Llorente's first two goals of 2014 came on 12 January, from a header and from close range as Juventus defeated Cagliari 4–1 away to extend their winning league run to 11 matches. On 7 April, he scored both of his team's goals in a 2–0 home win over Livorno, guaranteeing at least second place and Champions League qualification. On the final day of the season, again against Cagliari, he contributed with one goal as Juve won 3–0 and clinched the championship, finishing with a record 102 points in a Serie A season.