Samantha912/NLP_A2_WTH huggingface dataset:
Pauli is a lunar impact crater that is located on the Moon's far side. It lies about halfway  between the lunar equator and southern pole, across the southern rim of the larger walled plain Roche.

This crater has a well-defined outer rim that is only mildly worn by impact erosion. A small crater lies on the inner side along the south, and another on the opposite face of the crater to the north. There is some slight terracing along the southeast inner wall, but the remainder displays more of a radially grooved appearance. The inner wall is narrower along the northern side where it overlies Roche.

The interior floor has been flooded with lava, leaving a low-albedo surface that is darker than the surrounding terrain. In this respect it is similar to the crater Jules Verne located about four crater diameters to the northeast. There is a low ridge structure near the midpoint, and the remains of a ghost crater in the southeastern part of the floor.

Satellite craters
By convention these features are identified on lunar maps by placing the letter on the side of the crater midpoint that is closest to Pauli.

References

 
 
 
 
 
 
 
 
 
 
 
 

impact craters on the Moon
Pope Clement XII (r. 1730–1740) created 35 cardinals in 15 consistories.

August 14, 1730

 Neri Maria Corsini

October 2, 1730

 Alessandro Aldobrandini
 Girolamo Grimaldi
 Bartolomeo Massei
 Bartolomeo Ruspoli

September 24, 1731

 Vincenzo Bichi
 Sinibaldo Doria
 Giuseppe Firrao
 Antonio Saverio Gentili
 Giovanni Antonio Guadagni

October 1, 1732

 Troiano Acquaviva d'Aragona
 Agapito Mosca

March 2, 1733

 Domenico Riviera

September 28, 1733

 Marcello Passeri
 Giovanni Battista Spínola

March 24, 1734

 Pompeio Aldrovandi
 Serafino Cenci
 Pietro Maria Pieri
 Giacomo Lanfredini

January 17, 1735

 Giuseppe Spinelli

December 19, 1735

 Infante Luis, Count of Chinchón

December 20, 1737

 Tomás de Almeida
 Henri-Osvald de la Tour d'Auvergne de Bouillon
 Joseph Dominicus von Lamberg
 Gaspar de Molina y Oviedo
 Jan Aleksander Lipski
 Rainiero d'Elci
 Carlo Rezzonico

June 23, 1738

 Domenico Silvio Passionei

December 19, 1738

 Silvio Valenti Gonzaga

February 23, 1739

 Carlo Gaetano Stampa
 Pierre Guérin de Tencin

June 15, 1739

 Marcellino Corio

September 30, 1739

 Prospero Colonna di Sciarra
 Carlo Maria Sacripante

References

Clement XII
College of Cardinals
18th-century Catholicism
Rheingans is a surname. Notable people with the surname include:

 Brad Rheingans (born 1953), American wrestler
 Gustave Rheingans (1890–1951), American politician and farmer
 Penny Rheingans, American computer scientist
 Rowan Rheingans, English folk musician
SSZ-13 (framework type code CHA) is a high-silica aluminosilicate zeolite possessing 0.38 × 0.38 nm micropores. It belongs to the ABC-6 family of zeolites as well as offretite, cancrinite, erionite and other related small-pore zeolites. The framework topology is the same as that of chabazite but SSZ-13 has a high silica composition with Si/Al > 5, which leads to low cation exchange capacity. The typical chemical formula of the unit cell can be described as  QxNayAl2.4Si33.6O72•zH2O (1.4 < x <27)(0.7 < y < 4.3)(1 < z <7), where Q is N,N,N-1-trimethyladamantammonium.  The material was patented  by Chevron research Company in 1985, and could potentially be used as a solid catalyst for the methanol-to-olefins (MTO) process and the selective catalytic reduction (SCR) of NOx.

Structure
SSZ-13 corresponds to an isomorphous replacement of a aluminum atom with a silicon atom in the natural mineral chabazite. Although chabazite exists as a twin crystal, SSZ-13 is exclusively monocrystalline. Generally, zeolites corresponding to isomorphous replacement of chabazite are collectively called CHA-type zeolites. Lattice constants vary depending on the Si/Al ratio and the metal species contained, but the symmetry of the crystal remains basically the same.

The CHA framework, which is represented by connecting Si or Al atoms, is shown in the figure on the right and consists of only 4-, 6-, and 8-membered rings, with no 5-membered rings as found in ZSM-5 and mordenite. It is also characterized by a double six-membered ring structure (D6R) consisting of two six-membered rings and six four-membered rings.

The pore size of the zeolite is 0.38 nm when the size of the oxygen atoms is estimated by the ionic radius (0.135 nm), classifying it as a small pore zeolite. It can adsorb small gas molecules, but large organic molecules cannot enter the pores.

Another known rhyolite isotypic replacement is SAPO-34, a silicoaluminophosphate.

Synthesis
SSZ-13 can be synthesized using the following method.  The material is prepared from the following batch composition:

10 Na2O : 2.5 Al2O3 : 100 SiO2 : 4400 H2O : 20 TMAdOH.

2 g 1N NaOH, 2,78 g 0.72 M N,N,N-1-trimethyladamantammonium hydroxide (TMAdOH) and
3.22 g deionized water are mixed. 0,1 g Al2O3 is added to the solution and mixed with 0.6 g fumed silica. The resulting viscous gel is aged for two hours and heated for 4 days at 160 °C in a Teflon lined steel autoclave. The crystallized product can be recovered by filtration. 

Submicron-sized SSZ-13 can be prepared in 6 hours through a rapid steam-assisted crystallization method using tetraethyl orthosilicate (TEOS) as the silica source.

Uses
SSZ-13 is a high-silica zeolite with the CHA topology. Materials with this topology are of industrial interest, as potential catalysts for application in the methanol to olefins (MTO) reaction.

Recently SSZ-13 has attracted attention as the catalyst for selective catalytic reduction (SCR) of NOx. Actually copper-loading SSZ-13 is industrially applied to the emission control of diesel engines.

See also
Chabazite
Zeolite

References 

Zeolites
Diamant is an Ashkenazi Jewish occupational name, meaning diamond.

People with the name
 Alfred Diamant (1917–2012), American political scientist
 André Diamant (born 1990), Brazilian chess player
 Anita Diamant (born 1951), American author
 Dora Diamant (1898–1952), Polish teacher and actress associated with Franz Kafka
 Henri Diamant-Berger (1895–1972), French filmmaker
 Illana Diamant (born 1961), Israeli actress and activist
 József Diamant (1892–1975), Hungarian-born writer, also known as Joseph Bard
 Liron Diamant (born 1990), Israeli footballer
 Ruth Witt-Diamant (fl. 1931–1954), American poet and educator

See also
 Diamant (disambiguation)

References

German-language surnames
Jewish surnames
Yiddish-language surnames
In geometry, a spherical wedge or ungula is a portion of a ball  bounded by two plane semidisks and a spherical lune (termed the wedge's base). The angle between the radii lying within the bounding semidisks is the dihedral . If  is a semidisk that forms a ball when completely revolved about the z-axis, revolving  only through a given  produces a spherical wedge of the same angle . Beman (2008) remarks that "a spherical wedge is to the sphere of which it is a part as the angle of the wedge is to a perigon."   A spherical wedge of  radians (180°) is called a hemisphere, while a spherical wedge of  radians (360°) constitutes a complete ball.

The volume of a spherical wedge can be intuitively related to the  definition in that while the volume of a ball of radius  is given by , the volume a spherical wedge of the same radius  is given by

Extrapolating the same principle and considering that the surface area of a sphere is given by , it can be seen that the surface area of the lune corresponding to the same wedge is given by

Hart (2009) states that the "volume of a spherical wedge is to the volume of the sphere as the number of degrees in the [angle of the wedge] is to 360". Hence, and through derivation of the spherical wedge volume formula, it can be concluded that, if  is the volume of the sphere and  is the volume of a given spherical wedge,

Also, if  is the area of a given wedge's lune, and  is the area of the wedge's sphere,

See also 
Spherical cap
Spherical segment
Ungula

Notes 
A.  A distinction is sometimes drawn between the terms "sphere" and "ball", where a sphere is regarded as being merely the outer surface of a solid ball. It is common to use the terms interchangeably, as the commentaries of both Beman (2008) and Hart (2008) do.

References 

Spherical geometry
Jody Samson (November 4, 1946 – December 27, 2008) was a knifemaker and bladesmith from Burbank, California, who designed butterfly knives for Benchmade and the swords used in movies, including Conan the Barbarian, Conan the Destroyer, First Knight, The Mask of Zorro, Blade, Blind Fury, Batman & Robin, Batman Forever, and Streets of Fire.

Early life

Samson learned knife making and bladesmithing from John Nelson Cooper, a veteran knife maker located in Burbank, California, in 1969.  Samson began making knives full-time in 1974. Soon after, he was hired by Les DeAsis of Pacific Cutlery (now Benchmade) as a knife designer. Les deAsis credits Samson with grinding every custom balisong knife produced by Benchmade, Pacific Cutlery, and Bali-Song from 1979 to 1994.  Samson's first design won Blade magazine's Knife of the Year award in 1979.  The following year, Samson unveiled his "Wee-hawk" blade profile which was made by Benchmade for years.

Movie swords
Samson designed and built the swords, knives, and daggers used in a number of films including Conan the Barbarian, Conan the Destroyer, Blind Fury, and Streets of Fire while he was working for Benchmade. 

Samson left Benchmade in 1994 to return to Burbank to produce movie swords and props for Tony Swatton's Sword & Stone in Los Angeles, California.  He designed and built the weapons for the films First Knight, The Mask of Zorro, Blade, Batman & Robin, Babylon 5, and Batman Forever.

In 2001 Samson went to work for Albion Swords in New Glarus, Wisconsin, where he made replicas of the swords he originally made for the Conan films.

Later years and death

Samson was found dead of pneumonia in his workshop on December 27, 2008, after complaining of cold symptoms for a week.

References

External links

Knife makers
2008 deaths
1946 births
People from Burbank, California
Deaths from pneumonia in Wisconsin
People from New Glarus, Wisconsin
Gaines High School was a high school for African Americans and also later served as a normal school training teachers in Cincinnati, Ohio. It opened in 1866 and was named for school board member John I. Gaines, an advocate of schools for African Americans in Ohio. It was one of Ohio's first public high schools for African Americans. Peter H. Clark and then William H. Parham served as its principals. The year of the school's closure is uncertain; sources say 1887 or 1890. A historical marker commemorates the school. 

Clark introduced baseball as part of the school's program.

Clark became a Socialist and joined the Democratic Party, costing him support in the African American community and his job.

Privately funded Gilmore High School, also known as Cincinnati High School or Cincinnati High School for Colored People, preceded it.

John Isom Gaines
John Isom Gaines (November 6, 1821 - November 28, 1859) was an abolitionist and an advocate for African American rights and education in Ohio. He helped get a law passed in Ohio for the establishment of schools for African Americans. Gaines High School in Cincinnati was named for him. He abstained for drinking alcoholic beverages and was an advocate for temperance.

He gave speeches.

References

External links
The historical marker at Remarkable Ohio

High schools in Hamilton County, Ohio
Educational institutions established in 1866
Educational institutions disestablished in 1887
Educational institutions disestablished in 1890
1867 establishments in Ohio
Ernie Phillips may refer to:

Ernie Phillips (baseball), baseball player
Ernie Phillips (footballer) (1923–2004), English footballer
Arwyn Randall Davies, Baron Arwyn (17 April 1897 – 23 February 1978) was a Welsh Labour life peer.

He was a Chartered Mining Engineer, businessman and company director.

Marriage and family
He was married to Norah Davies, with children the Honourable Elizabeth Macnab, the Honourable Mary Webb and the Honourable Hugh Davies. 
He married secondly Beatrix Emily Bassett (née Organ).

Baron Arwyn
Davies took the name of Arwyn in lieu of Davies by Deed Poll on 14 December 1964 prior to being made a peer. On 29 December 1964, he was created a life peer as Baron Arwyn, of Glais in the County of Glamorgan. He was introduced to the House of Lords on 21 January 1965.

References

1897 births
1978 deaths
Arwyn
Life peers created by Elizabeth II
Donkey punch is a slang term for punching someone hard on the back of their head whilst having sex with them

Donkey punch may also refer to:

 Donkey puncher, slang term from the 1920s for operator of a small steam-powered winch used in logging
 Donkey punch (cocktail), a rum-based drink with orange juice and ginger ale
 Donkey Punch (2005 film), an adult film
 "Donkey Punch", a 2006 episode from season 2 of Robot Chicken
 Donkey Punch (novel), 2007 novel by Ray Banks
 Donkey Punch (2008 film), a British horror film
Legislative elections were held in France on 26 April and 3 May 1936, the last elections before World War II. The number of candidates set a record, with 4,807 running for election to the Chamber of Deputies. In the Seine Department alone, there were 1,402 candidates.

The Popular Front, composed of the French Section of the Workers' International (SFIO), the Radical-Socialists, the French Section of the Communist International (SFIC), and miscellaneous leftists, won power from the broad Republican coalitions that had governed since the 6 February 1934 crisis. Léon Blum became president of the council.

Results

The SFIC, predecessor of the Communist Party, doubled its score from 11 SFIC and 9 Union Ouvrière deputies in 1932 to 72 in 1936. The party made gains in industrialized suburbs and working-class areas of major cities. They also progressed in rural central and southwestern France (e.g., Dordogne, Lot-et-Garonne)
The Radicals lost votes to the SFIO and SFIC, but also to the right.
The SFIO declined slightly. In working-class suburbs, the party declined, but it gained votes in Brittany, to the dismay of the right.
Only 174 seats were elected in the first round, 424 were decided in a run-off. The right fared better in the second round.

References

External links
Map of Deputies elected in 1936 according to their group in the House, including overseas (in french)

Legislative elections in France
France
Legislative
William Charles Aroyn Walker (born 19 May 1978) is a former New Zealand rugby union footballer. He played for Gloucester and Worcester Warriors in the Guinness Premiership. He has also played for the New Zealand Maori.

Walker is currently the head coach of the Blues Women in the Super Rugby Aupiki competition.

Rugby career 
Walker debuted for North Harbour in 1997. He later played for Otago in 2002 and 2003. He also played for the Highlanders from 2002 to 2003 before going abroad.

Walker joined Gloucester for the start of the 2006/07 season on a 2-year contract from World Fighting Bull. He made 24 appearances in all competitions during his debut season, scoring 220 points. This included 2 tries against Bath & Bristol. In his second season, he made 23 appearances in all competitions, scoring 96 points. He scored 2 tries against Leicester Tigers and Bourgoin. On 22 May 2008, Walker signed a 2-year extension to his contract.

On 13 September 2008, Walker played a key role in Gloucester's victory at The Rec. He scored 1 try, 1 conversion, 2 penalties & 1 drop-goal to help Gloucester to a 21–17 victory.

On 16 May 2009, having played Nine games and scored 74 points whilst on loan to Worcester Warriors from Gloucester, it was officially announced that Walker had signed a 2-year deal with the Warriors, after being released from his contract by the Cherry & Whites. This new deal would keep Walker at the Worcester Warriors until 2011.

During his loan spell with Worcester Warriors Walker helped the Warriors achieve a huge derby double over local rivals Gloucester by kicking Worcester to victory both at Sixways and Kingsholm.

Coaching career 
Walker was appointed as Head Coach of Auckland Storm for the 2021 Farah Palmer Cup season. He then coached the Blues Women in the first-ever women's Super Rugby match in New Zealand on 1 May 2021.

With the announcement of the creation of the Super Rugby Aupiki competition by New Zealand Rugby, Walker was offered the position of Head Coach of the Blues Women for the inaugural season in 2022.

References

External links
 Worcester Warriors profile

1978 births
Living people
English rugby union players
Gloucester Rugby players
Highlanders (rugby union) players
Māori All Blacks players
New Zealand expatriate sportspeople in England
Rugby union players from Ōpōtiki
Worcester Warriors players
Rugby union fly-halves
People educated at Opotiki College
People educated at King's College, Auckland
New Zealand rugby union coaches
Waller Hugh Paton RSA RSW (27 July 1828 – 8 March 1895) was a Scottish landscape artist in the second half of the 19th century.

Early life
Paton was born in Wooer's Alley, Dunfermline, the son of Joseph Neil Paton (1797-1874), a damask designer, and Catherine McDiarmid. His brother and sister, Joseph Noel Paton and Amelia Robertson Hill (wife of David Octavius Hill), were also artists.

Career
In his teens, Paton worked with his father as a damask designer. From age twenty he trained under the mid-19th century artist John Houston (1802–1884) RSA. He was elected an associate of the Royal Scottish Academy (ARSA) in 1857 and became a full member (RSA) in 1865. In 1878 he became a member of the Royal Society of Watercolourists (RSW).

In 1858 he and his brother illustrated William Edmondstoune Aytoun's book "Lays of the Scottish Cavaliers", published in 1863.

Paton was one of the few of his generation to work "en plain air", the fashion then being to complete landscapes in the comfort of a studio. He enjoyed depicting the countrysides of Perthshire, Aberdeenshire, and especially the Isle of Arran. His work is typified by rich purple sunsets.

Personal life
From 1859, Paton lived in Edinburgh, initially staying with his brother Joseph in his large Georgian townhouse at 37 Drummond Place in the New Town.

In 1861 and 1868, he toured the Continent with his friend Donald MacKenzie Wallace and his brother Joseph.

In 1862 he married Margaret Kinloch of Maryculter near Aberdeen. They had four sons and three daughters.

In 1875, he moved to 14 George Square, Edinburgh. The house stood on the north side of the square, facing along the line of houses on the west side. It was demolished in the 20th century.

His son Waller Hubert Paton (1863-1940) was a sculptor.

Death
Paton died at his home, 14 George Square, Edinburgh, on 8 March 1895 from pleurisy, which had plagued him for the last 10 years of his life. He is buried in Grange Cemetery in southern Edinburgh.

Principal Works

"The Antique Room, Wooer's Alley, by Firelight" (1848)
"Glen Massen", Royal Scottish Academy (1851)
"Loch Lomond", Government Art Collection (1858)
"Winter Daybreak", McLean Museum and Art Gallery, Inverclyde (1864)
"Lamlash Bay, Isle of Arran", Royal Scottish Academy (1865)
"Entrance to the Cuiraing, Skye", National Gallery of Scotland (1873)
"The Border Keep", Welsh National Museum, Cardiff (1875)
"Cobbles at Sundown, Arrochar", Folkestone Library
"Craigmillar Castle", The Fleming Collection
"Outlet at Loch Achray, Perthshire", Fyvie Castle (NTS)

References

Oxford Dictionary of National Biography: Waller Hugh Paton
Dictionary of Scottish Art and Architecture, 2004

External links

1828 births
1895 deaths
People associated with Edinburgh
Scottish artists
Royal Scottish Academicians
Ateneo may refer to:

Cultural institutions 
 Ateneo de la Juventud, a society of Mexican writers, philosophers and intellectuals
 Ateneo de Madrid, a private cultural institution located in the capital of Spain
 Ateneo de Ponce, a nonprofit, civic, organization in Ponce, Puerto Rico
 Ateneo Puertorriqueño, one of Puerto Rico's chief cultural institutions
 Ateneo de Sevilla, a cultural, scientific, literary, and artistic association in Seville, Spain
 Ateneo Veneto, an institution for science, literature, and arts in Venice, Italy

Schools named Ateneo run by the Society of Jesus in the Philippines

Teaching and research universities 
 Ateneo de Davao University
 Ateneo de Manila University
 Ateneo de Naga University
 Ateneo de Zamboanga University
 Xavier University – Ateneo de Cagayan

Non-tertiary Schools 
 Sacred Heart School – Ateneo de Cebu
 Ateneo de Iloilo - Santa Maria Catholic School

Defunct institutions 
 Ateneo de San Pablo
 Ateneo de Tuguegarao

Other uses 
 El Ateneo Grand Splendid, a bookshop in Buenos Aires, Argentina
 Ateneo F.C., an association football club based in Quezon City in the Philippines
 Athenaeus of Naucratis, ancient Greek rhetorician and grammarian

See also 
 
 
 Athenaeum (disambiguation)
Farm to Market Road 1419 (FM 1419) is a farm to market road in Cameron County, Texas. It is the southernmost numbered route in the Texas state highway system.

Route description
FM 1419 begins at an intersection with  SH 4 west of downtown Brownsville. The route travels to the southeast, along Southmost Road, to an intersection with  FM 511. The roadway then turns to the south, and then the east, to an intersection with  FM 3086. After continuing to the east and passing the colonia of Southmost, FM 1419 turns to the north in South Point, and continues to its terminus at SH 4 near the Brownsville city limits.

History
FM 1419 was originally designated on July 15, 1949, from the junction with FM 511 to South Point. On October 7 of that year, the northward extension from South Point to SH 4 was approved, replacing a section of FM 511. The eastern addition, to SH 4, was designated on September 21, 1955. On June 27, 1995, the western section of the route, from SH 4 to FM 511, was officially redesignated as Urban Road 1419 (UR 1419), but that section was changed back to FM 1419 on November 15, 2018. On April 29, 2010, the sections from 1.9 miles west of FM 3068 to FM 3068 and from .04 mile north of Dockberry Road to 0.7 miles south of SH 4 were redesignated as SH 32.  The section from FM 3068 to .04 mile north of Dockberry Road was designated as FM 3550. The section from 0.7 miles south of SH 4 to SH 4 was redesignated as FM 3551. Since SH 32 has not been built yet, signage has not changed.

Major intersections

References

1419
Transportation in Cameron County, Texas
Transportation in Brownsville, Texas