In January 2016, Ustimkina/Volodin placed fifth at the Russian Junior Championships. In February, they represented Russia at the 2016 Winter Youth Olympics in Hamar, Norway. Ranked third in both segments, they were awarded the bronze medal behind Ekaterina Borisova / Dmitry Sopot and Dušková/Bidař. Assigned to Team Determination for the mixed NOC team event, Ustimkina/Volodin placed third in their segment and their team finished 8th.