Organotungsten chemistry | Wikipedia audio article
Channel: wikipedia tts
Date: 27/12/2018

This is an audio version of the Wikipedia Article:
https://en.wikipedia.org/wiki/Organomolybdenum_chemistry


00:00:21 1 Mo(0) and more reduced states
00:02:01 2 Mo(II)
00:02:32 3 Mo(IV)
00:02:45 4 Mo(V) and Mo(VI)
00:02:56 5 Organotungsten compounds
00:03:15 6 Applications
00:03:22 7 References
00:03:34 Mo(CH3)5, Mo(CH3)6, and salts of [Mo(CH3)7]- are known.Oxo and imide (RN=) ligands are found in several high oxidation state organomolybdenum compounds. The complexes (C5R5)MoO2X are illustrative. Schrock's Mo-based olefin metathesis catalysts feature molybdenum(VI) centers supported by alkoxide, alkylidene, and imido ligands.
00:04:12 Organotungsten compounds
00:04:24 Tungsten analogues of almost all organoMo compounds are known.  Some notable examples include hexamethyltungsten and analogues of Schrock olefin metathesis catalysts.
00:04:41 Applications



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SUMMARY
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Organomolybdenum chemistry is the chemistry of chemical compounds with Mo-C bonds.  The heavier group 6 elements molybdenum and tungsten form organometallic compounds similar to those in organochromium chemistry but higher oxidation states tend to be more common.