prompt_front: Now, answer the following question based on the text below, only give me the answer and do not output any other words.

Question: What is the average magnetic moment per column in Ge$_{1-x}$Mn$_{x}$ films?

Read the following text and answer briefly.

Context 1: \section{introduction}
In the past few years, the synthesis of ferromagnetic semiconductors has become a major challenge for spintronics  Actually, growing a magnetic and semiconducting material could lead to promising advances like spin injection into non magnetic semiconductors, or electrical manipulation of carrier induced magnetism in magnetic semiconductors \cite{ohno00,Bouk02}  Up to now, major efforts have focused on diluted magnetic semiconductors (DMS) in which the host semiconducting matrix is randomly substituted by transition metal (TM) ions such as Mn, Cr, Ni, Fe or Co \cite{Diet02}  However Curie temperatures ($T_{C}$) in DMS remain rather low and TM concentrations must be drastically raised in order to increase $T_{C}$ up to room temperature  That usually leads to phase separation and the formation of secondary phases  It was recently shown that phase separation induced by spinodal decomposition could lead to a significant increase of $T_{C}$ \cite{Diet06,Fuku06}  For semiconductors showing $T_{C}$ higher than room temperature one can foresee the fabrication of nanodevices such as memory nanodots, or nanochannels for spin injection  Therefore, the precise control of inhomogeneities appears as a new challenge which may open a way to industrial applications of ferromagnetism in semiconductors 

The increasing interest in group-IV magnetic semiconductors can also be explained by their potential compatibility with the existing silicon technology  In 2002, carrier mediated ferromagnetism was reported in  MBE grown Ge$_{0 94}$Mn$_{0 06}$ films by Park \textit{et al } \cite{Park02}  The maximum critical temperature was 116 K  Recently many publications indicate a significant increase of $T_{C}$ in Ge$_{1-x}$Mn$_{x}$ material depending on growth conditions \cite{Pint05,Li05,tsui03}  Cho \textit{et al } reported a Curie temperature as high as 285 K \cite{Cho02}  
Taking into account the strong tendency of Mn ions to form intermetallic compounds in germanium, a detailed investigation of the nanoscale structure is required  Up to now, only a few studies have focused on the nanoscale composition in Ge$_{1-x}$Mn$_{x}$ films  Local chemical inhomogeneities have been recently reported by Kang \textit{et al } \cite{Kang05} who evidenced a micrometer scale segregation of manganese in large Mn rich stripes  Ge$_3$Mn$_5$ as well as Ge$_8$Mn$_{11}$ clusters embedded in a germanium matrix have been reported by many authors  However, Curie temperatures never exceed 300 K \cite{Bihl06,Morr06,Pass06,Ahle06}  Ge$_3$Mn$_5$ clusters exhibit a Curie temperature of 296 K \cite{Mass90}  This phase frequently observed in Ge$_{1-x}$Mn$_{x}$ films is the most stable (Ge,Mn) alloy  The other stable compound Ge$_8$Mn$_{11}$ has also been observed in nanocrystallites surrounded with pure germanium \cite{Park01}  Ge$_8$Mn$_{11}$ and Ge$_3$Mn$_5$ phases are ferromagnetic but their metallic character considerably complicates their potential use as spin injectors 
Recently, some new Mn-rich nanostructures have been evidenced in Ge$_{1-x}$Mn$_{x}$ layers  Sugahara \textit{et al } \cite{Sugh05} reported the formation of high Mn content (between 10 \% and 20 \% of Mn) amorphous Ge$_{1-x}$Mn$_x$ precipitates  in a Mn-free germanium matrix  Mn-rich coherent cubic clusters were observed by Ahlers \textit{et al } \cite{Ahle06} which exhibit a Curie temperatures below 200 K  Finally, high-$T_{C}$ ($>$ 400 K) Mn-rich nanocolumns have been evidenced \cite{Jame06} which could lead to silicon compatible room temperature operational devices \\
In the present paper, we investigate the structural and magnetic properties of Ge$_{1-x}$Mn$_x$ thin films for low growth temperatures ($<$ 200$^{\circ}$C) and low Mn concentrations (between 1 \% and 11 \%)  By combining TEM, x-Ray diffraction and SQUID magnetometry, we could identify different magnetic phases  We show that depending on growth conditions, we obtain either Mn-rich nanocolumns or Ge$_{3}$Mn$_{5}$ clusters embedded in a germanium matrix  We discuss the structural and magnetic properties of these nanostructures as a function of manganese concentration and growth temperature  We also discuss the magnetic anisotropy of nanocolumns and  
Ge$_3$Mn$_5$ clusters  

\section{Sample growth}

Growth was performed using solid sources molecular beam epitaxy (MBE) by co-depositing Ge and Mn evaporated from standard Knudsen effusion cells   Deposition rate was low ($\approx$ 0 2 \AA s$^{-1}$)  Germanium substrates were epi-ready Ge(001) wafers with a residual n-type doping and resistivity of 10$^{15}$ cm$^{-3}$ and 5 $\Omega cm$ respectively  After thermal desorption of the surface oxide, a 40 nm thick Ge buffer layer was grown at 250$^{\circ}$C, resulting in a 2 $\times$ 1 surface reconstruction as observed by reflection high energy electron diffraction (RHEED) (see Fig  1a)  Next, 80 nm thick Ge$_{1-x}$Mn$_{x}$ films were subsequently grown  at low substrate temperature (from 80$^{\circ}$C to 200$^{\circ}$C)  Mn content has been determined by x-ray fluorescence measurements performed on thick samples ($\approx$ 1 $\mu m$ thick) and complementary Rutherford Back Scattering (RBS) on thin Ge$_{1-x}$Mn$_{x}$ films grown on silicon  Mn concentrations range from 1 \% to 11\% Mn 

For Ge$_{1-x}$Mn$_{x}$ films grown at substrate temperatures below 180$^{\circ}$C, after the first monolayer (ML) deposition, the  2 $\times$ 1 surface reconstruction almost totally disappears  After depositing few MLs, a slightly diffuse 1 $\times$ 1 streaky RHEED pattern and a very weak 2 $\times$ 1 reconstruction (Fig  1b) indicate a predominantly two-dimensional growth  For growth temperatures above 180$^{\circ}$C additional spots appear in the RHEED pattern during the Ge$_{1-x}$Mn$_{x}$ growth (Fig  1c)  These spots may correspond to the formation of very small secondary phase crystallites  The nature of these crystallites will be discussed below 

Transmission electron microscopy (TEM) observations were performed using a JEOL 4000EX microscope with an acceleration voltage of 400 kV  Energy filtered transmission electron microscopy (EFTEM) was done using a JEOL 3010 microscope equipped with a Gatan Image Filter   Sample preparation was carried out by standard mechanical polishing and argon ion milling for cross-section investigations and plane views were prepared by wet etching with H$_3$PO$_4$-H$_2$O$_2$ solution \cite{Kaga82} 

\begin{figure}[htb]
    \center
    \includegraphics[width= 29\linewidth]{ /fig1a eps}
    \includegraphics[width= 29\linewidth]{ /fig1b eps}
    \includegraphics[width= 29\linewidth]{ /fig1c eps}
    \caption{RHEED patterns recorded during the growth of Ge$_{1-x}$Mn$_{x}$ films: (a) 2 $\times$ 1 surface reconstruction of the germanium buffer layer  (b) 1 $\times$ 1 streaky RHEED pattern obtained at low growth temperatures ($T_g<$180$^{\circ}$C)  (c) RHEED pattern of a sample grown at $T_g=$180$^{\circ}$C  The additional spots reveal the presence of Ge$_3$Mn$_5$ clusters at the surface of the film }
\label{fig1}
\end{figure}

\section{Structural properties \label{structural}}

\begin{figure}[htb]
    \center
	\includegraphics[width= 49\linewidth]{ /fig2a eps}
	\includegraphics[width= 49\linewidth]{ /fig2b eps}
	 \includegraphics[width= 49\linewidth]{ /fig2c eps}
	 \includegraphics[width= 49\linewidth]{ /fig2d eps}
    \caption{Transmission electron micrographs of a Ge$_{1-x}$Mn$_{x}$ film grown at 130$^{\circ}$C and containing 6 \% of manganese  (a) cross-section along the [110] axis : we clearly see the presence of nanocolumns elongated along the growth axis  (b) High resolution image of the interface between the Ge$_{1-x}$Mn$_{x}$ film and the Ge buffer layer  The Ge$_{1-x}$Mn$_{x}$ film exhibits the same diamond structure as pure germanium  No defect can be seen which could be caused by the presence of nanocolumns  (c) Plane view micrograph performed on the same sample confirms the columnar structure and gives the density and size distribution of nanocolumns  (d) Mn chemical map obtained by energy filtered transmission electron microcopy (EFTEM)  The background was carefully substracted from pre-edge images  Bright areas correspond to Mn-rich regions }
\label{fig2}
\end{figure}

In samples grown at 130$^{\circ}$C and containing 6 \% Mn, we can observe vertical elongated nanostructures \textit{i e } nanocolumns as shown in Fig  2a  Nanocolumns extend through the whole Ge$_{1-x}$Mn$_{x}$ film thickness  From the high resolution TEM image shown in Fig  2b, we deduce their average diameter around 3 nm  Moreover in Fig  2b, the interface between the Ge buffer layer and the Ge$_{1-x}$Mn$_{x}$ film is flat and no defect propagates from the interface into the film  The Ge$_{1-x}$Mn$_{x}$ film is a perfect single crystal in epitaxial relationship with the substrate  In Fig  2c is shown a plane view micrograph of the same sample confirming the presence of nanocolumns in the film  From this image, we can deduce the size and density of nanocolumns  The nanocolumns density is 13000 $\rm{\mu m}^{-2}$ with a mean diameter of 3 nm which is coherent with cross-section measurements  In order to estimate the chemical composition of these nanocolumns, we further performed chemical mapping using EFTEM  In Fig  2d we show a cross sectional Mn chemical map of the Ge$_{1-x}$Mn$_{x}$ film  This map shows that the formation of nanocolumns is a consequence of Mn segregation  Nanocolumns are Mn rich and the surrounding matrix is Mn poor  However, it is impossible to deduce the Mn concentration in Ge$_{1-x}$Mn$_{x}$ nanocolumns from this cross section  Indeed, in cross section observations, the columns diameter is much smaller than the probed film thickness and the signal comes from the superposititon of the Ge matrix and Mn-rich nanocolumns  In order to quantify Mn concentration inside the nanocolumns and inside the Ge matrix, EELS measurements (not shown here) have been performed in a plane view geometry \cite{Jame06}  These observations revealed that the matrix Mn content is below 1 \% (detection limit of our instrument)  Measuring the surface occupied by the matrix and the nanocolumns in plane view TEM images, and considering the average Mn concentration in the sample (6 \%), we can estimate the Mn concentration in the nanocolumns  The Mn concentration measured by EELS being between 0\% and 1\%, we can conclude that the Mn content in the nanocolumns is between 30 \% and 38 \% \\
For samples grown between 80$^\circ$C and 150$^\circ$C cross section and plane view TEM observations reveal the presence of Mn rich nanocolumns surrounded with a Mn poor Ge matrix  In order to investigate the influence of Mn concentration on the structural properties of Ge$_{1-x}$Mn$_{x}$ films, ten samples have been grown at 100$^\circ$C and at 150$^\circ$C with Mn concentrations of 1 3 \%, 2 3 \%, 4 \%, 7 \% and 11 3 \%  Their structural properties have been investigated by plane view TEM observations  

\begin{figure}[htb]
    \center
    \includegraphics[width= 98\linewidth]{ /fig3a eps}
	\includegraphics[width= 45\linewidth]{ /fig3b eps}
		\includegraphics[width= 45\linewidth]{ /fig3c eps}
    \caption{Nanocolumns size and density as a function of growth conditions  Samples considered have been grown at 100$^{\circ}$C and 150$^{\circ}$C respectively  (a) Mn concentration dependence of the size distribution  (b) columns density as a function of Mn concentration  (c) Volume fraction of the nanocolumns as a function of Mn concentration }
 \label{fig3}
\end{figure}

For samples grown at 100$^\circ$C with Mn concentrations below 5 \% the nanocolumns mean diameter is 1 8$\pm$0 2 nm  The evolution of columns density as a fonction of Mn concentration is reported in figure 3b  By increasing the Mn concentration from 1 3 \% to 4 \% we observe a significant increase of the columns density from 13000 to 30000 $\rm{\mu m}^{-2}$  For Mn concentrations higher than 5 \% the density seems to reach a plateau corresponding to 35000 $\rm{\mu m}^{-2}$ and their diameter slightly increases from 1 8 nm at 4 \% to 2 8 nm at 11 3 \%  By plotting the volume fraction occupied by the columns in the film as a function of Mn concentration, we observe a linear dependence for Mn contents below 5 \%  The non-linear behavior above 5 \% may indicate that the mechanism of Mn incorporation is different in this concentration range, leading to an increase of Mn concentration in the columns or in the matrix  For samples grown at 100$^\circ$C, nanocolumns are always fully coherent with the surrounding matrix (Fig  4a)  

Increasing the Mn content in the samples grown at 150$^\circ$C from 1 3 \% to 11 3 \% leads to a decrease of the columns density (fig 3b)  Moreover, their average diameter increases significantly and size distributions become very broad (see Fig  3a)  For the highest Mn concentration (11 3 \%) we observe the coexistence of very small columns with a diameter of 2 5 nm and very large columns with a diameter of 9 nm  In samples grown at 150$^\circ$C containing 11 3 \% of Mn, the crystalline structure of nanocolumns is also highly modified  In plane view TEM micrographs, one can see columns exhibiting several different crystalline structures  We still observe some columns which are fully coherent with the Ge matrix like in the samples grown at lower temperature  Nevertheless, observations performed on these samples grown at 150$^\circ$C and with 11 3\% Mn reveal some uniaxially \cite{Jame06} or fully relaxed columns exhibiting a misfit of 4 \% between the matrix and the columns and leading to misfit dislocations at the interface between the column and the matrix (see fig  4b)  Thus we can conclude that coherent columns are probably in strong compression and the surrounding matrix in tension  On the same samples (T$_g$=150$^{\circ}$C, 11 3\% Mn), we also observe a large number of highly disordered nanocolumns leading to an amorphous like TEM contrast(fig  4c) 

\begin{figure}[htb]
    \center
   \includegraphics[width= 31\linewidth]{ /fig4a eps}
	\includegraphics[width= 31\linewidth]{ /fig4b eps}
	\includegraphics[width= 31\linewidth]{ /fig4c eps}
    \caption{Plane view high resolution transmission electron micrographs of different types of nanocolumns : (a) typical structure of a column grown at 100$^{\circ}$C  The crystal structure is exactly the same as germanium   (b) Partially relaxed nanocolumn  One can see dislocations at the interface between the columns and the matrix leading to stress relaxation  (c) Amorphous nanocolumn  These columns are typical in samples grown at 150$^{\circ}$C with high Mn contents }
 \label{fig4}
\end{figure}

In conclusion, we have evidenced a complex mechanism of Mn incorporation in Mn doped Ge films grown at low temperature  In particular Mn incorporation is highly inhomogeneous  For very low growth temperatures (below 120$^\circ$C) the diffusion of Mn atoms leads to the formation of Mn rich, vertical nanocolumns  Their density mostly depends on Mn concentration and their mean diameter is about 2 nm  These results can be compared with the theoretical predictions of Fukushima \textit{et al } \cite{Fuku06}: they proposed a model of spinodal decomposition in (Ga,Mn)N and (Zn,Cr)Te based on layer by layer growth conditions and a strong pair attraction between Mn atoms which leads to the formation of nanocolumns  This model may also properly describe the formation of Mn rich nanocolumns in our samples  Layer by layer growth conditions can be deduced from RHEED pattern evolution during growth  For all the samples grown at low temperature, RHEED observations clearly indicate two-dimensional growth  Moreover, Ge/Ge$_{1-x}$Mn$_{x}$/Ge heterostructures have been grown and observed by TEM (see Fig  5)  Ge$_{1-x}$Mn$_{x}$/Ge (as well as Ge/Ge$_{1-x}$Mn$_{x}$) interfaces are very flat and sharp thus confirming a two-dimensional, layer by layer growth mode  Therefore we can assume that the formation of Mn rich nanocolumns is a consequence of 2D-spinodal decomposition 

\begin{figure}[htb]
    \center
	\includegraphics[width= 7\linewidth]{ /fig5 eps}
    \caption{Cross section high resolution micrograph of a Ge/Ge$_{1-x}$Mn$_{x}$/Ge/Ge$_{1-x}$Mn$_{x}$/Ge heterostructure  This sample has been grown at 130 $^{\circ}$C with 6\% Mn  Ge$_{1-x}$Mn$_{x}$ layers are 15 nm thick and Ge spacers 5 nm thick  We clearly see the sharpness of both Ge$_{1-x}$Mn$_{x}$/Ge and Ge/Ge$_{1-x}$Mn$_{x}$ interfaces  Mn segregation leading to the columns formation already takes place in very thin Ge$_{1-x}$Mn$_{x}$ films }
\label{fig5}
\end{figure}

For growth temperatures higher than 160$^\circ$C, cross section TEM and EFTEM observations (not shown here) reveal the coexistence of two Mn-rich phases: nanocolumns and Ge$_{3}$Mn$_{5}$ nanoclusters embedded in the germanium matrix  A typical high resolution TEM image is shown in figure 6  
Ge$_{3}$Mn$_{5}$ clusters are not visible in RHEED patterns for temperatures below 180$^\circ$C  To investigate the nature of these clusters, we performed x-ray diffraction in $\theta-2\theta$ mode  Diffraction scans were acquired on a high resolution diffractometer using the copper K$_\alpha$ radiation and on the GMT station of the BM32 beamline at the European Synchrotron Radiation Facility (ESRF)  Three samples grown at different temperatures and/or annealed at high temperature were investigated  The two first samples are Ge$_{1-x}$Mn$_{x}$ films grown at 130$^\circ$C and 170$^\circ$C respectively  The third one has been grown at 130$^\circ$C and post-growth annealed at 650$^\circ$C  By analysing x-ray diffraction spectra, we can evidence two different crystalline structures  For the sample grown at 130$^\circ$C, the $\theta-2\theta$ scan only reveals the (004) Bragg peak of the germanium crystal, confirming the good epitaxial relationship between the layer and the substrate, and the absence of secondary phases in the film in spite of a high dynamics of the order of 10$^7$  For both samples grown at 170$^\circ$C and annealed at 650$^\circ$C, $\theta-2\theta$ spectra are identical  In addition to the (004) peak of germanium, we observe three additional weak peaks  The first one corresponds to the (002) germanium forbidden peak which probably comes from a small distortion of the germanium crystal, and the two other peaks are respectively attributed to the (002) and (004) Bragg peaks of a secondary phase  The $c$ lattice parameter of Ge$_3$Mn$_5$ hexagonal crystal is 5 053 \AA \ \cite{Fort90} which is in very good agreement with the values obtained from diffraction data for both (002) and (004) lines assuming that the $c$ axis of Ge$_3$Mn$_5$ is along the [001] direction of the Ge substrate 

\begin{figure}[htb]
    \center
	\includegraphics[width= 7\linewidth]{ /fig6 eps}
	\caption{Cross section high resolution transmission electron micrograph of a sample grown at 170$^{\circ}$C  We observe the coexistence of two different Mn-rich phases: Ge$_{1-x}$Mn$_{x}$ nanocolumns and Ge$_3$Mn$_5$ clusters }
\label{fig6}
\end{figure}

In summary, in a wide range of growth temperatures and Mn concentrations, we have evidenced a two-dimensional spinodal decomposition leading to the formation of Mn-rich nanocolumns in Ge$_{1-x}$Mn$_{x}$ films  This decomposition is probably the consequence of: $(i)$ a strong pair attraction between Mn atoms, $(ii)$ a strong surface diffusion of Mn atoms in germanium even at low growth temperatures and $(iii)$ layer by layer growth conditions  We have also investigated the influence of growth parameters on the spinodal decomposition: at low growth temperatures (100$^{\circ}$C), increasing the Mn content leads to higher columns densities while at higher growth temperatures (150$^{\circ}$C), the columns density remains nearly constant whereas their size increases drastically  By plotting the nanocolumns density as a function of Mn content, we have shown that the mechanism of Mn incorporation in Ge changes above 5 \% of Mn  Finally, using TEM observations and x-ray diffraction, we have shown that Ge$_3$Mn$_5$ nanoclusters start to form at growth temperatures higher than 160$^\circ$C 

\section{Magnetic properties \label{magnetic}}

We have thoroughly investigated the magnetic properties of thin Ge$_{1-x}$Mn$_{x}$ films for different growth temperatures and Mn concentrations  In this section, we focus on Mn concentrations between 2 \% and 11 \%  We could clearly identify four different magnetic phases in Ge$_{1-x}$Mn$_{x}$ films : diluted Mn atoms in the germanium matrix, low $T_{C}$ nanocolumns ($T_{C}$ $\leq$ 170 K), high $T_{C}$ nanocolumns ($T_{C}$ $\geq$ 400 K) and Ge$_{3}$Mn$_{5}$ clusters ($T_{C}$ $\thickapprox$ 300 K)  The relative weight of each phase clearly depends on the growth temperature and to a lesser extend on Mn concentration  For low growth temperature ($<$ 120$^{\circ}$C), we show that nanocolumns are actually made of four uncorrelated superparamagnetic nanostructures  Increasing T$_{g}$ above 120$^{\circ}$C, we first obtain continuous columns exhibiting low $T_{C}$ ($<$ 170 K) and high $T_{C}$ ($>$ 400 K) for $T_{g}\approx$130$^{\circ}$C  The larger columns become ferromagnetic \textit{i e } $T_{B}>T_{C}$  Meanwhile Ge$_{3}$Mn$_{5}$ clusters start to form  Finally for higher $T_{g}$, the magnetic contribution from Ge$_{3}$Mn$_{5}$ clusters keeps increasing while the nanocolumns signal progressively disappears 

\begin{figure}[htb]
\center
   \includegraphics[width= 6\linewidth]{ /fig7a eps}
   \includegraphics[width= 3\linewidth]{ /fig7b eps}
\caption{(a) Temperature dependence of the saturation magnetization (in $\mu_{B}$/Mn) of Ge$_{0 93}$Mn$_{0 07}$ samples for different growth temperatures  The magnetic field is applied in the film plane  The inset shows the temperature dependence of a sample grown at 130$^{\circ}$C and annealed at 650$^{\circ}$C for 15 minutes  After annealing, the magnetic signal mostly arises from Ge$_{3}$Mn$_{5}$ clusters  (b) ZFC-FC measurements performed on Ge$_{0 93}$Mn$_{0 07}$ samples for different growth temperatures  The in-plane applied field is 0 015 T  The ZFC peak at low temperature ($\leq$150 K) can be attributed to the superparamagnetic nanocolumns  This peak widens and shifts towards high blocking temperatures when increasing growth temperature  The second peak above 150 K in the ZFC curve which increases with increasing growth temperature is attributed to superparamagnetic Ge$_{3}$Mn$_{5}$ clusters  The increasing ZFC-FC irreversibility at $\approx$ 300 K is due to the increasing contribution from large ferromagnetic Ge$_{3}$Mn$_{5}$ clusters  The nanocolumns signal completely vanishes after annealing at 650$^{\circ}$C for 15 minutes }
\label{fig7}
\end{figure}

In Fig  7a, the saturation magnetization at 2 Tesla in $\mu_{B}$/Mn of Ge$_{1-x}$Mn$_{x}$ films with 7 \% of Mn is plotted as a function of temperature for different growth temperatures ranging from $T_{g}$=90$^{\circ}$C up to 160$^{\circ}$C  The inset shows the temperature dependence of the magnetization at 2 Tesla after annealing at 650$^{\circ}$C during 15 minutes  Figure 7b displays the corresponding Zero Field Cooled - Field Cooled (ZFC-FC) curves recorded at 0 015 Tesla  In the ZFC-FC procedure, the sample is first cooled down to 5 K in zero magnetic field and the susceptibility is subsequently recorded at 0 015 Tesla while increasing the temperature up to 400 K (ZFC curve)  Then, the susceptibility is recorded under the same magnetic field while decreasing the temperature down to 5 K (FC curve)  Three different regimes can be clearly distinguished  \\
For $T_{g}\leq$120$^{\circ}$C, the temperature dependence of the saturation magnetization remains nearly the same while increasing growth temperature  The overall magnetic signal vanishing above 200 K is attributed to the nanocolumns whereas the increasing signal below 50 K originates from diluted Mn atoms in the surrounding matrix  The Mn concentration dependence of the saturation magnetization is displayed in figure 8  For the lowest Mn concentration (4 \%), the contribution from diluted Mn atoms is very high and drops sharply for higher Mn concentrations (7 \%, 9 \% and 11 3 \%)  Therefore the fraction of Mn atoms in the diluted matrix decreases with Mn concentration probably because Mn atoms are more and more incorporated in the nanocolumns  In parallel, the Curie temperature of nanocolumns increases with the Mn concentration reaching 170 K for 11 3 \% of Mn  This behavior may be related to different Mn compositions and to the increasing diameter of nanocolumns (from 1 8 nm to 2 8 nm) as discussed in section \ref{structural} 

\begin{figure}[htb]
\center
   \includegraphics[width= 7\linewidth]{ /fig8 eps}
    \caption{Temperature dependence of the saturation magnetization (in $\mu_{B}$/Mn) of Ge$_{1-x}$Mn$_{x}$ films grown at 100$^{\circ}$C plotted for different Mn concentrations: 4 1 \%; 7 \%; 8 9 \% and 11 3 \% }
\label{fig8}
\end{figure}

ZFC-FC measurements show that the nanocolumns are superparamagnetic  The magnetic signal from the diluted Mn atoms in the matrix is too weak to be detected in susceptibility measurements at low temperature  In samples containing 4 \% of Mn, ZFC and FC curves superimpose down to low temperatures  As we do not observe hysteresis loops at low temperature, we believe that at this Mn concentration nanocolumns are  superparamagnetic in the whole temperature range and the blocking temperature cannot be measured  For higher Mn contents, the ZFC curve exhibits a very narrow peak with a maximum at the blocking temperature of 15 K whatever the Mn concentration and growth temperature (see Fig  7b)  Therefore the anisotropy barrier distribution is narrow and assuming that nanocolumns have the same magnetic anisotropy, this is a consequence of the very narrow size distribution of the nanocolumns as observed by TEM  To probe the anisotropy barrier distribution, we have performed ZFC-FC measurements but instead of warming the sample up to 400 K, we stopped at a lower temperature $T_{0}$  

\begin{figure}[htb]
\center
   \includegraphics[width= 6\linewidth]{ /fig9 eps}
\caption{Schematic drawing of the anisotropy barrier distribution n($E_{B}$) of superparamagnetic nanostructures  If magnetic anisotropy does not depend on the particle size, this distribution exactly reflects their magnetic size distribution  In this drawing the blocking temperature ($T_{B}$) corresponds to the distribution maximum  At a given temperature $T_{0}$ such that 25$k_{B}T_{0}$ falls into the anisotropy barrier distribution, the largest nanostructures with an anisotropy energy larger than 25$k_{B}T_{0}$ are blocked whereas the others are superparamagnetic }
\label{fig9}
\end{figure}

If this temperature falls into the anisotropy barrier distribution as depicted in Fig  9, the FC curve deviates from the ZFC curve  Indeed the smallest nanostructures have become superparamagnetic at $T_{0}$ and when decreasing again the temperature, their magnetization freezes along a direction close to the magnetic field and the FC susceptibility is higher than the ZFC susceptibility  Therefore any irreversibility in this procedure points at the presence of superparamagnetic nanostructures  The results are given in Fig  10a  ZFC and FC curves clearly superimpose up to $T_{0}$=250 K thus the nanocolumns are superparamagnetic up to their Curie temperature and no Ge$_{3}$Mn$_{5}$ clusters could be detected  Moreover for low $T_{0}$ values, a peak appears at low temperature in FC curves which evidences strong antiferromagnetic interactions between the nanocolumns \cite{Chan00} 

\begin{figure}[htb]
\center
    \includegraphics[width= 35\linewidth]{ /fig10a eps}
    \includegraphics[width= 63\linewidth]{ /fig10b eps}
\caption{(a) ZFC-FC measurements performed on a Ge$_{0 887}$Mn$_{0 113}$ sample grown at 115$^{\circ}$C  The in-plane applied field is 0 015 T  Magnetization was recorded up to different T$_{0}$ temperatures: 30 K, 50 K, 100 K, 150 K, 200 K and 250 K  Curves are shifted up for more clarity  (b) ZFC-FC curves for in-plane and out-of-plane applied fields (0 015 T) }
\label{fig10}
\end{figure}

In order to derive the magnetic size and anisotropy of the Mn-rich nanocolumns embedded in the Ge matrix, we have fitted the inverse normalized in-plane (resp  out-of-plane) susceptibility: $\chi_{\parallel}^{-1}$ (resp  $\chi_{\perp}^{-1}$)  The corresponding experimental ZFC-FC curves are reported in Fig  10b  Since susceptibility measurements are performed at low field (0 015 T), the matrix magnetic signal remains negligible  In order to normalize susceptibility data, we need to divide the magnetic moment by the saturated magnetic moment recorded at 5 T  However the matrix magnetic signal becomes very strong at 5 T and low temperature so that we need to subtract it from the saturated magnetic moment using a simple Curie function  From Fig  10b, we can conclude that nanocolumns are isotropic  Therefore to fit experimental data we use the following expression well suited for isotropic systems or cubic anisotropy: $\chi_{\parallel}^{-1}= \chi_{\perp}^{-1}\approx 3k_{B}T/M(T)+\mu_{0}H_{eff}(T)$  $k_{B}$ is the Boltzmann constant, $M=M_{s}v$ is the magnetic moment of a single-domain nanostructure (macrospin approximation) where $M_{s}$ is its magnetization and $v$ its volume  The in-plane magnetic field is applied along $[110]$ or $[-110]$ crystal axes  Since the nanostructures Curie temperature does not exceed 170 K, the temperature dependence of the saturation magnetization is also accounted for by writting $M(T)$  Antiferromagnetic interactions between nanostructures are also considered by adding an effective field estimated in the mean field approximation \cite{Fruc02}: $\mu_{0}H_{eff}(T)$ 
The only fitting parameters are the maximum magnetic moment (\textit{i e } at low temperature) per nanostructure: $M$ (in Bohr magnetons $\mu_{B}$) and the maximum interaction field (\textit{i e } at low temperature): $\mu_{0}H_{eff}$ 

\begin{figure}[htb]
\center
   \includegraphics[width= 7\linewidth]{ /fig11 eps}
\caption{Temperature dependence of the inverse in-plane (open circles) and out-of-plane (open squares) normalized susceptibilities of a Ge$_{0 887}$Mn$_{0 113}$ sample grown at 115$^{\circ}$C  Fits were performed assuming isotropic nanostructures or cubic anisotropy  Dashed line is for in-plane susceptibility and solid line for out-of-plane susceptibility }
\label{fig11}
\end{figure}

In Fig  11, the best fits lead to $M\approx$1250 $\mu_{B}$ and $\mu_{0}H_{eff}\approx$102 mT for in-plane susceptibility and $M\approx$1600 $\mu_{B}$ and $\mu_{0}H_{eff}\approx$98 mT for out-of-plane susceptibility  It gives an average magnetic moment of 1425 $\mu_{B}$ per column and an effective interaction field of 100 mT  Using this magnetic moment and its temperature dependence, magnetization curves could be fitted using a Langevin function and $M(H/T)$ curves superimpose for $T<$100 K  However, from the saturated magnetic moment of the columns and their density (35000 $\rm{\mu m}^{-2}$), we find almost 6000 $\mu_{B}$ per column  Therefore, for low growth temperatures, we need to assume that nanocolumns are actually made of almost four independent elongated magnetic nanostructures  The effective field for antiferromagnetic interactions between nanostructures estimated from the susceptibility fits is at least one order of magnitude larger than what is expected from pure magnetostatic coupling  This difference may be due to either an additional antiferromagnetic coupling through the matrix which origin remains unexplained or to the mean field approximation which is no more valid in this strong coupling regime  As for magnetic anisotropy, the nanostructures behave as isotropic magnetic systems or exhibit a cubic magnetic anisotropy  First we can confirm that nanostructures are not amorphous otherwise shape anisotropy would dominate leading to out-of-plane anisotropy  We can also rule out a random distribution of magnetic easy axes since the nanostructures are clearly crystallized in the diamond structure and would exhibit at least a cubic anisotropy (except if the random distribution of Mn atoms within the nanostructures can yield random easy axes)  Since the nanostructures are in strong in-plane compression (their lattice parameter is larger than the matrix one), the cubic symmetry of the diamond structure is broken and magnetic cubic anisotropy is thus unlikely  We rather believe that out-of-plane shape anisotropy is nearly compensated by in-plane magnetoelastic anisotropy due to compression leading to a \textit{pseudo} cubic anisotropy  From the blocking temperature (15 K) and the magnetic volume of the nanostructures , we can derive their magnetic anisotropy constant using $Kv=25k_{B}T_{B}$: K$\approx$10 kJ m$^{-3}$ which is of the same order of magnitude as shape anisotropy 

\begin{figure}[htb]
\center
    \includegraphics[width= 35\linewidth]{ /fig12a eps}
    \includegraphics[width= 63\linewidth]{ /fig12b eps} 
\caption{(a) ZFC-FC measurements performed on a Ge$_{0 93}$Mn$_{0 07}$ sample grown at 122$^{\circ}$C  The in-plane applied field is 0 015 T  Magnetization was recorded up to different T$_{0}$ temperatures: 50 K, 100 K, 150 K, 200 K and 250 K  Curves are shifted up for more clarity  (b) ZFC-FC curves for in-plane and out-of-plane applied fields  (0 015 T) }
\label{fig12}
\end{figure}

For growth temperatures $T_{g}\geq$120$^{\circ}$C and Mn concentrations $\geq$ 7 \%, samples exhibit a magnetic signal above 200 K corresponding to Ge$_{3}$Mn$_{5}$ clusters (see Fig  7a)  As we can see, SQUID measurements are much more sensitive to the presence of Ge$_{3}$Mn$_{5}$ clusters, even at low concentration, than TEM and x-ray diffraction used in section \ref{structural}  We also observe a sharp transition in the ZFC curve (see Fig  7b, Fig  12a and 12b): the peak becomes very large and is shifted towards high blocking temperatures (the signal is maximum at $T=$23 K)  This can be easily understood as a magnetic percolation of the four independent nanostructures obtained at low growth temperatures into a single magnetic nanocolumn  Therefore the magnetic volume increases sharply as well as blocking temperatures  At the same time, the size distribution widens as observed in TEM  In Fig  12a, we have performed ZFC-FC measurements at different $T_{0}$ temperatures  The ZFC-FC irreversibility is observed up to the Curie temperature of $\approx$120 K meaning that a fraction of nanocolumns is ferromagnetic (\textit{i e } $T_{B}\geq T_{C}$) 
In Fig  12b, in-plane and out-of-plane ZFC curves nearly superimpose for $T\leq$150 K due to the isotropic magnetic behavior of the nanocolumns: in-plane magnetoelastic anisotropy is still compensating out-of-plane shape anisotropy  Moreover the magnetic signal above 150 K corresponding to Ge$_{3}$Mn$_{5}$ clusters that start to form in this growth temperature range is strongly anisotropic  This perpendicular anisotropy confirms the epitaxial relation: (0002) Ge$_{3}$Mn$_{5}$ $\parallel$ (002) Ge discussed in Ref \cite{Bihl06}  The magnetic easy axis of the clusters lies along the hexagonal $c$-axis which is perpendicular to the film plane 

\begin{figure}[ht]
\center
   \includegraphics[width= 35\linewidth]{ /fig13a eps}
   \includegraphics[width= 63\linewidth]{ /fig13b eps} 
\caption{(a) ZFC-FC measurements performed on a Ge$_{0 887}$Mn$_{0 113}$ sample grown at 145$^{\circ}$C  The in-plane applied field is 0 015 T  Magnetization was recorded up to different T$_{0}$ temperatures: 50 K, 100 K, 150 K, 200 K, 250 K and 300 K  Curves are shifted up for more clarity  (b) ZFC-FC curves for in-plane and out-of-plane applied fields (0 015 T) }
\label{fig13}
\end{figure}

For growth temperatures $T_{g}\geq$145$^{\circ}$C the cluster magnetic signal dominates (Fig  13b)  Superparamagnetic nanostructures are investigated performing ZFC-FC measurements at different $T_{0}$ temperatures (Fig  13a)  The first ZFC peak at low temperature \textit{i e } $\leq$ 150 K is attributed to  low-$T_{C}$ nanocolumns ($T_{C}\approx$130 K)  This peak is wider than for lower growth temperatures and its maximum is further shifted up to 30 K  These results are in agreement with TEM observations: increasing $T_{g}$ leads to larger nanocolumns (\textit{i e } higher blocking temperatures) and wider size distributions  ZFC-FC irreversibility is observed up to the Curie temperature due to the presence of ferromagnetic columns  The second peak above 180 K in the ZFC curve is attributed to Ge$_{3}$Mn$_{5}$ clusters and the corresponding ZFC-FC irreversibility persisting up to 300 K means that some clusters are ferromagnetic  We clearly evidence the out-of-plane anisotropy of Ge$_{3}$Mn$_{5}$ clusters and the isotropic magnetic behavior of nanocolumns (Fig  13b)  In this growth temperature range, we have also investigated the Mn concentration dependence of magnetic properties  

\begin{figure}[ht]
\center
    \includegraphics[width= 49\linewidth]{ /fig14a eps}
    \includegraphics[width= 49\linewidth]{ /fig14b eps} 
\caption{Temperature dependence of the saturation magnetization (in $\mu_{B}$/Mn) of Ge$_{1-x}$Mn$_{x}$ films grown at 150$^{\circ}$C plotted for different Mn concentrations: 2 3 \%; 4 \%; 7 \%; 9 \%; 11 3 \%  (b) ZFC-FC measurements performed on Ge$_{1-x}$Mn$_{x}$ films grown at 150$^{\circ}$C  The in-plane applied field is 0 025 T for 2 3 \% and 4 \% and 0 015 T for 8 \% and 11 3 \%  }
\label{fig14}
\end{figure}

In Fig  14a, for low Mn concentrations (2 3 \% and 4 \%) the contribution from diluted Mn atoms in the germanium matrix to the saturation magnetization is very high and nearly vanishes for higher Mn concentrations (7 \%, 9 \% and 13 \%) as observed for low growth temperatures  Above 7 \%, the magnetic signal mainly comes from nanocolumns and Ge$_{3}$Mn$_{5}$ clusters  We can derive more information from ZFC-FC measurements (Fig  14b)  Indeed, for 2 3 \% of Mn, ZFC and FC curves nearly superimpose down to low temperature meaning that nanocolumns are superparamagnetic in the whole temperature range  Moreover the weak irreversibility arising at 300 K  means that some Ge$_{3}$Mn$_{5}$ clusters have already formed in the samples even at very low Mn concentrations  For 4 \% of Mn, we can observe a peak with a maximum at the blocking temperature (12 K) in the ZFC curve  We can also derive the Curie temperature of nanocolumns: $\approx$45 K  The irresversibility arising at 300 K still comes from Ge$_{3}$Mn$_{5}$ clusters  Increasing the Mn concentration above 7 \% leads to: higher blocking temperatures (20 K and 30 K) due to larger nanocolumns and wider ZFC peaks due to wider size distributions in agreement with TEM observations (see Fig  3a)  Curie temperatures also increase (110 K and 130 K) as well as the contribution from Ge$_{3}$Mn$_{5}$ clusters \\
Finally when increasing $T_{g}$ above 160$^{\circ}$C, the nanocolumns magnetic signal vanishes and only Ge$_{3}$Mn$_{5}$ clusters and diluted Mn atoms coexist  The overall magnetic signal becomes comparable to the one measured on annealed samples in which only Ge$_{3}$Mn$_{5}$ clusters are observed by TEM (see Fig  7a) \\
The magnetic properties of high-$T_{C}$ nanocolumns obtained for $T_{g}$ close to 130$^{\circ}$C are discussed in detail in Ref \cite{Jame06} \\
In conclusion, at low growth temperatures ($T_{g}\leq$120$^{\circ}$C), nanocolumns are made of almost 4 independent elongated magnetic nanostructures  For $T_{g}\geq$120$^{\circ}$C, these independent nanostructures percolate into a single nanocolumn sharply leading to higher blocking temperatures  Increasing $T_{g}$ leads to larger columns with a wider size distribution as evidenced by ZFC-FC measurements and given by TEM observations  In parallel, some Ge$_{3}$Mn$_{5}$ clusters start to form and their contribution increases when increasing $T_{g}$  Results on magnetic anisotropy seems counter-intuitive  Indeed Ge$_{3}$Mn$_{5}$ clusters exhibit strong out-of-plane anisotropy whereas nanocolumns which are highly elongated magnetic structures are almost isotropic  This effect is probably due to compensating in-plane magnetoelastic coupling (due to the columns compression) and out-of-plane shape anisotropy  

\section{Conclusion}

In this paper, we have investigated the structural and magnetic properties of thin Ge$_{1-x}$Mn$_{x}$ films grown by low temperature molecular beam epitaxy  A wide range of growth temperatures and Mn concentrations have been explored  All the samples contain Mn-rich nanocolumns as a consequence of 2D-spinodal decomposition  However their size, crystalline structure and magnetic properties depend on growth temperature and Mn concentration  For low growth temperatures, nanocolumns are very small (their diameter ranges between 1 8 nm for 1 3 \% of Mn and 2 8 nm for 11 3 \% of Mn), their Curie temperature is rather low ($<$ 170 K) and they behave as almost four uncorrelated superparamagnetic nanostructures  Increasing Mn concentration leads to higher columns densities while diameters remain nearly unchanged  For higher growth temperatures, the nanocolumns mean diameter increases and their size distribution widens  Moreover the 4 independent magnetic nanostructures percolate into a single magnetic nanocolumn  Some columns are ferromagnetic even if Curie temperatures remain quite low  In this regime, increasing Mn concentration leads to larger columns while their density remains nearly the same  In parallel, Ge$_{3}$Mn$_{5}$ nanoclusters start to form in the film with their $c$-axis perpendicular to the film plane  In both temperature regimes, the Mn incorporation mechanism in the nanocolumns and/or in the matrix changes above 5 \% of Mn and nanocolumns exhibit an isotropic magnetic behaviour due to the competing effects of out-of-plane shape anisotropy and in-plane magnetoelastic coupling  Finally for a narrow range of growth temperatures around 130$^{\circ}$C, nanocolumns exhibit Curie temperatures higher than 400 K  Our goal is now to investigate the crystalline structure inside the nanocolumns, in particular the position of Mn atoms in the distorted diamond structure, which is essential to understand magnetic and future transport properties in Ge$_{1-x}$Mn$_{x}$ films 

\section{Aknowledgements}
The authors would like to thank Dr  F  Rieutord for grazing incidence x-ray diffraction measurements performed on the GMT station of BM32 beamline at the European Synchrotron Radiation Facility 


Context 2: Margaret Way (b  Brisbane d  Cleveland, Queensland, Australia ) was an Australian writer of romance novels and women's fiction  A prolific author, Way wrote more than 120 novels since 1970, many through Mills & Boon, a romance imprint of British publisher Harlequin UK Ltd , owned by Harlequin Enterprises 

Biography
Before her marriage, she was a well-known pianist, teacher, vocal coach and accompanist  She began writing when her son, Laurence Way, was born, a friend took a pile of Mills & Boon books to her, she read all and decided that she also could write these types of novels  She began to write and promote her country with her stories set in Australia  She sold her first novels in 1970  Margaret Way lives with her family in her native Brisbane  Beginning in 2013, Margaret began to self-publish, releasing her first "e-book" mid-July 

Margaret died on the 10th of August 2022 in Cleveland, Queensland 

Bibliography

Single Novels
King Country (1970)
Blaze of Silk (1970)
The Time of the Jacaranda (1970)
Bauhinia Junction (1971)
Man from Bahl Bahla (1971)
Summer Magic (1971)
Return to Belle Amber (1971)
Ring of Jade (1972)
Copper Moon (1972)
Rainbow Bird (1972)
Man Like Daintree (1972)
Noonfire (1972)
Storm Over Mandargi (1973)
Wind River (1973)
Love Theme (1974)
McCabe's Kingdom (1974)
Sweet Sundown (1974)
Reeds of Honey (1975)
Storm Flower (1975)
Lesson in Loving (1975)
Flight into Yesterday (1976)
Red Cliffs of Malpara (1976)
Man on Half-moon (1976)
Swan's Reach (1976)
Mutiny in Paradise (1977)
One Way Ticket (1977)
Portrait of Jaime (1977)
Black Ingo (1977)
Awakening Flame (1978)
Wild Swan (1978)
Ring of Fire (1978)
Wake the Sleeping Tiger (1978)
Valley of the Moon (1979)
White Magnolia (1979)
Winds of Heaven (1979)
Blue Lotus (1979)
Butterfly and the Baron (1979)
Golden Puma (1980)
Temple of Fire (1980)
Lord of the High Valley (1980)
Flamingo Park (1980)
North of Capricorn (1981)
Season for Change (1981)
Shadow Dance (1981)
McIvor Affair (1981)
Home to Morning Star (1981)
Broken Rhapsody (1982)
The Silver Veil (1982)
Spellbound (1982)
Hunter's Moon (1982)
Girl at Cobalt Creek (1983)
No Alternative (1983)
House of Memories (1983)
Almost a Stranger (1984)
A place called Rambulara (1984)
Fallen Idol (1984)
Hunt the Sun (1985)
Eagle's Ridge (1985)
The Tiger's Cage (1986)
Innocent in Eden (1986)
Diamond Valley (1986)
Morning Glory (1988)
Devil Moon (1988)
Mowana Magic (1988)
Hungry Heart (1988)
Rise of an Eagle (1988)
One Fateful Summer (1993)
The Carradine Brand (1994)
Holding on to Alex (1997)
The Australian Heiress (1997)
Claiming His Child (1999)
The Cattleman's Bride (2000)
The Cattle Baron (2001)
The Husbands of the Outback (2001)
Secrets of the Outback (2002)
With This Ring (2003)
Innocent Mistress (2004)
Cattle Rancher, Convenient Wife (2007)
Outback Marriages (2007)
Promoted: Nanny to Wife (2007)
Cattle Rancher, Secret Son (2007)
Genni's Dilemma (2008)
Bride At Briar Ridge (2009)
Outback Heiress, Surprise Proposal (2009)
Cattle Baron, Nanny Needed (2009)

Legends of the Outback Series
Mail Order Marriage (1999)
The Bridesmaid's Wedding (2000)
The English Bride (2000)
A Wife at Kimbara (2000)

Koomera Crossing Series
Sarah's Baby (2003)
Runaway Wife (2003)
Outback Bridegroom (2003)
Outback Surrender (2003)
Home to Eden (2004)

McIvor Sisters Series
The Outback Engagement (2005)
Marriage at Murraree (2005)

Men Of The Outback Series
The Cattleman (2006)
The Cattle Baron's Bride (2006)
Her Outback Protector (2006)
The Horseman (2006)

Outback Marriages Series
Outback Man Seeks Wife (2007)
Cattle Rancher, Convenient Wife (2007)

Barons of the Outback Series Multi-Author
Wedding At Wangaree Valley (2008)
Bride At Briar's Ridge (2008)

Family Ties Multi-Author
Once Burned (1995)

Hitched! Multi-Author
A Faulkner Possession (1996)

Simply the Best Multi-Author
Georgia and the Tycoon (1997)

The Big Event Multi-Author
Beresford's Bride (1998)

Guardian Angels Multi-Author
Gabriel's Mission (1998)

Australians Series Multi-Author
7  Her Outback Man (1998)
17  Master of Maramba (2001)
19  Outback Fire (2001)
22  Mistaken Mistress (2002)
24  Outback Angel (2002)
33  The Australian Tycoon's Proposal (2004)
35  His Heiress Wife (2004)

Marrying the Boss Series Multi-Author
Boardroom Proposal (1999)

Contract Brides Series Multi-Author
Strategy for Marriage (2002)

Everlasting Love Series Multi-Author
Hidden Legacy (2008)

Diamond Brides Series Multi-Author
The Australian's Society Bride (2008)

Collections
Summer Magic / Ring of Jade / Noonfire (1981)
Wife at Kimbara / Bridesmaid's Wedding (2005)

Omnibus in Collaboration
Pretty Witch / Without Any Amazement / Storm Over Mandargi (1977) (with Lucy Gillen and Margaret Malcolm)
Dear Caliban / Heart of the Eagle / Swans' Reach (1978) (with Jane Donnelly and Elizabeth Graham)
The Bonds of Matrimony / Dragon Island / Reeds of Honey (1979) (with Elizabeth Hunter and Henrietta Reid)
The Man Outside / Castles in Spain / McCabe's Kingdom (1979) (with Jane Donnelly and Rebecca Stratton)
Winds From The Sea / Island of Darkness / Wind River (1979) (with Margaret Pargeter and Rebecca Stratton)
Moorland Magic / Tree of Idleness / Sweet Sundown (1980) (with Elizabeth Ashton and Elizabeth Hunter)
The Shifting Sands / Portrait of Jaime / Touched by Fire (1982) (with Jane Donnelly and Kay Thorpe)
Head of Chancery / Wild Heart / One-Way Ticket (1986) (with Betty Beaty and Doris Smith)
Heart of the Scorpion / The Winds of Heaven / Sweet Compulsion (1987) (with Janice Gray and Victoria Woolf)
One Brief Sweet Hour / Once More With Feeling / Blue Lotus (1990) (with Jane Arbor and Natalie Sparks)
Marry Me Cowboy (1995) (with Janet Dailey, Susan Fox and Anne McAllister)
Husbands on Horseback (1996) (with Diana Palmer)
Wedlocked (1999) (with Day Leclaire and Anne McAllister)
Mistletoe Magic (1999) (with Betty Neels and Rebecca Winters)
The Australians (2000) (with Helen Bianchin and Miranda Lee)
Weddings Down Under (2001) (with Helen Bianchin and Jessica Hart)
Outback Husbands (2002) (with Marion Lennox)
The Mother's Day Collection (2002) (with Helen Dickson and Kate Hoffmann)
Australian Nights (2003) (with Miranda Lee)
Outback Weddings (2003) (with Barbara Hannay)
Australian Playboys (2003) (with Helen Bianchin and Marion Lennox)
Australian Tycoons (2004) (with Emma Darcy and Marion Lennox)
A Mother's Day Gift (2004) (with Anne Ashley and Lucy Monroe)
White Wedding (2004) (with Judy Christenberry and Jessica Steele)
A Christmas Engagement (2004) (with Sara Craven and Jessica Matthews)
A Very Special Mother's Day (2005) (with Anne Herries)
All I Want for Christmas    (2005) (with Betty Neels and Jessica Steele)
The Mills and Boon Collection (2006) (with Caroline Anderson and Penny Jordan)
Outback Desire (2006) (with Emma Darcy and Carol Marinelli)
To Mum, with Love (2006) (with Rebecca Winters)
Australian Heroes (2007) (with Marion Lennox and Fiona McArthur)
Tall, Dark and Sexy (2008) (with Caroline Anderson and Helen Bianchin)
The Boss's Proposal (2008) (with Jessica Steele and Patricia Thayer)
Island Heat / Outback Man Seeks Wife / Prince's Forbidden Virgin / One Night Before Marriage / Their Lost-and-found Family / Single Dad's Marriage Wish (2008) (with Robyn Donald, Marion Lennox, Carol Marinelli, Sarah Mayberry and Anne Oliver)
Australian Billionaires (2009) (with Jennie Adams and Amy Andrews)
Cattle Baron : Nanny Needed / Bachelor Dad on Her Doorstep (2009) (with Michelle Douglas)

External links
Margaret Way at Harlequin Enterprises Ltd

Australian romantic fiction writers
Australian women novelists
Living people
Year of birth missing (living people)
Women romantic fiction writers
Context 3: A special tribute to Del Bigtree (pictured) and his team at ICAN for his stunning 88 page letter to the HHS regarding vaccine safety  As Del reported - in the latest edition of Highwire - the letter, in response to an earlier reply from the then acting Director National Vaccine Program Office, Melinda Wharton, took virtually a year to compile, and is a meticulous piece of research  Most sensationally they researched the HHS claim through US government archives that at least some pediatric vaccines had been trialed against genuine placebo, and came to a negative conclusion  Not only that, they established that none of the vaccines those vaccines had been trialed against had ever been trialed against genuine placebo either  At the end of the line the toxic products were only being compared with other toxic products, rather than against saline 
Leave aside the sceptics, for any believer in the vaccine program as a necessary intervention in public health, this should be a devastating finding  Fundamentally, the research into the safety of any of the products before marketing was simply not there  The manufacturers apparently had no faith that their proto-products could withstand this scrutiny, and for the rest they just did not care: under the alleged imperative of protecting the population it seems anything went  So even before all the sham monitoring procedures and reviews which Del and his team dismantle in forensic detail we are left with the proposition that none of the present products being given to US children – and frequently other children across most of the developed world – have any meaningful pre-marketing safety data all  If you are believer in the program you have been let down: if you wanted a program with any pretensions to safety - supposing such a thing to be possible - it looks like you would have to start from scratch  The manufacturers did this: the governments, the politicians and the regulators (internationally) let it happen 
This damning document is published simultaneously with a demand in the UK from the Royal Society for Public Health (which I had never heard of) to shut down comment about vaccines on the web  It echoes calls from Seth Berkley of GAVI, Heidi Larson of the Vaccine Confidence Project and the European Parliament  The pamphlet airily dismisses concerns that vaccines have side effects or that you could possibly have too many  It is pure public relations, and if the RSPH claims to be "independent" it also admits that the publication was paid for by Merck, a detail which was reported by British Medical Journal and the Guardian, but not true to form by the BBC  We have, in truth, been building to this moment for two decades: as the evidence piles up that every single aspect of the program lacks integrity or is simply rotten to the core all the perpetrators can do is call for the silencing of their critics, and maintain the products are safe because they say so 
Please help give the ICAN letter the widest possible distribution, particularly to politicians 
"The outcome of disease always depends both on the virulence of the pathogen and the health of the individual immune system "
Nope  This makes no sense  Lots of people who seemed vibrant will get a very severe case of the same illness that a vulnerable baby overcomes in a day 
And under the germ theory it doesn't matter how strong your immune system *was*  Once it's been overcome by the pathogen it is every bit as weak as anybody else's with that pathogen 
What you say makes no sense  There's no reason for me to reply to you again 
"Why do you think that within a few years (not many) of the introduction of the vaccines for them, pertussis, measles, mumps, rubella, tetanus, diphtheria, Hib disease, and chickenpox (and others) almost entirely disappeared?"
Why do you keep asking this question when I've already provided the answer hundreds of times? Why are you so desperate to believe the people who you already recognize are harming our children?
Why would Walter Reed be any more trustworthy than Paul Offit or Senator Pan? Why would Jenner or Pasteur?
And you went no way to explaining my arguments against germ theory  If we are attacked by billions of viruses every day then if even a tiny fraction of them are pathogenic then we couldn't possibly survive  And even if we could, we would already be immune rendering every vaccine pointless  Once we had survived our first few days on earth, then we could never get sick again 
If that's wrong then we must conclude that precisely 0% of germs are pathogenic 
Plus your comment about the immune system completely misunderstood my point  The immune system does not allow us to overcome our math problem  In fact, it makes it worse 
You did provide one solitary example of a patient with what are presumably yellow fever symptoms but you didn't say whether they had been given any toxic medical treatments 
And like I said before, the whole "incubation period" is more than a little suspicious  Clearly they never found what they thought they would and just rigged the results to tell them what they want to hear 
Like every other germ theorist/vaccine promoter in history 
Many kinds of bacteria are constantly evolving and changing, like flu viruses  Others are more stable over time, like the yellow fever virus  Those that change develop new ways of infiltrating the cells of the organism being attacked (from our point of view, from its unconscious point of view, it's just carrying out its need to replicate, which it can only do inside the cells of its host)  The changes which allow it to better infiltrate are more successful and result in more viruses with those traits 
Our immune system is designed to detect and destroy potentially dangerous invading pathogens  Many bacteria are usually harmless and absolutely necessary  The minority are dangerous, and most people's immune systems do a good job of analyzing them and killing them, often with no signs of disease  Others experience a clinical infection, and the immune system usually mounts a successful attack on them 
The outcome of disease always depends both on the virulence of the pathogen and the health of the individual immune system  Vaccines are usually effective in giving immunity to the targeted diseases  They also have many dangers which everyone should be aware of, and vaccines should be avoided whenever possible  But in the case of the most dangerous diseases, everyone should learn about them and think about what he wants to do to protect himself and his children from them, considering all the factors involved  And no one can have 100% certainty that he has made the right decision, but that's life  But if you live in the Congo and many people around you are currently dying of yellow fever, then that means that you yourself are at risk of being bitten by a loaded mosquito and getting, often dying, of yellow fever  The yellow fever vaccine is very effective at preventing yellow fever  From there, each person must make a choice 
At the end of this stage there is a remission of two or three days  About 80% of those with clinical disease recover at this point, with permanent immunity



ground_truth: 1425 $\mu_{B}$.

prompt_front: Now, answer the following question based on the text below, only give me the answer and do not output any other words.

Question: Where was Margaret Way born and where did she die?

Read the following text and answer briefly.

Context 3:  The other 20% enter the toxic stage, with a return of the fever, black vomit (coffee-ground emesis), diarrhea, a slowing of the pulse (Faget's sign), jaundice, yellow eyes, yellow skin, and failure of the kidneys, liver, and heart  The patient gets a strange hiccup (like with Ebola, a related disease), falls into a coma, and dies  About half of those patients who enter the toxic stage dies, even now, even with the best of hospital care  The Faget's sign can also occur at the end of the first stage 
You asked specifically about the symptoms of the Americans on Dr  Reed's team who got yellow fever in Cuba in 1900  I'll give the passage from The American Plague (162-5), which describes the course of Jesse Lazear's illness  "In his logbook, Lazear wrote an unusual entry on September 13  In all cases before those, page after page of records, Lazear had used the soldier's name and simply the date he was bitten, with no other attention to the mosquito  A one-line entry with a name and a date  On that day, however, in his elegant hand, Lazear did not write the soldier's name, but instead wrote 'Guinea Pig No  1 ' He went on to write that this guinea pig had been bitten by a mosquito that developed from an egg laid by a mosquito that developed from an egg laid by a mosquito that fed on a number of yellow fever cases: Suarez, Hernández, De Long, Ferández  It was a precise, detailed history that proved beyond doubt that the mosquito was loaded with the virus when it bit a healthy soldier   (If he had entered his name, then his death would have been considered medical suicide by the insurance company, and his wife and two children would not have gotten any payment ) For the next few days, Lazear's life continued much as it had over the last few months in Cuba  He fed and cared for the mosquitoes in the lab    Then he began to lose his appetite  He skipped a few meals in the mess hall  He didn't mention it to anyone, nor did he ask to see one of the yellow fever doctors; instead, he worked hard in the lab trying to ignore the oncoming headache 
"On September 18, he complained of feeling 'out of sorts,' and stayed in his officer's quarters  His head pounded and L  decided to write a letter    (he wrote to his mother, and referred to his one-year old son Houston and the baby his wife Mabel was about to have: they were staying with his mother in the US)    That night, L  started to feel chilled as the fever came on  He never went to sleep but worked at his desk all through the night, trying to get all the information about the mosquitoes organized  By morning, he showed all the signs of a severe attack of yellow fever  The camp doctors made the diagnosis, and L  agreed to go to the yellow fever ward    L  was carried by litter out of the two-room, white pine board house in which he had lived since he and Mabel first arrived in Cuba    (In the yellow fever ward, in a separate one-room building), Lena Warner (the immune nurse who had survived the yellow fever in 1878, when she was nine, and was found in her boarded-up house by a former slave who first thought she was dead, and carried her to safety) nursed J L , recording his vitals  (I put up a link to his case record and vital signs last week  The surgeon general required that this record be made for every yellow fever patient )    (On September 25,) Lena Warner braced L's arms with all of her weight, shouting for help  Still he bolted from the bed, darting around the small frame-wood room as wildly as a trapped insect beating against glass  Two soldiers ran into the ward, pinning L to his bed, tying restraints around his wrists and elbows



ground_truth: Margaret Way was born in Brisbane and died in Cleveland, Queensland, Australia.

prompt_front: Now, answer the following question based on the text below, only give me the answer and do not output any other words.

Question: What were the vaccines trialed against?

Read the following text and answer briefly.

Context 3:    Warner sponged his body with iced whiskey and water  She recorded his temperature, which had held at 104 degrees for days, on the chart beside his bed    (Warner watched him sleep ) But the quiet did not last  L's body began to lurch, and black vomit rolled from his mouth; through the bar hanging above his hospital cot  He writhed in the bed, and his skin grew deep yellow  His 104 temperature slowly fell, leveling out 99 degrees, and JL died at 8:45 p m  at the age of thirty-four "
As is obvious, there are many problems with vaccines  But, that being said, most of them usually work for a period of time to prevent the targeted diseases  The basic science behind vaccines is correct  Why do you think that within a few years (not many) of the introduction of the vaccines for them, pertussis, measles, mumps, rubella, tetanus, diphtheria, Hib disease, and chickenpox (and others) almost entirely disappeared? In the case of the routine childhood diseases, this was a bad thing, but it is a true thing 
Vaccines usually don't cause any obvious reactions  While they usually prevent the diseases, and that's why people continue to get them  With the increasing vaccination schedule, more and more are severely and permanently damaged, and it is immoral to mandate any vaccine for anyone for this reason  But it would also be immoral to prohibit vaccines for those who want them enough to take the risk 
Your article said as though it had any probative value that 90% of those who get pertussis had been vaxxed  The old DPT vaccine was MUCH more effective at preventing pertussis, but it was so dangerous (again, not to most, but to many), that developed countries replaced it with the acellular version, DTaP  From the beginning about twenty years ago, it was clear that it was not very effective and that huge numbers of vaxxed people got pertussis anyway, including my daughter who got pertussis at eight month old after having gotten three DTaPs  The pertussis vaccine continues to be very dangerous, and I do not recommend that anyone get it  It used to be a killer disease, but evolved to become much milder, to the extent that the disease is very rarely dangerous (usually only to newborns under three months old), while the vaccine is very dangerous  And they're trying to see how they can go back to the old DPT  This does not show that vaccine science has collapsed, but rather that the vaccine they developed to replace the DPT turned out to be much less effective than they first thought, while continuing to be much more dangerous than they first thought 
Your article extrapolated from that that modern medical science in general has collapsed, but that, again, is going too far  A older woman in Mexico City who is like my mother to me had a pacemaker inserted about two months ago to aid her failing heart, and it has restored her to optimism and energy, when she was despondent, weak, and close to death  I took my daughter to the dentist yesterday, who said she has three wisdom teeth coming in and that she said that the lower right one was sore  So, although I am cautious about X-rays, I made an appointment for a panoramic X-ray in a month to assess the wisdom teeth, and, if it seems appropriate, I'll take her to an oral surgeon to have one or more extracted under IV sedation, in his office, if possible (the dentist thought that it would be)  And I am confident that there will be no serious problems, but this is thanks to technology and training in modern medicine that haven't been available for that long 
I think that everyone should inform himself on all medical procedures before agreeing to anything, but I also think that he should have access to any medical procedure which is reasonable (and opinions can differ as to that) 
One problem is that you have not said how you think people should protect themselves against tetanus, bacterial meningitis, and yellow fever in the relevant cases, for example  These are diseases which healthy, well-nourished people used to die from very readily 
If most people stopped vaxxing and the mortality from these diseases rose to something like pre-vaccine levels, do you think they should just accept dying from them?
I put that in a separate paragraph because it is the crucial issue 
balinaheuchter Air Traffic Control You Tube - Colin Campbell example of - How to "Fudge a Nudge" -"Deal" or "No Deal" "Not in a month of Sundays" "No exceptions/no compromise?" -make a trade off -do an exception- everyone get's a good deal /good outcome!
Hans, you are right that we are looking at one of the biggest crimes in all history  When I read the story of that poor girl who was so healthy and is now confined to a wheelchair after getting her third Gardasil shot I could not believe that Merck could produce such a toxic vaccine and give it out to girls like it was something they absolutely had to have only to be mislead and made into cripples  Merck should be prosecuted for the damage they have done to so many girls who got the Gardasil vaccine and were physically debilitated for life  There is a place for the people who perpetrated this crime on young girls and women and it is called hell  They have destroyed people's lives and gotten away with it  My heart goes out to those who have suffered this damage for no damn good reason except to help make huge profits for Merck!
Here is the reason that the germ theory is nonsense 
1) Everyday we are bombarded with billions of germs  Presumably at least some of them are of the kind that germ theorists believe are dangerous (otherwise we would have to conclude that none of them are dangerous)  So how do we survive?
2) Let's just say that we ignore 1 and imagine that, by way of magic, none of the billions of viruses we get bombarded with are pathogenic but all those that are are tucked away somewhere  Ok  But presumably they reside in sick people right? So where are there lots of sick people? Doctor offices and hospitals! So everybody must be dying the moment they enter these places right?
3) I love this one because I have never seen anybody else ever raise it  Under the germ theory there are no negative feedbacks  This makes a stable biological system by definition impossible  The immune system is *not* a negative feedback it is the opposite  It actually reinforces our math problem because the immune system will weaken as the number of pathogens increase 
There is no way of resolving this problem without a discontinuity  A Deus ex Machina as The Almighty Pill so beautifully put it  So the germ theory is quite literally, mathematically impossible 
There is as much chance of it being true as 2+2 = 5 
There are plenty of other massive problems with germ theory such as why did things like SARS and bird flu magically disappear? Why do we have the symptoms that we do? Is our body controlling the symptoms to help fight the germs and if so, why would suppressing the symptoms with antibiotics or Tamiflu be considered a good idea? If the virus is causing the symptoms then why would it cause these kinds of things?



ground_truth: Other toxic products.