Samantha912/NLP_A2_WTH huggingface dataset:
In chemistry, a transition metal ether complex is a coordination complex consisting of a transition metal bonded to one or more ether ligand. The inventory of complexes is extensive.  Common ether ligands are diethyl ether and tetrahydrofuran.  Common chelating ether ligands include the glymes, dimethoxyethane (dme) and diglyme, and the crown ethers. Being lipophilic, metal-ether complexes often exhibit solubility in organic solvents, a property of interest in synthetic chemistry.  In contrast, the di-ether 1,4-dioxane is generally a bridging ligand.

Bonding, structure, reactions

Ethers are L-type ligands. They are σ-donors that exert weak field ligands.  They resemble water ligands as seen in aquo complexes. They do not, however, readily participate in hydrogen bonding.  The ether oxygen is nearly trigonal planar in its complexes.

Being weakly basic, ether ligands tend to be easily displaceable.  Otherwise, ether ligands are relatively unreactive. Cyclic ethers such as thf can ring-open or even deoxygenated when bound to highly electrophilic metal halides.  Thus treatment of tungsten hexachloride with one equivalent of thf gives 1,4-dichlorobutane:

At higher concentrations of thf, polytetrahydrofuran is produced.

Examples

Homoleptic complexes
Ethers are relatively bulky ligands, thus homoleptic (i.e., all ligands being the same) ether complexes are uncommon.   Examples often feature weakly coordinating anions such as BArF4− and Al(ORF)4−.
[V(thf)6](BArF4)2
[Mn(thf)6](Mn(CO)5]2
[[Fe(thf)6]][BArF24]2
[Ni(thf)6][Al(ORF)4 ]2

Metal halide complexes

Metal chloride-tetrahydrofuran complexes are especially studied. These compounds are often reagents because they are soluble in organic solvents as well as being anhydrous.

Metal carbonyl complexes
M(CO)5(thf) (M = Cr, Mo, W)
Mo(CO)3(diglyme)

References

Coordination chemistry
Coordination complexes
Saint-Romain-sous-Gourdon (, literally Saint-Romain under Gourdon) is a commune in the Saône-et-Loire department in the region of Bourgogne-Franche-Comté in eastern France.

It is 45 km south west of Chalon-sur-Saône, 25 km due south of Le Creusot and 6 km south east of Montceau-les-Mines.

See also
Communes of the Saône-et-Loire department

References

Communes of Saône-et-Loire
Nocturnal Omissions was the final, posthumous release by Athens, Georgia, United States, band Dreams So Real.  Self-released in 1992, it was a collection of unreleased and rare tracks.

Track listing
 "(Maybe I'll Go) Today"
 "Heaven"
 "Window"
 "History"
 "Up To Fate"
 "Golden"
 "Everywhere Girl"
 "Whirl"
 "And So We Love"
 "Open Your Eyes"
 "Entwined"
 "A Shipwrecked Sailor"
 "Appalachee Shoals"
 "Please Don't Cry"
 "In The Garden"
 "Egypt"
 "There's A Fire"
 "Red Lights (Merry Christmas)"
 "Just For Christmas Day"

Dreams So Real albums
1992 albums
The Miss Armenia (Armenian: Միսս Հայաստան; Miss Hayastan) is the national beauty pageant in Armenia. Its winners represent Armenia in Miss Universe, Miss World, and Miss Grand International.

History

Miss Armenia also debuted in 2017 with Miss World and in 2018 with Miss Universe. Through the Miss Armenia pageant, the winners represented her country at Miss Universe and Miss World.

It has been several years the competition "Miss Armenia" isn't being held in Armenia. "Miss Armenia" competition was first held in 1996, with certain intervals, up to 2012. Here are the winners of the "Miss Armenia" beauty competition.

After 6 years of hiatus, the Miss Armenian 2017 contest returned under the support of Armenian ministry of culture. The contest took take place in Armenian National Academic Theatre of Opera and Ballet in Yerevan.

On May 11, 2019 the original of Miss Hayastan (old, Miss Armenia) returned to hold national beauty pageant. There are two Miss Armenia contests such as Miss Hayastan (Miss Armenia) and Miss Armenian (for Miss Universe and Miss World Armenia).

In 2021, the  Miss Armenian organization purchased the license of the Miss Grand International for Armenian, which the Armenian American Kristina Ayanian was appointed to represent the country at the pageant, Ayanian was the second Armenian candidate for the said pageant following Lily Sargsyan (Miss Armenian 2017) who took part in its 2019 edition in Venezuela.

Titleholders
Color key

1996–2017

2018–present
Began 2018 the Miss Armenian separated the franchise of Miss Universe and Miss World national contest in two selections. First, the Miss Universe Armenia will crown the winner earlier than Miss World Armenia in different date before coming to International pageants. The Miss World Armenia will be crowned the new title holder in the last ending of Miss Armenia section. Armenia debuts at Miss Universe in 2018 while in 2017 Armenia started to join at the Miss World in China. Later in 2021, the organization also acquired the license of the Miss Grand International for Armenia.

Titleholders under Miss Armenia org.
The following women have represented Armenia in the international beauty pageants. The highest placement was the winner of Miss Commonwealth of CIS in 1998, won by Gohar Harutunyan, the current CEO of Miss Armenian organization.

Miss Universe Armenia

Miss World Armenia

Miss Grand Armenia 

Armenia made its debut at the Miss Grand International pageant in 2019 by Lili Sargsyan, Miss Armenia 2017 winner, under the direction of  Janna Gregory. The Miss Armenia organization later purchased the franchise in 2021..

References

External links
 missarmenia.org

 

Armenia
Armenia
Armenia
Beauty pageants in Armenia
1996 establishments in Armenia
Armenian awards
This is a list of the National Register of Historic Places listings in Cincinnati, Ohio.

This is intended to be a complete list of the properties and districts on the National Register of Historic Places in Cincinnati, Ohio, United States. Latitude and longitude coordinates are provided for many National Register properties and districts; these locations may be seen together in an online map.

There are 381 properties and districts listed on the National Register in Hamilton County, including 14 National Historic Landmarks. The city of Cincinnati is the location of 284 of these properties and districts, including 12 National Historic Landmarks; they are listed here, while the remaining properties and districts, including 3 National Historic Landmarks, are listed separately.

Number of listings by region
The properties are distributed across all parts of Cincinnati. For the purposes of this list, the city is split into three regions: Downtown Cincinnati, which includes all of the city south of Central Parkway, west of Interstates 71 and 471, and east of Interstate 75; Eastern Cincinnati, which includes all of the city outside Downtown Cincinnati and east of Vine Street; and Western Cincinnati, which includes all of the city outside Downtown Cincinnati and west of Vine Street. One district, the Over-the-Rhine Historic District, is split between Eastern and Western Cincinnati.

See also 
 List of National Historic Landmarks in Ohio
 National Register of Historic Places listings in Ohio

References
RFID is a wireless technology supported by many different vendors for tags (also called transponders or smart cards) and readers (also called interrogators or terminals). In order to ensure global operability of the products multiple test standards have been developed. Furthermore, standardization organizations like ETSI organize RFID Plugtests, where products from multiple vendors are tested against each other in order to ensure interoperability.

Test standards
The most important test standards are:

ISO/IEC 10373-6 for conformance to ISO/IEC 14443
ISO/IEC 10373-7 for conformance to ISO/IEC 15693
ISO/IEC 18047  multiple parts for conformance to ISO/IEC 18000 multiple parts
ISO/IEC 18046  multiple parts for performance of ISO/IEC 18000 systems, interrogators and tags

Testing Equipment Vendors 
  CISC Semiconductor GmbH
 JX Instrumentation Ltd
 Voyantic Ltd

Testing Vendors 
 MET Laboratories, Inc.
 TRaC Global
 FIME
 Arsenal Testhouse

Reference

External links
Toptag RFID Reader

Radio-frequency identification
Queen River or Queen of the River or River Queen or variant, may refer to:

Queen River
 Queen River, Tasmania; a tributary of the King River in Australia
 Queen River (Rhode Island); a river in the United States of America
 Quinn River (Nevada, USA); a river formerly known as "Queen River"

River Queen
 Paddle steamer nickname
 ; a U.S. steamboat
 River Queen (2005 film) a New Zealand war film
 Riverqueen; a French thoroughbred racehorse

See also
 Queen (disambiguation)
 River (disambiguation)
Ramon Torres Mendez (July 2, 1969 - September 1993) was a Mexican American who was a high-ranking member of the Logan Heights Gang, recruited by David "D" Barron in 1993. He reportedly served as a hitman to its leaders who trained him to carry out an assassination attempted against the Tijuana Cartel major rival Joaquín Guzmán Loera.

On May 24, 1993, he and other Logan Heights Gang members were assigned to kill Joaquín Guzmán Loera at the Guadalajara Airport but in the shoot-out that followed, six bystanders were killed, including the Roman Catholic Cardinal Juan Jesus Posadas Ocampo. Mendez was arrested in late June 1993.

Death 
On September 1993, Mendez was killed inside a Mexican prison by other inmates while awaiting trial for murder.

References

American people of Mexican descent
People from San Diego
1993 deaths
Tijuana Cartel traffickers
1969 births
Mexican people who died in prison custody
Hispanic and Latino American gangsters
The Church of the Holy Cross (Episcopal), which housed St. Mark's until 1954, is a historic church at 875 Cotton Street in Shreveport, Louisiana, United States.  The first services of the Episcopal church in Shreveport were celebrated by the Rt. Rev. Leonidas Polk, the Bishop of Louisiana in March 1839.  That liturgy is considered the founding day of St. Mark's Church.  Prior to this church building, the church was located on Fannin Street.  St. Mark's moved into a new church building at Fairfield Avenue and Rutherford Street in 1954.  That church became the cathedral of the Diocese of Western Louisiana on July 7, 1990.

Holy Cross was formed because a group of Episcopalians from St. Mark's felt that the Church should maintain a presence in the inner city. It owns and operates a number of ministries around Shreveport, but most notably it runs Holy Cross Hope House. Hope House is a day shelter down the street for homeless people.

Holy Cross is also known for its progressive attitude toward social issues. It is one of the few churches in North Louisiana that will marry gay couples. It is also known for its traditional worship style. It had an E.M. Skinner organ built in 1920, another large Aeolian-Skinner organ was ordered in 1956.

The current rector is the Reverend Garrett Boyte, M.Div.

Holy Cross has been served by the Reverend Mary Richard (2008-2019), and the Reverend Kenneth W. Paul (1968-2008).

The church was added to the National Register of Historic Places in 1991. It also became a contributing property of Shreveport Commercial Historic District when its boundaries were increased on .

See also
National Register of Historic Places listings in Caddo Parish, Louisiana

References

External links
The Website for Holy Cross

Episcopal church buildings in Louisiana
Churches on the National Register of Historic Places in Louisiana
Gothic Revival church buildings in Louisiana
Religious organizations established in 1839
Churches completed in 1905
Churches in Shreveport, Louisiana
National Register of Historic Places in Caddo Parish, Louisiana
Individually listed contributing properties to historic districts on the National Register in Louisiana
1839 establishments in Louisiana
is a railway station located in Kitakyūshū, Fukuoka.

Lines 

Chikuhō Electric Railroad
Chikuhō Electric Railroad Line

Platforms

Adjacent stations

Surrounding area
 Hagiwara Housing Complex
 Hagiwara Central Hospital
 Anoo Park
 Seirin High School
 Hagiwara Post Office

References

Railway stations in Fukuoka Prefecture
Railway stations in Japan opened in 1963
The Marble Steps Leading to the Church of Santa Maria in Aracoeli in Rome is an oil-on-canvas painting by the Danish painter C. W. Eckersberg. It was painted in 1814–1816.

Choosing a position from below, Eckersberg created a composition of firm vertical and diagonal lines in this painting of Santa Maria in Ara Coeli, a medieval church in Rome. He painted the picture while being outside and carefully recorded the mid-morning sunlight and shadows.

References 

Paintings by Christoffer Wilhelm Eckersberg
1816 paintings
Religious paintings
Architecture paintings
Paintings in the National Gallery of Denmark
19th-century paintings in Denmark
Churches in art
Images of Rome
Paquet Bay is an Arctic waterway in Qikiqtaaluk Region, Nunavut, Canada. Located at Baffin Island's Borden Peninsula, Paquet Bay is situated between Tay Sound and Oliver Sound.  Frechette Island is located at its mouth.

Bays of Baffin Island
Bays of Qikiqtaaluk Region
Neaera is a German heavy metal band from Münster. The band was active from 2003 before breaking up in 2015. The band released seven studio albums.

Musical style 
Tobias Buck started Neaera to change the musical influence of the style he had played before with fellow Münster death metal band Malzan. The band was interested in the Swedish death metal genre, and decided to create a sound of their own, based on similar styles.

Band members 
 Current members
 Benjamin Hilleke – lead vocals
 Stefan Keller – guitar
 Tobias Buck – guitar 
 Benjamin Donath – bass
 Sebastian Heldt – drums

Discography

Studio albums

Music videos

References

External links 

 
 
 Neaera at Metal Blade Records

German melodic death metal musical groups
Musical groups established in 2003
Musical quintets
Metal Blade Records artists
Patiwat Khammai (, born 24 December 1994) is a Thai professional footballer who plays as a goalkeeper for Thai League 1 club Muangthong United, on loan from Bangkok United, and the Thailand national team.

International career
On 12 April 2021, He was named in manager Akira Nishino’s 47-man squad for Thailand’s 2022 World Cup qualification he play the friendly matches against Tajikistan.

Style of play
Patiwat is often hailed as a contemporary footballer who excels in the role of a goalkeeper, displaying remarkable skills with his feet. He is renowned for adopting a style reminiscent of a sweeper keeper, proficient at venturing out of his penalty box to actively participate in the build-up play of his team.

Honours

Club
Bangkok United
 Thailand Champions Cup: 2023

References

External links
 

1994 births
Living people
Patiwat Khammai
Patiwat Khammai
Patiwat Khammai
Men's association football goalkeepers
Patiwat Khammai
Patiwat Khammai
Patiwat Khammai
Patiwat Khammai
Patiwat Khammai
Patiwat Khammai
Trix Vivier (born 28 June 1988) is a South African film, television and theater actress, who is known for portraying the role of Flea van Jaarsveld in the 2019 television series Trackers, for which she gained prominence and national recognition, as well as for her role as Kate Myburgh in kykNet and Showmax's co-production of Waterfront.

Her breakout role was that of Vicky Ferreira in the kykNET youth series Sterlopers. Vivier portrayed this role from 2014 – 2016 over two seasons.

Vivier joined the lead cast of the TV series Legacy, for season one as one of the lead female protagonists, Petra Potgieter, in 2020.

Early life 
Vivier was born in Melkbosstrand, Cape Town, and raised by her mother Adri Vivier, a teacher and father Pieter Vivier, an advocate. Vivier is from Afrikaans descent and has three siblings. Her younger sister Lea Vivier is also an actress.

Her parents noticed and encouraged her passion for the performing arts from a young age and she made her professional stage debut at age 15 in Annie Get Your Gun (Gilbert and Sullivan Society, 2004) and at age 16 in Die Ander Marta (KKNK, Baxter Theatre 2005)  Vivier Matriculated from Jan van Riebeeck High School and went on to study and graduate from the Waterfront Theater School in Cape Town in 2009.

Career 

Vivier's first paid theater role was that of Pippi in The National Children's Theater production of Pippi Longstocking (2009)

She continued to work professionally as dancer and actor from 2009 to 2013 performing in plays such as Reza de Wet's MIS, educational theater musicals both locally and abroad and many Children's Theater Productions  before landing her first Television role in the kykNET youth drama series Sterlopers (2013 – 2016).

She subsequently went on to portray lead roles in television series such as Trackers.

Filmography

Further reading 
 https://www.pressreader.com/south-africa/rooi-rose/20190101/281775630215840
 https://www.pressreader.com/south-africa/huisgenoot/20191121/283893049859680
 https://www.vrouekeur.co.za/bekendes/10-vrae-aan-trix-vivier
 https://stories.showmax.com/deon-meyers-trackers-is-top-on-showmax/
 https://www.netwerk24.com/huisgenoot/Bekendes/lea-trix-en-moeder-adri-ma-en-dogters-bekoor-sa-op-tv-20210219

References

External links 
 https://www.imdb.com/name/nm6366742/
 https://www.apm.co.za/artiste/trix-vivier-836/
 https://www.instagram.com/trixvivier

Living people
1988 births
South African actresses
Alumni of Hoërskool Jan van Riebeeck
Uwe Sauer (born 30 August 1943) is a German equestrian and Olympic champion. He was born in Hamburg. He won a gold medal in team dressage at the 1984 Summer Olympics in Los Angeles with Montevideo.

Montevideo and Sauer competed in the 1983 European Championships, where they took an individual bronze and helped the West German team to back-to-back team golds in the 1983 and 1985 European Championships. The pair also competed at the 1984 Olympics in Los Angeles, where they took a team gold and 6th individually. Other major accomplishments include a team gold and an individual silver at the 1984 German Championships and an individual silver at the 1985 German Championships.

References

1943 births
Living people
Sportspeople from Hamburg
German dressage riders
Olympic equestrians for West Germany
German male equestrians
Olympic gold medalists for West Germany
Equestrians at the 1984 Summer Olympics
Olympic medalists in equestrian
Medalists at the 1984 Summer Olympics
The Pnar, also known as Jaiñtia, are a sub-tribal group of the Khasi people  in Meghalaya, India. The Pnar people are matrilineal. They speak the Pnar Language, which belongs to the Austro-Asiatic language family and is very similar to the Khasi language. The Pnar people are natives of West Jaintia Hills and East Jaintia Hills District of Meghalaya, India. They call themselves as "Ki Khun Hynñiew Trep" (Children of 7-hut). Their main festivals are Behdeinkhlam, Chad Sukra, Chad Pastieh and Laho Dance.

Etymology 

The name "Pnar" is an endonym, while "Jaiñtia" and "Synteng" are exonyms. The word "Jaiñtia" is derived from the name of a former kingdom, the Jaintia Kingdom, whose rulers were Syntengs. One theory says that the word "Jaiñtia" is ultimately derived from the name of the shrine of Jayanti Devi or Jainteswari, an incarnation of the Hindu goddess Durga. Another theory says that the name is derived via Synteng from Sutnga, a former settlement; the myth of Jayanti Devi was probably created after the Hinduisation of the Jaintia kingdom.

History 

As with all sub-tribes of the Khasi tribe, the Pnar sub-tribals have no recorded history of their own. However, they are mentioned in the Buranji chronicles of Assam and the British records.

Like all the other sub-tribes of the Khasi tribe, the Pnar people also claim descent from Ki Hynñiew Trep (seven mothers or seven families). The rulers of the medieval Jaintia Kingdom belonged to the Synteng community. The Kingdom was annexed by the British East India Company in 1835, and merged into the Assam province. The Jaintia Hills district was established in the region after the establishment of the Meghalaya state in independent India, in 1972. There are Pnar people in the Jaintiapur upazila, Sylhet, Bangladesh.

Religion 

The original tribal religion of the Pnars is known as Niamtre. The Pnar tribals believe that their religion is God-given (not founded by man) and comes to this world by God's decree. The three cardinal principles dictated by God are kamai yei hok, tipbru tipblai and tipkur tipkha. They signify right living and practice based on right livelihood; fulfillment of duties towards fellow men to reach God; and showing respect to the members of one's father's and mother's clans. Therefore, Niamtre stresses equal weight to be given to fellow humans to attain God realisation.

Religious wise out of 4 lakh Jaintias, around 2.4 lakh (60% of the ethnic population) professed Christian faith of various denominations particularly (Protestant and Catholic) & rest remaining 1.6 lakh (40% of ethnic population) practice their original tribal religion called "Ka Niamtre".

References 

Khasi people
Scheduled Tribes of Meghalaya
Tribes of Meghalaya
Ethnic groups in Northeast India
Ethnic groups in South Asia
Alisha is the debut album by American freestyle and dance-pop artist Alisha. It was released in the US in 1985 by Vanguard Records.

Background
At age 14, Alisha got the attention of producer Mark S. Berry when a demo tape of hers got to him through Vanguard Records. Berry was looking for a vocalist for the track "All Night Passion" and after its success, he went on to produce her debut album.

The album was released on 12" vinyl in 1985. The original vinyl release contains the album versions of "Stargazing" and "Baby Talk". The album was released on CD in 1986, and the original mixes of "Stargazing" and "Baby Talk" were replaced by their extended dance mixes. 

"Baby Talk" was originally recorded by Gregg Brown and released in the UK in 1984, and "One Little Lie", written by singer-songwriter Kirsty MacColl, was recorded by Anni-Frid Lyngstad of ABBA, and released on her 1984 album Shine.

Singles and chart performance
The album spawned many club hits, "All Night Passion" was released in 1984 and reached No. 4 on the Hot Dance Club charts, staying there for 2 weeks. "Too Turned On" was released as a follow-up single and peaked at No. 6 on the Hot Dance Club charts in July 1985. Alisha's biggest single to date "Baby Talk" followed, peaking at No. 1 on the Hot Dance Club chart in December 1985 for one week. It was also her first appearance on the Billboard Hot 100, peaking at No. 68 in February 1986. "Stargazing" was released as the final single in the US, reaching No. 16 on the Hot Dance Club charts in July 1986, and "Boys Will Be Boys" was released as a single in Germany. The album did not chart on the Billboard Top 200.

Track listing

Personnel
Album credits adapted from the liner notes of Alisha.

Alisha - vocals
Mark Berry - producer, musician
The Brass Bed Factory - photography prop
Joel Broddsky - photography
Greg Brown - composer
Simon Climie - composer
Bev Collins - background vocals
Carol Collins - background vocals
Alexandra Forbes - composer
Greco & Emmi, Inc. - album design
Jimmy Halperin - composer, musician
Chuck Hammer - musician
Chris Hills - musician
Tay Hoyle - engineer
Robbie Kilgore - musician
Andrea La Russo - composer

Nikki Lauren - background vocals
Logankoya - composer
Kirsty MacColl - composer
Penny Mealing - background vocals
Richard Musk - musician
Shep Pettibone - mixer, additional producer, musician
Mark Richardson - musician
Beth Rudetsky - background vocals
Michael Rudetsky - arranger
Steve Schwartz - musician
Peggy Stanziale - composer
Rick Tarbox - composer
Jim Tunnel - musician, background vocals
Andy Wallace - musician, remix engineer
Jeff Zaraya - executive producer
Paul Zinman - musician, engineer

References

1985 albums
Vanguard Records albums
Alisha (singer) albums