Organoosmium chemistry | Wikipedia audio article
Channel: wikipedia tts
Date: 27/12/2018

This is an audio version of the Wikipedia Article:
https://en.wikipedia.org/wiki/Organoruthenium_chemistry


00:00:56 1 Ligands
00:01:44 1.1 Phosphine ligands
00:02:15 1.2 N-Heterocyclic carbene ligands
00:02:57 1.3 Cyclopentadienyl ligands
00:03:57 1.4 Arene and alkene ligands
00:04:55 1.5 Carbonyls
00:05:44 2 Organoosmium compounds



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SUMMARY
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Organoruthenium chemistry is the chemistry of organometallic compounds containing a carbon to ruthenium chemical bond. Several organoruthenium catalysts are of commercial interest and organoruthenium compounds have been considered for cancer therapy.
The chemistry has some stoichiometric similarities with organoiron chemistry, as iron is directly above ruthenium in group 8 of the periodic table. The most important reagents for the introduction of ruthenium are ruthenium(III) chloride and triruthenium dodecacarbonyl.
In its organometallic compounds, ruthenium is known to adopt oxidation states from -2 ([Ru(CO)4]2−) to +6 ([RuN(Me)4]−).  Most common are those in the 2+ oxidation state, as illustrated below.