He began his senior national team career at the EuroBasket 2003 when Serbia and Montenegro finished with 6th place. Perović has also been a member of the senior men's Serbian national basketball team. With them he won the silver medal at the EuroBasket 2009. In the following year, he was member of team that finished 4th at the World Championship in Turkey. At the EuroBasket 2011 in Lithuania, where he was capped, Serbia finished 8th.