query: What is carbon dioxide?

title: Carbon dioxide

text: than otherwise would. Life jackets often contain canisters of pressured carbon dioxide for quick inflation. Aluminium capsules of are also sold as supplies of compressed gas for air guns, paintball markers/guns, inflating bicycle tires, and for making carbonated water. Rapid vaporization of liquid carbon dioxide is used for blasting in coal mines. High concentrations of carbon dioxide can also be used to kill pests. Liquid carbon dioxide is used in supercritical drying of some food products and technological materials, in the preparation of specimens for scanning electron microscopy and in the decaffeination of coffee beans. Carbon dioxide can be used

title: Carbon dioxide

text: US and Australia and New Zealand (listed by its INS number 290). A candy called Pop Rocks is pressurized with carbon dioxide gas at about 4 x 10 Pa (40 bar, 580 psi). When placed in the mouth, it dissolves (just like other hard candy) and releases the gas bubbles with an audible pop. Leavening agents cause dough to rise by producing carbon dioxide. Baker's yeast produces carbon dioxide by fermentation of sugars within the dough, while chemical leaveners such as baking powder and baking soda release carbon dioxide when heated or if exposed to acids. Carbon dioxide is used

title: Carbon dioxide

text: family, like silicon (silica glass) and germanium dioxide. Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released. At temperatures and pressures above the critical point, carbon dioxide behaves as a supercritical fluid known as supercritical carbon dioxide. In this state it is starting (as of 2018) to be used for power generation. Carbon dioxide can be obtained by distillation from air, but the method is inefficient. Industrially, carbon dioxide is predominantly an unrecovered waste product, produced by several methods which may be practiced at various scales. The

title: Carbon dioxide

text: standard hydrogen electrode. The nickel-containing enzyme carbon monoxide dehydrogenase catalyses this process. Carbon dioxide is colorless. At low concentrations the gas is odorless; however, at sufficiently-high concentrations, it has a sharp, acidic odor. At standard temperature and pressure, the density of carbon dioxide is around 1.98 kg/m, about 1.67 times that of air. Carbon dioxide has no liquid state at pressures below . At 1 atmosphere (near mean sea level pressure), the gas deposits directly to a solid at temperatures below and the solid sublimes directly to a gas above −78.5 °C. In its solid state, carbon dioxide is commonly

title: Carbon dioxide

text: Carbon dioxide Carbon dioxide (chemical formula ) is a colorless gas with a density about 60% higher than that of dry air. Carbon dioxide consists of a carbon atom covalently double bonded to two oxygen atoms. It occurs naturally in Earth's atmosphere as a trace gas. The current concentration is about 0.04% (410 ppm) by volume, having risen from pre-industrial levels of 280 ppm. Natural sources include volcanoes, hot springs and geysers, and it is freed from carbonate rocks by dissolution in water and acids. Because carbon dioxide is soluble in water, it occurs naturally in groundwater, rivers and lakes,

title: Carbon dioxide

text: closed, prefilled chamber containing , or exposure to a gradually increasing concentration of . In 2013, the American Veterinary Medical Association issued new guidelines for carbon dioxide induction, stating that a displacement rate of 10% to 30% of the gas chamber volume per minute is optimal for the humane euthanization of small rodents. However, there is opposition to the practice of using carbon dioxide for this, on the grounds that it is cruel. Carbon dioxide is also used in several related cleaning and surface preparation techniques. Carbon dioxide in Earth's atmosphere is a trace gas, currently (mid 2018) having a

title: Carbon dioxide

text: ice caps, glaciers and seawater. It is present in deposits of petroleum and natural gas. Carbon dioxide is odorless at normally encountered concentrations. However, at high concentrations, it has a sharp and acidic odor. As the source of available carbon in the carbon cycle, atmospheric carbon dioxide is the primary carbon source for life on Earth and its concentration in Earth's pre-industrial atmosphere since late in the Precambrian has been regulated by photosynthetic organisms and geological phenomena. Plants, algae and cyanobacteria use light energy to photosynthesize carbohydrate from carbon dioxide and water, with oxygen produced as a waste product. It

title: Carbon dioxide equivalent

text: of carbon dioxide. Equivalent (e) is the concentration of that would cause the same level of radiative forcing as a given type and concentration of greenhouse gas. Examples of such greenhouse gases are methane, perfluorocarbons, and nitrous oxide. e is expressed as parts per million by volume, ppmv. Carbon dioxide equivalent Carbon dioxide equivalent (CDE) and equivalent carbon dioxide (e and eq) are two related but distinct measures for describing how much global warming a given type and amount of greenhouse gas may cause, using the functionally equivalent amount or concentration of carbon dioxide () as the reference. Carbon dioxide

title: Carbon dioxide

text: Sustainable automotive air conditioning) In enhanced coal bed methane recovery, carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane. Carbon dioxide is the lasing medium in a carbon dioxide laser, which is one of the earliest type of lasers. Carbon dioxide can be used as a means of controlling the pH of swimming pools, by continuously adding gas to the water, thus keeping the pH from rising. Among the advantages of this

title: Carbon dioxide equivalent

text: Carbon dioxide equivalent Carbon dioxide equivalent (CDE) and equivalent carbon dioxide (e and eq) are two related but distinct measures for describing how much global warming a given type and amount of greenhouse gas may cause, using the functionally equivalent amount or concentration of carbon dioxide () as the reference. Carbon dioxide equivalency is a quantity that describes, for a given mixture and amount of greenhouse gas, the amount of that would have the same global warming potential (GWP), when measured over a specified timescale (generally, 100 years). Carbon dioxide equivalency thus reflects the time-integrated radiative forcing of a quantity

title: Carbon dioxide

text: combustion of all carbon-based fuels, such as methane (natural gas), petroleum distillates (gasoline, diesel, kerosene, propane), coal, wood and generic organic matter produces carbon dioxide and, except in the case of pure carbon, water. As an example, the chemical reaction between methane and oxygen: It is produced by thermal decomposition of limestone, by heating (calcining) at about , in the manufacture of quicklime (calcium oxide, ), a compound that has many industrial uses: Iron is reduced from its oxides with coke in a blast furnace, producing pig iron and carbon dioxide: Carbon dioxide is a byproduct of the industrial production

title: Carbon dioxide

text: the content of arterial blood may be lowered to 10–20 mm Hg (the oxygen content of the blood is little affected), and the respiratory drive is diminished. This is why one can hold one's breath longer after hyperventilating than without hyperventilating. This carries the risk that unconsciousness may result before the need to breathe becomes overwhelming, which is why hyperventilation is particularly dangerous before free diving. Carbon dioxide Carbon dioxide (chemical formula ) is a colorless gas with a density about 60% higher than that of dry air. Carbon dioxide consists of a carbon atom covalently double bonded to two

title: Carbon dioxide clathrate

text: Carbon dioxide clathrate Carbon dioxide hydrate is a snow-like crystalline substance composed of water ice and carbon dioxide. It normally is a Type I gas clathrate. However, there has been some experimental evidence for the development of a metastable Type II phase at A temperature near the ice melting point. The clathrate can exist below 283K (10 °C) at a range of pressures of carbon dioxide. It is quite likely to be important on Mars due to the presence of carbon dioxide and ice at low temperatures. The first evidence for the existence of CO hydrates dates back to the

title: Supercritical carbon dioxide

text: 2000 Free preview at Google Books Supercritical carbon dioxide Supercritical carbon dioxide (s) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure. Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as a solid called dry ice when frozen. If the temperature and pressure are both increased from STP to be at or above the critical point for carbon dioxide, it can adopt properties midway between a gas and a liquid. More specifically, it behaves as a supercritical fluid above its critical

title: Supercritical carbon dioxide

text: Supercritical carbon dioxide Supercritical carbon dioxide (s) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure. Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as a solid called dry ice when frozen. If the temperature and pressure are both increased from STP to be at or above the critical point for carbon dioxide, it can adopt properties midway between a gas and a liquid. More specifically, it behaves as a supercritical fluid above its critical temperature () and critical pressure (),

title: Carbon dioxide scrubber

text: estimated to be $72. The project ended in 2010,estimating that the total capital required to implement such a project in a 580 MW power plant was 354 million dollars. Many other methods and materials have been discussed for scrubbing carbon dioxide. Carbon dioxide scrubber A carbon dioxide scrubber is a piece of equipment that absorbs carbon dioxide (CO). It is used to treat exhaust gases from industrial plants or from exhaled air in life support systems such as rebreathers or in spacecraft, submersible craft or airtight chambers. Carbon dioxide scrubbers are also used in controlled atmosphere (CA) storage. They have

title: Carbon dioxide reforming

text: the commercialization of this process is that the hydrogen that is produced tends to react with the carbon dioxide. For example, the following reaction typically proceeds with a lower activation energy than the dry reforming reaction itself: Typical catalysts are noble metals, Ni or Ni alloys. In addition, a group of researchers in China investigated the use of activated carbon as an alternative catalyst. Carbon dioxide reforming Carbon dioxide reformation (also known as dry reformation) is a method of producing synthesis gas (mixtures of hydrogen and carbon monoxide) from the reaction of carbon dioxide with hydrocarbons such as methane. Synthesis

title: Carbon dioxide reforming

text: Carbon dioxide reforming Carbon dioxide reformation (also known as dry reformation) is a method of producing synthesis gas (mixtures of hydrogen and carbon monoxide) from the reaction of carbon dioxide with hydrocarbons such as methane. Synthesis gas is conventionally produced via the steam reforming reaction. In recent years, increased concerns on the contribution of greenhouse gases to global warming have increased interest in the replacement of steam as reactant with carbon dioxide. The dry reforming reaction may be represented by: Thus, two greenhouse gases are consumed and useful chemical building blocks, hydrogen and carbon monoxide, are produced. A challenge to

title: Carbon dioxide scrubber

text: Carbon dioxide scrubber A carbon dioxide scrubber is a piece of equipment that absorbs carbon dioxide (CO). It is used to treat exhaust gases from industrial plants or from exhaled air in life support systems such as rebreathers or in spacecraft, submersible craft or airtight chambers. Carbon dioxide scrubbers are also used in controlled atmosphere (CA) storage. They have also been researched for carbon capture. The primary application for CO scrubbing is for removal of from the exhaust of coal- and gas-fired power plants. Virtually the only technology being seriously evaluated involves the use of various amines, e.g. monoethanolamine. Cold

title: Carbon dioxide

text: and microbial fermentation. In 1772, English chemist Joseph Priestley published a paper entitled "Impregnating Water with Fixed Air" in which he described a process of dripping sulfuric acid (or "oil of vitriol" as Priestley knew it) on chalk in order to produce carbon dioxide, and forcing the gas to dissolve by agitating a bowl of water in contact with the gas. Carbon dioxide was first liquefied (at elevated pressures) in 1823 by Humphry Davy and Michael Faraday. The earliest description of solid carbon dioxide was given by Adrien-Jean-Pierre Thilorier, who in 1835 opened a pressurized container of liquid carbon dioxide,

title: Carbon dioxide

text: whiteflies and spider mites in a greenhouse. It has been proposed that from power generation be bubbled into ponds to stimulate growth of algae that could then be converted into biodiesel fuel. In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the balance in blood. Carbon dioxide can be mixed with up to 50% oxygen, forming an inhalable gas; this is known as Carbogen and has a variety of medical and research uses. Carbon dioxide is used in enhanced oil recovery where it is injected

title: Carbon dioxide flooding

text: the water acts to sweep the oil towards the production zone. CO flooding is the second most common tertiary recovery technique and is used in facilities around the world. In connection with greenhouse gas emissions and global warming, CO flooding sequesters underground and therefore offsets CO emissions elsewhere. Carbon dioxide flooding Carbon dioxide (CO) flooding is a process whereby carbon dioxide is injected into an oil reservoir in order to increase output when extracting oil. When a reservoir’s pressure is depleted through primary and secondary production, carbon dioxide flooding can be an ideal tertiary recovery method. It is particularly effective

title: Carbon dioxide

text: of hydrogen by steam reforming and the water gas shift reaction in ammonia production. These processes begin with the reaction of water and natural gas (mainly methane). This is a major source of food-grade carbon dioxide for use in carbonation of beer and soft drinks, and is also used for stunning animals such as poultry. In the summer of 2018 a shortage of carbon dioxide for these purposes arose in Europe due to the temporary shut-down of several ammonia plants for maintenance. Acids liberate from most metal carbonates. Consequently, it may be obtained directly from natural carbon dioxide springs, where

title: Carbon dioxide sensor

text: Carbon dioxide sensor A carbon dioxide sensor or CO sensor is an instrument for the measurement of carbon dioxide gas. The most common principles for CO sensors are infrared gas sensors (NDIR) and chemical gas sensors. Measuring carbon dioxide is important in monitoring indoor air quality, the function of the lungs in the form of a capnograph device, and many industrial processes. NDIR sensors are spectroscopic sensors to detect CO in a gaseous environment by its characteristic absorption. The key components are an infrared source, a light tube, an interference (wavelength) filter, and an infrared detector. The gas is pumped

title: Carbon dioxide sensor

text: measurement principle. Most CO₂ sensors are fully calibrated prior to shipping from the factory. Over time, the zero point of the sensor needs to be calibrated to maintain the long term stability of the sensor. Carbon dioxide sensor A carbon dioxide sensor or CO sensor is an instrument for the measurement of carbon dioxide gas. The most common principles for CO sensors are infrared gas sensors (NDIR) and chemical gas sensors. Measuring carbon dioxide is important in monitoring indoor air quality, the function of the lungs in the form of a capnograph device, and many industrial processes. NDIR sensors are

title: Ocean storage of carbon dioxide

text: IEA Greenhouse Gas R&D Programme estimates that dilute carbon dioxide injection would cost $70 per tonne of carbon dioxide including costs of carbon capture, transport, and storage before boat dispersal. Carbon dioxide ocean storage can occur through solid or solid hydrate of carbon dioxide. The solid state density of carbon dioxide is approximately 1.5 times greater than seawater and thus tends to sink to the ocean floor. The dissolving rate at the surface is about 0.2 cm/hr such that a small quantity of carbon dioxide can be completely dissolved before reaching the sea floor. In addition to solid carbon dioxide

title: Carbon dioxide

text: to extinguish flames by flooding the environment around the flame with the gas. It does not itself react to extinguish the flame, but starves the flame of oxygen by displacing it. Some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure. Carbon dioxide extinguishers work well on small flammable liquid and electrical fires, but not on ordinary combustible fires, because although it excludes oxygen, it does not cool the burning substances significantly and when the carbon dioxide disperses they are free to catch fire upon exposure to atmospheric oxygen. Their desirability in electrical fire stems

title: Carbon dioxide clathrate

text: Celsius (bottom and top respectively). On the vertical ones are given the pressure (left) and the estimated depth in the Martian regolith (right). The horizontal dashed line at zero depth represents the average Martian surface conditions. The two bent dashed lines show two theoretical Martian geotherms after Stewart & Nimmo (2002) at 30° and 70° latitude. Carbon dioxide clathrate Carbon dioxide hydrate is a snow-like crystalline substance composed of water ice and carbon dioxide. It normally is a Type I gas clathrate. However, there has been some experimental evidence for the development of a metastable Type II phase at A

title: Carbon dioxide clathrate

text: becomes clear that all the above-mentioned speculations rest on extremely unstable bases. On Enceladus decomposition of carbon dioxide clathrate is a possible way to explain the formation of gas plumes. In Europa (moon), clathrate should be important for storing carbon dioxide. In the conditions of the subsurface ocean in Europa, carbon dioxide clathrate should sink, and therefore not be apparent at the surface. The hydrate structures are stable at different pressure-temperature conditions depending on the guest molecule. Here is given one Mars-related phase diagram of CO hydrate, combined with those of pure CO and water (Genov 2005). CO hydrate has

title: Carbon dioxide laser

text: Carbon dioxide laser The carbon dioxide laser (CO laser) was one of the earliest gas lasers to be developed. It was invented by Kumar Patel of Bell Labs in 1964, and is still one of the most useful. Carbon dioxide lasers are the highest-power continuous wave lasers that are currently available. They are also quite efficient: the ratio of output power to pump power can be as large as 20%. The CO laser produces a beam of infrared light with the principal wavelength bands centering on 9.4 and 10.6 micrometers (μm). The active laser medium (laser gain/amplification medium) is a

title: Carbon dioxide scrubber

text: lime kiln fired with oxygen in order to avoid an additional gas separation step. Hydration of the lime (CaO) completes the cycle. Lime hydration is an exothermic reaction that can be performed with water or steam. Using water, it is a liquid/solid reaction as shown here: Other strong bases such as soda lime, sodium hydroxide, potassium hydroxide, and lithium hydroxide are able to remove carbon dioxide by chemically reacting with it. In particular, lithium hydroxide was used aboard spacecraft, such as in the Apollo program, to remove carbon dioxide from the atmosphere. It reacts with carbon dioxide to form lithium

title: Gorgon Carbon Dioxide Injection Project

text: making the final investment decision. An ongoing monitoring program, including observation wells and seismic surveys, will assist in managing the performance of the injected carbon dioxide in the Dupuy Formation. Gorgon Carbon Dioxide Injection Project The Gorgon Carbon Dioxide Injection Project is part of the Gorgon Project,Todd Lewis Nordby Chevrons U.S.A Corporate CEO 2018 the world's largest natural gas project. The Gorgon Project, located on Barrow Island in Western Australia, includes a liquefied natural gas (LNG) plant, a domestic gas plant, and a Carbon Dioxide Injection Project. The initial carbon dioxide injections are planned to take place by the end

title: Gorgon Carbon Dioxide Injection Project

text: Gorgon Carbon Dioxide Injection Project The Gorgon Carbon Dioxide Injection Project is part of the Gorgon Project,Todd Lewis Nordby Chevrons U.S.A Corporate CEO 2018 the world's largest natural gas project. The Gorgon Project, located on Barrow Island in Western Australia, includes a liquefied natural gas (LNG) plant, a domestic gas plant, and a Carbon Dioxide Injection Project. The initial carbon dioxide injections are planned to take place by the end of 2017. Once launched, the Gorgon Carbon Dioxide Injection Project will be the world's largest CO injection plant, with an ability to store up to 4 million tons of CO

title: Carbon dioxide in Earth's atmosphere

text: actual surface temperature of approximately 14 °C (57.2 °F). Carbon dioxide is believed to have played an important effect in regulating Earth's temperature throughout its 4.7 billion year history. Early in the Earth's life, scientists have found evidence of liquid water indicating a warm world even though the Sun's output is believed to have only been 70% of what it is today. It has been suggested by scientists that higher carbon dioxide concentrations in the early Earth's atmosphere might help explain this faint young sun paradox. When Earth first formed, Earth's atmosphere may have contained more greenhouse gases and concentrations

title: Carbon dioxide

text: from the burning of fossil fuels remains in the atmosphere and is not absorbed by vegetation and the oceans. While transparent to visible light, carbon dioxide is a greenhouse gas, absorbing and emitting infrared radiation at its two infrared-active vibrational frequencies (see the section "Structure and bonding" above). Light emission from the earth's surface is most intense in the infrared region between 200 and 2500 cm, as opposed to light emission from the much hotter sun which is most intense in the visible region. Absorption of infrared light at the vibrational frequencies of atmospheric carbon dioxide traps energy near the

title: Carbon dioxide in Earth's atmosphere

text: atmosphere, oceans, soil, rocks, and volcanism. Both carbon cycles are intrinsically interconnected and atmospheric gaseous carbon dioxide facilitates the carbon cycle. Natural sources of atmospheric carbon dioxide include volcanic outgassing, the combustion of organic matter, wildfires and the respiration processes of living aerobic organisms. Man-made sources of carbon dioxide include the burning of fossil fuels for heating, power generation and transport, as well as some industrial processes such as cement making. It is also produced by various microorganisms from fermentation and cellular respiration. Plants, algae and cyanobacteria convert carbon dioxide to carbohydrates by a process called photosynthesis. They gain the

title: Carbon dioxide

text: from the fact that, unlike water or other chemical based methods, Carbon dioxide will not cause short circuits, leading to even more damage to equipment. Because it is a gas, it is also easy to dispense large amounts of the gas automatically in IT infrastructure rooms, where the fire itself might be hard to reach with more immediate methods because it is behind rack doors and inside of cases. Carbon dioxide has also been widely used as an extinguishing agent in fixed fire protection systems for local application of specific hazards and total flooding of a protected space. International Maritime

title: Carbon dioxide

text: to prevent oxidation, though it has the problem that it can dissolve into the wine, making a previously still wine slightly fizzy. For this reason, other gases such as nitrogen or argon are preferred for this process by professional wine makers. Carbon dioxide is often used to "stun" animals before slaughter. "Stunning" may be a misnomer, as the animals are not knocked out immediately and may suffer distress. It is one of the most commonly used compressed gases for pneumatic (pressurized gas) systems in portable pressure tools. Carbon dioxide is also used as an atmosphere for welding, although in the

title: Carbon dioxide

text: surface, warming the surface and the lower atmosphere. Less energy reaches the upper atmosphere, which is therefore cooler because of this absorption. Increases in atmospheric concentrations of and other long-lived greenhouse gases such as methane, nitrous oxide and ozone have correspondingly strengthened their absorption and emission of infrared radiation, causing the rise in average global temperature since the mid-20th century. Carbon dioxide is of greatest concern because it exerts a larger overall warming influence than all of these other gases combined and because it has a long atmospheric lifetime (hundreds to thousands of years). Not only do increasing carbon dioxide

title: Carbon dioxide in Earth's atmosphere

text: Carbon dioxide in Earth's atmosphere Carbon dioxide () is an important trace gas in Earth's atmosphere. It is an integral part of the carbon cycle, a biogeochemical cycle in which carbon is exchanged between the Earth's oceans, soil, rocks and the biosphere. Plants and other photoautotrophs use solar energy to produce carbohydrate from atmospheric carbon dioxide and water by photosynthesis. Almost all other organisms depend on carbohydrate derived from photosynthesis as their primary source of energy and carbon compounds. absorbs and emits infrared radiation at wavelengths of 4.26 µm (asymmetric stretching vibrational mode) and 14.99 µm (bending vibrational mode) and

title: Carbon dioxide

text: ethanol, also known as alcohol, as follows: All aerobic organisms produce when they oxidize carbohydrates, fatty acids, and proteins. The large number of reactions involved are exceedingly complex and not described easily. Refer to (cellular respiration, anaerobic respiration and photosynthesis). The equation for the respiration of glucose and other monosaccharides is: Anaerobic organisms decompose organic material producing methane and carbon dioxide together with traces of other compounds. Regardless of the type of organic material, the production of gases follows well defined kinetic pattern. Carbon dioxide comprises about 40–45% of the gas that emanates from decomposition in landfills (termed "landfill gas").

title: Carbon dioxide

text: invisible substance he termed a "gas" or "wild spirit" ("spiritus sylvestris"). The properties of carbon dioxide were further studied in the 1750s by the Scottish physician Joseph Black. He found that limestone (calcium carbonate) could be heated or treated with acids to yield a gas he called "fixed air." He observed that the fixed air was denser than air and supported neither flame nor animal life. Black also found that when bubbled through limewater (a saturated aqueous solution of calcium hydroxide), it would precipitate calcium carbonate. He used this phenomenon to illustrate that carbon dioxide is produced by animal respiration

title: Carbon dioxide cleaning

text: In addition, care must be taken to prevent the concentration of carbon dioxide in the work area from exceeding safe levels. Some commercial grades of carbon dioxide may contain traces of heavy hydrocarbons, which can be left behind on the surface being cleaned. Abrasive particles originating in the cleaning equipment itself may need to be filtered out as well. The low temperature of the carbon dioxide stream can also induce moisture condensation on the part, which may be mitigated with hot plates, heat guns, heat lamps, or dry boxes. Ionization caused by the flowing gas can result in potentially damaging

title: Carbon dioxide in Earth's atmosphere

text: satellite to successfully achieve orbit in 2009. NASA's OCO-2 launched in 2014 was the second. Various other satellites missions to measure atmospheric X are planned. Carbon dioxide in Earth's atmosphere Carbon dioxide () is an important trace gas in Earth's atmosphere. It is an integral part of the carbon cycle, a biogeochemical cycle in which carbon is exchanged between the Earth's oceans, soil, rocks and the biosphere. Plants and other photoautotrophs use solar energy to produce carbohydrate from atmospheric carbon dioxide and water by photosynthesis. Almost all other organisms depend on carbohydrate derived from photosynthesis as their primary source of

title: Carbon dioxide

text: global average concentration of 409 parts per million by volume (or 622 parts per million by mass). Atmospheric concentrations of carbon dioxide fluctuate slightly with the seasons, falling during the Northern Hemisphere spring and summer as plants consume the gas and rising during northern autumn and winter as plants go dormant or die and decay. Concentrations also vary on a regional basis, most strongly near the ground with much smaller variations aloft. In urban areas concentrations are generally higher and indoors they can reach 10 times background levels. The concentration of carbon dioxide has risen due to human activities. Combustion

title: Carbon dioxide

text: emissions – primarily from use of fossil fuels and deforestation – have rapidly increased its concentration in the atmosphere, leading to global warming. Carbon dioxide also causes ocean acidification because it dissolves in water to form carbonic acid. Carbon dioxide was the first gas to be described as a discrete substance. In about 1640, the Flemish chemist Jan Baptist van Helmont observed that when he burned charcoal in a closed vessel, the mass of the resulting ash was much less than that of the original charcoal. His interpretation was that the rest of the charcoal had been transmuted into an

title: Carbon dioxide

text: The body produces approximately of carbon dioxide per day per person, containing of carbon. In humans, this carbon dioxide is carried through the venous system and is breathed out through the lungs, resulting in lower concentrations in the arteries. The carbon dioxide content of the blood is often given as the partial pressure, which is the pressure which carbon dioxide would have had if it alone occupied the volume. In humans, the blood carbon dioxide contents is shown in the adjacent table: is carried in blood in three different ways. (The exact percentages vary depending whether it is arterial or

title: Carbon dioxide

text: of fossil fuels and deforestation have caused the atmospheric concentration of carbon dioxide to increase by about 43% since the beginning of the age of industrialization. Most carbon dioxide from human activities is released from burning coal and other fossil fuels. Other human activities, including deforestation, biomass burning, and cement production also produce carbon dioxide. Human activities emit about 29 billion tons of carbon dioxide per year, while volcanoes emit between 0.2 and 0.3 billion tons. Human activities have caused to increase above levels not seen in hundreds of thousands of years. Currently, about half of the carbon dioxide released

title: Carbon dioxide

text: aerobic fungi and bacteria. In vertebrates, the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians) or the gills (e.g., fish), from where it dissolves in the water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration. Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and (cyanobacteria) into energy-rich organic molecules such as glucose, thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce

title: Carbon dioxide

text: called dry ice. Liquid carbon dioxide forms only at pressures above 5.1 atm; the triple point of carbon dioxide is about 5.1 bar (517 kPa) at 217 K (see phase diagram). The critical point is 7.38 MPa at 31.1 °C. Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid. This form of glass, called "carbonia", is produced by supercooling heated at extreme pressure (40–48 GPa or about 400,000 atmospheres) in a diamond anvil. This discovery confirmed the theory that carbon dioxide could exist in a glass state similar to other members of its elemental

title: Carbon dioxide scrubber

text: a carbon dioxide scrubber. Air with high carbon dioxide content, such as air from fruit storage locations, can be blown through beds of activated carbon and the carbon dioxide will adsorb onto the activated carbon. Once the bed is saturated it must then be "regenerated" by blowing low carbon dioxide air, such as ambient air, through the bed. This will release the carbon dioxide from the bed, and it can then be used to scrub again, leaving the net amount of carbon dioxide in the air the same as when the process was started. Metal-organic frameworks are one of the

title: Carbon dioxide removal

text: need atmospheric reduction of 50 ppm plus an additional 2 ppm per year of current emissions. Carbon dioxide removal is different from reducing emissions, as the former produces an outlet of carbon dioxide from Earth's atmosphere, whereas the latter decreases the inlet of carbon dioxide to the atmosphere. Both have the same net effect, but for achieving carbon dioxide concentration levels below present levels, carbon dioxide removal is critical. Also for meeting higher concentration levels, carbon dioxide removal is increasingly considered to be crucial as it provides the only possibility to fill the gap between needed reductions to meet mitigation

title: Carbon dioxide

text: to produce carbonated soft drinks and soda water. Traditionally, the carbonation of beer and sparkling wine came about through natural fermentation, but many manufacturers carbonate these drinks with carbon dioxide recovered from the fermentation process. In the case of bottled and kegged beer, the most common method used is carbonation with recycled carbon dioxide. With the exception of British Real Ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with nitrogen. Carbon dioxide in the form of dry ice is often used during

title: Carbon dioxide

text: Organization standards also recognize carbon dioxide systems for fire protection of ship holds and engine rooms. Carbon dioxide based fire protection systems have been linked to several deaths, because it can cause suffocation in sufficiently high concentrations. A review of systems identified 51 incidents between 1975 and the date of the report (2000), causing 72 deaths and 145 injuries. Liquid carbon dioxide is a good solvent for many lipophilic organic compounds and is used to remove caffeine from coffee. Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional

title: Carbon dioxide removal

text: Carbon dioxide removal Carbon dioxide removal (CDR) refers to a number of technologies, the objective of which is the large-scale removal of carbon dioxide from the atmosphere. Among such technologies are bio-energy with carbon capture and storage, biochar, ocean fertilization, enhanced weathering, and direct air capture when combined with storage. CDR is a different approach than removing from the stack emissions of large fossil fuel point sources, such as power stations. The latter reduces emission to the atmosphere but cannot reduce the amount of carbon dioxide already in the atmosphere. As CDR removes carbon dioxide from the atmosphere, it creates

title: Carbon dioxide flooding

text: Carbon dioxide flooding Carbon dioxide (CO) flooding is a process whereby carbon dioxide is injected into an oil reservoir in order to increase output when extracting oil. When a reservoir’s pressure is depleted through primary and secondary production, carbon dioxide flooding can be an ideal tertiary recovery method. It is particularly effective in reservoirs deeper than 2,500 ft., where will be in a supercritical state, with API oil gravity greater than 22–25° and remaining oil saturation greater than 20%. Carbon dioxide flooding is not affected by the lithology of the reservoir area, but simply by the reservoir porosity and permeability,

title: Carbon dioxide removal

text: targets and . In the "OECD Environmental Outlook to 2050" released at the 2011 United Nations Climate Change Conference, the authors commented on the need for negative emissions, stating "Achieving lower concentration targets (450 ppm) depends significantly on the use of BECCS". A carbon dioxide sink such as a concentrated group of plants or any other primary producer that binds carbon dioxide into biomass, such as within forests and kelp beds, is not carbon negative, as sinks are not permanent. A carbon dioxide sink of this type moves carbon, in the form of carbon dioxide, from the atmosphere or hydrosphere

title: Carbon dioxide

text: elongatus" has been genetically engineered to produce the fuels isobutyraldehyde and isobutanol from using photosynthesis. Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical. Solid carbon dioxide is always below −78.5 °C at regular atmospheric pressure, regardless of the air temperature. The global automobile industry is expected to decide on the next-generation refrigerant in car air conditioning. is one discussed option.(see

title: Extracorporeal carbon dioxide removal

text: where the carbon dioxide is filtered out. Extracorporeal carbon dioxide removal Extracorporeal carbon dioxide removal (ECCOR) is the removal of carbon dioxide (CO) from the bloodstream in people who have elevated levels of carbon dioxide as a result of respiratory failure. The use of extracorporeal carbon dioxide removal is currently considered experimental, but it has been studied in a number of situations, specifically severe exacerbations of chronic obstructive pulmonary disease and in adult respiratory distress syndrome where conventional mechanical ventilation would cause excessive lung damage. It requires the insertion of a tube similar to a dialysis catheter into a large

title: Carbon dioxide

text: solvents such as organochlorides. It is used by some dry cleaners for this reason (see green chemistry). It is used in the preparation of some aerogels because of the properties of supercritical carbon dioxide. Plants require carbon dioxide to conduct photosynthesis. The atmospheres of greenhouses may (if of large size, must) be enriched with additional to sustain and increase the rate of plant growth. At very high concentrations (100 times atmospheric concentration, or greater), carbon dioxide can be toxic to animal life, so raising the concentration to 10,000 ppm (1%) or higher for several hours will eliminate pests such as

title: Carbon dioxide

text: into the oceans through hydrothermal vents. The "Champagne" hydrothermal vent, found at the Northwest Eifuku volcano in the Marianas Trench, produces almost pure liquid carbon dioxide, one of only two known sites in the world as of 2004, the other being in the Okinawa Trough. The finding of a submarine lake of liquid carbon dioxide in the Okinawa Trough was reported in 2006. Carbon dioxide is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism. This includes all plants, algae and animals and

title: Carbon dioxide cleaning

text: static charge buildup on non-conductive parts. This can be mitigated by grounding or positive ionization sources. Carbon dioxide cleaning Carbon dioxide cleaning (CO cleaning) comprises a family of methods for parts cleaning and sterilization, using carbon dioxide in its various phases. It is often preferred for use on delicate surfaces. CO cleaning has found application in the aerospace, automotive, electronics, medical, and other industries. Carbon dioxide snow cleaning has been used to remove particles and organic residues from metals, polymers, ceramics, glasses, and other materials, and from surfaces including hard drives and optical surfaces. cleaning has found application in many

title: Carbon dioxide cleaning

text: Carbon dioxide cleaning Carbon dioxide cleaning (CO cleaning) comprises a family of methods for parts cleaning and sterilization, using carbon dioxide in its various phases. It is often preferred for use on delicate surfaces. CO cleaning has found application in the aerospace, automotive, electronics, medical, and other industries. Carbon dioxide snow cleaning has been used to remove particles and organic residues from metals, polymers, ceramics, glasses, and other materials, and from surfaces including hard drives and optical surfaces. cleaning has found application in many industries and technical areas, including aerospace, automotive, electronics, medical, manufacturing, basic and applied research, and optics.

title: Extracorporeal carbon dioxide removal

text: Extracorporeal carbon dioxide removal Extracorporeal carbon dioxide removal (ECCOR) is the removal of carbon dioxide (CO) from the bloodstream in people who have elevated levels of carbon dioxide as a result of respiratory failure. The use of extracorporeal carbon dioxide removal is currently considered experimental, but it has been studied in a number of situations, specifically severe exacerbations of chronic obstructive pulmonary disease and in adult respiratory distress syndrome where conventional mechanical ventilation would cause excessive lung damage. It requires the insertion of a tube similar to a dialysis catheter into a large vein. Blood is pumped through a machine

title: Electrochemical reduction of carbon dioxide

text: Electrochemical reduction of carbon dioxide The electrochemical reduction of carbon dioxide (ERC) is the conversion of carbon dioxide to more reduced chemical species using electrical energy. The first examples of electrochemical reduction of carbon dioxide are from the 19th century, when carbon dioxide was reduced to carbon monoxide using a zinc cathode. Research in this field intensified in the 1980s following the oil embargoes of the 1970s. Electrochemical reduction of carbon dioxide represents a possible means of producing chemicals or fuels, converting carbon dioxide () to organic feedstocks such as formic acid (HCOOH), methanol (CHOH), ethylene (CH), methane (CH), and

title: Ocean storage of carbon dioxide

text: has already gone into the oceans. Carbon dioxide is currently emitted at 10 GtC per year and the oceans currently absorb 2.4 Gt carbon dioxide per year. The ocean is an enormous carbon sink with the capacity to hold thousands more gigatons (Gt) of carbon dioxide. Ocean sequestration has the potential to decrease atmospheric carbon dioxide concentrations according to some scientists. After atmospheric carbon dioxide dissolves into the ocean, the aqueous carbon dioxide reacts with seawater to form carbonic acid. As carbonic acid continues to interact with water molecules, carbonate is formed, which increases the concentration of hydrogen ions in

title: Carbon dioxide removal

text: a "Business as usual" concentration pathway, the deep ocean will remain acidified for centuries, and as a consequence many marine species are in danger of extinction. Carbon dioxide removal Carbon dioxide removal (CDR) refers to a number of technologies, the objective of which is the large-scale removal of carbon dioxide from the atmosphere. Among such technologies are bio-energy with carbon capture and storage, biochar, ocean fertilization, enhanced weathering, and direct air capture when combined with storage. CDR is a different approach than removing from the stack emissions of large fossil fuel point sources, such as power stations. The latter reduces

title: Ocean storage of carbon dioxide

text: injection, carbon dioxide hydrate is another popular method for storage. Hydrate formation takes place when the dissolved concentration of liquid carbon dioxide is around 30% and 400 meters below sea level. Hydrates form as an external layer around liquid carbon dioxide droplets or as a solid mass. The molecular composition is composed of carbon dioxide and water, carbon dioxide•nHO (n ≈ 5.75). The resulting density is denser than seawater by approximately 10%. Compared to liquid carbon dioxide, the hydrate form dissolves significantly slower in seawater, at about 0.2 cm/hr as well. Additionally, the hydrate remains immobile on the seafloor and

title: Ocean storage of carbon dioxide

text: atmosphere, the resulting change in ocean pH would also be similar as ocean mixing would eventually absorb excess carbon dioxide. Dilute carbon dioxide injection requires injection at depths where carbon dioxide can be dispersed by ocean currents and ocean mixing. Upon injection, waters interact and mix based on density and dilute the concentration of carbon dioxide. Boat based carbon dioxide injection distributes low carbon dioxide concentrations in open waters while moving to increase carbon dioxide dispersal area. carbon dioxide dispersal via boat can also occur by a pipe attached to the ship injecting a dilute carbon dioxide mixture into the

title: Carbon dioxide

text: concentrations lead to increases in global surface temperature, but increasing global temperatures also cause increasing concentrations of carbon dioxide. This produces a positive feedback for changes induced by other processes such as orbital cycles. Five hundred million years ago the carbon dioxide concentration was 20 times greater than today, decreasing to 4–5 times during the Jurassic period and then slowly declining with a particularly swift reduction occurring 49 million years ago. Local concentrations of carbon dioxide can reach high values near strong sources, especially those that are isolated by surrounding terrain. At the Bossoleto hot spring near Rapolano Terme in

title: Ocean storage of carbon dioxide

text: Ocean storage of carbon dioxide Ocean storage of carbon dioxide (CO) is a method of carbon sequestration. The concept of storing carbon dioxide in the ocean was first proposed by Italian physicist Cesare Marchetti in his 1976 paper "On Geoengineering and the carbon dioxide Problem." Since then, the concept of sequestering atmospheric carbon dioxide in the world's oceans has been investigated by scientists, engineers, and environmental activists. 39,000 GtC currently reside in the oceans while only 750 GtC are in the atmosphere. Of the 1300 Gt carbon dioxide from anthropogenic emissions over the last 200 years, about 38% of that

title: Carbon dioxide

text: oceans act as an enormous carbon sink, and have taken up about a third of emitted by human activity. As the concentration of carbon dioxide increases in the atmosphere, the increased uptake of carbon dioxide into the oceans is causing a measurable decrease in the pH of the oceans, which is referred to as ocean acidification. This reduction in pH affects biological systems in the oceans, primarily oceanic calcifying organisms. These effects span the food chain from autotrophs to heterotrophs and include organisms such as coccolithophores, corals, foraminifera, echinoderms, crustaceans and mollusks. Under normal conditions, calcium carbonate is stable in

title: Ocean storage of carbon dioxide

text: water column. The carbon dioxide is usually injected at 1000 m depth to reduce carbon dioxide bubble escape. As injected carbon dioxide bubbles rise, dispersal increases up the water column. Large dispersal areas and low concentrations of carbon dioxide significantly decrease any significant changes in local pH and resulting effects on marine ecosystems. Wickett et al. used measurements in natural pH fluctuations from atmospheric carbon dioxide to suggest that dilute carbon dioxide injection at 0.37 GTC/ yr would have a negligible effect on ocean pH. Dilute ocean injection requires little infrastructure in comparison to other forms of ocean injection. The

title: Supercritical carbon dioxide

text: selectively dissolve organic compounds and assist the functioning of enzymes, s has been suggested as a potential solvent to support biological activity on Venus- or super-Earth-type planets. Environmentally beneficial, low-cost substitutes for rigid thermoplastic and fired ceramic are made using s as a chemical reagent. The s in these processes is reacted with the alkaline components of fully hardened hydraulic cement or gypsum plaster to form various carbonates. The primary byproduct is water. Supercritical carbon dioxide is used in the foaming of polymers. Supercritical carbon dioxide can saturate the polymer with solvent. Upon depressurization and heating the carbon dioxide rapidly

title: Metal carbon dioxide complex

text: Metal carbon dioxide complex Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands. Aside from the fundamental interest in the coordination chemistry of simple molecules, studies in this field are motivated by the possibility that transition metals might catalyze useful transformations of CO. This research is relevant both to organic synthesis and to the production of "solar fuels" that would avoid the use of petroleum-based fuels. Carbon dioxide binds to metals in only a few ways. The bonding mode depends on the electrophilicity and basicity of the metal centre. Most common is the η-CO coordination mode as

title: Metal carbon dioxide complex

text: Ni(I) carboxylate to Ni(0) releases the zinc carboxylate (Scheme 6). Similarly, such carboxylation has been achieved on aryl and benzyl pivalate, alkyl halides, and allyl esters. Metal carbon dioxide complex Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands. Aside from the fundamental interest in the coordination chemistry of simple molecules, studies in this field are motivated by the possibility that transition metals might catalyze useful transformations of CO. This research is relevant both to organic synthesis and to the production of "solar fuels" that would avoid the use of petroleum-based fuels. Carbon dioxide binds to metals

title: Ocean storage of carbon dioxide

text: on the dispersal to make the change in carbon dioxide concentration in the ocean low enough to not affect the marine biosphere significantly. The proposed method of injection is droplets of supercritical carbon dioxide mixed with seawater. Plumes can be engineered to dissolve at different rates based on the size, concentration, and rate of injection of the carbon dioxide/seawater droplets. For rising plumes which rely on dissolution to sequester carbon dioxide, a smaller droplet with a greater rate of injection is better because it leads to faster dissolution. Sinking plumes ideally form lakes of carbon dioxide on the ocean floor

title: Carbon dioxide removal

text: to the biosphere. This process could be undone, for example by wildfires or logging. Carbon dioxide sinks that store carbon dioxide in the Earth's crust by injecting it into the subsurface, or in the form of insoluble carbonate salts (mineral sequestration), are considered carbon negative. This is because they are removing carbon from the atmosphere and sequestering it indefinitely and presumably for a considerable duration (thousands to millions of years). However, Carbon Capture technology remains, at best, theoretical and is yet to reach more than 33% efficiency. Furthermore, this process could be rapidly undone, for example by earthquakes or mining.

title: Ocean storage of carbon dioxide

text: However, organisms are not only affected by the acidification of water in the presence of heightened carbon dioxide (carbon dioxide) levels. carbon dioxide itself interacts with the physiological function of individual organisms. These effects are more damaging than those associated with changes in pH of environment. When carbon dioxide enters organisms, through diffusion across tissue, it becomes internally accumulated which can then cause anesthesia and, depending on the concentration of carbon dioxide, death. The internal accumulation will also cause organisms to experience blood acidification. This weakens organisms' ability to uptake oxygen and consequently weakens their performances. This effect is more

title: Carbon dioxide

text: stretching mode at 1388 cm which is only observed in the Raman spectrum. Carbon dioxide is soluble in water, in which it reversibly forms (carbonic acid), which is a weak acid since its ionization in water is incomplete. The hydration equilibrium constant of carbonic acid is formula_1 (at 25 °C). Hence, the majority of the carbon dioxide is not converted into carbonic acid, but remains as molecules, not affecting the pH. The relative concentrations of , and the deprotonated forms (bicarbonate) and (carbonate) depend on the pH. As shown in a Bjerrum plot, in neutral or slightly alkaline water (pH

title: Carbon dioxide

text: Most of the remaining 50–55% is methane. Carbon dioxide is used by the food industry, the oil industry, and the chemical industry. The compound has varied commercial uses but one of its greatest use as a chemical is in the production of carbonated beverages; it provides the sparkle in carbonated beverages such as soda water, beer and sparkling wine. In the chemical industry, carbon dioxide is mainly consumed as an ingredient in the production of urea, with a smaller fraction being used to produce methanol and a range of other products, such as metal carbonates and bicarbonates. Some carboxylic acid

title: Carbon dioxide

text: venous blood). Hemoglobin, the main oxygen-carrying molecule in red blood cells, carries both oxygen and carbon dioxide. However, the bound to hemoglobin does not bind to the same site as oxygen. Instead, it combines with the N-terminal groups on the four globin chains. However, because of allosteric effects on the hemoglobin molecule, the binding of decreases the amount of oxygen that is bound for a given partial pressure of oxygen. This is known as the Haldane Effect, and is important in the transport of carbon dioxide from the tissues to the lungs. Conversely, a rise in the partial pressure of

title: Carbon dioxide

text: the cold soak phase in wine making to cool clusters of grapes quickly after picking to help prevent spontaneous fermentation by wild yeast. The main advantage of using dry ice over water ice is that it cools the grapes without adding any additional water that might decrease the sugar concentration in the grape must, and thus the alcohol concentration in the finished wine. Carbon dioxide is also used to create a hypoxic environment for carbonic maceration, the process used to produce Beaujolais wine. Carbon dioxide is sometimes used to top up wine bottles or other storage vessels such as barrels

title: Ocean storage of carbon dioxide

text: Earth's climate. This presents itself as a readily available carbon sink to store and capture atmospheric carbon dioxide. Due to the solubility of carbon dioxide in water, CO2 naturally dissolves in oceanic waters to form an equilibrium. With an increase in the concentration of carbon dioxide in the atmosphere, the position of equilibrium pushes the equilibrium in the direction such that more CO2 dissolves into the water. Utilizing this mechanism, more than 500 Gtons of carbon dioxide (amounting to a total of 140 Gtons of carbon) of anthropogenic carbon dioxide emissions released over the past 2 centuries have been absorbed

title: Ocean storage of carbon dioxide

text: hydrate. Two regions are defined for exploration: the negative buoyancy zone (NBZ), which is the region between liquid carbon dioxide denser than surrounding water and where liquid carbon dioxide has neutral buoyancy, and hydrate formation zone (HFZ), which typically has low temperatures and high pressures. Several research models have shown that the optimal depth of injection requires consideration of intrinsic permeability and any changes in liquid carbon dioxide permeability for optimal storage. The formation of hydrates decreases liquid carbon dioxide permeability, and injection below HFZ is more energetically favored than within the HFZ. If the NBZ is a greater column

text: carbon monoxide (CO). In carbon fixation, plants convert carbon dioxide into sugars, from which many biosynthetic pathways originate. The catalyst responsible for this conversion, RuBisCo, is the most common protein on earth. Some anaerobic organisms employ enzymes to convert CO to carbon monoxide, from which fatty acids can be made. In industry, a few products are made from CO, including urea, salicylic acid, methanol, and certain inorganic and organic carbonates. In the laboratory, carbon dioxide is sometimes used to prepare carboxylic acids. No electrochemical process involving CO has been commercialized. The electrochemical reduction of carbon dioxide to CO is usually

title: Carbon dioxide laser

text: excited vibrational levels are therefore metastable and relatively long-lived. Collisional energy transfer between the nitrogen and the carbon dioxide molecule causes vibrational excitation of the carbon dioxide, with sufficient efficiency to lead to the desired population inversion necessary for laser operation. The nitrogen molecules are left in a lower excited state. Their transition to ground state takes place by collision with cold helium atoms. The resulting hot helium atoms must be cooled in order to sustain the ability to produce a population inversion in the carbon dioxide molecules. In sealed lasers, this takes place as the helium atoms strike the

title: Ocean storage of carbon dioxide

text: to mineralization processes that takes place within rocks, mineralization can also occur under the sea. The rate of dissolution of carbon dioxide from atmosphere to oceanic regions relies upon the circulation period of the ocean and buffering ability of subducting surface water. Researches have demonstrated that the carbon dioxide marine storage at several kilometers deep could be viable for up to 500 years, but is dependent on injection site and conditions. Several studies have shown that although it may fix carbon dioxide effect, carbon dioxide may be released back to the atmosphere over time. However, this is unlikely for at

title: Carbon dioxide in Earth's atmosphere

text: been proposed for removing excess carbon dioxide from the atmosphere in carbon dioxide sinks. Currently about half of the carbon dioxide released from the burning of fossil fuels is not absorbed by vegetation and the oceans and remains in the atmosphere. Excess emitted since the pre-industrial era is projected to remain in the atmosphere for centuries to millennia, even after emissions stop. Even if human carbon dioxide emissions were to completely cease, atmospheric temperatures are not expected to decrease significantly for thousands of years. The first reproducibly accurate measurements of atmospheric CO were from flask sample measurements made by Dave

title: Carbon dioxide (data page)

text: Carbon dioxide (data page) This page provides supplementary chemical data on carbon dioxide. The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. MSDS for solid carbon dioxide is available from Pacific Dry Ice, inc. Table data obtained from "CRC Handbook of Chemistry and Physics" 44th ed. Annotation "(s)" indicates equilibrium temperature of vapor over solid. Otherwise temperature is equilibrium of vapor over liquid. For kPa values, where datum is whole numbers of atmospheres

title: Carbon dioxide (data page)

text: °C and below, which are taken from "Lange's Handbook of Chemistry", 10th ed. page 1463. Except where noted otherwise, data relate to standard ambient temperature and pressure. Carbon dioxide (data page) This page provides supplementary chemical data on carbon dioxide. The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions. MSDS for solid carbon dioxide is available from Pacific Dry Ice, inc. Table data obtained from "CRC Handbook of Chemistry and Physics" 44th ed.

title: Ocean storage of carbon dioxide

text: so detrimental to more complex and larger species that require a greater exertion of energy to move and perform vital bodily functions. If deep-sea ocean sequestration becomes a common practice, long term effects will continue to be investigated to predict future scenarios of deep sea impacts by carbon dioxide. Ocean sequestration of liquid carbon dioxide would not only impact deep-sea ecosystems, but in the long-run would begin to affect surface-water species. It is estimated that organisms not fit for high carbon dioxide levels will begin to experience permanent effects at levels of 400/500ppm of carbon dioxide and/or shifts of 0.1-0.3

title: Ocean storage of carbon dioxide

text: There is consensus among scientists that ocean sequestration of carbon dioxide is not a long-term plan to be relied on, but may solve immediate atmospheric concerns if implemented temporarily. Scientists believe that it is possible to engineer ways to discharge carbon dioxide at rates that resemble the natural fluctuation of carbon dioxide in the oceans. Ocean storage refers to the use of large water bodies and marine lifeforms to capture carbon by exploiting natural and geological mechanisms. Oceans cover slightly more than 70% of the total surface area of the Earth, and plays a major role in helping to stabilize

title: Ocean storage of carbon dioxide

text: for more long term sequestration. Carbon dioxide lakes will form on ocean floors in depressions or trenches in the seabed. These lakes sequester carbon dioxide through isolation. The deep ocean has a very slow rate of mixing with the surface ocean. Additionally, the surface of the carbon dioxide lake will form a layer of crystal hydrates that will slow dissolution of carbon dioxide into the above ocean. Convective motion over the surface of the lake due to ocean bottom storms or normal sea currents will increase dissolution. Without any bulk flow over the lake, the storage timeline of the carbon

title: Ocean storage of carbon dioxide

text: experiments, continuous streams of hydrates have not yet been achieved. Studies show that delivering liquid carbon dioxide by a towed pipeline (attached to boat traveling perpendicular to the current), can minimize "clumps" of highly concentrated carbon dioxide levels. Delivery by fixed pipe would be confined to a small region of the ocean and in turn instantly kill sensitive species inhabiting the region. Theoretically, if we assume future anthropogenic emissions of carbon dioxide drop drastically and only 0.37 Gt of liquid carbon dioxide were to be injected each year through a towed pipe, only 1% of the ocean would be affected.

title: Ocean storage of carbon dioxide

text: Different amounts and concentrations of sequestered carbon dioxide will affect each ecosystem and species differently such that a general, universal limit of carbon dioxide to be sequestered doesn't exist. Corporations in favor of ocean sequestration, such as ExxonMobil, argue that the uncertainties involved with such predictions instill doubt in the conclusions of the research. Supporters of ocean sequestration argue that because of the ocean's size, diluted carbon dioxide injections will not be enough to create an actual impact on ecosystems and that species can evolve to these increased levels of carbon dioxide eventually. Scientific research shows that sites of injection

title: Ocean storage of carbon dioxide

text: units in pH. These levels of carbon dioxide are predicted to be met solely as a result of atmospheric carbon dioxide acidifying the surface waters over a matter of a century, without considering ocean sequestration effects. Although the long-term effects are the most relevant to understand, they are also the most difficult to predict accurately due to the scale of the ocean and the diversity in species sensitivity to elevated carbon dioxide levels. Surface sea organisms have been better studied than deep-sea animals in terms of consequences due to prolonged carbon dioxide exposure and have been proven to experience "reduced

title: Carbon dioxide clathrate

text: Type I clathrate for the first time by von Stackelberg & Muller (1954). On Earth, CO hydrate is mostly of academic interest. Tim Collett of the United States Geological Survey (USGS) proposed pumping carbon dioxide into subsurface methane clathrates, thereby releasing the methane and storing the carbon dioxide (Michael Marshall, 2009). As of 2009, ConocoPhillips is working on a trial on the Alaska North Slope with the US Department of Energy to release methane in this way, (ConocoPhilips, January 2010, New Scientist, no. 2714, p. 33). At first glance, it seems that the thermodynamic conditions there favor the existence of

title: Supercritical carbon dioxide

text: the supercritical state and injected into geological storage, possibly into existing oil fields to improve yields. The unique properties of s ensure that it remains out of the atmosphere. Supercritical could be used as a working fluid in enhanced geothermal systems. Possible advantages compared to water include higher energy yield resulting from its lower viscosity, better chemical interaction, storage through fluid loss and higher temperature limit. As of 2011, the concept had not been tested in the field. Supercritical carbon dioxide is used in the production of silica, carbon and metal based aerogels. For example, silicon dioxide gel is formed

title: Supercritical carbon dioxide

text: perceived dangers related to their use in food preparation. s is forced through the green coffee beans which are then sprayed with water at high pressure to remove the caffeine. The caffeine can then be isolated for resale (e.g. to the pharmaceutical or beverage manufacturers) by passing the water through activated charcoal filters or by distillation, crystallization or reverse osmosis. Supercritical carbon dioxide is used to remove organochloride pesticides and metals from agricultural crops without adulterating the desired constituents from the plant matter in the herbal supplement industry. Supercritical carbon dioxide can be used as a more environmentally friendly solvent