Organocopper compound | Wikipedia audio article
Channel: wikipedia tts
Date: 15/01/2019

This is an audio version of the Wikipedia Article:
https://en.wikipedia.org/wiki/Organocopper_compound


00:00:40 1 Structure and bonding
00:01:42 2 Simple complexes with CO, alkene, and Cp ligands
00:02:40 3 Alkyl and aryl copper compounds
00:02:50 3.1 Alkyl and aryl copper(I) compounds
00:05:38 3.1.1 Structures
00:07:17 3.2 Alkyl and aryl copper(III) compounds
00:08:28 4 Reactions of organocuprates
00:08:38 4.1 Cross-coupling reactions
00:11:35 4.2 Coupling reactions
00:12:41 4.3 Carbocupration
00:13:13 5 Synthetic applications
00:14:03 5.1 Reducing agents
00:15:02 5.2 Cu alkylation reaction
00:15:36 5.3 Vicinal functionalization reactions
00:16:09 6 Further reading



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SUMMARY
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Organocopper compounds in organometallic chemistry contain carbon to copper chemical bonds. Organocopper chemistry is the science of organocopper compounds describing their physical properties, synthesis and reactions. They are reagents in organic chemistry.
The first organocopper compound, the explosive copper(I) acetylide Cu2C2 (Cu-C≡C-Cu), was synthesized by Rudolf Christian Böttger in 1859 by passing acetylene gas through copper(I) chloride solution:
C2H2 + 2 CuCl → Cu2C2 + 2 HCl