In the 2013–14 season Di Francisca claimed three silver medals in St Petersburg, Tauberbischofsheim and Turin, as well as a bronze medal in Marseille. At the European Championships in Strasbourg she made her way to the semi-finals where she met Valentina Vezzali. After a cagey beginning which saw the first period end on 1 all, Di Francisca took control of the bout, striking 10 hits in a row and closing on 15–3. In the final she met another Italian, Martina Batini, against whom she had lost in the final at Tauberbischofsheim earlier in the season. Her opponent took a 5–2 lead, but Di Francisca hit 13 times in a row to conquer her third European title. In the team event Italy reached the final without any hassle, but met with strong opposition from Russia, who led most of the match. Chosen to close against Inna Deriglazova, Di Francisca entered the last leg on 38–40 for Russia. Deriglazova gained a 4–0 lead, taking the score to 44–38 with only one hit needed for the victory and 2′04″ to go. Di Francisca hit six times in a row to level the score. She finally struck the winning hit with one second remaining, allowing Italy to retain their European title and taking her second double European gold haul in a row.