## April 17, 2013
Carey Willoughby Monitoring and Analysis Division Source Test Engineering South Coast Air Quality Management District 21865 Copley Drive Diamond Bar, CA 91765-4182 Subject; Initial Source Test Report for Unit 5 CPV Sentinel, LLC (CEC Docket No. 07-AFC-3) SCAQMD Title V (A/N 472137, Facility ID No. 152707)

Dear Mr. Willoughby: 

# sierra research 1801 

### J Street Sacramento CA 95811 Tel: (916) 444-6666 Fax: (916) 444-8373 Ann Arbor MI Tel: (734) 761-6666 Fax: (734) 761-6755



## On behalf of CPV Sentinel, LLC, I am submitting the enclosed initial source test report for Unit 5 at the CPV Sentinel Energy Project. Testing was conducted in accordance with Condition of Certification AQ-7 and Section H, Condition D29.3 ofthe facility's Title V Permit. Please note that one ofthe natural gas fuel samples taken as part ofthis test (included in Appendix B.2) had a sampling container leakage problem. Therefore, we are in the process of collecting additional natural gas fuel samples and will report the results in a separate submittal to the SCAQMD. Should you have any questions or require additional information related to this submittal, please contact me at (916) 444-6666. Sincerely,

# ~~---------------- Tom Andrews Senior Engineer Enclosure

cc: Roy Olivares, SCAQMD Craig Hoffinan, California Energy Commission EPA Region 9 

## (r9.aeo@epa.gov) Charles Aldred, EPA Region 9 Mark McDaniels, CPV Sentinel, LLC

# SOURCE TEST REPORT FOR INITIAL COMPLIANCE TESTING AT CPV SENTINEL ENERGY PROJECT UNIT 5
PREPARED FOR: GEMMA POWER SYSTEMS CALIFORNIA, INC. 

## 2461 MAIN STREET GLASTONBURY, CONNECTICUT 06033 FOR SUBMITTAL TO: SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 

## 21865 COPLEY DRIVE DIAMOND BAR, CALIFORNIA 91765-4178 PREPARED BY: DELTA AIR QUALITY SERVICES, INC. 

## 1845 N. CASE ST
. ORANGE, CALIFORNIA 92865 714-279-6777 ALI ALESHAIKER 

# I ROBERT 

# A. FINKEN APRIL 15 , 2013 REPORT NUMBER : R5210729 

# 8el/a !1
Air Quality Services, Incorporated

## CONFIDENTIALITY STATEMENT

This information contained in this communication is intended exclusively for the individual or entity to which it is addressed
. This communication may contain information that is proprietary, privileged or confidential or otherwise legally exempt from disclosure. If you are not the named addressee, you are not authorized to read, print, retain, copy, or disseminate this message or any part of it.

R521 0729 

### ii

## REPORT 

## REV I EW AND CERTIFICATION

I certify that all work performed in the preparation and production of this report was performed by me or under my supervision and that all data presented is authentic.

_______ G .A.< kv"'-'

# """""~**"'-.**==-___ Date: Ali Aleshaiker Project Engineer

I certify that I have also reviewed this report , both in form and content , and that all data , calculations , and presentations are authentic , accurate , and complete.

R5210729 

## Robert 

## A. Finken President

iii

## CONTENTS SECTION 1
. 0 INTRODUCTION AND SUMMARY
............. . . ........... . ....... ... ... . ........ .. . .. . ... .. ..... . ......... 1 2.0 UNIT DESCRIPTION AND TEST CONDITIONS
.. ... ..... . .. . ..... . .. ............. ... .. .. . .. .. . ...... 3 2
. 1 UNIT DESCRIPTION
.............................................. . .. .... .... ... ........ . .. .. .... .... .. ... . 3 2
. 2 TEST CONDITIONS
. ... ........ .. . ...... .. . .................. .. .... . ..... . ........ ... ......... .... .......... 5 2
. 3 SAMPLE LOCATION
........... . .... .. ....... . .. ... ..... .. .. .... . .. . .. ..... . ... ...... .. . .. .. .... .. ..... . .. . . 6 3.0 TEST DESCRIPTION
.. .. ............. . . .... ..... . .. ......... . . ... ......................... . ........................ 9 3
. 1 O 2 , 

## CO 2 , 

## NOx AND CO
........................................................................ . .......... 10 3 .2 NH3 BY SCAQMD METHOD 207.1
... ... .. . .... .. .. ........ .. .... . ........ ... .. . . .. .... . .......... 11 3.3 SOx BY SCAQMD METHOD 307.91
........ . ......................... . ...... .. .. .. . ... .......... . 11 3.4 ROG BY MODIFIED SCAQMD METHOD 25.3
. . .. . .. . .. . ..... .. ....... . .. . ... . ........ . . ... 11 3.5 PM BY SCAQMD METHOD 5
. 1
.......................... . .. ... ...... . .... . ............. .. . . ........ 14 4.0 RESULTS
........................................................... . ................................................... 16 5
. 0 DISCUSSION AND TEST CRITIQUE
.. . . .. . ..... . .. . . .. . . .................... . .......... . .... . ........... 24 APPENDICES A QUALITY ASSURANCE
. .. . ... . ... .. . ... ..... .. . . .. ........... . . . ....... .. .......... . .......... . ............... A-1 A.1 Quality Assurance Program Summary
..........................................................A-2 A.2 SCAQMD and CARB Certificat i ons ....... . .. .. .. . . .. .... .... . . ..... ... . .. .. .. ..... .. .. .... ..... .. A- 7 A.3 Equipment Calibration and Calibration Gas Certificates
. ...... . ........................ A-8 A.4 Delta CEM System Description and SCAQMD Method 100.1 Calibration and Test Sequence
.. .. . .... .......... .. ........................ . ............... .. .... .. A-9 B PROCESS DATA
................................................................................................... B-1 B.1 Process and CEMS Data
....... . ...... . .. . .. . . .. . .. .. . .. ....... . ....... .. .. . ... .. ........ .. .. ....... .. . B-2 B
. 1.1 Sentinel Unit 5 Stratification Test
..... .. . . . ...... ......... ...... ...... .. ........... . ... . . B- 3 B.1
. 2 Sentinel Unit 5 Ammonia, ROG , and 

## NOx/CO Testing
. .. . .... . . . ... . . . ... . .. . B-4 B
. 1.3 Sentinel Unit 5 PM Testing
.............. .. .... .. . ..... ...... .. ...... .. .. . .. . ..... . . ......... B-5 B.2 Fuel Analysis Data
........... . .. .... .. . ..... ......... ....... ........... .. ............ .. ..... ... . .. : .. .. ... B-6 C TEST DATA
..... . ............................... . ..... . ..... . .. . ........ . .. .... ........ . .. . .......... . ..... . ......... C-1 C.1 Stratification and Preliminary Flow Rate Tests
........... .... ... .. ..... .. .. . ............... C-2 C.2 CEM Data
.......................................................................... . .......... . ............... C-3 C
. 2
. 1 CEM Quality Assurance Measurements
... . .. . .. . ... . ..... . .... . ..... . ..... . .. ...... C-4 C .2. 2 NOx and CO Compliance
.. .... . . ..... . ........ . ........... ... ......... ... .. .. .... ..... . . .. . C-5 C
. 2.3 One Minute Data Logger Data
....................................... . .. . .. .. .... . .... .... C-6 C.3 Ammonia Data by SCAQMD Method 207
. 1
.................................................. C - 7 C.4 SO x by SCAQMD Method 307.91
........ ...... ........ .. ... . .......... .. ......................... C-8 C.5 ROG by Modified SCAQMD Method 25
. 3
......... . . . ... . ........... . ..... . ........ .. . .. . .. . . . C-9 C
. 6 PM by SCAQMD Method 5.1
...... .. . . . . ............ ..... ..... ..... ............. ........... . .. . .. . C - 10

R5210729 iv

## D GENERAL EMISSIONS CALCULATIONS
. .. . .. . .. . ... .. ... .... . ... .... ... .. .. . .. . . ... . .. . .. .. . . .. . .. 

## D-1 E CHAIN OF CUSTODY
.. .... . . . ... . . .. . .... . . .. . . . .. . .. . ..... . .. ... . ........ . . . ... ..... .... .. .......... .... . . .... E-1 

## F INSTRUMENT STRIP CHARTS
........... . .......... . .. . .... . .......... . ...... . ... . .. . . . ... . . . ...... . . . ... F-1 G FACILITY PERMIT TO OPERATE CONDITION D29.1
. ............. . .. .. . .. .... .. . .. .. . .. .... . 

## G-1 H CORRESPONDENCE AND TEST PLAN
.... . ..... . ... . .... .. ... .. ... .. ........ .. ... .. . ... .. .. . . . ... . . 

## H-1

R521 0729 

## v

# 1.0 INTRODUCTION AND SUMMARY Delta Air Quality Services , Inc
. has been contracted by Gemma Power Systems California, I nc. (GEMMA) to perform the i n itial Permit to Operate Compliance Testing at the CPV Sentinel Energy Project Units 1, 2, 3, 4, 5 , 6, 7, and 8
. Condition D29
. 1 of the Permit to Operate requires source tests with i n 180 days of initial startup
. This document is the test report for the initial compliance for CPV Sentinel Unit 5. Tests were performed at three load conditions to determine oxides of nitrogen (NO x ), carbon mono x ide (CO), oxides of sulfur (SO x ) , reactive organic gases (ROG), part i culate matter (PM), and ammonia (NH 3 ) emissions
. Bob Finken was the Senior Program Manager for Delta and can be reached at (714) 279-6777. No conflict of interest, as defined in SCAQMD Rule 304, exists between Gemma or CPV Sent i nel Energy Project and Delta
. Testing was conducted on February 25-28, 2013. The Delta test crew cons i sted of Ali Aleshaiker, Ray Madrigal , Mike Chowsanitphon, and Just i n Miller
. Table 1-1 contains a summary of the test results and applicable limits. Th i s table also compares the results at three load conditions, 50%, 75%, and 100%, that were tested. All test results showed the unit to meet the permit limits
. Section 2
. 0 of th i s document provides a description of the facility and sample locations
. A description of the sampling strategy and test methods i s provided in Section 3.0
. Section 4.0 contains detailed test results. Sect i on 5 contains a discussion and test cr itique
. The appendices contain all test and laboratory data , calculations , and qual ity assurance data
.

R5210729

### Parameter Units ppm@ 15%0, NO, ppm @ 15% 0, Ib/MMscl CO ppm @ 15% 0, NH3 ppm@ 15% 0, gr/dscl @ 3% 0, Particulate gr/dscl @ 12% CO, Ib/hr PM 1O

### /PM'
.5 Ib/MMscl SO,l3) Ib/MMBtu gr H,S/1 00 scI ROGs ppm @ 15% 0, 

## TABLE 1-1 CPV SENTINEL ENERGY PROJECT UNIT 5 STACK TEST RESULTS SUMMARY 100% 75% 50% 1.68 1
. 54 1
. 97 1.68 1.54 1
. 97 706 6.29 7
. 96 2
. 93 2.74 0.42 3.75 1.91 0.67 0.0007 0
. 0007 0.0013 0.0008 0
. 0009 0.0015

0.85 0.84 1.02 0.97 1.19 1.90 000002(5 )

0.006(5) ND<0.51 ND<0.51 ND<0.59 (1) The 12.26 Ib/MMscf is a RECLAIM emission factor, not a limit. (2) This is stated in the permit as an emission factor. (3) SO, results calculated based on 100% load condition
. Limit 2.5 15 12.26(1) 4 5 0.01 0.1 11 5.71(' ) 0.06 0.25(4)

2.0
(4) 0
. 25 gr H , S/100 scf sulfur content limit is based on annual average of monthly sample results
. Rule 1703(a)(2) 40 CFR 60 2012 1703(a)(2) 1303(a)(1) 475 409 475

40 CFR 60 SCAQMD Permit Condition B61.1 1303(a)(1)

(5) Results from one sample. One of the duplicate samples obtained a leak and was compromised. An addendum to this report will be submitted with results from two new duplicate samples when the information becomes available.



### R521 0729 

### 2

## 2.0 UNIT DESCRIPTION AND TEST CONDITIONS
2.1 UNIT DESCRIPTION CPV Sentinel Energy Project is located at 15775 Melissa Lane, North Palm Springs, California 92240. The facility consists of eight (8) identical generating units. The CPV Sentinel Energy Project consists of eight (8) LMS100PA combustion turbines in simple cycle operation
. The units are natural gas fired with a rated heat input of 891.7 MMBtu per hour at 

## 72 degrees Fahrenheit. Each LMS100PA employs water injection and is equipped with a CO catalyst and Selective Catalytic Reduction (SCR) system for NO , control. The LMS100PA is a General Electric (GE) combustion turbine with an intercooler located between the low pressure compressor (LPC) and high pressure compressor (HPC)
. Off engine combustion air to closed loop water intercooling is used for increased gas turbine thermal efficiency. Heat removed from the off-engine intercooler is circulated through a closed loop cooling system
. Heat is rejected from the closed loop cooling system to an open loop cooling system via a shell and tube heat exchanger. The open loop system rejects heat via a mechanical draft counterflow cooling tower. The cooling tower is provided with drift elimination to comply with air emissions limits
. Figure 2-1 presents a block diagram of the units. Figure 2-2 shows a general arrangement of the major components.

R5210729 3

## FIGURE 2 · 1 SIMPLIFIED PROCESS BLOCK DIAGRAM CPV SENTINEL ENERGY PROJECT COMBUSTION TURBINES

Simplified Process Flow Diagram


### Air Water

Air 

## Cooling Tower

Closed Loop Cooling

LMS100PA

Water Natural Gas Fuel Demineralized

R521 0729 

### Air Water Heat

Exhaust to Atm.

Exhaust 

## CO Catalyst SCR 

# -

Ammonia 19% Aqueous



## 4

## FIGURE 2-2 GENERAL ARRANGEMENT OF MAJOR COMPONENTS

2.2 TEST CONDITIONS**r~AM5Tll'-"" T'\'~~** **~'**

# !~,~~t~**_** 

# !

, ,r ' , , , , , , 

# ,

v

Q • ' . 14 II



## The 

## permit requires that the tests will be performed at three operating conditions ; 1) maximum, 2) average, and 3) minimum load. Full load is nominally 100 megawatts and minimum load is approximately 50 megawatts
. Since these will be the initial tests for the units and no long term average will have been established, average conditions w i ll be approximated at 75% of capacity or approximately 75 megawatts.

R521 0729 5

## Unit operating data was collected during the tests by the facility from the CEMS DAS
. Table 2-1 below presents the average operating condition for each parameter. TABLE 2-1 AVERAGE OPERATING CONDITIONS 

## Parameter 50% Load 75% Load 100% Load Fuel Flow Rate, hscfh 5,392 7,063 8,747 Turbine Generating Output (MW) 

## 55.1 80.0 105.9 Ammonia Flow, Ib/hr 103.3 130.7 193.8 Exhaust Temperature, of 

## 776 733 736 Exhaust Flow Rates, kscfh 14,994 19,243 22,377 Notes: Data from facility DAS except exhaust gas temperature where PM test data was used
. Data collected during PM test intervals at each condition.



## Process data obtained during testing is contained in Appendix B. 

# 2.3 SAMPLE LOCATION 

## There are four 4" test ports located at 90 degrees apart around the circumference of the 13'6" diameter stacks
. The ports are located 323" downstream (2.0 diameters) of the nearest flow disturbance (duct breeching) 84" upstream (0.5 diameters) of the nearest flow disturbance (silencers). The sampling location meets the minimum requirements of SCAQMD Method 2
. 1; at least 2 diameters downstream and at least 0.5 diameters upstream of the nearest flow disturbances. Figure 2-3 presents the details of the sample location.

R521 0729 6

## FIGURE 2-3 SAMPLE LOCATION DETAILS

Inside Diameter, in.



### - 162

-- Stack Exit 1080 .0 in. Silencer Bottom 925 .9 in. 

# I

Ports 841.6 in. Platform 789 .6 in. 84 Distance A, inches, 0.5 Diameters 

# ! Sam pie ports 

# T
323 Distance B, inch es. 2.0 Diameters

Base of Stack 518.5 in . 

# 1

__ ..::E::;

xh,:::aust Flow Grade 0.0 in . Elevation View 

### 90 11.



### 66 ft.



## o 11.



## Prior to performing the tests, gaseous stratification was investigated with a 12 point traverse as described in 40 CFR 75, and the presence of cyclon i c flow was checked using the techniques described in SCAQMD Method 2
. The results of the yaw angle and stratification checks indicate that the angle criteria was met. The average angle was 0
. 8 0 

## which meets the SCAQMD criteria of 10 degrees or less. The stratification criteria was not met. Results of the stratif i cation checks are presented in Table 2- 2. 12-point traverses were used for ammonia, NO x, 

## and CO compliance tests.

R521 0729 

## 7

## TABLE 2-2 12-POINT STRATIFICATION CHECK RESULTS GEMMA POWER SYSTEMS CPV SENTINEL UNIT 5 02 CO2 Port Point % % West 3 13.24 4.54 West 2 13.24 4.54 West 1 13.25 4.54 South 3 13.25 4
. 54 South 2 13
. 64 4.31 South 1 13.62 4.32 East 3 13.55 4.40 East 2 13
. 53 4.41 East 1 13.50 4.43 North 3 13.53 4.42 North 2 13.53 4.43 North 1 13.49 4.45 Average 13.4 4.4 

### Maximum 13.6 4
. 5 

### Minimum 13.2 4.3 Maximum Difference from Average 0.2 0.1 Max Difference (% of average) 1.5% 3.0% Criteria:

If 

### < 10%, use single point. Action Taken :

12-point traverse used for RATA runs Runs in conjunction with NH3 test, use 12-point traverse NO , CO ppm ppm 2
. 23 2.18 2.24 3.08 2.24 2.40 1.93 3.35 1.98 3
. 94 1
. 66 3.54 1.92 3.80 1.89 4.03 1.79 4.22 1.93 4
.69 1
.90 4.17 1
. 78 3.69 2
. 0 3
. 6 2
. 2 4.7 1
. 7 2.2 0
. 3 1.4 15.4% 39.3%



## Table 2-3 illustrates the location of sample traverse pOints for each type of test. TABLE 2-3 SAMPLE POINT LAYOUT PM (24 pis
. ) Cydonic Flow Check (16 pis.) Strat.lNH 3, NO " and CO Compliance (12 Pts
. ) Sample 

### % of in. % 

### of in . %of 

### in.

Point Diameter 

### from Wall Diameter from Wall Diameter from Wall 

### 2.1 3
.4 3.2 5.2 4.4 7.1 2 6.7 10.9 10.5 17
.0 14.6 23
.7 3 11
. 6 19
. 1 19
.4 31.4 29
.6 46
.0 4 17
.7 26
.7 32
.3 52.3 70
.4 114
.0 5 25 40
.5 67.7 109.7 85
.4 136.3 6 35
.6 57.7 80.6 130
.6 7 64.4 104
. 3 89
.5 145
. 0 6 75 121
. 5 9 62
. 3 133
. 3 10 86.4 140
. 0 11 93.3 151
. 1 12 97.9 156.6



### R521 0729 

## 8

# 3.0 TEST DESCRIPTION Table 

## 3-1 summarizes the test methods and techniques that were used as the reference methods
. The test matrix has been developed to meet the requirements of Section 

## 29.1 of the facility Permit (App l ication Number 

## 472137) dated April 

## 15, 2011. The test matrix indicates the number of runs that were performed for each parameter and each condition
. The permitted emission limits are summarized in Table 

## 3-2 . The following sections describe each method in further detail. Flue gas oxygen and carbon dioxide concentration were measured in conjunction with all tests using SCAQMD Method 

## 100 . 1. The flue gas flow rate was measured in conjunction with each ammonia and particulate test. This measured flue gas flow rate was used for all emission rate calculations of NO" CO, NH 3 , 

## ROGs and SO,. 

## TABLE 3-1 TEST MATRIX 

## SENTINEL UNIT 5 Parameter Method 50% Load 75% Load 100% Load Test Duration NO , SCAQMD 100.1 2 runs· 

## 2 

## runs· 2 

## runs· 60 minutes


# ° i C0 2 

## SCAQMD 100.1 With each run

CO SCAQMD 100.1 2 

## runs· 2 

## runs· 2 

## runs· 60 minutes NH3 SCAQMD 207.1 2 runs 2 runs 2 runs 60 minutes S0 2 SCAQMD 307
.91 Fuel Sample, 2 Samples N/ A PM SCAQMD 5.1 1 run 1 run 1 run 240 minutes ROG Modified SCAQMD 25
. 3 1 pair 1 pair 1 pair - 60 minutes!' ) 1) 

## ROG tests were nominally 60 minutes. Flow controllers will be setup for 60 minutes. The test was performed until the canister vacuum reaches approximately 10 "Hg
. Actual test time may be less than or more than 60 minutes per sample
. • Additional runs performed compared to test plan
.



## R5210729 9

## TABLE 3-2 CPV SENTINEL ENERGY PROJECT PERMITTED EMISSION LIMITS Parameter Units ppm@ 15 % 0 2 NO, ppm @ 15% O 2 Ib/MMscf 

# co ppm@ 15 % O 2 NH 3 ppm@15 % 0 2 gr

/dscf @ 3% O 2 Particulate gr / dscf @ 12% CO 2 Ib/hr PM , 01 PM 25 Ib/ MMscf SO , Ib/ MMBtu gr 

## H 2 

## S

/ 100 scf ROGs ppm @ 15% O 2 (1) The 12.261b/MMscf is a RECLAIM emission fa cto r , not a limit. (2) This is stated in the penmit as an emission factor
. Limit 2
. 5 15 12.26 (1) 4 5 0
. 01 0.1 11 5 .7 1 (2) 0
. 06 0
. 25 (3)

2
. 0 Rule 1703(a)(2) 40 CFR 60 2012 1703(a)(2) 1303(a)(1 ) 475 409 475

40 CFR 60 SCAQMD Permit Condition B61.1 1303(a)(1 ) (3) 0.25 gr H2S/ 100 scf sulfur content limit is based on annual a verage of monthly sample results
.


## 3.1 O 2 • 

## CO 2 • 

## NO 

## x AN D CO 

## O 2 , 

## CO 2 , 

## NO , and CO concentrations were measured using SCAQMD Method 100.1. These measurements were made with one of Delta ' s mobile emission measurement laboratories
. The system consists of a stainless steel or glass probe, heated Teflon line, moisture removal system, sample pump, sample filter, unheated Teflon line, and individual component analyzers. The measured concentrations are averaged over each sampling period, then corrected for system bias and analyzer drift
. All quality assurance procedures required by SCAQMD Method 100.1 were performed including pre- and post-test Calibration Error, Sample System Bias and Analyzer Drift. The sampling was performed us i ng a 12-point traverse at each test condition
. For some test runs, the compliance test was performed concurrently with the Relative Accuracy Test Audit (RATA). In this case, data from the RATA was used to demonstrate compliance with the NO , and CO emission limits.

R521 0729 10

## NOx 

## concentrations were measured on a 0-5 ppm range. CO concentrations were measured on a 0-10 ppm range . CO 2 

## concentrations were measured on a 0-10% range. O 2 

## concentrations were measured on a 0-20% range. The measured concentrations are averaged over each sampling period, then corrected for system bias and analyzer drift
. The drift and bias corrected result were then used to calculate emissions in units required by the permit including ppm, ppm corrected to 15% O 2 , 

## pounds per hour, and pounds per million standard cubic feet of natural gas. 3.2 NH3 BY SCAQMD METHOD 207.1 Duplicate flue gas samples were collected non-isokinetically at each test condition using SCAQMD Method 207
. 1. A 12-point traverse was performed during each NH3 slip test. The sample gas is drawn through a glass probe , Teflon sample line, two impingers each containing approximately 100 ml of 0
. 1 N H 2 

## S0 4 , 

## an empty impinger, an impinger containing silica gel , and a dry gas meter. The optional nozzle and filter were not used since the units are natural gas fired. The contents of the probe, sample line and the first three impingers are recovered and analyzed by SCAQMD Method 207.1 for ammonia concentration using the Ion Selective Electrode technique
. One reagent blank sample, one DI water sample, and one field blank sample was analyzed. Ammonia slip is reported in units of ppm , corrected to 15% O 2 • 

## The tests were performed over a period of at least 60 minutes
. 3.3 SOx BY SCAQMD METHOD 307.91 Oxides of sulfur were measured using SCAQMD Method 307-91
. Two fuel samples were collected in Tedlar bags and sent to Saybolt Laboratory for sulfur analysis as total reduced sulfur as H 2 

## S
. 3.4 ROG BY MODIFIED SCAQMD METHOD 25.3 Sampling and analyses are performed using Modified SCAQMD Method 25.3 procedures. The sample apparatus and analyses are provided by Atmospheric Analysis and Consult i ng (MC) in Ventura California. At each test condition, two (one paired sample, consist of 2 canisters) flue gas samples are extracted simultaneously from four points (one per port) in the stack through pre-cleaned (high temperature conditioned) stainless steel probes connected to an outof-stack flow controller , into stainless steel Summa polished canisters. The flow controller is set to fill the evacuated canister to a pressure of -400 mm Hg over a period of a period of one hour.

R5210729 11

## Modifications to the Method 25.3 sampling procedures suggested or accepted by SCAQMD are : • Elimination of the in-stack filter • Elimination of the water vial portion of the 25.3 equipment • The final pressure in the Summa Canisters is maintained at between 

## 400 and 

## 500 mm HG 

## (10 -14 in
. Hg) absolute. Figure 3-1 presents a schematic drawing of the sample apparatus
.

R521 0729 

## FIGURE 

## 3

- 1 MODIFIED SCAQMD METHOD 25.3 SAMPLING APPARATUS

Filter Probe

Flow Controlier

12 

### Vacuum Gauge

## The samples are analyzed for NMNEOC (Non-Methane Non-Ethane Organic Compounds, i.e
. Reactive Organic Compounds ROG) using modifi ed SCAQMD Method 25
. 3 TCA procedures
. Analysis consists of a fore-flush and back-flush of a gas chromatography (GC) column , followed by an oxidizer , a methanizer, and a flame ionization detector (FlO). The GC separates the NMNEOC from other constituents of the samp l e (methane, ethane, CO 2 , 

## H 2 

## 0, O 2 , 

## N 2 , 

## etc
. )
. The ox i dizer converts the NMNEOC to carbon dioxide
. The methanizer converts the resulting CO 2 

## to methane. The methane content is detected by the FlO as ppm cart>on
. Modifications suggested by SCAQMD to the Method 25
. 3 analytical procedures approved for MC under the lAP are : • Pressurization of the canisters to 900 mm Hg w ith Ultra High Purity (UHP) helium analyzed/certified to contain less than 0
. 05 ppmv of tota l hydrocarbons as carbon • Analyzing only the Summa canister fraction of the no r mal 25.3 sample
. No water vial used in sampling, no water vial analysis. • Utilization of a larger (-2 ml) sampling loop • Development of a custom l ow level (0.1 - 5.0 ppmV propane) calibrat i on curve • Performance of a Minimum Detection Limit (MOL) study • Determination of a Practical Quantitation Limit (PQl) from the MOL study Results are reported in parts per million by volume 

## as carbon to 2 sign ificant digits , corrected to 15% O 2 

## using the O 2 

## from the CEM measurements
. The average 

## of the results for the duplicate samples i s compared to the Emission Standard for determination of the compliance status. Detailed procedures from SCAQMD concerning the application of the modified SCAQMD Method 25.3 to permit condition 029.1 are located in the test plan in Appendix 

# H

.

R5210729 

## 13

## 3.5 PM BY SCAQMD METHOD 5.1 Particulate matter was measured using SCAQMD Method 5.1
. SCAQMD Method 5
. 1 is cited as the table in Condition D29
. 1 lists District Method 5
. District Method 5.1 measures total particulate. This total particulate measurement could include material >10 microns
. Use of the cyclone as in 201A prevents overstat i ng of PM lO 

## emissions if all of the PM emissions from these units are not PM lO . 

## It was assumed for reporting purposes that the SCAQMD Method 5
. 1 total PM results will be used to determine PM ,o compliance
. A s i ngle test was performed at each of the three conditions; 100% , 75 % , and 50% load conditions. Flue gas is drawn through a stainless steel nozzle, glass or stainless steel probe , unheated Teflon line followed by four impingers. Impingers #1 and #2 contain approximately 100 ml of deionized water, impinger #3 is empty, and impinger 

# #4 contains silica gel. A backup filter is placed between impingers #3 and 

# #4 . The sample was collected isokinetically (90 - 110% ) using a 24-po i nt traverse at the exhaust stack location
. Each point was sampled for 10 minutes resulting in a 240 minute sample time per test. Figure 3 - 3 presents a diagram of the sampling system
.

R521 07 2 9 

## 14Tempe ratu re Sensor P robe

# ~

Pilot Tube

Nozzle


# / S-Type Pitot Tube



## R5210729 FIGURE 

## 3-3 SCAQMD METHOD 

## 5.1 SAMPLE SYSTEM

Manometer


## Orifice Connecting TubIng



### Temperature



## Dry Gas

Meter



## 15 Temperature Sensor

Gel 

### Vacuum 

### Gauge 

### line

## 4.0 RESULTS The test results are presented in the following tables : Table 4-1 Table 4-2 Table 4-3 Table 4-4 Table 4-5 Table 4 - 6 Table 4-7 NO x, 

## CO, Ammonia (NH 3 ) , 

## and 

## RaG -100% load PM 

## results - 

## 100% load NO x, 

## CO , NH 3 , 

## and 

## RaG - 75% load PM 

## results - 75% load NO x , 

## CO , NH 3 , 

## and 

## RaG - 50% load PM 

## results - 50% load 

# saxresults Additional test runs were performed for some parameters to ensure that sufficient data were collected
. Table 3-1 contains a test matrix with this information
. Additional data is presented in the Appendices, including all field data , laboratory data, and calculations
.

R521 0729 

## 16

### TABLE 4-1 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 5 NO., CO, NH 3 , AND ROG 100% LOAD FEBRUARY 25, 2013 Test Number Run 1 Run 2 Average Limit Condition 106 MW 106 MW Test Date 2/25/2013 2/25/2013 Start Time 11 : 35 13 :04 Stop Time 12:43 14 : 17 Fuel F low, hscfh 8 , 746 8 , 742 Stack Flow Rate, dscfm 416 , 170 393 , 969 Stack 

## 0 , (%) 13.54 13
. 50 13
. 52 Stack NO, (ppm) 

## @ 15% 

## 0, 1.70 1.65 1.68 2.5 Stack NO, (lb/MMscf) 7.36 6.77 7.06 12
. 26 1 ') 

### Stack CO (ppm) 

## @ 15% 

## 0, 2.98 2.87 2.93 4 Moisture Fract io n 0
. 098 0
. 099 PPM NH 3 (f lue gas ) 4
. 59 4
. 78 4
. 69 PPM NH 3 

## @ 15% 

## 0, 3.68 3.81 3
. 75 5 Ib/hr NH3 5
. 14 5.06 5
. 10 Ib/MMscf fuel NH3 5
. 87 5.79 5.83 Stack ROG ( 1 ), 

### ppm 

## @ 15% 

## 0, NO<0.51 NO<0.51 2.0 1 ) 

### Collected as a simultaneous pair
. 2) 

### The 12.26 

### Ib/MMscf is a RECLAIM emission factor, not a limit.

R5210729 17

## TABLE 4-2 COMPLIANCE TEST RESU LTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 5

Test Number Condition Test Date Start Time Stop Time Fuel F l ow , hscfh Stack Flow Rate , dscfm Stack O 2 , 

### % Stack CO 2 , 

### % Moisture Fract i on

Grain Load i ng , gr/dscf 

### Grain Loading 

## @ 3% O 2 

### Grain Load i ng 

## @ 15% O 2 

### Grain Loading 

## @ 12% CO 2 

### Mass Emissions, Ib/hr Emission Rate, Ib/MMscf 

## PM - 100% LOAD FEBRUARY 25,2013

S-5/STK-PM-100-1 106 MW 

### 2/25/2013 10:56 15:20 8 , 747 356 , 867

134 7 4
. 34 0.090 Particulate Emissions 0
. 0003 

## 0.0007 0
. 0002 

## 0 .0008

0.85 0.97 (1) 11 Ib/hr PM limit from SCAQMD Rule 475. (2) Th i s is stated i n the permit as an emiss i on factor
.



### R5210729 18 Average

0.0003 

## 0.0007 0
. 0002 

## 0.0008

0.85 0.97 Limit



## 0.01

0.1 5.71(2 1



# !!.f!t !!!d

### TABLE 4-3 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 5 NO" CO, NH 3 , AND ROG 75% LOAD FEBRUARY 25,2013 Test Number Run 1 Run 2 Average Limit Condition 81 MW 80MW Test Date 2/25/2013 2/25/2013 Start Time 16:42 18 : 07 Stop Time 17:48 19 : 14 Fuel Flow, hscfh 7,078 7 , 085 Stack Flow Rate , dscfm 349,945 332 , 898 Stack 

## 0, ('!o) 13.98 14
. 04 14
. 01 Stack NO. (ppm) 

## @ 15% 

## 0, 1.33 1.75 1.54 2.5 Stack NO. (lb/MMscf) 5.63 6.94 6.29 12.26 1 ') 

### Stack CO (ppm) 

## @ 15% 

## 0, 1.95 3.54 2.74 4 Moisture Fraction 0.082 0.095 PPM NH3 (flue gas) 2.60 1
. 86 2
. 23 PPM NH 3 

## @ 15% 

## 0, 2.21 1.60 1.91 5 Ib/hr NH3 2:44 1.66 2
. 05 Ib/MMscf fuel NH3 3:45 2.35 2
. 90 Stack ROG I1 ), 

### ppm 

## @ 15% 

## 0, NO<0.51 NO<0.51 2.0 1) Collected as a simultaneous pair. 2) The 12.26 Ib/MMscf is a RECLAIM emission factor, not a limit.

R5210729 19

### TABLE 4-4 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 5

PM -75% LOAD FEBRUARY 25,2013 Test Number S-5/STK-PM-75-1 Average Limit Condition 80MW Test Date 2/25/2013 Start Time 16:42 Stop Time 20 : 54 Fuel Flow, hscfh 7,063 Stack Flow Rate, dscfm 349,451 Stack 

## 0" % 14.01 Stack CO" % 3
. 91 Moisture Fraction 0.090 Particulate Emissions Grain Loading , gr/dscf 0.0003 0
. 0003 Grain Loading 

## @ 

## 3% 0, 0
. 0007 0.0007 0.01 Grain Loading 

## @ 15% 

## 0, 0
. 0002 0
. 0002 Grain Loading 

## @ 12% 

## CO, 0.0009 0.0009 0.1 Mass Emissions, Ib/hr 0.84 0.84 11(11 Emission Rate, Ib/MMscf 1,19 1 , 19 5.71('1 (1) 11 

### Ib/hr PM limit from SCAQMD Rule 475. (2) 

### This is stated in the permit as an emission factor.

R521 0729 20 

# Rff/B.A,

## TABLE 4-5 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 5 NO" CO, NH 3 , AND ROG 50% LOAD FEBRUARY 26, 2013 Test Number Run 1 Run 2 Average Limit Condition 55MW 55MW Test Date 

## 2 / 26/ 2013 2 / 26 / 2013 Start Time 8 : 30 10 : 00 Stop Time 9 : 37 11 : 09 Fuel F low , hscfh 5 , 384 5,400 Stack F low Rate , dscfm 259 , 659 261 , 782 Sta c k 

## 0 , ('!o) 

## 14
. 15 14
. 13 14
. 14 Stack NO, (ppm) 

## @ 15% 

## 0, 1.83 2.12 1.97 2.5 Stack NO, (lb/MMscf) 7.34 8.58 7.96 12.26 1 ') 

## Stack CO (ppm) 

## @ 15% 

## 0, 0.41 0.43 0.42 4 Moisture Fract ion 0
. 091 0
. 092 PPM NH 3 (flue gas ) 0
.73 0
. 81 0.77 PPM NH, 

## @ 15% 

## 0, 0.64 0.71 0
. 67 5 Ib/ hr NH 3 0
.51 0
. 57 0
. 54 Ib/MMscf fue l NH3 0
. 94 1
. 06 1
. 00 Stack ROG(1), ppm 

## @ 15% 

## 0, ND<0.59 ND<0.59 2.0 1 ) Collected as a simultaneous pair. 

## 2) The 12
. 26 

## Ib/ MMscf is a RE CLAIM emis sion fa c tor , not 

## a limit.

R5210729 21

## TABLE 4-6 

## COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 5



## PM - 50% 

## LOAD FEBRUARY 26, 2013 Test Number S-5/STK-PM-50-1 Average Limit Condition 55MW Test Date 

### 2/26/2013 Start Time 8:30 Stop Time 12:40 Fuel Flow, hscfh 5,392 Stack Flow Rate , dscfm 242,273 Stack 

## 0" % 14.10 Stack CO" % 3.85 Moisture Fraction 0
. 089 Particulate Emissions Grain Loading , gr/dscf 0
. 0005 0.0005 Grain Loading 

## @ 3% 

## 0, 0.0013 0.0013 0.01 Grain Loading 

## @ 15% 

## 0, 0.0004 0.0004 Grain Loading 

## @ 12% 

## CO, 0.0015 0.0015 0.1 Mass Emissions, Ib/hr 1.02 1.02 11111 Emission Rate, Ib/MMscf 1.90 1.90 5.71 1 '1 (1) 11 Ib/hr PM limit from SCAQMD Rule 475. (2) 

### This is stated in the permit as an emission factor

R5210729 22

### R5210729 Test Number Condition Test Date 

## SOx
. Ib/MMBtu gr 

## H,S/1 00 scf 

## TABLE 4-7 COMPLIANCE TEST RESULTS CPV SENTINEL ENERGY PROJECT SENTINEL UNIT 5 SOx FROM FUEL ANALYSIS FEBRUARY 28,2013 Average

100% 

## 2/28/2013 000002(' )

0.006(') Limit

0.06 0.25(1) (1) 0
. 25 

## H,S/100 scf sulfur content limit is based on annual average of monthly sample results. 

### (2) Results from one sample. One of the duplicate samples obtained a leak and was compromised. Two additional samples were collected on April? 2013. The samples were not analyzed due to laboratory equipment failure. 

### An addendum to this report will be submitted with results from two new duplicate samples when the information becomes available .



## 23 

# R,f/a f.,.

## 5.0 D I SCUSS I ON AND TEST CRITIQUE Testing was conducted according to the test plan and reference methods. All tests demonstrated compliance with the permit limits. The following should be noted: • Two runs were conducted for NO, and CO at the 100%, 75% and 50% load conditions to ensure that sufficient valid data were collected. • One of the duplicate Fuel Sulfur samples obtained a leak and was compromised. Two additional samples were collected on April 7, 

## 2013
. The samples were not analyzed due to laboratory equipment failure. • An addendum to this report will be submitted with results from two new duplicate samples when the information becomes available.

R521 0729 

## 24

# fJelfl!**~**

## APPENDIX A QUALITY ASSURANCE

R5210729 

## A-1

## Appendix A.1 Quality Assurance Program Summary

R5210729 A-2

## QUALITY ASSURANCE PROGRAM SUMMARY 

## Delta Air Quality Services, Inc. is committed to providing emission related data which is complete, precise, accurate, representative, and comparable. Delta's quality assurance program and procedures are designed to ensure that the data meet or exceed the requirements of each test method for each of these items. The quality assurance program consists of the following items : • Assignment of an Internal QA Officer • Development and use of an internal QA Manual • Personnel training • Equipment maintenance and calibration • Knowledge of current test methods • Chain-of-custody • QA reviews of test programs Assignment of an Internal QA Officer: Delta has assigned an internal QA Officer who is responsible for administering all aspects of the QA program . Internal Quality Assurance Manual: Delta has prepared a QA Manual according to the guidelines issued by EPA. The manual documents and formalizes all of Delta's QA efforts
. The manual is a " living" document which is revised as Delta adds capabilities and procedures. The QA manual provides details on the items provided in this summary. Personnel Training: Personnel training is essential to the production of high quality test results
. Delta's training programs include : • A requirement for all technical personnel to read and understand the test methods performed • A requirement for all technical personnel to read and understand the Delta QA manual • In-house training • Quality Assurance meetings • Attendance at EPA sponsored training courses • Maintenance of training records. Eguipment Maintenance and Calibration: All laboratory and field equipment used as a part of Delta's emission measurement programs is maintained according to manufacturer's recommendations. A summary of the major equipment maintenance schedules is summarized in Table A-1. In addition to routine maintenance, calibrations are performed on all sampling equipment according to the procedures outlined in the applicable test method. The calibration intervals and techniques for major eqUipment components is summarized in Table A-2. Knowledge of Current Test Methods: Delta maintains current copies of EPA, ARB, and SCAQMD Source Test Manuals and Rules and Regulations. Delta personnel coordinate, attend, and present papers at emission testing related conferences. Delta personnel maintain memberships in the Air and Waste Management Association and Source

R5210729 A-3

## Evaluation Society. Delta personnel continually work with industry and regulatory agencies in monitoring and developing new methods and rules. Chain-of-Custody: Delta maintains chain-of-custody documentation on all data sheets and samples. Samples are stored in a locked area accessible only to Delta source test personnel. Data sheets are kept in the custody of the originator, program manager, or in locked storage until return to Delta ' s office
. Upon return to the office, copies are made and stored in a locking file. The original data sheets are used for report preparation and any additions are initialed and dated. QA Reviews: Every Delta report is reviewed by someone separate from the report author. The reviewer is selected based on knowledge of the test methods used and the source tested. Periodic field, laboratory, and report reviews are performed by the QA Officer. Test plans are reviewed to ensure proper test methods are selected and reports are reviewed to ensure that the methods were followed and any deviations from the methods are justified and documented
.

R5210729 

## A-4

### Equipment Pumps

Flow Meters Sampling Instruments

Integrated sampling tanks Mobile van sampling system
Sampl i ng lines

R521 0729 

## TABLE A-1 EQUIPMENT MAINTENANCE SCHEDULE

Acceptance Lim its 1
. Absence of leaks 2
. Ability to draw manufacturers required vacuum and flow 1
. Free mechanical movement 1
. Absence of

malfunction 2
. Proper response to zero, span gas 1
. Absence of leaks 1
. Absence of leaks

1
. Sample

degradation less than 2% Frequency of Service Every 500 hours of operation or 6 months, whichever is less Every 500 hours of operation or 6 months , whichever is less As recommended by manufacturer Depends on nature of use Depends on nature of use

After each test ser i es

A-5 Methods of Service 1. Visual inspection 2
. Clean 3. Replace parts 4
. Leak check 1
. Visual inspection 2
. Clean 3
. Calibrate As recommended by manufacturer

1
. Steam clean 2
. Leak check 1
. Change filters 2. Change gas dryer 3. Leak check 4
. Check for system contamination 1. Blow dry , inert gas

through line unt i l dry.

## TABLEA-2 MAJOR SAMPLING EQUIPMENT CALIBRATION REQUIREMENTS Sampling Equipment Calibration Frequency Calibration Procedure Acceptable Calibration 

### Criteria Continuous Analyzers Before and after each 3-point calibration error < 

### 2% of analyzer range test day test Continuous Analyzers Before and after each 2-point sample system < 

### 5 % of analyzer range test run bias check Continuous Analyzers After each test run 2-point analyzer drift < 

### 3% of analyzer range 

### determination CEMS System Beginning of each day leak check < 

### 1 in
. Hg decrease in 5 min. at> 20 in
. Hg Continuous Analyzers Daily 3-point linearity < 

### 1% 

### of analyzer range NO , Analyzer Daily NO, -> NO converter 

### >90 % efficiency S-type pitot tube Semi-annually Dimensional calibration Meet dimensional criteria of Method 2 S-type pitot tube Annually Wind tunnel calibration Defined in Method 2 S-type pitot tube Prior to each project Visual inspection Meet dimensional criteria of Method 2 Differential Pressure Sem i -annually Correction factor based + /- 5% 

### Gauges (except for on 5-point comparison to manometers) standard Differential Pressure Bi-monthly 3-point comparison to +/- 

### 5% Gauges (except for 

### standard , no correction manometers) factor

Manometer Semi-annually Clean and replace fluid Barometer Semi-annually Adjusted to mercury-in- +/- 

### 0
. 1 inche s Hg glass or National Weather Service Station Dry gas meter Semi-annually Calibration check at 4 +/- 

### 2% flow rates using a NIST

traceable standard Dry gas meter Bi-monthly Calibration check at 2 + /- 

### 2 % 

### of semi-annual flow rates using a NIST factor

traceable standard Dry gas meter orifice Annually 4-point calibration for LlH@ 

### Temperature sensors Semi-annually 3-point calibration vs . +/- 

### 1
. 5 % NIST traceable standard



### R5210729 A-6

## Appendix A.2 SCAQMD and CARB Certifications

R521 0729 

### A-7

# South Coast Air Quality Management District 21865 Copley Drive, Diamond Bar, CA 91765-4178 (909) 396-2000 • www . aqmd
. gov



## Mr. Robert A. Finken Delta Air Quality Services, Inc. 1845 N. Case Street Orange , CA 92865 Subject: LAP Approval Notice Reference # 96LA 1220 Dear 

## Mr . Finken: December 19 , 2012

We completed our review of the renewal application you submitted for approval under the South Coast Air Quality Management District's Laboratory Approval Program (AQMD LAP). We are pleased to inform you that your firm is approved for the period beginning January 31 , 2013 , and ending January 31, 2014 for the following methods, subject to the requirements in the LAP Conditions For Approval Agreement and conditions listed in the attachment to this letter: SCAQMD Methods 1-4 SCAQMD Method 100.1 SCAQMD Methods 25 . 1 and 25.3 (Sampling) SCAQMD Methods 5 . 1 , 5 .2 , 5.3 , and 6.1 SCAQMD Rule 1420

- (Lead) Ambient Sampling USEPA CTM-030 and ASTM 06522-00 Thank you for participating in the SCAQMD LAP . Your cooperation helps us to achieve the goal of the LAP : to maintain high standards of quality in the sampling and analysis of source emissions
. You may direct any questions or information to LAP Coordinator, Glenn Kasai. He may be reached by telephone at (909) 396-2271, by facsimilie at (909) 396-2099, or via e-mail at gkasai @ aqmd.gov.

RE : GKlgk 

## cc: Mike Garibay Glenn Kasai 121218 LapRenewal.doc

# ~ Rody 

# Ed"

# s,~ Laboratory Services & 

## Source Test Engineering

# State of California 

# Air Resources Board Approved Independent Contractor Delta Air Quality**Servic~~** 

# Incorporated

. , 

# This is to certify thCilt the company'listed above has been approved by the Ail Resources Board 

# 'to tonduclyompliance testing pursuant to title 17, California**Coq~** 

# of-Regtnat1ons,**~ection** 

# 91207 until June 30, 2013, for thOse 

# teSt methods listed below: .' , " 

### "

. 

## .ARB S\)Ql'ce 

## Test Methods! 

# h 2, 3;

_ 4,' 5, 6, 

## '8, 17, 20, SOt 100 

## ' (CQ. 

# cOu NO", 

# qz, S02)

Alberto**Aya~,** 

# Ph.D ., M.S.E. Chief, Monitoring and Laboratory Division

# State of Califo rn ia 

# Ai r Resources Board l OeaeAQent Contractor 

# Delta**Aj fflU3JiW** **Set:ri es** **lR@{** 

# T his i s to**("prtiM K'~t**  

# by the pursuant to

# ~l**~~ .::tti.;** **~** until 

# J**f~~V oV** **'''.I'l~ :i>** 

# \b een app roved

# ~~**~ce** testing

. .

# ~t~**,** ection 91207

# Ti**;e~~ 9!** **J** , d below :

v ersion)

Alberto Ayala, 9fl
. D. , M
. S
. E. Chief, Monitoring and Laboratory Division

## Appendix A.3 Equipment Calibration and Calibration Gas Certificates

R5210729 A-8

# Jf1IIPRAXAIR. Praxair D istribution, Inc. 5700 5. Alameda 51.



### Delta A i r Quality 1845 N
. Case St. Orange, CA 92865 

# - Los Angeles , CA 90058 Tel : 323-585-2154 Fax : 714-542-6689 

### 01/23/2013



### Work Order No. 

## 22514330 Customer Reference No. Product LotiBatch No
. 

## N109301805 Product Part No. 

## NI 5.5CE-AS 

# C A**~/?q~/.** CERTIFICATE OF ANALYSIS ;)" '" ., NItrogen, 

# 5.5 Continuous Emission Monitoring Zero Analytical Analytical Analytical Analyte5 Specification Results Principle Accuracy Nitrogen >99.9995 % >99.9995 % N Carbon Dioxide 

## < 1 ppm 

## < 0.20 ppm L 

## ± 10 % Carbon Monoxide < 

### 0.5 ppm < 0.5 ppm L 

## ± 15 % Total Hydrocarbons < 0.1 ppm < 0.1 ppm Q 

## ± 15 % Oxides of Nitrogen <0.1 ppm < 0.01 ppm U 

## ± 15 % 

### Oxygen < 0.5 ppm <0.5 ppm W 

## ± 15 % Sulfur Dioxide 

## < 0.1 ppm < 0.1 ppm Z 

## ± 15 % Water 

## < 2 ppm < 0.2 ppm P 

## ± 0.4 ppm Analytical Instruments : Meeco-Aquavolt -Moisture-Electolytic Hygrometer

Cylinder Style : Cylinder Pressure @70F : Cyl in der Volume: Valve Outlet Connection: Cylinder No(s). Horiba Instruments Inc.-GA · 360E-NDIR-Non-dispersive Infrared Thermo Environmental-42i-Nilric Oxide Analyzer-Chemiluminescence Rosemount Analytical-NGA-2000-THC - Total Hydrocarbon Analyzer-FlO - Flame Ionization Detector AMETEK-921CE-UV S02 Analyzer-Ultraviolet Absorption DeltaF-Nanotrace- Trace Oxygen-Electrochemical AS Filling Method : 2000 pslg Date of Fi ll: 158 ft3 CGA-580 SA21794 Temperature/Pressure 01/18/2013



## '""'."

# H,"~ .",,&06" Approved Signer: Charles

# MiY (/

E G.I CflromalO9l.phW willi f lam, Photometric: Deledor**G~5** CIvomltogtlP.'Iy -..Itn ReduC\ion Gas Afl.ryze, M aIIUS SpearDtfleuy • loiS Of GCMS Q**Tot~ 1** **i'ird ~rbon**  An.lyzlf U cn.rrWluminescenet v PI'Ised Fluoresunet I MPORTANT B OU Chro<nllog
.... phy wilh**Di$dl~ on** **u~on** Delee/or F Gn Chrom",oor.llhy wi t h H. li<.r!llOnltllion Oe1ector Gas Cl\n:ImlllOO""phy willi**~** CondudMly Detector N a, Oilftreoee of**ly~llmll\lliUes** R W10I CIIIUlIiQI V**Gra~lmel rt~**  Z W Sp!cIrometry C G.s ChrolTUllog
.. pIly wilh EJectrotyIie COIIducllvn) ODledor G GIS Cnromltography Willl**M81f11~iler** C,rtIonIler K 8Ir'I1I}'G!I$l\rn!Iyzlrwl\h**TlIIITTUIJC~lIy** OelG'dor o**Parlm."n~** S Oeu,c;tOf T",b8 W**EIoclr~1c;** Clf\lEJectrod'lernical o GIs Cftrom.log'lplly WIth f l ..." IOr'IilPool Del eaD , H GlI$**C~rom'logtaph)** with P ho!l>icniUlion De1e-ctOi l 1 111"'1(1' FTlR 01 NctR P Specllic Wiler MII)'l" T """ X PflOiO l onlt.I IQn
The inform ation contained herein has been prepared at your r e quest by pertomel within Praxa l r Distribution , Inc.. While we believe the information is accurete with in the limits of the analytical methods employed and is complete to Ihe exlent 01 the specific ana lyses performed, we make no warranly or rapresenLation as to Ihe suitability of the U5e of the Information for any particufar purpose The information is olfered with !he underslanding thaI any use of the Information is at the sole discretlon and risk cA the user . In no event shal! liabiffty of Praxair Dislrioot ion, Inc. arising out of the use of the information contained herein**e~ceed** the fee established fO( providing suel1 informallon
. Pg
. 1 

### of 1 

# Z-I'J-IgP

# 'ffff**~PRAXAIR** PrRXair 5700 South A lam eda Street Los Angeles, CA 90058 

### Tel , (323) 585-2154 F,,,(714) 542-6689 DocNumbe" 

### 000037792 PGYPID , F22012 -.-**,~ ~"<':'r-'<"~~r'f':':** **~- ""** **~** L--"- '" > '.
.. )



# - €1! : I!J!!lBll24 TE 

# OFA'H..J1.!lp" J{;S,!'8;ifJiliRR ' p:BXiJlF{f)C(f)1!; 

# OAS Cus/o F/If IAIII: : 4/2012012 

### Delta Air Quality 1845 N
. Case St. Orange, CA 92865 Praxair Order Number: 20034099 Customer P. O. . Vumber : 03852345 

### Customer Reference Number: Pori Numhar: EV NICOOXE78-AS J , mNllmbc:,.,' 109211114 Gyll",l,,/'**Sly/~** & (Jillllf': AS eGA 590 

# 0" /0.00 Cf).", 

# t;. 00 Certified Concentration: 140cu . ft Expiration Date : Cylinder Number:

# CC/~"'5 5.00 % 

### 10.00 ' % Balance

# ~"oS/OI 511/2015 CC181115 CARBON DIOXIDE OXYGEN NITROGEN NIST Traceable Analytical Uncertainty :



### ± 

### 1 

### % 

### ± 1 %

Cerli/ c arion Iltformalio Certification 

### Dare : 5/112012 Term : 

### 36 Months Expirat;on Date : 5 / 1

/ 2015 Th is cylinder was certified according to the 1997 EPA Traceability Protocol , Document #EPA·600JR-97/121, using P roced ure G1 Do Not Use this Standard if Pressure i s less than 150 PS1G PGVP 1.0
.# F22012 AI/Myfical Dala: (R=Reference Standard, Z::.Zero Gas, C=Gas Candida/e)

1 . Component : CARBON DIOXIDE ReQuesled Concentralion 5 % Cer1ifiod Concentration : 5

_ 00 % Instrument Us ed : Analytical Method : Siemens U ltremat 5E SIN A12 ·7 30 NOIR Las l Multipoint Celibrelion 411112012 Date: 

### z, 0 R , 

### '17 C, 

# , Cone : 

### I R, 51' Z , 0 C, 5 Cone:

Z, 0 C, 5 R , 5
. 17 Cone: 

# , 

# .. Mean Test Assay : ; UOM :



### ---- 2. Component : OXYGEN ReQuested Concenlration : Cert ifled Concentrat ion: Instrument Used :**Ana yt~al**  Method : 10% 10.00% OXYMAT 5E PARAMAGNETIC las! MuMipolnt CelibraliaT 411112012**/;;;~1~ ---** **-1** 

# , !

__ : ..__J**(~ Anal;~~~;a** **---** ---- -**~~te** - - ;';7;012

-- . - •• Z 0 R 1542 C 10 Conc 10 R 1542 Z 0 C 10 Cone 10 Z 0 C 10 R 1542 Conc , 10 I UOM : %



# -------- - Analyzed by: Reference Standard Type : Ref. Std
. Cylinder fI : ReI. Std
. Cooc : Ref
. Sid. Treceap i s 10 SRM 1/ ' SRM S<lmplo 1/ : SRM Cy li nder 

# * : GMIS CC263449 5
. 17% VI . 1574P 7 · F· 32 SAL01 4&4 5 

## ,---.------------ -r 

# ISecond Analysis Ollta : t

# ~**'~ .** **~** 

# j Oat .; 0 Cone: 0 Cone: Z: 0 C: 0 R : 0 0 Cone : UOM : % Mean Tesl ASSI_"

_ __ 0**.~** __ Ref9f&nee Standa rd Type : Ref
. Std
. Cylinder t/. : Ret Std
. Cone : GMIS HA 9153 15
. 42 % Ret Std
. Traceable to SRM 1/ : v s. 2559a SRM Sampl e II : 71·37·6 SRM Cylinder II : CLM · 006734 

# I ."Md AMI,,,. 0 ..,

Z: 0 R: 0 Dale: C: 0 Cone:

# ~M~%~·**~** C: 0 Cone: R: 0 Cone : Mean Test Assay : 

## o o o 

## - 1 

# I 

# I Cert ifi ed by :

# Sham~~

Informati on contained herein has been prepared at your reQuest by Qua l if ia d**tI~per1s** within Praxair Olslr i bl.llioo. Inc. While we pelieve that the informalloo Is accurate wilhinlhe li mits of the analyllcal me thod s employed and I s**com~eta** 10 tha exlant of the specific analyses performed, we make flO warranty or representation as to the suitability of the use of the i n format i on fOf any purpose. The Informalion is offered wit h the understanding that any use of the infor mldion i s a\ the sole discretion and risk of the user . In no avent Shall the liability of Praxair Oi stribulion , Inc ., ar i sing oul 01 the use of Ihe Informallon con talned herein exceed Ihe fee establ i shed for provid i ng such In formation
. 

# /1

- 2-

- 

# /2---7CII.<;(O 

# UffffflPRAXAIR

DocNumber : 

### 000038940 Praxair 5700 South Alameda Street Los Angeles, CA 90058 Telephone: (323) 585·2154 facsimile: (7 t 4) 542·6689 

# CERTIFICATE OFANALYSIS / EPA PROTOCOL GAS
/';///)we : 5/22r.<012 

### Delta Air Quality 1845 N. Case St. Orange, CA 92865 Praxair Order Number: 20362117 Cuslomer P. 

### 0. Number 03901124 Customer Reference .VlImber: !',u'/,V"mhcr: NI CD9.503E-AS 1."/ Number: 1092111306 ('ylill<kr Slylu cf**()III/~,:** AS eGA 590 

# OJ, 18.98 

# Co" tf·'-z.,**CC2.~'''''** 

# E'/fos/,ot Certified Concentration: ( 'ylilU.kr 

## "HM!!,. c\I Vo/""''' : 2000 p$ig Expiration Date: Cylinder Number: 

### 9.62 % 

### 18,98 % Balance 5/30/2015 

### CC246737 CARBON D IOXIDE OXYGEN NITROGEN NIST Traceab !e Analytical Uncertainty:

± 

### 1 % ± 1 

### %

Ce rfijcufi() n Illformation: Certification Date: 5/30/2012 Term : 36 Months Expiration Date: 5/30/2015 This cylinder was certified according to the 1997 EPA Traceability Protocol, Document #EPA·600/R·97/121 , using Procedure Do Not Use this Standard if Pressure is less than 150 PSIG 

### PGVP ID .# F22012 Ana(l'licai Data: (R.,Re ference Standard. Z=ZefO Gas. C"Gos Candidate)

1
. Component: CARBON DlOXtDE Requ est ed Concentration ' Certffied Concentration : tn st rument Used
. Analytical Method : last Mu lti point Cal ibr at i on : First Analysis Data: 

### z, 0 R, 10
. 08 R, 1006 Z, 0 Z, 0 C , 9.58 UOM: % 2
. Component : OXYGEN Roquested Concentralion. ConJf lcd Concent ration Instrument Used ' Analylical Method Last Mulllpoil1t Calibration First Analysis Data:

UOM: 

### o 20 

### o % R: 7.0 Z: 0 C: 18 . 98 95% 9
. 62% Siemens Ultramat SE SIN A12-730 NOIR 5/1112012 [lata: C, 9.62 Cone: C, 9.5 Cone: R, 10 ,0 5 Cone: Mean Tost Assay:

19% 18.98% OXYMAT 5E PARAMAGNETIC 5/1112012 5/301201
.. 9.62 9.62 9,61 9 . 62 %

Dale: 5/3012012 C: 18 .98 Cone: C: 18.98 Cone: R: 20 Cone: 18.98 18.98 18.98 MOiln**Te~(AsSiI,** Analyzed by \ \ 

# ROl l Reference Standard Type ' Ref. Std , Cylinder 1# ; Ref. Std. Cone: Ref
. Std
. Traceable to SRM fI SRM Sample" SRM Cylinder It : I .- ..• - I Second Analysis Data: I Z, 0 R 0 C, 

## ! R, 0 Z, 0 C, i 

## z, 0 C, 0 R, 

## , GMIS SA 1 471 10.08% VS. 1675b 6·F · 51 CAI.D14538 Date: 0 Cone: 0 Cone: 0 Cone: 0 0 0 I UOM: % Moan last Assay: 0% 

### L
... _ .. _ . Rmelence Standard Typo' Ref. Std
. Cylinder #I : Ref. Std
. Cone: Ref , Std
. Traceable to SRM #I : SRM Sample # : SRM Cylinder II
. Second Amlty$is Oatil: 

### z, 0 R, 0 R, 0 Z, 0 2, 0 C, 0 GMIS SA12632 20 .00% 2659;j 71·37·8 ClM..Q0673-4



### o o 

### o Dale: Cone: Cone: Cone: 

### o o 

### o UOM : % Melin Tesl Assay: 0 % Certified by : Shameela Jiffrey G1 140cu fl

Intormation ,::ootained herein has been prepared at yOU!" request by qualified experts wflnin Prllxai : DisltibutiOfl, Inc
. 'oNh it e we believe t t Ult ttm Information i9 aecureto witliin the I lITlits of the analyllca l methods emp loyed and i s complete to the cdent of the specific analyses performed , we meke no warrAnty or representation as 10 Ihe suitab ility of tho use o f the informalion for any pu rpose . The in formation IS offered W ith the understanding that any use of the Information i s at the sole discretk'n and risk of the user. In no evant Sha ll the liability of Pra)(sir**OistribUtion,~nc.,** aris i n 01 the use of the informat,on con ta i ned herein exceed the faD established for providing such Information 

# '6 ' '7 (-/1-- 

# I

# 'jf**f:~PRAXAIR**

D oc Number : 

### 000042731

Custor 

### Praxair 5700 Sou th Alameda Street Los Angeles, CA 90058 Tel : (323) 585-2154 Fax (714) 542

- 6689 

### PGVPID: F22012



# - Delta Air Quality Praxair Order Nllmber: 

### 21232031 PiIfDoI, : 1f1.t1i2012 

### 1845 N
. Case St. Customer P. 

### 0. Number; 04033576**p(lriMmllJ~, ;**  NI N02
. 5ME·AS



### range 

## CA 92865:. Cu s tomer Reference Number:

# ~ La/ Numbllr: 109201406

, C )llll/du Sryle**~** 0 111 1,, : AS eGA 660 

# tJ 0**~** 

# 2. 

# S**'r-E-x-p-ira-t-io-n-D-a-te-:-----9-,-11-~-:-:-:.:.:-le-d-C _o_r._.c_e_n_t_r_a_ti_o_n_:** ___

# N_I_S_T_**:_':_·~_~_:_a~_b _I:_** **,, vo** **''' "'** **: 2000p** **~i g**  1040 CU. 

### rt. 

# CC,,' -z. 

# 8**C_YI ~~~** **~ber** ppm

# :~::2::IDE ___

# :I;~~:**1** Uncerta i nty : 

# €'(fo' 

# /11

# fi
Balance 

### NITROGEN
NOx 

### = 2.56 ppm NOx for Reference Only Ce flif cO lioll In/orm a t ion: Certification Date : 9 /1 1/2012 

### Term : 24 Months 

### Ex piration Date : 9/11/2014 Th i s cy l inder was cert ified according 10 the 1997 EPA Traceab ility Protocol , Document #EPA-$OO/R·97/121, us i ng Procedure G1 Do Not Use th is Standard if Pressure is less than 

### 150 PS I G Last certif i ed concen t ration was 2.52 ppm, \ NOxJ=2
. 54 ppm on 

### 2/13/2012
. Allal y ti cal Data: 1 • Component: NITRIC OX IDE Requesled Conce n tration : Cert ified Conce n t rat ion : In strument U seo : Ana lyt ica l Me t hod
. Last Mult i po i n t Calibrat ion : F irSI Analysis Data : 

### z, 0 R , 

### ' .95 R, 9.95 Z, 0 

# i z, 0 

### c, 2,59

UOM: ppm (R:Refer ence Standard. Z=Zero Gas. C=Gas Candida/e) 2 .5 ppm :2 54 ppm Themo EIectrO(1 42C SIN 5 1 81 1 2467**Ch milumin** **e~ ce**  81 11 12012
C; 2,59 Conc : :2 59 R: 9.95 Conc' 259 Mean Te st Assay :2 59 ppm C:

# ~5~**~ ~:~ec:** **~~ --** **l ----:::::::::::.=-==-** **----** Ana l yzed by : 

## ,**-.--** Referenc e Standard Type : Ref. STd. Cylinder # : Raf. Sid
. Cone : Ref. SIC!
. Tri5Ceeble to SRM,, : SRM Sample" : SRM Cyl i nde r 1# • Second AnaIY$ i $ D al a : 

### z , 0 R , 0 Z, 0 R, Z, C , 0 0 0 

### c , C, R

, GMIS

CC335604 995 ppm 26298 SO

-G -1 09 F F 31631



### o 

### o o 0,"" -.-. - 0

- 

# - l

Conc Conc : 0 : Conc : 0 

# J

L.

_ _ -'-

_ _____ M

_'

_

an Test Assay:
__ . _ _**~ _._**  UOM; ppm 

### Certified by :**/**

I n formation conlained here i n has been prepared at your requesl by qua li fied 8lq)ert s w it hin Praxair OJstribulioo, Inc
. While we believe thatille informatio n is accurate wiU'1ln the lim it s of the an alytical methods employ&d and I s complell1 to tM extent of the speCific aNllyses performed, we make no wart'en ly or r8presenta ti O(1 a s to the ',"itability o f t he use of I he In forma tion for any p ur pose. The I nformation is offerfJd w ith the understanding lhatany use o f Ihe information is etlhe so l e d iscretion and risk of the user . I n no event shall the liab i lity of Praxair Distribution
. Inc
.. arising out of the use of the info r ma tion con teined herein exceed the fe e esleblished for prov i d i ng such i nfocmalion
.Praxair 5700 South A lam eda Street Los Angeles, CA 9005 8 OocNumber : 000045093 T el : (323) 585·2154 Fax:(714) 542 · 6689 

### PGVPlD: F22 0 12

Fill DalI: 1 Of5l2012 

### Delta Ai r Qua l ity 1845 N
. Case St. Orange, CA 92865 Praxalr Order Numb er: 21683572 

### Cu

stome r P. 

### 0. Number: 04102891 

### Customer Reference Number: PanNllmlHr : NI N04.5ME-AS 1.01 Numbtr : 1 09227908 Cyllrnhr Stylt &- O ll/I tl: AS CGA 660 

# /Joy. 

# t./.,." Expiration Dale : 

### Certified Concentration: 11/5/2014 

### CC101204 Cylinder Number: 

# C(:./OI.2..D 4
. 52 ppm NITRIC OXIDE NIST T raceable Analytical Uncertainty :

±2 % Balance NITROGEN

# ~yp 

# ',/DS/''f--- No

- x =-4.-S2-pp-m ------N-::-Ox-:-for-Ref-eren-Ce---'OnIY Ce rti/ cation Information: Cerlification Date : 11/5/2012 Te rm: 2 4 Months ExpIration Date : 11/5/2014 2000 ps l g

This cylinder was certified according t o the 1997 EPA Traceab ility Proto co l, Document #EPA ·600/ R·971121 , using Procedure G1 Do Not Use this Sta ndard if Pressure is l ess than 

### 150 PSIG Analytical Data: (R=Reference Standard, Z "ZfJfO Gas. C=GBS Candidate) 1
. Component : NITRIC OXIDE Reference Sten1:le rd Type: GMIS Ref Std
. Cylinder Ii : CC335699 

# R,,' . ;l td. Cone : 9
. 87 ppm Req..ested Concentrtltion : 4 . 5 ppm Certified Concentration : 4
. 52 ppm tl'\slrumttn l UStttl : Themo E l ectron 42C SIN 518112467 Ref
. Sid
. Traceab le to SRM II ; 26290 SRM S ample '# : 5O-G-,09 SRM Cy lind er Ii ' FF31631 Analytical Method: Chemiluminescence Last MuUiplint Calibration : __**~fU_'~1I~20~ 2,-**  

## _______ , Firsl An, lysi. Data : Da le : 1011812012 Se co nd Analys is Dale; Dal e; 10125120 12 Z , 0 R , 9
. 87 C , 4
. 52 Cone: 4
. 52 Z, 0 R, 9
. 87 C, 4 .54 Cone : 4 . 54 R, 9
. 8 7 Z, 0 C, 4.51 Cone: 4 .5 1 R, 9.87 Z, 0 C , 4
. 53 Cone: 4 . 53 

### z, 0 C, 4
. 51 R, 9
. 87 Cone: 4
. 51 Z, 0 C, 4 .53 R , 9.81 Cone ; 4.53 

# I UO M' ppm Me,n Tesl As5ly : 4
. 51 ppm UOM : ppm Mea n Tnt Assay: 4
. 53 ppm Cert ifi ed 

### b y: 140eu. ft.

Information contained herein has been prepared al your r&quelll by Qualified experts WIthln Praxair Distribulion, I nc . While we believe that the i'l formalton is accurate within the lim its of the analytica l methods emp loyed and is complete 10 lhe extent of Ihe specific analyses perlormed, we make no warranty Of replesenialion 8S 10 Ule sui tabil ity of the use of tha information for any purpose . The i nfor mation i s offe red with Ih e understanding t haI any use of the Informati on 15 a\ the sole discretion and r is k of Ihe user. In no even! 'h a ll the IlsbHliy of Praxeir Distribution , Inc" ari sing out of 

### u. . 

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# /f!fl~PRAXAIR Praxair 5700 South Alameda Street Lo s Angeles. CA 90058 OocNumber: 

### 000042196 Tel ; (323) 585-2154 Fax;(714) 542-6689 PGVPID ; 

### F22012

Praxalr Order Number : Fill Dolt: 712612012 

### Delta Air Quality 1845 N
. Case St. Orange, CA 92865 

# - Customer P. 0. 

### Number: Customer Reference Number: 

### 20846451 03972778 ParI H"mbtr ; LoI f{"/Ilber : EV NINX4ME ·AS 109220806 ('yll"drr Slyl, II:**O"II~/ :**  AS CGA660 

# N ()**~ ~**  

# .? 

# I Expirallon Dale

# 212r~:::;ed COllcen/ration: NIST C : :::::' : " & 

# v,/".. 

# e ,.**~** 

# 3 L 

# 16 1 , CY.lin

_ d

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_ r

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_ 1b

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_ p

_ m

_ _ C

_ C

_ 3

_

36_1

_ 6 ._ 9
___ ----- ____

## !'~~**Iyt ca** **l ~ncertajnty:**  

# "- 7 0 NITROGEN DIOXIDE (as NOx) ± 2 % Balance NITROGEN 2000 pslg

# E'ff()VZ11"L~

# ____ _ Cerfifctltiolt 

### Informat/on: Certification Dale : 8/27/2012 Tenn : 6 Months Expirotion Date : 2/27/2013 This cylinder was cert ified according to the 1997 EPA Traceab ility P rotocol, Document #EPA-600 /R-97/ 121 , us i ng Procedure G1 Do Not Use this Standard if Pressure is less than 150 PSIG [NO)=O
. 06 ppm ; for reference on ly. Analytical Data: (R=Reference Standard , Z=Zero Gas, C = GIIS Cllndlaa le) 1
. Component: NITROGEN DIOXIOE (as NOx) Requested Concentration : <I ppm Certified Conronlralion: 3.71 ppm Instrument Used : Thermo Elect ron 42 1SIN 072602432C Analytical Method: Chemiluminescence Last Mu lUpoir.l Calibration : 811612012 Reference Standard Type : Ref
. Sid. Cy linder;; : Rei. Sid. Cone: ReI. Std. Traceable to SRM ti : SRM Sample II : SRM Cylinder II : GMIS CC335804 9 . 95 ppm 26298 5O-G-l09 FF3t631 140 cu. ft

## r;**~~An.'Y' ~Data:** **~-- ~1** **12012** 

# 1 I Z: 0 R: 1032 C : 3 . 85 Con c: 371 

## ! R: 10
. 35 Z; 0 C; 3 , 63 Conc: 37 

### i Z : 0 C : 3 . 83 R: 1 0
. 35 Cone ; 37

## ~o**~_ ~** **~** 

# ..____ ._

Meso Test Asuy :

_ ":1 p pm __. Second An,ly:s i, Dala : Date:

# M~~" 1 Z : 0 R: 10. 35 C : 3 .97 Cone : R : 1024 z : 0 C : 392 Cone : Z : 0 C: 3 .93 R: 1022 Cone : 

## ,**~~:**

# __**~pm** ..**~** ____ .__**~a** ..n Test A nay:**82PP ~**  Analyzed by :**~**

## Ja~ Certified by:

### ~,**Q'd~ _** 

Infor rJiarion contained herein has been prepared et your requesl by quellfied eKP8(ta wilhin PrsKair Oi&lr l bulion, Inc. While we bel i eve thaI (he Information i l aCC\I{ate with i n the lim i ls of the ana lytical methods omployed and is complete to the extenl of the specific analyses performed, we make no waiTanty or representation 8S to the**suilobH~y** of the use of the information fo r ony purpose . The Information is offared with the understanding thai any use of the information il at the sole discretion 11M r i sk of the user In no evant sha lt the liability 01 PrBJlsir Oistrioution, I rlC " jB'fiS i llQ 0 r the use of the information con talned herain exceed the fee estebhehed for providing luen Informolion
. ) / 

# (-1 

# 1**~f:; ~**  

### v

### Praxair 5700 So uth Alameda Street Los Angeles, CA 90058 DocNumber : 

### 000041947 Tel: (J2J) 585-2154 Fax:(114 ) 542-6689 

### PGYPID : F22012 

# CERTIFICATE OFANALYSIS/ EPA PROTOCOL GAS

, ..... '." , 

### -.. . 

### Custo Fill Dol,: 7127/2012 

### Delta Air Quality 1845 N
. Case SI. Orange, CA 92865 Praxair Order Number: 21015531 

### Customer P. 0. 

### Number: 

### 03998407 Customer Reference N umber: Pari N"mMr: 1.f>I Number : NI C04
. 7ME · AS 109220904 Cy/ill,kr Slylr ,(. Q,IIlrI: AS CGA350 Cylinder Pr. , f.wrr tf**Vvl"m~ :**  

# co I. 

# J. I 

# J**~** Certified Concentration: 

# T 'T

# 7 Expiration Date: 2120/2013 

### NIST Traceable 

## II**~~** 

### Cylinder Number: CC325462 Analytical Uncertainty: 

# CC 

# 3**~** 

# 5**~· ·--** **4. "'** **-- OXtDE** **-- ---** **--** --

# -- 2000 psig



### Balance NITROGEN



### Certijcation Information: Certification Date : 8/2012012 Term : 6 Months 

### Expiration Date : 2 / 20

/ 2013 Th is cyl i nder was certified according to the 1997 EPA Traceab ili ty Protocol, Document 

### #EPA-600 / R-97/121 , using Procedure G1 

### 00 Not Use this Standard if Pressure is less than 150 PSIG 

### A nalytico / Data: (R=Reference Standard, Z= Zero Gas, C=Gas cand ida te) 1 . Component; CARBON MONOXIDE Requested Concentration : 4
. 7 ppm Certified Concentration : 4.49 ppm Insllument Used : Horiba V I A· 510 SIN 576876015 Analylical Method : NOIR L85t Multipoint Calibration :



## z, 0 R, 84.3 R, 8 4
. 1 Z, 0 811112012


### c , 36
. 8 Date: Cone: 817(2012 4.45 c: 37 Cone ; 4.49 

# l
Z, 0 C , 36 . 9 UOM; ppm R: 84 Cone: 4
. 48**~** Mean Test ASliily: 4
. 47 p pm 

### --_. -- -- -----

## AnalYZedb~p 

# <g 

# Iwlzo Reference Standard Type ' Ref
. Std
. Cylinder '# : Ref
. Std
. Cone: Ref
. Std
. Traceable to SRM' : SRM Samp le' : SRM Cylinde r 11. : 

# ,.

# __ ._.. i Second Analysis Data : 

### I Z, 

### o 84 . 3 

### c,

Certified by : GMIS SA6687 1 0
. 2 ppm 1677 e 5-1-42 XF 0021438 Date ; 37
. 3 Cone; 8/1512012 4,51



# E**p~** 

# Tr-IA tltfJ,; 

# li-ly 

# Pf".f"U1/ 

# .p.r 

# Assuy**Gi~ Ctl'h'/{{,,~W!** **5fA,J,I',{~_** 

# RtVI$/o., 

# l1y lull 

# of-**~(oI.f~** 

# Cu libl4-/i"", '0'\ 

# /0.12 • 140 cu, n.

Information contained herein has been prepared at your request by qualified exper1s within Praxai r Distribution, Inc
. Vvhile we believe that It1e information is aCClJrate within the l im its of the analyt ical method s e m ployed and is complete to the exlent of the specific analyses performed , we make no wurranty or repr esenta tion as to the su itabiity of the us e of tile i nformation for any purpose . The inform ation is offered with the und erstanding that an y use of the information is at the sole discret ion and ris k of t he use r. In no event sha illhe**ab ~ity**  of Praxa iI D ist ri bution , Inc. , arising ou! of the ". of 'h. ,",0"""; 00 ron ,.n.d h.", ; n "",.d the f.e .".blohed fo'**pfO,~;ng** ,,,," " fom"'
. n 

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# i!ffiI!lPRAXAIR

DocNumber: 000038542 Praxair 5700 South Alam eda Street Los Angeles, CA 90058 Telephone: (323) 585·2154 Facs imile ; (714) 542-6689 

# CERTIFICATE OFANALYSIS/ EPA PROTOCOL GAS Delta Air Quality 18 45 N
. Case St. Orange , CA 92865 Praxair Order l\'umber: 20155225 Customer P. 0. Number: 03870012 (·uslorner Reference Number: Fill /)ole : J.ul**N"m~"r :**  Cylill<kr**Siyl~** &**Ollrl~l :**  5/112012 NI C09
. 5ME-AS 109 212204 AS CGA3SO 

# CO q 5**CJ'Ii"derf'rnsllrc<fr'ol",,,~ ~**  

### Certified Concentration: 

## •

## r-E-xp-ir-a-tio-n--D-at-e-**-------6-1-2-1/-20-1~5~------------------N-IS-T-T-r-a-ce-a-b-Ie-----.** 2000 psig 140 cu . fl
. 

# a::. '" 1'3

# ott! Cylinder

# N~~6b=,**~~~ _** **-- ~;~~~:2MONOXIDE**  _____ _ ___

# A~~~;a**l** Uncertainty Balance NITROGEN

# £~,~~~~;------------~ Certifcation Information: Certification 

### Dale: 5/21/2012 Term: 36 Months 

### Expiration Oate: 5/21/2015 This cylinder was certified according to the 1997 EPA Traceability Protoco l, Document #EPA-600/R-97/121 , using P roc edure G1 Do Not Use this Standard if Pressure is less than 150 PS IG PGVP I.D.# F22012 Allalytical Data:**(R"'Ref~rence** Slenderd, Z"'Zero Gss, C"'GBS Ci;Jndidate)

1
. Componenl: CARBON MONOXIDE Reque5ted Concentration: Car1i1ied Concentrahon: tnstrument Used Ana lytical Method' Last Mu N ipoint Calibration : first Analysis Data: 

### z, 0 R, 16 8.6 R, 168.7 Z, 0 

### z, 0 C, 158.4 UOM: ppm Analyzed by: 9.5O ppm 9
.56 ppm Horiba VIA-510 SIN 576876015 NOIR 5/1112012 Date: C, 158.4 Cone: C, 158.6 Cone: R, 168.8 Cone: Mean Test Anay: 5/1112012 9.58 9 . 59 9
. 57 9
. 58 ppm

Shameela Jiffrey I 

## , I I 

# J RelArence Standard TYPA : Ref Std. Cylinder" : Ref
. Sid
. Cone: Ref SId. Traceabla to SRM tI SRM Samp l e #: SRM Cyl i nder # : r - - 

### -- I Second Analysis Data: 

## , I Z, 0 R, 16' 

### c, 

## I 

# "' 1685 Z, 0 

### c·

Z, 0 C, 157.6 R, UOM: ppm Certified by: GMIS SA6687 10.2 ppm 1677c 5-1-42 XF 0021438 Dilte: 158.2 Cone: 157 . 5 Cone: 158.6 Cone: 5/2112012 9 . 55 9 .53 9.54

Information contained herein has been prepared at your requesl by qualified experts within Praxair Distr i bution, Inc
. V..tIile we oa li eve thallhe information is accurate within the limits of Ihe analytica l methods employed and is comp l ete to the extent of the specific analyses perform6d, we m ake no warranty or representation as to the suitability of t he use of the informetion for any purpose . The in for mation is offered with the understanding that any use of the information is at the sole discret i on ami risk of the user. In no evenl shall the liability of**Pra~air** Distribut7 ' n, Inc. arisi out 01 the use of the information con la l ned herein exceed the fee established for providlng:ruch information. 

# G -(z 

# -/1;;' 

# I

# EPA Traceability Protocol for Gaseous Calibration Standards: What Changed? Background In June 2012 , EPA published a revised version of the traceability protocol for gaseous calibration standards, which had not been updated since 1997. The protocol was revised in response to a 2009 evaluation report by the EPA Office of the Inspector General, which recommended that the EPA Office of Research and Development update and maintain the protocol gas procedures to ensure that the protocol meets the objectives of the Acid Rain, ambient air, and stationary source air programs. The revised protocol can be found at http ://www.epa.gov/nrmrllappcd/mmd/db-traceability-protocol.html.ltis a significant improvement over earlier versions of the protocol and has received consensus support by EPA , NIST , specialty gas producers, and other interested parties. There are several revisions that may be of direct interest to Source Evaluation Society (SES) members, as is discussed below : 

## 1. New Gas Mixtures and Concentration Ranges for EPA Protocol 

## Gases As a result of new or anticipated EPA regulations, the list of available EPA Protocol Gases has been expanded and can be seen in the table at the end of this article
. The gas mix1ures and concentration ranges that specialty gas producers can prepare, assay , and certify as EPA Protocol Gases is limited to those available from the National Institute of Standards and Technology (NIST) as NIST-certified gaseous reference standards (e
. g., Standard Reference Materials)
. NIST has or will expand the gas mix1ures and concentration ranges that it will certify. 

## 2. Extended Certification Periods for New and Existing EPA Protocol Gases Certification periods were ex1ended because NIST and specialty gas producers have gathered more informat i on about the long - term stability of gas mix1ures than was available when the 1997 version of the protocol was prepared
. Based on this information , the certification periods for NIST-certified reference standards have been ex1ended. If the assumption is made that the cylinder passivation techniques used by specialty gas producers for EPA Protocol Gases are the same as they have used for preparing NIST standards , then the stability for EPA Protocol Gases should be similar to that for NIST standards. The certification periods for new EPA Protocol Gases have been changed to match those for NIST standards. Because the stability data are for NIST standards that were produced in the past, they should be representative of existing EPA Protocol Gases
. Consequently, the ex1ended certification periods are applicable to existing EPA Protocol Gases. For example , an EPA Protocol Gas containing 50 ppm propane in air was originally certified on January 1 , 2009 under the 1997 revision of the protocol. Its certification ended three years later on January 2 , 2012. Because the new certification period for this gas mix1ure is eight years as a result of the 2012 revision, the new certification expiration date would be January 2, 2017
. The EPA Protocol Gas would not have to be recertified by its producer to receive the longer certification period, but would have to be recertified after January 2,2017. Producers can use their discretion regarding notifying end users about the ex1ended certification periods and the manner they use to make the notification. For those end users who are required by EPA regulations to use EPA Protocol Gases as calibration gases, some form of written documentation should be provided for the end users' records. For example, the producer could send a blanket letter or E-mail message to its end users and could offer to send a new certificate to those users who need wr itten documentation and/or are required to

## report about the expiration date of their calibration gases to EPA's Emissions Collection and Monitoring Plan System (ECMPS)
. ECMPS was designed to flag data obtained using expired EPA Protocol Gases
. This feature of the system has been temporarily disabled while ECMPS is being updated with the extended certification periods. The old expiration dates may be reported to ECMPS in the meantime. The extended certification periods do not protect against concentration shifts due to back diffusion of air from an improperly purged regulator or gas manifold into an open cylinder
. End users still have to be cautious to prevent such concentration shifts over time by properly purging regulators and gas manifolds before use and by closing hand valves after use . Given the longer certification periods, they must be more cautious than previously. 

## 3. Lower Cylinder Pressure Limits The minimum cylinder pressure for which EPA Protocol Gases may be used has been lowered from 150 psig to 100 psig. Formerly , an EPA Protocol Gas could be recertified if the cylinder pressure was greater than 500 psig before the recertification assay . Now , it can be recertified if the cylinder pressure is greater than 100 psig after the recertification assay. 

## 4. Zero Air Materials The protocol includes a new procedure for the assay and certification of compressed gas zero air materials as conforming to 40 CFR Part 72
. 2
. At this time, EPA does not require the regulated community to use NIST-traceable zero air materials for the calibration of ambient air or continuous emission monitors that are required by 40 CFR Parts 50, 58 , 60, and 75
. However, end users may elect to purchase these standards from specialty gas producers who elect to assay and certify them
. 

## 5. Dynamic Gas Dilution Systems The protocol includes a new procedure for the assay and certification of dynamic gas dilution systems. At this time, EPA does not require the regulated community to use NIST-traceable dynamic gas dilution systems certified under this protocol for the calibration of all ambient air quality or continuous emission monitors that are required by 40 CFR Parts 50 , 58, and 60. End users may elect to use NIST-traceable dynamic gas dilution systems certified under this protocol for calibrations under these CFR parts
. EPA does require NIST-traceable calibrations of dynamic gas dilution systems that may be used under Appendices A and C of Part 50 to calibrate ambient air quality monitors for S02 and CO. 40 CFR Part 75 only allows use of compressed gas calibration standards when calibrating CEMSs that are being used for purposes of Part 75 and when calibrating Test Methods 3A, 6C , and 7E when these methods are used for Part 75 testing. 

## 6. Implementation Period The producers of EPA Protocol Gases are allowed until June 2013 to implement the changes that have been made to this protocol. Afterwards, producers must follow the procedures given in this revision of the protocol if they wish to sell calibration gases as "EPA Protocol Gases"
. 

## 7

. Protocol Gas Verification Program The producers of EPA Protocol Gases must also participate in the Protocol Gas Verification Program (PGVP). EPA air pollution monitoring regulations specify that the regulated community must use EPA Protocol Gases from PGVP participants
. One component of the PGVP concerns calibration gases for ambient air quality monitoring and another component concerns calibration gases for continuous emission monitoring systems (CEMS). The PGVP

## is the primary accuracy assessment for EPA Protocol Gases . I t provides information about the accuracy of the certified concentrations of EPA Protocol Gases that were purchased from specific spec i alty gas producers
. As such , the PGVP resu lts assist end users' purchasing decisions
. See www . epa . gov/airmarkets/emissions/pgvp-detail.htmlfor deta i ls about the ambient air PGVP and www.epa.gov/ttnamti1/aapgvp
. htmlfor details about the emiss i on PGVP
. 

## Summary The protocol has been revised to allow specialty gas producers to meet the needs of calibration gas users for new gas mixtures and new concentrations
. It presents a new method for generating NIST-traceable calibration gases. Calibration gas users will have greater confide n ce i n EPA Protocol Gases as a result of the rev i sion
. Questions about the protocol can be directed to: Robert S
. Wright Air Pollution Prevention and Control Divis i on U
. S
. Environmental Protection Agency Phone : 919 - 541-4502 E-mail: wright.bob@epa
.gov

## Gas Mixtures, Concentration Ranges, and Maximum Certification Periods for EPA Protocol Gases under the 2012 EPA Traceability Protocol Components Balance gas Concentration range Period (years)· Ammonia Nitrogen 5 to 50 ppm 1 Carbon dioxide Air" 360 to 420 ppm 

## 8 Carbon dioxide Nitrogen 5 ppm to 20% 

## 8 Carbon monoxide Air 40 to 500 ppb TBD Carbon monoxide Air 500 ppb to 10% 

## 8 Carbon monoxide Nitrogen 1 ppm to 15% 

## 8 Formaldehyde Nitrogen 0.5 to 10 ppm 1 Hydrogen chloride c 

## Nitrogen 10 to 5000 ppm 2 Hydrogen sulfide Nitrogen 1 to 1000 ppm 3 Methane Air 1 to 1000 ppm 

## 8 Methane Nitrogen 500 ppb to 10% 

## 8 Methanol or ethanol Nitrogen or Air 75 to 500 ppm 4 Natural gas components' Natural gas Contact NIST 4 Nitric oxide 02-free nitrogen" 0
. 5 to 50 ppm 3 Nitric oxide 02-free nitrogen" 50 ppm to 1% 

## 8 Nitrous oxide Air 300 ppb to 5% 

## 8 Oxides of nitrogen' Air 3 ppm to 1% 3 Oxygen Nitrogen 10 ppm to 25% 

## 8 Propane Air 0.1 to 500 ppm 

## 8 Propane Nitrogen 5 ppb to 2% 

## 8 Sulfur dioxide Nitrogen 1 to 50 ppm 4 Sulfur dioxide Nitrogen 50 ppm to 1%- 

## 8 Volatile organics Nitrogen 1 ppb to 1 ppm 4 Zero air material g 

## Air Not applicable Unlimited Multicomponent See protocol mixtures Mixtures with lower See protocol concentrations

a 

## Specialty gas producers may elect to certify candidate standards for less than the maximum certification period. Each producer has discretion in this matter
. See protocol. b 

## "Air" is defined as a mixture of oxygen and nitrogen where the minimum concentration of oxygen is 10 percent and the concentration of nitrogen is greater than 60 percent. C 

## Hydrogen chloride may be contained in passivated aluminum or nickel-coated steel cylinders
. , Natural gas components are methane, ethane, propane, n-butane , iso-butane, n-pentane, iso-pentane, helium, nitrogen, and carbon dioxide
. " 02-free nitrogen contains**~** 

## 100 ppb of oxygen . , NIST defines its total NOx standards as containing nitrogen dioxide plus contaminant nitric acid. g 

## Concentrations of S02, NO x. and THC are not >0
. 1 ppm; concentration of CO is not >1 ppm; and concentration of CO 2 is not >400 ppm as per 40 CFR Part 72
. 2
. Zero air material may be contained in steel cylinders
.Orifice Method - Triplicate RunsfFour Cahbrahon POints English Meter**Bo~** Units , EnglISh K' Fattor SEMI

_ ANNUAL DRY G AS METER/ORIFICE CALIBRATION

Mode t # 10# : Filename l\RecepbOnldeltil pubtu:\C iI !lbrallonslMeters I12 ·wcsI2 012\(SeIl'll_Annuat MeIer CatlbfallOnl2 WC$ 10-23-12 xtsIWCS Date**12~** 1 012312012 File M odified From APEX 522 Senes Meter box Callbf ation Revised 4/812005

Volume Volume dH Time Initial F i nal in H2O (min (eu It) (eu It) 011 2600 44 ,960 50 ,3 84 011 2600 50,384 55 ,812 011 26
. 00 55
. 8 1 2 61 ,279 059 1200 61
.279 66 871 059 1200 66 ,871 72 .44 5 0,59 12,00 72 445 78.039

DRY GAS METER VOLU M E VOLUME VOLUME CORRECTED CORRECTED CORRECTED

Vm(std) Vrn{std) Ver{s td) leu tt)' (liters) (eu tt) 5.401 1530 5
. 236 5
. 385 1 525 5
. 236 5 .40 3 1 53,0 5
. 236
5518 156 3 5 ,392 5 4 95 1556 5392 551 4 156 2 5392
5 465 

# "" 5 "5 

# "as 1554 5 "5 5.474 155 a 5.345
5
. 356 151 7 5318 5312 150 , 5318 5
. 341 1512 5318

SIGNED Sig nature on Fi le Bar P ressure Perlo rmed By 2977 (m Hg ) G Bndge 099 DRY GAS METER READINGS CRITICAL ORIFICE READINGS Volume In itial Temps Fmal Temps Onfice K' Onfice Actual Total Inlet Oullet Inlet**Ou~el** Senatit CoeffiCien t Vacuum IMlal (cu tt (de F d. F (de F) (d F, (number) see aoove (in H (de F) 5424 67,0 66 . 0 69
. 0 68 ,0 33 0 1 553 235 6 7
. 0 5426 

### '90 '80 71
. 0 70 ,0 33 0
. 1 553 235 67.0 5.467 710 700 73.0 ; 20 33 0
. 1 553 23,5 67
. 0 5
. 592 730 720 7<0 73.0 

# " 03465 "0 

### '70 5574 74
. 0 73.0 74 .0 730 

# " 03465 21
. 0 67
. 0 559' 7<0 730 7<0 730 

# '. 0,3465 21,0 67.0

ORIFICE DRY GAS METER ORIFICE CALIBRATIO N FACTOR CALIBRATIO N FACTOR IndIvidual Individual VOlUME VOLUME R" Onfice CORRECTED NOMINAL Y dH @

Vcr(std) 

### va Value Value 095 < Y Ymax - Ymin

lite r s) (eu tt ) (number) {in H20) < lO S? < 0 ,010? 1 4 83 5
. 255 0969 1 .52 1 Pass 148,3 5 255 0
. 972 1.5 15 Pass 148
. 3 5
. 255 0,969 1 ,509 Pas s Average 0
.970 1.515 Pass 1527 5 411 0
. 977 1
.622 Pass 1 527 5411 098 1 1620 Pass 152
. 7 5411 0978 1.620 Pass AverOlige 0.979 1 . 621 POIISS lSI 4 5'" 0.976 1.605 Pass 1514 5364 0974 1 803 Pass 151 4 5'" 0976 1803 Pass AvetOlige 0
. 976 1
. 804 Pass 150' 5337 0993 1 .712 Pass 1506 5337 1001 1
. 712 Pass 150' 5331 0 . 996 1710 Pass Averaqe 0
. 997 1
. 111 Pass Average Yd : 0
. 980' dH@ : 1.663 Q@dH:l : 0
. 582 Da te : 1012312012 Ambient Temper at ure Fin al Average (de F) (d F 67
.0 670 67
. 0 

### '70 67
. 0 67
. 0 67.0 

### '70 67
. 0 670 67.0 

### '70

Orifice OrifICe Average Average 0.96 < YfYd dH@ - dH@av

< 1 .0 2? < 0, ISS?

Pass Pass

POIISS POIIS S

Pass Pass

Pass Pass

s.. ..... A nnual M ete r Cal ibral"", ' 2.....,1 10·23- ' 2 xis WCS l/1612013 2 ' 17 PMOnfice Method - T riplic a le Runs/Four Calibr ation POin ts Engl i sh Meter Box Units, Eng l ish K' Factor SEMI-ANNUAL DRY GAS M ETERIORIFICE CALIBRATION

Model # . 10#: Filename \\ Recep llonldel la**pubilc\CalibrationslMeters\I-P&M\2012~Seml Ann** **ual** Meter Ca l i b ration l ·pm 10-26-12 xlsjWCS Dale ' 1 pam 10/26/ 2012 File M odified From : APEX 522 Senes M eter bo x Calibration ReVised 4 /8/2005

Volume Volume dH T ime 1000Iai Fina l in H2O (mill) 

# co, (cu ft) 0.13 26,00 633 .300 638 .575 0,13 26 ,00 638
. 575 643.880 0.13 26 00 643
. 880 649
. 138 067 12
.00 64g , l38 654.468 067 "00 654
. 468 659
.800 067 "00 659800 665140 200 7.00 665
. 140 670.440 200 7 .00 670
. 440 675.775 200 7.00 675
. 775 681
. 132 390 500 681.13 2 686.340 3.90 5 .00 686,340 691
. 560 3 .90 5.00 691 , 560 696
. 807

VOLUME VOLU M E VO LUME CORRECTED CORRECTED CORRECTED

Vm(sld) Vm(std) Vcr(std)
5267 14 9.2 5.255 5
. 22 1 147
. 8 5
. 253

5
.291 1498 5 .4 07 5299 1 50
. 1 5
. 4 07
5277 1494 5.359 5306 "OJ 5.357 5 ,3 23 "06 5,354
5
. 199 14 7
. 2 5.327 5
. 211 147 6 5
. 327 5
. 238 148
. 3 5
. 325

SIGNED S igna t ure on File Bar. Pressure ' Perform ed By ' Meter Serial # 2985 (Ill Hg) gary bridge 134641600 DRY GAS METER READINGS CRITICAL ORIFIC E READINGS 

# V.""" I niti a l Temps Final Temps Ooliee K' Orifice Actual Tota l Inl et Outlet Inlet Outle t Senal# Coefficient Vacuum 1000Iai 

# '"' {d F, " F d F, (d e F numDer see above (In H ) F 5275 710 70 ,0 710 70.0 J3 0.15 53 27.0 66.0 5
. 305 710 70,0 71
.0 70
. 0 J3 0
. 1553 27.0 660 5
. 258 710 700 710 70
. 0 J3 0
. 1553 27.0 66
. 0 5330 71.0 700 72.0 

# '" " 0 3465 225 67
. 0 5 332 72.0 710 720 710 

# " 0.3465 22.5 670 5"0 72.0 710 720 710 

# " 0_ 225 670 5 . 300 72.0 710 720 71.0 63 0_ 19
. 0 670 5335 72.0 710 730 720 63 05888 19
. 0 670 5357 73.0 720 730 72.0 63 0
. 5888 19
. 0 68 .0 5208 730 720 730 72.0 73 0
. 8202 16.5 68
. 0 5,220 73.0 720 73
. 0 72.0 73 0
. 8202 '6 5 68
. 0 52 4 7 73.0 720 73.0 72.0 73 0.8202 16 , 5 68 .0

CALIBRATION FACTO R CALIBRATIO N FACTOR IndMdual I nchvldua l VOLUME VOLUME Roo ""fire CORRECTED NOM INAL Y dH@

Vcr(std) Vcr Value Value 0
. 95 < Y Ymu-Ym i n H20l 0< 1
. 05? 0< 0
. 010? 779 Pass 146 ,8 5
.250 0
. 996 1779 Pass 148 ,8 5
. 252 ' . 006 1
. 781 Pass Average 1
. 002 1 ,779 Pass 

# A"" :' 1
. 843 Pas s 1531 5. 411 1642 Pa ss 1531 5411 1
. 842 Pass 1 .842 Pass 1518 536< 1016 

# "" P 151
. 7 5.366 , 009 '.904 Pus 1516 5
. 389 , 006 , 904 Pass Average 1
. 010 1 .904 Pass 15 0,9 5
. 342 1
. 913 P 1509 5
. 342 1913 Pa ss 1SO
.8 5
. 345 1017 1
. 915 Pass r---AVe'rage Yd: 1 . 014 ' dH@ : 1 , 860 

# I a@dH:l : 0 , 550 Da te 1 0126/2012 Ambient Temperature Fillal Average {d F (de F) 66.0 660 66
. 0 660 67,0 665 670 670 67
. 0 670 67 .0 670 67
. 0 670 68 .0 675 68.0 680 68.0 680 68,0 68,0 69 ,0 68 ,5 

## 0,,,,, Oofice Avefage Ave rag e 0
. 98 '" YNd d H @ - dH@ av

'" 1.02? <0
. IS5?

Pas s Pass

Pass Pass

Pass Pass

Se""'Annu.1 Me! .... C. lib4"flion 1.pm 10·26--12 xi s WCS 311612013**2~** PM

# _----e 

# A**~j[ J**  , Si d e V iew
Acceptability

Crit e r i a z < 1/ S " w < 1 / 32 "
S i d e View , S i de View,

Impa c t I mpa ct Pilot 10 Da t e Calibrat e d B y op e nings open i n gs Properly Prope r ly aligned , Z < aligned, w 11S" < 1132"
026 y 

### Y 

### S Type Pitot Tube Dimensional Calibration Record 

# 1 <\ 

# i

"3/ 16" < Ot < Y e, 3 / S "

Pa::Pb Tubing Diameter , dt



### Y 0 . 37 4

# ~ M, 

# -1**~ ~**  M,

# ~ E nd View

n /. nf
. n/ .

M1 M2 M3

0
. 882 0. 8 70 0
.882 n/. n / .

M' M'

0
.876 0.43 7

Re fere nce "A Type - S Pito t Tu be Calibra tion Study, Robert F
. Vol1 aro, October 15, 1 975 If t ube is not visibly deformed it is assumed that Pa " Pb '"
. 5 x a vg. of M1 M2, and that a v erage f ace opening plane angles repre se nt individual angles to tube axis 

# ....

n / .

M

6

0 .4 5 7 

# ----I M s 

# r- 

# ;' §;C f -r- M: M

, p, i 

# ! 

# -I I-- Too V iflw
1 ,0 5 O t< P < 1
. 5 10 d eg rees 5 deg rees Dt
A ve rage Fa ce Average Fa ce Ope ning P lane An gl e , o ffs et Opening Plan e fro m F rontal Angl e Rat io o f Pl Ot Stat u s p e rp e ndicular from parallel t o t o transverse Longitudinal axi s Axis 0
. 9 0 .4 1
. 2 Pass

### Standard Pitot Tube Dimensional Calibration Record

A 

# -

J 

### @ 

# " A 

# '" , &"' Section AA 

# • 

# "' 

# T
Tip**cce~ ,a~I** **IIIY** Criteria V" V" 

# 0" 0 " 0 " 0" ·0.101 M1 > 6 01 M2 >8 01 Hemispheri c al , 90· Bend with Pitot 1 0 Date Calibrated B Elliptical, or curved or mitered 0' 02 

# ., .2 Ratio 02/01 '0' 80' Status Conical T i p ' unction 7 y Y 0 . 125 0 . 015 1 , 100 1 . 700 0.120 0 . 750 1 . 0 Pass 8 

### y Y 0.31 0 . 029 2 . 110 2 . 550 0 . 094 1 . 860 2 . 5 Pass 33 

### y Y 0 , 258 0 . 029 1.550 2 . 120 0 . 112 1 . 548 2 . 1 Pass 79 

### y Y 0 . 25 0 . 029 1.500 2 . 200 0 . 116 1 . 500 2 . 0 Pass 80 

### y Y 0 . 25 0 . 029 1 . 530 2.200 0 . 116 1 . 500 2 . 0 Pass 81 

### y Y #DIV /O' 0 . 000 0 . 0 84 at Doug's 

### Y Y #DIV /Dt 0 . 000 0 . 0 85 

### Y Y 0 . 25 0 . 03 1.600 2 . 220 0 . 12 0 1 . 500 2 .0 Pass 88 at DOUQ's 

### Y Y #OIV/O ! 0 . 000 0.0 103 

### Y Y #OIV/O! 0 . 000 0.0 107 #OIV/O I 0 . 000 0 . 0 108 

### Y Y 0 . 254 0 . 029 1 . 550 2 . 200 0 . 114 1 , 524 2 . 0 Pass Notes : Reference · Standard P i tot Tube Calibratlons, South Coast Air Qual ity Manag ement District Source Test Manual, Chapter III, March , 1989TEMPERATURE SYSTEM CALIBRATION 

### #8 T2 F95 - 195 T3 F95-195 I D
.

I OIL PTC-23 360 360 360 360 360 360 360 360 0 WATER PTC - 23 214 214 214 214 212 212 212 

### 2"

OIL PTC-24 36' 36' 36' 36. 360 360 360 360 WATER PTC-24 

### 2" 2" 

# '" '" 2" 2" 212 212

Calibrated By: DMW , RM , RMO , DA, ME JanuOiry 2 , 20 1 3Reference Thermometer 1.0. TIC Readout 1. 0 10 

# .. Read ing 1 OIL PTC-2S 362 WATER PTC-2S 213

ICE PT C-2S 

# " OIL PTC-26 362 WATE R PTC-26 211

ICE PTC-26 32 OIL PTC-27 362 WATER PTC-27 213

ICE PTC-27 30 OIL PTC-2 8 36' WATER PTC-28 213

ICE PTC-28 33 OIL PTC-29 362 WATER PTC-29 213

ICE PTC-29 32 OIL PTC-30 360 WATER PTC-30 212

ICE PTC-30 32 OIL T RO-1 360 WATER T RO-l 213

ICE TRO-1 

# " OIL TRO--4 359 WATER TRO -4 213

ICE TRO-4 

# " OIL TRO-S 36' WATER TRO-S 213

ICE TRO-S 33 OIL TRO-6 360 WATER TRO-6 21'

IC E TRO-6 30 OIL TRO-S 361 WAT ER TRO - S 213

ICE TRO-s 33 OIL TRO- 9 359 WATER TRO·9 21'

ICE TRO-9 32 OIL T R O-ll 359 WATER TRO-l1 213

I CE TRO-l1 33 OIL TRO·12 360 WATER TRO-12 212

ICE TRO-12 32 OIL TRO-13 360 WATER TRO-13 214

ICE TRO-13 

# " OIL TRO-iS 360 WATER TRO-IS 213

ICE TRO-tS 30 OIL T R O- 16 36' WATER TRO-16 213

ICE TRO -16 

# " OIL TRO-IS 36' WATER TRO-1S 213

ICE TRO-1S 34 OIL TRO-19 360 WA TER TRO·19 212

ICE TRO-19 33 OIL TRO-20 362 WATER TRO -2 0 213

ICE TRO-20 32 OIL TRO -22 363 WATER TRO-22 213

ICE TR O- 22 32 OIL TRO-23 363 WATER TRO-23 213

ICE T RO - 23 32 OIL TRO-24 362 WATER TRO -24 

# '"

ICE TRO-24 32

Cal ib rated By : DMW , RM , RMO. OA. ME 

### n TEMPERATURE SYSTEM CALIBRATION STANDARD 

### #8 F9S·19S T2 F9S·19S T3 F9S-19S TIC - Readout Reference Th ermometer of of Reading 2 Reading 3 Average Readil'l9 1 Reading 2 Read ing 3 Average 362 362 362 36D 36D 360 36D 213 213 213 212 212 212 212 

# " 

# " 

# " 32 32 32 32 362 362 362 360 360 360 360 21' 211 

# '" 212 212 212 2 12 32 32 32 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 30 30 30 32 32 32 32 36 ' 36' 36' 360 360 360 360 213 213 213 212 212 212 212 33 33 33 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 212 212 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 213 213 213 212 212 212 212 

# " " 

# " 32 32 32 32 359 359 359 360 360 360 360 213 213 213 212 212 212 212 

# " " " 32 32 32 32 36 ' 361 36' 360 360 360 360 213 213 213 212 212 212 212 33 33 33 32 32 32 32 360 360 360 360 360 360 360 21' 

# '" 21' 212 212 212 212 30 30 30 32 32 32 32 361 361 361 360 360 360 360 213 213 213 212 212 212 212 33 33 33 32 32 32 32 359 359 359 360 360 360 360 21' 21' 21' 212 212 212 212 32 32 32 32 32 32 32 35' 359 35' 360 360 360 360 213 213 213 212 212 212 212 33 33 33 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 212 212 212 32 32 32 32 32 32 32 360 360 360 360 360 360 360 214 214 214 212 212 212 212 

# " " " 32 32 32 32 360 36D 360 360 360 360 360 213 213 213 212 212 212 212 30 30 30 32 32 32 32 36' 36' 36' 36D 360 36D 36D 213 213 213 212 212 212 212 

# " " 

# " 32 32 32 32 361 36' 36 ' 360 360 36D 360 213 213 213 212 212 212 212 34 34 34 32 32 32 32 360 360 360 360 360 360 360 212 212 212 212 212 212 212 33 33 33 32 32 32 32 362 362 362 360 360 360 360 213 213 213 212 212 212 212 32 32 32 32 32 32 32 363 363 363 36D 36D 360 36D 213 213 213 212 212 212 212 32 32 32 32 32 32 32 363 363 363 36D 36D 360 36D 213 213 213 212 212 212 212 32 32 32 32 32 32 32 362 362 362 360 360 360 360 

# '" '" 

# '" 212 212 212 212 32 32 32 32 32 32 32 Differenc e "F 2 

# , , 2 

# , 0 2 

# , 2 

# , , 

# , 2 

# , 0 0 0 0 0 

# , 

# , , 

# , , , 

# , , 0 

# , 2 

# , 

# , , , 

# , 0 

# , 

# , , 0 0 0 0 2 

# , 0 

# , 2 

# , , , 

# , , 2 0 0 

# , 2 

# , 0 3 

# , 0 3 

# , 0 2 

# , 0 %,("R) 0.2% O.t% 0.2% 0.2% 0.1% 0.0% 0 . 2% 0 . 1% 04% 0 . 1% 0.1% 0 . 2% 0 . 2% 0 . 1% 0.0% 0 . 0% 0 . 0% 0 . 0% 0 . 0% 0 .1 % 0.2% 0 . 1% 0.1% 0 . 2% 0 . 1% 0 . 1% 0.2% 0.0% 0,1% 0.4% 0,1% 0 . 1% 0 . 2% 0 . 1% 0 . 1% 0 . 0% 0. 1 % 0 . 1% 0 . 2 % 0 . 0% 0,0% 0,0% 0 ,0% 0 ,3% 0 ,2% 0 ,0% 0 . 1% 0.4% 0 . 1% 0 . 1% 0 . 2%**1°~** 0.1% 0.4% 0 . 0% 0 . 0% 0.2% 0 . 2% 0 . 1% 0 . 0% 0 . 4 % 0 . 1% 0 . 0% 0.4% 0.1% 0 . 0% 0 . 2% 0 . 1% 0 . 0% P 

## '" ." P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P 

# ."

'" '" '" 

# ." '" '" '" '" 

# '" '" 

# ." '" '" '" '" 

# '" '" '" '" '" 

# '" '" '" '" 

# '" '" '" 

# ." ." '" '" '" '" 

# '" '" 

# '" '" 

# '" '" '" '" '" '" 

# '" '" '" 

# '" '" 

# ." '" '" 

# ." '" '" '" '" '" '" 

# '" 

# ." '" '" '" '" 

# '" '"

January 2, 2013WATER PTC-9 Oil PTC-10 WATER PTC-10

OIL WATER

WATER

I OIL WATER

OIL WATER

I PTC-22 PTC-23 PTC-23 PTC-2 4 PTC-24

Calibraled By OMW , RM , RMO , DA, ME 213 361 

# '" 362 

# '"

213 363 

# '" 361 

# '" TEMPERATURE SYSTEM CALIBRATION

213 361 

# '" 36' 

# '"

213 363 

# '" 361 

# '" 213 361 

# '" 36' 

# '"

213 363 

# '" 361 

# '" 213 361 

# '"

213 363 

# '" 361 

# '12 360 

# '"

'" 360 

# '" 360 

# '" 360 

# '"



# '" 360 

# '" 360 

# '" 360 

# '"



# '" 360 

# '" 360 

# '" 

# '" 360 

# '" 360 

# '" 3

0

January 2 , 2013TEMPERATURE SYSTEM CALIBRATION 

### #26 F95-195 1 . 0 .

Calibrated By · DMW , RM
. RMO , DA , ME January 2, 2013

# Del/a~ Air Qua li fy Services , Incorporat ed 

## NOZZLE CALIBRATION DATA 

## Nozzle I.D. 

# ').s- s ti< Date 2 

# ns If) Material 

## C, \ 

## By M ( ConfiQuration (L orffoo'R-l '--.....---'



## Maximum Difference D j - 

## D j 

## = 0. CC1- 

## (must be 0.004" or less) Average Dn 

## = O
. 

# 7.. ') 

# 'i

Note : Measure three diameters with micrometer

DS1204098 

# Della /j.

..

.". "' 

### ........ . ............. Date of last revision 

## 1 /

7/2013 Master Document StoragelFormslDatasheetslCalibration Forms

# Delfa l1

A ir Q ual i ty S e rvices, I n co rp or a te d 

## NOZZLE CALIBRATION DATA Nozzle 1.0
. 

## $S->fK Date 

## 'Z/Z-GI 

# I > Material \, ) 

## Bv , Me 

## Configuration (L 

## or(l1oo lS-) '----'



# D, = (::.2-3



# D

3 = 

# C. 

# 'l ].)'

Maximum Difference D ; - D j 

## = 

# C - CVL. (must be 0.004" or less) Average Dn 

## = 6"Z.") 

# '1

Note : Measure three diameters with micrometer

DS1204098 

# Della /).


# .. """"" 

### ...... " 

## ........... Date 

## of last revis i on 

## 1 /

7 / 2013 Master Document Storage l Forms l DatasheetslCalibration Forms

## Appendix A
. 4

R521 0729 

## Delta CEM System Description and SCAQMD Method 100.1 Calibration and Test Sequence

A-9

## SCAQMD METHOD 100.1 CALIBRATION SEQUENCE AND CA L CU LATIONS DEFINITIONS : 

## 1) Analyzer Calibration :
2) Calibration Error :

3) Analyzer Linearity:

4) Sample System Bias:

R521 0729 

## Zero and span gas(es) are introduced directly to the analyzer. Adjustments are made to the analyzer zero and upscale readings, as necessary to match the certified concentrations of the calibration gas . Zero, mid (40-60% of full scale), and high (80-100% of full scale) calibration gases are introduced directly to the analyzer and the analyzer response to each gas is recorded (without adjustment to the analyzer)
. The 

## Calibration Error (difference between the analyzer response to the calibration gas and the certified concentration of the calibration gas) must not exceed ±2% of the analyzer full scale for any of the three gases. Analyzer linearity is defined as the difference between an analyzer response to the mid range gas and the predicted analyzer response to the mid range gas based on the analyzer response to the zero and high range gas . The 

## Analyzer Linearity test is required on a semi-annual basis and must not exceed ±1 

## % of the analyzer range. It should be noted that this linearity requirement is more stringent than the best available calibration standards (+/-2%) for the low CO and NOx 

## concentrations expected during this test program. For this reason, an analyzer linearity of less than 2% will be considered as acceptab l e for this program. The sample system bias test involves introducing zero and one upscale (mid or high) calibration gas to the entire sampling system and recording the analyzer response. The analyzer response to the calibration gas after it has passed through the entire sample system is compared to the analyzer response to same the calibration gas injected directly to the analyzer. The test is used to determine the effect which the sample system has on the species of interest and correct the measured values for any effect which the system has
. The sample system bias is required to be less than ± 5% of the analyzer range for both the zero and upscale gas.

A-10

## PROCEDURES AND CALCULATIONS: Figure 1 presents a flow chart for the SCAQMD Method 100.1 calibration sequence. All calibrations are documented as one-minute averages from the reference method Data Acquisition System. Following assembly of the system, analyzer warm up time, and a successful leak check of the sample system, the calibration/test sequence presented in Figure 1 can begin
. An Analyzer Calibration is performed as necessary by adjusting the zero and span settings of the analyzer. These calibrations are not necessarily recorded on the chart recorder. Calibration Error is then determined at three levels for each range (which is expected to be used) of each analyzer
. This check is performed , at a minimum, once at the beginning and once at the end of each test day. The calibration error must not exceed ±2% of the full range of the analyzer as determined by the following equation : C E Analyzer Response- Cal. Gas Value 

# * 0



## alibration rror = 

## A I R 100 

# Yo na yzer ange The data from the Calibration Error test can be used to determine Analyzer Linearity. The analyzer response to the mid gas is predicted using linear regression and the analyzer response to the zero and high calibration gas and the zero and high calibration gas values. The analyzer linearity must be demonstrated on a semi-annual basis using the following equation: Analyzer Response - Predicted Response Analyzer Linearity 

# = * 

## 100% Analyzer Range where: Response to High Gas - Response to Zero Gas Predi cted Response = • 

### Mid Gas V alue + 

### Response to Zero Gas High Gas Value 

## The Sample System Bias test is performed before and after each test run and must not exceed ±S% of the analyzer range for both the zero and upscale span gas. The system bias is calculated using the following equation: Response to System Bias - Response to Analyzer Cal Sample System Bias 

## = * 

## 100% Analyzer Range

R5210729 A-11

## where : Response to Analyzer Cal 

## = The analyzer response to the last time the same calibration gas was introduced directly to the analyzer (this may be the pre-test calibration error value or a more recent analyzer calibration adjustment) Zero and Calibration Drift are calculated for each test run based on the analyzer response during the pre- and post-test sample system bias test. Zero and upscale drift must not exceed ± 3% of the analyzer range. Post - Test Sys tem Bias Resonse - Pre - Test System Bias Response Analyzer Drift = • 

## 100% Analyzer Range The pre- and post-test analyzer response during the sample system bias test are used to correct the raw test average for any sample system bias and analyzer drift. The drift/bias corrected data are the actual reported concentrations and are used for subsequent calculations (mass emission rates, Ib/MMBtu, corrections to 3% or 15% O2, etc
. )
. The drift/bias corrections is performed using the following equation : 

# c-c C 0 

## * 

# c

c =C-C ma where: Cc 

## = Drift/bias corrected concentration C = 

## Raw Test Average m 0



## Cm 

## = Average of pre- and post-test response to sample system bias span Co 

## = Average of pre- and post-test to sample system bias zero C

# m a = Span gas value ADDITIONAL QUALITY ASSURANCE CHECKS : SCAQMD Method 

## 100 . 1 specifies the allowed analyzer interferences for each analyzer type. No interference checks are required for O 2 or NO , analyzers. Interference tolerances are given for CO, CO 2, and S02 analyzers
. The analyzers used by Delta are certified by the manufacturers to have interference responses which meet the requirements of Method 100
. 1. SCAQMD has published a draft method for determining the efficiency of a N0 2 to NO converter. This test will be performed once on the day of the test. The converter efficiency must be 90% or greater.

R5210729 A-12

## Analyzer Cal Cal No Error 

## < 2% No Yes IYes

System 

# 1 Nn 

## System tBias 

## < 5% Problem? Yes Don't Know Stratified No Location? Yes Multi-Point Single Point Test Test

# ~ System No Bias 

## < 5% Yes Cal No Drift 

## < 3% Yes Note: AQMD policy allows multiple 

## Another No Analyzer Cal test runs to be validated by one set of pre- and post-test sample system 

## Test? (if neCeSSary) bias tests as long as the bias 

# 1 checks are performed within 2 hours 

## Yes of the previous bias check. 

## No No Analyzer Cal Cal? Error 

## < 2% Yes 

# 1 Yes No Yes System 

# ( Finish 

# ) Bias 

## < 5% 

## I- FIGURE 1: SCAQMD METHOD 100 . 1 CALIBRATION AND TEST SEQUENCE

R5210729 

## A·13

## APPENDIX B PROCESS DATA

R521 0729 

### 8-1

## Appendix B.1 Process and CEMS Data

R521 0729 8-2

## Appendix 

## B.1.1 Sentinel Unit 5 Stratification Test

R5210729 B-3

# Data Summary Report Company : CPV Sentinel, LLC 62575 Powerline Road

# e.1**1i~** 

# \**~**

# ~-h~(v~17**"** (£-nlL Desert Hot Springs , CA 92240 Source: 

### Data Group : Report Name : 

### Start of Report : Turbine 5 S>l-Min Cales S>Summary

- I-Min RATA 

### 02/25/2013 09,49 G45-C4 

### End of Report, 02/25/2013 11,08 G4S-Cll G4S-C20 G45-C3 G4S-C13 

# TRACE
ElII; ironm enla l**!l ~,**  

### T ll c.



### validation: All Available Data G4S-CIO G45-C6 G4S-C7 G4S -C S G45-C18 G4S-C 

### Group#-Channel# 

### Long Descrip. Short Descrip
. Units G45-C2 S;:.Stk NOx

Stk NOx 

### ppm 0 -15 0 5>Stk 02 5>NOx Mass S>StkFlow 

### 5>Stk CO S>CO Mass 5>NDx Rate S>Stk NOXC s>Stk CDc 5>Gas Flow 5>NH3 Inj S>MW La 

### Range 02/25/2013 09:49 02/25/2013 09:50 0 2 /25/2013 09:51 02/25/2013 09:52 02/25/ 2 013 09:53 02/ 2 5/ 2 013 09:54 02/25/2013 09:55 02/25/2013 09:56 02/25/2013 09:57 02/25/2013 09:58 02/25/2013 09:59 02/25/2013 10:00 02/25/2013 10:01 02/25/2013 10:02 02/25/2013 10:03 02/25/2013 10:04 02/25/2013 10:05 02/25/2013 10:06 02/25/2013 10:07 02/25/2013 10:08 02/25/ 2 013 10:09 02/25/2013 10:10 02/25/2013 10:11 02/25/2013 10:12 02/25/2013 10:13 02/25/2013 10:14 02/25/2013 10:15 02/25/ 2 013 10:16 02/25/2013 10:17 02/25/ 2 013 10:18 

### Date/Time Printed: 1., 1.. 1.. 2.0 2.0 1.9 1.9 1.9 1.9 1.9 1., 2.0 1.9 1.9 1.9 1.7 0.3 0.6 0.6 1.5 2.1 1.9 1.9 1.9 1.9 1.9 1.8 1.9 1.9 1.9 stk 02 

# • 0-25 13 .19 13 .18 13 .18 13 . 19 13 . 19 13 .18 13 .18 13 . 18 13 . 18 13 .18 13 .18 13.55 13.55 13 . 52 13 .47 13 . 80 16.53 15 . 74 14 . 89 13 . 98 13 .44 13 .4 5 13 .48 13 .47 13 .45 13.44 13. 4 8 13 .47 13
. 4 8 13 . 48 

### 02/25/2013 11046 NDx Mass Ib/hr 0

- 100 4.59 4.59 4.59 5.51 5.51 4.59 4.59 4.59 4.59 4 .59 4.59 5.51 5.51 5.51 5.53 3.60 0.22 1.10 1. 06 3.80 5.50 5.51 5.50 5.51 5.51 5.51 4.59 5.50 5.49 5.49 StkFlow kscfh 0-300000

21674 21652 21653 21673 21667 21646 21659 21652 21658 21652 21652 22742 22743 22667 2 2597 18437

9369 12891 16023 19979 2 2 373 22430 22506 22 4 80 22435 22417 22500 22 449 2 2 462 22469 Stk CO 

### ppm 0-1000

1.4 1.4 2.2 1.9 1.7 1.7 3 . 1 3.3 3.5 3.0 3.0 3.6 3.6 3.4 2.4 1.1 0.1 0.0 0.2 0.3 1.5 4.6 4 . 3 3.8 3.1 0.7 1.9 1.7 0.6 0.8 CO Mass 

### Ib/hr 0-100 1. 84 1. 84 3.67 2.75 2.75 2.75 4.59 5.51 5.51 4.59 4.59 5.51 5.51 5.51 3.69 1.44 0.00 0.00 0.00 0.76 2 . 75 7 . 34 7.34 6.42 5.51 0.92 2.75 2.75 0.92 0.92 

### NOx Rate Ib/mmBtu 0-1 0.005 0.005 0.005 0.006 0.00 6 0 . 005 0 . 005 0.005 0.005 0.005 0.005 0.006 0.006 0.00 6 0.006 0.005 0.001 0.003 0.002 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.006 

### Stk NOXc ppm 0-300 1. 45 1.45 1.45 1. 53 1. 53 1.45 1.45 1. 45 1. 45 1. 45 1.45 1.61 1. 53 1. 52 1. 51 1.41 0.41 0.69 0.59 1. 28 1. 66 1. 50 1.51 1. 51 1. 50 1. SO 1. 43 1. 51 1. 51 1. 51 Stk COc Gas 

### ppm 0

- 1000

1. 07 1. 07 1. 68 1. 45 1. 30 1. 30 2.37 2.52 2.67 2.29 2.29 2.89 2. 89 2. 72 1. 91 0.91 0.14 0.00 0 . 20 0.26 1.19 3. 64 3.42 3.02 2.46 0.55 1.51 1.35 0. 4 8 0.64 

### hscfh hscfh 0-10000 8742.6 8745.0 8745.6 8742.0 8739.6 8742.6 8748.0 8745.0 8747.4 8745.0 8745.0 8745.0 8745.6 8751.6 8784.0 6848.4 2142.0 3480.0 5038.2 7233.0 8731.8 8742.6 8736.6 8738.4 8744 . 4 8749.2 8734.2 8726.4 8719.8 8722.2 NH3Inj 

### 1b/hr 0-200 200.0 200.0 199.8 200.0 200.0 2 00.0 197.3 198.8 196.8 198.7 198.7 197.7 132.8 198 . 7 200.0 186 . 5

72.2 114.8 102.2 155.0 198.3 196.3 196.2 195.8 198.7 200.0 196.7 200.0 200.0 199.5 MW Lo 0-1 105 .. 105 . . lOS. : 105 .. 105. IDS .. 105. : lOS
.. 105 .. 105 .. 105. : lOS. : 105. : 105 .. 106 ..

70. : 11. 29 . . 51. : 85. 105 . 105 . . 105. 105. 106.1 IDS. 105. 106. ( lOS
. . 105. ! PagEGroup#-Channel# Long Descrip
. S hort Des cr ip
. Units Range 02/25/2013 10:19 02/25/2013 10:20 02/25/2013 10:21 02/25/2013 10:22 02/25/2013 10:23 02/25/2013 10:24 02/25/2013 10:25 02/25/2013 10:26 02/25/2013 10:27 02/25/2013 10:28 02/25/2013 10:29 02/25/2013 10:30 02/25/2013 10:31 02/25/2013 10:32 02/25/2013 10:33 02/25/ 2 013 10:34 02/25/2013 10:35 02/25/2013 10:36 02/25/2013 10:37 02/25/2013 10:38 02/25/2013 10:39 02/25/2013 10:40 02/25/2013 10:41 02/25/2013 10:42 02/25/2013 10:43 02/25/2013 10:44 02/25/2013 10:45 02/25/2013 10:46 02/25/2013 10:47 02/25/2013 10:48 02/25/2013 10:49 02/25/2013 10:50 02/25/2013 10:51 02/25/2013 10:52 02/25/2013 10:53 02/25/2013 10:54 02/25/2013 10:55 02/25/2013 10:56 02/25/2013 10:57 02/25/2013 10:58 

### Date/Time Printed : G45-C4 G45-C11 G45-C20 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass 5>StkFlow

2.6 2.2 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.8 1.9 1.8 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.8 1.8 1.8 1.8 1.9 1.8 1.8 1.8 Stk 02 % 0-25 13.47 13.47 13 . 47 13 .47 13 .48 13 .48 13 . 49 13 . 4 8 13.48 13 .48 13 .48 13 .47 13.48 13 .47 13. 4 7 13 .47 13 .48 13 .48 13 .48 13.48 13.48 13 . 48 13 . 48 13 .4 8 13 .47 13 .48 13 .47 13 .48 13.48 13. 4 7 13 . 48 13 .48 13.48 13 .48 13 .48 13 .49 13 .48 13 .4 8 13. 4 7 13.47 

### 02/25/2013 11046 NOx Mass lb/hr 0-100 7.33 5.50 5.51 5.51 5.51 5.51 5.50 5.50 5.50 4.59 5 .5 1 4.59 5.50 5.51 5.50 5.51 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.51 5.51 4.59 4.59 4.59 4.59 5.51 4.60 4.60 4.59 StkFlow kscfh 0-300000

22462 22455 22500 22492 22515 22515 22522 22493 22504 22518 22513 22478 22483 22489 22474 2 2485 22479 22486 22487 22496 22501 22484 22486 22506 22460 22489 22451 22475 22481 22471 22 517 22526 22526 22527 22532 22547 22521 22552 22520 22509 G4S-C3 G45-C13 G45

- C10 G4S-C6 G45

- C7 G4S-C8 G45-C18 G45-C 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXc 5>Stk COc 5>Gas Flow 5>NH3 Inj 5>MW La

Stk CO 

### ppm 0-1000

1.2 loS 3.4 3.9 4.0 3.1 3.1 2.7 2.3 2.8 3.0 2.8 2.3 2.6 2.S 2.3 2.4 2.3 2.6 2.9 2.3 2.S 2.6 2.9 2.7 2.S 2.S 2.3 2.S 2.8 3.1 3.3 3.1 3.4 3.0 3.3 2.9 3 . S 3.9 3.8 CO Mass lb/hr 0 -1 00 1. 83 2.75 5.51 6.43 6.42 5.51 5.50 4 . 58 3.67 4.59 4.59 4.59 3.67 4.59 3.67 3.67 3.67 3.67 4.58 4.59 3.67 3.67 4.58 4.59 4.58 3.67 3.67 3.66 3.67 4.59 5.51 5.51 5.51 5.51 4.59 5.51 4.59 5.52 6.43 6.43 NOx Rate lb/mmBtu 0-1 0.008 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.005 0.005 0.006 0 . 005 0.005 0.005 Stk NOXc 

### ppm 0

- 300 2.06 1. 75 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1.43 1. 51 1.43 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1.51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1.51 1. 51 1. 51 1. 51 1. 51 1. 43 1. 43 1.43 1.43 1. 51 1.43 1. 43 1. 43 Stk COc Gas 

### hscfh ppm 0-1000 0.95 1.19 2.70 3.10 3.18 2.46 2.47 2.15 1. 83 2.23 2.39 2.22 1. 83 2.06 1. 99 1. 83 1. 91 1. 83 2.07 2.31 1. 83 1. 99 2.07 2.31 2.14 1. 99 1. 99 1. 83 1. 99 2 . 22 2.46 2.62 2.46 2.70 2.39 2.63 2.31 2.78 3.10 3.02 

### hscfh 0-10000 8731. 2 8728.8 8746.2 8743.2 8740.2 8740.2 8731.2 8731.8 8736.0 8741.4 8739.6 8737 8 8727.6 8742.0 8736.0 8740.2 8726.4 8728.8 8729.4 8733.0 8734.8 8728.2 8728.8 8736.6 8730.6 8730.0 8727.0 8724.6 8727.0 8734.8 8740 . 8 8744.4 8744.4 8745.0 8746.8 8740.8 8742.6 8754.6 8754. 

## a 8749.8 NH3Inj 

### 1b/hr 0-200 171.7 198.5 196.2 197.0 197.3 197.2 197.3 197.0 199.0 198.0 197.0 198.0 197.5 197.5 198.3 197.3 196.7 196.8 196.3 196.7 197.7 196.5 196.0 196.5 195.8 196.2 196.5 196.7 194 . 8 196.7 196.0 196.7 196.5 196.2 196.7 195.3 196.8 196.5 1 95.8 194.8 S>Summary

- l-Min 

### RATA

- Continued MW Lo 0-1 105. : 105. : 105 .. 105 .. 105. : 105. : 105. : 106.1 105. : 105. 106 .• 105 .. 105.**~** 106.1 105 .**~** 105. : 105.: 105 .. 105. : 105. 105 . . 105. 105 . 105 .. 105 .. 105. : 105. 105 . . 106. 1 105. 106.1 105 . . 106 . 1 105. : 105. : 106.1 105. 105 .. 105. 105. : 

### Pagf

### Group#-Channel# Long Descrip
. Short Descrip. Units Range 02/25/2013 10;59 02/25/2013 11:00 02/25/2013 11:01 02/25/2013 11:02 02/25/2013 11:03 02/25/2013 11:04 02/25/2013 11:05 02/25/2013 11:06 02/25/2013 11:07 02/25/2013 11:08 

### Period Average Period Max Value Period Min Value Period Totals 

# = Period % Recovery

Date/Time Printed: G4S-C4 G45 -C 11 G45-C2 5>Stk N Ox Stk NOx 

### ppm 0-150 5>S tk 02 5>NOx Mass Stk 02 

# • 0-25 1.8 13.47 1.9 13.48 1.8 13.47 1.8 13.47 1.8 13.48 1.9 13.48 1.8 13.48 1.8 13.47 1.8 13.47 1.8 13.47 1.8 13.53 2.6 16.53 0.3 13.18 1.4690E+2 1.0825E+3 100.0 100 . 0

02/25/2013 11,46 NOx Mass 

### Ib/hr 0-100 4.59 5 . 51 4.60 4.60 4.59 5.52 4.60 4.59 4.60 4.59 5.00 7.33 0.22 3.9983E+2 100.0 G4S-C20 5>StkFlow

StkFlow



### kscfh 0-300000

22509 22544 22525 22528 22540 22555 22 552 22509 22519 22 514 21943 22743

9369 1.755 4E+6 100.0 G45

- C13 G45-C10 G4S -C 6 G45

- C3 5>Stk CO

Stk CO S>CO Mass S>NOx Rate 5>Stk NOXc 

### ppm 0-1000 CO Mass Ib/hr 0-100 3.8 6.43 3.5 5.51 4.2 6.44 3.9 6.44 4.2 6.43 3.7 6.44 3.7 6.43 3.9 6.43 3.4 5.51 3.8 6.43 2.7 4.33 4.6 7.34 0.0 0.00 2.1460E+2 3.4646E+2 100.0 100.0 NOx Rate Ib/mmBtu 0-1 0.005 0.006 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.005 0.006 0.008 0.001 4.4100E-1 100 . 0 Stk NOXc 

### ppm 0-300 1.43 1. 51 1. 43 1. 43 1. 43 1. 51 1. 43 1. 43 1. 43 1.43 1.46 2.06 0.41 1.1673E+2 100.0 G45-C7 G4S-C8 S>Stk COc S>Gas Flow

Stk COc Gas hscfh ppm hscfh 0-1000 0 -1 0000 3.02 2.78 3.34 3.10 3.34 2.94 2.94 3.10 2.70 3.02 2.13 3.64 0.00 1.7000E+2 100 . 0 8749.8 8751. 6 8755.8 8757.0 8749.8 8755.8 8754.6 8749.8 8753.4 8751.6 8503.8 8784.0 2142.0 6.8030E+5 100.0 G45-C18 S>NH3 Inj NH3Inj

Ib/hr 0-200 194.8 196.3 196.3 197.2 194.7 194.8 196.0 194.7 195.2 195.0 191.7 200.0

72.2 1.5332E+4 100.0



### S>Summary

- I-Min RATA

- Continued G45-C 5>MW La

MW La 0-1 105. 105 105.' 105.: 

### I DS .! 105.' 105.: 106 .1 105.: 106.1 102.2

106.

11. 8.1775E+ 100.

PagE

## Appendix B.1.2 Sentinel Unit 5 Ammonia, ROG and NOxlCO 

## Testing

R521 0729 

## 8·4

# Data Summary Report Company: CPV Sentinel, LLC 62575 Powerline Road 

### Desert Hot Springs, CA 92240 Source: Turbine 5 Data Group: Report Name: 

# 5lt'\ 

# fill(, 

# I**~** 

# 7:170**COVl\p';~"'<.** 

# TRACE Elw ironmenlai Syslems , lllc. 

# , I
Start of Report: 

### 5::>1-Min Cales s>Summary

- 1

- Min RATA 02/26/2013 08,30 End of Report, 02/26/2013 09,37 

### validation: All Available Data Group#-Channel# 

### Long Descrip. Short Descrip. 

### Units Range 02/26/2013 08:30 02/26/2013 08:31 02/26/2013 08:32 02/26/2013 08:33 02/26/2013 08:34 02/26/2013 08:35 02/26/2013 08:36 02/26/2013 08:37 02/26/2013 08:38 02/26/2013 08:39 02/26/2013 08:40 02/26/2013 08:41 02/26/2013 08:42 02/26/2013 08:43 02/26/2013 08:44 02/26/2013 08:45 02/26/2013 08:46 02/26/2013 08:47 02/26/2013 08:48 02/26/2013 08:49 02/26/2013 08:50 02/26/2013 08:51 02/26/2013 08:52 02/26/2013 08:53 02/26/2013 08:54 02/26/2013 08:55 02/26/2013 08:56 02/26/2013 08:57 02/26/2013 08:58 02/26/2013 08:59 

### Date/Time Printed: G45

- C4 G45-C11 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0

- 150 5 >Stk 02 5 >NOx Mass

1.4 1.4 1.4 1.4 1.5 1.5 1.5 1.4 1.4 1.5 1.4 1.5 1.5 1.6 1.6 1.6 1.7 1.7 1.6 1.7 1.7 1.8 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.5 Stk 02 % 0

- 25 14.07 14.06 14.06 14.07 14.08 14.07 14.06 14.07 14.06 14.06 14.07 14.07 14.06 14.06 14.06 14. OS 14.05 14.05 14.05 14.06 14.05 14.05 14.05 14.05 14.03 14.02 14.03 14.04 1 4.02 14.03
02/26/2013 10,13 NOx Mass Ib/hr 0

- 100 2.24 2.25 2.25 2.24 2.80 2.81 2.81 2.24 2.25 2.81 2.24 2.80 2.81 2.81 2.80 2.81 2.81 2.82 2.82 2.81 2.82 3.39 2.82 2.83 3.41 3.41 3.40 3.41 3.42 2.85 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

14953 14969 14953 14953 14953 14966 14976 14943 14976 14976 14939 14931 14964 14936 14916 14922 14936 14963 15003 14954 14963 15009 15001 15043 15063 15024 15031 15081 15077 15093 G45

- C3 5>Stk CO

Stk CO ppm 0

- 1000

0.2 0.2 0.1 0.1 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0 . 1 0.1 0.1 0.1 0.1 0.1 0.0 0.0 0.0 0.0 0 . 1 G4S - C13 G45

- C10 G45-C6 5>CO Mass 5>NOx Rate 5 >Stk NOXc

CO Mass 

### lb/hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NDx Rate 

### Ib/mmBtu 0-1 0.004 0.004 0.004 0.004 0.005 0.005 0.005 0.004 0.004 0.005 0.004 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.005 Stk NDXc 

### ppm 0-300 1. 21 l. 21 1. 21 l. 21 l. 30 l. 30 l. 29 l. 21 1.21 1.29 1.21 1.30 1. 29 1. 38 1. 38 l. 38 l. 46 l. 46 l. 38 l. 47 1.46 1.55 1.46 1.46 1. 55 1. 54 l. 55 1. 55 l. 54 1. 29 G45

- C7 G45

- C8 5>Stk COc 5 >Gas Flow



### Stk CDc Gas hscfh ppm hscfh 0-1000 0-10000 0.17 0.17 0.09 0.09 0.17 0.17 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.00 0.00 0.00 0.00 0.09 5343.0 5356.8 5350.8 5343.0 5335.2 5347.8 5359.2 5339.4 5359.2 5359.2 5338.2 5335.2 5355.0 5344.8 5337.6 5347.8 5352.6 5362.2 5376.6 5351.4 5362.2 5379.0 5376.0 5391. 0 5413.8 5407.8 5402.4 5412.6 5427.0 5424.6 G4S-C18 5>NH3 Inj NlBlnj

lb/hr 0

- 200 104.7 104 . 5 103.7 104.5 104 . 3 103.7 103.8 105.0 103.8 104.7 104.3 103.8 103.8 102.8 102.8 103.0 102.8 104.2 104.3 104.3 104.5 103.8 105.7 106.3 107.7 107.5 108.7 108.8 109.2 108.3 G45-C 5>MW 

### Lo

MW Lo 0

- 1 54. ( 54. ( 54. ! 54. ! 53 .. 54. 1 54. ( 54. ! 54. ( 54. ! 54. ( 53. : 54.J 54. ! 53 .. 54. ! 54. : 54 .. 54. ' 54. ( 54. ! 54. ! 54 .. 54. 55. ( 55. ( 54. : 55. ( 55 .J 55. ( pagE

### Group#-Channel# Long Descrip. Short Descrip. Units Range 02/26/2013 09:00 02/26/2013 09:01 02/26/2013 09:02 02/26/2013 09:03 02/26/2013 09:04 02/26/2013 09:05 02/26/2013 09:06 02/26/2013 09:07 02/26/2013 09:08 02/26/2013 09:09 02/26/2013 09:10 02/26/2013 09:11 02/26/2013 09:12 02/26/2013 09:13 02/26/2013 09:14 02/26/2013 09:15 02/26/2013 09:16 02/26/2013 09:17 02/26/2013 09:18 02/26/2013 09:19 02/26/2013 09:20 02/26/2013 09:21 02/26/2013 09:22 02/26/2013 09:23 02/26/2013 09:24 02/26/2013 09:25 02/26/2013 09:26 02/26/2013 09:27 02/26/2013 09:28 0 2 /26/2013 09:29 02/26/2013 09:30 02/26/2013 09:31 02/26/2013 09 :3 2 02/26/2013 09:33 02/26/2013 09:3 4 02/ 26 /2013 09:35 02/26/2013 09:36 02/26/2013 09:37



### Date/Time Printed: G45-C4 G45-C11 G45-C2 5>Stk NOx

Stk NOx 5>Stk 02 5>NOx 

### Mass ppm 0-150

1.6 1.6 1.7 1.6 1.6 1.6 1.6 1.6 1.7 1.7 1.7 1.7 1.7 1.6 1.6 1.7 1.6 1.6 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.7 1.7 1.7 1.7 1.7 1.7 1.7 Stk 02 

# • 0-25 14.01 14.02 14.02 14.03 14.04 14.03 14.02 14.03 14.03 14.02 14.02 14 . 02 14 . 02 14.02 14.02 14.02 14.03 14.04 14.03 14.02 1 4. 02 14.03 14.04 14.04 14 . 04 1 4. OS 14.05 14.04 14.03 14.03 14.03 14.02 14.02 14.02 14.02 14.03 14.03 14.03

02/26/2013 10,13 NOx 

### Mass 

### Ib/hr 0-100 2.85 2.85 2.85 2.84 2.83 2.84 2.85 2.84 2.85 2.85 2.85 2.84 2.85 2.84 2.84 2.84 2.84 2.83 2.83 2.83 2.84 2.83 2.82 2.82 2.82 2.82 3.37 3.39 3.38 3.39 3.39 2.83 2 .8 3 2.83 2.83 2.83 2.83 2.83 G45-C20 5>StkFlow

StkFlow



### kscfh 0-300000

15077 15071 15094 15034 15033 15046 15062 15063 15096 15057 15067 15047 15059 15029 15051 15042 15033 15041 15021 14996 15007 15006 14964 14973 1 4 944 14971 14931 14976 14946 14971 14961 14962 14962 14962 14962 15002 15002 15002 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000

0.1 0.2 0.2 0 . 2 0.2 0.2 0.2 0 . 2 0.2 0 . 2 0 .2 0.2 0.2 0.2 0.2 0.2 

## o 2 0.2 0.2 0.2 0 . 2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0 .1 0.2 0.2 0 .2 0.2 0 .2 0.2 0.2 0.2 0.2 G45-C13 G45-C10 G45-C6 5>CO 

### Mass 5>NOx Rate 5>Stk NOXc

CO 

### Mass lb/hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0.00 0.00 0 . 00 0.00 0 . 00 0.00 0.00 0.00 0.00 NOx Rate lb/mmBtu 0-1 0.005 0.005 0 . 005 0.005 0.005 0.005 0 . 005 0.005 0.005 0.005 0.005 0 . 005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0 . 005 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0 . 005 0.005 0 . 005 0.005 0.005 Stk NOXc 

### ppm 0-300 1. 37 1. 37 1. 46 1.37 1.38 1.37 1.37 1.37 1. 46 1. 46 1.46 1.46 1.46 1.37 1.37 1.46 1. 37 1. 38 1.46 1.46 1.46 1. 46 1. 46 1. 46 1. 46 1.46 1.55 1. 55 1. 55 1. 55 1. 55 1.46 1.46 1.46 1. 4 6 1. 46 1.46 1.46 G45-C7 G45-C8 5>Stk COc 5>Gas Flow

Stk COc Gas hscfh 

### ppm hscfh 0-1000 0-10000 0.09 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 0.17 0.17 0.17 0.17 0 . 17 0 . 17 0.17 0.17 0.17 0.17 0.09 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 5434.8 5424.6 5433.0 5403.6 5395 . 2 5407.8 5421.6 5413 .8 5425 .8 5419 . 8 5423.4 5416.2 54 2 0.4 5409 . 6 5417 . 4 5414.4 5403.0 5398.2 5398.8 5397.6 540 1.8 5393.4 5370 . 6 5373.6 5363.4 5365 .2 5350.8 5374.8 5371. 8 5380.8 5377.2 5385 . 6 5385.6 5385.6 5385.6 5392.2 5392.2 5392.2 G45-C18 5>NH3 Inj NH3lnj



### lb/hr 0-200 105.5 103.3 102 . 8 103.2 102.5 103.2 103.7 102.5 102.3 102.5 102.3 102.0 102 . 7 103.0 102.5 102.3 102.8 102.5 102.5 101. 3 101.3 101.2 101.2 101. 3 101.8 101.3 101.2 101.2 100.8 101.2 101. 5 102.5 102.5 102.5 102.5 101.8 101. 8 101.8


### S>Summary - I

- Min RATA

- Continued G45-C 5>MW 

### Lo

MW 

### Lo 0-1 55.: 55. : 55.

- 55. ( 55. ( 55. ( 55.1 55. ( 55.1 55. ( 55. : 55.1 55. : 55.1 55.1 55 .1 55.1 55.1 55.1 55 . 1 55. ! 55. ( 54 .. 54. ' 54. 54 .. 54 54 .. 54.: 54. : 54. : 54. : 54. : 54. : 54. : 54. : 54. : 54. :

PagE

### Period Average = 1.6 14.04 2 .86 15000 0. 2 0.00 0 . 005 1.41 0.13 538 4 .0 103 . 4 54.6 

### Period Max Value 1. 8 14.08 3.42 15096 0.2 0.00 0 . 006 1. 55 0 . 17 5434 . 8 109.2 55. 

### Period Min Value 1. 4 1 4. 01 2. 2 4 1491 6 0.0 0.00 0 . 00 4 1. 21 0.00 5335.2 100 . 8 53. 

### Period Totals = 1.1170E+2 9.54 6 7E+2 1 . 9 4 51E+2 1 . 019 9 E+6 1.0400E+l O . OOOOE+O 3.4400E-l 9 . 6060E+l 8 . 9600E+0 3.6611E+5 7.0341E+3 3.7129E+ 

### Period % Recovery 100 . 0 100 . 0 100 . 0 100 . 0 100.0 100 . 0 100 . 0 100 . 0 100.0 100.0 100.0 100 .

# Data Summary Report Company : 

### CPV Sentinel, LLC 62575 Powerline Road Desert Hot Springs , CA 92240

# 5~+;1\(,\**~** t]1)'J"



# CJ>Mp. 2. Source : Data Group: Report Name: 

### Start of Report: 

### Turbine 5 

### 5>1-Min Cales S>Summary

- I-Min RATA 02/26/2013 10,00 G45-C4 

### End of Report, 02/26/2013 11,09 G45-Cl1 G45-C13 

# TRACE E,wirollmenlal 

## Systems , [IIC.

Va lidation : All Available Data G4S-CIO G45-C6 G45-C7 G45-C8 

### Group#-Channel# 

### Long Descrip . 

### Short Descrip. Units G45-C2 5>Stk NOx

stk NOx 

### ppm 0-150 5>Stk 02 S>NOx Mass G45-C20 

### 5>StkFlow



### StkFlow

kscfh 0-300000 G45-C3 s>Stk CO

Stk CO 

### ppm 0-1000 

### S>CO Mass 5>NOx Rate s>Stk NOXc 5>Stk COe S>Gas Flow G45-C18 5>NH3 Inj NH3Inj



### Ib/hr 0-200 G45-C 

### 5>MW Lo

MW Lo 

### Range 02/26/2013 10;00 02/26/ 2 013 10 ; 01 02/26/2013 10;02 02/26/2013 10 ; 03 02/26/2013 10;04 02/26/2013 10;05 02/26/2013 10;06 02/26/2013 10:07 02/26/2013 10;08 02/26/ 2 013 10:09 02/26/2013 10:10 02/26/2013 10:11 02/26/2013 10:12 02/26/2013 10;13 02/26/2013 10;14 02/26/2013 10;15 02/26/2013 10:16 02/26/2013 10,17 02/26/2013 10:18 02/26/2013 10:19 02/26/2013 10 : 20 02/26/2013 10:21 02/26/2013 10;22 02/26/ 2 013 10:23 02/26/2013 10:24 02/26/2013 10,25 02/26/2013 10:26 02/26/2013 10;27 02/26/2013 10:28 02/26/2013 10:29 

### Date/Time Printed : 1.7 

### loB 1.8 

### loB 1.8 1.7 1.7 

### loB 1.8 1.8 1.8 1.8 

### loB 1.8 1.8 1.9 1.9 1.8 1.8 1.8 1.8 1.9 1.9 

### loB 1.8 

### loB 1.8 1.8 1.8 1.8 Stk 02 

# • 0-25 14.00 14.01 14.01 14.01 14.01 1 4. 00 14.00 14.00 14.00 14 . 00 14.00 1 4.01 14.01 14.01 14.01 14.01 14.01 14.02 14.02 14.02 14.0 2 14.02 14.0 2 14.02 1 4. 02 14.02 14.02 14.02 14.02 14 . 02 

### 02/26/2013 11,31 NOx Mass 

### 1b/hr 0-100 2.88 3.43 3.43 3.43 3.43 2 . 88 2.88 3.44 3.44 3.44 3.44 3.42 3.42 3 . 42 3.42 3.43 3.43 3.41 3.41 3.41 3.41 3.40 3.40 3 . 43 3.43 3.43 3.43 3. 4 1 3.41 3.41 15190 15122 15122 15122 15122 15220 15220 15112 15112 15112 15112 15055 15055 15055 15055 15089 15089 15044 15044 15044 150 44 15004 15004 15124 15124 15124 15124 15021 150 2 1 15021 0.2 0.2 

### 0.2 0. 2 

### 0.2 0 . 2 

### 0 .2 0.2 

### 0.2 0.2 

### 0.2 0.2 

### 0.2 0.2 

### 0.2 0 .2 

### 0.2 0.2 

### 0 .2 0.2 

### 0.2 0.2 

### 0.2 0.2 

### 0.2 0.2 

### 0.2 0.2 

### 0 . 2 0.2 

### CO Mass Ib/hr 0-100 0.00 0.00 0.00 0.00 0.00 0 .00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0 . 00 0.00 0 . 00 0.00 0.00 0.00 0.00 0 . 00 0.00 0 . 00 0.00 0 . 00 0.00 0.00 0.00 

### NOx Rate Ib/mmBtu 0-1 0.005 0 . 006 0.006 0 . 006 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.006 0 . 006 0.006 0.006 0 . 006 0 . 006 0.006 0.006 0.006 0 . 006 0.006 0 . 006 0.006 0.006 0.006 

### Stk NOXc 

### ppm 0-300 1. 45 1. 54 1. 54 1. 54 1. 54 1. 45 1. 45 1.54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 63 1. 63 1. 54 1.54 1. 54 1. 54 1. 63 1. 63 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 Stk COe Gas 

### ppm 0-1000 0 .1 7 0 . 17 0.17 0 . 17 0 . 17 0.17 0.17 0.17 0 . 17 0.17 0 . 17 0.17 0.17 0 . 17 0.17 0.17 0 . 17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 

### hscfh hscfh 0-10000 5 4 83 .4 5451. 0 5451.0 5451 . 0 5451. 0 5494.2 5494.2 5 4 55 . 2 5455.2 5455.2 5455.2 5427.0 5427.0 5427 . 0 5427.0 5439.0 5439.0 5415.0 5415.0 5 4 15.0 5415.0 5400.6 5400.6 5443.8 5443 .8 5443.8 5443.8 5406.6 5406.6 5406.6 101.5 100.8 100.8 100 . 8 100.8 103.2 103.2 101.5 101. 5 101 . 5 101.5 101. 2 101. 2 101.2 101. 2 101.7 101.7 102.0 102.0 102.0 102 . 0 101.2 101.2 102.5 102 . 5 102.5 102.5 103 . 2 103.2 103 . 2 0-1 56 . 1 55. 55. : 55. : 55. 56 .. 56 .. 56. ! 56.1 56. ( 56.1 5S. : 55 . 55 . 55. : 55 .. 55 .. 55 .. 55 .. 55 .. 55 .. 55 .. 55. : 56.1 56 . ( 56.1 56. ( 55. ! 55. ! 55. ! 

### PagE

### G ro up#-Chann e l # Long Descrip
. Sho r t Descri p. Units Range 02/26/2013 10:30 02/26/2013 10:31 02/26/2013 10:32 02/26/2013 10:33 02/26/2013 10:34 02/26/2013 10:35 02/26/2013 10:36 02/26/2013 10:37 02/26/2013 10:38 02/26/2013 10:39 02/26/2013 10:40 02/26/2013 10:41 02/26/2013 10:42 02/26/2013 10:43 02/26/2013 10:44 02/26/2013 10:45 02/26/2013 10:46 02/26/2013 10:47 02/26/2013 10;48 02/26/2013 10:49 02/26/2013 10:50 02/26/2013 10:51 02/26/2013 10:52 02/26/2013 10:53 02/26/2013 10:54 02/26/2013 10:55 02/26/2013 10:56 02/26/2013 10:57 02/26/2013 10:58 02/26/2013 10:59 02/26/2013 11:00 02/26/2013 11:01 02/26/2013 11:02 02/26/2013 11:03 02/26/2013 11:04 02/26/2013 11:05 02/26/2013 11:06 02/26/2013 11:07 02/26/2013 11:08 02/26/2013 11:09 

### Date/Time Printed: G45-C4 G45-C11 G45-C2 5>Stk NOx

Stk NOx ppm 0-150 5>Stk 02 5>NOx Mass

1.8 2.0 2.0 1.9 1.9 1.. 1.. 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.. 1.. 1.8 stk 02 

# • 0-25 14.02 14 .02 14.02 14.02 14.02 14.02 14.02 14.04 14.04 14.03 14.03 14.04 14.04 14.05 14.05 14.05 14.05 14.05 14.05 14.04 14 .04 14.04 14.04 14.02 14.02 14.02 14.02 14.02 14.02 14.03 14.03 14.03 14.03 14.03 14.03 14.03 14 . 03 14.02 14.02 14.02 02/26/2013 11,31 NOx Mass 

### 1b/hr 0

- 100 3.41 3.41 3.41 3.40 3.40 3.40 3.40 3.38 3.38 3.39 3.39 3.37 3.37 3.36 3.36 3.36 3.36 3.37 3.37 3.36 3.36 3.36 3.36 3.39 3.39 3 . 39 3.39 3.39 3.39 3.39 3.39 3.38 3.38 3.38 3.38 3.39 3.39 3.39 3.39 3.39 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

15021 15019 15019 14987 14987 14987 14987 14957 14957 14971 14971 14921 14921 14901 14901 14901 14901 14917 14917 14867 14867 14867 14867 14961 14961 14961 14961 14939 14939 14962 14962 14939 14939 14936 14936 14964 14964 14969 14969 14962 G45-C3 5>Stk CO

Stk CO ppm 0-1000

0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.2 0.2 0.2 0.2 0.1 0.1 0.2 0.2 0.2 0.2 0.2 0.2 0.2 G45-C13 G45-C10 G45

- C6 5>CO Mass 5>NOx Rate s>Stk NOXc

CO Mass Ib/hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NOx Rate lb/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 Stk NOXc ppm 0-300 1. 54 1. 72 1. 72 1. 63 1. 63 1. 63 1. 63 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1.55 1.55 1. 55 1. 55 1. 55 1.55 1. 55 1. 55 1. 55 1. 55 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 63 1. 63 1. 54 G45-C7 G45-C8 5>Stk COc 5>Gas Flow

Stk COc Gas hscfh ppm 0-1000 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.17 0.17 0.17 0.17 0.09 0.09 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 hscfh 0

- 10000 5406.6 5406.0 5406.0 5394.6 5394.6 5394.6 5394.6 5368.2 5368.2 5380.8 5380.8 5355.0 5355.0 5340.0 5340.0 5340.0 5340.0 5346.0 5346.0 5335.8 5335.8 5335.8 5335.8 5385.0 5385.0 5385.0 5385.0 5377.2 5377.2 5377.8 5377.8 5369.4 5369.4 5368.2 5368.2 5378.4 5378.4 5388.0 5388.0 5385.6 G45-C18 5>NH3 Inj NH3Inj



### 1b/hr 0-200 103.2 102.3 102.3 101. 7 101.7 101.7 101. 7 101. 3 101. 3 102.8 102.8 102.5 102.5 102.5 102.5 102 . 5 102.5 102.5 102.5 103.2 103.2 103.2 103.2 103.7 103.7 103.7 103.7 104.2 104.2 103.2 103.2 104.2 104.2 104.5 104.5 103.7 103.7 102.8 102.8 103.7 

### S>Summary

- I-Min RATA

- Continued G45

- C 5>MW 

### Lo

MW La

0-1 S5 .**~** 55.: 55.' 55.1 55.1 55.1 55.1 55.1 55.1 55.1 55.1 54 .. 54 . . S4.: 54 .. 54. : S4. : 54. 54 .. 54 . . 54 . . S4 . . 54 . . 55 .. 55 .. 55.: 55 .. 5S .1 55.1 S5.: 55 55.1 55.1 5S .1 5S .1 55.1 5S .1 S5.1 55.1 55.**pag~**

### Period Average = 1.8 14.02 3.38 15008 0.2 0.00 0.006 1. 56 0.16 5399.8 102.5 55.2 

### Period Max Value 2.0 14 . 05 3.44 15220 0.2 0.00 0.006 1. 72 0.17 5494.2 104.5 56. 

### Period Min Value 1.7 14.00 2.88 14867 0.1 0.00 0.005 1.45 0.09 5335.8 100.8 54. 

### Period Totals 

# = 1 . 2710E+2 9.8160E+2 2.3637E+2 1.0505E+6 1.2800E+1 O.OOOOE+O 4.1700E-1 1.0903E+2 1.0940E+1 3.7798E+5 7.1746E+3 3.8682E+ 

### Period % Recovery 100.0 100 . 0 100.0 1 00.0 100.0 100.0 100 . 0 100.0 100.0 100 . 0 100.0 100 .

# Data Summary Company:

Source: Data Group: Report Name: Start of Report : 

# Report CPV Sentinel, LLC 62575 Powerline Road Desert Hot Springs, CA Turbine 5 S>l-Min Cales S>Summary

- I-Min RATA 02/25/2013 16,42 G45-C4 

### 92240 

# 5el\+i1K. \ 

# 5**~** 

# ('\i(..ru \

# ~~~ 

# -:wiD End of Report , 02/25/2013 17 ,4 8 G45-Cll G4S -C13 

# TRACE
ElIlJ ;rolllllelllal 

## Systems , Illc.

Validation: All Available Data G45-CIO G45

- C6 G45-C7 G4S-C8 

### Group#-Channel# Long Descrip. Short Descrip
. Units G4 5-C 2 5>Stk NOx

Stk NOx 

### ppm 0-150 s>St k 02 5>NOx Mass G45-C20 5>StkFlow



### StkFlow

kscfh 0-300000 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000 5>CO Mass 5>NOx Rate S,Stk NOXc 

### S>Stk CDc S>Gas Flow 

### Stk CDc 

### Gas hscfh G45-C18 5>NH3 Inj NH3Inj



### 1b/hr 0-200 G45-C 

### 5>MW Lo

MW Lo 

### Range 02/25/2013 16:42 02/25/20 13 16 :43 02/25/ 2013 16 :44 02/25/2013 16:45 02/25/2013 16:46 02/25/2013 16:47 02/25/2013 16:48 02/2 5/2013 16:49 02/25/2013 16:50 02/25/20 13 1 6:51 02/25/201 3 16:52 02/25/2013 16:53 02/25/2013 16:54 02/ 2 5/2013 16:55 02/25/2013 16:56 02/25/201 3 16:57 02/25/2013 16 :58 02 / 25/2013 16:59 02/25/2013 17:00 02/25/2013 17:01 02/25/2013 17:02 02/25/2013 17:0) 02/25/2013 17:04 02/25/2013 17:05 02/25/ 2013 17:06 02/25/2013 17:07 02/25/20 13 17:08 02/25/2013 17:09 02/25/2013 17:10 02/25/2013 17:11 

### Date/Time Printed: 1.2 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1., 1., 1., 1.4 1.. 1., 1., 1., 1., 1., 1.' 1., 1.5 1.5 1.5 1.5 1.5 1.6 1.5 1.5 1.6 1.5 Stk 02 

# , 0-25 13.91 13.91 13.90 13.90 13. 90 13.89 13. 88 13.88 13.88 13.89 13.89 13.88 13 .89 13.89 13.89 13.89 13.90 13.89 13.88 13.88 13.86 13 .89 13.88 13 .86 13.86 13.89 13.88 13 .86 13.87 13.86 

### 02/25/2013 18,46 NOx Mass 

### 1b/hr 0

- 100 2.94 2.93 2.94 2.93 2.94 2.96 2 .96 2.97 2.97 2.96 2.96 2.97 2.96 2.96 2.94 2.95 2.94 2.95 2.95 2.95 3.71 3.67 3.70 3.72 3.73 3.70 3.70 3.71 3.70 3.7 1 19140 19108 19136 19080 19139 19195 19207 19224 19258 19213 19238 19232 19189 19200 19117 19145 19084 19141 19140 19144 19188 19069 19196 19239 19281 19190 19214 19187 19178 19193 0. ' 0.' 0.' 

### D.' 0.' 

### 0.3 0.3 0.3 0.3 

### A.' 0.4 0.' 0.' 0.' 

### A.' 0.' 0.' 0.' 

### 0.8 1.8 

### 3.3 2.5 1.8 

### 3.0 6.0 2.8 

### 2.3 '.9 1.9 

### 3.0 CO Mass 1b/hr 0-100 0.74 0 .7 3 0.74 0.73 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.73 0.74 1. 48 2.21 4.4 5 3.67 2.22 4.46 8.20 3.70 2.96 6.68 2.96 4.45 

### NOx Rate Ib/mmBtu 

### 0-1 0.004 0.004 0.004 0.004 0.004 0.00 4 0.004 0.004 0.004 0.00 4 0.00 4 0.00 4 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.005 0.005 0.005 0.005 0.00 5 0.00 5 0.005 0.005 0.005 0.005 Stk NOXc 

### ppm 0

- 300 1. 01 1.10 1.10 1.10 1.10 1.09 1. 09 1. 09 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1. 26 1. 26 1.26 1.26 1. 26 1. 35 1. 26 1. 26 1. 34 1. 26 

### ppm hscfh 0-1000 0

- 10000 0.34 0.34 0.34 0.34 0.34 0.25 0.25 0 . 25 0.25 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.34 0.67 1. 51 2.77 2.10 1.51 2.51 5.03 2.36 1. 93 4.11 1. 59 2.51 6999.6 6987.6 7008.0 6987.6 7009.2 7039.8 7054.2 7 060.2 7072.8 7046.4 7055.4 7063.2 7037.4 7041.6 7011.0 7021.2 6988.8 7020.0 7029.6 7030.8 7067.4 6993.6 7050.0 7086.0 7101.6 7038.0 7056.6 7066.8 7053.6 7069.2 148.2 149.0 149.5 148 . 3 149.5 149.2 148 . 7 149.3 148.2 147.7 147.5 147. 7 146.2 147 . 3 144. 7 145.3 145. 7 145.7 140.5 135.0 132.8 131.8 134.8 133.0 128.8 134.7 133.8 129.2 133.8 131.3 

### 0-1 80.! 80. ! 80. ! 80.: 80.1 80. ! 80 .. 81.1 81.1 81.1 81.1 81.1 80. : 80 .. 

### 80. 80. : 80.1 80.: 80.1 80 .. 80. ! 79. i 80.1 80. : 80. : 80. : 80. : 80. i 80. ! 80. i 

### PagE

### Group#-Channel # Long Descrip . Short Des c r i p . Units Ra n ge 02/25/2013 17:12 02/25/2013 17:13 02/25/2013 17:14 02/25/2013 17:15 02/25/2013 17:16 02/25/2013 17:17 02/25/2013 17:18 02/25/2013 17:19 02/25/2013 17:20 02/25/2013 17:21 02/25/2013 17:22 02/25/2013 17:23 02/25/2013 17:24 02/25/2013 17:25 02/25/2013 17:26 02/25/2013 17:27 02/25/2013 17:28 02/25/2013 17:29 02/25/2013 17:30 02/25/2013 17:31 02/25/2013 17:32 02/25/2013 17:33 02/25/2013 17:34 02/25/2013 17:35 02/25/2013 17:36 02/25/2013 17:37 02/25/2013 17:38 02/25/2013 17:39 02/25/2013 17:40 02/25/2013 17:41 02/25/2013 17:42 02/25/2013 17:43 02/25/2013 17:44 02/25/2013 17:45 02/25/2013 17:46 02/25/2013 17:47 02/25/2013 17:48



### Date/Time Printed: G45-C4 G45-C11 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass

1.6 1.6 1.6 1.6 1.5 1.6 1.6 1.6 1.6 1.7 1.6 1.7 1.7 1.7 1.7 1.8 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.8 1.8 1.7 Stk 02 

# • 0-25 13.86 13.87 13.87 13.87 13.86 13.86 13.86 13.86 13.85 13.85 13.85 13.84 13.84 13.82 13.82 13.82 13.84 13.86 13.85 13.84 13.84 13.84 13.85 13.84 13.84 13.84 13.85 13.84 13.84 13.84 13 . 84 13.84 13.84 13.83 13.83 13.83 13.83

02/25/2013 18,46 NOx Mass 

### lb/hr 0-100 3.72 3.72 3.71 3.71 3.71 3.72 3.72 3.73 3.72 3.73 3.73 3.74 3.74 3.75 3.75 4.50 3.73 3.72 3.72 3.73 3.73 3.73 3.72 3.74 3.73 3.74 3.73 3.74 3.74 3.73 3.74 3.75 3.75 3.75 4.51 4.51 3.76 G45-C20 5 >StkFlow

StkFlow

ksefh 

### 0

- 300000

19226 19276 19226 19217 19203 19218 19216 19275 19189 19239 19261 19264 19266 19265 19262 19273 19223 19219 19225 19238 19223 19220 19233 19277 19251 19301 19249 19301 19298 19256 19275 19314 19329 19316 19346 19339 19357 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000

.3.6

2.9 2.3 2.1 2.7 2.8 2.1 2.1 2.3 2.0 2.7 2.3 2.1 2.9 2.7 2.3 2.3 2.4 2.3 2.3 2.0 2.2 2.3 2.2 2.0 2.3 2.1 2.1 2.3 2.9 

### 3.1 2.6 2.6 2.6 2.8 

### 3.1 2.9 G45-C13 G45

- C10 G45-C6 5>CO Mass 5>NOx Rate 5>Stk NOXe

CO Mass 

### lb/hr 0-100 5.20 3.72 2.97 2.97 3.71 3.72 2.97 2.98 2.97 2.98 3.73 2.99 2.99 3.75 3.75 3.00 2.98 3.72 2.98 2.98 2.98 2.98 2.98 2.99 2.99 2.99 2.98 2.99 2.99 3.73 4.49 3.75 3.75 3.75 3.76 4.51 3.76 NOx Rate lb/mmBtu 

### 0

- 1 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.005 Stk NOXe 

### ppm 0-300 1. 34 1. 34 1. 34 1. 34 1. 26 1. 34 1. 34 1. 34 1. 34 1. 42 1. 34 1. 42 1. 42 1. 42 1.42 1. 50 1.42 1.42 1.42 1.42 1.42 1. 42 1.42 1.42 1. 42 1. 42 1. 42 1. 42 1. 42 1. 42 1.42 1.42 1.42 1.42 1. 50 1. 50 1.42 G45-C7 G45-C8 5>Stk COe 5>Gas Flow

Stk COe Gas hsefh 

### ppm hscfh 0-1000 0-10000 3.02 2.43 1. 93 1. 76 2.26 2.35 1. 76 1. 76 1.92 1. 67 2.26 1. 92 1. 7S 2.42 2.25 1. 92 1. 92 2.01 1. 92 1. 92 1. 67 1. 84 1. 92 1. 84 1. 67 1. 92 1. 76 1. 75 1. 92 2.42 2.59 2.17 2.17 2.17 2.34 2.59 2 . 42 7081. 2 7089.6 7071.0 7068.0 7072.8 7078.2 7077.6 7099.2 7077.6 7096.2 7104.0 7115.4 7116.0 7135.8 7134.6 7138.8 7100.4 7078.8 7090.8 7105.8 7100.4 7099.2 7093.8 7120.2 7110.6 7129.2 7099.8 7129.2 7128.0 7112.4 7119.6 7134.0 7139.4 7144.8 7155.6 7153.2 7159.8 G45-C18 5>NH3 Inj NH3Inj



### lb/hr 0

- 200 132.2 132.3 133.5 132.8 132.3 132.3 134.2 133.8 133.2 134.0 133.3 133.7 135.2 131. 0 132.5 133.5 132. S 133.0 132.0 133.3 133.0 133.2 131.7 133.7 132.2 134.5 133.7 133.0 134.0 132.2 132.5 132.8 132.7 131.8 132.3 132.2 133.0



### S>Summary

- I-Min RATA

- Continued G45-C 5>MW 

### Lo

MW La 

### 0-1 80 .**~** 81.1 81.1 80 .. 80.! 80. : 80. 81.1 80. ! 81.1 80. : 81.1 81.1 81.: 81.1 81.1 80.! 80.: 80.! 80 .. 81.1 80 .. 80 . . 81.1 81.1 81. . 80. ! 81.1 81.1 80. : 81.1 80. : 81.: 81.1 81. . 81.: 81.:

PagE

### Period Average 

# = 1.6 13 . 8 6 3. S3 19223 2.0 2.78 0.005 1. 31 1. 65 7077.7 137.0 80.6 

### Period Max Value 1.8 13.91 4.51 19357 6.0 8.20 0.00 6 1. 50 5.03 7159.8 149.5 81. 

### Period Min Value 1.2 13 .82 2.93 19069 0.3 0.73 0 . 004 1. 0 1 0.25 6987.6 128.8 79. 

### Period Totals 

# = 1. 0440E + 2 9.2878E+2 2.3648E+2 1.287 9 E + 6 1.3220E+2 1.8616E+2 3.1800E-1 8.7510E + 1 1.1067E+2 4.7420E+5 9 . 1763E+3 5.4056E+ 

### Period 

### % Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100 . 0 100.0 100.0 100.

# Data Summary Report Company : CPV Sentinel, LLC 62575 Powerline Road 

### Desert Hot Springs, CA 92240 Source : TUrbine 5 Data Group : Report Na me: 

### Start of Report : 5>1-Min Cales S >S ummary - I-Min RATA 02/25/2013 18,07 

# 5eA,'N-\**~** 

# 1-'7'1# C-p**\~1A14.{.** 

# z..**~**

# rA- (2y.Y\ 

# {o

End of Report, 02/25/2013 19,14 G45-C 4 G45-Cll G45-C20 G45-C3 G45 - C13 

# TRACE Envi ro nm e nt a l S y s t e lll s, In c.

validation: All Available Data G45

- CIO G45-C6 G45-C7 G45

- C8 G45-CIB G4S-C 

### Group#-Channel# Long Descrip. Short Descrip. Units G45-C2 S>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass 5>StkFlow 5>Stk CO 5>CO Mass S:>NOx Rate 5>Stk NOXc S>Stk CDc 5>Gas Flow 5>NH3 Inj 5>MW La 

### Range 02/25/2013 18;07 02/25/2013 18:08 02/25/2013 18:09 02/25/2013 18:10 02/25/2013 18;11 02/25/2013 18:12 02/25/2013 18:13 02/25/2013 18:14 02/25/2013 18:15 02/25/2013 18:16 02/25/2013 18:17 02/25/2013 18:18 02/25/2013 18:19 0 2 /25/2013 18:20 02/25/2013 18:21 02/25/ 2 013 18:22 02/25/2013 18:23 02/25/2013 18:24 02/25/2013 18:25 02/25/2013 18:26 02/25/2013 18:27 02/25/2013 18:28 02/25/20 1 3 18:29 02/25/2013 18:30 02/25/2013 18:31 02/25/2013 18:32 02/25/2013 18:33 02/25/2013 1 8:34 02/ 2 5/ 2 013 18:35 02/25/2013 18:36 

### Date/Time Printed: 1.7 1.7 1.7 1.7 1.7 1.7 1.6 1.6 1.7 1.7 1.7 1.7 1.6 1.7 1.7 1.7 1.8 1.8 1.7 1.7 1.7 1.7 1.8 1.7 1.8 1.7 1.8 1.8 1.8 1.8 Stk 02 

# • 0-25 13.86 13 . 87 13 . 87 13.87 13 .87 13.88 13.87 13.87 13.87 13 . 87 13 . 86 13 . 87 13 . 88 13. 8 8 13.87 13.88 13.88 13.88 13 . 89 13.88 13.89 13 . 88 13.88 13.88 13 . 88 13 . 88 13 . 88 13 . 89 13. 8 8 13. 8 9
02/25/2013 20,45 

### NOx Mass Ib/hr 0-100 3.72 3.72 3.71 3.71 3.71 3.70 3.71 3.72 3.70 3.71 3.72 3.72 3.72 3.72 3.73 3.71 4.47 4.45 3.70 3.71 3.71 3.71 4.46 3.72 4.47 3.73 4.47 4.46 4. 4 6 4.47 

### StkFlow kscfh 0 -3 00000

19237 19258 19226 19203 19226 19196 19196 19242 19170 19221 19228 19289 19281 19312 19302 19251 19302 19250 19231 19240 19256 19220 19268 19300 19300 19328 19309 19316 19268 19334 Stk CO 

### ppm 0-1000

3.4 2.8 2.8 2.3 3.8 3.3 3.0 4.2 3.6 3.9 3. 4 3.4 4 . 1 4.1 5.3 4.1 3.7 2.8 3.4 3.8 3.2 3.5 3 . 0 3.9 3.6 4.0 3.7 2.4 3 . 6 3.1 CO Mass 

### 1b/hr 0-100 4.46 3.72 3.71 2.97 5.20 4.44 4.45 5.94 5.18 5.20 4.46 4.47 5 . 95 5.96 7.45 5.94 5.21 3.71 4.44 5.19 4.45 5.19 4.46 5.21 5.21 5 . 96 5.21 3.72 5.20 4 . 4 7 

### NOx Rate Ib/mmBtu 0 -1 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.005 0.005 0.005 0.005 0.006 0.005 0.006 0.005 0.006 0.006 0.006 0.006 Stk NO X c 

### ppm 0

- 300 1.42 1.43 1. 43 1.43 1.43 1. 43 1. 34 1. 34 1. 43 1.43 1.42 1.43 1. 34 1. 43 1.43 1.43 1. 51 1. 51 1.43 1.43 1.43 1.43 1. 51 1. 43 1. 51 1. 43 1.51 1. 51 1. 51 1. Sl 

### Stk CDc Gas hscfh p pm hscfh 0

- 1000 0-10000 2.85 7085.4 2.35 7083.0 2.35 7071.0 1.93 7062.6 3.19 7071.0 2.77 7050.0 2.52 7060.2 3 . 52 7077.0 3 . 02 7050.6 3 . 27 7069.2 2 . 85 7081.8 2.85 3. 45 3 . 45 4.45 3.45 3 . 11 2.35 2 . 86 3.19 2.69 2.94 2.52 3 . 28 3.03 3 . 36 3.11 2.02 3 . 03 2.61 7094.4 7081.2 7092.6 7099.2 7070.4 7089.0 7069.8 7053.0 7066 . 2 7062.0 7059.0 7076. 4 7088.4 7088.4 7098.6 7091.4 708 4 .2 7076.4 7090.8 

### NH3Inj lb/hr 0

- 200 130.7 130.8 129.7 130.5 129.8 128.8 129.2 128.0 127.2 128.0 128.8 129.3 128.5 127.7 127.3 127.7 126.8 129.0 128.2 127.7 127.5 128.0 128.0 128.0 129.0 128.2 128.8 129.2 127.2 129.0 MW La
0-1 80.1 80.1 80.1 80.1 80. 1 79. 79. ' 80. I 80. 1 80.1 80 .. 80. 80. : 80 . . 80.1 80.1 80,1 80. I 79 . . 80 .. 79. : 80, 1 80.1 80 .. 80.1 80, ' 80 .. 80. : 80. : 80 .. pagE

### Gr o up#-Channel# L

o ng Descrip . S h o rt De s crip. U

n i ts Range 02/25/2013 18:37 02/25/2013 18:38 02/25/2013 18:39 02/25/2013 18:40 02/25/2013 18:41 02/25/2013 18:42 02/25/2013 18:43 02/25/2013 18:44 02/25/2013 18;45 02/25/2013 18;46 02/25/2013 18;47 02/25/2013 18:48 02/25/2013 18;49 02/25/2013 18;50 02/25/2013 18:51 02/25/2013 18;52 02/25/2013 18:53 02/25/2013 18:54 02/25/2013 18:55 02/25/2013 18:56 02/25/2013 18;57 02/25/2013 18:58 02/25/2013 18:59 02/25/2013 19:00 02/25/2013 19:01 02/25/2013 19:02 02/25/2013 19:03 02/25/2013 19;04 02/25/2013 19;05 02/25/2013 19:06 02/25/2013 19:07 02/25/2013 19:08 02/25/2013 19:09 02/25/2013 19:10 02/25/2013 19:11 02/25/2013 19:12 02/25/2013 19;13 02/25/2013 19:14



### Date/Time Printed: G45-C4 G45 -C11 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass

1.8 1.8 1.8 1.8 1.. 1.8 1.. 1., 1.. 2.0 1.. 1.. 1.' 1.8 1.8 1.7 1.8 1.8 1.8 1.8 1.. 1.8 1.8 1.7 1.8 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Stk 02 

# • 0-25 13 . 89 13.87 13.88 13.87 13.86 13.87 13.86 13.86 13.87 13.88 13.87 13.87 13.88 13.88 13.89 13.90 13.89 13.89 13 .89 13.89 13.90 13.89 13.90 13.89 13.89 13.88 13.88 13.89 13.89 13.89 13.89 13.90 13.90 13.89 13.89 13.88 13.89 13 . 88

02/25/2013 20,45 NOx Mass 

### 1b/hr 0-100 4.46 4.48 4.48 4.49 4.50 4.49 4.50 4.50 4.50 4.50 4.50 4.49 4.49 4.47 4.45 3.70 4.45 4.44 4.45 4.45 4.44 4.45 4.45 3.70 4.46 3.72 3.72 4.46 4.46 4.46 4.45 4.45 4.45 4.46 4.46 4.48 4.47 4.47 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

19313 19332 19346 19385 19386 19387 19407 19389 19418 19434 19439 19392 19392 19326 19277 19224 19248 19222 19240 19269 19260 19267 19274 19240 19302 19302 19310 19318 19323 19307 19272 19296 19296 19310 19318 1 9344 19325 19333 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000

3.5 4.4 3.6 4.2 3.4 3.7 4.2 2.6 3.2 3.0 3.2 2.8 3.4 4.2 4.0 4.1 3.0 3.7 3.5 3.8 3.0 2.6 3.2 3.0 3.3 4.1 4.3 4.7 3.6 4.0 4.0 2.6 3.2 3.4 3.4 3.1 3.6 3.4 G45 -C13 G45-C10 G45-C6 5>CO Mass 5>NOx Rate 5>Stk NOXc

CO Mass 

### 1b/hr 0-100 5.21 5.97 5.22 5.99 4.50 5.24 6.00 3.75 4.50 4.50 4.50 3.74 4.49 5.96 5.94 5.91 4.45 5.18 5.19 5.19 4.44 3.71 4.45 4.45 4.46 5.95 5.96 6.70 5.21 5.95 5.94 3.71 4.45 4.46 4.46 4.48 5.21 4.47 NOx Rate 

### Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 stk NOXc 

### ppm 0-300 1. 51 1. 51 1. 51 1. 51 1.59 1. 51 1. 59 1. 59 1. 59 1. 68 1. 59 1. 59 1. 60 1. 51 1. 51 1.43 1. 51 1. 51 1. 51 1. 51 1. 60 1. 51 1. 52 1.43 1. 51 1.43 1.43 1. 51 1. 51 1. 51 1. 51 1. 52 1. 52 1.51 1. 51 1. 51 1. 51 1. 51 G45-C7 G45-C8 5>Stk COc 5>Gas Flow

Stk CDc Gas hscfh ppm hscfh 0-1000 0-10000 2.95 3.69 3.03 3.52 2.85 3.11 3.52 2.18 2.69 2.52 2.69 2.35 2.86 3.53 3.37 3.46 2.52 3.11 2.95 3.20 2.53 2.19 2 . 70 2.52 2.78 3.45 3.61 3.96 3.03 3.37 3 . 37 2.19 2.70 2.86 2.86 2.61 3 . 03 2.86 7083.0 7110.0 7105.2 7129.8 7140.0 7130.4 7147.8 7141.2 7141.8 7137.6 7149.6 7132.2 7122.0 7098.0 7069.8 7040.4 7059.0 7049.4 7056.0 7066.8 7053.6 7066.2 7058.4 7056.0 7078.8 7089.0 7092.0 7084.8 7086.6 7080.6 7068.0 7066.8 7066.8 7081. 8 7084.8 7104.6 7087.2 7100.4 G45 -C18 5>NH3 Inj NH3Inj



### 1b/hr 0-200 128.0 127.7 128.8 128.0 130.0 129.8 129.5 130.0 129.8 129.3 129.5 131. 0 128.8 128.5 128.0 127.5 129.3 128.0 127.7 129. 0 129.3 131.0 130.0 130.2 128.2 129.7 128.5 127.7 128.8 129.3 128.0 129.7 129.3 127.8 128.8 129.0 130.0 128.8


### S>Summary

- I-Min RATA

- Continued G45-C 5>MW Lo

MW Lo

0-1 80.: 80 .. 80. 81. I 81.1 81. I 81.1 81.( 81.( 81.· 81.**~** 81.1 81. 80 . . 80. : 79. ! 80.1 79 .. 79.l 80.1 80. ( 80. ( 80.1 80.1 80. : 80. ! 80.: 80. : 80.: 80.: 7'. 80 .. 80 .. 80. 80. 80 .. 80 .. 80 .**~**


### PagE

### Period Average 

# = 1.8 13.88 4.18 19294 3.5 4.96 0.006 1.49 2.96 7085.4 128.8 80.2 

### Period Max Value 2.0 13.90 4.50 19439 5.3 7.45 0.006 1. 68 4.45 7149.6 131. 0 81. 

### Period Min Value 1.6 1 3.86 3.70 19170 2.3 2.97 0.005 1.34 1. 93 7040.4 126.8 79. 

### Period Totals = 1.2050E+2 9.4388E+2 2.8422E+2 1.3119E+6 2.3920E+2 3.3702E+2 3.8200E-l 1.0117E+2 2.0109E+2 4.8180E+5 8.7589E+3 5.4594E+ 

### Period % Recovery 100.0 100 . 0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.

# Data Summary Report Com pany: CPV Sentinel, LLC 62575 Powerline Road 

# 5Q.v.41 A( \ 

# ?

Desert Hot Springs, CA 92240 

# (2Jr11\-**~p.** \ 

# 100'7,

# (~p\'llMUt S o urce : Turbine 5 

### D

ata Gro up : 5>1

- Min Cales Report Nam e: Start of Report : S>Summary

- l

- Min RATA 02/25/2013 11,35 G45-C4 

### End of Report , 02/25/2013 12,43 G45-Cll G45 - C13 

# TRACE \ Ellvi ronm ental Sy s te ms, [II C.



### validation: 

### All Available Data G45-CIO G45 -C6 G45-C7 G45-CB G45-C18 

### Group#-Channel# 

### Long Descrip
. Short Descrip
. Units G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass G45-C20 

### S>StkFlow

StkFlow

kscfh G4S

- C3 s>Stk CO

Stk CO 5>CO Mass S>NOx Rate s>Stk NOXc S>Stk CDc S>Gas Flow 5>NH3 Inj G45-C 5>MW Lo

MW Lo 

### Range 02/25/2013 11:35 02/25/2013 11:36 02/25/2013 11:37 02/25/2013 11:38 02/25/2013 11:39 02/25/2013 11:40 02/25/2013 11:41 02/25/2013 11:42 02/25/2013 11:43 02/25/2013 11:44 02/25/ 2013 11:45 02/25/2013 11:46 02/25/2013 11: 4 7 02/25/2013 11:48 02/25/2013 11:49 02/25/2013 11:50 02/25/2013 11:51 02/25/2013 11:52 02/25/2013 11:53 02/25/2013 11:54 02/25/2013 11;55 02/25/2013 11:56 02/25/2013 11:57 02/25/2013 11:58 02/25/2013 11:59 02/25/2013 12:00 02/25/2013 12:01 02/25/2013 12:02 02/25/ 2 013 12:03 02/25/2013 12:04 

### Date/Time Printed: l.9 l.9 l.9 l.9 l.9 l.9 l.9 1.9 1.9 1.9 l.9 l.9 1.9 1.9 1.9 1.9 1.9 l.9 1.9 1.9 l.9 1.9 1.9 1.9 1.9 1.9 2.7 

### 2.0 1.9 l.9 Stk 02 % 0-25 13 .47 13 . 4 7 13 .47 13 .46 13 .46 13 .46 13 . 47 13 .46 13. 4 6 13 .46 13 .46 13 .46 13 .45 13 .45 13 .46 13 .46 13 .46 13 . 46 13.46 13 . 47 13 . 4 6 13.46 13 . 4 5 13 .45 13.45 13 .46 13 .46 13.45 13 . 4 6 13 .46 

### 02/25/2013 12,55 NOx Mass Ib/hr 0-100 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.52 5.51 5.52 5.51 5.51 5.52 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.50 7.34 5.51 5.51 5.50 0-300000 22511 22508 22503 22487 22490 22471 22509 22490 22487 22498 22487 22478 22460 224 4 1 22454 22462 22471 22471 22476 22494 22467 22450 22446 224 44 22444 22447 22454 22424 22450 22441 

### ppm 0-1000

2.' 3.0 2.' 

### 3.0 3.7 3.7 

### 3.5 3 . ' 3.6 

### 3.5 3.5 3.3 3.9 3.0 2.9 

### 2.5 2.5 2.8 2.9 

### 3.1 2.7 2.7 

### 2.5 3.2 3.2 2.8 2.9 

### 3.1 2.9 3.0 

### CO Mass 1b(hr 0-100 4.59 4.59 4.59 4.60 6.43 6.43 5.51 6.43 5.51 5.52 5.51 5.51 6.43 4.59 4.59 3.67 3.67 4.59 4 .59 5.51 4.59 4.59 3.67 5.51 5.51 4.59 4.59 5.51 4.59 4.59 

### N Ox Rate 

### Ib/mmBtu 0·1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 .006 0.006 0.006 0.006 0.006 0.008 0.006 0.006 0.006 Stk NOXc 

### ppm 0-300 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1.51 1. 51 1. 51 1. 51 1. 50 1. 50 1. 51 1.51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1.50 1. 50 1. 50 1. 51 2.14 1. 58 1. 51 1. 51 Stk CDc Gas hscfh NH3Inj 

### ppm 0-1000 2.22 2.38 2.22 2.38 2.93 2.93 2.78 3.01 2.85 2.78 2.78 2.62 3 . 09 2 . 38 2.30 1. 98 1. 98 2.22 2.30 2.46 2.14 2.14 1. 98 2.53 2.53 2.22 2.30 2.46 2.30 2.38 

### hscfh 0-10000 8750.4 8749 . 2 8747.4 8752.8 8754.0 8746.8 8749.8 8754.0 8752.8 8757.0 8752.8 8749.2 8754.0 8746.8 8740.2 8743.2 8746.8 8746.8 8748 . 6 8743.8 8745.0 8738.4 8748.6 8748.0 8748.0 8737.2 8740.2 8740.2 8738 . 4 8734.8 

### lb/hr 0-200 196.2 196.2 195.8 195.8 195.0 195.7 195.7 163.8 196.0 196 .5 195.3 196.3 194.3 196 . 0 196.5 196.2 196.3 197.0 198.0 196.0 196.0 197.3 195 . 7 196.5 196.5 179.2 189.2 196.2 196.3 196.5 

### 0-1 105.: 105. : 105. : 106.! 106.! 1 05.: 106.4 105. : 106.1 106.1 105. : 105. : 106.1 106.4 106.! 106.1 106.1 105. : 106.1 105. : 106.1 1 05. : 106.1 105. : 105.: 106.4 105. : 105 .. 106.1 106.1 

### pag£

### Group#-Channel# Long Descrip
. S h o rt De scrip. Units Range 02/25/2013 12:05 02/25/2013 12:06 02/25/2013 12:07 02/25/2013 12:08 02/25/2013 12:09 02/25/2013 12:10 02/25/2013 12:11 02/25/2013 12:12 02/25/2013 12:13 02/25/2013 12:14 02/25/2013 12:15 02/25/2013 12:16 02/25/2013 12:17 02/25/2013 12:18 02/25/2013 12:19 0 2 /25/ 2 013 12:20 02/25/2013 12:21 02/25/2013 12:22 02/25/2013 12:23 02/25/2013 12:24 02/25/2013 12:25 02/25/2013 12:26 02/25/2013 12:27 02/25/2013 12:28 02/25/2013 12:29 02/25/2013 12:30 02/25/2013 12:31 02/25/2013 12:32 02/25/2013 12:33 02/25/2013 12:34 02/25/2 0 13 12:35 02/25/ 2 013 12:36 02/25/2013 12:37 02/25/2013 12:38 02/25/2013 12:39 02/25/2013 12:40 02/25/2013 12:41 02/25/2013 12:42 02/25/ 2 013 12:43



### Date/Time Printed: G45

- C4 G45-C11 G45-C20 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass 5>StkFlow

1.9 1.9 1.9 1.9 1 .9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 Stk 02 t 0-25 13 .4 5 13 . 4 6 13 . 46 13 .45 13 .45 13 .45 13 .45 13 .4 5 13 . 4 5 13 .45 13 .45 13.44 13.4 4 13. 44 13 .44 13. 44 13 . 4 4 13 .45 13 .45 13 .45 13.45 13.4 4 13. 44 13. 4 4 13. 4 3 13.44 13 .44 13 .44 13 . 4 4 13 . 44 13 .44 13 . 4 4 13. 44 13 .44 13 .43 13 .43 13 . 4 4 13 .44 13 .44



### 02/25/2 013 12,55 NOx M ass 

### 1b/hr 0-100 5.50 5.51 5.50 5.50 5.51 5.51 5.51 5.51 5.50 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.51 5.51 5.S1 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.51 5.51 StkFlow kscfh 0-300000

22 4 15 22453 22436 22415 22430 22427 22432 2 2 4 40 22 415 22424 22424 22408 22405 22420 2 2 410 22 4 20 22 4 02 22443 2243 4 22463 22430 2 2411 22422 22 420 22407 22396 22420 22402 22408 22422 2 2 4 25 22419 2 2423 22405 22404 22395 22423 2 2399 2 2417 G45-C3 G45 -C13 G45-C10 G45 -C6 G45-C7 G45-C8 G45-C18 G45-C 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXc 5>Stk COe 5>Gas Flow 5>NH3 Inj 5>MW Lo

Stk CO 

### ppm 0-1000

3.6 3.0 3.1 2 .• 3.2 3.' 3.1 3.1 2.9 3.2 3.6 3.1 3.2 3.' 3.' 3.7 3.7 3.3 3.1 3.2 3.6 3.5 3 .• 3.3 3.6 3.2 3.5 3.6 3.0 3.2 3.6 3.1 3.6 3.6 3.2 3.1 2 .• 3.0 2.5 CO Mass 

### 1b/hr 0

- 100 5.50 4.59 5.50 4.59 5.51 5.51 5.51 5.5 1 4.59 5.51 5.S1 4.59 5.51 5.51 5.51 6. 4 3 6. 4 3 5.51 5.51 5.52 5.51 5.51 6.43 5.51 5.52 5.51 5.51 5.51 4.59 5.51 5.51 4.59 5.51 5.51 5.52 4.60 4.59 4 .59 3.67 NOx Rate 

### Ib/mmBtu 0-1 0 . 00 6 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.00 6 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.00 6 0.00 6 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.00 6 Stk NOXe 

### ppm 0-300 1. SO 1. 51 1. 51 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1.50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 Stk COe Gas 

### ppm hsefh hsefh 0-1000 2 . 85 2 .38 2.46 2.22 2.53 2.69 2 .4 6 2 .46 2.30 2.53 2.85 2.45 2.53 2.69 2. 6 9 2.93 2.93 2.61 2.46 2.53 2.85 2.77 3.0 1 2.61 2.84 2.53 2.77 2.85 2.37 2.53 2. 8 5 2 . 45 2.85 2.85 2.53 2.45 2.21 2. 37 1. 98 0-10000 8736.6 8739.6 8733.0 8736.6 8742.6 8741. 4 8743.2 8746.2 8736.6 8740.2 8740.2 8745.6 8744.4 8750.4 8746.2 8750.4 8743.2 8747.4 8743 . 8 8755.2 8742.6 8746.8 8751 . 0 8750.4 8757.0 8740.8 8750.4 8743.2 8745.6 8751.0 8752 . 2 8749.8 8751.6 8744.4 8755.8 8752.2 8751 . 6 8742 . 0 8749.2 NH3Inj 

### 1b/hr 0-200 195 . 3 197.3 197.0 197.3 197. 0 195.7 197.2 197.3 196.7 196.3 195.7 195.7 195.8 195.7 195.2 1 96 .5 196.8 196.2 195.7 197 .5 196.5 196.3 195.3 195.8 194.5 195.5 195.3 194.2 196.3 195.7 196.0 196.2 195.7 195.2 195.7 194.7 196.0 1 9 6.5 196.0 

### S>Summary

- I-Min RATA

- Continued MW Lo 0-1 105. : 106.1 105 .. 106.1 105. : 105. : 106 . 1 106.1 106 . 1 106.1 105. 106.4 106.1 106.1 106.1 105. : 105. : 105. : 106.1 106.1 106.1 106.1 106 . 1 106.1 106. t 106.1 105. : 106.4 105. : 106.1 10 6 .1 106.1 105. : 106.1 105. 106.1 106.1 106.1 105. Pagf

### Period Average**~** 1.9 13 .45 5.54 22442 3.2 5.19 0.006 1. 51 2.53 8746.3 195.3 105.9 

### Period Max Value 2.7 13.47 7.34 22511 3.9 6.43 0.008 2.14 3.09 8757.0 198.0 106. 

### Period Min value 1.9 13 .43 5.50 22395 2.S 3.67 0.006 1. SO l. 98 8733.0 163.8 105. 

### Period Totals = l.3200E+2 9.2809E+2 3.8203E+2 1.5484E+6 2.2070E+2 3.5815E+2 4.1600E-1 1.0447E+2 1.7479E+2 6.0349E+5 1. 34 73E+4 7.3084E+ 

### Period % Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 1 00.0 100.

# Data Summary Report Co m pany : CPV Sentinel, LLC 

### 62575 Powerline Road De-sert Hot Springs, CA 92240

# ~A+;1o\L1 

# $ 

# fZAn\**~I'\** 

# Z I WL 

# C ''"It

# rilt 

# t1c.t 

# t. Source: 

### Data Group : Report Name : 

### Start of Report : Turbine 5 S>l-Min Cales 

## s>Summary

- I-Min RATA 02/25/2013 13,04 G45-C4 

### End of Report, 02/25/2013 14,17 G4S-Cll G45-C13 

# TRACE Env i ro nm ental Systems, Inc .

validation: All Available Data G45-CIO G45-C6 G45-C7 G45-Ca 

### Group#-Channel# 

### Long Descrip
. 

### Short Descrip
. units G45-C2 S>Stk NOx

Stk NOx 

### ppm 0-150 S>Stk 02 5>NOx Mass G45-C20 S>StkFlow

S tkFlow



### kscfh 0-300000 G4S-C3 5>Stk CO

Stk CO 

### ppm 0-1000 5>CO Mass 5>NOx Rate 5>Stk NOXc 5>Stk CDc S>Gas Flow 

### Stk CDc Gas hscfh G45-C18 5>NH3 Inj NH3Inj



### Ib/hr 0-200 G45-C 5>MW Lo

MW Lo 

### Range 02/25/2013 13:04 02/25/2013 13:05 02/25/2013 13:06 02/25/2013 13:07 02/25/2013 13:08 02/25/2013 13:09 02/25/2013 13:10 02/25/2013 13:11 02/25/2013 13:12 02/25/2013 13:13 02/25/2013 13:14 02/25/2013 13:15 02/25/ 2 013 13:16 02/25/2013 13:17 02/25/ 2 013 13:18 02/25/2013 13:19 02/25/2013 13:20 02/25/2013 13:21 02/25/2013 13:22 02/25/2013 13:23 02/25/2013 13:24 02/25/2013 13:25 02/25/2013 13:26 02/25/2013 13:27 02/25/2013 13:28 02/25/2013 13:29 02/25/2013 13:30 02/25/2013 13:31 02/25/ 2 013 13:32 02/ 2 5/2013 13:33 

### Date/Time Printed: 1., 1.. 1.. 1.. 1.9 

### 1.. 1.9 1.9 1.. 1.9 

### 1.. 1.9 1.9 1.9 1.9 1.. 1.9 

### 1.. 1.. 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 2.6 2.3 Stk 02 % 0-25 13.43 13 .43 13 .43 13 . 4 3 13 .4 3 13 . 4 2 13 . 43 13 .4 3 13 .43 13.43 13. 4 2 13 . 4 2 13 . 41 13 .42 13 .42 13 .4 3 13 .42 13.42 13.42 13 . 4 1 13 . 4 2 13 .4 2 13 .4 2 13 .4 1 13 .4 1 13 .41 13 .41 13. 41 13 . 4 1 13. 4 0 

### 02/25/2013 14,59 NOx Mass Ib/hr 0-100 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.50 5.50 5.50 5.50 5.51 5.51 5.50 5.50 5.50 5.50 5.51 5.50 5.50 5.50 5.50 5.50 5.51 5.50 5.50 5.50 5.50 7.33 6.42 22367 22384 22373 22370 2 2 364 2 2 354 22358 22355 22343 22347 22325 22334 22 305 22 305 22314 22349 22316 22330 22324 2 2 2 89 2 2308 2 2304 22324 22312 22291 22285 2227 4 2 2271 22 283 22255 2.' 2.' 2.' 2.6 2.8 3.1 

### 2.5 2.4 2.5 2.3 

### 2.7 2.5 2.4 2.5 2.' 2.3 2.' 

### 2.5 2.8 2.8 2.2 

### 2.5 2.1 2.7 3.1 2.6 2 . ' 

### 2.5 2 . ' 2.8 CO Mass 

### 1b/hr 0-100 4.59 4.59 4.59 4.59 4.59 4.59 3 . 67 3.67 3.67 3.67 4.59 3.67 3.67 3.67 3.67 3.67 3.67 3.67 4.59 4.59 3.67 3.67 3.67 4.59 4.59 4.58 4.58 3.67 4.58 4.58 NOx Rate 

### Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.00 6 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 006 0.00 6 0.006 0.006 0.006 0.006 0.006 0.006 0.00 8 0.007 Stk NOXc 

### ppm 0

- 300 1. 50 1. 50 1.50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. SO 1. 50 1. 50 1. 50 1. 50 1. SO 1. 50 1. 50 1. 50 1. 50 

### 1. 

### 50 1. 50 1. 50 1. 50 1. 50 2.05 1. 81 ppm hscfh 0-1000 0-10000 2.29 2.29 2.29 2.05 2 . 21 2 .45 1. 97 1. 90 1. 97 1.82 2 .13 1. 97 1. 8 9 1. 97 1. 89 1. 82 1. 89 1. 97 2.21 2.21 1. 74 1. 97 1 66 2 . 13 2.44 2.05 2.28 1. 97 2. 28 2.20 8741.4 8748.0 8743.8 8742.6 8740.2 8748.0 8737.8 8736.6 8731.8 8733.6 8736.6 8740.2 8740.2 8728.8 8732.4 8734.2 8733.0 8738.4 8736.0 8734.2 8730.0 8728.2 8736.0 8743.2 8734.8 8732.4 8728.2 8727.0 8731. 8 8732.4 197.3 196.3 196.7 196.8 197.3 196.8 197.3 196.3 196.8 198.7 196.5 196.5 196.2 197.7 197.8 198.3 197.8 196.8 197.2 197 . 2 197.7 198.3 198.2 197.0 196.3 197.7 198.3 1 97. 8 1 6 5.3 198 . 5 0-1 105. : 105. : 106.1 106. t 105. : 106 . 1 106.1 106.1 106.1 105. : 105.: 106. t 106.1 106.1 105. : 105. : 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106. r 106.1 106.1 106. ( 

### pagf

### Group#-Chann e l# Long Descr i p. Short Descrip
. units Range 02/25/2013 13:34 02/25/2013 13:35 02/25/2013 13:36 02/25/2013 13:37 02/25/2013 13:38 02/25/2013 13:39 02/25/2013 13:40 02/25/ 2 013 13:41 02/25/2013 13:42 02/25/2013 13:43 02/25/2013 13:44 02/25/2013 13:45 02/25/2013 13:46 02/25/2013 13:47 02/25/2013 13:48 02/25/2013 13:49 02/25/2013 13:50 02/25/2013 13:51 02/25/2013 13:52 02/25/2013 13:53 02/25/2013 13:54 02/25/2013 13:55 02/25/2013 13:56 02/25/2013 13:57 02/25/2013 13:58 02/25/2013 13:59 02/25/2013 14:00 02/25/2013 14:01 02/25/2013 14:02 02/25/2013 14:03 02/25/2013 14:04 02/25/2013 14:05 02/25/2013 14:06 02/25/2013 14:07 02/25/2013 14:08 02/25/2013 14:09 02/25/2013 14:10 02/25/2013 14:11 02/25/2013 14:12 02/25/2013 14:13 Date/Time Printed: G45-C4 G45-C11 G45-C20 G45 -C 2 5>Stk NOx

Stk NOx 

### ppm 0 -15 0 5>Stk 02 5>NOx Mass 5>StkFlow

1.9 2.0 1.9 1.9 2.2 1.9 1.9 2.1 2.0 2.0 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 2.5 2.2 2.6 2.2 1.9 1.9 1.9 1.9 1.8 1.9 1.8 1.8 1.9 1.9 1.8 1.9 1.9 1.9 1.9 1.9 Stk 02 

# • 0-25 13. 4 1 13.41 13.41 13 . 41 13 .41 13 .41 13 .40 13 .40 13 .41 13 .41 13 .41 13 .40 13 .40 13.39 13.39 13 .4 1 13 .41 13.41 13.40 13 .41 13 .41 13 .41 13 .4 0 13 .41 13.41 13 .41 13 .41 13 .4 0 13 .40 13 .41 13 .40 13.40 13 .40 13 .40 13.40 13 .39 13 .39 13.40 13 . 4 1 13 .40 02/25/2013 14,59 NOx Mass 

### lb/hr 0-100 5.50 5.50 5.50 5.51 5.50 5.50 5.51 5.51 5.51 5.50 5.50 5.51 5.51 4.59 4.59 5.50 5 . 51 5.51 5.50 5 . 51 6.43 5.52 7.35 5.51 5.51 5.51 5.51 5.52 4.60 5.51 4.60 4.60 5.51 5.52 4.60 4.60 4.59 5.51 5.52 5.52 StkFlow kscfh 0-300000

22282 222 77 22291 22323 22295 22289 22272 222 87 22315 22297 22280 22292 22276 22259 22267 22279 22306 22301 22258 22329 22334 22340 22296 22331 22334 22321 22324 22312 22308 22324 22310 22305 22305 22310 22305 22291 22274 22293 22340 223 18 G45-C3 G45-C13 G45-C10 G45-C6 G45-C7 G45

- C8 G45-C18 G45-C 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXc 5>Stk COc 5>Gas Flow 5>NH3 Inj 5>MW Lo

Stk CO 

### ppm 0-1000

2.4 2.5 2.3 3.1 2.8 2.8 2.6 2.6 3.3 2.8 2.8 2.7 2.9 3.2 3.1 3.1 2.8 3.3 2.9 3.3 3.8 3.5 3.6 3.9 3.9 3.8 3.6 3.7 3.6 4.2 4.1 4.2 4.0 3.8 4.1 4.2 4.4 4.3 4.0 4.4 CO Mass 

### lb/hr 0-100 3.67 3.67 3.67 4.59 4.59 4.59 4.59 4. 59 5.51 4.59 4.58 4.59 4.59 5.51 4.59 4.58 4.59 5.51 4.59 5.51 6.43 5.52 5.51 6.43 6.43 6.43 5.51 6 . 43 5.51 6.43 6.43 6.43 6.43 6.43 6.43 6.44 7.35 7.35 6.43 7.36 NOx Rate Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.007 0.006 0.008 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.005 0.005 0.006 0.006 0.005 0.005 0.005 0.006 0.006 0.00 6 Stk NOXc 

### ppm 0

- 300 1. 50 1. 58 1. 50 1. SO 1. 73 1. 50 1. 49 1. 65 1. 58 1. 58 1. SO 1.49 1.49 1.49 1.49 1. SO 1. 50 1. SO 1.49 1. 50 1. 97 1. 73 2.05 1.73 1. SO 1. 50 1. 50 1.49 1. 42 1. 50 1. 42 1. 42 1. 49 1. 49 1.42 1.49 1.49 1.49 1. 50 1. 49 Stk COc Gas 

### ppm hscfh hscfh 0-1000

1. 89 1. 97 1. 81 2.44 2.21 2.21 2.05 2.05 2.60 2.21 2.21 2.12 2.28 2.51 2.44 2.44 2 . 21 2.60 2.28 2.60 2.99 2.7G 2.83 3.07 3.07 2.99 2.84 2.91 2.83 3 .3 1 3.23 3.30 3.15 2.99 3.23 3.30 3.46 3 . 38 3.15 3.46 0-10000 8731.2 8729.4 8734.8 8747.4 8736.6 8734.2 8739.0 8745.0 8744.4 8737.2 8730.6 8746.8 8740.8 8745 . 6 8748.6 8730.0 8740.8 8739.0 8733.6 8749.8 8751.6 8754.0 8748.6 8750.4 8751. 6 8746.8 8748.0 8754.6 8753.4 8748.0 8754.0 8752.2 8752.2 8754.0 8752.2 8758.2 8751.6 8747.4 8754.0 8757.0 NH3Inj 

### lb/hr 0-200 198.3 197.8 198.2 199.0 182.2 200.0 199.3 190 . 3 198.2 199.3 198.7 198.0 198.5 198.0 198.3 163.8 199.8 165.7 199.3 165.5 170.5 199.8 170.2 200.0 165.8 199.0 199.0 200.0 200.0 198.8 198.3 198.7 198.2 198.7 198.3 197.2 198.0 164 . 3 199.2 197.7 S>Summary

- l-Min RATA - Continued MW Lo 0-1 106. ( 105. : 105.: 105. : 106. ( 106. ( 106.( 106. ( 106. ( 106. ( 105. 106.( 106.: 106. ( 106. ( 106.( 106 . ( 106. ( 106. ( 106.( 106. ( 106. ( 105. 106. ( 106. ( 106. ( 106.( lOG. ( 106. ( 105. : 105 . : 106. ( 106. ( 106. ( 106. ( 105. : 105.: lOG .( 106. ( 105. : pagEGroup#-Channel# G45-C2 G45-C4 G45-Cll G45-C20 G45-C3 G45-C13 G45-C10 G45-C6 G45-C7 G45-C8 G45-C18 G4S-C Long Descrip. 5>Stk NOx 5>Stk 02 5>NOx Mass S>StkFlow S>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXc S>Stk COc 5>Gas Flow 5>NH3 Inj 5>MW La Short Descrip. Stk NOx Stk 02 NOx Mass StkFlow Stk CO CO Mass NOx Rate Stk NOXc Stk CDc Gas hscfh NH3Inj MW Lo units ppm 

# • 1b/hr kscfh ppm 

### 1b/hr Ib/mmBtu ppm ppm hscfh 

### 1b/hr Range 0-150 0-25 0-100 0-300000 0-1000 0-100 0-1 0-300 0-1000 0-10000 0-200 0-1 02/25/2013 14:14 1.9 13.41 5.51 22338 4.0 6.43 0.006 1. 50 3.15 8753.4 198.3 106. t 02/25/2013 14;15 1.9 13.41 5.51 22331 3.7 6.43 0.006 1. 50 2.91 8750.4 198.5 105. : 02/25/2013 14:16 1.9 13.40 5.52 22312 4.1 6.43 0.006 1.49 3.23 8754.6 197.5 106.1 02/25/2013 14:17 1.9 13 .40 5.S1 22299 3.9 6.43 0.006 1.49 3.07 8749.8 199.7 106.1 Period Average 1.9 13 .41 5.48 22311 3.1 5.00 0.006 1. 53 2.45 8742.1 194.3 105.9 Period Max Value 2.6 13 .43 7.35 22384 4.4 7.36 0.008 2.05 3.46 8758.2 200.0 106. Period Min Value 1.8 13.39 4.59 22255 2.1 3.67 0.005 1. 42 1. 66 8727.0 163.8 105. Period Totals 

# = 1.4400E+2 9.9239E+2 4.0572E+2 1.6510E+6 2.3060E+2 3.6999E+2 4.4200E-1 1. 1349E+2 1.8165E+2 6.4691E+5 1. 4381E+4 7.8406E+ Period 

### % Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.



### Date/Time Printed: 02/25/2013 14,59 

### S;:.Summary

- 1-Min RATA

- Continued Pagf

## Appendix 

## 8.1.3 Sentinel Unit 5 PM Testing

R521 0729 

## 8·5

# Data Summary Report Company : CPV Sentinel, LLC 62575 Powerline Road 

# 5ty. 

# nV\(.\**~** Desert Hot Springs , CA 92240 

# Ljrfl o 

# P M Source: Data Group : Report Name : 

### Start of Report : Turbine 5 S>l-Min Cales S>Summary

- I-Min RATA 02/26/2013 08,30 G45-C4 End of Report , 02/26/2013 12,40 G4S-Cll G45-C13 

# TRACE EIII ';rtmmenta l Sy s tems, In c.

Validation: All Available Data G45-CIO G45-C6 G45-C7 G45-C8 

### Group#-Chann e l# 

### Long Descrip. Short Descrip. Units G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass G45-C20 5>StkF!ow



### StkFlow

kscfh 0-300000 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000 5>CO Mass 5>NDx Rate s>Stk NOXc S>St k CDc 5>Gas Flow 

### Stk CDc Gas hscfh G45 -C18 5>NH3 Inj 

### NH3Inj

Ib/hr 0-200 G45-C S,.MW Lo

MW Lo 

### Range 02/26/2013 08:30 02/26/2013 08:31 02/26/2013 08:32 02/26/2013 08:33 02/26/2013 08:34 02/26/2013 08,35 02/2 6 /2013 08:36 02/26/2013 08:37 02/26/2013 08:38 02/26/2013 08:39 02/26/2013 08:40 02/26/2013 08;41 02/26/ 2 013 08:42 02/26/2013 08:43 02/26/2013 08:44 02/26/2013 08:45 02/26/2013 08:46 02/26/2013 08;47 02/26/2013 08:48 02/26/2013 08:49 02/26/ 2 013 08:50 02/26/ 2 013 08:51 02/26/2013 08;52 02/26/2013 08:53 02/26/2013 08;54 02/26/2013 08;55 02/26/2013 08;56 02/26/2013 08:57 02/ 2 6/ 2 013 08:58 02/26/2013 08:59 

### Date/Time Printed: 1.4 1.4 1.4 1.4 1.5 1.5 1.5 1.4 1.4 1.5 1.4 1.5 1.5 1.6 1.6 1.6 1.7 1.7 1.6 1.7 1.7 1.8 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.5 Stk 02 

# • 0-25 14 . 07 14.06 14.06 14.07 1 4. 08 14.07 14.06 14.07 14.06 14.06 14.07 14.07 14.06 1 4 .06 14.06 14. OS 14 . 05 14.05 14.05 14.06 1 4. 05 14. OS 14.05 14.05 14.03 14.02 14.03 14.04 14. 02 14 . 03
02/26/2013 12 , 55 

### NOx Mass Ib/hr 0-100 2.24 2.25 2.25 2.24 2.80 2.81 2.81 2.24 2.25 2.81 2.24 2.80 2.81 2.81 2.80 2.81 2.81 2.82 2.82 2.81 2.82 3.39 2.82 2.83 3.41 3.41 3.40 3.41 3.42 2.85 14953 14969 14953 14953 1 4 953 1 4 96 6 1 4 976 1 4 943 14976 14976 14939 14931 1 4 964 14936 14916 14922 14936 14963 15003 14954 1 4 9 63 15009 15001 15043 15063 15024 15031 15081 15077 15093 0.2 0.2 0.1 0.1 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0 . 1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.0 0.0 0.0 0.0 0.1 CO Mass 

### Ib/hr 0 -100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 

### NOx Rate Ib/mmBtu 0-1 0.004 0.004 0.004 0.004 0.005 0 . 005 0.005 0.004 0.004 0.005 0.004 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0 . 00 6 0.005 

### Stk NOXc ppm 0 -3 00 1. 21 1. 21 1. 21 1. 21 1. 30 1. 30 1. 29 1. 21 1. 21 1. 29 1. 21 1. 30 1. 29 1.38 1.38 1.38 1.46 1.46 1. 38 1. 47 1. 46 1. 55 1. 46 1.46 1. 55 1. 54 1. 55 1. 55 1. 54 1. 29 p p m hscfh 0-1000 0-10000 0 . 17 0.17 0.09 0.09 0.17 0 . 17 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0 . 09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0 . 09 0.09 0.09 0.09 0.00 0.00 0.00 0 . 00 0.09 5343.0 5356.8 5350.8 5343.0 5335.2 5347.8 5359.2 5339.4 5359.2 5359.2 5338.2 5335.2 5355.0 5344.8 5337.6 5347.8 5352.6 5362.2 5376.6 5351. 4 5362.2 5379.0 5376.0 5391.0 5413.8 5407.8 5402.4 5412.6 5427.0 5424.6 104.7 104.5 103.7 104.5 104.3 103.7 103.8 105.0 103.8 104.7 104.3 103.8 103.8 102.8 102.8 103.0 102.8 104.2 104.3 104.3 10 4 .5 103 . 8 105.7 106.3 107.7 107.5 108.7 1 08.8 109.2 108.3 0-1 54.1 54. 1 54.1 54. ( 53 .. 54.1 54.1 54.1 54.1 54.1 54.1 53. : 54. t 54. t 53 .. 54.1 54.: 54 . . 54 .. 54.1 54.1 54 .**~** 54.' 54.' 55.1 55,( 54.: 55.1 55. 1 55.1 

### PagE

### Group#-Channel# Long Descrip. Short Descri p . Uni.ts 

### Range 02/26/2013 09:00 02/26/2013 09:01 02/26/2013 09:02 02/26/2013 09,03 02/26/2013 09:04 02/26/2013 09:05 02/26/2013 09:06 02/26/2013 09:07 02/26/2013 09:08 02/26/2013 09:09 02/26/2013 09:10 02/26/2013 09:11 02/26/2013 09:12 02/26/2013 09:13 02/26/2013 09:14 02/26/2013 09:15 02/26/2013 09:16 02/26/2013 09:17 02/26/2013 09:18 02/26/2013 09:19 02/26/2013 09:20 02/26/2013 09:21 02/26/2013 09:22 02/26/2013 09:23 02/26/2013 09:24 02/26/2013 09:25 02/26/2013 09:26 02/26/2013 09:27 02/26/2013 09:28 02/26/2013 09:29 02/26/2013 09:30 02/26/2013 09:31 02/26/2013 09:32 02/26/2013 09:33 02/26/2013 09:34 02/26/2013 09:35 02/26/2013 09:36 02/26/2013 09:37 02/26/2013 09:38 02/26/2013 09,39 

### Date/Time Printed: G45-C2 5>Stk NOx



### Stk NOx ppm 0-150

1.6 1.6 1.7 1.6 1.6 1.6 1.6 1.6 1.7 1.7 1.7 1.7 1.7 1.6 1.6 1.7 1.6 1.6 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.8 G45-C4 G45-C11 5>Stk 02 5>NOx Mass



### Stk 02 

# • 0-25 14.01 14.02 14. 02 14. 03 14. 04 14.03 14.02 14.03 14.03 14.02 14.02 14.02 14.02 14.02 14.02 14.02 14.03 14.04 14 .03 14.02 14.02 14.03 14.04 14.04 1 4.04 14.05 14.05 14.04 14.03 14.03 14.03 14.02 14.02 14.02 14.02 14.03 14.03 14.03 14.03 14.01 

### NOx Mass 1b/hr 0-100 2.85 2.85 2.85 2.84 2.83 2.84 2.85 2.84 2.85 2.85 2.85 2.84 2.85 2.84 2.84 2.84 2.84 2.83 2.83 2.83 2.84 2.83 2.82 2.82 2.82 2.82 3.37 3.39 3.38 3.39 3.39 2.83 2.83 2.83 2.83 2.83 2.83 2.83 2.83 3.43 02/26/2013 12,55 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

15077 15071 15094 15034 15033 15046 15062 15063 15096 15057 15067 15047 15059 15029 15051 15042 15033 15041 15021 14996 15007 15006 14964 14973 14944 14971 14931 14976 14946 14971 14961 14962 14962 14962 14962 15002 15002 15002 15002 15089 G45-C3 s>Stk CO

Stk. CO ppm 0-1000

0.1 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0 . 2 0.2 0.2 0.2 0.2 0.2 0 . 1 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 G4S-C13 G4s-C10 G4S

- C6 5>CO Mass S>NOx Rate s>Stk NOXc

CO Mass 1b/hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NOx Rate Ib/mmBtu 0

- 1 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 Stk NOXc ppm 0

- 300 1. 37 1. 37 1. 46 1. 37 1. 38 1. 37 1. 37 1. 37 1.46 1. 46 1. 46 1.46 1. 46 1. 37 1. 37 1. 46 1.37 1.38 1. 46 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1. 55 1. 55 1. S5 1.55 1. 55 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1. 54 G45-C7 G45

- C8 5>Stk COc 5>Gas Flow

Stk COc Gas hscfh ppm hscfh 0-1000 0-10000 0.09 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 0 . 17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 0.17 0.17 0.17 0.09 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 0.17 0.17 5434.8 5424.6 5433.0 5403.6 5395.2 5407.8 5421.6 5413.8 5425.8 5419.8 5423.4 5416.2 5420.4 5409.6 5417.4 5414.4 5403.0 5398.2 5398.8 5397.6 5401.8 5393.4 5370.6 5373.6 5363.4 5365.2 5350.8 5374.8

. 5371.8

5380.8 5377.2 5385.6 5385.6 5385.6 5385.6 5392.2 5392.2 5392.2 5392.2 5439.0 G45-C18 5>NH3 Inj NH3Inj



### lb/m 0-200 105.5 103.3 102.8 103.2 102.5 103.2 103.7 102.5 102.3 102.5 102.3 102.0 102.7 103.0 102.5 102.3 102.8 102.5 102.5 101. 3 101. 3 101. 2 101. 2 101. 3 101.8 101. 3 101.2 101.2 100.8 101. 2 101.5 102.5 102.5 102.5 102.5 101. 8 101.8 101. 8 101.8 101.3 

### S>Summary

- I -Min RATA

- Continued G45-C 5>MW 

### Lo

MW Lo

0-1 55. : 55 .. 55.: 55.1 55. ! 55. ( 55. ! 55. ( 55. ( 55. t 55.: 55. ! 55.

- 55. ! S5 . ( 55. ( 55. ( 55. ( 55. ( 55. ! 55. ( 55.1 54 .. 54 .. 54 .**~** 54.' 54.: 54.' 54.: 54.1 54. 1 54.1 54. : 54. 1 54.: 

### 54. : 54.1 54.1 54.:**5S.~** 

### pag(

### Group#-Channel# Lo ng De sc rip
. S h o rt Descrip
. Units Range 02/26/2013 09:40 02/26/2013 09:41 02/26/2013 09:42 02/26/2013 09:43 02/26/2013 09;44 02/26/2013 09:45 02/26/2013 09:46 02/26/2013 09:47 02/26/2013 09:48 02/26/2013 09:49 02/26/2013 09:50 02/26/2013 09:51 02/26/2013 09:52 02/26/2013 09:53 02/26/2013 09:54 02/26/2013 09:55 02/26/2013 09:56 02/26/2013 09:57 02/26/2013 09:58 02/26/2013 09:59 02/26/2013 10:00 02/26/2013 10:01 02/26/2013 10:02 02/26/2013 10:03 02/26/2013 10:04 02/26/2013 10:05 02/26/2013 10;06 02/26/2013 10;07 02/26/2013 10:08 02/26/2013 10:09 02/26/ 2 013 10:10 02/26/2013 10:11 02/26/2013 10:12 02/26/2013 10:13 02/26/2013 10:14 02/26/2013 10:15 02/26/2013 10;16 02/2 6 /2013 10:17 02/26/2013 10:18 02/26/2013 10:19 

### Date/Time Printed: G45-C4 G45 -Cll G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5 >Stk 02 5 >NOx Mass

1.8 1.8 1.8 1.8 1.8 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.8 1.8 1.8 1.8 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 

# I.. I.' 1.8 1.8 1.8 Stk 02 

# • 0-25 1 4 .01 14.01 14.01 14.02 14.02 14.03 14 . 03 14.03 1 4 .03 14.03 14.03 14.02 14.02 14.01 1 4. 01 1 4. 03 14.03 14.03 14.03 14.00 14.00 14.01 14.01 14.01 14 . 01 14.00 14.00 14.00 14.00 14.00 14. 00 14 . 01 14. 01 14 . 01 14 .01 14.01 14 . 01 14.02 14 . 02 14.02 02/26/2013 12,55 NOx Mass 

### 1b/hr 0-100 3.43 3.43 3.43 3.41 3.41 2 . 84 2.84 2.84 2.84 2.85 2.85 2.84 2.84 2.85 2.85 2.84 2.84 2.84 2.84 2.88 2.88 3.43 3.43 3.43 3.43 2.88 2.88 3.44 3.44 3.44 3.44 3.42 3.42 3 A2 3.42 3.43 3 A3 3.41 3.41 3.41 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

15089 15089 15089 15024 15024 15056 15056 15056 15056 15083 15083 15042 15042 15060 15060 15033 15033 15033 15033 15190 15190 15122 15122 15122 15122 15220 15220 15112 15112 15112 15112 15055 15055 15055 15055 15089 15089 1504 4 15044 15044 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000

0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0 . 2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 G45 -C13 G45

- ClO G45-C6 5>CO Mass 5>NOx Rate 5>Stk NOXc

CO Mass 

### 1b/hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NOx Rate lb/mmBtu 0-1 0.006 0.006 0 . 006 

### o 006 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0 . 005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.006 0.005 0.005 0.006 0.006 0.006 0.00 6 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 Stk NOXc 

### ppm 0-300 1.54 1.54 1.54 1.54 1.54 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1A6 1.46 1.46 1.46 1A5 1.45 1.54 1.54 1.54 1.54 1.45 1.45 1.54 1. 54 1. 54 1.54 1. 54 1. 54 1. 54 1. 54 1. 63 1.63 1. 54 1. 54 1. 54 G45-C7 G45-C8 G45 -C 18 5>Stk COc 5>Gas Flow 5>NH3 Inj

Stk COc Gas hscfh NH3Inj 

### ppm hscfh lb/hr 0-1000 0-10000 0-200 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0 . 17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0 . 17 0.17 0.17 0.17 0.17 0 . 17 0.17 0.17 0.17 0.17 0.17 0.17 0 . 17 0.17 0.17 5439.0 5439.0 5439.0 5407.8 5407.8 5411.4 5411.4 5411.4 5411 . 4 5421.0 5421. 0 5414.4 5414.4 5428.8 5428.8 5403.0 5403.0 5403.0 5403.0 5483.4 5483.4 5451.0 5451.0 5451.0 5451.0 5494.2 5494.2 5455.2 5455.2 5455.2 5455.2 5427.0 5427.0 5427.0 5427.0 5439.0 5439.0 5415.0 5415.0 5415.0 101.3 101.3 101.3 101.0 101.0 101.3 101.3 101.3 101.3 102.2 102.2 100.8 100.8 102.7 102.7 102.2 102.2 102.2 102.2 101. 5 101. 5 100.8 100 . 8 100 . 8 100.8 103.2 103.2 101. 5 101. 5 101.5 101.5 101.2 101. 2 101.2 101.2 101.7 101.7 102.0 102.0 102.0 

### S>Summary

- I-Min RATA

- Continued G45-C 5>MW Lo

MW Lo 0-1 55. ! 55. 55. 55.1 55.1 55.1 55. j 55. ( 55. j 55. c 55.1 S5.1 55. j 55. : 55. : 55. : 55. : 55. : 55. : 56.1 56.1 55. : 55. : 55 . : 55. : 56.: 56.: 56.1 56.1 56. j 56. j 55. : S5. : S5. : 55. : 55 .. 55 .. 55 .. 55 . . 55 .. pagE

### Group#-Channel# Long Descrip
. Short Descrip. Units Range 02/26/2013 10:20 02/26/2013 1 0:21 02/26/2013 10:22 02/26/2013 10:23 02/26/2013 10:24 02/26/2013 10:25 02/26/2013 10:26 02/26/2013 10:27 02/26/2013 10:28 02/26/2013 10:29 02/26/2013 10:30 02/26/2013 10:31 02/26/2013 10:32 02/26/2013 10:33 02/26/2013 10:34 02/26/2013 1 0:35 02/26/2013 10:36 02/26/ 2013 10:37 02/26/2013 10:38 02/26/2013 10:39 02/26/2013 10:40 02/26/2013 10:41 02/26/2013 10:42 02/26/2013 10:43 02/26/2013 10:44 02/26/2013 10:45 02/26/2013 10:46 02/26/2013 10:47 02/26/2013 10;48 02/26/2013 10:49 02/26/2013 10:50 02/26/2013 10:51 02/26/2013 10:52 02/26/2013 10:53 02/26/2013 10:54 02/26/2013 10:55 02/26/2013 10:56 02/26/2013 10:57 02/26/2013 10:58 02/26/2013 10:59 

### Date/Time Printed: G45-C4 G45-Cll G45

- C20 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass 5>StkFlow

1.8 1.. 1.. 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 2.0 2.0 1.. 1.. 1.. 1.. 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1. 8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Stk 02 

# • 0-25 14.02 14.02 14.02 14.02 14.02 14.02 14.02 14 . 02 14.02 14.02 14.02 14.02 14.02 14.02 14.02 14.02 14.02 14.04 14. 04 14. 03 14.03 14.04 14.04 14.05 14.05 14 . 05 14 . 05 14.05 14. 05 14.04 14.04 14.04 14.04 14.02 14.02 14.02 14.02 14. 02 1 4. 02 14.03 

### 02/26/2013 12,55 NOx Mass 

### 1b/hr 0-100 3.41 3.40 3.40 3.43 3.43 3.43 3.43 3.41 3.41 3.41 3.41 3.41 3.41 3.40 3.40 3.40 3.40 3.38 3.38 3.39 3.39 3.37 3.37 3.36 3.36 3.36 3.36 3.37 3.37 3.36 3.36 3.36 3.36 3.39 3.39 3.39 3.39 3.39 3.39 3.39 StkFlow ksefh 0-300000

15044 15004 15004 15124 15124 15124 15124 15021 15021 15021 15021 15019 15019 14987 14987 14987 14987 14957 14957 14971 14971 14921 14921 14901 14901 14901 14901 14917 14917 14867 14867 14867 14867 14961 14961 14961 14 961 14939 14939 14962 G45-C3 G45-C13 G45-CI0 G45-C6 G45-C7 G45-C8 G45

- C18 G45-C 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXe 5>Stk COe 5>Gas Flow 5>NH3 Inj 5>MW Lo

Stk CO 

### ppm 0-1000

0.2 0.2 0.2 0.2 0.2 0.2 0 . 2 0 .2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.2 0.2 0.2 CO Mass 

### 1b/hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NOx Rate lb/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 Stk NOXe 

### ppm 0-300 1. 54 1. 63 1.63 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 72 1. 72 1. 63 1. 63 1. 63 1. 63 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 55 1. 54 1. 54 1. 54 1. 54 1. 54 1. 54 1. 55 Stk COe Gas hsefh hsefh 0-10000 

### ppm 0-1000 0.17 0 .1 7 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.09 0.09 0.09 O. 09 0.09 0.09 0.09 0.09 0.09 0.09 0.17 0.17 0.17 5415.0 5400.6 5400.6 5443.8 5443.8 5443.8 5443.8 5406.6 5406.6 5406.6 5406.6 5406.0 5406.0 5394.6 5394.6 5394.6 5394.6 5368.2 5368.2 5380.8 5380.8 5355.0 5355.0 5340.0 5340.0 5340.0 5340.0 5346.0 5346.0 5335.8 5335.8 5335.8 5335.8 5385.0 5385.0 5385.0 5385.0 5377.2 5377.2 5377.8 NH3Inj 

### 1b/hr 0-200 102.0 101.2 101.2 102.5 102.5 102.5 102.5 103.2 103.2 103.2 103.2 102.3 102.3 101.7 101.7 101.7 101.7 101.3 101. 3 102.8 102.8 102.5 102.5 102.5 102.5 102.5 102.5 102.5 102.5 103.2 103.2 103.2 103.2 103.7 103.7 103.7 103.7 104.2 104.2 103.2 

### 5>Summary

- I-Min RATA

- Continued MW La 0-1 55 .. S5 .. 55. ; 56.1 56.1 56.1 56.1 55. ! 55. 1 55. 55. 55.: 55 55.1 55. 1 55. 1 55.1 55. 1 55.1 55.1 55.1 54 .. 54 . . 54 .. 54 54 54 .. 54 . . 54 . . 54. 54 . . 54. 54 . . 55 . . 55. : 55. : 5S. : 55.1 55.1 55. ; 

### PagE

### Group#-Channel# Long Descrip. S hort Descrip
. units Range 02/26/2013 11:00 02/26/2013 11:01 02/26/2013 11:02 02/26/2013 11 :03 02/26/2013 11:04 02/26/2013 11:05 02/26/2013 11:06 0 2 /2 6 /2013 11:07 02/26/2013 11:08 02/26/2013 11:09 02/26/2013 11:10 02/26/2013 11:11 02/26/2013 11:12 02/26/2013 11:13 02/26/2013 11:14 02/ 26 / 2 013 11:15 02/26/2013 11:16 02/26/2013 11:17 02/26/2013 11:18 02/26/2013 11:19 02/26/2013 11:20 02/26/2013 11:21 02/26/ 2 013 11 : 22 02/26/2013 11:23 02/26/2013 11:24 02/26/2013 11:25 02/26/2013 11:26 02/26/2013 11:2 7 02/26/2013 11:28 02/26/2013 11:29 02/ 2 6/ 2 013 11:30 02/26/2013 11:31 02/26/2013 11:32 0 2/26/2013 11:33 02/26/2013 11:34 0 2/26/2013 11:35 02/26/2013 11:36 02/26/ 2 013 11:37 02/26/2013 11:38 02/26/ 2 013 11:39 

### Date/Time Printed: G45-C4 G45-C11 G45-C2 5>Stk NOx

stk NOx ppm 0-150 S>Stk 02 5>NOx Mass

1.8 1.8 1.8 1.8 1.8 1.8 1.8 

# I.. I.' 1.8 1.8 1.8 1.8 1.7 1.7 

# I.. I.. 1.8 1.8 1.8 1.8 1.8 1.8 1.7 1.7 1.7 1.7 1. 7 1.7 1.7 1.7 1.8 

# I.' 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Stk 02 

# • 0-25 14. 0 3 14.03 14.03 14.03 14.03 14.03 14 . 03 1 4 .0 2 1 4. 02 14.02 14.02 14.03 14.03 14 . 05 1 4. 05 1 4 . 0 4 1 4 .0 4 14.0 4 14.04 14 . 02 14.02 14.0 2 14 .0 2 14 . 03 14.03 14 . 03 14.03 14.03 14.03 1 4. 05 1 4 . 0 5 1 4 .03 14.04 14.03 14.04 14 . 04 14.02 1 4. 0 4 14 . 0 4 14.03 

### 02/26/2013 12,55 NOx Mass Ib/hr 0-100 3.39 3.38 3.38 3.38 3 .38 3.39 3.39 3.39 3.39 3.39 3.39 3.38 3.38 2.81 2.81 3.39 3.39 3.38 3.38 3.40 3.40 3.40 3.40 2.82 2.82 2.82 2.82 2.82 2.82 2.81 2.80 3.37 3.38 3.38 3.37 3.38 

### 3.3' 3.37 3.38 3.39 G45

- C20 5>StkFlow

StkFlow

ksefh 0-300000

14962 14939 14939 14936 14936 14964 14964 1 4 969 1 4 969 14962 14962 14907 14907 1 4 934 1 4 934 14984 14984 14964 14964 14989 14989 15009 15009 1 4 941 14941 14919 14919 14939 14924 14911 1 4 879 14896 14936 14917 14911 14926 1 4 944 1 4 916 14937 14954 G4S-C3 5>Stk CO

Stk CO ppm 0

- 1000

0.2 0.1 0.1 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 0.1 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.2 0.1 0.2 0.2 0.2 0.2 0.1 0.2 0.1 0.2 G45 -C13 G4S-C10 G45-C6 5>CO Mass S>NOx Rate S>Stk NOXe

CO Mass Ib/hr 0 -100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 NOx Rate Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 . 00 6 0.006 0.006 0.006 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.00 5 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.00 6 0 . 006 0 . 00 6 0.00 6 stk NOXe ppm 0

- 300 1. 55 1. 55 1. 55 1.55 1. 55 1. 55 1. 55 1. 63 1. 63 1. 54 1.54 1. 55 1. 55 1.46 1.46 1. 63 1. 63 1. 55 1. 55 1. 54 1. 54 1. 54 1. 54 1. 46 1. 46 1. 46 1.46 1.46 1.46 1.46 1.46 1. 55 1. 63 1. 55 1.55 1. 55 1. 54 1. 55 1. 55 1. 55 G4S-C7 G45-C8 5>Stk COe 5>Gas Flow

Stk COe Gas hsefh ppm hsefh 0-1000 0 -100 00 0.17 0.09 0.09 0.17 0.17 0.17 0 . 17 0.17 0 . 17 0.17 0.17 0.17 0.17 0.17 0.17 0.09 0.09 0.09 0.09 0.17 0.17 0 . 09 0.09 0.0 9 0.09 0.09 0.09 0.09 0.09 0 . 09 0.17 0 . 0 9 0.17 0.17 0.17 0.17 0.09 0 . 17 0 . 09 0.17 5377.8 5369.4 5369.4 5368.2 5368.2 5378.4 5378.4 5388.0 5388.0 5385.6 5385.6 5358.0 5358.0 5352.0 5352.0 5377.8 5377.8 5370.6 5370.6 5395.2 5395.2 5402 . 4 5402.4 5370.0 5370.0 5362.2 5362.2 5369.4 5364.0 5343.6 5332.2 5353.8 5360.4 5361.6 5351. 4 5356.8 5379.0 5353.2 5361.0 5374.8 G45

- C18 5>NH3 Inj NH3Inj



### Ib/hr 0

- 200 103.2 104.2 104.2 104.5 104.5 103.7 103.7 102.8 102.8 103.7 103.7 102.5 102.5 104.0 10 4 .0 103.8 103.8 104.3 104.3 104.5 104.5 104.7 104 . 7 104.3 104.3 104.8 104.8 105.0 104.0 104.7 103.2 103.7 103.3 104.0 103.8 103.5 104.0 102.7 103.3 104.2 

### S>Summary

- l-Min RATA

- Continued G4S-C 5>MW Lo

MW Lo 0

- 1 55. : 55.1 55.1 55.1 55.1 55.1 55.1 55 . 1 SS .1 55 55.: 55 55 55.1 55.1 55. 1 55.1 55 . . 55 . . 55. 55. ; 55 . . 55 .. 55. 1 5S .1 55. 1 55.1 55. 55.1 55 . 1 5 4 . : 55.1 54 .. 55.1 54. ; 55. 1 55.1 55.1 55.1 55. : 

### PagE

### Group#-Channel# Long Descrip. Short Des crip. Units Range 02/26/2013 11:40 02/26/2013 11:41 02/26/2013 11:42 02/26/2013 11:43 02/26/2013 11:44 02/26/2013 11:45 02/26/2013 11:46 02/26/2013 11:47 02/26/2013 11:48 02/26/2013 11:49 02/26/2013 11:50 02/26/2013 11:51 02/26/2013 11:52 02/26/2013 11:53 02/26/ 20 13 11:54 02/26/2013 11:55 02/26/2013 11:56 02/26/2013 11:57 02/26/2013 11:58 02/26/2013 11:59 02/26/2013 12:00 02/26/2013 12:01 02/ 26/2013 12:02 02/26/2013 12:03 02/26/2013 12:04 02/26/2013 12:05 02/26/2013 12:06 02/26/2013 12:07 02/26/2013 12:08 02/26/2013 12:09 02/26/2013 12:10 02/26/2013 12:11 02/26/2013 12:12 02/26/2013 12:13 02/26/2013 12:14 02/26/2013 12:15 02/26/2013 12:16 02/26/2013 12:17 02/26/2013 12:18 02/26/2013 12:19 

### Date/Time Printed: G45-C4 G45

- C11 G45

- C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass

1.8 1.7 1.8 1.8 1.8 1.7 1.7 1.8 1.7 1.8 1.7 1.8 1.7 1.8 1.8 1.7 1.7 1.7 1.7 1.8 1.8 1.8 1.7 1.7 1.7 1.7 1.7 1.7 1.6 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.6 1.7 1.7 1.7 Stk 02 % 0-25 14 . 03 14.03 14.03 14.03 14.03 14.04 14.04 14.05 14.04 14.03 14.04 14 .03 14.03 14.02 14 .02 1 4.02 14.02 14.02 14.02 14.02 14.01 14.02 14.02 1 4.02 14.02 14.01 14.01 14.00 14.01 14.01 14.00 1 4.00 14.01 14.00 13.99 14.00 14.01 1 4.00 14.00 14.00 

### 02/26/2013 12 , 55 NOx Mass 

### 1b/hr 0-100 3.39 2.82 3.38 3.38 3.37 2.80 2.80 3.36 2.80 3.37 2.81 3.38 2.81 3.38 3.38 2.82 2.82 2.82 2.81 3 . 38 3.39 3.40 2.84 2.85 2.84 2.85 2.84 2.84 2.84 2.85 2.85 3.42 3.41 3.41 3.42 3.44 2.84 2.85 2.86 2 . 84 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

14974 14969 14934 14914 14884 14854 14867 14879 14862 14896 14892 14922 14889 14914 14899 14921 14932 14912 14889 14912 14926 15004 15041 15061 15002 15074 15026 15004 15026 15055 15037 15055 14999 15014 15038 15103 15002 15040 15097 14985 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000

0.1 0.1 0.1 0.1 0.2 0.2 0.1 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.2 0.1 0.1 0 . 2 0.1 0.1 0.1 0.1 0.1 0.2 0.1 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.2 G45-C13 G45-C10 G45-C6 5>CO Mass 5>NOx Rate 5>Stk NOXc

CO Mass 

### Ib/hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NOx Rate 

### Ib/mmBtu 0-1 0.006 0.005 0.006 0.006 0.006 0.005 0.005 0.006 0.005 0.006 0.005 0.006 0.005 0.006 0.006 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.005 0 . 005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.005 0.005 Stk NOXc 

### ppm 0

- 300 1.55 1. 46 1. 55 1. 55 1. 55 1.46 1.46 1. 55 1.46 1. 55 1.46 1. 55 1. 46 1. 54 1. 54 1. 46 1. 46 1.46 1.46 1. 54 1. 54 1. 54 1.46 1. 46 1. 46 1. 46 1.46 1.45 1.37 1.46 1.45 1. 54 1. 54 1. 54 1. 54 1.54 1.37 1.45 1.45 1.45 G45-C7 G45

- C8 5>Stk COc 5>Gas Flow

Stk COc Gas hscfh 

### ppm hscfh 0-1000 0

- 10000 0.09 0 . 09 0.09 0.09 0.17 0.17 0 . 09 0.17 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0 . 09 0 .1 7 0.09 0.09 0.17 0.09 0.09 0.09 0.09 0.09 0.17 0.09 0.17 0.17 0.17 0.17 0.17 0.09 0.09 0.17 5382.0 5380.2 5367.6 5360.4 5349.6 5331.0 5335.8 5332.2 5334.0 5353.8 5344.8 5363.4 5351.4 5368.2 5362 . 8 5370.6 5374.8 5367.6 5359.2 5367.6 5380.2 5400.6 5413.8 5421.0 5400.0 5433.6 5416.2 5416.2 5416.2 5427.0 5428 . 2 5434.8 5406.6 5419.8 5436.6 5452.2 5407.8 5429.4 5449.8 5409.6 G45-C18 5>NH3 Inj NH3Inj



### Ib/hr 0-200 103.3 105.0 103.8 103.3 103.8 104.0 104 . 2 103.8 102.8 103.8 103.7 104.2 104.3 104.5 104.7 104.7 105.2 104.8 104.3 104.8 104.5 104.7 105.8 105.3 105.5 106.3 106.0 104.7 106.8 105.3 105.2 105.0 104.3 104.8 104.5 104.7 105.2 105.7 105 . 2 104.3 

### 5>Summary

- 1-Min RATA

- Continued G45-C 5>MW La

MW Lo 0-1 55.1 55.1 55 . 1 55. 1 55.1 54 . . 54. 54 .. 54 .. 55.1 55.1 55 .. 55.1 55.1 55.1 55 .. 55.1 55.1 55.1 55.: 55. : 56.1 56.1 56. : 56 . 1 56.1 56. 1 56. 1 56.1 56.1 56 .1 56.1 55 .. 56.1 ' 56.1 56.1 56.1 56.1 56. ! 56.1 

### PagE

### Group#

- Channel# Long Descrip
. Short Descrip
. Units Range 02/26/2013 12:20 02/26/2013 12:21 02/26/2013 12:22 02/26/2013 12:23 02/26/2013 12:24 02/26/2013 12:25 02/26/2013 12:26 02/26/ 2 013 12:27 02/26/2013 12:28 02/26/2013 12:29 02/26/2013 12:30 02/26/2013 12:31 02/26/2013 12:32 02/26/2013 12:33 02/26/2013 12;34 02/26/2013 12:35 02/26/2013 12:36 02/26/2013 12:37 02/26/2013 12:38 02/26/2013 12:39 02/ 26 /2013 12:40 

### Period Average Period Max Value Period Min Value Period Totals 

# = Period % Recovery

Date/Time Printed: G45

- C4 G45-C11 G45-C2 5>Stk NOx

Stk NOx ppm 0-150 5.>Stk 02 5>NOx Mass

1.7 1.8 1.8 1.8 1.8 1.8 1.7 1.7 1.7 1.8 1.8 1.9 1.7 1.7 1.8 1.8 1.7 1.7 1.7 1.7 1.8 1.7 2 .0 1.4 4.3650E+2 100.0 Stk 02 

# • 0-25 14.01 14 .00 14.00 14.00 13.99 14.00 1 4.01 1 4.02 14 .02 1 4.02 1 4.02 14.02 1 4. 03 14.03 14.02 14.02 1 4.02 14.02 1 4 .02 14.01 14.01 14.03 1 4.08 13 . 99 3.5207E+3 100.0



### 02/26/2013 12,55 NOx Mass lb/hr 0-100 2.85 3.43 3.44 3.43 3.44 3.43 2.85 2.83 2.82 3. 4 0 3.39 3.39 2.82 2.82 3.39 3.38 2.81 2.82 2.81 2.83 3.38 3.11 3.44 2 . 24 7.8130E+2 100.0 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000 G45-C3 5>Stk CO

Stk CO ppm 0-1000 15050 0.2 15062 0.1 15118 0.1 15090 0.2 15092 0.2 15069 0.2 15044 0.2 1498 7 0.1 14937 0.2 14991 0.1 14962 0.2 14967 0.2 14957 0.1 14927 0.2 14934 0.1 1 49 19 0.1 14889 0.1 14916 0.1 14886 0.1 14946 0 .1 14876 0.1 14994 0.2 15220 0.2 14854 0.0 3.7634E+6 4.0200E+1 100.0 100.0 G45-C13 G45-C10 G45-C6 S>CO Mass 5>NOx Rate 5>Stk NOXc

CO Mass

Ib /hr 0-100 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 0.00 0 . 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0 . 00 O.OOOOE+O 100.0 NOx Rate Ib/mmBtu 0-1 Stk NOXc ppm 0-300 0.005 1.46 0.006 1.54 0.006 1.54 0.006 1.54 0.006 1.54 0.006 1 .5 4 0.005 1. 4 6 0.005 1.46 0.005 1.46 0.006 1.54 0.006 1.54 0.006 1 .63 0.005 1.46 0.005 1.46 0.006 1 . S4 0.006 1.54 0.005 1.46 0.005 1.46 0.005 1.46 0.005 1.46 0.006 1.54 0.005 1.49 0.006 1.72 0.004 1.21 1.3800E+0 3.7469E+2 100.0 100.0 G45-C7 G45-C8 5.>Stk COc 5>Gas Flow

stk CDc Gas hscfh ppm hscfh 0-1000 0-10000 0.17 0.09 0.09 0.17 0.17 0.17 0.17 0 . 09 0.17 0 . 09 0.17 0.17 0 . 09 0.17 0.09 0.09 0.09 0.09 0.09 0 . 09 0.09 0.14 0.17 0.00 3.4630E+1 100.0 5425.2 5437.2 5457.6 5447.4 5455 . 8 5439.6 5422.8 5394.6 5376.6 5395.8 5385.6 5387.4 5376.0 5365.2 5375.4 5370.0 5359.2 5368.8 5358.0 5387.4 5362.2 5391.5 5494.2 5331.0 1.3532E+6 100.0 G45-C18 5> NH3 Inj NH3Inj



### Ib/hr 0-200 104.2 105.3 104.5 103.7 104 . 0 105.0 105.0 105.2 103.7 103.8 103.7 103.5 104.3 103.0 103.0 103.3 104.0 102.8 104.7 104.7 103.8 103.3 109.2 100.8 2.5935E+4 100.0



### S>Summary

- 1-Min RATA

- Continued G45-C 5>MW Lo

MW Lo 0-1 56.1 56 .. 56.1 56. : 56. : 56. : 55. 55. 55 . . 55 .. 55. : 55 . . 55. 1 55. : 55. c S5.1 55.1 SS .1 55.1 55 .. 55.1 55.1



### 56. 53 . 1.3833E+ 100.

pagE

# Data Summary Report Co m pany : CPV Sentinel, LLC 

### 62575 Powerline Road 

# 5

Desert Hot Springs, CA 92240 

# 5eAt.v-\ 

# 17'7 14 

# PM Source: Turbine 5 

### Data Group: 5>1-Min Cales Report Name : 

### Start of Report : S>Summary

- I-Min RATA 02/25/2013 16,42 G4S-C4 End of Report , 02/25/2013 20,54 G45-Cll G45-C13 

# TRACE Enviro nm enta l S y s te m s, In c.

validation : 

### All Available Data G45-CIO G45-C6 G4S-C7 G4S

- C8 

### Group#-Chann e l# Long Descrip. 

### Short Descrip
. Units G4S-C2 S>Stk NOx

Stk NOx 

### ppm 0

- 150 5>Stk 02 5>NOx Mass G45-C20 5>StkFlow

StkFlow



### kscfh 0-300000 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000 5>CO Mass S>NDx Rate 5>Stk NOXC S>Stk COc 5>Gas Flow Stk CDc Gas hscfh G45-C18 5>NH3 Inj NlBlnj



### Ib/hr 0-200 G45-C 5>MW Lo

MW Lo 

### Range 02/25/2013 16:42 02/25/2013 16;43 02/25/2013 16:44 02/25/2013 16:45 02/25/ 2 013 16;46 0 2 /25/2013 16:47 02/25/2013 16:48 02/25/2013 16:49 02/25/2013 16:50 02/25/2013 16:51 02/25/2013 16:52 02/25/2013 16:53 02/25/2013 16;54 02/ 2 5/2013 16:55 02/25/2013 16;56 02/25/2013 16:57 02/25/2013 16:58 02/25/2013 16:59 02/25/2013 17:00 02/25/2013 17;01 02/ 2 5/ 2 013 17:02 02/25/2013 17:03 02/25/2013 17:04 02/25/2013 17:05 02/25/2013 17;06 02/25/2013 17:07 02/25/2013 17:08 02/25/ 2 013 17:09 02/25/ 2 013 17:10 02/25/2013 17:11 

### Date/Time Printed: 1.2 1.3 1.3 1.3 1.3 1.3 1.3 1.3 

### I., I., I., I.' I., I., I., I., I., I.' I., I., 1.5 1.5 1.5 1.5 1.5 1.6 1.5 1.5 1.6 1.5 Stk 02 

# • 0- 2 5 13.91 13.91 13.90 13.90 13.90 13 . 8 9 13 . 8 8 13.88 13.88 13 .89 13 .89 13.88 13.89 13 . 89 13.89 13.89 13.90 13.89 13.88 13 . 88 13.8 6 13.89 13.88 13.86 13.86 13.89 13.88 13 . 86 13.87 13.86
02/25/2013 21 , 33 NOX Mass 

### Ib/hr 0

- 100 2.94 2.93 2.94 2.93 2.94 2.96 2.96 2.97 2.97 2.96 2.96 2.97 2.96 2.96 2.94 2.95 2.94 2.95 2.95 2.95 3.71 3.67 3.70 3.72 3.73 3.70 3.70 3.71 3.70 3.71 19140 19 1 08 19136 19080 19139 19195 19207 19224 19258 19213 19238 19232 19189 19200 19117 19145 19084 19141 19140 19144 1 9 188 19069 19196 19239 19281 19190 19214 19187 19178 19193 

### D.' 0.' 

### D.' 

## a.' a.' 0.3 0.3 0.3 0.3 

## a.' 0.4 

## a.' a.' 0.4 

## a.' 0.' D.' 0.4 0.8 1.8 3.3 2.5 1.8 3.0 6.0 2.8 2.3 '.9 1.9 3.0 

### CO Mass 

### Ib/hr 0-100 0.74 0.73 0.74 0.73 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.73 0.74 1. 48 2.21 4 .45 3.67 2.22 4.46 8.20 3.70 2.96 6.68 2.96 4.45 

### NOx Rate Ib/mmBtu 0-1 0.004 0.004 0.004 0.00 4 0.00 4 0.00 4 0.00 4 0.004 0.004 0.004 0.004 0.004 0.00 4 0.00 4 0.00 4 0.004 0.004 0.004 0.004 0.004 0 . 005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 

### Stk NOXc ppm 0

- 300 1. 01 1.10 1.10 1.10 1.10 1. 09 1. 09 1. 09 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.18 1.26 1.26 1. 26 1.26 1. 26 1. 35 1. 26 1. 26 1. 34 1. 26 ppm hscfh 0-1000 0

- 10000 0.34 0.34 0.34 0.34 0.34 0.25 0 . 25 0.25 0.25 

### o 3' 0.34 0 . 34 0.34 0 . 34 0 . 34 0.34 0.34 0.34 0.67 1.51 2 .77 2 .10 1. 51 2.51 5.03 2.36 1. 93 4.11 1. 59 2.51 6999.6 6987.6 7008.0 6987.6 7009.2 7039 . 8 7054.2 7060.2 7072.8 7046.4 7055.4 7063.2 7037.4 7041.6 7011.0 7021. 2 6988.8 7020.0 7029.6 7030.8 7067.4 6993.6 7050.0 7086.0 7101.6 7038.0 7056.6 7066.8 7053.6 7069.2 148.2 149. 

## a 149.5 148.3 149.5 149.2 148.7 149.3 148.2 147.7 147.5 147.7 146.2 147.3 144.7 145.3 145.7 145.7 140.5 135.0 132.8 131.8 134.8 133.0 128.8 134.7 133.8 129.2 133.8 131. 3 0-1 80.1 80.1 80.1 80 .: 80.1 80.! 80 . . 81.1 81.1 81.1 81. t 81.1 80. : 80 . . 80. : 80 . . 80.1 80. : 80.1 80.: 80.! 79. : 80. 80. 80. 80 . . 80. : 80 . : 80 .**~** 80. : Pagt

### Group#-Channel# Long Descrip
. S h o rt Descrip
. Units Range 02/25/2013 17:12 02/25/2013 17:13 02/25/2013 17:14 02/25/2013 17:15 02/25/2013 17:16 02/25/2013 17:17 02/25/2013 17:18 02/25/ 2 013 17:19 02/25/2013 17:20 02/25/2013 17:21 02/25/2013 17:22 02/25/2013 17:23 02/25/2013 17:24 02/25/2013 17:25 02/25/2013 17:26 02/25/2013 17:27 02/25/2013 17:28 02/25/2013 17:29 02/25/2013 17:30 02/25/2013 17:31 02/25/2013 17:32 02/25/2013 17:33 02/25/2013 17:34 02/ 2 5/2013 17:35 02/25/2013 17:36 02/25/2013 17:37 02/25/2013 17:38 02/25/2013 17:39 02/25/2013 17:40 02/25/2013 17:41 02/25/2013 17:42 02/25/2013 17:43 02/25/2013 17:44 02/25/2013 17:45 02/25/2013 17:46 02/25/2013 17:47 02/25/2013 17:48 02/25/2013 17:49 02/25/2013 17:50 02/25/2013 17:51 

### Date/Time Printed: G45-C4 G45-C11 G45-C2 5>Stk NOx

Stk NOx 5>Stk 02 5>NOx Mass ppm 0-150

1.6 1.6 1.6 1.6 1.5 1.6 1.6 1.6 1.6 1.7 1.6 1.7 1.7 1.7 1.7 1.8 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.8 1.8 1.7 1.7 1.8 1.7 Stk 02 

# • 0-25 13.86 13.87 13.87 13.87 13.86 13.86 13 . 86 13.86 13.85 13.85 13 . 85 13.84 13.84 13.82 13.82 13.82 13.84 13.86 13.85 13.84 13.84 13.84 13 . 85 13.84 13.84 13.8 4 13.85 13.84 13.84 13.84 13.84 13.84 13 . 84 13.83 13.83 13.83 13.83 13 .8 4 13 . 83 13.84 02/25/2013 21,33 NOx Mass Ib/hr 0-100 3.72 3.72 3.71 3.71 3.71 3.72 3.72 3.73 3.72 3.73 3.73 3.74 3.74 3.75 3.75 4.50 3.73 3.72 3.72 3.73 3.73 3.73 3.72 3.74 3.73 3.74 3.73 3.74 3.74 3.73 3.74 3.75 3.75 3.75 4.51 4.51 3.76 3.74 4.51 3.75 G45-C20 5>StkFlow

StkFlaw

kscfh 0-300000

19226 19276 19226 19217 19203 19218 19216 19275 19189 19239 19261 19264 19266 19265 19262 19273 19223 19219 19225 19238 19223 19220 19233 19277 19251 19301 19249 19301 19298 19256 19275 19314 19329 19316 19346 19339 19357 19306 19349 19313 G45-C3 5>Stk CO

Stk 

## co ppm 0-1000

3.6 2.9 2.3 2.1 2.7 2.8 2 . 1 2.1 2.3 2.0 2.7 2.3 2.1 2.9 2.7 2.3 2.3 2.' 2.3 2.3 2.0 2.2 2.3 2.2 2.0 2.3 2.1 2.1 2.3 2.9 3.1 2.6 2.6 2.6 2.8 3 . 1 2.9 2.8 2.9 3.0 G45-C13 G45-C10 G45-C6 5>CO Mass 5>NOx Rate 5>Stk NOXe

CO Mass lb/hr 0-100 5.20 3.72 2.97 2.97 3.71 3.72 2.97 2.98 2.97 2.98 3.73 2 . 99 2.99 3.75 3.75 3.00 2.98 3.72 2.98 2.98 2.98 2.98 2 . 98 2.99 2.99 2.99 2.98 2.99 2 . 99 3.73 4.49 3.75 3.75 3.75 3.76 4.51 3.76 3.74 3.76 4.49 NOx Rate lb/mmBtu 

### 0-1 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.005 0.005 0.006 0.005 Stk NOXc ppm 0-300 1. 34 1. 34 1. 34 1. 34 1. 26 1. 34 1. 34 1. 34 1. 34 1. 42 1. 34 1. 42 1. 42 1. 42 1.42 1. 50 1.42 1.42 1.42 1.42 1.42 1. 42 1. 42 1. 4 2 1. 42 1.42 1.42 1.42 1.42 1.42 1. 42 1.42 1.42 1.42 1. 50 1. SO 1.42 1.42 1. 50 1. 42 G45-C7 G45-C8 5>Stk COe 5>Gas Flow

Stk COe Gas hscfh ppm hscfh 0-1000 0-10000 3.02 2.43 1. 93 1. 76 2.26 2.35 1. 76 1. 7 6 1. 92 1. 67 2 . 26 1. 92 1. 75 2.42 2.25 1. 92 1. 92 2.01 1. 92 1.92 1. 67 1. 84 1.92 1. 84 1. 67 1. 92 1. 76 1. 75 1. 92 2.42 2.59 2.17 2.17 2.17 2.34 2.59 2. 4 2 2 . 34 2.42 2 . 51 7081. 2 7089.6 7071. 0 7068.0 7072.8 7078.2 7077.6 7099.2 7077.6 7096.2 7104.0 7115.4 7116.0 7135.8 7134.6 7138.8 7100.4 7078.8 7090.8 7105.8 7100.4 7099.2 7093 . 8 7120.2 7110.6 7129.2 7099.8 7129.2 7128.0 7112.4 7119.6 7134.0 7139.4 7144.8 7155.6 7153.2 7159.8 7131.0 7156.8 7133.4 G45-C18 5>NH3 Inj NH3Inj

Ib/hr 0-200 132.2 132.3 133.5 132.8 132.3 132.3 134.2 133.8 133.2 134.0 133.3 133.7 135.2 131.0 132.5 133.5 132.5 133.0 132.0 133.3 133.0 133.2 131.7 133.7 132.2 134.5 133.7 133.0 134.0 132.2 132.5 132.8 132.7 131. 8 132.3 132.2 133.0 132.7 132.7 132.5 

### S>Summary

- l-Min RATA

- Continued G45-C 5>MW 

### La

MW La



### 0-1 80. 81.1 81. ! 80 .. 80. ! 80. 80. 81.( 80 . 81.( 80. : 81.1 81.1 81." 81.1 81.1 80. ' 80.: 80. 80 .. 81.( 80 . . 80. : 81.1 81.1 81.: 80. ! 81.1 81.1 80. t 81. ! 80. : 81.: 81.( 81." B1.: B1.: 81.1 81. . 81.1 pagE

### Group#-Channe l # Long Descrip. Short De s crip
. Units Range 02/25/2013 17:52 02/25/2013 17:53 02/25/2013 17:54 02/25/2013 17:55 02/25/2013 17:56 02/25/2013 17:57 02/25/2013 17;58 02/25/ 2 013 17:59 02/25/2013 18:00 02/25/2013 18:01 02/25/2013 18:02 02/25/2013 18:03 02/25/2013 18;04 02/25/2013 18:05 02/25/2013 18:06 02/25/2013 18:07 02/25/2013 18:08 02/25/2013 18:09 02/25/2013 18:10 02/25/2013 18:11 02/25/2013 18:12 02/25/2013 18:13 02/25/2013 18:14 02/25/2013 18:15 02/25/2013 18:16 02/25/2013 18:17 02/25/2013 18:18 02/25/2013 18:19 02/25/2013 18:20 02/25/2013 18;21 02/25/2013 18:22 02/25/2013 18;23 02/25/2013 18:24 02/25/2013 18;25 02/25/2013 18:26 02/25/2013 18:27 02/25/2013 18:28 02/25/2013 18:29 02/25/2013 18;30 02/25/2013 18:31 

### Date/Time Printed: G 4 5-C4 G45-Cll G45-C20 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0

- 150 5>stk 02 5>NOx Mass 5>StkFlow

1.7 1.6 1.7 

### 1 7 1.7 1.7 1.7 1.7 1.6 1.7 1.7 1.B 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.6 1.6 1.7 1.7 1.7 1.7 1.6 1.7 1.7 1.7 1.B 1.B 1.7 1.7 1.7 1.7 1.B 1.7 1 .B Stk 02 

# • 0-25 13.85 13.85 13.85 13.85 13.86 13.86 13.84 13 .86 13.86 13.86 13.84 13.85 13.85 13 . 84 13.85 13 .86 13.87 13.87 13 .87 13.87 13.88 13.87 13 .8 7 13.87 13 . 87 13.86 13.87 13.88 13.88 13.87 13.88 13 .8 8 13.88 13.89 13.88 13.89 13.88 13.88 13.88 13.88 

### 02/25/2013 21,33 NOx Mass 

### 1b/hr 0-100 3.73 3.73 3.73 3.72 3.71 3.70 3.72 3.70 3.70 3.72 3.73 4.47 3.73 3.73 3.73 3.72 3.72 3.71 3.71 3.71 3.70 3.71 3.72 3.70 3.71 3.72 3 .72 3.72 3.72 3.73 3.71 4.47 4.45 3.70 3.71 3.71 3.7 1 4.46 3.72 4.47 StkFlow ksefh 0

- 300000

19262 19267 19274 19192 19162 19146 19204 19136 19149 19236 19243 19256 19262 19251 19272 19237 19258 19226 19203 19226 19196 19196 19242 19170 19221 19228 19289 19281 19312 19302 19251 19302 19250 19231 19240 19256 19220 19268 19300 19300 G45-C3 G45 -C13 G45-CI0 G45 -C6 G45

- C7 G45-C8 G45-C18 G45-C 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXe 5>Stk COe 5>Gas Flow 5>NH3 Inj 5 >MW Lo

Stk co 

### ppm 0-1000

2.9 3.3 3.7 3.6 3.7 4.0 4.1 4.2 4.8 4.5 4.1 2.5 3. 1 3.1 3.1 3.4 2.B 2.B 2.3 3.B 3.3 3.0 4.2 3.6 3.9 3.4 3.4 4.1 4.1 5.3 4.1 3.7 2.B 3.4 3.B 3.2 3.5 3.0 3.9 3.6 CO 

### Mass l b /hr 0

- 100 3.73 4.48 5.22 5.20 5.19 5.92 5.96 5.92 6.67 5.95 5.97 3.73 4.48 4.48 4.48 4.46 3.72 3.71 2.97 5.20 4.44 4 .45 5.94 5.18 5.20 4.46 4.47 5.95 5.96 7.45 5.94 5.21 3.71 4.44 5.19 4.45 5.19 4.46 5.21 5.21 NOx Rate lb/mmBtu 0-1 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.00 6 0.005 0.005 0.005 0.005 0.006 0.005 0.006 Stk NOXc 

### ppm 0-300 1.42 1. 34 1.42 1. 42 1. 42 1. 42 1. 42 1. 42 1. 34 1. 42 1. 42 1. 51 1.42 1.42 1.42 1.42 1.43 1.43 1 43 1. 43 1. 43 1. 34 1.34 1.43 1.43 1.42 1.43 1. 34 1. 43 1.43 1.43 1. 51 1. 51 1.43 1. 43 1. 43 1. 43 1. 51 1.43 1. 51 Stk COe 

### Gas ppm 0-1000 

### hscfh hscfh 0-10000 2 . 43 2.76 3.10 3.01 3.10 3.35 3.43 3 . 52 4.02 3.77 3.43 2.09 2.59 2.59 2.59 2.85 2.35 2.35 1. 93 3.19 2.77 2.52 3 . 52 3.02 3.27 2.85 2.85 3.45 3.45 4.45 3 .4 5 3.11 2 . 35 2.86 3.19 2.69 2 . 94 2.52 3.28 3 . 03 7104.6 7106. 4 7108.8 7078.8 7057.8 7051. 8 7093.2 7048.2 7053.0 7084.8 7107.6 7102.2 7104.6 7110.6 7108.2 7085.4 7083.0 707 1. 0 7062.6 7071. 0 7050.0 7060.2 7077.0 7050.6 7069.2 7081.8 7094.4 7081. 2 7092.6 7099.2 7070.4 7089.0 7069.8 7053.0 7066.2 7062.0 7059.0 7076.4 7088.4 7088.4 NH3Inj lb/hr 0

- 200 131.3 132 . 2 130.7 130.5 129.3 128.0 129.2 128.8 128.0 129.0 130.2 131.8 131. 0 131. 2 129.3 130 . 7 130.8 129.7 130.5 129.8 128.8 129.2 128.0 127.2 128.0 128.8 129.3 128.5 127.7 127.3 127.7 126.8 129.0 128.2 127.7 127.5 128.0 128.0 128.0 129.0 

### S>Summary

- I-Min RATA

- Continued MW Lo 0-1 80. ! 80 .. 

### BO. BO 80.1 80. ! 80 . . 79. 79 .. 80.1 

### BO. 80. : 80. 80. I 80.! 80.1 80.1 80.1 80.1 80 . 1 79. 79 .. 80.1 80.1 80.1 80 80. 80. : 80. : 80.1 80.1 80. 1 80.1 79 . . 80. : 79. SO. ! 80. ! 80 .. 80. ( Pagt

### Group#-Channel# Long Descrip
. Short Des c r i p. Unit s Range 02/25/2013 18:32 02/25/2013 18:33 02/25/2013 18:34 02/25/2013 18:35 02/25/2013 18:36 02/25/2013 18;37 02/25/2013 18:38 02/25/2013 18:39 02/25/2013 18:40 02/25/2013 18:41 02/25/2013 18:42 02/25/2013 18:43 02/25/2013 18:44 02/25/2013 18:45 02/25/2013 18:46 02/25/2013 18:47 02/25/2013 18:48 02/25/2013 18:49 02/25/2013 18:50 02/25/2013 18:51 02/25/2013 18:52 02/25/2013 18:53 02/25/2013 18:54 02/25/2013 18:55 02/25/2013 18:56 02/25/2013 18:57 02/25/2013 18:58 02/25/2013 18:59 02/25/2013 19:00 02/25/2013 19:01 02/25/2013 19:02 02/25/2013 19:03 02/25/2013 19:04 02/25/2013 19:05 02 / 25/2013 19:06 02/25/2013 19:07 02/25/2013 19:08 02/25/2013 19:09 02/25/2013 19:10 02/25/2013 19:11 

### Date/Time Printed: G45-C4 G45-Cl1 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass

1.7 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.9 1.8 1.9 1.9 1.9 2.0 1.9 1.9 1.9 1.8 1.8 1.7 1.8 1.8 1.8 1.8 1.9 1.8 1.8 1.7 1.8 1.7 1.7 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Stk 02 

# • 0-25 13. SS 13. S8 13 . 89 13.88 13.89 13.89 13.87 13.88 13 . 87 13.86 13.87 13.86 13.86 13.87 13.88 13.87 13.87 13.88 13.88 13.89 13.90 13.89 13.89 13 . 89 13.89 13.90 13.89 13.90 13.89 13.89 13.88 13.88 13.89 13.89 13.89 13.89 13.90 13.90 13 . 89 13.89 

### 02/25/2013 21,33 NOx Mass 

### 1b/hr 0-100 3.73 4.47 4.46 4.46 4.47 4.46 4.48 4.48 4.49 4.50 4.49 4.50 4.50 4.50 4.50 4. SO 4.49 4.49 4.47 4.45 3.70 4.45 4.44 4.45 4.45 4.44 4.45 4.45 3.70 4.46 3.72 3.72 4.46 4.46 4.46 4.45 4.45 4.45 4.46 4.46 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

19328 19309 19316 19268 19334 19313 19332 19346 19385 19386 19387 19407 19389 19418 19434 19439 19392 19392 19326 19277 19224 19248 19222 19240 19269 19260 19267 19274 19240 19302 19302 19310 19318 19323 19307 19272 19296 19296 19310 19318 G45-C3 5>Stk CO

Stk CO 

### ppm 0-1000

4.0 3.7 2.4 3.6 3.1 3.5 4.4 3.6 4.2 3.4 3.7 4.2 2.6 3.2 3.0 3 . 2 2.8 3.4 4.2 4.0 4.1 3.0 3.7 3.5 3.8 3.0 2.6 3.2 3.0 3.3 4.1 4.3 4.7 3.6 4.0 4.0 2.6 3.2 3.4 3.4 G45

- C13 G45-C10 G45-C6 5>CO Mass 5>NOx Rate 5>Stk NOXc

CO Mass 

### Ib/hr 0-100 5.96 5.21 3.72 5.20 4.47 5.21 5.97 5.22 5.99 4.50 5.24 6.00 3.75 4.50 4.50 4.50 3.74 4.49 5.96 5.94 5.91 4.45 5.18 5.19 5.19 4.44 3.71 4.45 4.45 4.46 5.95 5.96 6.70 5 . 21 5.95 5.94 3.71 4.45 4.46 4.46 NOx Rate Ib/mmBtu 0-1 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.00 6 0.006 0.006 0.006 

### o 006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0 . 006 0.006 0.006 0.006 0.006 0.005 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 Stk NOXc 

### ppm 0

- 300 1. 43 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 59 1. 51 1. 59 1. 59 1. 59 1. 68 1 . 59 1. 59 1. 60 1. 51 1. 51 1. 43 1. 51 1. 51 1. 51 1. 51 1. 60 1. 51 1. 52 1. 43 1. 51 1. 43 1. 43 1. 51 1. 51 1. 51 1. 51 1. 52 1. 52 1. 51 1. 51 G45-C7 G45-C8 G45

- C18 5>Stk CDc S>Gas Flow S>NH3 Inj

Stk CDc Gas hscfh NH3Inj 

### ppm hscfh Ib/hr 0-1000 0

- 10000 0-200 3 . 36 3.11 2.02 3.03 2.61 2.95 3.69 3.03 3.52 2.85 3.11 3.52 2.18 2.69 2.52 2.69 2.35 2.86 3.53 3.37 3.46 2.52 3.11 2.95 3.20 2.53 2.19 2.70 2.52 2.78 3.45 3 . 61 3.96 3.03 3.37 3.37 2.19 2.70 2.86 2.86 7098.6 7091.4 7084.2 7076.4 7090.8 7083.0 7110.0 7105.2 7129.8 7140.0 7130.4 714 7.8 7141.2 7141.8 7137.6 7149.6 7132.2 7122.0 7098.0 7069.8 7040.4 7059.0 7049.4 7056.0 7066.8 7053.6 7066.2 7058.4 7056.0 7078.8 7089.0 7092.0 7084.8 7086.6 7080.6 7068.0 7066.8 7066.8 7081.8 7084.8 128.2 128.8 129.2 127.2 129.0 128.0 127.7 128 . 8 128.0 130.0 129.8 129.5 130.0 129.8 129.3 129.5 131.0 128.B 128.5 128.0 127.5 129.3 12B.0 127.7 129.0 129.3 131. 0 130.0 130.2 128.2 129.7 12B.5 127.7 12B.8 129.3 128.0 129.7 129.3 127.8 128.8 S>Summary

- I-Min RATA

- Continued G45-C 5>MW Lo

MW Lo 0-1 BO. ! BO
.. 80. : 80 .. 80.

- 80 .. 80 .. 80. 81.1 81.1 81.1 81.1 81.1 81.1 81.: 81. 81.1 81.' 80 . . 80.: 79. 80.1 79 . . 79. : 80.1 80.1 80.1 80.1 80.1 80.: 80.! 80. : 80.: 80. : 80. : 79. : 80. 80. 80.! 80 .. PagE

### Group#-Channel# Long Descrip
. Short Descrip. units Range 02/25/2013 19:12 02/25/2013 19:13 02/25/2013 19:14 02/25/2013 19;15 02/25/2013 19;16 02/25/2013 19:17 02/25/2013 19:18 02/25/2013 19:19 02/25/ 2 013 19:20 02/25/2013 19:21 02/25/2013 19:22 02/25/2013 19:23 02/25/2013 19:24 02/25/2013 19:25 02/25/20 13 19:26 02/25/2013 19:27 02/25/2013 19:28 02/25/2013 19:29 02/25/2013 19:30 02/25/2013 19:31 02/25/2013 19:32 02/25/2013 19:33 02/ 2 5/2013 19:34 02/25/2013 19:35 02/25/2013 19:36 02/25/2013 19:37 02/25/2013 19:38 02/25/2013 19:39 02/25/2013 19:40 02/25/2013 19:41 02/25/2013 19:42 02/25/2013 19 :43 02/25/2013 19:44 02/25/2013 19:45 02/25/2013 19:46 02/25/2013 19:47 02/25/2013 19:48 02/ 25 /2013 19:49 02/25/2013 19:50 02/25/2013 19:51 

### Date/Time Printed: G45-C4 G45-C11 G45

- C2 5>Stk NOx

Stk NOx ppm 0-150 5>Stk 02 5>NOx Mass

1.8 1.8 1.8 1.8 1.. 1.8 1.8 1.. 1.B 1.7 1.7 1.7 1.B 1.7 1.7 1.B 1.7 1.7 1.7 1.B 1.8 1.B 1.8 1.B 1.B 1.B 1.7 1.7 1.7 1.7 1.7 1.B 1.8 1.8 1.7 1.B 1.7 1.7 1.7 1.8 Stk 02 

# • 0-25 13.88 13.89 13.88 13.90 13.89 13.89 13.89 13.90 13.91 13.91 13.92 13.91 13.90 13.89 13.89 13.88 13.89 13.88 13.89 13.88 13.87 13 .88 13.87 13.88 13.88 13.88 13.88 13.89 13.90 13.89 13.89 13.89 13.90 13.91 13.90 13.91 13.92 13.92 13.91 13.91 02/25/2013 21,33 NOx Mass Ib/hr 0-100 4.48 4.47 4.47 4.47 4.47 4.46 4.47 4.47 4 . 4 5 3.71 3.70 3.70 4.45 3.72 3.71 4.47 3.71 3.71 3.71 4.46 4.47 4.46 4.47 4.46 4.47 4.46 3.71 3.71 3.70 3.72 3.71 4.46 4.45 4.44 3.70 4.43 3.68 3.68 3.68 4.43 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

19344 19325 19333 19374 19359 19308 19331 19370 19329 19329 19314 19273 19290 19307 19287 19300 19258 19251 19272 19273 19279 19286 19289 19259 19309 19292 19243 19276 19260 19298 19290 19300 19287 19252 19229 19245 19197 19199 19176 19221 G45-C3 5>Stk CO

Stk CO ppm 0-1000

3.1 3.6 3.4 3.' 3.' 3.6 3.B 3.6 3.2 3.0 2.6 3.3 3.0 3.1 3.0 3.2 3.2 2.9 2.8 3.1 2.7 2.5 2.7 3.2 2.9 3.2 3.3 4.3 3.0 3.0 3.3 3.4 3.4 3.8 3.6 3.B 3.2 3.4 3.2 4.3 G45-C13 G45-C10 G45-C6 5>CO Mass 5>NOx Rate 5>Stk NOXc

CO Mass

Ib/hr 0-100 4.48 5.21 4.47 5.22 5.22 5 . 20 5 . 21 5.21 4.45 4.45 3.70 4.44 4.45 4.46 4.46 4.47 4.45 3.71 3.71 4.46 3.72 3.72 3.72 4.46 3.72 4.46 4.45 5.94 4.44 4.46 4.46 4.46 4.45 5.17 5.18 5.17 4.42 4.42 4.42 5.90 NOx Rate Ib/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.005 0.006 0.005 0.005 0.006 0.005 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.005 0.006 0.005 0.005 0.005 0.006 Stk NOXc ppm 0-300 1. 51 1. 51 1. 51 1. 52 1. 60 1. 51 1. 51 1. 60 1. 52 1.43 1.44 1.43 1. 52 1. 43 1.43 1. 51 1.43 1.43 1.43 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1.51 1. 43 1.43 1.43 1.43 1.43 1. 51 1. 52 1. 52 1. 43 1. 52 1. 44 1. 44 1. 43 1. 52 G45-C7 G45 -C 8 G4S-C18 5>Stk COc 5>Gas Flow S;:.NH3 Inj

Stk COc Gas hscfh NH3Inj ppm hscfh Ib/hr 0-1000 0 -10000 0-200 2.61 3.03 2.86 3.29 3.28 3 .03 3.20 3.03 2 . 70 2.53 2.20 2.79 2.53 2.61 2.52 2.69 2.69 2.44 2.36 2 . 61 2.27 2.10 2.27 2.69 2.44 2.69 2.77 3.62 2.53 2.52 2.78 2.86 2.87 3.21 3.03 3.21 2.70 2.87 2.70 3.63 7104.6 7087.2 7100.4 7095.0 7099.8 7081.2 7089.6 7093.8 7068.6 7068.6 7053.0 7048.2 7064.4 7080.6 7073.4 7088.4 7062.6 7070.4 7068.0 7078.2 7090.8 7083.0 7094.4 7073.4 7091. 4 7085.4 7067.4 7069.2 7053.6 7077.6 7074.6 7078.2 7063.2 7040.4 7042.2 7038.0 7010.4 7011.0 7012.8 7029.0 129.0 130 . 0 128.8 130.0 129.3 129.0 129.8 129.7 129.5 129 .0 129. B 129.2 127.8 129.5 129.7 130.3 129.3 129.5 128.8 128.5 130.2 129.7 130.8 129.7 129.8 129.2 129.5 128.0 128.2 130.7 129.0 128.0 128.0 128.3 128.2 127.7 128.5 126.7 127.2 127.7 

### S>Summary

- I-Min RATA

- continued G45-C 5>MW Lo

MW Lo 0-1 80.' 80.' BO. 80.' 

### BO.: 80.' 80 .**~** 80 .**~** 80. I 80.1 80 .. 79. : 80. : 80 . . 80,1 

### aD .: 80,1 

### aD .: 80.1 80.: 80 , . 80, : 80 .**~** 80. : 80, : 

## ao. : 80,1 80,1 80. 80. : 80,1 80.: 79. 79, . 79. : 79. ! 79 , 1 79. : 79,1 79. 

### PagE

### Group#-Channel # Long Descri p. Sho rt Des c ri p. U

n its Ra n ge 02/25/2013 19:52 02/25/2013 19:53 02/25/2013 19:54 02/25/2013 19:55 02/25/2013 19:56 02/25/2013 19:57 02/25/2013 19:58 02/25/2013 19:59 02/2S/2013 20:00 02/25/2013 20:01 02/25/2013 20:02 02/25/2013 20:03 02/25/2013 20:04 02/25/2013 20:05 02/25/2013 20:06 02/25/2013 20:07 02/25/2013 20:08 02/25/2013 20:09 02/25/2013 20:10 02/25/2013 20:11 02/25/2013 20:12 02/25/2013 20:13 02/25/2013 20:14 02/25/2013 20:15 02/25/2013 20:16 02/25/2013 20:17 02/25/2013 20:1S 02/25/2013 20:19 02/25/2013 20:20 02/25/2013 20:21 02/25/2013 20:22 02/25/2013 20:23 02/25/2013 20:24 02/25/2013 20:25 02/25/2013 20:26 02/25/2013 20:27 02/25/2013 20:28 02/ 2 5/ 2 013 20:29 02/25/2013 20:30 02/25/2013 20:31 

### Date/Time Printed: G4S-C4 G45-C11 G4S

- C20 G45-C2 5>Stk NOx

Stk NOx S>Stk 02 5>NOx Mass S>StkFlow 

### ppm 0-150

1.8 1.8 1.8 1.8 1.8 1.8 1.7 1.8 1.7 1.8 1.9 1.8 1.9 1.9 1.8 1.8 1.8 1.9 1.7 1.8 1.9 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.7 1.7 1.8 1.8 1.7 1.7 1.8 1.7 1.8 1.6 1.6 1.7 Stk 02 

# • 0-25 13.92 13.93 13.91 13.92 13.92 13 . 93 13.91 13.90 13.90 13.91 13.91 13.90 13.90 13.89 13.89 13.91 13.90 13.91 13.90 13.92 13.92 13.92 13 . 94 13.92 13.90 13.90 13.91 13.94 13.94 13.91 13.90 13.91 13.92 13.91 13.91 13.92 13.93 13.93 13.93 13 . 93 

### 02/25/2013 21,33 NOx Mass 

### 1b/hr 0-100 4.42 4.42 4.43 4.42 4.43 4.41 3.68 4.42 3.70 4.44 4.45 4.47 4.45 4.47 4.48 4.47 4.47 4.46 3.72 4.44 4.44 4.44 4.42 4.43 4.43 4.44 4.45 4.41 3.68 3.68 4.42 4.41 3.67 3.68 4.42 3.67 4.40 3.66 3.66 3.66 StkFlow kscfh 0-300000

19217 19228 19226 19215 19242 19215 19183 19172 19224 19254 19331 19357 19290 19359 19369 19383 19374 19357 19346 19309 19312 19289 19284 19253 19210 19249 19321 19238 19238 19185 19152 19142 19132 19155 19188 19161 19152 19139 19095 19097 G4S-C3 G45-C13 G4S-CI0 G4S-C6 G45-C7 G45-C8 G4S

- C18 G4S-C s>stk CO S>CO Mass S>NOx Rate 5>Stk NOXc S>Stk COc S>Gas Flow S>NH3 Inj 5>MW La

Stk CO 

### ppm 0-1000

4.7 3.7 3.0 2.7 3.7 2.7 4.0 3.4 3.4 4.2 3.3 3.3 2.9 

### 3.2 3.6 3.5 5.0 2.4 4.2 3.7 3.4 

### 3.5 3.1 3.4 3.0 3.0 4.1 3.1 3.4 3.8 

### 3.0 2.8 3.3 4.1 3.1 3.8 3 . 1 4.1 4.6 

### 3.1 CO Mass 

### Ib/hr 0-100 6.63 5.15 4.43 3.68 5.16 3.68 5.89 4 . 42 4 . 44 5.91 4.45 4.47 3.71 4.47 5.22 5.21 6.71 3.72 5.95 5.18 4.44 5.18 4.42 4.43 4.43 4.44 5.94 4.41 4.41 5.16 4.42 3.68 4.40 5.88 4.42 5.14 4.40 5.86 6 . 58 4.39 NOx Rate 

### Ib/mmBtu 0

- 1 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 

### 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.006 0.006 0.005 0.005 0.006 0.005 0.006 0.005 0.005 0.005 Stk NOXc 

### ppm 0-300 1. 52 1. 52 1. 52 1. 52 1. 52 1. 52 1.43 1. 52 1.43 1. 52 1. 60 1. 52 1. 60 1. 60 1. 51 1.52 1. 52 1.60 1.43 1. 52 1. 61 1. 52 1. 53 1. 52 1. 52 1. 52 1. 52 1. 53 1. 44 1. 43 1. 52 1. 52 1.44 1. 43 1. 52 1. 44 1. 52 1. 35 1. 35 1. 44 Stk COc Gas 

### ppm hscfh hscfh 0-1000 3.97 3.13 2.53 2.28 3.13 2.29 3.38 2. 87 2.87 3.55 2.79 2.78 2.44 2.69 3.03 2.95 4.21 2.03 3.54 3.13 2 . 87 2.96 2.63 2.87 2.53 2.53 3.46 2.63 2. S8 3.21 2.53 2.36 2.79 3.46 2.62 3.21 2.62 3.47 3.89 2.62 0-10000 7017.6 7011.6 7030.8 7017.0 7026.6 7006.8 7015.2 7021.2 7040.4 7041.0 7069.2 7089.0 7064.4 7099.8 7103.4 7088.4 7095.0 7078.8 7084.S 7051.2 7052.4 7044.0 7021.8 7030.8 7035.0 7049.4 7065.6 7005.0 7005.0 7015.8 7014.0 7000.2 6986.4 7005.0 7017.0 6997.2 6984 . 0 6979.2 6963.0 6963.6 NH3Inj 

### 1b/hr 0

- 200 125.8 126.0 128.3 128.7 126.8 128.2 126.0 127.0 126.8 125.7 128.8 130.3 129.2 129.0 128.3 129.2 126.8 131. 0 128.0 128.2 12S.2 12S.5 127.7 127.5 128.0 12S.0 12S.2 127.3 127 . 3 126.2 128.7 126 . 7 127.3 126.5 127.7 127.8 127.2 127.0 126.5 126.8 

### S>Summary

- 1-Min RATA

- Continued MW Lo 0-1 79 .. 79 .. 79 .. 79. : 79 .. 79" 79. ( 79 . . 79 .. 79 . 80. ( 80. f 80 .. 80.: 80 .. 80. 80 80.: 80.f 79. 80 .. SO .1 79. : 79 .. 79 .. 80. f 80. ( 79. : 79. ( 79 .. 79. : 79.( 79. t 79.: 79. ( 79. ( 79. ( 78 .. 78 .. 78. ( 

### Pag(

### Group#-Channel# Lo ng De s cri p. Short De sc rip
. Units Range 02/25/2013 20:32 02/25/2013 20:33 02/25/2013 20:34 02/25/2013 20:35 02/25/2013 20:36 02/25/2013 20:37 02/25/2013 20:38 02/25/ 2 013 20:39 02/25/2013 20:40 02/25/2013 20:41 02/25/2013 20:42 02/25/2013 20:43 02/25/2013 20:44 02/25/2013 20:45 02/25/2013 20:46 02/25/2013 20:47 02/25/2013 20:48 02/25/2013 20:49 02/25/2013 20:50 02/25/2013 20:51 02/25/2013 20:52 02/25/2013 20:53 02/25/2013 20:54 

### Period Average Period Max Value Period Min Value Period Totals 

# = Period 

### % Recovery

Date/Time Printed: G45

- C4 G45-C11 G45-C20 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass 5>StkFlow

1.7 1.7 1.7 1.8 1.6 1.6 1.8 1.7 1.8 1.8 1.8 1.8 1.7 1.7 1.7 1.7 1.6 1.7 1.6 1.7 1.7 1.8 1.7 1.7 

### 2.0 1.2 Stk 02 

# • 0-25 13 . 93 13.92 13.91 13 .92 13.91 13.91 13.93 13 . 90 13.90 13.89 13.90 13.92 13.92 13.92 13.92 13.92 13.93 13.93 13.93 13.92 13.91 13.92 13.92 13.88 13.94 13.82 4.3120E+2 3.5126E+3 100.0 100.0



### 02/25/2013 21,33 NOx Mass 

### 1b/hr 0-100 3.66 3.67 3.67 4.39 3.67 3.67 4.38 3.67 4.41 4.41 4.40 4.40 3.66 3.65 3.65 3.66 3.65 3.66 3.65 3.66 3.67 4.39 3.66 3.95 4.51 2.93 StkFlow ksefh 0-300000

19115 19122 19132 19100 19131 19116 19085 19100 19098 19078 19084 19140 19112 19049 19045 19074 19059 19098 19080 19076 19116 19063 19100 19243 19439 19045 9.9986E+2 4.8684E+6 100.0 100.0 G45-C3 G45-C13 G45-C10 G45-C6 G45-C7 G45-C8 G45-C18 G45-C 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXe 5>Stk COe 5>Gas Flow 5>NH3 Inj 5>MW Lo

Stk CO 

### ppm 0-1000

3.2 3.3 5.3 3.6 5.5 6.4 2.8 4.6 3.9 3.1 2.9 2.8 

### 3.0 1.9 1.7 1.7 2.7 1.8 3.1 

### 3.4 4.8 2.9 

### 3.4 3.1 6.4 

### 0.3 7.7340E+2 100.0 CO Mass 

### 1b/hr 0-100 4.39 4.40 7.35 5.13 7.35 8.81 3.65 6.61 5.14 4.41 3.67 3.67 4.40 2.92 2.19 2.19 3.65 2.19 4.38 4.39 6.61 3.65 4.39 4.27 8.81 0.73 1.0814E+3 100.0 NOx Rate lb/mmBtu 

### 0-1 0.005 0.005 0.005 0.006 0.005 0.005 0.006 0.005 0.006 0.006 0.006 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.006 0.004 Stk NOXe 

### ppm 0-300 1. 44 1. 44 1. 43 1. 52 1.35 1. 35 1. 52 1. 43 1. 52 1. 51 1. 52 1. 52 1.44 1. 44 1. 44 1. 44 1. 35 1. 44 1. 35 1.44 1.43 1. 52 1.44 1. 43 1. 68 1. 01 1.3480E+0 3.6243E+2 100.0 100.0 Stk COe Gas 

### ppm 0-1000 hsefh hsefh 0

- 10000 2.71 2.79 4.47 3.04 4.64 5.40 2.37 3.88 3.29 2.61 2.44 2.37 2.54 1. 61 1.44 1.44 2.29 1. 52 2.62 2.87 4.05 2.45 2.87 2.57 5.40 0.25 6970.2 6982.8 6996.6 6975.0 6996.0 6990.6 6959.4 6994.8 6994.2 6996.6 6988.8 6989.4 6979.2 6956.4 6954.6 6965.4 6949.8 6964.2 6957.6 6966.0 6990.6 6961.2 6975.0 7063.1 7159.8 6949.8 NH3Inj 

### 1b/hr 0-200 126.2 126.5 125.0 127.3 124.8 124.2 127.3 125.2 126.2 127.2 126.8 127.8 125.7 127.5 128.2 128.3 126.0 127.5 124.7 126.0 124.2 126.5 126.0 130.7 149.5 124.2 MW Lo 0- , 1 78 .. 78. 79.1 78.: 78. : 78. ! 78 .. 78. 79.1 79.1 79.1 79.1 78 .. 78. : 78 .. 78. : 78.1 78. : 78.1 78. 78. : 78. : 78 .. 80.0

81. 78. 6.5051E+2 100.0 1.7869E+6 3.3069E+4 2.0259E+ 100.0 100.0 100.



### 5>Summary

- I-Min RATA

- Continued PagE

# Data Summary Report Company: CPV Sentinel. LLC 62575 Powerline Road Desert Hot Springs, CA 92240

# »~A.l\ 

# lOrl'}D 

# 6 PM Source: Data Group : Report Name : 

### Start of Report: Turbine 5**5>1~Min** 

### Cales S>Summary

- 1

- Min RATA 02/25/2013 10,56 G45-C4 

### End of Report, 0 2 / 25/2013 15,20 G4S-Cll G4S-C20 G4S-C3 G4S - C13 

# TRACE Environmen t al Sys tems, fllC.



### Validation: Al l Available Data G45-CIO G45

- C6 G4S-C7 G4S

- C8 G45

- C18 G45

- C 

### Group#-Channel# Long Descrip. Short Descrip. 

### Units G45

- C2 S>Stk NOx

Stk NOx 

### ppm 0

- IS0 5>Stk 02 5>NOx Mass 5>StkFlow s> Stk CO S>CO Mass S>NOx Rate 5>Stk NOXc 5>Stk CDc 5>Gas Flow 5>NH3 Inj 5 > MW La 

### Range 02/25/2013 10:56 02/25/2013 10:57 02 / 25/2013 10:58 02/25/2013 10:59 02/25/2013 11:00 02/25/2013 11:01 02/25/2013 11:02 02/25/2013 11:03 02/25/2013 11:04 0 2 / 25/2013 11:05 02 / 25/2013 11:06 02/25/2013 11:07 02/25/2013 11:08 02/25/2013 11:09 02/25/2013 11:10 02 / 25/2013 11:11 02 / 25/2013 11:12 02/25/2013 1 1: 13 02/25/2013 11:14 02/25/2013 11:15 02/25/2013 11:16 02/25/2013 11:17 02/25/2013 11:18 02 / 25/2013 11:19 0 2/25/2013 11:20 02 / 25/2013 11:21 02/25/2013 11:22 02/25/2013 11:23 02/25/2013 11:24 02/25/2013 11:25 

### Date/Time Pr i nted: 1.8 1.8 1.8 1.8 1.9 1.8 1.8 1.8 1.9 1.8 1.8 1.8 1.8 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.8 1.9 1.9 1.8 1.9 1.9 Stk 02 

# • 0-25 13 .48 13 .47 13 .47 13 .47 13 .48 13 .47 13 .47 13 .48 13.48 13 .48 13 .47 13 .47 13 .47 13 .47 13 .47 13 .47 13.47 13 .47 13 .47 13 .48 13 .48 13 .48 13 .47 13.47 13 .48 13 .47 13 .46 13 .46 13 . 46 13.46 

### 02/25/2013 21,)2 NOx Mass 1b/hr 0-100 4.60 4.60 4.59 4.59 5.51 4.60 4.60 4 . 59 5 . 5 2 4.60 4.59 4.60 4.59 5.52 5.51 5.52 5 . 51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 4 . 59 5.51 5.52 4.59 5.51 5.51 

### stkFlow kscfh 0-300000

22552 22520 22509 22509 22544 22525 22528 22540 22555 22552 22509 22519 22514 22520 22512 22522 22492 22483 22494 22530 22527 22524 22488 22506 22538 22500 22495 22481 22488 22462 Stk CO 

### ppm 0

- 1000

3.5 3.9 3.8 3.8 3.5 4.2 3.9 4.2 3.7 3.7 3.9 3.4 3.8 

### 3.6 3.8 2.8 2.9 2 . 7 2.6 2.7 2.8 2.7 2.6 2.8 2.6 

### 3. 0 2.8 3.7 2.9 

### 3 . 1 CO Mass 1b/hr 0

- 100 5.52 6.43 6.43 6.43 5 . 51 6.44 6.44 6.43 6.44 6.43 6.43 5.51 6.43 5.52 6.43 4.60 4 . 59 4.59 4.59 4.59 4.59 4.59 4.59 4.59 4.59 4.59 4.60 6.43 4.60 5.51 NOx Rate 

### Ib/mmBtu 0-1 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.005 0.006 0.006 

### Stk NOXc 

### ppm 0

- 300 1.43 1. 43 1. 43 1. 43 1. 51 1. 43 1.43 1. 43 1. 51 1.43 1.43 1. 43 1. 43 1. 51 1. 51 1. 51 1. 5 1 1. 5 1 1. 5 1 1. 51 1. 51 1. 51 1. 51 1. 51 1.43 1. 51 1. 51 1. 43 1. 51 1. 51 Stk CDc Gas 

### ppm 0-1000 

### hscfh hscfh 0

- 10000 2.78 3.10 3.02 3.02 2.78 3.34 3.10 3.34 2.94 2.94 3.10 2.70 3.02 2.86 3.02 2.22 2.30 2.14 2.06 2.15 2.23 2.15 2.06 2.22 2.07 2.38 2.22 2.93 2.30 2.46 8754.6 8754.0 8749.8 8749.8 8751.6 8755.8 8757.0 8749.8 8755.8 8754.6 8749.8 8753.4 8751.6 8754.0 8751.0 8754.6 8743 . 2 8739.6 8743.8 8746.2 8745.0 8743.8 8741.4 8748.6 8749.2 8746.2 8755.8 8750.4 8753.4 8743.2 NH3Inj Ib/hr 0

- 200 196.5 195.8 194.8 194.8 196.3 196.3 197.2 194.7 194.8 196.0 194.7 195 . 2 195.0 194.5 195.5 196.2 195.7 196.5 196.0 195.7 194.7 195.0 197.3 195.8 197.2 195.8 196.7 195.0 197.0 195.8 MW Lo 0-1 105 .. 105. : 105. : 105. 1 105 . . 105 .. 105. 105. 105 . . IDS. : 106.1 105. 106. ( 105. ! 105. 1 105 . . 1 0 5. 

### 105 105. 106. : 106.1 105. : 106.1 106.1 105 . . 106.1 105. : 106. ( lOS. : 106.1 

### PagE

### Group#-Channel# Lo ng Descrip
. S h o rt Des c rip
. Units Range 02/25/2013 11:26 02/25/2013 11:27 02/25/2013 11:28 02/25/2013 11:29 02/25/2013 11 ;30 02/25/ 2013 11:31 02/25/2013 11:32 02/25/2013 11:33 02/25/2013 11:34 02/25/2013 11:35 02/25/2013 11:36 02/25/2013 11:37 02/25/2013 11: 38 02/25/2013 11:39 02/25/ 2 013 11:40 02/25/2013 11:41 02/25/2013 11:42 02/25/2013 11:43 02/25/2013 11:44 02/2 5/2013 11:45 02/25/2013 11:46 02/25/2013 11:47 02/25/2013 11:48 02/25/2013 11:49 02/25/2013 11:50 02 / 25/2013 11:51 02/25/2013 11:52 02/25/2013 11:53 02/25/2013 11:54 02/25/2013 11:55 02/25/2013 11:56 02/25/2013 11: 5 7 02/25/2013 11:58 02/25/2013 11: 59 02/2 5/20 13 12:00 02/25/2013 12:01 02/25/2013 12:02 02/25/2013 12:03 02/25/2013 12:04 02/25/2013 12:05 

### Date/Time Printed: G45-C4 G45-C11 G45-C2 0 G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass 5>StkFlow

1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 2.7 2.0 1.9 1.9 1.9 Stk 02 

# • 0-25 13 . 46 13 .46 13 .47 13 .46 13.47 13 .47 13 .46 13.46 13.46 13 . 47 13.47 13 .47 13.46 13. 4 6 13 . 46 13.47 13.46 13 .46 13 .46 13 .46 13 .46 13 . 45 13. 4 5 13.46 13. 4 6 13.46 13 .46 13 .46 13 .47 13 .46 13 .46 13 . 45 13 .45 13.45 13 .46 13 .46 13 .45 13 .46 13 .46 13 .45 02/25/2013 21,32 NOx Mass 

### 1b/hr 0-100 5.51 5.5 1 5.51 5.51 5.51 5.51 5 .51 5.52 5.52 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.52 5.51 5.52 5.51 5.51 5.52 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.50 7.34 5.51 5.51 5.50 5.50 StkFl ow kscfh 0-300000

22488 22471 22509 22462 22492 22497 22467 22490 22490 22511 2250B 22503 22487 22490 2 2471 22509 22490 22487 22498 22487 22478 22460 22441 22454 22462 22471 22471 22476 22494 22467 22 4 50 22446 22444 22444 22447 22454 22424 22450 22441 22415 G45-C3 G45-C13 G45-C10 G45-C6 G45-C7 G45-CB G45-C18 G45-C 5>Stk CO 5>CO Mass 5> NOx Rate 5>Stk NOXc 5>Stk COc 5>Gas Flow 5>NH3 Inj 5>MW Lo

Stk CO 

### ppm 0-1000

2.9 2.9 3.0 2.9 3.1 3.0 2.7 3.0 3.1 2." 3.0 2." 3.0 3.7 3.7 3.5 3." 3.6 3.5 3.5 3.3 3.9 3.0 2.9 2.5 2.5 2." 2.9 3.1 2.7 2.7 2.5 3.2 3.2 2." 2.9 3.1 2.9 3.0 3.6 CO Mass 

### 1b/hr 0-100 4.60 4. 59 4.59 4.59 5.51 4.59 4.59 4.60 5.52 4.59 4.59 4.59 4.60 6.43 6 . 43 5.51 6.43 5.51 5.52 5.5 1 5.51 6.43 4.59 4.59 3.67 3.67 4.59 4.59 5.51 4.59 4.59 3.67 5.51 5.51 4.59 4.59 5.51 4.59 4.59 5.50 NOx Rate lb/mmBtu 0-1 0.006 0.006 0.006 0 .006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0 .006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.006 0.008 0.006 0.006 0.006 0.006 Stk NOXc 

### ppm 0 -3 00 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 l. 51 1. 51 l. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 50 1. SO 1. 51 l. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1. 51 1.50 1.50 1. 50 1. 51 2.14 1. 58 1. 51 1. 51 1. SO Stk COc Gas hscfh 

### ppm hscfh 0-1000 0

- 10000 2.30 2.30 2 . 38 2.30 2.46 2.38 2.14 2.38 2.46 2 . 22 2.38 2.22 2.38 2.93 2.93 2.78 3.01 2. B5 2.78 2.78 2.62 3.09 2 . 38 2.30 1. 98 1. 98 2.22 2.30 2.46 2.14 2.14 1. 98 2.53 2.53 2.22 2.30 2.46 2.30 2.38 2.85 8753.4 8746.8 8749.8 8 7 4.3 .2 8743.2 8745.0 8745.0 8754.0 8754.0 8750.4 8749.2 8747.4 8752 . 8 8754.0 8746.8 8749.8 8754.0 8752.8 8757.0 8752.8 8749.2 8754.0 8746.8 8740.2 8743.2 8746.8 8 7 46.8 8748.6 8743.8 8745.0 8738.4 8748.6 8748.0 8748.0 8737.2 8740.2 8740.2 8738.4 8734.8 8736.6 NH3Inj 

### 1b/hr 0 -200 196.3 196.7 195.7 196 .7 196.5 197.5 197.0 195 . 0 196.2 196.2 196 .2 195.8 195.8 195.0 195.7 195.7 163.8 196.0 196.5 195.3 196.3 194.3 196.0 196.5 196 .2 196 .3 197.0 198.0 196.0 196.0 197.3 195.7 196.5 196.5 179.2 189.2 196.2 196.3 196.5 195.3 

### S>Summary

- I-Min RATA

- Continued MW Lo 0-1 106.1 105. ' 106. 1 105. ' 106.1 106.1 106,1 105. : 106.1 105. : 105. : 105. : 106. r 106.1 lOS, 106.1 105. 106.1 106. r 105, : 105. : 106,1 106.1 106.1 106,1 106.1 105. 106.1 105. : 106.1 105. : 106.1 105. : 105. : 106, 1 105. 105. 106.1 106,1 105. : 

### PagE

### Group#-Channel# Long Descrip. Short Descrip. units Range 02/25/2013 12:06 02/25/2013 12 :07 02/25/2013 12:08 02/25/2013 12:09 02/25/2013 12:10 02/25/2013 12:11 02/25/2013 12:12 02/25/2013 12:13 02/25/2013 12;14 02/25/2013 12;15 02/25/2013 12;16 02/25/2013 12;17 02/25/2013 12;18 02/25/2013 12;19 02/25/2013 12;20 02/25/2013 12:21 02/25/2013 12:22 02/25/2013 12:23 02/25/2013 12:24 02/25/2013 12:25 02/25/2013 12;26 02/25/2013 12:27 02/25/2013 12;28 02/25/2013 12:29 02/25/2013 12:30 02/25/2013 12:31 02/25/2013 12:32 02/25/2013 12:33 02/25/2013 12:34 02/25/2013 12:35 02/25/2013 12;36 02/25/2013 12:37 02/25/2013 12:38 02/25/2013 12:39 02/25/2013 12:40 02/25/2013 12;41 02/25/2013 12:42 02/25/2013 12:43 02/25/2013 12:44 02/25/2013 12:45 

### Date/Time Printed: G45-C4 G4S-C11 G4S-C20 G4S-C2 

### S>Stk NOx

Stk NOx 

### ppm 0-150 

### 5>Stk 02 

### 5>NOx Mass 5>StkFlow

1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.8 1.9 

### Stk 02 

# • 0-25 13.46 13.46 13.45 13.45 13. 4 5 13.45 13.45 13. 4 5 13.45 13 .4 5 13.44 13.44 13.44 13 .44 13 .44 13 .44 13 .45 13 .45 13 .45 13 .45 13 .44 13 .44 13 .44 13 .43 13.44 13 .44 13.44 13.44 13 .44 13 .44 13 .44 13 .44 13.44 13.43 13.43 13 .44 13.44 13 .44 13 .43 13 .44 

### 02/25/2013 21,32 NOx Mass 

### 1b/hr 0-100 5.51 5.50 5.50 5.51 5.51 5.51 5.51 5.50 5.51 5.51 5.51 5.51 5.51 5.51 

### 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.52 5.51 5.51 5.51 5.51 4.60 5.51 

### StkFlow kscfh 0-300000

22453 22436 22415 22430 22427 22432 22440 22415 22424 22424 22408 22405 22420 22410 22420 22402 22443 22434 22463 22430 22411 22422 22420 22407 22396 22420 22402 2240 8 22422 22425 22419 22423 22405 22404 22395 22423 22399 22417 22396 22408 G4S-C3 G45-C13 G45-C10 G45-C6 G45

- C7 G45-C8 G 4 5

- C18 G4S-C 

### 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXc 5>Stk COc S>Gas Flow S>NH3 Inj 5>MW Lo

Stk 

### co ppm 0-1000

3.0 3.1 2.8 3.2 3.4 3.1 3.1 2.9 3.2 3.6 3.1 3.2 3.4 3.4 3.7 3.7 3.3 3.1 3.2 3.6 3.5 3.8 3.3 3 . 6 3.2 3.5 3.6 3.0 3.2 3.6 3.1 3.6 3.6 3.2 3.1 2.8 3.0 2.5 2.8 2.7 

### CO Mass 

### 1b/hr 0-100 4.59 5.50 4.59 5.51 5.51 5.51 5.51 4.59 5.51 5.51 4.59 5.51 5.51 5.51 6.43 6.43 5.51 5.51 5.52 5.51 5.51 6.43 5.51 5.52 5.51 

### 5.51 5.51 4.59 5.51 5.51 4.59 5.51 5.51 5.52 4.6 0 4.59 4.59 3.67 4.60 4.59 

### NDx Rate lb/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 

### Stk NOXc 

### ppm 0-300 1. 51 1. 51 1. 50 1. 50 1.50 1. SO 1. 50 1. SO 1. 50 1. SO 1. SO 1. 50 1. SO 1.50 1.50 1. SO 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 1. SO 1. 50 1. 50 1. 50 1. 50 1. 50 1. SO 1. 50 1. 50 1. SO 1. 50 1. 50 1. SO 1. 50 1. 42 1. SO 

### Stk CDc Gas 

### ppm 0-1000 2.38 2.46 2.22 2.53 2.69 2.46 2 .4 6 2.30 2.53 2.85 2.45 

### 2.53 2.69 2.69 2.93 2.93 2.61 2.46 

### 2.53 2.85 2.77 3 . 01 2.61 2.84 

### 2.53 2.77 2.85 2.37 2.53 2.85 2.45 2.85 2.85 2.S3 2.45 2.21 2.37 1. 98 2.21 2.14 

### hscfh hscfh 0-10000 8739.6 8733.0 8736.6 8742.6 8741. 4 8743.2 8746.2 8736.6 8740.2 8740.2 8745.6 8744.4 8750.4 8746.2 8750.4 8743.2 8747.4 8743.8 8755.2 8742.6 8746.8 8751.0 8750.4 8757.0 8740.8 8750.4 8743.2 8745.6 8751.0 8752.2 8749.8 8751.6 8744.4 8755.8 8752.2 8751.6 8742.0 8749.2 8752.8 8745.6 

### NH3Inj 

### 1b/hr 0-200 197.3 197.0 197.3 197.0 195.7 197.2 197.3 196.7 196.3 195.7 195.7 195.8 195.7 195.2 196.5 196.8 196.2 195.7 197.5 196.5 196.3 195.3 195.8 194.5 195.5 195.3 194.2 196.3 195.7 196.0 196.2 195.7 195.2 195.7 194.7 196.0 196.5 196.0 197.2 195.8 

### S>Summary

- 1-Min RATA

- Continued MW Lo 0-1 106.1 105 .. 106.1 105. 105. 106. ( 106. ( 106 . 1 106. ( 105. : 106.1 106. ( 106. t 106.1 105. 105. : 105. 106.1 106. ( 106.1 106. ( 106.1 106.1 106.1 106.1 105. : 106.1 105. : 106.1 106.1 106.1 105. 106. ( 105. : 106.1 106.t 106.1 105. : 106.1 106.1 

### Pag(

### Gro up#-Channe l# Lo ng De sc r i p . S hort De sc r i p . Units Range 02/25/2013 12:46 02/25/2013 12:47 02/25/2013 12:48 02/25/2013 12:49 02/25/2013 12:50 02/25/2013 12:51 02/25/2013 12:52 02/25/2013 12:53 02/25/2013 12:54 02/25/2013 12:55 02/25/2013 12:56 02/25/2013 12:57 02/25/2013 12:58 02/25/2013 12:59 02/25/2013 13:00 02/25/2013 13:01 02/25/2013 13:02 02/25/2013 13:03 02/25/2013 13:04 02/25/2013 13:05 02/25/2013 13:06 02/25/2013 13:07 02/25/2013 13:08 02/25/2013 13:09 02/25/2013 13:10 02/25/2013 13:11 02/25/2013 13:12 02/25/2013 13:13 02/25/2013 13:14 02/25/2013 13:15 02/25/2013 13:16 02/25/2013 13:17 02/25/2013 13:18 02/25/2013 13:19 02/25/2013 13:20 02/25/2013 13:21 02/25/2013 13:22 02/25/2013 13:23 02/25/2013 13:24 02/25/2013 13:25 

### Date/Time Printed: G45-C4 G4S-Cl1 G45

- C2 

### 5::>Stk NOx

Stk NOx 

### ppm 0

- 150 

### 5::>Stk 02 

### 5::>NOx Mass



# 1.. 1.' 2.8 2.0 2.0 

# 1.' 1.. 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 

# 1., 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 

### Stk 02 % 0-25 13. 4 3 13.43 13.43 13.44 13.44 13 .43 13 . 43 13.43 13.43 13 .43 13 .42 13 .43 13 .43 13 .43 13 . 42 13.42 13.43 13 .43 13.43 13 .43 13 .43 13 .43 13 .43 13 .42 13 .43 13.43 13.43 13 .43 13 .42 13 .42 13 .41 13 .42 13 .42 13 .43 13.42 13.42 13.42 13 . 41 13 . 42 13.42 

### 02/25/2013 21,32 NOx Mass 

### 1b/hr 0 -100 5.51 5.51 7.34 5.51 5.50 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.51 5.50 5.50 5.50 5.50 5.51 

### 5.51 5.50 5.50 5.50 5.50 5.51 5.50 5.50 5.50 5.50 G45-C20 

### 5::>StkFlow

StkFlow

ksefh 0-300000

22393 22367 22347 22397 22385 22367 22375 22364 22373 22369 22356 22366 22361 22361 22348 22342 22380 22373 22367 22384 22373 22370 22364 22354 22358 22355 22343 22347 22325 22334 22305 22305 22314 22349 22316 22330 22324 22289 22308 22304 G45-C3 

### 5::>Stk CO

Stk CO 

### ppm 0-1000

3.2 3.2 3.4 2.9 3.0 2.5 3.0 2.8 2.8 2.8 3.2 3.3 2.8 2.8 2.7 2.8 3.3 2.7 2.9 2.9 2.9 2.6 2.8 3.1 2.5 2.4 2.5 2.3 2.7 2.5 2.4 2.5 2.4 2 . 3 2.4 2.5 2.8 2.8 2.2 2.5 G45 -C13 G45-ClO G45-C6 

### 5::>CO Mass 5::>NOx Rate 5::>Stk NOXe

CO Mass 

### 1b/hr 0-100 5.51 5.51 5.50 4.59 4.59 3.67 4.59 4.59 4.59 4.59 

### 5.51 5.51 4.59 4.59 4.59 4.59 

### 5.51 4.59 4.59 4.59 4.59 4.59 4.59 4.59 3.67 3.67 3.67 3.67 4.59 3.67 3.67 3.67 3.67 3.67 3.67 3.67 4.59 4.59 3.67 3.67 

### NOx Rate lb/mmBtu 0-1 0.006 0.006 0.008 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 

### Stk NOXe 

### ppm 0-300 1. 50 1. SO 2.21 1. 58 1. 58 1. 50 1. SO 1. 50 1. 50 1. 50 1. 50 1. 50 1. SO 1. 50 1. SO 1. 50 1. SO 1. 50 1. 50 1. SO 1. SO 1. SO 1. SO 1. SO 1. 50 1. SO 1. SO 1. 50 1. SO 1. SO 1. 50 1. 50 1. SO 1. SO 1. 

### 50 1. SO 1. 

### 50 1. SO 1. SO 1. SO G4S-C7 G45-C8 

### 5::>Stk COe 5::>Gas Flow

Stk COe Gas hsefh ppm 

### hsefh 0-1000 0-10000 2.53 

### 2.53 2.69 2.29 2.37 1. 97 2.37 2.21 2.21 2.21 2.52 2.61 2.21 2.21 2.13 2.21 2.61 2.13 2.29 2.29 2.29 2.05 2.21 2.45 1. 97 1. 90 1. 97 1.82 2.13 1. 97 1. 89 1. 97 1. 89 1. 82 1. 89 1. 97 2.21 2 . 21 1. 74 1. 97 8751.6 8741 4 8733.6 8741. 4 8736.6 8741.4 8744.4 8740.2 8743.8 8742.0 8748.6 8740.8 8739.0 8739.0 8745.6 8743.2 8746.2 8743.8 8741.4 8748.0 8743.8 8742.6 8740.2 8748.0 8737.8 8736.6 8731.8 8733.6 8736.6 8740.2 8740 . 2 8728.8 8732.4 8734.2 8733.0 8738.4 8736.0 8734.2 8730.0 8728.2 G45-C18 

### 5::>NH3 Inj NH3Inj



### 1b/hr 0-200 195.3 120 . 8 173.0 195.5 196.7 197.5 196.8 197.2 197.0 196.7 197.2 197.5 197.8 197.8 197.2 195.8 196.3 163.8 197.3 196.3 196.7 196.8 197.3 196.8 197.3 196.3 196.8 198.7 196.5 196.S 196.2 197.7 197.8 198.3 197.8 196.8 197.2 197.2 197.7 198.3 

### S>Summary

- l-Min RATA

- Continued G45-C 5>MW 

### Lo

MW Lo 0-1 106.1 106.1 106.1 106.1 106.1 106.1 106.1 105. : 106.1 105. : 106.1 106. 1 105. 105. : 106 . ( 106. : 106.1 106.1 IDS. : lOS .: 106.1 106.1 105. 106.1 106.1 106.1 106.1 

### IDS. lOS. 106.1 106.1 106.1 105. : 

### 105. : 106.1 106.1 106.1 106.1 106.1 106. 1 Pagt

### Group#- C hannel # Long Descr i p . Short Descr i p. Units Ra nge 02/25/2013 13:26 02/25/2013 13:27 02/25/2013 13:28 02/25/2013 13:29 02/25/2013 13:30 02/25/2013 13:31 02/25/2013 13:32 02/25/2013 13:33 02/25/2013 13:34 02/25/2013 13:35 02/25/2013 13:36 02/25/2013 13:37 02/25/2013 13:38 02/25/2013 13:39 02/25/2013 13:40 02/25/2013 13:41 02/25/2013 13:42 02/25/2013 13:43 02/25/2013 13:44 02/25/2013 13:45 02/25/2013 13:46 02/25/2013 13:47 02/25/2013 13:48 02/25/2013 13:49 02/25/2013 13:50 02/25/2013 13:51 02/25/2013 13:52 02/25/2013 13:53 02/25/2013 13:54 02/25/2013 13:55 02/25/2013 13:56 02/25/2013 13:57 02/25/2013 13:58 02/25/2013 13:59 02/25/2013 14:00 02/25/2013 14:01 02/25/2013 14:02 02/25/2013 14:03 02/25/2013 14:04 02/25/2013 14:05 

### Date/Time Printed: G45-C4 G45-C11 G45-C20 G45-C2 

### 5>Stk NOx

Stk NOx 

### ppm 0-150 

### 5>Stk 02 

### 5>NOx Mass 5>StkFlow

1.9 1.9 1.9 1.9 1.9 1.9 2.6 2.3 1.9 2.0 1.9 1.9 2.2 1.9 1.9 2.1 2.0 2.0 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 2.5 2.2 2.6 2.2 1.9 1.9 1.9 1.9 1.8 1.9 1.8 1.8 

### Stk 02 

# • 0-25 13 .42 13.41 13 .41 13.41 13.41 13.41 13 . 41 13.40 13.41 13 .41 13.41 13 .41 13 .41 13 .41 13 .40 13 .40 13 .41 13 .41 13.41 13.40 13 .40 13 .39 13.39 13 .41 13 .41 13 .41 13.40 13.41 13.41 13 .41 13 .40 13 .41 13 .41 13.41 13.41 13.40 13 .40 13 .41 13 .40 13 .40 02/25/2013 21,32 

### NOx Mass lb/hr 0-100 5.50 5.51 

### 5.50 5.50 5.50 5.50 7.33 6.42 5.50 5.50 5.50 5.51 5.50 5.50 5.51 5.51 5.51 5.50 5.50 5.51 5.51 4.59 4.59 5.50 5.51 5.51 5.50 5.51 6.43 5.52 7.35 5.51 5.51 5.51 5.51 5.52 4.60 5.51 4.60 4.60 

### StkFlow kscfh 0-300000

22324 22312 22291 22285 22274 22271 22283 22255 22282 22277 22291 22323 22295 22289 22272 22287 22315 22297 22280 22292 22276 22259 22267 22279 22306 22301 22258 22329 22334 22340 22296 22331 22334 22321 22324 22312 22308 22324 22310 22305 G45-C3 G45-C13 G45-C10 G45-C6 G45-C7 G45-C8 G45-C18 G45-C 

### 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXc 5>Stk CDc 5>Gas Flow 5>NH3 Inj 5>MW Lo

Stk CO 

### ppm 0-1000

2.1 2.7 3.1 2.6 2.9 2.5 2.9 2.8 2.4 2.5 2.3 3.1 2.8 2.8 2.6 2.6 3.3 2.8 2.8 2.7 2.9 3.2 3.1 3.1 2.8 3.3 2.9 3.3 3.8 3.5 3.6 3.9 3.9 3.8 3.6 3.7 3.6 4.2 4.1 4.2 

### CO Mass 

### 1b/hr 0-100 3.67 4.59 4.59 4.58 4.58 3.67 4.58 4.58 3.67 3.67 3.67 4.59 4.59 4.59 4.59 4.59 5.51 4.59 4.58 4.59 4.59 5.51 4.59 4.58 4.59 5.51 4.59 5.51 6.43 5.52 5.51 6.43 6.43 6.43 5.51 6.43 5.51 6.43 6.43 6.43 

### NOx Rate lb/mmBtu 0-1 0.006 0.006 0.006 0.006 0.006 0.006 0.008 0.007 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.005 0.006 0.006 0.006 0.006 0.006 0.007 0.006 0.008 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.005 0.005 

### Stk NOXc 

### ppm 0-300 1. 50 1. 50 1. 50 1. 50 1. 50 1. 50 2.05 1. 81 1. 50 1. 58 1. 50 1.50 1. 73 1. 50 1.49 1. 65 1. 58 1. 58 1. 50 1. 49 1. 49 1. 49 1.49 1. 50 1. 50 1. 50 1.49 1. 50 1. 97 1. 73 2.05 1. 73 1.50 1. 50 1. 50 1.49 1.42 1. 50 1.42 1. 42 

### Stk COc Gas hscfh hscfh 0-10000 

### ppm 0-1000

1. 66 2.13 2.44 2.05 2.28 1. 97 2.28 2.20 1. 89 1. 97 1. 81 2.44 2.21 2.21 2.05 2.05 2.60 2.21 2.21 2.12 2.28 2.51 2.44 2.44 2.21 2.60 2.28 2.60 2.99 2.76 2.83 3.07 3.07 2.99 2.84 2.91 2.83 3.31 3.23 3.30 8736.0 8743.2 8734.8 8732.4 8728.2 8727.0 8731.8 8732.4 8731.2 8729.4 8734.8 8747.4 8736.6 8734.2 8739.0 8745.0 8744.4 8737.2 8730.6 8746.8 8740.8 8745.6 8748.6 8730.0 8740.8 8739.0 8733.6 8749.8 8751.6 8754.0 8748.6 8750 4 8751.6 8746.8 8748.0 8754.6 8753.4 8748.0 8754.0 8752.2 

### NH3Inj lb/hr 0-200 198.2 197. 0 196.3 197.7 198.3 197.8 165.3 198.5 198.3 197.8 198.2 199.0 182.2 200.0 199.3 190.3 198.2 199.3 198.7 198.0 198.5 198.0 198.3 163.8 199.8 165.7 199.3 165.5 170.5 199.8 170.2 200.0 165.8 199.0 199.0 200.0 200.0 198.8 198.3 198.7 

### S>Summary

- I-Min RATA

- Continued MW Lo 0-1 106.1 106.1 106.1 106.1 106.1 106. ! 106.1 106.1 106.1 105. 105. : 105. : 106.1 106.1 106. 1 106.1 106.1 106.1 105. : 106. c 106 .. 106. ! 106. c 106.1 106.1 106.1 106.1 106.1 106.1 106.1 105. : 106.c 106.1 106.! 106. c 106.1 106. c 105. 105. 106. c PagE

### Group#

- Channel# Long Descrip. Short Descrip. Units Range 02/25/2013 14;06 02/25/2013 14:07 02/25/2013 14:08 02/25/2013 14:09 02/25/ 20 13 14;10 02/25/2013 14;11 02/25/2013 14:12 02/25/2013 1 4:13 02/25/2013 14:14 02/25/2013 14;15 02/25/20 13 14:16 02/ 25 /2013 14:17 02/25/2013 14:18 02/25/2013 14:19 02/25/2013 14:20 02/25/2013 14:21 02/25/2013 14:22 02/25/2013 14:23 02/25/2013 14:24 02/25/2013 14:25 02/25/2013 14:26 02/25/2013 14:27 02/25/2013 14:28 02/25/2013 14 : 2 9 02/25/ 2013 14:30 02/25/2013 14:31 02/25/2013 14:32 02/25/2013 14:33 02/25/2013 14:34 02/2 5 /2013 14:35 02/2 5 /2013 14:36 02/25/2013 14:37 02/25/2013 14:38 02/ 25 / 20 13 1 4 :39 02/ 25 /2013 14:40 0 2 / 25/20 13 14:41 02/25/2013 1 4:42**Q. .Q** **.~ 1;** **~** 

### 02/25/201 3 1 4,44 02/25/2013 14:45 

### Date/Time Printed: G45-C4 G45-C11 G45

- C20 G45-C2 S>Stk NOx

Stk NOx 

### ppm 0

- 150 5>Stk 02 5>NOx Mass 5>StkFlow

1.9 1.9 1.8 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 1.9 2.4 2.5 2.2 2.1 2.8 2.0 1.8 1.9 1.9 1.9 1.9 1.8 1.9 1.9 1.8 1.9 

# .. , 1.9 1.9 

### Stk 02 

# • 0-25 13 .4 0 13 .40 13 .40 13 .39 13.39 13.40 13.41 13 .40 13 .4 1 13 .41 13. 4 0 13.40 13.40 13 .4 0 13. 4 1 13 .40 13 .39 13 .4 0 13 .40 13 .40 13 .40 13 .4 1 13 .41 13 .41 13 .4 1 13.40 13 .41 13.41 13 . 40 13 .40 13 .40 13 .40 13 .40 13 .40 13.40 13. 40 13.40 lJ , 10 

### 13 .40 13 .4 0 

### 02/25/2013 21,32 NOx Mass 

### Ib/hr 0

- 100 5.51 5.52 4.60 4.60 4.59 5.51 5.52 5.52 5.51 5.51 5.52 5.51 5.52 5.52 5.51 5.52 4.60 5.52 5.51 5.52 5.51 6.43 6 . 4 3 5.52 5.51 7.35 5.51 4.59 5.51 5.51 5.52 5.51 4.59 5.51 5.51 4.60 5.51 

## :J , :n 5.51 5.51 StkFlow kscfh 0-300000

22305 22310 22305 22291 22274 22293 22340 22318 22338 22331 22312 22299 22316 22312 22309 22313 22282 22312 22308 22316 22298 22332 22309 22344 22314 22313 22326 22317 22307 22299 22310 22305 22296 22299 22293 22305 22279 

## ZZZ'G 22284 22308 G45-C3 G45-C13 G45

- C10 G45-C6 G45-C7 G45

- C8 G45

- C18 G45-C 5>Stk CO 5>CO Mass 5>NOx Rate 5>Stk NOXe 5>Stk COe 5>Gas Flow 5 >NH3 Inj 5>MW La

Stk CO 

### ppm 0-1000

4.0 3.8 4.1 4.2 4.4 4.3 4.0 4.4 4.0 3.7 4.1 3.9 3.9 3.7 3.6 3.4 3.9 4.0 3.8 4.2 3.8 3.5 3.2 3.' 3.6 3.7 4.0 3.4 3.5 3.5 3.5 3.9 4.0 3 .1 3.6 3 .6 3.' 

### J . G 3.5 3. 4 CO Mass 

### Ib/hr 0-100 6.43 6.43 6.43 6.44 7.35 7.35 6.43 7 . 36 6.43 6.43 6.43 6.43 6 . 44 6.43 5.51 5.52 6.43 6.43 6.43 6.44 6.43 5.51 5.51 5.52 5 . 51 6.44 6.43 5.51 5.51 5.51 5.52 6.43 6.43 4.59 5.51 5 . 51 5.51 5.51 

### 5.51 5.51 NOx Rate 

### Ib/mmBtu 0

- 1 0.006 0.006 0.005 0.005 0.005 0.006 0.006 0.006 0 . 006 0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.006 0.006 0.007 0.007 0.006 0.006 0.008 0.006 0.005 0.006 0.006 0.006 0.006 0.005 0.006 0.006 0.005 0.006 

### 0 . 006 0.006 0.006 Stk NOXc 

### ppm 0-300 1.49 1.49 1.42 1.49 1.49 1.49 1. SO 1.49 1. 50 1. 50 1. 49 1.49 1.49 1.49 1. 50 1. 49 1. 49 1. 49 1. 49 1.49 1. 49 1. 89 1. 97 1. 73 1. 65 2.20 1. 58 1.42 1.49 1.49 1. 49 1. 49 1. 4 2 1.49 1. 49 1.42 1.49 1.4' 1.49 1.49 Stk COe Gas 

### ppm hsefh hsefh 0-1000 3.15 2.99 3.23 3.30 3.46 3.38 3.15 3.46 3.15 2.91 3.23 3.07 3.07 2.91 2.84 2.67 3.06 3.15 2.99 3.30 2.99 2.76 2.52 2.68 2.84 2.91 3.15 2.68 2.75 2.75 2.75 3.07 3.15 2.44 2 .83 2.83 2.67 

### 2.6J 2.75 2.67 0

- 10000 8752.2 8754.0 8752.2 8758.2 8751.6 8747.4 8754.0 8757.0 8753. 4 8750.4 8754.6 8749.8 8756.4 8754.6 8742.0 8755.2 8754.6 8754.6 8753.4 8756.4 8749.2 8751.0 8742.0 8755.8 8743.8 8755.2 8748.G 8745.0 8752.8 8749.8 8754.0 8752.2 8748.6 8749.8 8747.4 8752.2 8742.0 

### 67 4 6.6 874 3. 8 8753.4 NH3Inj 

### Ib / hr 0-200 198.2 198.7 198.3 197.2 198.0 1G4.3 199.2 197.7 198.3 198.5 197.5 199.7 196.8 198.8 198.3 198.3 199.5 198.7 199.2 197.5 197.5 163.7 200.0 187.5 162.3 200.0 199 . 8 200.0 159 . 5 200.0 200.0 198.2 198.5 200.0 199.7 200.0 199.5**D~.O** 

### 200.0 199.3 

### S>Summary

- I-Min RATA

- Continued MW La 0-1 106.1 lOG.**~** 106.1 

### IDS. 105. 106.**~** 106.1 105. 106.1 105. : 106. ! lOG .1 106 .1 106.1 106. 1 106.1 106.1 lOG .1 lOG .1 106. ! 106, ! 106. ! 106. ! 106 . ! lOG. ! 106.1 105 106.1 106 . . 106.1 106,1 106.1 106 .1 106.1 10 6 .1 106,1 106 . 1 

### 106. IDS. 106.1 

### Pag(

### Group#-Channel# Long Descrip
. Short Descrip
. Units Range 02/25/2013 14:46 02/25/2013 14:47 02/25/2013 14:48 02/25/2013 14:49 02/25/2013 14;50 02/25/2013 14:51 02/25/2013 14:52 02/25/ 2 013 14:53 02/25/2013 14:54 02/25/2013 14:55 02/25/2013 14:56 02/25/2013 14:57 02/25/2013 14:58 02/25/2013 14:59 02/25/2013 15:00 02/25/2013 15:01 02/25/2013 15:02 02/25/2013 15:03 02/25/2013 15:04 02/25/2013 15:05 02/25/2013 15:06 02/25/2013 15:07 02/25/2013 15:08 02/25/2013 15:09 02/25/2013 15:10 02/25/2013 15:11 02/25/2013 15:12 02/25/2013 15:13 02/25/2013 15:14 02/25/2013 15:15 02/25/2013 15;16 02/25/201) 15:1 7 02/25/2013 15;18 02/25/2013 15:19 02/25/2013 15:20



### Date/Time Printed: G45-C4 G45-Cll G45-C2 5>Stk NOx

Stk NOx 

### ppm 0-150 5>Stk 02 5>NOx Mass

1.8 1.8 2.6 1.9 1.8 1.8 1.9 

### 2.1 2.9 

### 2.1 1.9 1.8 1.9 1.9 1.8 1.8 1.8 2.7 

### 2.0 1.9 6.1 

### 2.0 1.8 1.8 1.8 

### 2.1 2.7 1.9 1.9 2.6 1.9 1.9 2.7 1.9 1.8 Stk 02 

# • 0-25 13 .40 13 .40 13 .40 13 .40 13 .40 13 . 40 13 .40 13 .4 0 13 .39 13 .40 13 .39 13 .39 13.38 13.38 13.39 13.39 13 .39 13.40 13.39 13 .40 13 .40 13.39 13 .39 13 . 39 13.39 13.39 13.39 13.39 13.40 13 .39 13 .39 13 .40 13 .39 13.39 13.39



### 02/25/2013 21 ,32 NOx Mass lb/hr 0-100 4.60 4.60 7.35 5.51 4.59 4.60 5.52 5.52 7.36 5.51 4.60 4.60 4.60 4.60 4.59 4.60 4.60 7.36 5.52 5.52 16.55

5.52 4.60 4.60 4.60 5.52 7.36 4.60 5.52 7.36 4 .60 5.52 7.36 4.60 4.60 G45-C20 5>StkFlow

StkFlow

kscfh 0-300000

22307 22310 22293 22307 22296 22308 22331 22315 22285 22299 22299 22311 22278 22278 22238 22286 22291 22334 22303 22321 22319 22282 22292 22305 22292 22308 22294 22314 22330 22292 22302 22328 22305 22305 22305 G45-C3 5>Stk CO

Stk 

### co ppm 0-1000

3.7 

### 3.1 3.6 3.4 3 .6 3.7 3.9 3.8 4.2 3.7 4.0 4.5 4.7 4.7 4.6 4.1 4.2 4.4 4.1 4.4 4.0 3.9 4.3 4.3 4.5 4.0 4.4 4.3 4.2 4.4 4.1 4.3 4.3 4.7 4.5 G45-C13 G45

- C10 G45-C6 5>CO Mass S>NOx Rate 5>Stk NOXe

CO Mass lb/hr 0-100 6.43 4.60 5.51 5.51 5.51 6 .4 3 6.44 6.44 6 .44 6.43 6.44 7.36 7.36 7.36 7.34 6.44 6.44 7.36 6.44 7.36 6.44 6.43 7.36 7.36 7.36 6.44 7.36 7.36 6.44 7.36 6.44 7.36 7.36 7.36 7.36 NOx Rate lb/mmBtu 

### 0-1 0.005 

### 0.005 0.008 0.006 0.005 0.005 0.006 0.006 0.008 0.006 0.005 0.005 0.005 0 . 005 0.005 0.005 0.005 0.008 0.006 0.006 0.018 0.006 0.005 0.005 0.005 0.006 0.008 0.005 0.006 0.008 0.005 0.006 0.008 

### 0.005 0.005 Stk NOXe 

### ppm 0-300 1.42 1.42 2.05 1.49 1.42 1.42 1.49 1. 65 2.28 1. 65 1.49 1.41 1.49 1.49 1.41 1. 41 1. 41 2.12 1. 57 1. 49 4.80 1. 57 1.41 1.41 1.41 1. 65 2.12 1.49 1.49 2.04 1.49 1.49 2.12 1.49 1.41 G45

- C7 G45-C8 5>Stk CDc 5>Gas Flow

Stk COe 

### Gas hsefh ppm hsefh 0-1000 0-10000 2.91 2.44 2.83 2.67 2 . 83 2.91 3.07 2.99 3.30 2.91 3.14 3.54 3.69 3.69 3.61 3.22 3.30 3.46 3.22 3 . 46 3 . 15 3.06 3.38 3 . 38 3.54 3.14 3.46 3.38 3.30 3.46 3.22 3.38 3.38 3.69 3.54 8752.8 8754.0 8747.4 8752.8 8748.6 8753.4 8762.4 8755.8 8755.8 8749.8 8761.2 8766.0 8764.8 8764.8 8737.2 8756.4 8758.2 8763.6 8763.0 8758.2 8757.6 8754.6 8758.8 8763.6 8758.8 8764.8 8759.4 8767.2 8761. 8 8758.8 8762.4 8761.2 8763.6 8763.6 8763.6 G45-C18 5>NH3 Inj NH3Inj

lb/hr 0-200 134.2 200.0 176.2 200.0 200.0 199.0 200.0 180.7 164.8 200.0 200.0 165.5 199.0 199.0 200.0 200.0 191. 3 178.5 166.2 188.0 164.3 200.0 200.0 200.0 181. 5 200.0 176.5 200.0 173.0 200.0 200.0 168.7 200.0 200.0 200.0



### S>Summary

- l-Min RATA

- Continued G45-C 5>MW 

### Lo

MW La



### 0-1 106.1 106. 1 106. ( 106.1 106.1 105. 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106. ( 106.: 106.1 106. : 106. ( 105. 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106.1 106. ( 106. ( 106. 1 106. ( 106.1 106. 1 106 .1



### Pag(

### Period Average 

# = 2.0 13 . 43 5 . 49 22377 3.3 5.40 0.006 1. S4 2.63 87 4 7.4 193.8 105.9 

### Period Max Value 6.1 13 . 4 8 16.SS 22SSS 4.7 7.36 0.018 4 .80 3.69 8767.2 200.0 106. 

### Period Min Value l.8 13 . 38 4.S9 22238 2.1 3.67 0.005 1.41 1. 66 8727.0 120.8 105. 

### Period Totals =: 5.1840E+2 3.5584E+3 1.4549E+3 5.9299E+6 8.8230E+2 1.4311E+3 1 . 5840E+0 4.0917E+2 6.9651E+2 2.3180E+6 5.1355E+4 2.8074E+ 

### Period 

### % Recovery 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100 . 0 100.0 100.0 100.

## Appendix B.2 Fuel Analysis Data

R521 0729 8-6

### SAYBOLTLP 21730 S. Wilmington Avenue Suite 201 

## Fast To The Point 

# .4\ 5aybol1: Carson, CA 90810 310-518-4400 Telephone 310-518-4455 Facsimile 

# Saybolt LP
" [ORI LABORAtORIES CnMPAHY 

## SUBMITTED LAB ANALYSIS CONFIRMAnON FORM CUSTOMER INFORMATION SAYBOL T INFORMATION Customer Name: DELTA AIR QUALITY SERVICES Completed 

### By: Gary Dela Cruz Job Nominated 

### By: BOB FINKEN Date: 

### 31112013 Report Results To: BOB FINKEN Job Number: 1300191 Phone Number: (714)279-6777 Fax Number: (714)279-6781 Email: SAMPLE INFORMATION 

### Product: Quanti!): Received: 

### VessellTankIDescriution: TYQe of Saml21e: Samu1e Marked As: POIRef# Gas 

### I-tedlar bag Sample #S5lFuel Sulfur

- Submitted Sample #S5lFuel Sulfur - I A Gas I-tedlar bag Sample #S5lFuel Sulfur

- 

### Submitted Sample #S5lFuel Sulfur

- 1 B Gas I-tedlar bag Sample #S6lFuel Sulfur

- Submitted Sample #S6lFuel Sulfur

- IA Gas 

### I-tedlar bag Sample #S6lFuel Sulfur

- Submitted Sample #S6lFuel Sulfur - I B

Referring to your sample submission dated 3/112013 

### 1:32:34 PM, we would like to thank you for appointing Saybolt 

### and herewith confirm acceptance of your order for the analyses listed below: TEST 

### 1METHOD (IF KNOWN) Carbon Dioxide I ASTM D19451D1946 Hydrogen Sulfide I AQMD 307/ASTM 05504



### COST DISTRIBUTION: Client DELTA AIR QUALITY SERVICES Percent 100 

### TEST 

### 1METHOD (IF KNOWN) Hydrogen I ASTM Dl9451D1946 Molar Mass Ratio I ASTM 0-3588

Please advise whether your sales/purchase contract contains a Final and Binding clause with respect to Saybolt's findings. We thank you for your support and look forward to mecting all your analytical needs in the future. If you arc satisfied with our services do tell others. If you arc NOT satisfied, please do tell us <http;lIwww.saybolt.com/complaint.nsf).> All our activities are carried out under our gencraltcnns and conditions and in accordance with our code ofpraetiec. The General Tenns Conditions can be consulted at «hnp:llwww.corelab.comisayooltiLega1fLegaLasp», and w ill be sent upon request free of charge
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### elF 05-06-004 rev 

### 0 Page 1 of 1

# A 5aybo lt: II C

OR E L ABORAT ORIES C OM P

A N Y 

## SAYBOLT LP 21730 S . Wilmington Avenue Suite 201 Carson , CA 90810 310-518-4400 T e lephone 310-518-4455 Facsimile 

## Fast To The Point 

# Saybolt LP 

# Certificate of Analysis DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N. CASE ORANGE, CA 92865 Date Sampled : 2/28/2013 

### Report Date : 3/612013 

### Product: Gas Job No : 13091-00008644 Location : Santa Ana, CA Sample Number : 1300191-01 Sample ID : Sample #S5/Fuel Sulfur - 1 A Client Ref : Sentinel Vessel: Test Method Result Units Refinery Gas Analysis Hydrogen ASTM D 1 945/D1946 

### < 0001 mo l e% Carbon Dioxide ASTM D1945/D1946 

### 0
. 321 mo l e% Carbon Monoxide ASTM D1945 /D1946 

### <0001 mo l e % Nitrogen ASTM D1945/D1946 

### 3.261 mole% Oxygen ASTM D 1945/D 1946 

### 0
. 007 mole% Methane ASTM D 1945/D 1946 

### 90
. 772 mole% Ethylene ASTM D1945/D1946 

### <0001 mole% Ethane ASTM D 1945/D 1946 

### 4
. 803 mole% Propane ASTM D 1945/D 1946 

### 0
. 670 mole% Propylene ASTM D 1945/D 1946 

### <0001 mole% Isobutane ASTM D1945/D1946 

### 0
. 042 mole% n-Butane ASTM D 1945/D 1946 

### 0
. 083 mole% 1-Butene ASTM D 1945 /D 1946 

### <0001 mole% Isobutylene ASTM D 1945/D 1946 

### <0.001 mole % t-2-Butene ASTM D1945/D1946 

### <0.001 mole % c -2-Butene ASTM D1945/D1946 

### <0
. 00 1 mole % 1 , 3-Butadiene ASTM D1945/D1946 

### < 00 01 m o le % Isopentane ASTM D1945/D1946 

### 0
. 009 mole% n-Pentane ASTM D1945/D1946 

### 0.009 mole% Hexanes Plus ASTM D1945/D1946 

### 0.023 mole % Total ASTM D1945/D1946 

### 100
. 000 mo l e% Molar Mass Rat i o ASTM D-3588 0.60306 Relat ive Density ASTM D-3588 0
. 60521 Compressability Factor ASTM D-3588 0.996 Gross Heating Value (Dry-Ideal) ASTM D-3588 1025 BTU /cf Gross Heating Value (Dry-Real) ASTM D-3588 1029 BTU/cf Gross Heating Value (Wet-Ideal) ASTM D-3588 1007 BTU /cf Net Heating Value (Dry-Ideal) ASTM D-3588 923 BTU/cf Issu e r warran ts that it has exercised du e diligence a nd care with re s pec t to thc informati on and p rofessional jud gments embodied in th is repon . This report reAee ts only t h e fi ndings al the lime and place of ins pection a nd testing. I s suer expressly disclaims a ny further indemni t y of any kind
. This report is nO I a guarantee or p o li cy of insurance w i th respect to the goods or the contractual perf ormance oran y party. Any person relyi ng upon this re pon should be aw are that issuer's activi ties are carried out un<Jer t hei r general terms and con diti ons "Precisio n paramet ers apply in the evaluat ion of the test re sults specified abov e , Ple ase als o refer!O ASTM D3244 (eXCept for analysis ofRFG) and IP 367 with respect to the utilization of the tes t data to de termine conforman c e with specifications ," 

### Page 1 of 12

## SAYBOLTLP 21730 S. Wilmington Avenue Suite 201 

## Fast To The Point 

# 5ayb[)It Carson , CA 90810 310-518-4400 Telephone 310-518-4455 Facsimile A CORt LABnRATORIES COtlPAHf



### OELTA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 Report Oate : 3/6/2013 Job No: 13091-00008644 Sample Number : 1300191-01 Client Ref : Sentinel Test 

## Refinery Gas Analysis Pressure Base Ethylene Ethane Propane Propylene Isobutane n-Butane 1-Butene Isobutylene t-2-Butene c-2-Butene 1 , 3-Butadiene Isopentane n-Pentane Hexanes Plus Total Carbon Hydrogen Nitrogen Oxygen Gross Heating Value Fuel Factor (FO) Average Molecular Weight 

## Sulfur Speciation Hydrogen Sulfide Carbonyl Sulfide Sulfur Oioxide Methyl Mercaptan 

# Certificate of Analysis

Oate Sampled: Product: Location: Sample 10 : Vessel: Method Result ASTM 0-3588 14
. 696 ASTM 0-3588 <0.001 ASTM 0-3588 1
. 282 ASTM 0-3588 0
. 184 ASTM 0-3588 <0001 ASTM 0-3588 0
. 014 ASTM 0-3588 0.026 ASTM 0 - 3588 <0001 ASTM 0-3588 <0001 ASTM 0-3588 <0
. 001 ASTM 0-3588 <0.001 ASTM 0-3588 <0.001 ASTM 0-3588 0
. 003 ASTM 0-3588 0
. 003 ASTM 0-3588 0
. 009 ASTM 0-3588 1.521 ASTM 0-3588 71.148 ASTM 0-3588 23
. 019 ASTM 0-3588 5.232 ASTM 0 -3588 0.601 ASTM 0-3588 21866 ASTM 0-3588 8831 ASTM 0 -3 588 1747 AQMO 307/ASTM 05504 <0.1 AQMO 307/ASTM 05504 <0.1 AQMO 307/ASTM 05504 <0
. 1 AQMO 307/ ASTM 05504 <0.1 

# Saybolt LP

2/28/2013 Gas Santa Ana , CA Sample #S5 / Fuel Sulfur - 1A Units psi GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM wt % wt% wt% wt% BTU/lb SCF /m m BTU
ppm v/v ppm v/v ppm v/v ppm v /v Issuer warrants thai il has**ex~rcised** due diligence and care wilh**res~t** 10 the in fo rmation.nd professional judgments embodied in this report This repon reflects only tile findings at the lirne and place of in speclion and testing. Issuer expressly disclaims any further indemnity of any kind. This repon is not a guarantee or policy of insurance with respect 10 th e goods or the cont ractual performance of any party AIly person relying upon th is report should be aware that issutr's activities are carried out under their general terms and conditions
.

" Precisi on parameters apply in the evaluation of the test results spedfied above
. Please al50 refer to ASTM 03244 (except for analysis ofRFG) and JP 367 with respec t to the utiliution of the test data to determine conformall(:e with specifications."' 

### Page 2 of 12

## SAYBOLTLP 21730 S. Wilmington Avenu e Suite 201 

## Fast To The Point 

# SByb[]lt: Carson, CA 90810 310-518-4400 Telephone 310-518-4455 Facsimile 

# Saybolt 

# LP
A CDIU LABDRAT O RIES COI1PA K Y



### DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N. CASE ORANGE, CA 92865 Report Date : 3/612013 

### Job No 13091-00008644 Sample Number: 1300191-01 Client Ref: Sentinel Test Sulfur Speciation Ethyl Mercaptan Dimethyl Sulfide Carbon Disulfide 2 - Propanethiol tert-Butyl Mercaptan 1-Propanethiol Thiophene Diethyl Sulf i de n-Butyl Mercaptan Dimethyl D isulfide tetra-Hydro Thiophene n-Pentanethiol D i ethyl Disulfide Total Unknown Mercaptan Total Reduced Sulfur 

# Certificate of Analys is

Date Sampled: 2/ 28/2013 

### Product: Gas Location : Santa Ana, CA Sample ID : Samp l e #S5 / Fuel Sulfur - 1A Vessel : Method Result Units AQMD 307/ASTM D5504 < 0.1 ppm v/v AQMD 307/ASTM D5504 <0
. 1 ppm v/v AQMD 307/ASTM D5504 <0
. 1 ppm v/v AOMD 307/ASTM D5504 <0
. 1 ppm v/v AQMD 307/ASTM D5504 <0.1 ppm v /v AOMD 307/ASTM D5504 < 0
. 1 ppm v/v AOMD 307/ASTM D5504 < 0.1 ppm v/v AQMD 307/ ASTM D5504 < 0.1 ppm v /v AQMD 307/ASTM D5504 <0. 1 pp m v /v AQMD 307/ASTM D5504 <0.1 ppm v /v AQMD 307/ASTM D5504 0
. 1 ppm v/v AQMD 307/ASTM D5504 <0
. 1 ppm v/v AQMD 307/ASTM D5504 <0 .1 ppm v/v AQMD 307/ASTM D5504 < 0
. 1 ppm v/ v AQMD 307/ASTM D5504 0
. 1 ppm v /v

App roved BY : ,3 

# CV){Y'I,& YlCD

# c\?h-....O~ Francine

## Hanby**~-::..J** Laboratory Manager

Issuer warrants that it has**exerci~ d**  due diligence and care with respect to the inf ormati on an d professional ju dgments embodied in th is report . This report reOects only the findings at the time an d place of inspection and testing. issuer express ly disclaims an y further indemnity of an y kind
. Thi s repon is not a guara nt ee or policy of insurance with r espec t to the goods or the cont ractua l perfonnance of any p arty . Any person rely ing upon this report should be aware that issuer's activities are carri ed ou t under their g eneral terms a nd co nditions
.

" Prec isi on parame ters apply in the evaluation of the test resu lt s specified abo v e Plea se als o re fe r to ASTM D3244 ( ex c ept for analys is of RFG) and IP 367 with respect to the mili zation of th e te st dat a to de termine conforma nce with sp ecifications" 

### Page 3 of 

### 12

# Saybol't II COilE LABORATORIES COI'!PA N Y 

### SA YBOLTLP 2173 0 S. Wilmington Avenue Suite 20 1 Ca rson, CA 90810 310 -518 -4400 Telephone 310 -5 18- 4455 Fac simi l e 

## Fast To The Point 

# Saybolt 

# LP Certificate of Analysis DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 Report Date: Job No: 3/6/2013 

### 13091-00008644 Sample Number : 1300191-02 Client Ref : Sent i ne l Test Refinery Gas Analysis Hydrogen Carbon Dioxide Carbon Mono xide Nitrogen Oxygen Methane Ethylene Ethane Pro pane Propy lene Isobutane n-Butane 1-Butene Isobutylene t-2-Butene c-2-Butene 1 , 3- Butad ie ne Isopentane n-Pentane Hexanes Plus Total Molar Mass Ratio Relati ve Dens ity Compressability Fact o r Gross Heating Value (Dry-Ideal) Gross Heating Value (Dry-Real) Gross Heating Value (Wet-Ideal) Net Heating Va lue ( Dry-Idea l) Method ASTM 0194510194 6 ASTM 01945101946 ASTM 01945 / 01946 ASTM 01945 / 01 946 ASTM 01945 /01946 ASTM 01945 /01946 ASTM 01945/01946 ASTM 01945 /01946 ASTM 01945/ 0 1946 ASTM 01945/ 01946 ASTM 01945 / 01946 ASTM 01945/01946 ASTM 01945/01946 ASTM 01945 /01946 ASTM 01945 /0 1946 ASTM 0 1945/ 0 19 46 ASTM 01945/ 01946 ASTM 01945 / 01946 ASTM 01945 / 01946 ASTM 01945/01946 ASTM 01945 / 0194 6 ASTM 0 -3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 ASTM 0-3588 Date Sampled 2/2 8/201 3 

### Product: Locat ion : Sample 10 : Vessel : Result <000 1 0.302 <0
. 001 14
. 666 0.739 79
. 050 <0001 4.453 0.637 <0001 0
. 037 0.082 <0001 <000 1 <0001 <000 1 <0
. 001 0.012 0.005 0
. 017 100.000 0.65177 0
. 65345 0
. 997 899 901 883 806 Gas Santa Ana , CA Sample #S5/ Fue l Sulfur - 1B Units mole% mole% mole % mo le% mole% mole% mole% mole% mole % mole % mole% mole% mole% mole% mole% mole % mole % mole % mole% mole% mole%

BTU/cf BTU/cf BTU /cf BTU /cf Issuer warrants that it has uercised due diligeoce and care witll respect to the information and professional judgmenu embodied in this n:pon This rcp o rt reneels onl y the findings at lhe lime and place ofinspection and testing. Issuer expressly disclaims lny further indemnity of any kind This report is 1101 a guarantee or policy ofinsuraocc with respect 10 the goods or t he conlraclUal pcrfomlance of any pany Any peTSOn relying upon this report should be aware \hall!Wer's ac; l ivi l ies are carried out under their general tenns and condit ions "Precision parameters apply in the eyalUaTion of The TeS! resulTs specified abo ve Ple a se also ref er TO ASTM**D3~44** (exc e pt for analysis of RFG) and lP 367 with respect 10 lhe UTilization of the les\ data to determine conformance w ith spec i fica tions
. " 

### Page 4 of 12

## SAYBOLTLP 2 1730 S. Wilmington Avenu e Suite 201 

# Fast To The Point 

# 5aybolt Carson , CA 90810 3 10-518-4400 T e lephon e 3 10- 5 18-4455 Facs imil e A toRr LABOIlATOR[[S COItPANY 

# Certificate of Analysis OEL TA AIR QUALITY SERVICES BOB FINKEN 1845 N
. CASE ORANGE , CA 92865 Oate Sampled: Report Oate : 3/6/2013 

### Product: Job No : 13091-00008644 Location: Sample Number : 1300191-02 Sample 10 : Client Ref : Sentinel Vessel : Test Method Result Refinery Gas Analysis Pressure Base ASTM 0- 3588 14
. 696 Ethylene ASTM 0- 3588 <0001 Ethane ASTM 0-3588 1
. 188 Propane ASTM 0-3588 0
. 175 Propylene ASTM 0-3588 <0
. 001 Isobutane ASTM 0-3588 0
. 012 n-Butane ASTM 0-3588 0
. 026 1-Butene ASTM 0 - 3588 <0
. 001 Isobutylene ASTM 0-3588 <0
. 001 t-2-Butene ASTM 0-3588 <0
. 001 c-2-Butene ASTM 0-3588 <0
. 001 1 , 3-Butad iene ASTM 0-3588 <0
. 001 Isopentane ASTM 0-3588 0
. 004 n-Pentane ASTM 0-3588 0
. 002 Hexanes Plus ASTM 0- 3 588 0
. 007 Total ASTM 0-3588 1.414 Carbon ASTM 0-35 88 57.806 Hydrogen ASTM 0 - 3588 18.660 Nitrogen ASTM 0 - 3588 21.769 Oxygen ASTM 0 - 3588 1
. 765 Gross Heating Value ASTM 0-3588 17726 Fuel Factor (FD) ASTM 0 - 3588 8948 Average Molecular Weight ASTM 0-3588 18.88 Sulfur Speciation Hydrogen Sulfide AQMO 307 / ASTM 05504 

### <0
. 1 Carbonyl Sulfide AQMO 307/ASTM 05504 <0
. 1 Sulfur Oioxide AQMO 30 7/ ASTM 05504 <0
. 1 Methyl Mercaptan AQMO 307/ASTM 05504 <0.1 

# Saybolt LP

2/28/2013 

### Gas Santa Ana , CA Sample #S5 / Fuel Sulfur - 1 B Units ps i GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM wt % wt % wt % wt% BTUllb SCF /

mm 

### BTU
ppm v/v ppm v/v ppm v /v ppm v /v Issuer warrann thaI it ha s exercised due diligence and care with respect to the information and professional judgments embodied in this report This report rcileclS only the findings 81 ttle time and place ofinspection and testing
. (ssu cr expressly disclaims any further indemni ty of any k ind
. This report is 1'101 a guarantee or policy of insurance with respec t !O the goods or the contractual performance efany party _Any person relying upon this report shol.lld be aware that issuer's activities are carried out under their generallerms and conditions
. "Precision parameters app ly in the evaluation of the te s t r

e sults spec i fied above Pl ease also refer to ASTM D3244**(e~cept** for anal ys i s of RFG) and l P 367 with re spec t to lhe ut ilization of the lest data to de termine conformance with specifications
. " 

### Page 5 of 12

### SAYBOLT LP 2 1730 S
. Wilmin gt on Avenu e Su i te 20 I 

# Fast T o T he Point 

# S aybolt:

,., (ORE L A BORATDRIES CUMP"HY 

### Carson , CA 90810 3 10-518-4400 T el e phone 310 - 518-4455 Facsimile 

# Certif i cate of Analys is DELTA AIR QUALITY SERVICES BOB FINKEN 1845 N. CASE ORANGE, CA 92865 

# Saybolt LP

Date Sampled : 

### 2/ 28/2013 Report Date : Job No : 

### 3/612013 13091-00008644 Sample Number : 1300191-02 Client Ref : Sentine l Test Sulfur Speciation Ethyl Mercaptan Dimethyl Sulfide Carbon Disulfide 2-Propanethiol tert-Butyl Mercaptan 1-Propanethiol Thiophene Diethyl Sulfide n-Butyl Mercaptan Dimethyl Disulfide tetra-Hydro Th iophene n-Pentanethiol Diethyl Disulfide Total Unknown Mercaptan Total Reduced Sulfur Produ ct: Gas Loca ti on : Santa Ana , CA Samp l e ID : Sample #S 5/ Fuel Sulfur - 1 B Vessel : Method Result Units AQMD 307/ASTM D5504 <0. 1 ppm v/v 

### AQMD 307/ASTM D5504 <0
. 1 ppm v/v 

### AQMD 307/ASTM D5504 <0.1 ppm v / v 

### AQMD 307/ASTM D5504 <0
. 1 ppm v / v 

### AQMD 307/ASTM D5504 <0. 1 ppm v / v 

### AQMD 307/ASTM D5504 <0. 1 ppm v / v 

### AQMD 307/ASTM D5504 <0. 1 ppm v / v 

### AQMD 307/ASTM D5504 <0
. 1 ppm v / v 

### AQMD 307/ ASTM D5504 <0. 1 ppm v / v 

### AQMD 307/ASTM D5504 <0. 1 ppm v / v 

### AQMD 30 7/ASTM D5504 0. 1 ppm v / v 

### AQMD 307/ASTM D5504 < 0
. 1 p pm v /v 

### AQMD 307/ASTM D5504 < 0
. 1 ppm v / v 

### AQMD 307/ASTM D5504 0. 1 ppm v / v 

### AQMD 307/ASTM D5504 0
.2 ppm v / v



### Approved By : 

# .3-

- Franc i ne Hanby Laboratory Manager

Issuer warrants that it has exercised due diligence and care with respe<:t to the info rmation and professional judgments embodied in this report , T his report reflects only the r,n di ng, at the time and place of in s pection and testing
. Issuer ex pressly disclaims any further indemnity of a ny kind
. This report is not a guarantee or policy of insurance with respect to the goods or the contractual performance o f any party, Any person relying upon this report should be aware that issuer's activities are carried out under their general tc r ms and conditions "Precision parameters apply in the evalu ation ofthe te s t re su lt s specified above
. Pl ease also ref
... ,. to ASTM 0 3244**(e~c pt**  for analysis of RFG) and IP 367 with respect to the utilization of t he te st data to de termine conformance with specifications
. " 

### Page 6 

### of 12

# APPENDIXC TEST DATA

R521 0729 

### C-1

## Appendix C.1 Stratification and Preliminary Flow Rate Tests

R5210729 C·2

### 12-POINT STRATIFICATION CHECK Gemma 5 

### 2/25/2013 

### 02 CO2 NOx CO Port Point % % ppm ppm



## W 3 13.24 4.54 2.23 2.18 

## W 2 13
.24 4.54 2.24 3.08 

## W 1 13.25 4.54 2.24 2.40



## S 3 13.25 4.54 1.93 3.35 

## S 2 13.64 4.31 1.98 3.94 

## S 13.62 4.32 1.66 3.54 

## E 3 13.55 4.40 1.92 3
. 80 E 2 13.53 4.41 1.89 4.03 E 13.50 4.43 1.79 4.22 N 3 13.53 4.42 1.93 4.69 N 2 13.53 4.43 1.90 4.17 N 13.49 4.45 1.78 3.69 Average 13.4 4.4 2.0 3.6 Maximum 13.6 4.5 2.2 4.7 Minimum 13.2 4.3 1.7 2.2 Maximum Difference from Average 0
.2 0.1 0.3 1.4 Max Difference (% of average) 1
. 5% 3.0% 15.4% 39
.3%
Criteria :

If < 

### 10%, use single point.TEST CONSTANTS RELATIVE ACCURACY TEST DATA AND WORKSHEET CPV Sentinel · 5·CEMS ·1 02 - STRAT TEST VARIABLES Station : CPV Sentinel Start Dale: 2 / 25

/ 2013 Unit: 5 Performed 

### By : AA , MC, RM , JM Cp : 0 .8 4 Tref : 68 

### o f Stack Area : 143
. 14 ft' MeterY d : 1.014 METHOD 2,1 DATA dP Temp Vel. Point (in
. H 2O) sqrt(dP) 

### of (fps)

4 1
. 80 1
. 3416 723 113.63 3 2
. 10 1
. 4491 722 122
. 68 2 2
. 20 1.4832 722 125
. 57 1 2
. 50 1
. 5811 722 133
. 86 4 1
. 90 1.3784 728 116
. 99 3 2
. 10 1.4 491 728 122
. 99 2 2
. 70 1
. 6432 726 139
. 35 1 2
. 10 1.4491 725 122
. 84 4 2.40 1.5492 730 131
. 60 3 2
. 50 1
. 5811 731 1 34
. 37 2 2
. 90 1
. 7029 732 144
. 78 1 3
. 60 1
. 8974 730 161.17 4 1
. 70 1
. 3038 726 110
. 57 3 1 .90 1
. 3784 727 116
. 94 2 2
. 10 1.4491 726 122.89 1 2
. 00 1.4142 726 119
. 93 Average 2.2596 1.5032 726.5 127
. 51

Slack Flow Rate : 1 , 095
. 1 kwacfm Stack Flow Rate : 451
. 5 kdscfm Dry Gas Meter T i me Vol. Tm (in) T m(o ut) #/ MaU
. Start 138
. 944 88 88 H , O 87 87 H,O 78 78 Empty End 156.968 79 79 SG Line Rinse Total 1 8.024 83.0 Tolal
NO x ppm NO x , ppm @ 1 5% O 2 NO x Ib/MMBlu NO" I b/hr CO ppm CO , ppm @ 15% 

### 0 , CO I blhr O 2 % Stack F low dscfh CT Fue l F l ow hscfh T urbine Wa t er I njectio n gpm

1845 N
. Case St reet Orange , California 92865 714-279-6777 CT Load MW SCR NH3 Injection I b/ hr NO, Ib/MMSCF CO Ib/MMBtu CO Ib/MMSCF Start/End Time : 9 :49 Load (MW)/Replicate# 102 Barom. Pressure : 29
. 60 Pstack: 2
. 80 Pstack: 29
. 81 MW: 28 .44 METHOD 100.1 DATA 

### 0, CO, Analyzer Range 20 10 Cal Gas Value 18
. 98 9.62 Pre-Test Direct Zero 0.14 0
. 03 Pre-Test Direct Span 19
. 02 9
. 62 Pre- T est System Zero 0
. 15 0
. 09 Pre- T est System Span 19
. 00 9
. 66

Post-Test System Zero 0
. 16 0
. 24 Post-Test System Span 18
. 93 9
. 82 Post-Test Direct Zero 0
. 11 0
. 20 Post- Test Direct Span 18 .9 5 9
. 85 Average 13.45 4.44 Corr. results 13.41 4
. 30 Pre -t est zero b i as 0.0% 0 . 6% Pre-lest span bias

- 0 . 1% 0.4% Post-test zero bias 0 . 2% 0 . 3% Post-test span b i as - 0
. 1% 

### -0 . 3% Zero drift 0
. 1 % 1.4% Span drift - 0.4% 1.6% METHOD 4.1 DATA Imp i ngers End Start D i ff
. 807
. 1 684
. 8 122
. 3 Meter Pressure : 657
. 7 656
. 9 0.8 578
. 6 578
. 5 0.1 Samp l e Vo l ume : 997
. 8 992
. 9 4
. 9 H 20 Volume : 100
. 0 - 100
. 0 Moisture Content: 28
. 1 RESULTS Ref. Meth CEMS Diff
. Diff. %

1
. 98 1
. 80 0.18 9.1% 1
. 56 1.46 0.10 6.4% 0
. 006 0.006 0
. 000 0
.0%. 6.41 5
. 00 1.41 21
. 9% 3.44 2
. 70 0.74 21
. 5% 2 .7 1 2 .13 0
. 58 21.4% 6.77 4
. 33 2.4 4 36
. 0% 13
. 41 13.53 -0
. 12 -0
. 9% 27 , 09 1 , 703 2 1 , 943,000 5 , 148 ,703 19 .0%



## - 8 , 503
. 8 

### -



## - -

- 102 

### - 

## -

- 191
. 7 

## - - 7
. 53 0.006 

## - 6.38 11 : 08 STRAT 

### iwg "H9 Ib/ lb -m ole NO, CO

5 10 4
. 62 9
. 56 -0
. 02 0.01 4 .60 9.57 -0
. 01 0.25 4
. 58 9.85

-0. 01 0
. 02 4
. 57 9
. 63

- 0
. 01 -0.03 4 .60 9.55 1.96 3.59 1 .98 3.44 0 . 3% 2.4%

- 0.5% 2.8% 0 . 1% 0 . 5% -0.5% 0 . 8% 0
. 0% -2
. 3% -0. 1% -2
. 2%

1.5 iwg 17.646 dscf

1
. 326 scf

7
. 0 %

Sentinel Unit 

### 5 RATA.xls 3/14/2013 12 :22 P M

### Port Point Date 

### W 3 2/25/2013 

### W 2 2/ 2 5/2 013 

### W 1 2/25/2 013 

### 5 3 2/ 25

/ 2013 

### S 2 2125/20 13 

### S 1 2/ 25

/2 013 

### E 3 2/ 25/2013 

### E 2 2/25/2013 E 

### 1 2/25/2013 

### N 3 2/25/2013 N 

### 2 2/ 25

/ 2013 N 2125/2013 Average



# DBhaAlrQual/fY SBtYlceS 1845 N. Case Street Orange, California 92865 714·279·6777 Time 

### 9 :50 9 :52 9:54 9 :5 9 10 :01 10 :03 10 :55 10:57 10:59 11 :04 11:06 11 :08 REFERENCE METHOD 1·MINUTE AVERAGE DATA 

### 0, CO, NO, CO 13 . 239 4 .54 2.231 2 . 179 13 . 242 4 . 54 2 .2 36 3.083 13.247 4 . 536 2 . 236 2 .401 13 . 247 4 .535 1 .934 3.354 13.643 4 . 311 1 .975 3.938 13.624 4 . 323 1 .656 3.541 13 .5 51 4 .4 1 .924 3 .798 13 .533 4.41 1 . 894 4.026 13.495 4.434 1 .79 4.219 13 . 533 4.42 1 .925 4 . 692 13 . 525 4.426 1 . 898 4.171 13.486 4.45 1 .779 3 . 694 13 .4 5 4.44 1.96 3 . 59

Sentinel Unit 5 RATA-xis 3/4/2013 

### 10:02 AM

### Port Point Angle 

### N 4 

## 2 N 3 0 N 

## 2 2 N 1 1 

## E 4 1 

## E 3 0 

## E 2 1 

## E 1 0 S 4 0 S 3 0 S 

## 2 1 S 1 0 

## W 4 0 

## W 3 3 

## W 2 2 

## W 0 Average 0.8 Average Angle < 

### 10 deg.? Yes No Points w/ Reverse Flow? Yes Less Than 4 Po i nts> 30 Deg
. ? Yes PASS

## FLUE GAS VELOCITY DATA AND WORKSHEET 

## CLIENT: 

# C-ev""'- vVI."I , PERFORMED BY: 

# IS' k\

# ~ , ) 

# ::V'\ LOCATION :

# SoQ!"~' "\Y \ 

## BAR.

# PRESSURE:_~**2",,"\ ....l.-'-** **'** "",l ,"'-,,
______ _ 

## UNIT: 

# '-2 STATIC PRESSURE:--'.j+--,2-",,'--,-- , ...



# h ..l--
____ _ TEST DATE: '2../ Z-**~** 

## - 

# \» TC READOUT**ID:_-:-1L.:2.~** ...:.""-'.=...:..\...... 

# S'---
____ _ TEST NUMBER: TC ID::-=:-I,=,:L::-:-,::: - :-,v-",--",:L-"'j...,.,,-
_______ _ 

## LEAK CHECK PRE- 

# V POST- , 

# V PITOT TUBE

# ID:-='**,:l:b ~_'\:1::'o~"::__---;---,;--;,----**  c.P INDICATOR TYPE: 

# (2

- \ 0**\~cA:>** 

## PITOT TUBE COEFFICIENT: 

# ?', 

# b L( c.P INDICATOR 

# 10: \ 0 - c/ 

### C 

# "> ZERO:**~** 

## ,,/ LEVEL:_-6b""'L"--
__ _ Yaw Angle, c.P, Temperature, Time Port Point Degrees(1) inches H2O OF 

# I :U) 

# <::, 

# IV Lj lj 

# 'Z- 1 , 

# g 7 2 

# 7 '7.,**~** 

### () 

## '2 , 

# \ 72.2- 

# '2 '7 

# 2 2, 

# 2- 72.2- I 

# l 2 , ::;- 72-"2- 

# t2-1 U 

# r;: 

# L/ 

# ;, 

# , \ ' i1 72-'(- 

# :s 7 Q 

# 2 , 

# I '726 

# 2 2- \ 

# n , 7 '72 (., I () 

# 2 , 

# , '72 )- 12- l 

# s "S I- 

### U 

# 0 

# '2 , L/ 

# 1Ju 'OS

# ~ 

# 0 2, :; '7 J 

# i 

# 2. ,') 

### J 

# 2 , 

# t1 

# 73 

# 2

I I 

# 0 

# '). (.", 7?,D 

## 12'2.() 

# I t.( ) 

# U Li 

# 0 I , 'I 72[, 

# ;;; 

# i "7 

# [ , '1 12-7 

# 2 ,., 2 '2. / '/2-(' t.- 

# I \ ;) '2 , 0 

# 72- 

# f:

Comments: 1) Positive yaw angles correspond to clockwise rotation of the probe ,

# 1IIIIta**~** 

# "'--- Date of last revision 11/13/08 DS834033 Master Document StoragelFormslDatasheetslField Datasheets

## Appendix C .2 CEM Data

R5210729 C-3

## Appendix 

## C.2.1 CEM Quality Assurance Measurements

R521 0729 C-4

### Source Test Date AETB Name AETB Phone Number AETB e-ma i l QI Last Name QI F i rst Name QI Middle In itia l QI Exam Date Exam Provider Exam Contact Gemma CPV Sentinel Unit 5 

## 2/

25-26 / 2013 Delta Air Q u ality Serv i ces , Inc
. 7 14-279-6777 contact@deltaags.com Aleshaiker Ali M November 21 , 2008 Source Evaluation Soc i ety gstiprogram@gmail.com

# DellaAilQualifY SelVices CEMS PERFORMANCE DATA SHEET Client: Gemma Date : 

## 2/25-26/2013 Location : CPV Sentinel Unit 5 Performed By : 

## M, MC , RM, JM CEMS 

## 10# : -=5-c-C::..;E=.cM"'S=--
__________ _ Analyzer: O2 CO 2 NO , CO Manufacturer: AMI C A l CAl TECO Serial Number : 021119-3 W06004-M V10043 CM0490048 CEMS Probe: Material: S .S. Length : 8' 

### He ated Line Material: Tefl o n Length : 6' Sample Conditioner : Type : Universal CEMS Line : Material: Teflon Length : 200' Bias Line: Material: Teflon Length : 200' Upscale Resp onse Time : 30 Downscale Response Time :

Sample Pres sure (psi): 6 TECO Vacuum (" Hg) : Sample Flow Rate : 8 

### SCFH S0 2



# -- Gas Temp: 735 

## o f Gas Temp: 300 

## o f Gas Temp : 31 

## o f

30 seconds NA

Sentinel Unit 5 CEMS QA.xls 

## 3/16/2013

2:40 PM

# DellaAi, QualitySefVices SPAN GAS RECORD AND SCAQMD CALIBRATION ERROR/LINEARITY CLIENT/LOCATION: Gemma CPV Sentinel Unit 5 DATE: 

## 2/25/13

TRUCK/CEM I.D.: .,::::5-....::C:..:E::,:M,:.::SC-.
_________ _ BY : AA, MC, RM, JM Exp. Vendor %of Gas Cylinder 

## # Value Date ID Range ZERO Low SA21794 0.0 

## 1/8/18 F22013



## 0, Mid CC181115 10.00 

## 5/1/15 F22012 50.0% 

## 0, High CC246737 18.98 

## 5/30/15 F22012 94.9% CO, Mid CC181115 5.00 

## 5/1/15 F22012 50.0% CO, High CC246737 9.62 

## 5/30/15 F22012 96.2% NO, Mid CC363284 2.56 

## 9/11/14 F22012 51.2% NO, High CC101204 4.62 

## 11/5/14 F22012 92.4% NO, NO, CC336169 3.71 

## 2/27113 F22012 74.2% CO Mid CC325462 4.49 

## 8/20/20 F22012 44.9% CO High CC313042 9.56 

## 5/21/15 F22012 95.6% PRE-TEST INSTRUMENT CALIBRATION ERROR ANALYZER 

## 0, CO, NO, CO Analyzer Range 20 10 5 10 Zero Gas Value 0.0 0.0 0.0 0.0 AnalYzer Reads 0.14 0.03 -0.02 0.01 Error (% of scale) 0.7% 0.3% -0.5% 0
. 1%

Hiah Gas Value 18.98 9.62 4
. 62 9.56 Analyzer Reads 19.02 9.62 4
. 60 9.57 Error (% of scale) 0.2% 0.0% -0.3% 0.1%

Mid Gas Value 10.00 5.00 2.56 4.49 Analyzer Reads 10.10 5.05 2.53 4.49 Error (% of scale) 0.5% 0.5% -0.6% 0.0% Linearity at Mid Point 0.1% 0.4% -0.2% -0.1% POST-TEST INSTRUMENT CALIBRATION ERROR ANALYZER 

## 0, CO, NO x 

### CO Analyzer Range 20 10 5 10 Zero Gas Value 0.0 0.0 0.0 0.0 Analyzer Reads 0.12 0.10 -001 0.03 Error (% of scale) 0.6% 1.0% -0.2% 0.3%

HTcih Gas Value 18.98 9.62 4.62 9.56 AnalYzer Reads 18.88 9.70 4.56 9.58 Error (% of scale) -0.5% 0.8% -1.1% 0
. 1%

Mid Gas Value 10.00 5.00 2.56 4.49 AnalYzer Reads 10.01 5.12 2.53 4.49 Error (% of scale) 0.0% 1.2% -0.7% 0.0% Linearity at Mid Point 0.0% 0.3% 0.0% -0.2% STATUS



# --

-- PASS



# --

-- PASS



# --

-- PASS PASS

STATUS



# --

-- PASS



# --

-- PASS



# --

-- PASS PASS Sentinel Unit 5 CEMS QA.xls 3/12/2013

3 : 30 PM

# DellaAirQualityServices SPAN GAS RECORD AND SCAQMD CALIBRATION ERROR/LINEARITY CLIENT/ LOCATION: Gemma CPV Sentinel Un it 5 DATE : 2/26/13

TRUCK/CEM 1.0 .: ..:5_-Co..;E::;.M;.;.S"-
__________ _ BY : AA , MC , RM , JM Exp, Vendor 'loaf Gas Cylinder 

## # Value Date 

## to Range ZERO Low SA21794 0
. 0 1 /8/ 18 F22013



## 0, Mid CC181115 10.00 5/1/15 F22012 50.0% 

## 0, High CC246737 18
. 98 5/3 0/15 F22012 94.9% CO, Mid CC181115 5
. 00 5 / 1 / 15 F22012 50.0% CO, High CC246737 9.62 5/30/15 F22012 96.2% NO, Mid CC363284 2,56 9/11/14 F22012 51.2% NO , High CC101204 4 , 62 11 /5/ 14 F22012 92.4% NO, NO, CC336169 3,71 2/27113 F22012 74.2% CO Mid CC325462 4.49 8/20/20 F22012 44.9% CO High CC313042 9.56 5/21 / 15 F22012 95 , 6% PRE-TEST INSTRUMENT CALIBRATION ERROR ANALYZER 

## 0, CO, NO, CO Analyzer Range 20 10 5 10 Zero Gas Value 0 , 0 0 , 0 0 , 0 0.0 Analyzer Reads 0
. 11 0.07 -003 -0.04 Error (% of scale) 0,6% 0,7% -0.5% -0.4%

High Gas Value 18 ,98 9.62 4,62 9.56 Analyzer Reads 18 , 95 9,68 4 , 60 9.55 Error (% of scale) -0
. 1% 0
. 6% -0.4% -0,1 %

Mid Gas Value 10,00 5,00 2,56 4.49 Analyzer Reads 10 , 06 5
. 11 2.53 4 ,5 1 Error (% of scale) 0
. 3 % 1 , 1 % -0
. 6% 0.2% Linearity at Mid Point 0 , 1% 0.4% -0.1% 0.4% POST-TEST INSTRUMENT CALIBRATION ERROR ANALYZER 

## 0, CO, NO, CO Analyzer Range 20 10 5 10 Zero Gas Value 0 , 0 0,0 0.0 0,0 Analyzer Reads 0
. 11 0 , 12 -0,01 0,04 Error (% of scale) 0 , 6% 1
. 2% -0
. 3% 0.4%

High Gas Value 18
. 98 9,62 4
. 62 9.56 Analyzer Reads 18 ,90 9,76 4 , 59 9.60 Error (% of scale) -0.4% 1.4% -0 , 5% 0.4%

Mid Gas Value 10.00 5
. 00 2.56 4.49 Analyzer Reads 10 , 02 5
. 18 2,55 4 ,5 1 Error (% of scale) 0 , 1% 1 ,8% -0,2% 0,2% Linearity at Mid Point 0 , 1 % 0 , 5% 0 , 2% -0.1% STATUS



# - -

-- PASS



# --

-- 

### PASS



# --

-- PASS PASS

STATUS

--



# -- PASS

--



# -- PASS



# --

-- PASS PASS Sentine l Unit 5 CEMS QA.xls 311612013

2 : 15 PM

## Analyzer Manufacturer: Analyzer Model : Analyzer Serial Number : Date : ANALYZER GAS MODE Zero NO, Zero NO NO NO, NO NO NO , NO NO, NO ,

Abs
. Value Co- C ,: Abs
. Value C , -C ,: 

## C, / C, CE 

## = D ,/D , 

## * 100 %: 

# DellaAirQualitySefllices NO, to NO 

## Converter Efficiency Test Gemma CPV Sentinel Unit 5 600CLD V 10043 2/

25 / 13 

## ANALYZER RESPONSE -0.02 -0
. 03 4.60 4.57 0
. 00 3.45
Label 3.7 D, 3.4 D , 1 % D 3 93% NO Cal Gas Value: 4.62 NO, Cal Gas Value : 3
.71 Performed By : AA 

## CEMS ID# : 5-CEMS CAL CORRECTED LABEL

0.0 C , 3.5 C, Requirement

<5% > 

## 90%

Sentinel Unit 5 CEMS QA.xls 3/16/2013



## 2 : 16 PM

## Analyzer Manufacturer: Analyzer Model : Analyzer Serial Number : Date : ANALYZER GAS MODE Zero NO, Zero NO NO NO, NO NO NO, NO NO, NO,

Abs
. Value Co -C ,: Abs
. Value C , -C ,: C, / C, 

## CE 

## = D,/ D, * 

## 100%: 

# Della AirQualitY Services NO, to NO 

## Converter Efficiency Test Gemma CPV Sentinel Unit 5 600CLD V10043 2/

26 /13 

## ANALYZER RESPONSE -0
. 03 -0
. 04 4.61 4.60 0.00 3.47
Label 3
.7 D , 3.4 D , 1 % D 3 94% NO Cal Gas Value : 4
. 62 NO, Cal Gas Value : 3.71 Performed By : AA 

## CEMS ID# : 5-CEMS CAL CORRECTED LABEL

0
. 0 C, 3
. 5 C, Requirement

<5% > 

## 90%

Sentinel Unit 5 CEMS QA.xls 3/16/2013



## 2 : 16 PM

## Appendix C.2.2 NO x and CO Compliance

R521 0729 

### C-5COMPLIANCE TEST OATA AND WORKSHEET CPV S e ntinel-5-CEMS - 100 - 1 TEST CONSTANTS Stalion: CPV Sentinel Unit; 

### 5 Performed 

### By : AA , MC , RM , JM Cp : 

### 0 .99 Tret: 

### 60 o f Stack Area: 

### 143 . 14 

### ft' Meter Yd : 

### 1 . 014 METHOD 

### 2 . 1 DATA dP Temp Vel. Po in t (in. H,O) sqrt(dP) of (I ps)



### 4 1 .70 1 . 3038 732 131.39 3 1 . 60 1 .2649 733 127 .52 2 1 . 50 1 . 2247 734 123 .52 1 1.40 1 . 1832 733 119.28 4 1 . 50 1 . 2247 734 123 .52 3 1.40 1 . 1832 735 119 . 38 2 1 .70 1.3038 736 131 .61 1 1 .90 1 . 3784 734 139.02 4 0.98 0 .9899 735 99.88 3 1.70 1.3038 736 131 . 61 2 1 .90 1 . 3784 735 139 .07 1 1 .70 1 . 3038 734 131.50 4 1.10 1.0488 735 105.82 3 1 . 30 1 . 1402 736 11 5 .09 2 1.50 1 . 224 7 730 123.31 1 1.40 1.1832 735 119.38 Average 

### 1 . 5067 1 . 2275 734 . 2 123 .81

Stack Flow Ra te : 

### 1 ,063 .3 kwacfm Sta ck Flow Rate: 416 .2 kdscfm Dry Gas Meter Time Vol . Tm(in ) T m(out) # IM ati
. Start 

### 158.456 79 78 H,O 

### 77 

### 78 H ,O End 

### 202.298 76 75 Emply 

### 73 74 SG Total 

### 43 . 842 76 . 3 Total NO, ppm NO x , ppm @ 15% O 2**NO~** Ib/MMBt u**NO~** l b /hr CO ppm CO, ppm@ 15% O 2 CO Iblhr O2 % Stack Fl ow dscfh CT Fue l Flow hscfh Turb ine Water Injection gpm



### 1845 N . Case Street Orange, California 

### 92865 714-279-6777 CT Load MW SCR NH3 Injection Ib/hr NO, IblMMSCF CO IblMM Blu CO IblMMSCF TEST VARIABLES Start Dale: 

### 2125113 Start/End Time : 

### 11 : 35 12:43 Load ( MW)/Replicate# 

### 100 1 Barom . Pressure : 

### 29 .60 Pstack : 

### 2 . 80 iwg 

### Pstack : 

### 29 .8 1 " Hg MW : 

### 28. 12 Ib/lb -mole METHOD 

### 100 , 1 DATA 

### 0, CO, NO, CO Analyzer Range 

### 20 1 0 5 10 Cal Gas Value 

### 18.98 9 . 62 4 . 62 9.56 Pre· Test Direct Zero 

### 0. 11 0.20 -0 .0 1 -0.0 3 Pre-Test Direct Span 

### 18. 95 9. 8 5 4. 60 9 .55 Pre-Test System Zero 

### 0.16 0 .24 -0.0 1 0.02 Pre-Test Syslem Span 

### 18 .9 3 9 . 82 4 .57 9 .63

Post-Tes l System Zero 

### 0 . 16 0 . 25 -0.01

-0 .01 Post-Test System Soan 

### 18 . 83 9 . 85 4 .56 9 .59 Post-Test Di r ect Zero 

### 0 . 11 0 . 20 -0 .02 -0 .03 Post -Test Direct Span 

### 18 . 89 9 . 86 4 . 60 9.55 Average 

### 13.51 4.44 2 . 10 3 .75 Carr. results 

### 13 .54 4 .2 1 2.13 3 . 72 Pre-test zero bias 0 .2% 0 .3% 0 . 1% 0 .5% Pre-test span bias -0 . 1% -0 .3% -0 .5% 0 .8% Post- lest zero bias 0.2% 

### 0 . 5 % 0.1% 0 . 1% 

### Post-test span bias -0.3% - 0 . 1% -0 . 7% 0.4% Zero dri ft 0 .0% 

### 0.2% 0.0% -0 . 3% Span drift -0 .5% 0 . 3% -0. 2% -0.4% METHOD 

### 4 ,1 DATA Im pingers End Start D iff . 

### 910 . 2 728 . 7 181 .5 Meter P r essure : 1 .5 iwg 

### 7 4 3.5 742 . 2 1 .3 Sample Volume : 

### 42 . 803 dscl 

### 630.0 628.2 1 . 8 H2 0 Volume : 

### 4 . 635 scI 

### 946.9 931.8 15.1 Moisture Content: 9 .8 %

Ir 

### 100 99.7 RESULTS Ref. Meth CEMS



### 2 . 13 1 .90 1.70 1 .51 0 .006 0 .01 6.44 5 . 54 3 .72 3 . 20 2.98 2 . 53 6.76 5 . 19 13 . 54 13 .4 5 24 ,970 ,209 22.442 ,000



## - 8 ,746



### -



## - 106



### - 195 7 . 36 0 .007 7 .03 

## - Sentinel Unit 5 100 % NOx- NH3-ROG Com pliance. xls 3116/2013



### 2 :46 PMCOMPLIANC E TEST DATA AND WORKSHEET CPV Sentinel - 5-CEMS-100-2 TEST CONSTANTS Station: CPV Sentinel Unit: 5 Performed 

### By : AA , MC , RM, JM Cp : 0
. 99 Tref : 60 

### o f Stack Area : 143.1 4 ft' Meier Y(j: 1
. 014 METHOD 2,1 DATA dP Temp Vel. Po int (in. H,O) sqrt(dP) 

### o f (fps) 4 1 , 20 1
. 0954 736 110.58 3 1.30 1.1402 737 115.15 2 1.40 1
. 1832 738 119.54 1 1 , 60 1 , 2649 736 127.69 4 1
. 30 1
. 1402 737 115.15 3 1
. 80 1
. 3416 739 1 35.61 2 1 , 90 1
. 3784 740 139.38 1 1.60 1 .2649 739 127.85 4 1.10 1.0488 740 106 .0 5 3 1.20 1 , 0954 741 110
. 82 2 1.40 1.1832 739 119.59 1 1 , 60 1.2649 738 127.80 4 1.00 1
. 0000 740 101
. 12 3 1
. 20 1.0954 739 110.72 2 1
. 20 1 ,0954 739 110.72 1 1 , 10 1 , 0488 737 105.92 Average 1
. 3574 1 , 1651 738.4 117
. 73

Stack Flow Rate: 1,011 . 1 kwacfm Stack Flow Rate : 394
. 0 kdsefm Dry G as Meter Time Vol . Tm (i n) Tm(out) #/Ma l l. Slart 204 , 664 78 76 H,O 74 74 H,O End 240 , 825 76 76 Emply 74 74 SG Total 36
. 161 75 , 3 Total
NO x ppm NO x , ppm 

### @ 15 % O 2 NO, Ib/MMBlu NO x Ib/hr CO ppm CO, ppm@ 15% O 2 CO Ib/hr O2 

### % Stack Flow dscfh CT Fue l F low hscfh Turb ine Water In jection gpm

1845 N
. Case Street Orange , California 92865 714-279-6777 CT Load MW SCR NH3 Injection Ib/hr NO, Ib/MMSCF CO Ib/MMBlu CO Ib/MMSCF TEST VARIABLES S

ta rt Date: 2/25/13 Start/End Time : 13 : 04 14:17 Load (MW)/Replicale # 100 2 

### Baram . Pressure : 29 , 60 Pstack : 2
. 80 iwg Pstack : 29.81 "H g MW: 28 , 11 Ib/lb-mole METHOD 100 , 1 DATA 

### 0, CO, NO, CO Analyzer Range 20 10 5 10 Cal Gas Value 18 , 98 9
.62 4.62 9.56 Pre-Test Direct Zero 0.11 0.20 -0.02 -0.03 Pre -Test Direct Span 18.89 9
. 86 4 , 60 9.55 Pre-Test System Zero 0.16 0
. 25 -0.01 -0.0 1 Pre -Test System Span 18.83 9
. 85 4
. 56 9
. 59

Post -Test System Zero 0
. 14 0
. 21 -0.0 1 0.02 Post-Test System Span 18
. 79 9 , 80 4 , 55 9
. 51 Post-Test Direct Zero 0
. 1 1 0 , 19 -0 , 0 1 -0,03 Post-Test Direct Span 18
. 89 9 , 84 4
. 57 9
. 57 

### Average 13.42 4
.46 2.03 3
. 60 Carr. results 13.50 4 ,2 4 2 , 06 3.60 Pre-lest zero bias 

### 0 .2% 0 . 5% 0.1% 0 . 1% Pre-lest span bias 

### -0 .3% -0. 1% -0 . 7% 0.4% 

### PosHest zero bias 0 . 1% 0.2% 0 .0% 0 . 5% Post-test span bias -0 .5% 

### -0 .4% -0.5% -0.5% Zero drift -0 . 1% - 0.4% 0 .0% 

### 0 .3'% Span drift -0. 2% -0. 5% -0.3% -0.8% METHOD 4,1 DATA Imp in gers End Start Diff , 856.7 683.6 173 , 1 Meter Pressure : 1 .5 iwg 664.0 662 , 2 1
. 8 Sample Volume : 35.370 dsel 579.9 579 , 6 0
. 3 H2 0 Volume : 3.868 sef 948
. 7 940.7 8
. 0 Moisture Content: 9 .9 

### %

I r 100 83 , 2 RESULTS Ref, Melh CEMS

2.06 1
. 90 1.65 1 , 53 0,006 0.01 5
. 92 5.48 3
. 60 3 , 10 2 , 87 2.45 6 , 19 5 , 00 13 , 50 13.41 23 , 638 , 15 8 22,311 , 000



## - 8 , 742



### -



## - 106



## - 1 9 4 6
. 77 

### - 0 .00 6 

## - 6
. 77 

## - Sentinel Unit 5 100% NOx- NH3 - ROG Compliance.xls 3/16/2013

2 :46 PM

### REFERENCE METHOD 1-MINUTE AVERAGE DATA Port Point Date Time 

### 0, CO, NO, CO 02-ln NOx-ln 

### CO-In THC-In W 

### 3 2/25/2013 

### 11 : 36 13 . 521 4.45 2 . 215 3.458 W 

### 3 2/ 25/ 2013 

### 11 : 37 13 . 526 4.447 2 . 211 3 . 719 W 

### 3 2/ 25/ 2 0 13 

### 11 : 38 13 .528 4.446 2
.206 

### 3.499 W 

### 3 2/ 25

/ 2 0 13 

### 11 : 39 13 .517 4.453 2 . 188 3 . 752 W 

### 3 2/ 25

/ 2 01 3 11 : 40 

### 13 . 513 4.456 2 . 198 4 . 326 W 

### 2 2/ 25

/ 2013 

### 11 :41 13 . 525 4:449 2 . 268 4 . 375 W 

### 2 2/ 25

/ 2013 

### 11 :42 13 . 535 4:443 2 . 288 4 . 314 W 

### 2 2/25/2013 

### 11 :43 13 .534 4:441 2 . 343 4 .551 W 

### 2 2/25/2013 

### 11 :44 13.534 4.438 2.363 4:426
2/

25/2013 

### 11 :47 13 .557 4:42 2
. 409 

### 4 . 156 2/

25

/ 2013 

### 11 :48 13 . 558 4.42 

### 2:423 4
. 708 2/

25

/ 2013 

### 11 :49 13 . 555 4 .419 2:436 3 . 834 1 2/ 25/ 2013 11 :50 

### 13 .577 4:409 

### 2:47 3 .786 

### 5 3 2/ 25

/ 2013 

### 11 : 54 13:498 4 .45 1. 829 3 . 193 

### S 3 2/ 25

/ 2013 

### 11 : 55 13 . 51 4.448 1 . 824 3.398 

### S 3 2/25/ 2013 

### 11 :56 13 . 5 4:454 1 . 822 2 .962 

### S 3 2/25/2013 

### 11 : 57 13
. 504 

### 4:451 1 . 845 2.952 

### S 3 2/25/2013 

### 11 :58 13:499 4.454 1 . 813 2.825 

### S 2 2/ 25/2013 

### 11 :59 13 .497 4:459 1 . 835 3 . 538 

### S 2 2/ 25/2013 12 :00 

### 13 . 515 4:45 1 .722 3 . 224 

### S 2 2/ 25

/ 2013 12 : 01 

### 13 .519 4 .449 1 .711 3
. 005 

### S 2 2/ 25

/ 2013 12 :02 

### 13 .521 4:449 2 . 345 3
. 023 

### S 2 2/ 25

/ 2013 12 :03 

### 13 .519 4:45 1 . 821 3 . 234 

### S 1 2/ 25

/ 2013 12 :04 

### 13 .536 4:438 1 .69 3.086 

### S 1 2/ 25/2013 12 :05 

### 13 . 55 4 .431 1 .584 3 . 289 

### S 2/25/2013 12 :06 

### 13 .548 4:429 1 .588 3.487 

### S 2/25/2013 1 2 : 07 

### 13 . 555 4:421 1.571 3 . 139
E 

### 3 2/ 25

/ 2013 

### 12 : 13 13 . 5 4:433 2
. 049 

### 3 . 397 E 

### 3 2/ 25

/ 2013 

### 12 : 14 1 3. 501 

### 4 .431 2
. 022 

### 3:432 E 

### 3 2/ 25

/ 2013 

### 12 : 15 13 .5 4:432 2
. 055 

### 3 . 647 E 

### 3 2/ 25

/ 2013 

### 12 : 16 13:499 4:433 2 .046 3.845 E 

### 2 2/ 25

/ 2013 

### 12 : 17 13:493 4:435 2
. 06 

### 3 . 618 E 

### 2 2/25/2013 

### 12 : 18 13:493 4:436 2
. 108 

### 3 . 648 E 

### 2 2/25/2013 

### 12 : 19 13.493 4:437 2
. 034 

### 3.831 E 

### 2 2/25/2013 12 : 20 

### 13:488 4:436 2
. 07 

### 3.834
E 2/ 25

/ 2013 

### 12 :23 13:495 4:436 2
. 041 

### 3 .757 E 2/ 25

/ 2013 

### 12:24 13:496 4:436 2
. 044 

### 3 .62 E 

### 1 2/ 25

/ 2013 

### 12 :25 13:487 4:439 1.978 3 .653 E 

### 1 2/ 25/ 2013 

### 12 :26 13:484 4:443 1 .969 3.852 N 3 2/25/2013 

### 12 :29 13.496 4:436 2 . 184 3.933 N 

### 3 2/25/2013 12:30 

### 13:486 4:44 2 . 172 4.255 N 

### 3 2/25/2013 

### 12:31 13:495 4:435 2 . 219 3
. 802 N 

### 3 2/25/2013 

### 12:32 13:487 4:44 2 . 159 4.132 N 

### 3 2/25/2013 

### 12 : 33 13.492 4:436 2.158 4.142 N 

### 2 2/ 25

/ 2013 

### 12 : 34 13:49 4:436 2 . 188 3.684 N 

### 2 2/ 25

/ 2013 

### 12 : 35 13:48 4:441 2 . 161 3
. 907 N 

### 2 2/ 25

/ 2013 

### 12 : 36 13:483 4:436 2 . 186 4
. 091 N 

### 2 2/ 25

/ 2013 

### 12 : 37 13:473 4:44 2 . 154 3 . 927 N 2/25/2013 12:40 

### 13.494 4:431 2.373 N 2/25/2013 

### 12:41 13:496 4:43 2 .413 N 2/25/2013 

### 12 :42 13 . 5 4:43 2:439 N 2/25 / 2013 

### 12:43 13
. 505 

### 4:428 2.407 Average 

### 13.51 4.44 2.10 3.75 13.26 31.79 92.03 

# Della Ai'QualitY Services 1845 N. Case Street Sentinel Unit 5 100% NOx-NH3 - ROG Compliance.xls 

### Orange , California 92865 3/16/2013 

### 714-279-6777 2:47 PM

### REFERENCE METHOD 1-MINUTE AVERAGE DATA Port Point Date Time 

### 0, CO, NO, CO W 

### 3 2/25/2013 

### 13 :05 13.424 4.465 1 .784 3.191 W 

### 3 2/25 / 2013 

### 13 :06 13.422 4.466 1 .764 3.218 W 

### 3 2 / 25

/ 2013 

### 13 :07 13.425 4.462 1 . 802 3 . 208 W 

### 3 2 / 25

/ 2013 

### 13:08 13.422 4.466 1 .762 2 . 924 W 

### 3 2/ 25

/ 2013 

### 13 :09 13.422 4.465 1 .767 3 . 104 W 

### 2 2/ 25

/ 2013 

### 13 : 10 13.426 4.462 1.689 3 . 255 W 

### 2 2/25/2013 

### 13 : 11 13.432 4.456 1 .698 2.758 W 

### 2 2/25/2013 

### 13:12 13.434 4.455 1.716 2.712 

# w 2 2/25/2013 

### 13:13 13.435 4.456 1 .706 2 .727 W 

### 2 2/25/2013 

### 13 : 14 13.437 4.453 1 .689 2 . 598 W 

### 1 2/25/2013 

### 13 : 15 13.451 4.448 1 .6 2 . 915 W 2 / 25/2013 

### 13 : 16 13.462 4.445 1 .622 2 .774 W 2 / 25

/ 2013 

### 13:17 13.455 4.44 8 1 . 625 2.744 W 2 / 25

/ 2013 

### 13 : 18 13.466 4 .446 1.609 2 . 698 W 

### 1 2 / 25

/ 2013 

### 13 : 19 13.458 4.45 1.616 2 .725 S 3 2/25 / 2013 

### 13 :28 13 . 394 4 .49 1 . 952 3.265 

### S 3 2/25/2013 

### 13 :29 13 . 393 4.493 1 . 98 3.398 

### S 3 2/25/2013 

### 13:30 13.395 4.489 1 . 975 3 . 114 

### S 3 2/25/2013 

### 13:31 13.396 4.487 1.979 3.181 

### S 2 2/ 25

/ 2013 

### 13 : 34 13 . 382 4.497 2.417 3.145 

### S 2 2 / 25

/ 2013 

### 13 : 35 13 . 38 4.498 1.992 2 . 975 

### S 2 2 / 25

/ 2013 

### 1 3 : 36 13 . 385 4.494 1.991 2 . 865 

### S 2 2/25 / 2 013 

### 13 : 37 13 . 375 4.499 1 .902 2.803 

### S 2/25/2013 

### 13 : 38 13 . 358 4 . 509 1 .79 3.347 

### S 2/25/2013 

### 13 : 39 13 . 358 4.511 2 . 103 2.998 

### S 2/25/2013 

### 13 :40 13.362 4.508 1 . 87 2.992 

### S 2/25/2013 

### 13:41 13 . 36 4 . 509 1 . 815 2 . 747 

### E 3 2 / 25

/ 2013 

### 13:46 13 .421 4 .476 2 .023 3 . 191 

### E 3 2 / 25

/ 2013 

### 13 :47 13.421 4.472 2 .019 3 . 364 

### E 3 2 / 25

/ 2013 

### 13 :48 13.421 4.472 2 .048 3 . 653 

### E 3 2 / 25/2013 

### 13 :49 13.42 4 .472 2 .019 3.632 

### E 2 2/25/2013 

### 13 : 50 13.422 4.466 2.023 3.342 

### E 2 2/25/2013 

### 13 : 51 13 .428 4.461 2 .018 3 . 287 

### E 2 2/25/2013 

### 13 :52 13.421 4.463 1 . 995 3.592 E 

### 2 2/25/2013 

### 13 : 53 13.421 4.46 1 . 999 3 .38 1
E 2/ 25

/ 2013 

### 13:56 1 3.423 4.45 2 . 372 3.796 E 2 / 25

/ 2013 

### 13 :57 13 .422 4.452 2 . 873 3.914 

### E 1 2/ 25

/ 2013 

### 13:58 13.418 4.453 2 . 316 4 . 134 E 

### 1 2/ 25

/ 2013 

### 13 :59 13.421 4.449 1 . 986 4 .062 N 3 2/25/2013 

### 14 :03 13.433 4.427 2 .093 4 . 272 N 

### 3 2/2 5/2013 

### 14:04 13.434 4.427 2 .072 4.719 N 

### 3 2/25/2013 

### 14 :05 13.433 4.427 2 .085 4 . 709 N 

### 3 2/25/2013 

### 14 :06 13.432 4.425 2 . 074 4 . 61 N 

### 3 2/25/2013 

### 14 :07 13.435 4.423 2 . 165 4 . 71 1 N 2 2 / 25

/ 2013 

### 14 :08 13.441 4.419 2 . 238 4 . 564 N 

### 2 2 / 25

/ 2013 

### 14 :09 13.433 4.425 2 . 198 4 . 859 N 

### 2 2 / 25

/ 2013 

### 14 : 10 13.432 4.429 2 . 225 4 . 884 N 

### 2 2 / 25/2013 

### 14 : 11 13.435 4.429 2 . 214 5 .171 N 

### 2 2/25/2013 

### 14 : 12 13.468 4.413 2 . 353 5 .061 N 

### 1 2/25/2013 

### 14 : 13 13.47 4.411 2 .3 47 4 .97 N 2/25/2013 

### 14 : 14 13.471 4.412 2 . 338 5.223 N 2/25/2013 

### 14:15 13.471 4.413 2 . 361 4 .712 N 2/25/2013 

### 14:16 13.47 4.414 2 . 336 4 . 665 N 2 / 25/2013 

### 14 : 17 13 .47 4.418 2 . 376 4 . 994 Average 

### 13 . 42 4.46 2.03 3.60 

# Delta AirQualifY ServIces 1845 N
. Case Street Sentinel Unit 5 100% NOx-NH3 - ROG Compliance.xls 

### Orange , Californ i a 92865 3/16/2013 

### 714-279-6777 2:47 PMCOMPLIANCE TEST DATA AND WORKSHEET CPV Sentinel-5-CEMS -7S-1 TEST CONSTANTS Station: CPV Sentinel 

### Unit: 5 Performed By : AA , MC , RM , JM Cp o 0
. 99 Tref: 60 O F Stack Area: 143
. 14 ft' Meter Yd : 1 .01 4 METHOD 2.1 DATA dP Temp Vel. Point (i n . H 2O) sqrt(dP) o f (fps) 4 0.80 0
. 8944 726 89
. 67 3 0
. 78 0.8832 728 88
. 61 2 0
. 81 0
. 9000 729 90.34 1 0
. 83 0
. 9110 727 91.37 4 0
. 97 0
. 9849 729 98.86 3 1
. 00 1 .00 00 730 100.42 2 1
. 20 1.0954 729 109
. 96 1 1.30 1
. 1402 728 114.40 4 0.90 0
. 94 87 730 95
. 27 3 1.20 1
. 0954 731 110
. 05 2 1
. 50 1
. 2247 730 122
. 99 1 1.30 1
. 14 02 729 114.45 4 0.81 0
. 9000 730 90.38 3 0
. 97 0.9849 731 98
. 94 2 1.10 1.0488 730 105.32 1 1
. 20 1.0954 729 109.96 Average 1
. 0312 1 .0 155 729.1 101
. 94

Slack Flow Rate: 875.5 kwacfm Stack Flow Rate : 349.9 kdscfm Dry Gas Meter Time Vol . Tm(in) Tm(out) #/Ma l l. Slart 288
. 919 69 69 H,O 72 72 H,O End 325
. 284 72 72 Emply 70 70 SG Tota l 36
. 365 70
. 8 Total
NO x ppm NO x , ppm@ 15% O2 NO x IbfM MBtu NO x Ib/hr CO ppm CO, ppm @ 15% O 2 CO Ib/hr 

### 02. % Stack Flow dscfh CT Fue l Flow hscfh Turb ine Water Injection gpm



### 1845 N
. Case Street Orange , Californi a 

### 92865 714-279-6777 CT Load MW SCR NH3 Injection Ib/hr NO , Ib/MMSCF CO Ib/MM Blu CO Ib/MMSC F TEST VARIABLES Start Date : 2/25/13 StartJEnd Time : 16:42 17:48 Load (MW}/Replicate# 75 1 Barom . Pressure : 29
. 60 Pstack : 2
. 80 iw9 Pstack : 29
. 81 "H 9 MW : 28.27 Ib/lb-moJe METHOD 100 , 1 DATA 

### 0, CO , NO , CO Analyzer Range 20 10 5 10 Cal Gas Value 18.98 9
. 62 4
. 62 9
. 56 Pre-Test Direct Zero 0.13 0
. 12 -0.02 0.03 Pre -Test Direct Span 18.94 9
. 73 4.60 9
. 56 Pre-Test System Zero 0
. 17 0
. 18 -0
. 01 -0
. 03 Pre-Test System Span 18.88 9
. 74 4
. 56 9
. 57

Post-Test System Zero 0
. 16 0
. 13 -0.0 1 0.00 Post-Test System Span 18
. 83 9
.66 4
. 55 9
. 52 Post-Test D irect Zero 0
. 13 0
. 08 -0
. 01 0 .02 Post-Test Direct Span 18.89 9
.68 4.58 9.59 Average 13.93 4 .0 7 1 .5 4 2
. 27 Corr. results 13
. 98 3
. 94 1.57 2.28 Pre -test zero bias 0.2% 0 .6% 0 . 1% -0 .5% Pre - lest span bias -0.3% 0 . 1% -0 . 8% 0. 1 % Post-test zero bias 0 . 1 % 0 .5% 0 .0% -0 .2% Post-test span bias - 0.3% -0. 2% -0.4% -0.6% Zero drift**~0. 1%** **~0.5%,** 0.0% 0.3% Sp an drift**~0. 3%** **0.8%** -0 . 1%**~0.5%** METHOD 4 , 1 DATA Jmpingers End St art Diff . 887.8 728
. 9 158
. 9 Meter Pressure : 1 .5 iwg 744 .5 743
. 8 0.7 Sampl e Volume : 35
. 871 dscf 630.3 630.2 0.1 H 2

### 0 Volume: 3.221 scf 936.1 926
. 5 9
. 6 Moisture Content: 8 .2 

### %

Ir 100 69
. 3 RESULTS Ref. Meth CEMS

1 .57 1 .60 1
. 33 1
. 31 0 .0 05 0
. 005 3
. 98 3
. 53 2
. 28 2
. 00 1 .95 1
. 65 3.49 2
. 78 13
. 98 13
. 86 20 , 996 , 712 19 , 223 , 000



## - 7 , 077.7



### -



## - 81



### - 137 .0 5
.63 

## - 0.00 4 

### - 4
. 59 

## - Sentinel Unit 5 75%**NOx- H3~ROG**  Compliance. xls 3/16/2013

2 : 47 PMCOMPLIANCE TEST DATA AND WORKSHEET CPV Sentinel-5 - CEMS -7S-2 TEST CONSTANTS Station: CPV Sentine l Unit: 5 Performed 

### By : AA
. MC. RM
. JM Cp : 0.99 Tref: 60 OF Stack Area: 143
. 14 

### ft' Meter Yd : 1.014 METHOD 2.1 DATA dP Temp Vel. Point (in
. H,O) sqrt(dP) o f (fps) 4 0.76 0.8718 736 87.99 3 0.85 0.9220 738 93
. 13 2 1.00 1
. 0000 740 101.10 1 1
. 20 1
. 0954 739 110 .70 4 0
. 99 0.9950 736 100.42 3 1.20 1 .0 954 738 110.65 2 1.30 1
. 1402 740 115.27 1 1.40 1.1832 741 119 .6 7 4 0
. 79 0
. 8888 7 42 89.93 3 0
. 92 0
. 9592 743 97.09 2 1
. 00 1
. 0000 742 101.18 1 1
. 20 1
. 0954 739 110
. 70 4 0
. 57 0 .7 550 740 76
. 33 3 0.73 0
. 8544 743 86.48 2 0.88 0 .938 1 741 94.88 1 0
. 83 0
. 9110 7 4 0 92
. 10 Average 0
. 9635 0
. 9816 739.9 99.23

Stack Flow Rate: 852.2 kwacfm Stack Flow Rate : 332 .9 kdscfm Ory G as Meier Time Vol. Tm(in) Tm(oul) #/Ma t l. Slart 325
. 617 65 66 H,O 66 66 H,O End 359.658 65 65 Emply 69 69 SG Tola l 34
. 041 66.4 Tolal
NO x ppm NO,
. ppm 

### @ 15 % 

### 0, NO x IbfMMBtu NO x I b fhr CO ppm CO, ppm 

### @ 15% O2 CO Iblhr °2% Stack Flow dscfh CT Fuel Fl ow hscfh Turbine Water Injection gpm

1845 N
. Case Street Orange
. California 92865 714-279-6777 CT Load MW SCR NH3 Iniection Ib lhr NO, IblMMSCF CO Ib lMMBlu CO Ib lMMSCF TEST VARIABLES Start Date: 2125113 StartlEnd Time: 18 : 07 19:14 Load (MW)IReplicate# 75 2 Baram . Pressure : 29
.60 Pstack: 2.80 iwg Psta ck: 29.81 "Hg MW : 28.12 Ib/lb-mole METHOD 100
. 1 DATA 

### 0, CO, NO, CO Analyzer Range 20 10 5 1 0 Cal Gas Value 18.98 9
.62 4
. 62 9.56 

### Pre-Test Direct Zero 0.13 0
. 08 -0.01 0.02 Pre-Test Direct Span 18 .89 9
. 68 4.58 9.59 Pre -Test System Zero 0
. 16 0
. 13 -0.01 0.00 Pre-Test System Span 18.83 9
. 66 4 .55 9.52

Post · Test System Zero 0
. 17 0
. 16 ·0.01 -0.03 Post- Test System Span 18
.83 9 .7 1 4
. 56 9.60 Post-Test Direct Zero 0
. 11 0
. 11 -0
. 02 0 .0 0 Post- Test Direct Span 18
. 87 9
. 72 4
. 58 9
. 59 Average 13
. 97 4
. 04 2.00 4 .11 Carr. r esults 14 .04 3
. 92 2.03 4
. 11 Pre-test zero bias 0,1% 0 .5% 0 .0% - 0.2% Pre-lest span bias -0.3% -0 .2% 

### -0.4% -0 ,6% Post- t est zero bias 0 .3% 0 . 5% 0 .2% - 0 .3% PosHest span bias -0.2% -0.1% 

### ·0.4 % 0.1% Zero drift 0 . 1% 0.4% 0.0% -0.3% Span drift 0 .0% 0 . 5% 0.1%, 0 .8% METHOD 4
. 1 DATA Im pingers End Start Diff . 855.5 687
. 9 167
. 6 Meter Pressure : 1 .5 iwg 659 .7 658.5 1
. 2 Sample Volume : 33.858 dscf 578
. 7 578
. 5 0
. 2 H2

### 0 Volume: 3.561 scf 956
. 3 948
. 7 7.6 Moisture Content : 9 .5 %

Ir 100 76.6 RESULTS Ref. Meth CEMS

203 1.80 1
. 75 1.49 0
. 006 0
. 006 4 .92 4
. 18 4
. 11 3
. 50 3.54 2.96 5
. 97 4
. 96 14.04 13
. 88 19
. 973
. 905 19.294
. 000



### - 7 .0 85.4



## -

- 80



### - 128.8 6.94 

## - 0
.008 

## - 8
. 33 

## - Sentinel Unit 5 75% NOx-NH3-ROG Compliance.xls 3116120 13

2:47 PM

### REFERENCE METHOD 1-MINUTE AVERAGE DATA Port Point Date Time 

### CO, CO O2-ln 

### NOx-ln CO -I n THe-In



### N 3 2 / 25

/ 2013 

### 16:43 4 .078 0 .725 N 

### 3 2/25/2013 

### 16 :44 4.077 0 .702 N 

### 3 2 / 25

/ 2013 

### 16:45 4 .078 0 .694 N 

### 3 2 / 25

/ 2013 

### 16 :46 4 .079 0 . 664 N 

### 2 2/25 / 2013 

### 16 :49 4 .091 1.54 0 . 668 N 

### 2 2 / 25

/ 2013 

### 16 : 50 4 .092 1.573 0 . 67 1 N 

### 2 2/25/2013 

### 16 : 51 4.09 1.607 0 . 684 N 

### 2 2/25/2013 

### 16 : 52 4.082 1.601 0.687 N 

### 1 2 / 25

/ 2013 

### 16 : 53 4 .085 1.549 0 .688 N 2 / 25

/ 2013 

### 16 :54 0 . 661 N 2/25/2013 

### 16 :55 0 . 653 N 2/25/2013 

### 16 :56 0 .678 0 .703 E 3 2/25/2013 

### 17 :01 13 . 936 4 .082 1.441 1.218 

### E 3 2/25/2013 

### 17 :02 13 . 938 4 . 082 1 . 514 2 . 267 

### E 3 2 / 25/2013 

### 17 : 03 13 . 922 4 .091 1 . 548 3 . 948 E 

### 3 2 / 25

/ 2013 

### 17 :04 13 . 95 4 .075 1 .6 3 .035 

### E 2 2/25/2013 

### 17 :05 13 . 936 4 .084 1.595 2.309 E 

### 2 2 / 25/2013 

### 17 : 06 13 . 917 4 .095 1 . 537 3 . 619 

### E 2 2 / 25

/ 2013 

### 17 :07 13 . 914 4 .094 1.51 6 . 581 E 

### 2 2/ 25/2013 

### 17 :08 13 .951 4 .073 1 . 629 3 .401 

### E 2 2/25/2013 

### 17 :09 13 . 942 4.076 1.536 2.946 

### E 2 / 25/2013 

### 17 : 10 13 . 926 4 .082 1 . 534 5.491 

### E 2 / 25 1 2013 

### 17 : 11 13 . 937 4076 1 . 647 2.426 

### E 212512013 17 : 12 13 . 896 4 .098 1.457 3 . 241 

### E 212512013 17 : 13 13 . 899 4 .094 1.472 3 . 699 

### E 1 2 1 25

/ 2013 

### 17 : 14 13 . 91 4 .089 1 . 509 3 . 078 S 3 2 1 25 1 2013 17 : 17 13 . 984 4 .044 1 . 513 3 .001 

### S 3 212512013 17 : 18 13.969 4 .052 1.622 3 .082 

### S 3 212512013 17 : 19 13.962 4 .053 1 . 542 2 . 355 

### S 3 2 / 25 1 2013 

### 17 : 20 13 . 958 4 .051 1.619 2 . 369 

### S 3 2 / 25 1 2013 

### 17 :21 13 . 948 4 .053 1.536 2 . 554 

### S 2 2/2512013 

### 17 :22 13 . 942 4.054 1.531 2 . 227 

### S 2 2/2512013 

### 17 :23 13.936 4.058 1.469 2 .733 

### S 2 2 1 25

/ 2013 

### 17 :24 13 . 93 4 .059 1.556 2.409 

### S 2 2 1 25

/ 2013 

### 17 :25 13 . 922 4 . 061 1.525 2 . 326 

### S 2 2125/2013 

### 17 :26 13 . 917 4 .064 1.458 2 .941 

### S 2125/2013 

### 17 :27 13 . 927 4 . 06 1.438 2 .733 

### S 2 / 25 1 2013 

### 17 : 28 13 . 919 4 .064 1.455 2 . 564 

### S 2 1 2512013 17 : 29 13 . 935 4 .051 1 .456 2 . 546 

### S 2125/2013 

### 17 : 30 13.962 4 .036 1.44 2.548 

### S 212512013 17 : 31 13 . 946 4 .04 1.421 2 .478 W 

### 3 2 / 25 1 2013 

### 17 : 34 13 . 92 4 .052 1 .656 2 . 524 W 

### 3 2/2512013 

### 17 : 35 13 . 926 4.047 1 . 665 2 . 634 W 

### 3 212512013 17 : 36 13 . 915 4 .055 1.661 2 . 516 W 

### 3 2 1 2512013 17 : 37 13 . 918 4 .052 1.681 2 . 359 W 

### 2 2125/2013 

### 17 :40 13 . 913 4 . 057 1 . 511 2.27 W 

### 2 2 1 25 1 2013 17 :41 13 . 912 4 .055 1.556 2.435 W 

### 2 2 / 25 1 2013 

### 17:42 13 . 917 4 .048 1.497 2 . 896 W 

### 2 2/2512013 

### 17:43 13 . 907 4 .052 1 . 539 3.051 W 

### 1 2/2512013 

### 17 :44 13 . 903 4 .051 1.567 2 .649 W 2 1 25

/ 2 0 13 

### 17 :45 13 . 894 4 .055 1 .579 2 . 646 W 

### 2 1 2512013 17 :46 13 . 902 4 .049 1 . 518 2 .738 W 

### 212512013 17 :47 13 . 904 4.048 1.473 2 . 853 W 2125/2013 

### 17:48 13 . 915 4 .041 1.492 2 . 975 Average 

### 13 . 93 4 . 07 1 . 54 2.27 13.68 28 . 31 81.68 

## Dlllta AIrQualifY SIIIVlclIS 1845 N . 

### Case Street Sentinel Un it 5 75% NOx- NH3-ROG Compliance.xls 

### Orange , Californ i a 92865 3/16/20 13 714-279-6777 2:48 PM

### REFERENCE METHOD 1-MINUTE AVERAGE DATA 

### Port Point Date Time 

### 0, CO, NO. CO O2-ln NOx-ln 

### CO-In THe-In W 

### 3 2/25/2013 

### 18 :08 13.937 4.04 2.126 4.251 W 

### 3 2/25/2013 

### 18 :09 13 .947 4 .038 2 . 101 3 . 658 W 

### 3 2/25/2013 

### 18 : 10 13 .952 4 .036 2 .073 3 . 615 

# w 3 2/25/2013 

### 18 : 11 13 .957 4 .037 2.122 3.131 W 

### 3 2/25/2013 

### 18 : 12 13.965 4 .03 4 2 .053 4 . 695 

# w 2 2 /25/2013 

### 18 : 13 13 .97 4 .0 31 2 .077 4 . 112 W 

### 2 2 / 25

/ 2013 

### 18 : 1 4 13 . 97 4 .032 2 .066 4 .058 

# w 2 2/25/2013 

### 18 : 15 13 .981 4 .027 2.161 5.381 W 

### 2 2/25/2013 

### 18:16 13 .977 4 .027 2.174 4.788 W 

### 2 2/25/2013 

### 18:17 13 .9 87 4 .018 2.367 5 .039 W 2/25/2013 

### 18:18 13 .992 4 .0 14 2.373 4 .506 

# w 2/25/2013 

### 18 : 19 13 .989 4 .017 2.404 4 . 539 W 2/25/2013 

### 18 :20 14 .005 4 .008 2 . 342 5.498 

# w 2/25/2013 

### 18 :2 1 14.01 4 .007 2 . 394 5.505 W 2/25/2013 

### 18 :22 14 .003 4 .009 2 . 319 6 .592 

### 5 3 2/25/2013 

### 18 :26 13.965 4 .042 1.704 3 . 83 

### 5 3 2/25/2013 

### 1 8 :27 13 .946 4 .054 1.669 4 .092 

### 5 3 2/25/2013 

### 18 :28 13 .9 46 4 .051 1.683 3.543 

### 5 3 2/25/2013 

### 18 :29 13 . 946 4 .05 4 1.606 3.81 

### 5 3 2/25/2013 

### 18 : 30 13 .939 4 .061 1 .762 3.352 

### 5 2 2/25/2013 

### 18 : 31 13 .941 4 .058 1 .575 4 .058 

### 5 2 2/ 25

/ 2013 

### 18 : 32 13 .95 4 .055 1 .579 3 .613 

### 5 2 2/25/2013 

### 18 : 33 13.947 4 .056 1.552 3.997 

### 5 2 2/25/2013 

### 18 :3 4 13.944 4 .058 1 .621 3.586 

### 5 2 2/25/2013 

### 18 : 35 13 .95 4 .05 4 1.627 2 .545 

### 5 1 2/25/2013 

### 18 : 36 13 .975 4 .042 1.464 3.411 

### 5 1 2/25/2013 

### 18 : 37 13 . 962 4.049 1.528 3 . 1 

### 5 1 2/25/2013 

### 18:38 13.964 4 .0 49 1 . 503 3.58 

### 5 1 2/25/2013 

### 18:39 13.953 4 .057 1 .5 42 3 .95 8 E 3 2/25/2013 

### 18:44 13.92 9 4 .073 1 .929 4.4 5 E 3 2/25/2013 

### 18 :45 13 . 927 4 .07 1.929 3.036 E 

### 3 2/25/2013 

### 18 :46 13.937 4 .064 1.941 3.552 E 3 2/25/2013 

### 18 :47 13 . 939 4 .059 1 .98 3.325 E 2 2/25 / 2013 

### 18:48 13 .938 4 .061 1.917 3.48 E 

### 2 2 /25/2013 

### 18 :49 13.945 4 .056 1 .763 3 .0 29 E 2 2/25/2013 

### 18 : 50 13 .9 59 4 .048 1 .743 3.518 E 

### 2 2/25/2013 

### 18 : 51 13 .959 4 . 048 1 .71 1 4.164 E 2/25/2013 

### 18 :54 13 .975 4 .037 1 .546 3 .023 E 2/25/2013 

### 18:55 13 .98 4 .034 1.516 3.51 E 2/25 /20 13 

### 18 :56 13.976 4 .035 1.54 3.434 E 

### 1 2 / 25

/2013 

### 18 : 57 13 .971 4 .038 1.545 3 . 563 N 3 2/25/2013 

### 19 :00 13.986 4 .0 27 2 .226 4 .076 N 

### 3 2/25/2013 

### 19 :01 13.987 4.029 2.228 3 .91 1 N 

### 3 2/25/2013 

### 19 :02 13 .982 4 .03 2 2 .23 4 .232 N 

### 3 2/25/2013 

### 19:03 13.981 4 .034 2 .255 5 . 123 N 

### 3 2/25/2013 

### 19 :04 13 . 981 4 .034 2 . 309 5.437 N 

### 2 2 / 25

/2013 

### 19 :05 13.99 4 .022 2.464 5 . 903 N 

### 2 2/25/2013 

### 19 :06 13 .99 1 4.025 2 . 545 4.53 N 

### 2 2/25/2013 

### 19:07 13 .989 4 .0 26 2.421 5 . 164 N 

### 2 2/25/2013 

### 19 :08 13 .999 4 .019 2.498 4 .999 N 

### 2 2/25/2013 

### 19 :09 13 .997 4 .02 2.507 3 . 638 N 2/25/2013 

### 19 : 10 14.018 4 .006 2 .536 4 .16 7 N 2/25/2013 

### 19 : 11 14 .008 4.012 2 . 636 4.484 N 2/25/2013 

### 19 : 12 14.004 4.013 2 .68 3 4 . 502 N 2 /25/ 2 0 13 

### 19 : 13 14.004 4 .013 2.732 4 . 301 N 2 / 25

/ 2013 

### 19 : 14 14 4 .016 2 .638 4 . 817 Average 

### 13.97 4.04 2.00 4.11 13.67 27.29 132.88 

# DellaAirQualityServices 1845 N. Case Street Sentinel Unit 5 75% NOx-NH3-ROG Compliance.xls 

### Orange , Californ i a 92865 3/16/2013 

### 7 14 -279 -67 77 2 :48 PMCOMPLIANCE TES T DATA AN D WOR K SHEET CPV Sent in el- 5- CE M S -50-1 TEST CONSTANTS Stat ion : CPV Sentinel U n it: 5 Performed 

### B y: AA , MC , RM , JM Cp : 0
. 99 T ref : 60 o f Stack Area : 143.1 4 ft' Meter y o;!: 1
. 014 METHOD 2 .1 DATA dP Temp Ve l. P oi nt (i n . H 2 O ) sqrt (d P) o f (Ips ) 4 0
. 67 0
. 8185 764 83
. 7 1 3 0.73 0
. 8544 766 87.45 2 0
. 84 0
. 9165 769 93.92 1 0
. 82 0
. 9055 768 92
. 76 4 0 .46 0
. 6782 769 69
. 50 3 0
. 58 0
. 7616 770 78
. 07 2 0
. 63 0 .7 937 771 81.40 1 0.69 0
. 8307 770 85.16 4 0.56 0
. 7483 772 76.78 3 0
. 59 0
. 7681 774 7 8
. 87 2 0
. 67 0
. 8185 777 84
. 15 1 0
. 78 0
. 8 832 775 90
. 72 4 0
. 36 0
. 6000 775 61.64 3 0.41 0
. 6403 777 65.83 2 0 .4 8 0
. 6928 778 7 1 .26 1 0
. 47 0
. 6856 776 70.45 Averag e 0
.6002 0 .7748 771
. 9 79.48

Stack Fl o w Rate : 682 .6 kw acfm Stack Flow Rate : 259
. 7 kdscfm Dry G as Me t er Ti me Vol. Tm(i n) Tm (out ) # / Mati
. Start 423
. 639 69 70 H , O 72 72 H,O E n d 461.418 73 73 E mpty 70 71 SG Tota l 37.77 9 71
. 3 Tota l**NO~** ppm NO x , ppm@ 15% O 2 N O . I b /MMBtu N O . Ib /hr CO ppm CO, ppm@ 15% O 2 CO Ib/hr O 2 % S l ack F low dscfh CT Fuel F low hscfh Tu rbine Water I nje c tion gpm

1845 N
. Case Stre et Oran g e , California 92865 7 1 4-279 - 6 77 7 CT Load MW SCR NH3 Inject i on I b/hr NO. Ib/MMSCF CO I b/ MMBtu CO I b/ MMSC F TEST VARIABLES Start Date : 

### 2/26/13 Start/End Time : 8 : 30 9 : 37 Load (MW )/Replicate# 

## SO 1 Barom . Pressure : 29.47 Pstack : 2
. 8 0 iwg Pstack : 29
. 68 "Hg MW: 28
. 16 Ib/l b-mole METHOD 100
. 1 DATA 

### 0, C O , NO
. CO Ana l yzer Range 20 10 5 10 Cal Gas Value 18
. 98 9
. 62 4
.62 9.56 P r

e-Test Direct Zero 0
. 11 0.07 -0
. 03 -0
. 04 Pre -Test Direct Span 18.95 9
. 68 4 .60 9.5 5 Pre- Test System Zero 0
. 16 0
. 11 -0
. 03 0
. 03 P r

e-Test System Span 18
. 96 9
. 65 4
. 55 9
.6 6

Post- Test System Zero 0
. 15 0
. 11 -0
. 01 0
. 05 Post - Test System Span 18
. 85 9
.64 4
. 57 9
. 65 Pos t - Test D irect Zero 0
. 13 0 .07 - 0
. 02 0 .0 5 Post-Test Di rect Span 18
. 91 9
.6 6 4
. 60 9
. 58 Average 1 4
. 13 3
. 90 2
. 05 0
. 51 Ca rr. results 14. 1 5 3
. 83 2
.09 0.47 Pre- lest zero bias 0 .2% 0.4 % -0 . 1% 0. 7% Pre - test span bias 0 .0 % 

### ·0 .4 % - 1.0 % 1 . 1 % Post-te st zero b ias 0 . 1% 0 .4 % 0 . 2 % -0 . 1 % Post-test span bias - 0 .3% -0 .2 % -0 . 7% 0 .7 % Zero drift 0 .0% 0 .0 % 0 .4 % 0 .2% Span d r ift - 0.6% - 0 . 1% 0.4% - 0 .2% METHOD 4
. 1 DATA I mp i nge r s End Start D itt . 895
. 2 727
. 2 168.0 Meter Press ure : 1. 5 i wg 744.8 744
. 3 0
. 5 Sample Volume : 37
. 068 dscl 629
. 8 629
. 3 0
. 5 H 20 Vol ume : 3
. 728 scI 947
. 3 936
. 1 11
. 2 Mo isture Co n tent : 9 . 1 

### % I r 1 00 80
. 2 RESULTS ReI
. Meth CEMS

2
. 09 1
. 60 1
. 83 1.41 0. 007 0
. 0 0 5 3
. 95 2
. 8 6 0.47 0
. 20 0.41 0
. 13 0
. 53 0
. 00 14
. 15 14
. 0 4 15 , 5 7 9 , 523 15 , 000 , 000



## - 5
. 384



### -

- 55



## - 1 03 7
. 34 

### - 0
. 001 

## - 0
. 96 

## - Sentinel U nit 5 50% N Ox-NH3- ROG Compliance .xl s 

### 3/16/20 1 3

2:48 PMCOMPLIANCE TEST DATA AND WORKSHEET CPV Sentinel-5-CEMS-50-2 TEST CONSTANTS Station : CPV Sentinel Unit : 5 Performed 

### By : AA. MC
. RM
. JM Cp : 0
. 99 Tref: 60 

### o f Stack Area: 143 .1 4 ft ' Meter Yd : 1.014 METHOD 2
. 1 DATA dP Temp Vel. Point (in. H ,O) sqrt(dP) 

### o f (Ips) 4 0
. 38 0
. 6164 774 63.30 3 0.49 0
. 7000 776 71
. 94 2 0.45 0
. 6708 776 68
. 94 1 0.36 0
. 6000 775 61.64 4 0.61 0
. 7810 776 80.26 3 0
. 66 0
. 8124 778 83.56 2 0.72 0
. 8485 779 87.31 1 0.78 0
. 8832 777 90
. 80 4 0.65 0
. 8062 775 82
. 82 3 0
. 81 0
. 9000 776 92.49 2 0
. 84 0
. 9165 774 94.11 1 0.88 0
. 9381 774 96
. 33 4 0.47 0.6856 773 70
. 37 3 0
. 56 0
. 7483 775 76 .87 2 0.64 0
. 8000 776 82
. 21 1 0.66 0
. 8 124 774 83.42 Average 0.6123 0
. 7825 775
. 5 8040

Stack Flow Rate : 

### 690.5 kwacfm Stack F low Rate : 261.8 kdscfm Dry Gas Meter Time Vol. T m(in) T m(out) #/Matl. Start 462
. 644 78 78 H,O 74 75 H,O End 499
. 270 75 75 Empty 72 72 SG Total 36
. 626 74
. 9 Total**NO~** ppm**NO~ ,**  ppm@ 15% O 2 NO, Ib/MMBtu NO, Ib/hr CO ppm CO , ppm@ 15% O 2 CO Ib/hr O 2 % Stack Flow dscfh CT Fuel F low hscfh Turb in e Water Injection gpm CT Load MW SCR NH3 Injection Ib/hr

'vV'''vvv 

### 1845 N
. Case Street Orange
. California 92865 714-279- 6777 NO, Ib/MMSCF CO IblMMBtu CO Ib/MMSCF TEST VARIABLES Start Date : 2 /26/13 Start/End Time : 10:00 11 : 09 Loa d (MW)/Replica1e# 50 

### 2 Baram . Pressure : 29.47 Pstack: 2 .80 iwg Ps ta ck : 29
.68 "Hg MW : 28.16 Ih/lb-mole METHOD 100.1 DATA 

### 0, CO, NO, CO Analyzer Range 20 10 5 10 Cal Gas Va l ue 18
. 98 9
. 62 4
. 62 9
. 56 Pre-Test Direct Zero 0
. 13 0.07 -0.02 0
. 05 Pre-Test Direct Span 18
. 91 9.66 4
. 60 9.58 Pre-Test System Zero 0
. 15 0.11 -0
. 01 0.05 Pre -Test System Span 18
. 85 9.64 4
. 57 9.65

Post-Test System Zero 0
. 16 0
. 18 -0
. 01 -0.02 Post-Test System Span 18
. 83 974 4
. 56 9
. 62 Post-Test Direct Zero 0
. 13 0.13 -0
. 01 0
. 04 Post-Test Direct Span 18
. 87 9.75 4
. 59 9.60 Average 14 .07 3
. 98 2.40 0.51 Corr . results 14
. 13 3.86 2.43 0.49 Pre-test zero bias 0 . 1 % 0.4% 0 .2% -0. 1% Pre-test span bias 

### -0 .3% -0.2% - 0 .7% 0 .7% Post-test zero bias 0 .2% 0 . 5 % 0 . 1% 

### -0.6% 

### PosHest span bias - 0 .2% -0.1% -0 . 7% 0 .2% Zero drift 0 .0% 0 .7 % 0 .0% -0,7% Soan drift -0 . 1% 1 .0% -0.2% -0 . 3% METHOD 4
. 1 DATA Imp ingers End Start Diff
. 855
. 1 687.7 167.4 Meter Pressure: 1 .5 iwg 658
. 2 657.2 1.0 Sample Volume: 35
.693 dscl 579
. 0 578
. 7 0
. 3 H 2 0 Volume : 3 ,607 scf 1012
. 1 1003.2 8
. 9 Moisture Content: 9 .2 %

Ir 100 77.6 RESULTS Ref . Meth CEMS

2.43 1
. 80 2
. 12 1
. 56 0
. 008 0
. 006 4
. 63 3
. 38 0.49 0
. 20 0.43 0
. 17 0.56 0
. 00 14 .13 14
. 02 15.706.947 15.008.000



### - 5.400



## -

- 55



### - 103 8.58 

## - 0.001 

### - 1.01 

## - Sentinel Unit 5 50% NOx-NH3-ROG Compliance. xls 311612013

2:48 PM

### REFERENCE METHOD 1 -M INUTE AVERAGE DATA Port Point Date Time 

### 0, CO, NO , CO 02-ln NOx-ln 

### CO-In THC

- In W 3 2 / 26

/ 2013 

### 8 : 31 14.211 3 . 9 1 .789 0 . 52 14 . 21 25 .975 54 . 795 3 .638 W 

### 3 2/26/2013 

### 8 : 32 14 . 208 3 . 901 1 .793 0.547 14.208 25 .974 54 . 967 3 .641 W 

### 3 2/26/2013 

### 8 : 33 14.203 3 .902 1.834 0.544 14 . 208 26 .055 54 . 372 3 .61 W 

### 3 2/26/2013 

### 8 : 34 14.214 3 . 894 1 . 84 0 .542 14.207 26 .033 54.419 3 .627
W 2 / 26

/ 2013 

### 8 : 37 14 . 201 3 . 89 2 . 188 0 .52 14 . 208 26 . 17 53 . 632 3 . 591 W 2 / 26

/ 2013 

### 8 : 38 14 . 214 3 . 879 2 .071 0.506 14 . 208 26 . 173 53 . 644 3 . 517 W 2/26/2013 

### 8 : 39 14.199 3 . 883 2.11 0 .513 14.208 26 . 297 53.477 3.47
W 2 / 26

/ 2013 

### 8 :42 14.206 3 . 87 2 . 365 0 .481 14 . 208 26 . 182 53 . 502 3.591 W 2 / 26

/ 2013 

### 8 :43 14 . 183 3 . 874 2 . 38 0.496 14 . 196 26 . 191 53 . 144 3 .568 W 2 / 26

/ 2013 

### 8 :44 14 . 185 3 . 872 2 .471 0.478 14 . 193 26 . 25 52 .732 3.487 W 2/26/2013 

### 8:45 14 . 179 3 . 871 2 .511 0.479 14 . 19 4 26 . 313 52 . 189 3.428 

### 5 3 2/26/2013 

### 8:48 14.147 3 . 887 1 . 828 0.374 14.17 26.468 50.903 3 . 27 4 S 

### 3 2/26/2013 

### 8 :49 14.145 3 . 887 1 . 688 0 . 378 14.165 26 . 513 51 . 299 3 . 368 S 

### 3 2 / 26

/ 2013 

### 8 :50 14.148 3 .883 1.735 0 . 364 14 . 179 26 . 651 50 . 379 3 . 232 S 

### 3 2 / 26

/ 2013 

### 8 : 51 14 . 143 3 . 885 1 .768 0 . 337 14 . 162 26 . 757 49.824 3 . 151 S 

### 3 2/ 26

/ 2013 

### 8 : 52 14 . 132 3 . 89 1 .964 0 . 345 14 . 165 26 . 861 49.405 3 .059 S 

### 2 2/26/2013 

### 8 : 53 1 4 .127 3 . 893 1 .751 0 . 3 14 . 161 27 .023 48 .783 3 .02 

### 5 2 2/26/2013 

### 8 :54 1 4 .123 3 . 896 1 .704 0.286 14.154 27.269 4 7.667 2 .939 

### 5 2 2/26/2013 

### 8 :55 14.099 3.91 1 .779 0.271 14.134 27.4 76 46 .625 2 .757 

### 5 2 2 / 26

/ 2013 

### 8 :56 14 .098 3 . 911 1.819 0 . 241 14 . 124 27 . 805 45 . 339 2 . 695 27 8 : 58 S 2 / 26/2013 

### 8 : 59 1 .961 0 . 237 14.13 27 . 842 44.088 2.547 

### 5 2/26/2013 

### 9 :00 1 . 63 0.283 14 . 128 26 .933 47.536 2 . 854 S 2/26/2013 

### 9 :01 1 . 654 0 . 316 14.109 26.422 50.461 3.175 

### 5 2 / 26/2013 

### 9:02 1 .688 0 . 36 14 . 126 26 . 148 52.456 3 . 362 E 2 / 26

/ 2013 

### 9 :0 5 14.12 3 . 899 1.748 0 . 624 14 . 141 26 .039 53 .54 3 . 621 E 2 / 26

/ 2013 

### 9 :06 14 . 107 3 . 905 1.739 0 . 63 14 . 134 25 .998 53.496 3 .529 E 2 / 26

/ 2013 

### 9 :0 7 14 .095 3 .912 1 .723 0 . 647 14 . 117 26 .038 53 .654 3 .59 E 2/26/2013 

### 9 :08 1 4 .102 3 .91 1 .744 0 .636 14.125 26 . 039 53 . 328 3 .554 E 

### 2 2 / 26

/ 2013 

### 9 : 11 14.097 3 .911 1 .79 0 . 62 14 . 116 26 .039 53 . 327 3 . 378 E 2 2 / 26

/ 2013 

### 9 : 12 14 .089 3 .916 1.842 0 . 62 14 . 111 26 .091 52 .996 3.44 4 E 

### 2 2 / 26

/ 2 0 13 

### 9 : 13 14 . 095 3 . 913 1.825 0 . 628 14 . 119 26 .059 53 .063 3 . 521 E 

### 2 2/26/ 2013 

### 9 : 14 14.093 3 .916 1 .731 0 . 662 14.12 26 .034 53 .025 3 . 586 E 

### 1 2/26/2013 

### 9 : 15 14 .093 3 .916 1 . 674 0.674 14.117 26 .072 53.076 3 . 547 E 

### 1 2/26/2013 

### 9 : 16 14 .089 3 .917 1.708 0 .705 14 . 115 26 .044 53 . 12 2 3.52 E 2/26/2013 

### 9 : 17 14.096 3 .914 1 .691 0 .68 14 . 128 26 .016 53 . 347 3 . 618 E 2 / 26

/ 2013 

### 9 : 18 14 . 103 3 .91 1 . 696 0 . 691 14.132 26 .026 53 . 36 3 . 614
N 

### 3 2/26 / 2013 

### 9 :24 14 . 12 3.902 2 . 298 0 . 597 14. 13 26.02 53.319 3.63 4 N 

### 3 2/26/2013 

### 9:25 14 . 122 3 . 899 2 . 274 0 . 581 14. 133 25 .986 53 .62 1 3.625 N 

### 3 2/ 26/2013 

### 9 :26 1 4 . 123 3 . 899 2 . 295 0 . 578 14 . 138 26 .024 53 . 18 3 . 588 N 

### 3 2 / 26

/ 2013 

### 9 :27 14 . 119 3 .901 2 . 358 0 . 572 14 . 133 26 .043 53 . 329 3 .599 N 

### 2 2 / 26

/ 2013 

### 9 :28 14. 106 3 . 907 2 . 601 0 . 557 14 . 121 26 .097 52 .986 3 .566 N 

### 2 2 / 26

/ 2013 

### 9 :29 14 . 106 3 .909 2 . 567 0 . 579 14 . 126 26 .055 52 .921 2 .997 N 

### 2 2/26/2013 

### 9:30 14.102 3 .912 2 .595 0 . 574 14 . 113 26 .08 52.752 3.43 N 

### 2 2/26/2013 

### 9 : 31 14.102 3.912 2 . 542 0 .576 14 . 117 26 .056 52 .974 3.443 N 

### 2 2/26/2013 

### 9 : 32 14 . 1 3 . 913 2 . 539 0.581 14.113 26 .033 53.323 3.486 N 2/26 / 2013 

### 9 : 33 14 . 1 07 3 .91 2 . 725 0.531 14.125 26 .04 53.032 3.437 N 2 / 26

/ 2013 

### 9 : 34 14 . 104 3 .9 1 2 2 . 84 0 . 537 14 . 111 26 .025 52 .975 3.422 N 2/ 26/2013 

### 9 : 35 14 . 107 3 .912 2 .773 0 . 53 14.11 26 .004 53.404 3.459 N 2 / 26/2013 

### 9 : 36 14.099 3 .915 2 . 825 0 . 555 14 . 108 25 .948 53.415 3 . 517 N 2/26/2013 

### 9 : 37 14.102 3 . 91 4 2 . 828 0 .566 1 4 . 112 25 .904 54 . 118 3.522 Average 

### 14.13 3.90 2 . 05 0 . 51 14 . 15 26 . 32 52 . 12 

## DellaAirQualityServices 1845 N . Case Streel Sentinel Unit 5 50% NOx· NH3·ROG Compliance.xls 

### Orange , California 92865 3/16/2013 

### 714-279

- 6777 2:48 PM

### REFERENCE METHOD 1-MINUTE AVERAGE DATA Port Point Date Time 

### 0, CO 02-ln**NOx~ln** 

### THC-In W 3 2/26/2013 

### 10:01 14.077 14 .052 25.316 3.952 W 

### 3 2/26/2013 

### 10:02 14.062 14 .044 4 .024 W 

### 3 2/26/2013 

### 10 :03 14.057 14 .039 4 .04 

# w 3 2/26/2013 

### 10 :04 14 .04 14 .035 3.686
W 

### 2 2/2612013 

### 10:07 14.059 3.947 2 .591 0.608 14 .038 25.875 52 .678 3.48 W 

### 2 2/26/2013 

### 10 :08 1 4 .056 3 .949 2 .553 0 . 637 14 .0 41 25.925 52 .567 3.509 W 

### 2 2/26/2013 

### 10:09 14.073 3.942 2 .56 2 0.607 14 .055 25.999 51.727 3 . 298 W 

### 2 2/26/2013 

### 10 : 10 14.083 3 . 942 2.459 0.595 14.059 25.846 52.463 3 .433 

# w 1 2/26/2013 

### 10:11 14.067 3 . 949 2.566 0 . 595 14 .0 58 25.848 52 . 853 3.504 

# w 1 2/26/20 13 

### 10 : 12 14 .072 3 . 949 2 .564 0 . 607 14 .056 25 . 887 52.603 3.446 W 2/26/2013 

### 10:13 14 .091 3 .941 2 .7 0 . 552 14 .062 25 . 835 53 . 211 3.471 W 2 / 26

/ 2013 

### 10 : 14 14 .067 3 .955 2 . 831 0 .559 14 .044 25 . 881 52 . 765 3 . 37 

### S 3 2 / 26/2013 

### 10 : 20 14 .0 54 3.968 1.947 0.438 14 .034 26 .0 11 52 .3 83 3.46 

### S 3 2/26/2013 

### 10 : 21 14 .042 3.976 1 .9 89 0.445 14 .02 25 .997 52 . 894 3.556 

### S 3 2/26/2013 

### 1022 14 .038 3.98 1 .952 0.429 14 .01 1 26.008 52 . 165 3.388 

### S 3 2/26/2013 

### 10:23 14 .04 3.983 1 .925 0.421 14.013 25 . 986 51 .964 3.322 

### S 2 2/26/2013 

### 10:24 14 .04 3 .982 1 . 88 0.454 14.016 25.898 53 . 23 3 . 607 

### S 2 2/26/2013 

### 10 :25 14 .041 3 .982 1 . 834 0 .353 14 .03 25 .934 53 . 279 3 . 684 

### S 2 2/26/2013 

### 10 :26 14 .037 3.987 1 . 848 0 .339 14 .015 25 .942 53 . 32 3 . 263 

### S 2 2/ 26

/ 2013 

### 1 0:27 14 .04 3 . 988 1 . 815 0.322 14 .0 14 25 .958 52 .914 3.464 

### S 2/26 / 2013 

### 10 : 30 14 .032 3 . 997 2 .037 0 . 343 14 .00 1 26 .087 52.209 3.454 

### S 2/26/2013 

### 10 : 31 14.026 4 1 .952 0 . 327 13 .991 26.082 51.881 3.383 

### S 2/26/2013 

### 10 :32 14.038 3.994 1 . 852 0.287 14 .006 26.009 51 . 848 3.309 

### S 1 2/26/2013 

### 10 : 33 14 . 038 3 . 995 1 . 864 0 . 322 14 .007 25.986 52 . 28 3.361 E 3 2 /2 6/2013 

### 10:38 14.061 3 . 988 2 . 382 0 . 577 14 .02 25.876 52 . 895 3.551 E 

### 3 2/26/2013 

### 10:39 14.072 3 . 984 2 . 276 0 . 557 14 .029 25 . 838 53 .538 3 .59 E 

### 3 2 / 26

/20 13 

### 10 :40 14 .074 3 .984 2 . 294 0 . 568 14 .028 25 . 895 52 . 921 3 . 393 E 

### 3 2 /26/ 2013 

### 10:41 14 .06 1 3 .99 2 . 36 0.581 14 .01 25.965 52 . 318 3 .013 E 

### 3 2/26/ 2013 

### 10 :42 14 .075 3 .986 2.429 0.565 14 .028 25.903 52 . 544 2.718 E 

### 2 2/26/2013 

### 10:43 14 .089 3.979 2 .588 0.551 14 .034 25 .914 52.46 3 . 108 E 

### 2 2/26/2013 

### 10:44 14 .088 3.977 2 .59 0 .548 14 .033 25 .902 52.459 3.219 E 

### 2 2/26/2013 

### 10:45 14.078 3.98 2 . 611 0.559 14.026 25 . 917 53.233 3.627 E 

### 2 2/26/2013 

### 10:46 14 .088 3.973 2 . 603 0.542 14 .035 25 .915 53 .047 3.515 E 

### 2 2/26/2013 

### 10 :47 14 .087 3 . 973 2.725 0.548 14 .034 25.932 52 . 77 3.403 E 

### 1 2/26/2013 

### 10 :48 14 .089 3 . 969 2.9 0.52 14 .036 25.927 52 .998 3.548 E 2 / 26

/ 2013 

### 10:49 14 .087 3 .968 2 . 762 0.494 14 .031 25 .94 52 .075 3 . 243 E 2 / 26

/ 2013 

### 10 :50 14 .091 3 .964 2 . 894 0.476 14 .037 26 .009 51 . 393 3 .035 E 2/26/2013 

### 10 : 51 14 .089 3.967 2 .921 0 .489 14 .031 26 .031 51 . 119 3 . 135 E 2/26/2013 

### 10 : 52 14 .065 3.981 2 .93 7 0.491 14 .01 26 .095 50 . 237 3 .021 N 3 2/26/2013 

### 10 : 55 14 .069 3 .986 2 . 319 0 .536 14 .016 26 .03 50 .096 3 . 038 N 

### 3 2/26/2013 

### 10:56 14.057 3.994 2 . 331 0.515 14 .004 26 .058 49 . 941 2 . 961 N 

### 3 2/26/2013 

### 10 : 57 14.063 3.993 2 . 368 0.531 14 .01 26 .011 50 . 829 3.177 N 

### 3 2/26/2013 

### 10 : 58 14 .074 3.991 2 . 357 0.533 14.024 26 . 067 50 .0 33 2 .994
N 

### 2 2 /26/ 2013 

### 11 :01 14 .081 3 . 995 2 .658 0.486 14 .02 26 .066 49 .799 2 .97 N 

### 2 2/ 26

/ 2013 

### 11 :02 14 .083 3.993 2 .572 0 . 504 14 .024 26 .05 50 . 11 3 .01 N 

### 2 2/ 26

/2013 

### 11 :03 14 .088 3 .995 2 . 664 0.485 14 .03 26 . 106 49 .595 2 .992 N 

### 2 2/ 26/2013 

### 11 :04 14 .089 3 .993 2 . 656 0.495 14 .034 26.014 50.111 3.02 N 2/26/2013 

### 11 :0 5 14.085 4 .001 2 . 691 0 .479 14 .0 25 26.05 50 . 318 3 .0 13 N 2/26/2013 

### 11 :06 14.082 4 .001 2 .711 0 . 51 14 .024 26 . 109 50 . 881 3.338 N 2/26/2013 

### 11 : 07 14 .084 4 .006 2 . 941 0.5 14 .017 26 .065 50.857 3 . 386 N 2/26/2013 

### 11 : 08 14 .083 4.004 2 . 866 0 . 538 14.023 26.07 50.118 3.086 N 2/26/2013 

### 11 :09 14 .085 4 .006 2 .771 0 . 501 14 .022 26 .045 50.128 3 .062 Average 

### 14 . 07 3.98 2 ,40 0,51 14 , 03 25,94 52 , 18 

## OllIlaAirQualilY SlIrvlclIS 1845 N , Case Street Sentine l Un it 5 50% NOx-NH3-ROG Compliance.xls 

### Orange, California 92865 3/16/2013 

### 714-279-6777 2:48 PM

## Appendix 

## C.2.3 One Minute Data Logger Data

R5210729 

## C-6Date Time 

### 0 , % CO, 

### % 2/25/2013 7:44:00 AM 

## 1L...,;:,0.,,'4,:,...._;0.;::03,;2'-1 2/25/2013 7:45:00 AM 14 . 55 7805 2125/2013 7:46:00 AM 19.018 9.711 2125/2013 7:47 :00 AM 

## I 19 .022 9 .623 212512013 7:48 :00AM 11.639 5.769 2125 / 2013 7:49 :00AM 10 . 105 5.055 2125 / 2013 7:50:00 AM 

## 1,.....;,;::0.",0;;;4;-...;:;5.;;;05;;3,...., 2125/2013 7:51 :00 AM

## '-:'';'7.':;:496;;;;--~'.';'73;i8~**NO~** CO PPM PPM ·0.005 ·0.02 -0015 -0 . 037 ·0 . 021 

## J -0.017 -0 . 022 -0.031 ·0 . 027 

## I -0.014 2 . 331 7.471 4 . 543 9.971 4 . 558 9.542 2125/2013 7:52 :00 AM 20.915 0.082 4.596 10.059 2/25/2013 7:53:00 AM 20.928 0.079 4 .604 4.889 2/25/2013 7:54:00 AM 20.941 0.079 4 . 599 4.451 2125/2013 7:55:00AM 20.941 0 . 078 4 . 576 4.314 2125/2013 7:56 :00 AM 20 . 941 0 . 079 4 . 574 1 .234 2125/20 13 7:57 :00 AM 20 . 936 0 . 076 4 . 567 0 .657 2125 / 2013 7:58 :00 AM 20 . 926 0 .075 0.417 0.646 2125 / 2013 7 :59 :00 AM 20.939 0.075 0 . 001 0.644 2125/2013 8:00:00 AM 20 . 942 0.076 2 .738 0.659 2/25/2013 8:01 :00 AM 20.933 0.076 3 .457 0.681 2/25/2013 8:02:00 AM 20.932 0.079 3.445 3.964 2125/2013 8:03 :00 AM 20 . 941 0.078 3.452 0.723 2/25/2013 8 :04:00AM 20 . 941 0 . 079 2 . 175 0.638 2125 / 2013 8 :05:00 AM 20 . 942 0.079 -0 . 013 0.629 212512013 8:06 :00 AM 20 . 942 0 . 078 -0 . 024 0 . 621 2125 / 2013 8:07:00 AM 20 .942 0 .079 -0 .015 0 .606 2 / 25

/ 2013 8:08:00 AM 20 .941 0.0 79 1 . 548 0.596 2/25/2013 8:09:00 AM 20.941 0.079 4 .589 0.581 2/25/2013 8:10 :00 AM 20.937 0.079 4 .596 0.581 2/25/2013 8:11 :00 AM 20.932 0.08 4 . 601 0.57 2125/2013 8:12:00 AM 20 . 922 0.08 4 . 603 0.569 2/25/2013 8:13:00 AM 20.917 0.081 2 . 837 0.57 2/2512013 8:14 :00 AM 20 . 916 0 .081 2.462 0 . 547 212512013 8 : 15 :00 AM 20 . 917 0.081 2.53 0 . 546 212512013 8:16 :00 AM 20 . 915 0 . 081 2 .531 0 . 546 2125 / 2013 8:17 :00 AM 20 . 903 0.08 1.8 0 . 543 2125/2013 8 : 18:00 AM 20.892 0.08 0.007 0.495 2/25/2013 8:19:00 AM 20.893 0.082 0.005 0.477 2/25/2013 8:20:00 AM 20.893 0.082 0 . 012 0.483 2125/2013 8:21 :00 AM 20 .893 0.083 0 . 014 0.486 2125/2013 8:22 :00 AM 20.893 0.084 0 . 017 0.483 212512013 8:23 :00 AM 20 .894 0 .085 0 . 013 0.474 212512013 8:24:00 AM 20 .941 0.083 0 . 005 0.459 2125 / 2013 8:25 :00 AM 20.942 0.083 0 .002 0.457 2125/2013 8:26:00 AM 20 . 942 0.082 -0 .007 0.459 2/25/2013 8:27:00 AM 20.908 0.084 -0.007 0.446 2/25/2013 8:28 :00 AM 20.477 1.539 -0 . 005 0.448 2125/2013 8 :29:00 AM 19.004 9 . 576 -0 . 005 -0.104 2125 / 2013 8 : 30 :00 AM

## rl""1;';9:;;**0;;;0";2-""9;;; 6;;;0';'~"';-0;;;** **0;;;':;:6""** -0.187 2125/201 3 8 : 31:00AM 16 .767 8 . 202 0.387 -0.17 2125 / 2013 8 : 32 :00AM 0 . 355 0 . 077 4 .552 0 . 155 2125/2 013 8 : 33 :00 AM

## rl-:i-0**~'64~-""0::'.0i::5;-i'---:4:;; 5~8i:9--::0':i** **2';'74:-"** 2125 / 2013 8 : 34 :00AM 0 . 144 0.046 3.142 1.771 2125/2013 8 : 35 :00 AM 0.138 0 . 044 -0 . 007 9.395 2125/2013 8 : 36 :00 AM 0.138 0.042 ·0 . 02 9 .78 1 2125/2013 8:37 :00 AM 0.138 0 .043 ·0 .025 9 .781 2/25/2013 8:38:00 AM 0 . 138 0.044 1 .272 8.64 2 / 25/2013 8:39 :00 AM 0 . 138 0.043 4.568 0.422 2125 / 2013 8:40:00 AM 3 . 124 0 .05 4 .005 0 . 17 2125 / 2013 8 :41 :00 AM 20 .684 0 . 088 0 .083 0 . 01 212512013 8 :42:00 AM 20 . 832 0 . 092 0.034 0 . 012 2125/2013 8:43 :00 AM 20 . 842 0 . 092 0 .013 5 . 33 2125/2013 8 :44:00 AM 20.852 0.092 0 . 01 9.424 

### 0, %**NO ~**  CO THC PPM PPM PPM 0.022 0.336 7 .294 27.37 39.861 7.428 48.025 232 . 184 4 .905 42 . 059 1 241.1321 1.56 16 . 902 186.927 1.406 0 . 022 131 . 9 0 . 872 ·0 . 045 1 132.885 

## 1 0 . 87 ·0 . 055 99.753 0.758 0.442 0.432 02lC02lCO Cal Zero N2INOx Mode 02lC02lCO Car Hi gh N2INO Mode NO/NOx Mode 02lC02lCO M id N2INO Mode; CO Car High 0.063 12.161 18 . 929 18 . 929 13.488 10 .015 10 .014 4 . 955 0 .071 0.057 0.042 0.46 0.043 0 . 043 0 .043 0 .043 2 . 537 20.725 20 .86 5 2.773 4.686 4 . 61 1.726 0.07 0.067 2.272 0 . 15 0.432 NO/NOx Mode; CO M id;THC Cal Zero 4 . 585 4 . 581 4 . 577 0.494 -0 . 031

2 .8 3.462 3.458 4 .322 25 .7 NO/NO Mode ·0 .0 1 26 . 954 0.035 27 . 325 0 .036 27. 135 N02lNO Mode -0 . 036 26.494 10.453 20.865 3.449 0.19 0.265 0 . 265 0.269 0.261 0.26 0 . 265 0.311 0.538 0.341 0 . 315 0 . 587 0 . 035 

### O

.OOg 0.446 0.436 N02/NOx Mode 0.431 20.819 2.362 0.431 20 .741 ·0.029 3 . 04 20 .744 -0 .03 25 .892 NOx Cal Zero 25 .704 20 .766 ·0 . 037 20.767 12.449 15 .293 20.774 38.842 3 .478 20.865 41.701 0.445 19 .962 28.837 0.434 9 . 591 0 . 08 

### 0 .068 0 .402 0 .048 0.042 0 . 042 0 . 042 0.043 0 . 043 0 . 043 0 . 293 0 . 125 0 . 043 0 . 042 0 . 201 0 . 106 0.042 0.043 0 .043 0 .043 0.317 42.361 24.648 23 .586 23.858 0.434 NOx Ca l High 0.43 0.434 THC Cal Zero 0 .86 23 .867 0.175 17 . 088 NOx Mid 17 . 224 0.Q18 20 . 377

0.1 ·0.017 33 . 127 0 . 051 -0.023 86 . 849 0.031 -0.045 87 . 535 0 . 019 ·0.043 89 .53 0.009 -0.013 88 .98 0 . 344 -0 . 045 89 .824 0 . 574 8.203 60.41 0 . 018 -0 . 038 24 .715 0 . 005 ·0 .038 24 . 155 0.215 -0.044 23.619 0.414 0 . 012 0.007 ·0 . 001 0 .004 0 .779 3 .392 53.496 ·0.044 87.68 -0.045 86 .785 02/C02 bias -0 .047 85 . 56 -0.047 85 .078 1.521 64 .889 NOx bias 0.045 0.015 2.943 21 .898 0 . 519 0 . 995 0.135 0.431 0.109 0.541 9.675 22.615 CO bias 0 . 044 0 .011 0.226 44.658 0.043 0 . 003 0 . 238 45.123 7.298 14 . 652 33.888 42 . 87 13 . 217 30 . 175 165.265 39 .858 13 . 238 30 .707 155.668 34 . 372 13 .239 31 .045 151.591 31 . 152 CO Cal Zero 13 .239 31.137 145.34 23 .29' 13 . 244 31.005 163.322 22.337Date T i me 

### 0, % 

### CO, % 2125/2013 8:45 :00 AM 20 . 851 0.095 2125/2013 8 :46 :00 AM 20.855 0.096 2125/2013 8:47:00 AM 20.864 0.096 2125 / 2013 8 :48 :00 AM 20 . 866 0 . 098 212512013 8 :49 :00 AM 20 . 867 0 . 1 2/2512013 8 : 50 :00 AM 20 . 867 0 . 102 2/25 / 2013 8 : 51 :00 AM 20 .87 0 . 104 2/

25

/ 2013 8 : 52 :00AM 20 . 868 0.105 

### NO , PPM 0.018 0 . 011



## o

-0 . 004 0.008 0 .006 0 .007 -0 .001 

### CO PPM 9.492 9 . 526 9.565 9 . 571 7.05 4 . 506 4.488 2 . 176 

### 0, % NO, PPM 

### CO PPM THC PPM 13 . 239 31 . 292 143.83 22 . 272 13.231 31.403 150 .242 26 . 525 13 . 227 31.41 139.437 27 . 382 13 . 242 31 .641 137 . 5 29.439 CO Cal High 13 . 246 31 . 338 136 . 107 24 .705 13 . 234 31.724 128 .409 24 . 886 13 . 24 31.248 142.487 25 .669 CO M i d 13 . 227 31 . 545 136.666 26 .748 2125/2013 8 : 53 :00AM 19 . 294 4.391 0 . 176 0 . 211 13 .245 31 . 385 148.156 31 . 123 2/25/2013 8:54 :00 AM 19 . 001 9.637

-0 .003 -0.251 13 .242 31.433 143 . 93 28 .775 2/25/2013 8 : 55 :00 AM 

## 1"1"'1"'9;; . 0"'0';'1-....:;;9. :;;6"6---:-0"' . 0"0"'9..., -0.235 13.243 31.43 146.417 29 .948 02/C02 bias 2 1

25/2013 8 : 56 :00 AM 8 . 511 3.988 2.433 -0.123 13 . 247 31.494 144.405 29 .968 2125 / 2013 8:57 :00 AM 0 . 178 0 . 103 4 . 576 0 .212 13 . 24 31 .413 151.061 16.342 2125 / 2013 8 : 58 :00 AM

## 1"1-:i'0**';'14:i8:-~0i:' 0:':i9~2~-'4::'** **5i:8r--';;0;;; 2i53~**  13 .246 31.462 165.249 0 .975 NOx b ias 2125 / 2013 8 : 59 :00 AM 0.137 0.088 4.44 0 . 30 1 13.244 31 . 635 148 .688 0 . 924 2125 / 2013 9:00 :00 AM 0 . 138 0 . 088 0 .069 3 .811 13.248 31.315 161.292 0 . 964 2125/2013 9:01:00AM 0 . 138 0 . 088 -0 . 016 7 .074 16 .888 18 .624 131.847 0 . 865 2125 / 2013 9 :02 :00 AM 0.137 0.089 -0 . 008 9.814 20.908 0 . 861 7.278 0.453 2/25/2013 9:03:00 AM 0.137 0.088 -0 . 009 9.86 20.927 0 . 613 0.559 0.431 2125/2013 9:04:00 AM 0 . 137 0.088 -0 .02 9 . 849 20 . 925 0 . 507 0.384 0.433 CO bias 2125/2013 9:05:00 AM 7 . 007 0 . 105 2125 / 2013 9 :06 :00 AM 0 . 805 0.091 2/25 / 2013 9 :07 :00 AM 0 . 137 0 . 091 2/25 / 2013 9 :08 :00AM 14 .459 0.124 2125 / 2013 9 :09 :00 AM 20 . 859 0 . 14 2125/2013 9:10:00AM 20 . 88 0 . 141 2/25/2013 9:11:00AM 20 . 888 0.143 2/25/2013 9:12 :00 AM 20.902 0.143 2/25/2013 9:13:00AM 20 . 916 0.145 2 / 25

/ 2013 9:14 :00 AM 20 . 916 0 . 145 2 / 25

/ 2013 9 : 15 :00 AM 20 . 917 0 .1 46 2125 / 2013 9:16 :00 AM 20 .917 0 . 146 21 25 / 2013 9 : 17 :00 AM 20 . 916 0.146 2/25 / 2013 9 : 18 :00 AM 20 . 916 0.147 2/

25

/ 2013 9:19 :00AM 20 . 917 0.145 2125/2013 9:20:00 AM 20 . 918 0.145 2125/2013 9:21 :00 AM 20.922 0.146 2125/2013 9:22 :00 AM 20.926 0.146 2125 / 2013 9:23:00 AM 20 . 928 0 . 147 21 25 / 2013 9:24 :00AM 20 . 932 0.148 2125 / 2013 9 : 25 :00 AM 20 . 94 0 . 149 2/25 / 2013 9 : 26 :00AM 20 . 939 0.151 2/25 / 2013 9 : 27 :00AM 20 . 94 0.151 2/

25/2013 9:28 :00 AM 20.94 2125/2013 9:29 :00 AM 20 . 938 2125/2013 9:30:00 AM 20 . 933 2125/2013 9:31 :00 AM 20.932 2125 / 2013 9 : 32:00 AM 20 . 929 2125 / 2013 9 : 33 :00 AM 20 . 929 2125 / 2013 9 : 34 :00 AM 14 . 366 2125 / 2013 9 : 35 :00 AM 2125/2013 9 : 36:00 AM 2/25/2013 9:37:00 AM 13 . 298 13 . 279 13.272 2/25/2013 9:38:00 AM 13 . 264 2125/2013 9:39 :00 AM 13 . 254 2125 / 2013 9:40:00 AM 13 . 271 2125 / 2013 9:41:00 AM 13 . 273 2125 / 2013 9 :42:00 AM 1 3 . 272 2125 / 2013 9 :43 :00 AM 13 . 284 21 25 / 2013 9 :44 :00 AM 13 . 272 2125 / 2013 9:45 :00 AM 13 . 261 2125/2013 9:46 :00 AM 13 . 247 0.153 0.155 0.157 0 . 157 0.158 0.159 3 . 989 4 .509 4.516 4.521 4.525 4.53 4 . 523 4 . 519 4 . 522 4.515 4.523 4.526 4.534 0 .001 -0 . 012 -0 . 019 0 . 001



## o 0 . 009 0 .001 -0.004



## o

-0 . 006 -0 . 003 -0 . 003 -0 . 004 -0 . 002 -0.006

-0.006 -0 . 004 -0 . 002



## o -0 . 002 0 . 005 0 . 009



## o 0 . 004 0 . 003 0 . 001 0.001 0 . 004 0 . 002 4 .862 5.411 5.411 5 .411 5.411 5.411 2 .716 2 . 369 2 . 256 2 .24 2 . 238 2 . 203 2 . 182 7 . 685 20 . 923 0 .423 0.463 0 .431 5 . 048 20 . 914 0 . 379 0 .459 0.432 4 .782 20 . 923 0 . 313 0.457 0.432 4.55 20 . 93 0 . 242 0 . 26 0.432 1.968 20 . 922 0 . 245 0.54 0.435 0.45 20.928 0 . 182 0.287 0 .94 0.434 20 . 928 0 . 148 0.263 0 . 344 0.436 20.926 0 . 131 0.138 0.437 0.43 20.917 0 . 147 0 .287 0.437 0.45 20 . 914 0 . 132 0.361 0 .436 0.433 20 . 916 0 . 106 0 . 315 0 .437 0 . 159 20 . 91 0 . 125 0 . 386 0 .436 0.418 20 .912 0 . 103 0 . 362 0.434 0 .453 20 .915 0.086 0.338 0.435 0.453 20.916 0 .061 0.258 0.433 0.446 20.917 0.066 0 . 212 0.433 0.434 20 .914 0.083 0.363 0.434 0.441 20 .921 0.068 0.311 0.434 0 .437 16 .773 15 .017 29 . 195 0 .529 0 .445 13 .633 29 . 371 156 . 943 0 .952 0.448 18 .90 1 0 . 946 43 . 031 0 .576 0.438 18.978 0 . 246 -0 . 323 0.434 0.441 18 . 978 0 . 191 -0 . 373 0.43 18 .978 0 . 156 -0.376 0.432 0.45 0.445 0.452 0.448 0 .442 0.445 2.995 4 . 93 4 .856 5.06 5.739 6.393 6 . 109 3 .552 1 . 578 1.477 1.356 1.35 1.993 18.978 10.494 0 . 112 0.313 0 . 135 2.913 4 .781 35 . 336 -0.42 3.714 1.597 4.499 0.434 02 bias 0.445 0 .439 0.447 0 .055 0 . 042 0.462 0 . 042 4 . 329 41.924 4 1. 954 0.063 0 .036 0.432 NOx b ias 0.438 12.345 95.601 0 .752 0 . 132 1 240.1991 1.226 8 .769 235 .73 1.212 13.195 30 . 3 176 .326 1.021 13.216 30 . 287 179.263 3.083 13 . 238 30.443 172.535 4 . 364 13 .217 33.348 106 . 051 3 . 909 13 .217 34 . 074 36 . 378 3 . 211 13.228 33.749 33.781 3 . 141 13 . 216 34 . 086 31.81 3 .703 1 3.21 33.98 29.573 5 .745 13.203 33 . 044 50.429 9 . 621 CO biasDate Time 

### 0, % 212512013 9"7:00 AM 13.247 212512013 9"8:00 AM 13.246 212512013 9"9:00 AM 13.247 212512013 9:50:00 AM 13.239 212512013 9:51:00AM 13.237 212512013 9:52:00 AM 13.242 212512013 9:53:00 AM 13.243 212512013 9:54:00 AM 13.247 212512013 9:55:00AM 13.247 212512013 9:56:00 AM 13.247 212512013 9:57:00 AM 15.057 212512013 9:58:00 AM 15.262 

## co, % 4.533 4.536 4.536 4.54 4.54 4.54 4.538 4.536 4.536 4.535 3.422 3.455 212512013 9:59:00 AM 13.247 4.535 212512013 10:00:00 AM 13.448 4.417 21251201310:01:00AM 13.643 4.311 21251201310:02:00AM 13 .642 4.311 212512013 10:03:00 AM 13.624 4.323 212512013 10:04:00 AM 13.604 4.342 212512013 10:05:00 AM 15.922 2.962 212512013 10:06:00 AM 16.613 2.609 212512013 10:07:00 AM 15 .807 3.072 212512013 10:08:00 AM 14.966 3.565 212512013 10:09:00 AM 14.067 4.089 212512013 10:10:00 AM 13.533 4.393 212512013 10:11 :00 AM 13.543 4.387 212512013 10:12:00AM 13.569 4.376 212512013 10:13:00 AM 13.564 4.381 212512013 10:14:00 AM 13.547 4.394 212512013 10:15:00 AM 13.536 4.4 212512013 10:16:00AM 13.58 212512013 10:17:00AM 13.572 212512013 10:18:00AM 13.589 212512013 10:19:00AM 13.593 212512013 10:20:00 AM 13.582 212512013 10:21 :00 AM 13.569 212512013 10:22:00AM 13.573 212512013 10:23 :00 AM 13.567 212512013 10:24:00 AM 13.584 212512013 10:25:00AM 13.574 212512013 10:26:00 AM 13.582 212512013 10:27:00 AM 13 .576 212512013 10:28:00 AM 13.567 212512013 10:29:00 AM 13.566 212512013 10:30:00 AM 13.571 212512013 10:31:00AM 13.556 212512013 10:32:00AM 13.568 212512013 10:33:00 AM 13.556 2/25/2013 10:34:00 AM 13.555 212512013 10:35:00AM 13.552 212512013 10:36:00 AM 13.558 212512013 10 :37:00 AM 13.555 212512013 10:38:00 AM 13.556 212512013 10:39:00 AM 13.558 212512013 10:40:00 AM 13.556 21251201310:41:00AM 13.556 212512013 10 :42:00 AM 13.547 212512013 10"3:00 AM 13.551 212512013 10:44:00 AM 13.545 212512013 10:45:00 AM 13.547 212512013 10:46:00 AM 13.548 212512013 10"7:00AM 13.549 212512013 10:48:00AM 13.547 4.384 4.389 4.385 4.386 4.394 4.4 4.399 4.404 4.399 4.403

4.4 4.4 4.401 4.401 4.4 4.401 4.394 4.396 4.396 4.395 4.392 4.392 4.393 4.393 4.394 4.395 4.4 4.395 4.398 4.394 4.391 4.389 4.391 NO, 

### PPM 2.248 2.247 2.237 2.231 2.223 2.236 2.27 2.236 2.283 2.296 1.852 1.326 1.934 1.964 1.975 1.705 1.656 1.653 1.082 0.364 0.73 0.649 1.708 2.195 2.022 1.986 1.965 2 .009 1.97 1.964 2.007 1.967 1.952 2.79 2.314 2.029 1.956 1.948 1.956 1.96 1.955 1.952 1.942 1.962 1.94 1.974 1.968 1.971 1.961 1.976 1.966 1.948 1.969 1.959 1.959 1.958 1.949 1.978 1.976 1.994 2.002 1.973 

### CO PPM 2.453 2.7 2.164 2.179 2.251 3.083 2.53 2.401 2.535 3.997 3.777 2.291 3.354 3.886 3.938 3.853 3.541 2.592 1.547 0.37 0.262 0.661 0.675 2.744 5.065 4.72 4.43 2.938 1.188 2.609 1.773 1.14 1.345 1.671 2.091 3.863 4.391 4.293 3.623 3.469 3.143 2.808 3.266 3.392 3.189 2.808 3.127 2.979 2.73 2.83 2.783 3.124 3.303 2.759 3.011 3.141 3.416 3.14 3.02 2.978 2.802 3.035 

### 0, % NO, 

### PPM 

### CO PPM 

### THe PPM 13.213 32.771 69.75 13.209 13.2 32.897 84.543 15.989 13.204 33.341 60.032 11.414 13.19 33.212 59.83 11.385 13.192 32.989 61.019 11.584 13.194 32.599 95.135 17.962 13.207 32.99 76.389 14.475 13.21 32.929 67.275 12.766 13.201 32.647 75.966 14.412 13.206 31.555 131.992 24.878 13.209 31.745 134.045 25.17 13.214 31.778 142.049 26.673 13.206 32.021 120.D78 22.6 13.635 30.212 135.847 25.529 13.991 28.873 114.339 21.543 13.979 28.835 112.473 21.197 13.979 29.205 107.298 20.213 13 .92 30.683 70.368 13.339 14.519 29.448 40.529 7.755 16 .889 29.868 26.238 5.092 16.04 28.182 22.487 4.399 15.268 22.274 50.362 9.593 14.338 27.763 35.847 6.871 13.89 29.206 76.345 14.449 13.905 28.598 152.17 28.601 13.923 28.832 137.661 25.889 13.927 28.928 126.926 23.862 13.908 30.73 86.6 16.388 13.892 31.108 23.665 4.645 13.94 29.521 65.889 12.498 13.946 30.871 46.747 8.926 13.945 30.734 22.231 4.38 13.94 30.355 28.615 5.547 13.916 30.538 39.189 7.532 13.941 29.868 48 .02 9.178 13.936 28.832 103.554 19.511 13.936 28.915 124.12 23.337 13.94 29.068 120.384 22.731 13.95 29.18 94.655 17.901 13.93 29.52 93.436 17.737 13.918 29.818 82.72 15.64 13.921 29.713 69.03 13.118 13.929 29.427 85.163 16.11 13.933 29.539 90.179 17.044 17.716 29.68 82.407 15.654 13 .9 16 29.829 68.172 12.926 20.426 3.595 38.49 7.318 19.702 0.562 0.511 0.196 18.369 3.234 16 .5 47 3.211 14.161 27.711 47.424 9.079 14.011 29.102 67.25 12.775 14.02 28.89 68.597 13.049 14.015 28.866 89.59 17.056 14.004 29.331 67.045 12.763 14.013 29.034 72.013 13.701 13 .995 29.05 73.849 14.014 14.016 28.763 81.028 15.383 13.974 29.211 82.526 15.654 13 .388 31.617 75.508 14.376 13.365 31.839 84.966 16.125 13 .362 31.966 74.145 14.112 13.36 31.831 80.413 15.251Date Time 

### 0, % 

### CO , % 212512013 10:49:00AM 13.543 4.396 212512013 10:50 :00AM 13.547 4.392 212512013 10:51 :00AM 13.545 4.395 212512013 10:52 :00AM 13 .541 4.401 2125 1 2013 10:53 :00 AM 13 . 544 4.401 2125 1 2013 10:54 :00AM 13 . 545 4.401 212512013 10:55 :00AM 13.551 4.4 2125 1 2013 10:56 :00AM 13.542 4.405 212512013 10:57:00AM 13.533 4.41 212512013 10:58:00 AM 13.518 4.421 212512013 10:59:00 AM 13.495 4.434 212512013 11 :00 :00 AM 13.499 4.434 212512013 11:01:00AM 16.274 2 .839 2125 1 2013 11:02:00AM 13 .545 4.418 2I251201311 :03 :00AM 13 .529 4.423 2125 1 2013 11 :04 :00 AM 13 . 533 4.42 212512013 11 :05 :00 AM 13 . 533 4.42 212512013 11:06:00 AM 13 . 525 4.426 212512013 11:07:00 AM 13 . 515 4.435 212512013 11:08:00 AM 13.486 4.45 212512013 11 :09:00 AM 13.473 4.458 212512013 11 : 10 :00 AM 17 . 351 2.153 2125 1 2013 11 : 11:00AM 20 . 814 0 . 256 212512013 11 : 12 :00 AM 20 . 808 0 . 259 

### NO, PPM 1.976 1 . 949 1 . 947 1 . 923 1.926 1.945 1 . 924 1.944 1 .894 1.886 1.79 1 . 835 1 . 131 1 .906 1 .915 1 .925 1.931 1.898 1.906 1.779 1 .793 0 . 903 -0 . 004 0 . 002 

### CO PPM 3.312 3.66 3.69 3.667 3 .954 3 .592 3 .798 3.41 4.026 4 . 363 4.219 4.042 2.587 4 . 365 4.423 4 .692 4 . 232 4 . 171 4.37 3.694 4 . 009 2 .766 0.313 0 .231 212512013 11:13:00AM 20.828 0.25 -0.008 0 .215 212512013 11:14:00AM 20.068 1.004 0.001 0.247 212512013 11 :15:00 AM 18.88 9.783 -0 . 004 -0.233 212512013 11:16:00AMI 18.928 9 .818 -0.01 -0.413 21251201311:17:00AM 6.664 3.122 2.846 -0 . 266 212512013 11 : 18:00 

### AM!"I

## ~0**':'16:i:2i-~0;;; ';;23;;;5'---:4~** **5~7~4--:i0'i.0:i22:i--,** 212512013 11 : 19:00 AM 0 . 215 0 .226 2 .236 1.42 212512013 11 : 20 :00 AM 0 . 186 0 . 233 0 .003 4.441 212512013 11 : 21 :00 AM 4 . 844 1.713 0 .809 5531 2125 1 2013 11 : 22 :00 AM 0 . 139 0 . 224 -0 . 004 9.452 212512013 11:23 :00 AM 0 . 133 0.223 -0 . 003 

## I 9 .631 212512013 11 : 24:00 AM 16.468 8.968 3.268 9 . 604 212512013 11:25:00 AM 18 . 943 9.845 4.6 9.565 212512013 11 : 26:00

# AM~I**:;18~ ~95~:::9;** **~84~8~::~4ri 5~9~7:::~9~** **5;48;:::** 212512013 11 : 27 :00 AM 4 . 227 3.464 1.535 5 . 057 212512013 11 : 28 :00 AM 0 . 126 0 . 202 -0 . 006 0 . 028 

### 0 , % NO, PPM 

### CO PPM 

### THC PPM 13.347 31 . 67 89.503 17 .025 13.347 31.408 100.174 19.06 13 . 347 31.424 107 . 21 20.315 13 . 342 31 . 638 98 .802 18 .778 13 . 35 31 . 614 112.799 21 . 379 13 .348 31.726 99 .812 18 .967 Start 100% PM 1 3 . 361 31 . 664 108 . 93 20 .663 13.351 31 .855 91.935 17 . 519 13.352 31 .262 114.574 21.732 13 . 34 31.297 128.513 24 . 341 13.34 31.204 127.289 24 . 074 13.34 31.519 128 . 913 24.409 13.342 31 . 199 118 .833 22.488 13.34 31.154 142 .679 26 . 971 13 . 342 31 . 227 132 . 363 25 . 052 13 . 341 31 . 143 143 . 16 27 .097 13 . 342 31 . 31 125 . 134 23 .7 13 . 34 31.446 120.665 22 .881 13 . 34 31.36 132.607 25.115 13.34 31.486 109.476 20.741 13.321 31.472 129.449 24.481 13 .336 31 . 372 120.646 22.814 13.332 31.604 127 .245 24 . 03 13 . 327 32 . 11 92.484 17 . 506 13 . 334 31 .969 95.852 18.15 13.33 32 .233 85.414 16 . 213 13 . 338 31 .993 84.521 16 . 098 13.327 32.065 89.417 17 . 02 021C02 b;as 13 . 336 31.95 91.62 17 . 354 13.33 32 . 134 88 . 108 16 .77 NOx bias 15.412 21 .677 75 . 109 14 .224 18 . 924 0 . 878 6 . 979 1.411 18927 0675 -0417 0 . 033 18.928 8 . 208 0.078 0.231 0 .566 

## I -0.441 0 . 039 21 .427 0.451 0 . 291 41 . 884 0.147 

### I 0 . 303 25.09 32.062 6 . 232 02 bias CO bias NOx bias 0.045 0.42 230.888 43.478 Span Oirect 0.043 0 . 322 1 240.3891 45 . 152 CO b;as 1 2.956 29 . 085 237 .241 44 .666 2 1

2512013 11 : 29 :00 AM 0 . 113 0 . 202 -0 . 011 -0.032 18 .927 42 .051 240.469 45 .25 Direct Span 212512013 11 : 30 :00 AM ....

### ~0.~1i:'13'-~0;;;.::-20~2~-;.0:'**0:::1~3'--:i-O'i.0~2:i-5**..... 212512013 11 :31 :00 AM 5 . 95 2 . 044 0 .751 0.345 212512013 11:32 :00 AM 13 . 505 4.445 2 . 172 3.299 212512013 11:33:00 AM 13.522 4.447 2.231 3.399 212512013 11 :34:00 AM 13.519 4.452 2 .211 3 .764 212512013 11 : 35 :00 AM 13.519 4.454 2.257 3 . 892 2125 1 2013 11 : 36:00 AM 13 . 521 4.45 2 .215 3 .458 2125 1 2013 11 : 37:00 AM 13 . 526 4.447 2 .211 3 .719 212512013 11 : 38 :00 AM 13 . 528 4.446 2 .206 3.499 2125 1 2013 11 : 39 :00 AM 13 . 517 4.453 2 . 188 3 .752 212512013 11:40 :00 AM 13 . 513 4.456 2.198 4 . 326 212512013 11 :41 :00 AM 13.525 4.449 2.268 4.375 212512013 11:42:00 AM 13 . 535 4.443 2 .288 4 . 314 212512013 11 :43:00 AM 13 . 534 4.441 2 . 343 4.551 212512013 11 :44:00 AM 13 . 534 4.438 2 . 363 4.426 2125 1 2013 11 :45:00 AM 13.536 4 .435 2.347 4.328 212512013 11 :46 :00 AM 13 .557 4 .422 2.41 4 . 311 2125 1 2013 11 :47:00 AM 13.557 4.42 2.409 4 . 156 2I251201311 :48:00AM 13 . 558 4.42 2 .423 4 .708 212512013 11 :49:00 AM 13.555 4 .419 2.436 3 . 834 212512013 11 : 50:00 AM 13.577 4.409 2.47 3 .786 5 . 653 0.048 0.042 0.041 7.903 13 . 253 11 .913 140.418 26 .425 Di rectZero 0 .052 0.029 0.01 16.449 31.497 0.513 -0.036 -0.037 20.967 100.633 0 . 189 0 . 096 0 .086 Di rect Zero 4 . 072 19.07 Start RATA 1/100% Camp 13 . 266 31 .872 86 .682 16.474 13 . 265 31.684 96.799 1 8 . 335 13 .265 31 . 833 89 . 33 16 . 951 13 .258 31.625 94.569 17 .898 13.262 31.367 104.728 19 . 81 13.259 31 . 536 103.008 19 . 506 13.265 31.447 97 . 844 18.544 13.262 31.431 106.686 20 . 196 13 .261 31 . 517 103 . 26 19.57 13 .262 31 . 59 100.414 19 . 008 13 . 263 31.714 98 . 174 18 .603 13 .263 31 . 634 92 . 032 1 7. 443 13.262 31 . 373 109 . 373 20 .658 13 . 26 32.105 83.721 15 .883 13.265 31.916 81 . 262 15.431O2 CO 2 NO x Dale Time 

### % % PPM 21251201311:51:00AM 14 .759 3.722 1.651 21251201311 : 52:00AM 13 . 505 4.447 1.847 21251201311:53:00AM 13 . 504 4.448 1.816 21251201311 :54: 00AM 13.498 4 .45 1.829 212512013 11 : 55 :00 AM 13 . 51 4 .448 1.824 21251201311 : 56:00AM 13 .5 4.454 1.822 212512013 11 : 57 :00 AM 13 . 504 4.451 1 . 845 212512013 11 :58 :0 0AM 13.499 4 .454 1.813 21251201311:59:00AM 13.497 4.459 1.835 212512013 12 :00:00 PM 13 .5 15 4.45 1.722 212512013 12 :01:00 PM 13 . 519 4.449 1.711 212512013 12 :02 :00 PM 13 .521 4.449 2 .345 212512013 12:03:00 PM 13 . 519 4.45 1 . 821 212512013 12 :04 :00 PM 13 .536 4.438 1.69 212512013 12 :05:00 PM 13 . 55 4.431 1 . 584 212512013 12 :06 :00 PM 13 .5 48 4.429 1 .588 212512013 12:07:00 PM 13 . 555 4.421 1 . 571 212512013 12 :08 :00 PM 13 .5 54 4.419 1 .569 212512013 12:09:00 PM 17.841 1.908 0.66 212512013 12 : 10:00 PM 13.584 4.426 2 . 058 21

25 1 2013 12:11:00 PM 13 .496 4.434 2.047 212512013 12 :1 2 :00 PM 13.494 4.432 2 .052 2125 1 2013 12 : 13 :00 PM 13 . 5 4.433 2.049 212512013 12:14:00 PM 13 .501 4.431 2.022 212512013 12:15:00 PM 13 .5 4.432 2 . 055 212512013 1 2: 16 :00 PM 13.499 4.433 2 .046 2125 1 2013 12 :17: 00 PM 13.493 4.435 2.06 212512013 12:18 :00 PM 13.493 4.436 2.108 212512013 12:19:00 PM 13.493 4.437 2.034 212512013 12 : 20 :00 PM 13.488 4 .436 2.07 212512013 12 :2 1 :00 PM 13.489 4.437 2 . 057 2 1

25 1 2013 12 :2 2 :00 PM 13.492 4.438 2.032 212512013 12:23 :00 PM 13.495 4.436 2 . 041 212512013 12:24 :00 PM 13.496 4.436 2 . 044 212512013 12:25:00 PM 13 .487 4.439 1 . 978 212512013 12:26 :00 PM 13.484 4 .443 1 . 969 212512013 12:27 :00 PM 16.731 2.485 1.179 212512013 12:28:00 PM 15 .24 3 . 519 1.599 212512013 12:29:00 PM 13.496 4.436 2 . 184 212512013 12 : 30 :00 PM 13.486 4.44 2.172 212512013 12:31 :00 PM 13.495 4.435 2.219 212512013 12 :3 2 :00 PM 13.487 4.44 2 . 159 212512013 12:33 :00 PM 13.492 4.436 2 . 158 212512013 12:34:00 PM 13.49 4.436 2.188 2 1

25 1 2013 12 : 35 :00 PM 13.48 4.441 2.161 212512013 12:36 :00 PM 13.483 4.436 2 . 186 212512013 12:37 :00 PM 13.473 4.44 2 . 154 212512013 12:38:00 PM 13.49 4.429 2 . 268 212512013 12 : 39 :00 PM 13 . 503 4.423 2.388 212512013 12 :40 :00 PM 13.494 4.431 2.373 212512013 12:41 :00 PM 13 .496 4.43 2.413 212 512013 12 :42 :00 PM 13.5 4 .43 2.439 

### CO PPM 2.736 2.819 3 .058 3 .1 93 3.398 2.962 2 .952 2 .825 3.538 3.224 3.005 3.023 3.234 3.086 3.289 3.487 3.139 3.1 1 .747 2.961 3.76 3.521 3 . 397 3.432 3.647 3 . 845 3.618 3.648 3 . 831 3 . 834 4 . 119 3.966 3.757 3 .62 3.653 3.852 3 . 05 2.451 3.933 4 . 255 3.802 4.132 4 . 142 3.684 3.907 4.091 3.927 4 .3 94 4 . 263 4 . 108 3.857 3.784 

### 0, NO, CO THC 

### % PPM PPM PPM 13 . 263 32 .257 70.69 13.434 13.265 32.048 70.128 13.325 13 . 263 32.057 76.546 14 . 508 13 . 265 31.926 80.231 15 . 216 13 .266 31 .745 87.538 16.581 13 .265 32 . 116 74.96 14.238 13.265 32.111 75.371 14.306 13.265 32 .1 27 69.49 13 .203 13 .265 31 .643 92.754 17 .524 13.265 31.984 88.117 16.679 13 . 27 31.965 79.201 15.026 13 .267 31 .858 85 . 258 16.139 13.266 31.838 90 . 274 17 .092 13 .273 31 . 919 83.509 15 .786 13 .274 31.703 87.508 16.588 13.271 31.497 103.009 18.469 13.275 31.916 88 .61 4 13.575 13 .28 31 . 872 89.411 9 . 86 13 . 269 31.887 81.894 8.744 13 . 268 31 . 849 92 . 658 0 .824 13 . 266 31 . 835 98 . 568 0 .843 13.267 31.915 90.359 0.816 13 .2 66 32 . 126 88.954 0.811 13 . 267 31 .896 85 .723 0.8 13 .2 67 31.825 92 . 859 0.823 13 . 267 31.81 101.432 0.853 13 .266 31 .9 19 89 .662 0 . 812 13.266 31.941 91.068 0 . 817 13.266 31 .74 94 . 64 0 .832 13 .267 31 .769 97 .9 98 0.84 13 .266 31.514 106.941 0 .87 13 .265 31 .8 41 104.004 0.86 13 .266 31.845 93 .293 0 . 827 13.266 32 .0 24 88.065 0.808 13.264 31 .81 91.531 0.819 13 .265 31.744 100.784 0 . 85 13 .2 57 31.624 96.224 0.836 13.253 3 1.6 57 106.907 0 .87 13 .241 31 .84 94 . 822 0 . 83 13 .245 31.606 102.844 0 .857 13 . 251 32 . 031 92 . 529 0.825 13 . 242 31 . 552 95.518 0.832 13 .246 31.813 99 .13 5 0 .846 13.242 31 .934 82.956 0.796 13 .24 31.689 90.536 0 . 828 13 . 237 31 .7 69 99 . 143 0 .859 13.223 31.665 89 . 675 0.827 13 .22 31.432 103 .417 0 .8 77 13.218 31 .795 98 .566 13 . 212 31.808 88.389 13 . 193 32.043 82 .753 13 .202 31 . 989 78.578 212512013 12 :43 :00 PM 13.505 4.428 2.407 3 .757 13 .201 32.056 82 .572 0 . 854 0 . 823 0 . 804 0 .791 0 .8 04 0 .755 0 .782 0 .771 212512013 12:44 :00 PM 17 . 243 2.188 1.233 2 .474 13 . 194 32 . 18 68.53 212512013 12:45 :00 PM 19 .751 1.736 0.009 0 . 333 13 .17 4 32 .085 78.707 21251201312:46:00PM 18 . 803 9 . 82 -0 . 011 -0 . 208 13.181 31.973 73 . 704 212512013 12 :47 :00

# PM~I**:1~84 8~2~5:::9~** **~84~9~::~-~0~ 0;1:::**  -0.465 13 . 171 31 .6 31 85.044 212512013 12 :48 :00 PM 6.743 3.374 2 .811 -0 .318 13 . 173 31 .657 88.164 212512013 12:49 :00 PM 

### r l....;;0."1'"55:--0;;;."25"'1;..........:4;;;.5;;6,;2-....;-0"
.0;.;1.;;2..., 13 . 136 31 .792 94 . 035 212512013 12 : 50 :00 PM 0.138 0 . 242 4 .577 0 . 025 0.817 5 .015 40 . 25 21 25 120 13 12 : 51 :00 PM 0.142 0 . 239 1.755 7.492 0.063 0.86 0.975 212512013 12 : 52 :00 PM 0 . 128 0.237 -0.007 10.381 0.044 0 .712 0.065 0 .807 Q2IC02 bias 2.266 6 .888 NOx bias 1 . 271 0.539 0.534Date T ime 

### 0 , % CO, % NO. CO PPM PPM 212512013 12 : 53 :00 PM 0 . 112 0.235 -0 . 009 9 .603 212512013 12 : 54 :00 PM 0 . 112 0.236 -0.009 9.592 212512013 12 : 55 :00 PM 12.513 7.593 3 . 237 9.561 2125 1 2013 12 : 56 :00 PM 18 .874 9.859 4 . 614 9 .544 21 25 1 2013 12 : 57 :00 PM 18 .887 9 .863 4 . 603 9 .544 21 25 12013 12 : 58 :00 PMI"1-;8"i
.8'i:92,--';;9
. 'o86:;'--'4-; . 5:l;98i--'i:9
. ;:554"" 21 251201312 : 59:00PM 3. 383 1 .753 1 . 304 4 . 391 2125 1 2013 1 :00 :00 PM 0 . 125 0.206 -0.Q16 0 .004 2125 1 2013 1 :01 :00 PM

## 1~0~**1i':1'i-4-~0.'::20~3:----i-0~.0~1~5--'-0;:' :::02~5""**  2125 1 2013 1:02 :00 PM 4 . 979 1.132 0.251 0.132 212512013 1:03 :00 PM 13.424 4.459 2125 1 2013 1 :04 :00 PM 13.427 4.462 2125 1 2013 1 :05 :00 PM 13.424 4.465 21 2512013 1 :06 :00 PM 13.422 4.466 2125 1 2013 1 :07 :00 PM 13.425 4.462 2125 1 2013 1 :08 :00 PM 1 3.422 4.466 212 5 1 2013 1 :09:00 PM 13.422 4.465 2 1

25 1 2013 1 :10:00 PM 13.426 4.462 212512013 1 :11 :00 PM 13.432 4.456 212512013 1:12:00 PM 13.434 4.455 2 1

2512013 1 : 13:00 PM 13.435 4.456 21 25 1 2013 1 : 14:00 PM 13.437 4.453 21 25 12013 1 : 15 :00 PM 13.451 4.448 21 25 12013 1 : 16 :00 PM 13.462 4.445 2125 1 2013 1 : 17 :00 PM 13.455 4.448 21 25 1 2013 1:18 :00PM 13.466 4.446 2125 1 2013 1:19:00 PM 13.458 4.45 212512013 1 :20 :00 PM 13.465 4.448 212512013 1:21 :00 PM 17 . 086 2.34 21 25 1 2013 1:22 :00 PM 1 3.431 4.48 2125 1 2013 1: 23 :00 PM 1 3 . 396 4.49 21 25 1 2013 1 : 24 :00 PM 13 . 394 4.492 2 1

25 1 2013 1 : 25 :00 PM 13 . 396 4.487 21 25 1 2013 1 : 26:00 PM 13.405 4.483 2 1

25 1 2013 1 : 27 :00 PM 13.395 4.488 212512013 1 : 28:00 PM 13.394 4.49 212512013 1 :29:00 PM 13 . 393 4.493 2 1

2512013 1:30 :00 PM 13.395 4.489 21 25 1 2013 1 :31 :00 PM 13 . 396 4.487 21 25 1 2013 1 : 32 :00 PM 13 . 396 4.486 2125 1 2013 1 : 33 :00 PM 13 . 391 4.493 2 1

25 1 2013 1 : 34 :00 PM 13 . 382 4.497 2 1

25 1 2013 1 : 35:00 PM 13 . 38 4.498 212512013 1 : 36:00 PM 13.385 4.494 212512013 1 :37:00 PM 1 3 . 375 4.499 212512013 1 :38:00 PM 13 . 358 4 . 509 2125 1 2013 1:39 :00 PM 13 . 358 4 . 511 212 512013 1 :40 :00 PM 1 3 . 362 4 . 508 2125 1 2013 1:41 :00 PM 13 . 36 4.509 212512013 1 :42 :00 PM 13 .359 4 . 511 2 1

25 1 2013 1 :43 :00 PM 17 . 1 5 3 2 . 27 2 1

25 1 2013 1:44 :00 PM 13.503 4.46 2125 1 2013 1:45 :00 PM 13.431 4.467 212512013 1:46 :00 PM 13.421 4.476 2125 1 2013 1:47 :00 PM 13.421 4.472 21 25 1 2013 1 :48 :00 PM 13.421 4.472 2125 120 13 1 :49 :00 PM 13.42 4.472 2125 12013 1 :50 :00 PM 1 3.422 4.466 2125 12 0 13 1 :51 :00 PM 13.428 4.461 2125 12 013 1:52 :00 PM 13.421 4.463 21 25 1 2013 1 :53 :00 PM 13.421 4.46 1 .822 1 .783 1. 784 1 .764 1 .8 02 1. 7 62 1. 7 67 1 .689 1.698 1 .716 1 .706 1.689 1 .6 1 . 622 1 .62 5 1 .609 1 .616 1.606 0 .838 1 . 963 1 . 948 1.982 1 . 995 1 . 994 1 . 977 1 . 952 1 . 98 1.975 1 . 97 9 1.965 2 .661 2.417 1.992 1.991 1 . 902 1 .79 2 . 103 1 .87 1 .815 2 .029 0. 969 2 . 072 2 . 054 2.023 2 .019 2 .048 2 .019 2 .023 2 .018 1. 995 1.999 3 . 105 3 .065 3.191 3 . 218 3 . 208 2 . 924 3 . 104 3 . 255 2 .758 2.712 2 .727 2 .598 2 .915 2. 774 2.744 2 .698 2 .725 2 . 646 1 . 659 2 .762 3 . 099 3 . 125 2.657 2.898 2.55 3.265 3.398 3 . 114 3 . 181 3 . 002 3 .304 3.145 2 .975 2 .865 2.803 3 . 347 2 . 998 2 . 992 2 .747 2 .921 2.231 2.565 3 . 293 3 . 191 3 . 364 3 . 653 3 . 632 3 . 342 3 .287 3.592 3 . 381 

### 0, % 0 . 044 0.044 0.541 0.044 0. 044 0 .044 0 .043 0 .38 0 . 045 0.343 0 .041 0 . 041 0 . 358 0 . 04 1 0 . 041 0 .041 0 . 041 0 .041 0 .041 0.083 0.223 0 .043 NO . PPM 0 .613 0 .519 1.925 0.41 0 . 354 0 . 307 0 . 247 1 .3 11 0 . 229 1 .096 0 . 177 0 . 15 1 . 126 0 . 14 0 . 128 0 . 121 0 . 098 0 . 081 0 .087 0 .098 0 .721 0 .049 CO PPM 0 . 039 0 . 015 THC PPM 0 .5 29 0 .527 CO bias 3 . 009 18 .213 0 .4 2 86 . 098 -0 .008 8 7 . 051 0 .0 1 6 87. 0 26 Direct S p a n -0.038 85.4 08 1.083 83 . 936 1 .563 53 .977 Di rect Ze r o 2.184 49.766

1.4 27.749 -0 .027 26.016 Start RATA 2 /100 % Comp 3 . 352 17 .51 1 -0 . 006 0 . 528 -0 . 036 0 . 528 ITHC Cal Zero -0.032 0 .528 -0.036 0 .529 -0 . 038 0.529 -0.033 0 .531 -0.032 0 .529 1.442 37 . 617 -0.041 85 . 33 0 .043 -0 .003 -0 .035 85 .861 I nl et Direct Zero 16 .004 29 .813 92 .87 86.426 18 .87 7 41.043 239 .859 87 .097 18 .891 41 . 966 240 . 032 87 . 325 THCCa l Hi9h 18.898 42 240.53 86 .955 I nl et Oirect Span 11 .638 0 .068 0 . 318 0 .042 0 .04 1 8.419 18 .747 18 .753 18 .773 5.823 0 . 063 0.169 0 .04 1 0 .04 1 28 .746 0 . 206 0 . 943 0 . 1 0 7 0 .086 0 . 1 5 2 0 .096 0.086 0 .081 25 .699 41 . 398 207.607 56 .707 11.601 I 50 . 144 ITHCMid 1.444 51 . 343 1.219 29.407 -0 .034 27 .0 06 ITHC Low 5.893 25. 96 6 2 . 061 2 . 591 -0.442 -0.448 1 .872 0.167 0 . 528 0 .528 02 bias 1.459 31 . 097 13.517 0.532 NOx bias 0 . 574 0 . 214 218.056 1.519 0 .1 13 1 2 39 .681 

# I 1 . 3 1 8 CO b i as 6.715 13 .989 208 .82 1 . 535 13 . 158 31.476 86.641 1 1 .425 13 . 166 31.871 78 . 138 10.889 13.167 31 . 696 78.288 11 . 152 13 . 166 31 . 514 102.921 16.472 13 . 167 3 1. 759 91 . 063 14 . 348 13 . 177 31.844 92 . 159 13 .703 13 . 174 3 2 . 053 84 .414 13 . 84 13 . 169 31 .899 86 .564 1 1 .3 9 2 Start 1 00% In l et 1 13.222 31 .672 112 .699 2 0. 174 13.228 32.141 90.605 13 . 901 13 .238 31 .935 91 .776 13.546 13 . 222 32 . 089 89 . 572 13.523 13 . 228 31 . 931 93 .747 13 . 572 13 . 226 3 1 .766 107.986 17 . 991 13 . 22 5 3 1.774 104.488 16 .79 13 . 229 3 2 . 276 96 .743 1 7 .478 13.2 36 31 .849 92.459 13 .093 13 .234 31 .872 107 . 244 17 . 98 1 13 .235 32 . 105 96.412 15 . 117Date Ti me 

### 0, % CO2 NO. 

### % PPM 2125 / 2013 1 :54 :00 PM 13.421 4.456 1.992 2/25/2013 1 :55 :00 PM 13.42 4.459 2.67 2125 / 2013 1 :56 :00 PM 13.423 4.45 2.372 2125 / 2013 1 :57 :00 PM 13.422 4.452 2 .873 212512013 1 : 58 :00PM 13.418 4.453 2 . 316 2125/2013 1 : 59 :00 PM 13.421 4.449 1 . 986 2125/2013 2:00 :00 PM 15.447 3.138 1.423 2125 / 2013 2 :01 :00 PM 16 .032 3 . 062 1.345 21 25 12 013 2:02 :00 PM 13.432 4.433 2 . 109 2125 / 2013 2 :03 :00 PM 13.433 4.427 2 . 093 2125/2013 2 :04 :00 PM 13.434 4.427 2 . 072 2125 / 2013 2:05 :00 PM 13.4 3 3 4.427 2 . 085 2125 / 2013 2:06 :00 PM 13.432 4.425 2 . 074 21 2512013 2:07 :00 PM 13.435 4.423 2 . 165 2125/20 1 3 2:08:00 PM 13.441 4.419 2.238 2125/2013 2 :09 :00 PM 13.433 4.425 2 . 198 212512013 2 : 10 :00 PM 13 .432 4.429 2 . 225 2125 12 013 2 : 11 :00 PM 13 .435 4 .429 2 . 2 14 2/2512013 2:12:00 PM 13.468 4.4 1 3 2 . 353 2125/2013 2:13 :00 PM 13.47 4.411 2 . 347 2125 / 2 0 13 2 :1 4 :00 PM 13.471 4.412 2 . 338 212512013 2 : 15 :00 PM 13.471 4.413 2 . 361 2125 / 2013 2 : 16:00 PM 13.47 4.414 2 . 336 2/25/2013 2 : 17:00 PM 13.47 4.4 1 8 2 . 376 2125 / 2013 2:18 :00 PM 15 .683 5 . 365 1 . 351 2125 / 2013 2 : 19 :00 PM

## rl-':':18~**7;';9~~9';' 8~0~1-~-0;'-** **0;;;1;-:'-'** 2125 / 2013 2 : 20 :00 PM 12 . 656 4.557 1.492 2125/2013 2 : 21 :00 PM 5 .787 0.24 3.259 2 / 25

/ 2013 2 : 22 :00 PM 2 . 348 0.222 4 . 037 CO PPM 3 .745 4 . 011 3 .796 3. 9 14 4 .1 34 4.062 3.484 2 . 111 4 . 121 4.272 4.719 4 .709 4 . 61 4 .711 4.564 4 .859 4 .884 5 . 171 5 . 061 4.97 5 . 223 4 .712 4 . 665 4 . 994 

### 0 , % 

### NO , PPM CO PPM THC PPM 13 .237 31 .613 112 .715 18 . 696 1 3 . 235 31.718 126.421 24.097 13 . 24 31.614 117 . 941 20.576 13 . 235 31 .65 7 120 . 94 21.366 13 .2 3 5 31 . 543 132 . 363 25 . 266 13 .236 31.606 128.853 23 . 348 13.237 31.717 126 . 057 22 . 628 13 .244 31.641 122 . 806 21.886 13 .237 31 .894 121 .067 21.509 13 .239 31.601 121.429 20 . 913 13.244 31.434 140 . 325 27 . 342 1 3 . 241 3 1 .481 139 . 348 26 . 949 13 . 242 31.484 137 . 05 7 27 . 342 13 .238 31 . 511 134 .614 25 . 957 13.238 31 . 661 126.546 23.533 13 .241 31.408 138 . 64 26 .066 13 .236 31 .46 139 .746 27.438 13 . 233 31 . 3 1 6 147.359 29.057 13 . 239 31.595 139.357 26.33 13 .24 31.46 135 .808 25.478 13 . 23 8 31.432 143 .631 27 . 138 13 .24 31 .85 127.992 24.822 13 . 239 31.539 124.184 2 1. 1 94 13 . 234 31 . 647 134.887 25.781 3 . 552 13 .237 31 . 645 128 . 197 24.006

-0 . 323 13 . 232 31.723 129 .313 23 .82 1 02lC02 b ;as -0 .345 13 . 243 31.688 122.395 21 . 376 0 . 011 13 . 243 31 .864 118.4 21.828 0 . 029 13 . 244 31 .764 113.616 20.204 212 5 / 2013 2 : 23 :00 PM 0 . 164 0 . 215 4 . 546 0 .01 212512013 2 : 24 :00 PM rl

## ~0**-i-'3:::6;-~0';'.2;;,,:-i3;-~4~ 5;':4~7--;i0::;** **0::-'60"1** 13 .24 3 1. 522 130 .806 23 .799 1 3. 242 31 .7 11 130 .366 26.408 NOx bias 2 / 25

/ 2013 2 : 25 :00 PM 0 . 123 0.214 2.206 6 . 397 13 . 242 31.543 125 .878 22.221 2125/2013 2:26:00 PM 0 . 818 0.216 2 / 25

/ 2013 2 : 27 :00 PM 3 .711 0.221 2125 / 2013 2 : 28 :00 PM 3 . 36 2 0.474 2 / 25

/ 2013 2 : 29 :00 PM 0 . 689 0 . 367 2/25/2013 2:30 :00 PM 0 . 234 0.25 2125 / 2013 2 : 31 :00 PM 7.414 5 . 173 2125 / 2013 2 : 32 :00 PM 18 .86 9 .837 2 / 2512013 2 : 33 :00 PM 18 . 888 9 .838 2/25/2013 2 : 34 :00 PM 1 0 . 877 5.981 2125/2013 2 : 35 :00 PM 0.138 0.195 212512013 2 : 36 :00 PM 0 . 112 0 . 193 2125 / 2013 2 : 37 :00 PM 10.461 3.598 2125 / 2013 2 : 38 :00 PM 13 .428 4.459 2/25/2013 2 : 39 :00 PM 13.428 4.465 212512013 2 :40 :00 PM 1 3. 434 4.465 2125 / 2013 2 :41 :00 PM 13.433 4 .465 2 / 25

/ 2013 2 :42 :00 PM 13.4 3 3 4.467 2/25/2013 2 :43 :00 PM 13.434 4.462 2125 / 2013 2 :44 :00 PM 13.435 4.462 212 51 2013 2 :45 :00 PM 13.464 4.453 2125 / 20 1 3 2 :46 :00 PM 13.469 4.455 2/25/2013 2 :47 :00 PM 13.471 4.455 2125 / 2013 2 :48 :00 PM 17 .83 1.908 212512013 2 :49 :00 PM 13.485 4.482 212 51 2013 2 : 50 :00 PM 13.423 4.49 2 / 25/2013 2 : 51 :00 PM 13.423 4.493 2125/2013 2 : 52 :00 PM 13.423 4.495 2125 / 2013 2 : 53 :00 PM 13.428 4.492 2125 / 20 1 3 2 : 54 :00 PM 13.426 4.495 2125 / 2013 2 : 55 :00 PM 13.421 4.499 -0.011 10 .779 13 . 244 31.449 138.596 26 . 812 -0 .015 10 . 367 13 . 245 31 .799 125.339 23 . 201 0 . 14 8 . 114 13 .25 3 1. 875 115 . 261 20 .669 0.162 9 .012 13 . 24 31.988 106 . 056 18.479 0.004 9 .514 13 . 244 31 . 77 113 . 355 19 . 028 CO b ;as 2.265 9 . 514 13 . 244 31.766 119 . 043 21.83 4 . 574 9 . 56 13 . 241 31 .558 126 . 106 22 .8 4 .572 9 .568 13 . 251 31.54 137 . 317 26.493 3.306 8 . 581 13 . 239 31.967 111 . 624 20 . 321 -0.005 0 . 586 13 . 238 31 .776 118 .53 20 . 881 -0 .013 -0 . 03 13 . 237 31.785 113 . 923 16 . 96 1 . 136 1 .521 13 . 237 31 . 822 116 . 196 19.806 1.688 3.975 13.232 31.615 130.787 24.786 Start RATA 3 1.681 4 .045 13 . 227 31.672 131 . 945 25 . 055 1 .721 3 . 301 13 . 233 32 . 057 101.912 16 . 239 1.734 3 .759 13 .234 31 .825 119 . 184 22 . 129 1 .672 3 .756 13 .233 31 . 844 120.751 22.033 1.658 1.638 1 .532 1. 541 1 .513 0.614 2.737 2 .049 1 . 927 1.926 1 .919 2.227 3.001 3 .388 3 .674 3 .319 3 . 343 3.489 1 .835 3 . 322 3 .911 4.086 4 . 143 4 . 394 4 .249 4.511 12 .992 31.662 1 8 . 534 2 . 632 18 .83 0 . 833 8 .762 1 9 . 993 0 . 073 41.921 0 . 046 41.915 109 . 21 46.758 -0 . 36 1.698 0.495 0.046 16 . 582 77 . 182 19 . 124 8 .815 0 .528 0 2 bias 2.214 0.561 0 .53 NOx bias 1.303 0 . 176 0 .042 0 . 042 0 . 575 0 . 132 0 .041 0 . 042 0.487 238.531 1.315 0 . 386 

# I 239 .954 

# I 1 . 317 CO b;as 1 . 296 240 . 035 1 . 319 0 . 956 72.033 28 . 041 0 .081 0 . 075 48 .247 THC M ;d 0.062 -0.037 47.673 D i rect ZeroDate T i me 

### 0, % 

## co, %**NO~** 

### CO PPM PPM 2125/2013 2:56:00 PM 13.421 4.496 2 .1 54 4 .1 79 2125/2013 2:57 :00 PM 13.405 4 . 51 1 . 6 36 4 . 231 2125/2013 2 : 56 :00 PM 13.396 4 . 516 1.734 4 .656 2125/2013 2 : 59 :00 PM 13.396 4 .519 1 .763 4.72 1 2125/2013 3 :00 :00 PM 14 .766 3.662 1.457 4.362 2125 / 2013 3:01 :00 PM 15.54 3.324 1.342 2.661 2125/2013 3 :02 :00 PM 13.442 4.462 1.961 4.279 2125/2013 3:03 :00 PM 13.44 4.462 1.959 4.392 2125/2013 3:04 :00 PM 13.443 4.46 2 . 97 4.529 2/25/2013 3:05:00 PM 13.436 4.463 2.116 4.274 2/25/2013 3:06:00 PM 13.446 4.475 2.095 4.461 2/25/2013 3:07:00 PM 13.437 4.477 4 .432 4 .1 43 2/25/2013 3:06:00 PM 13.436 4.476 2 . 141 4 . 131 2125/2013 3 :09 :00 PM 13.433 4.476 1 . 932 4.417 2125/2013 3:10:00 PM 13.432 4.46 1 . 653 4.364 2125/2013 3:11 :00 PM 13.435 4.474 1 . 902 4.445 2125 / 2013 3 : 12 :00 PM 14.241 3.969 2 . 046 4.03 2125 / 2013 3 : 13 :00 PM 15 .651 3.113 1.639 2.645 2125/2 013 3 : 14 :00 PM 13.439 4.465 1 . 925 4.494 212512013 3 : 15 :00 PM 13.441 4.461 1.67 4 .496 212512013 3 : 16 :00 PM 13.435 4.463 2.541 4.631 2125/2 013 3 : 17 :00 PM 13.435 4.464 1.624 4.44 2125/2013 3 : 16 :00 PM 13.434 4.462 1.699 4 . 559 2125/2013 3 : 19 :00 PM 13.434 4.464 2 . 56 4 . 577 2125/2013 3 : 20:00 PM 13.435 4.456 1.747 4.747 2/25/2013 3:21:00 PM 13.44 4 .454 1.576 4 . 291 2/25/2013 3:22:00 PM 13.445 4.45 1.556 4.06 2/25/2013 3:23:00 PM 13.462 4.441 1.512 4 . 099 2/25/2013 3:24:00 PM 15.267 6.526 1.456 3.247 2/25/2013 3 :25 :00 PM .. 1...;1.;;6;;;.60;5,--....;;9.

## .;;6~16:---.:-0,:.:**0;,:;1:;,2...,** -0 .305 2/25/2013 3:26:00 PM 6.136 4.026 2.515 -0 .341 2/25/2013 3:27:00 PM 1"1

## ~0;;.;;15"'5--;;0.':;23~3;---;4:'i**5"'6~6--i:-0:'; 0:;"3..,**  2/25 / 2013 3 : 26 :00 PM 0.195 0.237 2 .743 2 .066 2 / 2512013 3:29:00 PM 0.137 0 . 214 -0 .015 9 . 312 2125 / 2013 3 : 30 :00 PM 0 . 112 0.21 -0.017 9 . 562 212512013 3 : 31 :00 PM 16.062 6.49 3 . 169 9 . 551 2125/2 013 3 : 32 :00 PM '"1""1"6';'; .6"9;;'3

## -""9:;..6;::2;,1-.....;4C:**6~0"3-** ..... 9;;

. 5.;;39;,-, 2125 / 2013 3 : 33 :00 PM 3 .677 2.076 1.492 5 . 355 2125 / 2013 3 : 34 :00 PM 0.12 0 .177 -0.Q16 0.051 2125 / 2013 3 : 35 :00 PM 1"1

## ~0**':'11:"2;--""0;; .1** **:'7;-;4--""-0';- 0;;;2;';1--i-O;-;** **0;';3':'1"** 2125/2013 3 : 36 :00 PM 9 .763 3.395 1.271 1.211 2125/2013 3 : 37 :00 PM 13.431 4.432 2.07 3.341 2125/2013 3:36:00 PM 13.433 4.43 2.09 3.266 2/25/2013 3:39:00 PM 13.441 4.426 2.102 3 . 343 2/25/2013 3:40:00 PM 13.436 4.426 2.067 3.107 2/25/2013 3:41 :00 PM 13.451 4.423 2.145 3.666 2/25/2013 3:42:00 PM 13.459 4.421 2.192 3.42 2125/2013 3:43:00 PM 13.466 4.42 2.195 3.626 2125/2013 3 :44:00 PM 13.466 4.419 3.109 3 .704 2125/2013 3 :45:00 PM 13.47 4.417 2.547 3 . 356 2125/2013 3 :46 :00 PM 13.47 4.416 2.247 3 .713 2125 / 2013 3 :47 :00 PM 15 . 536 3.209 1.493 2 .606 2125 / 2013 3 :46 :00 PM 13.464 4.421 1 .676 3 . 107 2125 / 2013 3 :49 :00 PM 13.435 4.429 1.659 3 .614 212512013 3 :50 :00 PM 13.442 4.425 1.66 3.441 2125 / 2013 3 :51 :00 PM 13.444 4 .423 1.664 3.44 2125/2013 3 : 52 :00 PM 13.444 4.422 1 .65 3.56 2125/2013 3:53 :00 PM 13.475 4.406 1.626 4 . 066 2/25/2013 3 :54 :00 PM 13.463 4.4 1.565 4 . 275 2/25/2013 3:55 :00 PM 13.474 4.406 1.577 2 . 375 2/25/2013 3:56:00 PM 13.507 4.39 1.477 2.95 2/25/2013 3:57:00 PM 13.496 4.394 1.46 2.755 

### 0 , % 1 .661 16 .794 16 . 927 14 .69 13.243 13.242 13.241 13.2 4 13 .239 13.234 13 .241 13.233 13.227 13 .226 13 . 23 13.226 13 .216 13 . 22 13.216 13 . 222 13 .215 13.212 13.216 13 . 216 13 . 215 13 . 212 13 . 206 13.21 13 . 202 13.195 13.165 13 . 173 13.176 

### NO, PPM 0.721 40.203 41 .914 33 .669 30 .992 31.063 31.411 31.263 31.309 31.494 31 .3 03 31.66 31.594 31.4 31.409 31.501 31.604 31.374 31.536 31.444 31.543 31 . 525 31.423 31 . 353 31 . 304 31 . 347 31.501 31.337 31.606 31.962 34.731 32.966 31.612 CO PPM -0.032 152.557 240.233 

## 1 190 . 336 152.296 154.953 141 .814 142.71 150.353 139.452 149.106 136 . 5 129.611 146.741 144.505 146.392 135.411 146.02 145 . 192 140 .22 1 147 . 156 136.034 145.627 145.914 155 .929 152.761 146.302 152.578 145.642 146.942 41.922 47 . 656 131 . 97 

### THe PPM 26.461 26.61 31 .247 Di r ect Span 33 . 939 31.926 Start 100 % Inlet 2 32 . 997 26 .472 26 .462 31.979 27 .90 2 31.075 26.445 24 . 556 30.267 29 . 333 26 . 233 23 . 261 29 . 502 29 . 231 27 . 95 30 .936 25.632 29.429 26.637 31.943 31.215

29.7 31 .719 24 . 672 26 .579 02/C02 bias 6.679 3.458 NOx bias 26 .701 13.194 31.934 126.467 23 . 59 13 .1 65 32.566 109.94 19 . 341 CO b ;as 13 .1 93 32.696 61.707 11.056 13.183 32.636 89.456 13 .593 Di rect Span 13 . 179 32.756 65.436 11.342 13 . 192 32 .632 79 . 34 10.965 13.189 32.61 86.583 13.195 Direct Zero 13 . 166 32.554 93.269 14.232 13.193 32.533 95.099 14.604 Start RATA 4 13 .201 32.66 66.219 12.336 13.166 32 .751 92.759 14.693 13.165 32.794 79.165 10.471 13 . 196 32.419 99.646 15.543 13.197 32.743 88.045 13 .575 Start 75% PM , RATA 5, Comp 1 13 . 213 32.411 101.974 15 . 512 13 . 206 32.619 99 . 24 14.746 13 . 21 32 .695 64.162 10 . 611 13 . 212 32 . 55 99 . 165 16 . 133 13 . 212 32.693 62.359 10.939 13 . 214 32.179 97.412 14 .726 13 . 216 32 .042 121.713 21 . 541 13 . 216 32 . 364 105.935 16 . 543 13 .227 32 . 261 100.473 15.694 13.226 32. 166 110.443 17.276 13.256 31.396 123.512 21.611 13 .252 31.724 140 . 126 26.461 13.236 33 . 041 69.632 6 . 339 13.242 32.537 63.594 12.049 13.244 32.74 76.926 10Dale Time 

### 0, % 21251201 3 3:56 :00 PM 17 . 615 2/25/2013 3:59 :00 PM 13.494 2/25/2013 4:00:00 PM 13.435 2125/2013 4:01 :00 PM 13.433 2125/2013 4:02:00 PM 13.432 212512013 4:03 :00 PM 13.433 212512013 4:04:00 PM 13.433 2/2512013 4:05 :00 PM 13.422 2/25/2013 4:06:00 PM 13.421 2/25/2013 4:07 :00 PM 2/25/2013 4:08:00 PM 2/25/2013 4:09:00 PM 2125/2013 4 :10:00 PM 2125/2013 4 : 11 :00 PM 212512013 4:12 :00 PM 2125/2013 4:13 :00 PM 2125/2013 4:14:00 PM 13.422 13.426 16 . 646 13.49 13.479 13.473 13.474 13.479 

### CO, % NO, PPM 1.994 0 . 622 4.432 1 .776 4.433 1 . 664 4.434 1 . 666 4.431 1.652 4.436 1 .65 4.435 1 . 664 4.446 1 .716 4.446 1 .725 4.446 1.731 4.443 1.733 2.47 0 . 965 4 .402 1.96 4.405 1 . 913 4.407 1.935 4.405 1 . 964 4.402 1.699 2125/2013 4:15 :00 PM 13.476 4.4 1.916 2/25/2013 4:16 :00 PM 13.463 4.396 1.937 2125/2013 4:17 :0 0 PM 13.46 4.396 1 . 922 2125/2013 4 :16:00 PM 13.461 4.392 1 . 956 2125/2013 4:19 :00 PM 13.46 4 .392 1 . 935 2125/20 13 4:20:00 PM 16.479 7.676 0 . 647 

### CO PPM 1.633 3.169 4.973 5.022 4 .851 4 .885 4.988 4.567 4.847 4.67 4 .642 2.882 4.457 4 .906 4.726 4.652 4.76 4.523 4.722 4.671 4.857 4 . 978 2 . 552 

### 0, % NO, PPM 

### CO PPM 

### THC PPM 13.24 32 . 576 84.913 11.247 13.242 32.016 108.937 17.493 13 . 246 31.491 142.727 28 . 227 13 .262 31.475 144 . 997 26 . 246 17.394 7 . 551 79.462 14 . 296 18.889 0 . 912 0.103 0 .528 18.903 0 .736 6 .779 19 .844 0 . 075 41.72 0.145 17.042 0.041 0.494 0 . 041 0 . 39 13.474 31.362 18 . 941 41 . 937 11.127 24 . 054 -0.445 2.195 0 . 625 74.471 236.539 1 240.369 

## 1

234.596 241.2651 199 .003 0.528 02 bias 1.786 0.532 NOx bias 1 . 152 1 . 312 1 .32 CO bias 5 . 536 32 .959 Direct Span 28 .746 0.058 0 .095 6.519 29 . 152

## L..,;:;0**.;:;04 -::1;,-......,;0:;.** **.0;,4:;.9,........,,; -0;;;.0~3;;4,.-11**  25.467 Direct Zero 11 . 109 23 .721 61.544 27. 428 13.265 31 . 305 147.557 30.256 13.265 31.315 153.389 30.671 13 . 266 31.482 154.394 31.781 13 . 27 31.443 157 .731 32 .664 13 . 266 31 . 351 162.9 34 . 524 2125 / 2013 4 :21:00 PM 16.661 9.736 -0 .01 -0.413 13 . 265 31.26 167 .495 34 .494 212512013

## 22:00PMrl""1ii6'i.6:i:6':"4-""9~.7~4i'i3""'-_~0**'i:0-i-1-'** -0.463 13.577 31 . 156 112.905 23.056 021C02bias 2/25/2013 4 : 23 :00 PM 6 . 562 4 . 207 2.402 -0.341 13 .75 29 . 955 32.261 1 . 536 2/25/2013 4:24:00 PM 

### rl

## ~0**-:-16;;6;--""0':'.1~7;;'6,....--i4;;'.5;';5~6---i-O:':.0;';2i6-'** 13.742 29.946 32.13 1.452 NOx bias 2/25/2013 4 :25:00 PM 0 . 139 0.163 1 . 5 4.429 2/25/2013 4:26:00 PM 0 . 137 0 .156 -0 . 013 9.467 2 / 25/2013 4 :27:00 PM 0 . 137 0.151 -0 . 02 9.569 2125/2013 4:26 :00 PM 12 . 636 7.779 3 . 546 9.57 2125 / 2013 4 : 29 :00 PM

## rl""1ii8'i**9;';3~9-""9;-.7;:3;:i2""'--i4" 5"'96:;;--n9';:** **5'<55;:--'** 2125 / 2013 4:30:00PM 7.438 2.816 1 . 511 4.793 2125/2013 4 :31 :00 PM 

### rl"'"'o

## .~**12:;';9;---i0~ .**  ;,11i'i 7 ,....-...,_0:i'
. 0i::

1 ;";7"-°0';.

## 0;:;25~ 2125/2013 4:32 :00 PM 8.595 2.577 0 . 675 0.133 2/25/2013 4:33 :00 PM 13 .944 4.08 1.332 0.609 2/25/2013 4:34 :00 PM 13.942 4 .083 1.361 0 .677 2125/2013 4 :35:00 PM 13.943 4 . 081 1.384 0.676 2/25 / 2013 4 : 36 :00 PM 1 3 . 938 4 . 085 1.416 0.65 212512013 4:37 :00 PM 13.939 4 . 081 1.422 0.67 2125/2 013 4:38 :00 PM 13 . 935 4.083 1 .463 0 .671 2125/2013 4 :39:00 PM 13.94 4.079 1.46 0.668 2125/2013 4 :40:00 PM 13.929 4 .066 1.429 0.674 2/25/2013 4:41 :00 PM 13.938 4 .0 63 1.44 0.685 2125/2013 4:42 :00 PM 13 . 938 4.082 1.468 0.692 2/25/2013 4:43:00 PM 13.941 4 . 076 1.432 0.725 2/25/2013 4 :44:00 PM 13 . 948 4 . 077 1.432 0 .702 2125/2013 4 :45:00 PM 13 . 949 4 . 078 1.479 0 . 694 2125 /2 013 4 :46 :00 PM 13 . 952 4.079 1.467 0 . 664 212512013 4 :47 :00 PM 13 . 944 4.082 1.531 0 . 682 2125/2013 4 :48 :00 PM 13 . 942 4.086 1 . 531 0.653 2125/2013 4 :49:00 PM 13 . 932 4.091 1 .54 0.668 2/25/2013 4:50:00 PM 13 .931 4 .0 92 1.573 0.671 2/25/2013 4 : 51:00 PM 13.929 4.09 1 .60 7 0 . 684 2/25/2013 4:52:00 PM 13.936 4.082 1 . 601 0 . 687 2/25/2013 4:53 :00 PM 13 . 927 4 .085 1 .549 0.688 2125/2013 4 : 54:00 PM 13.915 4.09 1 . 557 0 .661 212512013 4 : 55 :00 PM 13 . 933 4 . 078 1 . 572 0 . 653 212512013 4 : 56 :00 PM 13 . 933 4 .077 1 .5 64 0 .678 2 / 25/2013 4:57:00 PM 13 . 939 4 . 075 1.626 0 .703 2/25/2013 4 : 58:00 PM 17.013 2.302 0.644 0.46 13.721 30 . 091 31.665 13.712 30.151 30.625 13.705 30 . 055 31.695 13 .69 30.132 31 .495 13.724 29 . 666 32 . 064 13.724 29 .84 32.684 13 .726 29 . 663 32.733 13.726 29.669 33.111 13 .717 29.69 32 .653 13 .705 29 . 626 32.911 13.703 29 . 602 32 . 967 13.695 29 . 652 32.379 13.702 29 .732 33 . 0 33 13.696 29 .794 32 . 606 13.696 29 .775 32 .984 13 .693 29 .795 32.681 13 .706 29 .721 32.961 13.696 29.751 33.007 13.696 29.606 33.589 13 .697 29.536 33 . 969 13 . 69 29 .671 33.647 13 .697 29.749 32.81 13.705 29 .637 33 . 262 13.697 29 . 909 33.032 13 .666 30.003 32.166 13.69 29 . 939 32.352 13.692 29.604 32.503 13.694 29.695 32.783 13.696 29 .667 33.011 13 .686 29 .76 32 .712 13 . 689 29 . 67 33 . 243 13 . 69 29 .634 33.213 13.686 29.656 33.519 13.669 29.774 33 . 121 1.32 1 . 224 1 .288 CO bias 1 . 263 1 . 187 Direct Span 1 . 27 1 .299 Direct Zero 1.305 1 . 31 1 . 323 1 . 274 1.236 1 .2 36 1 .242 1 . 26 1 .2 56 1.269

1 .3 1 . 334 1 . 127 1.276 1.2 1 . 276 1 . 285 1.245 1.226 1.259 1 . 305 1 . 286 1.034 1.249 1 . 3 1.31 1 . 291Date Ti me 

### 0, % CO , % 2125/2013 4:59:00 PM 13 . 976 4 . 066 2125/2013 5:00:00 PM 13 .943 4.075 2/25/2013 5:01 :00 PM 13 .936 4.082 2125/2013 5:02 :00 PM 13 .938 4.082 2125 / 2013 5 :03 :00 PM 13 .922 4.091 212512013 5 :04 :00 PM 13 . 95 4 .075 212512013 5 :05 :00 PM 13 .936 4 . 084 2125 / 2013 5 :06:00 PM 13 . 917 4 . 095 2 / 25/2013 5 :07 :00 PM 13 . 914 4 . 094 2 / 25/2013 5:08:00 PM 13 . 951 4 . 073 2/25/2013 5:09:00 PM 13 . 942 4.076 2 / 25/2013 5:10:00 PM 13 . 926 4 . 082 2125 / 2013 5 : 11 :00 PM 13 . 937 4 . 076 21 2512013 5 : 12 :00 PM 13 . 896 4 . 098 21 25 / 2013 5 : 13 :00 PM 1 3 . 899 4 . 094 21 25 / 2013 5 : 14 :00 PM 13 .91 4 . 089 2125 / 2013 5 : 15 :00 PM 16 .423 2 . 639 2125/2013 5:16 :00 PM 13 .995 4 .043 2125/2013 5:17 :00 PM 13 .984 4.044 2125/2013 5:18 :00 PM 13.969 4.052 2125/2013 5:19 :00 PM 13 .962 4 . 053 2125 / 2013 5 :20 :00 PM 13.958 4 . 051 2125 / 2013 5:21 :00 PM 13 .948 4.053 2125 / 2013 5 :22 :00 PM 13 .942 4 .054 2125 / 2013 5 : 23 :00 PM 13 .9 36 4.058 2125 / 2013 5 : 24 :00 PM 13.93 4 . 059 2 / 25

/ 2013 5 : 25 :00 PM 13 . 922 4.061 2/25/2013 5:26 :00 PM 13 . 917 4.064 2125/2013 5 : 27 :00 PM 13 . 927 4.06 2125 / 2013 5 : 28 :00 PM 1 3 .919 4.064 2 / 25

/ 2013 5 : 29 :00 PM 13 .935 4 . 051 212512013 5 : 30 :00 PM 13 .962 4 . 036 212 5 / 2013 5 : 31 :00 PM 13 .946 4 . 04 2125 / 2013 5 : 32 :00 PM 16 . 574 2.528 2125 / 2013 5 : 33 :00 PM 13 . 933 4.051 21 25 / 2013 5:34:00 PM 13.92 4 . 052 2/25/2013 5:35:00 PM 13 . 926 4.047 2/25/2013 5:36 :00 PM 13.915 4.055 21 25 / 2013 5:37 :00 PM 13 . 918 4.052 2125 / 2013 5:38:00 PM 13 . 912 4 .057 2125 12 013 5 : 39 :00 PM 13 .9 31 4.046 212 512013 5 :40 :00 PM 13 . 913 4.057 2 / 25120 1 3 5 :41 :00 PM 13 . 912 4 . 055 2125 / 2013 5 :42 :00 PM 13 . 917 4.048 2125/2013 5:43 :00 PM 13 . 907 4.052 2/25/2013 5:44:00 PM 13 . 903 4.051 2125/2013 5:45 :00 PM 13 .894 4.055 2125 / 2013 5:46 :00 PM 13 . 902 4 . 049 212 5 / 2013 5:47 :00 PM 13 .904 4 . 048 2125 / 2013 5 :48 :00 PM 13 .915 4 . 041 NO. CO PPM PPM 1 .517 0.631 1 . 503 0 .696 1.441 1.218 1 . 514 2.267 1 . 548 3 . 948 1 .6 3 .035 1.595 2 . 309 1 .537 3. 619 1 .51 6 . 58 1 1 .629 3.401 1 .536 2.946 1.534 5 .491 1 .647 2. 426 1.457 3 . 241 1 .472 3 .699 1 . 509 3 . 078 0 . 919 1.883 1 . 554 2.176 1 . 513 3.001 1 .622 3.082 1 . 542 2 . 355 1 .6 1 9 2 . 369 1 . 536 2 .554 1.5 3 1 2 . 227 1.469 2 .733 1 .55 6 2.409 1 .525 2 . 326 1.458 2.941 1.438 2 .733 1 .455 2 . 564 1.456 2 . 546 1.44 2 .548 1.421 2 .478 0 . 918 1 .681 1 . 655 2.153 1 . 656 2.524 1 . 665 2.634 1 . 661 2 . 516 1 . 681 2.359 1 . 6 38 2.491 1 .51 2 . 24 1 . 5 1 1 2.27 1 . 556 2.435 1.497 2 .896 1 . 539 3.051 1 . 567 2.649 1 . 579 2 .646 1 . 518 2 .7 38 1.473 2 .853 1.492 2 .975 

### 0 , % NO. PPM CO PPM THC PPM 13.69 1 29 . 674 33.13 1 . 252 1 3 . 689 29 .704 33.516 1 . 309 13 . 688 28.463 41 . 207 2 .024 1 3 . 687 27 .701 71.101 10.42 13 . 685 26 .712 123 . 374 3 0 .1 4 13 . 68 9 27 . 689 100 .711 23 .1 12 13 . 693 27 .785 72 .875 10 .73 13 .689 26 .521 110 . 932 21.442 13.694 25 .673 225.779 81 .745 13 .714 27 .766 116.863 32.157 13.708 26 .852 86.307 11 . 17 13.699 26 .669 190.801 70.5 74 13 .697 27.962 74 . 883 10 .8 13 .701 27 . 135 110.518 25 . 963 13 .71 26 .977 138 . 202 29 . 882 13 .713 27 .516 110.547 24 . 607 13.718 27 .841 92.486 19 . 16 13 .706 28 . 078 80.259 1 4 .2 96 13 .72 27.418 102.717 22 . 114 13.699 27 .793 109.676 27 . 348 13 .69 28.204 80.813 14 .654 13 . 689 28 . 104 79 .719 12 .924 13 .686 27 . 925 90.479 18 . 145 13 . 67 1 28 . 144 79 . 137 1 2 .728 13 .67 4 27 .679 10 1. 743 21.7 06 13 .667 28 .296 88.295 17 .6 13.662 27 . 996 82.882 12 .79 1 13.642 27 .888 112 . 174 27 . 104 13 .652 28.269 100.626 21 .77 13 .656 28 . 386 91.159 18.496 13 .663 28 . 197 9 1 .532 16 . 168 13 .673 28 . 047 92 . 869 19 .3 63 13 . 665 28 . 035 88 . 355 16 . 13 9 13 . 659 28 .001 87 . 594 16 . 008 13 .66 28 . 134 82.299 12.997 13 . 662 28 .053 86.238 13 .728 1 3 . 661 27.923 89 .766 16 .703 13 . 658 28.202 88 .493 16 . 288 13 . 662 28 .257 80 .77 13 .795 13 .66 28 .355 86 . 225 15 . 182 13 . 669 28 . 2 3 9 85.498 15. 589 13 .662 28 .249 82.497 12 . 878 13 .655 28.228 86.747 16 . 289 13 .653 27.637 107.764 23 . 561 13.649 27 .794 119.515 28 . 895 13 . 642 27 . 89 97.697 19 . 286 13 . 636 28 . 04 98.146 20 . 246 13 . 637 27 .988 95 . 553 18 . 149 13 .636 2 7 .957 101.789 21.721 13 . 638 27 .858 110 . 665 2 5 .2 55 2125 / 2013 5:49 :00 PM 16.717 7.969 0.428 1.636 16 .585 10 .586 79.948 18 .774 2 / 25

/ 2013 5:50:00 PM 

## 1 18 .826 9.662 -0 .009 -0.42 18 . 8 1 7 0 . 819 0 . 875 0 .5 32 02lC02 b ;as 2 / 25

/ 2013 5:51 :00PM 6 . 933 3 . 318 2 .779 -0 . 305 7.38 22 .894 0.063 0 .717 2/25/2013 5:52:00 PM 

## LI

## _0~**.;;15;;6~.....;0",.1;.;2:;;9_....;4;; 5:;;5;3_...:;.0.:;;0;01;-_0~.;07:;2;-....;.4;,;1** **:;:92;;3;-....,;;0,:.0,:;92;;,-_.,:0,;; 5;;;3,..-1INOX**  b;as; THC Zero 2/25/2013 5:53:00 PM 0 . 139 0.119 1 . 267 4.959 0.179 13.468 95.445 1.533 2 / 25

/ 2013 5:54:00PM 0 . 137 0.113 -0 . 014 9 .524 0 .043 0 . 5 1240 .7931 1 . 321 COb ;as 212512013 5 : 55 :00 PM 12 . 322 6 . 943 3 . 031 9.569 13 .798 31.423 238 .053 10 . 103 212512013 5 :56 :00 PM 

## 1 1 8 .891 9 . 68 4 . 575 9.586 18 . 887 41.964 241 . 671 

## 1 42 . 23 D;rect Span 212512013 5 : 57 :00 PM 7 . 043 2 . 758 1.507 3.798 4.739 9 . 941 132.472 47 .349 2125 / 20 13 5 :58 : 00 PM 0 . 128 0.084 ·0 .01 0.021 0 .047 0 .089 0.446 47 .325 D irect Zero 212 5/ 2013 5 : 59 :00 PM 

# L-: 1 

## ':i 2 ';; .

## 7ii69:;-......;2:':.0~4~3---:;0"i**96~2**-"";'1

## ;';1;;'73i:-~0;';**~12~5~""";0:': 2:i2~5-~0':i.9::;'68i:-r.4~7;:** **6ii3-i-4'THC** Md 2/25/2013 6:00:00 PM 13 .94 4 . 024 2 . 022 4.878 7 . 11 12 . 169 29 . 305 46.553Date Time 

### 0, % 

## co, % 2125/2013 6:01 :00 PM 13.94 4 . 028 2/25/2013 6:02:00 PM 13.931 4.037 2/25/2013 6:03:00 PM 13.923 4.044 2/25/2013 6 :04:00 PM 13 .918 4 . 048 2125/2013 6:05:00 PM 13 . 923 4.047 2125/20 13 6 :06:00 PM 13 . 919 4 . 051 2125120 13 6:07 :00 PM 13.926 4 . 047 2125/2013 6:08:00 PM 13.937 4 .04 2125/2013 6:09:00 PM 13.947 4 .038 2/25/2013 6:10:00 PM 13.952 4.036 2/25/2013 6:11 :00 PM 13.957 4.037 2/25/2013 6:12:00 PM 13 . 965 4.034 2125120 13 6:13:00 PM 13 . 97 4.031 2125/2013 6:14:00 PM 13 . 97 4.032 2125/20 13 6:15:00 PM 13 . 981 4 . 027 212512013 6:16:00 PM 13 .977 4 .027 2125/2013 6:17 :00 PM 13.987 4 . 018 2/25/2013 6:18 :00 PM 13.992 4 . 014 2/25/2013 6:19:00 PM 13 .989 4 . 017 2/25/2013 6:20 :00 PM 14.005 4 . 008 2/25/2013 6:21 :00 PM 14 .01 4.007 2125/2013 6:22:00 PM 14.003 4 . 009 2125/2013 6 :23:00 PM 15.606 3.095 2125 / 2013 6 :24:00 PM 13.957 4.047 2125/2013 6:25 :00 PM 13 . 952 4 .049 2125/2013 6:26 :00 PM 13.965 4.042 2125/2013 6:27 :00 PM 13.946 4.054 2125/2013 6:28 :00 PM 13.946 4.051 2125/2013 6:29 :00 PM 13.946 4.054 2125/2013 6:30:00 PM 13.939 4.061 2125/2013 6:31:00 PM 13 . 941 4 .058 2125/2013 6:32 :00 PM 13 . 95 4.055 2125 / 2013 6 : 33 :00 PM 13.947 4 .056 2/

25/2013 6:34:00 PM 13 . 944 4.058 2125/2013 6:35 :00 PM 13 . 95 4.054 2/25/2013 6:36:00 PM 1 3.975 4.042 2125/2013 6:37 :00 PM 13.962 4.049 2125/2013 6:38 :00 PM 13 . 964 4 .049 2125/2013 6:39:00 PM 13.953 4.057 2125/2013 6:40 :00 PM 13.959 4.056 2125 / 2013 6:41 :00 PM 17 .623 1.95 212512013 6:42 :00 PM 13 . 958 4.065 2125/2013 6 :43 :00 PM 13.941 4 .065 2125/2013 6:44 :00 PM 13 . 929 4 .073 2125/2013 6:45:00 PM 13.927 4.07 2/25/2013 6:46:00 PM 13.937 4.064 2/25/2013 6:47 :00 PM 13.939 4.059 2125 / 2013 6:48:00 PM 13.938 4.061 2125/2013 6 :49:00 PM 13.945 4.056 2125/2013 6 :50 :00 PM 13 . 959 4 .048 212512013 6:51:00 PM 13 . 959 4.048 2125/2013 6:52:00 PM 13 . 973 4.039 2125/2013 6:53:00 PM 13.985 4 .0 33 2/25/2013 6:54:00 PM 13.975 4.037 2125/2013 6:55:00 PM 13 .98 4.034 2125/2013 6 :56:00 PM 13.976 4.035 2125/2013 6 : 57 :00 PM 13 . 971 4 . 038 2125/2013 6 :58:00 PM 16. 105 2.807 2125/2013 6 : 59 :00 PM 13 .988 4.028 2/

25

/ 2013 7:00:00 PM 13.986 4.027 2/25/2013 7:01 :00 PM 13 . 987 4.029 2125/20 13 7:02:00 PM 13.982 4.032 

### NO , PPM 1 . 984 2 . 077 2 . 099 2 .1 72 2 . 097 2 . 077 2 . 13 2 . 126 2 . 101 2 . 073 2 . 122 2 . 053 2 . 077 2 . 066 2 . 161 2 . 174 2 .367 2.373 2.404 2 . 342 2 . 394 2 . 319 1 .479 1 .76 1 .751 1.704 1 .669 1 .6 83 1.606 1 .762 1.575 1 . 579 1 . 552 1 .621 1.627 1.464 1 . 528 1 . 503 1 . 542 1.558 0 .74 1.785 1 . 821 1.929 1 .929 1.941 1 . 98 1.917 1 .763 1 .743 1.7 11 1 .57 1.475 1 .546 1.516 1 . 54 1 .545 1 .514 2 . 371 2.226 2.228 2 . 23 

### CO PPM 5.704 5.461 5.093 3.439 3 . 89 4.027 4.092 4 .251 3.658 3 .615 3.131 4.695 4.112 4 .058 5 . 381 4.788 5.039 4.506 4.539 5.498 5.505 6.592 4.068

4 3.139 3.83 4 . 092 3.543 3.81 3 . 352 4 . 058 3 . 613 3 . 997 3 .586 2.545 3.411 3.1 3.58 3 . 958 3 . 559 2 . 149 3 . 124 4 .038 4.45 3 . 036 3.552 3 . 325 3.48 3 . 029 3 . 518 4 . 164 3 . 891 3.832 3 . 023 3.51 3.434 3.563 2.442 3 .447 4 . 076 3 . 911 4.232 

### 0, % NO, PPM 

### CO PPM 

## THe PPM 13.611 25.957 173.494 59 . 382 13 .61 4 26.775 167 . 059 55.904 13 .612 27.222 153.095 53.875 13.628 27 .896 91.171 16 .939 13 . 62 27.649 115.873 33 . 554 13.624 27.634 113 . 386 27 .535 13 .638 27.499 114.897 27.545 Start RATA 6, 75% Comp 2 13 .637 27 . 501 128 . 534 37.402 13.637 27 . 957 105 . 656 24 .068 13.645 27 .757 105 . 183 24 . 16 13 . 64 27.9791.29517.453 13.637 27.097 137.682 38.679 13.646 27.687 125.064 37.872 13 .645 27 .245 116.939 23 .3 86 13.634 27 .022 158.212 55.423 13 .645 27 .051 134.997 37 . 394 13 .634 27 . 277 144.683 45 . 059 13 .64 27.469 127.58 34 . 108 13.647 27 . 387 122.363 32.32 13 .67 4 26 . 944 153 .763 47 .271 13 .673 27.008 148 . 903 46 .836 13.672 26.396 191 .851 69 .635 13 .6 71 2 7.409 154 .403 48.498 13 .678 27.233 133.921 36.426 13 .67 27.668 108.498 26 . 741 13.669 27.129 123.438 32 . 65 13.658 27.195 141.787 42 . 107 13 .65 8 27.463 120,47 33 . 607 1 3 .659 27 . 314 127.516 31.41 13 .663 27.79 1 111.864 27.817 13 .668 27 . 131 141.516 41 .028 13.666 27 .3 97 136.648 39 . 71 13.671 26 . 953 145 . 966 43 .619 13 .671 27 .713 145.205 45 . 046 13.676 27 .695 90 . 56 16 . 303 13.665 26 . 947 133.097 37.854 13.666 27.529 120.643 32 . 116 13 .675 26.746 134 . 826 36 .218 13 .67 27 . 225 168.149 60.741 13 .676 27 . 106 140.356 40 .062 13 .68 27.231 155 .751 52.461 13 .67 27 .811 125.055 34 .898 13.675 26 . 968 138.377 38.134 13 .669 27.402 163.573 50.486 13.663 27.819 100.88 22.365 13.679 27.512 119.466 30.408 13 .679 27.469 117.471 29.746 13 .676 27 . 67 118.43 30.617 13 .684 27.784 105.976 26.189 13 . 687 27 . 135 123 . 956 32.219 13.682 27 . 121 151.759 47 . 979 13.677 26.908 142.532 32 . 119 13.672 27 . 271 149.028 50 . 111 13.664 27.526 118 . 916 29.723 13.658 27.097 140.496 40.872 13 .661 27.184 132 . 137 38 . 902 13 .658 27 .078 142.495 39 . 054 13 .667 27 .672 117 . 138 31 .886 13 . 682 27 .844 102 . 065 23.562 13.669 27.427 119.332 31.007 13.672 27.656 115.167 31 . 314 13.669 27.239 123.049 30 . 887Date Time 212512013 7:03 :00 PM 212512013 7:04:00 PM 212512013 7 :05 :00 PM 212512013 7:06:00 PM 21

2512013 7:07:00 PM 212512013 7:08 :00 PM 2125 1 2013 7 :09 :00 PM 2125 1 2013 7 : 10 :00 PM 212512013 7:11 :00 PM 212512013 7:12:00 PM 212512013 7:13:00 PM 212512013 7:14 :00 PM

212512013 7:20 :00 PM 212512013 7:21 :00 PM 212512013 7:22 :00 PM 

### 0, % 13 .981 13.981 13 . 99 13 .991 13 .989 13 . 999 13.997 14 .018 14.008 14.004 14.004

14

0.139 0.137 0 . 116 212512013 7:23:00 PM 15 . 377 212512013 7 : 24 :00 PM 

## 1 18.87 2125 / 2013 7 : 25 :00 PM 3 . 557 212512013 7 : 26 :00 PM 0 . 121 2125 1 2013 7 : 27:00PMI 0 . 114 2125/2013 7:28:00 PM 0.59 2/25/2013 7:29:00 PM 13 . 628 2/25/2013 7:30:00 PM 13.94 1 2/25/2013 7:31 :00 PM 13 . 944 2125/2013 7 : 32:00 PM 13 . 937 2125/2013 7 : 33 :00 PM 13 . 936 2125/2013 7:34:00 PM 13 . 943 

### CO , %

2125/20 13 7 : 35 :00 PM 13 . 948 4 . 043 2125/2013 7 :36:00 PM 13.967 4 . 035 2125/2013 7:37 :00 PM 13.964 4.039 2125/2013 7:38:00 PM 13.993 4.02 2/25/2013 7:39:00 PM 14 . 006 4.011 2125/2013 7:40:00 PM 14 .001 4 . 016 2/25/2013 7:41:00 PM 16 . 043 2.847 212512013 7:42 :00 PM 13 . 951 4.059 2125120 13 7 :43 :00 PM 13 . 933 4 .064 212512013 7:44:00 PM 13.93 4.068 2125/2013 7:45 :00 PM 13.935 4.065 212512013 7:46:00 PM 13.942 4 .062 2/2512013 7:47 :00 PM 13.939 4.064 2125/2013 7:48:00 PM 13 . 951 4.06 2125/2013 7:49:00 PM 13.962 4.057 2125/2013 7:50 :00 PM 13 . 977 4 . 047 2125 / 2013 7:51 :00 PM 13 . 966 4 . 048 2125 / 2013 7 : 52 :00 PM 13 .979 4 . 034 2125/2013 7 : 53 :00 PM 17 .644 1.902 2125/2013 7:54 :00 PM 13.982 4 . 03 2125/2013 7:55:00 PM 13.928 4.038 2125/2013 7:56:00 PM 13.922 4 .0 35 2125/2013 7:57:00 PM 13 . 921 4 . 031 2/25/2013 7:58:00 PM 13 . 931 4 .02 2125 / 2013 7:59:00 PM 13 . 907 4.031 2125/2 013 8 :00 :00 PM 13.8 8 4 . 043 212512013 8:01:00 PM 13 . 885 4 . 042 2125 / 2013 8:02:00 PM 13 . 894 4 . 039 2125/2013 8 :03:00 PM 13 . 898 4 . 041 212512013 8:04:00 PM 16 . 815 2.284 

### NO , PPM 2.255 2.309 2.464 2 . 545 2 .421 2.498 2 . 507 2.536 2 .636 2.683 2.732 2 . 638

2.531 -0.006 -0 .01 

### CO PPM 5.123 5.437 5 . 903 4 . 53 5 . 164 4 . 999 3 . 638 4 .167 4.484 4.502 4 . 301 4 . 817

2.401 9.331 9 . 601 

### 0 , % 13.68 2 13 .669 13 . 67 13 .677 13.671 13 .681 13.678 13 .681 13.683 13.673 13 .671 13 . 68

0 . 201 0 . 043 0 . 044 

### NO, PPM 26 . 909 26 .741 26 .74 27 . 507 26.81 27.257 27 .859 27 . 223 27 . 251 27 . 294 27 . 3 27 . 237

26 . 23 

### CO THC PPM PPM 153.709 50.058 162.845 53 . 593 171.992 60 . 157 135.745 43 . 931 151.445 45 .771 153.155 52 . 136 104 . 003 25 . 381 121 . 309 32 .989 128 . 817 37 .274 132.717 37.129 123.021 24 . 585 135 .996 37 .3 42

29.736 1.14 0.534 231.154 1.301 0.402 1 241.4231 1.326 2 . 312 9 . 606 12.807 26 .717 237 . 516 6 .86 CO bias 4 .582 9.59 18.851 41.878 241.4281 34 . 1 Direct Span 1.412 5 .751 9 . 335 19.671 176.492 33.597 -0 . 014 0 .223 0 . 054 0 . 103 2.469 46 . 192 -0 .015 0.004 0.042 0 .069 -0 .034 46 .982 Direct Zero -0.016 -0.009 0 .042 0 . 067 -0.036 47 .399 1.874 2.204 2.204 2.277 2 . 359 2 . 271 2 .4 18 2 . 38 2.454 2.67 2.599 2.456 1.559 1 .765 1 .709 1.787 1.79 1 .821 1.757 1 . 65 1 . 585 1.474 1.568 1 . 502 0 .731 1 . 909 1 . 935 1 . 901 1 .93 1 . 931 1.744 1 .813 1 .784 1 . 807 1. 883 1.074 2.14 3.777 3.652 4 . 011 3.544 3 . 381 3 . 566 4 . 186 3.904 4.355 4.661 5.587 3.107 3 . 149 3 . 62 3.742 3.842 4.199 3.969 3 . 899 3 . 298 3 . 393 3 . 242 3 . 975 2 .614 3 . 614 3 . 678 3.368 4.342 3.297 4.765 3. 9 13 4 .016 4 .654 3.792 3.003 8.822 9 .93 9 . 935 9 .923 9.926 9 .9 35 16.933 51.26 47 .737 22.411 131.5251 48 .073 

### ITHC Mid 23.62 132.821 47 . 944 Start RATA 7 23 .724 132 .805 41 .434 23 .729 133.153 25 . 926 23 .723 133.00 1 

## 1 20 . 835 tntet M i d 12 .726 25 . 191 115 . 929 24 . 194 13 . 65 27 . 111 115.398 30 .988 13.649 27 . 378 106 .315 24.457 13.663 27 .33 4 122.363 34.242 13.662 27.061 123.656 33.059 13 . 662 26.987 156.538 53 . 016 13 . 666 27.459 112.328 26.412 13 .659 27 .663 108.734 28 . 235 13 . 655 27 .1 9 115 . 077 30.474 13.648 27 .233 128 . 346 36 .611 13.65 27.023 127.531 33 .747 13.653 26.911 135.724 39.682 13.662 27.3 137.056 43.6 13.657 27 . 27 136 .0 1 42 . 247 13 .663 27.39 117.319 33 . 298 13 .664 27 .1 6 128. 4 32 37 . 508 13.668 27 . 258 122.618 30 . 292 13 .673 26.559 149.841 18 .5 3 13 .679 26.504 169.118 1 . 09 13 .665 27 . 069 138.475 0 . 984 13.656 27.61 116.828 0 . 917 13.649 27.503 104.743 0 . 881 13 .648 27.064 135.797 0 . 977 13 .657 27 . 531 99 . 98 0 .86 13 . 641 26.499 152.62 1 . 035 13 .633 27.39 131 . 603 0 . 963 13 .641 27 . 107 128 . 062 0 . 953 13 . 65 26 . 977 151.985 1.023 13 . 66 27 . 506 123.403 0 . 933 13.667 27.469 122.129 0.933Dale Time 

### 0, % 

### CO, % 2/25/2013 6:05:00 PM 16.399 2.693 2/25/2013 6:06:00 PM 13.965 4 . 01 2125/2013 6:07:00 PM 13.954 4 .015 2/25/2013 6:06 :00 PM 13.964 4 . 012 212512013 6 :09:00 PM 13 . 956 4 . 013 2125/20 13 6:10:00 PM 13 . 961 4 . 001 2 / 2512013 6 : 11 :00 PM 13 .996 3.991 2125/2013 6:12:00 PM 14.007 3.966 2/2512013 6:13:00 PM 14.01 3.966 2/25/2013 6:14:00 PM 14 . 009 3 .99 2/25/2013 6:15:00 PM 14.036 3.976 

### NO, PPM 1.479 2.361 2 .3 55 2 .3 23 2 . 299 2 . 605 2 . 564 2 .722 2.691 2 . 599 2 . 562 

### CO PPM 1.556 4 . 056 4.71 4.513 5 . 929 3.266 5 . 563 4.651 4 .527 4.554 4.271 

### 0, % NO, PPM 

### CO PPM THC PPM 13.662 27 .74 110.636 0.694 13.657 27.502 116.553 0.921 13.664 27 . 359 136.606 0 . 967 13.66 26 . 665 131.065 0 .96 1 13 . 659 26 .759 162.627 1 . 131 13 . 659 26 . 053 91.354 0 . 633 13 . 657 26. 449 153.732 1 . 033 13.669 27.457 137.446 0.961 13.676 27 . 256 124.202 0 .941 13.665 27.456 126.664 0 .952 13.676 27 . 261 110.75 0.695 2/25/2013 6:16:00 PM 16.179 7.267 1 . 047 3 . 171 13 . 663 27 . 367 119 .764 0 . 922 2/25/2013 6:17:00 PM 

# I 16.623 9.665 -0.004 -0 . 345 13 .654 27 .55 6 119.627 0 .923 02lC02 bias 2 / 25/2013 6:16:00 PM 

### ,;;;6 . :';94:;;

1 '--;4,. 3;.;6;:;2_--;2"i.2"'6,;.5
__ --;:0:';

.3:;44", 13 . 655 27 . 233 121.567 0 . 932 2125/20 13 6:19:00 PM 

# I 0 . 16 0.146 4 . 551 -0 .0 17 13 . 666 27 . 035 150.315 1.025 NOxbias 2125120 13 6 :20:00 PM 0 . 137 0. 133 1 . 51 4.377 13 . 66 27 . 265 114.091 0.906 2125/2013 6:21:00 PM 0 . 137 0.129 -0 . 005 9.469 13.661 26.622 126 . 17 0 . 947 2125/20 13 6:22:00 PM 0 . 114 0.126 -0.Q1 9 . 591 13.655 27 . 181 137.397 0.984 CO bias 2125/2013 6:23:00 PM 9.514 2.91 1.559 6.639 13.656 27.613 115.43 0.911 2125/2013 6:24:00 PM 13.972 4.006 2.313 3 .769 13.667 27.563 102.264 0.666 Start RATA 6 2125/2013 6:25:00 PM 13.967 4.013 2 .227 4.319 13.67 27 . 15 121.662 0.931 2125/20 13 6:26:00 PM 13.965 4.014 2 . 16 5.074 13.671 26.679 153.905 1 . 037 212512013 6:27 :00 PM 13 . 965 4 . 016 2 . 379 4 . 092 13.675 27 .625 120.491 0 . 926 212512013 6:26 :00 PM 13 . 991 4.009 2.2 15 4.626 13 .672 26.626 137.326 0 . 962 2125/2013 6:29 :00 PM 13 . 991 4.01 2 . 261 3.966 13.669 27.374 121.665 0.926 2/25/2013 6:30 :00 PM 14 . 037 3.964 2 . 366 5.402 13 . 666 26.179 145.357 1.007 2/25/2013 6:31 :00 PM 14.042 3.96 2.424 5.935 13 . 674 26 .714 176.576 1.114 2/25/2013 6:32:00 PM 14 . 045 3.979 2.437 4.316 13.676 26.695 115 .326 0 . 91 2/25/2013 6 :33:00 PM 14.049 3.96 2.523 4.256 13 . 676 27 . 33 125 .321 0 .942 2125/2013 6:34 :00 PM 17.556 1.959 1.045 2.04 13.675 26 .679 116.039 0.913 2 / 25/2013 6:35 :00 PM 14 4.029 1 .65 6 4 .62 13 . 664 26 . 237 195.475 1 . 176 212512013 6:36 :00 PM 13.965 4 . 026 1 .761 3.659 13 .675 27.447 136 . 069 0.976 2125120 13 8:37 :00 PM 13.964 4.039 1 . 569 5.613 13.656 25 .256 201 . 3 1.191 2125/2013 6:36:00 PM 13.962 4.04 1.619 6.594 13 .653 25.664 245.317 1 .3 4 2125/201 3 6:39:00 PM 13.976 4.031 1.767 3 . 159 13.642 26 .044 111.92 0 . 697 2125/2013 6:40:00 PM 13.941 4.047 1 . 657 4.969 13.636 26.003 170.429 1.066 2/25/2013 6:41 :00 PM 13 .954 4.043 1.599 4.006 13.626 27.465 156.169 1.0 44 2/25/2013 6 :42:00 PM 13.943 4 .046 1 . 566 3.027 13.625 27.66 119 .673 0 .92 2/25/2013 6:43 :00 PM 13.946 4 . 042 1 . 522 2.906 13.63 27 . 601 112.331 0.904 2/25/2013 6:44 :00 PM 13 . 977 4 . 027 1.541 2 .752 13 . 652 27.729 102.792 0.672 212512013 6 :45:00 PM 13 . 96 4 . 029 1 .466 3 . 034 13 .653 27 . 504 115 .225 0.91 212512013 6:46 :00 PM 16.567 2.527 0 . 963 1.663 13.662 26 . 251 77.399 0.762 212512013 6:47:00 PM 13 . 964 4.041 1 . 642 2.106 13 . 656 26 . 071 66.575 0.753 2125/2013 6:46:00 PM 13 .94 4.046 1 .796 2.261 13.66 27 . 949 67.615 0.752 2/25/2013 6 :49 :00 PM 13.946 4 .041 1.77 3.265 13.672 27.46 102.063 0.666 2/25/2013 8 :5 0 :00 PM 13.948 4 .042 1.649 2.406 13.661 27.635 71.064 0.763 2125/2013 6:51:00 PM 13.943 4.041 1.757 3.746 13 . 659 27.011 121.73 0.931 2125/2013 6:52:00 PM 13 . 936 4.046 1 .7 65 4.063 13 . 656 26.677 122 . 199 0 .9 32 2125/2013 6:53:00 PM 13.93 4.05 1 .626 5 . 53 13.653 26.392 176.342 1 . 112 212512013 6:54:00 PM 13 . 939 4 .041 1.925 3.594 13 .659 27 .466 1 14 .52 1 0.904 2125/2013 6:55 :00 PM 13.93 4 . 049 1.63 4.046 13 . 651 26 .631 126 .663 0 .954 2125/2013 6:56 :00 PM 13 . 916 4 .056 1 .6 56 4.591 13 .6 36 27.209 152.695 1 .034 2/25/2013 6 :57:00 PM 16 . 065 2.72 1.267 2.97 13.631 27.445 109.474 0.669 2/25/2013 6:56:00 PM 14.297 3.931 2.103 3 . 639 13.636 27.105 140 .264 0.992 2125/2013 6:59:00 PM 13.976 4.015 2.337 4 . 237 13.626 27.027 124 .65 4 0.939 2/25/2013 9:00:00 PM 13.962 4.012 2 . 193 5.044 13.645 26.63 157 . 669 1 .049 2125/2013 9:01:00 PM 13.96 4 .014 2 . 256 4 . 127 13 .636 27 . 153 124.401 0.94 2125/2013 9 :02 :00 PM 13 . 977 4 .016 2 . 293 4 .725 13 .643 26 .653 143.457 2125/2 013 9:03 :00 PM 13 . 99 4 .006 2.453 3 . 36 13 .654 27.665 94.629 0.642 2125/2013 9:04:00 PM 14.015 3.969 2 .733 3.645 13 .653 27 .675 109.01 0 . 69 2125/2013 9:05:00 PM 14 . 016 3 .966 2.734 4.069 13 .651 27.426 106.617 0 .667 2125/2013 9:06:00 PM 14.024 3.962 2 . 563 4.545 13.666 26.94 130 .126 0.957Date Time 

### 0 , % 

### CO, % 

### NO, PPM 

### CO PPM 

### 0 , % NO, PPM 

### CO PPM 

### THC PPM 2/25/2013 

### 9:07:00 PM 14.024 3 . 98 2 . 511 5.705 13 . 655 26 .808 165.793 1.073 2125/2013 

### 9:08:00 PM 16.931 8.195 0 . 669 1.68 13.648 27.978 84.596 0.807 2125/2013 

### 9:09:00 PM

## rl"",i-i8~.8:;:0';'8-""9;;;**6:ii8;;5~-i_0;:;.0;::0:;8""** -0.41 13 .65 27.435 104.085 0 .872 02lC02 bias 2125/2013 

### 9 : 10 :00 PM .... ;i5
.

'4n'04:f-.....,2;;;
.5f.

3 ;.:4---;3;., . 1;;7;;5..... -0.267 13.634 27.473 110.216 0 . 89 2125/2013 

### 9:11:00 PM 

# I 0 .1 5 0.137 4 . 563 0 13 .638 26.87 1 138.523 0 .98 6 NOx bias 2125/2013 

### 9 : 12 :00 PM ....

## ;i0**':-,:::38;-.....,0;;; =',2;;7:--:,~** **.06 ~5-~5~** **2~96;;-'** 13.643 27 . 119 132 . 545 0.968 2125/20 13 

### 9 : 13 :00 PM 0 . 138 0 . 123 -0.009 9.529 13 .636 27 . 226 121.097 0 .928 212512013 

### 9 : 14 :00 PM 0.114 0.12 -0 . 008 9.614 13 .638 26 .268 150 .276 1 .026 CO bias 2125/20 13 

### 9:15:00 PM 6.303 1.99 1.038 8.096 13.64 27.553 138.887 0 . 986 2125/2013 

### 9 :16:00 PM 13.946 3 . 995 2 . 274 4 .216 13.643 27 . 177 116.544 0.914 Start RATA 9 2125/2013 

### 9 : 17 :00 PM 13.974 4 . 004 2 . 383 4 .205 13.648 27 . 564 126.024 0.944 2/25/2013 

### 9:18 :00 PM 13 . 986 4 . 003 2 . 368 4 . 35 13.653 26.79 122 . 895 0 .934 2125/2013 

### 9:19 :00 PM 13.987 3.999 2 .2 76 4 . 509 13 .658 27.486 132 . 637 0 .964 212512013 

### 9:20 :00 PM 13 . 991 3 . 995 2 .3 87 3 .258 13 . 66 27.498 86 . 381 0 .811 212512013 

### 9 : 21 :00 PM 13 . 993 3 . 996 2 . 272 4 .736 13 .652 27 . 158 132 .84 0 .967 2125/2013 

### 9 : 22 :00 PM 14 . 009 3 .985 2 .5 48 3.372 13 .655 27 . 377 86 .842 0 .817 2125/2013 

### 9 : 23 :00 PM 13 . 999 3.99 2.305 5.56 13 .646 26.769 156.071 1.043 2125/2013 

### 9 : 24:00 PM 13 . 994 3 . 993 2 . 342 3.048 13 .644 27 .881 81.229 0 .798 2125/2013 

### 9 : 25 :00 PM 14.001 3.989 2.281 4 . 16 13.661 26.423 113.541 0.902 2125/2013 

### 9:26 :00 PM 16 . 622 2.484 1.426 3.723 13.646 27.68 140.308 0 . 991 2125/2013 

### 9:27 :00 PM 1 3.997 4 . 004 2 .26 2.202 13 .644 28 . 047 61 . 251 0.731 2 / 25

/ 2013 

### 9 : 28 :00 PM 13 . 985 4 .01 2 .1 33 3 .79 13 .645 27.351 109 .529 0.891 2125/2013 

### 9 : 29 :00 PM 13 . 988 4 . 008 2 . 121 3 .772 13.654 27 . 342 107.763 0.884 2125/20 13 

### 9 : 30 :00 PM 13 . 988 4.009 2.158 3.727 13 .655 27.355 109.19 0 .889 2125/2 013 

### 9:31:00 PM 13.988 4.013 2 . 25 3.738 13 . 645 27 .42 108 .624 0 . 889 2125/2013 

### 9:32:00 PM 13 .991 4 . 009 2 . 261 3 .644 13 . 644 27.578 99.792 0 . 861 2125/2013 

### 9:33:00 PM 14 .011 3.994 2 . 531 3.238 13 . 642 27 .667 89.717 0 . 826 2125/2013 

### 9:34:00 PM 14 3.998 2 . 535 4.624 13 . 635 26.996 135.141 0 . 972 2125/2013 

### 9:35:00 PM 14 . 003 3.996 2 . 536 3 .658 13 . 635 27.727 102.606 0 . 867 2125/2013 

### 9:36:00 PM 13 . 991 4.001 2.325 5.794 13 . 628 26.238 163.094 1 . 066 2125/2013 

### 9 :3 7 :00 PM 16.748 2.411 1.473 3.274 13 . 633 27.638 122.634 0 .934 212512013 

### 9 : 38 :00 PM 13 .991 4 .01 2.307 4 . 905 13 . 6 1 8 26 . 58 149 . 804 1.023 2125/2013 

### 9:39 :00 PM 13.987 4.007 2.475 3.372 13 .621 27.713 98.404 0.854 2125/2013 

### 9:40 :00 PM 13.97 4.015 2 .265 5 . 337 13 .612 26 .684 147 . 129 1 .012 2125/2013 

### 9:41:00 PM 13 . 976 4.015 2 . 567 3.337 13.618 28 . 087 93.567 0 .833 2/25/2013 

### 9:42:00 PM 13.981 4.0 12 2.329 4.152 13 . 626 26.739 111 . 361 0 .896 2125/2013 

### 9:43 :00 PM 13.987 4.007 2 . 307 5.404 13 . 637 27.074 178 . 226 1.117 2125/2013 

### 9 :44 :00 PM 13 .989 4 . 005 2 . 337 3 . 14 13 . 646 27 .874 79 .948 0 .793 2125 / 2013 

### 9 :45 :00 PM 13.989 4 . 002 2 . 268 5.16 13 . 636 26 . 192 142 . 504 0 .997 2 / 25

/ 2013 

### 9 :46 :00 PM 13 . 994 4 .001 2.42 5 .084 13 .629 27.464 155. 107 1 . 04 2125/2 013 

### 9 :47 :00 PM 13 . 99 4 . 004 2 . 295 3 . 642 13 .63 27 .445 92.427 0 . 835 2125 / 2013 

### 9 :48 :00 PM 1 6 . 37 2.632 1.445 3.185 13.622 27 .0 53 126.177 0.944 2125/20 13 

### 9 :49:00 PM 13 . 992 4.01 2 . 2 4.649 13.631 26.705 138.83 0.986 2125/2013 

### 9:50 :00 PM 13 . 988 4 .011 2.232 4.472 13 . 634 27 . 129 128 . 291 0 .952 2125/2013 

### 9:51 :00 PM 13 . 987 4 .012 2.201 4.87 13.635 26.647 141.553 0.996 2/25/2013 

### 9:52:00 PM 13.989 4.012 2.362 4 .044 13 .641 27.21 118.328 0 . 92 2/25/2013 

### 9:53:00 PM 13.986 4.018 2 .284 5 . 287 13 .643 26 .5 64 156.556 1 . 045 2125/2013 

### 9 :54 :00 PM 13.99 4 .0 15 2.472 4.961 13 .634 27.175 139.725 0.99 212512013 

### 9 :55 :00 PM 13 . 991 4 .011 2.479 5.336 13.638 27 . 108 142.269 0 . 997 2125/2013 

### 9:56:00 PM 13.989 4 .0 16 2 . 397 5 .647 13 .636 26 . 878 155.142 1 .041 2125/2013 

### 9 :57 :00 PM 13 .9 89 4.018 2.478 5 . 228 13.646 26 .85 145 . 101 1 .005 2/25/2013 

### 9:58 :00 PM 13 . 978 4.027 2.461 5 . 273 13.643 27 . 18 150.469 1 .026 2125/20 13 

### 9:59:00 PM 15.861 6.982 1 . 152 3.698 13.637 26 . 923 149.136 1 . 022 2/25/2013 

### 10:00:00

## PM,.I..:..;,;;8;;:**8.:........;9;;; 6;;;9;:;4~-i-0;,.0;;;0,;6..,**  -0.295 13.634 26.443 176.069 1 . 108 02/C02 

### bias 2125/2013 

### 10 :01:00 PM 11.207 5.535 1 .728 -0 . 37 13 . 645 26 . 631 175.172 1.107 2125/2013 

### 10 :02 :00 

### PMfl

### nO. -;;177:

5 '.....,0;;; . 1;-;5



## oi 8:--4 • .

## :f.

53

f--

_ ;;0;;

. 0;,;2;3' 13 . 643 27.574 135.509 0.974 NOx bias 2125 / 2013 

### 10 :03 :00 PM 0 . 138 0 . 14 1 . 576 4.267 13 . 639 28 . 283 86.188 0.814 2125/2013 

### 10 :04 :00 PM 0.138 0 . 132 -0.008 9 .503 13 . 667 27 . 937 89 .77 0 .83 2125/20 13 

### 10 :05 :00 PM 0 . 122 0 . 128 -0 .0 1 6 9 . 6 2125/2013 

### 10 :06 :00 PM 14 . 992 8.7 1 9 3.868 9.604 2125/2013 

### 1 0 :07 :00

## PMrl""';';8;;.8"'8;-'-"':;9;".7:=--":;4;;.5~6;;3--;;9;;;.5;;75"'" 2/25/2013 

### 10 :0 8 :00 PM ....

### ;i5.-;',0n'4;-....,,;'.77'2;;,--:,'i.0;;i0'i-8--;-3~.8..

### ,4~ 14 . 216 26.993 63.109 15.398 27.391 51.061 16 .716 29.415 51.927 16.691 28 .855 68 .0 63 0.736 CO bias 

### 0.699 0 .703 Direct Span 

### 0 .753

### 0 , CO, NO , CO 

### 0 , NO , CO THC Date Time % % PPM PPM % PPM PPM PPM 2 / 25

/ 2013 10:09:00 

## PM! 0 . 122 0 . 098 -0 .009 0.029 16 . 694 28.548 74.348 0 .775 Direct Zero 2/25/2013 10:10:00 PM 8.378 4.462 2.404 2.43 16 .704 28 . 288 77.744 0 .786 2/25/2013 10:11 :00 PM 10 . 005 5 . 122 2.531 4.497 16 . 698 28 . 256 79 . 103 0 .792 2125 / 2013 10 : 12 :00 

## PM! 10 . 005 5 . 121 2 . 526 4.488 16 . 692 28 . 264 79 . 276 0 .7 88 Di rect MidO 2 CO 2 NO x CO O 2 NO x CO Date Time % % PPM PPM 

### % PPM PPM 2126/2013 7:48 :00 AM LI

## +.0**~1 i:i12':-....,0".0~7,.;4_....,-0"** **0;::3;:;1,.-_-~0;,; 0:;;36~....,0~."::04ii3':-.....;0;;.** **04~1,....~-0;;. 0:;:36~**  212612013 7 :49 :00AM 11 .787 7 .054 -0.037 4 .215 11.486

-0.Q15 91.745 2126 / 2013 7 :50:00 AM

### .-:1:.;8.;;**9;;:34,;....-;9".6~8;;:2;.-t.....;-0;;;.O;;:3:,;84-:;9;,:.4;,86;;-....,1;;:8.;;.96;;:9:o-1h-0;;; ,,036;,;-+;2,,3:;:8::;** **96;:,4:-,** THC 

### PPM 4 .056 N2INOx Mode ;02lC02/CO Ca l Zero 0 . 962 1.44 N 21NO Mode 1.445 02/C02/CO Cal High 2126/2013 7 :51:00 AM**L...,1.;;8'i 9~5;;2_...,9".6::;8;;;2~**  3.818 9.552 18. 997 3.675 240.491 2126/20137:52:00AM 14178 7138 46 9558 14668 4649 231.023 1.412 2126/2013 7 : 53 :00 AM 101.523 "1-0::" ."98"'7:-1INo/NOx Mode; THC Cal Zero 2126/2013 7 : 54 :00 AM 54 .628 0 . 831 021C021CO M id 212612013 7 : 55 :00AM 36.505 71 .537 NO/ NO Mode 2126/2013 7:56 :00 AM 20.814 2126/2013 7 : 57:00 AM 20 . 832 0.141 2.138 0.361 0.138 -0 .002 0.3 2126/2013 7:58:00 AM 20.844 0.137 2.839 0 . 297 2126/2013 7 : 59 :00 AM 20 . 853 0 . 138 3.465 0 . 287 2126 / 2013 8 :00 :00 AM 20.875 0 . 138 0 .798 0.29 212612013 8 :01 :00 AM 20 .889 0.137 -0 .027 0 . 295 2126/2013 8 :02 :00 AM 20.892 0.138 3 . 665 0 . 288 0.067 2204 0.047 I -0 . 027 0 . 043 2 . 936 0 . 051 I 3 .495 0 .719 0 . 933 0 . 061 -0 .033 0 . 042 27.323 52.983 89727 132.268 90.121 N02/NO Mode 132.565 I 85.076 CO Mid 80.615 I 84 .574 IN021NOx Mode; THC Cal H igh 1 . 304 83 . 8 3.079 54.054 NOx Cal Zero 0 . 308 48 .77 ITHC M id 2/26/2013 8:03:00 AM 20.896 0.137 4 . 595 0.292 0.424 40 .232 41 .91 5 42 .021 1 . 076 50.399 2126/2013 8:04:00 AM 20 . 902 0.136 4.599 0.305 0.046 212612013 8:05:00 AM 20 . 906 0 . 135 2.897 0 . 295 0.042 2126 / 2013 8:06:00 AM 20 . 904 0.136 2.506 0 . 296 4.435 1.223 0.058 27 .915 NO x Cal H igh 26 .633 INOx Inlet Cal High;THC l ow 25 .237 3 . 186 25 . 395 2126/2013 8 :07 :00AM 19.882 0 . 138 2 . 531 0.85 14 . 21 23 .74 49.218 6.529 NOx Mid 2126/2013 8 :08: 00 AM 0 . 556 0.094 0.597 10.782 0 . 879 23.906 1160.917 2.762 NOx Inlet M id 2126/2013 8 :09:00 AM 0 . 155 0.092

-0 . 018 9.955 0.054 6.291 240.738 1.448 2126/2013 8:10 :00AM 0 . 137 0.091 -0 . 032 9 .664 0.044 0 . 153 1240 .7641 1 .446 CO bias 212612013 8 : 11 :00AM 3 . 304 1.99 -0.03 9.158 4.177 0 . 122 234 . 617 1.425 2126/2013 8:12 :00 AM .-:1,;:8,;; .8;;:6:;.8_-i9"
.6:;;2,,1,.-.....;-0,. .0:;;3;,:3..., 1.013 .....,1;,:;8:;; . 9.,3;--:;0.:;:09,;;8;-, 41.785 0.941 2126/2013 8 : 13 :00 AM 

# 1 ..**_1;.8;i.9:':5;-7_-i9~.6;.,4;:;7_....,-::'-0.i:03i--'** -0 . 387

### ~1;;,8.;i;97ii7_-i:0**,,:08~4::-,** -0.34 0 .682 021C02 bias 2/26/2013 8:14 :00 AM 7 .544 3.631 2.61 -0 .2 73 8.249 21 . 112 -0 .22 0.789 2/26/2013 8: 15:00 AM 1..-0'" .;.15,;,9:-.....;0"'.1'"0;,;9--;4:; . 5::,4"9-..;,0.;;0;;,31::-.....;0;;.0;;7;;2:..-...:;4"'1. "58;,;2;;-....,0;;.06;;....., 0 . 651 NOx b i as 2126/2013 8:16:00AM 14 . 02 0.124 1.607 0 .1 89 9 . 861 31 .05 20 . 017 2126 / 2013 8 : 17 :00AM 20 .852 0 . 13 0 . 003 0 . 282 14.19 25 . 285 57 . 163 2126 / 20 1 3 8 : 18 :00 AM 20.868 0.129 -0 .008 0.276 14 . 207 25 . 352 57.461 2/26/2013 8:19:00AM 20.871 0.127

-0.011 0 .265 14.204 25.435 57 . 287 2/26/2013 8:20:00 AM 20.864 0 . 127 -0 .012 0.285 14.208 25.495 57 .097 2126/2013 8:21 :00 AM 20 . 875 0.127 0.001 0.29 14 .213 25 .536 56.988 212612013 8 : 22:00 AM 20 . 867 0.135 -0 . 017 0.304 14.223 25 .521 57 . 089 212612013 8 : 23:00 AM 20 . 866 0 . 135 -0 . 014 0 . 282 14.213 25 .682 56 .649 2126/2013 8 : 24:00 AM 15 . 001 3.525 1 . 371 0 . 384 14.225 25 .788 55.488 2126/2013 8 : 25:00 AM 14 . 222 3 . 897 1.549 0.552 14.217 25.743 56.129 2126/2013 8 : 26:00 AM 14 . 226 3.895 1.696 0.512 14.23 26.499 53.319 2126/2013 8 : 27 :00 AM 14.217 3.901 1.718 0.458 14 .215 26.644 48.031 212612013 8 : 28 :00 AM 14 . 211 3 . 903 1.551 0 .541 14.211 25 .842 54 .798 212612013 8 : 29 :00 AM 14 . 214 3 . 903 1 .728 0.551 14.208 25 .902 55.262 212612013 8 : 30:00AM 14.205 3.904 1 .789 0.541 14.208 25.961 55.059 2126/2013 8 : 31 :00AM 14.211 3.9 1.789 0 . 52 14.21 25.975 54.795 2126/2013 8:32:00 AM 14.208 3 . 901 1 .793 0.547 14.208 25 . 974 54.967 2/26/2013 8:33:00 AM 14 .203 3.902 1 . 834 0 . 544 14.208 26 . 055 54.372 212612013 8:34:00AM 14 . 214 3.894 1 . 84 0 . 542 14 . 207 26 . 033 54.419 2126/2013 8:35:00 AM 14.216 3.888 1.873 0 .524 14 . 217 26 . 111 53.975 2126/2013 8 : 36:00AM 14 .215 3.888 2 . 065 0 . 522 14 .208 26 . 08 54.076 2/26/2013 8:37:00 AM 14 .201 3.89 2.188 0.52 14.208 26.17 53.632 2126/2013 8 : 38:00AM 14.214 3.879 2.071 0.506 14 . 208 26.173 53.644 2126/2013 8 : 39:00 AM 14 . 199 3.883 2 . 11 0.513 14.208 26.297 53.477 2126 / 2013 8 :40:00AM 14.2 3.88 2 . 146 0.515 14 . 208 26 . 307 53 . 042 212612013 8 :41 :00AM 14.212 3 . 87 1 2 . 329 0.494 14.208 26 . 223 53 .658 2/26 /2013 8 :42:00AM 14 . 206 3 .87 2 . 365 0.481 14.208 26.182 53.502 2126/2013 8 :43:00 AM 14 . 183 3.874 2.38 0.496 14.196 26 . 191 53 . 144 2126/2013 8:44:00AM 14.185 3.872 2.471 0.478 14.193 26 . 25 52 .732 2126/2013 8:45 :00AM 14. 179 3.871 2.511 0.479 14 . 194 26 . 313 52.189 2126120 13 8:46 :00AM 16.714 2.426 1.33 1 0.375 14.179 26 . 386 51 .679 2126/2013 8 :47:00 AM 14 . 169 3.881 1.757 0.332 14.178 26 .516 51 . 069 1 . 659 3 .957 3.959 3.901 3 . 874 3 . 874 3 . 893 3 . 858 3 . 662 3 .727 3.522 2 . 932 3 .612 3 .688 3.68 Start 50% PM /CO MP 3.638 3.641 3 . 61 3 .627 3 . 559 3 . 569 3.591 3.517 3.47 3 .444 3 . 571 3 . 591 3.568 3.487 3 .428 3 . 316 3.285Date Time 212612013 8 :48 :00 AM 212612013 8 :49 :00 AM 212612013 8 : 50 :00 AM 2126/2013 8:51 :00 AM 2126/2013 8:52 :00 AM 2126/2013 8 : 53 :00 AM 2126/2013 8 : 54 :00 AM 2126/2013 8 : 55 :00 AM 212612013 8 : 56 :00 AM 2126/2013 8:57 :00 AM 2126/2013 8 : 58:00 AM 2126/2013 8 : 59 :00 AM 212612013 9 :00 :00 AM 2126120 13 9 :01 :00 AM 2126/2013 9 :02 :00 AM 2126/2013 9 :03:00 AM 2126/2013 9 :04:00 AM 2126120 1 3 9:05:00 AM 212 612 013 9 :06 :00 AM 2126/2013 9 :07:00 AM 2126/2013 9 :0 8:00 AM 2126/2013 9:09:00 AM 2126/2013 9 : 10:00 AM 2126/2013 9: 11 :00 AM 212612013 9:12:00 AM 212612013 9: 13:00 AM 2126/20 1 3 9:14:00AM 2126/2013 9:15:00AM 2126/2013 9:16:00AM 2126/2013 9:17 :00 AM 2126/2013 9 : 18 :00 AM 212612013 9 : 19:00 AM 2126/2013 9:20:00 AM 2126/2013 9 : 21 :00 AM 212612013 9 : 22 :00 AM 2126/2013 9 : 23 :00 AM 212612 0 13 9 : 24 :00 AM 2126/2013 9:25:00 AM 212612013 9 : 26 :00 AM 212612013 9 : 27 :00 AM 2126/2013 9 : 28 :00 AM 212612013 9 : 29 :00 AM 212612013 9 : 30 :00 AM 2126/2013 9 : 31 :00 AM 2126/2013 9:32:00 AM 2126/2013 9 : 33:00 AM 212612013 9 : 34:00 AM 212612013 9:35:00AM 

### O 2 

### % 14.147 14 .1 45 14 . 148 14 . 143 14 . 132 14.127 14 . 123 14.099 14 . 098 14 . 108 14 . 107 14 . 091 14 .092 14 . 079 14.08 3 18 . 803 14 . 183 14.12 14 .1 07 14 . 095 14 . 102

14.1 14.095 14 . 097 14 . 089 14 . 095 14 . 093 14 . 093 14 . 089 14.096 14 . 103 14.1 17 .5 61 14.178 14 . 111 14. 11 9 14 .12 14.122 14.123 14 .1 19 14 . 106 14.106 14 . 102 14.102 14 . 1 14 . 107 14 . 104 14 .1 07 CO 2 

### % NO, CO PPM PPM 3.887 1.828 0 . 374 3 . 887 1.688 0 . 378 3 . 883 1.735 0.364 3.885 1.768 0.337 3.89 1.964 0.345 3.893 1.751 0.3 3 . 896 1 .704 0 .286 3.91 1.779 0.271 3.911 1.819 0.241 3.905 1.907 0.259 3.907 1 .883 0.231 3 .919 1 . 961 0 .237 3.915 1.63 0.283 3.925 1 .654 0.316 3.921 1.688 0 . 36 1.205 0.512 0.311 3 . 892 1.76 0 . 531 3 . 899 1.748 0 . 624 3 . 905 1.739 0 .63 3.912 1 .723 0.647 3 . 91 1 .744 0.636 3.912 1.826 0 . 642 3.912 1 . 82 0 . 639 3 . 911 1 . 79 0.62 3.916 1.842 0.62 3.913 1 . 825 0 .628 3.9 16 1 .731 0 . 662 3.916 1.674 0 . 674 3.917 1.708 0.705 3.914 1.691 0 .68 3 . 91 1 .696 0 .69 1 3 . 912 1 .763 0.674 1.906 0.889 0.52 3.897 2.42 0.485 3.904 2 . 33 0 . 585 3.901 2 .292 0.591 3 . 902 2 .2 98 0 . 597 3 . 899 2.274 0.581 3.899 2.295 0.578 3.901 2.358 0.572 3.907 2 .601 0 .557 3.909 2 .567 0 .579 3 . 912 2.595 0 . 574 3.912 2.542 0.576 3 . 913 2.539 0.581 3 . 91 2.725 0.531 3.912 2.84 0.537 3 . 912 2.773 0 .5 3 212612013 9 : 36 :00AM 14 . 099 3.915 2 .825 0 .555 212612013 9 :3 7:00 AM 14 . 102 3.914 2.828 0.566 2126/2013 9 : 38:00 AM 16 . 066 6.961 1.28 0.226 2126/2013 9:39:00 AM

## '"!""1~8"i**84~6~-i:9"i.6~36i--_-ii0'i: 0:-1** -, -0.4 

### O 2 

### % 14.17 14.165 14.179 14.162 14.165 14.161 14 . 154 14 . 134 14 . 124 14.145 14.147 14 . 13 14.128 14.109 14.126 14.122 14.139 14.141 14.134 14 . 117 14.125 14.125 14.121 14.116 14 .1 11 14.119 14 .1 2 14.117 14 . 115 14.128 14.132 14 . 125 14.123 14.121 14.122 14 . 133 14.13 14.133 14 . 138 14 . 133 14.121 14.126 14.113 14.117 14.113 14 . 125 14.111 14 . 11 NO, PPM 26.468 26 . 513 26 .651 26 .757 26 . 861 27.023 27 .269 27.476 27.805 27.872 28 .031 27 . 842 26.933 26.422 26.148 26 . 121 26 . 038 26 . 039 25.99 8 26 . 038 26 . 039 26 . 012 26 . 04 26 . 039 26 . 091 26 . 059 26 . 034 26.072 26 . 044 26 . 016 26.026 26 . 078 26 . 051 26.016 26 . 025 25 . 996 26 .02 25 . 986 26.024 26 . 043 26 .097 26.055 26 .08 26.056 26.033 26.04 26.025 26 .004 CO PPM 50 . 903 51.299 50 . 379 49.824 49.405 48.783 47 .667 46.625 45 . 339 44.517 44.401 44.088 47 . 536 50.461 52.456 52.863 53.326 53 .54 53.496 53 .654 53.328 53.47 53 . 392 53.327 52.996 53.063 53 .025 53.076 53 . 122 53 . 347 53.36 53 .054 52.9 53.163 53 .234 53.44 53.319 53.621 53.18 53.329 52 .986 52 . 921 52 .752 52.974 53.323 53 .032 52.975 53.404 14 . 108 25 . 948 53.415 14.112 25.904 54 .118 16.083 14.593 42.392 18 . 875 0 .58 0.971 THC PPM 3 . 274 3 .3 68 3 . 232 3 . 151 3 . 059 3 .02 2 . 939 2 .757 2.695 2 . 601 2 . 638 2.547 2 . 854 3 . 175 3 . 362 3.45 4 3.501 3 .621 3 . 529 3 .5 9 3.554 3.605 3 . 586 3.378 3.444 3.521 3.586 3.547 3 .52 3 .618 3 .6 14 3 . 608 3.551 3.61 3 .6 32 3 .646 3 .634 3.625 3.588 3 . 599 3.566 2 . 997 3.43 3.443 3.486 3.437 3.422 3.459 3.517 3 . 522 3.278 0 .665 02lC02 bias 2126/2013 9:40:00AM 5 . 148 2.398 3 . 254 -0 . 241 5.537 26 .578 -0 . 014 0 .709 2126/20 13 9 :41 :00 AM 

### '"!....;:,0 . "1'"52 ..... -0;;..;,1

## 0;;;8:--.....;4~**;::57:,;--.,;0;;; 04;.:9,.....-;;.0** **"07:;;1:-....:;4:;;1**'i:
.84

.;,9

..... ....,0:;,.0"56:,;...-.;; 0;.;.6:::52 ;:...,!NOXbias 2126/2013 9 :42:00AM 0 . 14 0.099 2 . 002 3.403 0 . 192 20.387 56.906 0 . 883 2126/2013 9:43:00 AM 0.137 0.095 -0.017 9.461 0.044 0 . 368 237.799 1.434 2126/2013 9:44:00 AM 0 . 137 0.093 -0 .017 9 . 649 0.044 0.278 ! 

### 241.362! 1.446 CO bias 212612013 9 :45 :00AM 13.36 6 . 836 2 . 69 9.611 14.316 31 . 067 238.414 2 . 345 212612013 9 :46 :00 AM

## '"!"'1:':8~**9"09~-"'9;;' 6"'5;;8:---"'4;::.6;;;04"""-';;9;';** **5"'78;'---:1;';8;;.9;;'2;;'9-":;4"'1.'i:**

# 94**';'4;-"';2;'4;;1" 6"'78';"!**  28 .791 Di re ct Span 2126 1 2013 9 :47 : ooAM 7.434 2 . 857 1.484 3 . 949 4.799 10 . 541 133.921 45 . 233 2126/2013 9 :48 :00 

## AM! 0.128 0.07 -0.018 0 . 054 0 . 049 0 . 038 0 . 545 45 . 165 !Direct Zero; THC MidDate Time 212612013 9:49 :00 AM 212612013 9 : 50:00 AM 212612013 9 : 51 :00 AM 2126/2013 9 : 52:00 AM 2126/2013 9 : 53 :00 AM 2/26 / 2013 9 : 54:00 AM 212612013 9 : 55 :00 AM 21 2612013 9 : 56:00 AM 2126 / 2013 9 : 57 :00 AM 2126/2013 9 : 58 :00 AM 

### 0, % 11 . 323 14 .089 14 . 088 14 . 086 14 . 083 14 . 092 14 .096 14 .076 14 . 051 14.066 2126/2013 9 : 59:00 AM 14 . 057 2 / 26

/ 2013 10 :00 :00AM 14.069 2126120 1 3 10 :01 :00 AM 14 . 077 212612013 10 :02 :ooAM 14 . 062 2126/201310 :03:ooAM 14 . 057 2126/2013 10:04:00 AM 14.04 2126/2013 10:05:ooAM 14.049 2126 / 2013 10 :06 : ooAM 14 . 058 21261201310 :07:ooAM 14.059 21261201310 :08:ooAM 14 .056 2126/2013 10 :09:ooAM 14 . 073 2126/2013 10:10:00AM 14.083 2126/2013 10:11:00AM 14 . 067 2 / 26

/ 2013 10 : 12 : ooAM 14 .072 21261201310 : 13 : ooAM 14 .091 2126/201310 : 14:ooAM 14 . 067 2126/2013 10:15:00AM 14 . 088 2126/2013 10:16:00AM 17 . 256 2126/2013 10:17 :00AM 14.079 212612013 10 : 18 :00AM 14 . 058 2126/201310 : 19 :ooAM 14 . 059 2126/201310 : 20:00AM 14 . 054 2126/201310 : 21:00AM 14 . 042 2126/201310 : 22:00AM 14 . 038 2126/201310 : 23:00AM 14 . 04 2126/201310 : 24 :00AM 14 .04 2126/201310 : 25 :ooAM 14 . 041 2126 / 2013 10 : 26:ooAM 14 . 037 2126/201310:27:00AM 14 . 04 2126/201310:28:00AM 14 . 026 2126 / 2013 10:29 :00AM 14 . 033 2126 / 2013 10 : 30 :00 AM 14 . 032 2126/201310 : 31:ooAM 14 . 026 2126/201310:32:ooAM 14 . 038 2126/2013 10 : 33:00AM 14 . 038 2126/2013 10 : 34 :00AM 15 .775 2 / 26

/ 2013 10 : 35 : ooAM 15 . 031 21261201310 : 36 : ooAM 14 .08 2126/201310 : 37 : ooAM 14 . 056 2126/2013 10:38 :00AM 14.061 2126/2013 10:39 :00AM 14 . 072 2126/2013 10:40 : ooAM 14 . 074 212612013 10 :41 : ooAM 14 .061 212612013 10 :42 :00 AM 14 .075 21261201310 :43 :00AM 14 . 089 2126/201310:44 :00AM 14 . 088 2/26/2013 10:45 :00AM 14 . 078 2/26/2013 10 :46:00 AM 14.088 212612013 10 :47 :00 AM 14 .087 212612013 10 :48 :00 AM 14 . 089 2126/201310 :49 :00AM 14 . 087 

## co, % 3.216 3 . 926 3 . 932 3 . 938 3.938 3 . 929 3 . 927 3 . 937 3 . 945 3.939 3 . 943 3.938 3 . 936 3 . 941 3 . 945 3.954 3.954 3.948 3 . 947 3 . 949 3.942 3.942 3 . 949 3.949 3 . 941 3 . 955 3.943 2.124 3.954 3 . 965 3 . 964 3 . 968 3 . 976 3.98 3 . 983 3 . 982 3 . 982 3 . 987 3 . 988 3.994 3.993 3 . 997

4 3.994 3.995 3.001 3.43 3 . 978 3.99 3.988 3.984 3.984 3 . 99 3 .986 3.979 3.977 3.98 3.973 3 .973 3 . 969 3.968 NO, PPM 1 . 571 2 . 18 2 . 319 2 . 227 2 . 202 2 . 17 2 . 192 2 . 393 2 . 386 2 . 284 2 . 264 2 . 263 2 . 313 2 . 286 2 . 317 2.28 2 . 199 2 . 359 2 . 591 2 . 553 2 . 562 2.459 2 . 566 2 . 564 2 .7 2 . 831 2 .701 1 . 263 1 . 893 1.858 1 . 807 1 . 947 1.989 1 . 952 1 . 925 1 . 88 1 . 834 1 . 848 1 . 815 1 . 957 2 . 022 2 . 037 1 . 952 1 . 852 1 . 864 1 . 575 1.964 2.418 2 . 507 2 . 382 2 . 276 2 . 294 2 . 36 2.429 2 . 588 2.59 2.611 2.603 2 .725 2 .9 2 .762 

### CO PPM 0 . 193 0 . 597 0 .594 0.619 0 .627 0 . 596 0 . 58 0 . 628 0 . 62 0.666 0 . 656 0 . 634 0 . 622 0.721 0 .677 0.655 0 . 633 0 . 621 0 . 608 0 .637 0.607 0.595 0 .595 0 . 607 0 . 552 0.559 0.581 0.383 0.43 0.447 0.406 0.438 0.445 0.429 0 .421 0.454 0.353 0.339 0.322 0 . 288 0 . 302 0 . 343 0.327 0.287 0 .322 0 . 312 0 .408 0 . 582 0 .574 0.577 0.557 0 . 568 0 . 581 0 . 565 0 . 551 0 .548 0 . 559 0 . 542 0 . 548 0 . 52 0 .494 

### 0, % 2 .981 14 . 022 5 . 972 0.061 0.043 0.043 0 .043 0 .043 0 . 043 0.043 NO, PPM 3.427 25 . 31 12.844 0 . 293 0.23 0 . 197 0 . 165 0 . 148 0 . 131 0 . 114 

### CO PPM 1.914 45 . 264 42 . 25 1.46 0.279 0.281 0.279 0 .278 0.276 0.273 

## THe PPM 44 .669 14 . 026 9 . 845 44 . 354 44 . 981 45 . 507 45 . 687 45 . 821 45 .936 

## !THe Mid 45.86 8.805 14 . 02 16.019 37 . 918 14 .034 25 .274 54 .292 4 .097 Start 50% COMP 14 . 052 25 .316 55 . 364 3 .952 14 .044 14.039 14.035 14.035 14 . 037 14 . 038 14 .041 14.055 14.059 14.058 14 . 056 14 .062 14.044 14.059 14.041 14 .045 14.034 14 .039 14 .034 14.02 14.011 14 .013 14.016 14 . 03 14 .015 14.014 13.989 14 .009 14.001 13.991 14.006 25 . 369 56.202 25.549 55.571 25 .709 54.178 25.792 54.498 25 .834 53.178 25 .875 52 . 678 25 . 925 52.567 25 . 999 51.727 25 . 846 52.463 25 .848 52.853 25 .887 52 . 603 25 .835 53.211 25 .881 52 .765 25 . 812 54.297 25 . 868 54.532 25 . 92 53.301 25.915 53.632 25 .92 53 . 316 26 . 011 52.383 25.997 52.894 26 . 008 52.165 25 . 986 51.964 25 . 898 53 . 23 25 .934 53 . 279 25 . 942 53.32 25.958 52.914 26 . 094 51 .824 26 .054 52.129 26 .087 52.209 26 . 082 51.881 26 . 009 51 . 848 14.007 25 . 986 52.28 13.997 25.967 52.253 14 .004 26 .015 52 .011 14 . 03 25 .915 52.513 14.004 25.992 52.359 14 .02 25 . 876 52 . 895 14.029 25.838 53.538 14 .028 25 . 895 52 . 921 14 . 01 25.965 52.318 14 .028 25 .903 52.544 14.034 25 . 914 52.46 14 .033 25 . 902 52.459 14.026 25.917 53.233 14 . 035 25 .915 53 . 047 14 . 034 25 .932 52.77 14.036 25 .927 52.998 14.031 25 .94 52.075 4.024 4.04 3.686 4.046 3.577 3.48 3.509 3 . 298 3.433 3 . 504 3 .446 3.471 3 . 37 3 .664 3 . 923 3.59 3 .732 3 .649 3.46 3 . 556 3 . 388 3 . 322 3 .607 3 .684 3 . 263 3.464 3 .27 3 . 348 3.454 3 . 383 3 . 309 3 . 361 3 . 385 3 . 343 3 . 352 3.416 3 . 551 3.59 3 . 393 3 . 013 2 .718 3 . 108 3 . 219 3 . 627 3 . 515 3.403 3 . 548 3 . 243Date Time 

### 0, % CO, 

### % 2126 / 2013 10 : 50 :00AM 14.091 3 . 964 212612013 10 :51 :00 AM 14 . 089 3 . 967 2126 / 2013 10 : 52 :00AM 14 . 065 3 . 981 2126/2013 10:53 :00 AM 17.444 2 . 041 2126/2013 10:54:00AM 14 . 075 3.986 212612013 10:55:00AM 14 . 069 3 . 986 212612013 10 : 56:00 AM 14 . 057 3.994 212612013 10 : 57 :00AM 14 . 063 3 . 993 2126 1 2013 10:58:00AM 14 .074 3 . 991 212612013 10 :59:00AM 14 . 059 3.998 212612013 11 :00:00 AM 14.085 3.99 212612013 11 :01:00AM 14.081 3 . 995 2126 1 2013 11 :02:00AM 14 . 083 3 . 993 2126 1 2013 11 :03 :00 AM 14 . 088 3 . 995 212612013 11 :04:00 AM 14 . 089 3.993 2126/2013 11:05:00AM 14.085 4 .001 NO, PPM 2.894 2 .921 2.937 1.341 2.349 2.319 2 . 331 2 . 368 2 . 357 2.327 2.525 2 . 658 2 . 572 2.664 2 .656 2.691 CO PPM 0.476 0.489 0.491 0 . 318 0.462 0.536 0 .515 0 . 531 0 . 533 0.518 0.516 0.486 0.504 0 .485 0.495 0.479 O 2**NO~** CO 

### % 

### PPM PPM 14 . 037 26 . 009 51 . 393 14 . 031 26 . 031 51.119 14 . 01 26 .095 50 . 237 14 .002 26.069 50.1

14 26.039 50 . 122 14 . 016 26.03 50.096 14 . 004 26 . 058 49.941 14 . 01 26 .011 50 . 829 14.024 26.067 50.033 14.009 26 .061 49.976 14.023 26.066 49 .9 26 14 . 02 26 . 066 49 .799 14 . 024 26 . 05 50 . 1 1 14 .03 26 . 106 49 . 595 14.034 26.014 50.111 14 .025 26 . 05 50.318 212612013 11 :06:00 AM 14 .082 4 . 001 2 .711 0 .51 14 .024 26 . 109 50 . 881 212612013 11 :07:00 AM 14 . 084 4 . 006 2.941 0 . 5 14.017 26 . 065 50.857 212612013 11 :08 :00AM 14 . 083 4 .004 2 . 866 0.538 14 .023 26 . 07 50 . 118 212612013 11 :09:00 AM 14 . 085 4 . 006 2 .771 0 . 501 14 .022 26 .045 50.128 212612013 11 : 10 :00 AM 17 . 135 8.308 0.597 0 . 304 16.935 8.545 38.073 212612013 11:11:00AM'"1

## ~18~.8:::3~~9~.7;':3:i9:--:-0;".0;f,0~8;--' -0.447 18.752 0.542 0 . 333 212612013 11 : 12:00AM 9.636 4 .958 2.088 -0 . 36 10.536 15 . 036 -0.175 

### THC PPM 3.035 3 . 135 3 .021 3 . 024 3.03 3.038 2 . 961 3 . 177 2 .994 2 .841 2.974 2.97 3 .01 2 .992 3 . 02 3 .013 3 . 338 3 . 386 3 . 086 3.062 2 .238 0.654 

### 02/C02 bias 0 . 675 2126/2013 11 : 13:00 AM LI

## ~0**-:,15:::8:-~0~ ~18;:;1:-~4:,:** **.5::5-::8 _--:,-0:,:.0::;:2::,2** __

## 0:,:,.::08:-:3:--:;4:;,1**::50~5:--;;'0;' .0:i'56:,;-_-:0-:.6;:57,-,** **INOX** bias 21261201311 : 14 :00AM 0 . 138 0 . 166 1.0 18 5.437 0.214 13 .254 97 . 513 1 . 01 2126 1 2013 11 : 15 :00 AM 0 . 127 0.161 -0.017 9 . 553 0.044 0 . 312 240.052 1 .444 21261201311:16 :00AM 0 . 112 0.158 -0 .019 9 .615 0 . 044 0 . 242 1240.6961 1.444 CO bias 21261201311:17:00AM 14 . 579 6 . 516 2.813 9.597 14.71 30.079 236 . 998 2.368 2126/2013 11 : 18:00 AM 

### '"1""1;';8:': .8"'7"'4-""9"' . 7;;,54;;;--..;4;:.;.5;;94;;....-.;;9;; . 5.;;95 .....

## ~1i::8;;,.8;"75,,........;;4.,.1 .';;88"'6;--:2"'4';;0';; .6';;22;;"1 26.528 Direct Span 212612013 11:19 : ooAM 8 . 11 3 .397 1 .752 4 .21 5.79 12 . 342 141 .69 44 . 863 212612013 11 :20 :00 

### AMI 0 . 127 0.133 -0 .013 0 . 037 0 . 048 0 . 036 1 . 131 44 .882 Di rect Zero 212612013 11 : 21 :00AM 13.484 0 . 176 1.355 3 . 03 5.294 11 . 246 29.783 45.206 212612013 11 :22:00 AM 20 . 669 0.197 2.493 7 . 277 9.954 23.815 91.666 45 .585 212612013 11 :23 :00 AM 20 . 692 0.195 2.548 4 .745 9 . 962 23 .796 68.275 42 . 218 NOX/02 Direct Mid 212612013 11 : 24:00 AM 18 . 886 1 . 337 1.422 4.339 4 . 878 12 . 975 131 . 055 1.211 2126 1 2013 11 : 25 : ooAM 14 . 106 3 . 989 2 .636 4 . 513 0 . 053 0 . 189 1 1 32 .6631 1.087 212612013 11 : 26 :00 AM 14 . 088 3 .993 2 . 554 3 . 053 0.444 1 . 075 97.408 32 .528 21261201311:27 :00AM 14 . 073 4.005 2.588 0.55 0 . 042 0 . 13 1.594 78.425 212612013 11:28 :00AM 14.064 4 .007 2.614 0.531 212612013 11 :29:00 AM 14 . 065 4.008 2.599 0 . 538 212612013 11 :30:00 AM 14 . 087 4.001 2 .513 0.533 212612013 11 : 31 :00 AM 14.08 1 4 . 005 2 . 505 0 . 539 21261201311 : 32:00AM 14 . 057 4.014 2.715 0 . 53 212612013 11 :33 :00 AM 14 . 068 4.01 2.673 0 .538 21261201311:34 :00AM 14.059 4.014 2.652 0 . 532 2126/2013 11 :3 5:00 AM 14 . 067 4 .01 2.619 0 . 546 212612013 11 : 36 :00 AM 14 . 065 4.011 2 .653 0.55 212612013 11 : 37 :00 AM 14 . 047 4.019 2 .648 0 . 508 212612013 11 :3 8 :00 AM 14 . 071 4.011 2.624 0 . 518 212612013 11 :39 :00 AM 14 . 071 4 . 011 2.65 0 . 512 2126/2013 11 :40 :00 AM 14.052 4.019 2.596 0 . 521 212612013 11:41:00AM 14.052 4.017 2.642 0 . 528 212612013 11 :42:00 AM 14 . 049 4.019 2 . 567 0 . 525 2126 1 2013 11 :43 :00 AM 14.05 4 .02 2.601 0 .52 5 212612013 11 :44 :00 AM 14.054 4.015 2.578 0 . 546 212612013 11 :45 :00 AM 14.063 4 .0 13 2.616 0.498 212612013 11 :46:00AM 14.069 4.008 2.522 0 . 525 2126/2013 11 :47:00 AM 14 . 067 4 . 009 2 .532 0.491 2126 1 2013 11 :48 :00AM 14.065 4.007 2 . 526 0 .48 1 2126/2013 11 :49 :00 AM 14.075 4.004 2 .592 0 . 506 212612013 11 : 50:00AM 14.053 4.009 2.583 0.501 0 . 042 0.11 -0.029 0 . 042 0 . 091 -0.03 0.302 0 . 205 -0.027 0 .298 1 . 173 2 . 648 0.042 0 . 07 0.271 0.042 0.066 0 . 25 10.011 16.186 19.143 14.006 25.554 51.032 14 .019 25 .693 5 1. 085 14.006 25 .81 51 . 079 14.028 25.87 50.57 14.03 25.921 50.226 14.017 25.96 50.384 14.018 25.992 50.144 14.011 26 . 013 50.025 14 . 017 26 . 031 50.245 14 . 018 26 . 081 50 . 091 14.032 26.083 49.626 14.034 26 . 066 49.629 14.033 26 .05 49 .745 14.034 26 . 063 49.886 14.037 26 . 077 49.595 14.026 26.15 49 .302 78.845 81 .284 84 . 144 62 .061 49 . 039 48.875 35.516 3 . 985 3 .702 3 .687 3 .462 3.283 3.33 3.246 3 . 232 3 . 355 3 . 322 3.226 3 . 2 3 . 215 3 .21 3 . 164 3 . 078 CO D i rect M idDate Time 

### 0, % 2126/20131151:00AM 14.055 2126/201311:52 :00AM 14.048 2/26/2013 11 :53:00 AM 14.046 2126/2013 11:54 :00 AM 14.037 2126/2013 11 :55:00 AM 14 .036 2126/201311:56:00AM 14.029 2126 / 2013 11 :57:00 AM 14 .031 2126 / 2013 11 : 58 :00 AM 14.028 2126/2013 11 : 59 :00 AM 14 .03 2126/2013 12:00:00 PM 14.026 2126/2013 12:01 :00 PM 14.025 2126/2013 12 :02 :00 PM 14 . 024 2126/2013 12:03 :00 PM 14.028 2126/2013 12:04 :00 PM 14 . 03 212612013 12 :05 :00 PM 14 .029 212612013 12 :06 :00 PM 14 .021 2 / 26

/ 2013 12 :07 :00 PM 14 . 024 2126/2013 12:08 :00 PM 14.018 2/26/2013 12:09 :00 PM 14 . 025 2126/2013 12:10 :00 PM 14.024 2126/2013 12:11 :00 PM 14 .016 212612013 12:12:00 PM 14.013 2126/2013 12 : 13 :00 PM 14 .026 2126/2013 12 : 14 :00 PM 14 .0 13 2126/2013 12 : 15 :00 PM 14.012 2126/2013 12 : 16:00 PM 14.013 2/26/2013 12 : 17 :00 PM 14 . 023 2/26/2013 12:18 :00 PM 14.017 2/26/2013 12:19 :00 PM 14 . 022 2126/2013 12 : 20 :00 PM 14.051 2126 / 2013 12 : 21 :00 PM 14 . 061 212612013 12:22:00 PM 14.055 212612013 12:23:00 PM 14 .05 2126/2013 12 : 24:00 PM 14 . 054 2126/2013 12 : 25:00 PM 14 . 055 2/26/2013 12:26 :00 PM 14 . 073 2/26/2013 12:27:00 PM 14 . 085 2/26/2013 12:28 :00 PM 14.098 2126/201312:29:00PM 14 . 11 212612013 12 : 30 :00 PM 14.106 212612013 12 : 31 :00 PM 14.108 212612013 12 : 32 :00 PM 14.109 2126/2013 12 : 33 :00 PM 14 . 118 2/26/2013 12 : 34:00 PM 14 . 118 2126/2013 12:35 :00 PM 14.109 2126/2013 12:36:00 PM 14 . 108 2126/2013 12 : 37 :00 PM 14 . 107 2126/2013 12 : 38:00 PM 14 .9 39 2 / 26

/ 2013 12 :3 9 :00 PM 18 . 841 2126/2013 12 :40 :00 PM 7.485 2126/2013 12:41 :00 PM 0.149 2126/2013 12:42 :00 PM 0 . 12 2/26/201312:43:00PM 0.112 2126/2013 12:44:00 PM 10 . 958 2/26/2013 12 :45:00 PM 18 . 896 2126/2013 12 :46 :00 PM 1 2 .772 2126/2013 12 :47 :00 PM 10 . 02 212612013 12 :48 :00 PM 10 .0 27 

## co , % 4.004 4.006 3 . 998

4 3 . 999 3 . 997 3.994 3 . 994 3 . 993 3.994 3.995 3.997 3.995 3 . 995 3 . 994 3 . 997 3 . 995

4 4 4.002 4.006 4.012 4.006 4 .014 4 . 017 4 .0 19 4 . 013 4.015 4 . 021 4 . 016 4 . 012 4 . 016 4 . 015 4 . 013 4 . 014 4 . 006 3 . 998 3.99 3 . 983 3 . 987 3 . 987 3 . 989 3.984 3 . 983 3.989 NO
. PPM 2.493 2.606 2.533 2.625 2 .627 2 . 51 2 .525 2.539 2.557 2.433 2 .62 2 . 552 2.435 2.471 2 .524 2.479 2 .456 2.522 2.399

2.4 2.49 2 .512

2 . 5 2 .501 2.611 2 . 526 2 . 386 2.441 2 .549 2 .554 2.52 2.591 2 . 581 2 . 574 2 . 596 2 .54 2.447 2.444 2 . 56 2.638 2 .6 34 2 .56 2.521 2 .508 2.666 

## co PPM 0.476 0.521 0 .509 0.488 0.486 0 .4 67 0 .476 0.487 0.477 0.479 0.463 0.479 0 . 503 0.478 0 . 502 0 .486 0.528 0.509 0.494 0.485 0 .525 0 .494 0 . 505 0.513 0.528 0.535 0 .512 0.497 0 .518 0.503 0.525 0 .509 0 . 505 0.526 0 . 507 0.512 0.531 0 .501 0 .514 0.511 0 .509 0.527 0.508 0.528 0.507 

### 0 , % NO
. PPM 

### CO PPM 14 .028 26.15 49.026 14.016 26.185 48.857 14 . 023 26 . 193 48.705 14.01 26.178 49.562 1 4 .004 26.292 48.511 14 . 002 26 . 255 48 .1 93 14 . 001 26 . 251 48.309

14 26.268 48.087 14 26 . 264 48.024 13.999 26.292 47.915 13 . 992 26 .267 47.732 13.992 26.202 47.903 13.99 26 . 2 48 .033 13 . 998 26.158 48 . 06 13 . 995 26 . 159 48.221 13.991 26.217 47.89 13 . 996 26 . 132 48.246 13.992 26.17 48.576 13.998 26.18 47.937 13.996 26.133 48.152 13 . 986 26 . 167 48 .551 13.985 26.197 48.039 13 . 999 26.102 48 .782 13 .9 9 26.14 48 . 804 13.985 26 . 185 48 . 644 13 .986 26.162 48.65 13 .998 26.127 48.493 19.097 8 .707 29.095 20.418 0 .285 1 .772 20.408 0.207 0.421 20.393 0 . 166 0 . 216 20 . 373 0 . 137 0 . 134 20.368 0.12 0.129 20.358 0.103 0.128 20 . 343 0 . 099 0.127 20 . 343 0.084 0 . 125 20.343 0.083 0.125 20 .34 3 0 .077 0.12 20.343 0 .068 0 . 126 20.343 0.058 0 . 131 20.343 0 .061 0 . 134 20 .32 7 0 .059 0.131 20.299 0 .057 0 . 13 20.293 0 .056 0.132 20.287 0.048 0.127 3.989 2 .685 0.492 20 . 269 0 .045 0 .042 0 . 044 0 . 046 0 . 047 0 .043 0 .044 0.044 0 . 038 0.039 0.046 0 . 035 0 . 043 0 . 126 0 . 126 0.13 0 . 13 0 . 127 0.133 0.131 0.128 0.129 0.135 0 .1 3 0 . 128 0 . 131 3 . 989 2 . 572 0.501 20 . 247 5 . 691 1 .775 0 . 615 20 .2 35 

### '-9"'."'72"'6:---""0 . "'006""''' -0 . 309 20 . 219 3 .754 -0 . 012 -0 . 317 20.203 0.165 -0 . 012 

## o 20.194 0.133 0.424 0.07 20 . 174 0.121 -0 . 006 0.185 20.17 5.943 -0 . 015 0 . 166 20 . 169 9.757 -0.018 0.165 20 .1 48 6 . 591 -0 . 016 0 . 163 20 . 144 5 . 176 -0 .022 0 . 159 20.145 5 . 176 -0 .022 0 . 156 20 . 145 

### THe PPM 3 . 001 3.003 3.035 3.453 3.061 2 .832 2.842 2 . 853 2 .88 2 . 887 2 . 812 2.845 2 . 845 2.904 2 .8 99 2 .862 2.402 2 . 586 2.787 2.867 3 .04 2 . 947 3 . 073 3 . 112 3 . 103 3 . 051 3 . 014 2 . 657 6.053 5 . 339 6.433 3 . 585 2.964 3.209 5 .997 3 . 177 1 . 864 0 . 986 0 .708 0 . 654 0 .6 54 0 .655 0 .656 0 . 652 0.654 0 . 651 0 . 654 0.653 0 .656 02lC02 bias 0 .655 0.653 Zero bias 0.653 0 .653 Direct Zero 0 .653 0 .656 D irect Span 0 .65 5 0 .6 5 M id 0 .653

## Appendix 

## C.3 Ammonia Data by SCAQMD Method 207.1

R521 0729 

## C-l

### AMMONIA TEST RESULTS SUMMARY Client 

### Gemma Parameter 

### Location CPV Sentinel Fuel Unit 5 

### Data By Test Number C PV Sentinel-5-NH3-1 06-1 CPV Sentinel-5-NH3-106-2 

### Reference Temperature , F 60 60 Test Date 2/25/2013 2/25/2013 

### Test Method SCAQMD 207
. 1 SCAQMD 207
. 1 Sample Train 1 - P&M 1-P&M Meter Calibration Factor 1.014 1.014 Stack Area (sq It) 14 3
. 14 143
. 1 4 Sample Time (Min) 60 60 

### Barometr ic Pressure (in Hg) 29.60 29.60 Start Time 11:35 13 :04 Stop T ime 12:43 14:17 Meter Volume (acf) 43 .642 36.161 Meter Temperature (F) 76
. 3 75
. 3 Mete r Pressure (iwg) 1.50 1.50 Liqu id Volume (ml) 99.7 83.2 Stack 02 (%) 13 .54 13
. 50 Sta ck NOx (ppm) 

### @ 15% 02 1
. 70 1.65 Unit Load MW 106 106 Fuel Flow Rale, hsclh 8,746 8,742 Standa rd Sample Volume (SC F) 42 .803 35
. 370 

### Moistu re Fraction 0
. 098 0.099 Stack Flow Rale (dsclm , 60 of) 416,170 393 , 969 Stack Flow Rate (dsclm , 70 of) 

### nla nla Gas Constant (It-Ibl/lb-mole-R) 1545
. 33 1545.33 Standard Press ure (lbfllt2) 2116.224 2116
. 224 Molecu lar Weight NH3 (Ib/lb-mole) 17 17 Spec ilic Molar Volume (lt3/Ib-mole) 379 .50 379
.50 Mass Conversion (Ib/ug) 2.20E-09 2.20E-09 02 Correction Factor (%) 15 15 Mass NH3 (ug/sample) 3995
. 65 3437.99 Mass NH3 (mg) 3
. 996 3.438 Mass NH3 (Ib) 8
. 80E-06 7
. 57E-06 PPM NH 3 (Ilue cas) 4
. 6 4
. 8 PPM NH3_@ 02 Correction 3
. 68 3.81 Ib/hr 5
. 14 5
. 06 Ib/MMscl fuel 5
. 87 5.79
NH3 EQUATIONS: ppm NH3**~** 

### (mass NH3" Gas Const' Ref Temp" 106 )/(Sam p le vol
. "Press' M W) ppm NH3 

### @ 02 correction 

## = ppm' (20
. 9-02 Corr)/(20
. 9-%02) 

### NH3 

### natural gas AA, MC, RM , JM Averace 

### Lim it

13
. 52 1.68

4.7 3.75 5 5
. 10 5
. 8330

### AMMONIA TEST RESULTS SUMMARY Client Gemma Parameter Location 

### CPV Sentinel Fuel Unit 5 Data By Test Number CPV Sentinel-5-NH3-81-1 CPV Sentinel-5-NH3-80-2 Reference Temperature , F 

### 60 60 Test Date 2/25/2013 2/25/2013 Test Method SCAOMD 207.1 SCAOMD 207
. 1 Sample Train 1-P&M 1-P&M Meter Calibration Factor 1 .01 4 1.014 Stack Area (sq ft) 143.14 143
. 14 Sample Time (M in ) 60 60 Barometric Pressure (in Hg) 

### 29.60 29 .60 Start Time 16:42 18 : 07 Stop T ime 17:48 19 : 14 Meter Vo lume (act) 36
. 365 34
. 041 Meter Temperature (F) 70.8 66.4 Meter Pressure (iwg) 1
. 50 1.50 Liquid Volume (ml) 69.3 76.6 Stack 02 (%) 13
. 98 14
. 04 Stack NOx (ppm) 

### @ 15% 02 1 .33 1 .75 Unit Load MW 81 80 Fuel Flow Rate, hscfh 7,078 7,085 Standard Sample Volume (SCF) 35
. 871 33.858 

### Moisture Fraction 0
. 082 0.095 Stack Flow Rate (dscfm , 60 of) 349,945 332 , 898 Stack Flow Rate (dscfm, 70 of) n/a n/a Gas Constant (ft-Ibfllb-mole-R) 1545.33 1 545 .33 Standard Pressure (lbf/ft2) 2116.224 2116.224 Molecular Weight NH3 (Ib/lb-mole) 

### 17 17 SpeCific Molar Volume (ft3/lb-mole) 379.50 379.50 Mass Conversion (Ib/ug) 2.20E-09 2
.20E-09 02 Correction Factor (%) 15 15 Mass NH3 (ug/sample) 1893 .2 4 1278.55 Mass NH3 (mg) 1.893 1.279 Mass NH3 ( Ib) 4
. 17E -06 2.82E-06 PPM NH3 (flue qas) 2.6 1 .9 

### PPM NH3.@ 02 Correction 2.21 1.60 Ib/hr 2.44 1
. 66 Ib/MMscf fuel 3.45 2
. 35
NH3 EQUATIONS: ppm NH3 

### = (m ass NH3· Gas Const • RefTemp· 106 )/(Sample vol. • Press· MW) ppm NH3 

### @ 02 correction = 

### ppm· (20.9-02 Corr)/(20.9-%02) NH3 natural gas AA, MC, RM, JM Average Limit

14
. 01 1.54

2.2 1.91 

### 5 2.05 2.8984

### AMMONIA TEST RESULTS SUMMARY Client Gemma Parameter Location 

### CPV Sentinel Fuel Unit 5 Data By Test Number CPV Sentinel-5-NH3-55-1 CPV Sentinel-5 - NH3-55-2 Relerence Temperature, F 60 60 Test Date 

### 2/26/2013 2/26/2013 Test Method SCAOMD 207.1 SCAOMD 207
. 1 Sample Train 1 -P&M 1-P&M Meter Calibration Factor 1
. 014 1 .0 14 Stack Area (sq It) 143
. 14 1 43 .14 Sample Time (Mi n ) 60 60 Barometric Pressure (in Hg) 

### 29.47 29.47 Start Time 8 : 30 10:00 Stop Time 9 : 37 11 :09 Meter Vo lume (acf) 37
. 779 36
.626 Meter Temperature (F) 71
.3 74
. 9 Meter P ressure (iwg) 1.50 1
. 50 Liquid Vol ume (ml) 80
.2 77.6 Stack 02 (%) 14
. 15 14.13 Stack NOx (ppm) 

### @ 15 % 02 1 .83 2.12 Unit Load MW 55 55 Fuel Flow Rate, hsclh 5,384 5,400 Standard Sample Volume (SCF) 37.068 35.693 

### Moisture Fraction 0.091 0.092 Stack F l ow Rate (dsc lm , 60 of) 259 ,659 261 ,7 82 Stack Flow Rate (dsc lm , 70 of) n la n l a Gas Constant (It-I bl/lb-mole-R) 1545 .33 1545.33 Standard Pressure 

### (lbl/lt2) 2116
. 224 2116
. 224 Molecular Weight NH3 (Ib/lb-mole) 

### 17 17 S pecific Molar Volume (lt3/1b-mole) 379
. 50 379.50 Mass Conversion 

### ( Ib/ug) 2
.20E-09 2
. 20E-09 02 Co rrect io n Factor (%) 15 15 Mass NH3 (ug/sample) 549
. 19 587.91 Mass NH3 (mg) 0.549 0
. 588 Mass NH3 (Ib) 1
. 21 E -06 1.29E-06 PPM NH3 (flue gas) 0
. 7 0 .8 PPM NH3 

### @ 02 Correction 0.64 0.71 Ib/hr 0
. 51 0.57 Ib/MMsclluel 0
. 94 106
NH3 EQUATIONS : ppm NH3 = 

### (mass NH3 ' Gas Const' ReI Temp' 106 )/(Sample vol. • Press' MW) ppm NH3 @ 02 correction = 

### ppm' (20.9-02 

### Corr)/(20
.9-%02) NH3 natural gas AA, MC , RM , JM Average Limit

14
. 14 1
. 97

0
. 8 0.67 

### 5 0.54 1
. 0004

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Comments :

_ _________________________________________________________ _



### Date of last revision 1/25/2013 Page
__ of
__ DS834049 Master Document StoragelFormslDatasheets l Field Datasheets

### AMMONIA ELECTRODE CALIBRATION CURVE :Sample Koom 

### NH3 concentration log NH 3 concentration Electrode potential Temperature Temperature**(~g** 

### NH 3 1 ml as N) (mV) (C) 

### (C) 1 0.000 97.6 22.5 22.5 5 0.699 59.4 22
. 5 22
. 5 20 1.301 24.9 22.5 22.5 100 2
.000 -15.5 22.5 22
.5 Ammonia Electrode Calibration Curve y = - 56
.6126x 

### + 

### 98
. 2 1 26 

### 2/27/2013 R 2 = 0. 9998 

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. 0 

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# - " 0
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# ~O iij 

## -20
. 1) 00 0.500 1
. 000 1.500 2. 00 -40
. 0 logarithm of the concentration of ammon i a**(~g** 

### NH,I ml as N) slope y-intercept 

### Concentration**(~g** 

### NH , I ml as N) 1 5 20 100 Calculation: 

### -56
. 6126 98.2126 Value LR line 1
. 0252 4
. 8482 19
. 7237 102.0022 Regression Line:**P=M·log( g**  

### of NH,I ml as N)+B 

### Difference 0
. 0252

- 0.1518 -0
. 2763 2
. 0022

Measured Concentration of Ammonia (C) in**~g** 

### 1 ml NH, as N : C=10 ,P ,8 

### 1 /M 

### where P = electrode potential, M= slope (must be -57±3) and B= intercept 

### % Difference 2.5229 -3.0356 -1
. 3817 2
. 0022

All standards were prepared in 0.04N H 2 

### S0 4 

### and allowed to equilibrate to room temperature
.AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS CALCULATION ClienV Location : Sample Location : District Method: Sample Date: Analys is Date: Analyst's Initials : Calibration Curve ' 

## R' Sample Sentinel Unit 5 100% SCAQMD 207.1 2/26/2013 2/27/2013 

## RF y= -56
. 6126 x+ 98
. 2126 0
. 9998 

### P Cone . mV**g** NH3/ml as N 28 

### ug NH3/ ml as N 16.2 repeat 

### 28 ug NH3/ml as N 16
. 1
1-NH3 -100-1 56.4 repeat 1- NH3 - 100 - 1 56.8 2-NH3 -100-1 59.4 repeat 2- NH3 -100-1 59
. 2

spike 2-NH3100- 1 19.5

repeat spike 19
. 3 28 NH3/ml as N 16.1 repeat 28 ug NH3/ml as N 16.1 Reagent Blank 153.4 repeat ReaQent Blank 153
. 7 Field Blank 145.6 repeat Field Blank 146.2

DI H20 Blank 151.7 Repeat DI H20 Blank 152.1 28 NH3/ml as N 17.2 repeat 

### 28 ug NH3/ml as N 17
. 3 Notes: Measured Concentration of Ammonia (C) in 

### )..lg NH3 I mt as N C= 1 O(P-B}/M 

### P = electrode potential (mV), M=slope and B=intercept 28
. 097 28.212
5.477 5.389 4.848 4.888 24
. 568 24.769 28.212 28.212 0.106 0.105 0.146 0.142 0.114 0
. 112 26
. 977 26
. 868

Average Measured Ammonia Concentration (Cavg) = (C1 + C2)/2 where C1 , C2 results from dup li cate analyses (l1g NH3/ml as N) Cavg**(~g** NH,Iml as NH3) = Cavg**(~g** NH31 ml as N)' 17.03/14.01 Ilg NH3 I sample = Cavg (J.l.g NHy'ml as NH 3 ) * TV Used 100 ml of samples and standards with 2 mllSA and constant stirring rate . All solutions turned blue and remained blue with lSA un less otherwise indicated. Sample PH and Temperatures can be found on the laboratory datasheet . 

### C avg as 

### N
28
. 154

5.433 4.868 24
. 668 28
. 212 0.1053 0
. 1438 0.1126 26.923

Maximum samples ( including blanks) between 28 ug/ml check standard is 5 samples ana lyzed i n duplicate. TV C avg as NH3**~g** NH,I (ml) samp l e NA 34
. 223 NA

605 6
. 604 3995.651 581 5.917 3437
. 992 NA 29.986 NA NA 34.293 NA NA 0
. 128 NA 405 0.175 70
. 781 NA 0.137 NA NA 32
. 726 NA

### AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS QUALITY CONTROL Client! Location : Sample Location : District Method : Sample Date: Analysis Date: Analyst's Initials : Sample 28 ug NH3/ ml as N repeat 28 ug NH3/ml as N 1-NH3 -100-1 repeat 1- NH3 -100-1 2-NH3 -100-1 repeat 2- NH3 -100-1

spike 2-NH3 100-1 repeat spike 28 NH3/ml as N repeat 28 ug NH3/ml as N Reagent Blank repeat ReaQent Blank Field Blank repeat Field Blank DI H 2

## 0 Blank Repeat DI H 2 

### 0 Blank

28 NH3/ml as N repeat 28 ug NH3/ml as N Notes : Sentinel Unit 5 100% SCAQMD 207.1 2/26/2013 2/

27/2013 

### RF

% recovery NA

NA NA 103.45

NA NA NA NA NA
spike: 100 ml sample 

## + 2 ml (1000 I1g NH3/ ml as N) Matrix Spike Percent Recovery (%R) %R 

## = (C spike*O 104 - Csample*0.1 02)/2 *100 

### Cspike 

# =average result of matrix spike (l1g NH,I ml as N) RPD % -0.41

1.63 -0.81 -0.81 0.00 1.22 2.44 1
. 63 0.41 RPA % 0.552

NA NA NA 0
. 756

NA NA NA -3
. 848

Relative Percent Difference (RPD) 

## = (C1-C2)/ Cavg *100 (must be 5% or less) Relative Percent Accuracy (RPA) (must be 10% or less) RPA = 

### (Cavg-theoretical value of standard)/ theoretical value of standard * 100

# Oell811 Ai, Qw l i.., $....;.;., .**,"** 

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project# : _______ District Method: SCAQMD 207.1 Sample Date: 

# '4/ /13 Client/Location: 

# SeD1.ioe. ( Sample Location: 

# U/);t Calibration Date: 

# A 

# I /13 Analysis Date 

# z./ /13 Test #'s: 

# 1()6 

# % Calibration Curve: 

## V=

## -5'."l~**.Y~·9r.)./** Z 

## f Analyst's Initials: 

# R 7 ) 

### Sample Standard Check: 28**~g** 

### NH,Iml Repeat 28 

# /- Jlf/, - /bO

# ~ 

# I 2,. 

# NI/, - /(;0

- 

# I



# 2fAl/./, 

# field MCMK Electrode Potential

(mV) 

# It. 2, 

# It . ( 

# sc..'1 S'(, . J' 

# 59· 'I**J9·~**



# 19-3 

# It. ( Jf... r 

# /53.Q

# /5~, 1 

# /45. (, 

# /.5:/.1- }Sl.t TV (ml)



## {,6S 

# 5JI Cone. 

### fl9 NH 3 -



### N 

## 1 ml 

# U·C/i7- 

# S.**~/11**



# 2.f. 212.. U.212. 

# l OS 

# o.**D./4~** 

# O./J..(1... D. III.( 0, 

# (! 1.. Cavg (fl9 NH3 - N 

## 1 ml-)



# 5. 'f33



# 21 ; 2,12.. 

## ().ID S 

## 3 

# o. jJ/3f' O.lllc:. Notes: Total volume of samples and standards used: 100 ml Volume of pH adjusting ISA used in ml: 2 ml Absorbing solution: 0.1 N H2S04 Calculations: Conc. (fl9 NH3 - N 1 ml) = 

### 10 (P-S}/M 

### P 

## = electrode potential , B 

## = y·intercept and M 

## = slope fl9 NH31 sample



# 3975.**~** Commentsl 

### Temp/pH Percent Recovery :

Cavg = average result of duplicate analyses (fl9 NH3 - N 1 

### mil = (C1+C2)/2 

### fl9 NH31 sample 

## = Cavg* 17.03/14.01 

### * TV mg 1 sample 

## = fl9 Isample .,. 1000 ppm NH3 

# =mg NH 3 /sampie x 1Nmstd 

### x 1/454000 

### x SV/17 

### x 10 6 

# Della/). "' ''-''t '""'"'"' ............. 

### Date of last revision 12/5/2008 

### DS834059 Master Document StoragelFormslDatasheetslLab Forms

# Dellal1 ""O""ljtys...;........... _ ..... 

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project # : ________ District Method: SCAQMD 207
. 1 Sample Date :

## 212~ 

# 113 ClienULocation: 

# 5e.01. 

# t 1\

# ~ 

# t Calibration Date : 

# :z.lh113 Analysis Date : 

# 2/2.:;-/13 Sample Location : 

# Uf)/t:**~** Calibration Curve:
________

# ~Analyst's Init ials : 

# R?: Test # ' s : 

# P,j 1. R2:
_____ _ Sample Electrode TV Cone
. Cavg fig NH 3 1 Commentsl Temp/pH Potential (ml) fig NH 3 - (fig NH3 sample

( mV) N 1 

## ml - N 1 

## ml) Standard Check : Percent Recovery : 28 I-lg NH,Iml 

# /7.2- 2&. 

# 'in Repeat 28 

# /7.1**2'.~"f** 2(,.'113

Notes : Total volume of samples and standards used: 100 ml Volume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H 2S04 Calculations : Conc
. (fig NH 3 - N 1 

## ml) 

## = 10 (P·8 YM 

## P 

# =electrode potential , B 

# = y-intercep t and M 

# =slope Cavg 

## = average result of duplicate analyses (fig NH3 - N 1 

## ml) 

## = (C1+C2)/ 2 

## fig NH31 sample 

## = Cavg* 17
. 03/14.01 

## * TV mg 1 

## sample = 

## fig Isample ;- 1000 ppm NH3 = 

## mg NH3/sampie x 1Nmstd x 1/454000 

## x SV/17 

## x 10 6 

# Della/:). .--- - - DS834059 Date of last revision 12/5/2008 

## Master Document StoragelFormslDatasheetslLab Forms

### AMMONIA ELECTRODE CALIBRATION CURVE Sample Room 

### NH3 concentration log NH 3 concentration Electrode potential Temperature Tempe rature**g** 

### NH,I ml as N) (mV) (C) (C) 1 0
. 000 97
. 6 22.5 22.5 5 0.699 59.4 22
. 5 22.5 20 1.301 24
. 9 22
. 5 22.5 100 2
. 000 -15.5 22.5 22.5 Ammonia Electrode Calibration Curve y = 

### -56. 6126x + 

### 98.2126 

### 2/27/2013 R' = 

### 0.9998 

## 120.0 

# :;- 100.0 

## .§. 80.0 

# ..**~** 

## 60.0 g 0 

## 40.0 D- 

# .. "C 

## 20.0 0 

# - 

# - () 

## 0.0 

# ..**~O** jjj 

## -20!J·( 00 0.500 1.000 1
. 500 2
. 00 -40.0 logarithm of the concentration of ammonia**(~g** 

### NH,I ml as N) slope y-intercept Concentration**(~g** 

### NH ,I ml as N) 1 5 20 100 Calculation : -56.6126 98
. 2126 Value LR line 1.0252 4.8482 19.7237 102
. 0022 Regression Line :**P;M'log(~g** 

### of NH,t ml as N)+B Difference 0
. 0252 -0.1518 -0.2763 2.0022

Measured Concentration of Ammonia (C) in**~g** 

### 1 

### ml NH , as N : C;10 (P,81 /M 

### where P ; electrode potential, M; slope (must be -57±3) and B; intercept 

### % Difference 2.5229

- 30356 -1.3817 2
. 0022

All standards were prepared in O , 04N H 2 

### S0 4 

### and allowed to equilibrate to room temperature
.AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS CALCULATION ClienV Location : Sample Location: District Method: Sample Date: Analysis Date: Analyst's [nitials: Calibration Curve: 

## R' Sample Sentinel Unit 4 75% SCAQMD 207.1 2/26/2013 2/27/2013 

## RF y= -56.6126 x+ 96.2126 0.9996 

### P Conc. mV**~g** NH3/ml as N 28 

### ug NH3/ ml as N 16.2 repeat 

### 28 UQ NH3/ml as N 16.2**1~NH3** -75-1 73.2 repeat 1- NH3-75-1 73
. 6 2-NH3 -75-1 63.2 repeat 2- NH3 -75-1 63.1

spike 2-NH3 75-1 23.1

repeat spike 22.9 28 NH3/ml as N 16.2 repeat 

### 28 ug NH3/ml as N 16.2 Reagent Blank 153.4 repeat Reagent Blank 153.7 Field Blank 145.6 repeat Field Blank 146
. 2

DI H20 Blank 151.7 Repeat DI H20 Blank 152.1 28 NH3/ml as N 17.2 repeat 

### 28 uq NH3/ml as N 17.3
Notes: Measured Concentration of Ammonia (C) in f.l9 NH3! ml as N C= 1 O{P-B) IM 

### P = electrode potential (mV), M=slope and 8=intercept 26.097 26
. 097 2.766 2.699 1.642 1.649 21.222 21.395 26.097 26.097 0.106 0.105 0.146 0.142 0
. 114 0.112 26.977 26.666

Average Measured Ammonia Concentration (Cavg) = (C1 + C2)/2 where C1, C2 results from duplicate analyses (119 NH3/ml as N) Cav9 ("9 NH,Iml as NH3) = Cav9 ("9 NH31 ml as N)' 17.03/14.01 

### 119 NH31 sample = Cav9 (119 NH3/ml as NH 3 ) * TV Used 100 ml of samples and standards with 2 ml ISA and constant st ir rin9 rate. AI! solutions turned blue and remained blue with ISA unless otherwise indicated . Sample PH and Temperatures can be found on the laboratory datasheet. 

# e avg as N
26
. 097

2.732 1
. 645 21.306 26
. 097 0.1053 0.1436 0.1126 26
. 923

Maximum samp les (including blanks) between 28 ug/m l check standard is 5 samples ana lyzed in duplicate. TV C avg as NH3 "9 NH,I (ml) sample NA 34.154 NA

570 3.321 1693.236 570 2
. 243 1276.547 NA 25
. 902 NA NA 34
. 154 NA NA 0
. 126 NA 405 0.175 70
.761 NA 0
. 137 NA NA 32.726 NA

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS QUALITY CONTROL Client! Location: Sample Location : District Method: Sample Date : Analysis Date : Analyst's Initials:
Sample 28 ug NH3 1 

## ml as N repeat 28 ug NH3/ml as N 1-NH3 -75-1 repeat 1- NH3 -75-1 2-NH3 -75-1 repeat 2- NH3 -75-1

spike 2-NH3 75-1 repeat spike 28 NH3/ml as N repeat 28 ug NH3/ml as N Reagent Blank repeat Reaqent Blank Field Blank repeat Field Blank DI H 2 

## 0 Blank Repeat DI H 2 

## 0 Blank

28 NH3/ml as N repeat 28 ua NH3/ml as N Notes: 

## Sentinel Unit 4 75% SCAQMD 207
. 1 2/26/2013 2/27/2013 

## RF

% recovery NA

NA NA 101.39

NA NA NA NA NA
spike : 100 ml sample + 

## 2 ml (1000 ftg NH3 1 

## ml as N) Matrix Spike Percent Recovery (%R) %R 

## = (C spike*0.1 04 - Csample*0
. 102)/2 

## *100 Cspike 

## = average result of matrix spike (l1g NH,t ml as N) RPD % 000

2.44 -0.41 -0.81 0
. 00 1.22 2.44 1
. 63 0.41 RPA % 0.347

NA NA NA 0
. 347

NA NA NA -3.848

Relative Percent Difference (RPD) 

## = (C1-C2)1 

## Cavg *100 (must be 5% or less) Relative Percent Accuracy (RPA) (must be 10% or less) RPA 

## = (Cavg-theoretical value of standard)1 theoretical value of standard * 100

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project # : ______ District Method : SCAQMD 207.1 Sample Date : 

# 212(/1$ Client/Location: 

# SeDt!' oe ( Calibration Date :

# ~ 

# ht/l3 Analysis Date : 

# Z./zi/13 Sample Location: 

# Una; 5" Calibration Curve :Y: -s, . ,12'

## X=+94'.:ZI Z 

## E Analyst's Initials: 

# R 7**75 C>/~**  2 c,.-.L> 

## Test #'s:
__ ..:....:::'-'''<...: <v=--- __ 

## R: 

# o. -"7 

## fSample Electrode TV Cone. Cavg fl9 NH31 Commentsl Temp/pH Potential (ml) fl9 NH 3 - (fl9 NH3 sample

(mV) N Iml - N I ml") Standard Check : Percent Recovery : 28**~g** 

## NH,Iml 

# It. 2- 2f.617 Repeat 28 

# It.l.**2~,09l** 

## )f·697- 

# /- /If./, -75 - I 

# 7.n. 2.1ft,**&~ct** I

# ,.v~ 

# 7 5
- I 

# 1.H- 5"10 2.C,C;, 

# 2.7H. /f'l3. 2. 

# pI-I <. 2. 

# T::z;.S( 

# 2.. 

# NI/,

- "15 

# - I f3·1.. I.S't!..

# 1.Q~c:t 2}/#' 75

- 

# I 8-3·\ 5"10 

# ;. 'i'f7 

# /.H5 

# lUFfS: 1>/./c..l. 

# T= 22.5" ( 

# 5 £)iKe.2. 

# AlII, 75" - I 

# 23·'**2.{.~1.2.** 

# RU'ld 

# 5IJ/K, 22. '1 21.3'15 2.1· 

# 3o.r 

# re. {a-vetc/ :- 

# /6'**~V** o 

# 2.fAlIL**I~·** 2.., 

# n011

# Ig&>~[ 

# 2f**N'~** 1&'.2..**2~.O11** 

# ]f..on

12<:: 

# ,,,,,.J p,/rrr../( /5Y( o./or, 

# A It 50b 

# f i CI>t.5

# ~**~d** 

# R (J. /53,.7- {)./OS O./{)5**~**

# ~k( 

# c..t 

# IieJd /l. /""'/<.**/~s.~**

## o.!'-/~ 

# 22.S-° (.. 

# 'a:ALd fA 

# /'f/,.7.. 0·/1../2-**o'/1.3~** 

# f)/J

# ~ 6 

# I?J{CYlK. 

# /S/.T D. III{ 

# N.**'.42~:I:** 

# fi 

# lAo t3 J 

# K. /$7.. .\ 0./12- 

# {).II2.£ Notes : Total volume of samples and standards used : 100 ml Volume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H2S04 Calculations : Conc
. (fl9 NH3 - N 

## I ml) 

## = 10 (p·B I/M 

## P 

## = electrode potential , B 

## = y·intercept and M 

## = slope Cavg 

# =average result of duplicate analyses (fl9 NH3 - N I 

## ml ) 

# = (C1+C2)/2 

## fl9 NH31 sample 

## = Cavg* 17.03/14
. 01 

## * TV mg 

## I sample 

## = flg Isample + 

## 1000 ppm NH3 

## = mg NH3/sampie x 1Nmstd x 1/454000 

## x SV/17 

## x 106 

# Del/a!1

---- DS834059 Date of last revision 12/5/2008 

## Master Document Storage\Forms\Datasheets\Lab Forms

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project #:
________ District Method: SCAQMD 207.1 Sample Date : 

# :?**/~"** 

# 113 ClienULocation 

# Se.ct 

# t 1\ 

# e.1 Calibration Date : 

# .2.12?/13 Analysis Date 

# 2/21-/13 Sample Location : 

# Uf\,'t 5" Calibration Curve : _________ ,Analyst's Initials: 

# R:t Test #'s : 

# 75:0/0 R':



# ------ Sample Electrode TV Cone
. Cavg fl9 NH31 Commentsl Temp/pH Potential (ml) fl9 NH 3 - (fl9 

## NH3 sample

(mV) N 1 

## ml - N 1 

## mil Standard Check : Percent Recovery : 28**~g** 

## NH3/ ml 

# /7.2. 2(... '17 

# 7 Repeat 28 

# )7.3 

# 2e,. fe-I" 2(.,. 

# y2J

Notes : Total volume of samples and standards used : 100 ml Vo lume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H2S04 Calculations : Conc
. (fl9 

## NH3 - N 1 

## ml) 

## = 10 ( P · BVM 

## P 

## = electrode potential , B 

## = y-in tercept and M 

## = slope Cavg 

## = average result of duplicate analyses (fl9 

## NH3 - N 1 

## ml) 

## = (C1+C2)/2 

## flg NH31 sample 

## = Cavg' 17
. 03/14.01 • 

## TV mg 1 

## sample = 

## fl9 Isample .,. 1000 ppm NH3 = 

## mg NH,tsample x 1Nmstd x 1/454000 

## x SV/17 

## x 10' 

# Delfa/j.

- ----.- DS834059 Date of last revision 12/5/2008 

## Master Document StoragelFormslDatasheetslLab Forms

### AMMONIA ELECTRODE CALIBRATION CURVE ::>amp,e Koom 

### NH 3 concentration log NH 3 concentration Electrode potential Temperature Temperature (Mg NH 3 1 ml as N) (mV) (C) (C) 1 0.000 97.6 22.5 22.5 5 0
.699 59.4 22.5 22.5 20 1.301 24
. 9 22.5 22.5 100 2.000 -15
. 5 22.5 22.5 Ammon i a Electrode Calibration Curve y = -56
.6 1 26x + 

### 98.2126 

### 2/27/2013 R2 = 0
.9998 

## 120.0 

# :> 100.0 

# -S 80
. 0 C;

### ~ 

## 60.0 $ 0 

## 40.0 0- Q) 

# " 20.0 0**~ ~**  

# ... 0.0 Q)

# ~O iii 

## -20Jj.( 00 0.500 1.000 1.500 2. 00 -40
. 0 

# I logarithm of the concentration of ammonia ("g NH, 

### 1 ml as N)

s l ope V-intercept 

### Concentration (Mg NH 3 1 ml as N) 1 5 20 100 Calculation: -56.6126 98.2126
Value LR line 1.0252 4.8482 19
. 7237 102
. 0022 Regression Line : P=M'log(M9 of NH,J ml as N)+B 

### Difference 0
. 0252 -0
. 1518 -0
. 2763 2
. 0022

Measured Concentration of Ammonia (C) in M g 

### 1 ml NH, as N : C=10 (P-BjIM where P = electrode potential , M= slope (must be -57±3) and B= intercept % 

### Difference 2.5229 -3.0356 -1.3817 2.0022

All standards were prepared in 0.04N H2 

### S0 4 

### and allowed to equilibrate to room temperature
.AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS CALCULATION ClienU Location: Sample Location: District Method: Sample Date: Analysis Date: Analyst's Initials: Calibration Curve: 

### R' Sample Sentinel Unit 5 50% SCAQMD 207.1 2/26/2013 2/27/2013 

### RF y= -56.6126x+ 98.2126 0.9998 

### P Conc. mV )19 NH3/ml as N 28 ug NH3/ ml as N 16.3 reoeat 

### 28 ua NH3/ml as N 16.4
1-NH3-5D-l 100.8 reoeat 1- NH3-50-1 101.1 2-NH3 -50-1 102.9 reDeat 2- NH3 -50-1 103.3

spike 2-NH3 50-1 24.5

reneat snike 24.2 28 NH3/ml as N 16.2 repeat 

### 28 uo NH3/ml as N 16.2 Reagent Blank 153.4 rene at Reanent Blank 153.7 Field Blank 145.6 reoeat Field Blank 146.2

DI H20 Blank 151.7 ReDeat DI H20 Blank 152.1 28 NH3/ml as N 17.3 reoeat 

### 28 UD NH3/ml as N 17.2 Notes: Measured Concentration of Ammonia (C) in )19 NH3! ml as N C= 1 O(P-8)/M 

### P = electrode potential (mV), M=slope and B=intercept 27.983 27.870 0.900 0.889 0
. 826 0.813 20.047 20.293 28.097 28.097 0.106 0.105 0.146 0.142 0.114 0.112 26
. 868 26.977

Average Measured Ammonia Concentration (Cavg) 

### = (C1 + C2)/2 where C1, C2 results from duplicate analyses (J.19 NH3/m! as N) Cavg**(~g** NH,tml as NH3) = Cavg**(~g** NH31 ml as N)' 17.03/14
. 01 J.19 NH31 sample = Cav9 (J.19 NHiml as NH 3) * TV Used 100 ml of samples and standards with 2 mllSA and constant stirring rate . All solutions turned blue and remained blue with ISA un less otherwise indicated. Sample PH and Temperatures can be found on the laboratory datasheet. 

# e avg as N
27.926

0.895 0.820 20.170 28.097 0.1053 0
. 1438 0.1126 26.923

Maximum samples (including blanks) between 28 ug/ml check standard is 5 samples analyzed in duplicate. TV C avg as NH3**~g** NHJI (ml) sample NA 33.946 NA

505 1.088 549.190 590 0.996 587
. 912 NA 24.518 NA NA 34.154 NA NA 0
. 128 NA 405 0.175 70.781 NA 0.137 NA NA 32.726 NA

### AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS QUALITY CONTROL ClienV Location: Sample Location: District Method : Sample Date : Analysis Date : Analyst's Initials : Sample 28 ug NH31 ml as N repeat 28 ug NH3/ml as N 1-NH3 -50-1 repeat 1- NH3 -50-1 2-NH3 -50-1 repeat 2- NH3 -50-1

spike 2-NH3 50-1 repeat spike 28 NH3/ml as N repeat 28 ug NH3/ml as N Reagent Blank repeat Reagent Blank F ield Blank repeat Field Blank 

## 01 H 2

## 0 Blank Repeat 

## 01 H 2 

### 0 Blank

28 NH3/ml as N repeat 28 ug NH3/ml as N Notes: Sentinel Unit 5 50% SCAQMD 207
. 1 2/26/2013 2/27/2013 RF

% recovery NA

NA NA 100.70

NA NA NA NA NA
spike : 100 ml sample + 

### 2 ml (1000 I"g NH31 ml as N) Matrix Spike Percent Recovery (%R) %R 

## = (C spike*0
. 104 - Csample*0.1 02)/2 *100 Cspike 

## = average result of matrix spike (fig NH,t ml as N) RPD % 0.41

1.22 1.63 -1
. 22 0.00 1
. 22 2.44 1
. 63 -0.41 RPA % -0
.263

NA NA NA 0
. 347

NA NA NA -3
. 848

Relative Percent Difference (RPD) 

## = (C1-C2)1 Cavg *100 (must be 5% or less) Relative Percent Accuracy (RPA) (must be 10% or less) RPA 

## = (Cavg-theoretical value of standard)1 theoretical value of standard * 100

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project# : ______ District Method: SCAQMD 207.1 Sample Date : 

# ?,/zt,./13 ClienULocation : 

# SeD-/.ioe.f Calibration Date :

# ~ 

# ht/l3 Analysis Date : 

# Z./J,+/<3 Sample Location: 

# u!)a; 5 Calibration Curve:V=-Y.
. 611f X=+"1<f',.2IZt; Analyst's Initials: 

# R7 Test#'s : 

## $0% R': 

# 0.9'1'1[' ,**----=-~-=----** 

### Sample Electrode TV Cone. Cavg**~g** 

### NH 31 

## Commentsl Temp/pH Potential (ml)**~g** 

### NH 3 -**(~g** 

### NH3 sample

(mY) N 

## Iml - N 

## I mil Standard Check : Percent Recovery : 28 IJg NH,tml 

# It3 27·9'f3 Repeat 28 

# It .ll 2;;·);7-0 

# n·. t;zCr



# 1- 

# JlI/, - So

- 

# I 

# 160 ·" D
. 900 

# /0,tci /**#~** 

# 50 - \ /6/.1 

# sos D. 

# ff7 ().f%- 

# 5 t 

# /9. I 

# pH < 2. 

# T::22.sc 

# Z·NI/,

- .50 

# - I /02 . .,**6·f1.~**

# f<L~c.t 

# Z##' 50 - 

# I**/(')~ .~**  

# 590 0.f/3 

# D. 

# no sH·9 

# /J/-/ < 2.... 

# T=' 22. S' ( 

# Sj),'lft.. 2.. 

# AlII, 5D - I 

# 21.(.r:; 

# 2e> , /)L{':f

# Db" ,.I. 

# 5IJ,'KL 2L(.2.. 

# lb,273 

# 2(!)·/70 

# re.. {avetl/ :: 

# 100 < 

# 2fAl/J. IC·2. 

# Zf. 

# on 2 AO/

_

t v 

# 1 f. 

# HI/., If,
. 2. 

# 2f;097- 

# 2f.M7 

# h: ".11-1. P, /0Yt.i<. 

# 18.1./ 

# D./Orr 

# A I { soL-l:i 011,5 

# h**~d** 

# R/!..**/~<,·1** 

# D./OS**J~~** 

# -Le..s·kJ c. 

# t

lie.(d f>..lfMl<. }I{s.c, 

# D·Nf, 

# 22S o (.. 

# R(fit,-t f IJ. It.{

# r,. 1- 

# D-/'{1- 

# D.**J'-{3~** 

# lilll**~** 6 

# /3{CH-,K.**{~/.1** 

# D-I/I{ 

# 1M**~4-1::**

# /Y 

# /Ao t3 J K.. 

# /5Z. I 0.111- O. 

# {1M. Notes : Tota l volume of samples and standards used : 100 ml Volume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H2S04 Calculations : Conc
.**(~g** 

### NH3 - N 

## I ml) 

## = 10 ( P ·B)/M 

### P = e l ectrode potential , B = y-intercept and M = slope Cavg 

### = average result of duplicate analyses**(~g** 

### NH3 - N 

## 1 ml ) 

### = 

## (C1+C2)/2**~g** 

### NH31 sample 

## = Cavg· 

## 17
. 03/14
. 01 • TV mg 

## I sample 

## =**~g** 

### Isample .,. 1000 ppm NH3 

# =mg NH,tsample x 1Nmstd x 

## 1/ 454000 x 

## SV /17 x 106 

# !!P!@A Date of last revision 

## 12/5/2008 DS834059 Master Document StoragelFormslDatasheets l Lab Forms

# ~

## AMMONIA BY ION SELECTIVE ELECTRODE ANALYSIS Project # : ________ District Method : SCAQMD 207
. 1 Sample Date : 

# 2. 

# 1)4/13 ClienULocation : 

# Se.at,' 1\

# ~ 

# I Calibration Date :

# 2..1z':j11.~ Analysis Date : 

## 2 

# IH/ 13 Sample Location : 

# U()/t!l Calibration Curve : _________ Analyst ' s Initials : 

# R:lTest # ' s : .50 

# 70 

# fJ 1.. R' : _____ _ Sample Electrode TV Cone. Cavg**~g** 

## NH 31 Commentsl 

## Temp/pH Potential (ml)**~g** 

## NH 3 -**(~g** 

## NH 3 sample

(mV) N 

## 1 ml - N 

## 1 m l) Standard Check : Percent Recovery : 28 I-Ig NH ,I ml 

# (n 2(.· 

# fC fRepeat 28 

# 1'7.2... 2t,.977- )(,·923

Notes : Total volume of samples and standards used : 100 ml Volume of pH adjusting ISA used in ml : 2 ml Absorbing solution : 0
. 1 N H2S04 Calculations : Conc.**(~g** 

## NH 3 - N 1 

## ml) 

## = 10 (P-BVM 

## P 

# =electrode potential , B 

# = y-in tercept and M 

# =slope Cavg 

# =average result of duplicate analyses**(~g** 

## NH 3 - N 1 

## ml ) 

# = (C1 +C2)/2**~g** 

## NH31 sample 

## = Cavg" 17
. 03/14
. 01 

## "TV mg 1 

## sample 

## =**~g** 

### Isample -;- 

## 1000 ppm NH3 

## = mg NH3/sampie x 1Nmstd x 1/454000 

## x SV/17 x 10' 

# Oe//a/j, .-- .--- DS834059 Date of last revision 12/5/2008 

## Master Document StoragelFormslDatasheetslLab Forms

## Appendix C.4 SOx 

## by SCAQMD Method 307.91

R521 0729 

### C-8

## Parameter



# so, Units Ib/ MMBtu Ib/ MMsef 

## gr H2S/ 100sef Ma x Result Limit 0
. 00002

0
. 017 0
. 006 0
. 06 0.67 0
.25 Rule 40 CFR 60 Rule 2011 SCAQMD Perm it B61
. 1Sen t inel Unit 5 Fuel Analysis and Sulfur Cales.xls Sulfur Client Facility Unit Gemma Sentinel 

### 5



## - - 

# - Sentinel 5 fuel 1&2 Fuel Sulfur HHV Content , (BTU/ft3@

ppmv 60F) MW (H2S) MW(S02) Result 0
. 1 1026
. 8 34
. 00 64.00 Limit Reference 

### gr/100 scI = ppmv luel / 10'6 x MW ( H2S )/SV x gr/lb x 100 Ib/10"6 sef 

### = ppmv fue1/10"6 x MW (H2S)/SV x 10"6 Ib-S02lMMBtu = ppm lue1/10'6 x MW (S02)/SV/HHV x 10'6**(~peeilie** Molar Volume@6 OF) 379.5 grnb gr-H2S/ 100 sci 7.000 0.006 0
. 25 SCAQMD

Permit, 861 .1 lbsH2S/ MMscl

0.009 0.690 Rule 2011 IbS02lMMBtu

0.00002

0.06
40 CFR 60

4/15/2013

2: 26 PM

### Client Facility Unit



### Load, MW 106 Gemma Senlinel 

### 5

Fuel Sulfur

Content , ppm 10
. 1 S e nti n e l 

### Unit 5 Fue l Anal y sis a nd Sulfu r Cales . xls 

### SOx

Sentinel-5-Fuel-1 &2 

### Spec ific

Molar Slack Flow Volume Rate Fuel Flow

(SV), (Qsd19), Rate , dscf / lb-mol dscfm hscf/h 02 Ib/hr, S02 ppmv 379
. 5 405 , 070 8744 13 .5 2 0
. 01475 0
. 004 S021b/ hr 

## = (sulfur ppmv)/ 10 " 6 x (MW S02)/SV x hscf / hr x 100 scl / hscf ppm S02 = Ib/hr x SV/ MW x 1 /Qsd19 x 

### 10 "6/ 60 S02 , ppmv@ Ib/MMscf15% 02 Fuel 0
. 003 0.017

Load, Stack fiow rate, fuel fiow and 02 average of data collected in 

### conjuction with NOxiCO 

### tests at 100 % load condition

4/15120 13 2 , 26 PM

### Client Facility

Unit



## Carbons

1 2 2 3 3 4 4 4 4 4 4 4 

## 5 5 6 Gemma Sentinel 

### 5 

## Compound Hydrogen Carbon Dioxide Carbon Monoxide Nitrogen Oxvaen Methane t:thylene Ethane Propane Propylene SODutane n-Butane 1 - Butene Isobuty lene t-2-Butene c-2-Butene 1,3-Butadiene sopentane n-Pentane HexaneSt-'IUS Compound Total Reduced Sulfur FUEL F-FACTOR CALCULATIONS

Sentinel-5-Fuel-1 &2 

## 1 2 Average detect? 1 MOLE 

## % detect? 1 MOLE 

## % detect? MOLE 

## % < 0
. 001 < 0.001 0 .32 1 0.321 < 0.001 < 0
. 001 3.261 3.261 0.007 0.007 90 .7 72 90.772 < 0
. 001 < 0.001

4.803 4
. 803 0.670 0.670 < 0
. 001 < 0
. 001 0.042 0
. 042 0.083 0
. 083 < 0
. 001 < 0.001 < 0
. 001 < 0.001 < 0.001 < 0.001 < 0
. 001 < 0
. 001 < 0.001 < 0.001
. 0.009 0.009 0.009 0.009 0.023 0.023 detect? 1 ppm detect? 1 ppm detect? ppm 10
. 1 1 0.1 Note: Results from one sample. One of the duplicate samples obtained a leak and was compromised.

### FUEL F- FACTOR CALCULATIONS Client Gemma Unit 5 

### Facility Sentinel Sentinel-5-Fuel-1 &2

SPECIES MW 

### MOLE 

## % MW*% 

# HHV BTU/SCF 

## C H 

## 0 N CO 2 

### 44 0
. 321 14
. 13 0
. 04 0
. 00 0
. 10 0
. 00 CO 

### 28 0.001 0
. 03 32 1 .0 0
. 003 0.00 0.00 0
. 00 0
. 00 N 2 

### 28 3.261 91.35 0
. 00 0.00 0
. 00 0.91 O 2 

### 32 0
. 007 0.22 0.00 0.00 0.00 0
. 00 C , 

### 16 90.772 1456
.2 1012
. 0 918
. 61 10
. 89 3
. 63 0
. 00 0
. 00 C 2 

### 30 4
. 804 144.45 1773
. 0 85
. 17 1
. 15 0
.29 0
. 00 0
. 00 C 3 

### 44 0
. 671 29.59 2524
. 0 16
. 94 0
.24 0.05 0
. 00 0
. 00 C 4 

### 58 0.130 7
. 54 3271
. 0 4.25 0
. 06 0.01 0
. 00 0.00 C 

## s 72 0
. 018 1.30 3998.0 0
. 72 0
. 01 0
. 00 0
. 00 0
. 00 C 6 + 

### 86 0
. 023 1
. 98 4743
. 0 1
. 09 0
. 02 0.00 0
. 00 0
. 00 Ave
. 1 

### Total 100.01 1641.09 1026.79 12
. 38 3
. 99 0
. 00 0
. 00 Weight, % 

### 99
. 74 75.42 24.32 0.00 0.00 GasMW 16.41 Btu /scf= 1027 @60F Btu /scf= 1043 @68F Btu / lb
. = 23 , 744 Ib '/scf= 0
. 0432 Fd"(60)= 8,458 (0 2 

### Based) Fd"(68)= 8,588 Fc"(60)= 1,004 (C0 2 

### Based) Fc"(68)= 1 , 020 Calculations: 

### Fd"(68) = 10'6' [3
. 64 • (H % ) 

## + 1
.53 • (C%) 

## + 0
. 14 • (N % ) - 

### 0.46 • (0%)] 1 HHV, 

### Btu/lb Fd"(60) = Fd"(68) • 520 R 1528 

### R Fc"(68) = 10 ' 6' [0
. 321 • (C%)] 

### 1 HHV , 

### Btu / lb Fc"(60) = Fc"(68) • 520 R 1 

### 528 R

## Sentinel Unit 5 Fuel Analysis and Sulfur Cales.xls F-Summary Client Facility Unit Gemma Sentinel 5 

### Sentinel-5-Fuel-1 &2 GasMW 

## 16.41 Btu/set= 

## 1,027 Btu/set= 

## 1,043 Btu/lb.= 

## 23,744 Ib.Jset= 

## 0.04324 Fd"(60)= 

## 8,458 Fd"(68)= 

## 8,588 Fe"(60)= 

## 1 ,004 Fe"(68)= 

## 1,020



## 4/15/2013 2:26 

## PM

### Parameter Method No. Fixed Gases ASTM D1945/1946 

### HHV ASTM D3588 Sulfur ASTM D5504/S CAQMD METHOD 307-91 Method Title Analysis of Natura l Gas/Reformed Gas by Gas C h romatography Calculating Heat Value , Compressibility Factor , and Relative Dens ity of Gaseous Fuels Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence/ Determination of Sulfur In A Gaseous Matr ix

## Appendix C.5 ROG by Modified SCAQMD Method 25.3

R521 0729 C-9

### Client/location Gemma CPV Sentinel Unit 5 Sample location Stack Test No. S-S/STK-ROG-100-1A Date 2/ 25/ 2013 Test Method Modified SCAQMD 25
. 3 Sample Time (HH :M M) 1 : 13 Start Time 13 : 04 Stop Time 14 : 17 Stack 

## 0, (%) 13
. 54 Results Canister NMNEOC (ppm) 0
. 62 ROG, ppm' 0
. 62 ROG, ppm 

## @ 15% 

## 0, 0
. 50 RPO', % 

# - 1) Includes bias correction of 1.086 2) Relative percent difference less than 20% 3) Samples were collected simultaneously as a pair Results reported at POL Reference Temp (F) 60 Data By AA , MC , RM , JM

S-S/STK-ROG-100-1 B Average 2

/ 25/ 2013 Mod ified SCAQMD 25
. 3 1 : 13 13:04 14:17 13.54
0
. 66 0.66 0
. 64 0
. 53 0
. 51

- 

### 3
. 1%

## Client/location Gemma GPV Sent i nel Unit 5 Sample location Stack Test No
. S-5/STK-ROG-75-1A Date 2/25/ 2013 

## Test Method Mod ified SGAOMD 25
. 3 Sample Time (HH : MM) 1 : 08 Start Time 16:42 Stop Time 17 : 50 Stack O 2 

## (%) 13
. 98 Results Canister NMNEOC (ppm) 0
. 58 ROG, ppm' 0
.58 ROG, ppm @ 15% O 2 

## 0.49 RPD 2
, 

## % 

# - 1) Includes bIas correctIon of 1
. 086 2) Relative percent difference less than 20% 3) Samples were collected simultaneously as a pair Results reported at POL Reference Temp (F) 60 Data By AA , MG , RM , JM

S-5/STK-ROG -7S - 1 B Average 2/

25

/ 2013 

## Modified SGAOMD 25.3 1 : 08 16:42 17 : 50 13 .98
0
.61 0
.61 0
. 60 0
. 52 0
.51

- 

## 2
. 5 %

## Client/location Gemma CPV Sentinel Unit 5 Sample location Stack Test No. S-5/STK-ROG-50-1A Date 2/26/2013 

## Test Method Modified SCAOMD 25
. 3 Sample Time (HH:MM) 1 :0 8 Start Time 8 : 30 Stop Time 9:38 Stack 

## 0, (%) 1 4
. 15 Results Canister NMNEOC (ppm) 0.62 ROG, ppm' 0
. 62 ROG , ppm @ 15% 

## 0, 0.54 RPD', % 

# - 1) Includes bias correction of 1.086 2) Relative percent difference less than 20% 3) Samples were collected simultaneously as a pair Results reported at pal Reference Temp (F) 60 Data By AA, MC , RM , JM

S-5/STK-ROG-50-1 B Average 2/26/2013 

## Modified SCAOMD 25.3 1 : 08 8:30 9:38 14.15
0
.73 0
. 73 0
. 68 0
. 64 0
. 59



# - 8 .1%

## SCAQMD METHOD 

## 25 . 3 EVACUATED CANISTER SAMPLING DATA Client/Facility : 

# Oe vt--\.

# .~ 7 

# 7 ")**~c** 

## c -**~** 

# I, ,", Oate:
___ C7"

___ J
__ 

### ----=: -'
___ _ 

## Unit/Location: 

# 5 S-.?IA.-'-'r,\., J Performed By:---.: c? "'-..:....:.. ,4 -/.'f
____ _ 

# 4"'"5 d'- Probe Material_--=-- --

_'--
______ Probe Length
__ 

# ?

_______ _ Connecting Tubing Material
___ ----- ___ , Connecting T u bing Length,
_____ _**~~** 

## /**~c** 

## Barometri c Pressure,

_ ----' o<- =----

_ 7

_

. __ ,= =-

_ Ambient Temperature
___ J... \ 

## --< , _ _ _ Test No
. ;5 

### -5js1K - !?Ofr-fOo -fA 

## S- S/#rlo-II?cJ&- 

# ,,./J,,
. ,-**~** 

## Via l 

## 10 

## rJfI- 

# f\fft Canister 

## 10 "'5"2, '/ j 

## i 

# 5 Time Vac u um Time Vac u um TinlI e Vacuum Pre-Test Leak Start 

# 1Q(u 10/0 

# 3u 

# \ C heck 

# 50 Pre-Test Leak Stop 

# IJ 

# 2- 0 

# 3 0 ( 1)2u 

# "

, 

## Check J(.-J 

## Sample 

# N Start 

# 13 0 '-( 

### ( 36 

# 'I Collection 

# 5v 

# 30 G**5~,+** 

# nz-v 2:[ (37-U 

# r3Z J 

# <5 S'fM 1- 

# i 'JL{, J V 

# (?'i') 

# eN] 

# tv je,**~r** 

# !,{ o1 Ix{ 1'-1 0 

# 1 I 

# 'Iv?

Sample Stop 

# /'In ( u 

# Iff? /1 Collecti on P ost -Test Leak Start 

# i 

# {n. 

# If Check 

## ( J 

# fy l?..- Post-Test Leak Stop 

# ('-{ 32- 

# t V flf) 2.- 

# II Check Line Rinse V o lume 

# / ./ 

# ,..- 

# /' 

# \ \ 

## Comments :

_____ ______ ____ _________ _ 

# Della/1 ,.,o_"s-;,.. ,__ ... 

## Date of last revision 11/13/08 

## DS834043 Master Document Storage\Forms\Datasheets\Field Datasheets

## SCAQMD METHOD 

## 25.3 EVACUATED CANISTER SAMPLING DATA Client/Facility: 

# GevIA MOl

-

# Se"",L~ \ Oate:_--= C2.-:

_ -


# _ 2

_ '5

_ -

_

2D
__ 

# '

_

'...::"2:;, ==--_ Unit/Location: 

# 5

- skc/< Performed

# By**_-' r<** **c....:...c '--.l..-**  ___ _ Probe Material_----= 5 =--.=:: 5
_____ Probe Length 

# tfOilrr-rf/-e 

# S Connecting Tubing Material,
___ ------

__ Connecting Tubing Length,
___ ..--- __ _ Barometric Pressure
__

# 2-**L·----'Y=-.L** 

# __ ,Ambient Temperature·
__ 

# ...::

(; --'f
.... · 

# "",2
__ _ Test No
. Vial 10 

## Canister 

## 10 Pre-Test Leak Check Pre-Test Leak Check Sample Collection

Sample Collection Start Stop Start

Stop Post -Test Leak Start Check Post-Test Leak Stop Check Line Rinse Volume Time Vacuum 

# (Mc(' 

# 1J;


# ( 7

175'0 / 

# 0 

# Iv If 

# I cJ



# / / i ! 

# / Time Vacuum Time Vacl,lum**/(/) ~**  

# / / /

/'7 /

# ~ 

# j 

# / I 

# / I I 11<) 

# 0 

# II 

# I (gou II 

# / II 

# /' / Comments : _______________________ _

Date of last revision 11/13/08 

## DS834043 Master Document StoragelFormslDatasheetslField Datasheets

## SCAQMD METHOD 25,3 EVACUATED CANISTER SAMPLING DATA

() ,A 

### <"" i' / 'lr ..., 

# t;; c 

# /3- ClientlFacility: 

# lY--ew"v, c ,) ...... LhHe 

## Oate:
__ 

# =- ""

__ .?-
________ _ 

## UnitlLocation :_..;: 5

=---___ 

# Sl-er

__ C'

_ k:'

_'

__ 

## Performed BY:_--L I'f

---"'<'<cc;1
__ 

# J.-f -'-
__ _ Probe Material
___ 

# ----=-

S'

--"

5'

=---____ Probe Length
__

# -'1!**(;l i**  _____ _ 

## Connecting Tubing Material
___ ,,- /
__ Connecting Tubing Length,
__ ""' / "----- Barometric Pressure_---= ,,') =--- '1 _,_ C( -'-. '

# '1**=---_~Ambient** Temperature
__ 

## --'y"- '

# -,-**~2 ,,-** **'** __ _ 

## Test No , 

# S- S/.<;!i<.

-**~c&--5 p..**  

## S 

# -Skit. RVb- -5 a·lt Vial 

## 10 

## NT\- NI\, 

## Can i ster 

## 10 

# /7 .;L 

# It!**~** 

## Time Vacuum T i me Vacuum Tme Vacuum Pre - Test Leak Start Check 0&'/2- 

# 2'1 " Ii 

## /2- 

# :2.<; Pre-Test Leak Stop 

## P[j 2

- 2-- 

# 2; (/ ?7-J-- 

# 2-'1 Check Sample Start 

## 06 30 

# 2-') Collection 

# III ti?Jo 

# 2-9 &: 

### tJ 

# lb <1'1 ,;2,/ 

# {/ [3 

# 'I "7 2.,5'



# 5' ()9 0 

# (;J 

# 11 09'-'3 2-2. i.f) 

# 0"1.; c.) 

# 1 <1 i/'".-J () 

# 1&

Sample Stop 

# 01:; 

# 0 

# w 1)73 

# J I] Collection Post -Test Leak Start 

# t7 '1 

# '-f**~** 

## Check 

# /0 0'1'1 

# r 1'2. Post-Test Leak Stop 

# 0755 (u 

# "755 /) Check 

# \ \ Line Rinse 

# ./ V / ' 

# \ Volume 

# ,.------ /" 

## I Comments : _________________________ _

Date of last revision 11/13/08 DS834043 Master Document StoragelFormslDatasheetslField Datasheets

# Atmospheric Analysis & 

# Consu l ting, I nc.
CLIENT PROJECT NAME AAC PROJECT NO. REPORT DATE Delta Air Quality Services , Inc. Gemma, Sentinel 5 \30219 3/5/2013 On February 27, 2013, Atmospheric Analysis & 

## Consulting, Inc. received six (6) Six-Liter Summa Canisters for TNMNEOC analysis by SCAQMD 25.3 Modified and Fixed Gases analysis by EPA 3C . Upon receipt the samples were ass igned unique Laboratory ID numbers as follows: Client lD Lab 

## No . Initial 

## Pressure (mmHg) S5 /Stk-VOC-100-IA 130219-61285 476.4 S5/Stk-VOC-100-IB 130219-61286 445.0 S5/Stk-VOC-75-1 A 130219-61287 506.3 S5/Stk-VOC-75-IB 130219-61288 479.7 S5 /Stk- VOC-50-IA \30219-61289 473.4 S5 /Stk- VOC-50-1B 130219-61290 403.7 Upon receipt at the laboratory , the initial vacuum was recorded and the cani ster was pressurized to 900 mmHg using dry UHP Helium. The PQL for this modified method was estab li shed at 0.10 ppmV (as Propane) as dictated by the lowe st point in the calibration curve. All results were detected below this level and therefore reported as <PQL. I certify that this data is technically accurate, complete and in compliance with the terms and conditions of the contract. Release of the data conta in ed in this hardcopy data package ha s been authorized by the Laboratory Director or his designee, as verified by the f o ll owing s ignature . If you have any questions or require an expla nation of your data results, please contact the undersigned.

Marcus Hueppe Laboratory Director
This report cons ists of 

# 41 pages . CertHlca t l ' f . l. l7



# Page 1
1534 Eastman A v

e ., Ste . A • Ve n tura, • C A 93003 

# @ www. aaclab.com. ( 805) 650-1642 • FAX ( 805 ) 650

- 1644

# ® lAce Atmospheric Analysis & 

### Consulting, Inc , 

# SAMPLE RECEIPT / LOG-IN REPORT 

# AAe Proiect 130219 Received By: 

## J. Zachman Sample 

### Project Desc 

### Clients ID Matrix Sampling Sampled 

### By Sa mple # 

### Analysis 

### Receipt Date Daterrime 

### Requested 

## 2/2712013 Delta Air Quality SS/Stk-VOC

- IOO Summa 

## 2/ 2S/ 20 13 Client 6128S SCAQMD 2S.3M lOIS -IA Cani ster Gemma. Sentinel S 

## 2/27 / 2013 Delta Air Quality SS /Stk- VOC-I 00 Summa 

## 2/2S120 13 Client 61286 SCAQMD 2S.3M lOIS -IB Canister Gemma, Sentinel S 

## 2127 / 2013 Delta Air Quality SS /Stk- VOC

-7S

- 

### Summa 

## 212S12013 Client 6 1287 SCAQMD 2S.3M lOI S IA Canister Gemma , Sentinel S 

## 212712013 Delta Air Quality SS/Stk-VOC-7S- Summa 

## 2 / 2S/ 2013 Client 61288 SCAQMD 2S.3M lOIS IB Canister Gemma, Sentinel S 

## 2/27/2013 Delta Air Quality 

## SS/Stk- VOC-SO- Summa 

## 2/26 / 2013 Client 61289 SCAQMD 2S.3M lOIS IA Canister Gemma, Sentinel S 

## 212712013 Delta Air Quality SS/ Stk-VOC-SO- Summa 

## 2/ 26

/ 2013 Client 61290 SCAQMD 2S.3M lOIS IB 

## Canister Gemma, SentinelS



### TURN AROUND TIME: Normal (lOdays) Lab Due Date: 

## 3 / 612013 Total Samples: 

### 6 REMARKS: Client returned 6 x Summa canisters 

## + 6 x Flows.



# Page 2

### Client: Date : Delta Air Quality 2/27/2013


### Canister 

## # 357 115 086 119 172 106 

# Atmospheric Analysis & 

# Consulting, Inc ,

CANISTER PRESSURE LOG Project No. : 

## 130219

Sample 

## # Initial Pressure Final Pressure



## 61285 476.4 912 . 3 61286 445 .0 906 . 8 61287 506.3 902.4 61288 479 .7 901.0 61289 473.4 902 . 7 61290 403.7 910.5

1


# Page 3

# c,;zZ's

# re /-z-15' It> 

### fA I 

## z.? ·7 

## 'I ; z.t?tJ 

## o I 

# -z. fJ<'l " 11-'1 0 

# /I.4 C 

# # /3021cr
CHAIN OF CUSTODY CLIENT : Sentinel TEST OATE(S) : 212512013 212612013 LOCATION : 5 SAMPLER(S): .:; R "'M'-
___________ _ SAMPLE LOCATION : Slk PROJECT MANAGER : SF TEST METHOD(S) : SCAQMD 25 .3 DATE DUE : 3 / 6 / 2013 OU T SIDE LAB REQUIRED? : Yes COMPLIANCE TEST? Yes ot 0 212512013 S5/ Stk ·VOC·101J.1A SCAQMD25
. 3 an ter # 

### 0(90 ." . 1 2125/2013 S5/Stk-VOC·100·1 B SCAQMD 25 .3 Canister # 

### 0'" 1 2 / 25

/ 2013 SSlSt k-V OC · 75-1A SCAQMD25
.3 Canister # 0001> 1 2125 / 2013 S5/ Stk·VOC·75·1 B SCAQMD 25 ,3 Ca ni ster # 

### 00 1 1 9 1 2126/2013 S5/Stk ·VOC·50·1A SCAQMD 25 .3 Cani ster # 

# r- ' 01 

### 2- 1 212612013 S5IStk-VOC -50-1 B S CAQMO 25 .3 Can ister # t) 1

ola ampes 6 eagen t: eagent ot s: 

# I

# oe«!~ : /' 

# 6. 

# z 

# I 

# ;111;;;;/**~** 

# z;; I 

# ;;**~A**

# Results

Page 5

# Atmospheric Analysis 

# & Consulting, In c . LABORATORY ANALYSIS REPORT CLIENT PROJECT NO. MATRIX UNITS

Client ID S5/Stk-VOC-100-1A SS/Stk-VOC

- 100-1B 

### S5/Stk-VOC-75-1A SS/Stk-

### VOC-75-1 B SS/Stk-VOC-50-1A SS/Stk- VOC

- 50-IB Delta Air Quality Services, Inc. 

### 130219 Air 

### ppmC

Tank Vol Liters

LabID# (VT.nk) 130219-61285 6.00 130219-61286 6.00 130219-61287 6.00 130219-61288 6.00 130219-61289 6.00 130219-61290 6.00 

# SCAQMD 25.3 

# Modified Initial Return Final Pressure Pressure Pressure mmHg 

## (P;) mmHg(P,) mmHg (Pr) 0.0 476.4 912.3 0 .0 445 .0 906 .8 0.0 506.3 902 .4 0.0 479 .7 901.0 0 . 0 473.4 90 2.7 0 .0 40 3.7 910.5 * TNMNEOC Includes Bias Correction=1.086, as per method PQL = 0.10 ppmV Propane 

## x 3.0 (carbon conversion) x Tank Dilution Factor x 1.086 (correction factor) 

# EPA3C PQL: 0.1 

## % Analvte Client ID Lab ID# Oxygen CO S5/ Stk-VOC

- 100-1A 

### 130219-61285 13 .6 <PQL SS/Stk

- VOC

- IOO-IB 

### 130219-61286 13.5 <PQL S5/ Stk- 

### VOC-75-1A 130219-61287 14.0 <PQL S5/ Stk-VOC-7S-IB 

### 130219-61288 14 . 0 <PQ L SS/Stk- 

### VOC-SO-1A 130219-61289 14 . 1 <PQL S5/Stk-VOC-SO-IB 

### 130219-61290 14 .2 <PQL 

### Fixed Gase s hav e been normali zed to 100 % on a dry weight baSIS Sample Vol. (L) (VS.mpl,) 3.76 3.51 4.00 3.7 9 3. 74 3. 19

CO2

5.6 5.3 5.0 5.1 5. 0 5. 0 Tank Dil Factor (DFT.nk) 1.91 2.04 1.78 1.88 1.91 2.26

I 

### SAMPLING DATE : 2/25,26/2013 

### RE CEIVING DATE : 02/ 27/2013 

### ANALYSIS DATE : 03/ 04 , 05n013 

### REPORT DATE : 03/ 05

/ 2013



### Total PQL NMNEOC* <PQL 0 .62 <PQL 0.66 <PQL 0.58 <PQL 0.6 1 <PQL 0 .62 <PQL 0 .73

# ~L-..-~ Marcus Huepp e 1534 Eastman Ave . , Ste. A • Ventura, 

# • CA 93003 

# * (805) 650 -1 642 • FAX (805) 650-1644 

## Laboratorv 0l'rector Page 

## 6 • WWW.3acab . com

# Method 25.3 Modified Calculation Summary Sheet TNMNEOC

- C TCA 

# x DFTank X 

# 3.0 

# x 1.086 Where: 

## TNMNEOC = Gaseous concentration of Source, ppmV (as Carbon) C rcA 

## = Average of analysis results from chromatograms, ppmv (as Propane) DFrank 

## = Dilution factor reSUlting from tank pressurization upon receipt (PrlPr) 3.0 = Conversion of result (as Propane) to (as Carbon) Per method section 4.11, the final concentration includes a 1.086 bias correction factor. Where: 

## Pf= Final canister pressure after pressurization for analysis !from Sample Receiving Data Sheet) 

## Pr = Return canister pressure upon sample receipt (from Sample Receiving Data Sheet)



## Page 7

# QA/QC 

# Summary

Page 8

# Atmo spheric Anal ys is & 

# Consultin g, Inc.

Quality Control/Quality Assuran ce Report Date Analyz e d : 03/ 05

/ 2013 

### Analyst : ZG Units : G/ o 

### 1- QDenine: 

### C ontinuin2: Calibration Verific ation

- Se A 

### MD25.125 .3 

# I AA C ID 

# I**Anal~ te**  

# I 0 , 

## N , Spike C one 10 .46 19 . 6 

### C CV R es ult 10 .46 21.01 

### % Re e- * 1 00 .0 107. 1
AACID 

## 0, 

## N,

MB 

### NO N O IflL b 

### C ISik&D

- a oratory' 

### ontro p 

# • uplicat e - 

### S C QM A 

# , D 25.1,25 . 3 AACID . .<\nalyte 

## N, CO, S ample C ofl(' 

### 0.0 0.0 Spike Con(' 19.6 

### 10.3 

### Lab C ontrul L C S Result 20 .7 10.6

Standal"d s 

### L C SD Re s ult 19 .1 

### 9.8 

### L CS % 

### Rcc "" IOS. 7 10 3 .7 L e SJ) 

### % Ret '" 97 . 2 95.2



### % 

### RPD""" 8.4 8.6 

## IV -Sample & 

### S ill ampIe 

### uplicate

- S C AQM

### D 25 . 125 . 3 AAC ID Analy te 

## 0, 

## N, S ampl. 6. 1 34.8 

### 130219·61290 S ample Dup 6.0 34.S 

### Mcan 6. 1 3 4 .6 

### % RPD ..... 1.S 

### 0.' V · Matrix**~ik e**  & 

### DUDlie.te
. SCAQMIl25.1 25 . 3 

# I AACID 

# I Analy te 

# I N, CO, S ample C one 17.3 1.1 

### Spike Cone 

### 9. 2 10.3 MS Result 28.0 1 1.8 130219 · 612 9 0**MSDR~uJt** 2 7 . 1 

### 1 1.3 MS 

### % Rec 

### *'" 1\ 6. 7 104 .7 

### M S D %Rec"'· 106. 1 100.3



### %RPD 

## "' * '" 9.6 4.3 V I - Closing C ontinuine: C alibration V e rific ation - S C AQMD 25 . 12 5. 3 

# I AACID CCV

• Must be 85

- 11 5%

.. M ust b e 7 5

- 125 %

.. .**fust** b e < 1 5% ND '" N ot D eject ed 

# I Ana1lte Spike Cone



### Re su1t % 

### Ref'"**L** '" Ius th lln R e p orting Limit 

# II 0, 

# I N, 10.46 

### 19.6 9.98 20 .0 9S.S 102.2 

### CO, 10.3 10.54 

### 102.8 

# co, NO 

# CH. 0.0 9.9 10.2 9. 2 102 .7 

### 92.9 10.0 CO, 2.2 2.0 2.1 8.6 CH, 0. 0 9.9 10 .2 

### 9 . 9 102.8 100. 1 2. 6 

# I CO, 10.3 10.2 9 9. 3 

# I Instrument ID Calb Date TCD#1 04/13/ 2012 

### R epo rting Limit: (tl % 

### CH. 9.9 10. 18 102.5


### CH. 

### N

O
CO 0.0 10.3 10.6 

### 9 . 6 102.6 93.0 9.8 CH, 0.0 0.0 0. 0 0.0
CO 0.0 10.3 10.6 10. 3 102. 9 99 . 6 3.3
CH. 

# I 9.9 9.6 9 7 .0



### Marc us Huepp e Laboratory Dir ector C O 10 . 3 10.56 

### 102. 1 

# co NO

CO 0.0 0.0 0. 0 0.0

CO 10.3 10. 1 9 7 .4 

# I

P age 9 

## 1 534 Eastman Ave., Ste. A • Ve ntu ra, • CA 93003 www.aacl a b
.com • (805) 650- 1 642 • FAX (805) 650·16 4 4

# Atmospheric Analysis & 

# Consulting, In c.

SCAQMD Method 25.1,3 

## Quality Control/Quality Assurance Report Date Analyzed Analyst 03 / 0412013 

## ZG 1- Openine: Calibratio n Verification Standard 

# I AAC1D 

# I Analyte 

# I Concentration O·CV NMNEOC 0.27 O-CV dp NMNEOC 0.27 O-CV tp NMNEOC 0.27
11- 

### Method Blank AA C ID 

### Analytc 

### Result

MB NMNEOC ND 

### III - Matrix SDike & 

### Duplicate AA C lD . - \n al ylc Sa mple Concentnt t io n 

# I 130220-61291 

# I NMNEOC 

# /I 0.00


### IV 1 ppm Backfl sh Standa d 

# - u 

### r s A,\ClD 

### Analyte 

### Result Backflush 1 NMNEOC 1.003 Backflush 2 NMNEOC 0 .985 

### Backflush 3 NMNEOC 0.937 

# I Result 0.257 0.253 0.251



### Spike Added 

# I 54.35

" /0 

### Recovery 

# "' * 92.3 90.6 86.2 

## v - Bracketed C losing Calibration Verification Standards AAC ID Ana l y te 

# I Concentra tion 

# I Result 

### C-CV Low C-CV 

### High



### • Must be 90-110% •• Must be 80-120% 

## *** Must be 75-125% 

## **** Must be < 

### 25% 

## * **** Must he < 

### 10% NMNEOC NMNEOC 0.27 0.293 2.72 2.48 

# I % 

### Recovery 

### *' 

# I 94.6 93.1 92 .4



## MS Result 

# I 43.36 

# I

% 

### Reco ve ry ." 

### I 107.8 91.3 MSD Result 45.38 

# I Instrument ID: FID#4 Units: PPMV 

### Calibration Date:



## MS MSD % 

### Rec ... • % 

### Ret orr ..

79.8 

# I 83.5



### Marcus Hueppe Laboratory Director 111012013

% RPD** U 

# I 4.5



### Page 10 1534 Eastman Ave., Ste. A • Ventura, • CA 93003 www.aaclab
. co m • (805) 650-1642 • FAX (805) 650-1644 

# I

# Atmo spheric Analysis & 

# Consulting, Inc.

SCAQM D Me th o d 25 . 1,3 

## Qu ality Control/Quality Assu rance Repo rt Date Analyz ed : 03 / 04/2013 

### Analyst: : ZG


# s a m p le u pllc a e a n a lys I s 

# lo r t 1 . RPO ' 

# I AACID 

# I Resu lt 

# I Result UU!! 

### 130220-6 1291 <PQL <PQL 130220-6 1292 <PQL <PQL 1 30219

- 61285 <PQL <PQL 130219-61286 <PQL <PQL 130219

- 61287 <PQL <PQL 130219

- 61288 <PQL <PQL 13 02 19

- 61289 <PQL <PQL 1302 1 9

- 61290 <PQL <PQL 130228

- 6133 0 <PQL <PQL 130228-6 1 331 <PQL <PQL 1 30228-61332 <PQL <PQL 130228

- 61333 <PQL <PQL 130239-61413 <PQL <PQL 130239

- 61414 <PQL <PQL



# I Qualit,r Ass urance C riteria 

### Cone. (ppmv) 

### %RPD 

## 1

- 3 S20 4- 6 

## S l 5 7- 12 < 12 13-30 < 10 31

-50 < 5 

## s



# I Instrument ID: Un its: 

### FID#4 PPMV Calibration Date: 1/1012013 

# I %RPD 

# I NA NA NA NA NA NA NA NA N

A N

A NA NA NA NA

Marcus Hueppe Laboratory Director



## Page 11 1534 E astm an 

## Ave . , Ste. A • Ventu ra, • CA 93003 

# *

www .aa c lab. com · ( 805 ) 650- 1 642 • F AX (805 ) 650 - 1644

# Raw Data

Page 12

### Chrom Perfect Chromatog r am Report 1 3

02 1 9-61285
600

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### Instrume n t 

## =TCD #1 Raw Fi le Name = C:ICPDATAllnst#01120131030513.0006.raw Met h od F il e Name = C I CPDATAllnst#01120131030513
. 0006
. bnd Cal i brati o n F i le Name 

### = C : ICPDATAl lnst#011201310305 1 3.0006
. bnd

Peak 

### # Ret. T ime Name Amount Amt % 1 7. 03 Oxygen-MS5A 6
. 501 13
. 578 2 9
. 16 Nitrogen - MS5A 38.736 80'
. 905 3 9
. 55 C02 - Q bo n d 2
. 642 5.518 Total Area 

### = 685342.7 Total Height 

### = 98875.56

Printed on 3 1512013 8:0244 AM 14 «**~** W 

# "**~** 

# . " w

16 18 20 22

Date Taken (end ) 

### = 3 15120 1 3 741 : 29 AM 

### Di luti on Factor = 1
Area Area 

### % Type Width 890 79 12.998 BB 0
. 09 564546 82.374 SBB 0
. 11

31 7 18 4
. 628 TBB 0.20 Tota l Amo u nt 

### = 47
. 87892 24



# Page 13 Page 1 of 1

### Chrom Perfect Chromatogram Report 130219 - 61285 dp 600
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## ;§ 300 

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### Instrument 

## =TCD #1 R aw File Name 

### = C :I CPDATAllns!#01 120131030513.0007
. raw Method F ile Name = C:ICPDATAl l nst#01\20131030513 0007 bnd Ca l i br at ion File N ame 

### = C:ICPDATAl l nst#01\20131030513.0007.bnd

Peak 

### # 

### Ret. Time N ame Amount Amt% 1 7.04 Oxyg e n-M S SA 5.897 13.573 2 9.16 

### N itrogen - MS5A 35. 1 17 80.83 2 3 9.55 C02-Q bond 2.431 5.595 T otal Area 

# =621786 To tal H eig h t 

# =92023.47

Printed on 

### 3/5/20 1 3 8:06:05 AM 14 

## ::i 

# "' 

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16 18 20 22

Da te T aken (end) 

### = 3/5/20 1 3 7:58:58 AM 

### Dilut ion Factor = 1
Area Area % Type Wid t h 80802 12.995 BB 0.09 24

51 1 802 82.312 S B B 0.11

29182 4
. 693 T B B 0.20 Total Amount 

# =43.4 44 65



# P age 14 Page 1 of 1 

# 2"1"1..-\\3Chrom Perfect C h ro m atog ram Re p o r t 1 3 02 1

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-100 0 2 6 8 10 12 14 1 6 1 8 20 22 24 Tim e - Minutes Sample Name = 130219-61286 Inst rument:; TCD # 1 Raw F i le Name = C :I CPDATAl ln s !#01 12 01 31 03051 3 .0010.raw Date Taken (end ) 

### = 3 / 5/2013 922:29 AM Method F i le Na m e 

# = C :I Cpmethods l lnst#0112012ID1945-D1946-3C
. MET D i l u ti o n Factor 

# = 1 Calibration F i le Name 

### = C :I Cpmet h odsllnst #01 \20 1 2 I D 1 94 5-D 1 946-3C-04 1 3 1 2-standa r d
. CA L Peak # Ret T i me N ame Amoun t Amt % A r ea Area % Type W i dt h 1 7
. 03 Oxygen - MS5A 6
. 159 13.509 84401 1 2
. 929 BB 0
. 09 2 9.16 N itrogen-MS5A 36.970 81.084 538805 82
. 536 SBB 0
. 11 3 9.55 C02 - Q bo n d 2.466 5.408 29602 4
. 535 T B B 0.19 Tota l Area 

# =6528086 Tota l H e ight 

# = 95549
. 37 T otal Amount 

# =45
. 59514

Pri n ted on 

### 3/5 / 20139 : 23 : 24 AM 

# Page 1 5 Page 1 of 1Chrom Perfect Chromatogram Report 130219-81286 dp 600

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## , 0 2 4 6 8 10 12 14 16 18 20 22 24 Time - Minutes 

### Samp le Name 

### = 1 3 0219-6 1 286 dp I nstrument 

## =TeO #1 

### Raw File Name 

### = C :IC PDATA l l ns!#011 20131 0 30 5 1 3
. 0011
. raw Date Taken (end) 

### = 3/5/2013 9:45:33 AM Method File Name = C:ICpmethodsllnst #0112012ID1945-D1946-3C
. MET Dilution Factor = 1 Calibration File Name 

### = C:ICpmethodsllnst #0112012I D 1945-D1946·3C·04 1 312 - standard.CA L

Peak # Re t. Time Name Amount Amt % Area Area % 

### Type W idth 1 7.03 Oxygen-MS5A 6.140 13.532 84142 12.948 

## BB 0
. 09 2 9.16 Nitrogen-MS5A 36.838 81
. 1 78 536875 82 .6 16 

## BV 0.11 3 9.55 C02-Q bond 2.401 5.291 28826 4.436 

## VB 0.19 Total Area 

# =649842.3 Total H eight 

# =95267.48 Total Amount 

# = 45
. 37908

Printed on 

### 3/5/20 1 3 9:51:02 AM 

# Page 16 Page 1 of 1600

500
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### TeO #1 Chrom Perfect Chromatogram Report



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16 18 20 22

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### = C: I CPDATA lln st#01120131030513_0012_raw Date Taken (end ) = 

### 315/2013 10:03:33 AM Method File Name 

# = C:ICpmethodsllnst #0112012ID 19 45-D 1946 - 3C.MET D il ution Factor 

# =1 Calibration Fi le Name = C :I Cpmethods l lnst #01120 1 2ID1945-D1946-3C-041312-standard

_ CA L Peak # Ret T i me Na me Amount Amt% Area Area % Type Width 1 7
. 03 Oxygen -M S5A 7.357 13.983 1 008 1 1 13.378 BB 0_09 2 9.15 N itrogen-MS5A 42.584 80.935 620620 82.361 SBB 0.11 3 9
. 54 C02 - Q bond 2.674 5.082 32105 4

_ 261 TBB 0.20 Total Area 

### = 753534
. 9 Total Height 

### = 106098.2 T otal Amount 

### = 52.6 14 8 24

Printed on 

### 3/5/2013 10 : 03:59 AM 

# Page 17 Page 1 of 1

### Chrom Perfect Ch romatogram Repo r t



## --------------------
600

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### = C:ICPDATAllnst#01120131030513.0013.raw Date Taken (end) 

### = 3/5/201310 : 19 : 29 AM Method F i le Name 

# =C:ICpmethodsllnst #0 112 0 12I D1945 - D1946 - 3C
. MET Di lu ti on Factor 

# = 1 Calibrat i o n F i le Name 

### = C:ICpmethodsl l nst #0112012ID1945-D194 6 -3C-041312 -standard.CAL

Peak # 

### Ret. Time Name Amount Amt % Area Area % Type Width 1 7 .0 3 Oxygen-MSSA 7.308 1 4
. 0S4 1 00136 13. 44 1 

## BB 0.09 2 9 .1 5 N itrogen-MSSA 42
. 177 81.1 13 614692 82
. 509 

## BV 0 .1 1 3 9.54 C02-Q bond 2.513 4
. 833 3017 1 4 .0S0 

## VB 0.20 Total Area 

### = 744999.4 Tota l Height 

### = 105646
. 8 T otal Amount 

### = 51
. 99781 24

Printed on 3/5/201310:19:56AM 

# Page 18 Page 1 of 1 

# 2s1 3/.,;-/1 3Chrom Perfect Chromatogram Report 130219-61288 600
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### Sample Name' 130219·61288 Instrument = TCD #1 

### Raw File Name ' C:ICPDATA\lnst#01120131030513.0014.raw Date Taken (end)' 31512013 10:36 :30 AM Method File Name· C:ICpmethodsllnst#0112012ID1945-D1946-3C.MET Dilution Factor
. 1 Calibration Fi le Name· C:ICpmethodsllnst #0112012ID1945-D1946-3C-041312-standard.CAL

Peak # Ret. Time Name Amount A mt% Area Area 

### % Type Width 1 7.03 Oxygen-MS5A 7.007 14.028 96014 13.421 BB 0
. 09 2 9 .15 Nitrogen - MS5A 

### 40.432 80949 589263 82.369 SBB 0.11 3 9.54 C02-Q bond 2.509 5.023 30121 4.210 TBB 0.20 Total Area' 715398.1 Total Height· 102342 .9 Total Amount· 49.948

Prin ted on 31512013 10:38:11 AM 

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### 3 / 5/2013 10:54:06 AM Method Fi le Name 

# = C : ICpmethodsllnst #01\20 1 2ID1945-D1946-3C
. MET D i lu ti on Factor 

# =1 Cal i bration F il e Name 

### = C :I Cpmethods l lnst #01 \2012 I D1945-D1946-3C-041312-standard
. CAL Peak # Ret. 

### Time Name Amount Amt % Area Area % Type Width 1 7 .03 Oxygen-MS5A 6
. 978 13.945 95617 13.346 BB 0
. 09 2 9
. 1 5 N itrogen-MS5A 40.450 80
. 839 589522 82
. 28 1 SBB 0
. 11 3 9
. 55 C02-Q bond 2.610 5
. 216 3 1 334 4
. 373 TBB 0
. 20 To t al Area 

# =7 16472.4 Total He ight 

# = 102323.3 Tota l Amount 

# =50
. 03 77 8 

# "

Pr i n ted on 

### 3 / 5/2013 1 0 : 55 :32 AM 

# Page 20 Page 1 of 1600
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### Raw F i le Name: C:ICPDATAllnst#01120131030513.0016.raw Date Taken (end): 3/5/201311:12:14 

### AM Me thod Fi l e Name: C : ICpmethodsllnst #0112012ID1945-D1946-3C.MET Dilution Factor: 1 Calibration File Name: C:ICpmethods\lnst #0112012ID1945 - D1946-3C -0 41312 - standard
. CAL

Peak # Ret 

### Time Name Amount Amt% Area Area % Type Width 1 7.03 Oxygen-MS5A 6
. 828 14.102 93568 13.492 BB 0.09 2 9
. 16 

### Ni trogen -MS5A 39
. 166 80.885 570814 82.306 SBB 0
. 11 3 9
. 54 C02 - Q bond 2,427 5.013 29145 4.202 TBB 0.20 Total Area: 693526.8 Total He ight: 99945
. 16 Total Amount: 48.4223 24



### Printed on 3/5/2013 

### 11: 14:54 AM 

# Page 21 Page 1 of 1Chrom Perfect Chromatogram Report 130219-61289 dp 600

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### = C:ICPDATAlinst#01120131030513.0017.raw Date Taken (end) = 

### 3/5/201311:29:01 AM Method File Name 

# =C:ICpmethodsl l nst #01\2012ID1945-D1946-3C.MET Dilution Factor 

# = 1 Calibration File Name 

### = C:ICpmethodsllnst #01\2012ID1945-D1946-3C-041312-standard.CAL Peak # Ret. Time Name Amount Amt% Area Area % Type Width 1 7.03 Oxygen-MS5A 6
. 916 14. 134 94774 13.522 

## BB 0.09 2 9
. 15 N itrogen-MS5A 39
. 582 80.889 576872 82
. 306 

## BV 0.11 3 9
. 55 C02-Q bond 2435 4
. 977 29240 4.172 

## VB 0.20 Total Area 

# = 700885.5 Total He ight 

# =100880 Total Amount 

# = 48.93388

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### 3/5/2013 1129:28 AM 

# Page 22 Page 1 of 1600
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### Raw File Name; C:ICPDATA lln st#01120131030513
. 0018 .raw Date Take n (en d ) ; 3/5/2013 11 :46:57 AM Method F i le Name; C:ICpmethodsl l nst #011201 2ID 1 945-D 1 946-3C.MET Dilution Factor; 1 Calibration File Name ; C :IC pmethodsllnst #01 120 12 I D1945 - D1946-3C- 04 1 312 - standard.CAL

Peak# Re t. 

### T ime Name Amou nt Amt% Area Area % Type Width 1 7.03 Oxygen-MS5A 6
. 120 14.203 83859 13.593 BB 0.09 2 9.16 Nitrogen-MS5A 34.754 80.659 506509 82.099 SSB 0 .11 3 9.55 C02-Q bond 2.214 5.138 26579 4
.308 TBB 0.20 Total Area; 6169 46
. 8 Total Height; 91623.7 Total A moun t; 43.08774 

# "

Printed on 3/5/2013 11 :47:25 AM 

# Page 23 Page 1 of 1

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### 130219-61290 dp 

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### = C :\CPDATA\lnst#01\2013\030513

_ 0019 _raw Date Take n (end ) c 

### 3/5/2013 12 :0 3: 32 PM Method Fi le Name c 

### C:\Cpmethods\lnst #01 \2012\D1945-D1946-3C.MET Dilution Factor c 

### 1 Calibrat i on File Name c 

### C :\ Cpmethods\lnst #01 \2012\D1945-D1946 - 3C -041312-standard.CAL Peak # Ret 

### Time Name Amount Amt % Area Area % Type Wid th 1 7.03 Oxygen-MS5A 6.027 1 4

_ 174 82593 13

_ 555 

## BB 0 .0 9 2 9.16 

### N itroge n-MS5A 34.467 81 .0 50 502319 82.442 

## BV 0
. 11 3 9.55 C02 - Q bond 2.031 4 .776 24385 4.002 

## VB 0.20 Tot al Area c 

### 609296 .8 Tota l Height c 

### 90987.09 T otal Amoun t c 

### 42.525 1 2

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### 3/5/2013 12:03:55 PM 

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### = C:ICPDATAllnst#04120131030413_0014.raw Dale Taken (end ) = 

### 3 / 4 / 2013 9:25 : 55 AM Method Fi le Name = C :\Cpmethods \ lnst #04\2013\M ethod25.1 ,3 J ow . met D ilution Factor = 1 Cal ib ral io n File Name = C :I Cpmelhodsllnsl #0412013IM25.1 , 310w-0110 1 3 CAL

Peak 

### # Ret. T i me Name Amount Amt % Area Area % Type Widlh 1 0.67 0
. 000 0.000 9682 0
. 022 

## BV 0
. 05 2 0
. 86 Car bo n Monox ide 10
. 899 0
. 501 154370 0
. 346 

### W 0. 1 7 3 1
. 05 Methane 9.755 0.449 190509 0.427 

## VB 0
. 18 4 1
. 94 Carbon Dioxide 2153
. 096 99
. 048 44241740 99
. 200 

## BB 0.52 5 5.88 NMNEOC 1 0.038 0
. 002 2018 0
. 005 

## BB 0
. 36 Tola l Area 

### = 4.459832E+07 Tolal He ight 

### = 1105364 Total Amounl 

### = 2173.787

Pr i nted o n 

### 3 / 4 / 20 1 3 9:48 : 37 AM 

# Page 25 Page 1 of 1

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### = C: I CPDATA l lnst#04 120131030413.0015
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### = 31412013 9:42 : 14 AM Method File Na me;:;; C:\Cpmethods\ l nst # 04\2013\ Me thod25 . 1 , 3Jow.met D ilu tion Factor::; 1 Ca li brat ion File Name 

### = C :I Cpme th odsllnst # 0412013I M25
. 1 , 3tow-011013.CA L

Peak # Ret Time N ame Amo unt 

### Amt % A r ea Area % Type Width 1 0
. 87 Carbon Monoxide 10
. 280 0.475 14 5608 0
. 32 8 

## BV 0
. 17 2 1.05 Met han e 9 .705 0.448 189546 0.427 

## V B 0
. 19 3 1
. 92 Carbon Di oxide 2146
. 096 99
. 076 44097908 99.242 

## BB 0
. 52 4 5
. 89 N M N EOC 1 0
. 033 0
. 002 1755 0
. 004 

## BB 0
. 36 T otal Area 

### = 4.443 4 82E+07 T ota l He ight 

### = 1 101517 Total Amount 

### = 2166
. 115

P r inted on 31412013 9:48:43 AM 

# Page 26 Page 1 of 11600
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### = C:ICPDATAllnst#04120131030413.0016_raw Date Taken (end) 

### = 3/4/ 2013 956 : 30 AM Method F ile Name 

### = C : \Cpmethods\lnst#04\2013\Method25.1 ,3Jow . met Dil ution F actor 

### = 1 Calib ratio n File Name = C I Cpmethodsllnst #04\2013IM25
. 1 , 310w- 011 013 CAL Peak 

### # R et. T ime Name Amount Amt% Area Area % Type W i dth 1 0
. 87 Carbon Mo noxi de 9

_ 554 0.45 1 1 35323 0.311 

## BV 0. 1 7 2 1
. 05 Met hane 9.123 0.430 1 78174 0.410 

## VB 0
. 18 3 1
. 94 Ca rb on D iox ide 2101.174 99
. 117 43174852 99.275 

## BB 0
. 51 4 5.82 NMNEOC 1 0
. 037 0
. 002 1978 0
. 005 

## B B 0.42 Tota l Area 

### = 4.349032E+07 Total H eight 

### = 1099692 Total Amo u nt 

### = 2119
. 888

Pr i nte d on 3/4/2013 10 : 1 5 : 40 AM 

# Page 27 Page 1 of 11600
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### 3/4/2013 10:11:28 AM Method Fi le Name 

### = C : ICpmethodslinst #0412013IMethod25.1
. 3Jow
. met D i l u t i on Factor 

### = 1 Ca l ib rati on File Name 

### = C :I Cpmethodslinst #0412013IM25
. 1
. 3 1 0w-Oll013 CAL Peak # 

### Ret . T ime Name Amount Ami 

### % Area Area 

### % Type W i dth 1 0
. 8 7 

### Carbon Monoxide 9.293 0.439 1316 1 8 0
. 303 

## BV 0.17 2 1
. 05 

### Methane 8.916 0.421 174133 0.401 

## VB 0.18 3 1. 92 

### Carbon Diox ide 2097
. 610 99
. 1 37 43101624 99.289 

## BB 0
. 51 4 5
. 84 NMNEOC 1 0
. 053 0
. 002 2825 0.007 

## BB 0.35 Tota l Area 

# =4.34102E+07 Tota l Height 

# = 1099291 Tota l Amount 

# = 21 1 5
. 872

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### 3 / 4

/ 2013 1 0 : 15:45 AM 

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### 3/412013 10:53:06 AM Method File Name = C:\Cpmethods\lnst #04\2013\Method25.1 ,3_fow.met Dilution Factor = 1 Ca li bratio n File Name 

### = CICpmethodsllnst #04\2013IM25.1 , 310w-011 0 1 3
. CAL Peak # Ret. T ime Name Amount Amt% Area A re a 

### % Type Width 1 0.87 Carbon Mo n ox ide 10.150 0.467 143759 0.323 

## BV 0.17 2 1. 07 Met hane 12
. 922 0.595 252369 0.566 

## VB 0
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. 95 Carbon Dioxide 2149
. 652 98
. 936 441 7 0980 99. 10 6 

## BB 0.52 4 5.84 NMNEOC 1 0
. 043 0
. 002 2305 0.005 

## BB 0
. 37 Total Area 

# =4.45694 1 E+07 Total Height 

# = 1108920 Tota l Amount 

# =2172.767

Pr i nted on 

### 3 / 4/20 1 311 : 12 : 54 AM 

# Page 29 Page 1 of 11600
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### = C:\CPDATA\lnst#04\2013\030413.0021.raw Date Taken (end) = 31412013 11 :10:36 AM Method F il e Name 

## = C:\Cpmethods\lnst #04\2013\Method25 .1 ,3_low.met Dilution Factor;; 1 Ca li bration F i le Name 

### = C :\ Cpmethods\lnst #04\2013\M25 .1 , 310w - 011013
. CAL Pea k # Ret. Time Name Amount Amt% Area Area 

### % Type Width 1 0.87 Carbon Monoxide 6.941 0.414 126633 0
. 266 

## BV 0.16 2 1.06 Methane 12.671 0
. 596 251365 0.566 

## VB 0.17 3 1.95 Carbon Dioxide 2136.365 96
. 966 43697946 99
. 142 

## BB 0.52 4 5.82 NMNEOC 1 0.036 0.002 2050 0
. 005 

## BB 0.39 Tota l Area 

# = 4.427799E+07 Total Height 

# = 1106 766 Total Amount 

# =2158.214

Printed on 3141201311 : 12:56AM 

# Page 30 Page 1 of 11600
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### = C:ICPDATAllnst#04120131030413
. 0022.raw Date Tak en (end) 

### = 314 120 13 11 :2 4 :0 1 AM Melhod File Name 

# =C:ICpmethodslinst #0412013I Me thod 25. 1 ,3_low
.met D ilutio n Factor 

# = 1 Ca li b rat io n Fi le Name = C: I Cpmelhodsli nst #0412013 IM 25 .1 ,3 10w -0 11 onCAl Peak 

### # 

### Ret. Tim e Nam e Amount Am t% Are a Area 

### % Type Width 1 0.87 

### Carbon Monox ide 8
. 087 0.381 11 4543 0.263 

## BV 0
. 16 2 1.0 5 

### Methane 12.328 0.581 240765 0
. 55 3 

## VB 0
. 1 7 3 1
. 96 

### Carbon Dioxide 2100.858 99.036 43168368 99.180 

## BB 0
. 51 4 5.80 NMNEOC 1 0.034 0
. 002 1798 0.004 

## BB 0
. 36 To lal Area = 4.352547E+07 Total He ight = 1104110 Total Amount = 212 1. 307

Pr inted on 31412013 11 :3 8 :5 4 AM 

# Page 31 Page 1 of 1Ch rom Perfect Chromatogram Report 1302 19-61288 dp

### 1600.---------**---------- --** **----------------------~------------------------------__,** 

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Raw File Na me 

### = C:ICPDATAllnst#04120131030413.0023
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# , 6.0 7.0 80 9 .0

Date Taken (end) 

### = 3/4/201311 :37 :34 AM Method Fi le Name = C :\Cpmethods\lnst #04\2013\Method2S . 1 ,3_low.met Dilut ion Factor = 1 Calibrat i on F il e Name 

### = C:ICpmethodsllnst #0412013\M25
. 1 , 3Iow- 0 1 1013.CAL

Peak # Ret. Time Name Amount Amt% Area Area 

### % Type Width 1 0.87 Carbon Monox ide 7.923 0
. 374 112225 0.258 

## BV 0
. 16 2 1.05 Methane 12
. 134 0.573 236970 0.545 

## VB 0.17 3 1
. 90 Carbon D ioxide 2098
. 037 99.052 43110396 99
. 192 

## BB 0.51 4 5
. 86 NMNEOC 1 0
. 033 0.002 1772 0.004 

## BB 0.36 Total Area = 4.346136E+07 Tota l He ig ht = 1103681 Total Amount = 2118.127

Printed on 

### 3/4/2013 11 : 38 : 59 AM 

# Page 32 Page 1 of 11600
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### = 3 1 412013 11510 1 AM Method F i le Na m e = C : I Cpmethodsllnst #0412013 I Method25
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### = C :I Cpmet h ods l lnst #04120131M251 , 310w-01 1 0 1 3 CAL

Peak# 

### Re t. Time Name 

### Amount Amt % 

### Area Area % Type Width 1 0
. 88 

### Carbon Monoxide 14
. 025 0
. 669 198640 0.462 

### BB 0
. 30 2 1
. 97 

### Carbon D iox ide 2082
. 876 99.330 42 7 98864 99.535 

### BB 0
. 50 3 6
. 26 NMNEOC 1 0.026 0.001 1370 0
. 003 

### BB 020 Tota l A rea 

# =4.299888E+07 Total Height 

# = 1081921 Total Amount 

# =2096
. 926

Pr i nted o n 3 14 12013 12 : 07 : 32 PM 

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### = C: I Cpmeth odslinst # 04 12013I M 25.1 , 3 Iow - Ol 1onCA l

Peak # 

### Ret. T ime Name Amo u nt Amt % Area Area 

### % Type W idth 1 0
. 87 

### Carbon Monoxi de 1 3.970 0
. 666 197870 0.460 BB 0
. 30 2 1. 93 

### Carbon D ioxide 208 4
. 988 99
. 333 42842268 99
. 53 7 BB 0.50 3 6
. 23 NM N EOC 1 0
. 026 0
. 00 1 1398 0
. 003 BB 0.20 T ota l A rea 

# = 4
. 304154 E +07 Tota l H eight 

# = 1 082516 Tota l Amoun t 

# =2098.985

P ri nted o n 3 / 4/20 1 312 :07 :35 PM 

# Page 34 Pa g e 1 of 11600
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### = FID #4 Chrom Perfect Chro m atog r am Report



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### ;:> iii

50 Tim e - Minu t e s u 0 W Z 

# " Z**~** m 

### ':'

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# " z

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Raw F i le Name; C:\CPDATA\inst#04\2013\030413.0026.raw Date Take n (end); 

### 3/4/20131219 : 11 PM Method F ile Name = C : \Cpmethods\lnst#04\2013\Method25 . 1 , 3_low.met D i l ution Factor = 1 Calibrat i on F i le Name; C : \Cpmethods\inst #04\2013\M25
. 1 , 310w-011 0 1 3
. CAL Peak 

### # Ret. Time Name Amount Amt% A r ea Area 

### % Type Width 1 0
. 88 Carbon Monoxide 12
. 524 0.622 177384 0.430 BB 0
. 29 2 1
. 93 Carbon Diox ide 1999
. 988 99.376 41095688 99
. 565 BB 0.48 3 5
. 97 NMNEOC 1 0.044 0.002 2343 0
. 006 BB 0
. 30 Total Area; 4
. 127542E+07 Total Height; 1081506 To ta l Amount; 2012
. 556

Pri n ted on 

### 3/4/2013 12 :35 :03 PM 

# Page 35 Page 1 of 11600
1400
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### Instrument 

## = Fl O #4 Chrom Perfect Chromatogram Report 130219-61290dp



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## • £; 

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# , , 3.0 4 .0 5.0 6.0 70 8.0 9.0 Time - M inu tes

Raw File Name = C :I CPD A TAll n s1# 04 12 01 31 030413
. 0027 .raw Date T aken (end) 

### = 3/4/201312 :31 :51 PM Method File Name 

# = C :I Cpmethodsllns t # 04120 1 3IMethod25. 1 ,3Jow
. met Di l ution Factor 

# = 1 Calibration Fi le Name 

### = C:ICpm e thodsl l nst #0412013\M251 , 3 1 0w- Oll 013CAL Peak # 

### Ret. Time N ame Amoun t Amt% Area Area % Type Wid t h 1 0
. 88 

### Carbon Monoxide 11
. 352 0
. 565 160791 0
. 390 

## B B 0.28 2 1
. 84 

### Carbon Dioxide 1998.254 99,433 41060064 99
. 605 

## BB 0,48 3 6
. 00 NMNEOC 1 0
. 04 0 0
. 002 2136 0
. 005 

## BB 0
. 31 T otal Area = 4 .1 22299E + 07 T otal He i ght = 1 081180 T o t al Amount = 2009.647

P ri nted on 3/4/201312 :35 :06 P M 

# Page 36 Page 1 of 1

# Calibration Summary

Page 37

### SCAQMD Method 25.1 

## 125 . 3 Calibrati o n Curve (GC/FIDITCA #4) ANALYTE: TNMNEOC las Propane) Analysis Date: 1/10/2013 

### Theoretical Retention time Response RPDfrom 

### Std 

### Theoretical Concentration initial result 

### Concentration (ppmv) (min) Area (+1- 20%) Deviation 

### (ppmv)



### 0 . 11 6 .89 6436 0 . 11 6 . 84 6635 3 .0 140 .71 0. 11 0 . 27 6 . 85 14293 0 . 27 6 . 86 14483 1 . 3 134.35 0.27 0 .54 6 .86 26743 0 .54 6 . 85 28478 6 .3 1226 . 83 0 .54 1.09 6 . 85 62346 1 .09 6 . 85 65692 5 . 2 2365.98 1 .09 2 .72 6 . 84 167066 2 .72 6.85 1583 27 5.4 6179.41 2.72 5.44 6 . 84 282757

____ 5.44
____ 6.84 280611 

### _Q.8 1517.45_ 5.44 AvgRT 

### 6.85 RTWindow +/- 0.20 

### min Calibration Verification Standards : 

### CCV Retention Time Result (oomv % Rec" 

### 2
. 5 ppmv 

### 6 . 84 2.89 106 . 3 2
. 5 PDmv dp 

### 6 .85 2 .79 102 . 5 Must be +/- 10 

### % of Theoretical Conce ntra tion


### Analysl (Inlilial &

## dale)**~** 

# ,I \0113 Lab Direclor (I nil ial & da le): 

# Jd14!

# ~**~I** Analyst: 

### Response Area (mean)



### 6536 14388 276 11 64019 162697 281684 Calb. Type 

### R2 value: Intercept (8) Lin Consl (M) 

### ZG Calculated Concentration (From Mean) 

### 0.12 0.27 0 . 52



# . . 1.19 3.04 5.26 Linear 

### 0 . 9925

0.00 53584.69 Recovery (+1-16 

### '!o) 112 99 95 110 112 97 Y=MX+B Must be> 0. 990 Included 00 <'"l <1)

## ~ p...

# ..**~** 

# « 4 .E +05 3 .E+05
3 .E+05
2 .E+05
2 . E+05
1 .E+05
5 .E+04 

# 1/ O

.E +OO 0 .00 

# TNMNEOC (as Propane) Plot



# ./'

# V 

# * ........./' 

# / 

# V

1 .00 2 . 00 3 . 00 4 .00 Concentration (ppmv) 

## y; 53584.6911 X R 2 ; 

## 0.9925



# ,/

# ~

5 .00 

# I

6 .00 0- <'1

# ~ p...

### Date: 

### 01/10/2013 Analyst: 

## ZG Analvte: Conc
. MOL #1 NMOC 

### 0 .050 0 . 058

Analvte : Mean Std Dev NMOC 

### 0 .051 0 .005 

## FlO MOL Study per SCAQMO 

## 25.1/25.3 Instrument: GC/FID #4 Units: ppmV MOL#2 MOL#3 MOL 

### #4 MOL #5 MOL #6 MOL#7 

### 0 .050 0 .054 0 .043 

### 0 .051 0 .056 0 .047 

### MOL· Method Detection Limit Study per USEPA Guidelines MOL MRL 

### 0 .01 6 0 .0 4 9 M OL (M etho d**Otl ~c** **ion** Li mit) (7 re pli cQf r '$) 

### = St Li n d a :d D evi ation x 3
. 1 " 3 MR L ( M i ni m u m Rp. p ort i ng Li mi t )**~** MOL x 3 .0 Is the spiked concentration 

### < 10 times the calculated MOL

# 0 N Definition: MDL- The minimum concentratio n 

### of a s ubst a n ce thar 

### ca n be Id ufJtified , measured and reported with 

### a 99% confidence interval, t /J at the a na/ y te concen tratio n 

### is greater than lero :tnd is det e rmined fro m U w analysis of 

### a sample i n 

### a given matrix containing the a n al yf

u. De finition : MRL - The sma lle st measu , red concen t ra tion 

### ora s ubst ance that 

### can be re liably measured by 

### using a give n analytical metho d
. 

## o 

# """ 

# '" 00 CO 

### >l-.Analvte : LOD LOQ Canc./MOL NMOC 

## o**O~H** 

### 0052 3 

### Alternative Supporting Calculations M%Rec S : N Ratio**10~** 

### .S) . 0[1 ( Lim it o f Det ect ion ) St a n dard O('>li. i iIQ :l )' : '\.0 

### LOO ( L:m t t of Qu a n tltatio n) = 

### St-lnd<1rd**Dr-~, ~tlo** **n** 

### x 1 0 :.,.l e" n · ( Rcc -( Mc 2 n R esf T r u o Valuc) y 1 ClO' 't. Is the Mean % Ree between 80% and

### 120%?~ I N**~onc.!M DL** **~** Conce nt ratio n J MOL Is the Conc.lMDL between 2 to 

### 5?{J)1 N 5 1qna l t o N o i s l; Ratio · ( Ma a nl St d D fW ) Is the signal to Noise Ratio between 2.5 and 

### 10(2)1 N 

### Definitio n : LOD - The lowest concentration that can be determined to be st a r;st ica lly diffe rent from 

### a bla nk. Definit i on : 

### LOO · The concentration above which quantit ative re sults ca n be obtain ed with 

### a specific degree 

### of confide n ce. Analyle : PQL RL NMOC 0
. 1 04 0.1 04 

### Proposed PQL and RL Pra c t i c a l Qu a n titation Li mi t Is the PQl 2 to 5 times higher than the 

### lOa?(Jjf N 

### Re portmg limi l Is the RL equal to or greater than the 

### pal

# -(5)1 N PO L (pra cti c d l QU3 n t i t ali o n Umi t) = Es t a b l i s h ed 

### by the labo ra t ory**as~ d**  o n t h e: a bove c (l i cu lati ons R L ( R c po rt in q li mit) :.**Es.ta bli** **d** by th o l a b ora tory b ased on th e PQ l an d/o r m et h o d. Definition : P OL - Th e low es t level tl1at can be reliably achieved witlli n spo cified limits of pr eci sion an d ac c uracy during rou tine laboratory operating conditio ns. In addition , if qllatit a ting 

### at th is level, the lowest point of the calib ra tio n curve must b e 

### set at th is point. Comments : Ana lys t (sign & date ): 

### $3 \ \ t 0 \ (5 Lab Director (sign & date) : 

# 1141# 

# - '<t 

# ..,**~** 0...

## Appendix 

## C.6 PM 

## by SCAQMD Method 

## 5.1

R521 0729 

## C-10SCAOMD METHOD 5.1 PARTICULATE TEST DATA SUMMARY CUenU1.ocalion. Unit Samp l e Location Test No. Tes! Melhoct Dale Start T ime Slap Ti me Sample Train Pilot Factor MeIer Cal Factor S la ck Area (SCI It) S ampl e Time (Min) Bar Press (In Hg) Nozzle Dlam (in) Slack Press (iwg) Stack Temp (F) Vel Head (iwg) Stack 02 (%0) Stack C02**~~ )**  Meter Vol (acf) Meter Temp (F) Meier Press (iwg) liqUid Vol (ml) Sid Sample Vo l (SCF) Moistu re Fraction Stack Gas Mol Wt Stack Gas Veloc i ty 1ft/sec) Stack Flow Rate (waclm) Slack F low Rate ( elsctm) Isoklnetlc Ratio ( %) Facility Average Gas Flow (hscfh)
. Facility AI/erage G as Flow (MMscfh)
. . To ta l We i ght Gain, mp .. Partic ul ate Emi ssions Grain Load i ng . grldscf.. Grain Loedi ng @ 3% 02
. Grain Loading@ I S +' . 02
.. Gra in Lo ading @ 12% C02
. Mass Emlss;ons,lblhr 1 •• • ..................... .. ............. . Emission Rale.lb/MMSCF 1 ) 11 Iblhr per Rule 475 PM limit Gemma Sent i nel 5 S·51STK·PM·1QO.l

SCAOMD 5 . 1

212512013

10 . 56 15 :20 12-WCS

0
. 84 0
.98 143 . 14 240 29
.60 0
. 234 2.60 735.8 1 .52 09 13.017 ' . 34 187.Q32

73.9 1.85 3916 177.408 0
. 090 28
. 22 105
. 43 905. 4 62 356.867 99 . 24 8747
. 4 0
.675 32 0 .0003 0 .0007 0
.0002 0.0008 0.85 0 . 97 Reference Temp ( F). 60 Fuel Nat
. Gas Data By AA Average Lim its

2
. 80 735
. 8 1
. 5209 13
. 5 4 . 3 187
. 03 73
. 9 1 .85 39 1
. 6 177 408 0 . 090 28 . 22 105.43 905.462 356 . 867 99 . 24 8747,4 0 . 875 3 . 2 0
. 0003 0 . 0007 0.0002 0 . 0008 0 . 85 0 . 97 Limits 0 .01 0.1 11 5
. 71**Senljo~1** Unil5 100% I' M.. \II Summa " l 16 :01) 3 :30 PM

# I**~**

# .~.**.** I- : 

# =**~ ~**  

# §! r--.

# ~**~** 

### l- 

# I l-I1-,

# ~

Page I

# pe.lla**~** SCAQMD METHOD 5
. 1 PARTICULATE TEST DATA SUM MARY ClienULocation. UnJl Sample l.ocati on Test No. Test Method Dale Slart Time Stop Time Sample T rain Pilot Factor Meter Cal Faclor Stack Area (sq It) Sample Time (Min) Bar Press (in Hg) Nozzle Diam (in) Slack Press (iwg) Slack Temp (F) Vel He ad (iwg) S la ck 02 (%l S la ck C02 (% ) Meier Vol (ad) Meter Temp (F) Meter Press (iwg) Liguld V ol (mt) Sid Sample Vol (SCF) Moislure Fraction Slac k Gas Mol Wt Slack Gas V elocity (ft/sec) Slack Ftow Rate (waclm) Stack Ftow Rate (dscfm) IsoklneUc Ratio /%) FaC ili ty Average Gas Flow ( hscfh) , Fac ili ty Average Gas Flow ( MMsclh ) , Total We i ght Gain. m g.. Particulate Em issions Gra i n Loading , gr/dscl
... Gra i n Loading @ 3% 02
.. . G ra in Lo ad ing@ 15% 02
... . G ra i n Loading@ 12%**~02** .. . Mas!> Emissions, Ib/hr •.•.• • Emission Rate
. l bIMMSC F 1) 11 Iblhr per Rule 475 PM Limit 2 ) 5·PM lesl res u!ls d i scarded due to glass and graph i te from sampling equipment Gemma Sentinel 5 S-5ISTK-PM

- 75

- 1

SCAOMO S . I

2125/20 13

16 : 42 20 : 54 !2-Wes

0 . 84 0 .980 1 43 . 14 240 29 .60 0.234 2
. 80 732
. 7 1
.4524 14
. 0 1 3
. 91 182
. 212

6< . 0 1 . 77 347 . 6 17 6 . 068 0 .090 28
. 18 1 02
. 97 884 , 360 349.451 100 . 58 7063 . 1 0 . 706 3 . 2 0
. 0003 0
. 0007 0
. 0002 0
. 0009 0
. 84 1. 19 Reference T emp (F). 60 Fuel Nat Gas Data By AA Average limits

2 .60 732 . 7 1.4524 14 . 0 3 . 9 162 . 21 64 . 0 1 . 77 347 .6 176 ,068 0 . 090 28 ,18 102 . 97 884,360 349 ,4 51 1 00 . 58 7063 . 1 0 . 706 3 . 2 0 . 0003 0 . 0007 0 . 0002 0 . 0009 0.84 1 . 19 Limits 

## am 0 . ' 

# " 5 . 71

Sc," incl Un;1 S 75 % PM ..

## ,I. Summary )116nOI) 3 : )0 PM

# 1-: 1- . , I

Page I

# Della**~** ... (

# . .....**.** 

### ' ''-' SCAQMO METHOD 5
. 1 PARTICULATE TEST DATA SUMMARY Client/Location. Unit Sample Locatlon Test No
. Test Method Da to Start Time StOP Time Sa m p l e Tra i n P i

lo t Faclor Meier Cal Factor Slack Are a (sq ttl Samp l e Time (Min) Bar Press (in Hg) Nozzle Diam (In) Sl ack Press (iwg) Stack Temp ( F) Vel Head ( iwg) Siaclot02 ( % ) Slack C02 ( % ) Melo r Vo l (aci) Meter Temp (F ) Meier Press ( iwgl liquid Vo l (mil Std Sample Vol (SCF) Mois t ure F ract i o n Stack G as Mo l Wt Stack Gas Ve l ocity (tusee) S ta ck Flow R ate (wac f m) Slack Flow R ate ( dscfm) I so k ln etic Ratio 1 %1 Faci li ty Average Gas Flow ( hscth)
.. Fa cili ty Average Gas Flo w ( MMsc:fh )
.. Tota l Weight Ga i n . mg . Part iculat e Emissions G r am Loading
. gr /dsc f
.. Grain Loading @ 3 % 02 Gram Loading @ 1 5% 02 Grain Lo ad in g@ 1 2% C02
... MaliS Emissions , Ib/ hr'•.......•.•...... . ••.• Emi u lon Ra le
. lbIMMSCF 1) 11 Ib lh r per Rule 475 PM lim it Ge mma Sentinel 5 S - 5/STK - PM · SQ · \

SCAQMD 5
. 1

212612013

8 : 30 12 :40 12 - WCS

0 . 84 0 . 98 1 43 . 14 '40 29 . 47 0 . 234 1 . 90 775 . 5 0 . 7267 14 . 10 3 . 85 132 . 322 71 . 1 0 . 65 26 4 125
. 310 0
.089 28
. 18 74
. 37 638.74 3 242. 27 3 103 .26 539 1. 5 0 . 539 4 . 0 0
. 0005 0
. 0013 0
. 0004 0
. 0015

1
.0 2 1
. 90 Reference Tomp (F). 60 Fue l Nat. Gas Dala Bv AA Average Limits

1 . 90 775 . 5 0 . 7267 14 . 1 ' . 9 132 . 32 71.1 0 . 85 264
. 0 125
. 310 0
.089 28 .18 74.37 638, 74 3 242 ,273 103 . 26 5391
. 5 0
. 539 4 .0 0
.0005 0
. 0013 0.0004 0.00 1 5

1.0 2 1
.90 Lim i ts 0
.0 1 0 . 1 11 5
. 71**nli n~l** **lJ ni** **l ~;.()%** **l>M.~ s** 

Summary

. l!l6 1 ZOI3 k lOI'MI 

### l":C i i 

# I t-



# ,**~** 

# - t- . . 

# EI , 

# , , , , t-:

# ~ , 

# tI ,

P age I

### CPV SENTINEL UNIT 5 PARTICULATE TEST STACK O 2 • 

### CO 2 

### DATA Test 

## #: S-5/STK-PM-100-1 Date: 2/25/2013 

### Time: 10:56 15:20 Load: 106MW O 2 

### CO 2 

### Range 20 10 Cal Gas 18.98 9.62 Analyzer Zero 0.14 0.03 Analyzer Span 19.02 9.62 Pre-Bias Zero 0.16 0.05 Pre-Bias Span 19.00 9.60 Post-Bias Zero 0.16 0.23 Post-Bias Span 18.81 9.82 Average Bias Zero 0.16 0.14 Average Bias Span 18.90 9.71 Pre-test zero bias 0.1% 0.2% Pre-tesl span bias -0.1% -0.2% Post-test zero bias 0.1% 2.0% Post-test span bias -1.1% 1.9% Zero Drift 0.0% 1.8% Span Drift -1.0% 2.2% Test Results (from data logger average) Average 13.46 4.45 Cal Corrected 13.47 4.34

O 2 

### CO 2 

### Date Time % % 2/25/2013 

### 10:55:00 13
. 551 4.4 2/25/2013 

### 10:56:00 13.542 4.405 2/25/2013 

### 10:57:00 13.533 4.41 2/25/2013 

### 10 : 58:00 13.518 4.421 2/25/2013 

### 10:59:00 13.495 4.434 2/25/2013 

### 11 :00:00 13.499 4.434 2/25/2013 

### 11 :02:00 13.545 4.418 2/25/2013 

### 11 :03:00 13.529 4.423 2/25/2013 

### 11 :04:00 13.533 4.42

### 2/ 25 / 2013 11 

## :05 : 00 13 .533 4.42 2/

25 / 2013 11 

## :06 : 00 13 . 525 4.426 2/

25 / 2013 11 

## :07 : 00 13 . 515 4.435 2/25/2013 11 

## :08:00 13.486 4.45 2/

25 / 2013 11 

## :09 :00 13.473 4.458 2/

25 / 2013 11 

## :32:00 13 . 505 4.445 2/25/2013 11 

## :33 :00 13 . 522 4.447 2/

25 / 2013 11 

## : 34 :00 13 . 519 4.452 2/

25 / 2013 11 

## :35:00 13 . 519 4 .454 2/

25 / 2013 11 

## :36:00 13 . 521 4.45 2/

25/2013 11 

## :37 :00 13 . 526 4.447 2/

25/2013 11 

## :38:00 13 .528 4.446 2/

25 / 2013 11 

## : 39 :00 13 . 517 4.453 2/

25/2013 11 

## :40:00 13.513 4.456 2/

25 / 2013 11 

## :41 :00 13.525 4.449 2/

25 / 2013 11 

## :42 :00 13 .535 4.443 2/

25/2013 11 

## :43:00 13 .534 4.441 2/25/2013 11 

## :44:00 13.534 4.438 2/

25 / 2013 11 

## :45:00 13 . 536 4.435 2/

25 / 2013 11 

## :46 :00 13.557 4.422 2/25 / 2013 

## 11 :47 :00 13 . 557 4.42 2/

25/2013 11 

## :48:00 13 .558 4.42 2/

25 / 2013 11 

## :49 :00 13 .555 4.419 2/

25 / 2013 11 

## : 50 :00 13 .577 4.409 2/

25 / 2013 11 

## : 52 : 00 13 .505 4.447 2/

25 / 2013 11 

## : 53 :00 13 .504 4.448 2/

25 / 2013 11 

## :54 :00 13.498 4 .45 2/25/2013 11 

## :55 :00 13 .51 4.448 2/

25/2013 11 

## :56 : 00 13 . 5 4.454 2/25 / 2013 11 

## : 57 : 00 13 . 504 4.451 2/

25 / 2013 11 

## :58 :00 13.499 4.454 2/

25/2013 11 

## : 59 : 00 13.497 4.459 2/

25 / 2013 

## 12 :00 :00 13 . 515 4.45 2/

25 / 2013 

## 12:01 : 00 13 . 519 4.449 2/25/2013 

## 12 :02:00 13.521 4.449 2/25/2013 

## 12 :03 : 00 13 . 519 4.45 2/

25 / 2013 

## 12 :04 : 00 13 . 536 4.438 2/

25/2013 

## 12 :05 :00 13 .55 4.431 2/25/2013 

## 12:06 : 00 13.548 4.429 2/

25 / 2013 

## 12 :07 : 00 13 . 555 4.421 2/

25 / 2013 

## 12 :08:00 13 .554 4.419 2/

25/2013 

## 12 : 10:00 13 . 584 4.426 2/

25 / 2013 

## 12:11 :00 13.496 4.434 2/25 / 2013 

## 12 : 12 :00 13.494 4.432 2/25/2013 

## 12:13:00 13.5 4.433 2/

25/2013 

## 12:14:00 13 . 501 4.431 2/

25 / 2013 

## 12:15 :00 13 .5 4.432 2/25 / 2013 

## 12:16 :00 13.499 4.433 2/25/2013 

## 12 : 17 : 00 13.493 4.435 2/

25 / 2013 

## 12 : 18 : 00 13.493 4.436 2/25/2013 

## 12 : 19 : 00 13.493 4.437

### 2/ 25 / 2013 

### 12 :20 : 00 13.488 4.436 2/

25/2013 

### 12 : 21 :00 13.489 4.437 2/

25 / 2013 

### 12 : 22 : 00 13.492 4.438 2/25 / 2013 

### 12 :23 : 00 13
.495 4.436 2/

25 / 2013 

### 12 :24 : 00 13.496 4.436 2/

25 / 2013 

### 12 :25:00 13.487 4.439 2/

25 / 2013 

### 12 :26:00 13.484 4.443 2/

25 / 2013 

### 12 :29 : 00 13.496 4.436 2/

25 / 2013 

### 12 : 30 : 00 13.486 4.44 2/25 / 2013 

### 12 : 31:00 13.495 4.435 2/

25 / 2013 

### 12 : 32:00 13.487 4.44 2/

25 / 2013 

### 12 : 33:00 13.492 4.436 2/25 / 2013 

### 12 : 34:00 13
.49 4.436 2/

25 / 2013 

### 12 : 35 : 00 13.48 4.441 2/

25 / 2013 

### 12 : 36:00 13.483 4.436 2/

25 / 2013 

### 12 : 37:00 13.473 4.44 2/

25 / 2013 

### 12 : 38:00 13.49 4.429 2/25/2013 

### 12 : 39 : 00 13
. 503 4.423 2/

25 / 2013 

### 12 : 40 : 00 13
. 494 4.431 2/25/2013 

### 12 : 41:00 13.496 4.43 2/

25/2013 

### 12:42:00 13
. 5 4.43 2/

25 / 2013 

### 12 : 43:00 13
. 505 4.428 2/

25 / 2013 

### 13 : 03:00 13.424 4.459 2/

25 / 2013 

### 13 : 04:00 13.427 4.462 2/

25 / 2013 

### 13:05:00 13.424 4.465 2/

25 / 2013 

### 13:06:00 13.422 4.466 2/

25 / 2013 

### 13 : 07:00 13.425 4.462 2/

25 / 2013 

### 13 : 08:00 13.422 4.466 2/25/2013 

### 13 : 09 : 00 13.422 4.465 2/

25 / 2013 

### 13:10:00 13.426 4.462 2/

25 / 2013 

### 13 : 11 : 00 13.432 4.456 2/

25 / 2013 

### 13:12 : 00 13.434 4.455 2/

25 / 2013 

### 13:13:00 13.435 4.456 2/

25/2013 

### 13 : 14:00 13.437 4.453 2/

25 / 2013 

### 13 : 15 : 00 13.451 4.448 2/

25 / 2013 

### 13 : 16 : 00 13.462 4.445 2/

25 / 2013 

### 13 : 17 : 00 13.455 4.448 2/

25 / 2013 

### 13 : 18 : 00 13.466 4.446 2/

25/2013 

### 13 : 19 : 00 13.458 4.45 2/

25 / 2013 

### 13 :20:00 13.465 4.448 2/

25 / 2013 

### 13 :22:00 13.431 4.48 2/

25 / 2013 

### 13:23:00 13
. 396 4.49 2/25/2013 

### 13:24 : 00 13
. 394 4.492 2/

25 / 2013 

### 13 :25 : 00 13
. 396 4.487 2/25 / 2013 

### 13 : 26 : 00 13.405 4.483 2/

25 / 2013 

### 13 :27 : 00 13
. 395 4.488 2/25 / 2013 

### 13 :28 : 00 13
. 394 4
. 49 2/25 / 2013 

### 13 :29:00 13.393 4.493 2/

25 / 2013 

### 13:30:00 13.395 4.489 2/

25 / 2013 

### 13:31:00 13
. 396 4.487 2/

25 / 2013 

### 13 : 32:00 13
. 396 4.486

### 2/ 25 / 2013 

## 13:33 :00 13 .3 91 4 .493 2/

25 / 20 1 3 

## 13:34 :00 13 . 382 4.497 2/25 / 20 1 3 

## 13:35 : 00 13 .38 4.498 2/

25 / 2013 

## 1 3 :36:00 13 .385 4.494 2/

25 / 20 1 3 

## 13:37 :00 13.375 4.499 2/

25 / 2013 

## 13:38:00 13 .3 58 4 . 509 2/

25 /2 013 

## 13:39 :00 13 . 358 4 . 511 2/

25 / 2013 

## 13 :40 :00 13 .3 62 4 . 50 8 2/

25 / 2013 

## 13 :41:00 13 . 36 4 . 509 2/

25 / 2013 

## 13:42:00 13 . 359 4 . 5 1 1 2/

25 / 2013 

## 13:44:00 13 . 503 4.46 2/25/2013 

## 13:45:00 1 3 .431 4.467 2/

25 / 2013 

## 13 :46:00 13.421 4.476 2/

25 / 2013 

## 13:47 :00 13.421 4 .472 2/

25 /2 013 

## 13:48 :00 13.421 4.472 2/25 / 2013 

## 13:49 :00 13.42 4.472 2/

25 / 2013 

## 13 : 50:00 13 .422 4.466 2/

25 /2 013 

## 13 : 51 :00 13.428 4.461 2/25 / 2013 

## 13 : 52 :00 13.421 4.463 2/

25 / 2013 

## 1 3:53 :00 13.42 1 4.46 2/

25 / 2013 

## 13 : 54:00 13.421 4.456 2/

25 /2 013 

## 1 3 : 55:00 13.42 4.459 2/

25 /2 013 

## 13:56:00 13.423 4.45 2/25 /2 013 

## 13 : 57 :00 13.422 4.452 2/25 / 2013 

## 1 3 : 58 : 00 13.418 4.453 2/

25 / 2013 

## 13:59:00 13.421 4.449 2/25/2013 

## 14:02 :00 13.432 4.433 2/

25 / 2013 

## 14:03 :00 13.433 4.427 2/25 / 2013 

## 14 : 04 :00 13.434 4 .427 2/25/2013 

## 1 4 : 05 :00 13.433 4.427 2/

25 / 2013 

## 14 :06 :00 13.432 4.425 2/25/2013 

## 14 :07 :00 13.435 4.423 2/25 / 2013 

## 1 4:08:00 13.441 4.419 2/

25 /2 013 

## 14:09:00 13.433 4.425 2/

25 /2 013 

## 14:10 :00 13 .432 4.429 2/25 /2 013 

## 14:11:00 13.435 4.429 2/2 5 / 2013 

## 14:12 :00 13.468 4.413 2/

25 / 2013 

## 14:13:00 13.47 4.411 2/25/2013 

## 1 4:14 :00 13.471 4.4 1 2 2/

25 /2 013 

## 14 : 15:00 13.471 4.413 2/25 / 2013 

## 14:16 :00 13.47 4.4 1 4 2/25/2013 

## 14:17:00 13.47 4.41 8 2/

25 /2 013 

## 14:38 :00 13.428 4.459 2/25 / 2013 

## 1 4:39:00 13.428 4.465 2/

25 / 2013 

## 14:40 :00 13.434 4.465 2/

25 /2 013 

## 14:41 :00 13.433 4.465 2/

25 / 2013 

## 14 :42 :00 13.433 4.467 2/25 /2 013 

## 14:43 :00 13 .434 4.462 2/25/ 2013 

## 14 :44 :00 13.435 4.462 2/25 /2 0 1 3 

## 14 :45:00 13.464 4.453 2/

25 / 2013 

## 14 :46 : 00 13.469 4.455

### 2/25 / 2013 

## 14 :4 7 :00 13.471 4.455 2/

25 / 2013 

## 14:49 :00 13.485 4.482 2/25/2013 

## 14:50:00 13.423 4.49 2/

25 / 2013 

## 14 : 51 :00 13.423 4.493 2/

25 / 2013 

## 14:52 :00 13.423 4 .495 2/

25 / 2013 

## 14 :53 : 00 13.428 4.492 2/

25 / 2013 

## 14:54 : 00 13.426 4.495 2/

25 / 2013 

## 14:55:00 13.421 4.499 2/

25 / 2013 

## 14:56 : 00 13.421 4.498 2/25/20 1 3 

## 14 :57 : 00 13.405 4.51 2/25/2013 

## 14 :58 : 00 13 .396 4 . 516 2/

25 / 20 1 3 

## 14:59 : 00 13 .396 4 .519 2/

25 / 2013 

## 15 : 02:00 13.442 4.482 2/

25 / 2013 

## 15 :03 : 00 13.44 4.482 2/25 / 2013 

## 15:04 :00 13.443 4.48 2/

25/2013 

## 15:05 :00 13.436 4.483 2/25/20 1 3 

## 15:06:00 13.446 4.475 2/

25/2013 

## 15 :07 : 00 13.437 4.477 2/

25/ 2013 

## 15 :08 : 00 13.436 4.478 2/

25 / 2013 

## 15 :09 :00 13.433 4.476 2/25 / 2013 

## 15 : 10 :00 13.432 4.48 2/

25 / 2013 

## 15 : 11 :00 13.435 4.474 2/25/2013 

## 15:14:00 13.439 4.465 2/

25/2013 

## 15:15:00 13.441 4.461 2/

25 / 2013 

## 15:16 : 00 13.435 4.463 2/

25 / 2013 

## 15 : 17 :00 13 .435 4.464 2/

25 / 2013 

## 15 : 18:00 13.434 4.462 2/

25/2013 

## 15:19 :00 13.434 4.464 2/

25/2013 

## 15 :20:00 13.435 4 .458

Average 

## 13 .46 4.45

### CPV SENTINEL UNIT 5 PARTICULATE TEST STACK O2 • 

### CO 2 

### DATA Test 

## #: S-5/STK-PM-75-1 Date: 2/25/2013 

### Time: 16:42 20:54 Load: 80MW O 2 

### CO 2 

### Range 20 10 Cal Gas 18.98 9.62 Analyzer Zero 0.13 0.12 Analyzer Span 18.94 9.73 Pre-Bias Zero 0.17 0.18 Pre-Bias Span 18.88 9 .74 Post-Bias Zero 0
. 15 0.14 Post-Bias Span 18
. 81 9
. 69 Average Bias Zero 0.16 0.16 Average Bias Span 18.85 9.71 Pre-test zero bias 0.2% 0.6% Pre-test span bias -0
. 3% 0.1% Post-test zero bias 0.1% 0.2% Post-test span bias -0.7% -0.5% Zero Drift -0.1% -0.4% Span Drift -0.4% -0
. 6% Test Results (from data logger average) Average 13.95 4.04 Cal Corrected 14.01 3
. 91

O 2 

### CO 2 

### Date Time % % 2/25/2013 16:43:00 13.941 4.078 2/25/2013 16:44:00 13.948 4.077 2/25/2013 16:45:00 13.949 4.078 2/25/2013 16:46:00 13.952 4.079 2/25/2013 16:47:00 13.944 4
. 082 2/25/2013 16:48:00 13.942 4.086 2/25/2013 16:49:00 13.932 4.091 2/25/2013 16:50:00 13.931 4.092 2/25/2013 16:51 :00 13.929 4.09 2/25/2013 16:52:00 13.936 4.082

### 2/ 25 / 2013 

## 16 : 53 :00 13 .927 4 .085 2/

25 / 2013 

## 16 :54 : 00 13 .915 4 .09 2/

25 / 2013 

## 16 : 55:00 13 .933 4.078 2/25/2013 

## 16:56:00 13 . 933 4 .077 2/

25/2013 

## 16:57:00 13 . 939 4 .075 2/

25/2013 

## 16:59:00 13 . 976 4 .066 2/

25/2013 

## 17:00:00 13 .943 4.075 2/

25 / 2013 

## 17:01:00 13.936 4 .082 2/

25 / 2013 

## 17 :02:00 13.938 4 .082 2/25/2013 

## 17 :03:00 13.922 4.091 2/25/2013 

## 17:04:00 13.95 4 .075 2/

25 / 2013 

## 17:05:00 13.936 4 .084 2/

25 / 2013 

## 17:06:00 13.917 4 .095 2/

25 / 2013 

## 17:07 :00 13 . 914 4 .094 2/

25 / 2013 

## 17 :08 :00 13 . 951 4 .073 2/

25 / 2013 

## 17 :09:00 13 . 942 4 . 076 2/

25/2013 

## 17 : 10:00 13 . 926 4 .082 2/25/2013 

## 17:11:00 13.937 4 .076 2/

25 / 2013 

## 17:12:00 13.896 4 .098 2/25 / 2013 

## 17:13:00 13 .899 4 .094 2/

25 / 2013 

## 17 : 14 :00 13 .91 4 . 089 2/

25 / 2013 

## 17 : 16:00 13.995 4 . 043 2/

25/2013 

## 17 : 17:00 13 .984 4 .044 2/25/2013 

## 17 : 18:00 13.969 4 . 052 2/25/2013 

## 17 : 19:00 13.962 4.053 2/

25 / 2013 

## 17 : 20 :00 13 .958 4.051 2/25 / 2013 

## 17 :21 :00 13 .948 4 .053 2/

25/2013 

## 17 : 22 : 00 13 .942 4.054 2/25/2013 

## 17 :23 : 00 13 .936 4 .058 2/

25/2013 

## 17:24 :00 13.93 4.059 2/25/2013 

## 17:25 : 00 13 .922 4 .061 2/25/2013 

## 17 :26 :00 13.917 4 .064 2/

25 / 2013 

## 17 :27:00 13 . 927 4.06 2/

25 / 2013 

## 17 :28:00 13 .919 4 .064 2/

25 / 2013 

## 17:29:00 13 . 935 4 . 051 2/

25 / 2013 

## 17:30:00 13 . 962 4 .036 2/

25 / 2013 

## 17 :31 :00 13.946 4 .04 2/25/2013 

## 17:33:00 13.933 4.051 2/

25/2013 

## 17:34:00 13.92 4.052 2/

25 / 2013 

## 17 :35:00 13 .926 4 .047 2/

25 / 2013 

## 17 : 36 : 00 13 .915 4 .055 2/

25/2013 

## 17 : 37:00 13 .918 4 .052 2/

25 / 2013 

## 17 :38 : 00 13 .912 4.057 2/

25/2013 

## 17 : 39 :00 13 .931 4.046 2/25/2013 

## 17 :40:00 13.913 4 .057 2/

25/2013 

## 17 :41 :00 13 .912 4 .055 2/

25/2013 

## 17:42:00 13 .917 4 .048 2/

25 / 2013 

## 17 :43:00 13 .907 4 .052 2/

25 / 2013 

## 17 :44 :00 13 .903 4 . 051 2/25 / 2013 

## 17:45:00 13 . 894 4 .055 2125 / 2013 

## 17:46:00 13 . 902 4.049

## 2/25/2013 17 :47 :00 13 .904 4.048 2/25/2013 17 :48 :00 13 .915 4 . 041 2/25/2013 18:00:00 13.94 4 . 024 2/25/2013 18:01 :00 13 .94 4 .028 2/25/2013 18:02 : 00 13 .931 4 .037 2/25/2013 18:03:00 13 . 923 4 .044 2/25/2013 18 :04 :00 13 .918 4 . 048 2/25/2013 18:05:00 13 .923 4 .047 2/25/2013 18 :06 :00 13 .919 4 .051 2/25/2013 18 :07 :00 13 .926 4 .047 2/25/2013 18 :08:00 13 .937 4 . 04 2/25/2013 18 :09 :00 13 . 947 4 .038 2/25/2013 18 : 10:00 13 . 952 4 .036 2/25/2013 18 : 11 :00 13.957 4 .037 2/25/2013 18 : 12 :00 13 .965 4 .034 2/25/2013 18 : 13 :00 13 .97 4 .031 2/25/2013 18 : 14 :00 13 .97 4 .032 2/25/2013 18:15 :00 13 . 981 4 .027 2/25/2013 18 : 16 :00 13 .977 4 .027 2/25 /2013 18 : 17 :00 13 .987 4 .018 2/25/2013 18 : 18 :00 13.992 4 . 014 2/25/2013 18 : 19:00 13 .989 4 .017 2/25/2013 18 :20 :00 14 .005 4 .008 2/25/2013 18 :21 :00 14 . 01 4 .007 2/25/2013 18 :22 :00 14 .003 4.009 2/25/2013 1 8 : 24 :00 13 .957 4 .047 2/25/2013 18:25 :00 13 .952 4 . 049 2/25/2013 18:26 :00 13 .965 4 . 042 2/25/2013 18:27 : 00 13 .946 4 .054 2/25/20 1 3 18 :28 :00 13 .946 4.051 2/25/2013 18:29 :00 13 .946 4.054 2/25/2013 18 :30 :00 13 .939 4 .061 2/25/2013 18 :31 : 00 13 .941 4 .058 2/25/2013 18 :32:00 13 .95 4 .055 2/25/2013 18 :33 :00 13.947 4.056 2/25/2013 18:34 : 00 13 .944 4.058 2/25/2013 18 :35 : 00 13 .95 4 .054 2/25/2013 18:36 :00 13 .975 4.042 2/25/2013 18:37 : 00 13 .962 4.049 2/25/2013 18 :38 :00 13 .964 4 .049 2/25/2013 18:39 :00 13 .953 4 .057 2/25/2013 18:40 :00 13 .959 4.056 2/25/2013 18:42 : 00 13 .958 4 .065 2/25/2013 18:43 :00 13 . 941 4 .065 2/25/2013 18:44 :00 13.929 4 .073 2/25/2013 18:45 : 00 13 .927 4 . 07 2/25/2013 18 :46 : 00 13 .937 4 .064 2/25/2013 18:47 : 00 13 .939 4 .059 2/25/2013 18 :48 : 00 13 .938 4.061 2/25/2013 18 :49 :00 13 .945 4 .056 2/25/2013 18 : 50 :00 13 .959 4 .048

### 2/ 25 / 2013 

## 18 : 51 :00 13 . 959 4 .048 2/25 / 2013 

## 18 : 52 :00 13 .973 4.039 2/

25 / 2013 

## 18 : 53:00 13 . 985 4 . 033 2/25 / 2013 

## 18 : 54 :00 13 . 975 4.037 2/

25 / 2013 

## 18 : 55 :00 13 .98 4 . 034 2/

25/ 2013 

## 18:56 :00 13 .976 4 . 035 2/

25 / 2013 

## 18:57:00 13 .971 4 . 038 2/

25 / 2013 

## 18 : 59 :00 13 .988 4 . 028 2/25 / 2013 

## 19 : 00:00 13 .986 4.027 2/

25/ 2013 

## 19 :01 :00 13 .987 4.029 2/25/2013 

## 19 :02:00 13 .982 4 .032 2/

25 / 2013 

## 19 :03:00 13 .981 4 . 034 2/25 / 2013 

## 19 :04:00 13 .981 4.034 2/25 / 2013 

## 19 : 05:00 13 .99 4 .022 2/

25/2013 

## 19 :06 :00 13.991 4 .025 2/25 / 2013 

## 19 :07 :00 13 .989 4.026 2/

25 / 20 1 3 

## 19 :08 :00 13 .999 4 .019 2/

25 / 2013 

## 1 9 :09 :00 13 .997 4 .02 2/

25 / 2013 

## 19 : 10 :00 14 .018 4.006 2/

25 / 2013 

## 19:11 : 00 14 . 008 4.012 2/

25 / 2013 

## 19:12 : 00 14 . 004 4 .013 2/

25 / 2013 

## 19 : 13 : 00 14 . 004 4 .013 2/

25 / 2013 

## 19 : 14 :00 1 4 4 .016 2/

25/2013 

## 19 : 30:00 13 .941 4.044 2/

25 / 2013 

## 19 :31 :00 13 .944 4.047 2/25 / 2013 

## 19 :32:00 13 .937 4.051 2/

25 / 2013 

## 19:33 :00 13 . 936 4 .052 2/

25 / 2013 

## 19 :34 : 00 13 . 943 4 .046 2/

25 / 2013 

## 19 :35 : 00 13 . 948 4.043 2/

25 / 2013 

## 19 :36 :00 13 .967 4 . 035 2/

25 / 2013 

## 19:37 : 00 13 . 964 4 . 039 2/

25 / 2013 

## 19 :38 :00 13 .993 4 .02 2/

25 / 2013 

## 19:39 :00 14 . 006 4.011 2/

25/2013 

## 19:40 : 00 14 . 001 4 . 016 2/

25 / 2013 

## 19:42 :00 13 .951 4.059 2/

25 / 2013 

## 19:43 :00 13 . 933 4.064 2/

25 / 2013 

## 19:44:00 13 .93 4 . 068 2/

25 / 2013 

## 19 :45:00 13 .935 4 . 065 2/

25 / 2013 

## 19 :46:00 13 .942 4.062 2/

25 / 2013 

## 19 :47:00 13 .939 4 . 064 2/

25 / 2013 

## 19 :48 :00 13 .951 4 .06 2/

25 / 2013 

## 19 :49:00 13 . 962 4 .057 2/

25 / 2013 

## 19 : 50:00 13.977 4 .047 2/

25 / 2013 

## 19 : 51 :00 13 .966 4 .048 2125 / 2013 

## 19 :52:00 13 .979 4 .034 2/

25 / 2013 

## 19 :54 :00 13.982 4 .03 2/

25 / 2013 

## 19:55:00 13.928 4 .038 2/

25 / 2013 

## 19 : 56 :00 13 .922 4 .035 2/25 / 2013 

## 19 : 57:00 1 3 .921 4 .031 2/

25 / 2013 

## 19 : 58 :00 13 .931 4.02

### 2/ 25 / 2013 

## 19 : 59 :00 13 .907 4 .031 2/

25 / 2013 

## 20 :00:00 13 . 88 4 .043 2/

25 / 2013 

## 20:01 :00 13 . 885 4 .042 2/

25/2013 

## 20 :02:00 13.894 4 .039 2/

25 / 2013 

## 20 :03 :00 13 . 898 4 .041 2/

25 / 2013 

## 20 :06 :00 13 .965 4 .01 2/

25/2013 

## 20 :07 :00 13 .954 4 .015 2/

25 / 2013 

## 20:08 :00 13 .964 4 .012 2 /

25 / 2013 

## 20 :09 :00 13 .956 4 .013 2/

25 / 2013 

## 20 : 10 :00 13 . 981 4 .001 2/

25 / 2013 

## 20:11 : 00 13 .996 3 . 991 2/

25 / 2013 

## 20 :1 2 :00 14 .007 3 . 986 2/

25 / 2013 

## 20 : 13 :00 14 .01 3 .986 2/

25/2013 

## 20 : 14 :00 14 . 009 3 .99 2/

25 / 2013 

## 20 : 15 :00 14 .036 3 . 976 2/

25 / 2013 

## 20 :24 : 00 13 .972 4 .006 2/25/2013 

## 20 :25 :00 13 . 987 4 .013 2/

25 / 2013 

## 20 :26 :00 13 . 985 4 .014 2/25 / 2013 

## 20 : 27:00 13 .985 4 .016 2/

25 / 2013 

## 20 :28:00 13 . 991 4.009 2/

25 / 2013 

## 20 :29 :00 13 . 991 4 . 01 2/

25 / 20 1 3 

## 20 :30 :00 14 .037 3 .984 2/

25 / 2013 

## 20 :31 :00 14 .042 3 .98 2/

25/2013 

## 20 :32 :00 14.045 3 .979 2/

25 / 2013 

## 20 :33 :00 14 .049 3 .98 2/

25/ 2013 

## 20 :35 :00 14 

## 4 .029 2/25/2013 

## 20:36:00 13 .985 4 .028 2/

25 / 20 1 3 

## 20:37 :00 13 .964 4 .039 2/25 / 2013 

## 20 :38 :00 13 .962 4 .04 2/25/2013 

## 20:39 :00 13 .978 4 . 031 2/

25/2013 

## 20:40 :00 13 .941 4 .047 2/

25 / 2013 

## 20:41 :00 13 .954 4 .043 2/

25 / 2013 

## 20:42 :00 13 .943 4 .048 2/

25 / 2013 

## 20:43 : 00 13 .948 4 . 042 2/

25 / 2013 

## 20:44 :00 13 .977 4 .027 2/

25 / 2013 

## 20:45 :00 13 .98 4 .029 2/

25/2013 

## 20:47 :00 13 .964 4 .041 2/

25 / 2013 

## 20 :48:00 13 .94 4 .046 2/

25/ 2013 

## 20:49 :00 13 .948 4 .041 2/25 / 2013 

## 20:50 :00 13 .948 4 .042 2/25 / 2013 

## 20 :51 :00 13 .943 4 .041 2/

25 / 2013 

## 20 :52 :00 13 .938 4 .046 2/

25 / 2013 

## 20 : 53 :00 1 3 .93 4 .05 2/

25/2013 

## 20 :54:00 13.939 4 . 041

## Average 

## 13 .95 4 .04

### CPV SENTINEL UNIT 5 PARTICULATE TEST STACK O2 • 

### CO 2 

### DATA Test 

## #: Date: Time: Load: S-5/STK-PM-50-1 

## 2/26/2013 8:30 12:40 55MW O 2 

### Range 20 Cal Gas 18.98 Analyzer Zero 0.11 Analyzer Span 18.95 Pre-Bias Zero 0.16 Pre-Bias Span 18.96 Post-Bias Zero 0.15 Post-Bias Span 18.84 Average Bias Zero 0.15 Average Bias Span 18.90 Pre-test zero bias 0.2% Pre-test span bias 0.0% Post-test zero bias 0.2% Post-test span bias -0.6 % Zero Drift -0.1% Span Drift -0
. 6% CO 2 

### 10 9.62 0.07 9.68 0.11 9
. 65 0.17 9.73 0.14 9.69 0.4% -0.4% 0
. 9% 0.4% 0.6% 0.8% Test Results (from data logger average) Average 14.08 3.96 Cal Corrected 14.10 3.85

O 2 

### CO 2 

### Date Time % % 2/26/2013 

### 8:31 : 00 14.211 3.9 2/26/2013 

### 8:32:00 14.208 3.901 2/26/2013 

### 8:33:00 14.203 3.902 2/26/2013 

### 8:34:00 14.214 3.894 2/26/2013 

### 8:35 : 00 14
.216 3
. 888 2/26/2013 

### 8:36:00 14.215 3.888 2/26/2013 

### 8:37:00 14 .2 01 3.89 2/26/2013 

### 8:38:00 14.214 3.879 2/26/2013 

### 8:39:00 14.199 3.883 2/26/2013 

### 8:40:00 14.2 3.88

### 2/ 26 / 2013 

## 8:41 :00 1 4 .2 12 3.871 2/

26/ 2013 

## 8:42:00 14 .2 06 3.87 2/26/2013 

## 8:43 :00 14 . 183 3.874 2/26 / 20 1 3 

## 8:44 :00 14 . 185 3 . 872 2/26 / 2013 

## 8:45:00 14.179 3.871 2/

26/2013 

## 8 :47:00 14.169 3 . 881 2/

26 / 2013 

## 8 :48:00 14.147 3 . 887 2/26 /2 013 

## 8:49:00 14 . 145 3.887 2126/2013 

## 8:50 :00 14.148 3 . 883 2/

26 / 2013 

## 8 : 51 :00 14 . 143 3.885 2/26 / 2013 

## 8:52 :00 14.132 3 . 89 2/26 / 2013 

## 8 : 53 :00 14 . 127 3.893 2/

26 / 2013 

## 8 : 54 :00 14 . 123 3.896 2/26 / 2013 

## 8 : 55 : 00 14 .099 3.91 2/26/2013 

## 8 : 56:00 14 .098 3 .9 1 1 2/26/2013 

## 8:57 :00 14.108 3.905 2/2 6 / 2013 

## 8 : 58 : 00 14 . 107 3 . 907 2/

26 /2 013 

## 8:59:00 14 .09 1 3.919 2/26/ 20 1 3 

## 9:00:00 14.092 3.9 1 5 2/

26 / 2013 

## 9:01:00 14 .079 3 . 925 2/

26/2 013 

## 9:02 :00 14.083 3 .921 2/26/ 2013 

## 9 :04 : 00 14.183 3 . 892 2/26/ 2013 

## 9:05:00 14 . 12 3.899 2/26/2013 

## 9:06 :00 14 . 107 3.905 2/

26 / 2013 

## 9:07:00 14 .095 3.912 2/

26 / 2013 

## 9:08:00 14 . 102 3 .91 2/26/2013 

## 9:09 :00 14 . 1 3.912 2/

26 / 2013 

## 9 : 10:00 14 . 095 3 .912 2/

26 / 2013 

## 9:11 :00 14 .097 3 .911 2/26/2013 

## 9:12:00 1 4.089 3.916 2/2 6 / 2013 

## 9 : 13:00 14.095 3 .913 2/

26 / 2013 

## 9 : 14 : 00 14 .093 3 . 9 1 6 2/26/2013 

## 9:15 :00 14.093 3.916 2/26 /2 013 

## 9:16:00 14 .089 3.917 2/26 / 2013 

## 9:17:00 14 .096 3 .9 14 2/26/2013 

## 9:18 :00 14. 1 03 3.91 2/26 / 2013 

## 9:19 :00 14 .1 3 .912 2/26/2013 

## 9:21:00 14.178 3.897 2/26 /2 013 

## 9:22 :00 14 . 111 3 .904 2/

26 /2 013 

## 9 :23 :00 14.119 3 .901 2/26/2013 

## 9:24:00 14.12 3 .902 2/2 6 / 2013 

## 9:25 :00 14 .1 22 3.899 2/

26 / 2013 

## 9:26 :00 14 .1 23 3.899 2/26/2013 

## 9:27 :00 14.119 3.901 2/26 / 2013 

## 9:28:00 14 . 106 3 .907 2/26 / 2013 

## 9 :29:00 14 . 106 3.909 2/26/2013 

## 9:30 :00 14 . 102 3 .912 2/

26 /2 013 

## 9:31 :00 14 . 102 3 .912 2/

26 / 2013 

## 9:32 :00 14.1 3.913 2/26/2013 

## 9:33:00 14 . 107 3 .91 2/26 / 20 1 3 

## 9 :34 :00 14 .1 04 3 .912

### 2/ 26 / 2013 

## 9 :35:00 14.107 3 . 912 2/

26 / 2013 

## 9:36:00 14.099 3 . 915 2/

26 / 2013 

## 9:37:00 14 . 102 3 .914 2/26 / 2013 

## 9 : 50 :00 14 .089 3 . 926 2/26 / 2013 

## 9 : 51 :00 14 .088 3 .932 2/

26/2013 

## 9:52 :00 14 .086 3 .938 2/

26/2013 

## 9:53:00 14.083 3 .938 2/

26 / 2013 

## 9 : 54 :00 14 .092 3 .929 2/

26 / 2013 

## 9 : 55 :00 14 .096 3 .927 2/

26/2013 

## 9:56 :00 14 .076 3.937 2/

26/2013 

## 9:57:00 14 .051 3 .945 2/26 / 2013 

## 9 : 58:00 14 .066 3 .939 2/

26 / 2013 

## 9 : 59 :00 14 .057 3 .943 2/

26/2013 

## 10:00:00 14 .069 3.938 2/26 / 2013 

## 10:01 : 00 14 .077 3 .936 2/

26 / 2013 

## 10:02 :00 14 .062 3 .941 2/

26 / 2013 

## 10:03 :00 14 .057 3 .945 2/26/2013 

## 10 :04:00 14 .04 3.954 2/

26 / 2013 

## 10 :05 :00 14 .049 3 .954 2/

26 / 2013 

## 10 :06 :00 14 .058 3 .948 2/26 / 2013 

## 10 :07:00 14.059 3 .947 2/

26/2013 

## 10:08 :00 14 .056 3 .949 2/

26 / 2013 

## 10:09 :00 14 .073 3 .942 2/

26/2013 

## 10 : 10 : 00 14 .083 3 .942 2/

26/2013 

## 10 : 11 :00 14 .067 3 .949 2/

26 / 2013 

## 10:12 :00 14 . 072 3 .949 2/

26 / 2013 

## 10 : 13 :00 14 .091 3.941 2/26 / 2013 

## 10 : 14 : 00 14 .067 3 .955 2/

26/2013 

## 10 : 15:00 14 .088 3 . 943 2/

26/ 2013 

## 10 : 17 :00 14 .079 3 . 954 2/26/2013 

## 10:18 :00 14 . 058 3 . 965 2/

26/2013 

## 10:19 :00 14 . 059 3 .964 2/

26 / 2013 

## 10 :20 :00 14 . 054 3 . 968 2/

26 / 2013 

## 10 :21 :00 14 .042 3 .976 2/

26/2013 

## 10:22:00 14 . 038 3 .98 2/

26/2013 

## 10:23:00 14 .04 3 .983 2/

26 / 2013 

## 10:24 :00 14 .04 3 .982 2/

26 / 2013 

## 10 :25 :00 14 .041 3 .982 2/

26/2013 

## 10 :26:00 14 .037 3.987 2/

26 / 2013 

## 10 :27:00 14 .04 3 .988 2/

26 / 2013 

## 10 : 28 :00 14 .026 3 .994 2/26 / 2013 

## 10 :29:00 14.033 3.993 2/26/2013 

## 10 : 30 : 00 14 .032 3 .997 2/

26 / 2013 

## 10 : 31 : 00 14 .026 4 2/

26 / 2013 

## 10 : 32 : 00 14 .038 3 .994 2/

26/2013 

## 10 : 33:00 14.038 3.995 2/

26/ 2013 

## 10 : 36 : 00 1 4 .08 3 .978 2/26/ 2013 

## 10:37 : 00 14 .056 3 .99 2/26/2013 

## 10:38 : 00 14 .061 3 .988 2/

26 / 2013 

## 10:39 :00 14 .072 3 .984 2/

26 / 2013 

## 10:40 :00 1 4 . 074 3 .984

### 2/ 26 / 2013 

## 10:41 :00 14 .061 3 .99 2/

26/ 2013 

## 10 :42:00 14 .075 3 .986 2/

26 / 2013 

## 10 :43:00 14 .089 3 .979 2/

26/ 2013 

## 10:44:00 14 .088 3 .977 2/

26 / 2013 

## 10 :45 :00 14 .078 3 .98 2/

26 / 2013 

## 10 :46 :00 14 .088 3 .973 2/

26 / 2013 

## 10 :47 : 00 14 . 087 3 . 973 2/

26/2013 

## 10 :48 :00 14 .089 3 .969 2/

26 / 2013 

## 10:49 :00 14 . 087 3 .968 2/

26 / 2013 

## 10 : 50 :00 14 . 091 3 . 964 2/

26 / 2013 

## 10 : 51 :00 14 .089 3 . 967 2/

26 / 2013 

## 1 0 : 52 :00 14 .065 3 .981 2/

26 / 2013 

## 10 :54 : 00 14 .075 3 .986 2/

26/2013 

## 10 :55 :00 14 .069 3 . 986 2/

26 / 2013 

## 10 : 56 :00 14 . 057 3 . 994 2/

26 / 2013 

## 10 : 57 : 00 14 .063 3 .993 2/

26 / 2013 

## 10 : 58 :00 14 .074 3 . 991 2/

26/2013 

## 10 : 59 : 00 14 .059 3 .998 2/

26 / 2013 

## 11 :00 :00 14 .085 3 .99 2/

26 / 2013 

## 11 :01 :00 1 4 .081 3 .995 2/

26/2013 

## 11 : 02 :00 14 .083 3.993 2/

26 / 2013 

## 11 : 03 : 00 14 .088 3 .995 2/

26 / 20 1 3 

## 11 : 04 :00 14 .089 3 . 993 2/

26 / 2013 

## 11 : 05 :00 14 .085 4 .001 2/

26/2013 

## 11 :06 :00 14 . 082 4 . 001 2/

26 / 2013 

## 11 : 07 :00 14 .084 4 .006 2/

26 / 2013 

## 11 :08 : 00 14 .083 4 .004 2/

26 / 2013 

## 11 :09 :00 14 .085 4 .006 2/

26 / 2013 

## 11 : 25 :00 14 . 106 3 .989 2/

26 / 2013 

## 11 : 26 :00 14 .088 3 .993 2/

26/2013 

## 11 : 27:00 14 .073 4 .005 2/

26 / 2013 

## 11 :28 : 00 14 .064 4 .007 2/

26 / 2013 

## 11 :29 : 00 1 4. 065 4 .008 2/

26 / 2013 

## 11 : 30 :00 14 .087 4 .001 2/

26/2013 

## 11 : 31 :00 14 .081 4 .005 2/

26/2013 

## 11 : 32 : 00 14 . 057 4 . 014 2/

26 / 2013 

## 11 : 33 :00 14 . 068 4 .01 2/

26 / 2013 

## 11 : 34 : 00 14.059 4 .014 2/

26/2013 

## 11 : 35 : 00 14 .067 4 . 01 2/

26 / 2013 

## 11 :36 :00 14 .065 4 .011 2/

26 / 2013 

## 11 : 37 : 00 14 .047 4 .019 2/

26/2013 

## 11 : 38 :00 14 .071 4 .011 2/26/2013 

## 11 :39:00 14 . 071 4 . 011 2/

26 / 2013 

## 11 :40 :00 14 .052 4 .019 2/

26 / 2013 

## 11 :41:00 14 . 052 4 .017 2/

26/2013 

## 11 :42 :00 14 .049 4 .019 2/

26/ 2013 

## 11 :43 :00 14 .05 4 .02 2/

26 / 2013 

## 11 :4 4: 00 14 .054 4 .015 2/

26/ 2013 

## 11 :45:00 14 .063 4 .013 2/

26/2013 

## 11 :46:00 14 .069 4.008 2/

26/2013 

## 11 :47:00 14 .067 4 .009 2/

26/ 20 1 3 

## 11 :48 :00 14 .065 4 .007

## 2/26/2013 

## 11 :49 :00 14 .075 4.004 2/26 / 2013 

## 11 :50 : 00 14 .053 4 .009 2/

26 / 2013 

## 11:51 : 00 14.055 4 .004 2/26/20 1 3 

## 11 :52:00 14.048 4 .006 2/26/2013 

## 11:53 : 00 14 .046 3 .998 2/26/2013 

## 1 1 :54 : 00 14 .037 4 2/26/2013 

## 11 :55 : 00 14 .036 3.999 2/26/2013 

## 11 :56:00 14.029 3.997 2/

26 / 2013 

## 11 :57 : 00 14 .031 3 .994 2/26 / 2013 

## 11 :58 :00 14 .028 3 .994 2/26/2013 

## 11 :59 :00 14.03 3 .993 2/26/2013 

## 12:00 : 00 14 .026 3.994 2/

26 / 2013 

## 12:01 : 00 14 .025 3 .995 2/26/2013 

## 12:02 :00 14 .024 3 .997 2/26/2013 

## 12:03:00 14 .028 3 .995 2/26 / 2013 

## 12:04 : 00 14 . 03 3.995 2/26 / 2013 

## 12 :05 :00 14 .029 3 .994 2/

26/2013 

## 12 :06:00 14.021 3 . 997 2/26/2013 

## 12:07 :00 14 .024 3.995 2/26/2013 

## 12:08 : 00 14 .018 4 2/26 / 2013 

## 12 :09 :00 14 .025 4 2/26/2013 

## 12:10:00 14.024 4.002 2/26/2013 

## 1 2:11 :00 14.016 4 .006 2/26/2013 

## 12 : 12 : 00 14 .013 4.012 2/26/2013 

## 12:13 :00 14.026 4 .006 2/26/2013 

## 12:14:00 14 .013 4.014 2/26 / 2013 

## 12:15 : 00 14 .012 4 .017 2/

26/2013 

## 12:16 :00 14 .013 4 .019 2/26/2013 

## 12 : 17:00 14 .023 4 .013 2/26/2013 

## 12:18 :00 14.017 4.015 2/

26/2013 

## 12:19 : 00 14 .022 4 .021 2/26/2013 

## 12 :20 :00 14 .051 4 .016 2/26/2013 

## 12:21 : 00 14.061 4 .012 2/26/2013 

## 12:22 :00 14 . 055 4 .016 2/

26

/ 2013 

## 12 : 23 : 00 14.05 4.015 2/26/2013 

## 12 :24 :00 14.054 4 .013 2/26/2013 

## 12 :25:00 14.055 4.014 2/26/2013 

## 12:26:00 14 .073 4 .006 2/26/2013 

## 12 : 27:00 14 .085 3 .998 2/

26/2013 

## 12 :28 :00 14.098 3.99 2/26/2013 

## 12 :29 :00 14 . 11 3.983 2/26/2013 

## 12 : 30:00 14 . 106 3.987 2/26 / 2013 

## 12:31 :00 14 . 108 3 .987 2/26/2013 

## 12 : 32:00 14 . 109 3 .989 2/26/2013 

## 12:33:00 14.118 3.984 2/

26 / 2013 

## 12 :34:00 14.118 3 .983 2/26 / 2013 

## 12 :35:00 14 . 109 3 .989 2/

26/20 1 3 

## 12:36:00 14 . 108 3.989 2/26 / 2013 

## 12:37 : 00 14 . 107 3 .989

### Average 14 . 08 

## 3 .96

## WET CHEMICAL SAMPLING SYSTEM DATA AND WORKSHEET - STANDARD CLIENT : .-, LOCA T I ON
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____________________________________________________________________________________________________________________ __

Date of last revision 

### 1/ 25 / 2013 Page L Of 

# A DS834049 Master Document Storage l Forms l Datasheets l Field Datasheets

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____________________________________________________________________________________________________________ __



## Date of last revision 

## 1/25/2013 page_I of 

# L DS834049 Master Document StoragelFormslDatasheetslField Datasheets

# Dellal1. 

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## 11~ 2. Insolub le Solids Filter 

## !;£-**Jf~f** 3. Impingers and Probe Catches

# (ex,~ a. Water Fraction b. O rganic Extract i on 125 ml MeCI2 

# If 3(,1.{ (5 x 25 ml) 

# IJ 1 

## {{2-D 

# B( I>f\ 

# '< 1{3P. 

# Me. C 

# k 1.3\ """ I( 

# 1/3(;3

Date of last rev i sion 

### 11 /13/08 Water Blank 

### mg / ml D. 6<:>**~ ~**  

### MeCl, Blank 

### mg/ml 

## p.**"""I~** Final Tare Gain

# W~tt W~tt Weight

### (m~) 

## 0
. (r;.(1**o.lr./~** 

## 0 · 0


## O·/5£S 

# O·/!ls'I 6·\
1'1.£'101 

## 2Cz.Q; 

# fG. 

# ,.5
2.,. 

# 'l'f'/5" la,o**~1C."1** 

### 0.(,**~"'.~5S0** 

## li':3S<{3 0·1
1'1'.14(; ( 

## ). '1. ').(,Sl

### o·~1 

### Sample Date Analysis Date Analyst Initia l s Aliquot Net Gain 

### Correction (mg/Sample)

(mllm!)



## --------- ------- 

## 6,0

--- ------------- 

# D.(

S/O 

# - 1..5 !lID 

### 5::(0**~** 

## 0.("

SID 

# 3:32:: 2. 

### SO

# ~ Blank based on Total Volume (mq)

-----------------

-----------------



# / . 1./
C),2...,



## Total Particulate 

## = __ 

# -='Z'-'.--='L=-
__ ---'m=-9 Method of Sample Prep/Notes

08834012 Master Document 8toragelFormslDatasheetslLab Forms

## APPENDIX D GENERAL EMISSIONS CALCULATIONS

R521 0729 

### D-1

## GENERAL EMISSION CALCULATIONS 

## 1) Stack Gas Velocity A
. Stack gas molecular weight, Ib/lb-mole MW d ", 

# = 0.44 * 

## %CO , + 

## 0
. 32 * 

## %0 , + 

## 0.28 * 

## %N , 

## MW w

el 

# = MW d ry 

## * 

## (1-Bwo) 

# + 18 * 

## Bwo B. Absolute stack pressure, iwg Ps 

# = Pbar + 

## Psg 

# 13.6 C
. Stack gas velocity, ft/sec

V s 

# = 

# 2.9 

# * C p 

# * ..jt,p 

# *.JT. * 2) Moisture A
. Sample gas volume , dscf

V msld 

# = 0.03342 * V m 

## * 

## (P b ", 

## + B
. Water vapor volume, scf 

# v = 0.0472 * 

## V. * T ro t

wsld Ie 

# 528 o R 29.92 * 

# 28 . 95 p. 

# * MWwel



## C . Moisture content, dimensionless 

# Bwo = 

## 3) Stack gas volumetric flow rate A. 

## Actual stack gas volumetric flow rate, wacfm Q 

## = 

# v * 

## A * 

## 60 s s 

## B
. 

## Standard stack gas flow rate , dscfm

R5210729 0 -2

## Q Sd 

## = Q * (1- B ) * T,ef 

## * P s wo 

# T s 29.92 4) Gaseous Mass Emission Rates. Ib/hr M 

## = ppm * MW, * Q sd 

## * 60 SV 

# * 10 6 

## 5) 

## Emission Rates. Ib/MMBtu Ib ppm*MW, *F * 20.9 MMBtu SV * 10 6 

## 20.9 - 

## %0 2 

## 6) Emission Factor. Ib/MMSCF Ib Ib *HHV MMSCF MMBtu VI. Percent Isokinetic 

## 17.32 x 

# T, (Vm sid) _52_8_ 0 

## _R 

# 1 = x (1- Bwa)O x V , x Ps x Dn' 

# r;,j VII. Particulate emissions a) Grain loading, gr/dscf C 

## = 0.01543 (M.JV m Sid) 

## b) Grain loading at 12% 

## CO 2 , 

## gr/dscf c) Grain loading at 3% 

## O 2 , 

## gr/dscf C 3 

### % 02 

# = C 

## * 

## 17.9/(20.9-%0 2 ) 

## d) Mass emissions, Ib/hr M 

## = C x Qsd x (60 min/hr)/(7000 gr/lb) e) Particulate emission factor
6 

# lib 20.. 9 [b / l0 Btu 

# = ex 7000gr x F x 20.9
_ 

## %02

R521 0729 

## D-3

## Nomenclature: 

## As 

## B

wo C 12 %C02 

## C3 %02 

## C 

# C

p 

## On 

## F 

## H HHV I 

# Mn M; MW 

## M

w;



# o**P** 

## P b ar 

# P

s P sg 

### Q Qws 

# QSd 

## SV 

# T

m T re f 

# Ts V

s V ic 

# V

m V mstd 

## V W Std 

# Y

d



### R521 0729 

## = stack area, 

## ft2 

## = flue gas moisture content, dimensionless 

## = particulate grain loading, gr/dscf corrected to 12% CO 2 

## = particulate grain loading , gr /dscf co r rected to 3% CO 2 

## = particulate grain loading , gr/dscf 

## = pitot calibration factor , d i mensionless 

## = nozzle diameter, in. 

## = fuel F-Factor, dscf/MMBtu 

## @ 0 % O 2 

## = orifice differential pressure , iwg 

## = fuel higher heating va l ue , Btu / SCF 

## = % isokinetics 

## = mass of collected particulate , mg 

## = mass emission rate of specie i, Ib/ hr 

## = molecular weight of flue gas , Ibllb-mole 

## = molecular weight of specie i: 

## S0 2 : 64 NO ,: 

## 46 CO: 

## 28 HC : 16 

## = sample time , min
. 

## = average velocity head, iwg 

## = (..{i;P) 2 = barometric pressure, inches Hg 

## = stack absolute pressure, inches Hg 

## = stack static pressure, iwb 

## = wet stack flow rate at actual cond i t ions, wacfm 

## = wet stack flow at standard condit i ons, wscfm 

## = dry standard stack flow rate, dscfm 

## =**s~ecific** 

## molar volume of an i deal gas at standard conditions ,



## ft lib-mole 

## = meter temperature, 

## O R 

## = reference temperature, 

## O R 

## = stack temperature, 

## O R 

## = stack gas velocity , fUsec 

# = volume of liquid collected in impingers , ml 

## = uncorrected dry meter volume , dcf 

## = dry meter volume at standard conditions, dscf 

## = volume of water vapor at standard conditions , scf 

## = meter calibration coefficient



## 0

- 4

## APPENDIX E CHAIN OF CUSTODY

R5210729 

### E-1CHAJN OF CUSTODY CLIENT: Sentinel TEST DATE (S) : 2125/2013 2126120 13 LOCATION : 5 SAMPLER(S) : -"S"S
___________ _ SAMPLE LOCATION : Stk PRO J ECT MANAGER : 

### BF TEST METHOD(S) : SCAQMD 207.1 DATE DUE : 3 / 6 / 2013 OUTS ID E LAB REQU I RED ?: No DATE TEST# 212512013 $5/Stk·NH3- FB Blank ,) / "" ' 'lni':l S5/Stk.NH3-1 212 5 / 20 13 212512013 2125 1 2013 2126120 13 2126/2013 SS/Stk-NH3 - 1**~'''C'''' .** **~'u** 

### ...

2/25/20 13**S5 /~** **~n k**  

## Method CAQMD 20' :AQM D20' :AQM[**~AOMr.** .... .
CA Probe, line , be , in e . I m p in gers ine ! Imp ingers COMPLIANCE TEST? RM Yes 

## ICOMMENTS 0.1 N H2S0 4 H2SO4 H2S04

• I " H2S04

. 1 N H2S04 

### ,04 ina, Impingers**rvl** 

## IU ' I I,. n..:;:)v.. " ., "2S04 "

8

### RE~S~::**DAT~~** 

# I**~c~n==t=;-~ATE7TlME-** )Jt;.;C(? 

# .112JJn**::qo/tj~2** 

# ,3 &-""2) R ,-- -. 

# 1- I'L / I 

# I
.

_ i , 

# Rl'fII A oCHAIN OF CUSTODY CLIENT : Se ntine l TEST DATE(S): 2 / 25

/ 2013 212612013 LOCATION : 5 SAMPLER(S): "'R"'M'-
__________ _ SAMPLELOCATlON : SIl< PROJECT MANAGER : BF TEST METHOD(S): SCAQMD 5.1 DATE DUE : 3/6/2013 OUTSIDE LAB REQUIRED ? : No COMPLIANCE TEST? Yes DATE TIME TEST#**~---.~--** .. 

## _- - .- 

### -- - --.- line 1m 1 RM Water 5.1 Filter 1 RM 55 mm Probe , line , 1 m 1 RM Water 5.1 Filter 1 RM 55 mm Probe , Line Imp. 1 RM Water 5 .1 Filter 1 RM 55 mm I Probe , Line Imp . 1 RM Water I !5

/ 20 5.1 Filter**R~agentJot #'~l**  Water 

# ,.L i**~y** 

# =1--- -F --- --OATElTIME- - 

# r**fj,RECE~** 

# I DATEITIME 

# 7tUO Uz.,,/J:S 

# Ii.: 'f.{)

### ~ . _ 

# U2Jdli.... ItJl(O I ' 

# z ---- - 

# -T '''' C(

# A

### (;1Z8'> 

# re l'1-li**~** 

### CA.I -Z-f! 

### 7**~** 

### lt-l1d Q 

### l7-ffM 

### A 

## ,"-'1 0 

# /!//c::/l /307/<7
CHAIN OF CUSTODY CUENT: Sentinel TEST OATE(S) : 212512013 2/2612013 LOCATION : 5 SAMPLER (S):**~RM~**___________ _ SAMPLELOCAnON: Stk PROJECT MANAGER : 

### BF TEST METHOO {S): SCAQMO 25.3 DATE DUE : 3ISI2013 OUTSIDE lAB REQUIRED? : Yes COMPLIANCE TEST?**~** 

### _ . . ... 

### - Ves 

# .- 212512013 S5/ -VQC-100-1A QM025.3 CanLSter# ()OD 1 RM 212512013 S51Stk- VOC-1 (l().1 B SCAQMD25.3 

### Can ister' I[) 

### <0 1 RM 212512013 S5lStkNOC-75--1A SCAQMD25..3 

### Canister" Oe>o 0**~** 

### .; 1 

### RM 212512013 SSlStk-VQC..75-1B SCAOMD25.3 Canister' 

# =1 1 RM 2126J2013 S5/Stk-VOC-5Q..1A SCAQMD25.3 Canister # 

### 2- 1 RM 2126/2013 S5JStk·VOC-5()..1 B SCAQM025 . 3 Canister" 1 RM

()1a es t 01\1 

### . :**~**

# . . 

# - 

# .

-

.... :z. 

# " /"/ 

# - - : L 'f':::' 

# ,,,,.
,



### ' - 

# .MLl



# -..

----- --- - - ---- ----_. _-_. _ - - --- - --- _.-

## APPENDIX F INSTRUMENT STRIP CHARTS

R521 0729 F-1

## APPENDIXG FACILITY PERMIT TO OPERATE CONDITION 029.1

R5210729 

## G-1

## SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Page: 35 Facility 10: 152707**R~i5ion#:** 

### 0 Date : April 15.20tI



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth helow: The operator shall also install and maintain a device to continuously record the parameter being measured The measuring device or gauge shall he accurate to within plus or minus 5 percent. It shall be calibrated once every twelve months It shall be calibrated once every twelve months The pressure drop across the catalyst shall not exceed 12 inches water column [RULE 1303(a)(1)-BACT, 5-10-1996; RULE 1303(aXI)-BACT, 12-6-2002; RULE 1703(aX2)

- PSD-BACT, 10-7-1988; RULE 2005, 5-6-2005] [Devices subject to this condition: C4, CIO, C16, C22, C28, C34, C40, C46] 012.5 The operator shall install and maintain a(n) non-resettable elapsed time meter to accurately indicate the elapsed operating time from the engine. [RULE I I 10.2, 2-1-2008; RULE 1303(b)(2)-OlTset, 5-10-1996; RULE 1303(bX2) -Offset, 12-6-2002; RULE 1470,6-1-2007; RULE 2012, 5-6-2005] [Devices subject to this condition: 049] 029.1 The operator shall conduct source testes) for the pollutant(s) identified below. Pollutant(s) to Required Test Methodes) Averaging Time 

# I Test Location he tested NOX emissions District method 100.1 I hour Outlet ofthe SCR serving this equipment CO emissions 

# I District method 100.1 I hour 

# IOutlet of the SCR serving this equipment SOX emissions 

# I AQMD Laboratory Method 307-9\ Not Applicable 

# I Fuel sample VOC emissions 

# I District Method 25.3 I hour 

# IOutlet ofthe SCR serving this equipment

## SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91765


# FACILITY PERMIT TO OPERATE CPV 

# SENTINEL LLC Section H Page: 36 Facilitv 10 : 152707 

### Revision #: 

### 0 Date: April IS, 2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: PMIO emissions NH3 em issions 

# I District Method 5 

# I District method 207.1

and 5.3 or EPA method 

## 17 

## 4 hours 1 hour 

# IOutlet of the SCR serving this equipment 

## 1Outlet of the SCR

serving this equipment

### SOLITH COAST AIR QUALITY MANAGEMENT DISTRlcr 21865 Copley Drive, Diamond Bar, CA 91 765 

# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Page: 37 Facility 10: 152707 Revision N: 0 Date: April IS. 2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: The test shall be conducted after AQMD approval of the source test protocol, but no later the later of 180 days after initial start-up or three hundred hours of operations after start-up. The AQMD shall be notified of the date and time of the test at least 10 days prior to the test The test shall be conducted to determine the oxygen levels in the exhaust. In addition, the tests shall measure the fuel flow rate (CFH), the flue gas flow rate, and the turbine generating output in MW. The test shall be conducted in accordance with AQMD approved test protocol. The protocol shall be submitted to the AQMD engineer no later than 45 days before the proposed test date and shall be approved by the AQMD before the test commences. 

## The test protocol shall include the proposed operating conditions of the turbine during the tests, the identity of the testing lab, a statement from the testing lab certifYing that it meets the criteria of Rule 304, and a description of all sampling and analytical procedures The test shall be conducted when this equipment is operating at maximum, average, and minimum loads. For natural gas fired turbines only, VOC compliance shall be demonstrated as follows: a) Stack gas samples are extracted into final canister pressure between 400-500 mm Hg canisters are done with zero gas analyzed/certified total hydrocarbon as carbon, and c) Analysis of TO-12 (with pre concentration) and temperature samples for analysis is not below 70 deg F . Summa canisters maintaining a absolute, b) Pressurization of to contain less than 0.05 ppmv canisters are per EPA Method of canisters when extracting The test shall be conducted for compliance verification of the BACT VOC 2.0 ppmv limit. The test results shall 

## be reported with two significant digits.

## SOUlli COAST AIR QUALIlY MANAGEMENT DISTRICT 21865 

## Copley DrIve. DIamond Bar. CA 91765


# FACll..ITY PERMIT TO OPERATE CPV SENTINEL LLC SectionH Facility ID: 

### Revision Ii; Date: 

### Page: 38 152707 

## o AprillS,201l



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: [RULE 1303(a)(1)-BACT, 5-10-1996; RULE 1303(aXI)-BACT, 12-6-2002; RULE 1303(b)(2)-Offset, 5-10-1996; RULE 1303(b)(2)-Offset, 12-6-2002; RULE 1703(a)(2)- PSD-BACT, 10-7-1988; RULE 2005, 5-6-2005] [Devices subject to this condition: DI, D7, DI3, D19, D25, D31, 037, D43] D29.2 The operator shall conduct source testes) for the pollutant(s) identified below. Pollutant(s) to be tested Required Test Method(s) Averaging Time 

# I Test Location NH3 emissions District method 207.1 1 hour Outlet ofthe SCR and 5.3 or EPA method serving this equipment 17 The test shall be conducted and the results submitted to the District within 45 days after the test date. The AQMD shall be notified of the date and time of the test at least 7 days prior to the test. The test shall be conducted at least quarterly during the first twelve months of operation and at least annually thereafter. The NOx concentration, as determined by the CEMS, shall be simultaneously recorded during the ammonia slip test. If 

## the CEMS is inoperable, a test shall be conducted to determine the NOx emissions using District Method 100.1 measured over 8 

## 60 minute averaging time period. If the turbine is not in operation during one quarter, then no testing is required during that quarter The test shall be conducted to demonstrate compliance with the Rule 1303 BACT concentration limit [RULE 1303(a)(1)-BACT, 5-10-1996; RULE 1303(a)(I)-BACT, 12-6-2002] [Devices subject to this condition: DI, D7, Dl3, D19, D25, D31, D37, D43]

## APPENDIX H CORRESPONDENCE AND TEST PLAN

R521 0729 

### H-1

## Bob: Here is an answer to one of the issues for the CPY Sentinel testing. From: 

## carey Willoughby [mailto:CWilioughby@aqmd.gov] 

## Sent: Wednesday, January 09, 2013 10:09 AM 

## To: Tom W. Andrews 

## Subject: RE: CPV Sentinel VOC Tests Mr. Andrews, Simultaneous duplicate sampling (six canister samples vs. nine sample canisters) for YOC is acceptable to the SCAQMD. Sincerely, 

## Carey Wifw'U{3/Wy Jtir 

# Quaaty 'Enaineer II 

## SCJtQ,:MV 21865 Coyfey 

## Vrive Viamona1Iar, CJt 91765 

# 'ref: (909) 396-3006 

# :J'ax: (909) 396-2099 

# cwiffirueIi6y@aqmtf.lJov

From: 

## Tom W. Andrews [mailto:TAndrews@sierraresearch.com] 

## Sent: Wednesday, January 09, 2013 9:39 AM 

## To: carey Willoughby Cc: 

## W. Andrews, Tom 

## Subject: CPV Sentinel VOC Tests Carey: Per our telecon this morning , for the YOC tests the test team would like to take duplicate simultaneous samples rather than triplicate samples in series at each ofthe three gas turbine loads. In other words a total of six canister samples vs. nine canister samples. Could you please confirm this is acceptable to the SCAQMD. Thanks. 

# Tom Andrews
1801/ Street Sacramento, CA 95811 (916) 273-5139 

## (direct/voice) (916) 444-8373 

## (fax)

# SOURCE TEST PROTOCOL FOR INITIAL COMPLIANCE TESTING AT CPV SENTINEL ENERGY PROJECT UNITS 1 - 8
PREPARED FOR: GEMMA POWER SYSTEMS CALIFORNIA, INC. 2461 MAIN STREET GLASTONBURY, CONNECTICUT 06033 FOR SUBMITTAL TO : SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT 21865 COPLEY DRIVE DIAMOND BAR, CALIFORNIA 91765-4178 PREPARED BY: DELTA AIR QUALITY SERVICES, INC. 1845 N
. CASE ST. ORANGE, CALIFORNIA 92865 714-279-6777 ROBERT 

# A. FINKEN DECEMBER 7,2012 DOCUMENT NUMBER: R0210458-R1 

# 8611811
Air Quality Services, Incorporated

## CONFIDENTIALITY STATEMENT

This information contained In this communication is intended exclusively for the individual or entity to which it is addressed. This communication may contain information that is proprietary, privileged or confidential or otherwise legally exempt from disclosure. If

## you are not the named addressee, you are not authorized to read, print, retain, copy, or disseminate this message or any part 

# of it.

R021 0458-R 1 

## ii

## CONTENTS SECTION 1
. 0 INTRODUCTION
.............................................................. . ....................................... 1 2.0 UNIT DESCRIPTION AND TEST CONDITIONS
.. .. .. .. .... . . ................... .... ... ........ .. .. .. 2 2.1 UNIT DESCRIPTION
................................................. . . . .... .. ... .. . . . ... . ..... .. ... . ........ 2 2.2 TEST CONDITIONS
...................... .. ... ,. ............. ... ... ....... .. . ... .... .. ... .. .. .. .. ... .. ...... . 4 2.3 SAMPLE LOCATION
.......... .. ............... . .......................... .... .......... ... .... ... ... . ....... 5 3
. 0 TEST DESCRIPTION
.. ... .... ... . ... .... .. ................ .. ... .. .... .. ..................................... , ...... 7 3
. 1 O 2 • 

## CO 2 • 

## NOx 

## AND CO
.............. .. .................. .. ..... .... .... . ........ . .. ..... .. ....... ....... .... 8 3.2 NH3 BY SCAQMD METHOD 207.1
................. . ............ . .. . . ..... .. ..... .. .. . .... .. ......... 9 3
. 3 SOx BY SCAQMD METHOD 307
. 91
............................... .. ..... . . ..... ... ....... .. ........ 9 3.4 ROG BY MODIFIED SCAQMD METHOD 25.3
.......... .. ............ . ......................... 9 3.5 PM BY SCAQMD METHOD 5.1
.......................................... ..... . ... ... ................. 13 4.0 REPORTING
......................... . ................................................................... ... ......... . 15 APPENDICES A QUALITY ASSURANCE
................... .. . .................................. .. ............ . .................A-1 B TEST METHODS
.............. ... .... . .... .. .... .. ... .. ..... ....... ... ... ... ......... .... .. ......... ... . ... .. .. .. .. B-1 C CALCULATIONS
................ .. .... ... .... . ..... ...... .. .. ......... .... .... ......... .... ........ ......... . ..... C-1 D FORMS
............................................ ...... ..................................................... .. ........ D-1 E FACILITY PERMIT TO OPERATE CONDITION D29.1
...................... ...... .. . .. ......... E-1

R021 0458-R 1 

## iii 

# De/fit:.. "'-

## ......... 

# -

# 1.0 INTRODUCTIO N Delta Air Quality Services, Inc. has been contracted by Gemma Power Systems Califomia, Inc
. (GEMMA) to perform the initial Permit to Operate Compliance Testing at the CPV Sentinel Energy Project Units 1, 2, 3, 4, 5, 6, 7, and 8
. Condition D29 .1 of the Permit to Operate requires source tests within 180 days of initial startup
. This document will serve as the test plan for the aforementioned tests. Tests will be performed at three load conditions to determine oxides of nitrogen (NO,J, carbon monoxide (CO), oxides of sulfur (SOx), reactive organic gases (ROG's), particulate matter (PM), and ammonia (NH3) emissions. Bob Finken will be the Senior Program Manager for Delta and can be reached at (714) 279-6777. No conflict of interest, as defined in SCAQMD Rule 304, exists between Gemma or CPV Sentinel Energy Project and Delta. Section 2
. 0 of this document provides a description of the facilities and sample locations. A description of the sampling strategy and test methods is provided in Section 3.0. Section 4
. 0 outlines the final source test report format. 

# A more detailed description of the test methods, calculations, and quality assurance procedures is provided in the Appendices
.

R0210458-R1 1 

# Delfa/).



# ..

# _--

# 2.0 UNIT DESCRIPTION AND TEST CONDITIONS
2.1 UNIT DESCRIPTION 

## CPV Sentinel Energy Project is located at 62575 Powerline Road, Desert Hot Springs, California 92240
. The facility consists of eight (8) identical generating units. The CPV Sentinel Energy Project consists of eight (8) LMS1 DOPA combustion turbines in simple cycle operation
. The units are natural gas fired with a rated heat input of 891
. 7 MMBtu per hour at 72 degrees Fahrenheit. Each LMS1 DOPA employs water injection and is equipped with a CO catalyst and Selective Catalytic Reduction (SCR) system for NO. control. The LMS100PA is a General Electric (GE) combustion turbine with an intercooler located between the low pressure compressor (LPC) and high pressure compressor (HPC)
. Off engine combustion air to closed loop water intercooling is used for increased gas turbine thermal efficiency. Heat removed from the off-engine intercooler is circulated through a closed loop cooling system
. Heat is rejected from the closed loop cooling system to an open loop cooling system via plate and frame heat exchangers. The open loop system rejects heat via a mechanica l draft counterflow cooling tower. The cooling tower is provided with drift elimination to comply with air emissions limits
. Figure 2-1 presents a block diagram of the units. Fi gure 2-2 shows a general arrangement of the major components.

R021 0458-R 1 2 

# Oellll1 

# ..

# _..-.-

## FIGURE 2-1 SIMPLIFIED PROCESS B L OCK DIAGRAM CPV SENT I NEL ENERGY PROJECT CO M BUSTION TURBINES

Simplified Process Flow Diagram


## Air Water Cooling Tower Air Water Heat

Closed Loop Exhaust to Atm
. Cooling

Air LMS100PA Exhaust CO Catalyst SCR 

## IWater Ammonia Natural Gas Fuel Demineralized 19% Aqueous

R021045B-R1 

# //eltab..
..

# - .-- 3

## FIGURE 2-2 GENERAL ARRANGEMENT OF MAJOR COMPONENTS

;.l'.t

... T

.... ·.TO· ...· ,. ....

.r.""'t>'



# - - .. . .... ........ .. .... - . . -.. . .- .....**--] ==I4i=** **=~.-** 

# .... . .... ... ' . .... .. .... -**'** ,.:_



### ... .. ........... , 

# :

.. \\, " .i'-, \ ' • \ ' 1 1''' I**I~** \ "Z \ , 

## -+--**~** 

## . ' -=.:.i- I



## . "**C~** 

### . "'t
. "
...**~:-.** 

### J : ,**//'~** 

### '1 I

# I~**/** 

# ,

v 

# J \ IN'/ ' '

,:: • '
. : . J,I


## 2.2 TEST CONDITIONS The permit requires that the tests will be performed at three operating conditions; 1) maximum , 2) average, and 3) minimum load. Full load is nominally 100 megawatts and minimum load will be approximately 50 megawatts
. Since these will be the initial tests for the units and no long term average will have been established, average conditions will be approximated at 75% of capacity or approximately 75 megawatts.

R021 0458-R 1 

# 111111811 

# "'--- 4

## Unit operating data will be gathered during the tests by the facility from the CEMS DAS
. These data will include, at a minimum : • Fuel flow rate • Turbine generating output (MW) • Ammonia Flow • Exhaust Temperatures • Exhaust Flow Rates 2.3 SAMPLE LOCATION 

## There are four 6" test ports located at 90 degrees apart around the circumference of the 13'6" diameter stacks. The ports are located 323" downstream (2.0 diameters) of the nearest flow disturbance (duct breeching) 84" upstream (0.5 diameters) of the nearest flow disturbance (silencers)
. The sampling location meets the minimum requirements of SCAQMD Method 2
. 1, being >2 diameters downstream and >0.5 diameters upstream of the nearest flow disturbances. Figure 2-3 presents the details of the sample location. FIGURE 2-3 SAMPLE LOCATION DETAILS

Inside Diameter , in .

- 162 .-- Stack Exit 1080.0 in. Silencer Bottom 925.9 In. 

### Ports 841
.6 in
. Platform 789
.6 in
.

Base 

### 01 Stack 518.5 in.

Grade 0 . 0 in .



## R021 0458-R 1 

# T 84 Distance A, inches, 0 .5 Diameters 

# l Sample ports 

# T
323 Distance 8, inches, 2 .0 Diameters



### ",----,E::;xh;.:;aust Flow 4


### Elevation View



## 5 90 It.

66 ft
.



# o ft
.



# 0611811 

# "'---

### Samp le Point

2 3 4 5 6 7 8 9 10 11 12 

## Prior to performing the tests , gaseous stratification will be investigated with a 12 point traverse as described in 40 CFR 75, 

## and the presence of cyclonic flow will be checked using the techniques described in SCAQMD Method 2
. If stratification is less than 10% or less than 1 ppm , all future gaseous concentration measurements will be made from a single point. If stratification is greater than 10% and greater than 1 ppm, all future concentration measurements will be performed using a multi-point traverse (3-point short line , 3-point long line, or 12-points (using 40 CFR Part 75 

## criteria))
. A 16-point cyclonic flow traverse will be performed with an S-type pitot tube
. If the average yaw 

## angle is less than 10 degrees, the locat i on will be deemed acceptable for Method 2.1 velocity measurements
. Table 2-1 illustrates the location of sample traverse pOints
. TABLE 2-1 SAMPLE POINT LAYOUT
PM (24 pts
. ) Flow D i sturbance (16 pts
. ) Strat.lNH3 (12 Pts
. ) 3 pI. Long Line CEMS 3 pt. Short Line CEMS 

### % of i n . 

### %of in
. % of 

### in . %01 

### i n. %of 

### Diamete r from Wall Diameter from Wall 

### Diameter from Wall 

### Diameter from Wall 

### Diameter

2
. 1 3.4 3
. 2 5.2 4.4 7
. 1 16
. 7 27.1 N/A 6
. 7 

### 10.9 10.5 17.0 14
. 6 23.7 50 

### 81
. 0 N/A 11
. 8 19
. 1 19
.4 31.4 29
. 6 

### 48
. 0 17
. 7 28
. 7 32
. 3 52
. 3 

### 70.4 114
. 0 25 

### 40
.5 67
. 7 

### 109
. 7 35
. 6 57.7 

### 80
. 6 130
. 6 64
. 4 

### 104
. 3 75 121.5 82
. 3 133.3 86.4 

### 140.0 93
. 3 151.1 97
. 158
. 6 

## Prior to performing the tests, gaseous stratification will be investigated with a 12 point traverse as described in 40 CFR 75, 

## and the presence of cyclonic flow will be checked using the techniques described in SCAQMD Method 2
. 1. If stratification is less than 10% or less than 1 ppm, all future gaseous concentration measurements will be made from a single point. If stratification is greater than 10% and greater than 1 ppm, all future concentration measurements will be performed using a multi-point traverse (3-point short line, 3-point long line, or 12-points (using 40 CFR Part 75 

## criteria)). A 16-point cyclonic flow traverse will be performed with an S-type pitot tube
. If the average yaw angle is less than 10 degrees , the location will be deemed acceptable for Method 2.1 velocity measurements
. R0210458-R1 6 

# De/tat:.. 

# -

--- in
. from Wa ll 15.7 47.2

# 3.0 TEST DESCRIPTION Table 3-1 summarizes the test methods and techniques which will be used as the reference methods. The test matrix has been developed to meet the requirements of Section 29.1 of the facility Permit (Application Number 472137) dated April 15, 2011
. The permitted em i ssion limits are summarized in Table 3-2. The following sections describe each method in further detail. Flue gas Oxygen and Carbon Dioxide concentration will be measured in conjunction with all tests using SCAQMD Method 100
. 1. The flue gas flow rate will be measured in conjunction with each particulate test. This measured flue gas flow rate in each duct will be used for all emission rate calculations of NOx , CO, NH 3 , 

## ROG's and SOx' TABLE 3- 1 TEST MATRIX Parameter Method 50% Load 75% Load 100% Lo a d Test Duration NOx 

### SCAQMD 100
. 1 1 run 1 run 1 run 60 minutes 

## 02 /C02 SCAQMD 100
. 1 With each ru n CO SCAQMD 100
. 1 1 run 1 run 1 run 60 m i nutes NH 3 SCAQMD 207
. 1 2 runs 2 runs 2 runs 60 m i nutes S02 SCAQMD 307
. 91 2 samples 

## N/A 

# PM EPA 201NSCAQMD 5
. 1 1 run 1 run 1 run 240 minutes RaG Modified SCAQMD 25
. 3 3 runs 3 runs 3 runs - 60 m i nutes t' ) 1) ROG tests will be nominally 60 minutes . F low controllers will be setup for 60 minutes
. The test will be performed until the canister vacuum reaches approx i mately 10 

### 'Hg
. Actual test time may be less than or more than 60 minutes per sample
.

R021 o4 5 8-R 1 

## 7 

# lie /

la b.

.. .....**~--** 

# ..

## TABLE 3-2 CPV SENTINEL ENERGY PROJECT PERM I TIED EMISSION LIMITS Parameter Units ppm@ 15%0, ppm @ 15% 0, Ibs/MMscf 

# co ppm @ 15% 0 , 

## NH3 ppm @ 15% 0, gr/dscf @ 3% 0, Particulate gr/dscf @ 12% CO, Ib/hr Ibs/MMscf (Ib/hr equivalent) PM1O"PM2.5 Ib/MMBtu Ibs/MMscf 

## SOx ROG's ppm @ 15% 0, (1) The 12 .2 61bs1MMscf i s a 

### RECLAIM em i ssion factor, not a l i mit. (2) Th i s is stated in the permit as an emiss i on factor. 

# 3,1 

# 0,. CO,. NO

# x AND CO Limit 2.5 15 12.26 (1) 4 5 0
. 01 0
. 1 11 5
. 71(') (5
. 0) 0.06 0
. 69 2.0 Rule 1703(a)(2) 40 CFR 60 2012 1703(a)(2) 1303(a)(1 ) 475 409 475

40 CFR 60 Rule 2011 1303(a)(1 )



# 0" CO " NOx 

## and CO concentrations will be measured using SCAQMD Method 100
. 1
. These measurements will be made with one of Delta ' s mobile emission measurement laboratories
. The system consists of a stainless steel or glass probe, heated Teflon line, moisture removal system , sample pump, sample filter , unheated Teflon line, and individual component analyzers
. The measured concentrations are averaged over each sampling period , then corrected for system bias and analyzer drift. All quality assurance procedures required by SCAQMD Method 100.1 will be performed including pre- and post-test Calibration Error, Sample System Bias and Analyzer Drift. The sampling will be perfonmed using a 12-point traverse at each test condition (or a single po i nt if previous testing demonstrates the absence of significant stratification (less than 10% or less than 1 ppm). At the full load condition , the compliance test may be performed concurrently with the Relative Accuracy Test Audit (RATA). In this case, data f r om the RATA may be used to demonstrate compliance with the NOx 

## and CO emission limits
. NOx 

## concentrations will be measured on a 0- 5 ppm range . CO concentrations will be measured on a 0-10 ppm range . CO, concentrations will be measured on a 0- 10% range. 

# 0 , concentrations will be measured on a 0-20% range. The measured concentrations are averaged over each sampling period , then corrected
R0210458-R1 

## 8 

# lie/tab..
..

# _--

## for system bias and analyzer drift. The drift and bias corrected result will then be used to calculate NOx 

## emissions in units of ppm, ppm corrected to 15% O2 , 

## pounds per hour, pounds per million Btu, and pounds per million standard cubic feet of natural gas . 3.2 NH3 BY SCAQMD METHOD 

## 207.1 Duplicate flue gas samples will be collected non-isokinetically at each test condition using a SCAQMD Method 207
. 1. A 12-point traverse will be performed during each NH3 slip test unless previous tests demonstrate the absence of significant NOx 

## stratification, then single point sampling will be performed
. The sample gas is drawn through a glass probe, Teflon sample line , two impingers each containing approximately 100 ml of 0.1 N H2 

## S0 4 , 

## an empty impinger, an impinger containing silica gel , and a dry gas meter
. The optional nozzle and filter will not be used since the units are natural gas fired
. The contents of the probe, sample line and the first three impingers are recovered and analyzed by SCAQMD Method 207.1 for ammonia concentration using the Ion Specific Electrode technique. One reagent blank sample and one field blank sample will be analyzed. Ammonia slip will be reported in units of ppm, corrected to 15% O 2 . 

## The tests will be performed over a period of at least 60 minutes. 3.3 SOx BY SCAQMD METHOD 

## 307.91 Oxides of sulfur will be measured using SCAQMD Method 307-91
. Two fuel samples will be collected i n a Tedlar bag and sent to Saybolt Laboratory for Sulfur analysis as total reduced sulfur as H 2 

## S
. 3.4 ROG BY MODIFIED SCAQMD METHOD 

## 25.3 Sampling and analyses are performed using Modified SCAQMD Method 25.3 procedures
. The sample apparatus and analyses are provided by Atmospheric Analysis and Consulting (MC) in Ventura California
. At each test condition, triplicate flue gas samples are extracted sequentially from four points (one per port) in the stack through pre-cleaned (high temperature conditioned) stainless steel probes connected to an out-of-stack flow controller, into stainless steel Summa polished canisters
. The flow controller is set to fill the evacuated canister to a pressure of -400 mm Hg over a period of a period of one hour
. Modifications to the Method 25
. 3 sampling procedures suggested or accepted by SCAQMD are: • Elimination of the in-stack filter • Elimination of the water vial portion of the 25
. 5 equipment • The final pressure in the Summa Canisters is maintained at between 400 and 500 mm HG (10 - 14 in. Hg) absolute
.
R021 0458-R 1 9

## Figure 3-1 presents a schematic drawing of the sample apparatus. FIGURE 3-1 MODIFIED SCAQMD METHOD 25.3 SAMPLING APPARATUS

Filter Probe

Flow Controller

The samples are analyzed for NMNEOC (Non-Methane Non-Ethane Organic Compounds, i.e
. Reactive Organic Compounds ROG) using modified SCAQMO Method 25.3 TCA procedures. Analysis consists of a fore-flush and back-flush of a gas chromatography (GC) column, followed by an oxidizer , a methanizer, and a flame ionization detector (FlO). The GC separates the NMNEOC from other constituents of the sample (methane, ethane, CO 2 , 

## H 2 

## 0, O 2 , 

## N 2 , 

## etc.). The oxidizer converts the NMNEOC to carbon dioxide
. The methanizer converts the resulting CO 2 

## to methane. The methane content is detected by the FlO as ppmcarlxm
.

R021 0458-R 1 10

## Modifications suggested by SCAQMD to the Method 25
. 3 analytical procedures approved for MC under the LAP are: • Pressurization of the canisters to 900 mm Hg with Ultra High Purity (UHP) helium analyzed/certified to contain less than 0
. 05 ppmv of total hydrocarbons as carbon • Analyzing only the Summa canister fraction of the normal 25
. 3 sample
. No water vial used in sampling, no water vial analysis
. • Utilization of a larger (-2 ml) sampling loop • Development of a custom low level (0.1 - 5
. 0 ppmV propane) calibration curve • Performance of a Minimum Detection Limit (MOL) study • Determination of a Practical Quantitation Lim it (PQl) from the MOL study Results are reported in parts per million by volume as carbon to 2 significant digits , corrected to 15% O2 

## using the O2 

## from the canister analysis. The average of the results for the duplicate samples is compared to the Emission Standard for determination of the compliance status
. 

## Note: The following message was received on November 9, 2012 and the content was incorporated into this protocol; 

## From: Roy Olivares [mailto:ROlivares@aqmd.gov) Sent: Friday, November 09, 2012 10:19 AM To: Mark McDaniels Subject: Revised VOC testing, condition D29 . 1 Mark The current VOC section of D29.1 is the following For natural gas fired turbines only, VOC compliance shall be demonstrated as follows: a) 

## Stack gas samples are extracted into Swnma canisters maintaining a 

## final canister pressure between 400-500 mm 

## Hg absolute, b) Pressurization of canisters are done with zero gas analyzed/certified to 

## contain less than 0.05 ppmv total hydrocarbon as carbon, and c) 

## Analysis of canisters are per EPA Method TO-12 (with pre concentration)and temperature of canisters when extracting samples for analysis is not below 70 deg F. The use of this alternative method for 

## VOC compliance determination does not mean that it is more accurate than AQMD Method 25.3, 

## nor does it mean that it may be used in lieu of

R021 0458-R 1 

## 11 

# Dellal'1


# .. 

# -.--

## AQMD Method 

## 25 . 3 without prior approval except for the determination 

## of compliance with the VOC BACT level 

## of 2.0 ppmv calculated 

## as carbon for natural gas fired turbines. Mike Garibay from source testing has proposed the following VOC testing For natural gas fired turbines only, VOC compliance shall be demonstrated 

## as follows 

## an alternative to AQMD Method 

## 25.3 for the purpose 

## of demonstrating compliance with BACT 

## as determined by CARB and AQMD, may be the following: a} 

## Triplicate S stack gas samples 

## are extracted directly into Summa canisters, maintaining a 

## final canister pressure between 400-500 mm Hg absolute, b} Pressurization 

## of the Summa canisters 

## are is done with zero gas analyzed/certified to containing less than 0.05 ppmv total hydrocarbons 

## as carbon, 

## and c} 

## Analysis 

## of Summa canisters 

## are is per unmodified EPA Method TO-12 (with preconcentration) 

## or the canister analysis portion 

## of AQMD Method 

## 25.3 with a 

## minimum detection limit 

## of 0.3 ppmvC 

## or less and reported to two significant figures, 

## and (d) The temperature 

## of the Summa canisters when extracting samples for analysis is not to be below 70 degrees Fahrenheit. The use 

## of this alternative method for VOC compliance determination does not mean that it is more accurate than unmodified AQMD Method 

## 25.3, nor does it mean that it may be used in lieu 

## of AQMD Method 

## 25.3 without prior approval, except for the determination 

## of compliance wi th the VOC BACT level 

## of 2.0 ppmv VOC calculated 

## as carbon set by CARB for natural gas fired turbines. please have the VOC testing portion 

## of the source test protocol address the above changes roy Roy Olivares Air Quality Engineer II Energy and 

## Public Service Team South 

## Coast Air Quality Management District 21855 Copley Drive Diamond Bar, CA 91755 909-395-2208

R021 0458-R 1 12

## 3.5 PM BY SCAQMD METHOD 

## 5.1 Particulate matter will be measured using EPA Method 201A in conjunction with SCAQMD Method 5
. 1
. SCAQMD Method 5.1 is cited as the Table in Condition D29.1 lists District Method 5
. District Method 5
. 1 measures total particulate
. This total particulate measurement could include material >10 microns
. Use of the cyclone as in 201A will prevent ove rstating of PM 10 

## emissions if all of the PM emissions from these units are not PM 1o . 

## A single test will be performed at each of the three conditions ; 100%, 75%, and 50% load conditions
. Flue gas is drawn through a stainless steel nozzle, glass or stainless steel probe, unheated Teflon line followed by four impingers. Impingers #1 and #2 contain approximately 100 ml of deionized water, impinger #3 is empty , and impinger 

## #4 contains silica gel. A backup filter is placed between impingers #3 and 

## #4 . The sample will be collected isokinetically (90 - 110%) using a 24-point traverse at the exhaust stack location
. Each point will be sampled for 10 minutes resulting in a 240 m i nute sample time per test. Figure 3-3 presents a diagram of the sampling system
.

R0210458 - R1 13 

# D ellaJ1.

...

# -._--Tempe ritu re Sensor Probe

# ~

PHot Tube



### S-Type Pi t ot Tube 

## FIGURE 3-3 SCAQMD METHOD 5.1 SAMPLE SYSTEM

Manometer 

## Orifice Connecting Tubing



## Dry 

## Gas

Meter Filter Temperature



### Line



## The sample is recovered in two fractions : 1) nozzle, probe, connecting line and impinger ri nse (01 water) and 2) backup filter. Filter weight gain and water solution weight gain are each determined gravimetrically.

R021 0458-R 1 14 

# lIellat3.. "'--"-'

# 4.0 REPORTING Following the test, a report will be generated which documents the results of the tests
. The report will be prepared using the following basic outline : I. Title page A
. Report Title B
. Prepared For : C. For Submittal To: D
. Prepared By : E
. Date F. Report Number II. Review Page A. 

## Signatures of person who prepared the report and signature of person who reviewed the report III. Table of Contents IV. Introduction and Summary A. 

## Identifies the client, source , reason for the test , test date(s), test personnel, clienUsource personnel B. Presents a summary of the test results C. Outlines the organization of remainder of the report
. V
. Unit Description A. 

## Process description B. Control equipment description C
. Sample location(s) description D
. Unit operating condition(s) during the test VI. Test Description A. 

## Test methods , replicates, duration, calculations VII
. Test Results and Evaluation A. 

## Re-states the results of the test B
. Results tables with more detail on individual test runs and supporting data C
. Evaluation of the test results and data validity VIII. Appendices A
. Test Data

R0210458-R1 15 

# O e/1I11


# ..

# ...., --

## 1
. Data Sheets/Stripcharts 2. Laboratory Data 3
. Quality Assurance Data B. Process data 1
. Unit and control equipment operating data C. Calculations D
. Quality Assurance Program Summary

R021 0458 - R 1 

## 16 

# llella/}. 

# "'-----

## APPENDIX A QUALITY ASSURANCE

R0210458 · R1 A·1 

# 1Ie/1a1'1 

# "'-- -

## QUALITY ASSURANCE PROGRAM SUMMARY 

## Delta Air Quality Services, Inc. is committed to providing emission related data which is complete, precise, accurate, representative, and comparable
. Delta's quality assurance program and procedures are designed to ensure that the data meet or exceed the requirements 

# ot each test method for each of these items
. The quality assurance program consists of the following items : • Assignment of an Internal QA Officer • Development and use of an internal QA 

## Manual • Personnel training • Equipment maintenance and calibration • Knowledge of current test methods • Chain-ot-custody • QA reviews of test programs Assignment of an Internal QA 

## Officer: Delta has assigned an internal QA Officer who is responsible for administering all aspects of the QA program. Internal Quality Assurance Manual : Delta has prepared a QA 

## Manual according to the guidelines issued by EPA
. The manual documents and formalizes all of Delta's QA 

## efforts
. The manual is a "living " document which is revised as Delta adds capabilities and procedures
. The QA manual provides details on the items provided in this summary . Personnel Training : Personnel training is essential to the production of high quality test results
. Delta's training programs include: • A requirement for all technical personnel to read and understand the test methods performed • A requirement for all technical personnel to read and understand the Delta QA manual • In-house training • Quality Assurance meetings • Attendance at EPA sponsored training courses • Maintenance of training records. Equipment Maintenance and Calibration: All laboratory and field equipment used as a part of Delta's emission measurement programs is maintained according to manufacturer's recommendations
. A summary of the major equipment maintenance schedules is summarized in Table A-1
. In addition to routine maintenance , calibrations are performed on all sampling equipment according to the procedures outlined in the applicable test method
. The calibration intervals and techniques for major equipment components is summarized in Table A-2
. Knowledge of Current Test Methods: Delta maintains current copies of EPA, ARB , and SCAQMD Source Test Manuals and Rules and Regulations
. Delta personnel coordinate, attend , and present papers at emission testing related conferences. Delta personnel maintain memberships in the Air and Waste Management Association and Source

R021 0458 - R 1 A-2 

# 1Ie//l1J. 

# --...-.--

## Evaluation Society. Delta personnel continually work with industry and regulatory agencies in monitoring and developing new methods and rules. Chain-of-Custody: Delta maintains chain-of-custody documentation on all data sheets and samples. Samples are stored in a locked area accessible only to Delta source test personnel. Data sheets are kept in the custody of the originator, program manager, or in locked storage until return to Delta's office. Upon return to the office , copies are made and stored in a locking file. The original data sheets are used for report preparation and any additions are initialed and dated. QA Reviews: Every Delta report is reviewed by someone separate from the report author. The reviewer is selected based on knowledge of the test methods used and the source tested
. Periodic field, laboratory, and report reviews are performed by the QA 

## Officer
. Test plans are reviewed to ensure proper test methods are selected and reports are reviewed to ensure that the methods were followed and any deviations from the methods are justified and documented.

R021 0458-R 1 A-3 

# /le/talJ... 

# M
_ ........_

## TABLE A-1 EQUIPMENT MAINTENANCE SCHEDULE Equ i pment Pumps

Flow Meters Sampling Instruments Acceptance Lim its 1
. Absence of leaks 2
. Ability to draw manufacturers required vacuum and fiow 1
. Free mechanical

movement 1
. Absence of

malfunct i on 2
. Proper response to zero, span gas Integrated sampling 1
. Absence of leaks tanks Mobile van sampling 1
. Absence of leaks system
Sampling lines

R021 0458-R 1 1
. Sample degradat i on less than 2%

A-4 Frequency of Service Every 500 hours of operation or 6 months , whichever is less Every 500 hours of operation or 6 months , whichever is less As recommended by manufacturer Methods of Service 1
. Visual inspection 2
. Clean 3. Replace parts 4. Leak check 1
. Visual inspection 2. Clean 3. Calibrate As recommended by manufacturer Depends on nature of 1
. Steam clean use 2
. Leak check Depends on nature of 1
. Change filters use 2. Change gas dryer 3
. Leak check 4
. Check for system contamination After each test series 1
. Blow dry , inert gas through line until dry
.



# lie/tal!!.

...

# - ..

# ---

## TABLE A-2 MAJOR SAMPLING EQUIPMENT CALIBRATION REQUIREMENTS Sampling Equipment Calibration Frequency Calibration Procedure Acceptable Calibration Criteria Continuous Analyzers Before and after each 3-point calibration error < 

### 2% of analyzer range test day test Continuous Analyzers Before and after each 2-point sample system < 

### 5% of analyzer range test run bias check Continuous Analyzers After each test run 2-point analyzer drift < 

### 3% of analyzer range 

### determination CEMS System Beginning of each day leak check < 

### 1 in. Hg decrease i n 5 min. at > 

### 20 in
. Hg Continuous Analyzers Daily 3-point linearity < 

### 1% of analyzer range NO , Analyzer Daily N02 -> 

### NO converter > 

### 90% efficiency S-type pitot tube Semi-annually Dimensional calibration Meet dimensional criteria of Method 2 S-type pitot tube Annually Wind tunnel calibration Defined in Method 2 S-type pitot tube Prior to each project Visual inspection Meet dimensional criteria of Method 2 Differential Pressure Semi -annually Correction factor based +/- 5% Gauges (except for on 5-point comparison to manometers) standard Differential Pressure Bi-monthly 3 - point comparison to +/- 5% Gauges (except for standard, no correction manometers) factor Manometer Semi-annually Clean and replace fluid Barometer Semi-annually Adjusted to mercury-in- +/- 0.1 inches Hg glass or National Weather Service Station Dry gas meter Semi-annually Calibration check at 4 +/-2% flow rates using a NIST

traceable standard Dry gas meter Bi-monthly Calibration check at 2 +/- 2% of semi-annual flow rates using a NIST factor

traceable standard Dry gas meter orifice Annually 4-point calibration for llH@ 

### Temperature sensors Semi-annually 3-point calibration vs . +/- 1
. 5% NIST traceable standard



## R021 0458-R 1 A-5 

# 1le11al3.

.. .



# -._-

# APPENDIXB TEST METHODS

R0210458 - R1 8 - 1 

# llella/).


# ..

# - .-

## SCAQMD METHOD 100 . 1 CALIBRATION SEQUENCE AND CALCULATIONS 

## DEFINITIONS: 1) Analyzer Calibration:
2) Calibration Error:

3) Analyzer Linearity :

4) Sample System Bias :

R0210458-R1 

## Zero and span gas(es) are introduced directly to the analyzer. Adjustments are made to the analyzer zero and upscale readings, as necessary to match the certified concentrations of the calibration gas. Zero, mid (40-60% of full scale), and high (80-100% of full scale) calibration gases are introduced directly to the analyzer and the analyzer response to each gas is recorded (without adjustment to the analyzer)
. The Calibration Error (difference between the analyzer response to the calibration gas and the certified concentration of the calibration gas) must not exceed ±2% of the analyzer full scale for any of the three gases. Analyzer linearity is defined as the difference between an analyzer response to the mid range gas and the predicted analyzer response to the mid range gas based on the analyzer response to the zero and high range gas. The Analyzer Linearity test is required on a semi-annual basis and must not exceed ±1 % 

## of the analyzer range. It should be noted that this linearity requirement is more stringent than the best available calibration standards (+/-2%) for the low CO and NOx 

## concentrations expected during this test program. For this reason, an analyzer linearity of less than 2% will be considered as acceptable for this program. The sample system bias test involves introducing zero and one upscale (mid or high) calibration gas to the entire sampling system and recording the analyzer response. The analyzer response to the calibration gas after it has passed through the entire sample system is compared to the analyzer response to same the calibration gas injected directly to the analyzer. The test is used to determine the effect which the sample system has on the species of interest and correct the measured values for any effect which the system has
. The sample system bias is required to be less than ±5% of the analyzer range for both the zero and upscale gas.

8-2 

# llelfa/).


# ..

# _--

## PROCEDURES AND CALCULATIONS: Figure 1 presents a flow chart for the SCAQMD Method 100.1 calibration sequence. All calibrations are documented as one-minute averages from the reference method Data Acquisition System
. Following assembly of the system , analyzer warm up time, and a successful leak check of the sample system, the calibration/test sequence presented in Figure 1 can begin
. An Analyzer Calibration is performed as necessary by adjusting the zero and span settings of the analyzer. These calibrations are not necessarily recorded on the chart recorder. Calibration Error is then determined at three levels for each range (which is expected to be used) of each analyzer. This check is performed, at a minimum, once at the beginning and once at the end of each test day
. The calibration error must not exceed ±2% of the full range of the analyzer as determined by the following equation: Calibration Error Analyzer Response- Cal. Gas Value. 100% Analyzer Range The data from the Calibratiori Error test can be used to determine Analyzer Linearity
. The analyzer response to the mid gas is predicted using linear regression and the analyzer response to the zero and high calibration gas and the zero and high calibration gas values
. The analyzer linearity must be demonstrated on a semi-annual basis using the following equation : Analyzer Linearity 

# = Analyzer Response - Predicted Response. 001 

## 10 10 

## Analyzer Range where : Response to H i gh Gas**~** 

### Response to Zero Gas 

### Predicted Response = • M i d Gas Value + Response to Zero Gas High Gas Value 

## The Sample System Bias test is performed before and after each test run and must not exceed ± 5% of the analyzer range for both the zero and upscale span gas. The system bias is calculated using the following equation : Response to System Bias - Response to Analyzer Cal Sample System Bias 

## = • 100% Analyzer Range

R0210458-R1 8-3 

# Ileltal1**.,.- --** 

## where: Response to Analyzer Cal 

# = The analyzer response to the last time the same calibration gas was introduced directly to the analyzer (this may be the pre-test calibration error value or a more recent analyzer calibration adjustment) Zero and Calibration Drift are calculated for each test run based on the analyzer response during the pre- and post-test sample system bias test. Zero and upscale drift must not exceed ±3% of the analyzer range. I D ·f 

## Post- Test System Bias Resonse - Pre - Test System Bias Response Ana yzer n t 

# = • 100% 

## Analyzer Range The pre- and post-test analyzer response during the sample system bias test are used to correct the raw test average for any sample system bias and analyzer drift. The drifUbias corrected data are the actual reported concentrations and are used for subsequent calculations (mass emission rates, Ib/MMBtu, corrections to 3% or 15% 

# Oz, etc
. ). The drift/bias corrections is performed using the following equation : 

# c-c c = o. 

## C

c 

# C _ C ma 

### m 0 

## where : C c 

# = Drift/bias corrected concentration 

# C 

# = Raw Test Average C m 

# = Average of pre- and post-test response to sample system bias span Co 

# = Average of pre- and post-test to sample system bias zero C ma 

# = Span gas value ADDITIONAL QUALITY ASSURANCE CHECKS: SCAQMD Method 

## 100 . 1 specifies the allowed analyzer interferences for each analyzer type. No interference checks are required for O2 or NO x 

## analyzers. Interference tolerances are given for CO, C02, and S02 analyzers. The analyzers used by Delta are certified by the manufacturers to have interference responses which meet the requirements of Method 

## 100 . 1 . SCAQMD has published a draft method for determining the efficiency of a NO z to NO converter. This test will be performed once on the day of the test. The converter efficiency must be 90% or greater.

R0210458-R1 

## 8-4 

# Oe/1I11

....

# _--

## Analyzer Cal Cal No Error < 

## 2% No Yes IYes

System Nn 

## System Bias < 

## 5% Problem? Yes Don't Know Stratified No Location? Yes Multi-Point Single Point Test Test System No Bias < 

## 5% Yes 

# I Cal No Drift < 

## 3% Yes Note: AQMD policy allows multiple 

## Another No Analyzer Cal test runs to be validated by one set of pre- and post-test sample system 

## Test? (if 

## necessary) bias tests as long as the bias 

# 1 checks are performed within 2 hours 

## Yes of the previous bias check. 

## No No Analyzer Cal Cal? Error < 

## 2% Yes 

# 1 Yes No Yes System 

# ( Finish 

# 1 Bias < 

## 5% t-- 

## FIGURE 1: SCAQMD METHOD 100 . 1 CALIBRATION AND TEST SEQUENCE

R021 0458-R 1 

## 8-5 

# De/lat::,.



# ---Temperature

# ~- Pti:olTube



### Nozzle



### S

-Type Pitot Tube



## R02 1 0458-R1 Manometer


## Orifice Connecting Tubing



## Dry Gas



## Meter



## SCAQMD METHOD 5.1 SA M PLING TRAIN

8-6 Temperature Sensor

Gel 

### Vacuum Gauge Li ne

### Filter Probe

Flow Controller



## MODIFIED SCAQMD METHOD 25.3 SAMPLING APPARATUS

R0210458-R1 B- 7 

# /Jella/).



# .

# ...,.--

# APPENDIXC CALCULATIONS

R0210458-R1 

### C-1 

# 1l6//811

...

# .....,.--

## GENERAL EMISS I ON CALCULATIONS 

## 1) Stack Gas Velocity A. Stack gas molecular weight , Ibllb-mole 

# MW dry 

# = 0.44 

# * %C0 2 

# + 0
. 32 

# * %0 2 

# + 0
. 28 * 

# %N 2 

# MW 

# w

e t 

# = MW dry 

# * (1-Bwo) + 

# 18 * 

# Bwo B. Absolute stack pressure, iwg 

# Ps 

# = Pbar 

# + Psg 

# 13.6 

# c . Stack gas velocity, ftlsec 

# v, 

# = 2
. 9 • C p • 

# .J AP • 

# F.
. 2) Moisture A
. Sample gas volume , dscf V

mstd 

# = 0
. 03342 • Vm 

## * (Pbar 

# + B
. Water vapor volume , scf 

# v = 0
. 0472 • 

# v.' Tref

w,td Ie 

## 528 oR 29
. 92 • 28
. 95 

# P, • MW 

# wet



# c. Moisture content, dimensionless 

# Bwo 

# = 3) Stack gas volumetric flow rate 

## A. Actual stack gas volumetric flow rate, wacfm Q 

# = V • A • 60 

# , , B
. Standard stack gas flow rate, dscfm

R021 0458-R 1 C -2 

# Ilellal1
.. ...... 

# _-

## Q 

# = Q * (1- B ) * 

# T ref 

## * 

# P, ,d 

### wo 

# T, 29.92 4) Gaseous Mass Emission Rates. Ib/hr M 

# = ppm * MW; * Q Sd 

## * 60 SV 

# * 10 6 

## 5) Emission Rates. Ib/MMBtu 

## Ib ppm*MW; *F * 20.9 MMBtu SV*10 6 

## 20
. 9-%0 2 

## 6) Emission Factor. Ib/MMSCF 

## Ib 

# = Ib *HHV MMSCF MMBtu VI. Percent Isokinetic 

# 1 = 

# 17.32 

# x 

# T, (Vm 

# std) x 5280 

# R (1- Bwo)O x V, x Ps x Dn 2 

# T"i VII. Particulate emissions a) Grain loading, gr/dscf 

## C = 

## 0.01543 

## (MrlVm std) 

## b) Grain loading at 12% CO 2 , 

## gr/dscf Cm'
. C02 

# = C 

## (121% CO 2) 

## c) Grain loading at 3% O2 , 

## gr/dscf 

# C3 

### % 02 

# = C * 

## 17.9/(20.9-%0 2 ) 

## d) Mass emissions, Ib/hr M 

# = ex Qsd 

## x (60 

## min/hr)/(7000 gr/lb) e) Particulate emission factor
6 

# lIb 20. . 9 lb 1 10 Btu 

# = ex 7000gr x F x 

# 20.9
_ %02

R021 0458-R 1 

## C-3 

# Della/).. 

# ..

# _ ..

# _-

## Nomenclature : 

## As Bwo C' 2% C02 C 3 % 02 

## C 

# C

p 

## On 

## F H HHV 

## I 

# Mn 

# M MW 

# M

wJ



# o**P** 

# P bar 

# Ps 

### Psg 

# a a ws 

# a Sd 

## SV 

# Tm T re f 

# Ts Vs Vic 

# V

m V mstd 

## V wstd 

# Y

d



## R021 0458 - R 1 

# = stack area , 

## ft2 

# = flue gas moisture content , dimensionless 

# =

particulate grain loading , 

## gr/dscf corrected to 12% CO 2 

## = particulate grain loading , 

## gr/dscf correct ed to 3% CO 2 

# =

particulate grain loading , 

## gr/dscf = pitot calibration factor , d i mensionless 

## = nozzle diameter, in. 

# = fuel F-Factor , dscf/MMBtu 

## @ 0% O 2 

## = orifice different i al pressure, iwg 

# =

fuel higher heating value, Btu/SCF 

## = % isokinetics 

# =

mass of collected particulate, mg 

## = mass emission rate of specie i, Ib/hr 

# = molecular weight of flue gas , Ib/lb-mole 

## = molecular weight of specie i: 

# S02: 64 NO
. : 

# 46 CO : 28 HC : 

# 16 = sample time , min
. 

# = average velocity head, iwg 

# = 

# ( .J

t,.p) 2 

# =

barometric pressure, inches Hg 

# = stack absolute pressure, inches Hg 

## = stack static pressure , iwb 

# =

wet stack flow rate at actual cond itions , wacfm 

## = wet stack flow at standard conditions, wscfm 

## = dry standard stack flow rate, dscfm 

# =**s~ecif c**  

## molar volume of an ideal gas at standard conditions ,



## ft lib-mole 

# =

meter temperature , 

# oR 

# =

reference temperature , 

# oR = stack temperature , 

# o R 

# = stack gas velocity , .ft/sec 

# = volume of liquid collected in impingers , ml 

# = uncorrected dry meter volume , dcf 

## = dry meter volume at standard conditions , dscf 

## = volume of water vapor at standard conditions , scf 

# = met er calibration coeffic i ent

C-4 

# 1Je/1811
..

# _--

## APPENDIX D FORMS

R0210458-R1 D-1

# South Coast Air Quality Management District 21865 Copley Drtve. DIamond Bar. CA 91765-4178 (909) 396-2000 • 

### www.aqmd.gov

Mr. Robert A. 

### Finken Delta Air Quality Services, Inc. 1845 N. Case Street Orange, CA 92865 Subject: LAP Approval Notice Reference 

## # 96LA 1220 Dear Mr. Finken: January 11,2012



### We completed our review 

### of the renewal application you submitted for approval 

### under the South Coast Air Quality Management District's Laboratory Approval Program (AQMD LAP). We are pleased to inform you that your firm is approved for the period beginning January 31, 2012, and ending January 3 I, 2013 for the following methods: SCAQMD Methods 1-4 SCAQMD Method 100.1 SCAQMD Methods 25.1 and 25.3 (Sampling) SCAQMD Methods 5.1, 5.2, 5.3, and 6.1 SCAQMD Rule 1420

- (Lead) Ambient Sampling USEPA CTM-030 and ASTM D6522-00 Thank you for participating in the SCAQMD LAP. Your cooperation helps us to achieve the goal ofthe 

### LAP: to maintain 

### high standards of quality in the sampling and anaJysis of source emissions. You may direct any questions or infonnation to LAP Coordinator. Glenn KasaL He may be reached by 

### telephone at (909) 396-2271, by facsimilie at (909) 396-2099, or via e-mail at gkasai@aqmd.gov.

RE:GK/gk cc: Mike Garibay 

### Glenn Kasal 120111 LapRenewaLdoc

# S:~& ;/

# ~n, Senior Manager Laboratory Services & 

### Source Test Engineering



# Dellafl R021 0458-R 1 D-2**.....,--**

### ::0 

### a N**~** 

### a 

# .... 

# '" '" ::0**~**



# o W**.~**



# Ii !:> State of California 

# Air Resources Board Approved Independent Contractor 

# Delta 

# Air Quality Servic
. es, Incorporated This is to certifytl;i<!tthe company listeej**above h~sbeen**  

## approved by the Air 

# ResolircElS' Boaro ti:l ' c(it:Kluct**t:oinp~ance** 

## testing

. . ". .. . . r ..... , . • ... 

## pursuant to titie ' -t7; , Califomia Code of Regulatlbns, section 91207 until

## Ju~36;**·. 2013,** **for** those testmetliods:fisted below:

. - -r 

# ARB S.,...."" Test 

# M.etli;,a,; F I, 2,.3, .4,**", 8,**  

### 17, 20, . 501 109 {CO; 

# co;. NO" 

### 0" SO,)

Alberto Ayai!l, Ph.D., M.S.E
. 

### Chief , Monitoring and Laboratory Division

## ::u a 

# '"**~** 

### a 

# ... en 0> 

## ;0**~**



# o j,.

# !~**I~** 

# C> State of California 

# Air Resources Board Approved Independent Contractor 

# Delta 

# Aii, Quality

# Se~iees>dncorporated This is to certifytl1at the coT)1pany liste<! :'above ' has been approved by the Air**Rfisoui:~S' Board**  

## to ' con,ctilptcomll!iance testing pursuant to titIEi ' 11 ;: Cal[fonila Code'cpf RegUlations; section 91207 until June 

## 30 ; i013;:for**thos&~~t.meihcidii listed**  

## below: 

## " ,. ' 

### ..**~** 

## . . 

# "visibIe · &nissioils Evaluanon U.S. EPATest Methods)OIA: (19n

### nni.\~), 202 .(1991 •• 

### "lion) 

# p
Alberto Ayala.Pfl
. D
. • M.S.E. Ch i ef. Monitoring and Laboratory Division

### STATEMENT OF NO CONFLICT OF INTEREST AS AN INDEPENDENT TESTING LABORATORY 

## (To be completed by authorized source testing firm representative and included in source test report) The following facility and equipment were tested by my source testing firm , and are the subjects of this Statement: Facility 10: 146536

## Oate(s)Tes7te-d~:---------=Te~s~t~P~la-n------------------------------------ Facility Name: .,-____**~C.!:P~V~S~e<!.n!ltl!!:·n~e:!,I.!::E~n~e!lrg:llyt....P!:.r!lo!1ie2!c!:.!t'--** 

### __________ _ Equipment Address:
__ ---:9:;1-:'1
... B<-:i;":xb:'-vl..;"0:!.ri;"v."e'"-=:-:-::;---:-===-
_________ _ City of Industry, California 91748 Equipment Tested:
_____**~U~nl!.!its~1..." 2~,,.,3!.L,-=4:a.,'** **5~,....!6"".f:7~, &~8~:--=--:":,--**  

### ______________ _ Device 10, AlN, 

## PIN : _____ -=0"'1
.... , 0",7""...,0<...1",3,,-,-=0",1,,-9**,,,,0~2,,,5<L'**

### -=3
.... 1 ,...,3",7
... , .,,&:.,:4"'2'__
______________ _ I state, as its legally authorized representative, that the source testing firm of: Source Test Firm: Delta Air Quality Services, Inc. Business Address: ..!.1**",84",5,,-!!N~ .**  

### C"""'as"'e'-S"'t"'re"'e.,t
__________________ _ Orange, California 92865-4234 is an "Independent Testing Laboratory" as defined in District 

## Rule 304(k): For the purposes of 

## this Rule, when an independent testing laboratory is 

## used for the purposes of 

## establishing compliance with District rules or to obtain 

# a District permit to operate, 

## it must meet all of 

## the following criteria:

(1) The testing laboratory shall have no financial interest in the company or facility being tested
. or in the parent company or any subsidiary thereof- (2) The company or facility being tested , orparent company or any subsidiary thereof, shall have no financial interest in the testing laboratory; (3) Any company or 

## facility responsible for the emission of 

## significant quantities of

## pollutants to the atmosphere, or parent company or any subsidiary thereof shall have no financial interest in the testing laboratory ; and (4) The testing laboratory shall not be in partnership with, own or 

## be owned by, in part or in full , the contractor who has provided or installed equipment (basic or control), or monitoring systems, or is 

## providing maintenance for installed equipment or monitoring systems, for the company being tested Furthermore, 

## I state that any contracts or agreements entered into by my source testing firm and the faciiity referenced above , or its designated contractor(s), either verbal or written , are not contingent upon the outcome of the source testing, or the source testing information provided to the**SCAQMD ~_----,**  

### Signature:

# (~**Ll** {.,i 

# J l,>
.

Bob Finken (Name) President <- 

### (Title) FORM ST-110 : stevforl.doc (Revised 

## 11/18/98)

R021 0458-R 1 0-5 Date:
______**~12~17!..!/,!:;20!!..1!..!!2'__** 

## ______ _ 714-279 - 6777 

## 121712012 (Phone) (Date)

# /Je/Ia~ 

# ..

# _--

## APPENDIX E FACILITY PERMIT TO OPERATE CONDITION 029.1

R038842 - R1 

## E-1

## SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT Z 

## 1865 Copley Drive, DJamond Bar, 

## CA 91 765 

# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H FaciJitv 10 :**R~isionll :**  Date : Page : 35 152701 

## o April 15,2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set Corth below: The operator shall also install and maintain a device to continuously record the parameter being measured The measuring device or gauge shall be accurate to within plus or minus 5 percent. It shall be calibrated once every twelve months 

## It shall be calibrated once every twelve months The pressure drop across the catalyst shall not exceed 12 inches water column [RULE 1303(a)(I)-BACT, 5-10-1996; RULE 1303(aXI)-BACT, 12-6-2002; RULE 1703(aX2)

- PSD-BACT, 10-7-1988; RULE 2005, 5-6-2005] [Devices subject to this condition: C4, CIO, C16 , C22, C28, C34, C40, C46] D 12.5 The operator shall install and maintain a(n) non-resettable elapsed time meter to accurately indicate the elapsed operating time from the engine. [RULE 1110.2,2-1-2008; RULE 1303(b)(2)-OtTset, 5-10-1996; RULE I303(bX2) -Offset, 12-6-2002; RULE 1470, 6-1-2007; RULE 2012, 5-6-2005] [Devices subject to this condition; 049] D29.1 The operator shall conduct source testes) for the pollutant(s) identified below. Pollutant(s) to 

# I Required Test Methodes) 

# I Averaging Time 

# I Test Location be tested NOX emissions District method 100.1 1 hour Outlet ofthe SCR serving this equipment CO emissions 

# I District method 100.1 

# I I hour 

# I Outlet of the SCR serving this equipment SOX emissions 

# I AQMD Laboratory Method 307-91 

# I Not Applicable 

# I Fuel sample VOC emissions 

# I District Method 25.3 

# I 1 hour 

# IOutlet ofthe SCR serving this equipment

## SOlIDi COAST AIR QUALITY MANAGEMENT DISTRICT 21865 Copley Drive , Diamond Bar, CA 9 

## J 765


# FACILITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Page : 36 FacilitY 10 : 152707 

### Revision I : 

### 0 Dele : Apri l 15, 2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shall comply with the terms and conditions set forth below: PM 1 0 

# I District Method 5 emissions NH3 emissions 

# I District method 207.1 and 5.3 or EPA method 17 

# I 4 hours 

# 11 hour 

# IOutlet ofthe SCR serving this equipment 

# IOutlet of the SCR

serving this equipment

# Im.i ,< "
.

- . .



# _ - SOUTH COAST AIR QUAUlY MANAGEMENT DISTRICT 21865 Copley Drive, Diamond Bar, CA 91 765


# FACILITY PERMIT T O OPERATE CPV SENTINEL LLC Seaion H Facility 10: Rcvisi o nll : Dale , 

### Page : 37 152707 

## o April 15,20 11



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator sh all comply with the terms and conditions set forth below: The test shall be conducted after AQMD approval of the source test protocol, but no later the later of 180 days after initial start-up or three hundred hours of operations after start-up . The AQMD shall be notified of the date and time of the test at least 10 days prior to the test The test shall be conducted to detennine the oxygen levels in the exhaust
. In addition, the tests shall measure the fuel flow rate (CHI), the flue gas flow rate, and 

## the turbine generating output in MW . The test shall be conducted in accordance with AQMD approved test protocol. The protocol shall be submitted to the AQMD engineer no later than 

## 45 days before the proposed test date and shall be approved by the AQMD before the test commences . The test protocol shall include the proposed operating conditions of the turbine during the tests, the identity of the testing Jab, a statement from the testing Jab certifying that it meets the criteria of Rule 304, and a description of all sampling and analytical procedures The test shall be conducted when this equipment is operating at maximum, average, and minimum loads. For natural gas fired turbines only, VOC compliance shall be demonstrated as follows : a) Stack gas samples are extracted into Summa canisters maintaining a final canister pressure between 400-500 mm 

## Hg absolute, b) Pressurization of canisters are done with zero gas analyzed/certified to contain less than 0.05 ppmv total hydrocarbon as carbon, and c) Analysis of canisters are per EPA Method TO-12 (with pre concentration) and temperature of canisters- when extracting samples for analysis is not below 70 deg F. The test shall be conducted for compliance verification of the BACT VOC 2 .0 ppmv limit. The test results shall 

## be reported with two significant dip;its
.

## SOtIll-f COAST AIR QUALI1Y MANAGEMENT DISTRICT 21865 Copley Drive, Diamond 8ar, CA 91 765


# FACll..ITY PERMIT TO OPERATE CPV SENTINEL LLC Section H Facility ID ; 

### Revision II : Otle : Page : 31 152701 

## o AprillS,2011



# SECTION H: PERMIT TO CONSTRUCT AND TEMPORARY PERMIT TO OPERATE The operator shaD comply with the terms and conditions let forth below: [RULE 1303(a)(I)-BACT, 5-1(1..1996; RULE 1303(aXI)-BACT, 12-6-2002; RULE 1303(b)(l)-Offset, 5-10-19%; RULE 1303(b)(2}-Offset, 12-6-2002; RULE 1703(8)(2)

- PSO-BACT, 10-7-1988; RULE 1005, 5-6-2005) [Devices subject to this condition: DI, D7, D13, Dl9, D25, 031, D37, D43] D29.2 The operator shall conduct source test(s) for the pollutant(s) identified below. Pollutant(s) to be tested NH3 em issions 

# I Required Test Method(s) I District method 207.1

and 5 . 3 or EPA method 17 

# I Avcraging Time II hour 

# I Test Location I Outlet ofthe SCR

serving this equipment The test shall be 

## conducted and the results submitted to the District within 45 days after the test date. The AQMD shaH be notified of the date and time of the test at least 7 days prior to the test. The test shall be conducted at least quarterly during the ftrst twelve months of operation and at least annually thereafter
. The NOx concentration, as determined by the CEMS, shall be simultaneously recorded during the ammonia slip test. If 

## the CEMS is inoperable, a test shall be conducted to 

## determine the NOx emissions using District Method 100 . 1 measured over a 60 minute averaging time period. If the turbine is not in operation during one quarter, then no testing is required during that quarter The test shall be conducted to demonstrate compliance with the Rule 1303 BACT concentration limit [RULE 1303(a)(1}-BACT, 5-10-1996; RULE 1303(aXI}-BACT, 12-6-2002] [Devices subject to this condition: DI, D7, 013, D19, D25, 031, D37, D43]

# END OF DOCUMENT