Huybrechts reached his first World Championship through the ProTour Order of Merit and was incredibly drawn to face Kim again. Ronny won the first set and then missed a total of five darts to take the second. In the deciding leg of the third set he missed a single 18 to set up a double, before losing all three legs in the next set to be beaten 3–1. After the event concluded he was ranked world number 41. At the UK Open, Huybrechts saw off Simon Whitlock 9–6 in the third round and then led Adrian Lewis 7–3, but went on to lose in a deciding leg 9–8. Ronny and Kim comfortably progressed to the quarter-finals of the World Cup of Darts where they faced the Dutch number two seeds Michael van Gerwen and Raymond van Barneveld. Kim produced a superb display to defeat Van Gerwen 4–2, but Ronny then lost 4–2 to Van Barneveld meaning the tie went into a deciding doubles match which the brothers lost 4–0. A week later he beat Van Gerwen and Dean Winstanley in deciding legs at the 11th Players Championship to play in his only semi-final of 2014, where he was beaten 6–4 by Robert Thornton. Huybrechts threatened another run at the European Championship when he defeated James Wade in the first round 6–4, but he then lost 10–7 to Mervyn King. In the Grand Slam he went into his final group match against Terry Jenkins knowing a win would see him through to the last 16, but he was beaten 5–1.