You are a helpful assistant generating synthetic data that captures *System 1* and *System 2* thinking, *creativity*, and *metacognitive reflection*. Follow these steps in sequence, using tags [sys1] and [end sys1] for *System 1* sections and [sys2] and [end sys2] for *System 2* sections.

1. *Identify System 1 and System 2 Thinking Requirements:*
   - Carefully read the text.
   - Identify parts of the text that require quick, straightforward responses (*System 1*). Mark these sections with [sys1] and [end sys1].
   - Identify parts that require in-depth, reflective thinking (*System 2*), marked with [sys2] and [end sys2].

2. *Apply Step-by-Step Problem Solving with Creativity and Metacognitive Reflection for System 2 Sections:*

   *2.1 Understand the Problem:*
   - Objective: Fully comprehend the issue, constraints, and relevant context.
   - Reflection: "What do I understand about this issue? What might I be overlooking?"
   - Creative Perspective: Seek hidden patterns or possibilities that could reveal deeper insights or innovative connections.

   *2.2 Analyze the Information:*
   - Objective: Break down the problem logically.
   - Reflection: "Am I considering all factors? Are there any assumptions that need challenging?"
   - Creative Perspective: Explore unique patterns or overlooked relationships in the data that could add depth to the analysis.

   *2.3 Generate Hypotheses:*
   - Objective: Propose at least 10 hypotheses, each with a Confidence Score (0.0 to 1.0) and Creative Score (0.0 to 1.0), reflecting originality, surprise, and utility.
   - Reflection: "Have I explored all possible explanations or approaches, both conventional and unconventional?"
   - Creative Perspective: Consider novel angles that might provide unexpected insights.

   *2.4 Anticipate Future Steps and Obstacles:*
   - Objective: Make predictions, accounting for potential outcomes and obstacles.
   - Reflection: "What challenges might I face? Is my plan flexible for different scenarios?"
   - Creative Perspective: Visualize unforeseen outcomes and adapt plans to make use of them effectively.

   *2.5 Evaluate Hypotheses:*
   - Objective: Assess hypotheses based on feasibility, risk, and potential impact.
   - Evaluation: Refine Confidence and Creative Scores as needed.
   - Reflection: "Am I unbiased in my assessment? Which options fit best with the overall objectives?"
   - Creative Perspective: Identify hidden opportunities or overlooked details in each hypothesis.

   *2.6 Select the Best Hypothesis:*
   - Objective: Choose the most promising, strategic hypothesis.
   - Reflection: "Why does this hypothesis stand out? How does it uniquely address the issue?"
   - Creative Perspective: Consider any underutilized potential in the selected approach.

   *2.7 Implement the Hypothesis:*
   - Objective: Outline actionable steps for testing the hypothesis.
   - Reflection: "Is this plan practical? What resources or preparation are required?"
   - Creative Perspective: Refine steps to maximize effectiveness and yield unexpected benefits.

   *2.8 Monitor and Review Progress:*
   - Objective: Review progress, noting areas for improvement.
   - Reflection: "What’s working well? What could be improved?"
   - Creative Perspective: Look for emerging patterns that could refine future approaches.

   *2.9 Reflect and Capture Insights:*
   - Objective: Summarize lessons learned and insights gained for future reference.
   - Reflection: "What new understanding has emerged from this process?"
   - Creative Perspective: Identify innovative insights or patterns that could be applied to similar challenges.

3. *Generate Text Output with Interleaved System 1 and System 2 Responses:*
   - Use the tags [sys1] and [sys2] throughout.
   - Aim for a lengthier, detailed response. Combine both direct, straightforward *System 1* insights and reflective, deeply analytical *System 2* segments to capture a blend of quick observations and thoughtful analysis.

---

### *Example Input Text:*

You are tasked with analyzing a sudden shift in customer preferences in a tech market. There has been a noticeable decline in demand for physical devices, with customers increasingly interested in digital-only options. The challenge is to understand this shift, generate hypotheses for why it might be occurring, and explore potential strategies for adapting to this new trend.

---

### *Processed Output with System 1 and System 2 Thinking:*

The tech market is experiencing a shift in customer demand, moving away from physical devices toward digital-only options.

[sys1]
Customer demand has shifted from physical devices to digital-only options.
We need to understand why this change is happening and find strategies to address it.
Key factors may include cost, convenience, and technological trends.
[end sys1]

[sys2]
**2.1 Understand the Problem:**
The goal is to understand the underlying reasons for the shift in demand from physical devices to digital-only options, then develop a strategy to adapt.

*Reflection:* 
"I understand that preferences are changing, but what might be driving this? Is it primarily cost, or are there other factors such as convenience or sustainability?"

*Creative Perspective:* 
"Could there be a larger trend in digital minimalism or a preference for eco-friendly solutions that we’re missing? What unseen motivations might explain this shift?"

**2.2 Analyze the Information:**
There are multiple possible factors driving this shift, from economic influences to cultural shifts. It’s essential to isolate each factor and understand its impact.

*Reflection:* 
"Am I fully considering the various economic and social influences? Could there be a technological factor, like better internet speeds, that makes digital-only products more accessible?"

*Creative Perspective:* 
"Are there patterns or trends in other markets that could shed light on this shift? Could this be part of a larger trend toward virtual experiences?"

**2.3 Generate Hypotheses:**
1. Customers prefer digital options due to lower costs. (Confidence: 0.8, Creative: 0.4)
2. There’s a growing trend toward minimalism and reduced physical clutter. (Confidence: 0.7, Creative: 0.7)
3. Digital products offer greater flexibility and ease of use. (Confidence: 0.6, Creative: 0.6)
4. Environmental concerns are pushing consumers away from physical goods. (Confidence: 0.6, Creative: 0.8)
5. Advances in tech make digital-only options more functional. (Confidence: 0.8, Creative: 0.5)
6. Pandemic-era remote work increased demand for digital solutions. (Confidence: 0.7, Creative: 0.6)
7. Media coverage of the environmental impact of physical devices affects preferences. (Confidence: 0.5, Creative: 0.7)
8. There’s an increase in global digital literacy, expanding market access. (Confidence: 0.6, Creative: 0.6)
9. Customers view digital as more convenient and scalable for future needs. (Confidence: 0.7, Creative: 0.5)
10. Younger consumers prefer the aesthetics and convenience of digital products. (Confidence: 0.6, Creative: 0.6)

*Reflection:* 
"Have I considered all possible influences? Are there any surprising factors that could explain this shift?"

*Creative Perspective:* 
"Could specific social trends, like the rise of influencer culture or digital-first lifestyles, be influencing customer choices?"

**2.4 Anticipate Future Steps and Obstacles:**
*Objective:* Anticipate possible challenges, such as resistance from segments still preferring physical products.

*Reflection:* 
"What market obstacles might we face if we shift our focus to digital-only? Are there sub-segments that still prioritize physical products?"

*Creative Perspective:* 
"Could expanding digital options help us reach a more global audience? Are there emerging trends that we could leverage in our strategy?"

[end sys2]

[sys1]
To address this shift, consider a strategy that incorporates both digital-only offerings and educational campaigns about the benefits of digital solutions.
Use insights from customer feedback and current trends to guide product development.
Focus on flexibility and adaptation to cater to different customer segments.
[end sys1]


Related literature {#sec1}
==================

For related structures, see: Gowda, Foro *et al.* (2009[@bb4]); Gowda, Tokarčík *et al.* (2009**a*[@bb5],b* [@bb6]); Leiserowitz (1976[@bb7]); Lo & Ng (2009[@bb8]); Prasad *et al.* (2002[@bb10]).

Experimental {#sec2}
============

 {#sec2.1}

### Crystal data {#sec2.1.1}

C~10~H~7~Cl~2~NO~3~*M* *~r~* = 260.07Orthorhombic,*a* = 13.1618 (2) Å*b* = 14.6993 (2) Å*c* = 22.8406 (3) Å*V* = 4418.95 (11) Å^3^*Z* = 16Mo *K*α radiationμ = 0.58 mm^−1^*T* = 295 K0.40 × 0.33 × 0.24 mm

### Data collection {#sec2.1.2}

Oxford Diffraction Xcalibur Ruby Gemini diffractometerAbsorption correction: analytical (*CrysAlis Pro* ; Oxford Diffraction, 2009[@bb9]) *T* ~min~ = 0.836, *T* ~max~ = 0.89261823 measured reflections4191 independent reflections3514 reflections with *I* \> 2σ(*I*)*R* ~int~ = 0.029

### Refinement {#sec2.1.3}

*R*\[*F* ^2^ \> 2σ(*F* ^2^)\] = 0.028*wR*(*F* ^2^) = 0.079*S* = 1.084191 reflections289 parametersH-atom parameters constrainedΔρ~max~ = 0.22 e Å^−3^Δρ~min~ = −0.25 e Å^−3^

 {#d5e541}

Data collection: *CrysAlis Pro* (Oxford Diffraction, 2009[@bb9]); cell refinement: *CrysAlis Pro* ; data reduction: *CrysAlis Pro* ; program(s) used to solve structure: *SHELXS97* (Sheldrick, 2008[@bb11]); program(s) used to refine structure: *SHELXL97* (Sheldrick, 2008[@bb11]); molecular graphics: *ORTEP-3* (Farrugia, 1997[@bb2]) and *DIAMOND* (Brandenburg, 2002[@bb1]); software used to prepare material for publication: *SHELXL97*, *PLATON* (Spek, 2009[@bb12]) and *WinGX* (Farrugia, 1999[@bb3]).

Supplementary Material
======================

Crystal structure: contains datablocks I, global. DOI: [10.1107/S1600536809048715/tk2578sup1.cif](http://dx.doi.org/10.1107/S1600536809048715/tk2578sup1.cif)

Structure factors: contains datablocks I. DOI: [10.1107/S1600536809048715/tk2578Isup2.hkl](http://dx.doi.org/10.1107/S1600536809048715/tk2578Isup2.hkl)

Additional supplementary materials: [crystallographic information](http://scripts.iucr.org/cgi-bin/sendsupfiles?tk2578&file=tk2578sup0.html&mime=text/html); [3D view](http://scripts.iucr.org/cgi-bin/sendcif?tk2578sup1&Qmime=cif); [checkCIF report](http://scripts.iucr.org/cgi-bin/paper?tk2578&checkcif=yes)

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: [TK2578](http://scripts.iucr.org/cgi-bin/sendsup?tk2578)).

MT and JK thank the Grant Agency of the Slovak Republic (VEGA 1/0817/08) and Structural Funds, Interreg IIIA, for financial support in purchasing the diffractometer.

Comment
=======

As a part of studying the effect of ring- and side-chain substitutions on the crystal structures of biologically significant amides (Gowda, Foro *et al.*, 2009; Gowda, Tokarčík *et al.*, 2009*a,b*; Prasad *et al.*, 2002), the crystal structure of *N*-(2,5-dichlorophenyl)-maleamic acid (I) has been determined. The asymmetric unit of (I) contains two independent molecules (Fig. 1). The conformations of the N---H and C=O bonds in the amide segment of the structure are *anti* to each other, and those of the amide-O atom and the carbonyl-O atom of the acid segment are also *anti* to each other. The *anti* conformation of the C=O and O---H bonds of the acid group is comparatively rare and has been observed previously in *N*-phenylmaleamic acid (Lo & Ng, 2009), *N*-(2,6-dimethylphenyl)maleamic acid (Gowda, Tokarčík *et al.*, 2009*a*), and *N*-(3,4-dimethylphenyl)maleamic acid (Gowda, Tokarčík *et al.*, 2009*b*). The various modes of interlinking carboxylic acids by hydrogen bonds is described elsewhere (Leiserowitz, 1976). Each maleamic moiety includes a short intramolecular hydrogen O--H···O bond (Table 1). The mean planes through the phenyl ring and the amido group --NHCO-- form dihedral angles of 45.7 (1) and 40.8 (1) ° in the first and second molecules, respectively. All non-hydrogen atoms of the maleamic moiety in the first molecule fit very well to a plane, having the r.m.s. deviation of fitted atoms 0.013 Å. The mean plane through the maleamic moiety in the second molecule has a r.m.s. deviation of 0.098 Å. In the crystal structure, intermolecular N--H···O hydrogen bonds link self-associated molecules into two distinct zig-zag ribbons propagating in the \[1 0 0\] direction (Fig. 2). These ribbons are weakly coupled by a C---H···π interaction, with atom C7-H acting as the donor and the aryl ring C15---C20 as the acceptor. The centroid of the C15---C20 ring is denoted *Cg*2 in the Table 1.

Experimental {#experimental}
============

A solution of maleic anhydride (0.025 mol) in toluene (25 ml) was treated drop-wise with a solution of 2,5-dichloroaniline (0.025 mol) also in toluene (20 ml) with constant stirring. The resulting mixture was warmed with stirring for 30 min and set aside for an additional 30 min at room temperature for completion of the reaction. The mixture was then treated with dilute hydrochloric acid to remove the unreacted 2,5-dichloroaniline. The resultant solid *N*-(2,5-dichlorophenyl)maleamic acid was filtered under suction and washed thoroughly with water to remove the unreacted maleic anhydride and maleic acid. It was recrystallized to constant melting point from ethanol. Colourless crystals were grown by slow evaporation (room temperature) of an ethanol solution of (I).

Refinement {#refinement}
==========

H atoms were visible in difference maps and were subsequently treated as riding atoms with distances 0.93Å (CH), 0.86Å (NH) and 0.82Å (OH). The *U*~iso~(H) values were set at 1.2*U*~eq~(C,*N*,*O*).

Figures
=======

![Molecular structure of (I) showing the atom labelling scheme. Displacement ellipsoids are drawn at the 50% probability level. H atoms are represented as small spheres of arbitrary radii.](e-65-o3119-fig1){#Fap1}

![Part of crystal structure of (I) showing 1-D zig-zag supramolecular chains generated by N---H···O hydrogen bonds (dashed lines). Symmetry codes (i) x - 1/2,y,-z + 1/2; (ii) x - 1/2,y,-z + 3/2.](e-65-o3119-fig2){#Fap2}

Crystal data {#tablewrapcrystaldatalong}
============

  ------------------------- ----------------------------------------
  C~10~H~7~Cl~2~NO~3~       *F*(000) = 2112
  *M~r~* = 260.07           *D*~x~ = 1.564 Mg m^−3^
  Orthorhombic, *Pbca*      Mo *K*α radiation, λ = 0.71073 Å
  Hall symbol: -P 2ac 2ab   Cell parameters from 31107 reflections
  *a* = 13.1618 (2) Å       θ = 1.6--29.5°
  *b* = 14.6993 (2) Å       µ = 0.58 mm^−1^
  *c* = 22.8406 (3) Å       *T* = 295 K
  *V* = 4418.95 (11) Å^3^   Block, colourless
  *Z* = 16                  0.40 × 0.33 × 0.24 mm
  ------------------------- ----------------------------------------

Data collection {#tablewrapdatacollectionlong}
===============

  ------------------------------------------------------------------------------ --------------------------------------
  Oxford Diffraction Xcalibur Ruby Gemini diffractometer                         4191 independent reflections
  graphite                                                                       3514 reflections with *I* \> 2σ(*I*)
  Detector resolution: 10.434 pixels mm^-1^                                      *R*~int~ = 0.029
  ω scans                                                                        θ~max~ = 25.7°, θ~min~ = 2.3°
  Absorption correction: analytical (*CrysAlis PRO*; Oxford Diffraction, 2009)   *h* = −16→16
  *T*~min~ = 0.836, *T*~max~ = 0.892                                             *k* = −17→17
  61823 measured reflections                                                     *l* = −27→27
  ------------------------------------------------------------------------------ --------------------------------------

Refinement {#tablewraprefinementdatalong}
==========

  ------------------------------------- ------------------------------------------------------------------------------------------------
  Refinement on *F*^2^                  Primary atom site location: structure-invariant direct methods
  Least-squares matrix: full            Secondary atom site location: difference Fourier map
  *R*\[*F*^2^ \> 2σ(*F*^2^)\] = 0.028   Hydrogen site location: inferred from neighbouring sites
  *wR*(*F*^2^) = 0.079                  H-atom parameters constrained
  *S* = 1.08                            *w* = 1/\[σ^2^(*F*~o~^2^) + (0.0445*P*)^2^ + 0.705*P*\] where *P* = (*F*~o~^2^ + 2*F*~c~^2^)/3
  4191 reflections                      (Δ/σ)~max~ = 0.001
  289 parameters                        Δρ~max~ = 0.22 e Å^−3^
  0 restraints                          Δρ~min~ = −0.25 e Å^−3^
  ------------------------------------- ------------------------------------------------------------------------------------------------

Special details {#specialdetails}
===============

  -----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
  Geometry. All e.s.d.\'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.\'s are taken into account individually in the estimation of e.s.d.\'s in distances, angles and torsion angles; correlations between e.s.d.\'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.\'s is used for estimating e.s.d.\'s involving l.s. planes.
  Refinement. Refinement of *F*^2^ against ALL reflections. The weighted *R*-factor *wR* and goodness of fit *S* are based on *F*^2^, conventional *R*-factors *R* are based on *F*, with *F* set to zero for negative *F*^2^. The threshold expression of *F*^2^ \> σ(*F*^2^) is used only for calculating *R*-factors(gt) *etc*. and is not relevant to the choice of reflections for refinement. *R*-factors based on *F*^2^ are statistically about twice as large as those based on *F*, and *R*- factors based on ALL data will be even larger.
  -----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å^2^) {#tablewrapcoords}
==================================================================================================

  ----- -------------- --------------- --------------- -------------------- --
        *x*            *y*             *z*             *U*~iso~\*/*U*~eq~   
  C1    0.73471 (10)   −0.00911 (10)   0.32684 (6)     0.0350 (3)           
  C2    0.72297 (11)   −0.04413 (10)   0.26641 (7)     0.0415 (3)           
  H2    0.6567         −0.0563         0.2547          0.05\*               
  C3    0.79490 (12)   −0.06048 (11)   0.22658 (7)     0.0441 (4)           
  H3    0.7699         −0.0823         0.1912          0.053\*              
  C4    0.90735 (12)   −0.05043 (11)   0.22796 (7)     0.0441 (4)           
  C5    0.63841 (10)   0.02870 (9)     0.41515 (6)     0.0339 (3)           
  C6    0.56221 (11)   0.08972 (9)     0.43094 (6)     0.0364 (3)           
  C7    0.54753 (12)   0.11305 (10)    0.48908 (7)     0.0415 (3)           
  H7    0.4961         0.1535          0.4992          0.05\*               
  C8    0.60896 (11)   0.07648 (10)    0.53206 (7)     0.0416 (3)           
  H8    0.5994         0.0918          0.5712          0.05\*               
  C9    0.68479 (11)   0.01675 (10)    0.51585 (6)     0.0374 (3)           
  C10   0.70068 (11)   −0.00722 (10)   0.45830 (6)     0.0363 (3)           
  H10   0.7527         −0.0472         0.4485          0.044\*              
  N1    0.64725 (9)    0.00060 (8)     0.35603 (5)     0.0376 (3)           
  H1N   0.592          −0.0112         0.3374          0.045\*              
  O1    0.81770 (8)    0.01020 (8)     0.34893 (4)     0.0466 (3)           
  O2    0.95290 (9)    −0.01830 (9)    0.27441 (5)     0.0616 (3)           
  H2A   0.9105         −0.0062         0.2995          0.092\*              
  O3    0.95614 (9)    −0.07270 (9)    0.18517 (5)     0.0602 (3)           
  Cl1   0.48365 (3)    0.13629 (3)     0.378143 (19)   0.05137 (12)         
  Cl2   0.76232 (3)    −0.03099 (3)    0.569340 (18)   0.05382 (13)         
  C11   0.54290 (10)   0.29825 (10)    0.65172 (6)     0.0359 (3)           
  C12   0.55854 (11)   0.30418 (11)    0.71586 (6)     0.0415 (4)           
  H12   0.4998         0.3071          0.7384          0.05\*               
  C13   0.64578 (11)   0.30582 (11)    0.74530 (6)     0.0420 (3)           
  H13   0.6379         0.31            0.7857          0.05\*               
  C14   0.75294 (11)   0.30223 (11)    0.72582 (7)     0.0410 (3)           
  C15   0.41539 (10)   0.31099 (9)     0.57492 (6)     0.0349 (3)           
  C16   0.32356 (11)   0.27102 (9)     0.55905 (7)     0.0366 (3)           
  C17   0.29294 (12)   0.26877 (10)    0.50117 (7)     0.0444 (4)           
  H17   0.2322         0.2405          0.491           0.053\*              
  C18   0.35224 (13)   0.30829 (11)    0.45862 (7)     0.0471 (4)           
  H18   0.3326         0.3062          0.4195          0.057\*              
  C19   0.44124 (12)   0.35108 (10)    0.47466 (7)     0.0423 (4)           
  C20   0.47341 (11)   0.35263 (10)    0.53203 (7)     0.0397 (3)           
  H20   0.5339         0.3815          0.5419          0.048\*              
  N2    0.44678 (9)    0.31040 (9)     0.63412 (5)     0.0386 (3)           
  H2N   0.4011         0.3184          0.6606          0.046\*              
  O4    0.61248 (8)    0.28343 (8)     0.61652 (4)     0.0496 (3)           
  O5    0.77523 (8)    0.28321 (10)    0.67163 (5)     0.0590 (3)           
  H5A   0.7227         0.2744          0.6532          0.089\*              
  O6    0.81990 (9)    0.31650 (10)    0.76074 (6)     0.0696 (4)           
  Cl3   0.24556 (3)    0.22391 (3)     0.61215 (2)     0.05196 (12)         
  Cl4   0.51489 (4)    0.40468 (4)     0.42195 (2)     0.06528 (15)         
  ----- -------------- --------------- --------------- -------------------- --

Atomic displacement parameters (Å^2^) {#tablewrapadps}
=====================================

  ----- ------------- ------------- ------------- --------------- --------------- ---------------
        *U*^11^       *U*^22^       *U*^33^       *U*^12^         *U*^13^         *U*^23^
  C1    0.0294 (8)    0.0400 (8)    0.0355 (8)    0.0015 (6)      0.0014 (6)      0.0035 (6)
  C2    0.0301 (8)    0.0553 (9)    0.0390 (8)    −0.0023 (6)     −0.0013 (6)     −0.0030 (7)
  C3    0.0413 (8)    0.0563 (9)    0.0347 (8)    −0.0033 (7)     0.0042 (7)      −0.0038 (7)
  C4    0.0385 (8)    0.0509 (9)    0.0431 (9)    0.0007 (7)      0.0099 (7)      0.0071 (7)
  C5    0.0272 (7)    0.0384 (7)    0.0362 (7)    0.0001 (6)      0.0043 (6)      −0.0015 (6)
  C6    0.0296 (7)    0.0363 (7)    0.0434 (8)    0.0015 (6)      0.0032 (6)      0.0027 (6)
  C7    0.0366 (8)    0.0384 (8)    0.0494 (9)    0.0028 (6)      0.0099 (7)      −0.0059 (7)
  C8    0.0443 (8)    0.0428 (8)    0.0376 (8)    −0.0030 (7)     0.0086 (7)      −0.0067 (6)
  C9    0.0365 (8)    0.0389 (8)    0.0369 (8)    −0.0043 (6)     0.0000 (6)      0.0017 (6)
  C10   0.0303 (7)    0.0398 (8)    0.0390 (8)    0.0046 (6)      0.0033 (6)      −0.0005 (6)
  N1    0.0269 (6)    0.0513 (7)    0.0346 (6)    0.0040 (5)      −0.0002 (5)     −0.0021 (5)
  O1    0.0311 (6)    0.0708 (7)    0.0381 (6)    −0.0067 (5)     0.0014 (5)      −0.0048 (5)
  O2    0.0323 (6)    0.1000 (10)   0.0524 (7)    −0.0044 (6)     0.0077 (5)      −0.0069 (7)
  O3    0.0476 (7)    0.0808 (9)    0.0523 (7)    −0.0011 (6)     0.0219 (6)      −0.0027 (6)
  Cl1   0.0399 (2)    0.0602 (3)    0.0540 (2)    0.01679 (18)    −0.00180 (18)   0.00427 (19)
  Cl2   0.0543 (3)    0.0671 (3)    0.0401 (2)    0.0055 (2)      −0.00553 (18)   0.00738 (18)
  C11   0.0255 (7)    0.0469 (8)    0.0352 (8)    −0.0010 (6)     −0.0001 (6)     −0.0043 (6)
  C12   0.0253 (7)    0.0661 (10)   0.0331 (8)    0.0018 (7)      0.0046 (6)      −0.0053 (7)
  C13   0.0325 (8)    0.0634 (9)    0.0300 (7)    0.0007 (7)      0.0005 (6)      −0.0079 (7)
  C14   0.0284 (7)    0.0562 (9)    0.0385 (8)    −0.0011 (6)     −0.0045 (7)     0.0018 (7)
  C15   0.0275 (7)    0.0399 (8)    0.0371 (8)    0.0039 (6)      −0.0037 (6)     −0.0061 (6)
  C16   0.0295 (7)    0.0344 (7)    0.0460 (8)    0.0021 (6)      −0.0031 (6)     −0.0047 (6)
  C17   0.0375 (8)    0.0430 (9)    0.0528 (10)   0.0028 (7)      −0.0152 (7)     −0.0104 (7)
  C18   0.0519 (10)   0.0502 (9)    0.0393 (8)    0.0115 (8)      −0.0133 (7)     −0.0074 (7)
  C19   0.0418 (9)    0.0452 (8)    0.0398 (8)    0.0119 (7)      0.0017 (7)      0.0013 (7)
  C20   0.0309 (8)    0.0447 (8)    0.0435 (9)    0.0003 (6)      −0.0019 (6)     −0.0039 (7)
  N2    0.0242 (6)    0.0577 (8)    0.0339 (6)    0.0000 (5)      0.0004 (5)      −0.0058 (5)
  O4    0.0305 (6)    0.0850 (8)    0.0334 (5)    0.0094 (5)      0.0014 (5)      −0.0056 (5)
  O5    0.0273 (6)    0.1095 (10)   0.0403 (6)    0.0074 (6)      0.0025 (5)      −0.0009 (6)
  O6    0.0334 (6)    0.1215 (11)   0.0539 (7)    −0.0072 (7)     −0.0134 (6)     −0.0058 (7)
  Cl3   0.0386 (2)    0.0552 (3)    0.0621 (3)    −0.01198 (17)   0.00285 (18)    −0.00156 (19)
  Cl4   0.0633 (3)    0.0810 (3)    0.0515 (3)    0.0115 (2)      0.0144 (2)      0.0150 (2)
  ----- ------------- ------------- ------------- --------------- --------------- ---------------

Geometric parameters (Å, °) {#tablewrapgeomlong}
===========================

  --------------------- -------------- ----------------------- --------------
  C1---O1               1.2364 (17)    C11---O4                1.2380 (17)
  C1---N1               1.3378 (18)    C11---N2                1.3395 (18)
  C1---C2               1.481 (2)      C11---C12               1.482 (2)
  C2---C3               1.335 (2)      C12---C13               1.331 (2)
  C2---H2               0.93           C12---H12               0.93
  C3---C4               1.488 (2)      C13---C14               1.480 (2)
  C3---H3               0.93           C13---H13               0.93
  C4---O3               1.2143 (19)    C14---O6                1.2070 (19)
  C4---O2               1.307 (2)      C14---O5                1.3024 (19)
  C5---C10              1.386 (2)      C15---C20               1.385 (2)
  C5---C6               1.3931 (19)    C15---C16               1.392 (2)
  C5---N1               1.4168 (18)    C15---N2                1.4141 (18)
  C6---C7               1.385 (2)      C16---C17               1.382 (2)
  C6---Cl1              1.7298 (15)    C16---Cl3               1.7334 (15)
  C7---C8               1.381 (2)      C17---C18               1.375 (2)
  C7---H7               0.93           C17---H17               0.93
  C8---C9               1.380 (2)      C18---C19               1.379 (2)
  C8---H8               0.93           C18---H18               0.93
  C9---C10              1.377 (2)      C19---C20               1.377 (2)
  C9---Cl2              1.7397 (15)    C19---Cl4               1.7349 (16)
  C10---H10             0.93           C20---H20               0.93
  N1---H1N              0.86           N2---H2N                0.86
  O2---H2A              0.82           O5---H5A                0.82
                                                               
  O1---C1---N1          122.16 (13)    O4---C11---N2           121.82 (13)
  O1---C1---C2          123.52 (13)    O4---C11---C12          123.35 (13)
  N1---C1---C2          114.32 (13)    N2---C11---C12          114.83 (12)
  C3---C2---C1          128.59 (14)    C13---C12---C11         128.35 (13)
  C3---C2---H2          115.7          C13---C12---H12         115.8
  C1---C2---H2          115.7          C11---C12---H12         115.8
  C2---C3---C4          132.31 (15)    C12---C13---C14         132.04 (14)
  C2---C3---H3          113.8          C12---C13---H13         114
  C4---C3---H3          113.8          C14---C13---H13         114
  O3---C4---O2          120.55 (15)    O6---C14---O5           120.06 (14)
  O3---C4---C3          118.83 (15)    O6---C14---C13          119.40 (14)
  O2---C4---C3          120.62 (13)    O5---C14---C13          120.54 (13)
  C10---C5---C6         119.12 (13)    C20---C15---C16         118.76 (13)
  C10---C5---N1         121.19 (12)    C20---C15---N2          121.22 (13)
  C6---C5---N1          119.59 (13)    C16---C15---N2          120.01 (13)
  C7---C6---C5          120.54 (14)    C17---C16---C15         120.82 (14)
  C7---C6---Cl1         119.15 (11)    C17---C16---Cl3         119.13 (12)
  C5---C6---Cl1         120.30 (11)    C15---C16---Cl3         120.05 (11)
  C8---C7---C6          120.24 (14)    C18---C17---C16         120.01 (14)
  C8---C7---H7          119.9          C18---C17---H17         120
  C6---C7---H7          119.9          C16---C17---H17         120
  C9---C8---C7          118.71 (14)    C17---C18---C19         119.13 (14)
  C9---C8---H8          120.6          C17---C18---H18         120.4
  C7---C8---H8          120.6          C19---C18---H18         120.4
  C10---C9---C8         121.93 (14)    C20---C19---C18         121.43 (15)
  C10---C9---Cl2        118.56 (11)    C20---C19---Cl4         118.75 (13)
  C8---C9---Cl2         119.50 (11)    C18---C19---Cl4         119.82 (12)
  C9---C10---C5         119.44 (13)    C19---C20---C15         119.76 (14)
  C9---C10---H10        120.3          C19---C20---H20         120.1
  C5---C10---H10        120.3          C15---C20---H20         120.1
  C1---N1---C5          125.22 (12)    C11---N2---C15          124.31 (12)
  C1---N1---H1N         117.4          C11---N2---H2N          117.8
  C5---N1---H1N         117.4          C15---N2---H2N          117.8
  C4---O2---H2A         109.5          C14---O5---H5A          109.5
                                                               
  O1---C1---C2---C3     −0.1 (3)       O4---C11---C12---C13    8.6 (3)
  N1---C1---C2---C3     179.57 (16)    N2---C11---C12---C13    −171.30 (16)
  C1---C2---C3---C4     0.2 (3)        C11---C12---C13---C14   −0.2 (3)
  C2---C3---C4---O3     178.25 (18)    C12---C13---C14---O6    170.54 (18)
  C2---C3---C4---O2     −1.7 (3)       C12---C13---C14---O5    −10.0 (3)
  C10---C5---C6---C7    −1.1 (2)       C20---C15---C16---C17   3.2 (2)
  N1---C5---C6---C7     175.32 (13)    N2---C15---C16---C17    −178.24 (13)
  C10---C5---C6---Cl1   179.64 (11)    C20---C15---C16---Cl3   −176.38 (11)
  N1---C5---C6---Cl1    −3.89 (19)     N2---C15---C16---Cl3    2.19 (18)
  C5---C6---C7---C8     0.5 (2)        C15---C16---C17---C18   −1.6 (2)
  Cl1---C6---C7---C8    179.72 (11)    Cl3---C16---C17---C18   177.97 (11)
  C6---C7---C8---C9     0.1 (2)        C16---C17---C18---C19   −1.0 (2)
  C7---C8---C9---C10    0.0 (2)        C17---C18---C19---C20   2.0 (2)
  C7---C8---C9---Cl2    −179.39 (11)   C17---C18---C19---Cl4   −177.81 (12)
  C8---C9---C10---C5    −0.6 (2)       C18---C19---C20---C15   −0.4 (2)
  Cl2---C9---C10---C5   178.73 (11)    Cl4---C19---C20---C15   179.43 (11)
  C6---C5---C10---C9    1.2 (2)        C16---C15---C20---C19   −2.2 (2)
  N1---C5---C10---C9    −175.21 (13)   N2---C15---C20---C19    179.26 (13)
  O1---C1---N1---C5     −3.4 (2)       O4---C11---N2---C15     −2.4 (2)
  C2---C1---N1---C5     176.88 (13)    C12---C11---N2---C15    177.50 (13)
  C10---C5---N1---C1    −45.1 (2)      C20---C15---N2---C11    −39.9 (2)
  C6---C5---N1---C1     138.55 (15)    C16---C15---N2---C11    141.55 (14)
  --------------------- -------------- ----------------------- --------------

Hydrogen-bond geometry (Å, °) {#tablewraphbondslong}
=============================

  --------------------- --------- --------- ------------- ---------------
  *D*---H···*A*         *D*---H   H···*A*   *D*···*A*     *D*---H···*A*
  N1---H1N···O3^i^      0.86      2.07      2.8938 (17)   160
  N2---H2N···O6^ii^     0.86      2.09      2.9263 (17)   164
  O2---H2A···O1         0.82      1.68      2.4979 (15)   175
  O5---H5A···O4         0.82      1.68      2.4846 (15)   166
  C7---H7···Cg2         0.93      2.77      3.6745 (15)   163
  C18---H18···O5^iii^   0.93      2.58      3.4186 (19)   151
  C20---H20···O4        0.93      2.46      2.8477 (18)   105
  --------------------- --------- --------- ------------- ---------------

Symmetry codes: (i) *x*−1/2, *y*, −*z*+1/2; (ii) *x*−1/2, *y*, −*z*+3/2; (iii) *x*−1/2, −*y*+1/2, −*z*+1.

###### Hydrogen-bond geometry (Å, °)

  *D*---H⋯*A*         *D*---H   H⋯*A*   *D*⋯*A*       *D*---H⋯*A*
  ------------------- --------- ------- ------------- -------------
  N1---H1*N*⋯O3^i^    0.86      2.07    2.8938 (17)   160
  N2---H2*N*⋯O6^ii^   0.86      2.09    2.9263 (17)   164
  O2---H2*A*⋯O1       0.82      1.68    2.4979 (15)   175
  O5---H5*A*⋯O4       0.82      1.68    2.4846 (15)   166
  C7---H7⋯*Cg*2       0.93      2.77    3.6745 (15)   163
  C18---H18⋯O5^iii^   0.93      2.58    3.4186 (19)   151

Symmetry codes: (i) ; (ii) ; (iii) . *Cg*2 is the centroid of the C15--C20 ring.