In September 2013, Williams competed at the Nebelhorn Trophy, the final qualifying competition for the 2014 Winter Olympics in Sochi. She placed 8th in the short program and 14th in the free skate, finishing 12th overall. As a result of her placement, Brazil received one of the six remaining spots for countries which had not previously qualified for a ladies' entry. This was the first ever ladies' figure skating Olympics entry for Brazil. Williams finished in last place (30th) at the Olympic contest.