Rodríguez played with Antonio Alcinas for the third time in the World Cup of Darts and they qualified from Group D courtesy of a 5–3 win over Italy. They then repeated their 2010 shock win over the Scottish pair of Gary Anderson and Robert Thornton this time 5–4 and faced Richie Burnett and Mark Webster in the quarter-finals. Alcinas lost to Webster 3–4, but Rodríguez beat Burnett by the same scoreline to mean a doubles match was needed to settle the tie. Spain took an early 2–1 lead but went on to be defeated 2–4. In the second round of the 2014 edition of the event, Rodríguez and Alcinas lost their singles matches against the Dutch pair of Michael van Gerwen and Raymond van Barneveld to exit the tournament.