During the third attempt to relieve Mantua, Vukassovich participated in the Tyrol Corps' victories at Cembra on 2 November and the Battle of Calliano on 6–7 November. On the 17th, his troops battled their way out of the Adige River gorge to link up with Joseph Ocskay von Ocsko's column on the heights. Together they routed the French at Rivoli Veronese. After Bonaparte won the Battle of Arcole, the French army commander drove the Tyrol Corps back to Trento. During the fourth attempt to relieve Mantua, Jozsef Alvinczi directed Vukassovich to lead his 6th Column down the east bank of the Adige River. His artillery supported the attack of Prince Heinrich XV of Reuss-Plauen on the west bank of the river, but he exerted little other influence on the disastrous result of the Battle of Rivoli because his troops were on the wrong side of the river.