标题：王哲明
简介
王哲明 
无机化学，材料化学，晶体工程，博士，副教授
1962年生。出生地：福建省龙岩市.1983年获北京大学理学学士，1989年获福州大学理学硕士，1996年获北京大学理学博士学位。2002年，日本冈崎国立共同研究机构，  分子科学研究所，访问学者（文部省外国人研究员）。
学习经历1979-1983年，北京大学理学学士（放射化学）
1985-1989年，福州大学理学硕士（物理化学）
1993-1996年，北京大学理学博士（物理化学）
工作经历1983-1985年，化工部青岛劳动保护研究所，助理工程师
1889-1993年，福州大学化学系，讲师
1996-至今，北京大学化学与分子工程学院，博士生导师（2005年），教授（2006年）
2002-2003年，日本冈崎国立共同研究机构，分子科学研究所，日本文部省COE访问副教授
主讲课程：高等无机化学（研究生课），结构与物性（物理专业本科生），中级无机化学实验（化学专业本科生）
研究领域和兴趣
1． 磁电阻材料的化学制备和性质；
2． 分子间相互作用和分子组装；超分子聚集体的形和拓扑；
3． 磁性、电性功能材料的晶体工程。
在钙钛矿型稀土锰基氧化物磁电阻材料研究中，采用化学法从掺杂和复合两个方面考察对磁电阻性能及其机理的影响。获得了如MR得到显著增强，MR对外加磁场的灵敏度的明显改善，MR的符号可以得到调节等结果，这些结果对于磁电阻材料的实际应用具有重要意义。有关论文发表在Phys. Rev. B, Appl. Phys. Lett. 等期刊上。
在具有新颖拓扑特性的配位聚合物及其磁性、多卤素与生物氮碱组装的纳米结构、多核稀土配合物、新的分子间相互作用类型等方面的研究中得到了一系列的研究成果，有关工作发表在New J. Chem., J. Am. Chem. Soc., J Chem. Soc. Dalton Trans., CrystEngComm等期刊上。
研究工作得到国家科技部国家重点基础研究发展规划项目(G1998061310)、国家自然科学基金委青年基金(29701001)资助。
近年来发表论文
2008
Liu T, Zhang YJ, Wang ZM*, Gao S*, “A 64-nuclear cubic cage incorporating propeller-like FeIII8 apices and HCOO- edges”, J. Am. Chem. Soc. 2008, 130, 10500-10501.
Yao JY, Xiao Z, Gan LB*, Yang DZ, Wang ZM*, “Towards the Rational Synthesis of Norfullerenes. Controlled Deletion of One Carbon Atom from C60 and Preparation of 2,5,9-Trioxo-1-nor(C60-Ih)[5,6]fullerene C59(O)3 Derivatives”, Org. Lett. 2008, 10, 2003-2006.
Yang XB, Gan LB*, Wang ZM*, “Controlled regio- and chemoselective addition of isothiocyanate to the dione moiety of a cage-opened fullerene-mixed peroxide derivative”, Chem. Commun. 2008, 1980-1982.
Liu T, Yang YF, Wang ZM*, Gao S*, “Two diammonium copper azides with similar layerlike magnetic substructures made of chains of serially connected Cu6 rings show cation-modulated magnetism”, Chem. Asian J. 2008, 3, 950-957.
Wang XY, Wang ZM, Gao S*, “Detailed magnetic studies on Co(N-3)2(4-acetylpyridine)2: a weak-ferromagnet with a very big canting angle”, Inorg. Chem. 2008, 47, 5720-5726.
Liu T, Wang BW, Chen YH, Wang ZM*, Gao S*, “Syntheses, structures and magnetic properties of two mixed-valent disc-like hepta-nuclear compounds of [(FeIIFe6III)(tea)6](ClO4)2 and [(MnII3MnIII4)(nmdea)6(N3)6]·CH3OH (tea = N(CH2CH2O)33-, nmdea = CH3N(CH2CH2O)22-)”, Zeit. Anorg. Allge. Chem. 2008, 634, 778-783.
Wang XY, Wang ZM, Gao S*, “Constructing magnetic molecular solids by employing three-atom ligands as bridges”, Chem. Commun. 2008, 281-294.
2007
Wang ZM*, Zhang XY, Batten SR*, Kurmoo M*, Song Gao*, “[CH3NH2(CH2)2NH2CH3][M2(HCOO)6] (M=MnII and CoII): Weak ferromagnetic metal formate frameworks of unique binodal 6-connected (412·63)(49·66) topology, templated by a diammonium cation”, Inorg. Chem. 2007, 46, 8439-8441.
Xu HB, Wang BW, Pan F, Wang ZM, Gao S*,, “Stringing oxo-centered trinuclear [MnIII3O] units into single-chain magnets with formate or azide linkers”, Angew. Chem. Int. Ed. 2007, 46, 7388-7392.
Xiao Z, Yao JY, Yang DZ, Wang FD, Huang SH, Gan LB,* Jia ZS, Jiang ZP, Yang XB, Zheng B, Yuan G, Zhang SW, Wang ZM*, “Synthesis of [59]Fullerenones through Peroxide-Mediated Stepwise Cleavage of Fullerene Skeleton Bonds and X-ray Structures of Their Water-Encapsulated Open-Cage Complexes”, J. Am. Chem. Soc. 2007, 129, 16149-16162.
Pan F, Wang ZM, Gao S*, “Magneto-Structural Correlation in a Series of Bimetallic Alternating Chain Complexes of [CrIIIL(CN)4]n[MnIII(salpn)]n·nSolvents (L = 2,2’-bipy or 9,10-phen, salpn = Substituted Salicyldehyde, Solvents = Water and Methanol), Inorg. Chem.2007, 46, 10221-10228.
Wang XT, Wang ZM, Gao S*, “Honeycomb Layer of Cobalt(II) Azide Hydrazine Showing Weak Ferromagnetism”, Inorg. Chem.2007, 46, 10452-10454.
Wang ZM*, Zhang B, Zhang YJ, Kurmoo M, Liu T, Gao S*, Kobayashi, H*, “A family of porous magnets, [M3(HCOO)6] (M = Mn, Fe, Co and Ni)”, Polyhedron 2007, 26, 2207-2215.
Wang ZM*, Zhang YJ, Liu T, Kurmoo M, Gao S*, “[Fe3(HCOO)6]: A permanent porous diamond framework displaying H-2/N-2 adsorption, guest inclusion, and guest-dependent magnetism”, Adv. Funct. Mater. 2007, 17, 1523-1536.
Xu HB, Wang ZM, Liu T, Gao S*, “Synthesis, structure, and magnetic properties of (A)[FeIII(oxalate)Cl2] (A = alkyl ammonium cations) with anionic 1D [FeIII(oxalate)Cl2]- chains”, Inorg. Chem. 2007, 46, 3089-3096.
Wang XY, Wang ZM, Gao S*, “A pillared layer MOF with anion-tunable magnetic properties and photochemical [2+2] cycloaddition”, Chem. Commun. 2007, 1127-1129.
Zhang W, Zhao F, Liu T, Yuan M, Wang ZM*, Gao S*, “Spin crossover in a series of iron(II) complexes of 2-(2-alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of alkyl side chain, solvent, and anion”, Inorg. Chem. 2007, 46, 2541-2555.
Zhang B*, Wang ZM*, Kurmoo M, Gao S, Inoue K, Kobayashi H*, “Guest-induced chirality in the ferrimagnetic nanoporous diamond framework Mn3(HCOO)6”, Adv. Funct. Mater. 2007, 17, 577-584.
Zhu WH, Wang ZM*, Gao S*, “Two 3D porous lanthanide-fumarate-oxalate frameworks exhibiting framework dynamics and luminescent change upon reversible de- and rehydration”, Inorg. Chem. 2007, 46, 1337-1342.
Wang ZM*, Zhang B, Inoue K, Fujiwara H, Otsuka T, Kobayashi H*, Kurmoo M, “Occurrence of a rare 49·66 structural topology, chirality, and weak ferromagnetism in the [NH4][MII(HCOO)3] (M = Mn, Co, Ni) frameworks”, Inorg. Chem. 2007, 46, 437-445.
2006
Zhang YZ, Wang ZM, Gao S*, “Three-dimensional heterometallic chiral Cr-Mn compound constructed by cyanide and dicyanamide bridges”, Inorg. Chem. 2006, 45, 10404-10406.
Liu T, Chen YH, Zhang YJ, Wang ZM*, Gao S*. “NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M) Co, Cu), the first examples containing mu 1,3-nitrito bridges showing antiferromagnetism”, Inorg. Chem. 2006, 45, 9148-9150.
Wang ZM*, Zhang YJ, Kurmoo M*, Liu T, Vilminot S, Zhao B, Gao S*, “[Zn3(HCOO)6]: A porous diamond framework conformable to guest inclusion”, Aust. J. Chem. 2006, 59, 617-628.
He Z, Wang ZM*, Gao S, Yan CH*, “Coordination polymers with end-on azido and pyridine carboxylate N-oxide bridges displaying long-range magnetic ordering with low dimensional character”, Inorg. Chem. 2006, 45, 6694-6705.
Zhang YZ, Wernsdorfer W, Pan F, Wang ZM, Gao S*, “An azido-bridged disc-like heptanuclear cobalt(II) cluster: towards a single-molecule magnet”, Chem. Commun. 2006, 3302-2006.
Zhang YZ, Wang ZM, Gao S*, “Heterometallic Cr-Mn complexes containing cyanide and oxalate bridges’, Inorg. Chem. 2006, 45, 5447-5454.
Liu T, Zhang YJ, Wang ZM*, Gao S*, “Two chain compounds of [M(N3)2(HCOO)][(CH3)2NH2] (M = Fe and Co) with a mixed azido/formato bridge displaying metamagnetic behavior”, Inorg. Chem. 2006, 45, 2782-2784.
Zhu WH, Wang ZM*, Gao S*, “A 3D porous lanthanide-fumarate framework with water hexamer occupied cavities, exhibiting a reversible dehydration and rehydration procedure”, Dalton Trans. 2006, 765-768.
Wang XY, Wang L, Wang ZM, Gao S*, “Solvent-tuned azido-bridged Co2+ layers: Square, honeycomb, and Kagome”, J. Am. Chem. Soc. 2006, 128, 674-675.
Stride JA*, Kurmoo M, Wang ZM, “Investigations of guest-modulated ordering temperatures in open-framework 3D porous magnets”, Phys. B. Conds. Matter 2006, 385, 465-467.
Cui HB, Wang ZM, Takahashi K, Okano Y, Kobayashi H*, Kobayashi A, “Ferroelectric porous molecular crystal, [Mn3(HCOO)6](C2H5OH), exhibiting ferrimagnetic transition”, J. Am. Chem. Soc. 2006, 128, 15074-15075.
Huang QC*, Wang ZM, Chu QL, Zhu SZ*, “Crystal structure of a supramolecular complex formed between 1-bromo-2-iodo-tetrafluoroethane and N,N,N ',N '-tetramethyl-ethylenediamine”, J. Incl. Phen. Macrocyc. Chem. 2006, 54 177-180.
Zhang B*, Wang ZM, Zhang Y, Takahashi K, Okano Y, Cui HB, Kobayashi H*, Inoue K, Kurmoo M, Pratt FL, Zhu DB*, “Hybrid organic-inorganic conductor with a magnetic chain anion: k-BETS2[FeIII(C2O4)Cl2] [BETS = bis(ethylenedithio)tetraselenafulvalene]”, Inorg. Chem. 2006, 45, 3275-3280.
2005
Chang F, Wang ZM*, Sun HL, Gao S*, Wen GH, Zhang XX, “{[Cu2(bpdado)2(H2O)2]·H2O}n: A 1D nanotubular coordination polymer with wall made of edge-sharing hexagons, where bpdado=2,2 '-bipyridine-3,3 '-dicarboxylate-1,1 '-dioxide”, Dalton Trans. 2005, 2976-2978, inside front cover
He Z, Wang ZM*, Yan CH*, “Ligand-controlled dimensionality: 1D, 2D and 3D Gd(III) coordination polymers based on SO42- and pyridine carboxylate N-oxide ligands”, CrystEngComm. 2005, 7, 143-150.
He Z, Gao EQ, Wang ZM*, Yan CH*, Kurmoo M, “Coordination polymers based on inorganic lanthanide(III) sulfate skeletons and an organic isonicotinate N-oxide connector: Segregation into three structural types by the lanthanide contraction effect”, Inorg. Chem. 2005, 44, 862-874.
Wang ZM*, Zhang B, Kurmoo M, Green MA, Fujiwara H, Otsuka T, Kobayashi H*, “Synthesis and characterization of a porous magnetic diamond framework, Co3(HCOO)6, and its N2 sorption characteristic”, Inorg. Chem. 2005, 44, 1230-1237.
Wang XY, Wang L, Wang ZM, Su G, Gao S*, “Coexistence of spin-canting, metamagnetism, and spin-flop in a (4,4) layered manganese azide polymer”, Chem. Mater. 2005, 17, 6369-6380.
Zhang YZ, Wei HY, Pan F, Wang ZM, Chen ZD,* Gao S*, “Two molecular tapes consisting of serial or parallel azido-bridged eight-membered copper rings”, Angew. Chem. Int. Ed. 2005, 44, 5841-5846.
Zhang B*, Wang ZM, Fujiwara H, Kobayashi H*, Kurmoo M, Inoue K, Mori T, Gao S, Zhang Y, Zhu DB*, “Tetrathiafulvalene [FeIII(C2O4)Cl2]: An organic-inorganic hybrid exhibiting canted antiferromagnetism”, Adv. Mater. 2005, 17, 1988-1991.
Cui HB, Takahashi K, Kano Y, Kobayashi H*, Wang ZM, Kobayashi A, “Dielectric properties of porous molecular crystals that contain polar molecules”, Angew. Chem. Int. Ed. 2005, 44, 6508-6512.
Zhang YZ, Gao S,* Wang ZM, Su G, Sun HL, Pan F, “Rational synthesis and magnetic properties of a family of low-dimensional heterometallic Cr-Mn complexes based on the versatile building block [Cr(2,2 '-bipyridine)(CN)4]-”, Inorg. Chem. 2005, 44, 4534-4545.
Sun HL, Wang ZM, Gao S*, “Synthesis, crystal structures, and magnetism of cobalt coordination polymers based on dicyanamide and pyrazine-dioxide derivatives”, Inorg. Chem. 2005, 44, 2169-2176.
Wang XY, Wei HY, Wang ZM, Chen ZD*, Gao S*, “Formate - The analogue of azide: Structural and magnetic properties of M(HCOO)2(4,4 '-bpy)·nH2O (M=Mn, Co, Ni; n=0, 5)”, Inorg. Chem. 2005, 44, 572-583.
Before 2005 (selected)
Wang ZM*, Zhang B, Otsuka T, Inoue K, Kobayashi H*, Kurmoo M, “Anionic NaCl-type frameworks of [MnII(HCOO)3-], templated by alkylammonium, exhibit weak ferromagnetism”, Dalton Trans. 2004, 2209-2216.
Wang ZM*, Zhang B, Fujiwara H, Kobayashi H*, Kurmoo M, “Mn3(HCOO)6: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn4 tetrahedron and guest-modulated ordering temperature”, Chem. Commun. 2004, 416-417.
He Z, He C, Wang ZM*, Gao EQ, Liu Y, Yan CH*, “Self-assembly of molecular squares based on easy-to-prepare multidentate Schiff base ligands”, Dalton Trans. 2004, 502-504.
He Z, He C, Gao EQ, Wang ZM*, Yang XF, Liao CS, Yan CH*, “Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block”, Inorg. Chem. 2003, 42, 2206-2208.
Wang ZM, Sun BW, Luo J, Gao S, Liao CS, Yan CH*, Li Y, “Bimetallic sandwiches assembled with chelated Cu/Zn cations and manganese dicyanamide polymeric ladders”, Polyhedron, 2003, 22, 433-439.
Xu G, Wang ZM*, He Z, Lu Z, Liao CS, Yan CH*, “Synthesis and structural characterization of nonanuclear lanthanide complexes”, Inorg. Chem. 2002, 41, 6802-6807.
Cheng YJ, Wang ZM*, Liao CS, Yan CH*, “Novel sheet-like supramolecular architectures constructed from infinite hydrogen-bonded, protonated adenine water halide and polyiodide ribbons”, New J. Chem. 2002, 26, 1360-1364.
Wang ZM, Sun BW, Luo J, Gao S, Liao CS, Yan CH*, Li Y, “Bimetallic sheet and 3D threefold interpenetrating diamond-like network constructed by chelate Cu cations and Mn dicyanamide polymeric chains. Synthesis, crystal structure, and magnetism of [CuL2][Mn(dca)4] (L = ethylenediamine or 1,3-diaminopropane; dca = dicyanamide N(CN)2-)”, Inorg. Chim. Acta 2002, 332, 127-134.
Wang ZM, Cheng YJ, Liao CS, Yan CH*, “The first supramolecular architectures assembled by infinite hydrogen-bonded, protonated nucleobase-water ribbons and unusual polyiodide frameworks”, CrystEngComm. 2001, art no. 50.