Samantha912/NLP_A2_WTH huggingface dataset:
In materials science, a precipitate-free zone (PFZ) refers to microscopic localized regions around grain boundaries that are free of precipitates (solid impurities forced outwards from the grain during crystallization). It is a common phenomenon that arises in polycrystalline materials (crystalline materials with stochastically-oriented grains) where heterogeneous nucleation of precipitates is the dominant nucleation mechanism. This is because grain boundaries are high-energy surfaces that act as sinks for vacancies, causing regions adjacent to a grain boundary to be devoid of vacancies. As it is energetically favorable for heterogeneous nucleation to occur preferentially around defect-rich sites such as vacancies, nucleation of precipitates is impeded in the vacancy-free regions immediately adjacent to grain boundaries

History 
Pioneering studies on the theory and experimental observation of PFZs were made in the 1960s.

Effect on material properties 
PFZs are detrimental to the mechanical properties of materials. In particular, PFZs degrade the material's hardness, because the lack of precipitates in PFZs lead to these regions having fewer pinning sites. Dislocation motion – a condition necessary to cause a material to yield – will require an appreciably lower applied shear stress in PFZs, and consequently these locally weak zones will lead to plastic deformation. The width of PFZs have also been found to be negatively correlated with intergranular fracture

PFZs also accelerate pitting corrosion and stress corrosion cracking, significantly reducing the usable life of these materials in chemically aggressive environments.

Techniques to minimize 
It has been shown that PFZs can be minimized by quenching. First, quenching increases undercooling, favoring homogeneous nucleation in PFZs as it lowers the nucleation energy barrier even in the absence of potent nucleation sites. Additionally, low temperatures also lead to a reduction in diffusion rates, minimizing the loss of vacancies and premature growth of grain boundary precipitates. However, since diffusion rates at low temperatures are suppressed, the aging time (time taken for treatment to yield a desired grain size) would be long. Therefore, one processing technique to circumvent this is to increase the temperature slightly once a sufficient number of homogeneous nucleation sites have been formed.
Another technique to minimize PFZs is to introduce impurity elements, as they strongly interact with vacancies and allow for a more even distribution of vacancies in the material. One example would be to introduce Mg in Al alloys

Cyclic strengthening (CS), a process wherein a material is mechanically pushed and pulled repeatedly at room temperature, creates fine precipitates that is homogeneously distributed throughout the microstructure. It has been suggested as an alternative to conventional, precipitate hardened alloys as this process achieves strengthening effects without introducing PFZs.

References 

Materials science
Imre Bacskai (born 21 June 1961) is a Hungarian boxer. He competed in the men's light welterweight event at the 1980 Summer Olympics and in the men's welterweight event at the 1988 Summer Olympics.

References

External links
 

1961 births
Living people
Hungarian male boxers
Olympic boxers for Hungary
Boxers at the 1980 Summer Olympics
Boxers at the 1988 Summer Olympics
Martial artists from Budapest
Welterweight boxers
Woodlore is a studio album by saxophonist Phil Woods' Quartet. It was recorded in 1955 and released on the Prestige Records.

Reception

In his review for AllMusic, Scott Yanow stated "The altoist displays plenty of energy and a strong command of the bebop vocabulary, sounding quite enthusiastic".

Track listing
All compositions by Phil Woods except as indicated
 "Woodlore" - 5:23
 "Falling in Love All Over Again" (Neil Hefti) - 4:44
 "Be My Love" (Sammy Cahn, Nicholas Brodszky) - 5:38
 "Slow Boat to China" (Frank Loesser) - 5:04
 "Get Happy" (Harold Arlen, Ted Koehler) - 6:46
 "Strollin' With Pam" - 5:20

Personnel
Phil Woods - alto saxophone 
John Williams - piano
Teddy Kotick - bass 
Nick Stabulas - drums

References

Prestige Records albums
Phil Woods albums
1956 albums
Albums recorded at Van Gelder Studio
Albums produced by Bob Weinstock
Albums recorded in a home studio
Theodore Sedgwick III (January 27, 1811 – December 9, 1859) was an American attorney and author on legal topics.

He was born in Albany, New York, the son of Theodore Sedgwick II (1780–1839) and Susan Anne Ridley Sedgwick (1788–1867). He was a grandson of Theodore Sedgwick (1746–1813).

He graduated from Columbia College in 1829. He then studied law and was admitted to the bar in May, 1833.

Sedgwick spent 15 months in Europe, primarily as a member of Edward Livingston's legation when Livingston served as U.S. Minister to France. On his return home in May 1835, he joined his uncle Robert Sedgwick's law practice in New York. He took over the practice when Robert was debilitated by a stroke in 1838, and remained active until 1850.

Ill health forced Sedgwick to retire in 1850. He spent the next several years traveling in Europe, including visits to Italy, Switzerland, France, and England. In 1852, he became president of the Crystal Palace Association, organizing the construction of the building for the New York World's Fair.

In 1857, Sedgwick declined President James Buchanan's offers to become Minister to the Netherlands and assistant secretary of state. In 1858, he became United States Attorney for the Southern District of New York.

Sedgwick died in Stockbridge on December 9, 1859. He was buried at Stockbridge Cemetery.

His writings include his edition of the political writings of William Leggett (two volumes, 1840); Treatise on the Measure of Damages (1847; eighth edition, 1891); Treatise on the Rules which Govern the Interpretation and Application of Statutory and Constitutional Law (1857; second edition, 1874); and Thoughts on the Proposed Annexation of Texas (1844, originally published 1843 as letters to the New York Evening Post), which declared the annexation of Texas unconstitutional.

References

External links
 
 Theodore SEDGWICK III / Sarah Morgan ASHBURNER
 

1811 births
1859 deaths
American legal writers
American people of English descent
Columbia College (New York) alumni
United States Attorneys for the Southern District of New York
Writers from Albany, New York
Sedgwick family
Corey Mapes (born June 22, 1992) is a German professional ice hockey player. He currently plays for the Kassel Huskies in the DEL2. After playing as a youth and making his professional debut within Adler Mannheim, Mapes was signed to a one-year contract with DEL rival Düsseldorfer EG on May 22, 2013.

After three seasons within the Düsseldorfer organization, Mapes was left uncontracted as a free agent, and signed a one-year deal with DEL2 club, Kassel Huskies on June 22, 2016.

Career statistics

Regular season and playoffs

International

References

External links
 

1992 births
Living people
Adler Mannheim players
Düsseldorfer EG players
German ice hockey defencemen
Heilbronner Falken players
Sportspeople from Heilbronn
Ice hockey people from Baden-Württemberg
The Mozart Medal of the Mozartgemeinde Wien was a music award named after Wolfgang Amadeus Mozart.

Recipients

Heinrich Damisch, 1952
Wilhelm Furtwängler, 1952
Heinrich von Kralik, 1952
Joseph Marx, 1952
Edwin Fischer, 1953
Egon von Komorzynsky, 1953
Irmgard Seefried, 1953
Wiener Philharmoniker, 1953
Audrey Christie, 1954
John Christie, 1954
Ernst Moravec, 1954
Leopold Nowak, 1954
Leopold Wlach, 1954
Johann Nepomuk David, 1955
Anton Dermota, 1955
Hans Pemmer, 1955
Erich Schenk, 1955
Amis de Mozart Paris, 1956
Boston Symphony Orchestra, 1956
Comune di Milano, 1956
Deutsche Grammophon Gesellschaft, 1956
Karl Böhm, 1957
Maria Gerhart, 1957
Erich Kunz, 1957
Erich Müller-Asow, 1957
Willy Boskovsky, 1958
Franziska Martienssen-Lohmann, 1958
Julius Patzak, 1958
Wiener Oktett, 1958
Wiener Symphoniker, 1958
Hans Duhan, 1960
Bernhard Paumgartner, 1960
Erik Werba, 1960
Josef Witt, 1960
Wilhelm Backhaus, 1961
Ferdinand Grossmann, 1961
Wise Helletsgruber, 1961
Carl Schuricht, 1961
Dietrich Fischer-Dieskau, 1963
Ferenc Fricsay, 1963
Hans Joachim Moser, 1963
Wiener Phil. Streichquartett, 1963
Elisabeth Höngen, 1964
Sena Jurinac, 1964
Emmy Loose, 1964
Maria Reining, 1964
Paul Schöffler, 1964
Oscar Fritz Schuh, 1964
Otto Erich Deutsch, 1965
Frank Martin, 1965
Yehudi Menuhin, 1965
Gustav Hillström, 1966
Wilfried Scheib, 1966
Franz Samohyl, 1966
Gerhard Croll, 1968
Hilde Konetzni, 1968
Wilhelm Rohm, 1968
Hans Sittner, 1968
Hans Swarowsky, 1968
Christa Ludwig, 1969
Jacques Chailley, 1969
Karl Öhlberger, 1969
Walter Berry, 1969
Heinz Scholz, 1969
Dmitri Shostakovich, 1969
Nicolai Gedda, 1970
Walter Gerstenberg, 1970
Ingrid Haebler, 1970
Egon von Komorzynsky, 1970
George London, 1970
Alfred Uhl, 1970
Erich Marckhl, 1971
Manuel Capdevila, 1971
Norbert Sprongl, 1971
Henryk Szeryng, 1971
Erich Valentin, 1971
Claudio Abbado, 1973
Friedrich Gehmacher, 1973
Alexander Weinmann, 1973
Fritz Heindl, 1974
Walter Senn, 1974
Otto Strasser, 1974
Hans Zwölfer, 1974
Amadeus Quartet, 1975
Karl Pfannhauser, 1975
Keisei Sakka, 1975

References

Austrian music awards
Wolfgang Amadeus Mozart
Awards established in 1952
1952 establishments in Austria
Smashhdown! is an Australian children's sports game show on 9Go!. The show features sports challenges and trivia to find "Australia's number one junior sports all-rounder".

Production
Series 1 of the series began airing on 17 December 2018, presented by school teacher Andy Sunderland with commentators played by Michael Balk (Glen Goosebump) and Briana Goodchild (Glenda Goosebump). There are six tournaments in Series 1, featuring 25 shows per tournament. The show also features guest appearance from athletes such as netballer players Gretel Tippett (Diamonds) and Mahalia Cassidy (Firebirds), Australian Rules footballer Alex Witherden (Brisbane Lions), soccer player Daniel Leck (Brisbane Roar) and New Zealand international rugby league player Alex Glenn.

Series 2 began production in August 2019 and consists of four tournaments. Like the previous series, each tournament features 25 shows. The host for series 2 is Nick Allen-Ducat.

Series 3, titled Smashhdown!: Search for The G.O.A.T, is hosted by Ashlee Lollback, with Michael Balk continuing his role as a commentator. The series also features cast members Sami Afuni, Arnijke Larcombe-Weate and Danielle Remulta. The third series shifted the format of the series from a sports game show featuring child contestants due to COVID-19 restrictions. Horrible Histories inspired a new format featuring an ensemble of eight performers assuming historical and comedic characters. Head of Production and Programming for Nine Queensland, Geoff Cooper, stated in December 2022 that production of the third series (containing 250 episodes) had been completed. He estimated between 500 and 700 had been filmed overall; new episodes will air in 2023.

Series overview

References

Nine Network original programming
9Go! original programming
Australian children's game shows
Australian children's television series
2018 Australian television series debuts
2010s Australian game shows
Television shows set in Brisbane
English-language television shows
Saint Gwrhai was a 5th-century saint of Wales.

He is known from a 10th-century hagiography and is of  disputed historicity. He was reputedly the founder of the Church at Penystrywad, Montgomeryshire, and one at Caerleon. He was a colleague of Deiniol and was a son of Caw of Strathclyde. He is supposedly buried in the churchyard at Penystrywad.

References

5th-century Welsh people
Welsh Roman Catholic saints
Medieval Welsh saints
Year of birth unknown
In mathematical finite group theory, a rank 3 permutation group acts transitively on a set such that the stabilizer of a point has 3 orbits. The study of these groups was started by . Several of the sporadic simple groups were discovered as rank 3 permutation groups.

Classification
The primitive rank 3 permutation groups are all in one of the following classes:

 classified the ones such that  where the socle T of T0 is simple, and T0 is a 2-transitive group of degree .
 classified the ones with a regular elementary abelian normal subgroup
 classified the ones whose socle is a simple alternating group
 classified the ones whose socle is a simple classical group
 classified the ones whose socle is a simple exceptional or sporadic group.

Examples
If G is any 4-transitive group acting on a set S, then its action on pairs of elements of S is a rank 3 permutation group. In particular most of the alternating groups, symmetric groups, and Mathieu groups have 4-transitive actions, and so can be made into rank 3 permutation groups.

The projective general linear group acting on lines in a projective space of dimension at least 3 is a rank-3 permutation group.

Several 3-transposition groups are rank-3 permutation groups (in the action on transpositions).

It is common for the point-stabilizer of a rank-3 permutation group acting on one of the orbits to be a rank-3 permutation group. This gives several "chains" of rank-3 permutation groups, such as the Suzuki chain and the chain ending with the Fischer groups.

Some unusual rank-3 permutation groups (many from ) are listed below.

For each row in the table below, in the grid in the column marked "size", the number to the left of the equal sign is the degree of the permutation group for the permutation group mentioned in the row. In the grid, the sum to the right of the equal sign shows the lengths of the three orbits of the stabilizer of a point of the permutation group. For example, the expression 15 = 1+6+8 in the first row of the table under the heading means that the permutation group for the first row has degree 15, and the lengths of three orbits of the stabilizer of a point of the permutation group are 1, 6 and 8 respectively.

Notes

References

Finite groups
Gabriela Laperrière de Coni (1866 – 8 January 1907) was an Argentine journalist, socialist, and public health activist. She founded the Feminist Socialist Center of the Argentine Socialist Party, and served on the executive committee of the party, the first woman to do so. She was a pioneering intellectual who devoted her energy to the cause of feminist issues related to working women in Argentina.

Early life
She was born in Bordeaux, France in 1866. No further information is available about her early life, except that she wrote a novel on "woman's efforts to help sick children." At the age of 18, she married Dr. Emilio R. Coni, noted public-health physician from Buenos Aires who was actively engaged in immigration and health issues. She migrated to Argentina with him. His activity complimented her deep interests in the healthcare of women.

Career
In the initial years, Gabriella was constantly exposed to a stream of visitors seeking help from Emilio, the Director of Public Assistance in Buenos Aires, all related to the health, accommodation, living conditions, destitute children and unemployment among both men and women. Unable to cope with the situation, the couple moved to Paris. In 1895 they returned to Argentina but her husband Emilio was laid for months due to a paralytic stroke. She then attended to the duties of her husband and helped people who came seeking their assistance. In 1901, the city government of Buenos Aires permitted Gabriella to study and report on the working conditions of women and children. During this assignment she toured the neighborhood extensively and was appalled by the inhumane living conditions, lack of hygiene, food and health facilities, poor nutrition, people living in abject poverty, lack of electricity and many more miseries.

After this assessment, she launched on many rehabilitation programmes such as providing food rations, set crèches at workplaces so that women workers could breastfeed their babies, and improved access to urban services and housing. She visited factories and reported on the harsh attitude of its owners in treating their employees which received public attention through her writings in newspapers. She made a four-part report of her findings and also mooted a proposal to enact labor laws which would bring about protection of women and children. This bill was enacted by the Parliament after her death in 1907.

References

1866 births
1906 deaths
Argentine feminists
Argentine women journalists
Argentine women's rights activists
20th-century deaths from tuberculosis
French emigrants to Argentina
People from Bordeaux
Socialist Party (Argentina) politicians
Socialist feminists
Argentine health activists
19th-century Argentine women writers
Tuberculosis deaths in Argentina
Organization founders
Women founders
Turma do Lambe-Lambe was a Brazilian media franchise created by comic book artist Daniel Azulay in 1975. The franchise follows a group of characters that consist of human kids and anthropomorphic animals. It was publicly recognized in 1976 when Daniel Azulay signed a contract with the channel TV Educativa (currently known as TV Brasil) to present a children's show, known as A Turma do Lambe-Lambe, from which he used these characters. The program, however, was more successful on Rede Bandeirantes, where it was broadcast until 1986 and marked legacy as one of the most popular children's shows in Brazil during the 1980s. During this period A Turma do Lambe-Lambe derived a series of comic books and also several LP albums, which were later re-released as CD.

Characters 
Pita, a circus boy
Piparote, another circus boy
Ritinha, Piparote's girlfriend
Damiana, Pita's girlfriend
Tristinho, a pierrot
Professor Pirajá, a scientist owl
Xicória, a chicken
Gilda, a cow
Bufunfa, an elephant

Television series 
The series premiered in 1976 on TV Educativa at first with exclusive broadcast only to Rio de Janeiro, but subsequently debuted on Rede Bandeirantes where it started broadcasting nationwide. The series became known for its presentation by Daniel Azulay, that used to teach children how to draw, and also how to make toys with recyclable material. Azulay's characters were played by adults wearing costumes and masks. The series ended in 1986 with the decline of the program's style and the success of presenters like Xuxa. Even after the end of the series Azulay and his characters developed a considered legacy over the years.

Comic series 
Between 1982 and 1984 a series of comic books was published by Editora Abril, lasting 20 issues. These comics were designed by the publisher's team of artists who were also responsible for Disney comics such as José Carioca. In the comics Azulay also appeared as a recurring character alongside his characters.

References 

Brazilian comics titles
Child characters in comics
Brazilian children's television series
1976 Brazilian television series debuts
1986 Brazilian television series endings
Rede Bandeirantes original programming
Television shows set in circuses
Vilnis is a Latvian masculine given name. Individuals bearing the name Vilnis include: 
Vilnis Edvīns Bresis (1938–2017) Latvian politician 
Vilnis Ezeriņš, Latvian-born American football player
Vilnis Straume (born 1937), Latvian footballer

Latvian masculine given names
Masculine given names
The Statute Law (Repeals) Act 1989 (c. 43) is an Act of the Parliament of the United Kingdom.

This Act was partly in force in Great Britain at the end of 2010.

It implemented recommendations contained in the thirteenth report on statute law revision, by the Law Commission and the Scottish Law Commission.

Section 3 - Short title and commencement
The Statute Law (Repeals) Act 1989 (Commencement) Order 1992 (SI 1992/1275) (C 40) was made under section 3(2).

Schedule 2

Part I
Paragraph 3 was repealed by section 73(3) of, and Part I of Schedule 6 to, the Justices of the Peace Act 1997.

Paragraph 4 was repealed by section 109(3) of, and Schedule 10 to, the Courts Act 2003.

Part II
Paragraph 7 was repealed by section 423 of, and Part V of Schedule 34 to, the Greater London Authority Act 1999.

Paragraph 13 was repealed by section 17(2) of, and Part I of Schedule 2 to, the British Technology Group Act 1991.

See also
Statute Law (Repeals) Act

References
Halsbury's Statutes. Fourth Edition. 2008 Reissue. Volume 41. Page 891.
Peter Allsop (Editor emeritus). Scottish Current Law Statutes Annotated 1989. Sweet and Maxwell, Stevens & sons. London. W Green & son. Edinburgh. 1990. Volume 4.
The Public General Acts 1989. HMSO. London. 1990. Part III. Page 2387.
HL Deb vol 508, cols 945 and 1266 to 1268, vol 509, col 966, vol 510, col 263, HC Deb vol 159, col 1290.

External links
The Statute Law (Repeals) Act 1989, as originally enacted, from the National Archives.

United Kingdom Acts of Parliament 1989
The 2023 Big East women's basketball tournament was the postseason women's basketball tournament for the Big East Conference to be held March 3 to 6, 2023, at Mohegan Sun Arena in Uncasville, Connecticut. After four days of play, the #1 seed UConn Huskies defeated #2 seed Villanova Wildcats 67–56, thereby receiving the conference's automatic bid to the 2023 NCAA tournament.

Seeds 
All 11 Big East schools were scheduled to participated in the tournament. Teams were seeded by conference record with tie-breaking procedures to determine the seeds for teams with identical conference records. The top five teams received first-round byes. Seeding for the tournament was determined at the close of the regular conference season.

Schedule

Bracket 

Note: * denotes overtime

References 

Tournament
Big East women's basketball tournament
Big East women's basketball tournament
Big East women's basketball tournament
2020s in Connecticut
Women's sports in Connecticut
College basketball tournaments in Connecticut
Sports competitions in Uncasville, Connecticut
A crosshair is another name for a reticle. Other meanings include:

 A song by the Danish band Blue Foundation.
 Cross Hair (G.I. Joe), fictional G.I. Joe character.
 Crosshairs (Transformers), several robot superhero characters in the Transformers robot superhero franchise.
 Crosshairs, a feature of some screen magnifiers.
ASUS Crosshair, a line of computer motherboards for AMD processors.
Crosshair (Star Wars), a deformed clone trooper and former member of The Bad Batch in the Star Wars franchise.

See also
Corsair (disambiguation)