Describe Lie Algebra
Unfortunately, there is no universally accepted definition of a simple Lie group. In particular, it is not always defined as a Lie group that is simple as an abstract group. Authors differ on whether a simple Lie group has to be connected, or on whether it is allowed to have a non-trivial center, or on whether 
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\mathbb {R}  is a simple Lie group.

The most common definition is that a Lie group is simple if it is connected, non-abelian, and every closed connected normal subgroup is either the identity or the whole group. In particular, simple groups are allowed to have a non-trivial center, but 
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\mathbb {R}  is not simple.

In this article the connected simple Lie groups with trivial center are listed. Once these are known, the ones with non-trivial center are easy to list as follows. Any simple Lie group with trivial center has a universal cover, whose center is the fundamental group of the simple Lie group. The corresponding simple Lie groups with non-trivial center can be obtained as quotients of this universal cover by a subgroup of the center.

Alternatives
An equivalent definition of a simple Lie group follows from the Lie correspondence: A connected Lie group is simple if its Lie algebra is simple. An important technical point is that a simple Lie group may contain discrete normal subgroups. For this reason, the definition of a simple Lie group is not equivalent to the definition of a Lie group that is simple as an abstract group.

Simple Lie groups include many classical Lie groups, which provide a group-theoretic underpinning for spherical geometry, projective geometry and related geometries in the sense of Felix Klein's Erlangen program. It emerged in the course of classification of simple Lie groups that there exist also several exceptional possibilities not corresponding to any familiar geometry. These exceptional groups account for many special examples and configurations in other branches of mathematics, as well as contemporary theoretical physics.

As a counterexample, the general linear group is neither simple, nor semisimple. This is because multiples of the identity form a nontrivial normal subgroup, thus evading the definition. Equivalently, the corresponding Lie algebra has a degenerate Killing form, because multiples of the identity map to the zero element of the algebra. Thus, the corresponding Lie algebra is also neither simple nor semisimple. Another counter-example are the special orthogonal groups in even dimension. These have the matrix 
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-I in the center, and this element is path-connected to the identity element, and so these groups evade the definition. Both of these are reductive groups.