SDS: 0058331 Date Prepared: 01/27/2015 

## SAFETY DATA SHEET

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## 1. IDENTIFICATION

Product Name: 

### EBECRYL® 5849 radiation curing resin Synonyms: previously IRR 849 Product Description: Acrylated oligomer Molecular Weight: Not available Intended/Recommended Use: Coatings & Inks Allnex USA Inc., 9005 Westside Parkway, Alpharetta, Georgia 30009, USA For Product and all Non-Emergency Information callyour local Allnex contact point or contact us at http://www.allnex.com/contact EMERGENCY PHONE (24 hours/day) - For emergency only involving spill, leak, fire, exposure or accident call: Asia Pacific: Australia: +61 2801 44558 ( Carechem 24) China (PRC): +86(0)532-8388-9090 (NRCC) Japan: +81 345 789 341 (Carechem 24) New Zealand: +64 9929 1483 (Carechem 24) All Others: +65 3158 1074 (Carechem 24) Europe/Africa/Middle East (Carechem 24): Europe, Middle East, Africa, Israel: +44 (0) 1235 239 670 Middle East, Africa (Arabic speaking countries): +44 (0) 1235 239 671 Latin America (Carechem 24): Brazil: +55 113 711 9144 Mexico and all others: +52-555-004-8763 Canada and USA (Carechem 24 - Allnex29003-NCEC): +1-866-928-0789 (toll free) or +1-215-207-0061 ® indicates trademark registered in the U.S. Outside the U.S., mark may be registered, pending or a trademark. Mark is or may be used under license.



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## 2. HAZARDS IDENTIFICATION

GHS Classification Serious Eye Damage / Eye Irritation Hazard Category 2A Skin Corrosion / Irritation Hazard Category 2 LABEL ELEMENTS

Signal Word WarningEBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 2 of 10

Hazard Statements Causes skin irritation Causes serious eye irritation Precautionary Statements Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. Specific treatment (see supplemental first aid instructions on this label). If skin irritation occurs: Get medical advice/attention. Take off all contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Hazards Not Otherwise Classified (HNOC), Other Hazards Polymerization may occur from excessive heat, contamination or exposure to direct sunlight. This is a research and development (R&D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous. It may only be used for R&D purposes under the supervision of technically qualified individuals. Accumulation of fine dust may entail the risk of a dust explosion in the presence of air. By excessive exposure to dust, eye and respiratory tract irritation is possible.

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## 3. COMPOSITION/INFORMATION ON INGREDIENTS

HAZARDOUS INGREDIENTS Component / CAS No. % GHS Classification Carcinogen 4-Methoxyphenol 150-76-5 < 0.5 Acute Tox. 4 (H302) Skin Irrit. 3 (H316) Eye Irrit. 2A (H319) Skin Sens. 1B (H317) -

Acrylated oligomer

- 97.5 Skin Irrit. 2 (H315) Eye Irrit. 2A (H319) -

The specific chemical identity and/or exact percentage of composition for one or more ingredients has been withheld as a trade secret. Additional GHS classification or other information may be included in this section but has not been adopted by OSHA. See Section 16 for full text of H phrases.



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## 4. FIRST AID MEASURES

DESCRIPTION OF FIRST AID MEASURES Eye Contact: Rinse immediately with plenty of water for at least 15 minutes. Obtain medical advice if there are persistent symptoms. Rinse immediately with plenty of water for at least 15 minutes. Skin Contact: Remove contaminated clothing and shoes without delay. Wash immediately with plenty of water. Do not reuse contaminated clothing without laundering. Get medical attention if pain or irritation persists after washing or if signs and symptoms of overexposure appear. Wash immediately with plenty of water and soap.EBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 3 of 10 Ingestion: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED None known INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDS Not applicable



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## 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use water spray, alcohol foam, carbon dioxide or dry chemical to extinguish fires. Water stream may be ineffective. Use water spray or fog, carbon dioxide or dry chemical. Protective Equipment: Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing. See MSDS Section 8 (Exposure Controls/Personal Protection). Special Hazards: Keep containers cool by spraying with water if exposed to fire. Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition.



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## 6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Where exposure level is not known, wear approved, positive pressure, self-contained respirator. Where exposure level is known, wear approved respirator suitable for level of exposure. In addition to the protective clothing/equipment in Section 8 (Exposure Controls/Personal Protection), wear impermeable boots. Refer to Section 8 (Exposure Controls/Personal Protection) for appropriate personal protective equipment. Methods For Cleaning Up: Remove sources of ignition. Cover spills with some inert absorbent material; sweep up and place in a waste disposal container. Flush spill area with water. Sweep up into containers for disposal. Flush spill area with water. References to other sections: See Sections 8 and 13 for additional information.



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## 7. HANDLING AND STORAGE

HANDLING Precautions: Wash hands thoroughly after handling. Wear protective gloves and eye/face protection.EBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 4 of 10 Special Handling Statements: Contact with this material may not be apparent until 24-48 hours after the exposure. Therefore, good personal hygiene, such as washing immediately with soap and water after handling is highly recommended. This is a research and development (R&D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous. It may only be used for R&D purposes under the supervision of technically qualified individuals. Maintain good housekeeping to control dust accumulations. Provide good ventilation of working area (local exhaust ventilation if necessary). During processing and handling of the product, comply with the indicative occupational exposure limit values. STORAGE Containers which are opened must be carefully resealed and kept upright to prevent leakage. Prevent unauthorised access. Storage in stainless steel, amber glass, amber polyethylene or baked phenolic lined container. Keep containers tightly closed. Keep away from heat. Store in a cool, dry, well ventilated place and keep container tightly closed. Keep away from sources of ignition - refrain from smoking. Take precautionary measures against electrostatic loading - earthing necessary during loading operations. Storage Temperature: Store at <= 25 - 40 °C 39.2 - 104 °F Reason: Quality.



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## 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: Utilize a closed system process where feasible. Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure. Engineering controls are not usually necessary if good hygiene practices are followed. Respiratory Protection: For operations where inhalation exposure can occur use an approved respirator. Recommendations are listed below. Other protective respiratory equipment may be used based on user's own risk assessment. Recommended respirators include those certified by NIOSH (U.S.) or CEN (EU). For operations where inhalation exposure can occur, use an approved respirator recommended by an industrial hygienist after an evaluation of the operation. Where inhalation exposure cannot occur, no respiratory protection is required. Recommended respirators include those certified by NIOSH. Recommended: Full Face Mask with organic vapor cartridge, Type A filter (BP >65°C) Eye Protection: Prevent eye and skin contact. Provide eye wash fountain and safety shower in close proximity to points of potential exposure. Wear eye/face protection such as chemical splash proof goggles or face shield. Skin Protection: Prevent contamination of skin or clothing when removing protective equipment. Wear impermeable gloves and impervious protective clothing. Avoid skin contact. Wear impermeable gloves. Hand Protection: Wear protective gloves. Recommendations are listed below. Other protective materials may be used based on user's own risk assessment. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Replace gloves immediately when torn or any change in appearance (dimension, color, flexibility etc.) is noticed. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Wear impermeable gloves. Gloves for short term exposure: Laminated multilayer gloves, break through time: > 60 min Nitrile rubber (NBR), thickness: > 0.56 mm, break through time: < 60 min The chemical resistance depends on the type of product and amount of product on the glove. Therefore gloves need to be changed when in contact with chemicals.EBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 5 of 10 Not suitable gloves: Latex gloves Due to many conditions (e.g. temperature, abrasion) the practical usage of a chemical protective glove in practice may be much shorter than the permeation time determined through testing. Additional Advice: Food, beverages, and tobacco products should not be carried, stored, or consumed where this material is in use. Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water.



### _____________________________________________________________________________ Exposure Limit(s)
OSHA (PEL): Not established ACGIH (TLV): Not established Other Value: Not established 150-76-5 4-Methoxyphenol OSHA (PEL): Not established ACGIH (TLV): 5 mg/m3(TWA) Other Value: Not established



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## 9. PHYSICAL AND CHEMICAL PROPERTIES

Color: colorless to yellow white opaque Appearance: liquid resin flakes Odor: ester-like odorless Boiling Point: > 100 °C 212 °F Melting Point: Not available Vapor Pressure: 1.33 hPa @ 20 °C Specific Gravity/Density: 1.0 - 1.2 g/cm3 Vapor Density: Not available Percent Volatile (% by wt.): < 0.1 - 0.3 - pH: Not applicable Saturation In Air (% By Vol.): Evaporation Rate: Not applicable Solubility In Water: negligible Volatile Organic Content: Not available Flash Point: > 100 °C 212 °F Cleveland Open Cup Flammable Limits (% By Vol): Not available Autoignition Temperature: Not available Decomposition Temperature: Not available Partition coefficient (n-octanol/water): Not available Odor Threshold: Not available Viscosity (Kinematic): Not available



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## 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Avoid direct exposure to sunlight. Avoid temperatures above 60°C (140°F). Avoid friction with temperature increase as result. Avoid exposure to strong UV sources. Loss of dissolved air. Loss of polymerization inhibitor. Avoid direct contact with heat sources. No hazardous reactions when stored and handled according to prescribed instructions. Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.EBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 6 of 10
Polymerization: May occur Will not occur Conditions To Avoid: Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers Avoid contact with bases or amines. Avoid contact with strong oxidizing agents. Avoid contact with free radical initiators. None known Materials To Avoid: Avoid free radical producing initiators. Avoid contact with peroxides. Avoid contact with reactive metals. Avoid contact with strong alkalis. They give an exothermic reaction with the product. Unintentional contact with them should be avoided. Avoid contact with active metals. None known Hazardous Decomposition Products: Hazardous polymerization can occur when exposed to direct sunlight. Hazardous exothermic polymerization can occur when heated. oxides of carbon smoke hydrocarbons soot Carbon dioxide Carbon monoxide (CO) Irritant gases/vapours.



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## 11. TOXICOLOGICAL INFORMATION
PRODUCT TOXICITY INFORMATION Likely Routes of Exposure: Skin, Eyes, Oral, Respiratory System. ACUTE TOXICITY DATA

LOCAL EFFECTS ON SKIN AND EYE

ALLERGIC SENSITIZATION

GENOTOXICITY Assays for Gene Mutations

SPECIFIC TARGET ORGAN TOXICITY Specific target organ toxicity (single exposure): No data Specific target organ toxicity (repeated exposure): No data OTHER INFORMATION This is a research and development (R&D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous. It may only be used for R&D purposes under the supervision of technically qualified individuals. The product toxicity information above has been estimated. oral (gavage) rat Acute LD50

. 550 mg/kg Actual dermal rabbit Acute LD50

. > 2000 mg/kg No data inhalation rat Acute LC50 4 hr

. > 5 mg/l No data (Dust/Mist)
Acute Irritation dermal Irritating Acute Irritation eye Irritating

Sensitization skin No data Sensitization respiratory No data

Ames Salmonella Assay No dataEBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 7 of 10

HAZARDOUS INGREDIENT TOXICITY DATA 4-Methoxyphenol has an oral LD50 of 740 mg/Kg (rat), and intraperitoneal (ip) LD50 of 430 mg/Kg (rabbit). Suspect skin sensitizer (guinea pig). Depending on quantity and duration of exposure, 4-Methoxyphenol is a moderate to severe eye, skin, and respiratory tract irritant. Ingestion causes gastrointestinal irritation with nausea and vomiting. Overexposure (ingestion/inhalation) can cause methemoglobinemia with cyanosis, as well as central nervous system (CNS) depression, with symptoms ranging from headache, and confusion, to coma, and respiratory failure. 4-Methoxyphenol may be absorbed through skin, causing symptoms similar to ingestion/inhalation exposure routes. The toxicological properties of acrylated oligomer have not been fully investigated. Direct contact may cause moderate eye and skin irritation. Prolonged or repeated contact may cause allergic skin reaction in individuals previously sensitized to acrylates. California Proposition 65 Warning (applicable in California only) - This product contains (a) chemical(s) known to the State of California to cause birth defects or other reproductive harm.



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## 12. ECOLOGICAL INFORMATION
TOXICITY, PERSISTENCE AND DEGRADABILITY, BIOACCUMULATIVE POTENTIAL, MOBILITY IN SOIL, OTHER ADVERSE EFFECTS This is a research and development (R&D) sample. The ecological properties of this material have not been fully investigated. Avoid release to the environment. This material is not classified as dangerous for the environment. The ecological assessment for this material is based on an evaluation of its components.

RESULTS OF PBT AND vPvB ASSESSMENT This product does not meet the criteria for PBT (Persistent, Bioaccumulative and Toxic substance) or for vPvB (Very Persistent and Very Bioaccumulative).

HAZARDOUS INGREDIENT TOXICITY DATA Component / CAS No. Toxicity to Algae Toxicity to Fish Toxicity to Water Flea 4-Methoxyphenol 150-76-5 Not available LC50 = 28.5 mg/L - Oncorhynchus mykiss (96h) LC50 = 84.3 mg/L - Pimephales promelas (96h) Not available

Acrylated oligomer

- Not available Not available Not available



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## 13. DISPOSAL CONSIDERATIONSEBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 8 of 10 The information on RCRA waste classification and disposal methodology provided below applies only to the product, as supplied. If the material has been altered or contaminated, or it has exceeded its recommended shelf life, the guidance may be inapplicable. Hazardous waste classification under federal regulations (40 CFR Part 261 et seq) is dependent upon whether a material is a RCRA "listed hazardous waste" or has any of the four RCRA "hazardous waste characteristics." Refer to 40 CFR Part 261.33 to determine if a given material to be disposed of is a RCRA "listed hazardous waste"; information contained in Section 15 of this MSDS is not intended to indicate if the product is a "listed hazardous waste." RCRA Hazardous Waste Characteristics: There are four characteristics defined in 40 CFR Section 261.21-61.24: Ignitability, Corrosivity, Reactivity, and Toxicity. To determine Ignitability, see Section 9 of this MSDS (flash point). For Corrosivity, see Sections 9 and 14 (pH and DOT corrosivity). For Reactivity, see Section 10 (incompatible materials). For Toxicity, see Section 3 (composition). Federal regulations are subject to change. State and local requirements, which may differ from or be more stringent than the federal regulations, may also apply to the classification of the material if it is to be disposed. The Company encourages the recycle, recovery and reuse of materials, where permitted, as an alternate to disposal as a waste. The Company recommends that organic materials classified as RCRA hazardous wastes be disposed of by thermal treatment or incineration at EPA approved facilities. The Company has provided the foregoing for information only; the person generating the waste is responsible for determining the waste classification and disposal method.



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## 14. TRANSPORT INFORMATION This section provides basic shipping classification information. Refer to appropriate transportation regulations for specific requirements. US DOT Dangerous Goods? Not applicable/Not regulated

TRANSPORT CANADA Dangerous Goods? Not applicable/Not regulated
ICAO / IATA Dangerous Goods? Not applicable/Not regulated
IMO Dangerous Goods? Not applicable/Not regulated



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## 15. REGULATORY INFORMATION Inventory Information This is a research and development (R&D) sample. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous, and it must be used under the supervision of technically qualified individuals. The chemical inventory status has not been determined and may contain components NOT included on the pertinent national chemical inventories. Materials not included on the pertinent national chemical inventories may only be used for research and development (R&D) purposes or in other exempt activities. Exemptions for R&D uses or other activities vary for each country. These requirements are specifically defined and may include notification and/or record keeping.EBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 9 of 10 United States (USA): One or more components of this product are NOT included on the U.S. Toxic Substances Control Act (TSCA) Inventory. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous, and it must be used under the supervision of technically qualified individuals. Materials not included on the TSCA Inventory may only be used for research and development (R&D) purposes or in other TSCA exempt activities. Canada: One or more components of this product are NOT included on the Canadian Domestic Substances List (DSL). China: One or more components of this product are NOT included on the Chinese (IECSC) inventory. Japan: One or more components of this product are NOT included on the Japanese (ENCS and/or ISHL) inventories. Korea: One or more components of this product are NOT included on the Korean (ECL) inventory. Philippines: One or more components of this product are NOT included on the Philippine (PICCS) inventory. Taiwan: One or more components of this product are NOT included in the Taiwan chemical substance inventory (TCSI). All components of this product are included in the Taiwan chemical substance inventory or are not required to be listed on the Taiwan chemical substance inventory (TCSI).

OTHER ENVIRONMENTAL INFORMATION The following components of this product may be subject to reporting requirements pursuant to Section 313 of CERCLA (40 CFR 372), Section 12(b) of TSCA, or may be subject to release reporting requirements (40 CFR 307, 40 CFR 311, etc.) See Section 13 for information on waste classification and waste disposal of this product. Component / CAS No. % TPQ (lbs) RQ(lbs) S313 TSCA 12B <50 None No PRODUCT HAZARD CLASSIFICATION UNDER SECTION 311 OF SARA	




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## 16. OTHER INFORMATION NFPA Hazard Rating (National Fire Protection Association) Health: 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. Fire: 1 - Materials that must be preheated before ignition can occur. Instability: 1 - Materials that in themselves are normally stable, but that can become unstable at elevated temperatures and pressures. Reasons For Issue: New Product Date Prepared: 01/27/2015 Date of last significant revision: 01/27/2015 4-Methoxyphenol H302 - Harmful if swallowed. H316 - Causes mild skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. Acrylated oligomer H315 - Causes skin irritation. H319 - Causes serious eye irritation.



### _____________________________________________________________________________EBECRYL® 5849 radiation curing resin SDS: 0058331 Date Prepared: 01/27/2015 Page 10 of 10 Prepared By: Product Stewardship & Regulatory Affairs Department, http://www.allnex.com/contact



### _____________________________________________________________________________ This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation, and verification. Before using any product, read its label.



### _____________________________________________________________________________ Trade/Substance ID: 056742-02 Material Type: Product Business Group: Coating Resins Department: Coating Resins - Radcure (Specialties) Status: Active