Sammarinese shooters achieved quota places for the following events by virtue of their best finishes at the 2018 ISSF World Championships, the 2019 ISSF World Cup series, European Championships or Games, and European Qualifying Tournament, as long as they obtained a minimum qualifying score (MQS) by 31 May 2020. On 29 July Alessandra Perilli won bronze in the women's trap shooting, this was San Marino's first ever Olympic medal; Perilli had previously finished joint second but missed out on a medal in a shoot-off during the 2012 Summer Olympics.