In the 1890s Charlotte began to experiment with ceramics with the help of partners such as Auguste Delaherche (1857–1940) and (1848–1926). A high relief of "Cérès" was exhibited at the Objets d’Art section of the Salon of the Société Nationale des Beaux-Arts in 1892. She made an imposing statue of Saint Francis that won a silver medal at the Exposition Universelle de 1900. An article on the Besnard couple by Frantz Jourdain appeared in "La Vie heureuse" in 1904, with photographs showing this statue.