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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 16.11.2017*

Version number 13

Revision: 16.11.2017

SECTION 1: Identification of the substance/mixture and of the company/
undertaking· 1.1 Product identifier· Trade name: KEIM ROYALAN· 1.2 Relevant identified uses of the substance or mixture and uses advised against· Application of the substance / the mixture Silicate exterior paint· Uses advised against All other uses are not recommended.
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
KEIMFARBEN GMBH
Keimstraße 16 / 86420 Diedorf
Tel. +49 (0)821 4802-0
Fax +49 (0)821 4802-210
www.keim.com / info@keimfarben.de· Further information obtainable from:
Product safety department
Telefon: 49(0)821/4802-138
E-Mail: sdb.info@keimfarben.de· 1.4 Emergency telephone number:
GBK GmbH Global Regulatory Compliance
Emergency number: +49(0)6132/84463*

SECTION 2: Hazards identification· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms Void
· Signal word Void
· Hazard statements
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P102 Keep out of reach of children.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P273 Avoid release to the environment.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Additional information:
Contains propiconazole, 2-octyl-2H-isothiazol-3-one. May produce an allergic reaction.
· 2.3 Other hazards Alkaline product. Avoid contact with skin and eyes.
· Results of PBT and vPvB assessment· PBT: Not applicable.
(Contd. on page 2)
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Safety data sheet
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Printing date 16.11.2017

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Revision: 16.11.2017

Trade name: KEIM ROYALAN(Contd. of page 1)· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients· 3.2 Mixtures· Description: Purely mineral fillers, potassium water glass, pure acrylate emulsion· Dangerous components:
CAS: 60207-90-1
propiconazole<0.5%
EINECS: 262-104-4
Aquatic Acute 1, H400; Aquatic Chronic 1, H410;
Index number: 613-205-00-0
Acute Tox. 4, H302; Skin Sens. 1, H317
CAS: 886-50-0
Terbutryn<0.5%
EINECS: 212-950-5
Aquatic Acute 1, H400; Aquatic Chronic 1, H410;
Acute Tox. 4, H302
CAS: 26530-20-1
2-octyl-2H-isothiazol-3-one<0.05%EINECS: 247-761-7
Acute Tox. 3, H311; Acute Tox. 3, H331;
Skin Corr.
Index number: 613-112-00-5 1B, H314; Eye Dam. 1, H318;
Aquatic Acute 1, H400;
Aquatic Chronic 1, H410;
Acute Tox. 4, H302; Skin Sens.
1, H317
CAS: 57-55-6
propane-1,2-diol≤2.5%
EINECS: 200-338-0
substance with a Community workplace exposure limit· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures· 4.1 Description of first aid measures· General information:
Seek medical treatment in case of complaints.
When seeing the doctor we suggest to present this safety data sheet.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Do not use solvents or thinners.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse mouth and throat well with water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
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Printing date 16.11.2017

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Trade name: KEIM ROYALAN(Contd. of page 2)

SECTION 5: Firefighting measures· 5.1 Extinguishing media· Suitable extinguishing agents:
Product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
· 5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:carbon oxide (COx)silicon dioxid (SiO2)
acrylic monomers· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
In case of fire do not breathe smoke, fumes and vapours.

SECTION 6: Accidental release measures· 6.1 Personal precautions, protective equipment and emergency procedures
Respect the protection rules (see section 7 a. 8).
Ensure adequate ventilation
Avoid contact with skin and eyes.
Particular danger of slipping on leaked/spilled product.
· 6.2 Environmental precautions:
Do not allow product to reach soil, sewage system or any water course.
Follow local governmental rules and regulations.
Inform respective authorities in case of seepage into water course or sewage system.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of the material collected according to regulations.
Clear contaminated areas thoroughly.
Flush rests with sufficient amount of water.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage· 7.1 Precautions for safe handling
Avoid contact with skin and eyes.
Keep receptacles tightly sealed.
See item 8 for information about suitable protective equipment and technical precautions. Respect
the protection rules.
· Information about fire - and explosion protection:
The product is not flammable.
(Contd. on page 4)
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Revision: 16.11.2017

Trade name: KEIM ROYALAN(Contd. of page 3)

No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Keep in the original containers in a cool and dry place.
Store only in unopened original receptacles.
· Information about storage in one common storage facility:
Do not store together with acids.
Store away from metals.
· Further information about storage conditions:
Please note information on label
Protect from frost.
Store in a cool place.
Protect from heat and direct sunlight.
· Storage class: 12· 7.3 Specific end use(s) No further relevant information available.
*

SECTION 8: Exposure controls/personal protection· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:57-55-6 propane-1,2-diol
MAK (Germany) als Dampf und Aerosol;vgl.Abschn.IIb und Xc
26530-20-1 2-octyl-2H-isothiazol-3-one
AGW (Germany) Long-term value: 0.05 E mg/m³
2(I);DFG, H, Y
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Avoid contact with the eyes and skin.
Do not inhale aerosols.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.
Combination filter A/P· Protection of hands: Protective gloves· Material of gloves
suitable material e.g.:
Nitrile rubber, NBR
Natural rubber, NR
PVC gloves
Recommended thickness of the material:  0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of several(Contd. on page 5)
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Revision: 16.11.2017

Trade name: KEIM ROYALAN(Contd. of page 4)

substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
Value for the permeation: Level  6 (480 min)The determined penetration times according to EN 374 part III are not performed under practicalconditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,is recommended.
The exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.
· Eye protection: Tightly sealed goggles· Body protection:
Protective work clothing
After contact with skin wash thoroughly with water and apply lotion.
· Limitation and supervision of exposure into the environment See Section 12 and 6.2*

SECTION 9: Physical and chemical properties· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form:
Pasty
Colour:According to product specification· Odour:Weak, characteristic· Odour threshold:Not determined.
· pH-value at 20 °C:

11,4*· Change in condition
Melting point/freezing point:
Undetermined.
Initial boiling point and boiling range: Undetermined.
· Flash point:

Not applicable.

· Flammability (solid, gas):

Not applicable.

· Ignition temperature:

Not determined.

· Decomposition temperature:

Not determined.

· Auto-ignition temperature:

Product is not selfigniting.

· Explosive properties:

Product does not present an explosion hazard.

· Explosion limits:
Lower:
Upper:· Oxidising properties

Not applicable.
Not applicable.
Not applicable.

· Vapour pressure at 20 °C:~23 hPa· Density at 20 °C:

1,3-1,6* g/cm³(Contd. on page 6)
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Revision: 16.11.2017

Trade name: KEIM ROYALAN(Contd. of page 5)· Relative density· Vapour density· Evaporation rate

Not determined.
Not applicable.
Not applicable.

· Solubility in / Miscibility withwater:

miscible· Partition coefficient: n-octanol/water:

Not applicable.

· Viscosity:
Dynamic at 20 °C:
Kinematic:· 9.2 Other information

900-1200* mPas
Not determined.
* The values are for freshly produced material and maychange with the time.

SECTION 10: Stability and reactivity· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions of storage and use.
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials:
Acids
Metals· 10.6 Hazardous decomposition products:
In case of fire, the following can be released:carbon oxide (COx)silicon dioxid (SiO2)
acrylic monomers
No hazardous decomposition products if stored and handled as prescribed.

SECTION 11: Toxicological information· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
57-55-6 propane-1,2-diol
Oral
LD50
2,000 mg/kg (rat)DermalLD50
20,800 mg/kg (rabbit)
60207-90-1 propiconazole
Oral
LD50
1,517 mg/kg (rat)DermalLD50>4,000 mg/kg (rat)(Contd. on page 7)
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Trade name: KEIM ROYALAN(Contd. of page 6)

Inhalative LC50/4 h 1,264 mg/l (rat)
NOAEL 2.7 mg/kg (mouse)
100 mg/kg (rat)886-50-0 Terbutryn
Oral
LD50
2,045 mg/kg (rat)DermalLD50>2,000 mg/kg (rabbit)
Inhalative LC50/4 h >8,000 mg/l (rat)26530-20-1 2-octyl-2H-isothiazol-3-one
Oral
LD50
550 mg/kg (rat)DermalLD50>2,000 mg/kg (rabbit)
Inhalative LC50/4 h 0.76 mg/l (rat)· Primary irritant effect:· Skin corrosion/irritation Frequent persistent contact with the skin may cause skin irritation.
· Serious eye damage/irritation In case of longer exposure, irritating effect is possible.
· during inhalation: Irritant effect possible.
· during swallowing: Irritant effect possible· Respiratory or skin sensitisation
Contains propiconazole, 2-octyl-2H-isothiazol-3-one. May produce an allergic reaction.
· Other information (about experimental toxicology):
Experimental analysis are not available.
The product was not tested. The statements on toxicology have been derived from the properties of
the individual components.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) not applicable· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information· 12.1 Toxicity· Aquatic toxicity:
Harmful to aquatic organisms.
May cause long-term adverse effects in the aquatic environment.
60207-90-1 propiconazole
EC 50/48h 10.2 mg/l (daphnia)
EC 50/72 h 0.76 mg/l (algae)
LC 50/96 h 4.3 mg/l (fish)886-50-0 Terbutryn
NOEC
0.84 mg/l (fish)(Contd. on page 8)
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1.3 mg/l (daphnia)
EC 50/48h 2.66 mg/l (daphnia)
EC 50/3h >1,000 mg/l (Mikroorganismus)
26530-20-1 2-octyl-2H-isothiazol-3-one
EC 50/48h 0.32 mg/l (daphnia)
LC 50/96 h 0.047-0.18 mg/l (fish)· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· AOX-indication:
The product can take influence in small measure on the AOX-load of the waste water.
· According to the formulation contains the following heavy metals and compounds from theEU guideline NO. 2006/11/EC:
The product contains TiO2.
· General notes:
At present there are no ecotoxicological assessments.
Do not allow product to reach ground water, water course or sewage system.
Harmful to aquatic organisms
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations· 13.1 Waste treatment methods· Recommendation
Must not be disposed with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· European waste catalogue
08 01 11* waste paint and varnish containing organic solvents or other hazardous substances· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary with cleansing agents.

SECTION 14: Transport information· 14.1 UN-Number· ADR, IMDG, IATA

Void(Contd. on page 9)
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Trade name: KEIM ROYALAN(Contd. of page 8)· 14.2 UN proper shipping name
· ADR, IMDG, IATA

Void

· 14.3 Transport hazard class(es)· ADR, IMDG, IATA
· ClassVoid· 14.4 Packing group· ADR, IMDG, IATA

Void

· 14.5 Environmental hazards:· Marine pollutant:No· 14.6 Special precautions for user

Not applicable.

· 14.7 Transport in bulk according to Annex IIof Marpol and the IBC CodeNot applicable.
· Transport/Additional information:

No dangerous good in sense of these transport
regulations.

· UN "Model Regulation":

Void

SECTION 15: Regulatory information· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture· Labelling according to Regulation (EC) No 1272/2008
For information on labelling please refer to section 2 of this document.
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· National regulations:· Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· Other regulations, limitations and prohibitive regulations· Please note:
TRGS 200 (Germany)
TRGS 500 (Germany)
TRGS 510 (Germany)
TRGS 900 (Germany)· Substances of very high concern (SVHC) according to REACH, Article 57 not applicable· Product-Code/Giscode: BSW50· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
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SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
· Department issuing SDS: KEIMFARBEN Germany, Product safety department· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Dangerous Substances, BAuA, Germany)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
AGW: Arbeitsplatzgrenzwert (Germany)
EC10: Effective concentration at 10% mortality rate.
EC50: Half maximal effective concentration.
LC10: Lethal concentration at 10% mortality rate.
NOEC: No observed effect concentration.
REACH: Registration, Evaluation and Authorisation of Chemicals (Regulation (EC) No.1907/2006)
Acute Tox. 4: Acute toxicity – Category 4
Acute Tox. 3: Acute toxicity – Category 3
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3· * Data compared to the previous version altered.
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