Webster rose to prominence after performing at the opening ceremony of the 2000 Summer Olympics. Her debut studio album, "Follow Your Heart", was released in 2001. The album peaked at on the Australian Top 100 Albums Chart and received platinum certification by the Australian Recording Industry Association. The lead single "Strawberry Kisses" peaked at on the Australian Top 100 Singles Chart and received platinum certification. The album's subsequent singles "Depend on Me" and "The Best Days" reached and , respectively. The following year, Webster released her second studio album, "Bliss". The album peaked at and received gold certification. The lead single "Something More Beautiful" reached and received gold certification. Webster released her third studio album, "Let's Dance", in 2004. The album failed to achieve the commercial success of her previous albums, peaking at . The lead single "Dancing in the Street" reached . Later that year, she released a compilation album, "The Best of Nikki Webster". The album peaked at . As of February 2008, Webster is working on her fourth studio album. The lead single "Devilicious" reached .