Kimmich played every single minute in all 34 matches in the Bundesliga. In those 34 matches, Kimmich scored two goals and finished second in the league with 13 assists. On 14 August 2020, Kimmich scored one goal and provided an assist in an 8–2 win over Barcelona in the 2019–20 UEFA Champions League quarter-final. On 23 August 2020, Kimmich made an important assist for the winning goal against Paris Saint-Germain by Kingsley Coman in the final, to be his first Champions League title along with his teammate Serge Gnabry, another VfB Stuttgart academy product.