Samantha912/NLP_A2_WTH huggingface dataset:
Cyclooctadiene rhodium chloride dimer is the organorhodium compound with the formula Rh2Cl2(C8H12)2, commonly abbreviated [RhCl(COD)]2 or Rh2Cl2(COD)2.  This yellow-orange, air-stable compound is a widely used precursor to homogeneous catalysts.

Preparation and reactions
The synthesis of [RhCl(COD)]2 involves heating a solution of hydrated rhodium trichloride with 1,5-cyclooctadiene in aqueous ethanol in the presence of sodium carbonate:
2 RhCl3·3H2O + 2 COD + 2 CH3CH2OH + 2 Na2CO3 → [RhCl(COD)]2 + 2 CH3CHO + 8 H2O + 2 CO2 + 4 NaCl

[RhCl(COD)]2 is principally used as a source of the electrophile "[Rh(COD)]+."
[RhCl(COD)]2 + L → [LRh(COD)]+Cl− (where L = PR3, alkene, etc. and  = 2 or 3)
In this way, chiral phosphines can be attached to Rh. The resulting chiral complexes are capable of asymmetric hydrogenation.  A related but still more reactive complex is chlorobis(cyclooctene)rhodium dimer. The dimer reacts with a variety of Lewis bases (L) to form adducts with the stoichiometry RhCl(L)(COD).

Structure
The molecule consists of a pair of square planar Rh centers bound to a 1,5-cyclooctadiene and two chloride ligands that are shared between the Rh centers. The Rh2Cl2 core is also approximately planar, in contrast to the highly bent structure of cyclooctadiene iridium chloride dimer where the dihedral angle is 86°.

References

External links

Organorhodium compounds
Homogeneous catalysis
Cyclooctadiene complexes
Dimers (chemistry)
Chloro complexes
Rhodium(I) compounds
The 10th Filmfare Awards were held on 13 June 1963, honoring the best films in Hindi Cinema of the year 1962. 

Sahib Bibi Aur Ghulam led the ceremony with 8 nominations, followed by Bees Saal Baad with 7 nominations.

Bees Saal Baad and Sahib Bibi Aur Ghulam won 4 awards each, thus becoming the most-awarded films at the ceremony.

The ceremony marked the only occasion when all the nominations for Best Actor or Best Actress were for a single actor, with Meena Kumari receiving all 3 nominations for Best Actress for Aarti, Main Chup Rahungi and Sahib Bibi Aur Ghulam, winning for the lattermost.

Mehmood received dual nominations for Best Supporting Actor for his performances in Dil Tera Diwana and Rakhi, winning for the former.

Awards

Best Film
 Sahib Bibi Aur Ghulam 
Bees Saal Baad
Rakhi

Best Director
 Abrar Alvi – Sahib Bibi Aur Ghulam 
Biren Nag – Bees Saal Baad
Mehboob Khan – Son of India

Best Actor
 Ashok Kumar – Rakhi 
Guru Dutt – Sahib Bibi Aur Ghulam
Shammi Kapoor – Professor

Best Actress
 Meena Kumari – Sahib Bibi Aur Ghulam 
Meena Kumari – Aarti
Meena Kumari – Main Chup Rahungi

Best Supporting Actor
 Mehmood – Dil Tera Diwana 
Mehmood – Rakhi
Rehman – Sahib Bibi Aur Ghulam

Best Supporting Actress
 Shashikala – Aarti 
Lalita Pawar – Professor
Waheeda Rehman – Sahib Bibi Aur Ghulam

Best Music Director 
 Professor – Shankar-Jaikishan 
Anpadh – Madan Mohan
Bees Saal Baad – Hemanta Mukherjee

Best Lyricist
 Bees Saal Baad – Shakeel Badayuni for Kahin Deep Jale Kahin Dil 
Anpadh – Raja Mehdi Ali Khan for Aap Ki Nazron Ne
Professor – Hasrat Jaipuri for Aai Gulbadan

Best Playback Singer
 Bees Saal Baad – Lata Mangeshkar for Kahin Deep Jale Kahin Dil 
Anpadh – Lata Mangeshkar for Aap Ki Nazron Ne
Professor – Mohammad Rafi for Aai Gulbadan

Best Story
 Rakhi – K. P. Kottarakara 
Main Chup Rahungi – Jawar N. Sitaraman
Sahib Bibi Aur Ghulam – Bimal Mitra

Best Cinematography, B&W
 Sahib Bibi Aur Ghulam – V. K. Murthy

Best Editing
 Bees Saal Baad – Keshav Nanda

Best Sound
 Bees Saal Baad – S. Y. Pathak

Biggest winners
Sahib Bibi Aur Ghulam – 4/8
Bees Saal Baad – 4/7
Rakhi – 2/4

See also
9th Filmfare Awards
11th Filmfare Awards
Filmfare Awards

Notes

References

Filmfare Awards
Filmfare
1962 in Indian cinema
The Dhanu () is a river in Bangladesh.

The Dhanu, also called the Ghorautra, is a tributary of the Meghna. It flows directly southwards from Sunamganj in Sylhet through the
eastern thanas of Netrakona and Itna Upazila of the district of Kishoreganj of Mymensingh Region. It flows through the Dhanpur,  Itna Sadar, and Elongjuri union of the Itna Upazila. It is navigable
year-round. It falls and rises with the daily tides and even the canals connected with it a long way inland, at places like Gag Bazar and Badla, experience the effect of these tides.

References

Rivers of Bangladesh
Rivers of Sylhet Division
Kataphraktosaurus is a genus of the lizard family Gymnophthalmidae. The genus is monotypic, i.e. it has only one species, Kataphraktosaurus ungerhamiltoni. It occurs in Venezuela.

References

Gymnophthalmidae
Lizard genera
Reptiles of Venezuela
The 2014 Boston Pizza Cup, the provincial men's curling championship for Alberta, was held from February 5 to 9 at the Lacombe Curling Club in Lacombe, Alberta. The winner represented Alberta at the 2014 Tim Hortons Brier in Kamloops.

Qualification process
Twelve teams qualified for the provincial tournament through several methods. The qualification process is as follows:

Teams

Knockout Draw Brackets

A Event

B Event

C Event

Results
All draws are listed in Mountain Standard Time (UTC−7).

Draw 1
Wednesday, February 5, 9:30 am

Draw 2
Wednesday, February 5, 6:30 pm

Draw 3
Thursday, February 6, 9:00 am

Draw 4
Thursday, February 6, 2:00 pm

Draw 5
Thursday, February 6, 6:30 pm

Draw 6
Friday, February 7, 9:00 am

Draw 7
Friday, February 7, 2:00 pm

Draw 8
Friday, February 7, 6:30 pm

Draw 9
Saturday, February 8, 1:00 pm

Playoffs

A vs. B
Saturday, February 8, 6:30 pm

C1 vs. C2
Saturday, February 8, 6:30 pm

Semifinal
Sunday, February 9, 9:00 am

Final
Sunday, February 9, 2:00 pm

References

External links

Curling in Alberta
Boston Pizza Cup
Boston Pizza Cup
Lacombe, Alberta
2014 in Alberta
Platyceps schmidtleri is a species of snake of the family Colubridae.

The snake is found in Iran.

References 

schmidtleri
Reptiles described in 2001
Dada is a 1979 Hindi Bollywood film directed and produced by Jugal Kishore, starring Vinod Mehra, Bindiya Goswami, Amjad Khan, Jeevan in pivotal roles.

Cast 

 Vinod Mehra as Moti / Jeetu 
 Bindiya Goswami as Kamini
 Amjad Khan as Fazlu
 Jeevan as Bihari
 Raza Murad as Raghu / Jaggu (Double Role)
 Jagdeep as Jagdeep / Fake Moti
 Shashi Puri as Basheer
 Madhu Malini as Bobby 
 Ramesh Deo as Pyarelal 
 Indrani Mukherjee as Mrs. Pyarelal
 Satyendra Kapoor as Dharamdas
 Seema Deo as Tara 
 Pallavi Joshi as Munni
 Rajendranath as Alibhai Motorwala
 Mohan Sherry as Lawyer / Public Prosecutor

Soundtrack 
Music composed by Usha Khanna.

Trivia 
The film was titled "Dadaon Ka Dada"

Awards and nominations 
 Filmfare Award for Best Supporting Actor - Amjad Khan as Fazlu
 Filmfare Award for Best Male Playback Singer - K. J. Yesudas for the song "Dil Ke Tukde Tukde Karke"

References 

1979 films
1970s Hindi-language films
Films scored by Usha Khanna
Forchhammer is a surname. Notable people with the surname include:

August Friedrich Wilhelm Forchhammer (1797–1870), Danish jurist and writer
Bjarne Forchhammer (1903–1970), Danish actor and theatre director
Henni Forchhammer (1863–1955), Danish teacher and women's rights activist
Johan Georg Forchhammer (1794–1865), Danish mineralogist and geologist
Johannes Nicolai Georg Forchhammer (1827–1909), Danish philologist
Johannes Georg Forchhammer (1861–1938), Danish physicist and educator
Lukas Forchhammer (born 1988), Danish singer, songwriter, actor, and frontman of Lukas Graham
Peter Wilhelm Forchhammer (1801–1894), German classical archaeologist

Danish-language surnames
Nicola Rosenblum is an Australian diplomat who served as High Commissioner to Brunei Darussalam from 2016 to 2020. She has served as Deputy Head of the ANU National Security College, on secondment from the Department of Foreign Affairs and Trade, since October 2021.

Biography
Rosenblum earned a Bachelor of Arts in Politics and Government with Honours from Griffith University and a Graduate Certificate in Humanitarian Leadership from Deakin University.

References 

Australian women ambassadors
Living people
Year of birth missing (living people)
Griffith University alumni
Deakin University alumni
High Commissioners of Australia to Brunei
Morantel is an anthelmintic drug used for the removal of parasitic worms in livestock. It affects the nervous system of worms given the drug is an inhibitor of acetylcholinesterase. It is derived in part from 3-methylthiophene. Morantel is closely related to pyrantel.

References

Anthelmintics
Veterinary drugs
Thiophenes
Paramoron is a genus of longhorn beetles of the subfamily Lamiinae, containing the following species:

 Paramoron diadematum (Heller, 1910)
 Paramoron singulare Aurivillius, 1908

References

Pteropliini
The 2006–07 Scottish Challenge Cup was the 16th season of the competition, competed for by all 30 members of the Scottish Football League.

Ross County and Clyde were the finalists, the final was played at McDiarmid Park, Perth and was won on penalties by Ross County.

Schedule

First round

North and East region 
Alloa Athletic received a random bye into the second round.

Source: ESPN Soccernet

South and West region 
Clyde received a random bye into the second round.

Source: ESPN Soccernet

Second round

Source: ESPN Soccernet

Quarter-finals

Semi-finals

Final

Top scorers

4 goals
 Scott Chaplain – Albion Rovers

3 goals
 Craig Gunn – Ross County
 Kevin McKinlay – Ross County
 Paul McGowan – Greenock Morton

References

External links 
 BBC Scottish Cups page
 Scottish Football League Challenge Cup page

Scottish Challenge Cup seasons
Challenge Cup
Michael Weeder  is the current Dean of St. George's Cathedral, Cape Town.

Notes

External links 
 Michael Weeder's testimony to the Truth and Reconciliation Commission
 St. George's Cathedral

Living people
20th-century South African Anglican priests
21st-century South African Anglican priests
Deans of Cape Town
Year of birth missing (living people)
Wheeler Creek is a stream in the U.S. state of Indiana. It is a tributary of Eel River.

The namesake of Wheeler Creek is unknown.

See also
List of rivers of Indiana

References

Rivers of Kosciusko County, Indiana
Rivers of Wabash County, Indiana
Rivers of Whitley County, Indiana
Rivers of Indiana
Christian Chaubet (born 19 July 1961) is a former French racing cyclist. He rode in three editions of the Tour de France and one edition of the Giro d'Italia.

References

External links

1961 births
Living people
French male cyclists
Sportspeople from Toulouse
Cyclists from Occitania (administrative region)
La Rue sans nom is a novel by Marcel Aymé, published in June 1930. It was adapted into a film in 1934 by Pierre Chenal.

Plot
The story focuses on a street in the Parisian banlieue where Italian and French workers reside. Their neighborhood will soon be demolished, but a mysterious character hides himself in this street.

The main themes are xenophobia, poverty, the importance of alcohol, love, madness and aging.

Film adaptation
Street Without a Name (2 February 1934), directed by Pierre Chenal

Notes and references

Novels by Marcel Aymé
1930 French novels
Novels set in Paris
French novels adapted into films
Pedro Duarte may refer to
Pedro Duarte (general) (1829–1902), Paraguayan general
Pedro Duarte (footballer, born 1972), Portuguese goalkeeper 
Pedro Duarte (footballer, born 1978), Portuguese left-back footballer
Nikolina Knežević may refer to:
 Nikolina Knežević (handballer)
 Nikolina Knežević (basketball)
Kids Helpline is a free Australian telephone and online counselling service for young people aged between 5 and 25. Counsellors respond to more than 6,000 calls each week about issues ranging from relationship breakdown and bullying to sexual abuse, homelessness, suicidal thoughts, depression and drug and alcohol usage.

Funding 
The service is primarily funded by yourtown, an Australian youth community services organisation, which provides the Kids Helpline service. Supported by the Australian Government (through the Department of Health and Aged Care and the Australian Human Rights Commission), the Queensland Government, and Government of Western Australia. It is also supported by corporate sponsors, Optus, Bupa, Future Generation Investment Company, and First National Real Estate.

Counselling methods 
All counsellors that provide services through Kids Helpline are university-qualified and are formal employees of yourtown.

 Phone Counselling. Free counselling over the phone available 24 hours a day, 7 days a week on 1800 55 1800. The service is a freecall number from all mobiles on Australian carriers, landlines and public payphones.
 Online Counselling. Called 'WebChat', Kids Helpline counselling is also available online through the website. This service is available 24 hours a day, 7 days a week. Generally, this service has high wait times, ranging up to 50 minutes during peak times in evenings.
 Email Counselling. Kids Helpline also provides email counselling through counsellor@kidshelpline.com.au. The inbox is answered from 8am to 10pm daily, with response times often being within a few days.

Long-term users of the service can also access case management through Kids Helpline, as well as "wrap around care" where a trusted adult is involved in ensuring a child's welfare. Kids Helpline can also refer patients onwards to more formal and in-person services.

See also
Crisis hotline
List of suicide crisis lines
Lifeline (crisis support service)
Beyond Blue

References

External links

Child-related organisations in Australia
Crisis hotlines
Thaweekun Thong-on (), born March 1, 1998) is a Thai professional footballer who plays as an attacking midfielder for Thai League 3 side Sisaket United.

External links

1998 births
Living people
Thaweekun Thong-on
Thaweekun Thong-on
Men's association football midfielders
Thaweekun Thong-on
Thaweekun Thong-on
Thaweekun Thong-on
This is a list of hospitals in Nicaragua.
Bautista Hospital
Bertha Calderón (De la Mujer) Hospital
Carlos Marx (Alemán-Nicaragüense) Hospital
Alejandro Davila Bolaños Hospital (Military)
Japanese-Nicaraguan Hospital (Hospital Japonés-Nicaragüense)
Manuel de Jesús Rivera,"La Mascota" Hospital
Antonio Lenin Fonseca (Trauma) Hospital
Manolo Morales (Roberto Calderón) Hospital
Hospital Salud Integral
Metropolitano Vivian Pellas Private Hospital (and Child Burn Unit)
Psychiatric Hospital
Fernando Vélez Paiz, Pediatric Hospital
La Mascota Pediatric Hospital
Hospital Regional Santiago (Jinotepe, Carazo) 
Hospital San José (Diriamba, Carazo)
Hospital Santa Gema, Masaya (offers 24hr emergency)

References

Nicaragua
Hospitals
Hospitals
N
The University of Bohol, also referred to by its acronym U.B., is a private nonsectarian co-educational basic and higher education institution institution of higher learning in Tagbilaran City, Bohol, Philippines. It is the first university to be established in the province of Bohol.

History 
It was established as the Rafael Palma College in 1946. Its main building is situated along Maria Clara Street.

Notable alumni
 Rear Admiral Margarito Villamor Sanchez Jr. AFP
 Napoleon Abueva, national artist in sculpture

References

External links 
 University of Bohol website

Universities and colleges in Bohol
Education in Tagbilaran
Universities and colleges established in 1946
1946 establishments in the Philippines
Crossover may refer to:

Entertainment

Albums and songs
 Cross Over (Dan Peek album)
 Crossover (Dirty Rotten Imbeciles album), 1987
 Crossover (Intrigue album)
 Crossover (Hitomi Shimatani album)
 Crossover (Yoshinori Sunahara album), 1995
 "Cross Over" (song), a 2013 single by the Japanese girl idol group 9nine
 "Crossover" (song), by EPMD

Comics
 Cross Over (manga), by Kouji Seo
 Crossover (storyline), a 2005 Fantastic Four storyline
 The Crossovers, a 2003 CrossGen comic book series
 Crossover (Image Comics), a 2020 comic book series

Film and television
 Crossover (1980 film), a 1980 film
 Crossover (2006 film), a 2006 basketball drama by Preston A. Whitmore II
 "Crossover" (Adventure Time), a 2016 episode of the animated series Adventure Time
 "Crossover" (Star Trek: Deep Space Nine), a 1994 episode of Star Trek: Deep Space Nine

Other entertainment
 Crossover (fiction), a storyline combining characters or settings from separate fictional properties
 Intercompany crossover, a comic or series of comics where characters that at the time of publication are the property of one company meet those owned by another company
 Crossover music, a performer or work that finds success in multiple genres
 Crossover (theater), a passage for actors to move across a stage without being seen by the audience
 Crossover thrash, a musical genre combining thrash metal and hardcore punk
 Crossover (video games)
 Crossovers (dance), moves from the dance Balboa
 The Crossover, a 2014 book by Kwame Alexander

Science
 Crossover (genetic algorithm), a genetic operator that varies a chromosome's programming between generations
 Crossover experiment (chemistry), a method for studying the mechanism of chemical reactions
 Crossover, a generic term for a smooth phase transition in physics
 Crossover study, a type experimental design in a clinical trial
 Crossover distortion, a type of electronic distortion
 Chromosomal crossover, an exchange of genetic material between homologous chromosomes
 Mitotic crossover, a type of genetic recombination

Sports
 Crossover (figure skating), a technique for gaining impetus while skating along a curve
 Crossover (football trick)
 Crossover dribble, a basketball move
 Colorado Crossover, a basketball team
 Fayetteville Crossover, a semi-professional basketball team in Fayetteville, North Carolina

Technology
 Audio crossover, a type of electronic filter circuitry used to divide an audio signal into two or more frequency ranges
 CrossOver (software), Windows compatibility layer software
 Crossover cable, crossover cables in general
 Crossover switch, a switch connecting multiple inputs to multiple outputs
 Ethernet crossover cable, a cable for directly connecting two pieces of equipment

Transportation
 Crossover (automobile), a sport utility vehicle built on a car platform
 Crossover (rail), a configuration of railway track
 EuroSport Crossover, an electric glider and ultralight aircraft

Other
 Crossover, a former music radio station, currently an internet radio based in the Philippines
 Crossover effects, a concept in linguistics concerning interactions between words
 Crossover, a piece of dog agility equipment
Trifolium cherleri, the cupped clover, is a species of flowering plant in the family Fabaceae. It is native to the Canary Islands, the Mediterranean, and the Middle East as far east as Iran, and it has been introduced to Australia as a forage. Three cultivars have been developed in Australia; 'Beenong', 'Yamina' and 'Lisare'.

References

cherleri
Forages
Flora of the Canary Islands
Flora of North Africa
Flora of Southwestern Europe
Flora of Southeastern Europe
Flora of Western Asia
Plants described in 1753
Taxa named by Carl Linnaeus
The 1922 Tipperary Senior Hurling Championship was the 31st staging of the Tipperary Senior Hurling Championship since its establishment by the Tipperary County Board in 1887, held after a two-year hiatus.

Toomevara were the defending champions.

Boherlahan won the championship after a 5–01 to 2–03 defeat of a North Selection in the final. It was their fifth  championship title overall and their first title since 1919.

References

Tipperary
Tipperary Senior Hurling Championship
Events from the year 1539 in India.

Events
 Guru Angad Dev becomes second guru of Sikhism.
 Suhungmung's reign as king of Ahom ends with his death (began 1497).
 Suklenmung succeeds his father as king of Ahom (reigns until 1552)

Births

Deaths
 Suhungmung, king of Ahom

See also

 Timeline of Indian history

 
India
Rockingham is a village and civil parish in North Northamptonshire, England. Close to the border of Leicestershire and Rutland, the village is largely connected to the town of Corby where various local organisations utilise the Rockingham name. Other nearby villages include Cottingham, Great Easton and Caldecott. During the 2001 census, the parish's population was 115 people, falling marginally to 113 at the 2011 Census.

The village is the site of Rockingham Castle and gives its name to Rockingham Forest; the title Marquess of Rockingham; Rockingham Primary School in Corby; as well as Rockingham Motor Speedway which is located in North Northamptonshire.

History

The village's name means 'Homestead/village of the people of Hroc(a)'.

Rockingham was the site of a council convened by William II on 25 February 1095, intended to depose Anselm as Archbishop of Canterbury. The Lords Spiritual, led by the Bishop of Durham, fell in line with the king, arguing that Anselm's support of the French-backed pope Urban II against the imperial pope Clement III made him a traitor to the realm. The Lords Temporal demurred and supported Anselm, in the absence of any proof of felony.

References

External links

Villages in Northamptonshire
Civil parishes in Northamptonshire
North Northamptonshire
Brayville is an unincorporated area of southern Campbell County, Kentucky, in the United States. It is located approximately 23 miles southeast of Cincinnati, Ohio.

The Brayville Post Office is catalogued as a postal office by the U.S. Board on Geographic Names, however the post office itself no longer exists. The current zip code for residents of Brayville is 41007 (California, Kentucky), although California is located approximately 12 miles from Brayville, along the Ohio River. Brayville itself is located high upon a hillside along Kentucky Highway 154 (also known as Peach Grove Road), providing sweeping views of southern Greater Cincinnati. Brayville has an elevation of approximately .

Brayville was also once home to the Brayville Saloon and Brayville School, which eventually closed after Grant's Lick Elementary was built in 1935.

References

1. http://www.placekeeper.com/Kentucky/Brayville_Post_Office-2564920.html
2. http://www.roadonmap.com/us/where-is/Brayville_Post_Office_historical-Campbell_KY,post_office

Brayville, Kentucky  

Geography of Campbell County, Kentucky
A Tiger's Tale is a 1987 American comedy-drama film starring Ann-Margret and C. Thomas Howell, written and directed by Peter Douglas, based on the novel Love and Other Natural Disasters by Allen Hannay III.

Plot
Bubber Drumm is a Houston high school student. Rose Butts is an alcoholic, more than twice his age, and the mother of his girlfriend, Shirley. Bubber and Rose begin an affair after Bubber fixes Shirley up with his pal, Ransom McKnight.

Bubber and Rose carry on their affair under the nose of her daughter until everything comes out in the open at a drive-in movie theater. To get even with Bubber and Rose for "behaving badly", Shirley pricks a hole in Rose's diaphragm. Shirley goes on to live with her father and Bubber moves in with Rose along with his pet tiger. The diaphragm incident results in Rose getting pregnant with Bubber's baby. The couple must decide whether to keep the baby and continue their May/December romance or part ways.

Principal cast

Music
The non-score music is by the Textones (Carla Olson, Phil Seymour, Joe Read, George Callins, Tom Jr Morgan).

Critical reception
Roger Ebert of The Chicago Sun-Times gave the film 2 out of 4 stars although he did like certain aspects of the film:

Janet Maslin of The New York Times:

References

External links 

1987 films
1980s coming-of-age comedy-drama films
1980s sex comedy films
1980s pregnancy films
American coming-of-age comedy-drama films
American sex comedy films
Atlantic Entertainment Group films
Films based on American novels
Films based on romance novels
Films scored by Lee Holdridge
Films set in Houston
Films shot in Texas
1980s American films
Films produced by Peter Douglas
Films directed by Peter Douglas
Films with screenplays by Peter Douglas
Thomas Cushing (1725–1788) was an American lawyer, merchant and statesman from Boston, Massachusetts.

Thomas Cushing may also refer to:
 Thomas Cushing II (1694–1746), American merchant, lawyer and politician in Massachusetts
 Thomas Forbes Cushing (1838–1902), American member of Boston, New York, and Newport society during the Gilded Age
 Thomas Humphrey Cushing (1755–1822), American army officer and collector of customs
 Tom Cushing (1879–1941), American playwright