diff --git "a/PL9fwy3NUQKwZKGFtzoDcohntnVntNPdjS/zENVekzcB0Q_raw.json" "b/PL9fwy3NUQKwZKGFtzoDcohntnVntNPdjS/zENVekzcB0Q_raw.json" new file mode 100644--- /dev/null +++ "b/PL9fwy3NUQKwZKGFtzoDcohntnVntNPdjS/zENVekzcB0Q_raw.json" @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4886, "start": 20.74, "end": 48.86, "text": "بسم الله الرحمن الرحيم في موضوع أمثلة على حلقات معينة بعد ما اتكلمنا عن الحلقات السوداسية أخدنا البريديل، الكوينولين، الايزوكوينولين، فكرة عن ال .. ال byrons in general بننتقل للحلقات الخماسية طبعا أشهر الحلقات الخماسية ال byrol و الفيوران و الثيوفين برضه بناخد فكرة مختصرة عنهم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8978, 3714, 2407, 11242, 45367, 5551, 2304, 12984, 37977, 15844, 11331, 1211, 4587, 9307, 20449, 9957, 3660, 39182, 19446, 1975, 2655, 4117, 19528, 8315, 18871, 21542, 1211, 4587, 9307, 21136, 23328, 32277, 10632, 5551, 9778, 3215, 8315, 2423, 26890, 1829, 16254, 1211, 12399, 33251, 2407, 9957, 12610, 9957, 12399, 42963, 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"word": " عن", "probability": 0.994140625}, {"start": 364.72, "end": 365.52, "word": " البريدين", "probability": 0.8175048828125}, {"start": 365.52, "end": 367.04, "word": " وبنفس", "probability": 0.7823893229166666}, {"start": 367.04, "end": 367.7, "word": " الوقت", "probability": 0.9855143229166666}, {"start": 367.7, "end": 368.22, "word": " هو", "probability": 0.95849609375}, {"start": 368.22, "end": 368.72, "word": " عبارة", "probability": 0.9921875}, {"start": 368.72, "end": 368.92, "word": " عن", "probability": 0.9912109375}, {"start": 368.92, "end": 369.74, "word": " بيريدين", "probability": 0.90234375}, {"start": 369.74, "end": 370.18, "word": " و", "probability": 0.9287109375}, {"start": 370.18, "end": 371.02, "word": " بيروليدين", "probability": 0.8955078125}], "temperature": 1.0}, {"id": 17, "seek": 39458, "start": 371.82, "end": 394.58, "text": "وموجودين على موقع تلاتة على البريدين فهو في النهاية الكلويد من البريدين ومن البروليدين هذه كل المركبات هي عبارة عن مركبات في 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"word": " البروليدين", "probability": 0.9181640625}, {"start": 381.6, "end": 382.24, "word": " هذه", "probability": 0.69873046875}, {"start": 382.24, "end": 382.46, "word": " كل", "probability": 0.951171875}, {"start": 382.46, "end": 383.3, "word": " المركبات", "probability": 0.8236083984375}, {"start": 383.3, "end": 383.46, "word": " هي", "probability": 0.474609375}, {"start": 383.46, "end": 383.8, "word": " عبارة", "probability": 0.994873046875}, {"start": 383.8, "end": 383.98, "word": " عن", "probability": 0.986328125}, {"start": 383.98, "end": 384.78, "word": " مركبات", "probability": 0.9610595703125}, {"start": 384.78, "end": 385.22, "word": " في", "probability": 0.95166015625}, {"start": 385.22, "end": 385.88, "word": " الطبيعة", "probability": 0.9763997395833334}, {"start": 385.88, "end": 386.06, "word": " في", "probability": 0.6923828125}, {"start": 386.06, "end": 386.58, "word": " الحياة", "probability": 0.9892578125}, {"start": 386.58, "end": 386.74, "word": " في", "probability": 0.919921875}, {"start": 386.74, "end": 387.0, "word": " جسم", "probability": 0.980224609375}, {"start": 387.0, "end": 387.5, "word": " الإنسان", "probability": 0.9822998046875}, {"start": 387.5, "end": 387.74, "word": " فيها", "probability": 0.927001953125}, {"start": 387.74, "end": 388.14, "word": " بيرول", "probability": 0.7796223958333334}, {"start": 388.14, "end": 388.84, "word": " ولذلك", "probability": 0.8816731770833334}, {"start": 388.84, "end": 389.04, "word": " احنا", "probability": 0.8567708333333334}, {"start": 389.04, "end": 389.42, "word": " بنقول", "probability": 0.950439453125}, {"start": 389.42, "end": 389.6, "word": " ان", "probability": 0.60302734375}, {"start": 389.6, "end": 389.72, "word": " ال", "probability": 0.88037109375}, {"start": 389.72, "end": 390.34, "word": " بيرول", "probability": 0.7578125}, {"start": 390.34, "end": 391.54, "word": " له", "probability": 0.408447265625}, {"start": 391.54, "end": 392.28, "word": " أهمية", "probability": 0.90625}, {"start": 392.28, "end": 393.82, "word": " خاصة", "probability": 0.9617513020833334}, {"start": 393.82, "end": 394.58, "word": " مميزة", "probability": 0.9884765625}], "temperature": 1.0}, {"id": 18, "seek": 40618, "start": 396.22, "end": 406.18, "text": "الان لو اجينا لتحضير ال buy roll في عندنا ال ignore synthesis شو هو ال ignore synthesis؟", "tokens": [6027, 7649, 45164, 1975, 7435, 1829, 8315, 5296, 2655, 5016, 11242, 13546, 2423, 2256, 3373, 8978, 43242, 8315, 2423, 11200, 30252, 13412, 2407, 31439, 2423, 11200, 30252, 22807], "avg_logprob": -0.3863146633937441, "compression_ratio": 1.2178217821782178, "no_speech_prob": 0.0, "words": [{"start": 396.22, "end": 396.76, "word": "الان", "probability": 0.765625}, {"start": 396.76, "end": 397.06, "word": " لو", "probability": 0.83740234375}, {"start": 397.06, "end": 397.5, "word": " اجينا", "probability": 0.60601806640625}, {"start": 397.5, "end": 398.5, "word": " لتحضير", "probability": 0.94404296875}, {"start": 398.5, "end": 398.66, "word": " ال", "probability": 0.9228515625}, {"start": 398.66, "end": 398.94, "word": " buy", "probability": 0.32177734375}, {"start": 398.94, "end": 399.42, "word": " roll", "probability": 0.638671875}, {"start": 399.42, "end": 400.26, "word": " في", "probability": 0.358154296875}, {"start": 400.26, "end": 400.94, "word": " عندنا", "probability": 0.935791015625}, {"start": 400.94, "end": 401.14, "word": " ال", "probability": 0.324951171875}, {"start": 401.14, "end": 401.6, "word": " ignore", "probability": 0.2265625}, {"start": 401.6, "end": 402.98, "word": " synthesis", "probability": 0.92138671875}, {"start": 402.98, "end": 403.9, "word": " شو", "probability": 0.6285400390625}, {"start": 403.9, "end": 404.0, "word": " هو", "probability": 0.8095703125}, {"start": 404.0, "end": 404.08, "word": " ال", "probability": 0.693359375}, {"start": 404.08, "end": 404.42, "word": " ignore", "probability": 0.85986328125}, {"start": 404.42, "end": 406.18, "word": " synthesis؟", "probability": 0.947265625}], "temperature": 1.0}, {"id": 19, "seek": 42902, "start": 406.62, "end": 429.02, "text": "الأساس لـ Knorr Synthesis كان بيستعمل two equivalents من الـ Ethylacetoacetate واحد بيحوله إلى أكزيم بعدين بيدوبه في Iglesia الacetic من خلال أنه يدوب في Iglesia الacetic أسد مع Sodium Nitrite بيصير أكزيم بيعمل reduction للأكزيم لأمين وبعدين بتفعل مع الجزء التاني", "tokens": [6027, 10721, 3794, 32277, 5296, 39184, 10519, 24362, 318, 45601, 25961, 4724, 1829, 14851, 25957, 1211, 732, 9052, 791, 9154, 2423, 39184, 10540, 5088, 326, 19515, 326, 302, 473, 36764, 24401, 4724, 1829, 5016, 12610, 3224, 30731, 5551, 4117, 11622, 32640, 39182, 9957, 4724, 25708, 37746, 3224, 8978, 19271, 48507, 2423, 326, 3532, 9154, 16490, 1211, 6027, 14739, 3224, 7251, 3215, 37746, 8978, 19271, 48507, 2423, 326, 3532, 5551, 3794, 3215, 20449, 42059, 2197, 37942, 35002, 4724, 1829, 9381, 13546, 5551, 4117, 11622, 32640, 4724, 1829, 25957, 1211, 11004, 24976, 10721, 4117, 11622, 32640, 5296, 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الـ", "probability": 0.6148681640625}, {"start": 411.72, "end": 413.88, "word": " Ethylacetoacetate", "probability": 0.8301827566964286}, {"start": 413.88, "end": 414.66, "word": " واحد", "probability": 0.85986328125}, {"start": 414.66, "end": 415.24, "word": " بيحوله", "probability": 0.95390625}, {"start": 415.24, "end": 415.48, "word": " إلى", "probability": 0.73291015625}, {"start": 415.48, "end": 416.16, "word": " أكزيم", "probability": 0.7255859375}, {"start": 416.16, "end": 417.04, "word": " بعدين", "probability": 0.623046875}, {"start": 417.04, "end": 417.64, "word": " بيدوبه", "probability": 0.7239990234375}, {"start": 417.64, "end": 417.88, "word": " في", "probability": 0.9560546875}, {"start": 417.88, "end": 418.38, "word": " Iglesia", "probability": 0.355377197265625}, {"start": 418.38, "end": 419.18, "word": " الacetic", "probability": 0.6185709635416666}, {"start": 419.18, "end": 420.0, "word": " من", "probability": 0.5439453125}, {"start": 420.0, "end": 420.44, "word": " خلال", "probability": 0.9947916666666666}, {"start": 420.44, "end": 420.64, "word": " أنه", "probability": 0.7060546875}, {"start": 420.64, "end": 420.92, "word": " يدوب", "probability": 0.9552408854166666}, {"start": 420.92, "end": 421.08, "word": " في", "probability": 0.84375}, {"start": 421.08, "end": 421.4, "word": " Iglesia", "probability": 0.8310546875}, {"start": 421.4, "end": 421.78, "word": " الacetic", "probability": 0.92431640625}, {"start": 421.78, "end": 422.08, "word": " أسد", "probability": 0.8426106770833334}, {"start": 422.08, "end": 422.28, "word": " مع", "probability": 0.9775390625}, {"start": 422.28, "end": 422.62, "word": " Sodium", "probability": 0.756591796875}, {"start": 422.62, "end": 423.32, "word": " Nitrite", "probability": 0.688232421875}, {"start": 423.32, "end": 424.06, "word": " بيصير", "probability": 0.9150390625}, {"start": 424.06, "end": 424.58, "word": " أكزيم", "probability": 0.961181640625}, {"start": 424.58, "end": 424.92, "word": " بيعمل", "probability": 0.8359375}, {"start": 424.92, "end": 425.32, "word": " reduction", "probability": 0.89013671875}, {"start": 425.32, "end": 426.1, "word": " للأك��يم", "probability": 0.9505859375}, {"start": 426.1, "end": 427.06, "word": " لأمين", "probability": 0.9068603515625}, {"start": 427.06, "end": 427.62, "word": " وبعدين", "probability": 0.8351236979166666}, {"start": 427.62, "end": 428.04, "word": " بتفعل", "probability": 0.78271484375}, {"start": 428.04, "end": 428.22, "word": " مع", "probability": 0.9892578125}, {"start": 428.22, "end": 428.6, "word": " الجزء", "probability": 0.9851888020833334}, {"start": 428.6, "end": 429.02, "word": " التاني", "probability": 0.9625651041666666}], "temperature": 1.0}, {"id": 20, "seek": 44076, "start": 429.18, "end": 440.76, "text": "هذا الكلام وصفي لو بدنا نشوف الكلام زي ما اتفقنا احنا اكم equivalent بدي من الethyl acetoacetate اتنين الان هاي واحد منهم", "tokens": [3224, 15730, 2423, 28820, 10943, 4032, 9381, 5172, 1829, 45164, 47525, 8315, 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زي", "probability": 0.759765625}, {"start": 433.76, "end": 433.88, "word": " ما", "probability": 0.95166015625}, {"start": 433.88, "end": 434.5, "word": " اتفقنا", "probability": 0.97109375}, {"start": 434.5, "end": 434.72, "word": " احنا", "probability": 0.94921875}, {"start": 434.72, "end": 435.38, "word": " اكم", "probability": 0.74609375}, {"start": 435.38, "end": 435.92, "word": " equivalent", "probability": 0.931640625}, {"start": 435.92, "end": 436.22, "word": " بدي", "probability": 0.46612548828125}, {"start": 436.22, "end": 436.4, "word": " من", "probability": 0.96533203125}, {"start": 436.4, "end": 436.92, "word": " الethyl", "probability": 0.6665445963541666}, {"start": 436.92, "end": 438.22, "word": " acetoacetate", "probability": 0.77255859375}, {"start": 438.22, "end": 439.14, "word": " اتنين", "probability": 0.8699951171875}, {"start": 439.14, "end": 439.68, "word": " الان", "probability": 0.567626953125}, {"start": 439.68, "end": 439.9, "word": " هاي", "probability": 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1405.89, "word": " ليش؟", "probability": 0.7464192708333334}, {"start": 1405.89, "end": 1406.05, "word": " لأن", "probability": 0.81494140625}, {"start": 1406.05, "end": 1406.21, "word": " ال", "probability": 0.46044921875}, {"start": 1406.21, "end": 1406.51, "word": " green", "probability": 0.89697265625}, {"start": 1406.51, "end": 1406.79, "word": " yard", "probability": 0.91552734375}, {"start": 1406.79, "end": 1407.33, "word": " أساسا", "probability": 0.8883056640625}, {"start": 1407.33, "end": 1407.59, "word": " على", "probability": 0.83203125}, {"start": 1407.59, "end": 1408.81, "word": " carbon", "probability": 0.7568359375}, {"start": 1408.81, "end": 1409.87, "word": " MgBr", "probability": 0.9181315104166666}, {"start": 1409.87, "end": 1410.05, "word": " أنا", "probability": 0.537109375}, {"start": 1410.05, "end": 1410.45, "word": " عملته", "probability": 0.9607747395833334}, {"start": 1410.45, "end": 1410.63, "word": " على", "probability": 0.74169921875}, {"start": 1410.63, "end": 1411.05, "word": " إيش؟", "probability": 0.81390380859375}, {"start": 1411.05, "end": 1411.51, "word": " على", "probability": 0.31787109375}, {"start": 1411.51, "end": 1411.59, "word": " ال", "probability": 0.89404296875}, {"start": 1411.59, "end": 1412.05, "word": " nitrogen", "probability": 0.87841796875}, {"start": 1412.05, "end": 1412.53, "word": " مع", "probability": 0.83154296875}, {"start": 1412.53, "end": 1412.73, "word": " ال", "probability": 0.90869140625}, {"start": 1412.73, "end": 1413.11, "word": " lithium", "probability": 0.62744140625}, {"start": 1413.11, "end": 1413.85, "word": " حتى", "probability": 0.910400390625}, {"start": 1413.85, "end": 1414.03, "word": " لو", "probability": 0.994140625}, {"start": 1414.03, "end": 1414.27, "word": " كان", "probability": 0.98876953125}, {"start": 1414.27, "end": 1415.37, "word": " covalent", "probability": 0.742919921875}, {"start": 1415.37, "end": 1416.59, "word": " هو", "probability": 0.36767578125}, {"start": 1416.59, 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"temperature": 1.0}, {"id": 61, "seek": 144460, "start": 1422.76, "end": 1444.6, "text": "زوج الإلكترونات اللي على الـNitrogen الآن هذا زوج الإلكترونات اللي على الـNitrogen بفعله أنا مع الـElectrophile بيشتغل كالـNucleophile يعني مثلا لو فعلته مع الـMethyl Iodide بيجي بيهاجم و بيحل محل اليوت هيعملت Methylation", "tokens": [11622, 29245, 33688, 23275, 2655, 32887, 8315, 2655, 13672, 1829, 15844, 2423, 39184, 45, 270, 7747, 6024, 48506, 23758, 30767, 29245, 33688, 23275, 2655, 32887, 8315, 2655, 13672, 1829, 15844, 2423, 39184, 45, 270, 7747, 4724, 5172, 30241, 3224, 41850, 20449, 2423, 39184, 36, 1809, 11741, 794, 4724, 1829, 8592, 2655, 17082, 1211, 9122, 6027, 39184, 45, 1311, 306, 49242, 37495, 22653, 50113, 15040, 45164, 6156, 30241, 47395, 20449, 2423, 39184, 44, 3293, 5088, 286, 378, 482, 4724, 1829, 7435, 1829, 4724, 1829, 3224, 26108, 2304, 4032, 4724, 1829, 5016, 1211, 3714, 5016, 1211, 45595, 35473, 39896, 25957, 1211, 2655, 48602, 5088, 399], "avg_logprob": -0.23407452596494785, "compression_ratio": 1.7575757575757576, "no_speech_prob": 6.556510925292969e-07, "words": [{"start": 1422.76, "end": 1423.36, "word": "زوج", "probability": 0.926025390625}, {"start": 1423.36, "end": 1424.62, "word": " الإلكترونات", "probability": 0.8086344401041666}, {"start": 1424.62, "end": 1425.04, "word": " اللي", "probability": 0.747314453125}, {"start": 1425.04, "end": 1425.32, "word": " على", "probability": 0.7197265625}, {"start": 1425.32, "end": 1427.18, "word": " الـNitrogen", "probability": 0.67041015625}, {"start": 1427.18, "end": 1427.88, "word": " الآن", "probability": 0.53662109375}, {"start": 1427.88, "end": 1428.34, "word": " هذا", "probability": 0.8330078125}, {"start": 1428.34, "end": 1428.72, "word": " زوج", "probability": 0.988037109375}, {"start": 1428.72, "end": 1429.6, "word": " الإلكترونات", "probability": 0.9710286458333334}, {"start": 1429.6, "end": 1429.74, "word": " اللي", "probability": 0.97021484375}, {"start": 1429.74, "end": 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"end": 1465.01, "text": "لاحظوا معاه لو قلتلكوا how can you prepare الميثل بيرول و ايجي حد قاللي بهذا الشكل بدي اخد ال بيرول مباشرة مع الميثل ايودايد مش حياتي", "tokens": [15040, 5016, 19913, 14407, 20449, 40294, 45164, 12174, 1211, 2655, 23275, 14407, 577, 393, 291, 5940, 9673, 1829, 12984, 1211, 4724, 13546, 12610, 4032, 1975, 1829, 7435, 1829, 11331, 3215, 50239, 20292, 39627, 15730, 25124, 28820, 4724, 16254, 1975, 9778, 3215, 2423, 4724, 13546, 12610, 3714, 3555, 33599, 25720, 20449, 9673, 1829, 12984, 1211, 1975, 1829, 23328, 995, 25708, 37893, 11331, 1829, 9307, 1829], "avg_logprob": -0.33028846153846153, "compression_ratio": 1.5100671140939597, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1445.53, "end": 1446.15, "word": "لاحظوا", "probability": 0.85186767578125}, {"start": 1446.15, "end": 1446.51, "word": " معاه", "probability": 0.5902099609375}, {"start": 1446.51, "end": 1446.81, "word": " لو", "probability": 0.52099609375}, {"start": 1446.81, "end": 1447.35, 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"word": " الشكل", "probability": 0.991455078125}, {"start": 1453.45, "end": 1455.55, "word": " بدي", "probability": 0.655517578125}, {"start": 1455.55, "end": 1457.45, "word": " اخد", "probability": 0.7568359375}, {"start": 1457.45, "end": 1457.99, "word": " ال", "probability": 0.9638671875}, {"start": 1457.99, "end": 1458.87, "word": " بيرول", "probability": 0.7205810546875}, {"start": 1458.87, "end": 1461.95, "word": " مباشرة", "probability": 0.9881591796875}, {"start": 1461.95, "end": 1462.21, "word": " مع", "probability": 0.98974609375}, {"start": 1462.21, "end": 1462.71, "word": " الميثل", "probability": 0.81591796875}, {"start": 1462.71, "end": 1463.53, "word": " ايودايد", "probability": 0.700390625}, {"start": 1463.53, "end": 1464.63, "word": " مش", "probability": 0.5546875}, {"start": 1464.63, "end": 1465.01, "word": " حياتي", "probability": 0.6385498046875}], "temperature": 1.0}, {"id": 63, "seek": 149325, "start": 1466.49, "end": 1493.25, "text": "فانا بعمل بالصوديوم بخلي هذه ال minus و ال minus مع ال methyl iodide واضحة الفكرة اذا صار عندى by role negative ion بعدين بفعلها هاي كمان مرة مع ال methyl iodide اللي هو هذا اللي مع المغنيسيون الشبيه بال green يعني نفس الاشي عمل methylation و ال yield زي ما انتوا شايفين ايش معله ممتازة كل هذه التفاعلات على اي ذرة", "tokens": [5172, 7649, 995, 4724, 25957, 1211, 20666, 9381, 2407, 16254, 20498, 4724, 9778, 20292, 29538, 2423, 3175, 4032, 2423, 3175, 20449, 2423, 48441, 44422, 482, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 1975, 15730, 20328, 9640, 43242, 7578, 538, 3090, 3671, 17437, 39182, 9957, 4724, 5172, 30241, 11296, 8032, 47302, 9122, 2304, 7649, 3714, 25720, 20449, 2423, 48441, 44422, 482, 13672, 1829, 31439, 23758, 13672, 1829, 20449, 9673, 17082, 22653, 3794, 1829, 11536, 25124, 21292, 3224, 20666, 3092, 37495, 22653, 8717, 36178, 2423, 33599, 1829, 6225, 42213, 36599, 24278, 4032, 2423, 11257, 30767, 1829, 19446, 16472, 2655, 14407, 13412, 995, 33911, 9957, 1975, 1829, 8592, 20449, 43761, 3714, 2304, 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"end": 1482.57, "word": " هو", "probability": 0.76025390625}, {"start": 1482.57, "end": 1482.89, "word": " هذا", "probability": 0.470458984375}, {"start": 1482.89, "end": 1483.23, "word": " اللي", "probability": 0.906005859375}, {"start": 1483.23, "end": 1483.47, "word": " مع", "probability": 0.986328125}, {"start": 1483.47, "end": 1484.33, "word": " المغنيسيون", "probability": 0.6510823567708334}, {"start": 1484.33, "end": 1484.91, "word": " الشبيه", "probability": 0.83056640625}, {"start": 1484.91, "end": 1485.03, "word": " بال", "probability": 0.5634765625}, {"start": 1485.03, "end": 1485.31, "word": " green", "probability": 0.315673828125}, {"start": 1485.31, "end": 1485.65, "word": " يعني", "probability": 0.44781494140625}, {"start": 1485.65, "end": 1486.19, "word": " نفس", "probability": 0.991455078125}, {"start": 1486.19, "end": 1486.59, "word": " الاشي", "probability": 0.7369791666666666}, {"start": 1486.59, "end": 1486.95, "word": " عمل", "probability": 0.97607421875}, {"start": 1486.95, "end": 1488.11, "word": " methylation", "probability": 0.938720703125}, {"start": 1488.11, "end": 1488.29, "word": " و", "probability": 0.7744140625}, {"start": 1488.29, "end": 1488.39, "word": " ال", "probability": 0.90966796875}, {"start": 1488.39, "end": 1488.63, "word": " yield", "probability": 0.75439453125}, {"start": 1488.63, "end": 1488.89, "word": " زي", "probability": 0.8828125}, {"start": 1488.89, "end": 1488.97, "word": " ما", "probability": 0.98388671875}, {"start": 1488.97, "end": 1489.19, "word": " انتوا", "probability": 0.8154296875}, {"start": 1489.19, "end": 1489.57, "word": " شايفين", "probability": 0.98681640625}, {"start": 1489.57, "end": 1489.77, "word": " ايش", "probability": 0.66796875}, {"start": 1489.77, "end": 1490.17, "word": " معله", "probability": 0.680908203125}, {"start": 1490.17, "end": 1491.37, "word": " ممتازة", "probability": 0.77900390625}, {"start": 1491.37, "end": 1491.57, "word": " كل", "probability": 0.88037109375}, {"start": 1491.57, "end": 1491.77, "word": " هذه", "probability": 0.7900390625}, {"start": 1491.77, "end": 1492.47, "word": " التفاعلات", "probability": 0.8671875}, {"start": 1492.47, "end": 1492.67, "word": " على", "probability": 0.8701171875}, {"start": 1492.67, "end": 1492.89, "word": " اي", "probability": 0.719482421875}, {"start": 1492.89, "end": 1493.25, "word": " ذرة", "probability": 0.656005859375}], "temperature": 1.0}, {"id": 64, "seek": 152176, "start": 1494.08, "end": 1521.76, "text": "عال Nitrogen لكن لابد لها من خطوة تحضيرية هاي هنا مع ال Acetyl ال Acetyl is a nucleophile ولا لأ CH3C double bond OCl طبعا هيكون التفاعل تفاعل Substitution تحط ل Acetyl عال Nitrogen الآن هنا قملت كمان Electrophilic Substitution ع الحلقة لكن هذا التفاعل عال Nitrogen", "tokens": [3615, 6027, 37942, 7747, 44381, 5296, 16758, 3215, 5296, 11296, 9154, 16490, 9566, 2407, 3660, 6055, 5016, 11242, 13546, 10632, 8032, 47302, 34105, 20449, 2423, 5097, 2210, 75, 2423, 5097, 2210, 75, 307, 257, 14962, 49242, 49429, 5296, 10721, 5995, 18, 34, 3834, 6086, 422, 9966, 23032, 3555, 3615, 995, 39896, 30544, 16712, 5172, 995, 30241, 6055, 5172, 995, 30241, 42090, 6518, 6055, 5016, 9566, 5296, 5097, 2210, 75, 6225, 6027, 37942, 7747, 6024, 48506, 34105, 12174, 2304, 1211, 2655, 9122, 2304, 7649, 12575, 11741, 388, 299, 42090, 6518, 6225, 21542, 1211, 28671, 44381, 23758, 16712, 5172, 995, 30241, 6225, 6027, 37942, 7747], "avg_logprob": -0.2448918312214888, "compression_ratio": 1.6120689655172413, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1494.08, "end": 1494.48, "word": "عال", "probability": 0.600830078125}, {"start": 1494.48, "end": 1495.24, "word": " Nitrogen", "probability": 0.51275634765625}, {"start": 1495.24, "end": 1495.84, "word": " لكن", "probability": 0.71240234375}, {"start": 1495.84, "end": 1496.3, "word": " لابد", "probability": 0.8038736979166666}, {"start": 1496.3, "end": 1496.54, "word": " لها", "probability": 0.921875}, {"start": 1496.54, "end": 1496.7, "word": " من", "probability": 0.9833984375}, {"start": 1496.7, "end": 1497.4, "word": " خطوة", "probability": 0.9822998046875}, {"start": 1497.4, "end": 1498.96, "word": " تحضيرية", "probability": 0.94296875}, {"start": 1498.96, "end": 1499.72, "word": " هاي", "probability": 0.574462890625}, {"start": 1499.72, "end": 1499.92, "word": " هنا", "probability": 0.74658203125}, {"start": 1499.92, "end": 1500.16, "word": " مع", "probability": 0.9697265625}, {"start": 1500.16, "end": 1500.34, "word": " ال", "probability": 0.982421875}, {"start": 1500.34, "end": 1501.1, "word": " Acetyl", "probability": 0.678955078125}, {"start": 1501.1, "end": 1501.66, "word": " ال", "probability": 0.75830078125}, {"start": 1501.66, "end": 1502.22, "word": " Acetyl", "probability": 0.8932291666666666}, {"start": 1502.22, "end": 1502.46, "word": " is", "probability": 0.76220703125}, {"start": 1502.46, "end": 1502.6, "word": " a", "probability": 0.3525390625}, {"start": 1502.6, "end": 1503.38, "word": " nucleophile", "probability": 0.88720703125}, {"start": 1503.38, "end": 1503.62, "word": " ولا", "probability": 0.716796875}, {"start": 1503.62, "end": 1504.04, "word": " لأ", "probability": 0.9287109375}, {"start": 1504.04, "end": 1506.2, "word": " CH3C", "probability": 0.7054036458333334}, {"start": 1506.2, "end": 1506.44, "word": " double", "probability": 0.16455078125}, {"start": 1506.44, "end": 1506.8, "word": " bond", "probability": 0.9296875}, {"start": 1506.8, "end": 1507.76, "word": " OCl", "probability": 0.6551513671875}, {"start": 1507.76, "end": 1508.68, "word": " طبعا", "probability": 0.98388671875}, {"start": 1508.68, "end": 1509.06, "word": " هيكون", "probability": 0.739501953125}, {"start": 1509.06, "end": 1509.58, "word": " التفاعل", "probability": 0.9442138671875}, {"start": 1509.58, "end": 1510.22, "word": " تفاعل", "probability": 0.9119873046875}, {"start": 1510.22, "end": 1512.5, "word": " Substitution", "probability": 0.6923828125}, {"start": 1512.5, "end": 1513.26, "word": " تحط", "probability": 0.8445638020833334}, {"start": 1513.26, "end": 1513.36, "word": " ل", "probability": 0.455810546875}, {"start": 1513.36, "end": 1513.9, "word": " Acetyl", "probability": 0.7662760416666666}, {"start": 1513.9, "end": 1514.14, "word": " عال", "probability": 0.6209716796875}, {"start": 1514.14, "end": 1514.74, "word": " Nitrogen", "probability": 0.827880859375}, {"start": 1514.74, "end": 1515.44, "word": " الآن", "probability": 0.63916015625}, {"start": 1515.44, "end": 1515.7, "word": " هنا", "probability": 0.9306640625}, {"start": 1515.7, "end": 1516.16, "word": " قملت", "probability": 0.69732666015625}, {"start": 1516.16, "end": 1516.58, "word": " كمان", "probability": 0.9599609375}, {"start": 1516.58, "end": 1517.64, "word": " Electrophilic", "probability": 0.926513671875}, {"start": 1517.64, "end": 1518.42, "word": " Substitution", "probability": 0.906005859375}, {"start": 1518.42, "end": 1518.64, "word": " ع", "probability": 0.7001953125}, {"start": 1518.64, "end": 1519.22, "word": " الحلقة", "probability": 0.8860677083333334}, {"start": 1519.22, "end": 1519.94, "word": " لكن", "probability": 0.9306640625}, {"start": 1519.94, "end": 1520.46, "word": " هذا", "probability": 0.92333984375}, {"start": 1520.46, "end": 1521.04, "word": " التفاعل", "probability": 0.96875}, {"start": 1521.04, "end": 1521.26, "word": " عال", "probability": 0.7783203125}, {"start": 1521.26, "end": 1521.76, "word": " Nitrogen", "probability": 0.91650390625}], "temperature": 1.0}, {"id": 65, "seek": 153739, "start": 1522.83, "end": 1537.39, "text": "واضح؟ هاي مع ال بنزويل بنزويل كلورايد فينيل C double bond O Cl مع السالب اللي هنا بس عمل على ال nitrogen ماعملش على الحلقة", "tokens": [2407, 46958, 5016, 22807, 8032, 47302, 20449, 2423, 44945, 11622, 2407, 26895, 44945, 11622, 2407, 26895, 9122, 1211, 13063, 995, 25708, 8978, 22653, 1211, 383, 3834, 6086, 422, 2033, 20449, 21136, 6027, 3555, 13672, 1829, 34105, 4724, 3794, 6225, 42213, 15844, 2423, 17903, 19446, 25957, 1211, 8592, 15844, 21542, 1211, 28671], "avg_logprob": -0.3392427855959305, "compression_ratio": 1.4042553191489362, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1522.83, "end": 1523.71, "word": "واضح؟", "probability": 0.756591796875}, {"start": 1523.71, "end": 1524.03, "word": " هاي", "probability": 0.3931884765625}, {"start": 1524.03, "end": 1524.25, "word": " مع", "probability": 0.89599609375}, {"start": 1524.25, "end": 1524.65, "word": " ال", "probability": 0.83447265625}, {"start": 1524.65, "end": 1525.39, "word": " بنزويل", "probability": 0.62066650390625}, {"start": 1525.39, "end": 1526.25, "word": " بنزويل", "probability": 0.8416748046875}, {"start": 1526.25, "end": 1527.09, "word": " كلورايد", "probability": 0.69296875}, {"start": 1527.09, "end": 1528.43, "word": " فينيل", "probability": 0.5530192057291666}, {"start": 1528.43, "end": 1529.93, "word": " C", "probability": 0.2030029296875}, {"start": 1529.93, "end": 1530.17, "word": " double", "probability": 0.51513671875}, {"start": 1530.17, "end": 1530.57, "word": " bond", "probability": 0.89599609375}, {"start": 1530.57, "end": 1531.01, "word": " O", "probability": 0.9267578125}, {"start": 1531.01, "end": 1531.77, "word": " Cl", "probability": 0.4365234375}, {"start": 1531.77, "end": 1532.41, "word": " مع", "probability": 0.89990234375}, {"start": 1532.41, "end": 1533.11, "word": " السالب", "probability": 0.9132486979166666}, {"start": 1533.11, "end": 1533.31, "word": " اللي", "probability": 0.924560546875}, {"start": 1533.31, "end": 1533.69, "word": " هنا", "probability": 0.810546875}, {"start": 1533.69, "end": 1535.27, "word": " بس", "probability": 0.95068359375}, {"start": 1535.27, "end": 1535.53, "word": " عمل", "probability": 0.9638671875}, {"start": 1535.53, "end": 1535.69, "word": " على", "probability": 0.64111328125}, {"start": 1535.69, "end": 1535.81, "word": " ال", "probability": 0.8896484375}, {"start": 1535.81, "end": 1536.25, "word": " nitrogen", "probability": 0.4384765625}, {"start": 1536.25, "end": 1536.79, "word": " ماعملش", "probability": 0.8677978515625}, {"start": 1536.79, "end": 1536.93, "word": " على", "probability": 0.8876953125}, {"start": 1536.93, "end": 1537.39, "word": " الحلقة", "probability": 0.9860026041666666}], "temperature": 1.0}, {"id": 66, "seek": 156706, "start": 1538.14, "end": 1567.06, "text": "واضح يعني هنا تم إبدال عادي عن نيتروجين و لحظه كمان Electrophilic substitution على الحلقة هنا بس تم عن نيتروجين في نهاية الكيميا إيش علم تجريب يعني شو إفرجت ال acid ال chloride عن ال benzoyl chloride لكن مع ال acid ال chloride طلع عندى إبدال على الحلقة Electrophilic substitution مع ال benzoyl chloride بس الإبدال تم على ال nitrogen الآن", "tokens": [2407, 46958, 5016, 37495, 22653, 34105, 46811, 11933, 3555, 28259, 1211, 6225, 995, 16254, 18871, 8717, 36081, 2288, 29245, 9957, 4032, 5296, 5016, 19913, 3224, 9122, 2304, 7649, 12575, 11741, 388, 299, 35827, 15844, 21542, 1211, 28671, 34105, 4724, 3794, 46811, 18871, 8717, 36081, 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إبدال", "probability": 0.6209716796875}, {"start": 1540.74, "end": 1541.04, "word": " عادي", "probability": 0.88427734375}, {"start": 1541.04, "end": 1541.24, "word": " عن", "probability": 0.90283203125}, {"start": 1541.24, "end": 1541.82, "word": " نيتروجين", "probability": 0.78203125}, {"start": 1541.82, "end": 1542.02, "word": " و", "probability": 0.72998046875}, {"start": 1542.02, "end": 1542.36, "word": " لحظه", "probability": 0.60430908203125}, {"start": 1542.36, "end": 1542.8, "word": " كمان", "probability": 0.9630533854166666}, {"start": 1542.8, "end": 1544.3, "word": " Electrophilic", "probability": 0.812255859375}, {"start": 1544.3, "end": 1544.82, "word": " substitution", "probability": 0.53466796875}, {"start": 1544.82, "end": 1545.02, "word": " على", "probability": 0.70263671875}, {"start": 1545.02, "end": 1545.3, "word": " الحلقة", "probability": 0.9767252604166666}, {"start": 1545.3, "end": 1545.52, "word": " هنا", "probability": 0.69580078125}, {"start": 1545.52, "end": 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كلوريناشن، جروميناشن، وويلزمير إذا متذكرينه الـformal group لاحظوا في معظم الحلات على موقع اتنين، اتنين وخمسة، اتنين، اتنين، اتنين وخمسة، اتنين وخمسة في مرة يمكن طلع على نسبة تلاتة بنسبة يعني عدم فال substitution بشكل أساسي بيكون mono substitution على اتنين مرات بيصير على", "tokens": [6027, 2655, 5172, 995, 30241, 6024, 48506, 16247, 2304, 12984, 37977, 30767, 1829, 19446, 1975, 5016, 8315, 13412, 995, 33911, 9957, 9122, 2655, 13546, 8717, 36081, 2288, 33599, 1863, 12399, 9122, 1211, 13063, 1829, 8315, 8592, 1863, 12399, 10874, 2288, 20498, 1829, 8315, 8592, 1863, 12399, 4032, 2407, 26895, 11622, 2304, 13546, 11933, 15730, 44650, 8848, 37983, 9957, 3224, 2423, 39184, 837, 304, 1594, 20193, 5016, 19913, 14407, 8978, 20449, 19913, 2304, 21542, 1211, 9307, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 12399, 1975, 2655, 1863, 9957, 4032, 9778, 2304, 3794, 3660, 12399, 1975, 2655, 1863, 9957, 12399, 1975, 2655, 1863, 9957, 12399, 1975, 2655, 1863, 9957, 4032, 9778, 2304, 3794, 3660, 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