At the Rio Summer Olympics, Puig won the women's singles gold medal by defeating Polona Hercog, Anastasia Pavlyuchenkova, Garbiñe Muguruza, Laura Siegemund, Petra Kvitová, and finally Angelique Kerber. Puig became the second unseeded player to win a medal at the Olympics after Alicia Molik had won bronze in Athens and the first athlete representing Puerto Rico to win a gold medal in any sport. In Puerto Rico's Olympic history, Puig is the ninth sportsperson and the first woman to win an Olympic medal. She is the first Latin American representative to win the gold medal in singles and the second to win a medal, after Gabriela Sabatini won silver at the 1988 Summer Olympics. In November, Puig was presented the award for Best Female Athlete in Rio 2016 presented by the Association of National Olympic Committees (ANOC).