She was made presenter of Sky Sport's three-day event coverage of Formula One motor racing from the 2014 season onwards, and also conducted the pre-season presentations of the Ferrari racing team. Masolin prepared for the role by reviewing the sport's regulations and spoke with colleagues about it. She made her first appearance as presenter at the 2014 Australian Grand Prix, and has built a healthy working and personal relationship with fellow pundits Davide Valsecchi and 1997 world drivers' championship winner Jacques Villeneuve. In 2017, she was named TV Reporter of the Year over fellow broadcaster Giorgia Rossi with 52.4 per cent of the vote. Masolin is an ambassador for the Laureus Sport for Good Foundation and has taken part in charitable events for the foundation. She has been part of the Run That Track community raising money for foundations helping children in Bangladesh, Ghana and South Africa.