At the 2016 Summer Olympics in Rio de Janeiro, Przybylko competed for Germany, along with his fellow countryman Eike Onnen, in the men's high jump. Leading up to his maiden Games, Przybylko jumped a height of 2.30 metres to surpass the IAAF Olympic entry standard (2.29) by a single centimetre at the 2015 Kurpfalz Gala in Weinheim. During the qualifying phase, Przybylko elected to pass 2.17 at his second attempt and remained clean at 2.22, before he could not reach the 2.26-metre barrier with all three misses, ending his Olympic campaign in twenty-eighth place.