In 2001–02, Real failed to win the league after losing out to Valencia. Morientes continued his scoring form, however, scoring 18 league goals in only 25 starts, with six substitute appearances. He also netted five in a 7–0 demolition of UD Las Palmas, missing out on a double hat-trick after missing from the penalty spot late in the match. He finished second in the top scorers list, tied with Patrick Kluivert and behind Deportivo de La Coruña's Diego Tristán, as the "Merengues" were successful in winning the Champions League after beating Bayer 04 Leverkusen – he played in the final and received a third winners medal.