At the 2016 Summer Olympics in Rio de Janeiro, Pasqualucci was selected to compete for the Italian archery squad, shooting in both individual and team tournaments. First, Pasqualucci managed to score 685 points out of a maximum 720 to lead the Italian trio for the third seed heading to the knockout stage, along with his team's score of 2,007 collected from the classification round. Looking forward to defend the men's team recurve title for Italy, Pasqualacci and his compatriots Nespoli and Marco Galiazzo received a bye for the quarterfinals as a third-seeded team, but suffered an untimely defeat to China in a 0–6 upset. Rebounding from his Italian team's quarterfinal exit, Pasqualacci quickly dispatched Malawi's Areneo David in straight sets to book the round two spot in the men's individual recurve, before he bowed out to the Spaniard Antonio Fernández at 2–6.