ShantanuT01/DACTYL-Pretraining huggingface dataset:
We report a strongly temperature dependent luminescence Stokes shift in the electronic spectra of both hybrid and inorganic lead-bromide perovskite single crystals. This behavior stands in stark contrast to that exhibited by more conventional crystalline semiconductors. We correlate the electronic spectra with the anti-Stokes and Stokes Raman vibrational spectra. Dielectric solvation theories, originally developed for excited molecules dissolved in polar liquids, reproduce our experimental observations. Our approach, which invokes a classical Debye-like relaxation process, captures the dielectric response originating from an anharmonic LO phonon at about 20 meV (160 cm-1) in the lead-bromide framework. We reconcile the liquid-like picture with more standard solid-state theories of the Stokes shift in crystalline semiconductors.
We address the correspondence search problem among multiple graphs with complex properties while considering the matching consistency. We describe each pair of graphs by combining multiple attributes, then jointly match them in a unified framework. The main contribution of this paper is twofold. First, we formulate the global correspondence search problem of multi-attributed graphs by utilizing a set of multi-layer structures. The proposed formulation describes each pair of graphs as a multi-layer structure, and jointly considers whole matching pairs. Second, we propose a robust multiple graph matching method based on the multi-layer random walks framework. The proposed framework synchronizes movements of random walkers, and leads them to consistent matching candidates. In our extensive experiments, the proposed method exhibits robust and accurate performance over the state-of-the-art multiple graph matching algorithms.
Welschinger's invariant bounds from below the number of real rational curves through a given generic collection of real points in the real projective plane. We estimate this invariant using Mikhalkin's approach which deals with a corresponding count of tropical curves. In particular, our estimate implies that, for any positive integer $d$, there exists a real rational curve of degree $d$ through any collection of $3d-1$ real points in the projective plane, and, moreover, asymptotically in the logarithmic scale at least one third of the complex plane rational curves through a generic point collection are real. We also obtain similar results for curves on other toric Del Pezzo surfaces.
The rotational spectrum of silyl isocyanide (SiH$_3$NC), an isomer of the well studied silyl cyanide (SiH$_3$CN), has been detected in the laboratory in a supersonic molecular beam, and the identification was confirmed by observations of the corresponding rotational transitions in the rare isotopic species SiH$_3$$^{15}$NC and SiH$_3$N$^{13}$C. Spectroscopic constants derived from 19 transitions between $11 - 35$~GHz in the three lowest harmonically related rotational transitions in the $K = 0 ~{\rm{and}}~1$ ladders of the normal isotopic species including the nitrogen nuclear quadrupole hyperfine constant, allow the principal astronomical transitions of SiH$_3$NC to be calculated to an uncertainty of about 4~km~s$^{-1}$ in equivalent radial velocity, or within the FWHM of narrow spectral features in the inner region of IRC+10216 near 200~GHz. The concentration of SiH$_3$NC in our molecular beam is three times less than SiH$_3$CN, or about the same as the corresponding ratio of the isomeric pair SiNC and SiCN produced under similar conditions. Silyl isocyanide is an excellent candidate for astronomical detection, because the spectroscopic and chemical properties are very similar to SiH$_3$CN which was recently identified in the circumstellar envelope of IRC+10216 by \citet{cernicharo_discovery_2017} and of SiNC and SiCN in the same source.
A symmetry breaking (SB) involves an abrupt change in the set of microstates that a system can explore. This change has unavoidable thermodynamic implications. According to Boltzmann's microscopic interpretation of entropy, a shrinkage of the set of compatible states implies a decrease of entropy, which eventually needs to be compensated by dissipation of heat and consequently requires work. Examples are the compression of a gas and the erasure of information. On the other hand, in a spontaneous SB, the available phase space volume changes without the need for work, yielding an apparent decrease of entropy. Here we show that this decrease of entropy is a key ingredient in the Szilard engine and Landauer's principle and report on a direct measurement of the entropy change along SB transitions in a Brownian particle. The SB is induced by a bistable potential created with two optical traps. The experiment confirms theoretical results based on fluctuation theorems, allows us to reproduce the Szilard engine extracting energy from a single thermal bath, and shows that the signature of a SB in the energetics is measurable, providing new methods to detect, for example, the coexistence of metastable states in macromolecules.
We calculate the superfluid density of nucleons in disordered pasta phases in the inner crust of neutron stars using an effective medium approach which parallels that previously used for calculating the electrical conductivity of terrestrial matter. We allow for the effect of entrainment, the fact that the current density of one species of nucleon depends on the gradient of the phase not only of the same species but also of the other species. The superfluid density tensors for the perfectly ordered pasta phases are very anisotropic, and we derive expression for the effective superfluid densities of the disordered phases.
The single-valued parameter (SVP) method is a parametric method that offers the possibility of computing radiative accelerations in stellar interiors much faster than other methods. It has been implemented in a few stellar evolution numerical codes for about a decade. In the present paper, we describe improvements we have recently brought in the process of preparing, from atomic/opacity databases, the SVP tables that are needed to use the method, and their extension to a larger stellar mass domain (from 1 to 10 solar mass) on the main-sequence. We discuss the validity domain of the method. We also present the website from where new tables and codes can be freely accessed and implemented in stellar evolution codes.
We consider the effects of local interactions upon quantum mechanically entangled systems. In particular we demonstrate that non-local correlations cannot increase through local operations on any of the subsystems, but that through the use of quantum error correction methods, correlations can be maintained. We provide two mathematical proofs that local general measurements cannot increase correlations, and also derive general conditions for quantum error correcting codes. Using these we show that local quantum error correction can preserve nonlocal features of entangled quantum systems. We also demonstrate these results by use of specific examples employing correlated optical cavities interacting locally with resonant atoms. By way of counter example, we also describe a mechanism by which correlations can be increased, which demonstrates the need for it non-local interactions.
The magnetic, thermal and transport properties of Na0.75CoO2 single crystals grown by the floating zone (FZ) method are reported. Magnetic susceptibility, resistivity, magnetoresistance, and heat capacity data from these crystals indicate a bulk phase transition at T1 = 22 K. These data are most consistent with the formation of an antiferromagnet spin-density-wave (SDW) at 22 K with the easy axis for magnetization nearly along the c axis. Weak and soft ferromagnetism is observed for applied magnetic fields less than 0.5 T, which suggests a slight canting of the SDW magnetization with respect to the c axis. The jump in the heat capacity at the SDW transition is 0.45 J/K-mole-Co or about 50% of the value expected from mean-field weak-coupling theory. The reduced jump and the decrease in the resistivity below T1 are consistent with a gap for only part of the Fermi surface. The magnetoresistance is small at the SDW transition but increases in both directions reaching a value of 100% at 2 K for applied fields of 8 Tesla. The magnetoresistance data imply that the mobility of the remaining carriers is large and increases below T1. The observation of a SDW transition in this material is found to be sensitive to the preparation conditions and the degree of order in the Na layers. No SDW transition is observed in our polycrystalline powder with the same nominal composition (Na0.75CoO2) and lattice constants. Differential scanning calorimetry data, however, show distinct differences between the powder and crystal, suggesting a higher degree of order in the Na layers within the crystal. The crystal exhibits a sharp phase transition at T2 = 340 K while for the powder this transition is smeared over the temperature range from 250 to 310 K.
The Chow-Robbins game is a classical still partly unsolved stopping problem introduced by Chow and Robbins in 1965. You repeatedly toss a fair coin. After each toss, you decide if you take the fraction of heads up to now as a payoff, otherwise you continue.   As a more general stopping problem this reads   \[V(n,x) = \sup_{\tau }\operatorname{E} \left [ \frac{x + S_\tau}{n+\tau}\right]\] where $S$ is a random walk.   We give a tight upper bound for $V$ when $S$ has subgassian increments. We do this by usinf the analogous time continuous problem with a standard Brownian motion as the driving process. From this we derive an easy proof for the existence of optimal stopping times in the discrete case.   For the Chow-Robbins game we as well give a tight lower bound and use these to calculate, on the integers, the complete continuation and the stopping set of the problem for $n\leq 10^{5}$.
We analyze cosmic microwave background (CMB) data taking into account the effects of a momentum dependent effective sound speed (MESS). This approach allows to study the effects of primordial entropy in a model independent way, and its implementation requires a minimal modification of existing CMB fitting numerical codes developed for single scalar field models.   We adopt a phenomenological approach, and study the effects a local variation of the MESS around the scale where other analysis have shown some deviation from an approximately scale invariant curvature perturbation spectrum. We obtain a substantial improvement of the fit with respect to a model without MESS, showing that primordial entropy modeled by MESS can be an explanation of these deviations.
Clay mineral particles are interesting nanosized building blocks due to their high aspect ratio and the chemical properties. The main interest in this nanosized building blocks results essentially from the colloidal size and the permanent structural charge of the particles. Smectites or swelling clay minerals are naturally occurring nanomaterials that can be fully delaminated to elementary clay mineral platelets in dilute aqueous dispersion. This dilute aqueous smectite suspensions are well suited to convert into functional nanofilms. The functionalization is performed by ion exchange reaction with amphiphilic molecules carrying the desired functionality, such as chirality, two photon absorption, energy transfer, optical nonlinearity and magnetism, which are due to the nature of the amphiphilic cations and to the organization of both the amphiphilic molecules and the elementary clay mineral platelets. Controlling the structure of materials at the nanometre scale is of fundamental importance for tailoring such materials properties. Langmuir Blodgett films are known for a high degree of organisation of organic molecules. Fundamental research into the organization of molecules at clay mineral platelets is necessary to optimize the materials for specific applications. This paper gives an overview of organo-clay hybrid Langmuir-Blodgett nano films.
The stress-driven motion of dislocations in crystalline solids, and thus the ensuing plastic deformation process, is greatly influenced by the presence or absence of various point-like defects such as precipitates or solute atoms. These defects act as obstacles for dislocation motion and hence affect the mechanical properties of the material. Here we combine molecular dynamics studies with three-dimensional discrete dislocation dynamics simulations in order to model the interaction between different kinds of precipitates and a $\frac{1}{2}\langle 1 1 1\rangle$ $\{1 1 0\}$ edge dislocation in BCC iron. We have implemented immobile spherical precipitates into the ParaDis discrete dislocation dynamics code, with the dislocations interacting with the precipitates via a Gaussian potential, generating a normal force acting on the dislocation segments. The parameters used in the discrete dislocation dynamics simulations for the precipitate potential, the dislocation mobility, shear modulus and dislocation core energy are obtained from molecular dynamics simulations. We compare the critical stresses needed to unpin the dislocation from the precipitate in molecular dynamics and discrete dislocation dynamics simulations in order to fit the two methods together, and discuss the variety of the relevant pinning/depinning mechanisms.
Young solar-type stars rotate rapidly and are very magnetically active. The magnetic fields at their surfaces likely originate in their convective envelopes where convection and rotation can drive strong dynamo action. Here we explore simulations of global-scale stellar convection in rapidly rotating suns using the 3-D MHD anelastic spherical harmonic (ASH) code. The magnetic fields built in these dynamos are organized on global-scales into wreath-like structures that span the convection zone. We explore one case rotates five times faster than the Sun in detail. This dynamo simulation, called case D5, has repeated quasi-cyclic reversals of global-scale polarity. We compare this case D5 to the broader family of simulations we have been able to explore and discuss how future simulations and observations can advance our understanding of stellar dynamos and magnetism.
We present an optical and near-infrared photometric and spectroscopic study of supernova (SN) 2009kn spanning ~1.5 yr from the discovery. The optical spectra are dominated by the narrow (full width at half-maximum ~1000 km s^-1) Balmer lines distinctive of a Type IIn SN with P Cygni profiles. Contrarily, the photometric evolution resembles more that of a Type IIP SN with a large drop in luminosity at the end of the plateau phase. These characteristics are similar to those of SN 1994W, whose nature has been explained with two different models with different approaches. The well-sampled data set on SN 2009kn offers the possibility to test these models, in the case of both SN 2009kn and SN 1994W. We associate the narrow P Cygni lines with a swept-up shell composed of circumstellar matter and SN ejecta. The broad emission line wings, seen during the plateau phase, arise from internal electron scattering in this shell. The slope of the light curve after the post-plateau drop is fairly consistent with that expected from the radioactive decay of 56Co, suggesting an SN origin for SN 2009kn. Assuming radioactivity to be the main source powering the light curve of SN 2009kn in the tail phase, we infer an upper limit for 56Ni mass of 0.023 M_sun. This is significantly higher than that estimated for SN 1994W, which also showed a much steeper decline of the light curve after the post-plateau drop. We also observe late-time near-infrared emission which most likely arises from newly formed dust produced by SN 2009kn. As with SN 1994W, no broad lines are observed in the spectra of SN 2009kn, not even in the late-time tail phase.
Solid-state cooling using barocaloric materials is a promising avenue for eco-friendly, inexpensive and highly efficient cooling. To design barocaloric compounds ready for deployment, it is essential to understand their thermodynamic behaviour under working conditions. To this end, we have studied the rotational dynamics in the molecular-ionic crystal ammonium sulfate under pressure, providing detailed insight into the origin of its large barocaloric effect. Using quasielastic neutron scattering experiments, we show that rotation of the ammonium cations is facilitated by pressure in the low-entropy phase, with the rotational "hopping" motion increasing in frequency as the pressure-induced phase transition is approached. We explain this unusual behaviour in terms of the competing hydrogen-bond networks represented by the two phases. This work includes the first results of a recently developed low-background, high-pressure gas cell for neutron scattering, showcasing its power in obtaining high-precision measurements of molecular dynamics under pressure.
Let S be a Noetherian scheme and f:X -> S a proper morphism. By SGA 4 XIV, for any constructible sheaf F of Z/nZ-modules on X, the sheaves of Z/nZ-modules R^if_*F obtained by direct image (for the etale topology) are also constructible: there is a stratification of S on whose strata these sheaves are locally constant constructible. After previous work of N. Katz and G. Laumon, or L. Illusie, on the special case in which S is generically of characteristic zero or the sheaves F are constant (with invertible torsion on S), here we study the dependency of the stratification on F. We show that a natural "uniform" tameness and constructibility condition satisfied by constant sheaves, which was introduced by O. Gabber, is stable under the functors R^if_*. If f is not proper, this result still holds assuming tameness at infinity, relatively to S. We also prove the existence of uniform bounds on Betti numbers, in particular for the stalks of the sheaves R^if_*Z/lZ, where l ranges through all prime numbers invertible on S.
The field of face recognition (FR) has witnessed great progress with the surge of deep learning. Existing methods mainly focus on extracting discriminative features, and directly compute the cosine or L2 distance by the point-to-point way without considering the context information. In this study, we make a key observation that the local con-text represented by the similarities between the instance and its inter-class neighbors1plays an important role forFR. Specifically, we attempt to incorporate the local in-formation in the feature space into the metric, and pro-pose a unified framework calledInter-class DiscrepancyAlignment(IDA), with two dedicated modules, Discrepancy Alignment Operator(IDA-DAO) andSupport Set Estimation(IDA-SSE). IDA-DAO is used to align the similarity scores considering the discrepancy between the images and its neighbors, which is defined by adaptive support sets on the hypersphere. For practical inference, it is difficult to acquire support set during online inference. IDA-SSE can provide convincing inter-class neighbors by introducing virtual candidate images generated with GAN. Further-more, we propose the learnable IDA-SSE, which can implicitly give estimation without the need of any other images in the evaluation process. The proposed IDA can be incorporated into existing FR systems seamlessly and efficiently. Extensive experiments demonstrate that this frame-work can 1) significantly improve the accuracy, and 2) make the model robust to the face images of various distributions.Without bells and whistles, our method achieves state-of-the-art performance on multiple standard FR benchmarks.
The pyrochlore magnet Tb$_{2}$Ti$_{2}$O$_{7}$ shows a lack of magnetic order to low temperatures and is considered to be a quantum spin liquid candidate. We perform time-domain THz spectroscopy on high quality Tb$_{2}$Ti$_{2}$O$_{7}$ crystal and study the low energy excitations as a function of [111] magnetic field with high energy resolution. The low energy crystal field excitations change their energies anomalously under magnetic field. Despite several sharp field dependent changes, we show that the material's spectrum can be described not by a phase transitions, but by field dependent hybridization between the low energy crystal field levels. We highlight the strong coupling between spin and lattice degrees of freedom in Tb$_{2}$Ti$_{2}$O$_{7}$ as evidenced by the magnetic field tunable crystal field environment. Calculations based on single ion physics with field induced symmetry reduction of the crystal field environment can reproduce our data.
We study young star-forming clumps on physical scales of 10-500 pc in the Lyman-Alpha Reference Sample (LARS), a collection of low-redshift (z = 0.03-0.2) UV-selected star-forming galaxies. In each of the 14 galaxies of the sample, we detect clumps for which we derive sizes and magnitudes in 5 UV-optical filters. The final sample includes $\sim$1400 clumps, of which $\sim$600 have magnitude uncertainties below 0.3 in all filters. The UV luminosity function for the total sample of clumps is described by a power-law with slope $\alpha = -2.03^{+0.11}_{-0.13}$. Clumps in the LARS galaxies have on average $\Sigma_{SFR}$ values higher than what observed in HII regions of local galaxies and comparable to typical SFR densities of clumps in z = 1-3 galaxies. We derive the clumpiness as the relative contribution from clumps to the UV emission of each galaxy, and study it as a function of galactic-scale properties, i.e. $\Sigma_{SFR}$ and the ratio between rotational and dispersion velocities of the gas ($v_s/\sigma_0$). We find that in galaxies with higher $\Sigma_{SFR}$ or lower $v_s/\sigma_0$, clumps dominate the UV emission of their host systems. All LARS galaxies with Ly$\alpha$ escape fractions larger than 10% have more than 50% of the UV luminosity from clumps. We tested the robustness of these results against the effect of different physical resolutions. At low resolution, the measured clumpiness appears more elevated than if we could resolve clumps down to single clusters. This effect is small in the redshift range covered by LARS, thus our results are not driven by the physical resolution.
We examine the propagation of a weak probe light through a coherently driven $Y$-type system. Under the condition that the excited atomic levels decay via same vacuum modes, the effects of quantum interference in decay channels are considered. It is found that the interference in decay channels results in a lossless anomalous dispersion between two gain peaks. We demonstrate that the probe pulse propagation can in principle be switched from subluminal to superluminal due to the decay-induced interference. We also show that the system exhibits a high index of refraction with negligible absorption for the driving fields. A dressed-state picture of the atom-light interaction is described to explain the numerical results.
In this paper, we study the task of 3D human pose estimation in the wild. This task is challenging due to lack of training data, as existing datasets are either in the wild images with 2D pose or in the lab images with 3D pose.   We propose a weakly-supervised transfer learning method that uses mixed 2D and 3D labels in a unified deep neutral network that presents two-stage cascaded structure. Our network augments a state-of-the-art 2D pose estimation sub-network with a 3D depth regression sub-network. Unlike previous two stage approaches that train the two sub-networks sequentially and separately, our training is end-to-end and fully exploits the correlation between the 2D pose and depth estimation sub-tasks. The deep features are better learnt through shared representations. In doing so, the 3D pose labels in controlled lab environments are transferred to in the wild images. In addition, we introduce a 3D geometric constraint to regularize the 3D pose prediction, which is effective in the absence of ground truth depth labels. Our method achieves competitive results on both 2D and 3D benchmarks.