prompt_front: Now, answer the following question based on the text below, only give me the answer and do not output any other words.

Question: Where is McPherson County located?

Read the following text and answer briefly.

Context 1: McPherson County (standard abbreviation: MP) is a county located in the U S  state of Kansas   As of the 2020 census, the county population was 30,223  The largest city and county seat is McPherson  The county is named for Civil War General James B  McPherson 

History

Early history

For many millennia, the Great Plains of North America was inhabited by nomadic Native Americans  From the 16th century to 18th century, the Kingdom of France claimed ownership of large parts of North America  In 1762, after the French and Indian War, France secretly ceded New France to Spain, per the Treaty of Fontainebleau  In 1802, Spain returned most of the land to France, but keeping title to about 7,500 square miles 

In 1803, most of the land for modern day Kansas was acquired by the United States from France as part of the 828,000 square mile Louisiana Purchase for 2 83 cents per acre  In 1848, after the Mexican–American War, the Treaty of Guadalupe Hidalgo with Spain brought into the United States all or part of land for ten future states, including southwest Kansas  In 1854, the Kansas Territory was organized, then in 1861 Kansas became the 34th U S  state 

19th century

From the 1820s to 1870s, the Santa Fe Trail passed through, what is now McPherson County  The trail entered the county, east of Canton, then south of Galva, then north of Inman, and west towards Lyons  In 1855, Charles O  Fuller established a ranch adjacent to the Running Turkey Creek Crossing about two miles south and one mile east of Galva  Fuller's Ranch provided accommodations for travelers on the Santa Fe Trail and was probably the first white settlement in McPherson County 

Peketon County was established in 1860, by the passage of a bill by S  N  Wood:  An act to establish Peketon County  Section 1  - That all that territory west of the sixth principal meridian and south of Township 16, in Kansas Territory, be and the same is hereby erected into a county, to be known by the name of Peketon County  On February 17, 1865, Peketon County was abolished, and McPherson County was made a part of Marion County, which extended from the west line of Chase County to the present western boundary of Kansas 

In 1868, Solomon Stephens and L  N  Holmberg were appointed Justices of the Peace—the first officers in what is now McPherson County  The next year (1869) occurred the first election for the township, now the county of McPherson  McPherson was regularly organized as a county in the spring of 1870, a mass meeting being held at Sweadal  Sweadal, the county seat thus selected, was located about one mile and a half southwest of the present site of Lindsborg  In September, however, the County Commissioners resolved to meet at the latter place, McPherson which had already been located some two years 

In April, 1873, a petition was filed for the county seat re-location  It was signed by 483 voters, and a special election was accordingly ordered for June 10  Upon that day, McPherson received 605 votes, New Gottland 325, King City 3 and Lindsborg 1; McPherson's majority over all, 276  In May the McPherson Town Company had offered, as an inducement for the location of the county seat at this point, the free use of rooms for ten years, and the donation of two squares of land on the town site  The offer was accepted the next month, the County Commissioners selecting blocks 56 and 65  Thus the county seat was established at McPherson and has remained since 

As early as 1875, city leaders of Marion held a meeting to consider a branch railroad from Florence  In 1878, Atchison, Topeka and Santa Fe Railway and parties from Marion County and McPherson County chartered the Marion and McPherson Railway Company   In 1879, a branch line was built from Florence to McPherson, in 1880 it was extended to Lyons, in 1881 it was extended to Ellinwood  The line was leased and operated by the Atchison, Topeka and Santa Fe Railway  The line from Florence to Marion, was abandoned in 1968  In 1992, the line from Marion to McPherson was sold to Central Kansas Railway  In 1993, after heavy flood damage, the line from Marion to McPherson was abandoned  The original branch line connected Florence, Marion, Canada, Hillsboro, Lehigh, Canton, Galva, McPherson, Conway, Windom, Little River, Mitchell, Lyons, Chase, then connected with the original AT&SF main line at Ellinwood 

In 1887, the Chicago, Kansas and Nebraska Railway extended its main line from Herington to Pratt   This main line connected Herington, Ramona, Tampa, Durham, Waldeck, Canton, Galva, McPherson, Groveland, Inman, Medora, Hutchinson, Whiteside, Partridge, Arlington,  Langdon, Turon, Preston, Natrona, Pratt   In 1888, this main line was extended to Liberal   Later, this line was extended to Tucumcari, New Mexico and Santa Rosa, New Mexico, where it made a connection with the Southern Pacific from El Paso, Texas   The Chicago, Kansas and Nebraska Railway was absorbed by the Chicago, Rock Island and Pacific Railway  This line is also called the "Golden State Route" 

20th century
The National Old Trails Road, also known as the Ocean-to-Ocean Highway, was established in 1912, and was routed through Windom, Conway, McPherson 

Geography

According to the U S  Census Bureau, the county has a total area of , of which  is land and  (0 3%) is water 

Adjacent counties
 Saline County (north)
 Dickinson County (northeast)
 Marion County (east)
 Harvey County (southeast)
 Reno County (southwest)
 Rice County (west)
 Ellsworth County (northwest)

Major highways
  Interstate 135
  U S  Route 56
  U S  Route 81
  K-4
  K-61
  K-153

Demographics

The McPherson Micropolitan Statistical Area includes all of McPherson County 

2000 census
As of the census of 2000, there were 29,554 people, 11,205 households, and 7,966 families residing in the county   The population density was 33 people per square mile (13/km2)   There were 11,830 housing units at an average density of 13 per square mile (5/km2)   The racial makeup of the county was 96 53% White, 0 81% Black or African American, 0 34% Native American, 0 32% Asian, 0 06% Pacific Islander, 0 79% from other races, and 1 16% from two or more races   1 94% of the population were Hispanic or Latino of any race  37 1% were of German, 12 9% Swedish, 12 1% American, 6 7% English and 6 3% Irish ancestry according to Census 2000 

There were 11,205 households, out of which 33 00% had children under the age of 18 living with them, 62 50% were married couples living together, 6 00% had a female householder with no husband present, and 28 90% were non-families  25 50% of all households were made up of individuals, and 11 80% had someone living alone who was 65 years of age or older   The average household size was 2 49 and the average family size was 2 99 

In the county, the population was spread out, with 25 40% under the age of 18, 10 30% from 18 to 24, 25 20% from 25 to 44, 21 80% from 45 to 64, and 17 30% who were 65 years of age or older   The median age was 38 years  For every 100 females there were 95 90 males   For every 100 females age 18 and over, there were 92 90 males 

The median income for a household in the county was $41,138, and the median income for a family was $48,243  Males had a median income of $33,530 versus $21,175 for females  The per capita income for the county was $18,921   About 4 20% of families and 6 60% of the population were below the poverty line, including 5 20% of those under age 18 and 8 10% of those age 65 or over 

Government

Presidential elections
McPherson county is often carried by Republican candidates  The last time a Democratic candidate has carried this county was in 1964 by Lyndon B  Johnson 

Laws
Following amendment to the Kansas Constitution in 1986, the county remained a prohibition, or "dry", county until 1996, when voters approved the sale of alcoholic liquor by the individual drink with a 30 percent food sales requirement 

Education

Colleges
 McPherson College in McPherson
 Bethany College in Lindsborg
 Central Christian College in McPherson

Unified school districts
 Smoky Valley USD 400
 McPherson USD 418
 Canton-Galva USD 419
 Moundridge USD 423
 Inman USD 448

School district office in neighboring county
 Goessel USD 411
 Little River-Windom USD 444

Museums
 Birger Sandzén Memorial Gallery in Lindsborg
 McCormick-Deering Days Museum in Inman
 McPherson Museum in McPherson
 Lindsborg Old Mill & Swedish Heritage Museum in Lindsborg
 Kansas Motorcycle Museum in Marquette

Communities

Cities

 Canton
 Galva
 Inman
 Lindsborg
 Marquette
 McPherson (county seat) 
 Moundridge
 Windom

Unincorporated communities
† means a Census-Designated Place (CDP) by the United States Census Bureau 
 Conway
 Elyria†
 Groveland
 Johnstown
 New Gottland
 Roxbury†

Ghost towns
 Alta Mills
 Battle Hill
 Christian
 Doles Park
 Elivon
 King City
 Sweadal

Townships
McPherson County is divided into twenty-five townships   The cities of Lindsborg and McPherson are considered governmentally independent and are excluded from the census figures for the townships   In the following table, the population center is the largest city (or cities) included in that township's population total, if it is of a significant size 

See also
 List of people from McPherson County, Kansas
 National Register of Historic Places listings in McPherson County, Kansas
 McPherson Valley Wetlands
 Maxwell Wildlife Refuge

References

Notes

Further reading

 Wheeler, Wayne Leland  "An Analysis of Social Change in a Swedish-Immigrant Community: The Case of Lindsborg, Kansas " (PhD dissertation, University of Missouri-Columbia; ProQuest Dissertations Publishing, 1959  5905657) 

County
 Through the Years: A Pictorial History of McPherson County; McPherson Sentinel' Heritage House Publishing Co; 1992 
 McPherson County First Courthouse Built About 1869 or 1870; Lindsborg News-Record; March 30, 1959 
 Pioneer Life and Lore of McPherson County, Kansas; Edna Nyquist; Democratic-Opinion Press; 1932 
 A History of the Church of the Brethren in Kansas (includes McPherson College history); Elmer LeRoy Craik; McPherson Daily; Republican Press; 397 pages; 1922 
 Portrait and Biographical Record of Dickinson, Saline, McPherson, and Marion Counties, Kansas; Chapman Bros; 614 pages; 1893 
 Standard Atlas of McPherson County, Kansas; Geo  A  Ogle & Co; 82 pages; 1921 
 Plat Book of McPherson County, Kansas; North West Publishing Co; 50 pages; 1903 
 Edwards' Atlas of McPherson County, Kansas; John P  Edwards; 51 pages; 1884 

Trails
 The Story of the Marking of the Santa Fe Trail by the Daughters of the American Revolution in Kansas and the State of Kansas; Almira Cordry; Crane Co; 164 pages; 1915  (Download 4MB PDF eBook)
 The National Old Trails Road To Southern California, Part 1 (LA to KC); Automobile Club Of Southern California; 64 pages; 1916  (Download 6 8MB PDF eBook)

Mennonite Settlements
 Impact of Mennonite settlement on the cultural landscape of Kansas; Brenda Martin; Kansas State University; 1985/1988  
 Mennonite settlement : the relationship between the physical and cultural environment; Susan Movle; University of Utah; 1975/1886 
 Status of Mennonite women in Kansas in their church and home relationships; Eva Harshbarger; Bluffton College; 1925/1945 

External links

County
 
 McPherson County - Directory of Public Officials
Historical
 , from Hatteberg's People'' on KAKE TV news
Maps
 McPherson County Maps: Current, Historic, KDOT
 Kansas Highway Maps: Current, Historic, KDOT
 Kansas Railroad Maps: Current, 1996, 1915, KDOT and Kansas Historical Society

 
Kansas counties
1867 establishments in Kansas

Context 2: '用户指南 * User Guide 02 CN 11 EN * 包装内含 使用前注意事项 快速引导 产品部件详情说明 操作说明 02 02 03 06 08 01 
•本产品支持在系统设置中进行瞳距调节 , 调节时请务必注意，最小瞳距可能会碰触鼻梁。当您佩戴头盔后，您 “显示”中进行手动调节，请注意设置使用不合适的瞳距，可能会引起视觉重影或者眼睛疲劳。 可在“设置” ► •本产品“护眼模式”经德国 TÜV Rheinland 低蓝光认证，通过软件算法降低三色通道中的蓝光量，来达到保护 “护眼” “色彩调节” 眼睛的作用，该模式下画面颜色偏黄，您可根据个人喜好在“设置” 中激活或关闭此功能。 ““显示” ► ► ► 包装内含： VR 头盔 / 手柄 × 2 / 1 5V AA 碱性干电池 × 4/ 眼镜支架 / 遮光鼻托 / 手柄挂绳 × 2 / USB-C 电源适配器 / USB-Cto C 2 0 数据线 / 快速指南 / 用户指南 / 安全与质保指南使用前注意事项 •本产品在开阔的室內环境使用体验最佳，建议至少预留 2×2 米 的空间。使用前请确认身体没有不适且周围环 境安全，特别是佩戴头盔在室内行走移动时，要尽量避免发生意外。 •不建议 12 岁及以下儿童使用本产品，建议将头盔、手柄和配件置于儿童够不到的位置，13 岁以上青少年须在 成人监护下使用，以免发生意外。 •本产品无近视调节功能，近视用户请佩戴眼镜使用并尽量避免近视眼镜被头盔的光学镜片磨伤或刮伤。建议在 使用和收纳时注意防护光学镜片，避免尖锐物体划伤镜片，擦拭清洁时请使用柔软的眼镜布，否则可能划伤镜片， 影响视觉效果。 •长时间使用可能引发轻微的昡晕或者眼疲劳，建议使用 30 分钟后适当休息，可通过眼保健操或观看远处物体缓 解眼疲劳。如果您的身体感到任何不适，请立即停止使用。如果不适持续，请咨询医生。 •当头盔镜片被阳光或紫外线照射时（尤其在户外、阳台、窗台及汽车内存放时），可能导致屏幕出现永久性黄斑。 请尽量避免该情况发生，此种屏幕损坏不在产品的质保范围内。 *本产品最终外观及功能以实物为准，部分地区包装内含物品有所差异，本说明仅供参考。 02 CN
六自由度 VR 体验 本产品可以追踪头盔和手柄前、后、左、右、上、下和旋转的运动状态，您在现实中的肢体运动会实时反映在虚 拟世界中。 由于没有任何线缆的束缚，您在虚拟世界自由探索时请确保游玩区域的安全。 1  建议准备一个整洁安全的体验空间：至少 2×2 米；保持房间明亮，避免在只有单色的墙或大面积玻璃、镜子类 反射物以及许多移动画面和物体的空间中使用。 2  撕下 VR 头盔前端摄像头上的保护膜，并佩戴手柄挂绳。 3  根据开机后的画面提示进行游玩区域的设定。 ❶ 安装电池 按箭头方向拔出电池盖侧边的绝缘纸 快速引导 提示：本产品虚拟的安全区提醒功能，不能完全保证您在设定好的游戏区域中的安全，请时刻注意周围的安全情况。 提示：建议使用 1 5V AA 碱性电池。 按照图示拨动电池盖拨钮打开电池盖更换电池。 03 CN
❷ 手柄开机 ❸ 头盔开机 ❹ 佩戴头盔，调节至清晰舒适的位置 首次开机：拔出绝缘纸，手柄自动开机（蓝灯闪烁） 非首次开机：短按手柄 Home 键开机（蓝灯闪烁） 长按头盔电源键 2 秒（蓝灯常亮） 调节旋钮转动绑带，使后脑垫套在头上，微调绑带长度及佩戴位置至视野清晰 04 提示：近视用户请佩戴眼镜或镜片插件使用，本产品不具备近视调节功能。 CN
❺ 微调顶绑带 微调顶绑带使其受力以减少额头压力 ❻ 瞳 距 调 节 在系统设置：“设置” ► “显示”界面中进行瞳距调节，点击“+”或“-”按钮可微调瞳距直至画面清晰 64mm 请勿 强行 掰动镜 筒，以 免造 成损坏 ！ 请注 意设 置使用 不合适 的瞳 距，可 能 会引起 视 觉重影 或 者眼睛 疲 劳。准 确 的瞳距 设 置有助 于 获得清 晰 的图像 并 减少眼睛 疲劳。 05 CN
产品部件详情说明 头盔状态指示灯 蓝灯常亮：开机进行中或工作状态 黄灯常亮：充电中，电量低于 98% 红灯常亮：充电中，电量低于 20% 绿灯常亮：充电完毕，电量大于 98% 或 充满 蓝灯闪烁：关机进行中 红灯闪烁：电量低于 20% 指示灯熄灭：休眠或关机 06 ① 电源键 开机：长按 2 秒 关机：长按 5 秒 复位：长按 10 秒 开机时，短按休眠 ② ③ ④ ⑤ 状态指示灯 贴脸泡棉 音量键 彩色透视摄像头 使用时请勿遮挡 ⑥ ⑦ ⑧ 顶部绑带 可拆卸 绑带旋钮 环境追踪摄像头 使用时请勿遮挡 ⑨ ⑩ ⑪ USB-C 接口 左 / 右喇叭 距离传感器 佩戴头盔后，系统自动唤醒 摘下头盔后，系统自动休眠 ⑫ ⑬ 眼球追踪摄像头 此功能仅 Pro 版支持 使用时请勿遮挡 面部追踪摄像头 此功能仅 Pro 版支持 使用时请勿遮挡 CN
手柄状态指示灯 熄灭：已连接或者关机 蓝灯常亮：固件升级模式 蓝灯闪烁：连接中 红蓝灯交替慢速闪烁：等待配对 ① ② 摇杆 菜单键 ③ Home 键 开机 : 短按关机 : 长按 6 秒退出应用 : 短按屏幕中心校正 : 长按 1 秒④ ⑤ ⑥ ⑦ 状态指示灯 抓握键 截屏键 扳机键 ⑧ ⑨ 电池盒 打开：拨动拨钮，电池盒弹出 安装：按压直至自动锁紧 追踪光环 使用时请勿遮挡 注：手柄挂绳可按图示将粗绳穿过细绳并锁紧在手柄尾端 07 CN
手柄硬件复位 如果手柄出现按 Home 键和任何按键均无反应或者头盔中虚拟手柄卡死不动的问题可拆装电池重新启动手柄。 近视用户配戴 本设备不具备近视调节功能，头盔可支持佩戴镜框宽度小于 150mm 的大多数标准眼镜。 操作说明 头控模式 未连接手柄的情况下，您可通过转动头部光标及点击头盔音量加减按键进行操作。 切换主控手柄射线 在主控菜单下，短按对应手柄的扳机键可以切换主控手柄的射线。 屏幕中心校正 戴着头盔直视前方，按住手柄 Home 键（或头控模式下头盔上的音量减键）1 秒以上，进行屏幕中心的校正将菜 单拉到当前视野朝向位置。 断开手柄 长按手柄 Home 键直至手柄状态指示灯红灯亮起并伴随振动产生时即可松手，此时手柄关机并断开与头盔的连接。 您无需刻意进行手柄关机操作，在以下状态下手柄会自动关机省电： •头盔进入深度休眠时（摘下头盔后一段时间） •头盔手柄管理界面解绑手柄时 •头盔关机时 添加新手柄 如需添加新手柄（头盔最多可同时连接一对手柄，即左右手柄各一只），或解绑手柄后再次连接 , 可进入“设置” “手 柄”，点击“配对”，同时按住手柄 Home 键和扳机键直至手柄状态指示灯红蓝交替闪烁时即可松开，然后根据 头盔画面提示操作。 ► 休眠 / 唤醒 方式一：摘下头盔一段时间后，系统自动休眠；戴上头盔时，系统自动唤醒。 方式二：短按头盔电源键也可以进行休眠或唤醒操作。 硬件复位 头盔硬件复位 如果头盔出现短按头盔电源键没有反应或头盔的画面卡死等问题，可以长按头盔电源键 10 秒以上重新启动头盔。 08 CN
安装眼镜支架 安装遮光鼻托 如您存在眼镜摩擦光学镜片或者压迫鼻梁的问题，请按照图示安装眼镜支架以增加间隔空间。 您可根据佩戴的舒适度选择是否安装。 如您感觉鼻子处漏光影响体验，请按照图示安装遮光鼻托配件。 由于眼睛空间密闭可能加剧起雾及出汗问题，您可根据喜好选择是否安装。 ❶ 摘下贴脸泡棉 ❷ 将眼镜支架按照图示安装在产品上 ❸ 将贴脸泡棉按照图示安装眼镜支架上 ❶ 摘下贴脸泡棉 ❸ 安装贴脸泡棉❷ 将遮光鼻托按照图示方式安装在贴脸泡棉上 注：按照图示拆卸眼镜支架 09 CN
更换贴脸泡棉 贴脸泡棉多次清洁和长时间使用后会变色和质地变软，您可酌情更换新泡棉。 更换顶绑带 摘下贴脸泡棉 ❸ 安装贴脸泡棉 按照图示捏住顶绑带金属扣，往下压到底然后抽出 ❷ •购买优质热门应用 •畅 聊 社 区， 与 众 多 PICO 玩 家 一起探索 VR 世界 •管理设备更便捷 •参与丰富互动活动 •更多精彩内容等你来发现 ❶ 微 信公 众 号：PICO VR抖音：PICO官 方 旗 舰 店哔 哩 哔 哩：PICO-VR官 方微 博：PICO-VR ❶ ❷ 10 CN
In The Box: VR Headset / 2 Controllers / 4 1 5V AA Alkaline Batteries / Glasses Spacer / Nose Pad / 2 Controller Lan- yards / USB-C Power Adapter / USB-C to C 2 0 Data Cable / Quick Guide / User Guide / Safety and WarrantyGuide Important Health & Safety Notes • This product is designed and intended to be used in an open and safe indoor area, free of anytripping or slipping hazards  To avoid accidents, remain conscious to the potential confines ofyour physical area and respect the boundary of your virtual area whenever you see it  Be sure towear the lanyards when using the Controllers  Make sure that there is enough space around yourhead and body (at least 2 meters by 2 meters) to stretch your arms to avoid damage or injury toyourself, others, and your surroundings  • This product is not recommended for children aged 12 and under  It is recommended to keep headsets,controllers and accessories out of the reach of children  Teenagers aged 13 and over must use it underadult supervision to avoid accidents  • This product is designed to accommodate most prescription glasses  Make sure to wear the VR Headsetin a manner in which the VR Headset lenses do not rub or impair your prescription lenses  • Prolonged use may cause dizziness or eye fatigue  It is recommended to take a break every 30 minutes Try relieving your eyestrain by looking at distant objects  If you feel any discomfort, stop using the prod- uct immediately  If the discomfort persists, seek medical advice • Do not expose the optical lenses to direct sunlight or other strong light sources  Exposure to directsunlight may cause permanent yellow spot damage on the screen  Screen damage caused by sunlightexposure or other strong sources of light is not covered by the warranty  • This product supports interpupillary distance (IPD) adjustment in system settings  When adjusting,please be aware that with the minimum IPD, it may touch the bridge of the nose  You can adjust the IPDaccording to your actual interpupillary distance in "Settings"►"Display"  Please note that using inap- propriate IPD may increase the risk of discomfort  • This product has an “Eye Protection Mode”, certified by TÜV Rheinland (Germany), which can protectyour eyes by reducing blue light in the three color channels using software algorithms  The screen ap- pears yellowish in this mode and you can turn this feature on/off in "Settings"►"Display"►"Color"►“- Eye Protection”  • Protect optical lenses during use and storage to prevent damage, such as scratches or exposure tostrong light or direct sunlight  * Product and packaging are updated regularly, and the functions and contents of the standalone headset may be upgraded in the future Therefore, the content, appearance and functionality listed in this manual and product packaging are subject to change and may notreflect the final product  These instructions are for reference only  * Carefully read this user guide before using the product and share this information with any other users, as it contains important safetyinformation  Keep the user guide as reference for the future  11 EN
6 Degrees of Freedom VR The device can track your translational and rotational movements in all directions (up/down, left/right,forward/backward, pitch, roll, and yaw)  Your movements in the real world will be captured and translatedto what you see in the virtual world when using the appropriate content  Ensure a safe environment before you start your VR experience  1  Clear a safe indoor area of at least 2 meters by 2 meters  Keep the room bright, avoid spaces with main- ly single-colored walls, glass, mirrors, moving pictures or other similar objects  2  Remove the protective film that covers the headset front cameras  Wear the lanyards connected to theControllers  3  Set up your environment by following instructions on the VR Headset screen  Install Batteries ❶Pull the tab to remove the insulating paper  Quick Guide 2 m 2m This product can not guarantee your safety with guardian system, you will need to always pay attention to the surrounding safety  * Note: 1 5V AA alkaline batteries should be used
Context 3: Paper Info

Title: Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene
Publish Date: Unkown
Author List: Shantanu Mishra (from IBM Research Europe -Zurich), Manuel Vilas-Varela (from Department of Organic Chemistry, Center for Research in Biological Chemistry and Molecular Materials (CiQUS), University of Santiago de Compostela), Leonard-Alexander Lieske (from IBM Research Europe -Zurich), Ricardo Ortiz (from Donostia International Physics Center (DIPC)), Igor Rončević (from Department of Chemistry, University of Oxford), Florian Albrecht (from IBM Research Europe -Zurich), Diego Peña (from Department of Organic Chemistry, Center for Research in Biological Chemistry and Molecular Materials (CiQUS), University of Santiago de Compostela), Leo Gross (from IBM Research Europe -Zurich)

Figure

Fig  1 | Non-benzenoid non-alternant polycyclic conjugated hydrocarbons a, Classical nonbenzenoid non-alternant polycyclic conjugated hydrocarbons: pentalene, azulene and heptalene b, Generation of indacenes and indenoindenes through benzinterposition and benzannelation of pentalene, respectively Gray filled rings represent Clar sextets c, Closed-shell Kekulé (left) and openshell non-Kekulé (right) resonance structures of QDMs Note that meta-QDM is a non-Kekulé molecule All indenofluorene isomers, being derived through benzannelation of indacenes, contain a central QDM moiety d, Closed-shell Kekulé (top) and open-shell non-Kekulé (bottom) resonance structures of indenofluorenes Compared to their closed-shell structures, 1 and 5 gain two Clar sextets in the openshell structure, while 2-4 gain only one Clar sextet in the open-shell structure Colored bonds in d highlight the ortho-and para-QDM moieties in the two closed-shell Kekulé structures of 5  e, Scheme of on-surface generation of 5 by voltage pulse-induced dehydrogenation of 6 (C20H14) Structures 7 and 8 represent the two monoradical species (C20H13) 
Fig  2 | Characterization of open-shell indeno[1,2-a]fluorene on bilayer NaCl/Au(111) a, DFTcalculated wave functions of the frontier orbitals of 5OS in the triplet configuration for the spin up (occupied) level (isovalue: 0 002 e -Å -3 ) Blue and red colors represent opposite phases of the wave function b, Corresponding DFT-calculated spin density of 5OS (isovalue: 0 01 e -Å -3) Blue and orange colors represent spin up and spin down densities, respectively c, Probability density of the SOMOs of 5OS (isovalue: 0 001 e -Å -3 ) d, DFT-calculated bond lengths of 5OS e, Constant-height I(V) spectra acquired on a species of 5 assigned as 5OS, along with the corresponding dI/dV(V) spectra Open feedback parameters: V = -2 V, I = 0 17 pA (negative bias side) and V = 2 V, I = 0 17 pA (positive bias side) Acquisition position of the spectra is shown in Supplementary Fig 7 f, Scheme of many-body transitions associated to the measured ionic resonances of 5OS Also shown are STM images of assigned 5OS at biases where the corresponding transitions become accessible Scanning parameters: I = 0 3 pA (V = -1 2V and -1 5 V) and 0 2 pA (V = 1 3 V and 1 6 V)  g, Laplace-filtered AFM image of assigned 5OS STM set point: V = 0 2 V, I = 0 5 pA on bilayer NaCl, Δz = -0 3Å The tip-height offset Δz for each panel is provided with respect to the STM setpoint, and positive (negative) values of Δz denote tip approach (retraction) from the STM setpoint f and g show the same molecule at the same adsorption site, which is next to a trilayer NaCl island The bright and dark features in the trilayer NaCl island in g correspond to Cl -and Na + ions, respectively Scale bars: 10 Å (f) and 5 Å (g) 
Fig  3 | Characterization of closed-shell indeno[1,2-a]fluorene on bilayer NaCl/Au(111) a, DFTcalculated wave functions of the frontier orbitals of closed-shell 5 0 (isovalue: 0 002 e -Å -3 ) The wave functions shown here are calculated for the 5para geometry b, DFT-calculated bond lengths of 5ortho (top) and 5para (bottom) c, Constant-height I(V) spectra acquired on a species of 5 assigned as 5para, along with the corresponding dI/dV(V) spectra Open feedback parameters: V = -2 V, I = 0 15 pA (negative bias side) and V = 2 2 V, I = 0 15 pA (positive bias side) Acquisition position of the spectra is shown in Supplementary Fig  7  d, Scheme of many-body transitions associated to the measured ionic resonances of 5para Also shown are STM images of assigned 5para at biases where the corresponding transitions become accessible Scanning parameters: I = 0 15 pA (V = -1 5 V) and 0 2 pA (V = 1 7 V)  e, Laplace-filtered AFM image of assigned 5para STM set point: V = 0 2 V, I = 0 5 pA on bilayer NaCl, Δz = -0 7 Å  f, Selected bonds labeled for highlighting bond order differences between 5para and 5ortho For the bond pairs a/b, c/d and e/f, the bonds labeled in bold exhibit a higher bond order than their neighboring labeled bonds in 5para g, Laplace-filtered AFM images of 5 on bilayer NaCl/Cu(111) showing switching between 5OS and 5para as the molecule changes its adsorption position The faint protrusion adjacent to 5 is a defect that stabilizes the adsorption of 5  STM set point: V = 0 2 V, I = 0 5 pA on bilayer NaCl, Δz = -0 3Å  STM and STS data in c and d are acquired on the same species, while the AFM data in e is acquired on a different species Scale bars: 10 Å (d) and 5 Å (e,g) 
NMR (300 MHz, CDCl3) δ: 7 51 (m, 2H), 7 40 -7 28 (m, 5H), 7 27 -7 20 (m, 2H), 7 13 (d, J = 7 7 Hz, 1H), 2 07 (s, 3H), 1 77 (s, 3H) ppm  13C NMR-DEPT (75 MHz, CDCl3, 1:1 mixture of atropisomers) δ: 141 2 (C), 141 1 (C), 140 0 (C), 139 4 (2C), 137 5 (C), 137 4 (C), 136 0 (3C), 134 8 (C), 134 5 (C), 134 1 (C), 134 0 (C), 133 7 (C), 133 6 (C), 131 6 (CH), 131 2 (CH), 131 1 (CH), 130 7 (CH), 129 8 (CH), 129 7 (CH), 129 5 (CH), 129 4 (CH), 129 0 (CH), 128 9 (CH), 128 7 (2CH), 128 6 (2CH), 127 2 (CH), 127 1 (CH), 127 0 (CH), 126 9 (CH), 126 7 (CH), 126 6 (CH), 20 6 (CH3), 20 5 (CH3), 17 7 (CH3), 17 5 (CH3) ppm MS (APCI) m/z (%): 327 (M+1, 100) HRMS: C20H16Cl2; calculated: 327 0702, found: 327 0709 
NMR (500 MHz, CDCl3) δ: 7 93 (d, J = 7 6 Hz, 1H), 7 85 (d, J = 7 5 Hz, 1H), 7 78 (d, J = 7 7 Hz, 1H), 7 65 (d, J = 7 4 Hz, 1H), 7 61 (d, J = 7 5 Hz, 1H), 7 59 (d, J = 7 7 Hz, 1H), 7 47 (ddd, J = 8 4, 7 2, 1 1 Hz, 1H), 7 42 (dd, J = 8 1, 7 0 Hz, 1H), 7 35 (m, 2H), 4 22 (s, 3H), 4 02 (s, 3H) ppm  13C NMR-DEPT (125 MHz, CDCl3) δ: 144 1 (C), 143 3 (C), 142



ground_truth: McPherson County is located in the U.S. state of Kansas.

prompt_front: Now, answer the following question based on the text below, only give me the answer and do not output any other words.

Question: What may happen if the VR headset lenses are exposed to sunlight or strong light?

Read the following text and answer briefly.

Context 2: Slide the toggle according to arrow direction toopen the battery case  12 EN
Power on the Controller ❷ First Start: The Controller will start automaticallyafter removing the insulating paper  Others: Short press the Home button for 1second until the status indicator flashes blue Power on the VR Headset ❸ Long press the Power button for 2 seconds untilthe status indicator turns blue Wear Your Headset for a Comfortable Fit and View ❹ Adjust the strap dial to turn the strap so that the back of your head rests on the padding  Fine-tune thelength and position of the strap to give a clear view  * Note: You can use this product with prescription glasses or lenses insert  13 EN
Fine-tune the Top Strap ❺ Fine-tune the head strap to reduce pressure on the forehead  Interpupillary Distance (IPD) Adjustment ❻ In System Setting, go to “Setting” ► “Display” to adjust IPD, tap “+” or “-” button to slightly adjust IPDuntil the picture is clear  14 64mm Please note that inappropriate IPD setting may cause ghosting or eyestrain Accurate IPD setting helps you get a clear imaging and ease eyestrain  EN
Product Details VR Headset Status Indicator Legend Blue: Powered on with battery over 20% Yellow: Charging: Battery is less than 98% Red: Charging: Battery is less than 20% Green: Charging: Battery is more than 98% or charge complete Blue flashing: Shutting down Red flashing: Battery is less than 20% Off: Sleeping or Powered off Power Power on: Long press for 2 seconds Power off: Long press for 5 seconds Hardware reset: Long press for 10 seconds Short press to enter sleep or wake up Status Indicator Face Cushion Volume ① ② ③ ④ ⑤ ⑥ ⑦ ⑧ RGB See Through Camera Do not block during use  Top Strap Removable Strap Dial Tracking Cameras Do not block during use  ⑨ ⑩ ⑪ USB-C Interface Left/Right Speaker Proximity Sensor The system wakes upwhen the VR headset isput on, sleeps when VRheadset is taken off  ⑫ ⑬ Eye Tracking Cameras Pro version only  Do not block during use  Face Tracking Camera Pro version only  Do not block during use  15 EN
Controller Status Indicator Legend Off: Connected or Powered off Blue: Firmware updating in progress Blue flashing: Searching for connection Red and blue flashing alternately: Pairing in progress 16 Joystick Menu ③ ① ② Home Power on: Short pressPower off: Long press for 6 secondsReturn home screen: Short pressScreen recentering: Press for 1 secondStatus Indicator Grip Capture Trigger ④ ⑤ ⑥ ⑦ ⑧ ⑨ Battery Case Open: Slide down the toggle andpop up the battery case  Lock: Push the battery case to lock  Tracking Ring Do not block during use  * Note: Pass the Controller Lanyardthrough the string as shown andlock at the end of the Controller EN
Operating Instructions Headset Control Mode If the Controller is not connected, you can interact with the home screen by moving your head to directthe crosshairs over your intended selection and clicking the Volume Up/Down button on the VR Headset  Switch the pointer of the master Controller In the home screen, short press the Trigger of the corresponding Controller to switch the pointer of themaster Controller  Screen re-centering Wear the VR Headset and look straight ahead, press and hold the Home button of the Controller or VRHeadset ( or the Volume Down button of the VR Headset in head control mode) for more than 1 second tore-center the screen  Disconnect the Controller Press and hold the Home button until the status indicator turns red and the Controller vibrates Controllers will automatically shut down to save power in the following cases:When the VR Headset enters deep sleep (a while after the VR Headset is taken off)When the Controller is unpairedWhen the VR Headset is powered off Add a new Controller If you need to add a new Controller (the VR Headset can only connect one left Controller and one rightController) or reconnect with an unpaired Controller  Go to “Settings” ► “Controller”, click on “Pair” Press and hold the Home button and the Trigger of the Controller at the same time until the red and bluelights of the Controller flashing alternately, and then follow the instructions on the VR Headset screen  Sleep / Wake up Option 1 (Proximity Sensor) Take off VR Headset for automatic sleeping: wear the VR Headset for automat- ic waking up  Option 2 (POWER Button) Press the Power button of the VR Headset for manual sleeping or waking up  Hardware reset VR Headset reset If the visual in the VR Headset freezes, or the VR Headset does not respond after short press the Powerbutton, you can press the Power button of the VR Headset for more than 10 seconds to reboot the VRHeadset  Controller reset If the virtual Controller, the Home button or any buttons of the Controller doesn\'t respond, remove andreinstall the battery case to restart the Controller  The VR Headset Adjustment This device has no myopia adjustment function  The VR Headset allows wearing most standard glasseswith a frame width of less than 150mm  to install Glasses Spacer to increase the space  You can install or not according to your situation  17 EN
Install Glasses Spacer Install Nose Pad If you have glasses collision with headset lens or pressure on the bridge of nose, please follow the pictureto install Glasses Spacer to increase the space  You can install or not according to your situation  If you feel light leaking from your nose, please follow the picture to install Nose Pad to block the light You can consider having it installed at your own discretion  Disassemble the Face Cushion  Install the Glasses Spacer on the Headset  ❸ ❶ ❷ Install the Face Cushion on the Glasses Spacer  Disassemble the Face Cushion  Install the Nose Pad on the Face Cushion  ❶ ❷ Install the Face Cushion on the Headset  ❸ * Note: Disassemble the Glasses Spacer 18 EN
Replace Face Cushion The Face Cushion will have the following phenomena such as color change, surface fluff, soft texture afterlong-term use and repeated cleaning  You can replace a new Face Cushion as needed  Replace Top Strap ❶ ❷ Disassemble the Face Cushion  Pinch the metal buckle of the top strap asshown, press it down and pull it out Install the Face Cushion on  ❸ ❷ ❶ • Purchase high-quality and trending apps • Join PICO Community and explore the VR worldwith other PICO players• Manage your device with ease • Engage in diverse and interactive activities • More exciting features waiting for you 19 EN
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Context 3: 3 (C), 141 9 (C), 141 8 (C), 141 2 (C), 138 2 (C), 136 5 (C), 127 0 (CH), 126 9 (CH), 126 7 (CH), 126 6 (CH), 125 3 (CH), 125 2 (CH), 123 6 (CH), 122 2 (CH), 119 9 (CH), 118 4 (CH), 37 4 (CH2), 36 3 (CH2) ppm MS (APCI) m/z (%): 254 (M+, 88) HRMS: C20H14; calculated: 254 1090, found: 254 1090 

abstract

Indenofluorenes are non-benzenoid conjugated hydrocarbons that have received great interest owing to their unusual electronic structure and potential applications in nonlinear optics and photovoltaics  Here, we report the generation of unsubstituted indeno[1,2-a]fluorene, the final and yet unreported parent indenofluorene regioisomer, on various surfaces by cleavage of two C-H bonds in 7,12-dihydro indeno[1,2-a]fluorene through voltage pulses applied by the tip of a combined scanning tunneling microscope and atomic force microscope 
On bilayer NaCl on Au(111), indeno[1,2a]fluorene is in the neutral charge state, while it exhibits charge bistability between neutral and anionic states on the lower work function surfaces of bilayer NaCl on Ag(111) and Cu(111)  In the neutral state, indeno[1,2-a]fluorene exhibits either of two ground states: an open-shell π-diradical state, predicted to be a triplet by density functional and multireference many-body perturbation theory calculations, or a closedshell state with a para-quinodimethane moiety in the as-indacene core 
Switching between open-and closed-shell states of a single molecule is observed by changing its adsorption site on NaCl  The inclusion of non-benzenoid carbocyclic rings is a viable route to tune the physicochemical properties of polycyclic conjugated hydrocarbons (PCHs)   Non-benzenoid polycycles may lead to local changes in strain, conjugation, aromaticity, and, relevant to the context of the present work, induce an open-shell ground state of the corresponding PCHs  
Many nonbenzenoid PCHs are also non-alternant, where the presence of odd-membered polycycles breaks the bipartite symmetry of the molecular network   Figure shows classical examples of non-benzenoid non-alternant PCHs, namely, pentalene, azulene and heptalene  Whereas azulene is a stable PCH exhibiting Hückel aromaticity ([4n+2] π-electrons, n = 2), pentalene and heptalene are unstable Hückel antiaromatic compounds with [4n] π-electrons, n = 2 (pentalene) and n = 3 (heptalene) 
Benzinterposition of pentalene generates indacenes, consisting of two isomers s-indacene and as-indacene (Fig  )  Apart from being antiaromatic, indacenes also contain proaromatic quinodimethane (QDM) moieties (Fig  ) , which endows them with potential open-shell character  While the parent s-indacene and asindacene have never been isolated, stable derivatives of s-indacene bearing bulky substituents have been synthesized  
A feasible strategy to isolate congeners of otherwise unstable non-benzenoid non-alternant PCHs is through fusion of benzenoid rings at the ends of the π-system, that is, benzannelation  For example, while the parent pentalene is unstable, the benzannelated congener indeno[2,1-a]indene is stable under ambient conditions (Fig  )  
However, the position of benzannelation is crucial for stability: although indeno[2,1a]indene is stable, its regioisomer indeno[1,2-a]indene (Fig  ) oxidizes under ambient conditions   Similarly, benzannelation of indacenes gives rise to the family of PCHs known as indenofluorenes (Fig  ), which constitute the topic of the present work 
Depending on the benzannelation position and the indacene core, five regioisomers can be constructed, namely, indeno [ Practical interest in indenofluorenes stems from their low frontier orbital gap and excellent electrochemical characteristics that render them as useful components in organic electronic devices  
The potential open-shell character of indenofluorenes has led to several theoretical studies on their use as non-linear optical materials and as candidates for singlet fission in organic photovoltaics   Recent theoretical work has also shown that indenofluorene-based ladder polymers may exhibit fractionalized excitations 
Fundamentally, indenofluorenes represent model systems to study the interplay between aromaticity and magnetism at the molecular scale   Motivated by many of these prospects, the last decade has witnessed intensive synthetic efforts toward the realization of indenofluorenes  Derivatives of 1-4 have been realized in solution , while 1-3 have also been synthesized on surfaces and characterized using scanning tunneling microscopy (STM) and atomic force microscopy (AFM), which provide information on molecular orbital densities , molecular structure and oxidation state  
With regards to the open-shell character of indenofluorenes, 2-4 are theoretically and experimentally interpreted to be closed-shell, while calculations indicate that 1 and 5 should exhibit open-shell ground states   Bulk characterization of mesitylsubstituted 1, including X-ray crystallography, temperature-dependent NMR, and electron spin resonance spectroscopy, provided indications of its open-shell ground state  
Electronic characterization of 1 on Au(111) surface using scanning tunneling spectroscopy (STS) revealed a low electronic gap of 0 4 eV (ref  )  However, no experimental proof of an openshell ground state of 1 on Au(111), such as detection of singly occupied molecular orbitals (SOMOs) or spin excitations and correlations due to unpaired electrons , was shown 
In this work, we report the generation and characterization of unsubstituted 5  Our research is motivated by theoretical calculations that indicate 5 to exhibit the largest diradical character among all indenofluorene isomers   The same calculations also predict that 5 should possess a triplet ground state 
Therefore, 5 would qualify as a Kekulé triplet, of which only a handful of examples exist   However, definitive synthesis of 5 has never been reported so far  Previously, Dressler et al  reported transient isolation of mesityl-substituted 5, where it decomposed both in the solution and in solid state , and only the structural proof of the corresponding dianion was obtained 
On-surface generation of a derivative of 5, starting from truxene as a precursor, was recently reported   STM data on this compound, containing the indeno[1,2-a]fluorene moiety as part of a larger PCH, was interpreted to indicate its open-shell ground state  However, the results did not imply the ground state of unsubstituted 5  Here, we show that on insulating surfaces 5 can exhibit either of two ground states: an open-shell or a closed-shell 
We infer the existence of these two ground states based on high-resolution AFM imaging with bond-order discrimination and STM imaging of molecular orbital densities   AFM imaging reveals molecules with two different geometries  Characteristic bond-order differences in the two geometries concur with the geometry of either an open-or a closed-shell state 
Concurrently, STM images at ionic resonances show molecular orbital densities corresponding to SOMOs for the open-shell geometry, but orbital densities of the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) for the closed-shell geometry  Our experimental results are in good agreement with density functional theory (DFT) and multireference perturbation theory calculations 
Finally, we observe switching between open-and closed-shell states of a single molecule by changing its adsorption site on the surface  Synthetic strategy toward indeno[1,2-a]fluorene  The generation of 5 relies on the solution-phase synthesis of the precursor 7,12-dihydro indeno[1,2-a]fluorene (6)  Details on synthesis and characterization of 6 are reported in Supplementary Figs 
  Single molecules of 6 are deposited on coinage metal (Au(111), Ag(111) and Cu(111)) or insulator surfaces  In our work, insulating surfaces correspond to two monolayer-thick (denoted as bilayer) NaCl on coinage metal surfaces  Voltage pulses ranging between 4-6 V are applied by the tip of a combined STM/AFM system, which result in cleavage of one C-H bond at each of the pentagonal apices of 6, thereby leading to the generation of 5 (Fig  ) 
In the main text, we focus on the generation and characterization of 5 on insulating surfaces  Generation and characterization of 5 on coinage metal surfaces is shown in Supplementary Fig    )  Blue and orange colors represent spin up and spin down densities, respectively  c, Probability density of the SOMOs of 5OS (isovalue: 0 001 e -Å -3 ) 
d, DFT-calculated bond lengths of 5OS  e, Constant-height I(V) spectra acquired on a species of 5 assigned as 5OS, along with the corresponding dI/dV(V) spectra  Open feedback parameters: V = -2 V, I = 0 17 pA (negative bias side) and V = 2 V, I = 0 17 pA (positive bias side)  Acquisition position of the spectra is shown in Supplementary Fig    f, Scheme of many-body transitions associated to the measured ionic resonances of 5OS 
Also shown are STM images of assigned 5OS at biases where the corresponding transitions become accessible  Scanning parameters: I = 0 3 pA (V = -1 2 V and -1 5 V) and 0 2 pA (V = 1 3 V and 1 6 V)  g, Laplace-filtered AFM image of assigned 5OS  STM set point: V = 0 2 V, I = 0 5 pA on bilayer NaCl, Δz = -0 3
Å  The tip-height offset Δz for each panel is provided with respect to the STM setpoint, and positive (negative) values of Δz denote tip approach (retraction) from the STM setpoint  f and g show the same molecule at the same adsorption site, which is next to a trilayer NaCl island  The bright and dark features in the trilayer NaCl island in g correspond to Cl -and Na + ions, respectively 
Scale bars: 10 Å (f) and 5 Å (g)  To experimentally explore the electronic structure of 5, we used bilayer NaCl films on coinage metal surfaces to electronically decouple the molecule from the metal surfaces  Before presenting the experimental findings, we summarize the results of our theoretical calculations performed on 5 in the neutral charge state (denoted as 5 0 ) 
We start by performing DFT calculations on 5 0 in the gas phase  Geometry optimization performed at the spin-unrestricted UB3LYP/6-31G level of theory leads to one local minimum, 5OS, the geometry of which corresponds to the open-shell resonance structure of 5 (Fig  , the label OS denotes open-shell) 
The triplet electronic configuration of 5OS is the lowest-energy state, with the openshell singlet configuration 90 meV higher in energy  Geometry optimization performed at the restricted closed-shell RB3LYP/6-31G level reveals two local minima, 5para and 5ortho, the geometries of which (Fig  ) exhibit bond length alternations in line with the presence of a para-or an ortho-QDM moiety, respectively, in the as-indacene core of the closed-shell resonance structures of 5 (Fig  )  
Relative to 5OS in the triplet configuration, 5para and 5ortho are 0 40 and 0 43 eV higher in energy, respectively  Additional DFT results are shown in Supplementary Fig    To gain more accurate insights into the theoretical electronic structure of 5, we performed multireference perturbation theory calculations (Supplementary Fig  ) based on quasi-degenerate second-order n-electron valence state perturbation theory (QD-NEVPT2) 
In so far as the order of the ground and excited states are concerned, the results of QD-NEVPT2 calculations qualitatively match with DFT calculations  For 5OS, the triplet configuration remains the lowest-energy state, with the open-shell singlet configuration 60 meV higher in energy  The energy differences between the open-and closed-shell states are substantially reduced in QD-NEVPT2 calculations, with 5para and 5ortho only 0 11 and 0 21 eV higher in energy, respectively, compared to 5OS in the triplet configuration 
We also performed nucleus-independent chemical shift calculations to probe local aromaticity of 5 in the openand closed-shell states  While 5OS in the triplet configuration exhibits local aromaticity at the terminal benzenoid rings, 5OS in the open-shell singlet configuration, 5para and 5ortho all display antiaromaticity (Supplementary Fig  ) 
The choice of the insulating surface determines the charge state of 5: while 5 adopts neutral charge state on the high work function bilayer NaCl/Au(111) surface (irrespective of its openor closed-shell state, Supplementary Fig  ), 5 exhibits charge bistability between 5 0 and the anionic state 5 -1 on the lower work function bilayer NaCl/Ag(111) and Cu(111) surfaces (Supplementary Figs  ) 
In the main text, we focus on the characterization of 5 on bilayer NaCl/Au(111)  Characterization of charge bistable 5 is reported in Supplementary Figs    We first describe experiments on 5 on bilayer NaCl/Au(111), where 5 exhibits a geometry corresponding to the calculated 5OS geometry, and an open-shell electronic configuration 
We compare the experimental data on this species to calculations on 5OS with a triplet configuration, as theory predicts a triplet ground state for 5OS  For 5OS, the calculated frontier orbitals correspond to the SOMOs ψ1 and ψ2 (Fig  ), whose spin up levels are occupied and the spin down levels are empty 
Figure shows the DFT-calculated bond lengths of 5OS, where the two salient features, namely, the small difference in the bond lengths within each ring and the notably longer bond lengths in the pentagonal rings, agree with the open-shell resonance structure of 5 (Fig  )  Figure shows an AFM image of 5 adsorbed on bilayer NaCl/Au(111) that we assign as 5OS, where the bond-order differences qualitatively correspond to the calculated 5OS geometry (discussed and compared to the closed-shell state below) 
Differential conductance spectra (dI/dV(V), where I and V denote the tunneling current and bias voltage, respectively) acquired on assigned 5OS exhibit two peaks centered at -1 5 V and 1 6 V (Fig  ), which we assign to the positive and negative ion resonances (PIR and NIR), respectively  Figure shows the corresponding STM images acquired at the onset (V = -1 2
V/1 3 V) and the peak (V = -1 5 V/1 6 V) of the ionic resonances



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prompt_front: Now, answer the following question based on the text below, only give me the answer and do not output any other words.

Question: What are the two ground states observed for indeno[1,2-a]fluorene on NaCl surfaces?

Read the following text and answer briefly.

Context 3:  To draw a correspondence between the STM images and the molecular orbital densities, we consider tunneling events as many-body electronic transitions between different charge states of 5OS (Fig  )  Within this framework, the PIR corresponds to transitions between 5 0 and the cationic state 5  
At the onset of the PIR at -1 2 V, an electron can only be detached from the SOMO ψ1 and the corresponding STM image at -1 2 V shows the orbital density of ψ1  Increasing the bias to the peak of the PIR at -1 5 V, it becomes possible to also empty the SOMO ψ2, such that the corresponding STM image shows the superposition of ψ1 and ψ2, that is, |ψ1| 2 + |ψ2| 2 (ref 
)  Similarly, the NIR corresponds to transitions between 5 0 and 5 -1   At the NIR onset of 1 3 V, only electron attachment to ψ2 is energetically possible  At 1 6 V, electron attachment to ψ1 also becomes possible, and the corresponding STM image shows the superposition of ψ1 and ψ2  The observation of the orbital densities of SOMOs, and not the hybridized HOMO and LUMO, proves the open-shell ground state of assigned 5OS 
Measurements of the monoradical species with a doublet ground state are shown in Supplementary Fig    Unexpectedly, another species of 5 was also experimentally observed that exhibited a closedshell ground state  In contrast to 5OS, where the frontier orbitals correspond to the SOMOs ψ1 and ψ2, DFT calculations predict orbitals of different shapes and symmetries for 5para and 5ortho, denoted as α and β and shown in Fig   
For 5ortho, α and β correspond to HOMO and LUMO, respectively  The orbitals are inverted in energy and occupation for 5para, where β is the HOMO and α is the LUMO  Fig  shows an AFM image of 5 that we assign as 5para  We experimentally infer its closed-shell state first by using qualitative bond order discrimination by AFM 
In high-resolution AFM imaging, chemical bonds with higher bond order are imaged brighter (that is, with higher frequency shift Δf) due to stronger repulsive forces, and they appear shorter   In Fig  , we label seven bonds whose bond orders show significant qualitative differences in the calculated 5ortho, 5para (Fig  ) and 5OS (Fig  ) geometries 
In 5para, the bonds b and d exhibit a higher bond order than a and c, respectively  This pattern is reversed for 5ortho, while the bond orders of the bonds a-d are all similar and small for 5OS  Furthermore, in 5para bond f exhibits a higher bond order than e, while in 5ortho and 5OS bonds e and f exhibit similar bond order (because they belong to Clar sextets) 
Finally, the bond labeled g shows a higher bond order in 5para than in 5ortho and 5OS  The AFM image of assigned 5para shown in Fig  indicates higher bond orders of the bonds b, d and f compared to a, c and e, respectively  In addition, the bond g appears almost point-like and with enhanced Δf contrast compared to its neighboring bonds, indicative of a high bond order (see Supplementary Fig  for height-dependent measurements) 
These observations concur with the calculated 5para geometry (Fig  )  Importantly, all these distinguishing bond-order differences are distinctly different in the AFM image of 5OS shown in Fig  , which is consistent with the calculated 5OS geometry (Fig  )  In the AFM images of 5OS (Fig  and Supplementary Fig  ), the bonds a-d at the pentagon apices appear with similar contrast and apparent bond length 
The bonds e and f at one of the terminal benzenoid rings also exhibit similar contrast and apparent bond length, while the central bond g appears longer compared to assigned 5para  Further compelling evidence for the closed-shell state of assigned 5para is obtained by STM and STS  dI/dV(V) spectra acquired on an assigned 5para species exhibit two peaks centered at -1 4 V (PIR) and 1 6 V (NIR) (Fig  ) 
STM images acquired at these biases (Fig  ) show the orbital densities of β (-1 4 V) and α (1 6 V)  First, the observation of α and β as the frontier orbitals of this species, and not the SOMOs, strongly indicates its closed-shell state  Second, consistent with AFM measurements that indicate good correspondence to the calculated 5para geometry, we observe β as the HOMO and α as the LUMO 
For 5ortho, α should be observed as the HOMO and β as the LUMO  We did not observe molecules with the signatures of 5ortho in our experiments  We observed molecules in open-(5OS, Fig  ) and closed-shell (5para, Fig  ) states in similar occurrence after their generation from 6 on the surface  We could also switch individual molecules between open-and closed-shell states as shown in Fig  and Supplementary Fig   
To this end, a change in the adsorption site of a molecule was induced by STM imaging at ionic resonances, which often resulted in movement of the molecule  The example presented in Fig  shows a molecule that was switched from 5para to 5OS and back to 5para  The switching is not directed, that is, we cannot choose which of the two species will be formed when changing the adsorption site, and we observed 5OS and 5para in approximately equal yields upon changing the adsorption site 
The molecule in Fig  is adsorbed on top of a defect that stabilizes its adsorption geometry on bilayer NaCl  At defect-free adsorption sites on bilayer NaCl, that is, without a third layer NaCl island or atomic defects in the vicinity of the molecule, 5 could be stably imaged neither by AFM nor by STM at ionic resonances (Supplementary Fig  ) 
Without changing the adsorption site, the state of 5 (open-or closedshell) never changed, including the experiments on bilayer NaCl/Ag(111) and Cu(111), on which the charge state of 5 could be switched (Supplementary Figs  )  Also on these lower work function surfaces, both open-and closed-shell species were observed for 5 0 and both showed charge bistability between 5 0 (5OS or 5para) and 5 -1 (Supplementary Figs  ) 
The geometrical structure of 5 -1 probed by AFM, and its electronic structure probed by STM imaging at the NIR (corresponding to transitions between 5 -1 and the dianionic state 5 -2 ), are identical within the measurement accuracy for the charged species of both 5OS and 5para  When cycling the charge state of 5 between 5 0 and 5 -1 several times, we always observed the same state (5OS or 5para) when returning to 5 0 , provided the molecule did not move during the charging/discharging process 
Based on our experimental observations we conclude that indeno[1,2-a]fluorene (5), the last unknown indenofluorene isomer, can be stabilized in and switched between an open-shell (5OS) and a closed-shell (5para) state on NaCl  For the former, both DFT and QD-NEVPT2 calculations predict a triplet electronic configuration 
Therefore, 5 can be considered to exhibit the spin-crossover effect, involving magnetic switching between high-spin (5OS) and low-spin (5para) states, coupled with a reversible structural transformation  So far, the spin-crossover effect has mainly only been observed in transition-metal-based coordination compounds with a near-octahedral geometry  
The observation that the switching between open-and closedshell states is related to changes in the adsorption site but is not achieved by charge-state cycling alone, indicates that the NaCl surface and local defects facilitate different electronic configurations of 5 depending on the adsorption site 
Gas-phase QD-NEVPT2 calculations predict that 5OS is the ground state, and the closed-shell 5para and 5ortho states are 0 11 and 0 21 eV higher in energy  The experiments, showing bidirectional switching between 5OS and 5para, indicate that a change in the adsorption site can induce sufficient change in the geometry of 5 (leading to a corresponding change in the ground state electronic configuration) and thus induce switching 
Switching between open-and closed-shell states in 5 does not require the breaking or formation of covalent bonds , but a change of adsorption site on NaCl where the molecule is physisorbed  Our results should have implications for single-molecule devices, capitalizing on the altered electronic and chemical properties of a system in π-diradical open-shell and closed-shell states such as frontier orbital and singlet-triplet gaps, and chemical reactivity 
For possible future applications as a single-molecule switch, it might be possible to also switch between open-and closed-shell states by changing the local electric field, such as by using chargeable adsorbates   Scanning probe microscopy measurements and sample preparation  STM and AFM measurements were performed in a home-built system operating at base pressures below 1×10 -10 mbar and a base temperature of 5 K  Bias voltages are provided with respect to the sample 
All STM, AFM and spectroscopy measurements were performed with carbon monoxide (CO) functionalized tips  AFM measurements were performed in non-contact mode with a qPlus sensor   The sensor was operated in frequency modulation mode with a constant oscillation amplitude of 0 5 Å  STM measurements were performed in constantcurrent mode, AFM measurements were performed in constant-height mode with V = 0 V, and I(V) and Δf(V) spectra were acquired in constant-height mode 
Positive (negative) values of the tip-height offset Δz represent tip approach (retraction) from the STM setpoint  All dI/dV(V) spectra are obtained by numerical differentiation of the corresponding I(V) spectra  STM and AFM images, and spectroscopy curves, were post-processed using Gaussian low-pass filters 
Au(111), Ag(111) and Cu(111) surfaces were cleaned by iterative cycles of sputtering with Ne + ions and annealing up to 800 K  NaCl was thermally evaporated on Au(111), Ag(111) and Cu(111) surfaces held at 323 K, 303 K and 283 K, respectively  This protocol results in the growth of predominantly bilayer (100)-terminated islands, with a minority of trilayer islands 
Sub-monolayer coverage of 6 on surfaces was obtained by flashing an oxidized silicon wafer containing the precursor molecules in front of the cold sample in the microscope  CO molecules for tip functionalization were dosed from the gas phase on the cold sample  Density functional theory calculations  DFT was employed using the PSI4 program package  
All molecules with different charge (neutral and anionic) and electronic (open-and closed-shell) states were independently investigated in the gas phase  The B3LYP exchangecorrelation functional with 6-31G basis set was employed for structural relaxation and singlepoint energy calculations  The convergence criteria were set to 10 −4 eV Å −1 for the total forces and 10 −6 eV for the total energies 
Multireference calculations  Multireference calculations were performed on the DFToptimized geometries using the QD-NEVPT2 level of theory , with three singlet roots and one triplet root included in the state-averaged calculation  A (10,10) active space (that is, 10 electrons in 10 orbitals) was used along with the def2-TZVP basis set  
Increasing either the active space size or expanding the basis set resulted in changes of about 50 meV for relative energies of the singlet and triplet states  These calculations were performed using the ORCA program package   Nucleus-independent chemical shift (NICS) calculations  Isotropic nucleus-independent chemical shift values were evaluated at the centre of each ring using the B3LYP exchangecorrelation functional with def2-TZVP basis set using the Gaussian 16 software package  
Starting materials (reagent grade) were purchased from TCI and Sigma-Aldrich and used without further purification  Reactions were carried out in flame-dried glassware and under an inert atmosphere of purified Ar using Schlenk techniques  Thin-layer chromatography (TLC) was performed on Silica Gel 60 F-254 plates (Merck) 
Column chromatography was performed on silica gel (40-60 µm)  Nuclear magnetic resonance (NMR) spectra were recorded on a Bruker Varian Mercury 300 or Bruker Varian Inova 500 spectrometers  Mass spectrometry (MS) data were recorded in a Bruker Micro-TOF spectrometer  The synthesis of compound 6 was developed following the two-step synthetic route shown in Supplementary Fig  , which is based on the preparation of methylene-bridge polyarenes by means of Pd-catalyzed activation of benzylic C-H bonds  
Supplementary Figure | Synthetic route to obtain compound 6  The complex Pd2(dba)3 (20 mg, 0 02 mmol) was added over a deoxygenated mixture of 1,3-dibromo-2,4-dimethylbenzene (9, 100 mg, 0 38 mmol), boronic acid 10 (178 mg, 1 14 mmol), K2CO3 (314 mg, 2 28 mmol) and XPhos (35 mg, 0 08 mmol) in toluene (1:1, 10 mL), and the resulting mixture was heated at 90 °C for 2 h 
After cooling to room temperature, the solvents were evaporated under reduced pressure  The reaction crude was purified by column chromatography (SiO2; hexane:CH2Cl2 9:1) affording 11 (94 mg, 76%) as a colorless oil  The complex Pd(OAc)2 (7 mg, 0 03 mmol) was added over a deoxygenated mixture of terphenyl 11 (90 mg, 0 27 mmol), K2CO3 (114 mg, 0 83 mmol) and ligand L (26 mg, 0 06 mmol) in NMP (2 mL) 
The resulting mixture was heated at 160 °C for 4 h  After cooling to room temperature, H2O (30 mL) was added, and the mixture was extracted with EtOAc (3x15 mL)  The combined organic extracts were dried over anhydrous Na2SO4, filtered, and evaporated under reduced pressure  The reaction crude was purified by column chromatography (SiO2; hexane:CH2Cl2 9:1) affording compound 6 (8 mg, 11%) as a white solid  in AFM imaging due to their reduced adsorption height compared to the rest of the carbon atoms 
We attribute this observation to the significantly different lattice parameter of Cu(111) (2 57 Å) compared to Au(111) and Ag(111) (2 95 Å and 2 94 Å, respectively) , such that the apical carbon atoms of the pentagonal rings of 5 adsorb on the on-top atomic sites on Au(111) and Ag(111), but not on Cu(111) 
Our speculation is based on a previous study of polymers of 1 on Au(111) by Di Giovannantonio et al  , where both tilted and planar individual units of 1 were observed depending on whether the apical carbon atoms of the pentagonal rings in 1 adsorbed on the on-top or hollow sites of the surface, respectively 
Given the strong molecule-metal interaction, we found no electronic state signatures of 5 on all three metal surfaces  STM set point for AFM images: V = 0  e, Frontier orbital spectrum of 5 -1   In the anionic state, ψ2 becomes doubly occupied and ψ1 is the SOMO  Filled and empty circles denote occupied and empty orbitals, respectively 
For each panel, zero of the energy axis has been aligned to the respective highest-energy occupied orbital 



ground_truth: Open-shell π-diradical state and closed-shell state with a para-quinodimethane moiety.