Sazuna/UAT_keywords huggingface dataset:
Molecular Outgassing in Centaur 29P/Schwassmann-Wachmann 1 during Its Exceptional 2021 Outburst: Coordinated Multiwavelength Observations Using nFLASH at APEX and iSHELL at the NASA-IRTF. The extraordinary 2021 September-October outburst of Centaur 29P/Schwassmann-Wachmann 1 afforded an opportunity to test the composition of primitive Kuiper disk material at high sensitivity. We conducted nearly simultaneous multiwavelength spectroscopic observations of 29P/Schwassmann-Wachmann 1 using iSHELL at the NASA Infrared Telescope Facility (IRTF) and nFLASH at the Atacama Pathfinder EXperiment (APEX) on 2021 October 6, with follow-up APEX/nFLASH observations on 2021 October 7 and 2022 April 3. This coordinated campaign between near-infrared and radio wavelengths enabled us to sample molecular emission from a wealth of coma molecules and to perform measurements that cannot be accomplished at either wavelength alone. We securely detected CO emission on all dates with both facilities, including velocity-resolved spectra of the CO (J = 2-1) transition with APEX/nFLASH and multiple CO (v = 1-0) rovibrational transitions with IRTF/iSHELL. We report rotational temperatures, coma kinematics, and production rates for CO and stringent (3σ) upper limits on abundance ratios relative to CO for CH4, C2H6, CH3OH, H2CO, CS, and OCS. Our upper limits for CS/CO and OCS/CO represent their first values in the literature for this Centaur. Upper limits for CH4, C2H6, CH3OH, and H2CO are the most stringent reported to date, and are most similar to values found in ultra CO-rich Oort cloud comet C/2016 R2 (PanSTARRS), which may have implications for how ices are preserved in cometary nuclei. We demonstrate the superb synergy of coordinated radio and near-infrared measurements, and advocate for future small-body studies that jointly leverage the capabilities of each wavelength.

Keywords: High resolution spectroscopy, Centaur group, Comae, Molecular spectroscopy, Comets, Radio astronomy, Near infrared astronomy
A Spectroscopic Study of Mars-analog Materials with Amorphous Sulfate and Chloride Phases: Implications for Detecting Amorphous Materials on the Martian Surface. The Chemistry and Mineralogy X-ray diffraction (XRD) instrument aboard the Curiosity rover consistently identifies amorphous material at Gale Crater, which is compositionally variable, but often includes elevated sulfur and iron, suggesting that amorphous ferric sulfate (AFS) may be present. Understanding how desiccating ferric sulfate brines affect the spectra of Martian material analogs is necessary for interpreting complex/realistic reaction assemblages. Visible and near-infrared reflectance (VNIR), mid-infrared attenuated total reflectance (MIR, FTIR-ATR), and Raman spectra, along with XRD data are presented for basaltic glass, hematite, gypsum, nontronite, and magnesite, each at three grain sizes (&lt;25, 25-63, and 63-180 μm), mixed with ferric sulfate (+/-NaCl), deliquesced, then rapidly desiccated in 11% relative humidity or via vacuum. All desiccated products are partially or completely XRD amorphous; crystalline phases include starting materials and trace precipitates, leaving the bulk of the ferric sulfate in the amorphous fraction. Due to considerable spectral masking, AFS detectability is highly dependent on spectroscopic technique and minerals present. This has strong implications for remote and in situ observations of Martian samples that include an amorphous component. AFS is only identifiable in VNIR spectra for magnesite, nontronite, and gypsum samples; hematite and basaltic glass samples appear similar to pure materials. Sulfate features dominate Raman spectra for nontronite and basaltic glass samples; the analog material dominates Raman spectra of hematite and gypsum samples. MIR data are least affected by masking, but basaltic glass is almost undetectable in MIR spectra of those mixtures. NaCl produces similar FTIR-ATR and Raman features, regardless of analog material.

Keywords: Planetary geology, Surface processes, Planetary mineralogy, Spectroscopy, Planetary science, Vibrational spectroscopy
Nuclear and Orbital Characterization of the Transition Object (4015) 107P/Wilson-Harrington. Comet 107P/Wilson-Harrington, cross-listed as asteroid 4015, is one of the original transition objects whose properties do not neatly fit into a cometary or asteroidal origin. Discovered in a period of apparently gas-dominated activity in 1949, it was subsequently lost and recovered as the inactive asteroid 1979 VA. We obtained new and reanalyzed archival observations of the object, compared to meteorites, and conducted new orbital integrations in order to understand the nature of this object and to understand where it falls on the asteroid-comet continuum. Wilson-Harrington's reflectance spectrum is approximately neutral from visible to near-infrared wavelengths, but has a reflectance maximum near 0.8-0.9 μm. The object's spectrum is well matched by laboratory spectra of carbonaceous chondrite meteorites like the CM Murchison or the C I Ivuna. The object's phase curve slope is compatible with either an asteroidal or cometary origin, and its recent orbital history has no periods with high enough temperatures to have altered its surface. While it is possible that some unknown process has acted to change the surface from an originally cometary one, we instead prefer a fundamentally asteroidal origin for Wilson-Harrington, which can explain its surface and orbital properties. However, this would require a way to maintain significant (hyper)volatile supplies on the near-Earth objects beyond what is currently expected. Wilson-Harrington's similar meteorite affinity and possible orbital link to sample return targets (162173) Ryugu and (101955) Bennu suggest that the returned samples from the Hayabusa-2 and OSIRIS-REx missions might hold the key to understanding this object.

Keywords: Comets, Surface composition, Asteroids, Orbital evolution
Two Seismic Events from InSight Confirmed as New Impacts on Mars. We report confirmed impact sources for two seismic events on Mars detected by the NASA InSight mission. These events have been positively associated with fresh impact craters identified from orbital images, which match predicted locations and sizes to within a factor of 3, and have formation time constraints consistent with the seismic event dates. They are both of the very high frequency family of seismic events and are present with chirps (dispersed infrasound/acoustic waves). This brings the total number of confirmed Martian impact-related seismic events to eight thus far. All seismic events with chirp signals have now been confirmed as having been caused by impact cratering events. This includes all seismic activity within 100 km of the lander and two out of the four events with source locations between 100 and 300 km distance.

Keywords: Impact phenomena, Collisional processes, Mars, Planetary interior, Craters
The Properties and Origin of Kuiper Belt Object Arrokoth's Large Mounds. We report on a study of the mounds that dominate the appearance of Kuiper Belt Object (486958) Arrokoth's larger lobe, named Wenu. We compare the geological context of these mounds and measure and intercompare their shapes, sizes/orientations, reflectance, and colors. We find the mounds are broadly self-similar in many respects and interpret them as the original building blocks of Arrokoth. It remains unclear why these building blocks are so similar in size-and this represents a new constraint and challenge for solar system formation models. We then discuss the implications of this interpretation.

Keywords: Accretion, Kuiper belt, Classical Kuiper belt objects, Planetesimals, Trans-Neptunian objects
Grain Size Effects on UV-MIR (0.2-14 μm) Spectra of Carbonaceous Chondrite Groups. Carbonaceous chondrites are among the most important meteorite types and have played a vital role in deciphering the origin and evolution of our solar system. They have been linked to low-albedo C-type asteroids, but due to subdued absorption bands, definitive asteroid-meteorite linkages remain elusive. A majority of these existing linkages rely on fine-grained (typically &lt; 45 μm) powders across a limited wavelength range in the visible to near-infrared (0.35-2.5 μm). While this is useful in interpreting the fine-grained regolith of larger main-belt objects like Ceres, recent spacecraft missions to smaller near-Earth asteroids (NEAs), such as Bennu and Ryugu, have shown that their surfaces are dominated by larger grain size material. To better interpret the surfaces of these smaller, carbonaceous NEAs, we obtained laboratory reflectance spectra of seven carbonaceous chondrite meteorite groups (CI, CM, CO, CV, CR, CK, C2-ungrouped) over the ultraviolet to mid-infrared range (0.2-14 μm). Each meteorite contained five grain size bins (45-1000 μm) to help constrain spectral grain size effects. We find a correlation between grain size and absolute reflectance, spectral slope, band depth, and the Christiansen feature band center. Principal component analysis of grain size variation illustrates a similar trend to lunar-style space weathering. We also show that the Bus-DeMeo asteroid taxonomic classification of our samples is affected by grain size, specifically shifting CM2 Aguas Zarcas from a Ch-type to B-type with increasing grain size. This has implications for the parent body of the OSIRIS-REx target, Bennu. With Aguas Zarcas, we present results from Hapke modeling.

Keywords: Meteorite composition, Infrared spectroscopy, Asteroids, Carbonaceous chondrites, Ultraviolet spectroscopy, Spectroscopy, Meteorites
Vitreous Magnesium Sulfate Hydrate as a Potential Mechanism for Preservation of Microbial Viability on Europa. Europa's subsurface ocean is postulated to contain appreciable amounts of Mg2+ and ${{\mathrm{SO}}_{4}}^{2-}$ ions, among other species. Recent laboratory experiments have shown that when solutions containing these species freeze to Europa-relevant temperatures, they can form vitreous MgSO4 hydrate, which can remain stable at these temperatures. Since vitreous phases can protect cells from physical damage that can occur during crystallization, their presence on Europa could potentially preserve entrained microorganisms from the ocean below. However, to date, it remains unclear whether such materials actually impact microbial survival. In this work, experiments were performed in which the motile nonspore-forming Antarctic isolate Pseudoalteromonas haloplanktis in solutions of 0.1 M MgSO4 were frozen to Europa surface temperatures (100 K) under conditions that resulted in the formation of either vitreous or crystalline salt hydrates. We found that cells survived in both cases, exhibiting a 3-log reduction in viable cells in the crystalline salt hydrate case while only a 1.5-log reduction in the vitreous salt hydrate case. Scanning electron microscopy accordingly showed much higher degrees of membrane lysis and cellular damage in the crystalline salt hydrate than the vitreous case. Our results demonstrate the ability of a terrestrial oceanic microorganism to survive in MgSO4 solutions frozen to Europa surface temperatures, with enhanced viability in vitreous salt-hydrate-producing conditions versus crystalline. These findings suggest that future missions should target vitrified salt-rich environments for life detection due to this potential for preserving viable microorganisms that may be present and trapped in ocean world ices.

Keywords: Biosignatures, Astrobiology, Natural satellites (Solar system), Europa
Timing and Abundance of Clathrate Formation Control Ocean Evolution in Outer Solar System Bodies: Challenges of Maintaining a Thick Ocean within Pluto. Clathrate hydrates may represent a sizable fraction of material within the icy shells of Kuiper Belt objects and icy moons. They influence the chemical and thermal evolution of subsurface oceans by locking volatiles into the ice shell and by providing more thermal insulation than pure water ice. We model the formation of these crystalline compounds in conditions relevant to outer solar system objects, using Pluto as an example. Although Pluto may have hosted a thick ocean in its early history, Pluto's overall heat budget is probably insufficient to preserve liquid today if its outer shell is pure water ice. One previously proposed reconciliation is that Pluto's ocean has a winter jacket: an insulating layer of methane clathrate hydrates. Unfortunately, assessments of the timing, quantity, and type of clathrate hydrates forming within planetary bodies are lacking. Our work quantifies the abundance of clathrate-forming gases present in Pluto's ocean from accreted ices and volatiles released during thermal metamorphism throughout Pluto's history. We find that if Pluto formed with the same relative abundances of ices found in comets, then a buoyant layer of mixed methane and carbon dioxide clathrate hydrates may form above Pluto's ocean, though we find it insufficient to preserve a thick ocean today. In general, our study provides methodology for predicting clathrate formation in ocean worlds, which is necessary to predict the evolution of the ocean's composition and whether a liquid layer remains at present.

Keywords: Planetary interior, Chemical abundances, Planetary thermal histories, Pluto
Ejected Particles after Impact Splash on Mars: Aggregates and Aerodynamics. Our earlier laboratory measurements showed that low-velocity sand impacts release fine &lt;5 μm dust from a Martian simulant soil. This dust will become airborne in the Martian atmosphere. Here, we extend this study by measuring aerodynamic properties of ejecta and characterizing deviations from the behavior of spherical, monolithic grains. We observe the settling of particles emitted as part of an impact splash. The sizes (20 to 280 μm) and sedimentation velocities (0.1 to 0.8 m s-1) of the particles are deduced from high-speed videos while the particles sediment under low ambient pressure of about 1 mbar. The particles regularly settle slower than expected, down to a factor of about 0.3. Using optical microscopy, the shape of the captured particles is characterized by simple axis ratios (longest/smallest), which show that the vast majority of particles are irregular but typically not too elongated, with axis ratios below 2 on average. Electron microscopy further reveals that the particles are typically porous aggregates, which is the most likely reason for the reduction of the sedimentation velocity. Due to the reduced bulk density, aggregates up to 10 μm in diameter should regularly be a part of the dust in the Martian atmosphere.

Keywords: Mars, Planetary atmospheres
Salt Distribution from Freezing Intrusions in Ice Shells on Ocean Worlds: Application to Europa. Several icy moons and dwarf planets appear to have hosted subsurface liquid water. Liquid water intruding upwards into the icy outer shells of these worlds freezes, forming ice and (from ocean solutes) non-ice solids. Here, we model concentrated aqueous solutions below 273 K to simulate the compositional evolution of freezing spherical intrusions. Starting solutions are based on five previously reported compositional end members for Europa's ocean. For moderate-pH end members dominated by chloride, sulfate, and/or carbonate, the solids formed include Ca-, Mg-, and Na-sulfates and -carbonates, as well as Na- and K-chlorides. For silica-rich, high-pH end members, abundant amorphous silica forms with, potentially, similarly abundant NaOH and KOH. We further develop a new numerical model to compute the spatial distribution of the formed solids and residual brine as freezing progresses. If non-ice solids settle to the bottom, their deposits tend to have stacked hourglass shapes, widening each time the crystallization temperature of a new solid is reached. We discuss the applicability of this model to vertical fractures and global freezing of a subsurface ocean. These results inform (i) how compositional heterogeneities may affect the thermophysical properties of ice shells, which in turn influence convective and cryovolcanic transport, (ii) the compatibility of brine pockets with physicochemical conditions suitable for microbial life, and (iii) possible measurements of compositional heterogeneities within ice shells by spacecraft such as NASA's Europa Clipper and ESA's JUICE missions. The methodology developed here is applicable to other ice-covered ocean worlds.

Keywords: Hydrosphere, Ganymede, Planetary mineralogy, Europa, Geological processes, Ceres, Planetary interior, Planetary structure, Natural satellite evolution
Evidence for Fine-grained Material at Lunar Red Spots: Insights from Thermal Infrared and Radar Data Sets. Lunar red spots are small spectrally red features that have been proposed to be the result of non-mare volcanism. Studies have shown that a number of red spots are silicic, and are spectrally distinct from both highlands and mare compositions. In this work, we use data from LRO Diviner, Mini-RF, and Arecibo to investigate the material properties of 10 red spots. We create albedo maps using Diviner daytime solar reflectance data to use as an input to our improved thermophysical model, and calculate the rock abundance (RA) and H-parameter values that best fit Diviner nighttime thermal infrared radiance measurements. The H-parameter can be considered analogous to the thermal inertia of the regolith, with a high H-parameter corresponding to low thermal inertia. We find that the red spots generally have low RA, and do not have a uniform H-parameter but contain localized regions of high H-parameter. We additionally find that the red spots have a low circular polarization ratio (CPR) in many of the same locations that show a low RA and high H-parameter. Low RA, high H-parameter, and low CPR indicate a relative lack of rocks larger than ~10 cm, which is consistent with previous findings of a mantling of fine-grained pyroclastic material for at least three red spots. Areas with high H-parameter but that do not show clear signs of pyroclastics in other data sets may be evidence of previously undiscovered pyroclastics, or could be due to the unique physical properties (e.g., porosity, rock strength/breakdown resistance) of the rocks that make up the red spots.

Keywords: Lunar regolith, Lunar science, Lunar surface, Lunar domes, Remote sensing, Radar observations
A New View of the Lunar South Pole from the Lunar Orbiter Laser Altimeter (LOLA). Upcoming missions to the lunar south pole require detailed maps over large areas to fully characterize landing sites locally and regionally and to place their data into proper geologic context. To that end, we enhanced the Lunar Orbiter Laser Altimeter altimetry data set for the south polar region, from which we produced new maps of topography, topographic roughness, and permanently shadowed regions (PSRs). The roughness maps reveal a diversity of terrains characterized by hectometer-scale roughness that is controlled in this region primarily by cratering and downslope mass transport. The south polar region is littered with linear roughness features of order ~1-10 km wide and approximately tens to hundreds of kilometers long hypothesized to be secondary impacts within extended ejecta rays. Nonuniformities in these features could reflect variations in secondary impactor properties and/or target terrain properties. Poleward of 80° S, the PSR cumulative size-frequency distribution (CSFD) shows an approximately power-law behavior whose exponent has a spatial variation of ~10%. PSRs with areas &lt;1 km2 contain 15% ± 5% of the total PSR area. Finally, we studied the effect of false positives and false negatives on the accuracy of the measured PSR CSFD and on the area for any individual PSR. The new maps presented here have many applications in the science and exploration of the lunar south polar region, such as geologic mapping and traverse planning.

Keywords: Lunar craters, Lunar geodesy, Lunar regolith, Lunar science, Lunar impacts, Lunar surface, Lunar features
Outgassing Composition of the Murchison Meteorite: Implications for Volatile Depletion of Planetesimals and Interior-atmosphere Connections for Terrestrial Exoplanets. Outgassing is a central process during the formation and evolution of terrestrial planets and their atmospheres both within and beyond the solar system. Although terrestrial planets' early atmospheres likely form via outgassing during planetary accretion, the connection between a planet's bulk composition and its initial atmospheric properties is not well understood. One way to inform this connection is to analyze the outgassing compositions of meteorites, and in particular carbonaceous chondrites, because they are some of the most volatile-rich, primitive materials (in terms of their bulk compositions) that are available for direct study. In addition, they may serve as compositional analogs for the building block materials of terrestrial planets in our solar system and around other Sun-like stars. This study builds upon previous outgassing experiments that monitored the abundances of volatile species (e.g., H2O, CO, and CO2) released from the Murchison meteorite. To gain a more complete understanding of Murchison's outgassing composition, we perform a series of heating experiments under atmospheric pressure (1 bar) and vacuum (∼10‑9 bar) conditions on samples of the Murchison meteorite and subsequent bulk element analysis to inform the outgassing trends of a suite of major elements in Murchison (e.g., Fe, Mg, Zn, and S). Under both pressure conditions, sulfur outgases significantly at the highest temperatures (∼800°C–1000 °C). For the samples heated under vacuum conditions, we also detect outgassing of zinc. Combined with prior outgassing experiments, this study provides important insights into the volatile depletion patterns of undifferentiated planetesimals and the early outgassing compositions of terrestrial exoplanets.

Keywords: Exoplanet atmospheric composition , Planetary atmospheres, Meteorite composition, Planetesimals
Fitting the Light Curve of 1I/'Oumuamua with a Nonprincipal Axis Rotational Model and Outgassing Torques. In this paper, we investigate the nonprincipal axis (NPA) rotational state of 1I/'Oumuamua-the first interstellar object discovered traversing the inner solar system-from its photometric light curve. Building upon Mashchenko, we develop a model which incorporates NPA rotation and Sun-induced, time-varying outgassing torques to generate synthetic light curves of the object. The model neglects tidal forces, which are negligible compared to outgassing torques over the distances at which 'Oumuamua was observed. We implement an optimization scheme that incorporates the NPA rotation model to calculate the initial rotation state of the object. We find that an NPA rotation state with an average period of &lt;P&gt; ≃ 7.34 hr best reproduces the photometric data. The discrepancy between this period and previous estimates is due to continuous period modulation induced by outgassing torques in the rotational model, as well as different periods being used. The best fit to the 2017 October data does not reproduce the 2017 November data (although the later measurements are too sparse to fit). The light curve is consistent with there being no secular evolution of the angular momentum, which is somewhat in tension with the empirical correlations between nuclear spin-up and cometary outgassing. The complex rotation of 'Oumuamua may be the result of primordial rotation about the smallest principal axis if (i) the object experienced hypervolatile outgassing and (ii) our idealized outgassing model is accurate.

Keywords: Small Solar System bodies, Light curves, Interstellar objects