After greatly impressing in his second spell with Salernitana, Iuliano caught the eye of several major scouts, most notably those of Serie A giants Juventus. In July 1996, Iuliano transferred to the Torino based outfit, and was a big hit right from the start, as Juventus continued their Serie A and European dominance. He made his Serie A début on 15 September 1996, 2–1 win over Cagliari Calcio. In his first season with Juventus he played in 21 league games scoring a single goal in a 1–1 away draw against Atalanta on 23 May 1997, which saw Juventus claim the league title that season.