During the War of the Fifth Coalition Prince Hohenlohe led an Austrian infantry division in the IV Corps under Franz Seraph of Orsini-Rosenberg at the Battle of Eckmühl on 22 April 1809. His division consisted of three battalions each of the Infantry Regiments Josef Mittrowsky Nr. 40, Bellegarde Nr. 44 and Chasteler Nr. 46, the 5th and 6th Battalions of the Archduke Karl Legion and 14 artillery pieces. At the Battle of Aspern-Essling on 21–22 May, he led Infantry Regiments Hiller Nr. 2, Czartorisky Nr. 9, Sztaray Nr. 33 and Reuss-Greitz Nr. 55. His division numbered 9,261 infantry and 16 6-pound cannons, The IV Corps was involved in the murderous struggle for the village of Essling. At the Battle of Wagram on 5–6 July he led the Hiller and Sztaray Regiments, a total of 4,479 men. He commanded a division in Ignaz Gyulai's III Austrian Corps during the 1814 Campaign in France. He led his troops during the First Battle of Bar-sur-Aube