Materazzi earned 41 caps for Italy from his debut in 2001 until 2008, playing in two World Cups and two European Championships. He was one of the key players in the 2006 FIFA World Cup Final against France; he gave away an early penalty that led to France's first goal, scored Italy's equalising goal twelve minutes later and, in extra time, received a headbutt from Zinedine Zidane who was punished with a red card. Italy then went on to win the World Cup in a penalty shoot-out, during which Materazzi scored again.