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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.03.2023*

Version number 1

Revision: 23.03.2023

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: CREARD R-448A
Article number: R448A STD
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Sector of Use SU8 Manufacture of bulk, large scale chemicals (including petroleum products)
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
DAIKIN INDUSTRIES, LTD. CHEMICALS DIVISION:OSAKA UMEDA TWIN TOWERS SOUTH, 1-13-1 Umeda, Kita-ku, Osaka-shi, Osaka, 530-0001, Japan
Phone:+81-6-6147-9702 Fax:+81-6-6147-9807
Further information obtainable from:http://www.daikin.com/
sales@daikinchem.de
1.4 Emergency telephone number:
Japan: +81-6-6349-7521
China: +86-532-8388-9090, +86-21-34151689
South Korea: +82-2-568-1722
Americas: CHEMTREC +1-800-424-9300 (Outside US/Canada: +1-703-527-3887)
Europe: +49-211-179 225-0*

SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008

Press. Gas (Comp.) H280 Contains gas under pressure; may explode if heated.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008:
The product is classified and labelled according to the CLP regulation.
Signal word: Warning
Precautionary statements:
P410+P403 Protect from sunlight. Store in a well-ventilated place.
*

SECTION 3: Composition/information on ingredients
Information on ingredients:
CAS: 75-10-5

Difluoromethane
Flam. Gas 1B, H221
Press. Gas (Liq.), H280

26%

CAS: 354-33-6

PentafluoroethanePress. Gas (Liq.), H280

26%

CAS: 811-97-2

1,1,1,2-TetrafluoroethanePress. Gas (Liq.), H280

21%

CAS: 754-12-1

2,3,3,3-tetrafluoro-1-Propene
Flam. Gas 1B, H221
Press. Gas (Liq.), H280

20%

CAS: 29118-24-9 trans-1,3,3,3-tetrafluoroprop-1-ene
Press. Gas (Liq.), H280
Additional information: For the wording of the listed hazard phrases refer to section 16.

7%(Contd. on page 2)

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SECTION 4: First aid measures
4.1 Description of first aid measures
General information: Seek immediate medical advice.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult a doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
In case of emergency to rescue the victims; be sure to wear supplied-air respirator (SAR) or self-contained breathing
apapratus (SCBA).
If the patient does not breathe or hardly breathes, unbutton clothes, secure the airway for breathing and perform
artificial respiration.
At high levels, cardiac arrhythmia may occur.
After skin contact:
Rinse with warm water.
Remove contaminated clothes immediately.
In cases of frost bites, rinse with plenty of water. Do not remove clothing.
Immediately rinse with warm water and soap.
Consult a doctor in case of complaints.
After eye contact:
Rinse opened eye for several minutes under running water.
Consult an ophthalmologist in case of complaints.
After swallowing: Not applicable.
Information for doctor:
Catecholamines such as adrenaline, and other compounds having similar effects, should be reserved for emergencies
and then used only with special caution.
The examining physician should advise workers taking medications containing catecholamines that they may be atincreased risk and should avoid excessive exposure.
4.2 Most important symptoms and effects, both acute and chronic:
Frost bitesHigh concentrations cause asphyxiation. May cause an abnormal heart rhythm and prove suddenly fatal.
4.3 Indication of any immediate medical attention and special treatment needed:
No further relevant information available.

SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
5.2 Special hazards arising from the substance or mixture:
In case of fire, the following can be released:
Hydrogen fluoride (HF)
Formation of toxic gases is possible during heating or in case of fire.
Receptacle may explode when heated.
5.3 Advice for firefighters:
Move receptacle to a safe place immediately if possible. If not, spray water on the receptacles and surrounding
equipment to cool.
If receptacle catches fire: cool them with plenty of water.
If possible, close valves of receptacles to shut off the gas supply.
Protective equipment:
Wear fully protective suit.
Wear self-contained breathing apparatus and protective suit.
Do not inhale explosion gases or combustion gases.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Wear appropriate protective devices (See Section 8 Exposure Controls/Personal Protection).
Avoid contact with eyes and skin.
Do not inhale the product.
Ensure adequate ventilation before entering the area.
(Contd. on page 3)

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Stay on the windward side.
Keep out unauthorized persons.
6.2 Environmental precautions:
Suppress gases/fumes/haze with water spray.
Do not allow to enter sewers/surface or ground water.
Must not be emitted into the environment.
6.3 Methods and material for containment and cleaning up:
Stop leakage if possible.
Ensure adequate ventilation.
6.4 Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
*

SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Waste air is to be released into the atmosphere only via suitable separators.
Do not inhale the gas.
Ensure good ventilation/exhaustion at the workplace.
Handle with care. Avoid jolting, friction and impact.
Stay on the windward side when working outdoors.
Be careful of leakage when attaching/detaching receptacles.
Inhaling large quantities may cause cardiac arrhythmia or asphyxiation or both.
Keep away from naked flame or metal heated over 300 - 400
to prevent thermal decomposition that may form
toxic gases.
Do not handle until all safety precautions have been read and understood.
For heating receptacle, use hot compresses or lukewarm water below 40 .
Do not use heaters.
Information about fire - and explosion protection:
The product is not flammable.
Keep ignition sources away - Do not smoke.
Keep respiratory protective device available.
7.2 Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles:
Store material at:
Store material at 5
to 25 .
Store in a cool and dry location.
Keep containers tightly sealed.
Information about storage in one common storage facility:
No further information available.
See section 10 for information on incompatible materials.
Further information about storage conditions:
Keep at temperature not exceeding 40 °C.
Protect from heat and direct sunlight.
Store containers in a well ventilated area.
Store locked up.
7.3 Specific end use(s): No further relevant information available.

SECTION 8: Exposure controls/personal protection
8.1 Control parameters No further information available.
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at theworkplace.
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Appropriate engineering controls No further data; see item 7.
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Individual protection measures, such as personal protective equipment
General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not eat or drink while working.
Keep away from tobacco products.
Respiratory protection: Use respiratory protective device with organic gas cartridge.
Hand protection
Protective gloves
To avoid skin problems reduce the wearing of gloves to the required minimum.
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality andvaries from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance ofthe glove material can not be calculated in advance and has therefore to be checked prior to the application.
Leather
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye/face protection
Safety glasses
Body protection: Protective work clothing*

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Gaseous
Physical state
Colourless
Colour:OdourlessOdour:
Not determined.
Odour threshold:
Undetermined.
Melting point/freezing point:
Boiling point or initial boiling point and boiling range -45.9 °C
Product is not flammable.
Flammability
Lower and upper explosion limit
None (ASHRAE34-2016)
Lower explosive limit:
None (ASHRAE34-2016)
Upper explosive limit:
Not applicable.
Flash point:>250 °C
Decomposition temperature:
Not determined.
pH
Viscosity:
Not determined.
Kinematic viscosity
Not determined.
Dynamic:
Solubility
No further information available.
water:
No further information available.
Partition coefficient n-octanol/water (log value)
12900 hPa (saturation steam pressure)
Vapour pressure at 25 °C:
No further information available.
Density and/or relative density
Not determined.
Density:
Not determined.
Relative density
Not determined.
Vapour density
No further information available.
Particle characteristics(Contd. on page 5)56.0

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9.2 Other information:
Form:
Auto-ignition temperature:
Explosive properties:
Evaporation rate

Liquefied gas
628 °CNot determined.
Not applicable.

Information with regard to physical hazard classes
Not applicable
Explosives
Not applicable
Flammable gases
Not applicable
Aerosols
Not applicable
Oxidising gases
Contains gas under pressure; may explode if heated.
Gases under pressure
Not applicable
Flammable liquids
Not applicable
Flammable solids
Not applicableSelf-reactive substances and mixtures
Not applicable
Pyrophoric liquids
Not applicable
Pyrophoric solids
Not applicableSelf-heating substances and mixtures
Substances and mixtures, which emit flammable gases
Not applicablein contact with water
Not applicable
Oxidising liquids
Not applicable
Oxidising solids
Not applicable
Organic peroxides
Not applicable
Corrosive to metals
Not applicable
Desensitised explosives

SECTION 10: Stability and reactivity
10.1 Reactivity No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
10.3 Possibility of hazardous reactions: No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid: Keep away from heat, sparks, flame, high temperature.
10.5 Incompatible materials: Alkali or alkaline earth metals - powdered Al, Zn, Mg, etc.
10.6 Hazardous decomposition products:
Fluorophosgene in contact with naked flame or red hot objects.
Hydrofluoric acid, carbonyl fluoride*

SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity Based on available data, the classification criteria are not met.
LD/LC50 values relevant for classification:
CAS: 75-10-5 Difluoromethane
Inhalative LC0/4h > 520000 ppm (Rat) (OECD 403)
CAS: 354-33-6 Pentafluoroethane
Inhalative LC50/4h > 800000 ppm (Rat)
CAS: 811-97-2 1,1,1,2-Tetrafluoroethane
Inhalative LC50/4h > 500000 ppm (Rat)
CAS: 754-12-1 2,3,3,3-tetrafluoro-1-Propene
Inhalative LC50
> 400000 ppm (Rat) (OECD 403)
CAS: 29118-24-9 trans-1,3,3,3-tetrafluoroprop-1-ene
Inhalative LC50/4h > 207000 ppm (Rat)(Contd. on page 6)56.0

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Skin corrosion/irritation:
No further information available.
Based on available data, the classification criteria are not met.
CAS:354-44-6 Pentafluoroethane The substance is not classified based on the results of tests using rabbits whichshowed slight irritation (P A T T Y (5 t h , 2 0 0 1 ) ) or no irritation (ECETOC JACC no. 50).
CAS:811-97-2 1,1,1,2-tetrafluoroethane The substance is not classified based on the results of tests using rabbits
which showed slight irritation (P A T T Y (5 t h , 2 0 0 1 ) ) or no irritation (ECETOC JACC no. 50).
CAS:29118-24-9 trans-1,3,3,3-tetrafluoroprop-1-ene No skin irritation Rabbit (OECD 404)
Serious eye damage/irritation:
No further information available.
Based on available data, the classification criteria are not met.
CAS:74-10-5 Difluoromethane No information available to indicate irritation.
CAS:811-97-2 1,1,1,2-tetrafluoroethane Not classified due to slight irritation (P A T T Y (5 t h , 2 0 0 1 ) ) and no
irritation (ECETOC JACC no. 50) in tests on rabbits.
after inhalation: No further information available.
Respiratory or skin sensitisation:
Based on available data, the classification criteria are not met.
CAS:74-10-5 Difluoromethane No information on sensitisation.
CAS:811-97-2 1,1,1,2-tetrafluoroethane No sensitisation (ECETOC JACC № 50)
Germ cell mutagenicity:
Based on available data, the classification criteria are not met.
CAS:811-97-2 1,1,1,2-tetrafluoroethane As a result of dominant lethal test, micronucleus test and chromosome
aberration test in mice by inhalation exposure, all of them came out negative, it was classified out of category.
(ECETOC JACC no.50)
Carcinogenicity:
Based on available data, the classification criteria are not met.
CAS:811-97-2 1,1,1,2-tetrafluoroethane The substance is not considered to be carcinogenic as no tumours havebeen observed in inhalation chronic toxicity and carcinogenicity studies in rats due to exposure testing.
(ECETOC JACC no.50)
Reproductive toxicity:
Based on available data, the classification criteria are not met.
CAS:74-10-5 Difluoromethane 50000 ppm (rats and rabbits)
Reproductive NOAEC (inhalation): 208000 mg/m3 (mouse) (OECD 478; read across)
Developmental NOAEC (inhalation): 105000 mg/m3 (rat)CAS:754-12-1 2,3,3,3-Tetrafluoro-1-propene Two-generation reproductive toxicity Inhalation Rat
NOAEL, Parent 50000ppm
NOAEL, F1 50000ppm
NOAEL, F2 50000ppm
catalytic formality NOAEL 50000ppm (rat) NOAEL 4000ppm (rabbit)
STOT-single exposure:
Based on available data, the classification criteria are not met.
CAS:811-97-2 1,1,1,2-tetrafluoroethane Cannot be classified due to lack of sufficient data.
STOT-repeated exposure:
Based on available data, the classification criteria are not met.
CAS:811-97-2 1,1,1,2-tetrafluoroethane No adverse effects have been reported in studies on rats, mice ordogs.(ECETOC JACC no.50).Not classified
CAS:29118-24-9 trans-1,3,3,3-tetrafluoroprop-1-ene NOEL 5000ppm (Heart) Rat Inhalation 13weeks
Aspiration hazard:
Based on available data, the classification criteria are not met.
CAS:811-97-2 1,1,1,2-tetrafluoroethane No adverse effects have been reported in studies on rats and mice.
(ECETOC JACC no. 50)
Other information (about experimental toxicology): No further information available.
Subacute to chronic toxicity: No further information available.
Additional toxicological information:
CMR effects Not genotoxic(Contd. on page 7)56.0

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Trade name: CREARD R-448A(Contd. of page 6)11.2 Information on other hazards:
Endocrine disrupting properties:
None of the ingredients is listed.
Other information
CAS:74-10-5 Difluoromethane
Cardiac sensitisation NOAEC: 735000 mg/m3
Increasing the aerial concentration to 35% did not induce cardiac sensitisation to adrenaline in dogs.
Ames test: negative (OECD 471)
Chromosome aberration test: Negative (OECD 473)
Mouse micronucleus test: Negative (OECD 474)
Chronic toxicity (inhalation) NOAEC: 50000 ppm (Rat) 90 day 105000 mg/m3 (OECD 413)
CAS:354-44-6 Pentafluoroethane
Cardiac sensitisation: 75000 ppm (Dog)
Developmental NOAEL: 50000 ppm (Rat and rabbit)
Chronic toxicity NOAEC 50000 ppm (Rat) (13 weeks)
CAS:811-97-2 1,1,1,2-tetrafluoroethaneHeartfelt Sense Making 75000 ppm (Dog)
Hepta 300000, 40000 ppm (Rat and rabbit)
chronic toxicity NOEL : 10000 ppm (Rat) (two-year study)
subchronic toxicity NOAEC 50000 ppm (Rat) (13weeks)
CAS:754-12-1 2,3,3,3-Tetrafluoro-1-propene
Repeated dose NOAEL 50000ppm Rat Inhalation 13weeks (OECD 413)
Ames test Positive
Irregular DNA synthesis test Negative (OECD486)
Micronucleus test Negative (rat OECD474)
CAS:29118-24-9 trans-1,3,3,3-tetrafluoroprop-1-ene
No cardiac sensitisation Canine
Chromosome aberration test Negative Chinese hamster ovary cells
Negative Human lymphocytes (OECD 473)
Ames test negative
Micronucleus test negative Mouse
No teratogenicity Rabbit, rat*

SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:
CAS: 75-10-5 Difluoromethane
LC50/96h 1507 mg/l (Fish) (QSAR)
LC50/48h 652 mg/l (Daphnia) (QSAR)
EC50/96h 142 mg/l (Alga) (QSAR)
CAS: 811-97-2 1,1,1,2-Tetrafluoroethane
LC50/96h 450 mg/l (Fish) (EU Method C.1)
rainbow trout
EC50/48h 980 mg/l (Daphnia) (EU Method C.2)
CAS: 754-12-1 2,3,3,3-Tetrafluoro-1-propene
LC50/96h > 197 mg/l (Fish) (OECD 203)
EC50/48h > 100 mg/l (Daphnia) (OECD 202)
EC50/72h > 100 mg/l (Alga) (OECD 201)
NOEC
> 75 mg/l /3 days (Alga) (OECD 201)
CAS: 754-12-1 2,3,3,3-tetrafluoro-1-Propene
LC50/96h > 197 mg/l (Fish) (OECD 203)
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EC50/48h > 83 mg/l (Daphnia) (OECD 202)
EC50
> 83100 mg/l (Alga) (OECD 201)
CAS: 29118-24-9 trans-1,3,3,3-tetrafluoroprop-1-ene
LC0/96h > 117 mg/l (Fish) (Cyprinus carpio (OECD 203))
EC50/48h > 160 mg/l (Daphnia) (Daphnia magna (OECD 202))
NOEC> 170 mg/l (Alga) (72h) (OECD 201)12.2 Persistence and degradability: No further relevant information available.
12.3 Bioaccumulative potential: Non significant accumulation in organisms
12.4 Mobility in soil:
CAS: 75-10-5 Difluoromethane
Henry's law constant 295 Pa*m³/mol (air) (25 °C)
log Koc
0.17 (soil)
12.5 Results of PBT and vPvB assessment
PBT: No further relevant information available.
vPvB: No further relevant information available.
12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties.
12.7 Other adverse effects:
Ecotoxical effects: no data
Additional ecological information:
CAS:74-10-5 Difluoromethane Slightly degradable 5% 28days (OECD 301 D)
CAS:754-12-1 2,3,3,3-Tetrafluoro-1-propene Persistent (OECD 301F)
CAS:29118-24-9 trans-1,3,3,3-tetrafluoroprop-1-ene Persistent
General notes:
Global warming potential(GWP) : 1386(CO2=1 100year integrated value)(IPCC 4th report estimate)
CAS:74-10-5 Difluoromethane
Half-life in air: 1237 days
Ozone depletion factor: 0 (assuming CFC-11 is 1.0)
Global Warming Potential: 675 (assuming CO2 = 1, integrated over 100 years) (IPCC AR4)
CAS:354-44-6 Pentafluoroethane
Ozone depletion factor = 0 (assuming CFC-11 as 1.0)
Global Warming Potential: 3500 (assuming CO2=1, integrated over 100 years) (IPCC AR4)
CAS:811-97-2 1,1,1,2-tetrafluoroethane
Ozone depletion factor = 0 (assuming CFC-11 as 1.0)
Global Warming Potential: 1430 (assuming CO2=1, integrated over 100 years) (IPCC AR4)SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation:
Disposal must be made according to official regulations.
Incineration in an adequate incinerator is recommended.
Uncleaned packaging
Recommendation: Disposal must be made according to official regulations.
*

SECTION 14: Transport information
14.1 UN number or ID number
ADR, IMDG, IATA
14.2 UN proper shipping name:
ADR, IMDG, IATA

UN3163LIQUEFIED GAS, N.O.S.
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14.3 Transport hazard class(es):ADR

Class:
Label:
IMDG, IATA

2 2A Gases.
2.2

2 Gases.
Class:
2.2
Label:
14.4 Packing group:
Not applicable
ADR, IMDG, IATA
14.5 Environmental hazards:
No
Marine pollutant:Warning: Gases.
14.6 Special precautions for user:
20
Hazard identification number (Kemler code):
F-C,S-V
EMS Number:A
Stowage Category
14.7 Maritime transport in bulk according to IMO
Not applicable.
instruments
Avoid direct sunlight. Make sure of no damage, corrosion, leaks
Transport/Additional information:on the receptacles.
Take necessary measures for preventing cargo shift.
ADR
120 mlLimited quantities (LQ):
Code: E1
Excepted quantities (EQ)
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
3
Transport category:
C/E
Tunnel restriction code:
IMDG
120 mlLimited quantities (LQ)
Code: E1
Excepted quantities (EQ)
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN 3163 LIQUEFIED GAS, N.O.S., 2.2
UN "Model Regulation":*

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS04
Signal word Warning(Contd. on page 10)56.0Page 10/10

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Hazard statements
H280 Contains gas under pressure; may explode if heated.
Precautionary statements
P410+P403 Protect from sunlight. Store in a well-ventilated place.
DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronicequipment – Annex II
None of the ingredients is listed.
Annex I - RESTRICTED EXPLOSIVES PRECURSORS (Upper limit value for the purpose of licensing under
Article 5(3))
None of the ingredients is listed.
Annex II - REPORTABLE EXPLOSIVES PRECURSORSNone of the ingredients is listed.
National regulations No further information available.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
*

SECTION 16: Other information
The product is for the industrial use only. We do not guarantee the safety in case the product is used for the otherpurposes. When using the product for health-care application or food/feed application, consult us in advance.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specificproduct features and shall not establish a legally valid contractual relationship.
Department issuing SDS: EHS Department
Contact:
http://www.daikin.com/
sales@daikinchem.dewww.daikinchem.deAbbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning theInternational Transport of Dangerous Goods by Rail)ICAO: International Civil Aviation Organisation
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Gas 1B: Flammable gases – Category 1B
Press. Gas (Comp.): Gases under pressure – Compressed gas
Press. Gas (Liq.): Gases under pressure – Liquefied gas* Data compared to the previous version altered.