As a member of the International Olympic Committee and the Italian National Olympic Committee (CONI) and as one of Italy's most accomplished Winter Olympic athletes, Di Centa played a prominent public role in the 2006 Winter Olympics in Turin. She was one of the eight flag bearers during the Opening Ceremonies. At the Closing Ceremonies, she participated in the awarding of medals to the winners of the men's 50 km cross-country race. Coincidentally, the gold medal winner was her younger brother Giorgio.