{"segments": [{"id": 1, "seek": 4794, "start": 20.82, "end": 47.94, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله بتكون المحاضرة الأخيرة لنا في هذا المساق بعد ما اتكلمنا عن تسمية ال heterocycle compounds و الطرق العامة للتحضير و أخدنا أمثلة منتقال بعض الحلقات تحضيرها و تفاعلاتها أخدنا حلقات سداسية و بعدين من الحلقات الخمسية درسنا ال by role", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 39894, 30544, 9673, 5016, 46958, 25720, 16247, 9778, 48923, 5296, 8315, 8978, 23758, 9673, 3794, 995, 4587, 39182, 19446, 1975, 2655, 4117, 19528, 8315, 18871, 6055, 38251, 10632, 2423, 20789, 31078, 2160, 21810, 4032, 41950, 2288, 4587, 18863, 10943, 3660, 24976, 2655, 5016, 11242, 13546, 4032, 5551, 9778, 3215, 8315, 5551, 2304, 12984, 37977, 9154, 2655, 4587, 6027, 45030, 11242, 21542, 1211, 4587, 9307, 6055, 5016, 11242, 13546, 11296, 4032, 6055, 5172, 995, 30241, 9307, 11296, 5551, 9778, 3215, 8315, 11331, 1211, 4587, 9307, 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الحيوية", "tokens": [37746, 6027, 2655, 6027, 1829, 4724, 40228, 1211, 7435, 2407, 11296, 20666, 2304, 11242, 18513, 9307, 21542, 1829, 2407, 10632, 20449, 37893, 2655, 4587, 9307, 36632, 11242, 14111, 995, 11331, 1211, 4587, 9307, 16490, 2304, 3794, 10632, 13672, 1829, 31439, 2423, 18568, 404, 3906, 401, 20449, 3714, 11242, 18513, 9307, 2033, 289, 7804, 20021, 4032, 2012, 5230, 302, 327, 37495, 22653, 4724, 1829, 38251, 2407, 3224, 18863, 1211, 26108, 2423, 15508, 9492, 13672, 1829, 6024, 48506, 3714, 29245, 23328, 23032, 3555, 3615, 14111, 995, 23758, 7251, 47341, 3615, 8978, 3224, 24976, 10721, 9566, 3555, 16606, 44381, 31439, 16490, 20292, 9566, 9154, 9673, 11242, 18513, 9307, 21542, 1829, 2407, 10632], "avg_logprob": -0.17656249431046572, "compression_ratio": 1.6740088105726871, "no_speech_prob": 0.0, "words": [{"start": 162.0, "end": 163.04, "word": "وبالتالي", "probability": 0.9166015625}, {"start": 163.04, "end": 164.28, "word": " بيعلجوها", "probability": 0.8633626302083334}, 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0.76416015625}, {"start": 296.01, "end": 296.25, "word": " أنه", "probability": 0.73486328125}, {"start": 296.25, "end": 296.53, "word": " برضه", "probability": 0.90185546875}, {"start": 296.53, "end": 296.75, "word": " لما", "probability": 0.951904296875}, {"start": 296.75, "end": 297.05, "word": " احنا", "probability": 0.8270670572916666}, {"start": 297.05, "end": 297.65, "word": " أخدنا", "probability": 0.9541015625}], "temperature": 1.0}, {"id": 13, "seek": 31967, "start": 298.53, "end": 319.67, "text": "الـ Pyrrole Synthesis كنا ناخد هدولة التنين لكن نضيف عليهم كمان ايش ال ammonia او ال amine الان لو أخدناهم لوحدهم طبعا مر علينا كيف هذا التفاعل بتم في وجود base الان هذه ال CH2 هي عبارة عن activated", "tokens": [6027, 39184, 430, 6016, 29114, 318, 45601, 9122, 8315, 8717, 47283, 3215, 8032, 3215, 12610, 3660, 16712, 1863, 9957, 44381, 8717, 11242, 33911, 25894, 16095, 9122, 2304, 7649, 1975, 1829, 8592, 2423, 46833, 1975, 2407, 2423, 669, 533, 2423, 7649, 45164, 5551, 9778, 3215, 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"word": " اتتم", "probability": 0.4475911458333333}, {"start": 957.38, "end": 957.68, "word": " هذه", "probability": 0.724609375}, {"start": 957.68, "end": 958.82, "word": " الحركة", "probability": 0.986328125}, {"start": 958.82, "end": 959.14, "word": " هو", "probability": 0.81103515625}, {"start": 959.14, "end": 959.7, "word": " زوج", "probability": 0.9853515625}, {"start": 959.7, "end": 960.52, "word": " الإلكترونات", "probability": 0.9720865885416666}, {"start": 960.52, "end": 960.64, "word": " في", "probability": 0.80908203125}, {"start": 960.64, "end": 960.84, "word": " هذه", "probability": 0.544921875}, {"start": 960.84, "end": 961.32, "word": " الحالة", "probability": 0.98388671875}, {"start": 961.32, "end": 962.24, "word": " بيطرد", "probability": 0.94140625}, {"start": 962.24, "end": 962.78, "word": " البروم", "probability": 0.9703776041666666}, {"start": 962.78, "end": 963.06, "word": " على", "probability": 0.9287109375}, {"start": 963.06, "end": 963.52, "word": " شكل", 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nucleophile", "tokens": [13063, 7435, 3615, 30767, 29245, 1829, 33688, 23275, 2655, 2288, 11536, 9307, 39627, 15730, 25124, 28820, 12602, 7435, 3615, 8315, 5296, 19528, 31747, 3555, 16247, 9381, 20292, 23032, 3555, 3615, 995, 45164, 11933, 7435, 1829, 8315, 8608, 10721, 1211, 8315, 11933, 1829, 8592, 8717, 45367, 33688, 44510, 6027, 23758, 16247, 9778, 13546, 23032, 1211, 3615, 43242, 7578, 11568, 3175, 11933, 7435, 7578, 43242, 7578, 1131, 35735, 23032, 1211, 3615, 2423, 14962, 49242], "avg_logprob": -0.22217466243325848, "compression_ratio": 1.5058823529411764, "no_speech_prob": 0.0, "words": [{"start": 970.9, "end": 971.42, "word": "ورجع", "probability": 0.8624674479166666}, {"start": 971.42, "end": 971.82, "word": " زوجي", "probability": 0.9659830729166666}, {"start": 971.82, "end": 972.66, "word": " الإلكترونات", "probability": 0.8822428385416666}, {"start": 972.66, "end": 973.1, "word": " بهذا", "probability": 0.92626953125}, {"start": 973.1, "end": 973.6, "word": " الشكل", 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Substitution أنا عارف أنه Substitution لكن السؤال أي Substitution ما هو ال Substitution نوعين في Nucleophilic Substitution و في Electrophilic Substitution أنا لما شيلت PR minus و حطيت يعني ال hydrogen مازالوا موجودات ال hydrogen", "tokens": [10721, 1829, 10874, 16606, 2423, 39184, 426, 1311, 306, 49242, 11933, 15730, 34105, 33688, 44510, 6027, 2423, 39184, 426, 1311, 306, 5317, 388, 299, 42090, 6518, 41850, 6225, 9640, 5172, 14739, 3224, 42090, 6518, 44381, 21136, 33604, 6027, 36632, 42090, 6518, 19446, 31439, 2423, 42090, 6518, 8717, 45367, 9957, 8978, 426, 1311, 306, 5317, 388, 299, 42090, 6518, 4032, 8978, 12575, 11741, 388, 299, 42090, 6518, 41850, 5296, 15042, 13412, 26895, 2655, 11568, 3175, 4032, 11331, 9566, 36081, 37495, 22653, 2423, 12697, 3714, 31377, 6027, 14407, 3714, 29245, 23328, 9307, 2423, 12697], "avg_logprob": -0.30930780210802633, "compression_ratio": 1.854368932038835, "no_speech_prob": 0.0, "words": [{"start": 991.56, "end": 991.9, "word": "أي", "probability": 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1725.79, "word": " مش", "probability": 0.9853515625}, {"start": 1725.79, "end": 1726.03, "word": " بس", "probability": 0.954833984375}, {"start": 1726.03, "end": 1726.59, "word": " الإنسان", "probability": 0.9923095703125}, {"start": 1726.59, "end": 1727.31, "word": " بيعمل", "probability": 0.8673095703125}, {"start": 1727.31, "end": 1728.15, "word": " التفاعل", "probability": 0.949951171875}, {"start": 1728.15, "end": 1728.81, "word": " أول", "probability": 0.947265625}, {"start": 1728.81, "end": 1729.09, "word": " مرة", "probability": 0.9921875}, {"start": 1729.09, "end": 1729.23, "word": " و", "probability": 0.9951171875}, {"start": 1729.23, "end": 1729.57, "word": " خلاص", "probability": 0.9484049479166666}, {"start": 1729.57, "end": 1729.77, "word": " لأ", "probability": 0.843505859375}, {"start": 1729.77, "end": 1729.87, "word": " و", "probability": 0.54345703125}, {"start": 1729.87, "end": 1729.99, "word": " الله", "probability": 0.97216796875}, {"start": 1729.99, "end": 1730.43, "word": " طب", "probability": 0.874267578125}, {"start": 1730.43, "end": 1730.67, "word": " أنتوا", "probability": 0.713134765625}, {"start": 1730.67, "end": 1730.99, "word": " عملتوا", "probability": 0.899169921875}, {"start": 1730.99, "end": 1731.69, "word": " التفاعل", "probability": 0.971435546875}, {"start": 1731.69, "end": 1732.89, "word": " لسه", "probability": 0.8251953125}, {"start": 1732.89, "end": 1733.27, "word": " توي", "probability": 0.3360595703125}, {"start": 1733.27, "end": 1733.51, "word": " كنا", "probability": 0.94677734375}, {"start": 1733.51, "end": 1734.39, "word": " بنحكي", "probability": 0.9178466796875}, {"start": 1734.39, "end": 1734.81, "word": " في", "probability": 0.8056640625}, {"start": 1734.81, "end": 1736.05, "word": " abrotic", "probability": 0.6051228841145834}, {"start": 1736.05, "end": 1736.55, "word": " solvent", "probability": 0.94775390625}], "temperature": 1.0}, {"id": 73, "seek": 175561, "start": 1737.55, "end": 1755.61, "text": "طب يا تورا لو عملناها في protein solvent لاحظته قبل شوية كيف التفاعل هنا اتغير ما بين ال protein solvent و ما بين ال protein solvent ما بين الحرارة الضغط الاستعمال catalyst هنا استعملوا Lewis acid", "tokens": [9566, 3555, 35186, 6055, 13063, 995, 45164, 6225, 42213, 8315, 11296, 8978, 7944, 33575, 20193, 5016, 19913, 47395, 12174, 36150, 13412, 2407, 10632, 9122, 33911, 16712, 5172, 995, 30241, 34105, 1975, 2655, 17082, 13546, 19446, 49374, 2423, 7944, 33575, 4032, 19446, 49374, 2423, 7944, 33575, 19446, 49374, 21542, 2288, 9640, 3660, 6024, 114, 17082, 9566, 42963, 14851, 25957, 6027, 23868, 34105, 44713, 25957, 1211, 14407, 17412, 8258], "avg_logprob": -0.238740805974778, "compression_ratio": 1.664804469273743, "no_speech_prob": 0.0, "words": [{"start": 1737.55, "end": 1737.85, "word": "طب", "probability": 0.66748046875}, {"start": 1737.85, "end": 1737.97, "word": " يا", "probability": 0.89013671875}, {"start": 1737.97, "end": 1738.19, "word": " تورا", "probability": 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"probability": 0.6982421875}, {"start": 1748.53, "end": 1748.81, "word": " بين", "probability": 0.98974609375}, {"start": 1748.81, "end": 1749.87, "word": " الحرارة", "probability": 0.98291015625}, {"start": 1749.87, "end": 1750.69, "word": " الضغط", "probability": 0.780029296875}, {"start": 1750.69, "end": 1751.77, "word": " الاستعمال", "probability": 0.93310546875}, {"start": 1751.77, "end": 1752.51, "word": " catalyst", "probability": 0.6337890625}, {"start": 1752.51, "end": 1753.09, "word": " هنا", "probability": 0.80615234375}, {"start": 1753.09, "end": 1754.05, "word": " استعملوا", "probability": 0.853759765625}, {"start": 1754.05, "end": 1754.95, "word": " Lewis", "probability": 0.63916015625}, {"start": 1754.95, "end": 1755.61, "word": " acid", "probability": 0.880859375}], "temperature": 1.0}, {"id": 74, "seek": 177186, "start": 1756.4, "end": 1771.86, "text": "في النهاية حصلوا على 100% yield خلال 48 ساعة، كل أحوال هذه شروط تعتبر سهلة وممتازة، فهذا هو وظيفة الإنسان اللي 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"word": "%", "probability": 0.96484375}, {"start": 1759.32, "end": 1759.8, "word": " yield", "probability": 0.87841796875}, {"start": 1759.8, "end": 1760.82, "word": " خلال", "probability": 0.9931640625}, {"start": 1760.82, "end": 1762.54, "word": " 48", "probability": 0.37109375}, {"start": 1762.54, "end": 1763.9, "word": " ساعة،", "probability": 0.75897216796875}, {"start": 1763.9, "end": 1764.12, "word": " كل", "probability": 0.3486328125}, {"start": 1764.12, "end": 1764.46, "word": " أحوال", "probability": 0.90869140625}, {"start": 1764.46, "end": 1764.64, "word": " هذه", "probability": 0.86083984375}, {"start": 1764.64, "end": 1765.14, "word": " شروط", "probability": 0.8660481770833334}, {"start": 1765.14, "end": 1766.4, "word": " تعتبر", "probability": 0.7705078125}, {"start": 1766.4, "end": 1767.44, "word": " سهلة", "probability": 0.95849609375}, {"start": 1767.44, "end": 1768.5, "word": " وممتازة،", "probability": 0.8809988839285714}, {"start": 1768.5, "end": 1768.92, "word": " 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{"start": 1959.36, "end": 1960.24, "word": " والإيثالين", "probability": 0.648193359375}, {"start": 1960.24, "end": 1961.3, "word": " وانا", "probability": 0.7486979166666666}, {"start": 1961.3, "end": 1962.12, "word": " حصلنا", "probability": 0.9523111979166666}, {"start": 1962.12, "end": 1962.42, "word": " على", "probability": 0.89697265625}, {"start": 1962.42, "end": 1962.72, "word": " a", "probability": 0.439208984375}, {"start": 1962.72, "end": 1963.16, "word": " new", "probability": 0.828125}, {"start": 1963.16, "end": 1964.0, "word": " furan", "probability": 0.792724609375}, {"start": 1964.0, "end": 1965.1, "word": " derivative", "probability": 0.9462890625}, {"start": 1965.1, "end": 1966.06, "word": " فلو", "probability": 0.9630533854166666}, {"start": 1966.06, "end": 1966.56, "word": " أجينا", "probability": 0.7955322265625}, {"start": 1966.56, "end": 1966.82, "word": " و", "probability": 0.62939453125}, {"start": 1966.82, "end": 1967.4, "word": " سألنا", "probability": 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101, "seek": 239385, "start": 2364.99, "end": 2393.85, "text": "في عندنا مثلًا هذا مثلًا هذا تترازولون بـ C double bond O مع الـ Lewisin's reagent تترازول ثيون تترازول ثيون هيتحول لـ C double bond S التحول إلى C double bond S الان ال synthesis التاني", "tokens": [41185, 43242, 8315, 50113, 1211, 14111, 995, 23758, 50113, 1211, 14111, 995, 23758, 6055, 2655, 2288, 31377, 12610, 11536, 4724, 39184, 383, 3834, 6086, 422, 20449, 2423, 39184, 17412, 259, 311, 26949, 317, 6055, 2655, 2288, 31377, 12610, 38637, 1829, 11536, 6055, 2655, 2288, 31377, 12610, 38637, 1829, 11536, 8032, 36081, 5016, 12610, 5296, 39184, 383, 3834, 6086, 318, 16712, 5016, 12610, 30731, 383, 3834, 6086, 318, 2423, 7649, 2423, 30252, 16712, 7649, 1829], "avg_logprob": -0.4124999856948853, "compression_ratio": 1.7579617834394905, "no_speech_prob": 0.0, "words": [{"start": 2364.99, "end": 2365.29, "word": "في", "probability": 0.1279296875}, {"start": 2365.29, "end": 2366.01, "word": " عندنا", "probability": 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Thiophane في الـ Hinsberg Synthesis of Thiophane بناخد احنا 1,2-Diketo System يعني C double bond O متجاورات على موقع واحد واتنين", "tokens": [6027, 20292, 31439, 2423, 39184, 389, 1292, 6873, 318, 45601, 295, 334, 1004, 950, 1929, 8978, 2423, 39184, 389, 1292, 6873, 318, 45601, 295, 334, 1004, 950, 1929, 44945, 47283, 3215, 1975, 5016, 8315, 502, 11, 17, 12, 35, 1035, 19515, 8910, 37495, 22653, 383, 3834, 6086, 422, 44650, 7435, 995, 13063, 9307, 15844, 3714, 30543, 3615, 36764, 24401, 4032, 9307, 1863, 9957], "avg_logprob": -0.33398436242714524, "compression_ratio": 1.3375, "no_speech_prob": 0.0, "words": [{"start": 2394.85, "end": 2395.15, "word": "اللي", "probability": 0.436767578125}, {"start": 2395.15, "end": 2395.45, "word": " هو", "probability": 0.96484375}, {"start": 2395.45, "end": 2395.83, "word": " الـ", "probability": 0.714111328125}, {"start": 2395.83, "end": 2396.39, "word": " Hinsberg", "probability": 0.57666015625}, {"start": 2396.39, "end": 2397.15, "word": " 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ببساطة وهذه صارت double bond وهذه صارت double bond وهنا R وR ايش بيكون شكل الناتج الأخير؟ اتطلعوا معنا، هيكون R وR ع موقع 3 و4 وCO2 إيثل وCO2 إيثل", "tokens": [10721, 8592, 1829, 16606, 11933, 11242, 31845, 10632, 32239, 8592, 28242, 4386, 32239, 8592, 6225, 42213, 28242, 23758, 2423, 28820, 10943, 22807, 45164, 16712, 5172, 995, 30241, 46811, 20666, 9566, 16572, 28671, 13672, 1829, 1975, 5016, 8315, 11331, 4117, 1829, 8315, 11296, 4724, 3555, 3794, 41193, 3660, 37037, 24192, 20328, 9640, 2655, 3834, 6086, 37037, 24192, 20328, 9640, 2655, 3834, 6086, 37037, 8315, 497, 4032, 49, 1975, 1829, 8592, 4724, 1829, 30544, 13412, 28820, 2423, 8315, 2655, 7435, 16247, 9778, 13546, 22807, 1975, 2655, 9566, 1211, 3615, 14407, 20449, 8315, 12399, 8032, 1829, 30544, 497, 4032, 49, 6225, 3714, 30543, 3615, 805, 4032, 19, 4032, 12322, 17, 11933, 1829, 12984, 1211, 4032, 12322, 17, 11933, 1829, 12984, 1211], "avg_logprob": -0.22452731443052532, "compression_ratio": 1.7155555555555555, "no_speech_prob": 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"probability": 0.9483642578125}, {"start": 2478.78, "end": 2479.08, "word": " تم", "probability": 0.9892578125}, {"start": 2479.08, "end": 2479.72, "word": " بالطريقة", "probability": 0.9622802734375}, {"start": 2479.72, "end": 2479.88, "word": " اللي", "probability": 0.873291015625}, {"start": 2479.88, "end": 2480.2, "word": " احنا", "probability": 0.8331705729166666}, {"start": 2480.2, "end": 2481.38, "word": " حكيناها", "probability": 0.9330078125}, {"start": 2481.38, "end": 2482.68, "word": " ببساطة", "probability": 0.863134765625}, {"start": 2482.68, "end": 2483.06, "word": " وهذه", "probability": 0.687744140625}, {"start": 2483.06, "end": 2483.44, "word": " صارت", "probability": 0.93408203125}, {"start": 2483.44, "end": 2483.68, "word": " double", "probability": 0.334716796875}, {"start": 2483.68, "end": 2483.98, "word": " bond", "probability": 0.953125}, {"start": 2483.98, "end": 2484.32, "word": " وهذه", "probability": 0.8369140625}, {"start": 2484.32, "end": 2484.7, "word": " 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107, "seek": 252656, "start": 2500.3, "end": 2526.56, "text": "الان الناتج اللى طلع معه مافيش فيه CO2 إثل على الجهتين هنا في CO2 إثل هنا في عنده CO2 minus واضح و بناء على ذلك صار مضطر انه يحاول يفكر ليش هذه بدل ما تكون CO2 إثل بيانت على شكل CO2 minus في النتيجة", "tokens": [6027, 7649, 2423, 8315, 2655, 7435, 13672, 7578, 23032, 1211, 3615, 20449, 3224, 19446, 41185, 8592, 8978, 3224, 3002, 17, 11933, 12984, 1211, 15844, 25724, 3224, 2655, 9957, 34105, 8978, 3002, 17, 11933, 12984, 1211, 34105, 8978, 43242, 3224, 3002, 17, 3175, 4032, 46958, 5016, 4032, 44945, 16606, 15844, 29910, 23275, 20328, 9640, 3714, 11242, 9566, 2288, 16472, 3224, 7251, 5016, 995, 12610, 7251, 5172, 37983, 32239, 8592, 29538, 47525, 1211, 19446, 6055, 30544, 3002, 17, 11933, 12984, 1211, 4724, 1829, 7649, 2655, 15844, 13412, 28820, 3002, 17, 3175, 8978, 28239, 31371, 7435, 3660], "avg_logprob": -0.16110197337050186, "compression_ratio": 1.7354497354497354, "no_speech_prob": 0.0, "words": [{"start": 2500.3, 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"end": 2514.34, "word": " ذلك", "probability": 0.99462890625}, {"start": 2514.34, "end": 2514.98, "word": " صار", "probability": 0.97412109375}, {"start": 2514.98, "end": 2515.64, "word": " مضطر", "probability": 0.9805908203125}, {"start": 2515.64, "end": 2516.3, "word": " انه", "probability": 0.78662109375}, {"start": 2516.3, "end": 2517.06, "word": " يحاول", "probability": 0.9879150390625}, {"start": 2517.06, "end": 2517.74, "word": " يفكر", "probability": 0.9890950520833334}, {"start": 2517.74, "end": 2518.58, "word": " ليش", "probability": 0.961181640625}, {"start": 2518.58, "end": 2519.06, "word": " هذه", "probability": 0.75439453125}, {"start": 2519.06, "end": 2519.54, "word": " بدل", "probability": 0.938232421875}, {"start": 2519.54, "end": 2519.66, "word": " ما", "probability": 0.837890625}, {"start": 2519.66, "end": 2520.04, "word": " تكون", "probability": 0.986572265625}, {"start": 2520.04, "end": 2521.08, "word": " CO2", "probability": 0.966064453125}, {"start": 2521.08, 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"probability": 0.970703125}], "temperature": 1.0}, {"id": 126, "seek": 297317, "start": 2958.63, "end": 2973.17, "text": "أنشط في الـ Electrophilic Substitution، حكينا هذا الكلام، أن الـ Birol أنشط كتير من الفيوران، الفيوران أنشط من الثيوفين و كلهم أنشط من البنزين", "tokens": [33456, 8592, 9566, 8978, 2423, 39184, 12575, 11741, 388, 299, 42090, 6518, 12399, 11331, 4117, 1829, 8315, 23758, 2423, 28820, 10943, 12399, 14739, 2423, 39184, 363, 5182, 75, 14739, 8592, 9566, 9122, 2655, 13546, 9154, 27188, 1829, 13063, 7649, 12399, 27188, 1829, 13063, 7649, 14739, 8592, 9566, 9154, 6024, 104, 1829, 38688, 9957, 4032, 28242, 16095, 14739, 8592, 9566, 9154, 29739, 1863, 11622, 9957], "avg_logprob": -0.215625, "compression_ratio": 1.5503355704697988, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 2958.63, "end": 2959.57, "word": "أنشط", "probability": 0.69207763671875}, {"start": 2959.57, "end": 2959.71, "word": " في", "probability": 0.89892578125}, {"start": 2959.71, "end": 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ايش addition يعني بالاضافة لل substitution الفيوران اللي بيميز انه بيعمل addition يعني الثيوفين لسه معظم تفاعلاته", "tokens": [6027, 7649, 27188, 1829, 13063, 7649, 20193, 5016, 19913, 19446, 8978, 3714, 15040, 5016, 19913, 3660, 39894, 46456, 46538, 25894, 16095, 16472, 3224, 25961, 31439, 1975, 4117, 49115, 36764, 24401, 4724, 1829, 25957, 1211, 1975, 1829, 8592, 4500, 37495, 22653, 20666, 46958, 31845, 3660, 24976, 35827, 27188, 1829, 13063, 7649, 13672, 1829, 4724, 32640, 1829, 11622, 16472, 3224, 4724, 1829, 25957, 1211, 4500, 37495, 22653, 6024, 104, 1829, 38688, 9957, 5296, 3794, 3224, 20449, 19913, 2304, 6055, 5172, 995, 30241, 9307, 3224], "avg_logprob": -0.1667921715472118, "compression_ratio": 1.7627118644067796, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 2975.4, "end": 2976.52, "word": "الان", "probability": 0.80126953125}, {"start": 2976.52, "end": 2977.64, "word": " الفيوران", "probability": 0.7391357421875}, {"start": 2977.64, "end": 2978.2, "word": " 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"word": " يعني", "probability": 0.888916015625}, {"start": 2989.98, "end": 2990.62, "word": " الثيوفين", "probability": 0.81396484375}, {"start": 2990.62, "end": 2991.32, "word": " لسه", "probability": 0.9664713541666666}, {"start": 2991.32, "end": 2991.86, "word": " معظم", "probability": 0.9915364583333334}, {"start": 2991.86, "end": 2992.82, "word": " تفاعلاته", "probability": 0.9012044270833334}], "temperature": 1.0}, {"id": 128, "seek": 301723, "start": 2993.49, "end": 3017.23, "text": "substitution ال addition فيه قليل اكثر واحد في هدولة التلاتة بيعمل addition اللي هو الفيوران اكثر واحد بيعمل addition اللي هو الفيوران طبعا لو اجينا لل cycle addition وعملنا مقارنة بينهم قولنا ال by role بيعمل cycle addition", "tokens": [30131, 372, 6518, 2423, 4500, 8978, 3224, 12174, 20292, 1211, 1975, 4117, 49115, 36764, 24401, 8978, 8032, 3215, 12610, 3660, 16712, 1211, 9307, 3660, 4724, 1829, 25957, 1211, 4500, 13672, 1829, 31439, 27188, 1829, 13063, 7649, 1975, 4117, 49115, 36764, 24401, 4724, 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"word": " addition", "probability": 0.96337890625}, {"start": 3004.71, "end": 3005.33, "word": " اللي", "probability": 0.983642578125}, {"start": 3005.33, "end": 3005.69, "word": " هو", "probability": 0.98779296875}, {"start": 3005.69, "end": 3007.51, "word": " الفيوران", "probability": 0.9852294921875}, {"start": 3007.51, "end": 3010.37, "word": " طبعا", "probability": 0.9857177734375}, {"start": 3010.37, "end": 3010.71, "word": " لو", "probability": 0.9306640625}, {"start": 3010.71, "end": 3011.13, "word": " اجينا", "probability": 0.8565673828125}, {"start": 3011.13, "end": 3011.37, "word": " لل", "probability": 0.7646484375}, {"start": 3011.37, "end": 3011.71, "word": " cycle", "probability": 0.457763671875}, {"start": 3011.71, "end": 3012.27, "word": " addition", "probability": 0.63525390625}, {"start": 3012.27, "end": 3013.27, "word": " وعملنا", "probability": 0.8629150390625}, {"start": 3013.27, "end": 3014.05, "word": " مقارنة", "probability": 0.982421875}, {"start": 3014.05, "end": 3014.59, "word": " بينهم", "probability": 0.973876953125}, {"start": 3014.59, "end": 3015.11, "word": " قولنا", "probability": 0.7635091145833334}, {"start": 3015.11, "end": 3015.27, "word": " ال", "probability": 0.876953125}, {"start": 3015.27, "end": 3015.47, "word": " by", "probability": 0.2890625}, {"start": 3015.47, "end": 3015.75, "word": " role", "probability": 0.35009765625}, {"start": 3015.75, "end": 3016.27, "word": " بيعمل", "probability": 0.9754638671875}, {"start": 3016.27, "end": 3016.71, "word": " cycle", "probability": 0.83837890625}, {"start": 3016.71, "end": 3017.23, "word": " addition", "probability": 0.9423828125}], "temperature": 1.0}, {"id": 129, "seek": 302988, "start": 3018.38, "end": 3029.88, "text": "قليل جدا، الفيوران لأ بيشتغل كضيين بشكل أساسي، الثيوفين بيشتغل كضيين وبيشتغل كضيين وفاعل", "tokens": [4587, 20292, 1211, 10874, 28259, 12399, 27188, 1829, 13063, 7649, 5296, 10721, 4724, 1829, 8592, 2655, 17082, 1211, 9122, 11242, 1829, 9957, 4724, 8592, 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0.869140625}, {"start": 3114.41, "end": 3114.89, "word": " هيصل", "probability": 0.892822265625}, {"start": 3114.89, "end": 3115.77, "word": " هذا", "probability": 0.6513671875}, {"start": 3115.77, "end": 3116.31, "word": " الكلام", "probability": 0.96435546875}, {"start": 3116.31, "end": 3116.49, "word": " يعني", "probability": 0.748046875}, {"start": 3116.49, "end": 3117.09, "word": " في", "probability": 0.498046875}, {"start": 3117.09, "end": 3117.39, "word": " نهاية", "probability": 0.9046223958333334}, {"start": 3117.39, "end": 3117.91, "word": " نتيجة", "probability": 0.981201171875}, {"start": 3117.91, "end": 3119.09, "word": " تجربية", "probability": 0.8494873046875}, {"start": 3119.09, "end": 3121.13, "word": " الآن", "probability": 0.6787109375}, {"start": 3121.13, "end": 3122.67, "word": " سكروا", "probability": 0.8050130208333334}, {"start": 3122.67, "end": 3123.21, "word": " عليه", "probability": 0.97265625}, {"start": 3123.21, "end": 3125.75, "word": " موقع", "probability": 0.9884440104166666}, {"start": 3125.75, "end": 3126.23, "word": " اتنين", "probability": 0.869384765625}, {"start": 3126.23, "end": 3126.35, "word": " و", "probability": 0.994140625}, {"start": 3126.35, "end": 3127.07, "word": " خمسة", "probability": 0.8922119140625}], "temperature": 1.0}, {"id": 134, "seek": 315073, "start": 3129.37, "end": 3150.73, "text": "و بناءً على ذلك عملوله Acetylation لاحظوا أنه تم التفاعل على موقع تلاتة و تم أيضًا إبدال Electrophilic Substitution على موقع خمسة لاحظوا هنا شيلنا احنا PR Plus و حطينا مكانها", "tokens": [2407, 44945, 16606, 14111, 15844, 29910, 23275, 6225, 42213, 12610, 3224, 5097, 302, 5088, 399, 20193, 5016, 19913, 14407, 14739, 3224, 46811, 16712, 5172, 995, 30241, 15844, 3714, 30543, 3615, 6055, 1211, 9307, 3660, 4032, 46811, 36632, 11242, 14111, 995, 11933, 44510, 6027, 12575, 11741, 388, 299, 42090, 6518, 15844, 3714, 30543, 3615, 16490, 2304, 3794, 3660, 20193, 5016, 19913, 14407, 34105, 13412, 26895, 8315, 1975, 5016, 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"probability": 0.91455078125}, {"start": 3135.07, "end": 3135.67, "word": " على", "probability": 0.90087890625}, {"start": 3135.67, "end": 3136.31, "word": " موقع", "probability": 0.9806315104166666}, {"start": 3136.31, "end": 3137.79, "word": " تلاتة", "probability": 0.8802490234375}, {"start": 3137.79, "end": 3138.21, "word": " و", "probability": 0.6044921875}, {"start": 3138.21, "end": 3138.55, "word": " تم", "probability": 0.96533203125}, {"start": 3138.55, "end": 3139.93, "word": " أيضًا", "probability": 0.892333984375}, {"start": 3139.93, "end": 3140.95, "word": " إبدال", "probability": 0.755126953125}, {"start": 3140.95, "end": 3142.71, "word": " Electrophilic", "probability": 0.88427734375}, {"start": 3142.71, "end": 3143.31, "word": " Substitution", "probability": 0.904296875}, {"start": 3143.31, "end": 3143.55, "word": " على", "probability": 0.853515625}, {"start": 3143.55, "end": 3144.09, "word": " موقع", "probability": 0.9915364583333334}, {"start": 3144.09, "end": 3145.35, "word": " خمسة", "probability": 0.9715576171875}, {"start": 3145.35, "end": 3146.13, "word": " لاحظوا", "probability": 0.9012451171875}, {"start": 3146.13, "end": 3146.49, "word": " هنا", "probability": 0.97802734375}, {"start": 3146.49, "end": 3147.41, "word": " شيلنا", "probability": 0.95849609375}, {"start": 3147.41, "end": 3147.81, "word": " احنا", "probability": 0.7892252604166666}, {"start": 3147.81, "end": 3148.55, "word": " PR", "probability": 0.60888671875}, {"start": 3148.55, "end": 3149.23, "word": " Plus", "probability": 0.2890625}, {"start": 3149.23, "end": 3149.63, "word": " و", "probability": 0.97119140625}, {"start": 3149.63, "end": 3150.05, "word": " حطينا", "probability": 0.8536376953125}, {"start": 3150.05, "end": 3150.73, "word": " مكانها", "probability": 0.98974609375}], "temperature": 1.0}, {"id": 135, "seek": 316334, "start": 3151.32, "end": 3163.34, "text": "C O Methyl Plus يعني هذا الإبدال Electrophilic Substitution زي ما كنا نشيل H Plus و نحط بدالها Electrophile هنا shall be R Plus هنا يمكن نستعمل كلمة", "tokens": [34, 422, 48602, 5088, 7721, 37495, 22653, 23758, 33688, 44510, 6027, 12575, 11741, 388, 299, 42090, 6518, 30767, 1829, 19446, 9122, 8315, 8717, 8592, 26895, 389, 7721, 4032, 8717, 5016, 9566, 47525, 6027, 11296, 12575, 11741, 794, 34105, 4393, 312, 497, 7721, 34105, 7251, 43020, 8717, 14851, 25957, 1211, 9122, 19528, 3660], "avg_logprob": -0.20857900830934634, "compression_ratio": 1.3012820512820513, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 3151.32, "end": 3151.6, "word": "C", "probability": 0.135009765625}, {"start": 3151.6, "end": 3151.98, "word": " O", "probability": 0.32666015625}, {"start": 3151.98, "end": 3152.48, "word": " Methyl", "probability": 0.71435546875}, {"start": 3152.48, "end": 3152.78, "word": " Plus", "probability": 0.71435546875}, {"start": 3152.78, "end": 3153.04, "word": " يعني", "probability": 0.822998046875}, {"start": 3153.04, "end": 3153.3, "word": " هذا", "probability": 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"probability": 0.8225911458333334}, {"start": 3158.2, "end": 3159.36, "word": " Electrophile", "probability": 0.9251302083333334}, {"start": 3159.36, "end": 3159.84, "word": " هنا", "probability": 0.5322265625}, {"start": 3159.84, "end": 3160.1, "word": " shall", "probability": 0.66357421875}, {"start": 3160.1, "end": 3160.36, "word": " be", "probability": 0.92431640625}, {"start": 3160.36, "end": 3160.6, "word": " R", "probability": 0.95703125}, {"start": 3160.6, "end": 3160.96, "word": " Plus", "probability": 0.8291015625}, {"start": 3160.96, "end": 3161.76, "word": " هنا", "probability": 0.8193359375}, {"start": 3161.76, "end": 3162.04, "word": " يمكن", "probability": 0.983642578125}, {"start": 3162.04, "end": 3162.68, "word": " نستعمل", "probability": 0.869140625}, {"start": 3162.68, "end": 3163.34, "word": " كلمة", "probability": 0.9757486979166666}], "temperature": 1.0}, {"id": 136, "seek": 318282, "start": 3164.36, "end": 3182.82, "text": "Ipso ماعرفش إذا هذه الكلمة مرت عليكم ولا لأ Ipso معناه على نفس الموطن يعني عادة لما بيتم ال substitution في ال aromatic compounds لو افترضنا ان هنا في مجموعة X احنا كنا نقول ان ال substitution ممكن يتم على ال ortho", "tokens": [40, 1878, 78, 19446, 3615, 28480, 8592, 11933, 15730, 29538, 33251, 19528, 3660, 3714, 43500, 25894, 24793, 49429, 5296, 10721, 286, 1878, 78, 20449, 8315, 3224, 15844, 8717, 36178, 9673, 2407, 9566, 1863, 37495, 22653, 6225, 18513, 3660, 5296, 15042, 4724, 36081, 2304, 2423, 35827, 8978, 2423, 45831, 21810, 45164, 1975, 5172, 2655, 43042, 8315, 16472, 34105, 8978, 3714, 7435, 2304, 2407, 27884, 1783, 1975, 5016, 8315, 9122, 8315, 8717, 39648, 16472, 2423, 35827, 3714, 43020, 7251, 39237, 15844, 2423, 19052, 78], "avg_logprob": -0.21103162399257522, "compression_ratio": 1.5885167464114833, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3164.3599999999997, "end": 3165.14, "word": "Ipso", "probability": 0.5474446614583334}, {"start": 3165.14, "end": 3165.92, "word": " ماعرفش", 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"probability": 0.97412109375}, {"start": 3177.58, "end": 3177.66, "word": " ان", "probability": 0.3505859375}, {"start": 3177.66, "end": 3177.9, "word": " هنا", "probability": 0.72998046875}, {"start": 3177.9, "end": 3178.12, "word": " في", "probability": 0.9228515625}, {"start": 3178.12, "end": 3178.9, "word": " مجموعة", "probability": 0.89970703125}, {"start": 3178.9, "end": 3179.3, "word": " X", "probability": 0.61328125}, {"start": 3179.3, "end": 3179.86, "word": " احنا", "probability": 0.8260091145833334}, {"start": 3179.86, "end": 3180.08, "word": " كنا", "probability": 0.989990234375}, {"start": 3180.08, "end": 3180.34, "word": " نقول", "probability": 0.807861328125}, {"start": 3180.34, "end": 3180.48, "word": " ان", "probability": 0.705078125}, {"start": 3180.48, "end": 3180.6, "word": " ال", "probability": 0.966796875}, {"start": 3180.6, "end": 3181.04, "word": " substitution", "probability": 0.9697265625}, {"start": 3181.04, "end": 3181.46, "word": " ممكن", "probability": 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3187.17, "word": " ميتا،", "probability": 0.8712158203125}, {"start": 3187.17, "end": 3187.27, "word": " هذه", "probability": 0.82763671875}, {"start": 3187.27, "end": 3187.71, "word": " بارا،", "probability": 0.9212646484375}, {"start": 3187.71, "end": 3187.89, "word": " طب", "probability": 0.87548828125}, {"start": 3187.89, "end": 3188.03, "word": " لو", "probability": 0.94677734375}, {"start": 3188.03, "end": 3188.41, "word": " الإبدال", "probability": 0.8273111979166666}, {"start": 3188.41, "end": 3188.63, "word": " يجي", "probability": 0.7040201822916666}, {"start": 3188.63, "end": 3188.93, "word": " محل", "probability": 0.8802083333333334}, {"start": 3188.93, "end": 3189.25, "word": " هذه", "probability": 0.865234375}, {"start": 3189.25, "end": 3190.33, "word": " نفسها،", "probability": 0.886962890625}, {"start": 3190.33, "end": 3190.71, "word": " وقتها", "probability": 0.7314453125}, {"start": 3190.71, "end": 3191.33, "word": " بنسميه", "probability": 0.8326416015625}, {"start": 3191.33, "end": 3193.65, "word": " Ipsosubstitution،", "probability": 0.782470703125}, {"start": 3193.65, "end": 3194.89, "word": " واضح؟", "probability": 0.955078125}, {"start": 3194.89, "end": 3196.43, "word": " فكل", "probability": 0.89404296875}, {"start": 3196.43, "end": 3196.67, "word": " هذه", "probability": 0.966796875}, {"start": 3196.67, "end": 3197.31, "word": " الأمثلة", "probability": 0.9842529296875}, {"start": 3197.31, "end": 3197.99, "word": " واضح", "probability": 0.9147135416666666}, {"start": 3197.99, "end": 3198.37, "word": " تمام", "probability": 0.993896484375}, {"start": 3198.37, "end": 3198.67, "word": " أنها", "probability": 0.5028076171875}, {"start": 3198.67, "end": 3199.21, "word": " أمثلة", "probability": 0.9886474609375}, {"start": 3199.21, "end": 3202.07, "word": " تجريبية", "probability": 0.923828125}], "temperature": 1.0}, {"id": 138, "seek": 322806, "start": 3204.24, "end": 3228.06, "text": "طبعا هل ممكن يتم عند الـ nucleophilic substitution أيضا جربوا انهم يفعلوا هذا المركب مع نيوكليوفايل امين جابوا امين و الامين هم نيوكليوفايل في النهاية الامين حل ما حل ايش ال PR minus في المحصلة", "tokens": [9566, 3555, 3615, 995, 8032, 1211, 3714, 43020, 7251, 39237, 43242, 2423, 39184, 14962, 5317, 388, 299, 35827, 36632, 11242, 995, 10874, 25513, 14407, 16472, 16095, 7251, 5172, 30241, 14407, 23758, 9673, 31747, 3555, 20449, 8717, 1829, 2407, 28820, 1829, 38688, 995, 26895, 1975, 2304, 9957, 10874, 16758, 14407, 1975, 2304, 9957, 4032, 2423, 10943, 9957, 8032, 2304, 8717, 1829, 2407, 28820, 1829, 38688, 995, 26895, 8978, 28239, 11296, 10632, 2423, 10943, 9957, 11331, 1211, 19446, 11331, 1211, 1975, 1829, 8592, 2423, 11568, 3175, 8978, 9673, 5016, 36520, 3660], "avg_logprob": -0.295138892200258, "compression_ratio": 1.6546391752577319, "no_speech_prob": 0.0, "words": [{"start": 3204.24, "end": 3204.78, "word": "طبعا", "probability": 0.8604736328125}, {"start": 3204.78, "end": 3205.78, "word": " هل", "probability": 0.81640625}, {"start": 3205.78, 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الامين", "probability": 0.8746744791666666}, {"start": 3223.54, "end": 3224.12, "word": " حل", "probability": 0.73828125}, {"start": 3224.12, "end": 3224.24, "word": " ما", "probability": 0.88720703125}, {"start": 3224.24, "end": 3224.6, "word": " حل", "probability": 0.95361328125}, {"start": 3224.6, "end": 3225.02, "word": " ايش", "probability": 0.6202799479166666}, {"start": 3225.02, "end": 3225.78, "word": " ال", "probability": 0.91259765625}, {"start": 3225.78, "end": 3226.12, "word": " PR", "probability": 0.59228515625}, {"start": 3226.12, "end": 3226.84, "word": " minus", "probability": 0.318603515625}, {"start": 3226.84, "end": 3227.22, "word": " في", "probability": 0.86328125}, {"start": 3227.22, "end": 3228.06, "word": " المحصلة", "probability": 0.85986328125}], "temperature": 1.0}, {"id": 139, "seek": 325773, "start": 3228.47, "end": 3257.73, "text": "عبر ميكانيزم الـ Nucleophilic Substitution زي اللي حكيناها أول ما اتكلمنا عن الـ Chichibabine reaction وغيره بنفس المنطق بإمكانه لـ Nucleophile يهاجمها تتحرك البن تتحرك لاحظوا الـ Nitro اللي هنا ساعد على إتمام الـ Nucleophilic Substitution يمكن أنتم مروا معاكم حتى على البنزين الـ Nucleophilic Substitution كان ممكن وين؟", "tokens": [3615, 26890, 3714, 1829, 41361, 1829, 11622, 2304, 2423, 39184, 426, 1311, 306, 5317, 388, 299, 42090, 6518, 30767, 1829, 13672, 1829, 11331, 4117, 1829, 8315, 11296, 5551, 12610, 19446, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 39184, 761, 480, 897, 455, 533, 5480, 4032, 17082, 13546, 3224, 44945, 36178, 9673, 1863, 9566, 4587, 4724, 28814, 2304, 41361, 3224, 5296, 39184, 426, 1311, 306, 49242, 7251, 3224, 26108, 2304, 11296, 6055, 2655, 5016, 31747, 29739, 1863, 6055, 2655, 5016, 31747, 20193, 5016, 19913, 14407, 2423, 39184, 37942, 340, 13672, 1829, 34105, 8608, 995, 22488, 15844, 11933, 39237, 10943, 2423, 39184, 426, 1311, 306, 5317, 388, 299, 42090, 6518, 7251, 43020, 14739, 39237, 3714, 2288, 14407, 20449, 995, 24793, 11331, 49975, 15844, 29739, 1863, 11622, 9957, 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3241.53, "end": 3242.21, "word": " يهاجمها", "probability": 0.81845703125}, {"start": 3242.21, "end": 3242.87, "word": " تتحرك", "probability": 0.9251708984375}, {"start": 3242.87, "end": 3243.25, "word": " البن", "probability": 0.555419921875}, {"start": 3243.25, "end": 3243.81, "word": " تتحرك", "probability": 0.90966796875}, {"start": 3243.81, "end": 3244.47, "word": " لاحظوا", "probability": 0.81854248046875}, {"start": 3244.47, "end": 3244.59, "word": " الـ", "probability": 0.71142578125}, {"start": 3244.59, "end": 3244.97, "word": " Nitro", "probability": 0.71728515625}, {"start": 3244.97, "end": 3245.11, "word": " اللي", "probability": 0.9501953125}, {"start": 3245.11, "end": 3245.49, "word": " هنا", "probability": 0.921875}, {"start": 3245.49, "end": 3246.79, "word": " ساعد", "probability": 0.9635416666666666}, {"start": 3246.79, "end": 3247.07, "word": " على", "probability": 0.93115234375}, {"start": 3247.07, "end": 3247.63, "word": " إتمام", "probability": 0.8811848958333334}, {"start": 3247.63, "end": 3248.99, "word": " الـ", "probability": 0.52655029296875}, {"start": 3248.99, "end": 3249.73, "word": " Nucleophilic", "probability": 0.93798828125}, {"start": 3249.73, "end": 3250.27, "word": " Substitution", "probability": 0.951416015625}, {"start": 3250.27, "end": 3250.61, "word": " يمكن", "probability": 0.7734375}, {"start": 3250.61, "end": 3250.89, "word": " أنتم", "probability": 0.626220703125}, {"start": 3250.89, "end": 3251.21, "word": " مروا", "probability": 0.705078125}, {"start": 3251.21, "end": 3251.69, "word": " معاكم", "probability": 0.9646809895833334}, {"start": 3251.69, "end": 3252.45, "word": " حتى", "probability": 0.9111328125}, {"start": 3252.45, "end": 3252.69, "word": " على", "probability": 0.83642578125}, {"start": 3252.69, "end": 3253.57, "word": " البنزين", "probability": 0.9698486328125}, {"start": 3253.57, "end": 3254.21, "word": " الـ", "probability": 0.73095703125}, {"start": 3254.21, "end": 3254.89, "word": " Nucleophilic", "probability": 0.943115234375}, {"start": 3254.89, "end": 3255.87, "word": " Substitution", "probability": 0.981689453125}, {"start": 3255.87, "end": 3256.65, "word": " كان", "probability": 0.9716796875}, {"start": 3256.65, "end": 3257.05, "word": " ممكن", "probability": 0.987060546875}, {"start": 3257.05, "end": 3257.73, "word": " وين؟", "probability": 0.85009765625}], "temperature": 1.0}, {"id": 140, "seek": 328784, "start": 3259.88, "end": 3287.84, "text": "أه يعني في البنزين المثال المشهور المثال المشهور اللى بتنفي ال nucleophilic substitution لما يكون عندى Cl و تلاتة نيترو الآن هذه النيترو بتسحب الإلكترونات وبناء على ذلك طالما في كتير مجموعات بتسحب الإلكترونات بإمكان ال nucleophile ييجى يهاجم زى مثلا ال OH minus", "tokens": [10721, 3224, 37495, 22653, 8978, 29739, 1863, 11622, 9957, 9673, 12984, 6027, 9673, 8592, 3224, 13063, 9673, 12984, 6027, 9673, 8592, 3224, 13063, 13672, 7578, 39894, 1863, 41185, 2423, 14962, 5317, 388, 299, 35827, 5296, 15042, 7251, 30544, 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"word": " المثال", "probability": 0.9112955729166666}, {"start": 3262.76, "end": 3263.62, "word": " المشهور", "probability": 0.9871826171875}, {"start": 3263.62, "end": 3264.36, "word": " المثال", "probability": 0.8408203125}, {"start": 3264.36, "end": 3264.92, "word": " المشهور", "probability": 0.991455078125}, {"start": 3264.92, "end": 3265.06, "word": " اللى", "probability": 0.6871337890625}, {"start": 3265.06, "end": 3265.58, "word": " بتنفي", "probability": 0.6392415364583334}, {"start": 3265.58, "end": 3266.06, "word": " ال", "probability": 0.82666015625}, {"start": 3266.06, "end": 3266.76, "word": " nucleophilic", "probability": 0.7430419921875}, {"start": 3266.76, "end": 3267.3, "word": " substitution", "probability": 0.83642578125}, {"start": 3267.3, "end": 3267.52, "word": " لما", "probability": 0.932373046875}, {"start": 3267.52, "end": 3267.74, "word": " يكون", "probability": 0.971923828125}, {"start": 3267.74, "end": 3268.08, "word": " عندى", "probability": 0.8974609375}, {"start": 3268.08, "end": 3268.62, "word": " Cl", "probability": 0.40087890625}, {"start": 3268.62, "end": 3270.14, "word": " و", "probability": 0.6357421875}, {"start": 3270.14, "end": 3270.88, "word": " تلاتة", "probability": 0.78363037109375}, {"start": 3270.88, "end": 3271.56, "word": " نيترو", "probability": 0.8361002604166666}, {"start": 3271.56, "end": 3272.78, "word": " الآن", "probability": 0.6207275390625}, {"start": 3272.78, "end": 3273.62, "word": " هذه", "probability": 0.5263671875}, {"start": 3273.62, "end": 3274.06, "word": " النيترو", "probability": 0.769287109375}, {"start": 3274.06, "end": 3274.7, "word": " بتسحب", "probability": 0.9561767578125}, {"start": 3274.7, "end": 3275.76, "word": " الإلكترونات", "probability": 0.8740234375}, {"start": 3275.76, "end": 3276.52, "word": " وبناء", "probability": 0.8544921875}, {"start": 3276.52, "end": 3276.84, "word": " على", "probability": 0.85693359375}, {"start": 3276.84, "end": 3277.26, "word": " ذلك", "probability": 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"end": 3773.0, "text": "الـ aromatic system مش كأنها ضمن منظومة الـ aromatic system فمش مقدسة الـ aromaticity عنده الآن هنا في عندنا مرة تالتة أو رابعة أو خامسة ثيوفين مع ال triple bond هيعمل و هنا لو قلنا carbon carbon", "tokens": [6027, 39184, 45831, 1185, 37893, 9122, 33456, 11296, 48812, 27842, 9154, 19913, 20498, 3660, 2423, 39184, 45831, 1185, 6156, 2304, 8592, 3714, 28543, 3794, 3660, 2423, 39184, 45831, 507, 43242, 3224, 6024, 48506, 34105, 8978, 43242, 8315, 3714, 25720, 6055, 6027, 2655, 3660, 34051, 12602, 16758, 27884, 34051, 16490, 10943, 3794, 3660, 38637, 1829, 38688, 9957, 20449, 2423, 15508, 6086, 39896, 25957, 1211, 4032, 34105, 45164, 12174, 1211, 8315, 5954, 5954], "avg_logprob": -0.20659722801711825, "compression_ratio": 1.6742857142857144, "no_speech_prob": 0.0, "words": [{"start": 3745.52, "end": 3745.88, "word": "الـ", "probability": 0.5311279296875}, {"start": 3745.88, "end": 3746.28, "word": " aromatic", "probability": 0.6572265625}, {"start": 3746.28, "end": 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في الأساس اللي مستعمله تترا مثل ثيوفين عليه أربع مجموعات مثل مش مشكلة وهي مع Acetylene derivative أو دايسيانو أسيتيلين", "tokens": [17, 1804, 568, 10295, 66, 2907, 67, 849, 23032, 3555, 3615, 995, 2423, 12984, 1829, 38688, 9957, 8978, 16247, 3794, 32277, 13672, 1829, 3714, 14851, 25957, 43761, 6055, 2655, 23557, 50113, 1211, 38637, 1829, 38688, 9957, 47356, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 50113, 1211, 37893, 37893, 28820, 3660, 37037, 1829, 20449, 5097, 2210, 21323, 13760, 34051, 11778, 47302, 3794, 1829, 7649, 2407, 5551, 3794, 36081, 26895, 9957], "avg_logprob": -0.2407570435127742, "compression_ratio": 1.4114285714285715, "no_speech_prob": 0.0, "words": [{"start": 3775.65, "end": 3777.05, "word": "2", "probability": 0.4609375}, {"start": 3777.05, "end": 3777.35, "word": " plus", "probability": 0.26611328125}, {"start": 3777.35, "end": 3781.19, "word": " 2", "probability": 0.9541015625}, {"start": 3781.19, "end": 3782.69, "word": " Cycloaddition", "probability": 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addition حقيقة موجودة على", "tokens": [995, 2655, 5172, 30241, 9122, 11778, 47302, 9957, 38688, 995, 26895, 4032, 1975, 2655, 5172, 30241, 9122, 11778, 47302, 9957, 6156, 28820, 5551, 2304, 12984, 37977, 2423, 6586, 4500, 11331, 38436, 28671, 3714, 29245, 23328, 3660, 15844], "avg_logprob": -0.3264802608050798, "compression_ratio": 1.297029702970297, "no_speech_prob": 1.7285346984863281e-06, "words": [{"start": 3821.95, "end": 3822.69, "word": "اتفعل", "probability": 0.637847900390625}, {"start": 3822.69, "end": 3823.07, "word": " ك", "probability": 0.9892578125}, {"start": 3823.07, "end": 3824.77, "word": " دايينوفايل", "probability": 0.7010701497395834}, {"start": 3824.77, "end": 3825.01, "word": " و", "probability": 0.5546875}, {"start": 3825.01, "end": 3825.45, "word": " اتفعل", "probability": 0.9425048828125}, {"start": 3825.45, "end": 3825.85, "word": " ك", "probability": 0.9892578125}, {"start": 3825.85, "end": 3826.91, "word": " دايين", "probability": 0.798828125}, {"start": 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