Carolin Golubytskyi attended Riemenschneider-Realschule Tauberbischofsheim and the Kaufmännische Schule Tauberbischofsheim. Golubytskyi fought for the Fencing-Club Tauberbischofsheim. She is coached by her husband, Sergei Golubytskyi, a former world class fencer, 3 time consecutive World Champion, and Olympic silver medallist. Golubytskyi was part of the German team winning the bronze medal at the 2009 World Fencing Championships in Antalya, Turkey. She also won three medals at European Championships and participated in the 2008 Summer Olympics in Beijing.