The Olympic season 2013–14 began Yuskov with a 3:34.37 at the 3000 meter run in a quartet starts during a training race before the first World Cup race of the season. This is the fastest time ever ridden, but is not recognized as an official world record. Yuskov competed at the 2014 Sochi Olympics, however only 6th place in 5000 m, 17th in men's 1000 m and finished on the 4th place in the 1500 meters. In March 2014, at the 2014 World Allround Speed Skating Championships in Heerenveen, Yuskov won the 1500 meters and took a new personal record in the 10,000 meters. He came 3rd in the allround standings earning him the bronze medal. In early April, at the National championships in Chelyabinsk, he won the gold medal in the 500 m, 1500 m, 5000 m and 10,000 m. Thus, becoming the new undisputed champion in allround of Russia.