Organic Chemistry 51C. Lecture 11. More Reactions of Enols and Enolates. (Nowick)
Channel: UCI Open
Date: 14/05/2012

UCI Chem 51C Organic Chemistry (Spring 2012)
Lec 11. Organic Chemistry -- More Reactions of Enols and Enolates --
View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html
Instructor: James S. Nowick, Ph.D.

License: Creative Commons BY-NC-SA
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Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html

Recorded on May 10, 2012

Index of Topics:

1:05-Enolates
3:57-Enolates and Electrophiles
9:11-Alpha-Halogenation of Ketones and Aldehydes
13:58-Halogenation Mechanism
21:58-Halogenation Example
25:10-Alpha-Halogenation Promoted by Base
35:29-Haloform Reaction
39:02-Haloform Reaction Mechanism
43:37-pKa Values
53:20-Reason for Acidity
1:00:35-AcetoAcetic Ester Synthesis
1:10:36-Malonic Ester Synthesis
1:14:44-Example Problem

Required attribution: Nowick, James S. Organic Chemistry 51C  (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).