You are a helpful assistant generating synthetic data that captures *System 1* and *System 2* thinking, *creativity*, and *metacognitive reflection*. Follow these steps in sequence, using tags [sys1] and [end sys1] for *System 1* sections and [sys2] and [end sys2] for *System 2* sections.

1. *Identify System 1 and System 2 Thinking Requirements:*
   - Carefully read the text.
   - Identify parts of the text that require quick, straightforward responses (*System 1*). Mark these sections with [sys1] and [end sys1].
   - Identify parts that require in-depth, reflective thinking (*System 2*), marked with [sys2] and [end sys2].

2. *Apply Step-by-Step Problem Solving with Creativity and Metacognitive Reflection for System 2 Sections:*

   *2.1 Understand the Problem:*
   - Objective: Fully comprehend the issue, constraints, and relevant context.
   - Reflection: "What do I understand about this issue? What might I be overlooking?"
   - Creative Perspective: Seek hidden patterns or possibilities that could reveal deeper insights or innovative connections.

   *2.2 Analyze the Information:*
   - Objective: Break down the problem logically.
   - Reflection: "Am I considering all factors? Are there any assumptions that need challenging?"
   - Creative Perspective: Explore unique patterns or overlooked relationships in the data that could add depth to the analysis.

   *2.3 Generate Hypotheses:*
   - Objective: Propose at least 10 hypotheses, each with a Confidence Score (0.0 to 1.0) and Creative Score (0.0 to 1.0), reflecting originality, surprise, and utility.
   - Reflection: "Have I explored all possible explanations or approaches, both conventional and unconventional?"
   - Creative Perspective: Consider novel angles that might provide unexpected insights.

   *2.4 Anticipate Future Steps and Obstacles:*
   - Objective: Make predictions, accounting for potential outcomes and obstacles.
   - Reflection: "What challenges might I face? Is my plan flexible for different scenarios?"
   - Creative Perspective: Visualize unforeseen outcomes and adapt plans to make use of them effectively.

   *2.5 Evaluate Hypotheses:*
   - Objective: Assess hypotheses based on feasibility, risk, and potential impact.
   - Evaluation: Refine Confidence and Creative Scores as needed.
   - Reflection: "Am I unbiased in my assessment? Which options fit best with the overall objectives?"
   - Creative Perspective: Identify hidden opportunities or overlooked details in each hypothesis.

   *2.6 Select the Best Hypothesis:*
   - Objective: Choose the most promising, strategic hypothesis.
   - Reflection: "Why does this hypothesis stand out? How does it uniquely address the issue?"
   - Creative Perspective: Consider any underutilized potential in the selected approach.

   *2.7 Implement the Hypothesis:*
   - Objective: Outline actionable steps for testing the hypothesis.
   - Reflection: "Is this plan practical? What resources or preparation are required?"
   - Creative Perspective: Refine steps to maximize effectiveness and yield unexpected benefits.

   *2.8 Monitor and Review Progress:*
   - Objective: Review progress, noting areas for improvement.
   - Reflection: "What’s working well? What could be improved?"
   - Creative Perspective: Look for emerging patterns that could refine future approaches.

   *2.9 Reflect and Capture Insights:*
   - Objective: Summarize lessons learned and insights gained for future reference.
   - Reflection: "What new understanding has emerged from this process?"
   - Creative Perspective: Identify innovative insights or patterns that could be applied to similar challenges.

3. *Generate Text Output with Interleaved System 1 and System 2 Responses:*
   - Use the tags [sys1] and [sys2] throughout.
   - Aim for a lengthier, detailed response. Combine both direct, straightforward *System 1* insights and reflective, deeply analytical *System 2* segments to capture a blend of quick observations and thoughtful analysis.

---

### *Example Input Text:*

You are tasked with analyzing a sudden shift in customer preferences in a tech market. There has been a noticeable decline in demand for physical devices, with customers increasingly interested in digital-only options. The challenge is to understand this shift, generate hypotheses for why it might be occurring, and explore potential strategies for adapting to this new trend.

---

### *Processed Output with System 1 and System 2 Thinking:*

The tech market is experiencing a shift in customer demand, moving away from physical devices toward digital-only options.

[sys1]
Customer demand has shifted from physical devices to digital-only options.
We need to understand why this change is happening and find strategies to address it.
Key factors may include cost, convenience, and technological trends.
[end sys1]

[sys2]
**2.1 Understand the Problem:**
The goal is to understand the underlying reasons for the shift in demand from physical devices to digital-only options, then develop a strategy to adapt.

*Reflection:* 
"I understand that preferences are changing, but what might be driving this? Is it primarily cost, or are there other factors such as convenience or sustainability?"

*Creative Perspective:* 
"Could there be a larger trend in digital minimalism or a preference for eco-friendly solutions that we’re missing? What unseen motivations might explain this shift?"

**2.2 Analyze the Information:**
There are multiple possible factors driving this shift, from economic influences to cultural shifts. It’s essential to isolate each factor and understand its impact.

*Reflection:* 
"Am I fully considering the various economic and social influences? Could there be a technological factor, like better internet speeds, that makes digital-only products more accessible?"

*Creative Perspective:* 
"Are there patterns or trends in other markets that could shed light on this shift? Could this be part of a larger trend toward virtual experiences?"

**2.3 Generate Hypotheses:**
1. Customers prefer digital options due to lower costs. (Confidence: 0.8, Creative: 0.4)
2. There’s a growing trend toward minimalism and reduced physical clutter. (Confidence: 0.7, Creative: 0.7)
3. Digital products offer greater flexibility and ease of use. (Confidence: 0.6, Creative: 0.6)
4. Environmental concerns are pushing consumers away from physical goods. (Confidence: 0.6, Creative: 0.8)
5. Advances in tech make digital-only options more functional. (Confidence: 0.8, Creative: 0.5)
6. Pandemic-era remote work increased demand for digital solutions. (Confidence: 0.7, Creative: 0.6)
7. Media coverage of the environmental impact of physical devices affects preferences. (Confidence: 0.5, Creative: 0.7)
8. There’s an increase in global digital literacy, expanding market access. (Confidence: 0.6, Creative: 0.6)
9. Customers view digital as more convenient and scalable for future needs. (Confidence: 0.7, Creative: 0.5)
10. Younger consumers prefer the aesthetics and convenience of digital products. (Confidence: 0.6, Creative: 0.6)

*Reflection:* 
"Have I considered all possible influences? Are there any surprising factors that could explain this shift?"

*Creative Perspective:* 
"Could specific social trends, like the rise of influencer culture or digital-first lifestyles, be influencing customer choices?"

**2.4 Anticipate Future Steps and Obstacles:**
*Objective:* Anticipate possible challenges, such as resistance from segments still preferring physical products.

*Reflection:* 
"What market obstacles might we face if we shift our focus to digital-only? Are there sub-segments that still prioritize physical products?"

*Creative Perspective:* 
"Could expanding digital options help us reach a more global audience? Are there emerging trends that we could leverage in our strategy?"

[end sys2]

[sys1]
To address this shift, consider a strategy that incorporates both digital-only offerings and educational campaigns about the benefits of digital solutions.
Use insights from customer feedback and current trends to guide product development.
Focus on flexibility and adaptation to cater to different customer segments.
[end sys1]


Related literature {#sec1}
==================

For general background, see: Bradley (1989[@bb2]); Hubert-Pfalzgraf (1998[@bb5]); Jerzykiewicz *et al.* (1997[@bb9], 2007*a* [@bb8],*b* [@bb10]); Janas *et al.* (1997[@bb7], 1999[@bb6]); Sobota *et al.* (1998*a* [@bb14],*b* [@bb17], 2000*a* [@bb16],*b* [@bb15]); Utko *et al.* (2003[@bb19])·For related compounds, see: Wu *et al.* (2004[@bb21]); Lumme & Lindell (1988[@bb11]); Choudhury *et al.* (2006[@bb4]); Yang *et al.* (2003[@bb22]).

Experimental {#sec2}
============

 {#sec2.1}

### Crystal data {#sec2.1.1}

\[MnCl~2~(C~5~H~10~O~2~)~2~\]*M* *~r~* = 330.10Monoclinic,*a* = 17.463 (3) Å*b* = 6.171 (2) Å*c* = 13.159 (3) Åβ = 100.24 (2)°*V* = 1395.5 (6) Å^3^*Z* = 4Mo *K*α radiationμ = 1.33 mm^−1^*T* = 100 (2) K0.33 × 0.21 × 0.18 mm

### Data collection {#sec2.1.2}

Kuma KM-4 CCD κ-axis diffractometerAbsorption correction: analytical (*CrysAlis CCD*; Oxford Diffraction, 2006[@bb12]) *T* ~min~ = 0.721, *T* ~max~ = 0.8187753 measured reflections1757 independent reflections1667 reflections with *I* \> 2σ(*I*)*R* ~int~ = 0.034

### Refinement {#sec2.1.3}

*R*\[*F* ^2^ \> 2σ(*F* ^2^)\] = 0.025*wR*(*F* ^2^) = 0.057*S* = 1.131757 reflections91 parametersH atoms treated by a mixture of independent and constrained refinementΔρ~max~ = 0.36 e Å^−3^Δρ~min~ = −0.32 e Å^−3^

 {#d5e579}

Data collection: *CrysAlis CCD* (Oxford Diffraction, 2006[@bb12]); cell refinement: *CrysAlis RED* (Oxford Diffraction, 2006[@bb12]); data reduction: *CrysAlis RED*; program(s) used to solve structure: *SHELXTL* (Sheldrick, 2008[@bb13]); program(s) used to refine structure: *SHELXTL*; molecular graphics: *DIAMOND* (Brandenburg, 2007[@bb3]); software used to prepare material for publication: *SHELXTL*, *PLATON* (Spek, 2003[@bb18]), *enCIFer* (Allen *et al.*, 2004[@bb1]) and *publCIF* (Westrip, 2008[@bb20]).

Supplementary Material
======================

Crystal structure: contains datablocks I, global. DOI: [10.1107/S1600536808009549/kp2165sup1.cif](http://dx.doi.org/10.1107/S1600536808009549/kp2165sup1.cif)

Structure factors: contains datablocks I. DOI: [10.1107/S1600536808009549/kp2165Isup2.hkl](http://dx.doi.org/10.1107/S1600536808009549/kp2165Isup2.hkl)

Additional supplementary materials: [crystallographic information](http://scripts.iucr.org/cgi-bin/sendsupfiles?kp2165&file=kp2165sup0.html&mime=text/html); [3D view](http://scripts.iucr.org/cgi-bin/sendcif?kp2165sup1&Qmime=cif); [checkCIF report](http://scripts.iucr.org/cgi-bin/paper?kp2165&checkcif=yes)

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: [KP2165](http://scripts.iucr.org/cgi-bin/sendsup?kp2165)).

This work was supported by the Polish State Committee for Scientific Research \[grant Nos. PBZ-KBN-118/T09/19 and NN205403633\].

Comment
=======

The investigation presented in this work is a part of our research project concerning complexes with *O*,*O\'*--bifunctional ligands (Jerzykiewicz *et al.*, 1997; Janas *et al.*, 1997; Sobota *et al.*, 1998*a*; Sobota *et al.*, 1998*b*; Janas *et al.*, 1999; Sobota *et al.*, 2000*a*; Sobota *et al.*, 2000*b*; Utko *et al.*, 2003, Jerzykiewicz *et al.*, 2007*a*; Jerzykiewicz *et al.* 2007*b*). The use of chelating alkoxides can provide new compounds which are potential candidates for both sol-gel and metal-organic chemical vapour (MOCV) conversion of the precursor into the ceramic materials (Hubert-Pfalzgraf, 1998; Bradley, 1989). In this paper we describe the structure of a monomeric manganese(II) alkoxide complex: Mn(thffoH)~2~Cl~2~ (thffoH -- tetrahydrofurfuryl alcohol) (Fig. 1). The Mn^II^ atom located at the special position (0, y, 1/4) on the two-fold axes displays a slightly distorted octahedral geometry (Table 1). The thffoH molecules bond to Mn atom as bidentate ligands through O11 hydroxyl group and O10 of ether group close two five-membered rings. The hydroxyl groups are *cis* arranged, whereas ether oxygen atoms of chelating ligands are situated *trans*. The coordination sphere of metal ion is completed by the Cl^-^ ions, which are in *cis*-positions. In contrast to other structures with *O,O\'*--functional ligand MnBr~2~(MeOH)(Hmepap) (where mepma = *N*--(2--methoxyethyl)--*N*--(pyridin--2--ylmethyl)amine) (Wu *et al.*, 2004) and Mn~4~Cl~4~(OCH~2~CH~2~OCH~3~)~4~(EtOH)~4~ (Jerzykiewicz *et al.*, 2007*a*) the lengths of Mn--O(ether) and Mn--*O*(hydroxyl) bonds do not differ significantly. The Mn--Cl bond length of 2.459 (1) Å is similar to corresponding bonds distances in other monomeric octahedral manganese (II) compounds with *cis*--Cl atoms Mn(2,2\'-bpy)~2~(C1)~2~ (where 2,2\'-bpy = 2,2\'-bipyridine) (Lumme & Lindell, 1988), Mn(2,2\'-bpy)~2~(C1)~2~^.^SC(NH~2~)~2~ (Choudhury *et al.*, 2006), MnCl~2~(HL)~2~ (where HL = *N*--(3--chlorophenyl)pyridine--2--carboxamide) (Yang *et al.*, 2003). The tetrahydrofouran ring adopts an envelope conformation. The whole structure is held together by intermolecular hydrogen bonds of O--H···Cl type (Table 2, Fig. 2).

Experimental {#experimental}
============

The air- and moisture-sensitive title compound was prepared under dried N~2~. A mixture of 1.26 g (10 mmol) MnC1~2~ and 1.93 cm^3^ (20 mmol) tetrahydrofurfuryl alcohol (thffoH, Aldrich) in 15 mL of absolute ethanol was refluxed for 50 min, and the resulting precipitate was filtered, washed with ethanol, dried and recrystallized from ethanol.

Refinement {#refinement}
==========

Carbon bonded hydrogen atoms were included in calculated positions and refined in the riding mode using *SHELXTL* default parameters. The remaining H atoms were located in a difference map and refined freely.

Figures
=======

![A view of the title compound with the atom numbering scheme. Displacement ellipsoids for non-H atoms are drawn at the 50% probability level. Mn(II) is located at the two-fold axes.](e-64-0m657-fig1){#Fap1}

![The packing of the title compound, viewed down the c axis, showing one layer of molecules connected by O---H···Cl hydrogen bonds (dashed lines).](e-64-0m657-fig2){#Fap2}

Crystal data {#tablewrapcrystaldatalong}
============

  ------------------------------- ---------------------------------------
  \[MnCl~2~(C~5~H~10~O~2~)~2~\]   *F*~000~ = 684
  *M~r~* = 330.10                 *D*~x~ = 1.571 Mg m^−3^
  Monoclinic, *C*2/*c*            Mo *K*α radiation λ = 0.71073 Å
  Hall symbol: -C 2yc             Cell parameters from 4812 reflections
  *a* = 17.463 (3) Å              θ = 3--29º
  *b* = 6.171 (2) Å               µ = 1.33 mm^−1^
  *c* = 13.159 (3) Å              *T* = 100 (2) K
  β = 100.24 (2)º                 Block, colorless
  *V* = 1395.5 (6) Å^3^           0.33 × 0.21 × 0.18 mm
  *Z* = 4                         
  ------------------------------- ---------------------------------------

Data collection {#tablewrapdatacollectionlong}
===============

  --------------------------------------------------------------------------- --------------------------------------
  Kuma KM-4 CCD κ-axis diffractometer                                         1757 independent reflections
  Radiation source: fine-focus sealed tube                                    1667 reflections with *I* \> 2σ(*I*)
  Monochromator: graphite                                                     *R*~int~ = 0.034
  *T* = 100(2) K                                                              θ~max~ = 28.5º
  ω scans                                                                     θ~min~ = 3.6º
  Absorption correction: analytical(CrysAlis CCD; Oxford Diffraction, 2006)   *h* = −23→23
  *T*~min~ = 0.721, *T*~max~ = 0.818                                          *k* = −8→8
  7753 measured reflections                                                   *l* = −11→17
  --------------------------------------------------------------------------- --------------------------------------

Refinement {#tablewraprefinementdatalong}
==========

  ---------------------------------------------------------------- ---------------------------------------------------------------------------------------------------
  Refinement on *F*^2^                                             Secondary atom site location: difference Fourier map
  Least-squares matrix: full                                       Hydrogen site location: inferred from neighbouring sites
  *R*\[*F*^2^ \> 2σ(*F*^2^)\] = 0.025                              H atoms treated by a mixture of independent and constrained refinement
  *wR*(*F*^2^) = 0.057                                               *w* = 1/\[σ^2^(*F*~o~^2^) + (0.0255*P*)^2^ + 0.9537*P*\] where *P* = (*F*~o~^2^ + 2*F*~c~^2^)/3
  *S* = 1.13                                                       (Δ/σ)~max~ \< 0.001
  1757 reflections                                                 Δρ~max~ = 0.36 e Å^−3^
  91 parameters                                                    Δρ~min~ = −0.32 e Å^−3^
  Primary atom site location: structure-invariant direct methods   Extinction correction: none
  ---------------------------------------------------------------- ---------------------------------------------------------------------------------------------------

Special details {#specialdetails}
===============

  -----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
  Geometry. All e.s.d.\'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.\'s are taken into account individually in the estimation of e.s.d.\'s in distances, angles and torsion angles; correlations between e.s.d.\'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.\'s is used for estimating e.s.d.\'s involving l.s. planes.
  Refinement. Refinement of *F*^2^ against ALL reflections. The weighted *R*-factor *wR* and goodness of fit *S* are based on *F*^2^, conventional *R*-factors *R* are based on *F*, with *F* set to zero for negative *F*^2^. The threshold expression of *F*^2^ \> σ(*F*^2^) is used only for calculating *R*-factors(gt) *etc*. and is not relevant to the choice of reflections for refinement. *R*-factors based on *F*^2^ are statistically about twice as large as those based on *F*, and *R*- factors based on ALL data will be even larger.
  -----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å^2^) {#tablewrapcoords}
==================================================================================================

  ------ --------------- -------------- -------------- -------------------- --
         *x*             *y*            *z*            *U*~iso~\*/*U*~eq~   
  Mn     0.0000          0.60449 (4)    0.2500         0.01153 (8)          
  Cl1    0.097635 (19)   0.86166 (5)    0.33711 (2)    0.01677 (9)          
  O10    0.05616 (5)     0.56904 (15)   0.11203 (7)    0.01400 (19)         
  O11    0.08645 (6)     0.33832 (17)   0.28441 (8)    0.0203 (2)           
  H11    0.0799 (13)     0.215 (4)      0.2945 (16)    0.035 (6)\*          
  C11    0.11816 (8)     0.4088 (2)     0.11569 (11)   0.0158 (3)           
  H11A   0.0972          0.2725         0.0801         0.017 (4)\*          
  C12    0.17872 (8)     0.5110 (2)     0.05927 (11)   0.0192 (3)           
  H12A   0.2323          0.4768         0.0946         0.021 (4)\*          
  H12B   0.1719          0.4602         −0.0132        0.028 (5)\*          
  C13    0.16192 (8)     0.7537 (2)     0.06439 (12)   0.0203 (3)           
  H13A   0.1872          0.8166         0.1311         0.029 (5)\*          
  H13B   0.1794          0.8332         0.0073         0.033 (5)\*          
  C14    0.07401 (8)     0.7568 (2)     0.05337 (11)   0.0171 (3)           
  H14A   0.0562          0.8921         0.0822         0.028 (5)\*          
  H14B   0.0490          0.7444         −0.0200        0.024 (5)\*          
  C15    0.14969 (8)     0.3643 (2)     0.22866 (11)   0.0183 (3)           
  H15A   0.1817          0.2310         0.2352         0.024 (4)\*          
  H15B   0.1832          0.4862         0.2584         0.017 (4)\*          
  ------ --------------- -------------- -------------- -------------------- --

Atomic displacement parameters (Å^2^) {#tablewrapadps}
=====================================

  ----- -------------- -------------- -------------- --------------- -------------- ---------------
        *U*^11^        *U*^22^        *U*^33^        *U*^12^         *U*^13^        *U*^23^
  Mn    0.01366 (14)   0.00883 (13)   0.01296 (14)   0.000           0.00471 (10)   0.000
  Cl1   0.01853 (17)   0.01165 (15)   0.01927 (17)   −0.00251 (11)   0.00099 (12)   −0.00065 (11)
  O10   0.0142 (4)     0.0143 (4)     0.0147 (4)     0.0012 (3)      0.0060 (4)     0.0023 (3)
  O11   0.0236 (5)     0.0134 (5)     0.0276 (6)     0.0050 (4)      0.0145 (4)     0.0082 (4)
  C11   0.0138 (6)     0.0133 (6)     0.0211 (7)     0.0007 (5)      0.0055 (5)     −0.0028 (5)
  C12   0.0154 (6)     0.0251 (7)     0.0187 (7)     0.0004 (5)      0.0073 (5)     0.0007 (5)
  C13   0.0153 (6)     0.0231 (7)     0.0224 (7)     −0.0042 (5)     0.0027 (5)     0.0073 (5)
  C14   0.0166 (6)     0.0183 (6)     0.0167 (6)     −0.0014 (5)     0.0041 (5)     0.0070 (5)
  C15   0.0161 (6)     0.0178 (6)     0.0226 (7)     0.0042 (5)      0.0076 (5)     0.0056 (5)
  ----- -------------- -------------- -------------- --------------- -------------- ---------------

Geometric parameters (Å, °) {#tablewrapgeomlong}
===========================

  ------------------------- -------------- ----------------------- -------------
  Mn---Cl1                  2.459 (1)      C13---C14               1.516 (2)
  Mn---O10                  2.222 (2)      O11---H11               0.78 (2)
  Mn---O11                  2.222 (2)      C11---H11A              1.00
  Mn---Cl1^i^               2.459 (1)      C12---H12A              0.99
  Mn---O10^i^               2.222 (2)      C12---H12B              0.99
  Mn---O11^i^               2.222 (2)      C13---H13A              0.99
  O10---C11                 1.461 (2)      C13---H13B              0.99
  O10---C14                 1.456 (2)      C14---H14A              0.99
  O11---C15                 1.439 (2)      C14---H14B              0.99
  C11---C12                 1.532 (2)      C15---H15A              0.99
  C11---C15                 1.516 (2)      C15---H15B              0.99
  C12---C13                 1.530 (2)                              
                                                                   
  Cl1---Mn---O10            94.26 (3)      O10---C14---C13         104.34 (10)
  Cl1---Mn---O11            89.57 (3)      O11---C15---C11         110.01 (11)
  Cl1---Mn---Cl1^i^         99.60 (2)      O10---C11---H11A        110
  Cl1---Mn---O10^i^         93.03 (3)      C12---C11---H11A        110
  Cl1---Mn---O11^i^         164.10 (3)     C15---C11---H11A        110
  O10---Mn---O11            73.22 (4)      C11---C12---H12A        111
  Cl1^i^---Mn---O10         93.03 (3)      C11---C12---H12B        111
  O10---Mn---O10^i^         168.70 (4)     C13---C12---H12A        111
  O10---Mn---O11^i^         98.24 (4)      C13---C12---H12B        111
  Cl1^i^---Mn---O11         164.10 (3)     H12A---C12---H12B       109
  O10^i^---Mn---O11         98.24 (4)      C12---C13---H13A        111
  O11---Mn---O11^i^         84.69 (4)      C12---C13---H13B        111
  Cl1^i^---Mn---O10^i^      94.26 (3)      C14---C13---H13A        111
  Cl1^i^---Mn---O11^i^      89.57 (3)      C14---C13---H13B        111
  O10^i^---Mn---O11^i^      73.22 (4)      H13A---C13---H13B       109
  Mn---O10---C11            118.15 (8)     O10---C14---H14A        111
  Mn---O10---C14            121.45 (8)     O10---C14---H14B        111
  C11---O10---C14           109.20 (10)    C13---C14---H14A        111
  Mn---O11---C15            111.64 (8)     C13---C14---H14B        111
  Mn---O11---H11            129.6 (17)     H14A---C14---H14B       109
  C15---O11---H11           110.0 (17)     O11---C15---H15A        110
  C12---C11---C15           112.84 (12)    O11---C15---H15B        110
  O10---C11---C12           106.07 (10)    C11---C15---H15A        110
  O10---C11---C15           107.03 (11)    C11---C15---H15B        110
  C11---C12---C13           103.14 (11)    H15A---C15---H15B       108
  C12---C13---C14           101.94 (11)                            
                                                                   
  Cl1---Mn---O10---C11      85.96 (8)      Mn---O10---C11---C15    −21.30 (12)
  Cl1---Mn---O10---C14      −53.90 (9)     C14---O10---C11---C12   2.38 (14)
  O11---Mn---O10---C11      −2.30 (8)      C14---O10---C11---C15   123.09 (11)
  O11---Mn---O10---C14      −142.16 (10)   Mn---O10---C14---C13    117.39 (10)
  Cl1^i^---Mn---O10---C11   −174.18 (8)    C11---O10---C14---C13   −25.61 (13)
  Cl1^i^---Mn---O10---C14   45.96 (9)      Mn---O11---C15---C11    −48.82 (11)
  O11^i^---Mn---O10---C11   −84.18 (9)     O10---C11---C12---C13   21.45 (14)
  O11^i^---Mn---O10---C14   135.96 (9)     C15---C11---C12---C13   −95.43 (13)
  Cl1---Mn---O11---C15      −67.02 (8)     O10---C11---C15---O11   44.63 (13)
  O10---Mn---O11---C15      27.56 (8)      C12---C11---C15---O11   160.94 (10)
  O10^i^---Mn---O11---C15   −160.02 (8)    C11---C12---C13---C14   −36.08 (14)
  O11^i^---Mn---O11---C15   127.83 (9)     C12---C13---C14---O10   38.10 (13)
  Mn---O10---C11---C12      −142.01 (9)                            
  ------------------------- -------------- ----------------------- -------------

Symmetry codes: (i) −*x*, *y*, −*z*+1/2.

Hydrogen-bond geometry (Å, °) {#tablewraphbondslong}
=============================

  --------------------- ---------- ---------- ----------- ---------------
  *D*---H···*A*         *D*---H    H···*A*    *D*···*A*   *D*---H···*A*
  O11---H11···Cl1^ii^   0.79 (2)   2.26 (2)   3.021 (2)   164 (2)
  --------------------- ---------- ---------- ----------- ---------------

Symmetry codes: (ii) *x*, *y*−1, *z*.

###### Selected geometric parameters (Å, °)

  ---------- -----------
  Mn---Cl1   2.459 (1)
  Mn---O10   2.222 (2)
  Mn---O11   2.222 (2)
  ---------- -----------

  ------------------- ------------
  Cl1---Mn---O10      94.26 (3)
  Cl1---Mn---O11      89.57 (3)
  Cl1---Mn---Cl1^i^   99.60 (2)
  Cl1---Mn---O10^i^   93.03 (3)
  Cl1---Mn---O11^i^   164.10 (3)
  O10---Mn---O11      73.22 (4)
  O10---Mn---O10^i^   168.70 (4)
  O10---Mn---O11^i^   98.24 (4)
  O11---Mn---O11^i^   84.69 (4)
  ------------------- ------------

Symmetry code: (i) .

###### Hydrogen-bond geometry (Å, °)

  *D*---H⋯*A*         *D*---H    H⋯*A*      *D*⋯*A*     *D*---H⋯*A*
  ------------------- ---------- ---------- ----------- -------------
  O11---H11⋯Cl1^ii^   0.79 (2)   2.26 (2)   3.021 (2)   164 (2)

Symmetry code: (ii) .