Organoaluminium chemistry | Wikipedia audio article
Channel: wikipedia tts
Date: 27/12/2018

This is an audio version of the Wikipedia Article:
https://en.wikipedia.org/wiki/Organoaluminium_chemistry


00:00:51 1 History
00:01:38 2 Structure and bonding
00:01:48 2.1 Aluminium(III) compounds
00:03:15 2.1.1 Ligand exchange in trialkylaluminium compounds
00:03:26 2.2 Low valent organoaluminium compounds
00:03:38 3 Preparation
00:04:48 3.1 From alkyl halides and aluminium
00:06:20 3.2 Hydroalumination
00:06:29 3.3 Carboalumination
00:08:00 3.4 Laboratory preparations
00:09:39 4 Reactions
00:11:55 4.1 Lewis acidity
00:12:44 4.2 Electrophiles
00:13:06 4.3 Alkene polymerization
00:13:31 5 References
00:15:48 Alkene polymerization



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SUMMARY
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Organoaluminium chemistry is the study of compounds containing bonds between carbon and aluminium bond.  It is one of the major themes within organometallic chemistry. Illustrative organoaluminium compounds are the dimer trimethylaluminium, the monomer triisobutylaluminium, and the titanium-aluminium compound called Tebbe's reagent. The behavior of organoaluminium compounds can be understood in terms of the polarity of the C−Al bond and the high Lewis acidity of the three-coordinated species. Industrially, these compounds are mainly used for the production of polyolefins.