Angulo made 434 competitive appearances during his spell at the Mestalla Stadium, being a very important element in the "Che"'s La Liga conquest in 2002 and 2004 (totalling six goals in 48 games), while also starting in the 2004 UEFA Cup final which they won after defeating Olympique de Marseille. Due to the ageing of the previous starter, French Jocelyn Angloma, he played several matches as an attacking right back, as the team operated mainly in a 5–3–2 formation.