In the summer of 2001, Thuram made a transfer to Juventus, along with goalkeeper Gianluigi Buffon. Thuram formed defensive partnerships with the likes of Ciro Ferrara, Paolo Montero, Gianluca Pessotto, Mark Iuliano, Alessandro Birindelli, Igor Tudor, Gianluca Zambrotta, Nicola Legrottaglie, Fabio Cannavaro, Giorgio Chiellini, Federico Balzaretti and Jonathan Zebina during his five-year tenure with the club. In his first season with the club, as a right back under Marcello Lippi, Thuram won the 2001–02 Serie A title, also reaching the final of the 2001–02 Coppa Italia. Juventus started the following season by winning the 2002 Supercoppa Italiana, and defended their Serie A title, also reaching the UEFA Champions League final, where they were defeated by rivals Milan on penalties.