U. S. ENVIRONMENTAL PROTECIlON AGENCY 

. ft EDA PREMANUFACTURE o rr\ NOTICE 

FOR. NEW CHEMICAL SUBSTANCES 

AGENCY USE ONLY 

COtnruH:l' S.....:.:_....I rt~{'Ift-ll AUJu.c..QJ 

Hnter the total number of page. 


in the Premanufac:ture Notice 


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EPA FORM 771~2S (Key,5-9S) RIIpIaca pl'mOUI editiolll oi,F!A Fo~ 7l1G1t

I .~.}~ 

Y.. 
Public reporting burden for this collection of information is estimated to average 110 hours per response, including time for reviewing instructions, 

searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send 

comments regarding the burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden, to 

Chief, Information Policy Branch, PM-223, U.S. Environmental Protection Agency, 401 M.St.,S.W., Washington, D.C. 20460; and to the Office of 

Management and Budget, Paperwork Reduction Act (2070-0012), Washington, D.C. 20503. 

CERTIFICATION 

I certifY that to the best of my knowledge and belief: 

I. 	 The company named in Part I, section A, subsection I a of this notice fonn intends to manufacture or import for a commercial 

purpose, other than in small quantities solely for research and development, the substance identified in Part I, Section B. 

2. 	 All infonnation provided in this notice is complete and truthful as of the date of submission. 

3. 	 I am SUbmitting with this notice all test data in my possession or control and a description of a\1 other data known to or 

reasonably ascertainable by me as required by § 720.50 of the Premanufacture Notification Rule. 

Additional Certification Statements: 

Ifyou are submitting a PMN, Intennediate PMN, Consolidated PMN, or SNUN, check the following user fee certification 

statement that applies: 

~ The Company named in Part I, Section A has remitted the fee 0[$2500 specified in 40 CFR700.45 (b), or 

o 	The Company named in Part I, Section A has remitted the fee of $1 000 for an Intennediate PMN (defined @40CFR7oo.43) in 

accordance with 40CFR700A5.(b), or 

o 	The Company named in Part I, Section A is a small business concern under 40CFR 700.43 and has remitted a fee of $1 000 in 

accordance with 40CFR700A5(b) 

Ifyou are submitting a low volume exemption (LVE) application in accordance with 40CFR723.50( c)( 1) or a Low release and low 

exposure exemption (LoREX) application in accordance with 4OCFR723.50(c)(2), check the following certification statements: 

o 	The manufacturer submitting this notice intends to manufacturer or import the new chemical substance for commercial 

purposes, other than in sman quantities solely for research and development, under the tenns of40CFR723.50. 

The manufacture is familiar with the tenns of this section and wi\l comply with those tenns; and 

The new chemical substance for which the notice is submitted meets all applicable exemption conditions. 

o 	Ifthis application is for an LVE in accordance with 40CFR723 .50( c)( 1). the manufacturer intends to commence manufacture 

ofthe exempted substance for commercial purposes within 1 year of the date of the expiration of the 30-day review period. 

The accuracy of the statements you make in this notice should reflect your best prediction ofthe anticipated facts regarding the 

chemical substance described herein. Any knowing and wilful misinterpretation is subject to criminal penalty pursuant to 18 USC 

1001. 

Confidential 

Signature and title ofAuthorized Official (Original Signature Required) Date I 
 q""~''',1 11"<-V\if"{I.e r ' .Ad ..... ~.}tr-t\.t.~il 

C:::;Z~.~ :3/30/D3

Signature of agent (if applicable) ~ Date 

~~ 1//./tr'J

FORM EPA 7710-25 (Rev.5-95) 	 Page 2 
Part I - GENERAL INFORMATION 

Section A - SUBMITTER IDENTIFICATION 

1a. Person 

Submitting 

Notice 

(in U.S.) 

b. Agent (if 

applicable) 

c. If you are 

2. Technical 

Contact 

(in U.S.) 

Name of official 

Ronald S Ph.D. 

Company 

Environ International 

Mailing address (number and street) 

4350 North Fairfax Drive Suite 300 

State, ZIP Code 

VA 22203-1619 

Company 

Mailing address (number and street) 

City, State, ZIP Code 

Name of official 

Ronald Ph.D. 

Company 

Environ International 

Mailing address (number and street) 

4350 North Fairfax Drive Suite 300 

City, State, ZIP Code 

Arlington, VA 22203-1619 

3. Ifyou have had a prenotice communication (PC) 

concerning this notice and EPA assign a PC Number to the 

enter the number. 

4. Ifyou previously submitted an exemption application for 

the chemical substance covered by this notice, enter the 

exemption number assigned by EPA. If you previously 

submitted a PMN for this substance enter the PMN number 

EPA . e. withdrawn or' 

5. If you have submitted a notice of Bona fide intent to 

manufacture or import for the chemical substance covered 

this enter the notice number EPA. 

() Manufacture 

6. Type ofNotice Mark (X) 1. Only 

( ) Binding 

Option Mark 

President 

Senior Science 

Telephone 

Position 

Senior Science 

Telephone 

Mark (X) 

if none 

Mark (X) 

. Ifnone 

(X) Import Only 

2 3. 

(X) Binding 

Option Mark 

(X) 

(X) 

(X) 

( ) Both 

FORM EPA 7710-25 (Rev.5-95) Page 3 
Part I - GENERAL INFORMATION - Continued 

Section B - CHEMICAL IDENTITY 	 You must provide a currently correct Chemical Abstracts (CA) name of 

INFORMATION: the substance based on the ninth Collective Index (9CI) of CA

nomenclature 

Complete either item 1 (Class 1 or 2 substances) or 2 (Polymers) as appropriate. Complete aU other items. 

If another person will submit chemical identity information for you, mark (x) the box at the right. 

Identify the name, company and address of that person. 

[ ] Confidential 

I. Class 1 or 2 chemical substances (for definitions ofclass 1 and class 2 substances, see the Instructions Manual) 

a. Class ofsubstance Mark (X) 1 [ ] Class I or 2 [ ] Class 2 

b. Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for 

similar substance. For Class 1 substance a CA Index Name must be provided. For Class 2 substances either a CA Index 

Name or CA Preferred Name must be provided, whichever is appropriate based on CA 9CI nomenclature rules and 

conventions.). 

c. Please identify which method you used to develop or obtain the specified chemical identity information reported in this 

notice: (check one). 

[ 	 ] Method 1 (CAS Inventory Expert Service - a copy ofthe Identification [] Method 2 (Other Source) 

report obtained from the CAS Inventory Expert Service must be 

CAS # 

e. For a class 1 substance, provide a complete and correct chemical structure diagram. For a class 2 substance - (I) List the 

immediate precursor substances with their respective CAS Registry Numbers. (2) Describe the nature of reaction or 

process. (3) Indicate the range of composition and the typical composition (where appropriate). (4) Provide a correct 

representative or partial chemical structure diagram, as complete as can be known, if one can be reasonably ascertained. 

o Mark this box if you attach a continuation sheet. 

FORM EPA 7710-25 (Rev.5-95) 	 Page 4 

, ,"!"" t}~, ' . 

. 
Part I - GENERAL INFORMATION - Continued Q. B-C'HF.MrC'AT lUElYlTlY l.l"iJ:4tlllMA.TION Continued 

2. Polymers (For a definition of polymer, see the Instructions Manual.) 

~~~f~1 a. Indicate the number-average weight of the lowest molecular weight composition ofthe polymer you intend to manufacture. Indicate 

maximum weight percent oflow molecular weight species (not including residual monomers, reactants, or solvents) below 500 and 

below 1,000 absolute molecular weight of that composition. 

Describe the method of measurement or the basis for your estimates: ope (X) Other ( ): (Specify ) 

i) Lowest number molecular weight: 2454 

ii) Maximum weight % below 500 molecular weight: 1.28% 

iii) Maximum weight % below 1000 molecular weight: 8.89 % 

D Mark (X) this box if you attach a continuation sheet. 

b. You must make separate confidentiality claims for monomer or other reactant identity, composition information, and residual information. 

Mark (X) the "Confidential" box next to any item you claim as confidential. 

(1) Provide the specific chemical name and CAS Registry Number (if a number exists) of each monomer or other reactant used in the 

manufacture of the polymer. 

(2) Mark (X) this column if entry in column (I) is confidential. 

(3) Indicate the typical weight percent of each monomer or other reactant in the polymer. 

(4) Mark (X) the identity column if you want a monomer or other reactant used at two weight percent or less to be listed as part ofthe polymer 

description on the TSCA Chemical Substance Inventory. 

(5) Mark (X) this column if entries in column (3) and (4) are confidential. 

(6) Indicate the maximum weight percent of each monomer or other reactant that may be present as a residual in the polymer as manufactured for 

commercial purposes. 

(7) Mark (X) this column if entry in column (6) is confidential. 

Monomers or other reactant and CAS Registry Number Confi- Typical Identity Confi- Maximum Confi­

(I) dential composition Mark (x) dential Residual dential 

(2) (3) (4) (5) (6) (7) 

X X X X 

X X X X 

X X X X 

X X X X 

X X X X 

X X X X 

X X :x X 

X X X 

:x X 

D Mark (X) this box ifyou attach a continuation sheet. 

c. Please identify which method you used to develop or obtain the specified chemical identity information reported in this notice. 

(X) Method I (CAS Inventory Expert Service a copy ofthe Identification report obtained ( ) Method 2 (Other Source) 

from the CAS Inventory Expert Service must be submitted as an attachment 

to this notice) See Page 24 

d. The currently correct Chemical Abstracts (CA) name for the polymer that IS with TSCA Inventory listings for similar polymers. 

2-Propenoic acid, 2-methyl-, methyl ester, polymer with butyl-2-propenoate, ethyl-2-propenoate, zinc bis 

(2-methyl-2-propenoate) and zinc di-2-propenoate, 2,2'-azobis[2-methylbutanenitrile] -and 2,2'- azobis 

r2-methy!' itfile] initiated CAS No. 460739-39-3 

e. Provide a correct representative or partial chemical structure diagram, as complete as can be known, ifone can be reasonably be 

ascertained. 

Please see page 16 

~ Mark (X) this box if you attach a continuation sheet 

FORM EPA 7710-25 (Rev.5-95) Page 5 
Part I - GENERAL INFORMATION - Continued 

3. Impurities 

(a) 	 Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial purposes. 

Provide the CAS Registry Number if available. Ifthere are unidentified impurities, enter "unidentified." 

(b) Estimate the maximum weight % of each impurity. Ifthere are unidentified impurities, estimate their total weight %. 

Impurity and CAS Registry Number Maximum

(a) percent dential

[ ] Mark (X) this box if you attach a continuation sheet 

Enter any Confidential 

None 

[ ] Mark (X) this box if you attach a continuation sheet 

5. Trade identification - List trade names for the new chemical substance identified in subsection 1 or 2. 

LR-1672 

attach a continuation sheet 

6. Generic chemical name - If you claim chemical identity as confidential, you must provide a generic chemical name for your substance that 

reveals the specific chemical identity of the new chemical substance to the maximum extent possible. Refer to the 

TSCA chemical Substance Inventory, 1985 edition, Appendix B for guidance on developing generic names. 

CAS 

attach a continuation sheet 

FORM EPA 7710-25 (Rev.5-95) 	 Page 6 

m~m1Jlta(~ture, pCl.l!x;~l:jlIlg, use, or disposal of the new chemical 
Part I - GENERAL INFORMATION - Continued 

Section C - PRODUCTION, Il\1PORT, AND USE INFORMATION: 

Mark (X) the "Confidential" box next to any item you claim as confidential. 

1. Production volume - Estimate the maximum production volume during the first 12 months ofproduction. Also estimate the maximum production 

volume for any consecutive 12-month period during the first three yeas ofproduction. Estimates should be on 100% new chemical substance 

basis. For a Low Volume Exemption application. ijyou choose to have your notice reviewed at a lower production volume than 10.000kg/yr. 

specifY the volume and mark (x) in the binding box. Ifgranted. you are bound to this volume. 

Maximum first 12-month production (kg/yr) Maximum 12-month production (kglyr) Confidential Binding 

(100010 new chemical substance basis) (100010 new chemical substance basis) Option Mark 

(xl 

3,300 kg/year 4,800 kg/year 

I 

2. Use Information - You must make separate confidentiality claims for the description of he category of use, the percent of production volume 

devoted to each category, the formulation of the new substance, and other use information. Mark (X) the "Confidential" Box next to any item you 

claim as confidential. 

a. (I) Describe each intended category of use of the new chemical substance by function and application. 

(2) Mark (X) this colunm if entry in colunm (1) is confidential business information (CBI). 

(3) Indicate your willingness to have the information provided in colunm (I) binding. 

(4) Estimate the percent oftOlal production for the first three years devoted to each category of use. 

(5) Mark (X) this colunm if entry in colunm (4) is confidential business information (CBI). 

(6) Estimate the percent of the new substance as formulated in mixtures, suspensions, emulsions, solutions, or gels as manufactured for 

commercial purposes at sites under your control associated with each category of use. 

(7) Mark (X) this colunm if entry in colunm (6) is confidential business information (CBI) 

(8) Indicate % ofproduct volume expected for the listed "use" sectors. Mark more than one box if appropriate. Mark (X) to indicate your 

willingness to have the use type provided in (8) binding. 

(9) Mark (X) this column ifentr:v(ies) in column (8) is (are) confidential business information (CBI). 

Category of Use (I) CBI Binding Produc- CBI 0/. in Form- CBl % ofsubstance expected per use (8) CBI 

(by function and application (i.e. a (2) Option tion% (5) ulation (7) Site- Consu Indus Com- Binding (9) 

dispersive dye for finishing polyester Mark (x) (4) (6) limited mer trial mercial Option fibers) (3) 

Binder polymer in paints 100* 10-13% 100% 

% 

% % 

If you have identified a "consumer use", please provide 

I 

on 

% 

% 

a detailed description 

% 

% 

ofthe use(s) ofthis chemical substance in consumer 

H

products. In addition include estimates of the concentration ofthe new chemical substance as expected in consumer products and 

describe the chemical reactions by which this substance loses its identity in the consumer product. 

[ ] Mark (X) this box if you attach a continuation sheet. 

b. Generic use Ifyou claim any category of use description in subsection 2a as confidential, enter a generic description of that 

description category. Read the Instructions Manual for examples of generic use descriptions. 

[ ] Mark (X) this box if you attach a continuation sheet 

3. Hazard Information ­ Include in the notice a copy of reasonable facsimile of any hazard warning statement, label, material safety data sheet, or Binding other information which will be provided to any person who is reasonably likely to be exposed to this substance regarding protective equipment or practices for the safe handling, transport, use or disposal ofthe new substance. List in part III hazard information you include. Option 

Mark (x) 

[ X J Mark (X) this box if you attach hazard infonnation MSDS is provided 

FORM EPA 7710-25 (Rev.5-95) Page 7 
Part II ­ HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE 

Complete section A for each type of manufacture, processing, or use operation involving the new chemical substance at industrial sites you control. 

Importers do not have to complete this section for operations outside the U.S.; however, you may still have reporting requirements if there are 

further industrial 

of the site at which the "''''r<ll',nn will occur. 

Confid 

ential 

Name 

Site address 

City, County, State, ZIP Code 

Ifthe same operation occur at more one enter the on a #Of sites 

sheet, and if any of the sites have significantly different production rates or operations, include all the information requested 

in this section for those sites as attachments. 

[ ) Mark (X) if you attach a continuation sheet 

Hourslbatch Batcheslyear 

Hourslbatch Batches/year 

(I) Diagram the major unit operation steps and chemical conversions. Include interim storage and transport containers (specifY e.g. 5 gallon pails, 55 

gallon drum, rail car, tank truck, etc.). 

(2) Provide the identity, the approximate weight (by kg/day or kglbatch on an 100% new chemical substance basis), and entry point of all starting 

materials and feedstocks (including reactants, solvents, and catalysts, etc), and of all products, recycle streams, and wastes. Include cleaning 

chemicals (note frequency ifnot used daily or per batch.). 

(3) Identify by number the points of release, including small or intermittent releases, to the environment of the new chemical substance. 

No production, processing or use of the PMN substance occurs in the U.S. at sites controlled by the 

submitter. 

o Mark (X) this box if attach a continuation sheet 

FORM EPA 7710-25 (Rev.5-95) Page 8 
Part II - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE -Continued 

Section A - INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER - Continued 

2. Occupational Exposure'You must make separate confidentiality claims for the description of worker activity, physical form of the new 

chemical substance, number of workers exposed, and duration of activity. Mark (X) the "Confidential" box next to any item you claim as 

confidentiaL 

(}) Describe the activities (e.g. bag dumping. tote filing. unloading drums. sampling, cleaning, etc) in which workers may be exposed to the 

substance. 

(2) Mark (X) this column ifentry in column (}) is confidential business information (CBI>. 

(3) Describe any protective equipment and engineering controls used to protect workers. 

(4) and (6) Indicate your willingness to have the information provided in column (3) or (li) binding. 

(5) Indicate the physical form(s) ofthe new chemical substance (e.g. solid: crystal, granule, powder, or dust) and % new chemical substance (if 

part of a mixture) at the time of exposure. 

(7) Mark 00 this column if entry in column (li) is confidential business information (CBI). 

(8) Estimate the maximwn nwnber of workers involved in each activity for all sites combined. 

(9) Mark 00 this column if entry in column (5) is confidential business information (CBO. 

(10) and (11) '~stimate the maximwn duration ofthe activity for any worker in hours per day and days per year. 

(12) Mark 00 this column ifentry in column (5) is confidential business infurmation (CBI). 

Worker activity 

(e.g. bag dwnping, filling 

drwns) 

( I) 

CBI 

(2) 

Protective Equipment 

!Engineering Controls 

(3) 

Binding 

Option 

Mark (x) 

(4) 

Physical 

formes) 

(5) 

Binding 

Option 

MlIrk(x) 

(6) 

CBI 

(7) 

# of 

Workers 

Exposed 

(8) 

CBI 

(9) 

MaximwnDu 

ration 

CBI 

(12) 

HrsIday 

(1/n 

Days/yr 

()n 

[ ] Mark (X) this box if you attach a continuation sheet 

3. Environmental Release and disposal-You must make separate confidentiality claims for the release number and the amount of the new chemical 

substance released and other release and disposal information. Mark (X) the "Confidential" box next to each item you claim as confidentiaL 

(I) Enter the number of each release point identified in the process description, Part II, section A, subsection I d(3). 

(2) Estimate the amount ofthe new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch). 

(3) Mark (X) this column if entries in columns (l) and (2) are confidential business information (CBI) 

(4) Identify the media of reI ease i.e. stack air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land or incineration, 

POTW, or other (please specify) to which the new substance will be released from that release point. 

(5) a. Describe control technology, if any, and control efficiency that will be used to limit the release ofthe new substance to the environment. For 

releases disposed of on land, characterize the disposal method and state whether it is approved for disposal ofRCRA hazardous waste. On a 

continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subject to secondary or 

tertiary on-site treatment. b. Estimate the amount released to the environment after control technology (in kg/day). 

(6) Mark (X) this column if entries in columns (4) and (5) are confidential business information (CBI). 

(7) Identify the destination(s) ofreleases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct 

dischargers or NPDES numbers of the POTW (Publicly Owned Treatment Works). Mark (X) if the POTW name or NPDES# is confidential 

business information (CBn. 

Release 

Nwnber 

(I) 

Amount ofnew substance released CBI 

(3) 

Media of 

release 

(4) 

Control technology and efficiency CBI 

(2a) (2b) (Sa) Binding (6)

Mark (x) 

(5b) 

(7) Mark (Xl the ( 1 POTW provide name{s) below 

destination(s) of 

releases to water 

CBI - ( ) Navigable ( ) Other - specify 

waterway 

Provide NPDES# CBr 

D Mark (Xl this box if you attach a continuation sheet 

FORM EPA 7710-25 (Rev.5-95) Page 9 
Part n - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued 

Section B - INDUSTRIAL SITES CONTROLLED BY OTHERS 

Complete section B for typical processing or use operations involving the new chemical substance at sites you do not control. Importers do not have to 

complete this section for operations outside the U.S.; however, you must report any processing or use activities after import. See the Instructions 

Manual. Complete a separate section B for each type of processing, or use operation involving the new chemical substance. If the same operation is 

performed at more than one site describe the typical operation common to these sites. IdentiiY additional sites on a continuation sheet. 

1. Operation Description To claim information in this section as confidential, circle or bracket the specific information that you claim as 

confidential. 

(I) Diagram the major unit operation steps and chemical conversions, including interim storage and transport containers (specify e.g. 5-gallon pails, 

55-gallon drum, rail car, tank truck, etc.). On the diagram, identify by letter and briefly descnbe each worker activity. (2) Provide the identity, the 

approximate weight (by kg/day or kglbatch on a 100% new chemical substance basis), and entry point of all feedstocks (including reactants, solvents, 

and catalysts, etc), and of all products, recycle streams, and wastes. Include cleaning chemicals (note frequency if not used daily or per batch.). (3) 

Identify by number the points ofrelease, including small or intermittent releases, to the environment ofthe new chemical substance. (4) Please enter the 

# of sites (remember to identify the locations ofthese sites on a continuation sheet): 

# of Sites 

Please see page 14,15 

[X] Mark (X) this box if you attach a continuation sheet 

2. Worker ExposurelEnvironmental Release 

(I) From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity described. 

(2) Estimate the number of workers exposed for all sites combined. 

(4) Estimate the typical duration of exposure per worker in (a) hours per day and (b) days per year. 

(6) Describe physical form of exposure and % new chemical substance (if in mixture), and any protective equipment and engineering controls used 

to protect workers. 

(7) Estimate the percent of the new substance as formulated when packaged or used as a final product. 

(9) From the process diagram above, enter the number of each release point. Complete 9-13 for each release point identified. 

(10) Estimate the amount ofthe new substance released (a) directly to the environment or (b) into control technology to the environment (in kg/day 

or kglbatch). 

(12) Describe media of release i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-site land or incineration, 

POWT, or other (specify) and control technology, ifany, that will be used to limit the release of the new substance to the environment. 

(14) Identify by-products, which may result from the operation. 

(3 , (5),(8),(11), (13) and (15) Mark(X this column ifanj' oftheproceedillg entries are confidential business information CBn. 

Letter #of CBI Duration of cm Protective Equip.! %in CBI Release AmOWlt ofNew CBI Media of CBI 

of Workers (3) Exposure (5) Engineering Controls! Form­ (8) Number Substance (II) Release & (13) 

Act- Exposed Physical Form and % ulation (9) Released Control 

ivity (2) (4a) I (4b) new substance (7) ! (lOa) (lOb) Technology 

(I) , hours! daysl kg/day • (12) 

! day year 

J 

1 2 ! 0.5 40-60 Helmet, goggles, 50 1 .... 2 1 0.5 40-60 glove, mask 12.5 0.1 ::: !--­ (') 

3 1 1.0 40-60 1 0.1 I S· - n 

4 2 2-4 40-60 Helmet, goggles, 12.5 1 iil - :to 

0 ;..­ 5 4 4-8 60-80 glove, mask 12.5 10 20 ::l 

6 2 J 0.5 60-80 protective suit 0.1 0.1 0.1 !--­

(l4)-By-products: (15) 

[ 1 Mark (X) this box if you attach a continuation sheet Please see page 14,15 

... 

FORM EPA 7710-25 (Rev.5-95) Page 10 
OPTIONAL POLLUTION PREVENTION INFORMATION 

To claim infonnation in this section as confidential circle or bracket the specific infonnation that you claim as confidential. 

In this section you may provide information not reported elsewhere in this form regarding your efforts to reduce 

or minimise potential risks associated with activities surrounding manufacturing, processing, use and disposal 

of the PMN substance. Please include new information pertinent to pollution prevention, including source 

reduction, recycling activities and safer processes or products available due to the new chemical substance. 

Source reduction includes the reduction in the amount or toxicity ofchemical wastes by technological 

modification, process and procedure modification, product reformulation, raw materials substitution, and lor 

inventory control. Recycling refers to the reclamation of useful chemical components :from wastes that would 

otherwise be treated or released as air emissions or water discharges, or land disposal. Descriptions ofpollution 

prevention, source reduction and recycling should emphasize potential risk reduction subsequent to compliance 

with existing regulatory requirements and can be either quanti t~,ti vC 0 ..... ualitative. The EPA is interested in this 

information to assess overall net reductions in toxicity or environmental releases and exposures, not the shifting 

ofrisks to other environmental media or non-environmental areas (e.g., occupational or consumer exposure). In 

addition, information on the relative cost or performance characteristics ofthe PMN substance to potential 

alternatives may be provided. 

All information provided in this section will be taken into consideration during the review of this 

substance. See the revised Instructions Manual that includes a Pollution Prevention manual for 

guidance and examples. 

Describe the expected net benefits, such as (1) an overall reduction in risk to human health or the environment; (2) a reduction in the 

volume manufactured; (3) a reduction in the generation ofwaste materials through recycling, source reduction or other means; (4) a 

reduction in potential toxicity or human exposure and/or environmental release; (5) an increase in product perfonnance, a decrease in 

the cost of production and/or improved operation efficiency of the new chemical substance in comparison to existing chemical 

substances used in similar applications; or (6) the extent to which the new chemical substance may be substitute for an existing 

substance that poses a greater overall risk to human health or the environment. 

[ ] Mark (X) this box ifyou attach a continuation sheet 

FORM EPA 7710·25 (Rev.5-95) Page 11 
Part III -LIST OF ATTACHMENTS 

Attach continuation sheets for sections ofthe fonn and test data and other data (including physicaVchemical properties and 

structure/activity infonnation), and optional infonnation after this page. Clearly identify the attachment and the section ofthe fonn to 

which it relates, if appropriate. Number consecutively the pages ofthe attachments. In the column below, enter the inclusive page 

numbers of each attachment. 

Mark (x) the "Confidential" box next to any attachment name you claim as confidential. Read the Instructions Manual for guidance on 

how to claim any infonnation in an attachment as confidential. You must include with the sanitized copy ofthe notice fonn a sanitized 

version of any attachment in which YOU claim infonnation as confidential. 

Attachment name Attachment page 

nwnber(s) 

Contidential 

Physical and chemical properties worksheet 

Continuation Page: Part II. Section B. 1. 

Continuation Page 5: Part 1. Section B. 2. c 

Material Safety Data Sheet (MSDS) 

13 

14 - 15 

16 

17 - 23 

CAS Inventory Expert Service Report 24 

GPC Measurement for Polymers 25 - 31 

0 Mark (X) this box if you attach a continuation sheet. Enter the attachment name and number 

FORM EPA 7710-25 (Rev.5-95) Page 12 
PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET 

To assist EPA's review ofphysical and chemical properties data, please complete the following worksheet for data you provided and include it in the 

notice. IdentifY the property measured, the page of the notice on which the property appears, the value of the property, the units in which the 

property is measured (as necessary), and whether or not the property is claimed as confidential. The physical state of the neat substance should be 

provided. These measured properties should be for the neat (100%) chemical substance. Properties that are measured for mixtures or formulations 

should be noted (% PMN substance in -). You are not required to submit this worksheet; however, EPA strongly recommends that you do so, as it 

will simplifY review and ensure that confidential information is properly protected. You should submit this worksheet as a supplement to your 

submission of test data. This worksheet is not a substitute for submission of test data. 

Property 

(a) 

Mark (x) if 

provided 

Page 

number 

(b) 

Value 

(c) 

Measured 

or 

Estimated 

(MorE) 

Confident 

ial Mark 

(x) 

(d) 

Physical state of neat substance X 21 Liquid 

Vapor pressure 

@ temperature °c 

Density / relative density X 21 1.015 ± 0.010 

Solubility in solvent 

@ temperature "C 

Solubility in water 

@ temperature "C 

Melting temperature 

Boiling/sublimation temperature 

Torr pressure 

Spectra (lR, UV-vis, NMR) 

Dissociation constant 

Particle size distribution 

Octanol/water partition coefficient 

Henry's Law constant 

V olatilization from water 

V olatilization from soil 

pH @ concentration 

Flammability 

Exp lodability 

Adsorption/coefficient 

Other Specify 

Molec, WT, Distrib, Analysis X 25-31 

[ J Mark 00 this box if you attach a continuation sheet. Enter the attachment name and number 

FORM EPA 7710-25 (Rev.5-95) Page 13 
Continuation Page: Part II. Section B. 1. 


INDUSTRIAL SITES CONTROLLED BY OTHERS 


< >

Supply 

I.Dumping materials 

Mixer 

+ 2.Sampling 

Packaging to cans 

3.Cleaning 

< > 

Supply 

4.Charging 

Spray gun 

+ 5.Spraying 

Coating object 

6.Cleaning 

<AT FORMULATION> 


The product, LR-l672 resin, is mixed with other materials to form paint. Typical composition ofthe paint is as 


follows. 


LR-1672 resin: 28% 


Pigment: 55% 


Additives: 5% 


Solvents: 12% 


The materials are introduced to a tank by electric pumps automatically. The size oftank would be typically about 


1000-4000 Liters. The tank is closed after materials are introduced and it has a standard design to minimize the 


release ofthe.ulatile solvents to the working environment, but 100% containment cannot be achieved. The 


Page 14 
Continuation Page: Part II. Section B. 1. (cont.d) 

operation site is usually equipped with local ventilation system. The mixing is automatically processed and 


completes in several hours at the longest and this may take place three to six times/month. 


The formulated paint is charged to 5-gallon cans or drums. This process can be handled and monitored by one or 


two workers who wear gloves and a mask designed with a cartridge that provides protection from inhalation of 


chemical solvents. 


During this process, the formulated paints may be sampled and checked, but the direct contact to the substance by 


worker is unlikely and dermal exposure is obvious because ofthe paint pigments. 


A small amount of this product, LR-: \) 12 resin, is left in the drums after use. The amount is assumed less than 


0.2% relative to the total volume as the product is a xylene solution which is not viscous and typically flows easily 


from the container( s). The drums are not washed at the site, but passed to a dedicated company who recycles or 


disposes ofthe industrial wastes. The application equipment is washed with organic solvents after use and the 


resulting solvents, which would be about 10 to 20L, are passed to a dedicated company for recycling or disposal 


ofthe industrial wastes. The use ofsolvents may contain LR-1672 resin at less than 1 %. When the amount ofthe 


used solvents is large, the recycling ofthe solvents may be attempted and the residues are incinerated. When the 


amount of used solvents is small, it would be usually incinerated. Water is not used to wash the equipment or 


holding tank so releases to water would be unexpected. 


<AT USE> 


The paint product is delivered to the site ofuse in 5 gallons metal cans or drums. The mixed paint is charged to 


spray guns and sprayed on the ship hull or other structures by two to four workers, who wear whole body suit, 


goggle and mask designed with an absorbent for chemical solvents. The process may take place in a dock where a 


scatter proofnet is located to contain area contamination with paint. The process may take 4 to 8 hours depending 


on the size ofship. 


After use, the equipment is washed with paint remover or organic solvents .. The resulting solvents, which would 


be about 15 to 30 Liters, are passed to a dedicated company who recycles or disposes ofthe industrial wastes. The 


used solvents may contain LR-1672 resin at less than 1 %. When the amount ofthe used solvents is large, the 


recycling ofthe solvents may be attempted for economical reasons and the residues are incinerated. When the 


amount of used solvents is small, it would be usually incinerated. Water is not used to wash the mixer and no 


releases to water would be expected in the typical process ofmanufacture used. 


Page 15 
I-I 1-2 

Continuation Page 5: Part I. Section B. 2. c. 

Chemical Structure diagram 

CH3 I 

C-CH2 

I 

C=O 

I 

0 

I 

CH3 

a 

H 

I 

C-CH2 

I 

C=O 

I 

0 

I 

CH2 I 

CH3 

b 

H 

I 

C-CH2 

I 

C=O 

I 

0 

I 

(CH2h 

I 

CH3 

c 

CH3 J+-CH3 I I 

2

·l9-CH2 y-CH

C=O 

I

0­

I 


I 
 2+

Zn 

C=O 

I

0­

d 

H 

I 

C-CH2 

I 

C=O 

I

0­

I 

I 2+

Zn 

H 

I 

C-CH2 

I 

C=O 

I

0­

e 


e 

1-1 = Free-radical initiator fragment 1 

1-2 =Free-radical initiator fragment 2 

Page 16 
Page:1of7 

Firstissue: February 12, 2002 

Revised: . 

LR'1672 

MATERIAL SAFETY DATA SHEET (MSDS) 


1. CHEMICAL PRODUCT AND COMPANY IDENTlFICATION 

Product Name: DIANAL LR-1672 

General Use.: Acrylic Resin for coatings 

MANUFACTURER 


. Company Name: Mitsubishi Rayon Co., Ltd. 


Address: Chemicals & Plastic Technology Administration Office; 

6-41, Konan, 1-chomeMinato-ku, Tokyo 108-8506 JAPAN 

Telephone No. +81-03-5495-3103 

Fax No. . +81-03-5495-3215 

Specialty Chemicals Department I; 

8-30, Tenmabashi, 1-chomeKita-ku, Osaka 530-6040 JAPAN 

Telephone No. +81-06-6881-6461 

Fax No. +81-06-6881-6463 

EMERGENCY TELEPHONE NUMBER 

Mitsubishi Rayon Co.• Ltd. 

Telephone No. +81-03-5495-3103 

(Chemicals &. Plastic Technology Administration Office) 

9:30 am -6:00 pm Japan Time M-F 

z. COMPOSITION, INFORMATION ON INGREDIENTS 


No. Components Name CAS Registry # 

1) Acrylic Polymer A 

2) Xylene 

3) , Ethyl benzene 

4) Propylene glycol monomethyl ether 

45-50 

15 

21 

15-20 

Not registered 

1330-20-7 

100-41-4 

107-98-2 

3. HAZARDS IDEN'TlFICATION 

EMERGENCY OVERVIEW: 

COmbustible liquid, May cause explosion in high concentration ofits vapor. 

Substance ofacute toxicity. May d8mage health. 

POTENTIAL HEALTH EFFECI'S: 

PRIMARY ROUTE OF EXPOSURE 


INHALATION: Irritating to respiratory system I~ 

EYE CONTACT: Irritating to eyes 


11 

Page2of7 

First issue: February 12, 2002 

Revised: 

LR'1672 

SKIN CONTACT: Irritating to skin 

INGESTION: Toxic 

CHRONIC TOXICITY/CARCINOGENICITY 

Not Available 

MEDICAL CONDmONS AGGRAVATED BY EXPOSURE: 

Not Available 

4. FlRST AID MEASURES 

INHALATION: 

For such inhalation, remove to fresh air and rest with keeping warm. 

Ifnot breathing. give artificial respiration. Ifthere is breathing difficulty, . 

give oxygen. Get immediate medical attention, showing MSDS. 

If dizziness, nausea, headache or disorder occurs for· inhalation of vapor or gas, 

remove to fresh air, keep quiet and get immediate medical attention, 

showing MSDS. 

EYE ~ONTACT: 

Remove contact lenses where applicable, flush with clean water 


for at least 15 minutes. Wash sufficiently the back ofthe eyelids. too . 


. Getimmediate medical attention, showing MSDS. 

SKIN CONTACT: 

Immediately flood with water the area ofthe body without waiting to remove the 

contaminated clothing. Remove clothing under the water stream. 

Wash with plenty ofwater, then with soap and water. Discard contaminated 

clothing and shoes. Get medical attention ifnecessary. 

INGESTION: 

Do not induce vomiting. Dilute by giving milk or water. Nothing by mouth 

ifunconscious. Get immediate medical attention, showing MSDS. 

NOTE TO PHYSICIAN: 


Treatment may vary with condition ofvictim and specifics of incident. 


5. FIRE FIGHTING MEASURES 

FLAMMABLE PROPERTIES 

Flash point: 23OC(SETA:) Xylene 

Flammable (Bxplosive) Limit: 

Chemical name Composition (~Io) Lower Upper 

Xylene 15 1.0v01.% 7.6vol. % 

Propylene glycol 

monometyl ether 

15-20 3.0 vol. % 12.0 vol. % 

.\ 'B 

Page S of7 

Firstissue: February 12, 2002 

Revised: 

LR-1672 

Autoignition Temperatur~: More than 150"(; 

EXTINGUISHING MEDIA: 

Foam, COl" Dry Chemical 

FIREFIGHTING INSTRUCTIONS: 

Full protective equipment including self-contained breathing apparat:ls is 

recommended as toxic vapors and hazardous decomposi;ior.ai prod~s:s may 

. evolve. Do not use water for extinguishing. 

6. ACCIDENTAL RELEASE MEASURES 

LAND SPILL: 

Put on chemical resistant 'protectors (gloves, respirator, safe~y goggles, apr;:)", 

etc.). Recollect in container and keep in safety place with the container closed. 

Dispose of waste or clinging matter according to related regulat:ons. 

Remove all ignition sources or heat source, and also take away the other 

flammable. matters. In case of accidental release or spill, ventilate the spill area 

Furnish extinguisher proper for accidental fire. 

Recollect spill or leak with tool ofnon-spark material. 

Absorb the material with vermiculite or other material, such as sand,rags, dry clay, 

and place in a container for disposal. Prevent runoff to ditches leading 

to natural waterways. Dispose ofthe debris in local licensed facility.. 

Wash the surface area with 60-70% ethanol and then with soap and water. 

WATER SPILL: 

Put on chenuca1 resistant protectors (gloves, respirator, safety goggles, apron, 

etc.). Recollect in container and keep in safety place with the container closed. 

Dispose ofwaste or clinging matter according to re1ated regulations. 

Remove all ignition sources or heat source, and also take away the other 

flammable matters. In case ofaccidental release 'or spill, ventilate the spiU area. 

Furnish extinguisher proper for accidental fire. . 

Recollect spill or leak with tool ofnon-spark material. 

Prevent runoff to ditches leading to natufaI waterways. 

Dispose ofthe debris in local licensed facility. 

This material is a water pollutant and should be prevented from contaminating soil 

or from entering sewage and draining systems and bodies ofwater; 

7. HANDLING AND STORAGE 

:{fANDLING: 
Page 4of7 

First issue: February 12, 2002 

Revised: 

LR-1672 

, . . This material is stable at normal conditions, but do not drop. 

Avoid heat, fire, open flame, light, and ignition sources. Incompatible 

with strong oxidizers and reducing agents, acids and bases. Keep product away 

from metals, nitroform an4 oleum. Handle in well ventilated area, 

Close tightly container necessarily during and after use. 

Ground equipment for pre' 'ention of statIc electricity accider.t. 

Use electrical appliance or apparatus of explosIon p:"ooftype. 

Do not bring contaminated protectors of gloves, goggles ad C2.,iS, etc., 

in any place where person stays. 

Wash hands thoroughly after handling and before eating. ddnkirig, or s:noking. 

Keep out of reach of children. 

STORAGE: 

Do not conta:ninate water, food or feed by storage or disposal. 

Keep the product in the original containers. Store in cool, dry, well-ventilat~d. 

low fire risk area away from sunlight. Keep container closed. 

Store only in approved containers, under approved conditions.. 

Avoid pressure build-up in containers. Storage area should not be subject to rapid , , 

temperature changes as such changes may cause increased internal pressure. 

8. EXPOSURE CONTROLS, PERSONAL PROTECTION 

ENGINEERING CONTROLS: 

Use explosion proof type equipment. Install proper exhauster to prevent 

high concentration ofvapor. 

Ground equipment for fluid transfer, pumping and stirring. 

Arrange the neighborhood of.handling place so as to cut o~the influence of heat 

or ignition source. In indoor application, use an automatic application equipment 

or a local exhauster on which operators can avoid exposure to, or other equipment 

devised .for him to avoid exposure to. 

In application in the space of poor ventilation (tank bottom. etc.). 

install ventilation proper for the space. 

PERSONAL PROTECI1VE EQUIPMENT: 

EyeIFace Protection 

Chemical resistant goggles must be provided and worn to prevent'exposure. 

Goggles must provide an impervious barrier to prevent exposure during 

normal and exp~ed duration and conditions ofexposure within the particulardefined work area. 

Spectacle type safety glasses do not provide adequate protection. 

An eyewash fountain shOUld be readily accesSIble. Wear plastic &ce shield 

~o 

'. "'!f~ f}; .', .. .: . 
---,----­

Page 50f7 

First issue: February 12, 2002 

Revised: 

LR-1672 

in addition to safety goggles where there is a danger ofsplashing. 

Skin Protection 

Chemical resistant g~oves must be provided and worn to prevent dermal exposure. 

Gloves must provide an impervious barrier to prevent dermal exposure during 

normal and expected duration and conditions of exposure within the particular 

defined work area. 

Clothing that covers any exposed areas of the a:-ms, Jegs, and torso~ mus~ a:so be, 

provided and worn to prevent dermal exposure. Cbt;-.ing shadd be sek.:t,;;': f.::,;:, 

the duration ofthe anticipated exposure if there is a potential for ski:1 contact. 

Respiratory Protection 


Each person who is reasonably likeJy to be' exposed the product by inhalation 


in the forin ofdust, mist, or smoke shall be provided air purifying respirator 


equipped with combination cartridges approved for paints, lacquers, 


and enamels, including disposable respirators. 


Handle only in the presence of adequate ventilation. 


'General 

'An emergency shower should be readily accessible. 

Discard any contaminated clothing. 

EXPOSURE GUIDELINES: 

Chemical name Composition (wtOlo) Permission level ACGlH-TWA 

Xylene 15 lOOppm lOOppm 

Propylene glycol 

monometyl ethe 

15-20 Not Available lOOppm 

9. PHYSICAL AND CHEMICAL PROPERTIES 


Appearance: 


Color: 


Odor: ' 


Odor Threshold Level: 


Boiling point: 


Physical State: 


Melting Point: , 


Vapor Pressure: 


Vapor Density: 


Solubility in Water: 


Specific Gravity: ' 


Freezin8 Point: 


pH: 


% Volatile: 


Viscosity: (Gardonar) 


Clear 

.	Colorless 

Organic solvent odor 

Not AvailablE~ . 

Not Available 

Liquid 

Not Available 

Not Avail~le 

Heavy than air 

Insoluble 

l.Ol5±O.OlO 

Not Available 

Not Available 

55 -60wt% 

T.......Z at ,25°C 
Page 6of7 

First issue: February 12, 2002 

Revised: 

LR-1672 

10. STABruTY AND REACTIVITY 

CHEMICAL STABILITY: 

Stable under normal conditions. 

CONDITIONS TO AVOID: 

Excessive heat (High temperature), open flames, ig:1;~ion sou;ce, and exposu:-e to 

sunlight or ultraviolet ray, or contacting with oxida:1t or orgar.ic peibxide. 

INCOMPATIBILITY WITH OTHER l\1Ar2:"~.',.LS: 

Free radical initiators and oxidizing ~ents 

HAZARDOUS DECO:MPOSITION PRODUCTS: 

At"elevated temperatures decomposition may occur resulting in the release of 

smoke, carbon dioxide, carbon monoxi,de and other toxic gases. 

HAZARDOUS POLYMERIZATION: 

Hazardous polymerization may occur by heating or by exposure to sunlight or 

ultraviolet ray: 

11. TOXICOLOGICAL INFORMATION 

ACUTE IN;HALATION EFFECTS: Irritating to respiratory system 

EYE EFFECTS: Irritating to eyes 

SKIN EFFECTS: Irritating to skin 

. ACUTE ORAL EFFECTS: Not Available· 

SUBCHRONIC EFFECTS/CARCINOGENICITY: Not Available 

MUTAGENICITY: Not Available 

12. ECOLOGICAL INF'ORMATION 

The wastes ofthis product are toxic. Do not discharge the washing and lakes, 

streams. pons,'estuari~ oceans. or public waters. Do not discharge effluent 

containing this product to sewer systems without proper authority. 

13. DISPOSAL CONSIDERATIONS 

Let authorized industrial waste treaters dispose ofadhesive waste or container waste 

by making semce agreement. Do not dispose ofwaste water after cleaning container, 

equipment, too~ etc. without treatment into the ground and 'drainage ditch. 

With resp~ to disposing ofwaste resulting from effluent water treatment or from 

incineration. comply to regulations or acts relating to waste treatment or contro~ 

or let special treaters undertak.e. 

Bum up adhesive waste little by little using the incinerator ofopen type after 

absorption with diatomaceous earth in the case ofincineration. 
--~-.- . 

Page 7of7 

First issue: February 12, 2002 

Revised: 

LR-1672 

14. TRANSPORT INFORMATION 

Accord to precautions relating to handling and storing 

U.N .1 N.A. Number: Class3-3, No.1688 


Follow all regulations in your country. 


15. REGULATORY INFORL'fATION 

. Follow all regulations in your country. 

16. OTHER INFORJ.\lIATION 

Literature: 

(1) MSDS, Material Data Base (paint); Japan Paint Manufacturers Association 

(2) Hazard information on this product is estimated as a mixture based on that of 

individual raw materials. 

Remarks: 

This information is furnished without warranty, express or implied, except that it is 

accurate to the best knowledge of Mitsubishi Rayon Co., Ltd. It relates only to the 

specific material designated herein,' and. does not relate to use in combina~ion with 

any other material or in any process. Mitsubishi Rayon Co., Ltd. assumes no legal 

responsibility for use of or reliance upon this information. 

I.,' 

1""',},,', • .''. .'. " 
iii 003 lU/15/0~ l~E 11:01 PAX 814 4'7 3747 CAS 

ern Inventory Expert Service 


A dlYi$lon of the Americ:an Chemical SOciety Phone: 8OG-63J.I8114. 61.04-447.3600 (100:.2308) 

fax: 614-+f7-37.047 

E-malk answel'1@cas.orc 

INVEMTORY EXPERT SERVICE REPORT 

XES-ORDER NUMBER: 69472-1 

REGISTRY HUMBER: 460739-39·3 

. CA INDEX NAME 

2-Propenoic acid. 2-methyl-. methyl eSCer. polymer with butyl 2-propenoate. 

ethyl 2-propenoata. ~inc oisI2-metbyl-2-propenoate) 4nd zinc di-2-prope~oat~. 

2.2'-azobisf2-methylbutananitrile)- And 2,2'-a2Obill2·metbyp~opanenitr11e}­

initiated 

Please print the uove CA :Ind." Name on the app:t'OJ:)J:i&te' page of yellX' liMN. 

o If tlds bO'C is checked, CAS ha. made CloJ:l'ectio.c(a} markll4.!.n red to 

you tIS orier. neue make I\\ha 881118 conoation(.) to your PMN before 

submitting it to the EPA. 

, ~t:~ ..... 
2003/03/11 (*) 11:33:03 

GPO (DMF WBr) 

<Graph> 

[mV] [Lo, M] 

400.~~----~----------------r----------------r----. 

100. 

I 

I 

I 

I 

I 

------~---------~ I 

I 

I ______ IJ ___________ _ 

I 

I

, 

40.00 

Mn 2.464 

20.00 30.00 

[ft] 

<The result of Molecular weight calculation> 

[min] [mV] [MOL] 

5,112 

Peak top 28.93 107.858 5,338 Mz 8,739 

Peak end 30.15 47.425 282 MY 5.182 

Mz+l 12,514 

Area [mY sec] 9385.130 MP 5,338 

Area ratio [%] 100.000 Mz/Mw 1.688 

Peak start 24.47 33.571 50.804 Mw 

Hert 88.273 Mw/Mn 2.111 [mV] ('7 5.181.87237 Mz+l/Mw : 2.415 

I , 
2003/03/12 (Wed) 09:15:40 

Data base name: Nakamura. mdb Differential curve conversion factor : 1 

Stored data name yyyy0293 Differencial/Integration formula : Standerd 

Method data name yyyy0293 Sampling pitch [mSec] : 1200 

Channel : Ch. 1 

Peake No : 1 Time [min] : 24.47-26.93-30.15 

Time [min Molecular Different Integration 

24.47 50,804 0 100 

24.49 49,944 0.0007 100 

24.51 49,098 0.0035 100 

24.53 48,265 0.0047 100 

24.55 47,444 0.0049 100 

24.57 46,637 0.0064 100 

24.59 45,842 0.0086 99.99 

24.61 45,060 0.0098 99.99 

24.63 44,289 0.011 99.99 

24.65 43,531 0.013 99.99 

24.67 42, 785 0.0139 99.99 

24.69 42,051 0.0134 99.98 

24. 71 41. 328 0.0152 99.98 

24. 73 40,617 0.0161 99.98 

24. 75 39,917 0.0153 99.97 

24. 77 39,228 0.0143 99.97 

24. 79 38,550 0.0155 99.97 

24.81 37,884 0.0141 99.97 

24.83 37.227 0.0113 99.96 

24.85 36,581 0.0099 99.96 

24.87 35,946 0.0075 99.96 

24.89 35.321 0.0035 99.96 

24.91 34, 706 0.0013 99.96 

24.93 34, 101 0.001 99.96 

24.95 33,505 0.0044 99.96 

24.97 32,920 0.0085 99.96 

24.99 32,343 0.0107 99.96 

25.01 31. 777 0.0167 99.95 

25.03 31. 219 0.023 99.95 

25.05 30,671 0.0287 99.94 

25.07 30, 131 0.0365 99.93 

25.09 29,600 0.045 99.93 

25.11 29,078 0.0535 99.92 

25. 13 28,565 0.0616 99.9 

25. 15 28,060 0.0732 99.89 

25. 17 27,564 0.0858 99.87 

25. 19 27,076 0.0976 99.85 

25.21 26,595 0.1109 99.83 

25.23 26, 123 O. 125 99.81 

25.25 25.659 O. 1404 99. 78 

25.27 25,202 O. 1558 99. 75 

25.29 24, 753 0.1723 99. 72 

25.31 24,312 0.1911 99.68 

25.33 23.877 0.2091 99.64 

25.35 23,451 0.23 99.59 

~" 
25.37 23,031 0.2521 99.54 

25.39 22,618 0.2752 99.49 

25.41 22,213 0.2993 99.43 

25.43 21, 814 0.325 99. 37 

25.45 21,422 0.3514 99.3 

25.47 21,036 0.3792 99.22 

25.49 20,658 0.41 99. 14 

25.51 20,285 0.4434 99.05 

25.53 19,919 0.4748 98.96 

25.55 19,559 0.5097 98.86 

25.57 19.205 0.5471 98. 75 

25.59 18,858 0.5848 98.64 

25.61 18.516 0.6232 98.51 

25.63 18, 180 0.6641 98.38 

25.65 17,850 O. 7071 98.24 

25.67 17.526 O. 7496 98.09 

25.69 17,207 O. 7955 97.93 

25. 71 16,894 0.8439 97. 76 

25. 73 16.586 0.893 97.58 

25. 75 16.283 0.9436 97.4 

25. 77 15,986 0.9969 97.2 

25. 79 15,694 1. 0515 96.99 

25.81 15,407 1. 1082 96. 76 

25.83 15, 125 1. 1664 96.53 

25.85 14.848 1.2266 96.28 

25.87 14,576 1. 2883 96.02 

25.89 14,308 1.3504 95. 75 

25.91 14,045 1. 4148 95.47 

25.93 13. 787 1. 4801 95.17 

25.95 13,533 1. 5465 94.86 

25.97 13,284 1. 6149 94.53 

25.99 13,039 1. 6851 94. 19 

26.01 12. 799 1. 755 93.84 

26.03 12,562 1. 8256 93.47 

26.05 12,330 1. 8991 93.08 

26.07 12, 102 1. 972 92.68 

26.09 11,878 2.0451 92.27 

26. 11 11,659 2. 1208 91. 84 

26. 13 11,442 2. 1972 91. 39 

26. 15 11,230 2.2724 90.93 

26.17 11,022 2.3493 90.45 

26. 19 10,817 2.4268 89.96 

26.21 10.616 2.5021 89.45 

26.23 

26.25 

10,419 

10,225 

2.5783 

2.6554 

88.92 

88.38 

1. 

26.27 10,034 2. 7304 87.82 

26.29 9,847 2.8051 87.25 

26.31 9.664 2.8801 86.66 

26.33 9.483 2.9536 86.06 

26.35 9,306 3.0258 85.44 

26.37 9, 133 3.0974 84.81 

26.39 8,962 3. 1686 84. 16 al 
26.41 8, 794 3.2374 83.49 

26.43 8,630 3.3049 82.81 

26.45 8,468 3.3717 82. 12 

26.47 8,309 3.4368 81. 42 

26.49 8, 153 3.4991 80. 7 

26.51 8,000 3.5594 79.97 

26.53 7,850 3.6183 79.22 

26.55 7, 703 3.6743 78.46 

26.57 7,558 3. 7268 77. 7 

26.59 7,416 3. 7782 76.92 

26.61 7,276 3.8268 76. 13 

26.63 7, 139 3.8699 75.33 

26.65 7,005 3.9129 74.52 

26.67 6,873 3.9545 73. 71 

26.69 6, 744 3.9903 72.88 

26. 71 6,616 4.0244 72.05 

26. 73 6,492 4.0571 71. 21 

26. 75 6,369 4.0858 70.37 

26. 77 6,249 4.1109 69.52 

26. 79 6, 131 4. 1346 68.66 

26.81 6,015 4. 1552 67.8 

26.83 5,901 4.1707 66.93 

26.85 5, 789 4. 1847 66.07 

26.87 5,680 4. 1966 65.2 

26.89 5,572 4.2032 64.32 

26.91 5,467 4.2085 63.45 

26.93 5,363 4.2111 62.58 

26.95 5,262 4.211 61. 7 

26.97 5, 162 4.2066 60.83 

26.99 5,064 4.2008 59.95 

27.01 4,968 4. 1937 59.08 

27.03 4,874 4. 1824 58.21 

27.05 4, 781 4. 1696 57.35 

27.07 4,691 4. 1552 56.48 

27.09 4,601 4. 1387 55.62 

27. 11 4,514 4.1195 54. 76 

27. 13 4,428 4.0987 53.91 

27. 15 4,344 4.0773 53.06 

27.17 4,262 4.0513 52.21 

27. 19 4,181 4.0248 51. 38 

27.21 4,101 3.9982 50.54 

27.23 4,023 3.9683 49. 72 

27.25 3,946 3.9364 48.89 

27.27 3,871 3.9045 48.08 

27.29 3, 798 3.8712 47.27 

27.31 3, 725 3.8348 46.47 

27.33 3.654 3.8001 45.68 

27.35 3,585 3. 7656 44.89 

27.37 3,517 3. 728 44. 12 

27.39 3,450 3.6902 43.35 

27.41 3,384 3.6539 42.58 

27.43 3,320 3.6161 41. 83 

~~ 
27.45 3,256 3.5775 41. 08 

27.47 3,194 3. 5392 40.34 

27.49 3, 133 3.5002 39.61 

27.51 3,074 3.4599 38.89 

27. 53 3,015 3.42 38.17 

27.55 2,958 3.3808 37.47 

27. 57 2,901 3.3406 36. 77 

27.59 2,846 3.3008 36.08 

27.61 2, 792 3.2612 35.4 

27.63 2, 739 3.2223 34. 73 

27. 65 2,686 3. 1825 34.06 

27.67 2,635 3. 1438 33.41 

27.69 2,585 3.1072 32. 76 

27.71 2,536 3.069 32. 12 

27. 73 2,487 3.0306 31. 48 

27. 75 2,440 2.9948 30.86 

27. 77 2,394 2.9589 30.24 

27. 79 2,348 2.922 29.63 

27.81 2,303 2.8864 29.03 

27.83 2,259 2.8529 28. 43 

27.85 2,216 2.8171 27.84 

27.87 2.174 2. 7821 27.26 

27.89 2, 133 2. 7501 26.69 

27.91 2,092 2. 7161 26. 12 

27.93 2,052 2.6823 25. 56 

27.95 2,013 2.6509 25.01 

27.97 1, 975 2.6192 24.47 

27.99 1,937 2.5867 23.93 

28.01 1,901 2.5571 23.39 

28.03 1,865 2.5273 22.87 

28.05 1,829 2.4958 22.35 

28.07 1, 794 2.4662 21. 83 

28.09 1, 760 2.4392 21. 33 

28.11 1, 727 2.4109 20.82 

28. 13 1,694 2.3812 20.33 

28. 15 1,662 2.3533 19.84 

28.17 1, 630 2.3254 19. 36 

28. 19 1,599 2.2958 18.88 

28.21 1,569 2.2675 18.41 

28.23 1,539 2.24 17.94 

28.25 1,510 2.2123 17.48 

28.27 1,482 2. 1845 17.03 

28.29 1,454 2. 1569 16.58 

28.31 1,426 2. 1303 16.14 

28.33 1,399 2. 102 15.71 

28.35 1,373 2.0745 15.28 

28.37 1,347 2.0484 14.85 

28.39 1, 321 2.0216 14.43 

28.41 1,296 1. 9939 14.02 

28.43 1,272 1. 967 13.61 

28.45 1,248 1. 939 13.21 

28.47 1, 224 1. 9099 12.82 

~q 
28.49 1,201 1. 882 12.43 

28.51 1,179 1. 8537 12.05 

28.53 1,156 1. 824 11. 67 

28.55 I, 135 1. 7943 11. 3 

28.57 1,113 1. 7654 10.94 

28.59 1,092 1. 736 10.58 

28.61 1,072 1. 7054 10.23 

28.63 1, 052 1. 6761 9.88 

28.65 1,032 1. 6469 9.55 

28.67 1, 013 1. 6164 9.21 

28.69 994 

1.• o_,! '"\:1'7 8.89 

28.71 975 1. 5578 8.57 

28. 73 957 1. 528 8.26 

28. 75 939 1. 498 7.95 

28. 77 921 1. 4678 7.65 

28. 79 904 1. 4376 7.35 

28.81 887 1. 4052 7.07 

28.83 871 1. 3741 6. 79 

28.85 855 1. 343 6.51 

28.87 839 1.3115 6.24 

28.89 823 1. 2802 5.98 

28.91 808 1. 2494 5. 73 

28.93 793 1. 2184 5.48 

28.95 778 1. 1864 5.24 

28.97 764 1. 155 5.01 

28.99 749 1. 126 4. 78 

29.01 736 1. 0948 4.56 

29.03 722 1. 0645 4.34 

29.05 709 1. 0347 4. 13 

29.07 695 1. 0051 3.93 

29.09 683 0.9744 3. 73 

29.11 670 0.9444 3.54 

29. 13 658 0.9152 3.35 

29. 15 646 0.8852 3. 18 

29.17 634 0.8566 3 

29. 19 622 0.8283 2.84 

29.21 611 O. 7977 2.68 

29.23 599 O. 769 2.52 

29.25 589 O. 7414 2.37 

29.27 578 O. 7128 2.23 

29.29 567 0.6845 2.09 

29.31 557 0.6573 1. 96 

29.33 547 0.6308 1. 84 

29.35 537 0.6041 1. 72 

29.37 527 0.5794 1.6 

29.39 517 0.5551 1. 49 

29.41 508 0.5299 1. 38 1,,[ 

29.43 499 0.5048 1. 28 

29.45 490 0.4805 1. 19 

29.47 481 0.4573 1.1 

29.49 472 0.4337 1. 01 

29.51 464 O. 1098 0.93 

?JJ 


.rr: •...:.'! '. ", , 

29.53 455 

29.55 447 

29.57 439 

29.59 431 

29.61 423 

29.63 416 

29.65 408 

29.67 401 

29.69 394 

29. 71 387 

29. 73 380 

29. 75 373 

29. 77 367 

29. 79 360 

29.81 354 

29.83 347 

29.85 341 

29.87 335 

29.89 329 

29.91 324 

29.93 318 

29.95 312 

29.97 307 

29.99 302 

30.01 296 

30.03 291 

30.05 286 

30.07 281 

30.09 276 

30.11 271 

30. 13 267 

0.3875 0.86 

0.3645 O. 78 

0.3417 O. 72 

0.3206 0.65 

0.3009 0.59 

0.2806 0.54 

0.2615 0.49 

0.2454 0.44 

0.2285 0.4 

0.2114 0.35 

O. 1969 0.32 

O. 1822 0.28 

O. 167 0.25 

O. 154 0.22 

O. 142 O. 19 

O. 1287 0.17 

0.1169 0.14 

0.1071 O. 12 

0.0964 O. 1 

0.0852 0.09 

0.0771 0.07 

0.0688 0.06 

0.0604 0.05 

0.0531 0.04 

0.047 0.03 

0.0409 0.02 

0.0343 0.01 

0.0285 0.01 

0.0227 0 

0.0148 0 

0.0081 0