Jović started both semi-final and final match of 2019–20 Supercopa de España against Valencia and Atlético Madrid, respectively. Real won the final 4–1 on penalties on 12 January 2020, earning Jović his first trophy as a Real Madrid player. During an injury riddled season, he made 17 appearances during the league season, while scoring two goals, as Real Madrid won the 2019–20 La Liga title.