Li beat Mark Joyce in his opening match of the 2013–14 season to reach the first round of the Wuxi Classic where he made three breaks over 50 to establish a 3–0 lead over world number three Judd Trump and went on to seal a 5–2 win, the best of his career so far. He was edged out 5–4 by compatriot Xiao Guodong in the following round. At the UK Championship, Li beat David Gilbert and Andrew Higginson both by 6–4 scorelines to face world number one Neil Robertson in the last 32.&lt;ref name="2013/14"&gt;&lt;/ref&gt; Li gave the Australian a competitive game but lost 6–3, with Robertson stating afterwards that Li was much better than his ranking suggested and that his safety play had particularly impressed him. Li also qualified for the German Masters and China Open but lost 5–3 to ranking event winners Barry Hawkins and Marco Fu. Li whitewashed former world champion Peter Ebdon at the Welsh Open, before being beaten 4–1 by Anthony Hamilton in the last 64. Li was ranked world number 85 at the end of the season.