Matvere has played many roles, including the musical blockbusters of "Les Misérables" (Javert), "Tanz der Vampire" (Chagal), "The Sound of Music" (Von Trapp) and "Miss Saigon" (Engineer). He has performed the main role in several films (""Georg") and television series. He hosted the Eurovision Song Contest 2002 with Annely Peebo. Also he has hosted TV-show "Songs with Stars" with Karin Rask. He has been a member of the music group "Väikeste lõõtspillide ühing" ("Association of Little Accordions") since 1989 and released two albums with Jaan Tätte.