### P. 1



# OAR Box 1851 Prepped by Keeia Richards



# Document

Number: 

# 30 ) ll-A-4
Docket Number: 

# A-90-1 9

Printed 11/19/2008 11:19:51 AM Sheet 30 of 41

### P. 2



# r 1 

# I 1



# J J J J ] ] ]
J 

# A-90-1 9 ll-A- 4 

# EPA-450/3-73-005- d

1 J 

# SURVE

Y REPORT S -^SSCKBT 

# O N ATMOSPHERI C EMISSIONS FRO M THE PETROCHEMICAL INDUSTR

Y VOLUM E I V
b y J

. W

. Pervier , R

. C

. Barley , D

. E

. Field , B

. M

. Friedman , R

. B

. Morris , W

. A

. Schwart z

Houdr y Divisio n Ai r Product s an dChemicals , Inc

. P.O

. Bo x 42 7 Marcu s Hook , Pennsylvani a1906 1
Contrac t No

. 68-02-025 5
EPAProjec t

Officer : Lesli e B

. Evan s Prepare dfo r 

# ENVIRONMENTAL PROTECTIO NAGENC Y Offic e of Ai r an dWate r

Program s Offic e of Ai r Qualit y Plannin g an dStandard s Researc hTriangl e Park , N

. C

. 2771 1

Apri l 197 4



# ~ L

### P. 3



# Thi s repor t

i s issue db y th e Environmenta l Protectio nAgenc y t o repor t technica l dat ao f interes t t o alimite dnumbe r

of readers

. Copie s ar e availabl e fre e o f charg e t o Federa l employees , curren t contractor s an dgrantees , an dnonprofi t organization s - a s supplie s permi t

- fro mth e Ai r

Pollutio nTechnica l Informatio nCenter , Environ

menta l Protectio nAgency , Researc hTriangl e Park , Nort hCarolin a27711 , o r fro m th e Nationa l Technica l Informatio nServic e 528 5 Por t Roya l Road , Springfield , Virgini a22151

.

Thi s repor t

wa s furnishe dt o th e Environmenta l Protectio nAgenc y b y Ai r Product s an dChemicals , Inc

. , Marcu s Hook , Pennsylvania , i nfulfillmen t of Contrac t No

. 68-02-0255

. Th e content s of thi s repor t

ar e reproduce dherei na s receive d fro mAi r Product s an dChemicals , Inc

. Th e opinions , findings , an dconclusion s expresse dar e thos e of th e autho r

an dno t necessaril y thos e of

th e Environmenta l Protectio nAgency

. Mentio nof compan y o r

produc t name s i s no t

t o b e considere d a s a nendorsemen t

b y th e Environmenta l Protectio nAgency

.

Publicatio nNo

. EPA-450/3-73-005- d 

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### 'SUSPENSION ' V U



# tm^soumai ' mocns n Pag o l« f ) I M Cod aNo . :lty , Ton s o f

Polystyrena/Yr . t o Productio n- 1 o f Hu . •lon e t o Ataosphar e

lo w - Lba./Hr . lo w Characteristic , Continuou s O r Intermittent I f lotar«ittact , Hra./Yr . Plo w •poeltlon , Tona/To

no f Polyatyraoa 8tyreaa Polyatyrao a Vata r M M Nitroge n •thy l Bensen e hydrochlori cAci d U i PeatStack s 26- 1 100.00 0 

### JfcUt t Reactor Vaot
1,140,000/Yr . Continuou s

•sigh t- Ft . Maaate r• Incha a Exi tCa s Taa» . - F ° tom/Btaek . Lssla aContro l Davlca s Cyclon aSeparato r •a g P I 1 ta r CoadaaaaT/K . 0 . Dru m OthO T analysi s Dat ao rFrequenc y o f Staplin g Sna p l aTa p Locatio n Typ ao f Analysi s Odo rProbla a amar y o f Ai rPollutant s Hydrocarbons , Ton/To n o f Polystyren e Particulates , Ton/To no f Polystyren e HO, , Ton/To n o f

Polystyren e 80, . Ton/To o o f

Polyatyrao a C O . Ton/To no f

Polystyren e .0039 9 .0017 1

Ya a 

### 1 4 2 19 5 - 27 0 150 0 Non a

Neve r N/ A Calc'd . 2 a- 2 

### 150,00 0 Vashln g Exhaus t 

## <* ) 137,52 0 Continuou s Drya r

Exhaust s (B ) 261,28 8 Continuou s

.0000 2 

### Bi n

M M * Bjaxeuet s 

# (c ) 229,20 0 Continuou s



## + 4.0447 1 Ya a 1 0 4 0 t o 5 0 1 2 t o 1 8 Aablen t 300 0 (Avg. ) Non * 7.6849 4

Yaa 6 2 0 t o 5 0 1 2 t o 4 8 Aablen tt o 633 0 (Avg. ) Ya a + 120 » 6.7411 7

Ya a 1 7 2 0 t o 8 0 5 t o 1 8 Aablen t 294 0 (Avg. ) Non a "Alrvayins, " Systaa aExhaus t

105.43 1 Continuous



## +

3.1009 4 Yaa 2 0 

## i o t o e o 5 t o 8 Aablen t 115 0 (Avg. ) Yaa Extrude r

Exhaust s 

# <*) 91,68 0 Continuou s Alrveytn g Systaa aExhaus t

(Extrude rArea )
32.0 M (? ) Cantlouon s

.0039 9 0 0 0 0 

### Neve r

N/ A Calc'd . On

e tla e No tSpecIfla d Calc'd . Neve r

N/ A Calc' d Have r N/ A Calc' d 2.6964 7 Ya a 2 

## t o 1 2 x1 2 Aablen t 10,00 0 Ya a

B.E . Scrubbe r Neve r N/A Calc'd
. Ya a 7 1 0 t o 6 0 5 t o 8 Aablen t 100 0 Av g Ya a 

## + •

Neve r N/ A Calc'd
.



### + ) Rat acanno tb e determined . • )

j »

T J ft9 

### 1

NAT ! TABL E PS-II I POLTSTTBJOs

I PEOMUUTIO

W VI A 'SOBPEmBIOH ' AM

D 'JOUTnOH ' PROCESSE S Pag e 2 o f 3 EP A Cod e No . :lty . Ton e o f

Polystyrene/Yr . I n Productio n- I o f Max . iton e t o Atmospher e :rea m
lo w- Lba./Hr . lo wCharacterletlc . Continuou s o rIntermitten t i f Intermittent , Ih-s./Yr . Flo w taltlon , Tons/To no f Polyetyren e StyTen e Polyetyren e Vata r Pentao a Nitroge n Ethy l Benaen e Hydrochlori cAd d Ai r an tStack s Balght - Ft . Diamete r - Inche s Exi tGa s Tarns . • F ° SCFM/Stac k ladeelo n Contro l Device s Cycloo aSeparato r Ba g Filte r Condamear/K . 0 . Dru m Othe r kn a lysi s Dat a or Frequenc

y of Samplin

g Sampl e Ta pLocatio

n Typ e o f Analysi s Odor Proble

m •aer y o f Ai r Pollutant s Hydrocarbons , Ton/To nof Polystyren

e Pertlculetes . Ton/To no f Polystyren

e NO, , Ton/To

no f Polystyren

e 80, , Ton/Tono f Polystyren e C O , Ton/Tono f polystyren e Emergenc y Vent s - Reactor Sectio n Not Specifie

d Intermittent No t Spaclfte

d 

## +
• +

No Drye r Exhaus t Vent (G ) 39.65 2 

## •cTc 

### Conveyor Ven t (H ) 20,32 4 Continuou s 26- 3 58,75 0 Nona Pneumati c Convwym r Ven t(tf ) 6,23 1 Continuou s

+ IxtruJe r

Hood Exhaus t Ven t 14,89 8 Continuou s

+ Pneumati c

Conveyo r Ven t(H ) 5.60 3 Continuou s

+ Pneumati c

Conveyo r Ven t 5,60 3 Continuou s

+

None

None Never N/ A N/ A N o 2.9562 1

Te a 3 . 

## 4 1 1 3 1 t 5 ll»x « 16 0 | 15 0 57 0 K34 0 P8- 1 + 1 2 6

U 3x8. 5 15 0 17* 0 1.5152 1

N o

PS- 2 (A»8 )

On e tim e Std . Solv

e No Non e Never N/ A N/ A N o

Cannot b

e determine

d .4645 5 N o

PS- 2
+
Non e Neve r N/ A N/ A N o
•lned . (Avg. ) 1.1107 1 Ye s 1 6 0 2 7 18 0 331 0 Non e

Non e Neve r N/ A N/ A No .4177 8 (Avg. )

No

PS- 3
+
Non e Neve r N/ A N/ A N o .4177 8 (Avg. )

N o

P8- 3
+
None Neve r N/ A N/ A N o

T l CJ l

# 1 [ t fI f

TABL E FS-II I HATICTtATllflSSIOM

B IgVEWOR

I HiLTBTTEBm

T PEOBOCTTCB

I T U
len tEP A Code No . •peclty . Ton s o f

Polystyrene/Yr . •og e I n Productio n- 1 o f Max . •lsslon s t o Atmospher e Stree a
Flo w - Lbe./Hr . Flo w Charecterlstlc , Continuou s o r Intermittent i f Intermittent , Hrs./Yr . Flo w Composition , Tons/Tono f Polystyren e 8tyren e Polyetyren e Mete r Pantan e Nitroge n Ethy l Benaen e Hydrochlori cAci d Ai r Ven t8teck a Numbe r Heigh t- Ft . Diamete r- Inche s Exi tGa s Team . - F ° SCFM/Stac k Emissio n Contro l Device s Cyclon e Sepereto r Ba g Filte r Condenser/K . 0 . Dru m Othe r Analysi s Dat ao rFrequenc y o f Samplin g Sempl e Te p Loectlo n Typ e o f Analysi s Odo rProble m Summar y o f Ai rPollutant s Hydrocarbons , Ton/To no f Polystyren e Partlculetes , Ton/To no f Polystyren e NO, , Ton/To no f

Polystyren e -SO, , Ton/To no f

Polystyren e C O , Ton/To no f

Polystyren e Fee d Prep . Purg e 2 4 Continuou s
.0003 2

.0087 1 .0003 3
Ye s 1 3 5 8 x2 4 Ambien t 5 No

Neve r Non e Calc'd . No '80SPEW S IONFee d Prep . Purg e 4 Intermitten t 3 Hra./Da y <0000 1

.MM2 2 <•. 00001
Ye a 1 5 0 1 2 Ambien t 1 N o

Neve r Non e Calc'd . N o AI D 'SO U

8olven t Sectio n 8 0 Contino a
.0007 7

.02*4 5 .0010 7
Ye a 1 4 5 1 8 5 1 7 No

Neve r Non e Calc'd . N o 

## mom " FR

O

•acav . Ves t

m a CESSES

26- 4 10,00 0
Hoed Exheua t Fro m Extrusio n & Palletin g Section s 6,87 6 Continuou s

• f



### 2.7070 9 Ye s 1 2 5 7 x 8 9 0 150 0 N o

Neve r Non e Calc'd . N o .0024 9 + 0 0 0 Palletlae r Ven t 4,49 7 Continuou s

.0560 2

1.7144 9 Ye s 1 2 5 1 0 x1 2 9 0 100 0 M o

Neve r Hon e Calc'd . N o Pag e 3 o f 3

Hood Exhaus t Pro aExtrusio n * - Pelletin g Section s 6.87 6 Continuou s



## +

2.7070 9 Te e 1 2 5 7 x 8 9 0 150 0 No

Have r Non e Calc'd . M o Pneumati c Conveyo r 4.81 3 Continuou s



## +

1.8949 6 Te a ' 4 3 0 t o 6 0 3 t o 1 0 100 * 105 0 No

Neve r Non e Calc'd . N o

| T J 

### lb )TABL E PV-II I NATIONAL EMISSION S INVENTOR Y POLYVINY

L CHLORID

E Peg s 1 o f8 Company Locatio n 

### EP A Cod s No . Cspsclt y - Ton s o f

Polyviny l Chlorlde/Yr . Aversg e Productio n- Ton s o f PVC/Yr . Seasona l Rsng e I n Productio n - 7. o f Max . Emission s t o Atmospher e Street s - Lette ro nFlo wDiagra m Descriptio n
Flo w- Lbs./Hr . o f

Pollutant s Flo wChsracterletl c- Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Flo w Compositio n- Ton/To n o f PV C Hydrocarbon s Particulate s C O Seapl e Locstlo n Dst e o rFrequenc y o f Ssmplln g Typ e o f Analysi s Odo rPresen t Ven tStock s Flo w- SCF

M pe rstoc k Numbe r Heigh t- Fee t Diamete r- inche s Exi tGes Temperetur e - o p Emissio n Contro l Devic e Typ e - Flar e Be g Filter s Cyclon e Vote rScrubbe r Othe r Cstslo gI . D . Numbe r Tots l Hydrocarbo nEmission s - Ton/To n PV C Tots l Particulat e - Ton/To n PV C Tota l N0

„ - Ton/To nPV

C Tota l SO , - Ton/To nPV C Tota l C O - Ton/To nPV

C 27- 1 37,50 0 37,50 0 1 5 Viny l Chlorid e Ven tCondense r 8 Continuou s
0.000 8


### Non e No tSemple d Non e N o
17. 2 1 6 9 3 

### 6 5 Non e Indicate d 27- 3 50,00 0 SO,00 0 0

0.000 8 

### Viny l Chlorid e Ven tCondense r 1 2 Continuou s
0.001 0
None NotSemple d None N o
No tIndIcete d I 5 0 1. 5 3 0 Ye s



### Ven tCondense r 27-3.10 1 0.001 0 Viny l Chlorid e fra a Viny l Chlorid e Stil l Bett c
Continuou s
0.000 2


### Non e No t Seesle d 

### Non e N o
No tIndlcete d 1 10 0 1. 5 29 0 Ye s



### Viny l Chlorid e Still * 27-3.102 * 0.000 2 E Drye r Collecto r Effluen t 19 5 Continuou s
0.0101* * 0.0016* * Non e No t Seaple d Non e N o
15,00 0 5 0 2 4 x2 4 13 0 Ye s

27-3.10 3 0 010 1 0.001 6

*Thi s entry

la mod e I nsccordanc e wit hthe respondent' s labelling . **Frot n"Engineerin g Calculetion s en dplent Materie l Balance" .

4 1 junu-tii-^- a 

# il -TABL E PV-Il l NATIONA

L EMISSION S INVENTOR Y POLYVINYL CHLORID E Peg e 2 o f 8 Compan y LocatIo n EP A Cod e No . Capacit y - Ton s o f Polyviny l Chlorlde/Yr . Averag e Productio n - Ton s o f PVC'Yr . Seasons l Rsng e I n Productio n - I o f Msx . Emission s t o Atmospher e Street s - Lette ro n Flo wDlsgrs m Descriptio n

Flo w- Lbs./Hr . o f Pollutent a Flo wCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Flo w Compositio n - Ton/To n o f PV C HydrocSTbon s Psrtlculste s C O Sampl e Locetlo n Dat e o rFrequenc y o f Samplin g Typ e o f

Analyst * Odo rPresen t Ven tStock s Flo w- SCF

M pe rstoc k Numbe r Heigh t- Fee t Disaste r- Inche s Exi tGs s Temperstur e - o f Emissio nContro l Devic e Typ e - Fler e

Ba gFilter s Cyclon e Mete rScrubbe r Othe T Cetelo g I . D . Numbe r Tote l Hydrocarbo n Emission s Tots l Particulat e - Ton/To n Tote l NO , - Ton/To nPV C Tote l SO , - Ton/To n PV C Tote l C

O - Ton/To n PV

C - Ton/To n PV C PV C G Sil o Collecto

r Fine s

Continuou s

0.000 3
Non e No t Semple

d Non e N o



## ** * ** * 7 5 8 9 5 Ye s

27-3.10 4 0.000 3 H Begger Collecto

r Fine s 1 Continuou s 27- 3 50.00 0 50.00 0 0
J

Bul k Loadin

g Collector Fine s
3 i Continuou s

0.000 1
Non e Not Semple

d Non e N o

50 0 3 3 0 8 9 5 Ye s

27-3.10 5 0.000 1 K Fugitiv

e Emission s

0.002 0 0.000 3
None Not Sample

d None N o

1.50 0 2 3 0 8 9 5 Ye s

27-3.10 6 0.000 3 0 002 0

***U, 50 0 SCF

M tots l flo

w fro m 1 2 silos throug

h2 2 dus t collectors .TABL E PV-II I NATIONA

L EMISSION S INVENTOR Y POLYVINY

L CHLORID

E Pag e 3 o f 8 Compan y Locatio n EP A Cod e No . Capacit y - Ton s o f Polyviny l Chlorlde/Yr . Averag e Productio n - Ton s o f PVC/Yr . Sessone l Rsng e i n Productio n- 7. o f Msx . Emission s t o Atmospher e Strea m - Lette ro nFlo wDiagra m Descriptio n
Flo w- Lbs./Hr . o f Pollutent 8 Flo wCherecterlstl c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Flo w Compositio n - Ton/To no f PV C Hydrocsrbon s Pertlculete s C O Senpl e Locetlo n Det e o rFrequenc y o f Semplln g Typ e o f

Analysi s Odo rPresen t Ven tStock s Flo w- SCF

M pe rstoc k Numbe r Heigh t- Fee t Dlemste r- Inche s Exi tGs s Temperatur e - ° T Emissio n Contro l Devic e Typ e - Fler e

Be gFilter s Cyclon e Usta rScrubbe r Othe r Catalo gI . D . Numbe r Tota l Hydrocarbo n Emission s - Ton/To nPV C Tots l Psrtlculat e - Ton/To n PV C Tota l NO , - Ton/To n PV C Tots l SO , - Ton/To n PV C Tots l C

O - Ton/To n PV

C Viny l Chlorid e Ven tCondense r 1 Continuou s
0.000 2

Non e No tSemple d Non e N o
0.0 1 1 5 7 1 4 5 Non e Indicate d 

### E Drye r Collecto

r Effluent 2 Continuou s 27- 4 30.00 0 30.00 0 0 Non e "Da y Storage " Collecto

r Fine s 0 0 3 Continuou s C Bul k Storege Collector Fine s 0,0 2 Continuou s H Begger Collecto

r Fine s 0.0 2 Continuou s

0.000 3 Non e No tSemple d Non e N o 25,00 0 1 5 6 2 6 x4 6 15 0 Ye s

0.000 2 VJ.O.P . Dus tCollecto r 27-4.10 1 0.000 3 Negligibl e Non e No tSemple d Non e N o 3,75 0 1 5 6 1 3 x1 4 10 0 Ye s

27-4.10 2 Negligibl e Negligibl e Non e No tSemple d Non e N o
1.60 0 I 7 0 9 10 0 Ye s

27-4.10 3 Negligibl e Negligibl e 

### Non e No t Semple

d Non e N o
2.20 0 1 2 9 1 0 x1 0 8 5 Ye s

27-4.10 4 Negligibl e

•c oCompan y

Locatio n EP A Cod e No . Cspsclt y - Ton s o f Polyviny l Chloride/Yr . Averag e Productio n - Ton s o f PVC/Yr . Seasona l Rang e I n Productio n- 7. o f Max . Emission s t o Atmospher e

. Strea m - Lette ro nFlo wDiagra m Descriptio n

Flo w- Lbs./Hr . o f Pollutant s Flo wCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Flo w Compositio n - Ton/To n o f PV C Hydfocsrbon s Particulate s C O Sampl e Locetlo n Dat e o rFrequenc y o f Ssmplln g Typ e o f

Anelysl s Odo rPresen t Ven tStock s Flo w- SCF

M pe rstoc k Numbe r Heigh t- Fee t Dlemete r- Inche s Exi tGe s Temperetur e - ° F Emissio nContro l Devic e Typ e - Fler e

Ba gFilter s Cyclon e Vote rScrubbe r Othe r Catalo gI . D . Numbe r Tote l Hydrocarbo nEmission s - Ton/To nPVC Tote l Particulat e - Ton/To n PV C Tote l NO , - Ton/To n PV C Tote l S0 X- Ton/To n PV C Tote l C

O - Ton/To n PV

C B Slurr y Tan kVen t 

## *** * TABLE PV-II I

NATIONA L EMISSION S INVENTOR Y POLYVINYL CHLORID E

C Centrifug e Ven t 

## *** * Intermitten tIntermitten t

3 1 1 2 2 16 0 Non e 1 5 1 3 5 4 15 0 Non e 27- 5 47.50 0 47,50 0 0 E Drye rCollecto r Effluent**** * 82 3 Continuou s

0.059 9 0.002 2 0.013 4 Non e No tSemple d Non e N o Roter y Kil n 33.00 0 1 10 0 3 0 x3 6 18 0 Ye s Spre y

Drye r 38,00 0 1 8 0 6 0 14 0 Ye s Peg e 4 o f B

D Viny l Chlorid e Ven tCondense r 3 8 Continuou s
0.003 4

Non e No tSemple d Non e N o

Non e 

## ' Fugitiv e Emission s 8 6 I Continuou s
0-007 5



## '

Negligibl e Negligibl e Dus tCollecto r 0.059 9 0.002 2

0.013 4 0.003 4 0.007 5



## -* > ****Th e comblnetio n o f strea m flo wrst e sn d viny l chlorid e compositio n rsng e (o f 0. 0 t o 0. 5 vol . 7. ) lndlcste d b y th e responden tgiv e negligibl e emission s effect s *****Responden t27- 5 refer s t o "cyclones" , o npag e 6 (a ) an d t o "dus tcollector " o n peg e 6 (f) , bu tunde r"Sectio nIV , Emissio nContro l Device" , h e seys . "N o emissio n contro l devices" . I f a n In-dept h stud y ensue s relativ e t o th e 27- 5 dete , th e definitio n o f "emission s contro l device " shoul d b e reviewe d wit h th e respondent ^ an d th e questionnair e dat aamende d i f necessary . Further , i tshoul d b e note d the tth e "Drye rCollecto rEffluent " emissio ndst e er e calculate d (t o th e exclusio no f samplin g an d tes tmethods) .TABLE PV-11 1

Compan y Locatio n 

### EP A Cod e No . Cspsclt y - Ton s o f

Polyviny l Chloride/Yr . Avsrsg s Productio n- Ton s o f PVC/Yr . Ssssona l Rsng e I n Productio n - 7 . o f Max. Emission s t o Atmospher e Street s - Lette ro nFlo wDlegre m Descriptio n
Flo w- Lbs./Hr . o f

Pollutant s Flo wCharecterlsti c- Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Flo w Compositio n- Ton/To n o f PV C Hydrocarbon s Particulate s C O Sampl e Locetlo n Dat e o rFrequenc y o f Semplln g Typ e o f Analysi s Odo rPresen t Ven tStack s Flo w- SCF

M pe rstac k Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temperatur e - ° F Emissio n Contro l Devic e Typ e - Fler e Be g Filter s Cyclon e Wate rScrubbe r Othe r Cetelo g I . D . Numbe r Tota l Hydrocarbo nEmission s - Ton/To n PV C Tots l Partlculet e - Ton/To n PV C Tots l N0 X

### - Ton/To nPV C Tots l SO , - Ton/To nPV C Tots l C O - Ton/To nPV

C D Viny l Chlorid e Ven tCondense r 9 Continuou s NATIONA L EMISSION

S INVENTOR

Y POLYVINY

L CHLORID

E

27- 6 45.00 0

. 45.00 0 33. 3 E.G.H. J Collecto r Effluen tStream s 

## ***** * Continuou s Pag e 5 o f 8

0.000 9 

### Sampl e Top s A s Neede d Orsat , Usin g Xylen e N o
3 1 7 0 ebov e gred e 2 7 0 - 8 0 Ye s



### Ven tCondense r 27-6.10 1 0.000 9 Fugitiv e Emission s
1 0 Continuou s

0.001 0

• led Non e No t S « Non e Non e Indicate d D F 

### 27 M 5M H 

### 1.4 M J

38.35 M L

5M N

1.4 M

16 0 Ye e 11 0

Ye e Ambien t

Ye s 16 0

Ye a 11 0

Ye s As

m len t Ye s

27-6.10 2 27-6.10 3 27-6.104-11 0 27-6.11 1 27-6.11 2 27-6.11 3 0.001 0

******Re*ponden t 27- 6 include s no stsc k Informatio nfo r thes e streams ; andpollutan t flow s sr e lndetermlnete . sinc e th e composition s er e bese do nPVC loedlng s sn d er e no t quantifie d

### Compan

y Locatio n EP A Code No . Cepeclt y - Ton s o f

Polyviny l Chlorlde/Yr . Aversg e Productio n- Ton s o f PVC/Yr . Seesone l Rsng e i n Productio n - 7 . o f Mex . Emission s t o Atmospher e Street s - Lette ro nFlo wDiagra m Descriptio n
Flo w- Lbe./Hr . o f

Pollutsnt s Flo wCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Flo w Compositio n- Ton/To n o f PV C Hydrocarbon s Pertleulete s C O Sampl e Locstlo n Dat e o rFrequenc y o f Samplin g Typ e o f Analysi s Odo rPresen t Ven tStock s Flo w- SCF

M pe retac k Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temperatur e • o F 

### Emissio n Contro l Devic e Typ e - Flar e Be gFilter s Cyclon e Vote rScrubbe r Othe r Catslo g I . D . Numbe r Tote l Hydrocarbo nEmission s - Ton/To n PV C Tots l Particulat e - Ton/To n PV C Tots l NO , - Ton/To n PV C Tots l S0 X

### - Ton/To nPV C Tots l C O - Ton/To nPV

C TABL E PV-II I NATIONA L HUB S 10 W INVENTOR Y POLYVINY

L CHLORID

E



## -

E Drye r Collecto rEffluen t 9 Continuou s

0.000 7 Non e No tSemple d Non e Non e Indlcete d 54,00 0 1 9 0 3 2 x4 2 13 0 - 15 0 y ea 

### ****-** * 27- 7 62.50 0 61,70 0 (Estimated ) 7. 7 G Sil o Collecto rEffluen t 0. 3 Continuou s
Negligibl e Non e No tSample d Non e Non e Indlcete d 1,50 0 3 (guess ) "6 5 - 82 " "2 0 - 31 " "Abou tAmbient " Y(|AAA"AB B Pag e 6 o f8



### "Dus tCollector " 

## ****** * 0.000 7 

### "Dus tCollector " 

## ****** * "Strippin g V*ot " 1 0 Continuou s
0.000 7


### Nona No tSample d None Non e Indicate d "1,00 0 Lbs./Da y f75 Z H 2 

### 0 . balenc e VCM) " I 3 8 3 

### 21 2

0.000 7



### ******* F 

### o r in-dept h stud yusing 27- 7 informstlon , "Emission Contro l Device " definitio n woul d reaulr e clsrlfIcetlo nt o th e th e respondent , since h e report s for thi s cstegor y on th e questionnaire : "No t Applicable"
.

UPTABL E PV-II I

Compan y Locatio n EPA Cod e No . Capsclt y

- Ton s o f Polyviny l Chlorlde/Yr . Aversg e Productio n- Ton s o f PVC/Yr . Seesone l Rang e i nProductio n- 7 . o f Max . Emission s t o Atmospher e Strea m - Lette r o nFlow Diagra m Descriptio n

Flow - Lbs./Hr . o f Pollutant s Flow Characteristi c - Continuou s o r Intermitten t i f Intermitten t - Hrs./Yr . Flo w Compositio n- Ton/To no f PVC Hydrocerbon s Particulate s C O Sampl e Locatio n Dat e o r Frequenc y o f Samplin g Typ e o f Anelysl s Odo r Presen t Ven t Stock s Flo w - SCF M

pe r stoc k Numbe r Heigh t - Fee t Dlemete r - Inche s Exi t Ga s Temperatur e - o p Emissio nContro l Devic e Typ e - Fler e

Be g Filter s Cyclon e wate r Scrubbe r Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo nEmission s - Ton/To nPVC Tots l Particulat e - Ton/To nPVC Tota l NO , - Ton/To nPVC NATIONA L EMISSION S INVENTOR Y POLYVINY L CHLORID E

A Viny l Acetet e Storag e ven t 1 4 Ave . Intermitten t No t Indlcete d 27- 8 70,00 0 70,00 0 0
B Reecto r endBlen dTen k Are e Emission s 28 1 Cont1nuous******* * Peg e 7 o f 8

(Assumed )

E Drye r Collecto r Effluen t 8 Continuou s E Drye r Collecto r Effluen t 1 0 Continuou s

0.000 9

Non e No t Semple d Non e No t Indlcete d Non e

Non e

0.000 9 0.017 6

Non e No t Semple d Non e No t Indlcete d

"1.68 1 Lbs./Hr . 1 6 0 "0. 6 Ft. " 21 2 Non e

0.017 6 0.000 5
Non e No t Semple d Non e No t Indlcete d

"125,88 3 Lbs./Hr . 1 2 0 2 4 10 4 Ye s

27-8.10 3 0.000 5 0.000 6
Non e No t Semple d Non a No t Indicate d

"132,01 0 Lbs./Hr. " 1 2 0 3 0 10 4 Ye s

27-8.10 2 0.000 6

Tots l SO , - Ton/To nPVC Tots l C O - Ton/To nPV C

********I f responden t 27- 8 Informatio nbecome s s contrubtlo nt o ln-dept hstudy ectlvitles , thi s stream shoul db e reviewed , er e determine db

y "engineerin g calculation s anddesig nflow sheet , plen t meterle l belence s confirm" . Th e figure s supplie di nth e ouestlonnelr e



## ' >
T l smmmtmmmsuCompan y Locatio n 

### EP A Cod e No . Cspsclt y - Ton s o f

Polyviny l Chloride/Yr . Averag e Productio n- Ton s o f PVC/Yr . Seesons l Rsng e i n Productio n - 7 . o f Max. Emission s t o Atmospher e Stres m - Lette ro nFlo wDlegre m Descriptio n
Flo w- Lbs./Hr . o f

Pollutant s Flo wCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Flo w Compositio n- Ton/To no f PV C Hydrocarbon s Particulate s C O Ssmpl e Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Aoelyal s Odo rPresen t Ven tStock s Flo w- SCF

M pe rstoc k Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temperatur e • ° F 

### Emissio n Contro l Devic e Typ e - Flar e Ba gFilter s Cyclon e Wate rScrubbe r Othe r Catalo gI . D . Numbe r Tote l Hydrocarbo nEmission s - Ton/To n PV C Tots l Particulat e - Ton/To n PV C Tote l NO , - Ton/To nPV C Tota l SO , - Ton/To nPV C Tote l C O - Ton/To nPV

C TABL EPV-II I NATIONA L EMISSION

S INVENTOR

Y POLYVINY

L CHLORID

E



## •

B D Reecto rViny l Chlorid e Are e Emission s Ven tCondense r 27- 8 70,00 0 70,00 0 0

4 1 Trec e Continuous******** * Continuous******** * Pag e 8 o f 8

(Assumed )
D Viny l Chlorid e Ven tCondense r Trec e Continuou s
0.002 6
Non e No tSemple d Non e No tIndlcete d "4,67 1 Lb s /Hr. " 1 6 0 4 

### 21 2 Non e Trec e
Non e No tSemple d Non e No tIndlcete d
"6 0 Lbs./Hr . Air " 1 5 0 1. 5 7 8 Ye s



### Comp . & Cond . 28-8.10 4 Trec e
Non e No tSemple d None No tIndlcete d
"32 5 Lb s /H rAir " 1 5 0 1. 5 7 8 Ye s



### Comp. & Cond . 28-8.10 1 •et-ye r Collec t

0.002 6 

### o rEffluen t
Continuous***'**** *

0.000 6 

### Non e No tSemple d Non e No tIndlcete d 265,00 9 Lb s /Hr . 1 6 0 4 8 

### 10 4 Ye s

28-8.10 5 0.000 6



### *********Emulslo nproces s emission .

T JP A Cod e No . apacit y - Ton s o f Styrene/Yr . jerag e Productio n - Ton s o f Styrene/Yr . -nisslon s t o Atmospher e Stres m I . D . Strea m TABLE ST-II I NATIONAL EMISSION S INVENTOR Y STYREN E 28- 1

250,00 0 250,00 0

Primar y Dlstilletlo n Hotwel l Ven t
Flow - Lbs./Hr . Flo w Cherscterlsti c - i f Intermitten t - Compositio n- Tons/To n Hydroge n Methan e Ethylen e Ethen e Cerbo nMonoxid e Cerbo nDioxid e Bensen e Toluen e Ethylbensen e Styren e No nArometlc s Sulfu r Dioxid e Hydroge nSulfid e Nitroge n NO , Wate r COnt l



### Hr s nuou s o r /Yr . o f o f Styren e Intermitten t

Flo w 8 2

Continuou s

.0000 3 .0000 5

.0006 4 .0004 0 .0000 3

.0000 8

.0000 8 Seconder y Distillatio n Hotwel l Ven t

Continuou s

.0000 2 Finishin g Dlstillstlo n Hotvei l Ven t
5. 5 Continuou s Psg e 1 o f 7

Hotwel l Collectio nVen t F,d ) Emergenc y Flar e Flu e Co s
> 0 Continuou s Confiden t le i (2 ) Furnec e Flu e (.a s Confident)a l

0000 8 .0000 1

.0000 8 Ven tStock s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tCo s Temp . - F ° SCFM/Stec k Kmlsslo n Contro l Device s Flare/Incinereto r Refrlgeretor/Condense r Absorber/Scrubbe r Othe r Analyst s Dat e o rFrequenc y o f Semplln g Sampl e Ta p Locatio n Typ e o f

Analysi s Odo rProble m Summar y o f

Ai rPollutsnt s llydrocsrbons , Ton/To n o f Styren e Particulates . Ton/To n o f Styren e NO x , Ton/To n o f

Styren e SO„ , Ton/Ton"o f

Styren e CO , Ton/To n o f

Styren e 1 1 6 2 13 5 15. 9

Ye s
Non e
Calc'd . N o 1 1 6 2 13 5 1. 6

Non e
Celc'd . N o 1 1 6 2 13 5 1. 6

Ye s

Non e
Calc'd . N o .0005 4 0 0 0 0 N o

Non e

Non e N o 1 27 5 2 4 Unknow n

Ye s 1 17 5 111 6 48 0

I I ) •(2 ) F i = flu e j;a s fro m flar e i n strea m F . Informatio n abou tthes e stream s wa s labele d confidential .

TJ

. cjr iEP

A Cod e No . Capacit y - Ton s o f Styrene/Yr . Averag e Productio n - Ton s o f Styrene/Yr . Emission s t o Atmospher e Strea m I . D . Strea m
Flo w- Lbs./Hr . Flo wCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . o f Flo w Compositio n - Ton/To no f Styren e Hydroge n Methan e Ethylen e Ethen e Carbo n Monoxid e Cerbo n Dioxid e Benzen e Toluen e Ethylbenzen e Styren e Non-Arometlc s Sulfu rDioxid e Hydroge n Sulfid e Nitroge n NO , wate r Oxyge n Ven tStack s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tCe s Temp . - F O SCFM/Stec k Emissio n Contro l Device s Flore/Ineinereto r Refrlgeretor/Condense r Absorber/Scrubbe r Othe r Analysi s Dat e o rFrequenc y o f Samplin g Sampl e To p Locatio n Typ e o f

Analysi s Odo rProble m Summer y o f

Ai rPollutsnt s Hydrocarbon s - Ton/To n o f Styren e Particulate s - Ton/To no f Styren e NOj , - Ton/To n o f

Styren e S0 X- Ton/To n o f

Styren e C O - Ton/To n o f

Styren e TABL E ST-I1 I NATIONA

L EMISSION S INVENTOR Y SYTREN E 

### 28- 2 650,00 0 650.00 0 Peg e 2 o f 7

A Primar y Disti 1 lotio n Ven t 95 0 Continuou s

.0003 4 .0018 9 .0004 2 .0003 7 .0001 2 .0000 9

+ .0013 1
.0015 4 .0000 3 No t Specifie d



### N o

Onc e No t Specifie d Chromstogrep h N o

( 1 ) Strippe rno tshow n i nflo wdiagram , i tpreceed s primar y distillatio n column .

iinnn n itii.nninr
. •.!»•> « B Seconder y Distillatio nVent 10 0 ContInuou s

.0001 0

.0004 9 .0000 5
No t Specifie d

N o

• > Non e

CsleuIste d N o .004 2 7 0 .0003 5 .0000 3 0 (1 )

Strippe r Ven t 40 0 Con t i nuou s

.0009 6 .0003 2

.0012 8
No t Specifie d

N o

Non e

Calculate d N o



## _

- D Furnac e lin e Ca p 472,00 0 Con t i nuouf >

. 1987 2

.0000 3 7 250 6 .0003 5 .4615 4 .1109 2 2 17 0 12 0 54 0 65,20 0 N o

6-9-7 2 I nStres m Unknow n N o

^•rUijjajgBB j T 3 atP A Cod e No . :apacity

- Ton s o f Styrene/Yr . \verav; e Productio n- Ton s o f Styrene/Yr . •'.mission

s t o Atmospher e Stream I . D . Stream

Flov - Lbs./Hr . Flo* 1 Characteristi c - Continuou s or Intermitten t i f Intermitten t - Hrs./Yr . Flov Compositio n- Tons/To no f Styren e Hydroge n Methan e Ethylen e Ethan e Carbo nMonoxid e Carbo nDioxid e Benzen e Toluen e Ethylenebenzen e Styren e Non-Aromstic s Sulfu r Dioxid e Hydroge nSulfid e Nitroge n NO , Wate r Particulat e Formaldehyd e Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Cs s Temp . - F ° SCFM/Stac k Emissio nContro l Device s Flsre/Inclnersto r Refr i gerstor/Condense r Absorber/Scrubbe r Othe r An a lysi s Dat e o r Frequenc y o t Samplin g Sampl e Ta pLocatio n Typ e o f Analysi s Odo r Problem Summar y

o f Ai r Pollutant s Hydrocarbon s - Tun/To no f Styren e Particulate s - Ton/To no f Styren e N0 X- Ton/To no f Styren e SO x- Ton/To no f Styren e C O - Ton/To nof Styren e (1 ) Responden t use dpubli c healt hservic e publicatio nNo . (2 ) Sample dunde r non-emergenc y condition s onlv . (3 ) Estimate db

y Houdry

base do

nrespondent s information . TABL E ST-U l NATIONA

L EMISSION S INVENTOR Y STYREN E 

### 28- 3 250,00 0 250,00 0

Primar y Distillatio n Hotwel l Ven t
> 0 Con ti noon s

1 3 0 2 12 0 > 0
Ye s

Non e
Calculate d N o

999-AP-42 . B C Secondar y Distillatio n Finishin g Colum n Hotwel l Ven tHotwel l Ven t .001 7 Cont i nuou s .002 9 Con ti nuou s

1 3 0 2 11 4 > 0
Ye s

Non e 1 3 0 2 11 4 > 0

Ye s
Non e Liqui d Samplin g N o Calculate d N o Pag e 3 o f 7

E Reecto r Emergenc y

Ven t Unknown Intermitten t . 0 2 F l Emergenc y Fue l Co s Fler e No tSpecifie d Intermi tten t No tSpecifie d

N o

N o

Ye s Doll y (2) I nStrea m Liq.-Ge s Chr c N o No t Specifie d

Ye s

Non e

.0002 0 .0000 9 .0009 8 0 0 Furenc e Fugitiv e Flu e Ce s Emission s 24,02 5 9. 6 < 3 1 Continuou s Intermitten t

870 0 

## < ) (00011 ) 

## ( )

.1441 6

.0000 8

.0009 8 .2390 4 .0000 9 .0000 1 1 12 5 111. 6 50 0 23,20 0 N o N o

Calc'd . fl ) Calculate d N o No

ay wway-'se , T-TT

V ''MWT T • ^•:P A Cod e No . 

### capacit y - Ton s o f

Styrene/Yr . Wereg e Productio n- Ton s o f Styrene/Yr . amission s t o Atmospher e Strea m I . D . Strea m
Flo w- Lbs./Hr . Flo wCharacteristi c- Continuou s o rintermitten t I f Intermitten t- Hrs./Yr . Flo w Compositio n- Ton/To nStyren e Hydroge n Methan e Ethylen e Ethan e Carbo n Monoxid e 

### Carbo nDioxid e Benzen e Toluen e Ethy l Benzen e Styren e Non-Aromstlc s Sulfu rDioxid e Hydroge nSulfid e Nitroge n NO , Wate r Particulat e VentStack s Numbe r Heigh t- Ft . Diamete r - Inche s Exi t Ga s Temp . - F ° SCFM/Stec k Emissio nContro l Device s Flare/Incinerato r Refrigerator/Condense r A bsorb e r/ S crubbe r Othe r An s lysi s Dst e o r Frequenc y

o f Semplln g Sampl e Ta pLocatio n Typ e o f Anelysi s OdorProble m Summar y o f Ai rPollutant s Hydrocarbon s - Ton/To no f Styren e Particulate s - Ton/To n o f Styren e NO , - Ton/To n o f

Styren e S 0 X

### - Ton/To no f Styren e C O - Ton/To no f Styren e (1 ) 21.36 2 lhs./yr . <? ) Sample dunde r norma l operatin g conditions . tl" ) Fro m

I Uscrubher , whic hi s befor e distillatio nsyste m (no t show no nflo w diagram) . \ - . t Flo w i s variabl e dependin g o nH 2 custome r need s (averag e flow rat e given) . 1 >) Furnace s bur nbot hfue l ga s an d1ioni dvastes . TABL E ST-II I NATIONA

L EMISSION S INVENTOR Y STYREN E 28- 5 346,75 0 346,75 0 F . Reacto r Emergenc y Ven t 

## ( D Intermitten t No tSpecifie d .00000 4 + H 2 Scrubbe r Ven tO ) 1,39 9 Continuou s Pag e 4 o f 7

.00000 9 .00000 2 .00000 7 .00000 4

.000007 4

4 7 5 2 0 5 0 38 0 N o

Ye s (2 ) Infrequently Compresso

r Lin e Chromstograp

h N o D Furaece Flu e es s ( 

### ^"> (6 ) Cont1nuous Storage LOFSC F t o 

### Flar e - product ? (8 ) Con t inuou F

(6 )

17 ) (8 ) (9 ) (10 ) .0037 8 (7 ) (9 )

.0139 0

1 3 0 3 10 0 42 9

Ye s Non e (7 )

2 7 6 7 3 6 50 0 135 0 N o (9 )
Non e

N o Ye s

Ye s Continuou s Chrometogrep

h N o (11 ) .0000 2 0 Negliglel e 0 0 Fue l consumptio nI s confidentia l no t enoug hinformetio ngive nt o calculat e ouantit y o f combustio nproducts , 07 . sulfu r fue l used , therefore , complet e combustio nt o C0 ? 

### and N2 O assumed . Relativ e amount s o f C0 2 

### an dH2 O depend s onfue l reoulrements . Variabl e dependin g onrat e o f tan kfillin g Complet e combustio nt o N2 O en dCO 2 assumed . Continuou s samplin g for styren e vapor ; (10 ) Continuou s ssmplinj i tor styren e vapors . (11 ) Couldpresen t ey e irritatio nproble m I f styren e I s no t monitore dcarefully .EP

A Cod e No . Capacit y- Ton s o fStyrene/Yr

. Averag e Productio n - Ton s o f Styrene/Yr . Emission s t o Atmospher e Strea m I . D . Strea m

Flo w- Lbs./Hr . Flo wCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Flo w Compositio n- Tons/To no f Styren e Hydroge n Methan e Ethylen e Ethan e Carbo n Monoxid e Carbo n Dioxid e Benzen e Toluen e Ethy l Benzen e Styren e Non-Aromatlc s Sulfu rDioxid e Hydroge nSulfid e Nitroge n NO , Vste r Ven tStack s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tCs s Temp . - F ° SCFM/Stsc k Emissio n Contro l Device s Flare/Incinerato r Refrigerator/Condense r A b sorber/Scrubbe r Othe r Analysi s Dat e o rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f Analysi s Odo rProble m Summar y o f

Ai rPollutant s Hydrocarbon s - Ton/To n o f Styren e Particulate s - Ton/To n o f Styren e N0 X- Ton/To no f

Styren e S0 X- Ton/To n o f

Styren e C O - Ton/To n o f

Styren e TABL E ST-11 1 NATIONAL EMISSIO N INVENTOR Y STYREN E 28- 6 265,00 0 265,00 0

Incineratio nProducts , Unrecovere dFue l Cs s Flsr e 85 5 (») Continuou s

.0094 3

.0033 9 (2) 1 17 5 1 6 Unknow n 63 6 (3)
Ye s Ye s

Non e

Calculate d Non e Pag e 5 o f 7

D Furnac e Flu e Ga s 19,77 9 Continuou s Tan k Losse s 44. 6 Continuou s

,1351 0

0006 7

.0000 2 .1615 0 No t Specifie d



### N o Non e

Non e

Non e Estimat e Non e .0006 7 0

. 0000 2 0 0 ( 1 ) Base d o n tota l conversio no f unrecovere d fue l ga s t o CO - an d I^O . (2 ) Flar e i s use d fo rincineratio no f vapor s fro m othe rprocesse s elso . ( 3 ) Tota l fro m al l processes . (4 ) Complet e combustio nt o C(> 2 an d H2O . NO xconcentratio n i s approximatel y 3 0 PPM .

lonnmi anainoinn.ati n i 4 1 0 T JEPA

Cod e No . Capacit y

- Ton s o f Styrene/Yr . Averag e Productio n- Ton s o f Stvrene/Yr . Emission s t o Atmospher e Strea m ID . Strea m

Flow - Lbs./Hr . Flow Characteristi c - Continuou s or i f Intermitten t - Hrs./Yr . Flo v Compositio n- Ton/To no f Styren e Hydroge n Methan e Ethylen e Ethan e Csrbo nMonoxid e Csrbo nDioxid e Benaen e Toluen e Ethy l Benzen e Styren e Non-Arotna t lc s Sulfu r Dioxid e Hydroge nSulfid e Nitroge n N0 X Wate r Ven t Stack s Numbe T Heigh t - Ft . Diamete r - Inche s Exi t Ga s Temp . - F ° SCFM/Stsc k Emissio nContro l Device s Flsre/Inclnereto r Refrigerator/Condense r Absorber/Scrubbe r Othe r Analysi s Dat e or Frequenc y o f Samplin g Sampl e Ta pLocatio n Typ e o f Analysi s Odo r Proble m Summer y

o f Ai r Pollutant s Hydrocarbon s - Ton/To no f Styren e Particulate s - Ton/To no f Styren e N0 X- Ton/To no f Styren e S0 X- Ton/To no f Styren e C O - Ton/To no f Styren e TABL E ST-II I NATIONA L EMISSION S INVENTOR Y

STYREN E 28- 7 100,00 0 100.00 0

[nterm i tten t D i s tillatio n Hotwel l Ven t
> 0 Cont1nuou s

1 3 0 6 10 0

Ye s
Non e Peg e 6 o f 7

Atmospheri cDistillatio n Breethe rVent s
> 0 Cont1nuou s

2 40 , 6 0 3 , ? 100 , 10 0 N o

N o Fugitiv e Emissions ; A.P. I Sum p Sectio n
Continuou s

"00002 '

N o

N o

Non e D Furnac e Flu e Ga s 10.65 6 Con t inuou s



### 1897 4

.0000 7 .7370 0
No t Specifie d

N o Non a

N O .0000 7 .0000 ? 0 0 0

•""'••ajBmmmxemmxJImjmj PTABL EST-U I NATIONA

LEMISSION S INVENTOR Y

EP A Cod e No . Capacit y

- Ton s o f Styrene/Yr . Averag e Productio n- Ton s o f Stvrrne/Yr . Emission s t o Atmospher e Stream I . D . Stream

Flo w - Lbs./Hr . Flo w Chsrscteristi c - Continuou s o r Intermitten t i f Intermitten t - Hrs./Yr . Flow Compositio n- Tons/To no f Styren e Hydroge n Methan e Ethylen e Ethan e Carbo nMonoxid e Cerbo nDioxid e Benzen e Toluen e Ethylbenzen e Styren e Non-Aromatic s Sulfu rDioxid e Hydroge nSulfid e Nitroge n NO , Wete r Ven t Stack s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Ge s Temp . - FO SCFM/Stac k Emissio nContro l Device s Flare/Incinerato r Refrlgeretor/Condense r Absorber/Scrubbe r Othe r Analys i s Dat e o r Frequenc y

o f Samplin g Sampl e Ta pLocatio n Typ e o f Analysi s Odo r Problem Summar y o f Ai r Pollutant s Hydrocarbon s - Ton/To no f Styren e Particulate s - Ton/To no f Styren e N0 X- Ton/To no f Styren e SO x- Ton/To no f Styren e C O - Ton/To no f Styren e A , B & C Distillatio nVacuu m le t Exhaus t 300 0 Con t inuou s

+
+ + +

.0801 3 1 137. 6 9 6 69 0 60,00 0



### Ye e

Non e STYREN E 28- 8 155,00 0 155,00 0
E

Emergenc y

Fue l Ga s Ven t 6,80 0 Intermitten t 2 5

+ +

.0000 2 .0003 0 .0000 4 .0001 3 .0000 4

No t Specifie d

N o

Approximatel y

2 No t Specifie d Chromstogrsp h& Ye s time
Mas s s/yea r Spectromete r

.0005 4 0 .0000 2 0 0 Pag e 7 o f 7

D Furnac e Flu e (a s 11.55 5 fl) Con t i nuou s

.1064 4

0000 2 .2071 1 1 9 6 5 4 8 83 5 30,00 0

Non e Storsg e Losse s 1,33 0 Con t inuou s

j.00094 j

.0000 3



### N o

Non e

### TABL E SB-U I NATIONA L EMTSSToH S INVENTOR Y STYREN E BUTADIEN E RUBBE R

VI A EMUL S IO N POLYME

RI ZA T I O N Pag e 1 o f 8 Plan t EP A Cod e No . Capacity , Ton s o fSBR/Yr
. Rang e i n Productio n - 7 o fMax . 

### 29- 1 219.00 0 5. 7 [-.mission

s 1 0 mmospner e Strea m
Flo v - Lbs./Hr . Flo v Characteristic , Continuou s o r Intermitten t I f Intermittent . Hrs./Yr . - Flo w Composition . Tons/To no f SB R Styren e Butedien e Ammoni a Wate r Tel e Cerbo nBloc k Buten e Hexan e Methen e Oxyge n Nitroge n 

### SB R N0 

## » SO , Misc . H C 

### C O CO j ven t Stack s Numbe r Heigh t - Ft . (ebove grede ) Dlemete r - Inche s Exi t Ga s Temp . - F ° SCFM/Stac k Emissio nContro l Device s A bsorber/ S c rubbe r Cyclone s Be g File r Fler e Anslysl s Dst e o r Frequenc y o f Samplin g Sampl e To plocatio n Typ e o f Analysi s Odo r Proble m Summer y

o f Ai r Pollutant s Hydrocarbons , Ton/To no f SB R Particulates . Ton/To nol " SB R N0 X 

### , Ton/To no f SB R SO, , Ton/To no f SB R C O . Ton/To no f SBR Reacto r - Trai n"A " Fugitiv e Emission s 

### 1 7 Continuou s

.0000 2 .0001 7 .0001 5



### N o

N o

Non e

Celc'd . 

### N o



## , Trel n"A " Recover y Are a Fugitiv e Emission s 

### 9 Continuou s

< C 0000 1 .0001 7



### N o

N o



## •

Non e

Celc'd . 

### N o

SE E CONTINUATIO N Butsdlen e - "A " Absorbe r Ven t 

### 1 Continuou s

. 0000 1

No t give n

Yes . SB- l 

## +

Bl-dsll y Absorbe r 

### CL C N o Trel n"A " Drye r 4.26 0 Continuou s

.0005 8

.0846 1



### Ye s 

### 8 (44 ) 4 < ? 30 , 4 ( ? 3 6 

### 17 0 /W100 0 

### N o

Non e Neve r Non e Estimat e 

### N o

T J h o 

### p oTABLE SB-II I NATIONA

L EMISSION S INVENTOR Y STYREN E BUTADIENE RUBBE R VIA EMULSIO

N POLYMERIZATION Peg e 2 o f 8 Plan tEP

A Cod e No . Capacity , Ton s o f SBR/Yr . Rang e I n Productio n - 7 . o f Max . Emission s t o Atmospher e Strea m

Flo w- Lbs./Hr . Flo wCharacteristic , Continuou s O T Intermitten t i f Intermittent , Hrs./Yr . - Flo w Composition , Tons/To no f SB R Styren e Butedien e Amroonl e Vote r Tel e Carbo nBlac k Buten e Hexan e Methen e Oxyge n Nitroge n SB R NO x S 0 x Misc . H

C C O CO 2 Ven tStack s Numbe r Heigh t - F t Dlsmete r - Exi t Ge s Temp . SCFM/Stec k Emissio nContro l Device s Absorber/ S crubbe r Cyclone s Be g Filte r Fler e 29- 1 219,00 0 5. 7 Trsl n"A " Tsl c Dus t 12.000/Yr . Intermitten t No t specifie d

.0000 3 Reecto rTrei n B Fugitiv e Emission s 1 7 Continuou s

.0000 2 .0001 7 .0001 5 Trei n"B " Recover y Are a Fugitiv e Emission s

Continuou s Butsdlen e "B " Absorbe rVen t

Continuou s

(ebov e grade ) Inche s 

## F ° Yes , SB- 2 N o

N o ^.0000 1 .0001 7 .0000 1

N o

N o No tgive n

Yes , SB- 3 

## +

Analysi s Dat e o rFrequenc y o f Samplin g Sempl e Ta p Locatio n Typ e o f Analysi s Odo rProble m ar y o f Ai rPollutant s Hydrocarbons . Ton/To no f SB R Particulates , Ton/To no f SBR NO x , Ton/To no f SRR SO x . Ton/To no f SB R C O , To n/Tono f SH K Non e Neve r Non e Estlmet e N o Cslc'd . N o Non e

Cslc'd . No Bl-dsll y Absorbe r CL C N o

SE E CONTINUATIO N



### — ' -TasT 'TAB U SB-Il l NATIONAL EMISSION S INVENTOR Y STYREN E BUTADIENE RUBBE R VI A EMULSION POLYMERIZATIO N Psg e 3 o f 8 Plan tEP

A Cod e No . Capacity , Ton s o f SBR/Yr . Rang e I n Productio n - "I. o f Max . Emission s t o Atmospher e Strea m

Flo w - Lbs./Hr . Flo w Characteristic . Continuou s o r Intermitten t I f Intermitten t Hrs./Yr . - Flo w Composition . Tons/To no f SB R Styren e Butedlen e Ammoni e Wate r Tel e Cerbo nBlac k Buten e Hexen e Methan e Oxyge n Nitroge n SB R NO , S O x Misc . H C C O CO j Ven t Stack s Numbe r Heigh t - Diamete r Exi t Ga s Temp SCFM/Stec k Emissio nContro l Device s Absorber/Scrubbe r Cyclone s BS g Filte r Fler e Ft . (abov e grade )

- Inche s 

## F ° Trsi nB Drye r 4,26 0 Continuou s

.0005 8 Csrbo nBloc k e xBe g Filte r 2 Continuou s 29- 1 219,00 0 5. 7 Cerbo nBlac k e xScrubbe r 1 Continuou s

.0846 1 .0000 4 .0000 1



### Ye s 8 (44 ) 4 0 30 , 

### 17 0 ~<100 0 

### N o 4 O 3 6 No t spee l

Yes , SB- 4 No t specifie d

Yes , SB- 5 Cerbo n Bloc kSectio n Fugitiv e Emission s

Continuou s Tsn kFar m Fugitiv e Emission s 1 1 Continuou s

.0000 4 .0001 7 Compresso rHous e Fugitiv e Emission s 2 3 Continuou s

.000 4 6

.0000 3

N o

N o N o

N o

Anslysi s Dat e o rFrequenc y o f Semplln g Sampl e Ta p Locatio n Typ e o f

Analysi s Odo rProble m Summar y o f

Ai rPollutant s Hydrocarbons , Ton/To n o f SBK Psrticulates . Ton/To n o f SB R N0 X , Ton/To n o f

SB R SO x , Ton/To n o f

SB R C O , Ton/To n o f

SB K Non e Neve r Non e Estimat e N o Non e

Estimat e N o Non e

Estimat e N o Non e

Estimat e N o .0021 3 .0008 7 0 0 0 Estimat e N o Estimat e N o



## swaiKuv^aWtfWM N »ua,\Kv» ^ •AA»WW>C J \to«.r \ 

## •fr oTABLE SB-Il l NATIONA

L EMISSION S INVENTOR Y STYREN E BUTADIENE RUBBE R VIA EMULSIO

N POLYMERIZATION Peg e 4 o f 8 Plan tEP

A Cod e No . Capacity , Ton s o f SBR/Yr . Rsng e i n Productio n- 7 . o f Max . Emission s t o Atmospher e Strea m Butedlen e Absorbe r Ven t 29- 2 112,00 0 0 Conveyo r Drie r Ven t Extrude r Drie r Ven t
Flo w - Lbs./Hr . Flo w Cherecterl6tic , Continuou s o r Intermitten t i f Intermittent , Hrs./Yr . - Flo w Composition , Tons/To no f SB R Styren e Butedlen e Ammoni a Wate r Tal c Carbo nBlac k Buten e Hexen e Methan e Oxyge n Nitroge n SB R NO , SO , Misc . H C C O CO j Ven t Steck s Numbe r Heigh t - Dlemete r Exi t Ga s Temp . SCFM/Stec k Emissio nContro l Device s Absorber/Scrubbe r Cyclone s Bs g Filte r Fler e Ft . (ebov e grade )

- Inche s 

### F ° 6 2 Continuou s

.0001 7

.0000 6 .0000 2 .0004 3 .0014 0

Ye s 1 (40 ) 1 7 0 1 3 Yes , SB- 6 135,74 4 Continuou s

.0569 2

1.0371 4 3.4307 7 .0000 2

Ye s 6 (40 ) 3 0 - 3 6 17 0 ^5,00 0 N o 90.85 0 Continuou s

0189 7

.7015 4 2 3078 4 .0000 2

Ye s 2 (30 ) 2 4 22 0 10,00 0 Non e

Anelysl s Dst e o r Frequenc y o f Samplin g Sampl e Te pLocatio n Typ e o f Anelysl s Odo r Proble m Summer y

o f Ai r Pollutant s Hydrocarbons , Ton/To no f SBR Particulates , Ton/To no f SB R NO x . Ton/To no f SHR SO x , Ton/To no f SB R C O . Ton/To no f SB R Ye s No t specifie d Absorbe r Overhea d GL C N o Non e Non e Calc'd . N o .0002 3 .0000 4 Non e Non e Calc'd . N o



## W»\nlB3 * « > »WW M

\MJf l I NTABL E SB-U I

Plan tEP

A Cod e No . Capacity , Ton s o f SBR/Yr . Rang e i n Productio n - 7. o f Max . Emission s t o Atmospher e Street s

Flow - Lbs./Hr . Flow Characteristic . Continuou s o r Intermitten t I f Intermittent , Hrs./Yr . - Flo w Composition , Tons/To nSB R Styren e Butedlen e Ammoni a Wate r Tel e Cerbo nBloc k Buten e Hexen e Methan e Oxyge n Nitroge n SB R N 0 X S0

_ NATIONAL EMISSION S INVENTOR Y STYREN E BUTADIEN

E RUBBE

R VI A EMULSIO

N POLYMERIZATIO

N

Carbo nBlac kEmissio n Sectio n Ven t(I ) "C " (I ) 71 5 No tspecifie d Continuou s Continuou s 29- 3 175,00 0 0 Emlsslo n "D " (I ) No tspecifie d Continuou s Peg e 5 o f 8

Emissio n "E " (I ) No tspecifie d Continuou s

.0177 9 .0001 0

. x Misc . 

### HC C O CO j Ven t Stack s Numbe r Heigh t - Ft . (ebov e grede ) Dlemete r - Inche s Exi t Ce s Temp . - F ° SCFM/Stec k Emissio nContro l Device s Absorber/Scrubbe r Cyclone s Be g Filte r Fler e 1 4 0 6 16 5 30 0 Yes , SB- 7 + + + +
Ye s 1 3 0 2 0 47 0 34 5 N o .0298 8 .0000 1

.0000 8

Ye s I 4 0 3 4 14 7 8,89 0 N o .0707 6
J? . 0000 1

.0000 8

Ye s 1 41. 5 3 4 15 4 11.70 0 N o Emissio n "F " (I )
No t specifie d Continuou s

.0576 3 :.0000 1

.0000 6

Ye s 1 41. 8 3 4 15 2 10.80 0 No

Analysi s Dat e o r Frequenc y o f Samplin g Sampl e Te pLocatio n Typ e o f Anelysl s Odo r proble m Summer y

o f Ai r Pollutant s Hydrocarbons . Ton/To no f SB R Particulates . Ton/To no f SB R N0 X , Ton/To no f SB R S0 X , Ton/To no f SBR C O , Ton/To no f SB R Onc e Stoc k Estimat e N o Non e

Calc'd . N o Onc e Celc'd . N o

SE E CONTINUATIO N Onc e Calc'd . N o Onc e Calc'd . N o

nnail>a->v i p»

n siRiati M \KuiA .TABLE SB-II I NATIONAL EMISSION S INVENTOR Y STYREN E BUTADIENE RUBBE R VI A EMULSIO

N POLYMERIZATION Pag e 6 o f 8
Plan tEP

A Cod e No . Capacity , Ton s o f SBR/Yr . Rang e i n Productio n - X o f Max . Emission s t o Atmospher e Strea m


### Flo w - Lbs./Hr . Flo w Characteristic , Continuou s o r Intermittent i f Intermittent . Hrs./Yr . - Flo w Composition , Tons/To nSB R Styrene Butedlen

e Ammoni a Wate r Tel e CerbonBlock Butene Hexene Methene Oxygen Nitrogen SB R 

## N° x SO , Misc . H C C O CO j Ven t Stack s Number Heigh t - F t (abov

e grade ) Diameter - Inche s Exi t Ga s Temp . - F ° SCFM/Stec k Emissio nContro l Device s A bsorber/ S crubbe

r Cyclone s Ba g Filte r Flare Analysi s Dat e o rFrequenc y o f Samplin g Sampl e To p Locatio n Typ e o f Analysi s OdorProble m sr y o f Ai rPollutsnt s Hydrocarbons . Ton/To n o f SR R Particulates . Ton/To n o f SB R NO, . Ton/To n o f

SB R S0 X

### To n/To nof SB R CO ' , Ton/To

no f SB R Emissio n "C " (I ) Not specifie

d Continuou s Emissio n "H " (I ) Not specifie

d Continuou s 29- 3 175,00 0 0 Emissio n "I " (I ) No t specifie

d Continuou s Emissio n "J " (1 ) No t specifie

d Continuou s Emissio n "K " (I ) No t specifie

d Continuou s

.0603 0
< . 0000 1

.0000 6

Ye s 1 4 0 3 4 15 5 11,30 0 N o

Once Cslc'd . N o .0348 6

< \ 0000 1

.0001 8

Ye s 1 41 6 3 4 15 4 . 14,00 0 N o

Onc e Celc'd . N o .0378 5

.0000 1

.0001 8

Ye s 1 40. 8 3 4 15 4 14,00 0 N o

Once Celc'd . N o

SEE CONTINUATIO

N .0381 2

<,0000 l

.0001 5

Ye e 1 40. 8 3 4 15 3 14,10 0 N o

Once Celc'd . N o .0376 0

<.0000 1

.0001 5

Ye s 1 40. 3 3 4 14 5 15.10 0 N o

Onc e Celc'd . N o



## aua\K\a3> < W AWW M \"*i\r

\ Ta¥mmmaf|N> 

## -mm-mJTABL E SB-11 1 NATIONA

L EMISSION S INVENTOR Y STYREN E BUTADIENE RUBBE R VIA EMULSIO

N POLYMERIZATION Psg e 7 o f 8 Plan tEP

A Cod e No . Capacity , Ton s o f SBR/Yr . Rang e I n Productio n - 7 o f Max . Emission s t o Atmospher e Strea m


### Flo w - Lbs./Hr . Flo w Characteristic , Continuou s o r Intermittent If Intermittent , Hrs./Yr . - Flo w Composition , Tons/To nSB R Styren e Butadien

e Ammoni a Water Tsl c Csrbo nBlack Ruten e Hexan e Methan e Oxyge n Nitroge n SB R NO , SO , Misc . H C CO 

## co 2 

### Ven t Stock s Numbe r Heigh t Ft . (ebov

e grade ) Diameter - Inche s Exi t Ge s Temp . - F ° SCFM/Steck Emissio nContro l Device s Absorber/Scrubbe r Cyclone s Beg Filter Flare Emissio n "L " (I ) No t Specifie

d Continuou s

.0209 4

.0000 1

.0001 0

Ye s 1 45. 3 2 4 16 5 10,90 0 N o 29- 3 175,00 0 0 Emissio n "M " (I ) Not Specifie

d Continuou s

.0344 2

.0000 9

.0000 7

Ye s I 45. 5 1 8 10 2 6,72 0 N o Emissio n "N " (I ) Not Specified Continuou s Flar e Flu e Ga s No t Specifie

d Cont i nuou s

.0000 1

Ye s I 3 0 6 9 0 80 0 N o Ye s 1 15 0 1 8 28 0 50 0 Ye s SB- 8

Analysi s Dst e o r Frequenc

y of Samplin

g Sampl e Ta

pLocatio

n Typ e o f Anelysl s Odo r Proble

m Summar y o f Ai r Pollutant s Hydrocarbons . Ton/To nof SB R Psrticulstes , Ton/To no f SB R N0 X 

### , Ton/To

nof SB R SO x 

### , Ton/To

nof SB R C O , Ton/To

no f SB R Onc e Celc'd . N o Thric e Neve r Celc'd . N o .0011 1

.0002 9 + + + Celc' d

N o Cslc'd . N o



## aua\Kw> j «A«W» M 

## \toj»r

\ 

# I B
w—y »TABLE SB-Il l NATIONAL EMISS10NS~~JNVENTOR Y STYRENE BUTADIENE RUBBE R VI A EMULSION POLYMERIZATIO N

»n tEP A Cod e No . • paclty . Ton s o f

SBR/Y r ing e I n Productio n- 7. o f Max . nisslon s t o Atmospher e Strea m


### Flo w - Lbs./Hr . Flo w Characteristic , Continuou s o r Intermitten s I f Intermittent , Hrs./Yr. - Flo w Composition , Tons/To nSB R Styren e Butedlen

e Ammoni a Wate r Tal c Carbo nBlack Buten e Hexan e Methan e Oxygen Nitroge n SB R NO , SO , Misc . H C CO CO j Ven t Stock s Numbe r Heigh t Dlemeter Exi t Co s Temp . SCFM/Steck Emissio nContro l Device s Absorber/Scrubber Cyclone s Be g Filte r Flare 29- 4 342,00 0 0

Ft . (ebov

e grsde ) Inche s

. F 

### o

Analysi s Dat e o rFrequenc y o f Semplln g Sampl e Te p Locatio n Typ e o f

Analyst s Odo rProble m Summar y o f

Ai rPollutant s Hydrocarbons , Ton/To no f SB R Partlculstes , Ton/To n o f SB R NO x . Ton/To n o f

SBR 

### SO, , Ton/To

no f SB R CO , Ton/To

no f SH R Butadien e Absorber Ven

t vl O Continuous

.0000 2 Carbo nBlac k Sectio nVen t ~60 0 Continuou s

+ .0000 1

Ye s 1 1 0 I 10 0 2 Yes , SB- 9 +

Ye s Weekly Absorber C.L C N o 

## 1

Horlz . Dlsch . 4 10 0 13 9 Yes . SB-1 0 +

Ye s Onc e Cralmetri c N o Boiler

Flu e Ga s
Continuou s

.0002 6

Ye s 6 4 1 t o 18 9 3 0 to 10 8

N o

N o Neve r Peg e 8 o f 8

Drye r Exhaus t 

## (I D No t specifie

d Continuou s

.0060 0



## +

+ Ye s 4 7 (34 ) evg . (30 ) ev g 15 0 N o

N o Never Not specifie

dCalc'd . N o N

o 29- 5 109,00 0 0 29- 6 3b0.00 0 0 Butadien

e Absorbe r Ven

t 1 3 Continuou s

.0000 7

.0003 9 .0001 1

.0060 2 .0000 1 0 .0002 6 0 Ye s I 2 8 5 0 2 . 6 Yes . SB-1 1 (III )

Ye s Dell y C.LC N o .0000 9

<.. 0000 1 .0003 0 .0000 3 Wast e Solid s

Incinerato rFlu e Ga s No tspecifie d Intermitten t

<.0000 1 (perttc. )

.0003 0 .0000 2 .00O0 3 Ye s 1 3

N o n o k* > 

## <

N o

T.A.C.B . Est . N o Ye s + SB-1 2 

# 3 SB-1 3 + SB-1 4

Cs nno t b e determine d



## »ua\K\M ^ «.»»W M \ Ku

## \ NTABLE VI-II I NATIONA

L EMISSION S INVENTOR Y VINY L ACETAT E VI A ACETYLEN

E - ACETI C ACI D Pag e 1 o f 4 Plen tEP

A Cod e No . Capacit y - Ton s o f Viny l Acetete/Yr . Productio n- Ton s o f Viny l Acetete/Yr . Reng e I n Productio n- 7. o f Max . Emission s t o Atmospher e Stree m Flo w - Lbs./Hr . Flo w Characteristic , Continuou s o r Intermitten t i f Intermitten t - Hrs./Yr . Flo w Compositio n- Tons/To nViny l Acetet e Acetylen e Aceton e Aceteldehyd e Aceti c Aci d Viny l Acetat e Nitroge n CO 2 H- 0 N0

_ 30- 2 75,00 0 75.00 0 0

Absorbe r Ven t 60 0 Continuou s

.0268 0 .0030 0 .0012 6 .0019 0

Ven t Stock s Numbe r Heigh t - Ft . Diamete r - Inche s Exi t Co s Temp . - F ° Emissio nContro l Device s Flere/Inclnereto r Anelysl s Dat e o r Frequenc y o f Samplin g Sampl e Ta pLocatio n Typ e o f Anelysl s Odo r Problem Summer y

o f Ai r Pollutsnt s Hydrocarbons , Ton/To nViny l Acetat e Particulates , Ton/To nViny l Acetet e NO , Ton/To nViny l Acetet e C O Ton/To nViny l Acetet e 3 8 0 1 9 0
N o April , 197 2 No t Specifie d Cs s Chromatograp h N o Incineratio no f Liqui dVast e 1,24 0 Continuou s 

### (7 )

.0467 2 .0185 3

1 1 0 9 6 340 0
Ye s N o

.0299 6 0 0 0

T J I c o

# 1

TABL E Vl-I U NATIONA

L EMtSSION S INVENTOR Y VINYL ACETAT

E VI A ACETYLEN

E - ACETI C ACI D Pag e 2 o f 4 Plan t EP A Cod e No . Capacit y- Ton s o f Viny l Acetate/Yr
. Productio n - Ton s o f Viny l Acetate/Yr
. Rang e i n Productio n - "I. o f Max . Emission s t o Atmospher e Strea m

Flov - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten t i f Intermittent . Hrs./Yr . Flo v Compositio n- Ton/To nViny l Acetet e Acetylen e Aceton e Acetsldehyd e Aceti c Aci d Viny l Acetat e Nitroge n C0 2 H 2 0 Methy l Acetylen e Propylen e Propan e Methan e Ethan e Ethylen e Ven t Stack s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tCa s Temp . - F " Emissio n Contro l Device s Flare/1nclnerato r Absorbe r Analysi s Dat e o r Frequenc yo f Samplin g Sampl e Ta p Locatio n Typ e o f Analysi s Odo rProble m Summar y o f

Ai rPollutant s Hydrocarbons , Ton/To n Viny l Acetat e Particulates , Ton/To n Viny l Acetat e N 0 X . Ton/To n Viny l Acetat e C O , Ton/To n Viny l Acetat e Converte r Purg e Ca s 69 4 Intermitten t 6 0

.0001 0 0000 9

Calculate d Ye s O Reacto r Emergenc yVen t 147 0 Interm i tten t No t Specifie d 3 0

U , U , 0 - 3 75 0 25 0

Heav yEnd s

Colum n Ven t 6. 3 Con t i nuou s



### + + + + + + Ye s 3 5 0 3 11 0 N o

Once/Wee k Mas s Spectromete r Ye s ' O 0007 1 .0000 7

.0022 7

Non e Liqui d Samplin g Ye s '» ) '« ! Ligh t End s Colum n Ven t 71 4 1 Con t i nuou s

0010 ? 001P 5 .0078 5

.0017 8

N o

3 time s ayea r Recover y colum n fee d streai r Chromstogrsp h Ye s ' U

Se e Continuatio n

.ni«tti- i PI S amasx t \AUI/\ IT J 

### fluTABL E VI-II I NATIONA

L EMISSION S INVENTOR Y VINYL ACETAT

E VIA ACETYLEN

E - ACETI C ACID Pag e 3 o f 4 Plan tEP

A Cod e No . Capacit y - Ton s o f Viny l Acetate/Yr . Productio n- Ton s o f Viny l Acetate/Yr . Rang e i n Productio n - 7 o f Max . Emission s t o Atmospher e Strea m

Flo w - Lbs./Hr . Flo w Characteristi c - Continuou s o r Intermitten t I f Intermittent , Hrs./Yr . Flow Compositio n- Ton/To nViny l Acetat e Acetylen e Aceton e Acetaldehyd e Aceti c Aci d Viny l Acetat e Nitroge n CO , H 2 0 Methy l Acetylen e Pro p len e Propan e Methan e Ethen e Ethylen e Ven tStack s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tGa s Temp . - F » Emissio n Contro l Device s Flare/Incinerato r Absorbe r Analysi s Dat e o rFrequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o fAnalysi s Odo rProble m Summar y o f

Ai rPollutant s Hydrocsrbons , Ton/To n Viny l Acetat e Particulates , Ton/To nViny l Acetat e NO„ , Ton/To nViny l Acetat e C O , Ton/To n Viny l Acetat e Crud e Viny l Acetat e Storag e Tan kVent s 192. 3 Continuou s

.0004 7 .0028 4 30- 3 11,25 0 11,25 0 0

Refine d Viny l Acetat e Storag e Tan kVent s 35. 7 (5 1 Continuou s Aceti cAci d Storag e Tsn k"ent t 16. 9 '6 1 Continuou s

.0000 7 .0020 8 .003 7

N o

N o N o

Upo n Reques t Liqui d Sampl e Chromatograp h Ye s (1 ) Non e

Estimate d Ye s (1) Non e

Estimate d Ye s (1 ) .0136 6 0 0 0 Incinerstio no f l.inui dWast e Not Poeclfle d(3 ) Interm i tten t No t Specifie d

.0408 1 0180 0

Ye s Ope nsi r burnin g Non e
Estimate d No



## auainOA B W A amao\ / \^\hTABLE VI-lI I NATIONA

L EMISSION S INVENTOR Y V1NY1 . ACETAT E VI A ACETYLEN E - ACETI C ACI D Pag e 4 o f 4 Plant EP

A Cod e No . Capacit y

- Ton s o f Viny l Acetate/Yr . Productio n- Ton s o f Vinv l Acetate/Yr . Rang e I

nProductio n- 7 . o f Max . Emission s t o Atmospher e Strea m 30- 4 78,00 0 28,00 0 0

Flo v - Lbs./Hr . Flo v Characteristic , Continuou s o r Intermitten t i f Intermittent , Hrs./Yr . Flov Compositio n- Ton/To nViny l Acetat e Methan e Acetylen e Ethylen e Aceton e Acetaldehyd e Aceti c Aci d Viny l Acetat e l l 2 0 CO 2 N0 X Particulat e Ven t Stack s Numbe r Heigh t - Ft . Diamete r- Inche s Exi t Ga s Tem p - F " Emissio n Contro l Device s Flare/Incinerato r Analysi s Dst e o rFrequenc y o fSamplin g Sampl e Ta p Locatio n Typ e o fAnalysi s Odo rProble m Summar y o fAi rPollutant s Hydrocarbons , Ton/To n Viny l Acetat e Particulates , Ton/To n Viny l Acetat e N O x , Ton/To n Viny l Acetat e C O , Ton/To n Vinv l Acetat e Reacto rEmergenc yVen t 79 0 Intermitten t 3 0 .0000 4 0001 4 .0000 5

1 4 3 1. 5 18 5

Dail y I n strea m Cs s Chromstogrsp h Ye s Ligh t End s Colum nVen t 26 9 Cont i nuou s

.000 7 5 .0007 0 .0173 7 .0776 0

1 4 3 1 5 12 0

Onc e Ven t pip e Ga s Chromstogrsp h Ye s .0406 5

. 0000 2 .0000 6 0 Incinerate dV»st e 10 0 Interm i t ten t 15t .

.003b 0 .0110 0 .0000 6 .0000 2 No t Specifie d

Ye s Neve r

NoTABL EVAC-II I NATIONALEMISSIO NINVENTOR Y VINYLACETAT

E VIA ETHYLEN E PROCES S Plan t EPA

Cod e No . Capacit y

- Ton s o f Viny l Acetate/Yr . Rang e inProductio n- X o f Max . Emission s t o Atmospher e Stream I . D . No . Strea m Flow - Lbs./Hr . Flo w Characteristi c - Continuou s o r Intermitten t i f Intermitten t - Hrs./Yr . Flow Compositio n CO 2 Hj O N 2 NO , Particulat e Argo n Ven t Stock s Numbe r Heigh t - Diamete r Exi t Ga s Temp . - F ° Emissio nContro l Device s Absorber/Scrubbe r Incineretor/Flsr e Anslys i s Dst e or Frequenc y o f Samplin g Sampl e Ta p Locatio n Typ e o f Analysi s Odo r Problem Summar y

o f Ai r Pollutant s Hydrocarbon s - Ton/To no f Viny l Acetat e Particulate s - Ton/To no f Viny l Acetat e N0 X- Ton/To no f Viny l Acetat e S0 X- Ton/To no f Viny l Acetat e C O - Ton/To no f Viny l Acetat e 30- 5 115,00 0 0

Ft

. (sbov e grsde )

- Inche s t ' CO , Purg e 398 5 Cont1nuou s
.0962 7 .0009 2

1 6 5 4 11 0 N o

Non e
Calculate d N o Ligh t End s Flam e Combustio n Gase s 14.12 9 Continuou s

.0651 6 .0553 4 .2231 1 + .0010 0 1 10 0 1 4 100 0 Ye s
+ Non e

Calculate d N o 0 0 + 0 0 Incineratio n o f Liaui dVast e Con t inuou s

0148 0 .0088 1 .0471 5 4 -

1 5 0 4 8 160 0 Ye s 4 - Non e

Calculate d N o

BU kTABL E VC-U l EMISSION S INVENTOR Y FO RPRODUCTIO

N O F VINY L CHLORID

E MONOME

RB Y PYROLYS1 S O

F DICHl.OROETHAN

E Pag e 1 o f ft Compan y Locatio n EP A Cod e Numbe r Dat e on-strea m Capacity , Ton s VCM/Yr . Averag e Production , Tons/Yr . Rang e inProduction , X o f Max . (a ) Emission s t o Atmospher e Strea m Flow - Lbs./Hou r . Flow Characteristi c i f Intermittent , Hrs./Yr . Composition , Tons/To nVCM Dlchloroethan e Viny l Chlorid e Ethy l Chlorid e Acetylen e Hydroge nChlorid e Chlorin e Ethylen e Propylen e Methan e Misc . Chlorinate dHydrocarbon s Carbo nDioxid e Carbo nMonoxid e Nitroge n Oxyge n Wate r Sampl e Ta pLocatio n
Dat e o r Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Stack s Numbe r Height , Ft . Diameter , Inche s Exi t Ga s Temp . ° F SCFM Pe r Stoc k Emissio nContro l Device s (b l Wate r Scrubbe r Incinerato r Refrigerate dCondense r Flar e Othe ro rNon e Summar y o f

Ai rPollutant s Hydrocarbon s (c ) Particulat e (d ) N0 X 

## so x C O 31- 1 300.00 0 0 Scrubbe r Effluen t 4b,98 0 (e ) Con t i nuou s

0.0075 6 0.0010 9 0.0063 4 0.0004 0 0.0018 6 0.0062 4 0.0017 2 0.0144 0 0.0061 1 0.5499 9 0.0244 4 0.0039 3 3 fee t abov e grad e Weekl y C.L C & We t Ye s (e ) 1 14 8 3 6 9 0 11,00 0 (e ) Refrigeran t Leakag e 8 (avg. l Variabl e

0.000 1

Non e
Neve r Calculate d N o 1 12 0 8 8 0 2. 4


## v c

Non e

No tApplicabl e (e l 16 c

Drie r Ven t 20 0 Cont1nuou s

0.0013 7 0.0025 9 0.0004 9 3 1

- 2

,00 0 0 Starl-u p an d

Emergenc yVen t 2,35 0 Intermitten t 0. 5

-.0.0000 1 Quenc h Towe r Ven t 68 6 Interm i tten t 5 b 0.00002 2 0.00006 5

0.00004 3 31- 3

1 4 7.SO O 3 3 Flar e Pond

8,44 3 Con t i nuou s

0 05 8

0.0002 0

0.0002 4 8 floor s abov e grad e Infrequentl y C.L C N o 1 96. 5 3 10 0 - 12 0 1 7

0.0041. 5

0.0000 1 —0.0000 1

-0.0000 1 —0.0000 1 Non e Neve r Calculate d N o 1 12 0 1 2 Ver y Ho t 50 0 V C - 7



## vc- 10 Non e r!eve r Calculate d N o 1 17 5 4 12 5 8 2 0 14 2

0 02 8 Non e
Neve r Calculate d Ye s Non e (f t



### V C

0.0000 9 0.0580 4

T J 

### •Je nI 1

Compan y

Loca tio n EP A Cod e Numbe r Dat e on-strea m Capacity , Ton s VCM/Yr . Averag e Production , Tons/Yr . Rang e i n Production , "/. o f Max . Emission s t o Atmospher e Strea m 

### 31 - (g l (a l

Flow - Lbs./Hou r Flo w Characteristi c I f Intermittent , Hrs./Yr . Composition , Tons/To nVC M Dlchloroethsn e Viny l Chlorid e Ethy l Chlorid e Acetylen e Hydroge nChlorid e Chlorin e Ethylen e Propylen e Methan e Misc . Chlorinate dHydrocarbon s Carbo nDioxid e Carbo nMonoxid e Nitroge n Oxyge n Wste r Sempl e To pLocatio n
Dat e o r Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Stock s Numbe r Height , Ft . Diameter , Inche s Exi t Ga s Temp . ° F SCF M Pe r Stac k Emissio nContro l Device s (b) Wste r Scrubbe r Incinereto r Refrigerate dCondense r Fler e Othe ro rNon e Summer y o f

Ai rPollutant s Hydrocarbon s (c ) Particulat e (d ) N0 X S0 X C O TABL E VC-11 1 EMISSHI.N! . INVENTOR Y FO RPRODUCTIO

N O F VINYL CHLORID

E MONOME

RB Y PYROI.YSIS O

F DTCHLOROETHAN

E

31- 5 21b,00 0 0
HC1 . Towe r Non-conden s i bl e 6 Con t inuou s Tan k Ven t 28 0 Con t inuo u

0.00004 1 0.00008 2

0.0001 2 Safet y Relie f 

## 3 ( D Con t inuou s 31- 6

200,75 0 0 Scrubbe r 6 . Stac k Sea l Unknown

0.005 5

0.000 1 0.00006 5 Trac e

Balanc e Pag e 2 of 6

Emergenc y Ven t Unknown Intermitten t Unknown 3 . 57 .

96.57 .

None 

### V C

0.005 5 

### V

C 31- 7 (gl

Loa din g Ven t Unknown Intermitten t LuiMIOWI I

Trac e

Balanc e
Saturate d Non e Neve r Calculate d No
Non e (h )

10 0 - 12 0 1 Neve r Calcul a N o 1 U O 1 2 Ambien t 2 9 te

d Non e
Neve r Purg e Rat e N o 2 U O 6 Ambien t 0.3 3 Estimate d

No 1 11 5 4 Ambien t Unknow n Non e

Neve r Estimate d No 1 4 0 8 Am bi e nt Unknow n Non e
Neve r Estimate d N o
1 (g l (R ) Ambien t UnknownTABU : VC-II I NATIONALEMISSION S INVENTOR Y VINY LCHLORID EMONOME RPRODUCTION VI A PYROLYSI S O FDICHl.OROETHANE 

### Pag e 3 of 6 Compan y Locatio n EP A Cod e No . Dat e on-stree

m Capacity , Ton s VCM/Yr . Aversg e Production , Tons VCM/Yr . Rsng e I nProduction , 7 . o

f Max . (s ) Emission s t o Atmospher e Strea m 31- 7 85,00 0 0 VC M Drie r Ven t Distillatio n Ven t Ga s Header EDC

Drier Ven t ED

C Vaporizer Ven t 31- 4 432.00 0 400,00 0 t o 475,00 0 0 'Ligh t Ends ' 'Ligh t Ends ' Ven t Ven t ' Heav y En ds ' Ven t 'Heav y Ends ' Ven t 

### Flo w - lbs./hr . Flo w Characteristic , Continuou s o r Intermittent i f Intermittent , hrs./yr . flo w Composition , Tons/To nof VC M Dlchloroethene Viny l Chloride Ethy l Chloride Acetylene HydrogenChlorid

e Chlorine Ethylene Propylen

e Methane Misc . Chlorinate

dHydrocarbons CarbonDioxid

e CarbonMonoxid

e Nitrogen Oxygen Wate r Seapl e TapLocatio

n Dat e o r Frequenc

y o f Samplin

g Typ e o f Analysi s Odo r Proble

m Ven t Stacka Number Heigh t - Ft . Diameter - Inche s Exi t Ga s Temp . F ° SCF M pe r stock Emissio nContro l Device s (b ) Wste r Scrubbe r Incinerator Refrlgerete

dCondenser Othe r Summar y o f Ai r Pollutant s Hydrocarbon s Particulat e N0 X 

### SO , CO 1 5 lb./mo . 608 0 Intermitten

t Continuou s

< . 0000 1 20 6 9 Continuou s Continuou s

<0000 1

Non e Neve r Estimat e N o N o

N o .0105 6

.2146 5 .0506 6 .0095 8 Non e Onc e - 196 4 Variou s N o Ye s 1 4 0 3 0 8 0 135 0 Ye s - VC-1 8 + .0006 8 .0000 8

.00012 1

.0000 3 Non e Estimat e N o Ye s 1 8 0 1. 5 9 0 Non

e Calc' d N o Ye s 1 8 0 1. 5 12 0 VC-1 1 N

o 20 0

Continuou s
.0003 7 .0003 7

.0011 1

Non e Neve r Celc'd . N o Ye s 1 14 0 3 10 5 N o

Se e Contlnuetlo

n 20 0

Continuou s
.0003 7 .0003 7

.0011 1

Non e Never Calc'd . N o Ye s 1 14 0 3 10 5 N o 51 6

Continuou s
0047 8

Non e Never Celc'd . N o Ye s I 4 4 3 12 0 N o Continuou s

0000 5

None Neve r Celc' d N o Ye s 1 4 4 4 12 0 N o

•c o <> iTABL E VC-11 1 NATIONA

L EMISSION S INVENTOR Y VINYL CHLORID

E MONOME

RPRODUCTIO

N VIA PYROLYSI S O

F DICHLOROETHAN

E Pag e 4 o f6 

### Compan y Locatio n EP A Code No . Dat e on-strea m Capacity , Ton s VCM/Yr . Avereg e Production , Ton s VCM/Yr . Rang e i nProduction , 7 . o f Max. (a ) Emission s t o Atmospher e Stree m Flow - lbs./hr . Flow Characteristic , Continuou s o r Intermitten t I f Intermitten t hrs./yr . flow Compositio n- Tons/To no f VC M Dlchloroethen e Viny l Chlorid e Ethy l Chlorid e Acetylen e 

### Hydroge nChlorid e Chlorin e Ethylen e Propylen e Methan e Misc . Chlorinate d Hydrocarbon s Carbo nDioxid e Carbo nMonoxid e Nitroge n Oxyge n Wste r Sempl e Top Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Analysi s OdorProble m Ven tStock s Numbe r Heigh t- Ft . Diamete r- Inche s Exi tGa s Temp . - F ° SCF M pe rstoc k Emissio nContro l Device s (b ) Wate rScrubbe r Incinerato r Refrigerate d Condense r Othe r Summer y o f Ai rPollutant s Hydrocarbon s Particulat e NO, SO , C O 31- 4 432,00 0 400,00 0 t o 475,00 0

0 Toppin g Colum

n Off-Ga s 3 0 Continuou s

.0000 6

.0001 6

Neve r Calc'd . N o Ye s 1 4 6 2 120 °

VC-1 2 Heav y End s Recover y

Ven t 5 Continuou s

0000 5 Flsr e Flu e Co s No t Specifie d Con t inuou s

Neve r Cslc'd . N o Ye s 1 5 8 3 90 °
No

0095 b .0000 7 

### f" 0000 7

+

Neve r Calc' d N o Ye s 1 15 0 2 4

VC-1 6

Flar eTABI E VC-11 1 EMISSION S INVENTOR Y FO RPRODUCTIO

N O F VINYL CHLORID

E MONOME

RB Y PYROLYS1 S O

F D I CHLOROETHANF

. Pag e 5 of b Company Loca t io

n EPA Cod e Numbe r Dat e on-stream Capacity , Ton s VCM/Yr . Averag e Production , Tons/Yr . Rang e InProduction , 7 . o f Max . (a ) Emission s t o Atmospher e Strea m Flo w - Lbs./Hou r Flo w Characteristi c i f Intermittent , Hrs./Yr . Composition , Tons/To nVC M Dichloroethan e Viny l Chlorid e Ethy l Chlorid e Acetylen e Hydroge nChlorid e Chlorin e Ethylen e Propylen e Methan e Misc . Chlorinate dHydrocarbon s Carbo nDioxid e Carbo nMonoxid e Nitroge n Oxyge n Wate r Sampl e Ta pLocatio n
Dat e or Frequenc y o f Samplin g Typ e o f Anelysl s Odo r Problem Ven t Stack s Numbe r Height . Ft . Diameter , Inche s Exi t Ga s Temp . ° F SCF M Per Stac k Emissio nContro l Device s (bl Wate r Scrubbe r Incinerato r Refrigerate dCondense r Flar e Othe r o

r Non e Summar y

o f Ai r Pollutant s Hydrocarbon s (c ) Particulat e (d

> N O x 

### so , CO Variou s Towe r Overhead s 19 8 (j ) Con tinuou s

0.002 3

Non e
Neve r Calculate d No 1 U O 3 0 6 0 - 10 0 2 0 (j ) V C - 3 31- 8 350.00 0 0 Storag e Ven t 1 8 (avg. l Intermitten t Unknow n

0.0002 1

Non e Neve r Calculate d N o
I 7 5 7 Ambien t 2 (avg. )

Non e 0.00 2 S 1

Trac e Maintenanc e Ven t 1,00 0 (Ibs./yr. ) Interm i tten t Unknown 67 ,

Trac e

Trac e

Balanc e

Neve r Estimate d

1 4 0 8 Amb i en t 7,00 0 - 1 4 00 0 (CFY )

Non e Furnac e Oecok i ng 3 0 00 0 Interm i t ten t 5 0 - 10 0
Trac e

Unknown Unknown



## - \
v Mostl y 

### J Non e
Neve r Ai r& Strea m Meter s
1 4 0 1 2 21 2 6,00 0 V C 1

•t o •c o

## 0



## TABL E VC-II I EXPLANATIO N

O F NOTE S EMISSION S INVENTOR Y FORPRODUCTIO N

O F VINY L CHLORID E MONOME RB Y PYROLYSI S O F DICHLOROETHAN E Pag e 6 o f 6

(a ) Differenc e betwee nmaximum & minimum

quarterl y

productio ndivide dby maximum

quarterl y

production . (b ) Se e Tabl e IV , Catalo g o f Emissio nContro l Device s fo r details . (c ) Include s H 2 

## S . Exclude s CH ^ & H2 . (d ) Include s aerosol s suc ha s HC l an dCl£ - (e ) Unspecifie dportio no f thi s stream result s fro

m dichloroethan e production . (f ) Stream

i s vente dbelo w

surface o f pond , combustible s bur na t pondsurface . (g ) No dat a received . (h ) Vent s fro

m to po f 1 4 foo t scrubbe r tower . (i ) Purge dHeade r - pollutant s wil l increase durin g emergencie s o r relie f valve lifitng . (j ) Mino r portio no f a combine dven t fro m othe r process .