At the 2014 Winter Olympics Musgrave qualified in 27th place in the individual sprint, the best ever performance by a British cross-country skier, but failed to progress from his quarter-final. He then finished 44th in the 15km classical and 53rd in the 50km freestyle. After the Games Musgrave backed up his victory in the freestyle sprint at the Norwegian championships earlier in the season to win the overall national title.