In the middle of 2013, it was announced that Carlo Ancelotti would be Real Madrid's head coach for the 2013–14 season. Real Madrid started the season with a 2–1 victory over Real Betis in which Casillas was benched once again. He made his first start in 238 days in the Champions League group stage match against Galatasaray, but was injured in the 14th minute after Sergio Ramos caught him with an accidental elbow as the goalkeeper came from his line to make a routine catch. Despite being the club's second-choice 'keeper in La Liga, behind Diego López, Casillas continued to be Madrid's first choice keeper in the Champions League and Copa del Rey, setting a new record of 962 minutes without conceding a goal in the latter competition. In February 2014, he became the first goalkeeper to play in every round of the Copa del Rey prior to the final without conceding a goal. On 16 April, he captained Madrid in the final as they beat rivals Barcelona 2–1 at Valencia's Mestalla Stadium. On 24 May 2014, Casillas captained Real Madrid in the 2014 Champions League final, winning the title for the third time in his career with a 4–1 win over Atlético Madrid in Lisbon; this was the tenth time Real Madrid had won the trophy. Although Diego Godín's opening goal resulted from an error by Casillas, Sergio Ramos tied the match for Real Madrid in injury time; the club went on to win the title in extra-time.