Spanish shooters have achieved quota places for the following events by virtue of their best finishes at the 2014 and 2015 ISSF World Championships, the 2015 ISSF World Cup series, and European Championships or Games, as long as they obtained a minimum qualifying score (MQS) by 31 March 2016. The shooting team was named at the conclusion of the European Airgun Championships on 1 March 2016, including London 2012 fifth-place finalist Fátima Gálvez and two-time Olympians Alberto Fernández and Sonia Franquet.