"Psara" and her sisters saw extensive service with the Greek Navy. They participated in the Greco–Turkish War in 1897 until the Great Powers intervened and prevented the Greek Navy from capitalizing on their superiority over the Ottoman Navy. "Psara" saw action in the First Balkan War at the Naval Battle of Elli and was present at the Naval Battle of Lemnos, but was too slow to actively engage the Ottoman forces. She did not see action during World War I, and was reduced to a training ship for stokers after the end of the war. She was ultimately broken up for scrap in 1932.