After his first steps in the chess club of Vitinia, where he was born, he was trained by the Cuban-Italian GM Lexy Ortega, who followed his career until the age of 16, when he became an International Master. In 2006, Vocaturo played with team Italy B at the 37th Chess Olympiad in Turin. His team won a gold medal in their rating category. In 2008, after completing his school studies, he decided to follow in the footsteps of Michele Godena, becoming a professional player. GM Mihail Marin became his new trainer, helping him on the road to achieving his Grandmaster title.