In March 2014, Rodionova competed at the Cottbus World Cup event with Maria Kharenkova, Polina Fedorova and Daria Spiridonova. She qualified to the uneven bars final in second place and in the final won the silver medal behind Sophie Scheder of Germany. In May 2014, she competed at the European Championships in Sofia, Bulgaria. In qualifications she contributed scores of 13.933 on vault and 14.866 on uneven bars. In the team finals she contributed a score of 13.433 on uneven bars towards the Russian team's bronze medal finish. In August she competed at the Russian Cup and finished fourth with her team and sixth on the uneven bars.