Van Kerkhof competed at the 2014 Winter Olympics for the Netherlands. In the 500 metres she was second in her heat, advancing to a quarter-final, where she finished third, not advancing. In the 1500 metres she again advanced out of the first round, but was fifth in her semi-final, not advancing. She also competed in the 1000 metres, finishing third in her heat. As a member of the Dutch 3000 metre relay team, she was disqualified in the heats, again not advancing. Her best individual finish was in the 500m, where she was 11th.