Ukraine qualified ten wrestlers for each of the following classes into the Olympic competition. Five of them finished among the top six to book Olympic spots in the men's freestyle 125 kg, men's Greco-Roman (60 and 87 kg) and women's freestyle (50 and 68 kg) at the 2019 World Championships, while two additional licenses were awarded to the Ukrainian wrestlers, who progressed to the top two finals of the women's freestyle 57 and 62 kg, respectively, at the 2021 European Qualification Tournament in Budapest, Hungary. Three Ukrainian wrestlers claimed one of the remaining slots each in the men's freestyle 74 kg, women's freestyle 76 kg, and men's Greco-Roman 67 kg, respectively, to complete the nation's roster at the 2021 World Qualification Tournament in Sofia, Bulgaria.