Santos's most successful Copa Libertadores season started in 1962; the team was seeded in Group One alongside Cerro Porteño and Deportivo Municipal Bolivia, winning every match of their group but one (a 1–1 away tie versus Cerro). Santos defeated Universidad Católica in the semi-finals and met defending champions Peñarol in the finals. Pelé scored twice in the playoff match to secure the first title for a Brazilian club. Pelé finished as the second top scorer of the competition with four goals. That same year, Santos would successfully defend the Campeonato Paulista (with 37 goals from Pelé) and the Taça Brasil (Pelé scoring four goals in the final series against Botafogo). Santos would also win the 1962 Intercontinental Cup against Benfica. Wearing his number 10 shirt, Pelé produced one of the best performances of his career, scoring a hat-trick in Lisbon as Santos won 5–2.