His 19th red card came in a 4–3 home defeat to Barcelona, on 23 March 2014. On 26 April, Ramos scored a header against Osasuna in La Liga at the Bernabéu, in a counter-attack which he began with a strong tackle. It was his first goal in La Liga in six months, since his volley against Levante on match-day 8. On 29 April 2014, Ramos scored two headers in four minutes in a 4–0 away win against Bayern Munich in the semi-finals of the Champions League, with the tie ending with a 5–0 aggregate score and Madrid's qualification to the final for the first time in twelve years. Ramos' brace against Bayern (4 minutes) was the fastest brace in UEFA Champions League semi-final history at the time. On 4 May, Ramos scored in the 2–2 draw with Valencia at home in La Liga with another header, scoring in back-to-back league games. Just three days later, Ramos scored his first free-kick for a 1–1 draw away to Valladolid, having scored in three consecutive La Liga matches and scoring four consecutive matches for Real Madrid for the first time. On 24 May, in the Champions League final against Atlético Madrid, he headed home in the 93rd minute to tie the game 1–1, and Real Madrid went on to win 4–1 in extra-time to claim 'La Decima', their tenth trophy in the competition; he was also chosen by fans as Man of the match. Ramos ended 2013–14 with 7 goals, which made it his highest scoring season for Real Madrid at the time.