In the 2019 FA Community Shield against Liverpool on 4 August, Sterling scored the opening goal of the match in an eventual 1–1 draw; Manchester City ultimately won the title 5–4 on penalties. In Manchester City's opening game of the 2019–20 Premier League, Sterling scored a second-half hat-trick – his third of the calendar year – in a 5–0 away win over West Ham, which put them top of the table on goal difference after one game. On 22 October 2019, Sterling scored his first UEFA Champions League hat-trick in a 5–1 win over Atalanta in the group stages of the 2019–20 season.