The peak of Devereaux's career was from 1989 to 1993, with his best season coming in 1992 with the Orioles, when he played in 159 games, with 24 home runs, 107 RBIs and a .276 batting average. Devereaux won the 1995 NLCS MVP award with the Atlanta Braves by driving in the game-winning RBI in the 11th inning of Game One and hitting a three-run home run in Game Four against Cincinnati. The Braves went on to defeat the Cleveland Indians in the World Series.