Understand C.4.3.4 Electrolysis of aqueous solutions
Channel: Hands on Chemistry
Date: 2020-07-17

AQA Specification Notes:

The ions discharged when an aqueous solution is electrolysed using inert electrodes depend on the relative reactivity of the elements involved.
At the negative electrode (cathode), hydrogen is produced if the metal is more reactive than hydrogen.
At the positive electrode (anode), oxygen is produced unless the solution contains halide ions when the halogen is produced.
This happens because in the aqueous solution water molecules break down producing hydrogen ions and hydroxide ions that are discharged.

Students should be able to predict the products of the electrolysis of
aqueous solutions containing a single ionic compound.