Samantha912/NLP_A2_WTH huggingface dataset:
The tert-butyloxycarbonyl protecting group or tert-butoxycarbonyl protecting group (BOC group) is a protecting group used in organic synthesis.

The BOC group can be added to amines under aqueous conditions using di-tert-butyl dicarbonate in the presence of a base such as sodium carbonate:

Protection of amines can also be accomplished in acetonitrile solution using 4-dimethylaminopyridine (DMAP) as the base.

Removal of the BOC group in amino acids can be accomplished with strong acids such as trifluoroacetic acid in dichloromethane, or with HCl in methanol. A complication may be the tendency of the t-butyl cation intermediate to alkylate other nucleophiles; scavengers such as anisole or thioanisole may be used.
Selective cleavage of the N-Boc group in the presence of other protecting groups is possible when using AlCl3.

Sequential treatment with trimethylsilyl iodide then methanol can also be used for Boc deprotection, especially where other deprotection methods are too harsh for the substrate. The mechanism involves silylation of the carbonyl oxygen and elimination of tert-butyl iodide (), methanolysis of the silyl ester to the carbamic acid () and finally decarboxylation to the amine ().

Amine protection  

The tert-butyloxycarbonyl (Boc) group is used as a protecting group for amines in organic synthesis.

Common amine protection methods 
Simple rapid stirring of a mixture of the amine and di-tert-butyl dicarbonate (Boc2O) suspended in water at ambient temperature, an example of an on-water reaction.
Heating a mixture of the amine to be protected and di-tert-butyl dicarbonate in tetrahydrofuran (THF) at 40 °C
Add the amine to sodium hydroxide and di-tert-butyl dicarbonate in water and THF at 0 °C then warm to ambient temperature.
Heating a mixture of the amine to be protected and di-tert-butyl dicarbonate in a biphasic mixture of chloroform and aqueous sodium bicarbonate at reflux for 90 minutes.
Add the amine to di-tert-butyl dicarbonate, 4-dimethylaminopyridine (DMAP), and acetonitrile (MeCN) at ambient temperature

BOC-protected amines are prepared using the reagent di-tert-butyl-iminodicarboxylate.  Upon deprotonation, this reagent affords a doubly BOC-protected source of NH, which can be N-alkylated.  The approach is complementary to the Gabriel synthesis of amines.

Common amine deprotection methods 
 Mix the protected carbamate to be deprotected with 3 M hydrochloric acid (HCl) in ethyl acetate for 30 min at ambient temperature
 Heat the carbamate in a mixture of aqueous hydrochloric acid and toluene at 65 °C
 Dissolving desired protected compound in a 50/50 mix of dichloromethane and trifluoroacetic acid

References

Protecting groups
Tert-butyl compounds
Pradipta Kumar Naik (born 14 June 1966) is an Indian politician.He won the Vidhan sabha seat of Bhawanipatna Odisha four times with two times as Minister in Odisha. He became a Member of the Legislative Assembly in 1995 at the very young age of 27. He was elected to the Odisha Legislative Assembly from Bhawanipatna in the 2019 Odisha Legislative Assembly election as a member of the BJP. He is Leader of Opposition in Odisha Legislative Assembly.'''

References

1966 births
Living people
Bharatiya Janata Party politicians from Odisha
People from Bhawanipatna
Odisha MLAs 2019–2024
Sambalpur University alumni
Lauryshava Monastery () is an Eastern Orthodox monastery located in the Navahrudak rajon of the Hrodna voblast of Belarus. It is one of the oldest monasteries in the country.

According to Hypatian Chronicle, the monastery was founded around 1260 by the Lithuanian duke Voyshalk "on the river Nioman between Lithuania and Navahrudak". After adopting Orthodox Christianity, Voyshalk took the name Lawrence (, Laurysh). The area was later named after the monastery's founder.

Around 1329, the Lauryshava gospel has been written for the monastery. According to the gospel, the monastery's name was Lauryshava Monastery of the Blessed Virgin (). The monastery had two churches, it operated a school and a library.

In 1530 the Tatars destroyed the monastery and killed all monks. The monastery has consequently been rebuilt and destroyed several times.

By 1824 the monastery had 5 residents, the library consisted of 500 volumes. In 1836 the monastery was closed down.

The monastery was then renewed in early 20th century but was then burnt down during the First World War in 1915.

In 1993, the Orthodox Archbishop of Białystok and Gdańsk Sawa (Hrycuniak) and the Bishop of Navahrudak and Lida Kanstantsin (Haranau) consecrated the site of the monastery church. The church was completed in 1998 and consecrated in honor of the Reverend Elisha of Lauryshava, the monastery's first abbot who had been canonized in 1514.

By the decision of the Holy Synod of the Belarusian Orthodox Church, on August 15, 2007 the parish was converted into the Monastery of St. Elisha of Lauryshava. In place of the original location of the monastery are conducted archaeological excavations.

References

Christian monasteries in Belarus
1260 establishments in Europe
Sir Robert Bruce Lockhart Burnside (26 July 1833 – 10 August 1909) was the 16th Chief Justice of Ceylon and 25th Queen's Advocate of Ceylon.

Career

He served as the Speaker of the House of Assembly of the Bahamas from November 1866 to February 1867. 

He was appointed Chief Justice of Ceylon on 21 May 1883 succeeding Jacobus de Wet and served as Chief Justice until 1889. He was succeeded by John Winfield Bonser.

Harry Dias Bandaranaike acted as Chief Justice from 9 January to 6 June 1888 when Burnside and Lovell Clarence went on leave. Clarence acted from November 1890 to February 1891 when Burnside and Bandaranaike retired.

Personal life
Burnside was born to John and Mary Burnside. His son Robert Bruce Burnside was a judge on the Supreme Court of Western Australia.

References

Chief Justices of British Ceylon
19th-century Sri Lankan people
20th-century Sri Lankan people
Sri Lankan people of British descent
British expatriates in Sri Lanka
19th-century British people
1833 births
1909 deaths
Attorneys General of British Ceylon
People from Nassau, Bahamas
Speakers of the House of Assembly of the Bahamas
This is a list of the European Hot 100 Singles and European Top 100 Albums number ones of 1986, as published by Music & Media magazine (known as Eurotipsheet until April 1986).

Chart history

References

Europe
1986
1986
Thomas J. Hillery (June 16, 1904 – December 1, 1991) was an American politician who served in the New Jersey General Assembly from 1947 to 1954 and in the New Jersey Senate from 1954 to 1968.

He died of cardiac arrest on December 1, 1991, in Denville Township, New Jersey at age 87.

His father Thomas J. Hillery also served in the Assembly and the Senate.

References

1904 births
1991 deaths
Republican Party members of the New Jersey General Assembly
Republican Party New Jersey state senators
Majority leaders of the New Jersey Senate
Presidents of the New Jersey Senate
20th-century American politicians
This is a discography for the band The Pillows.

Discography

Studio albums

Extended plays

Compilations

Singles

Promotional singles

Soundtracks
 Love & Pop (various artists, 1998)
 FLCL No. 1: Addict (with Shinkichi Mitsumune) (2004)
 FLCL No. 2: King of Pirates (2004)
 Colors of Life (various artists, 2004)
 Moonlight Jellyfish (various artists, 2004)
 FLCL No. 3 (2005)
 FooL on CooL generation (2018)
 Ousama Ni Nare (2019)

Compilations (with or by other artists)
 Respectable Roosters (1999)
 Life Is Delicious (2001)
 Beat Offenders (2002)
 Synchronized Rockers (, tribute album,  2004)
 802 Heavy Rotations J-Hits Complete '94-'96 (2004)
 Wasurerarenai Koi no Uta (2005)
 The Collectors - 20th Anniversary Special Album (2006)
 Electric Rays (2008)
 Lightning Runaway (2009)
 ROCK AND SYMPATHY (tribute album,  2014)
 Yes, We Love Butchers: Mumps (2014)

Videography

Video albums

References

Discographies of Japanese artists
Rock music group discographies
This is a list of notable footballers who have played for Macclesfield Town F.C. Generally, this means players that have played 100 senior matches for the club. Other players who have played an important role for the club can be included, but the reason why they have been included should be added in the 'Notes' column.

For a list of all Macclesfield players, major or minor, with a Wikipedia article, see Category:Macclesfield Town players, and for the current squad see the main Macclesfield Town article.

Players are listed according to the date of their first team debut. Appearances and goals are for first-team competitive matches only; wartime matches are excluded. Substitute appearances included.

Table

References 

Macclesfield Players Football League Statistics at Neil Brown site

 
Association football player non-biographical articles
Macclesfield
Players
Nasr () is a given name and surname, more common as a surname, in the Arabic language. It may refer to:

Mononym
 Nasr I, Samanid amir ruled 864–892
 Nasr II, Samanid amir, ruled 914–943
 Nasr, Sultan of Granada (1287–1322), in the Nasrid dynasty

Given name
Nasr Abdel Aziz Eleyan (born 1941), Jordanian-Palestinian artist, television interior designer/producer
Nasr Abu Zayd (1943–2010), Egyptian Qur'anic thinker
Nasr ibn Sayyar (663–748), Arab general and the last Umayyad governor of Khurasan in 738–748
Nasr ibn Shabath al-Uqayli, early 9th-century rebel leader in the Jazira
Nasr Javed, Kashmiri senior operative of the militant group Lashkar-e-Taiba
Nasr Al-Madhkur, 18th century local governor of what was described by a contemporary account as an "independent state" of Bushire and Bahrain
Nasra Ali Abukar (born 2003) Somali female athlete
Nasr El Hag Ali, the first vice chancellor of the University of Khartoum

Middle name
Alireza Nasr Azadani (born 1985), Iranian taekwondo player

Surname
Abu Yaqub Yusuf an-Nasr (died 1307), Marinid ruler of Morocco
Ali Nasr (1891-1961), Iranian dramatist and playwright 
Farouk Seif Al Nasr (1922–2009), Egyptian politician 
Felipe Nasr, Brazilian racing driver
Ghassan Nasr, academic and translator
Hassan Mustafa Osama Nasr, Egyptian cleric who was living in asylum in Italy until being allegedly abducted by the CIA
Kamila Nasr, Canadian singer, composer and multi-instrumentalist based in Beijing
May Nasr, Lebanese singer, musician and microfinancing consultant
Mahmoud Nasr, Egyptian cinematographer 
Mahmoud Abo El-Nasr (born 1953), Egyptian engineering professor, politician and minister
Muhammad Hamid Abu al-Nasr, a General Guide of the Egyptian Muslim Brotherhood
Octavia Nasr, Lebanese-American journalist
Ramsey Nasr (born 1974), Dutch-Palestinian author and actor
Rasha Nasr (born 1992), Syrian-German politician
Said Al Nasr, Syrian Palestinian, convicted in Belgium in 1980 for terrorism
Salah Nasr (1920–1982), head of the Egyptian General Intelligence Directorate from 1957 to 1967
Saleh Nasr (born 1999), Egyptian football player
Seyyed Hossein Nasr, Iranian professor in the department of Islamic studies at George Washington University
Suad Nasr (1953–2007), Egyptian stage, television, and film actress
Vali Reza Nasr, Iranian-born U.S. academic and scholar teaching at the Naval Postgraduate School
Yasman Malek-Nasr (also spelt Yassamin Maleknasr, born 1955), Iranian filmmaker and actress

See also
Nasr (disambiguation)
Naser (disambiguation)
Nasser (disambiguation)

Arabic masculine given names
Masculine given names
Surnames of Egyptian origin
Surnames of Iranian origin
Surnames of Lebanese origin
Anissimov is a Russian surname. Notable people with the surname include:

Alexander Anisimov (born 1947), Russian conductor
Ellina Anissimova (born 1992), Estonian hammer thrower
Myriam Anissimov (born 1943), French writer

See also
 Anisimov

Russian-language surnames
Zeale is a genus of longhorn beetles of the subfamily Lamiinae, containing the following species:

 Zeale dubia Galileo & Martins, 1997
 Zeale nigromaculata (Klug, 1829)
 Zeale scalaris Pascoe, 1866

References

Hemilophini
ShotCode is a circular barcode created by High Energy Magic of Cambridge University. It uses a dartboard-like circle, with a bullseye in the centre and datacircles surrounding it. The technology reads databits from these datacircles by measuring the angle and distance from the bullseye for each.

ShotCodes are designed to be read with a regular camera (including those found on mobile phones and webcams) without the need to purchase other specialised hardware. ShotCodes differ from matrix barcodes in that they do not store regular data - rather, they store a look up number consisting of 40 bits of data. This needs to link to a server that holds information regarding a mapped URL which the reading device can connect to in order to download said data.

History 
ShotCode was created in 1999 at the University of Cambridge when researching a low cost vision based method to track locations and developed TRIPCode as a result. It has been used to track printed TRIPCode paperbadges in realtime with webcams. After that in Cambridge it had another research use; to read barcodes with mobile phone cams, and they used TRIPCode in a round barcode which was named SpotCode. High Energy Magic was founded in 2003 to commercialise research from the University of Cambridge Computer Laboratory and Laboratory for Communications Engineering. Least Bango.net, a mobile company used SpotCode 2004 in their ads. In 2005 High Energy Magic Ltd. sold the entire SpotCode IPR to OP3. Afterwards the name was changed from SpotCode to ShotCode. Heineken was the first company to officially use the ShotCode technology.

ShotCode's software 
The software used to read a ShotCode captured by a mobile camera is called ‘ShotReader’. It is lightweight and is only around 17kB. It ‘reads’ the camera’s picture of a ShotCode in real time and prompts the browsers to navigate to a particular site.

The last website update was from 2007, suggesting that updates for phones based on Android and iPhone will not be available.

See also 
QR Code
Semacode
SPARQCode

External links

Using visual tags to bypass Bluetooth device discovery, Mobile Computing and Communications Review, Volume 9, Number 1, 2005 (by SpotCode people)
SpotCode in action videos from University of Cambridge
RoBCode Generator https://github.com/rbur004/svg_rob_code
 Custom QR Code

Barcodes
Computer-related introductions in 1999
Perry K. Generating Station is a small multi-fired power station producing steam for one of the largest central district steam heating systems in the United States. The plant is located on the south side of downtown Indianapolis, at the intersection of Kentucky Avenue and West Street. Its coal-fired units were among the oldest operating power plants in the United States at the time, and were converted to natural gas in 2016. Perry K. is owned by Citizens Thermal, a division of Citizens Energy Group.

History
In 1892–1893, the Indianapolis Light and Power Company, a predecessor of the Indianapolis Power and Light Company (IPL), constructed a generating plant on Kentucky Avenue near the intersection with West Street. The $300,000 plant, originally known as the "Kentucky Avenue Plant", had a capacity of 1,120 kilowatts. Its output was initially used for street and commercial lighting, but in 1905 the plant was modified to provide steam for the district heating of a number of downtown businesses.

A plant expansion in 1937 included the installation of 650 psig boilers and the use of pulverized coal. That same year the Kentucky Avenue plant and the nearby West plant at 744 West Washington Avenue were renamed as Sections K and W, respectively, of the Charles C. Perry Plant.

In 2000, IPL sold the district heating system and the Perry K plant to Citizens Gas and Coke Utility (later renamed as Citizens Energy Group).

See also

 List of power stations in Indiana

References

External links

Energy infrastructure completed in 1925
Energy infrastructure completed in 1938
Buildings and structures in Indianapolis
Towers in Indiana
Coal-fired power stations in Indiana
1925 establishments in Indiana
District heating in the United States
Lists of horror film characters includes:

By character type
 List of horror film villains
 List of final girls

By series or franchise
 List of Alien (film series) characters
 List of The Texas Chainsaw Massacre characters
 List of Child's Play characters
 List of Evil Dead characters
 List of Final Destination characters
 List of Friday the 13th characters
 List of From Dusk till Dawn characters
 List of The Grudge characters
 List of Halloween (franchise) characters
 List of Hatchet characters
 List of Hellraiser characters
 List of Jurassic Park characters
 List of Let the Right One In characters
 List of The Mummy (film series) characters
 List of A Nightmare on Elm Street characters
 List of Predator (film series) characters
 List of Puppet Master characters
 List of Resident Evil film characters
 List of Ring characters
 List of Saw characters
 List of Scream (film series) characters
 List of Underworld characters

See also
 List of Scream (film series) cast members
 List of cast members of the A Nightmare on Elm Street film series
 List of Hellraiser cast members
 Lists of characters in a fictional work
James Murdock, born David Lee Baker, (June 22, 1931 – December 24, 1981) was an American film and television actor. He was known for playing Mushy in the American western television series Rawhide.

Life and career 
Murdock was born in Normal, Illinois, the son of Faye Baker. He reportedly used the surname "Murdock" because he thought it sounded tougher and would help him get roles. He began his acting career in 1958 playing a young outlaw in the western television series Have Gun, Will Travel. In 1959, he joined the cast of the new CBS western television series Rawhide playing the assistant cook Mushy. Murdock made a guest appearance in a 1966 episode of the western television series Gunsmoke.

Murdock had some small roles in films under the name David Baker, including Some of My Best Friends Are... in 1971 and Airport 1975 and The Godfather Part II in 1974.

Death 
Murdock died on December 24, 1981, of pneumonia in Calabasas, California, at the age of 50. He was buried in Cypress Lawn Memorial Park.

References

External links 

Rotten Tomatoes profile

1931 births
1981 deaths
Deaths from pneumonia in California
People from Normal, Illinois
Male actors from Illinois
American male film actors
American male television actors
20th-century American male actors
Western (genre) television actors
Burials at Cypress Lawn Memorial Park
David Grutman is an owner and partner in several Miami-based restaurants and night clubs. Rolling Stone magazine has listed Grutman as one of the 50 most important people in electronic dance music.

Personal life
David was born and raised in Naples, Florida to a Jewish family. He graduated from Barron G. Collier High School in 1993, and holds a degree in finance from the University of Florida. He married Isabela Rangel in 2016.

Career
Grutman opened the LIV nightclub at the Fontainebleau Miami Beach hotel in 2008, and it was the fifth highest grossing nightclub in the United States in 2014. Grutman subsequently opened the club Story in 2013, followed by the restaurant Komodo, the café OTL, the restaurant Planta South Beach, and the Swan and Bar Bevy, in which Pharrell is also a partner.    

In 2018, Grutman founded Groot Hospitality as a holding company for his ventures. In 2019, he sold a majority stake in the company to Live Nation Entertainment.

References

1974 births
Living people
Nightclub owners
University of Florida alumni
Businesspeople from Miami
People from Naples, Florida
Mark Bradford Watson (born January 23, 1974) is an American former professional baseball pitcher. He played in Major League Baseball for the Cleveland Indians (), Seattle Mariners (), and Cincinnati Reds (), and also played in Japan for the Hiroshima Toyo Carp ().

Amateur career
A native of Atlanta, Georgia, Watson attended the Marist School in Brookhaven, Georgia. He was selected out of high school by the Los Angeles Dodgers in the 21st round of the 1993 MLB Draft but opted to attend Clemson University and the University of Georgia. In 1994, he played collegiate summer baseball in the Cape Cod Baseball League for the Yarmouth-Dennis Red Sox where he tossed a no-hitter and was named a league all-star. He was selected by the Florida Marlins in the 8th round of the 1995 MLB Draft, but did not sign.

Professional career
In 1996, Watson signed with the Milwaukee Brewers as an amateur free agent. In 1998, the Brewers traded him to Cleveland, and Watson made his major league debut with the Indians in 2000, appearing in six games for the big league club. Over the next three years, he made five more big league appearances, three with Seattle and two with Cincinnati. Over 12.1 career major league innings, Watson posted a 10.95 ERA with seven strikeouts and seven walks.

References

External links

1974 births
Living people
Major League Baseball pitchers
Cleveland Indians players
Seattle Mariners players
Cincinnati Reds players
Buffalo Bisons (minor league) players
Akron Aeros players
Clemson Tigers baseball players
Georgia Bulldogs baseball players
Kinston Indians players
Louisville Bats players
Baseball players from Atlanta
American expatriate baseball players in Japan
Hiroshima Toyo Carp players
Tacoma Rainiers players
Colorado Springs Sky Sox players
Iowa Cubs players
Sacramento River Cats players
Long Island Ducks players
Marist School (Georgia) alumni
Yarmouth–Dennis Red Sox players
Reinaldo Román (born 23 May 1984, in Luque) is a Paraguayan footballer playing for 3 de Febrero.

He began his career at Sportivo Luqueño in 2004. Román received first cap at the friendly match against South Africa on 26 March 2008.

References

External links 
 

1984 births
Living people
Paraguayan men's footballers
Paraguay men's international footballers
Men's association football defenders
Sportivo Luqueño players
Club Guaraní players
Expatriate men's footballers in Ecuador
Sportspeople from Luque
Elizabeth Charlotte of Anhalt-Harzgerode (11 February 1647 – 20 January 1723) was a Princess of Anhalt-Harzgerode by birth and by marriage Princess of Anhalt-Köthen and later Duchess of Schleswig-Holstein-Sonderburg-Norburg.

Life 
She was the daughter of Frederick, Prince of Anhalt-Harzgerode and his first wife Princess Johanna Elisabeth of Nassau-Hadamar.  She married twice.  Her first husband was William Louis, Prince of Anhalt-Köthen.  After he died in 1665, she married Duke Augustus, Duke of Schleswig-Holstein-Sonderburg-Plön-Norburg.

From her second marriage she had the following children:
 Joachim Frederick, Duke of Schleswig-Holstein-Sonderburg-Plön (1668-1722), married:
 Magdalena Juliana, Countess of Palatinate-Birkenfeld-Gelnhausen
 Juliana Louise, Princess of Ostfriesland (1698-1721)
 Elisabeth Auguste (1669-1709), a nun at Herford Abbey
 Sophie Charlotte (1672-1720)
 Christian Charles (20 August 1674 – 23 May 1706), married Dorothea Christina of Aichelberg (1674-1762), from 1702 Lady of Karlstein, from 1722 Princess of Denmark
 Johanna Dorothea (24 December 1676 – 29 November 1727), married Prince William II of Nassau-Dillenburg (1670-1724)

After the death of her second husband, she lived at her widow seat, Østerholm Castle on Als Island.  In the dispute about the status of Christian Charles's marriage and his son's ability to inherit Schleswig-Holstein-Plön, she supported her daughter-in-law and former lady-in-waiting Dorothea Christina.

House of Ascania
1647 births
1723 deaths
German princesses
German duchesses
Princesses of Anhalt-Köthen
17th-century German people
18th-century German people
Daughters of monarchs
Remarried royal consorts