Samantha912/NLP_A2_WTH huggingface dataset:
The Blaise ketone synthesis (named after Edmond Blaise) is the chemical reaction of acid chlorides with organozinc compounds to give ketones.

The reaction was claimed to bring excellent yields by Blaise, however, investigators failed to obtain better than moderate yields (50%). Thus, the reaction is particularly ineffective in forming ketones from acyl chlorides. The reaction also works with organocuprates. Reviews have been written.

Reaction mechanism
The mechanism is sampled from the proposed mechanism for organocadmium compounds, given that the mechanisms are identical to one another the proposed mechanism for the reaction is the same as the one for organocadmium compounds.

After the oxygen forms a bond with the organozinc compound, R’ shifts to the carbonyl carbon, having chlorine act as a leaving group and removing the negative charge from zinc. The chlorine that left returns to form a bond with zinc, pushing the electrons back on to oxygen and thus forming the ketone.

Variations

Blaise-Maire reaction
The Blaise-Maire reaction is the Blaise ketone synthesis using β-hydroxy acid chlorides to give β-hydroxyketones, which are converted into α,β-unsaturated ketones using sulfuric acid.

Ketone formation from organocadmium compounds
This ketone formation is an identical reaction to the Blaise ketone synthesis. Only instead of organozinc compounds, organocadmium compounds are used and produce higher yields.

See also
Blaise reaction
Negishi coupling

References

  
  
  
  
  
  
  
  
  

Addition reactions
Carbon-carbon bond forming reactions
Name reactions
Organometallic compounds
Seth Millington Hays (April 23, 1811 – February 3, 1873) was the first white settler and a civic leader in Council Grove, Kansas.

Life 
Hays was born in Callaway County, Missouri, and moved to Kansas in 1847 to open a trading post on the Santa Fe Trail. While he originally worked for the mercantile company Boone & Hamilton, he owned his store outright by the early 1850s. The flood of trail travelers brought by the 1858 Pike's Peak Gold Rush both enriched Hays and spurred settlement in Council Grove, which was incorporated the same year. In 1859, Hays and business partner G. M. Simcock opened a new two-story store and restaurant in Council Grove under the name S. M. Hays & Co.

Hays moved to Colorado in 1862, selling his store to Simcock, but he returned to Council Grove in 1865. He took over his 1859 store from Simcock the next year. In 1970, Hays founded a newspaper, the Council Grove Democrat, and the Council Grove Savings Bank, the town's first.

Hays enslaved a woman named Sarah Taylor, nicknamed Aunt Sally, while living in Missouri. As the Kansas Territory still allowed slavery at the time, Hays brought Taylor with him to Kansas, where she remained a slave. After Kansas gained statehood and abolished slavery in 1861, Taylor stayed with Hays as a housekeeper. Also in 1861, Taylor and Hays began caring for the infant Kittie Parker Robbins, whose mother had died in childbirth while her father was delivering mail on the route through Council Grove. Hays formally adopted Robbins in 1867 with her biological father's consent.

Hays died in 1873, one year after Taylor; they are both buried in the same plot of Council Grove's Greenwood Cemetery. The S. M. Hays & Co. store is still in operation as a restaurant under the name Hays House; it bills itself as "the oldest continuously operating restaurant west of the Mississippi River". Hays' 1867 residence in Council Grove is now a county history museum and is listed on the National Register of Historic Places.

References

1811 births
1873 deaths
People from Council Grove, Kansas
People from Callaway County, Missouri
Businesspeople from Kansas
Editors of Kansas newspapers
Pain Management is the fourth album by the American rapper Bubba Sparxxx. It was released on October 15, 2013, by Average Joes Entertainment and Backroad Records. It was his first album in seven years and has guest appearances by Colt Ford, Rodney Atkins, Danny Boone, Dan Rockett, Crucifix, Dirt Reynolds, Daniel Lee and The Lacs.

Track listing

Chart performance

References

2013 albums
Bubba Sparxxx albums
Average Joes Entertainment albums
Philip Conroy O'Donnell (July 29, 1915 – November 23, 1986) was an American politician who served as mayor of Peabody, Massachusetts from 1952 to 1962 and was a member of the Massachusetts House of Representatives from 1967 to 1971.

Early life
O'Donnell was born on July 29, 1915, in Peabody. He graduated from Peabody High School and was a leather worker until he entered the United States Army during World War II. He was a technical sergeant in the Army Air Corps and served in Europe for 28 months. After the war he graduated Suffolk Law School and worked for the state airport management board.

Politics
O'Donnell was a member of the Peabody city council from 1947 to 1951. In 1951 he defeated incumbent Leo F. McGrath to become mayor of Peabody. During his decade as mayor, O'Donnell presided over a building boom that saw development of West Peabody and the North Shore Shopping Center, the construction of Leo Buckley Stadium, three new schools, three housing projects, two new fire stations, municipal parking lots, and little league fields, a $1 million addition to J. B. Thomas Hospital, and water rehabilitation, street paving, and sidewalk projects. He was not a candidate for reelection in 1961, but allowed his supporters to run a write-in campaign for him that saw him finish fourth out of eight candidates.

O'Donnell was chairman of the Massachusetts Alcoholic Beverage Commission from 1959 to 1962. In 1962 he was an unsuccessful candidate for the Democratic nomination for the Massachusetts's 6th congressional district in the United States House of Representatives. From 1967 to 1971 he represented the 5th Essex District in the Massachusetts House of Representatives. He later served as clerk of the House Rules Committee.

Personal life
Outside of politics, O'Donnell also served as the director of the Lowe Mart Shopping Center in West Peabody. He was the father of two children. In 1982 his son was convicted of attempting to bribe a Danvers, Massachusetts selectman. O'Donnell died on November 23, 1986, after a short illness.

References

1915 births
1986 deaths
Mayors of Peabody, Massachusetts
Democratic Party members of the Massachusetts House of Representatives
Suffolk University Law School alumni
United States Army Air Forces personnel of World War II
Jaynul Islam (born 1992) is a Bangladeshi cricketer. He made his List A debut for Partex Sporting Club in the 2016–17 Dhaka Premier Division Cricket League on 1 June 2017. He made his Twenty20 debut on 31 May 2021, for Partex Sporting Club in the 2021 Dhaka Premier Division Twenty20 Cricket League. He made his first-class debut on 21 November 2021, for Sylhet Division in the 2021–22 National Cricket League.

References

External links
 

1992 births
Living people
Bangladeshi cricketers
Partex Sporting Club cricketers
Sylhet Division cricketers
Place of birth missing (living people)
Ratemo Michieka is a former director-general of the National Environmental Management Authority (NEMA) in Kenya; he is also  the founding Vice-Chancellor of Jomo Kenyatta University of Agriculture and Technology.

For a long time, Michieka worked in education and agricultural policy in Eastern Africa. He earned a doctorate in weed science from Rutgers University. He returned to his native Kenya, where he taught and later became chairman of the Department of Crop Science at the University of Nairobi. In 1994, he was named vice chancellor of Jomo Kenyatta University of Agriculture and Technology in Nairobi, Kenya, a post equivalent to a U.S. university president. He held the post until he was appointed Director General of the National Environmental Management Authority.

Politics
In 2008 Ratemo Michieka ran for the parliamentary seat of Nyaribari Masaba. He came in third behind Prof. Sam Ongeri and Dr. Hezron Manduku.

References

3. Rutgers university hall of distinguished alumni 

4. Kyoto protocol compliance committee 

Kenyan educators
People from Nairobi
Year of birth missing (living people)
Living people
"Middle Ground" is a song by American pop rock band Maroon 5. It was released as a single through 222, Interscope, and Polydor Records on May 19, 2023.

The remix, a collaboration with American country singer Mickey Guyton, was released on August 11, 2023.

Background
In a March 2023 interview with Ryan Seacrest on On Air with Ryan Seacrest, Adam Levine revealed that new music was to be released within the year. "We are working on something that is unbelievably cool [...] I'm very excited about this thing," he said to Seacrest. On May 11, 2023, the band announced on social media that "Middle Ground" would be released on May 19, 2023.

Composition
A pop and soft rock song, "Middle Ground" was written by Adam Levine, Andrew Watt, Gregory Heinn, Jon Bellion, Marvin Hemmings, Pete Nappi, and Rodney "Darkchild" Jerkins and was produced by Andrew Watt, Jon Bellion, and Pete Nappi.

Music video
The music video for "Middle Ground" was released on May 23, 2023. It was directed by David Dobkin, who has also directed videos for Maroon 5 in the past such as "Sugar", "Girls Like You", and "Memories". The video features appearances from Adam Levine's wife Behati Prinsloo, and their two children, Dusty Rose and Gio Grace Levine, as well as members of the band performing the song in an indoor studio and having an outdoor gathering.

Live performances
On May 23, 2023, Maroon 5 debuted "Middle Ground" live on the season 23 finale of the American reality television series The Voice. It was the group's first performance on the show since performing "Beautiful Mistakes" on the season 20 finale in May 2021. On August 12, 2023, Maroon 5 performing the song with special guest, Mickey Guyton on the final night of Maroon 5: The Las Vegas Residency.

Critical reception
Billboard described "Middle Ground" as a "return to form", reminiscent to Maroon 5's debut studio album, Songs About Jane (2002).

Track listing 

Digital download
 "Middle Ground" – 3:39

Digital download – Remix
 "Middle Ground" (featuring Mickey Guyton) – 3:39

Charts

Release history

References

2023 singles
2023 songs
222 Records singles
Interscope Records singles
Maroon 5 songs
Music videos directed by David Dobkin
Polydor Records singles
Pop ballads
Sir Jan Alfred Lewando   (31 May 1909 – 2 July 2004) was a British businessman who was chairman of Carrington Viyella, and a former director of M&S.

Lewando was born into the Polish Ashkenazi community in Manchester, which included Marks and Spencer's founding families. His father who was a gifted tenor had left Poland for Ireland during the pogroms.

Lewando was knighted In the 1974 New Year Honours.

Personal life
In 1948, he married Nora Slavouski and they had three daughters.

He died on 2 July 2004, aged 95.

References

1909 births
2004 deaths
Knights Bachelor
Businesspeople awarded knighthoods
English Jews
British people of Polish-Jewish descent
20th-century English businesspeople
The following outline is provided as an overview of and topical guide to academia:

Academia – nationally and internationally recognized establishment of professional scholars and students, working for the most part in colleges and universities, who are engaged in higher education and research.

Purposes of academia 

 Higher education
 Research

Branches of academia 

 Academic disciplines
 Doctoral studies

History of academia 

 History of academia

Academic positions 
 Academic administration
 Academic ranks
 Professor
 Tenure

Academic communication 
 Academic conference
 Academic publishing
 Academic journal
 Academic article
 Academic literature
 Academic writing
 Peer review
 Scholarly communication
 Journal ranking

Academic culture 
 Academic acceleration
 Academic dishonesty (Scientific misconduct)
 Academic discipline  (Scientific community)
 Academic degree
 Academic dress
 Academic inflation
 Academic mobility
 Bullying in academia
 Ivory tower
 Town and gown
 Scholarly method (Scientific method)

See also 
 Outline of education
 Outline of knowledge

References

External links 

 Academia.edu - Online community of academic scholars
  - Community Contributor of academic Harvard
 Academia and web 2.0
 An Academic costume code and an Academic ceremony guide
 Bibliography on the history of the university , provided by Palinurus: The Academy and the Corporation, a web site from the University of California, Santa Barbara
 'Magistri et Scholares' - Academic News and Resources

 
Academia
Academia
Jesús Suárez (9 January 1912 – 27 December 1997) was a Spanish cross-country skier. He competed in the men's 18 kilometre event at the 1936 Winter Olympics.

References

1912 births
1997 deaths
Spanish male cross-country skiers
Olympic cross-country skiers for Spain
Cross-country skiers at the 1936 Winter Olympics
Sportspeople from Gijón
Jacques-Louis Potgieter (born 2 September 1984 in Pretoria) is a South African rugby union player, currently playing with French side . His regular position is fly-half.

Career
He made his Super 14 debut for the  against the  in 2007. In 2008 and 2009 he joined the , but was reunited with his  team-mates in 2010.  For the 2011 season, he joined the .

France
In January 2012, he signed for French Top 14 side Bayonne as a medical joker for the 2011–12 Top 14 season, then signed a one-year full-time contract for the 2012–13 Top 14 season.

Prior to the 2013–14 Rugby Pro D2 season, he joined Dax on a two-year deal, but gained an early release from this contract at the start of 2014.

Return to South Africa
He then returned to the  prior to the 2014 Super Rugby season on a two-year contract, which he then extended until October 2016.

Return to France

Potgieter left the Blue Bulls after the 2015 Super Rugby season, joining French Top 14 side . After two seasons at Lyon, he joined their compatriots  on a three-year deal.

Education
Potgieter attended Afrikaanse Hoër Seunskool (Afrikaans High School for Boys, also known as Affies), a public school located in Pretoria. He attended alongside former Bulls teammates Fourie du Preez, Wynand Olivier, Pierre Spies and Derick Kuun,  lock Adriaan Fondse, former Stade Français lock Cliff Milton and Titans cricketers AB de Villiers, Heino Kuhn and Faf du Plessis.

References

South African rugby union players
Living people
Afrikaner people
South African people of Dutch descent
1984 births
Rugby union players from Pretoria
Bulls (rugby union) players
Blue Bulls players
Cheetahs (rugby union) players
Free State Cheetahs players
Griffons (rugby union) players
Sharks (rugby union) players
Sharks (Currie Cup) players
Aviron Bayonnais players
Rugby union fly-halves
Expatriate rugby union players in France
South African expatriate sportspeople in France
South African expatriate rugby union players
Io tu noi tutti (Me, you, all of us) is the tenth album by the Italian singer and songwriter Lucio Battisti. It was released in March 1977 by Numero Uno.

Recorded in Hollywood, the album was Italy's second best selling album in 1977.

Charts

Track listing 
All lyrics written by Mogol, all music composed by Lucio Battisti.
 "Amarsi un po'" (To Feel in Love) – 5:07
 "L'interprete di un film" (Star in a Film) – 4:28
 "Soli" (Lonely) – 4:18
 "Ami ancora Elisa" (You're Still in Love with Elisa) – 6:41
 "Sì, viaggiare" (Keep on Cruising) – 6:07
 "Questione di cellule" (Matter of Cells) – 4:16
 "Ho un anno di più" (The Only Thing I've Lost) – 5:04
 "Neanche un minuto di 'non amore'" (There's Never Been a Moment) – 5:20

References

1977 albums
Lucio Battisti albums
Albums produced by Bones Howe
Daniel Earl Noble (October 4, 1901 – February 16, 1980) 
was an American engineer, and executive vice chairman of the board of Motorola, 
who is known for the design and installation of the nation's first statewide two-way FM radio 
communications system for the Connecticut State Police.

He received a BS degree in engineering from the University of Connecticut.

He joined Motorola as director of research in 1940. His Link SCR-300 backpack transmitter and receiver, which he had reduced to about forty pounds, provided the first practical FM band transmission for military use.  Introduced in 1943, and first used at the Battle of Anzio, the portable FM field radio allowed communication with less interference than the AM "walkie-talkie" systems that had been used earlier in World War II.

In 1949 he set up a solid state electronics research laboratory for Motorola in Phoenix, Arizona, which ultimately became the headquarters of the Semiconductor Products Sector of Motorola, and ultimately Freescale Semiconductor as it separated from Motorola.

The IEEE Daniel E. Noble Award (previously named the IEEE Morris N. Liebmann Memorial Award) was established by the IEEE in 2000 for outstanding contributions to emerging technologies recognized within recent years.

Honors and awards
 IEEE Edison Medal in 1978
 member, National Academy of Engineering
 Fellow, IEEE
 Fellow, Franklin Institute
 Stuart Ballantine Medal in 1972

US patents
, 1952
, 1951
, 1951
, 1950
, 1949
, 1948
, 1944
, 1937

Further reading

Daniel Noble's contributions to Motorola are examined in Gart, Jason H. "Electronics and Aerospace Industry in Cold War Arizona, 1945-1968: Motorola, Hughes Aircraft, Goodyear Aircraft." Phd diss., Arizona State University, 2006.

References

External links
 IEEE Daniel E. Noble Award
 Arcane Radio Trivia biography of
 Daniel E. Noble Science and Engineering Library

1901 births
Fellow Members of the IEEE
IEEE Edison Medal recipients
Motorola employees
Members of the United States National Academy of Engineering
1980 deaths
People from Naugatuck, Connecticut
American telecommunications engineers
Ida Caroline Gandy, née Hony (1885–1977), was an English social worker and author. She wrote children's books, plays, and books about rural life in Wiltshire and Shropshire.

Life
Ida Hony was born in 1885 in Bishops Cannings, Wiltshire, where her father, the Rev. Charles William Hony, was the vicar. Annie Elizabeth Lewin, her "somewhat unconventional" mother, was a writer. Hony moved to London to take up social work, working for the Workers' Educational Association. After moving to Peppard in Oxfordshire, she married the local GP, Thomas Gandy, in 1915. The couple had three children: the diplomat Christopher Gandy, the mathematician Robin Gandy and the physician Gillian Gandy. 

Ida Gandy wrote stage plays for the local amateur drama group, and published her first non-fiction book, A Wiltshire Childhood, in 1930. In 1930 she persuaded her husband to move to Clunbury in Shropshire. She was active in the local Women's Institute, and during World War II was the Billeting Officer for the Clun Valley. On her husband's retirement in 1945 the couple moved to Dorset. He died in 1948, and after his death Gandy returned to Wiltshire, settling in Aldbourne.

She died in September 1977, and is buried in the churchyard of the Church of St Michael, Aldbourne.

Works
 The deer stealers: a village play in three acts. London: Village Drama Society.
 The gipsy Countess : a play founded on the old folk-song "The wraggle-taggle gipsies". Kelly: Village Drama Society, 1924.
 Snowdrop and the dwarfs: a fairy play. London: Gowans & Gray, 1925.
 The fairy fruit: a play for children. London: Gowans & Gray, 1927.
 Three bold explorers : a story for children. London: Jarrolds, 1927.
 A good shepherd: a one-act play. London: Joseph Williams, 1927.
 Lardy cake: a comedy for village players. London: H. F. W. Deane, 1928.
 The stranger: a comedy in one act. London: H. F. W. Deane & Sons, 1929.
 Sunset Island. London: Oxford University Press, 1929. Illustrated by Frank Adams.
 A Wiltshire childhood. London: Allen & Unwin, 1929.
 When the queen passed by : an outdoor play in three scenes. London: H. F. W. Deane & Sons, 1932.
 The musical-box : a fantasy in one act. London: H. F. W. Deane & Sons, 1933.
 He boxed her ears: a farce in rhyme. London: H. F. W. Deane & Sons, 1938.
 Under the chestnut tree. London, Country Life Ltd., 1938. Illustrated by Clifford Webb.
 Come to the fair: a comedy in one act. London: H. F. W. Deane & Sons, 1939.
 Round about the little steeple; the story of a downland village and its parson in the seventeenth century.  London: G. Allen & Unwin, 1960.
 Staying with the aunts. London: Harvill Press, 1963.
 An idler on the Shropshire borders. Shrewsbury: Wilding, 1970.
 The heart of a village : an intimate history of Aldbourne. Bradford-on-Avon: Moonraker Press, 1975.

References

1885 births
1977 deaths
English social workers
English local historians
English children's writers
Ida
Villu Kangur (born 27 November 1957 in Pärnu) is an Estonian actor, poet, translator and scenarist.

1982-1992 he worked at Estonian State Youth Theatre. 1993-2002 he was an editor at the newspaper Eesti Ekspress.

He has written song texts, libretos and screenwritings for musicals, operas and films.

In 2018 he was awarded with Order of the White Star, V class.

Filmography
 1993 "Salmonid" (television series; scenarist)
 2005 "Hajameelselt abielus" (television series; scenarist)	
 2010, 2019 "ENSV" (television series; scenarist; role: doctor)
 2014 "A ja B" (television series; scenarist) 	
 2015 "Mustad lesed" (television series; role )
 2018 "Põrgu Jaan" (feature film; role: Jakub)

References

Living people
1957 births
Estonian male television actors
Estonian male film actors
Estonian male stage actors
20th-century Estonian male actors
21st-century Estonian male actors
Estonian screenwriters
Estonian translators
Estonian songwriters
Estonian male poets
20th-century Estonian poets
21st-century Estonian poets
Recipients of the Order of the White Star, 5th Class
People from Pärnu
The Shirley Scott Trio (also referred to as Moodsville Volume 5) is an album by organist Shirley Scott recorded in 1960 and released on the Moodsville label. The album features a trio session from 1958 with Scott overdubbed on piano from the sessions that produced Scottie and another from 1960.

Reception
The Allmusic review stated "These are mostly easygoing standards of the Rodgers-Hart variety (two of that team's songs are covered), and is too much on the sedate side to rate as one of her finest efforts".

Track listing 
 "Sweet Lorraine" (Cliff Burwell, Mitchell Parish) - 4:31   
 "I Thought I'd Let You Know" (Cal Massey) - 4:20   
 "I Should Care" (Sammy Cahn, Axel Stordahl, Paul Weston) - 4:48   
 "Spring Is Here" (Lorenz Hart, Richard Rodgers) - 4:45   
 "I Didn't Know What Time It Was" (Hart, Rodgers) - 3:57   
 "Gee, Baby, Ain't I Good to You" (Andy Razaf, Don Redman) - 4:15   
 "Until the Real Thing Comes Along" (Sammy Cahn, Saul Chaplin, L. E. Freeman) - 5:09   
 "Lover Man" (Jimmy Davis, Roger "Ram" Ramirez, Jimmy Sherman) - 3:48
Recorded at Van Gelder Studio in Hackensack, New Jersey on October 23, 1958 (tracks 1, 3, 6 & 7) and in Englewood Cliffs, New Jersey on April 8, 1960  (tracks 2, 4, 5 & 8)

Personnel 
 Shirley Scott - organ
 George Duvivier (tracks 1, 3, 6 & 7), George Tucker (tracks 2, 4, 5 & 8) - bass
 Arthur Edgehill - drums

References 

1960 albums
Albums produced by Esmond Edwards
Albums recorded at Van Gelder Studio
Moodsville Records albums
Shirley Scott albums