# Natural Haze Levels II: Application of the New IMPROVE Algorithm to Natural Species Concentrations Estimates Final Report by the Natural Haze Levels II Committee to the RPO Monitoring/Data Analysis Workgroup

# Note: This presentation contains substantial additional information in the notes section of PowerPoint that can be seen in the bottom panel of the “Normal” view mode, and can be printed by selecting “Notes Pages” from the “Print what” selection of the “Print” menu (go to “Files” on the top tool bar and select “Print”). You can also use “Preview” for the “Notes Pages” to more easily read the notes on your computer monitor
. These notes were prepared 1. to aid those hearing the presentation by relieving them of the burden of taking as many notes; 2. to allow

those who haven’t heard the presentation to understand it by providing the additional information that is spoken during presentations; and 3. to provide a more complete documentation of the natural haze levels II approach for anyone who may want to understand it For additional information contact Marc Pitchford at Marc.Pitchford@NOAA.gov

# Overall Goal

• Estimate 20% best and 20% worst natural haze levels for visibility-protected class I areas using the new IMPROVE algorithm for estimating light extinction from aerosol species concentrations.

– Needed for Regional Haze Rule (RHR) rate of progress glide slopes where the new IMPROVE algorithm is used to characterize current haze levels

– Should minimize the technical problems identified in the RHR default natural haze levels that were developed using the original IMPROVE algorithm

# Default Natural Haze Levels Approach

• Typical haze level estimates for East and West

– Typical light extinction by applying the original IMPROVE algorithm to Trijonis natural species concentration estimates for East and West

– Convert to haze index (deciview units) 

# • 20% best and 20% worst haze estimate for East and West

– Best = typical

– 1.28(standard deviation)

– Worst = typical + 1.28(standard deviation)

– Standard deviation is 3dv for the East and 2dv for the West (corresponds to the 10th 

# and 90th 

# percentile)

# Criticism of the Default Approach

• Limitations of the original IMPROVE algorithm

– Biased light extinction estimates at the extremes

– Uses an outdated organic compound mass to carbon mass ratio

– No sea salt (important at a few sites)

– Rayleigh scattering of 10Mm- 1 

# used for all site 

# • Flawed assumptions used to estimate 20% best and worst conditions

– Haze index for natural conditions are not likely to be normally distributed due to inclusion of Rayleigh scattering

– 10th 

# and 90th 

# percentiles don’t correspond to the best and worst conditions if the distribution were normal

# Natural Haze Levels II Approach

• Adjust each of the measured major species concentrations to the Trijonis natural concentration estimates

– Multiply each species concentration at a site by the sitespecific ratio of the (Trijonis natural estimate) divided by the (annual mean concentration) for the species for the 5 year baseline period

– If the annual mean concentration for a species is smaller than the Trijonis natural estimate, make no adjustment

– Current sea salt levels are taken to be natural levels 

# • Apply the new IMPROVE algorithm to the Trijonisadjusted species concentrations at each site to produce a distribution of natural light extinction values
• Convert to deciview and calculate the mean of the 20% best and 20% worst haze levels

# Trijonis-Adjusted Specie Frequency Distributions

• Sipsey Alabama
• Each aerosol species mass concentration frequency distribution scaled to estimated natural mass concentrations
• If current species mean is less than natural estimate, the that species is not scaled
• Geometric shape of species distributions is unchanged Current 2000-2004

Natural Estimate Hanging bars Solid - current mean Dashed - natural estimate mean

# Current and Natural Haze Frequency Distributions

• Sipsey Alabama • Natural scenario joint distribution shape is derived from scaling current aerosol species mass concentrations to natural condition estimates • Allows estimation of best and worst 20% dv or aerosol species extinction

# Natural Haze Levels II

# Default Natural Haze Levels

# Natural Haze Levels II, 10-Year Rate of Progress Glide Path

# Default Natural Haze Levels, 10-Year Rate of Progress Glide Path

# Status and Next Steps

• This presentation is the final report of the Natural Haze Levels II Committee of the RPO Monitoring/Data Analysis Workgroup
• Review comments received by August 25, 2006 will be considered in preparation of the RPO Monitoring/Data Analysis Workgroup approved approach
• Workgroup approved approach is forwarded to the RPOs for their consideration by August 31, 2006
• This presentation, including the natural haze estimates and any modifications will be made available on VIEWS

# Appendix

• Tables of Natural Haze Level II Estimates for all IMPROVE Sites by RPO and State**Site Name**  **State Complete**  **Years Worst** 

**Haze Natural II**  **(dv) Worst** 

**Haze Baseline**  **(dv) 10** **- year** 

**Glide Slope (dv)**  **Class I A rea(s)**  CACR1 Caney

Creek Arkansas 3 11.7 26.4 2.4 Caney Creek UPBU1 Upper Buffalo Wi lderness Arkansas 5 11.7 26.3 2.4 Upper Buffalo BRET1 Breton* Louisiana 4 12.3 0.0 0.0 Breton BOWA1 Boundary

Waters Canoe Area Minnesota 2 11.6 20.0 1.4 Boundary Waters Canoe Area VOYA2 Voyageurs NP #2 Minnesota 5 12.2 19.3 1.2 Voyageurs HEGL1 Hercules-Glades Missouri 3 11.4 26.7 2.6 Hercules-Glade MING1 Mingo Missouri 1 12.5 29.5 2.8 Mingo WI MO1 Wichita Mountains Oklahoma 3 7.6 23.8 2.7 Wichita Mountains BIBE1 Big Bend NP Texas 4 7.2 17.3 1.7 Big Bend GUMO1 Guadalupe Mountains NP Texas 5 6.8 17.2 1.7 Guadalupe Mountains; Carlsbad Caverns 

# CENRAP

MANE-VU & Midwest RPO **Site Name**  **State Complete**  **Years Worst** 

**Haze Natural II**  **(dv) Worst** 

**Haze Baseline**  **(dv) 10** **- year** 

**Glide Slope (dv)**  **Class I A rea(s)**  ACAD1 Acadia NP Maine 5 12.5 22.9 1.7 Acadia MOOS1 Moosehorn NW R Maine 5 12.1 21.7 1.6 Moosehorn; Roosevelt Campobello GRGU1 Great Gulf W ilderness New Hampshire 4 12.1 22.8 1.8 Great Gulf; Presidential Range- Dry River BRIG1 Brigantine NW R New Jersey 5 12.3 29.0 2.8 Brigantine LYBR1 Lye Brook W ilderness Vermont 5 11.9 24.4 2.1 Lye Brook ISLE1 Isle Royale NP Michigan 5 12.5 20.7 1.4 Isle Royale SENE1 Seney Michigan 5 12.8 24.2 1.9 Seney**Site Name**  **State Complet**  **e Years Worst** 

**Haze Natural II**  **(dv) Worst** 

**Haze Baseline**  **(dv) 10** **- year** 

**Glide Slope (dv)**  **Class I A rea(s)**  SIPS1 Sipsy

W ilderness Alabam a 4 11.1 29.0 3.0 Sipsey CHAS1 Chassahowitzka NW R Florida 3 11.3 26.1 2.5 Chassahowitzka EVER1 Everglades NP Florida 4 12.3 22.3 1.7 Everglades SAMA1 St. Marks Florida 2 11.6 26.0 2.4 Saint Marks COHU1 Cohutta Georgia 2 11.2 30.3 3.2 Cohutta OKEF1 Okefenokee NW R Georgia 5 11.5 27.1 2.6 Okefenokee; Wolf Island MACA1 Mam moth Cave NP Kentucky 5 11.2 31.4 3.4 Mam moth Cave LIGO1 Linville Gorge North Carolina 4 11.3 28.8 2.9 Linville Gorge SHRO1 Shining Rock Wi lderness North Carolina 2 11.6 27.9 2.7 Shining Rock SWAN1 Swanquarter North Carolina 2 12.0 25.5 2.2 Swanquarter ROMA1 Cape Romain NW R South Carolina 5 12.2 26.5 2.4 Cape Romain GRSM1 Great Smoky Mountains NP Tennessee 5 11.3 30.3 3.2 Great Smoky Mountains; Joyce Kilm er-Slickrock JARI1 James River Face W ilderness Virginia 4 11.2 29.1 3.0 James River Face SHEN1 Shenandoah NP Virginia 5 11.4 29.3 3.0 Shenandoah DOSO1 Dolly

Sods W ilderness West Virginia 5 10.4 29.0 3.1 Dolly Sods; Otter Creek VIIS1 Virgin Islands NP Virgin Islands 4 10.8 17.0 1.0 Virgin Islands 

# VIST AS + VI**Site Name**  **State Complete**  **Years Worst** 

**Haze Natural II**  **(dv) Worst** 

**Haze Baseline**  **(dv) 10** **- year** 

**Glide Slope (dv)**  **Class I A rea(s)**  DENA1 Denali NP Alaska 5 7.4 9.9 0.4 Denali SIME1 Sim eonof Alaska 3 15.7 18.6 0.5 Sim eonof TUXE1 Tuxedni Alaska 3 11.5 14.1 0.4 Tuxedni BALD1 Mount Baldy Arizona 2 6.6 11.5 0.8 Mount Baldy CHIR1 Chiricahua NM Arizona 5 7.3 13.4 1.0 Chiricahua NM; Chiricahua W ; Galiuro GRCA2 Hance Camp at Grand Canyon NP Arizona 4 7.2 11.7 0.7 Grand Canyon IKBA1 Ike's Backbone Arizona 4 6.7 13.3 1.1 Mazatzal; Pine Mountain PEFO1 Petrified Forest NP Arizona 5 6.6 13.2 1.1 Petrified Forest SAGU1 Saguaro NM Arizona 3 6.5 14.8 1.4 Saguaro SIAN1 Sierra Ancha Arizona 4 6.7 13.7 1.2 Sierra Ancha SYCA1 Sycamore Canyon Arizona 4 6.8 15.3 1.4 Sycamore Canyon TONT1 Tonto NM Arizona 3 6.7 13.9 1.2 Superstition 

# WRAP**Site Name**  **State Complete**  **Years Worst** 

**Haze Natural II**  **(dv) Worst** 

**Haze Baseline**  **(dv) 10** **- year** 

**Glide Slope (dv)**  **Class I A rea(s)**  AGTI1 Agua Tibia California 4 7.7 23.5 2.6 Agua Tibia BLIS1 Bliss SP (TRPA) California 4 6.2 12.6 1.1 Desolation; Mokelumne DOME1 Dome Lands W ilderness California 4 7.5 19.4 2.0 Dome Land HOOV1 Hoover California 3 8.0 12.9 0.8 Hoover JOSH1 Joshua Tree NP California 4 7.3 19.6 2.1 Joshua Tree KAIS1 Kaiser California 2 7.3 14.8 1.2 Ansel Adam s; Kaiser; John Muir LABE1 Lava Beds NM California 4 7.9 15.1 1.2 Lava Beds; South Warner LAVO1 Lassen Volcanic NP California 5 7.4 14.1 1.1 Lassen Volcanic; Caribou; Thousand Lakes; Caribou; Thousand Lakes PINN1 Pinnacles NM California 4 8.1 18.5 1.7 Pinnacles; Ventana PORE1 Point Reyes National Seashore California 3 15.9 22.8 1.2 Point Reyes RAFA1 San Rafael California 2 7.8 18.9 1.8 San Rafael REDW 1 Redwood NP California 5 14.0 18.5 0.7 Redwood SAGA1 San Gabriel California 3 7.1 19.9 2.1 San Gabriel; Cucamonga SAGO1 San Gorgonio W ilderness California 4 7.4 22.2 2.5 San Gorgonio; San Jacinto SEQU1 Sequoia NP California 3 7.6 24.6 2.8 Sequoia; Kings Canyon TRIN1 Trinity California 3 8.3 16.3 1.3 Marble Mountain; Yolla Bolly-Middle Eel YOSE1 Yosem ite NP California 5 7.7 17.6 1.7 Yosem ite; Em igrant 

# WRAP**Site Name**  **State Complete**  **Years Worst** 

**Haze Natural II**  **(dv) Worst** 

**Haze Baseline**  **(dv) 10** **- year** 

**Glide Slope (dv)**  **Class I A rea(s)**  GRSA1 Great Sand Dunes NM Colorado 5 6.7 12.8 1.0 Great Sand Dunes MEVE1 Mesa Verde NP Colorado 5 6.9 13.0 1.0 Mesa Verde MOZI1 Mount Zirkel W ilderness Colorado 4 6.6 10.5 0.7 Mount Zirkel; Rawah ROMO1 Rocky

Mountain NP Colorado 5 7.3 13.8 1.1 Rocky Mountain WE MI1 Weminuche Wi lderness Colorado 4 6.3 10.3 0.7 La Garita; Black Canyon of the Gunnison; Weminuche WH RI1 Wh ite River NF Colorado 4 6.7 9.6 0.5 Flat Tops; Maroon Bells-Snowm ass; West Elk; Eagles Nest HALE1 Haleakala NP Hawaii 4 7.5 13.3 1.0 Haleakala HAVO1 Hawaii Volcanoes NP Hawaii 4 7.2 18.9 1.9 Hawaii Volcanoes CRMO1 Craters of the Moon NM Idaho 4 7.6 14.0 1.1 Craters of the Moon SAWT1 Sawtooth NF Idaho 4 6.5 13.8 1.2 Sawtooth CABI1 Cabinet Mountains Montana 4 7.6 14.1 1.1 Cabinet Mountains GAMO1 Gates of the Mountains Montana 4 6.5 11.3 0.8 Gates of the Mountains GLAC1 Glacier NP Montana 3 9.1 20.5 1.9 Glacier MELA1 Medicine Lake Montana 5 8.0 17.7 1.6 Medicine Lake MONT1 Monture Montana 4 7.8 14.5 1.1 Bob Marshall; Mission Mountains; Scapegoat SULA1 Sula Peak Montana 4 7.5 13.4 1.0 Selway-Bitterroot; Anaconda- Pintler ULBE1 UL Bend Montana 4 8.2 15.1 1.1 UL Bend 

# WRAP**Site Name**  **State Complete**  **Years Worst** 

**Haze Natural II**  **(dv) Worst** 

**Haze Baseline**  **(dv) 10** **- year** 

**Glide Slope (dv)**  **Class I A rea(s)**  JARB1 Jarbidge W ilderness Nevada 4 8.0 12.1 0.7 Jarbidge BAND1 Bandelier NM New Mexico 5 6.3 12.2 1.0 Bandelier BOAP1 Bosque del Apache New Mexico 3 6.8 13.8 1.2 Bosque del Apache GICL1 Gila W ilderness New Mexico 4 6.8 13.1 1.1 Gila SACR1 Salt Creek New Mexico 4 6.9 18.0 1.9 Salt Creek SAPE1 San Pedro Parks New Mexico 4 6.2 10.2 0.7 San Pedro Parks WH IT1 Wh ite Mountain New Mexico 3 6.9 13.7 1.1 Wh ite Mountain WH PE1 Wheeler Peak New Mexico 3 6.6 10.4 0.6 Wheeler Peak; Pecos LOST1 Lostwood North Dakota 5 8.1 19.6 1.9 Lostwood THRO1 Theodore Roosevelt North Dakota 4 7.9 17.7 1.6 Theodore Roosevelt CRLA1 Crater Lake NP Oregon 3 8.0 13.7 1.0 Gearhart Mountain; Crater Lake; Diam ond Peak; Mountain Lakes HECA1 Hells Canyon Oregon 3 8.4 18.6 1.7 Hells Canyon KALM1 Kalm iopsis Oregon 4 9.5 15.5 1.0 Kalm iopsis MOHO1 Mount Hood Oregon 4 8.5 14.9 1.1 Mount Hood STAR1 Starkey Oregon 4 9.0 18.6 1.6 Eagle Cap; Strawberry Mountain THSI1 Three Sisters W ilderness Oregon 5 8.9 15.3 1.1 Three Sisters; Mount Jefferson; Mount Washington 

# WRAP**Site Name**  **State Complete**  **Years Worst Haze** 

**Natural II (dv)**  **Worst Haze**

**Baseline (dv)**  **10 -** **year**

**Glide Slope (dv)**  **Class I A rea(s)**  BADL1 Badlands NP South Dakota 5 8.1 17.1 1.5 Badlands WI CA1 Wi nd Cave South Dakota 5 7.8 15.8 1.3 Wi nd Cave BRCA1 Bryce Canyon NP Utah 5 7.0 11.6 0.8 Bryce Canyon CANY1 Canyonlands NP Utah 5 6.5 11.2 0.8 Canyonlands; Arches CAPI1 Capitol Reef NP Utah 2 5.7 10.0 0.7 Capitol Reef ZION1 Zion Utah 3 7.1 13.2 1.0 Zion MORA1 Mount Rainier NP Washington 4 8.6 18.2 1.6 Mount Rainier NOCA1 North Cascades Washington 2 8.1 14.0 1.0 North Cascades; Glacier Peak OLYM1 Olympic Washington 3 8.5 16.7 1.4 Olympic PASA1 Pasay

ten Washington 4 8.4 15.2 1.1 Pasay ten SNPA1 Snoqualm ie Pass Washington 4 8.5 17.8 1.6 Alpine Lakes WH PA1 Wh ite Pass Washington 4 8.5 12.8 0.7 Mount Adam s; Goat Rocks BRID1 Bridger W ilderness Wyom ing 5 6.7 11.1 0.7 Bridger; Fitzpatrick NOAB1 North Absaroka Wyom ing 3 6.9 11.5 0.8 North Absaroka; Washakie YELL2 Yellowstone NP 2 Wyom ing 5 6.6 11.8 0.9 Yellowstone; Red Rock Lakes; Grand Teton; Teton 

# WRAP