Spain qualified two athlete for singles table tennis events. Shen Yanfei qualified for the women's event based on the 2011 world rankings. On 14 April 2012, He Zhi Wen qualified in the European Qualification Tournament for the men's event, and on 14 May 2012 at the World Olympic Qualification Tournament in Doha, Carlos Machado for the men's event; Galia Dvorak and Sara Ramírez completed the Spanish team for the women's team event, and one of them played the women's event too.