Bloom subsequently established himself as a leading man in Hollywood films such as Balian de Ibelin in Ridley Scott's "Kingdom of Heaven" (2005) and "Elizabethtown" (2005).
 He made his professional stage debut in West End's "In Celebration" at the Duke of York's Theatre in London in 2007 and starred in a Broadway adaption of "Romeo and Juliet" in 2013.
 In 2009, Bloom was named a UNICEF Goodwill Ambassador.
 In 2015 he received the BAFTA Britannia Humanitarian Award.
Moore took over the role of Bond from Sean Connery in 1972, and made his first appearance as 007 in "Live and Let Die" (1973).
 The longest serving Bond, he went on to portray the spy in six more films until his retirement from the role in 1985.
 Appointed a UNICEF Goodwill Ambassador in 1991, Moore was knighted by Queen Elizabeth II in 2003 for "services to charity".
 In 2007, he received a star on the Hollywood Walk of Fame for his work in television and in film.
 In 2008, the French government appointed Moore a Commander of the Ordre des Arts et des Lettres.
Agnes Meiling Kaneko Chan (traditional Chinese: 陳美齡 simplified Chinese: 陈美龄 : "Chén Měilíng"Cantonese Yale: "Chan Mei ling" ) is a pop singer, a "foreign television personality" ("gaijin tarento"), a Doctor of Philosophy, a professor at Japanese universities, an essayist, and a novelist.
 Since 1988, Chan has been a UNICEF Goodwill Ambassador and also supports the Japan Committee for UNICEF.
Ani Choying Dolma (Nepali: आनी छोइङ डोल्मा (born June 4, 1971), in Kathmandu, Nepal, also known as Choying Dolma and Ani Choying ("Ani", "nun", is an honorific), is a Nepalese Buddhist nun and musician from the Nagi Gompa nunnery in Nepal.
 She is known in Nepal and throughout the world for bringing many Tibetan Buddhist chants and feast songs to mainstream audiences.
 She has been recently appointed as the UNICEF Goodwill Ambassador to Nepal.
Susan Abigail Sarandon ( ; née Tomalin; born October 4, 1946) is an American actress and activist.
 She is an Academy Award and BAFTA Award winner who is also known for her social and political activism for a variety of causes.
 She was appointed a UNICEF Goodwill Ambassador in 1999 and received the Action Against Hunger Humanitarian Award in 2006.
Mahmoud Kabil (Arabic: محمود قابيل‎ ‎ , born May 19, 1946) is an award-winning Egyptian actor and political activist.
 He is also the UNICEF Goodwill Ambassador for the Middle East and North Africa.
 Kabil served as an officer in the Military of Egypt's Special Forces before becoming a promising actor in Egyptian cinema during the 1970s.
 Blacklisted in 1980, Kabil moved to the United States and took a 14-year hiatus from acting.
 He made a successful comeback upon his return to Egypt in 1993, and has since starred in more than 50 films and TV series on his way to becoming one of Egypt's most popular actors.
 After years of involvement with the United Nations, Kabil was named a UNICEF Goodwill Ambassador in November 2003.
James and the Giant Peach is a 1996 British-American musical fantasy film directed by Henry Selick, based on the 1961 novel of the same name by Roald Dahl.
 It was produced by Tim Burton and Denise Di Novi, directed by Henry Selick, and starred Paul Terry as James.
 The film is a combination of live action and stop-motion animation.
 Co-stars Joanna Lumley and Miriam Margolyes played James's aunts in the live-action segments, and Simon Callow, Richard Dreyfuss, Susan Sarandon, Jane Leeves, David Thewlis, and Margoyles voiced his insect friends in the animation sequences.
Ruslana Stepanivna Lyzhychko (Ukrainian: Руслана Степанівна Лижичко , "Ruslana Lyžyčko"; born 24 May 1973), known mononymously as Ruslana, is a World Music Award and Eurovision Song Contest winning artist, holding the title of People's Artist of Ukraine.
 She is also a former MP serving as deputy in the Ukrainian parliament (Verkhovna Rada) for the Our Ukraine Party.
 Ruslana was the UNICEF Goodwill Ambassador in Ukraine in 2004-2005.
 She is recognized as the most successful Ukrainian female solo artist internationally and was included in the top 10 most influential women of 2013 by the Forbes magazine.
 The U.S. Secretary of State honored her with the International Women of Courage Award in March 2014.
 She has been named an honorary citizen of her hometown L'viv and was nominated to receive the title Hero of Ukraine.
Kal Naga (also credited as Khaled Naga or Khaled Abol Naga) is a multi award-winning actor, film producer and director from Egypt (he directed theatre mostly and short films).
 He is a movie star in the Arab World and the Middle East but also a familiar face internationally specially in European film festivals, where he has been honoured with a diverse range of awards as an actor and producer as well as a jury member in film festivals.
 Since 2016 he focused on English speaking markets ["Tyrant" TV series season 3 (2016), American FX TV Network, "Vikings" season 5 (2017), History Channel and "The Last Post" TV mini series, UK's BBC TV].
 His roles covered a multitude of genres, from musicals ["None but that!"
 (2007)], action ["Agamista"(2007), "Eyes Of A Thief" (2014)], thrillers ["Kashf Hesab" (2007)], art-house ["Heliopolis" (2009), "Villa 69" (2013), "Decor" (2014)] and a slapstick comedy ["Habibi Naeman (Sleeping Habibi)" (2008)].
 He played the lead in many award-winning films that gained him outstanding international critics acclaim as one of the finest actors in the world today out of the Arab region.
 He studied and graduated (with highest honours) as a Tele-communication engineer' from Ain Shams University, studied theatre (as a minor) at the American University in Cairo, and worked on a spacecraft design program (UoSAT-5 ) in the UK.
 He finally confirmed his passion and calling for the arts by the year 2000.
 In a film festival in 2016 celebrating Arabic films submissions to the "Oscars," he was honoured for being the most submitted actor in Arabic films submissions to the Academy Award for Best Foreign Language Film ("The Oscars)".
 He is often tagged in western media as "Egypt's "Brad Pitt" for his many career similarities with the latter, also described as "the next Omar Sharif" specially after his American debut movie "Civic Duty" in 2007.
 He was also described as "Egypt's International treasure" for advocating for freedom and standing up against injustice in his home country Egypt.
 He is one of the most recognisable faces of the 2011 revolution, seizing the anti-regime sentiment in the streets of Cairo and taking part in mass demonstrations that led to the removal of President Mubarak.
 He faced defamation campaigns against him by the state owned and controlled media during Mubarak era before the January 25th 2011 revolution in Egypt, and once again from the 2013 "coup d'etat" General Sisi government in Egypt.
 Nonetheless he continued his regional and international award-winning success, as well as waves of strong support on social media.
 He also had a very celebrated and successful career across the Arab world TV networks as a TV & radio host in prime time shows from 1997 till 2005.
 He is a human and child rights activist and has been Egypt's UNICEF Goodwill Ambassador 2007–2015.
 He has worked across a diverse variety of media, including theatre, radio, television and film in Arabic, English and some French and Italian.
Gavin Rajah is a South African born designer.
 He works out of his atelier based in Cape Town and regularly shows at Paris Fashion Week (Couture).
 He uses his visibility and fashion events to bring awareness to various child related issues.
 Gavin Rajah has been appointed by the United Nations as a UNICEF Goodwill Ambassador.

Question: In which year was this American actress and activist, who won an Academy Award and BAFTA Award and contributed to "James and the Giant Peach," appointed a UNICEF Goodwill Ambassador?
Answer: 1999