Organic Chemistry 51C. Lecture 07. Acid-Catalyzed Formation of Hydrates, Hemiacetals, & Acetals.
Channel: UCI Open
Date: 27/04/2012

UCI Chem 51C Organic Chemistry (Spring 2012)
Lec 07. Organic Chemistry -- Acid-Catalyzed Formation of Hydrates, Hemiacetals, & Acetals --
View the complete course: http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html
Instructor: James S. Nowick, Ph.D.

License: Creative Commons BY-NC-SA
Terms of Use: http://ocw.uci.edu/info.
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Description: This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds. Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chemistry.html

Recorded on April 24, 2012

Index of Topics:

1:19-Electrophilicity of Aldehydes and Ketones
5:37-Hydrates
12:17-Acid-Catalyzed Addition of Water to Acetone
21:29-Acetone Enol Example
24:01-Reverse Reaction
25:31-Energy Diagram
29:28-Reverse Reaction Mechanism
36:38-Acid-Catalyzed Acetal Formation
40:00-Hemiacetal
43:01-Strong Acid
47:23-Hemiacetal Formation Mechanism
50:52-Hemiacetal to Acetal Mechanism
1:00:52-Acid-Catalyzed Acetal Hydrolysis
1:06:12-Protecting Groups
1:12:15-Cyclic Hemiacetal


Required attribution: Nowick, James S. Organic Chemistry 51C  (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_51c_organic_chemistry.html [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License (http://creativecommons.org/licenses/by-sa/3.0/us/deed.en_US).