In fluid dynamics, Stokes' law is an empirical law for the frictional force – also called drag force – exerted on spherical objects with very small Reynolds numbers in a viscous fluid.  It was derived by George Gabriel Stokes in 1851 by solving the Stokes flow limit for small Reynolds numbers of the Navier–Stokes equations.

Statement of the law
The force of viscosity on a small sphere moving through a viscous fluid is given by:

where (in SI units):
  is the frictional force – known as Stokes' drag – acting on the interface between the fluid and the particle (newtons, kg m s−2);
  (some authors use the symbol ) is the dynamic viscosity (Pascal-seconds, kg m−1 s−1);
  is the radius of the spherical object (meters);
  is the flow velocity relative to the object (meters per second).

Stokes' law makes the following assumptions for the behavior of a particle in a fluid:
Laminar flow
Spherical particles
Homogeneous (uniform in composition) material
Smooth surfaces
Particles do not interfere with each other.

For molecules Stokes' law is used to define their Stokes radius and diameter.

The CGS unit of kinematic viscosity was named "stokes" after his work.

Applications

Stokes' law is the basis of the falling-sphere viscometer, in which the fluid is stationary in a vertical glass tube. A sphere of known size and density is allowed to descend through the liquid. If correctly selected, it reaches terminal velocity, which can be measured by the time it takes to pass two marks on the tube. Electronic sensing can be used for opaque fluids. Knowing the terminal velocity, the size and density of the sphere, and the density of the liquid, Stokes' law can be used to calculate the viscosity of the fluid. A series of steel ball bearings of different diameters are normally used in the classic experiment to improve the accuracy of the calculation. The school experiment uses glycerine or golden syrup as the fluid, and the technique is used industrially to check the viscosity of fluids used in processes. Several school experiments often involve varying the temperature and/or concentration of the substances used in order to demonstrate the effects this has on the viscosity. Industrial methods include many different oils, and polymer liquids such as solutions.

The importance of Stokes' law is illustrated by the fact that it played a critical role in the research leading to at least three Nobel Prizes.

Stokes' law is important for understanding the swimming of microorganisms and sperm; also, the sedimentation of small particles and organisms in water, under the force of gravity.

In air, the same theory can be used to explain why small water droplets (or ice crystals) can remain suspended in air (as clouds) until they grow to a critical size and start falling as rain (or snow and hail). Similar use of the equation can be made in the settling of fine particles in water or other fluids.

Terminal velocity of sphere falling in a fluid 

At terminal (or settling) velocity, the excess force  due to the difference between the weight and buoyancy of the sphere (both caused by gravity) is given by:

where (in SI units):
 is the mass density of the sphere [kg/m3]
 is the mass density of the fluid [kg/m3]
 is the gravitational acceleration [m/s]
Requiring the force balance  and solving for the velocity  gives the terminal velocity . Note that since the excess force increases as  and Stokes' drag increases as , the terminal velocity increases as  and thus varies greatly with particle size as shown below. If a particle only experiences its own weight while falling in a viscous fluid, then a terminal velocity is reached when the sum of the frictional and the buoyant forces on the particle due to the fluid exactly balances the gravitational force. This velocity  [m/s] is given by:

where (in SI units):
  is the gravitational field strength [m/s2]
  is the radius of the spherical particle [m]
  is the mass density of the particle [kg/m3]
  is the mass density of the fluid [kg/m3]
  is the dynamic viscosity [kg/(m•s)].

Derivation

Steady Stokes flow

In Stokes flow, at very low Reynolds number, the convective acceleration terms in the Navier–Stokes equations are neglected. Then the flow equations become, for an incompressible steady flow:

where:
  is the fluid pressure (in Pa),
  is the flow velocity (in m/s), and
  is the vorticity (in s−1), defined as  

By using some vector calculus identities, these equations can be shown to result in Laplace's equations for the pressure and each of the components of the vorticity vector:

   and   

Additional forces like those by gravity and buoyancy have not been taken into account, but can easily be added since the above equations are linear, so linear superposition of solutions and associated forces can be applied.

Transversal flow around a sphere

For the case of a sphere in a uniform far field flow, it is advantageous to use a cylindrical coordinate system . The –axis is through the centre of the sphere and aligned with the mean flow direction, while  is the radius as measured perpendicular to the –axis. The origin is at the sphere centre. Because the flow is axisymmetric around the –axis, it is independent of the azimuth .

In this cylindrical coordinate system, the incompressible flow can be described with a Stokes stream function , depending on  and :

with  and  the flow velocity components in the  and  direction, respectively. The azimuthal velocity component in the –direction is equal to zero, in this axisymmetric case. The volume flux, through a tube bounded by a surface of some constant value , is equal to  and is constant.

For this case of an axisymmetric flow, the only non-zero component of the vorticity vector  is the azimuthal –component 

The Laplace operator, applied to the vorticity , becomes in this cylindrical coordinate system with axisymmetry:

From the previous two equations, and with the appropriate boundary conditions, for a far-field uniform-flow velocity  in the –direction and a sphere of radius , the solution is found to be

The solution of velocity in cylindrical coordinates and components follows as:

The solution of vorticity in cylindrical coordinates follows as:

The solution of pressure in cylindrical coordinates follows as: 

The solution of pressure in spherical coordinates follows as: 

The formula of pressure is also called dipole potential analogous to the concept in electrostatics. 

A more general formulation, with arbitrary far-field velocity-vector , in cartesian coordinates  follows with:

In this formulation the non-conservative term represents a kind of so-called Stokeslet. The Stokeslet is the Green's function of the Stokes-Flow-Equations. The conservative term is equal to the dipole gradient field. The formula of vorticity is analogous to the Biot–Savart law  in electromagnetism.

The following formula describes the viscous stress tensor for the special case of Stokes flow. It is needed in the calculation of the force acting on the particle. In Cartesian coordinates the vector-gradient  is identical to the Jacobian matrix. The matrix  represents the identity-matrix. 

The force acting on the sphere is to calculate by surface-integral, where  represents the radial unit-vector of spherical-coordinates:

Rotational flow around a sphere

Other types of Stokes flow

Although the liquid is static and the sphere is moving with a certain velocity, with respect to the frame of sphere, the sphere is at rest and liquid is flowing in the opposite direction to the motion of the sphere.

See also
 Einstein relation (kinetic theory)
 Scientific laws named after people
 Drag equation
 Viscometry
 Equivalent spherical diameter
 Deposition (geology)

Sources 
 
 Originally published in 1879, the 6th extended edition appeared first in 1932.

References

Fluid dynamics