On 18 January 2014, he joined Napoli in a co-ownership deal with Verona for four and a half years. On 12 February, he scored the last goal as Napoli overturned a 3–2 first-leg deficit to beat Roma and reach the 2014 Coppa Italia Final. In the final, on 3 May, Jorginho played the full 90 minutes as Napoli defeated Fiorentina 3–1.