He was first appointed to Argentine national team in 2006 before the World League, but he did not play in any match. He began his participation during the World Championship where Argentina took 13th place. His national team won silvers medals at South American Championship in 2007, 2009, 2011, 2013 because four losses to Brazil in the finals. In 2009 and 2011 he was awarded "Best Setter" of South American Championship. In 2011, he achieved a title of the "Best Setter" of the World League. On December 4, 2011 he was "Best Setter" of World Cup. In 2015, Luciano won the gold medal at the 2015 Pan American Games.