Orsi Toth and Giombini did not make it out of the qualifiers in five of the six World Tour events they entered in 2012. They were given a wild card into the main draw of the $300K Rome Grand Slam in June as the No. 32 seeds. Despite losing two of their three group stage matches, the pair advanced to the knockout rounds following a forfeit by Canada's Heather Bansley and Elizabeth Maloney, but were defeated in the first round by their fifth-seeded compatriots Greta Cicolari and Marta Menegatti. At the end of the month, Orsi Toth and Giombini were one of two teams—the other being Daniela Gioria and Giulia Momoli—to represent Italy at the FIVB World Cup Olympic Qualification Tournament. Italy advanced to the final country match-up where they lost against the Netherlands, and thus did not win one of the remaining qualification spots for the 2012 Summer Olympics. Orsi Toth and Giombini ended the year 59th in the world rankings.