In the 2013–14 season Kharlan won four World Cups out of seven competitions in which she took part. At the European Championships in Strasbourg she earned her fourth European gold medal in a row and the fifth of her career after defeating Dyachenko again in the final. In the team event she had to rescue her team against underdogs Spain in the quarter-finals, scraping a 45–43 victory, but could not prevent a 45–30 defeat at the hands of France. Kharlan's contribution proved once again decisive in the match against Poland and Ukraine came away with a bronze medal. In the World Championships Kharlan won her second title in a row after prevailing 15–12 over No.2 seed Zagunis. In the team event, Ukraine were defeated by 44–45 by the United States and met Italy for the third place. Again Kharlan came back in the last leg to win her team a bronze medal. She finished the season No.1 in rankings for the second time in a row.