In January 2001, he moved to Bundesliga side Bayer Leverkusen. The following season was bittersweet for Leverkusen, as the club surrendered a five-point lead atop the Bundesliga by losing two of its last three matches while Borussia Dortmund swept ahead with three consecutive victories in the final matches to finish a point ahead of Leverkusen. They also experienced defeat in the DFB-Pokal Final, losing 4–2 to Schalke 04, and in the 2002 UEFA Champions League Final against Real Madrid, in which Lúcio cancelled out Raúl's eighth-minute goal just five minutes later with a header, only for Zinedine Zidane to give Real a 2–1 win with a sublime volley just before half-time. Despite the disappointing end to the season, Lúcio's impressive individual displays drew the attention of several of Europe's top clubs. In July 2003, Roma made an official bid, but the deal fell through.