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# EDA PREMANUFACTURE



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### Fo~ 7l1G1t EPA FORM**771~2S** (Key,5-9S) 

# I**.~.}~** Y

..Public reporting burden for this collection ofinformation is estimated to average 110 hours per response, including time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection ofinformation. Send comments regarding the burden estimate or any other aspect ofthis collection ofinformation, including suggestions for reducing this burden, to Chief, Information Policy Branch, PM-223, U.S. Environmental Protection Agency, 401 M.St.,S.W., Washington, D.C. 20460; and to the Office of Management and Budget, Paperwork Reduction Act (2070-0012), Washington, D.C. 20503. CERTIFICATION I certifY that to the best ofmy knowledge and belief: I. The company named in Part I, section A, subsection I a ofthis notice fonn intends to manufacture or import for a commercial purpose, other than in small quantities solely for research and development, the substance identified in Part I, Section B. 2. All infonnation provided in this notice is complete and truthful as ofthe date ofsubmission. 3. I 

### am SUbmitting with this notice all test data in my possession orcontrol and a description ofa\1 other data known to or reasonably ascertainable by me as required by 

### § 720.50 ofthe Premanufacture Notification Rule. Additional Certification Statements: Ifyou are submitting a PMN, Intennediate PMN, Consolidated PMN, orSNUN, check the following user fee certification statement that applies:**~** The Company named in Part I, Section A has remitted the fee 0[$2500 specified in 40 CFR700.45 (b), or 

# o The Company named in Part I, Section Ahas remitted the fee of$1000 for an Intennediate PMN (defined @40CFR7oo.43) in accordance with 40CFR700A5.(b), or 

# o The Company named in Part I, Section A is a small business concern under 40CFR700.43 and has remitted a fee of$1000 in accordance with 40CFR700A5(b) Ifyou are submitting a low volume exemption (LVE) application in accordance with 40CFR723.50(c)( 1) ora Low release and low exposure exemption (LoREX) application in accordance with 4OCFR723.50(c)(2), check the following certification statements: 

# o The manufacturer submitting this notice intends to manufacturer or import the new chemical substance for commercial purposes, other than in sman quantities solely for research and development, under the tenns of40CFR723.50
. The manufacture is familiar with the tenns ofthis section and wi\l comply with those tenns; and The new chemical substance for which the notice is submitted meets all applicable exemption conditions. 

# o Ifthis application is for an LVE in accordance with 40CFR723 .50(c)(1). the manufacturer intends to commence manufacture ofthe exempted substance for commercial purposes within 1year ofthe date ofthe expiration ofthe 30-day review period.
The accuracy ofthe statements you make in this notice should reflect your best prediction ofthe anticipated facts regarding the chemical substance described herein. Any knowing and wilful misinterpretation is subject to criminal penalty pursuant to 

### 18 USC 1001. Confidential Signature and title ofAuthorized Official (Original Signature Required) Date I**q""~''',1** 11"<-V\if"{I.e

### r ' .Ad
.....**~.}tr-t\.t.~il** 

# :3/30/D3**C:::;Z~.~** Signature ofagent (ifapplicable)**~** Date 

# 1//./ tr'J

# ~~

FORM EPA 7710-25 (Rev.5-95) 

### Page 2

## Part I - GENERAL INFORMATION Section A - SUBMITTER IDENTIFICATION
1a. Person Submitting Notice (in U.S.)

b. Agent (if applicable)

c. Ifyou are

2. Technical Contact (in U.S.) Name of official Ronald S Ph.D. Company Environ International Mailing address (number and street) 4350 North Fairfax Drive Suite 300 State, ZIP Code VA 22203-1619

Company Mailing address (number and street) City, State, ZIP Code Name of official Ronald Ph.D. Company Environ International Mailing address (number and street) 4350 North Fairfax Drive Suite 300 City, State, ZIP Code Arlington, VA 22203-1619 3. 

### Ifyou have had a prenotice communication (PC) concerning this notice and EPA assign a PC Number to the enter the number. 4. 

### Ifyou previously submitted an exemption application for the chemical substance covered by this notice, enter the exemption number assigned by EPA. Ifyou previously submitted a PMN for this substance enter the PMN number EPA
. e. withdrawn or' 5. Ifyou have submitted a notice ofBona fide intent to manufacture or import for the chemical substance covered this enter the notice number EPA. () Manufacture 6. Type ofNotice Mark (X) 1. Only 

### ( ) Binding Option Mark President

Senior Science

Telephone Position Senior Science

Telephone

Mark (X) ifnone

Mark (X)

. Ifnone (X) 

### Import Only 2 3. 

### (X) 

### Binding Option Mark (X) (X)

(X) 

### ( ) Both

FORM EPA 7710-25 (Rev.5-95) 

### Page 3

## Part I - GENERAL INFORMATION - Continued Section B - CHEMICAL IDENTITY You must provide a currently correct Chemical Abstracts (CA) name of the substance based on the ninth Collective Index (9CI) ofCA INFORMATION: nomenclature Complete either item 1 (Class 1 or 2 substances) or 2 (Polymers) as appropriate. Complete aU otheritems. Ifanother person will submit chemical identity information for you, mark (x) the box at the right. Identify the name, company and address ofthat person. [ ] Confidential I. Class 1 or 2 chemical substances (for definitions ofclass 1 and class 2 substances, see the Instructions Manual)

a. Class ofsubstance Mark (X) 1 [ ] Class I or 2 [ ] Class 2 b. Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for similar substance. For Class 1 substance a CA Index Name must be provided. For Class 2 substances either a CA Index Name or CA Preferred Name mustbe provided, whichever is appropriate based on CA 9CI nomenclature rules and conventions. ).

c. Please identify which method you used to develop or obtain the specified chemical identity information reported in this notice: (check one). [ 	 ] Method 1 (CAS Inventory Expert Service - a copy ofthe Identification [] Method 2 (Other Source) report obtained from the CAS Inventory Expert Service must be



### CAS #

e. For a class 1substance, provide a complete and correct chemical structure diagram. For a class 2 substance

- (I) List the immediate precursor substances with their respective CAS Registry Numbers. (2) Describe the nature ofreaction or process. (3) Indicate the range ofcomposition and the typical composition (where appropriate). (4) Provide a correct representative or partial chemical structure diagram, as complete as can be known, ifone can be reasonably ascertained.



# o Mark this box ifyou attach a continuation sheet.

FORM EPA 7710-25 (Rev.5-95) 

### Page 4

, ,"!""**t}~,** ' .


# .

## Part I - GENERAL INFORMATION

- Continued Q. B-C'HF.MrC'AT lUElYlTlY l.l"iJ:4tlllMA.TION Continued 2. Polymers (For a definition ofpolymer, see the Instructions Manual.)

# ~~~f~1 a. Indicate the number-average weight ofthe lowest molecular weight composition ofthe polymer you intend to manufacture. Indicate maximum weight percent oflow molecular weight species (not including residual monomers, reactants, or solvents) below 500 and below 1,000 absolute molecular weight ofthat composition. Describe the method ofmeasurement or the basis for your estimates: 

### ope ( X) Other ( ): (Specify ) i) Lowest number molecular weight: 

### 2454 ii) Maximum weight % below 500 molecular weight: 

### 1.28% iii) Maximum weight % below 1000 molecular weight: 

### 8.89 % 

# D Mark (X) this box ifyou attach a continuation sheet. b. You must make separate confidentiality claims for monomer or other reactant identity, composition information, and residual information. Mark (X) the "Confidential" box next to any item you claim as confidential. (1) Provide the specific chemical name and CAS Registry Number (ifa number exists) ofeach monomer or otherreactant used in the manufacture ofthe polymer. (2) Mark (X) this column ifentry in column (I) is confidential. (3) Indicate the typical weight percent ofeach monomer or otherreactant in the polymer. (4) Mark (X) the identity column ifyou want a monomer or otherreactant used at two weight percent or less to be listed as part ofthe polymer description on the TSCA Chemical Substance Inventory. (5) Mark (X) this column ifentries in column (3) and (4) are confidential. (6) Indicate the maximum weight percent ofeach monomer or other reactant that may be present as a residual in the polymer as manufactured for commercial purposes. (7) Mark (X) this column ifentry in column (6) is confidential. Monomers or other reactant and CAS Registry Number Confi- Typical Identity Confi- Maximum Confi­ (I) dential composition Mark (x) dential Residual dential (2) (3) (4) (5) (6) (7) X X X X X X X X X X X X X X X X X X X X X X X X X X 

# :x X X X X 

# :x X 

# D Mark (X) this box ifyou attach a continuation sheet. c. Please identify which method you used to develop or obtain the specified chemical identity information reported in this notice. (X) Method I (CAS Inventory Expert Service a copy ofthe Identification report obtained ( ) Method 2 (Other Source) from the CAS Inventory Expert Service must be submitted as an attachment to this notice) 

### See Page 24 d. The currently correct Chemical Abstracts (CA) name for thepolymer that IS with TSCA Inventory listings for similarpolymers. 

### 2-Propenoic acid, 2-methyl-, methyl ester, polymer with butyl-2-propenoate, ethyl-2-propenoate, zinc bis (2-methyl-2-propenoate) and zinc di-2-propenoate, 2,2'-azobis[2-methylbutanenitrile] -and 2,2'- azobis r2-methy!' itfile] initiated CAS No. 460739-39-3 e. Provide a correct representative or partial chemical structure diagram, as complete as can be known, ifone can be reasonably be ascertained. 

### Please see page 16

# ~ Mark (X) this box ifyou attach a continuation sheet

FORM EPA 7710-25 (Rev.5-95) 

### Page 5

## Part I - GENERAL INFORMATION - Continued
3. Impurities (a) Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial purposes. Provide the CAS Registry Number ifavailable. Ifthere are unidentified impurities, enter "unidentified." (b) Estimate the maximum weight % ofeach impurity. Ifthere are unidentified impurities, estimate their total weight %. Maximum Impurity and CAS Registry Number percent dential (a)



### [ ] Mark (X) this box ifyou attach a continuation sheet Enter any Confidential 

### None [ ] Mark (X) this box ifyou attach a continuation sheet 5. Trade identification

- List trade names for the new chemical substance identified in subsection 1 or 2. 

### LR-1672
attach a continuation sheet 6. Generic chemical name - Ifyou claim chemical identity as confidential, you must provide a generic chemical name for your substance that reveals the specific chemical identity ofthe new chemical substance to the maximum extent possible. Refer to the TSCA chemical Substance Inventory, 1985 edition, Appendix B for guidance on developing generic names.

CAS

attach a continuation sheet

FORM EPA 7710-25 (Rev.5-95) 

### Page 6**m~m1Jlta(~ture, pCl.l!x;~l:jlIlg,**  use, or disposal ofthe new chemical

## PartI - GENERAL INFORMATION

- Continued Section C - PRODUCTION, Il\1PORT, AND USE INFORMATION: Mark (X) the "Confidential" box next to any item you claim as confidential. 1. Production volume

- Estimate the maximumproduction volume during the first 12 months ofproduction. Also estimate the maximum production volume for any consecutive 12-month period during the first three yeas ofproduction. Estimates should be on 100% new chemical substance basis. For aLow Volume Exemption application. ijyou choose to haveyournotice reviewedat a lowerproduction volume than 10.000kg/yr. specifYthe volume andmark (x) in the binding box. 

### If granted. you are bound to this volume. Maximum first 12-month production (kg/yr) Maximum 12-monthproduction (kglyr) Confidential Binding

(100010 new chemical substance basis) (100010 new chemical substance basis) Option Mark (xl 

### 3,300 kg/year 4,800 kg/year 

## I 2. Use Information

- You must make separate confidentiality claims for the description ofhe category ofuse, the percent ofproduction volume devoted to each category, the formulation ofthe new substance, and other use information. Mark (X) the "Confidential" Box next to any item you claim as confidential. a. (I) Describe each intended category ofuse ofthe new chemical substance by function and application.

(2) Mark (X) this colunm ifentry in colunm (1) is confidential business information (CBI). (3) Indicate your willingness to have the information provided in colunm (I) binding. (4) Estimate the percent oftOlal production for the first three years devoted to each category ofuse. (5) Mark (X) this colunm ifentry in colunm (4) is confidential business information (CBI). (6) Estimate the percent ofthe new substance as formulated in mixtures, suspensions, emulsions, solutions, or gels as manufactured for commercial purposes at sites under your control associated with each category ofuse. (7) Mark (X) this colunm ifentry in colunm (6) is confidential business information (CBI) (8) Indicate % ofproduct volume expected for the listed "use" sectors. Mark more than one box ifappropriate. Mark (X) to indicate your willingness to have the use type provided in (8) binding. (9) Mark (X) this column ifentr:v(ies) incolumn (8) is (are) confidential business information (CBI). Category ofUse (I) CBI Binding Produc- CBI 0/. in Form- CBl % ofsubstance expected per use (8) CBI (by function and application (i.e. a (2) Option tion% (5) ulation (7) Site- Consu Indus Com- Binding (9) dispersive dye for finishing polyester Mark (x) (4) (6) limited mer trial mercial Option fibers) (3) 

### Binderpolymer in paints 100* 10-13% 

### 100% % % % 

# H % %
I % % Ifyou have identified a "consumer use", please provide on a detailed description ofthe use(s) ofthis chemical substance in consumer products. In addition include estimates ofthe concentration ofthe new chemical substance as expected in consumer products and describe the chemical reactions by which this substance loses its identity in the consumerproduct. [ ] Mark (X) this box ifyou attach a continuation sheet. b. Generic use Ifyou claim any category ofuse description in subsection 2a as confidential, enter a generic description ofthat description category. Readthe Instructions Manual for examples ofgeneric use descriptions.

[ ] Mark (X) this box 

### ifyou attach a continuation sheet 3. Hazard Information

­ Include in the notice acopy ofreasonable facsimile ofany hazard warning statement, label, material safety data sheet, or Binding other information which will be provided to any person who is reasonably likely to be exposed to this substance regarding protective equipment or practices for the safe handling, transport, use ordisposal ofthe new substance. List in part III hazard information you include. Option Mark (x) [ X 

## J Mark (X) this box ifyou attach hazard infonnation MSDS is provided

FORM EPA 7710-25 (Rev.5-95) 

### Page 7

## Part II

­ HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE Complete section Afor each type ofmanufacture, processing, or use operation involving the new chemical substance at industrial sites you control. Importers do not have to complete this section for operations outside the U.S.; however, you may still have reporting requirements ifthere are further industrial ofthe site at which the "''''r<ll',nn will occur. Confid ential Name

Site address City, County, State, ZIP Code
Ifthe same operation occur atmore one enter the on a #Ofsites sheet, and ifany ofthe sites have significantly different production rates oroperations, include all the information requested in this section for those sites as attachments.

[ ) Mark (X) ifyou attach a continuation sheet

Hourslbatch Batcheslyear
Hourslbatch Batches/year

(I)Diagram the majorunit operation steps and chemical conversions. Include interim storage and transport containers (specifY e.g. 5 gallon pails, 55 gallon drum, rail car, tank truck, etc.). (2) Provide the identity, the approximate weight (by kg/day orkglbatch on an 100% new chemical substance basis), and entry point ofall starting materials and feedstocks (including reactants, solvents, and catalysts, etc), and ofall products, recycle streams, and wastes. Include cleaning chemicals (note frequency ifnot used daily orper batch.). (3) Identify by number the points ofrelease, including small or intermittent releases, to the environment ofthe new chemical substance.



### No production, processing or use ofthe PMN substance occurs in the U.S. 

### at sites controlled by the submitter.



# o Mark (X) this box if attach a continuation sheet

FORM EPA 7710-25 (Rev.5-95) Page 8

### Part II - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE -Continued Section A - 

### INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER - Continued 2. OccupationalExposure'You must make separate confidentiality claims for the description ofworker activity, physical form ofthe new chemical substance, number ofworkers exposed, and duration ofactivity. Mark (X) the "Confidential" box next to any item you claim as confidentiaL (}) Describe the activities (e.g. bag dumping. tote filing. unloading drums. sampling, cleaning, etc) in which workers may be exposed to the

substance. (2) Mark (X) this column ifentry in column (}) is confidential business information (CBI>. (3) Describe any protective equipment and engineeringcontrols used to protect workers. (4) and (6) Indicate your willingness to have the information provided in column (3) or (li) binding. (5) Indicate the physical form(s) ofthe new chemical substance (e.g. solid: crystal, granule, powder, or dust) and % new chemical substance (if part ofa mixture) at the time ofexposure. (7) Mark 00 this column ifentry in column (li) is confidential business information (CBI). (8) Estimate the maximwn nwnber ofworkers involved in each activity for all sites combined. (9) Mark 00 this column ifentry in column (5) is confidential business information (CBO. (10) and (11)**'~stimate** the maximwn duration ofthe activity for any worker in hours per day and days per year. (12) Mark 00 this column ifentry incolumn (5) is confidential business infurmation (CBI). Worker activity (e.g. bag dwnping, filling drwns)

( I) CBI (2) Protective Equipment !Engineering Controls (3) Binding Option Mark (x)

(4) Physical formes)

(5) Binding Option MlIrk(x) (6) CBI (7) # of Workers Exposed

(8) CBI (9) MaximwnDu ration CBI (12) HrsIday (1/n Days/yr ()n

[ ] Mark (X) this box ifyou attach a continuation sheet 3. Environmental Release and disposal-You must make separate confidentiality claims for the release number and the amount ofthe new chemical substance released and otherrelease and disposal information. Mark (X) the "Confidential" box next to each item you claim as confidentiaL (I) Enter the number ofeach release point identified in the process description, Part II, section A, subsection Id(3). (2) Estimate the amount ofthe new substancereleased (a) directly to the environment or (b) into control technology (in kg/day or kg/batch). (3) Mark (X) this column ifentries in columns (l) and (2) are confidential business information (CBI) (4) Identify the media ofreIease i.e. stack air, fugitive air(optional-see Instruction Manual), surface water, on-site or off-site land or incineration, POTW, or other (please specify) to which the new substance will be released from that release point. (5) a. Describe control technology, ifany, and control efficiency that will be used to limit the release ofthe newsubstance to the environment. For releases disposed ofon land, characterize the disposal method and state whether it is approved for disposal ofRCRA hazardous waste. On a continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subject to secondary or tertiary on-site treatment. b. Estimate the amount released to the environment after control technology (in kg/day). (6) Mark (X) this column ifentries in columns (4) and (5) are confidential business information (CBI). (7) Identify the destination(s) ofreleases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct

dischargers or NPDES numbers ofthe POTW (Publicly Owned TreatmentWorks). Mark (X) ifthe POTW name orNPDES# is confidential business information (CBn. Release Nwnber

(I) Amount ofnew substance released CBI (3) Media of release

(4) Control technology and efficiency CBI (6) (2a) (2b) (Sa) Binding Mark (x) (5b)

(7) Mark (Xl the ( 1 POTW provide name{s) below destination(s) of releases to water CBI



### - ( ) Navigable ( )Other

- specify waterway Provide NPDES# CBr 

# D Mark (Xl this box ifyou attach a continuation sheet

FORM EPA 7710-25 (Rev.5-95) 

### Page 9

### Part

## n - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE

- Continued Section B - INDUSTRIAL SITES CONTROLLED BY OTHERS Complete section B for typical processing or use operations involving the new chemical substance at sites you do notcontrol. Importers do not have to complete this section for operations outside the U.S.; however, you must report any processing or use activities after import. See the Instructions Manual. Complete a separate section B for each type ofprocessing, or use operation involving the new chemical substance. Ifthe same operation is performed at more than one site describe the typical operation common to these sites. IdentiiY additional sites on a continuation sheet. 1. Operation Description To claim information in this section as confidential, circle or bracket the specific information that you claim as confidential. (I) Diagram the major unit operation steps and chemical conversions, including interim storage and transport containers (specify e.g. 5-gallon pails, 55-gallon drum, rail car, tank truck, etc.). On the diagram, identify by letter and briefly descnbe each worker activity. (2) Provide the identity, the approximate weight (by kg/day or kglbatch on a 100% new chemical substance basis), and entry point ofall feedstocks (including reactants, solvents, and catalysts, etc), and ofall products, recycle streams, and wastes. Include cleaning chemicals (note frequency ifnot used daily or perbatch.). (3) Identify by numberthepoints ofrelease, including small orintermittentreleases, to the environment ofthe new chemical substance. (4) Please enterthe # ofsites (remember to identify the locations ofthese sites on acontinuation sheet):


### # ofSites


### Please see page 14,15

[X] Mark (X) this box ifyou attach a continuation sheet 2. Worker ExposurelEnvironmental Release (I) From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity described. (2) Estimate the number ofworkers exposed for all sites combined. (4) Estimate the typical duration ofexposure per worker in (a) hours per day and (b) days per year. (6) Describephysical form ofexposure and %new chemical substance (ifin mixture), and any protective equipment and engineering controls used to protect workers. (7) Estimate the percent ofthe new substance as formulated when packaged orused as a final product. (9) From the process diagram above, enter the number ofeach release point. Complete 9-13 for each release point identified. (10) Estimate the amount ofthe new substance released (a) directly to the environment or (b) into control technology to the environment (in kg/day or kglbatch). (12) Describe media ofrelease i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-site land or incineration, POWT, orother (specify) and control technology, ifany, that will be used to limit the release ofthe new substance to the environment. (14) Identify by-products, which may result from the operation. (3 , (5),(8),(11), (13) and (15) Mark(X this column ifanj' oftheproceedillg entries are confidential business information CBn. Letter #of CBI Duration of 

## cm Protective Equip.! %in CBI Release AmOWlt ofNew CBI Media of CBI of Workers (3) Exposure (5) Engineering Controls! Form­ (8) Number Substance (II) Release & (13) Act- Exposed Physical Form and % ulation (9) Released Control ivity (2) (4a) I (4b) new substance (7) ! (lOa) (lOb) Technology (I) , hours! daysl kg/day • (12) ! day year J 1 2 ! 0.5 40-60 Helmet, goggles, 50 1


## .... 2 1 0.5 40-60 glove, mask 12.5 0.1 ::: !--­ (') 

### 3 1 1.0 40-60 1 0.1 I S· 

## - n 4 2 2-4 40-60 Helmet, goggles, 12.5 1 

### iil 

# - :to 0 ;..­ 5 4 4-8 60-80 glove, mask 12.5 10 20 ::l 6 2 

### J 0.5 60-80 protective suit 0.1 0.1 0.1 !--­
(l4)-By-products: (15) 

### [ 1 Mark (X) this box ifyou attach a continuation sheet Please see page 14,15



# ...
FORM EPA 7710-25 (Rev.5-95) Page 10

## OPTIONAL POLLUTION PREVENTION INFORMATION To claim infonnation in this section as confidential circle or bracket the specific infonnation that you claim as confidential. 

### In this section you mayprovide information notreported elsewhere in this form regarding yourefforts to reduce orminimise potential risks associated with activities surrounding manufacturing, processing, use and disposal ofthe PMN substance. Please include new information pertinent to pollution prevention, including source reduction, recycling activities and saferprocesses orproducts available due to the new chemical substance. Source reduction includes the reduction in the amount ortoxicity ofchemical wastes by technological modification, process and procedure modification, product reformulation, raw materials substitution, and 

### lor inventory control. Recycling refers to the reclamation ofuseful chemical components :from wastes that would otherwisebetreated orreleased as airemissions orwater discharges, or land disposal. Descriptions ofpollution prevention, source reduction and recycling should emphasizepotential risk reduction subsequentto compliance with existingregulatory requirements and canbe either quanti**t~,ti** vC 0

..... 

### ualitative. The EPA is interested in this informationto assess overall net reductions intoxicity orenvironmental releases and exposures, not the shifting ofrisks to other environmental media ornon-environmental areas (e.g., occupational orconsumerexposure). In addition, information on the relative cost orperformance characteristics ofthe PMN substance topotential alternatives may be provided. All information provided in this section will be taken into consideration during the review ofthis substance. See the revised Instructions Manual that includes a Pollution Prevention manual for guidance and examples. Describe the expected net benefits, such as (1) an overall reduction in risk to human health orthe environment; (2) a reduction in the volume manufactured; (3) a reduction in the generation ofwaste materials through recycling, source reduction or other means; (4) a reduction in potential toxicity or human exposure and/orenvironmental release; (5) an increase in productperfonnance, a decrease in the cost ofproduction and/or improved operation efficiency ofthe new chemical substance in comparison to existing chemical substances used in similar applications; or (6) the extent to which the new chemical substance may be substitute for an existing substance that poses a greater overall risk to human health orthe environment.

[ ] Mark (X) this box ifyou attach a continuation sheet

FORM EPA 7710·25 (Rev.5-95) 

### Page 11

## Part III -LIST OF ATTACHMENTS Attach continuation sheets for sections ofthe fonn and test data and other data (including physicaVchemical properties and structure/activity infonnation), and optional infonnation after this page. Clearly identifythe attachment and the section ofthe fonn to which it relates, ifappropriate. Number consecutively the pages ofthe attachments. In the column below, enter the inclusive page numbers ofeach attachment. Mark (x)the "Confidential"box next to any attachment name you claim as confidential. Read the Instructions Manual for guidance on howto claim any infonnation in an attachment as confidential. You must include with the sanitized copy ofthe notice fonn a sanitized version ofany attachment in which YOU claim infonnation as confidential. Attachment name Attachment page nwnber(s) Contidential 

### Physical and chemical properties worksheet Continuation Page: Part II. Section 

### B. 1. Continuation Page 5: Part 

### 1. Section 

### B. 2. c 

### Material Safety Data Sheet (MSDS) 13 14

- 15 16 17

- 23 CAS Inventory Expert Service Report 24 GPC Measurement for Polymers 25

- 31



# 0 Mark (X) this box ifyou attach a continuation sheet. Enter the attachment name and number FORM EPA 7710-25 (Rev.5-95) 

### Page 12PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET To assistEPA's review ofphysical and chemical properties data, please complete the following worksheet for datayou provided andincludeit in the notice. IdentifY the property measured, the page ofthe notice on which the property appears, the value ofthe property, the units in which the property is measured (as necessary), and whether or not the property is claimed as confidential. The physical state ofthe neat substance should be provided. These measured properties should be for the neat (100%) chemical substance. Properties that are measured for mixtures or formulations should be noted (% PMN substance in -). You are not required to submit this worksheet; however, EPA strongly recommends that you do so, as it will simplifY review and ensure that confidential information is properly protected. You should submit this worksheet as a supplement to your submission oftest data. This worksheet is not a substitute for submission oftest data. Property (a) Mark (x) if provided Page number

(b) Value (c) Measured or Estimated (MorE) Confident ial Mark

(x) (d) Physical state ofneat substance 

### X 21 Liquid Vapor pressure 

### @temperature 

## °c Density / relative density 

### X 21 1.015 ± 0.010 Solubility 

### in solvent 

### @ temperature 

### "C Solubility in water 

### @temperature 

### "C Melting temperature Boiling/sublimation temperature

Torr pressure Spectra (lR, UV-vis, NMR) Dissociation constant Particle size distribution Octanol/waterpartition coefficient Henry's Law constant Volatilization from water Volatilization from soil pH 

### @ concentration Flammability Explodability Adsorption/coefficient Other Specify Molec, WT, Distrib, Analysis 

### X 25-31 

### [ J Mark 

### 00 this box 

### ifyou attach a continuation sheet. Enter the attachment name and number

FORM EPA 7710-25 (Rev.5-95) Page 13

### Continuation Page: Part II. Section B. 1.


## INDUSTRIAL SITES CONTROLLED BY OTHERS
> < Supply I.Dumping materials Mixer



# + 2.Sampling Packaging to cans 3. Cleaning

< > 

### Supply


### 4.Charging Spray gun



# + 5.Spraying Coating object 6.Cleaning


### <AT FORMULATION> The product, LR-l672 resin, is mixed with other materials to form paint. Typical composition ofthe paint is as follows. LR-1672 resin: 28% Pigment: 55% Additives: 5% Solvents: 12% The materials are introduced to a tankbyelectric pumps automatically. The size oftank wouldbe typically about 1000-4000 Liters. The tank is closed after materials are introduced and ithas a standard design to minimize the release ofthe.ulatile solvents to the working environment, but 100% containment cannot be achieved. The Page 14

## Continuation Page: PartII. Section B. 1. 

## (cont.d) operation site is usually equipped with local ventilation system. The mixing is automatically processed and completes in several hours at the longest and this may take place three to six times/month. The formulated paint is charged to 5-gallon cans ordrums. This process can be handled and monitored by one or two workers who wear gloves and a mask designed with a cartridge that provides protection from inhalation of chemical solvents. Duringthis process, the formulated paints maybe sampled andchecked, butthe direct contactto the substanceby worker is unlikely and dermal exposure is obvious because ofthepaintpigments. A small amount ofthis product, LR-:\) 

### 12 resin, is left in the drums after use. The amount is assumed less than 0.2% relative to the total volume astheproductis a xylene solution which is not viscous and typicallyflows easily from the container(s). The drums are not washed at the site, but passed to a dedicated company who recycles or disposes ofthe industrial wastes. The application equipment is washed with organic solvents after use and the resulting solvents, which would be about 10 to 20L, are passed to a dedicated company for recycling ordisposal ofthe industrial wastes. The use ofsolvents may contain LR-1672 resin at less than 1 

### %. Whenthe amount ofthe used solvents is large, the recycling ofthe solvents maybe attempted and the residues are incinerated. When the amount ofused solvents is small, it would be usually incinerated. Water is not used to wash the equipment or holding tank so releases to water would beunexpected. <AT USE> Thepaintproduct is delivered to the site ofuse in 5 gallons metal cans ordrums. The mixed paint is charged to spray guns and sprayed on the ship hull orother structures by two to four workers, who wear whole body suit, goggle and mask designed with an absorbent for chemical solvents. Theprocess maytakeplace in a dock where a scatterproofnetis locatedto contain area contamination withpaint. Theprocess maytake 4 to 8 hours depending on the size ofship. Afteruse, the equipment is washed with paint remover or organic solvents
.. Theresulting solvents, which would be about 15 to 30Liters, are passed to a dedicated company who recycles ordisposes ofthe industrial wastes. The used solvents may contain LR-1672 resin at less than 1%. When the amount ofthe used solvents is large, the recycling ofthe solvents maybe attempted for economical reasons and the residues are incinerated. When the amount ofused solvents is small, it would be usually incinerated. Water is not used to wash the mixerand no releases to water wouldbe expected in the typical process ofmanufacture used.

Page 15

## I-I 1-2 Continuation Page 5: Part I. 

### Section B. 2. c.



## Chemical Structure diagram
CH3



## I C-CH2 

## I C=O 

## I 

## 0

I CH3


## a H 

## I C-CH2



## I C=O 

## I 

## 0

I CH2



## I CH3 

### b 

## H 

## I C-CH2



## I C=O 

## I 

## 0

I (CH2 

# h I CH3


## c CH3 

# J+-CH3 

## I I 2

# ·l9-CH2 y-CH C=O



## I 

## 0­ I I 

## 2+ Zn C=O 

## I 

## 0­ d 

## H 

## I C-CH2



## I C=O 

## I 

## 0­ I I 

## 2+ Zn H 

## I C-CH2



## I C=O 

## I 

## 0­ e e 1-1 = 

### Free-radical initiator fragment 1 1-2 

## =Free-radical initiator fragment 2

Page 16

### Page:1of7 

### Firstissue: February 12, 2002 

### Revised:
. LR'1672


## MATERIAL SAFETY DATA SHEET (MSDS)
1. CHEMICALPRODUCTAND COMPANYIDENTlFICATION 

### ProductName: DIANALLR-1672 General Use.: Acrylic Resin 

### for coatings MANUFACTURER



### . CompanyName: Mitsubishi Rayon Co., Ltd.

Address: Chemicals &

### Plastic Technology Administration Office; 6-41, Konan, 1-chomeMinato-ku, Tokyo 108-8506 JAPAN TelephoneNo. +81-03-5495-3103 FaxNo.
. +81-03-5495-3215 Specialty Chemicals 

### Department I; 

### 8-30, Tenmabashi, 1-chomeKita-ku, Osaka 530-6040 JAPAN 

### TelephoneNo. +81-06-6881-6461 Fax No. +81-06-6881-6463 EMERGENCY TELEPHONENUMBER



### Mitsubishi Rayon Co.• Ltd. Telephone No. +81-03-5495-3103 (Chemicals 

### &. Plastic Technology Administration Office) 9:30

# am-6:00 pmJapan Time M-F 

# z. COMPOSITION, INFORMATION ONINGREDIENTS 

### No. Components Name CAS Registry 

### #



### 1) Acrylic PolymerA 2) Xylene 3) , Ethyl benzene 

### 4) Propylene glycol monomethyl ether 

### 45-50 15 21 

### 15-20 Not registered 1330-20-7 100-41-4 107-98-2


### 3. HAZARDS IDEN'TlFICATION EMERGENCYOVERVIEW: 

### COmbustible liquid, May 

## cause explosion in 

### high concentration ofits 

### vapor. Substance ofacute toxicity. May d8mage health. POTENTIALHEALTHEFFECI'S:



### PRIMARYROUTE OFEXPOSURE INHALATION: Irritating to respiratory system**I~** 

### EYE CONTACT: Irritating to eyes 

# 11

### Page2of7 

### Firstissue: February 12, 2002 Revised: 

### LR'1672 

### SKIN CONTACT: Irritating to skin INGESTION: Toxic CHRONIC TOXICITY/CARCINOGENICITY Not Available MEDICAL CONDmONS AGGRAVATED BYEXPOSURE: Not Available
4. FlRSTAID MEASURES INHALATION: 

### For such inhalation, remove to fresh air 

### and rest with keeping warm. If

### not breathing. give artificial respiration. Ifthereis breathing difficulty,
. give oxygen. Get 

### immediate medical attention, showing MSDS. Ifdizziness, nausea, headache or disorder occurs for· inhalation ofvapor or gas, remove to fresh air, keep quiet and get immediate medical attention, showing MSDS. EYE**~ONTACT:** 

### Remove contact lenses where applicable, flush with clean water for at least 15 minutes. Wash sufficiently the back ofthe eyelids. too.

. Getimmediate medical attention, showing MSDS. SKIN CONTACT: 

### Immediately flood with waterthe area ofthebody without waiting to remove the contaminated clothing. Remove clothing underthe water stream. Wash with plenty ofwater, then with soap and water. Discard contaminated clothing and shoes. Get medical attention ifnecessary. INGESTION: 

### Do not induce vomiting. Dilute by giving milk 

### orwater. Nothing by mouth ifunconscious. Get immediate medical attention, showing MSDS. NOTE TO PHYSICIAN: 

### Treatment may 

### vary with condition ofvictim and specifics ofincident.
5. FIREFIGHTING MEASURES FLAMMABLE PROPERTIES 

### Flash point: 

### 23OC(SETA:) Xylene Flammable (Bxplosive) Limit: Chemical name Composition**(~Io)** 

### Lower Upper Xylene 15 1.0v01.% 

### 7.6vol. % 

### Propylene glycol monometyl ether 

### 15-20 3.0 vol. 

### % 12.0 vol. 

### % 

# .\ 'B

### Page Sof7 

### Firstissue: February 12, 2002 Revised: 

### LR-1672 

### Autoignition**Temperatur~:** 

### More than 

### 150"(; EXTINGUISHING MEDIA: Foam, COl" Dry Chemical
FIREFIGHTING INSTRUCTIONS: 

### Full protective equipment including self-contained breathing apparat:ls is recommended as toxic vapors and hazardous decomposi;ior.ai**prod~s:s** 

### may

. evolve. Do not use water for extinguishing.
6. ACCIDENTAL RELEASE MEASURES LAND SPILL: 

### Put on chemical resistant'protectors (gloves, respirator,**safe~y** 

### goggles, apr;:)", etc.). Recollect in container and keep in safety place with the container closed. Dispose ofwaste or clinging matter according to related regulat:ons. Remove all ignition sources or heat source, and also take away the other flammable.matters. In case ofaccidental release or spill, ventilate the spill area Furnish extinguisher proper for accidental fire. Recollect spill orleak with tool ofnon-spark material. Absorb the material with vermiculite or other material, such as sand,rags, dry clay, and place in a containerfor disposal. Prevent runoffto ditches leading to natural waterways. Dispose ofthe debris in local licensed facility
.. Wash the surface area with 60-70% ethanol and then with soap and water. WATER SPILL: 

### Put on chenuca1 resistant protectors (gloves, respirator, safety goggles, apron, etc.). Recollect in container and keep in safety place with the container closed. Dispose ofwaste or clinging matter according to re1ated regulations. Remove all ignition sources or heat source, and also take away the other flammable matters. In case ofaccidental release'or spill, ventilate the spiU area. Furnish extinguisher proper for accidental fire.
. Recollect spill or leak with tool ofnon-spark material. Prevent runoffto ditches leading to 

## natufaI waterways. Dispose ofthe debris in 

### local 

### licensed facility. This material is awater pollutant and should be prevented from contaminating soil orfrom entering sewage and draining systems and bodies ofwater;
7. HANDLINGAND STORAGE 

### :{fANDLING:

### Page 4of7 Firstissue: February 12, 2002 

### Revised: LR-1672

, 

### . . 

### This material 

### is stable at 

### normal conditions, but do not drop. Avoid heat, fire, open flame, light, and ignition sources. Incompatible with strong oxidizers and reducing agents, acids and bases. Keep product away from metals, nitroform an4 oleum. Handle in well ventilated area, Close tightly containernecessarily during and after use. Ground equipment for pre''ention ofstatIc electricity accider.t. Use electrical appliance or apparatus ofexplosIon p:"ooftype. Do not bring contaminated protectors ofgloves, goggles ad C2.,iS, 

### etc., 

### in any place where person stays. Wash hands thoroughly after handling and before eating. ddnkirig, or s:noking. Keep out ofreach ofchildren. STORAGE:



### Do not conta:ninate water, food or feed by storage or disposal. Keep the product in the original containers. Store in cool, dry,**well-ventilat~d.** 

### low fire risk area away from sunlight. Keep container closed. Store only 

### in approved containers, under approved conditions
.. Avoid pressure build-up 

### in containers. Storage area should not be subjectto rapid

, , 

### temperature changes as such changes may cause increased internal pressure. 8. EXPOSURE CONTROLS, PERSONALPROTECTION ENGINEERING CONTROLS: 

### Use explosion prooftype equipment. Install proper exhausterto prevent high concentration ofvapor. Ground equipment for fluid transfer, pumping and stirring. Arrange the neighborhood of.handling place so as to cut**o~the** 

### influence ofheat or ignition source. In indoor application, use an 

### automatic application equipment or alocal exhauster on which operators 

## can avoid exposure to, or other equipment devised.for him to avoid exposure to. In application in 

### the space ofpoor ventilation (tank bottom. etc.). install ventilation proper for the space. PERSONALPROTECI1VEEQUIPMENT: 

## EyeIFace Protection Chemical resistantgoggles must be provided and worn 

### to prevent'exposure. Goggles must provide an impervious barrierto prevent exposure during normal and**exp~ed** 

### duration and conditions ofexposure within theparticulardefined work area. Spectacle type 

### safety glasses do not provide adequate protection. An eyewash fountain shOUld be readily accesSIble. Wearplastic

# &ce shield

# ~o '.**"'!f~** f}; .',

..

.: 

# .

# ---,----­ Page 50f7 

### Firstissue: February 12, 2002 Revised: LR-1672 

### in addition to safety goggles where there is a danger ofsplashing. Skin Protection 

### Chemical resistant**g~oves** 

### must be provided and worn to prevent dermal exposure. Gloves must provide an impervious barrier to prevent dermal exposure during normal and expected duration and conditions ofexposure within the particular defined work area. Clothing that covers any exposed areas ofthe a:-ms, Jegs, and**torso~ mus~**  

### a:so be, 

### provided and worn to prevent dermal exposure. Cbt;-.ing 

### shadd be sek.:t,;;': f.::,;:, 

### the duration ofthe anticipated exposure if

### there is a potential for ski:1 contact. Respiratory Protection 

### Each person who is reasonably likeJy to be'exposed the productby inhalation in the forin ofdust, mist, or smoke shall be provided air purifying respirator equipped with combination cartridges approved for paints, lacquers, and enamels, including disposable respirators. Handle only in the presence ofadequate ventilation. 'General 'An 

### emergency shower should be readily accessible. Discard any contaminated clothing. EXPOSURE GUIDELINES: 

### Chemical name Composition (wtOlo) 

### Permission level ACGlH-TWA Xylene 

### 15 

### lOOppm lOOppm Propylene glycol 

### monometyl ethe 15-20 

### Not Available lOOppm

9. PHYSICALAND CHEMICALPROPERTIES 

### Appearance: Color: Odor: ' Odor Threshold Level: Boiling point: Physical State: Melting Point: , VaporPressure: VaporDensity: Solubility in Water: Specific Gravity: ' 

# Freezin8 Point: 

## pH: % Volatile: Viscosity: (Gardonar) Clear

.Colorless Organic solvent odor Not**AvailablE~** 

### . Not Available Liquid Not Available Not**Avail~le** 

### Heavythan air Insoluble l.Ol5±O.OlO 

### Not Available Not Available 55 

### -60wt% T
.......Z at,25°C

### Page 6of7 Firstissue: February 12, 2002 

### Revised: LR-1672

10. STABruTYAND REACTIVITY CHEMICAL STABILITY: 

### Stable under normal conditions. CONDITIONS TO AVOID:



### Excessive heat (High temperature), open flames,**ig:1;~ion** 

### sou;ce, and exposu:-e to sunlight or ultraviolet ray, or contacting with oxida:1t or orgar.ic peibxide. INCOMPATIBILITY WITH OTHER l\1A**r2:"~.',.LS :** 



### Free radical initiators and oxidizing**~ents** 

### HAZARDOUS DECO:MPOSITION PRODUCTS: 

### At"elevated temperatures decomposition may occur resulting in the release of smoke, carbon dioxide, carbon monoxi,de and othertoxic gases. HAZARDOUS POLYMERIZATION:



### Hazardous polymerization may occurby heating or by exposure to sunlight or ultraviolet ray: 11. TOXICOLOGICALINFORMATION 

### ACUTE IN;HALATION EFFECTS: Irritating to respiratory system EYE EFFECTS: Irritating to eyes SKINEFFECTS: Irritating to skin

. ACUTE 

## ORAL EFFECTS: Not Available·

SUBCHRONIC EFFECTS/CARCINOGENICITY: Not Available MUTAGENICITY: Not Available
12. ECOLOGICALINF'ORMATION 

### The wastes ofthis product are toxic. Do not discharge the washing and lakes, streams. pons,'**estuari~** 

### oceans. orpublic waters. Do not discharge effluent containing this product to sewer systems withoutproper authority.
13. DISPOSALCONSIDERATIONS 

### Let authorized industrial waste treaters dispose ofadhesive waste or containerwaste by making

# semce agreement. Do 

### not dispose ofwaste water after 

### cleaning container, equipment,**too~** 

### etc. without treatment into the ground and 'drainage ditch. With**resp~** 

### to disposing ofwaste resulting from effluent water

### treatment 

### or from incineration. comply to regulations or acts 

### relating to waste treatment or**contro~** 

### or let special treaters undertak.e. Bum up adhesive waste little by little usingthe incinerator ofopentype after absorption with 

### diatomaceous earth

### in the case ofincineration.**--~-.-** . 

### Page 7of7 

### Firstissue: February 12, 2002 Revised: LR-1672 

### 14. TRANSPORTINFORMATION 

### Accord to precautions relating to handling 

### and storing U.N 

### .1 N.A. Number: Class3-3, No.1688 Follow 

### all regulations in your country.
15. REGULATORY INFORL'fATION



### .Follow all regulations in your country. 16. OTHERINFORJ.\lIATION 

### Literature: (1) 

### MSDS, Material Data Base (paint); Japan Paint Manufacturers Association (2) Hazard information on this product

# is estimated as a mixture based on that of individual raw materials. Remarks: This information is furnished 

### withoutwarranty, express or implied, exceptthat it is accurate to the best knowledge ofMitsubishi Rayon Co., Ltd. It relates only to the specific material designated herein,' and. does not relate to use in**combina~ion** 

### with any other material or in any process. Mitsubishi Rayon Co., Ltd. assumes no legal responsibility for use ofor reliance upon this information.

I.,' 1""',},,', • .'

# '.


# . '. "

### iii003**lU/15/0~ l~E**  11:01 PAX 814 4'7 3747 CAS 

# ern InventoryExpert Service

A dlYi$lon oftheAmeric:an Chemical SOciety Phone: 8OG-63J.I8114. 61.04-447.3600 (100:.2308) fax: 614-+f7-37.047 E-malkanswel'1@cas.orc

INVEMTORY EXPERT SERVICE REPORT

XES-ORDER NUMBER: 69472-1 REGISTRY HUMBER: 460739-39·3

. CA INDEX NAME 2-Propenoic acid. 2-methyl-. methyl eSCer. polymer with butyl 2-propenoate. ethyl 2-propenoata.**~inc** oisI2-metbyl-2-propenoate) 4nd zinc**di-2-prope~oat~.** 2.2'-azobisf2-methylbutananitrile)- And**2,2'-a2Obill2·metbyp~opanenitr11e}­** initiated

Please print the uove CA :Ind." Name on the app:t'OJ:)J:i&te' page of yellX' liMN. 

# o If tlds bO'C is checked, CAS ha. made CloJ:l'ectio.c(a} markll4.!.n red to you tIS orier. neue make I\\ha 881118 conoation(.) to your PMN before submitting it to the EPA.

,**~t:~** 

## .....2003/03/11 (*) 11:33:03 GPO (DMF WBr) 

### <Graph> [mV] [Lo, M]**400.~~----~----------------r----------------r----.**

100. I I I I I**------~---------~** I I I I ______ J
___________ _ I I 

## , 40.00

Mn 2.464 20.00 30.00 [ft] 

### <The result of Molecular weight calculation> [min] [mV] [MOL] 5,112 

### Peaktop 28.93 107.858 5,338 Mz 8,739 

### Peak end 30.15 47.425 282 MY 5.182 Mz+l 12,514 

### Area 

### [mY sec] 9385.130 MP 5,338 

### Area ratio 

### [%] 100.000 Mz/Mw 1.688 

### Peak start 24.47 33.571 50.804 Mw

88.273 Mw/Mn 2.111 

### Hert [mV] ('7 5.181.87237 Mz+l/Mw : 2.415

I ,

### 2003/03/12 (Wed) 09:15:40 Data base name: Nakamura. mdb Differential curve conversion factor : 1 Stored data name yyyy0293 Differencial/Integration formula : Standerd Method data name yyyy0293 Sampling pitch [mSec] : 1200 Channel : Ch. 1 Peake No : 1 Time [min] : 24.47-26.93-30.15 Time [min Molecular Different Integration 24.47 50,804 0 100 24.49 49,944 0.0007 100 24.51 49,098 0.0035 100 24.53 48,265 0.0047 100 24.55 47,444 0.0049 100 24.57 46,637 0.0064 100 24.59 45,842 0.0086 99.99 24.61 45,060 0.0098 99.99 24.63 44,289 0.011 99.99 24.65 43,531 0.013 99.99 24.67 42, 785 0.0139 99.99 24.69 42,051 0.0134 99.98 24. 71 41. 328 0.0152 99.98 24. 73 40,617 0.0161 99.98 24. 75 39,917 0.0153 99.97 24. 77 39,228 0.0143 99.97 24. 79 38,550 0.0155 99.97 24.81 37,884 0.0141 99.97 24.83 37.227 0.0113 99.96 24.85 36,581 0.0099 99.96 24.87 35,946 0.0075 99.96 24.89 35.321 0.0035 99.96 24.91 34, 706 0.0013 99.96 24.93 34, 101 0.001 99.96 24.95 33,505 0.0044 99.96 24.97 32,920 0.0085 99.96 24.99 32,343 0.0107 99.96 25.01 31. 777 0.0167 99.95 25.03 31. 219 0.023 99.95 25.05 30,671 0.0287 99.94 25.07 30, 131 0.0365 99.93 25.09 29,600 0.045 99.93 25.11 29,078 0.0535 99.92 25. 13 28,565 0.0616 99.9 25. 15 28,060 0.0732 99.89 25. 17 27,564 0.0858 99.87 25. 19 27,076 0.0976 99.85 25.21 26,595 0.1109 99.83 25.23 26, 123 O. 125 99.81 25.25 25.659 O. 1404 99. 78 25.27 25,202 O. 1558 99. 75 25.29 24, 753 0.1723 99. 72 25.31 24,312 0.1911 99.68 25.33 23.877 0.2091 99.64 25.35 23,451 0.23 99.59

# ~"

### 25.37 23,031 0.2521 99.54 25.39 22,618 0.2752 99.49 25.41 22,213 0.2993 99.43 25.43 21, 814 0.325 99. 37 25.45 21,422 0.3514 99.3 25.47 21,036 0.3792 99.22 25.49 20,658 0.41 99. 14 25.51 20,285 0.4434 99.05 25.53 19,919 0.4748 98.96 25.55 19,559 0.5097 98.86 25.57 19.205 0.5471 98. 75 25.59 18,858 0.5848 98.64 25.61 18.516 0.6232 98.51 25.63 18, 180 0.6641 98.38 25.65 17,850 O. 7071 98.24 25.67 17.526 O. 7496 98.09 25.69 17,207 O. 7955 97.93 25. 71 16,894 0.8439 97. 76 25. 73 16.586 0.893 97.58 25. 75 16.283 0.9436 97.4 25. 77 15,986 0.9969 97.2 25. 79 15,694 1. 

### 0515 96.99 25.81 15,407 1. 

### 1082 96. 76 25.83 15, 125 1. 1664 96.53 25.85 14.848 1.2266 96.28 25.87 14,576 1. 

### 2883 96.02 25.89 14,308 1.3504 95. 75 25.91 14,045 1. 

### 4148 95.47 25.93 13. 787 1. 

### 4801 95.17 25.95 13,533 1. 

### 5465 94.86 25.97 13,284 1. 6149 94.53 25.99 13,039 1. 6851 94. 19 26.01 12. 799 1. 

### 755 93.84 26.03 12,562 1. 

### 8256 93.47 26.05 12,330 1. 

### 8991 93.08 26.07 12, 102 1. 

### 972 92.68 26.09 11,878 2.0451 92.27 26. 11 11,659 2. 1208 91. 84 26. 13 11,442 2. 1972 91. 39 26. 15 11,230 2.2724 90.93 26.17 11,022 2.3493 90.45 26. 19 10,817 2.4268 89.96 26.21 10.616 2.5021 89.45 26.23 26.25 10,419 10,225 2.5783 2.6554 88.92 88.38 1. 

### 26.27 10,034 2. 7304 87.82 26.29 9,847 2.8051 87.25 26.31 9.664 2.8801 86.66 26.33 9.483 2.9536 86.06 26.35 9,306 3.0258 85.44 26.37 9, 133 3.0974 84.81 26.39 8,962 3. 1686 84. 16 

# al

### 26.41 8, 794 3.2374 83.49 26.43 8,630 3.3049 82.81 26.45 8,468 3.3717 82. 12 26.47 8,309 3.4368 81. 42 26.49 8, 153 3.4991 80. 7 26.51 8,000 3.5594 79.97 26.53 7,850 3.6183 79.22 26.55 7, 703 3.6743 78.46 26.57 7,558 3. 7268 77. 7 26.59 7,416 3. 7782 76.92 26.61 7,276 3.8268 76. 13 26.63 7, 139 3.8699 75.33 26.65 7,005 3.9129 74.52 26.67 6,873 3.9545 73. 71 26.69 6, 744 3.9903 72.88 26. 71 6,616 4.0244 72.05 26. 73 6,492 4.0571 71. 21 26. 75 6,369 4.0858 70.37 26. 77 6,249 4.1109 69.52 26. 79 6, 131 4. 1346 68.66 26.81 6,015 4. 1552 67.8 26.83 5,901 4.1707 66.93 26.85 5, 789 4. 1847 66.07 26.87 5,680 4. 1966 65.2 26.89 5,572 4.2032 64.32 26.91 5,467 4.2085 63.45 26.93 5,363 4.2111 62.58 26.95 5,262 4.211 61. 7 26.97 5, 162 4.2066 60.83 26.99 5,064 4.2008 59.95 27.01 4,968 4. 1937 59.08 27.03 4,874 4. 1824 58.21 27.05 4, 781 4. 1696 57.35 27.07 4,691 4. 1552 56.48 27.09 4,601 4. 1387 55.62 27. 11 4,514 4.1195 54. 76 27. 13 4,428 4.0987 53.91 27. 15 4,344 4.0773 53.06 27.17 4,262 4.0513 52.21 27. 19 4,181 4.0248 51. 38 27.21 4,101 3.9982 50.54 27.23 4,023 3.9683 49. 72 27.25 3,946 3.9364 48.89 27.27 3,871 3.9045 48.08 27.29 3, 798 3.8712 47.27 27.31 3, 725 3.8348 46.47 27.33 3.654 3.8001 45.68 27.35 3,585 3. 7656 44.89 27.37 3,517 3. 728 44. 12 27.39 3,450 3.6902 43.35 27.41 3,384 3.6539 42.58 27.43 3,320 3.6161 41. 83

# ~~

### 27.45 3,256 3.5775 41. 08 27.47 3,194 3. 5392 40.34 27.49 3, 133 3.5002 39.61 27.51 3,074 3.4599 38.89 27. 53 3,015 3.42 38.17 27.55 2,958 3.3808 37.47 27. 57 2,901 3.3406 36. 77 27.59 2,846 3.3008 36.08 27.61 2, 792 3.2612 35.4 27.63 2, 739 3.2223 34. 73 27. 65 2,686 3. 1825 34.06 27.67 2,635 3. 1438 33.41 27.69 2,585 3.1072 32. 76 27.71 2,536 3.069 32. 12 27. 73 2,487 3.0306 31. 48 27. 75 2,440 2.9948 30.86 27. 77 2,394 2.9589 30.24 27. 79 2,348 2.922 29.63 27.81 2,303 2.8864 29.03 27.83 2,259 2.8529 28. 43 27.85 2,216 2.8171 27.84 27.87 2.174 2. 7821 27.26 27.89 2, 133 2. 7501 26.69 27.91 2,092 2. 7161 26. 12 27.93 2,052 2.6823 25. 56 27.95 2,013 2.6509 25.01 27.97 1, 

### 975 2.6192 24.47 27.99 1,937 2.5867 23.93 28.01 1,901 2.5571 23.39 28.03 1,865 2.5273 22.87 28.05 1,829 2.4958 22.35 28.07 1, 794 2.4662 21. 83 28.09 1, 

### 760 2.4392 21. 33 28.11 1, 727 2.4109 20.82 28. 13 1,694 2.3812 20.33 28. 15 1,662 2.3533 19.84 28.17 1, 

### 630 2.3254 19. 36 28. 19 1,599 2.2958 18.88 28.21 1,569 2.2675 18.41 28.23 1,539 2.24 17.94 28.25 1,510 2.2123 17.48 28.27 1,482 2. 1845 17.03 28.29 1,454 2. 1569 16.58 28.31 1,426 2. 1303 16.14 28.33 1,399 2. 102 15.71 28.35 1,373 2.0745 15.28 28.37 1,347 2.0484 14.85 28.39 1, 

### 321 2.0216 14.43 28.41 1,296 1. 

### 9939 14.02 28.43 1,272 1. 

### 967 13.61 28.45 1,248 1. 

### 939 13.21 28.47 1, 

### 224 1. 

### 9099 12.82

# ~q

### 28.49 1,201 1. 882 12.43 28.51 1,179 1. 8537 12.05 28.53 1,156 1. 

### 824 11. 67 28.55 I, 135 1. 7943 11. 3 28.57 1,113 1. 7654 10.94 28.59 1,092 1. 

### 736 10.58 28.61 1,072 1. 

### 7054 10.23 28.63 1, 

### 052 1. 

### 6761 9.88 28.65 1,032 1. 6469 9.55 28.67 1, 

### 013 1. 

### 6164 9.21 28.69 994 1.• '"\:1'7 o_,! 

### 8.89 28.71 975 1. 

### 5578 8.57 28. 73 957 1. 

### 528 8.26 28. 75 939 1. 

### 498 7.95 28. 77 921 1. 

### 4678 7.65 28. 79 904 1. 4376 7.35 28.81 887 1. 

### 4052 7.07 28.83 871 1. 3741 6. 79 28.85 855 1. 343 6.51 28.87 839 1.3115 6.24 28.89 823 1. 

### 2802 5.98 28.91 808 1. 

### 2494 5. 73 28.93 793 1. 

### 2184 5.48 28.95 778 1. 

### 1864 5.24 28.97 764 1. 

### 155 5.01 28.99 749 1. 126 4. 78 29.01 736 1. 

### 0948 4.56 29.03 722 1. 

### 0645 4.34 29.05 709 1. 

### 0347 4. 13 29.07 695 1. 0051 3.93 29.09 683 0.9744 3. 73 29.11 670 0.9444 3.54 29. 13 658 0.9152 3.35 29. 15 646 0.8852 3. 18 29.17 634 0.8566 3 29. 19 622 0.8283 2.84 29.21 611 O. 7977 2.68 29.23 599 O. 769 2.52 29.25 589 O. 7414 2.37 29.27 578 O. 7128 2.23 29.29 567 0.6845 2.09 29.31 557 0.6573 1. 96 29.33 547 0.6308 1. 84 29.35 537 0.6041 1. 

### 72 29.37 527 0.5794 1.6 29.39 517 0.5551 1. 49 29.41 508 0.5299 1. 

### 38 1,,[ 

### 29.43 499 0.5048 1. 28 29.45 490 0.4805 1. 

### 19 29.47 481 0.4573 1.1 29.49 472 0.4337 1. 01 29.51 464 O. 1098 0.93 

# ?JJ

.rr: • ...:.'! '. ", ,

### 29.53 455 29.55 447 29.57 439 29.59 431 29.61 423 29.63 416 29.65 408 29.67 401 29.69 394 29. 71 387 29. 73 380 29. 75 373 29. 77 367 29. 79 360 29.81 354 29.83 347 29.85 341 29.87 335 29.89 329 29.91 324 29.93 318 29.95 312 29.97 307 29.99 302 30.01 296 30.03 291 30.05 286 30.07 281 30.09 276 30.11 271 30. 13 267 0.3875 0.86 0.3645 O. 78 0.3417 O. 72 0.3206 0.65 0.3009 0.59 0.2806 0.54 0.2615 0.49 0.2454 0.44 0.2285 0.4 0.2114 0.35 O. 1969 0.32 O. 1822 0.28 O. 167 0.25 O. 154 0.22 O. 142 O. 19 O. 1287 0.17 0.1169 0.14 0.1071 O. 12 0.0964 O. 1 0.0852 0.09 0.0771 0.07 0.0688 0.06 0.0604 0.05 0.0531 0.04 0.047 0.03 0.0409 0.02 0.0343 0.01 0.0285 0.01 0.0227 0 0.0148 0 0.0081 0