Natalya Petrovna had five children with her husband. Her first son, Pyotr, was born in 1767, but died in 1778. Her second son Boris, born in 1769, became a lieutenant general, before dying in 1813 of wounds he sustained at the Battle of Borodino. Dmitry was born in 1771 and rose to be a statesman and military writer. He married Tatiana Vasilyevna Vasilchikova, with whom he had five children, before his death in 1844. The Golitsyn's two daughters, Ekaterina (1770–1854) and Sofia (1775–1845), married Stepan Stepanovich Apraksin and Pavel Alexandrovich Stroganov respectively, with each having five children. All received excellent educations, and while living in Paris before the revolution it was noted that they spoke French better than they did Russian.