000 55101 VOC 1.68E-06 0.98 1.00 0.88 0.86 1.65E-06 1.68E-06 1.47E-06 1.44E-062103007000 55101 VOC 8.71E-04 0.98 1.00 0.88 0.86 8.56E-04 8.73E-04 7.65E-04 7.51E-042103008000 55101 VOC 3.02E-07 1.00 1.00 0.87 0.84 3.02E-07 3.02E-07 2.63E-07 2.54E-072103008000 55101 VOC 1.57E-04 1.00 1.00 0.87 0.84 1.57E-04 1.57E-04 1.37E-04 1.32E-042103011000 55101 VOC 5.96E-09 0.98 1.00 0.89 0.89 5.83E-09 5.94E-09 5.30E-09 5.29E-092103011000 55101 VOC 3.10E-06 0.98 1.00 0.89 0.89 3.03E-06 3.09E-06 2.75E-06 2.75E-062104004000 55101 VOC 1.94E-07 1.01 0.98 0.75 0.65 1.96E-07 1.90E-07 1.45E-07 1.27E-072104004000 55101 VOC 2.01E-03 1.01 0.98 0.75 0.65 2.03E-03 1.97E-03 1.51E-03 1.32E-032104006000 55101 VOC 3.33E-05 0.98 1.01 0.90 0.88 3.27E-05 3.37E-05 3.01E-05 2.93E-052104006000 55101 VOC 4.33E-02 0.98 1.01 0.90 0.88 4.26E-02 4.39E-02 3.91E-02 3.81E-022104007000 55101 VOC 9.46E-07 0.98 1.01 0.94 0.93 9.23E-07 9.57E-07 8.93E-07 8.80E-072104007000 55101 VOC 1.23E-03 0.98 1.01 0.94 0.93 1.20E-03 1.24E-03 1.16E-03 1.14E-032104008100 55101 VOC 1.17E-010.99 1.01 0.92 0.901.16E-01 1.18E-01 1.07E-01 1.06E-012104008210 55101 VOC 2.04E-010.99 1.01 0.92 0.902.02E-01 2.06E-01 1.87E-01 1.84E-012104008220 55101 VOC 1.95E-020.99 1.01 0.92 0.901.93E-02 1.97E-02 1.79E-02 1.76E-022104008230 55101 VOC 7.89E-030.99 1.01 0.92 0.907.82E-03 7.96E-03 7.24E-03 7.12E-032104008310 55101 VOC 8.94E-010.99 1.01 0.92 0.908.86E-01 9.02E-01 8.20E-01 8.06E-012104008320 55101 VOC 6.40E-020.99 1.01 0.92 0.906.34E-02 6.46E-02 5.87E-02 5.77E-022104008330 55101 VOC 8.84E-020.99 1.01 0.92 0.908.76E-02 8.92E-02 8.11E-02 7.97E-022104008400 55101 VOC 1.28E-040.99 1.01 0.92 0.901.27E-04 1.29E-04 1.18E-04 1.16E-042104008510 55101 VOC 1.73E-010.99 1.01 0.92 0.901.71E-01 1.75E-01 1.59E-01 1.56E-012104008610 55101 VOC 4.08E-010.99 1.01 0.92 0.904.05E-01 4.12E-01 3.75E-01 3.68E-012104008700 55101 VOC 2.01E-010.99 1.01 0.92 0.901.99E-01 2.02E-01 1.84E-01 1.81E-012104009000 55101 VOC 2.24E-03 1.00 1.00 0.88 0.85 2.23E-03 2.24E-03 1.97E-03 1.90E-032104011000 55101 VOC 1.23E-09 0.98 1.01 0.90 0.88 1.21E-09 1.24E-09 1.11E-09 1.08E-092104011000 55101 VOC 1.28E-05 0.98 1.01 0.90 0.88 1.26E-05 1.29E-05 1.15E-05 1.13E-052302002100 55101 VOC 3.29E-03 0.97 1.03 1.03 1.05 3.21E-03 3.39E-03 3.38E-03 3.46E-032302002200 55101 VOC 1.13E-02 0.97 1.03 1.03 1.05 1.10E-02 1.17E-02 1.16E-02 1.19E-022302003000 55101 VOC 3.45E-03 0.97 1.03 1.03 1.05 3.36E-03 3.54E-03 3.53E-03 3.62E-032302003100 55101 VOC 1.62E-03 0.97 1.03 1.03 1.05 1.58E-03 1.67E-03 1.67E-03 1.71E-032302003200 55101 VOC 6.33E-05 0.97 1.03 1.03 1.05 6.17E-05 6.51E-05 6.49E-05 6.65E-052401001000 55101 VOC 8.25E-01 0.96 1.04 1.08 1.11 7.91E-01 8.62E-01 8.88E-01 9.15E-012401005000 55101 VOC 1.29E-01 0.97 1.03 1.05 1.10 1.25E-01 1.33E-01 1.36E-01 1.43E-01SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2401005000 55101 VOC 4.97E-04 0.97 1.03 1.05 1.10 4.81E-04 5.10E-04 5.23E-04 5.48E-042401008000 55101 VOC 1.56E-03 1.00 1.00 0.83 0.76 1.56E-03 1.57E-03 1.30E-03 1.19E-032401008000 55101 VOC 8.18E-06 1.00 1.00 0.83 0.76 8.16E-06 8.21E-06 6.77E-06 6.24E-062401015000 55101 VOC 1.14E-02 0.96 1.03 1.07 1.12 1.10E-02 1.18E-02 1.22E-02 1.28E-022401015000 55101 VOC 4.40E-05 0.96 1.03 1.07 1.12 4.23E-05 4.55E-05 4.69E-05 4.92E-052401020000 55101 VOC 8.59E-02 0.98 0.98 1.08 1.26 8.37E-02 8.43E-02 9.32E-02 1.09E-012401020000 55101 VOC 3.30E-04 0.98 0.98 1.08 1.26 3.22E-04 3.24E-04 3.58E-04 4.17E-042401025000 55101 VOC 2.07E-01 0.98 0.98 1.08 1.26 2.02E-01 2.03E-01 2.24E-01 2.62E-012401025000 55101 VOC 7.96E-04 0.98 0.98 1.08 1.26 7.76E-04 7.81E-04 8.63E-04 1.01E-032401030000 55101 VOC 6.86E-02 1.04 0.96 0.94 1.01 7.12E-02 6.58E-02 6.46E-02 6.92E-022401030000 55101 VOC 2.64E-04 1.04 0.96 0.94 1.01 2.74E-04 2.53E-04 2.48E-04 2.66E-042401040000 55101 VOC 0.00E+00 0.97 1.01 1.09 1.19 0.00E+00 0.00E+00 0.00E+00 0.00E+002401040000 55101 VOC 0.00E+00 0.97 1.01 1.09 1.19 0.00E+00 0.00E+00 0.00E+00 0.00E+002401045000 55101 VOC 4.74E-01 0.97 1.01 1.09 1.19 4.61E-01 4.81E-01 5.15E-01 5.65E-012401045000 55101 VOC 1.82E-03 0.97 1.01 1.09 1.19 1.77E-03 1.85E-03 1.98E-03 2.17E-032401055000 55101 VOC 1.57E-01 0.86 1.14 1.62 1.94 1.36E-01 1.79E-01 2.55E-01 3.04E-012401055000 55101 VOC 6.04E-04 0.86 1.14 1.62 1.94 5.22E-04 6.88E-04 9.79E-04 1.17E-032401060000 55101 VOC 5.51E-01 0.98 0.99 1.08 1.23 5.40E-01 5.47E-01 5.94E-01 6.77E-012401060000 55101 VOC 2.12E-03 0.98 0.99 1.08 1.23 2.08E-03 2.10E-03 2.28E-03 2.60E-032401065000 55101 VOC 0.00E+00 0.98 0.99 1.08 1.23 0.00E+00 0.00E+00 0.00E+00 0.00E+002401065000 55101 VOC 0.00E+00 0.98 0.99 1.08 1.23 0.00E+00 0.00E+00 0.00E+00 0.00E+002401070000 55101 VOC 1.43E-01 0.95 1.04 1.12 1.24 1.35E-01 1.48E-01 1.60E-01 1.77E-012401070000 55101 VOC 5.49E-04 0.95 1.04 1.12 1.24 5.20E-04 5.69E-04 6.17E-04 6.82E-042401075000 55101 VOC 1.63E-03 0.97 1.00 1.00 1.08 1.58E-03 1.62E-03 1.63E-03 1.76E-032401075000 55101 VOC 6.25E-06 0.97 1.00 1.00 1.08 6.09E-06 6.23E-06 6.26E-06 6.75E-062401080000 55101 VOC 0.00E+00 0.97 1.00 1.00 1.08 0.00E+00 0.00E+00 0.00E+00 0.00E+002401080000 55101 VOC 0.00E+00 0.97 1.00 1.00 1.08 0.00E+00 0.00E+00 0.00E+00 0.00E+002401085000 55101 VOC 1.33E-02 0.96 1.04 1.12 1.20 1.27E-02 1.38E-02 1.49E-02 1.60E-022401085000 55101 VOC 5.12E-05 0.96 1.04 1.12 1.20 4.90E-05 5.32E-05 5.73E-05 6.16E-052401090000 55101 VOC 1.84E-01 0.97 1.02 1.05 1.13 1.78E-01 1.88E-01 1.93E-01 2.09E-012401090000 55101 VOC 7.09E-04 0.97 1.02 1.05 1.13 6.87E-04 7.21E-04 7.42E-04 8.03E-042401100000 55101 VOC 3.01E-01 0.93 1.07 1.30 1.48 2.79E-01 3.22E-01 3.91E-01 4.45E-012401200000 55101 VOC 1.91E-03 1.00 0.99 1.00 1.07 1.91E-03 1.90E-03 1.91E-03 2.04E-032415000000 55101 VOC 4.91E-01 0.98 1.00 1.04 1.15 4.83E-01 4.89E-01 5.11E-01 5.65E-01SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2415000000 55101 VOC 1.57E-03 0.98 1.00 1.04 1.15 1.55E-03 1.57E-03 1.64E-03 1.81E-032425000000 55101 VOC 1.33E+00 1.02 0.97 0.97 1.04 1.36E+00 1.30E+00 1.30E+00 1.39E+002425000000 55101 VOC 4.28E-03 1.02 0.97 0.97 1.04 4.36E-03 4.16E-03 4.15E-03 4.46E-032460100000 55101 VOC 5.19E-01 0.99 1.01 0.97 1.00 5.13E-01 5.26E-01 5.04E-01 5.17E-012460200000 55101 VOC 4.92E-01 0.99 1.01 0.97 1.00 4.86E-01 4.98E-01 4.78E-01 4.90E-012460400000 55101 VOC 3.72E-01 0.99 1.01 0.97 1.00 3.67E-01 3.76E-01 3.61E-01 3.70E-012460500000 55101 VOC 2.60E-01 0.99 1.01 0.97 1.00 2.56E-01 2.63E-01 2.52E-01 2.58E-012460600000 55101 VOC 1.56E-01 0.99 1.01 0.97 1.00 1.54E-01 1.58E-01 1.51E-01 1.55E-012460800000 55101 VOC 4.86E-01 0.99 1.01 0.97 1.00 4.80E-01 4.92E-01 4.72E-01 4.84E-012460900000 55101 VOC 1.91E-02 0.99 1.01 0.97 1.00 1.89E-02 1.94E-02 1.86E-02 1.90E-022461021000 55101 VOC 1.36E-01 0.95 1.05 1.16 1.25 1.29E-01 1.43E-01 1.58E-01 1.70E-012461022000 55101 VOC 3.28E-02 0.95 1.05 1.16 1.25 3.11E-02 3.46E-02 3.82E-02 4.12E-022461800000 55101 VOC 5.13E-02 0.99 1.01 0.97 1.00 5.06E-02 5.19E-02 4.98E-02 5.10E-022461800000 55101 VOC 2.41E-04 0.99 1.01 0.97 1.00 2.38E-04 2.44E-04 2.34E-04 2.40E-042501011011 55101 VOC 7.08E-020.99 1.01 0.92 0.907.02E-02 7.15E-02 6.50E-02 6.39E-022501011012 55101 VOC 1.38E-010.99 1.01 0.92 0.901.37E-01 1.40E-01 1.27E-01 1.25E-012501011013 55101 VOC 1.78E-020.99 1.01 0.92 0.901.76E-02 1.79E-02 1.63E-02 1.60E-022501011014 55101 VOC 5.30E-030.99 1.01 0.92 0.905.25E-03 5.35E-03 4.86E-03 4.78E-032501011015 55101 VOC 4.87E-040.99 1.01 0.92 0.904.83E-04 4.92E-04 4.47E-04 4.39E-042501012011 55101 VOC 2.26E-030.99 1.01 0.92 0.902.24E-03 2.28E-03 2.08E-03 2.04E-032501012012 55101 VOC 4.42E-030.99 1.01 0.92 0.904.38E-03 4.46E-03 4.05E-03 3.98E-032501012013 55101 VOC 2.42E-020.99 1.01 0.92 0.902.40E-02 2.44E-02 2.22E-02 2.18E-022501012014 55101 VOC 1.02E-020.99 1.01 0.92 0.901.01E-02 1.03E-02 9.37E-03 9.21E-032501012015 55101 VOC 9.37E-040.99 1.01 0.92 0.909.29E-04 9.46E-04 8.60E-04 8.45E-042501050120 55101 VOC 4.52E-02 1.00 1.00 0.83 0.76 4.51E-02 4.54E-02 3.74E-02 3.44E-022501050120 55101 VOC 1.45E-04 1.00 1.00 0.83 0.76 1.45E-04 1.45E-04 1.20E-04 1.10E-042501055120 55101 VOC 1.42E-020.99 1.01 0.92 0.901.41E-02 1.43E-02 1.30E-02 1.28E-022501055120 55101 VOC 4.55E-050.99 1.01 0.92 0.904.51E-05 4.59E-05 4.17E-05 4.10E-052501060050 55101 VOC 2.04E-01 1.00 1.00 0.83 0.76 2.03E-01 2.04E-01 1.69E-01 1.55E-012501060050 55101 VOC 6.50E-04 1.00 1.00 0.83 0.76 6.49E-04 6.53E-04 5.39E-04 4.96E-042501060100 55101 VOC 1.57E-01 1.00 1.00 0.83 0.76 1.57E-01 1.57E-01 1.30E-01 1.20E-012501060100 55101 VOC 4.10E-04 1.00 1.00 0.83 0.76 4.09E-04 4.12E-04 3.40E-04 3.13E-042501060201 55101 VOC 1.75E-02 1.00 1.00 0.83 0.76 1.75E-02 1.76E-02 1.45E-02 1.34E-022501060201 55101 VOC 5.24E-05 1.00 1.00 0.83 0.76 5.23E-05 5.26E-05 4.34E-05 3.99E-05SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2501080050 55101 VOC 1.28E-01 0.93 1.07 1.19 1.28 1.19E-01 1.37E-01 1.52E-01 1.64E-012501080050 55101 VOC 4.09E-04 0.93 1.07 1.19 1.28 3.81E-04 4.38E-04 4.87E-04 5.25E-042501080100 55101 VOC 2.76E-02 0.93 1.07 1.19 1.28 2.57E-02 2.95E-02 3.28E-02 3.53E-022501080100 55101 VOC 7.58E-05 0.93 1.07 1.19 1.28 7.06E-05 8.10E-05 9.01E-05 9.71E-052505030120 55101 VOC 6.44E-03 1.00 1.00 0.83 0.76 6.42E-03 6.46E-03 5.33E-03 4.91E-032505030120 55101 VOC 2.25E-05 1.00 1.00 0.83 0.76 2.24E-05 2.25E-05 1.86E-05 1.71E-052610000100 55101 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55101 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55101 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55101 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002630010000 55101 VOC 0.00E+00 0.95 1.04 1.19 1.34 0.00E+00 0.00E+00 0.00E+00 0.00E+002630010000 55101 VOC 0.00E+00 0.95 1.04 1.19 1.34 0.00E+00 0.00E+00 0.00E+00 0.00E+002630020000 55101 VOC 1.15E-02 0.98 1.02 1.04 1.08 1.13E-02 1.18E-02 1.20E-02 1.25E-022630020000 55101 VOC 4.44E-05 0.98 1.02 1.04 1.08 4.33E-05 4.54E-05 4.61E-05 4.82E-052640000000 55101 VOC 4.02E-06 0.98 1.02 1.04 1.08 3.93E-06 4.11E-06 4.18E-06 4.36E-062640000000 55101 VOC 1.10E-08 0.98 1.02 1.04 1.08 1.08E-08 1.13E-08 1.15E-08 1.20E-082810030000 55101 VOC 3.80E-03 0.94 1.04 1.01 1.02 3.56E-03 3.93E-03 3.84E-03 3.87E-032810030000 55101 VOC 1.04E-05 0.94 1.04 1.01 1.02 9.78E-06 1.08E-05 1.05E-05 1.06E-052102004001 55133 VOC 1.26E-030.99 1.01 0.95 0.941.24E-03 1.27E-03 1.19E-03 1.19E-032102004001 55133 VOC 4.03E-060.99 1.01 0.95 0.943.97E-06 4.09E-06 3.82E-06 3.80E-062102004002 55133 VOC 7.34E-040.99 1.01 0.95 0.947.23E-04 7.45E-04 6.97E-04 6.94E-042102004002 55133 VOC 2.35E-060.99 1.01 0.95 0.942.32E-06 2.39E-06 2.23E-06 2.22E-062102005000 55133 VOC 4.61E-07 0.98 0.99 0.85 0.84 4.50E-07 4.57E-07 3.93E-07 3.87E-072102005000 55133 VOC 1.44E-04 0.98 0.99 0.85 0.84 1.41E-04 1.43E-04 1.23E-04 1.21E-042102006000 55133 VOC 5.74E-05 0.98 1.04 1.02 1.07 5.63E-05 5.95E-05 5.88E-05 6.12E-052102006000 55133 VOC 1.79E-02 0.98 1.04 1.02 1.07 1.76E-02 1.86E-02 1.84E-02 1.91E-022102008000 55133 VOC 1.64E-05 0.96 1.06 1.18 1.25 1.57E-05 1.74E-05 1.94E-05 2.06E-052102008000 55133 VOC 5.13E-03 0.96 1.06 1.18 1.25 4.90E-03 5.42E-03 6.07E-03 6.42E-032102011000 55133 VOC 2.62E-08 0.98 0.98 0.89 0.89 2.57E-08 2.57E-08 2.33E-08 2.34E-082102011000 55133 VOC 8.17E-06 0.98 0.98 0.89 0.89 8.02E-06 8.04E-06 7.28E-06 7.30E-062103002000 55133 VOC 9.28E-07 1.02 0.99 0.85 0.82 9.42E-07 9.17E-07 7.90E-07 7.60E-072103002000 55133 VOC 4.82E-04 1.02 0.99 0.85 0.82 4.90E-04 4.77E-04 4.11E-04 3.95E-042103004001 55133 VOC 2.07E-060.99 1.01 0.95 0.942.04E-06 2.10E-06 1.97E-06 1.96E-062103004001 55133 VOC 1.08E-030.99 1.01 0.95 0.941.06E-03 1.09E-03 1.02E-03 1.02E-03SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2103004002 55133 VOC 1.05E-030.99 1.01 0.95 0.941.03E-03 1.06E-03 9.95E-04 9.91E-042103004002 55133 VOC 2.02E-060.99 1.01 0.95 0.941.99E-06 2.05E-06 1.91E-06 1.91E-062103005000 55133 VOC 3.35E-09 0.99 1.03 0.88 0.86 3.33E-09 3.43E-09 2.95E-09 2.88E-092103005000 55133 VOC 1.74E-06 0.99 1.03 0.88 0.86 1.73E-06 1.79E-06 1.54E-06 1.50E-062103006000 55133 VOC 1.08E-04 0.99 1.01 0.89 0.90 1.07E-04 1.09E-04 9.61E-05 9.76E-052103006000 55133 VOC 5.64E-02 0.99 1.01 0.89 0.90 5.58E-02 5.67E-02 5.00E-02 5.07E-022103007000 55133 VOC 5.38E-06 0.98 1.00 0.88 0.86 5.29E-06 5.39E-06 4.73E-06 4.64E-062103007000 55133 VOC 2.80E-03 0.98 1.00 0.88 0.86 2.75E-03 2.80E-03 2.46E-03 2.41E-032103008000 55133 VOC 9.70E-07 1.00 1.00 0.87 0.84 9.70E-07 9.70E-07 8.44E-07 8.15E-072103008000 55133 VOC 5.04E-04 1.00 1.00 0.87 0.84 5.04E-04 5.04E-04 4.39E-04 4.24E-042103011000 55133 VOC 1.91E-08 0.98 1.00 0.89 0.89 1.87E-08 1.91E-08 1.70E-08 1.70E-082103011000 55133 VOC 9.96E-06 0.98 1.00 0.89 0.89 9.75E-06 9.92E-06 8.85E-06 8.84E-062104004000 55133 VOC 5.12E-07 1.01 0.98 0.75 0.65 5.17E-07 5.02E-07 3.84E-07 3.35E-072104004000 55133 VOC 5.31E-03 1.01 0.98 0.75 0.65 5.36E-03 5.22E-03 3.99E-03 3.48E-032104006000 55133 VOC 6.40E-05 0.98 1.01 0.90 0.88 6.29E-05 6.48E-05 5.78E-05 5.63E-052104006000 55133 VOC 8.32E-02 0.98 1.01 0.90 0.88 8.18E-02 8.43E-02 7.51E-02 7.32E-022104007000 55133 VOC 1.03E-06 0.98 1.01 0.94 0.93 1.01E-06 1.05E-06 9.76E-07 9.62E-072104007000 55133 VOC 1.34E-03 0.98 1.01 0.94 0.93 1.31E-03 1.36E-03 1.27E-03 1.25E-032104008100 55133 VOC 7.13E-020.99 1.01 0.95 0.947.02E-02 7.23E-02 6.76E-02 6.73E-022104008210 55133 VOC 3.69E-010.99 1.01 0.95 0.943.64E-01 3.75E-01 3.50E-01 3.49E-012104008220 55133 VOC 2.68E-020.99 1.01 0.95 0.942.64E-02 2.72E-02 2.55E-02 2.53E-022104008230 55133 VOC 1.12E-020.99 1.01 0.95 0.941.10E-02 1.13E-02 1.06E-02 1.06E-022104008310 55133 VOC 2.32E-010.99 1.01 0.95 0.942.29E-01 2.36E-01 2.21E-01 2.20E-012104008320 55133 VOC 1.69E-020.99 1.01 0.95 0.941.66E-02 1.71E-02 1.60E-02 1.59E-022104008330 55133 VOC 7.04E-030.99 1.01 0.95 0.946.94E-03 7.14E-03 6.68E-03 6.65E-032104008400 55133 VOC 1.16E-040.99 1.01 0.95 0.941.15E-04 1.18E-04 1.10E-04 1.10E-042104008510 55133 VOC 1.44E-010.99 1.01 0.95 0.941.42E-01 1.46E-01 1.37E-01 1.36E-012104008610 55133 VOC 8.43E-010.99 1.01 0.95 0.948.30E-01 8.55E-01 7.99E-01 7.96E-012104009000 55133 VOC 2.85E-02 1.00 1.00 0.88 0.85 2.84E-02 2.85E-02 2.51E-02 2.42E-022104011000 55133 VOC 3.38E-05 0.98 1.01 0.90 0.88 3.32E-05 3.40E-05 3.04E-05 2.98E-052104011000 55133 VOC 3.26E-09 0.98 1.01 0.90 0.88 3.20E-09 3.27E-09 2.93E-09 2.87E-092302002100 55133 VOC 6.29E-03 0.97 1.03 1.03 1.05 6.13E-03 6.47E-03 6.44E-03 6.60E-032302002200 55133 VOC 2.16E-02 0.97 1.03 1.03 1.05 2.11E-02 2.22E-02 2.22E-02 2.27E-022302003000 55133 VOC 6.57E-03 0.97 1.03 1.03 1.05 6.41E-03 6.76E-03 6.74E-03 6.90E-03SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2302003100 55133 VOC 3.10E-03 0.97 1.03 1.03 1.05 3.02E-03 3.19E-03 3.18E-03 3.25E-032302003200 55133 VOC 1.21E-04 0.97 1.03 1.03 1.05 1.18E-04 1.24E-04 1.24E-04 1.27E-042401001000 55133 VOC 1.57E+00 0.96 1.04 1.08 1.11 1.51E+00 1.64E+00 1.69E+00 1.75E+002401005000 55133 VOC 3.32E-01 0.97 1.03 1.05 1.10 3.22E-01 3.42E-01 3.50E-01 3.67E-012401005000 55133 VOC 1.28E-03 0.97 1.03 1.05 1.10 1.24E-03 1.31E-03 1.35E-03 1.41E-032401008000 55133 VOC 3.58E-03 1.00 1.00 0.83 0.76 3.57E-03 3.60E-03 2.97E-03 2.73E-032401008000 55133 VOC 1.87E-05 1.00 1.00 0.83 0.76 1.87E-05 1.88E-05 1.55E-05 1.43E-052401015000 55133 VOC 3.85E-02 0.96 1.03 1.07 1.12 3.71E-02 3.99E-02 4.11E-02 4.32E-022401015000 55133 VOC 1.48E-04 0.96 1.03 1.07 1.12 1.43E-04 1.53E-04 1.58E-04 1.66E-042401020000 55133 VOC 1.99E-01 0.98 0.98 1.08 1.26 1.94E-01 1.96E-01 2.16E-01 2.52E-012401020000 55133 VOC 7.66E-04 0.98 0.98 1.08 1.26 7.47E-04 7.52E-04 8.31E-04 9.69E-042401025000 55133 VOC 8.65E-02 0.98 0.98 1.08 1.26 8.43E-02 8.48E-02 9.38E-02 1.09E-012401025000 55133 VOC 3.33E-04 0.98 0.98 1.08 1.26 3.24E-04 3.26E-04 3.61E-04 4.20E-042401030000 55133 VOC 7.10E-02 1.04 0.96 0.94 1.01 7.36E-02 6.81E-02 6.68E-02 7.15E-022401030000 55133 VOC 2.73E-04 1.04 0.96 0.94 1.01 2.83E-04 2.62E-04 2.57E-04 2.75E-042401040000 55133 VOC 4.98E-01 0.97 1.01 1.09 1.19 4.84E-01 5.05E-01 5.40E-01 5.93E-012401040000 55133 VOC 1.91E-03 0.97 1.01 1.09 1.19 1.86E-03 1.94E-03 2.08E-03 2.28E-032401045000 55133 VOC 6.37E-01 0.97 1.01 1.09 1.19 6.20E-01 6.47E-01 6.92E-01 7.59E-012401045000 55133 VOC 2.45E-03 0.97 1.01 1.09 1.19 2.39E-03 2.49E-03 2.66E-03 2.92E-032401055000 55133 VOC 3.35E-01 0.86 1.14 1.62 1.94 2.89E-01 3.81E-01 5.42E-01 6.48E-012401055000 55133 VOC 1.29E-03 0.86 1.14 1.62 1.94 1.11E-03 1.47E-03 2.09E-03 2.49E-032401060000 55133 VOC 3.15E-03 0.98 0.99 1.08 1.23 3.09E-03 3.13E-03 3.39E-03 3.87E-032401060000 55133 VOC 1.21E-05 0.98 0.99 1.08 1.23 1.19E-05 1.20E-05 1.31E-05 1.49E-052401065000 55133 VOC 2.07E-02 0.98 0.99 1.08 1.23 2.03E-02 2.06E-02 2.23E-02 2.55E-022401065000 55133 VOC 7.98E-05 0.98 0.99 1.08 1.23 7.81E-05 7.91E-05 8.59E-05 9.79E-052401070000 55133 VOC 1.33E-01 0.95 1.04 1.12 1.24 1.26E-01 1.38E-01 1.49E-01 1.65E-012401070000 55133 VOC 5.11E-04 0.95 1.04 1.12 1.24 4.84E-04 5.30E-04 5.74E-04 6.35E-042401075000 55133 VOC 9.98E-04 0.97 1.00 1.00 1.08 9.72E-04 9.93E-04 9.99E-04 1.08E-032401075000 55133 VOC 3.84E-06 0.97 1.00 1.00 1.08 3.74E-06 3.82E-06 3.84E-06 4.14E-062401085000 55133 VOC 2.22E-03 0.96 1.04 1.12 1.20 2.12E-03 2.31E-03 2.48E-03 2.67E-032401085000 55133 VOC 8.53E-06 0.96 1.04 1.12 1.20 8.16E-06 8.87E-06 9.55E-06 1.03E-052401090000 55133 VOC 2.96E-01 0.97 1.02 1.05 1.13 2.86E-01 3.01E-01 3.09E-01 3.35E-012401090000 55133 VOC 1.14E-03 0.97 1.02 1.05 1.13 1.10E-03 1.16E-03 1.19E-03 1.29E-032401100000 55133 VOC 5.74E-01 0.93 1.07 1.30 1.48 5.33E-01 6.14E-01 7.46E-01 8.49E-01SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2401200000 55133 VOC 3.65E-03 1.00 0.99 1.00 1.07 3.64E-03 3.63E-03 3.65E-03 3.89E-032415000000 55133 VOC 1.60E+00 0.98 1.00 1.04 1.15 1.57E+00 1.59E+00 1.66E+00 1.84E+002415000000 55133 VOC 5.12E-03 0.98 1.00 1.04 1.15 5.04E-03 5.10E-03 5.33E-03 5.89E-032425000000 55133 VOC 3.66E+00 1.02 0.97 0.97 1.04 3.73E+00 3.56E+00 3.56E+00 3.82E+002425000000 55133 VOC 1.17E-02 1.02 0.97 0.97 1.04 1.20E-02 1.14E-02 1.14E-02 1.22E-022460100000 55133 VOC 9.91E-01 0.99 1.01 0.97 1.00 9.78E-01 1.00E+00 9.62E-01 9.86E-012460200000 55133 VOC 9.39E-01 0.99 1.01 0.97 1.00 9.27E-01 9.50E-01 9.11E-01 9.34E-012460400000 55133 VOC 7.09E-01 0.99 1.01 0.97 1.00 7.00E-01 7.18E-01 6.88E-01 7.06E-012460500000 55133 VOC 4.95E-01 0.99 1.01 0.97 1.00 4.89E-01 5.01E-01 4.81E-01 4.93E-012460600000 55133 VOC 2.97E-01 0.99 1.01 0.97 1.00 2.94E-01 3.01E-01 2.88E-01 2.96E-012460800000 55133 VOC 9.28E-01 0.99 1.01 0.97 1.00 9.17E-01 9.40E-01 9.01E-01 9.24E-012460900000 55133 VOC 3.65E-02 0.99 1.01 0.97 1.00 3.60E-02 3.69E-02 3.54E-02 3.63E-022461021000 55133 VOC 3.42E-01 0.95 1.05 1.16 1.25 3.24E-01 3.60E-01 3.97E-01 4.29E-012461022000 55133 VOC 8.26E-02 0.95 1.05 1.16 1.25 7.82E-02 8.70E-02 9.60E-02 1.04E-012461800000 55133 VOC 3.52E-02 0.99 1.01 0.97 1.00 3.48E-02 3.57E-02 3.42E-02 3.51E-022461800000 55133 VOC 1.66E-04 0.99 1.01 0.97 1.00 1.64E-04 1.68E-04 1.61E-04 1.65E-042501011011 55133 VOC 3.10E-010.99 1.01 0.95 0.943.06E-01 3.15E-01 2.94E-01 2.93E-012501011012 55133 VOC 6.06E-010.99 1.01 0.95 0.945.97E-01 6.14E-01 5.75E-01 5.72E-012501011013 55133 VOC 7.77E-020.99 1.01 0.95 0.947.66E-02 7.89E-02 7.38E-02 7.34E-022501011014 55133 VOC 2.32E-020.99 1.01 0.95 0.942.29E-02 2.35E-02 2.20E-02 2.19E-022501011015 55133 VOC 2.13E-030.99 1.01 0.95 0.942.10E-03 2.16E-03 2.02E-03 2.02E-032501012011 55133 VOC 9.91E-030.99 1.01 0.95 0.949.76E-03 1.01E-02 9.40E-03 9.36E-032501012012 55133 VOC 1.93E-020.99 1.01 0.95 0.941.91E-02 1.96E-02 1.83E-02 1.83E-022501012013 55133 VOC 1.06E-010.99 1.01 0.95 0.941.04E-01 1.08E-01 1.01E-01 1.00E-012501012014 55133 VOC 4.47E-020.99 1.01 0.95 0.944.40E-02 4.54E-02 4.24E-02 4.22E-022501012015 55133 VOC 4.10E-030.99 1.01 0.95 0.944.04E-03 4.17E-03 3.89E-03 3.88E-032501050120 55133 VOC 3.23E-01 1.00 1.00 0.83 0.76 3.22E-01 3.24E-01 2.68E-01 2.46E-012501050120 55133 VOC 1.04E-03 1.00 1.00 0.83 0.76 1.03E-03 1.04E-03 8.58E-04 7.89E-042501055120 55133 VOC 1.01E-010.99 1.01 0.95 0.949.99E-02 1.03E-01 9.62E-02 9.58E-022501055120 55133 VOC 3.25E-040.99 1.01 0.95 0.943.20E-04 3.30E-04 3.08E-04 3.07E-042501060050 55133 VOC 5.00E-01 1.00 1.00 0.83 0.76 4.99E-01 5.02E-01 4.14E-01 3.81E-012501060050 55133 VOC 1.60E-03 1.00 1.00 0.83 0.76 1.59E-03 1.60E-03 1.32E-03 1.22E-032501060100 55133 VOC 3.85E-01 1.00 1.00 0.83 0.76 3.84E-01 3.86E-01 3.19E-01 2.93E-012501060100 55133 VOC 1.01E-03 1.00 1.00 0.83 0.76 1.00E-03 1.01E-03 8.34E-04 7.67E-04SCCFIPSPOLLUTANT2008(TPWD)GF-2006GF-2010GF-2020GF-20252006(TPWD)2010(TPWD)2020(TPWD)2025(TPWD)2501060201 55133 VOC 4.30E-02 1.00 1.00 0.83 0.76 4.29E-02 4.32E-02 3.56E-02 3.28E-022501060201 55133 VOC 1.29E-04 1.00 1.00 0.83 0.76 1.28E-04 1.29E-04 1.06E-04 9.79E-052501080050 55133 VOC 1.22E-01 0.93 1.07 1.19 1.28 1.14E-01 1.31E-01 1.45E-01 1.57E-012501080050 55133 VOC 3.92E-04 0.93 1.07 1.19 1.28 3.65E-04 4.19E-04 4.66E-04 5.03E-042501080100 55133 VOC 2.64E-02 0.93 1.07 1.19 1.28 2.46E-02 2.83E-02 3.14E-02 3.39E-022501080100 55133 VOC 7.26E-05 0.93 1.07 1.19 1.28 6.76E-05 7.76E-05 8.63E-05 9.30E-052505030120 55133 VOC 1.58E-02 1.00 1.00 0.83 0.76 1.58E-02 1.59E-02 1.31E-02 1.20E-022505030120 55133 VOC 5.51E-05 1.00 1.00 0.83 0.76 5.50E-05 5.53E-05 4.56E-05 4.20E-052610000100 55133 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000400 55133 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610000500 55133 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002610030000 55133 VOC 0.00E+00 0.99 1.01 0.97 1.00 0.00E+00 0.00E+00 0.00E+00 0.00E+002630010000 55133 VOC 0.00E+00 0.95 1.04 1.19 1.34 0.00E+00 0.00E+00 0.00E+00 0.00E+002630010000 55133 VOC 0.00E+00 0.95 1.04 1.19 1.34 0.00E+00 0.00E+00 0.00E+00 0.00E+002630020000 55133 VOC 1.30E-02 0.98 1.02 1.04 1.08 1.27E-02 1.33E-02 1.35E-02 1.41E-022630020000 55133 VOC 5.01E-05 0.98 1.02 1.04 1.08 4.89E-05 5.12E-05 5.21E-05 5.44E-052640000000 55133 VOC 4.50E-05 0.98 1.02 1.04 1.08 4.39E-05 4.60E-05 4.67E-05 4.88E-052640000000 55133 VOC 1.23E-07 0.98 1.02 1.04 1.08 1.20E-07 1.26E-07 1.28E-07 1.34E-072810030000 55133 VOC 4.90E-03 0.94 1.04 1.01 1.02 4.60E-03 5.08E-03 4.96E-03 5.00E-032810030000 55133 VOC 1.35E-05 0.94 1.04 1.01 1.02 1.26E-05 1.40E-05 1.36E-05 1.37E-05Red font indicates population growth factors.GeoName PopAll2005PopAll2006(est)PopAll2008(est)PopAll2010 PopAll2020 PopAll2025MILW AUKEE 938,497 936,639 932,924 929,208 923,910 912,020RACINE 193,573 194,484 196,307 198,130 207,041 210,772WAUKESHA 377,905 380,764 386,481 392,198 421,489 434,657Population Estimateshttp://www.doa.state.wi.us/docview.asp?locid=9&docid=2107GeoName 2006 2010 2020 2025MILW AUKEE 1.0040 0.9960 0.9903 0.9776 MILWAUKEE 55079RACINE 0.9907 1.0093 1.0547 1.0737 RACINE 55101WAUKESHA 0.9852 1.0148 1.0906 1.1247 WAUKESHA 55133Population Estimated Growth FactorsCOUNTY FIPSYear 2010 2015 2020 2025 2020 20252004 AEO 111.77 119.75 127.92 136.48 - -2008 AEO 103.34 107.26 110.85 114.54 -13.34% -16.08%2009 AEO 99.06 102.08 104.67 108.16 -18.18% -20.75%2010 AEO 96.61 101.61 105.00 108.26 -17.92% -20.68%2011 AEO 97.77 102.02 104.92 107.95 -17.98% -20.90%2012 AEO 98.16 97.66 100.93 102.93 -21.10% -24.58%Conclusions* The EGAS growth factors are based on the 2004 Annual Energy Outlook from the U.S.Department of Energy.* Based on the 2008 - 2012 AEO reports, energy consumption projections for 2020 havedecreased by 13.34 - 21.10%.* Based on the 2008 - 2012 AEO reports, energy consumption projections for 2025 havedecreased by 16.08 - 24.58%.* To reflect these reduced energy consumption projections, the 2020 and 2025 growth factorswere conservatively reduced by 13% and 16%, respectively.Energy Consumption (Quadrillion Btu / Year)http://www.eia.gov/forecasts/aeo/index.cfmPercent Change from 2004 AEO

### APPENDIX 6 Summary of Onroad Emissions for PM2.5 Redesignation SIP Inventory Using U.S. EPA's MOVES2010a Model

2006 FIPS Code N O x ( tons per Jan.

wkdy) PM 2 .5 ( tons per Jan.

wkdy) SO2 ( tons per Jan.

wkdy) VOC ( tons per Jan.

wkdy) January Weekday

VMT Vehicle Population Milwaukee Co. 55079 53.93 2.74 0.88 26.68 18,013,879 551,282 Racine Co. 55101 10.48 0.49 0.16 5.62 3,968,227 123,581 Waukesha Co. 55133 28.69 1.39 0.45 15.26 10,705,254 330,439

2010 FIPS Code N O x ( tons per Jan.

wkdy) PM 2 .5 ( tons per Jan.

wkdy) SO2 ( tons per Jan.

wkdy) VOC ( tons per Jan.

wkdy) January Weekday

VMT Vehicle Population Milwaukee Co. 55079 34.73 1.86 0.25 19.17 17,052,240 527,225 Racine Co. 55101 7.96 0.40 0.06 4.63 4,258,146 133,003 Waukesha Co. 55133 23.02 1.19 0.16 13.44 12,234,608 379,442

2020 FIPS Code N O x ( tons per Jan.

wkdy) PM 2 .5 ( tons per Jan.

wkdy) SO2 ( tons per Jan.

wkdy) VOC ( tons per Jan.

wkdy) January Weekday

VMT Vehicle Population Milwaukee Co. 55079 18.60 1.32 0.22 8.72 21,490,660 650,395 Racine Co. 55101 3.91 0.28 0.05 2.01 5,170,693 159,714 Waukesha Co. 55133 10.11 0.73 0.12 5.16 13,127,292 401,771

2025 FIPS Code N O x ( tons per Jan.

wkdy) PM 2 .5 ( tons per Jan.

wkdy) SO2 ( tons per Jan.

wkdy) VOC ( tons per Jan.

wkdy) January Weekday

VMT Vehicle Population Milwaukee Co. 55079 16.32 1.22 0.21 6.63 22,698,923 678,923 Racine Co. 55101 3.45 0.26 0.05 1.52 5,461,397 166,850 Waukesha Co. 55133 8.92 0.68 0.12 3.83 13,865,343 419,575

NOTES: • The emission values include a "safety margin" of 7.5% for the years 2020 and 2025.

• VOC emissions do not include those from vehicle refueling. Those emissions are accounted for in the area source inventory.

• MOVES input files can be obtained by contacting Mr. Christopher Bovee (Christopher.Bovee@wisconsin.gov or 608-266-5542)

February 24, 2012

### APPENDIX 7: 2020 AND 2025 POINT SO URCE EMISSIONS CALCULATIONS

PROJECTED POINT EMISSIONS NOx (TPWD) PM25 (TPWD) SO2 (TPWD) VOC (TPWD) COUNTY FIPS ID 2020 (est) 2025 (est) 2020 (est) 2025 (est) 2020 (est) 2025 (est) 2015 (est) 2022 (est)

Milwaukee 55079 21.23 17.08 0.23 0.30 27.00 9.52 5.79 6.57 Racine 55101 1.16 1.15 0.05 0.08 0.68 0.78 1.30 1.34 Waukesha 55133 1.55 1.74 0.04 0.06 0.16 0.15 3.22 3.49

County 2018 EGU NOx 2018 NonEGU NOx 2018 Point NOx 2020(est) 2025(est) 2020 est (mod) 2025 est (mod) Milwaukee 14.97 4.56 19.53 17.93 13.93 21.23 17.08 Racine N/A 1.17 1.17 1.16 1.15 1.16 1.15 Waukesha N/A 1.47 1.47 1.55 1.74 1.55 1.74 Notes: 2018 Non-EGU estimates based on LADCO Base C, Version 7 modeling. EGU 2018 estimates based on LADCO Base M 5B modeling (includes NOx RACT). Excludes We Energies - Elm Road (FID 241219440). 2020 and 2025 estimates are modified to include projected emissions from We Energies - Elm Road (FID 241219440) - as well as EGU PM2.5 emissions - which were not included in the 2018 LADCO projections.

Point Source NOx total 2010: Milwaukee 25.93 Racine 1.19 Waukesha 1.17

County 2018 EGU PM25 2018 NonEGU PM2.5 2018 Point PM2.5 2020(est) 2025(est) 2020 est (mod) 2025 est (mod) Milwaukee 0.00 0.12 0.12 0.15 0.23 0.23 0.30 Racine N/A 0.04 0.04 0.05 0.08 0.05 0.08 Waukesha N/A 0.03 0.03 0.04 0.06 0.04 0.06 Notes: 2018 Non-EGU estimates based on LADCO Base C, Version 7 modeling. EGU 2018 estimates based on LADCO Base M 5B modeling (includes NOx RACT). Excludes We Energies - Elm Road (FID 241219440). 2020 and 2025 estimates are modified to include projected emissions from We Energies - Elm Road (FID 241219440) - as well as EGU PM2.5 emissions - which were not included in the 2018 LADCO projections.

Point Source PM2.5 total 2010: Milwaukee 0.00 Racine 0.00 Waukesha 0.00 Calculations for 2020 and 2025 Inventories (NOx)

Calculations for 2020 and 2025 Inventories (PM25)County 2018 EGU SO2 2018 NonEGU SO2 2018 Point SO2 2020(est) 2025(est) 2020 est (mod) 2025 est (mod) Milwaukee 32.40 0.55 32.94 25.97 8.53 27.00 9.52 Racine N/A 0.63 0.63 0.68 0.78 0.68 0.78 Waukesha N/A 0.16 0.16 0.16 0.15 0.16 0.15 Notes: 2018 Non-EGU estimates based on LADCO Base C, Version 7 modeling. EGU 2018 estimates based on LADCO Base M 5B modeling (includes NOx RACT). Excludes We Energies - Elm Road (FID 241219440). 2020 and 2025 estimates are modified to include pr ojected emissions from We Energies - Elm Road (FID 241219440) which were not included in the 2018 LADCO projections.

Point Source SO2 total 2010: Milwaukee 60.84 Racine 0.46 Waukesha 0.16

County 2018 EGU VOC 2018 NonEGU VOC 2018 Point VOC 2020(est) 2025(est) 2020 est (mod) 2025 est (mod) Milwaukee 0.44 5.04 5.48 5.79 6.57 5.79 6.57 Racine N/A 1.28 1.28 1.30 1.34 1.30 1.34 Waukesha N/A 3.11 3.11 3.22 3.49 3.22 3.49 Notes: 2018 Non-EGU estimates based on LADCO Base C, Version 7 modeling. EGU 2018 estimates based on LADCO Base M 5B modeling (includes NOx RACT). Excludes We Energies - Elm Road (FID 241219440). 2020 and 2025 estimates are modified to include pr ojected emissions from We Energies - Elm Road (FID 241219440) which were not included in the 2018 LADCO projections.

Point Source VOC total 2010: Milwaukee 4.23 Racine 1.22 Waukesha 2.67 Calculations for 2020 and 2025 Inventories (VOC) Calculations for 2020 and 2025 Inventories (SO2)2020 and 2025 Point Source EGU Emissions – ModificationsaFIDCOUNTYDVIDSCCPOLLUTANT2008(TPWD)2011(TPWD)GF-2020GF-2025GF-2020(mod)GF-2025(mod)2020(TPWD)2025(TPWD)241219440 Milwaukee 1 1-01-002-22 NOX --- 1.639 1.091 1.08 0.949 0.907 1.556 1.487241219440 Milwaukee 2 1-01-002-22 NOX --- 1.839 1.091 1.08 0.949 0.907 1.746 1.668241007690 Milwaukee B25 1-01-002-22 PM25 0.007 --- 1.091 1.08 0.949 0.907 0.006 0.006241007690 Milwaukee B26 1-01-002-22 PM25 0.008 --- 1.091 1.08 0.949 0.907 0.008 0.007241007690 Milwaukee B27 1-01-002-26 PM25 0.005 --- 1.091 1.08 0.949 0.907 0.005 0.004241007690 Milwaukee B28 1-01-002-26 PM25 0.012 --- 1.091 1.08 0.949 0.907 0.012 0.011241007800 Milwaukee B21 1-01-002-02 PM25 0.005 --- 1.091 1.08 0.949 0.907 0.005 0.005241007800 Milwaukee B22 1-01-002-02 PM25 0.004 --- 1.091 1.08 0.949 0.907 0.004 0.004241007800 Milwaukee B23 1-01-002-02 PM25 0.002 --- 1.091 1.08 0.949 0.907 0.002 0.002241007800 Milwaukee B24 1-01-002-02 PM25 0.004 --- 1.091 1.08 0.949 0.907 0.004 0.004241027050 Milwaukee B22 1-01-002-04 PM25 0 --- 1.091 1.08 0.949 0.907 0 0241027050 Milwaukee B23 1-01-002-04 PM25 0 --- 1.091 1.08 0.949 0.907 0 0241219440 Milwaukee 1 1-01-002-22 PM25 --- 0.017 1.091 1.08 0.949 0.907 0.016 0.015241219440 Milwaukee 2 1-01-002-22 PM25 --- 0.02 1.091 1.08 0.949 0.907 0.019 0.018241219440 Milwaukee 1 1-01-002-22 SO2 --- 0.563 1.091 1.08 0.949 0.907 0.534 0.51241219440 Milwaukee 2 1-01-002-22 SO2 --- 0.523 1.091 1.08 0.949 0.907 0.496 0.474241219440 Milwaukee 1 1-01-002-22 VOC --- 0 1.091 1.08 0.949 0.907 0 0241219440 Milwaukee 2 1-01-002-22 VOC --- 0 1.091 1.08 0.949 0.907 0 0

### Appendix 8 Annual 98th Percentile FRM PM 2.5 

### Concentrations and 24-Hour PM 2.5 

### Design Values

Site Name: 16th St. Health Ctr SER HQ College Ave / FAA Cleveland St. County: Milwaukee Milwaukee Milwaukee Waukesha Site ID #: 550790010 550790026 550790058/59 551330027 2008 98th%-ile Conc.: 27.3 27.5 26.9 29.9 2009 98th%-ile Conc.: 39.1 39.0 33.0 32.0 2010 98th%-ile Conc.: 30.9 31.9 35.3 35.9 2011 98th%-ile Conc.: 27.0 25.7 25.4 25.3

2008–2010 Design Value 32 33 32 33 2009–2011 Design Value 32 32 29 31