Organic Chemistry 51C. Lecture 10. Enols and Enolates. (Nowick)
Channel: UCI Open
Date: 2012-05-14

UCI Chem 51C Organic Chemistry (Spring 2012)
Lec 10. Organic Chemistry -- Enols and Enolates --
View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html
Instructor: James S. Nowick, Ph.D.

License: Creative Commons BY-NC-SA
Terms of Use: http://ocw.uci.edu/info.
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Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html

Recorded on May 3, 2012

Index of Topics:

1:16-Reactivity of Ketones
3:02-Enols
6:36-Enolate Anion
9:47-Enolates and Electrophiles
16:49-Equilibrium Between Tautomers
23:07-Acid-Catalyzed Enol Formation
29:18-Energy Diagram
37:51-Multiple Additions
46:41-pKa of Alpha Protons
53:05-Base-Catalyzed Enol Formation
58:56-Stereochemistry
1:03:42-LDA
1:11:28-Kinetic Product vs Thermodynamic Product
1:17:56-LDA and Stereochemistry


Required attribution: Nowick, James S. Organic Chemistry 51C  (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).