Luciana started playing at age seven for Club Atlético Fisherton in her native Rosario. She moved to Jockey Club de Rosario six years later. She gradually began training with the junior national team, for which she had to travel every day to Buenos Aires. In her international career she played for Rot Weiss Köln from Germany and for Real Club de Barcelona from Spain. In her country, Luciana played for Quilmes Atlético Club and GEBA, where she won La Liga Nacional (The National League) and the Torneo Metropolitano. In 1997 she was part of the Argentina junior team that won the Pan American Games Junior Championship and the bronze medal at the Hockey Junior World Cup and a year later she made her debut for the Argentina senior team, finishing fourth at the 1998 Hockey World Cup. She was the youngest Argentine to be accepted into the squad when she was just 16.