Calculating the cell emf for Nonstandard condition : A galvanic cell is constructed at `
Channel: Doubtnut
Date: 23/08/2020

Calculating the cell emf for Nonstandard condition : A galvanic cell is constructed at `298 K` as follows. One half-cell consists of a chlorine gas electrode (i.e. `Cl_(2)//Cl^(-)` couple) with the partial pressure of `Cl_(2) = 0.100` bar and `C_(CI-) = 0.100 M`. The other half-cell involves the `MnO_(4)^(-)//Mn^(2+)` couple in acidic solution with `C_(MnO_(4)^(-)) = 0.100 M, C_(Mn^(2+)) = 0.100 M`, and `C_(H+) = 1.00 M`. Apply the Nernst equation to datermine the cell potenital for this cell. Strategy: First datermine the overall cell reaction and then calculate the standard cell potential `(E_("cell")^(@))`  from the standard electrode potenital in Table 3.1. then use the Nernst equation to find the cell potential `(E)` under cited conditions