44.3.3

Page 1/8

Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

SECTION 1: Identification of the substance/mixture and of the company/
undertaking· 1.1 Product identifier· Trade name: KEIM CONCRETAL-LASUR· 1.2 Relevant identified uses of the substance or mixture and uses advised against· Application of the substance / the mixture
Thin layer paint / glaze, sol-silicate-based, for interior and exterior application to concretesurfaces.
· Uses advised against All other uses are not recommended.
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
KEIMFARBEN GMBH
Keimstraße 16 / 86420 Diedorf
Tel. +49 (0)821 4802-0
Fax +49 (0)821 4802-210
www.keim.com / info@keimfarben.de· Further information obtainable from:
Product safety department
Telefon: 49(0)821/4802-138
E-Mail: sdb.info@keimfarben.de· 1.4 Emergency telephone number:
GBK GmbH Global Regulatory Compliance
Emergency number: +49(0)6132/84463

SECTION 2: Hazards identification· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· 2.3 Other hazards Alkaline product. Avoid contact with skin and eyes.
· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients· 3.2 Mixtures· Description:
Aqueous solution of silicic acid potassium salt, silica sol, acrylic polymer, mineral fillers, pigments,
additives.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-LASUR(Contd. of page 1)· Dangerous components: Void

SECTION 4: First aid measures· 4.1 Description of first aid measures· General information:
No special measures required.
When seeing the doctor we suggest to present this safety data sheet.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Do not use solvents or thinners.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse mouth and throat well with water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures· 5.1 Extinguishing media· Suitable extinguishing agents:
Product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
· 5.2 Special hazards arising from the substance or mixture
No further relevant information available.
· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.
· Additional information
In case of fire do not breathe smoke, fumes and vapours.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures· 6.1 Personal precautions, protective equipment and emergency procedures
Respect the protection rules (see section 7 a. 8).
Avoid contact with skin and eyes.
Ensure adequate ventilation
Particular danger of slipping on leaked/spilled product.
· 6.2 Environmental precautions:
Do not allow product to reach soil, sewage system or any water course.
(Contd. on page 3)
DEN

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-LASUR(Contd. of page 2)

Follow local governmental rules and regulations.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of the material collected according to regulations.
Clear contaminated areas thoroughly.
Flush rests with sufficient amount of water.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage· 7.1 Precautions for safe handling
Keep receptacles tightly sealed.
Avoid contact with skin and eyes.
Do not inhale aerosols.
See item 8 for information about suitable protective equipment and technical precautions. Respect
the protection rules.
· Information about fire - and explosion protection:
The product is not flammable.
No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Keep in the original containers in a cool and dry place.
Store only in unopened original receptacles.
· Information about storage in one common storage facility: Do not store together with acids.
· Further information about storage conditions:Store in a cool place.
Protect from frost.
Protect from heat and direct sunlight.
· Storage class: 12· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:
14808-60-7 Quartz (SiO2)
MAK (Germany) alveolengängige Fraktion· Additional information: The lists valid during the making were used as basis.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-LASUR(Contd. of page 3)· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Avoid contact with the eyes and skin.
Do not inhale aerosols.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.
Filter: P· Protection of hands: Protective gloves· Material of gloves
suitable material e.g.:
Nitrile impregnated cotton-gloves
Recommended thickness of the material:  0.5 mm
Natural rubber, NR
Recommended thickness of the material:  0.6 mm
Nitrile rubber, NBR
Recommended thickness of the material:  0.4 mm
The selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
Value for the permeation: Level  6 (480 min)The determined penetration times according to EN 374 part III are not performed under practicalconditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,is recommended.
The exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.
· Eye protection: Safety glasses· Body protection: Protective work clothing· Limitation and supervision of exposure into the environment See Section 12 and 6.2*

SECTION 9: Physical and chemical properties· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form:
Fluid
Colour:Different, according to colouring.
· Odour:Odourless· Odour threshold:Not determined.
· pH-value at 20 °C:

11.2*(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-LASUR(Contd. of page 4)· Change in condition
Melting point/freezing point:~ 0 °C
Initial boiling point and boiling range: ~100 °C· Flash point:

Not applicable.

· Flammability (solid, gas):

Not applicable.

· Ignition temperature:

Not determined.

· Decomposition temperature:

Not determined.

· Auto-ignition temperature:

Product is not selfigniting.

· Explosive properties:

Product does not present an explosion hazard.

· Explosion limits:
Lower:
Upper:· Oxidising properties

Not applicable.
Not applicable.
Not applicable.

· Vapour pressure at 20 °C:~23 hPa· Density at 20 °C:· Relative density· Vapour density· Evaporation rate

1.1-1.3* g/cm³
Not determined.
Not applicable.
Not applicable.

· Solubility in / Miscibility withwater:

miscible· Partition coefficient: n-octanol/water:

Not applicable.

· Viscosity:
Dynamic at 20 °C:
Kinematic:· 9.2 Other information

400-600* mPas
Not determined.
* The values are for freshly produced material and maychange with the time.

SECTION 10: Stability and reactivity· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions of storage and use.
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Acids(Contd. on page 6)DEN

44.3.3

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-LASUR(Contd. of page 5)· 10.6 Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed.

SECTION 11: Toxicological information· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:· Skin corrosion/irritation Frequent persistent contact with the skin may cause skin irritation.
· Serious eye damage/irritation In case of longer exposure, slightly irritating effect is possible.
· during inhalation: Irritant effect possible.
· during swallowing: Irritant effect possible· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Other information (about experimental toxicology):
Experimental analysis are not available.
The product was not tested. The statements on toxicology have been derived from the properties of
the individual components.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) not applicable· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information· 12.1 Toxicity· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· AOX-indication:
Due to the substance of content which do not include organic jointed halogens, the product can nottake influence on the AOX-load of the waste water.
· According to the formulation contains the following heavy metals and compounds from theEU guideline NO. 2006/11/EC:
The product contains TiO2.
· General notes:
At present there are no ecotoxicological assessments.
Do not allow product to reach ground water, water course or sewage system.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-LASUR(Contd. of page 6)· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations· 13.1 Waste treatment methods· Recommendation
Must not be disposed with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· European waste catalogue
08 01 12 waste paint and varnish other than those mentioned in 08 01 11· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary with cleansing agents.

SECTION 14: Transport information· 14.1 UN-Number· ADR, IMDG, IATA

Void

· 14.2 UN proper shipping name
· ADR, IMDG, IATA

Void

· 14.3 Transport hazard class(es)· ADR, IMDG, IATA
· ClassVoid· 14.4 Packing group· ADR, IMDG, IATA

Void

· 14.5 Environmental hazards:· Marine pollutant:No· 14.6 Special precautions for user

Not applicable.

· 14.7 Transport in bulk according to Annex IIof Marpol and the IBC CodeNot applicable.
· Transport/Additional information:

No dangerous good in sense of these transport
regulations.

· UN "Model Regulation":

Void
DEN

(Contd. on page 8)

44.3.3

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 11

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-LASUR(Contd. of page 7)*

SECTION 15: Regulatory information· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· National regulations:· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Other regulations, limitations and prohibitive regulations· Substances of very high concern (SVHC) according to REACH, Article 57 not applicable· Product-Code/Giscode: BSW10· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

*

SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Department issuing SDS: KEIMFARBEN Germany, Product safety department· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Dangerous Substances, BAuA, Germany)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
AGW: Arbeitsplatzgrenzwert (Germany)
REACH: Registration, Evaluation and Authorisation of Chemicals (Regulation (EC) No.1907/2006)· * Data compared to the previous version altered.
DENPage 1/10

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

SECTION 1: Identification of the substance/mixture and of the company/
undertaking· 1.1 Product identifier· Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)· 1.2 Relevant identified uses of the substance or mixture and uses advised against· Application of the substance / the mixture
Paint
Glaze
· Uses advised against All other uses are not recommended.
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
KEIMFARBEN GMBH
Keimstraße 16 / 86420 Diedorf
Tel. +49 (0)821 4802-0
Fax +49 (0)821 4802-210
www.keim.com / info@keimfarben.de· Further information obtainable from:
Product safety department
Telefon: 49(0)821/4802-138
E-Mail: sdb.info@keimfarben.de· 1.4 Emergency telephone number:
GBK GmbH Global Regulatory Compliance
Emergency number: +49(0)6132/84463

SECTION 2: Hazards identification· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
The product is not classified, according to the CLP regulation.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Additional information:
Contains 2-methylisothiazol-3(2H)-one. May produce an allergic reaction.
· 2.3 Other hazards Alkaline product. Avoid contact with skin and eyes.
· Results of PBT and vPvB assessment· PBT: Not applicable· vPvB: Not applicable
DEN(Contd. on page 2)

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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)(Contd. of page 1)

SECTION 3: Composition/information on ingredients· 3.2 Mixtures· Description:
Aqueous solution of silicic acid potassium salt and/or silica sol, acrylic polymer, mineral fillers,
pigments, additives.
· Dangerous components:
CAS: 2682-20-4
2-methylisothiazol-3(2H)-one<0.0015%
EINECS: 220-239-6
Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox.
Index number: 613-326-00-9 2, H330;
Skin Corr. 1B, H314; Eye Dam. 1, H318;
Aquatic Acute 1, H400; Aquatic Chronic 1, H410;
Skin Sens. 1A, H317
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures· 4.1 Description of first aid measures· General information:
With appearance of symptoms or in cases of doubt seek medical advice .
When seeing the doctor we suggest to present this safety data sheet.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Do not use solvents or thinners.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse mouth and throat well with water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures· 5.1 Extinguishing media· Suitable extinguishing agents:
Product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
· 5.2 Special hazards arising from the substance or mixture
No further relevant information available.
· 5.3 Advice for firefighters· Specila protective equipment: Wear self-contained respiratory protective device.

(Contd. on page 3)
DEN

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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)(Contd. of page 2)· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
In case of fire do not breathe smoke, fumes and vapours.
Cool endangered receptacles with water spray.

SECTION 6: Accidental release measures· 6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Avoid contact with skin and eyes.
Particular danger of slipping on leaked/spilled product.
Respect the protection rules (see section 7 a. 8).
· 6.2 Environmental precautions:
Do not allow product to reach soil, sewage system or any water course.
Follow local governmental rules and regulations.
Dilute with plenty of water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Dispose of the material collected according to regulations.
Clear contaminated areas thoroughly.
Flush rests with sufficient amount of water.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage· 7.1 Precautions for safe handling
Keep receptacles tightly sealed.
Avoid contact with skin and eyes.
Do not inhale aerosols.
Ensure good ventilation/exhaustion at the workplace.
See item 8 (8.2) for information about suitable protective equipment and technical precautions.
Respect the protection rules.
· Information about fire - and explosion protection:
The product is not flammable.
No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Keep in the original containers in a cool and dry place.
Store only in unopened original receptacles.
· Information about storage in one common storage facility: Do not store together with acids.

(Contd. on page 4)
DEN

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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)· Further information about storage conditions:Store in a cool place.
Protect from frost.
Protect from heat and direct sunlight.
· Storage class: 12· 7.3 Specific end use(s) No further relevant information available.

(Contd. of page 3)

SECTION 8: Exposure controls/personal protection· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:alveoles penetrating component
14808-60-7 Quartz (SiO2)
MAK (Germany) alveolengängige Fraktion
2682-20-4 2-methylisothiazol-3(2H)-one
MAK (Germany) Long-term value: 0.2 E mg/m³
vgl. Abschn. Xc· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Avoid contact with the eyes and skin.
Do not inhale aerosols.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing.
· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.
Filter: P2· Protection of hands: Protective gloves· Material of gloves
suitable material e.g.:
Nitrile impregnated cotton-gloves
Recommended thickness of the material: ³ 0.5 mm
Nitrile rubber, NBR
Recommended thickness of the material: ³ 0.4 mm
Butyl rubber, BR
Recommended thickness of the material: ³ 0.7 mm
The selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
Value for the permeation: level ³ 6 (480 min)The determined penetration times according to EN 16523-1:2015 are not performed under practicalconditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,is recommended.
(Contd. on page 5)DEN

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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)(Contd. of page 4)

The exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.
· Eye protection: Tightly sealed goggles· Body protection:
Protective work clothing
After contact with skin wash thoroughly with water and apply lotion.
· Limitation and supervision of exposure into the environment
See Section 12 and 6.2
No further relevant information available.

SECTION 9: Physical and chemical properties· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form:
Pasty
Colour:Medium and dark shades· Odour:Weak, characteristic· Odour threshold:Not determined· pH-value:

Alkaline· Change in condition
Melting point/freezing point:
Not determined
Initial boiling point and boiling range: >100 °C· Flash point:

Not applicable· Flammability (solid, gas):

Not applicable· Ignition temperature:

Not determined· Decomposition temperature:

Not determined· Auto-ignition temperature:

Product is not selfigniting.

· Explosive properties:

Product does not present an explosion hazard.

· Explosion limits:
Lower:
Upper:· Oxidising properties:

Not applicableNot applicableNot applicable· Vapour pressure at 20 °C:~23 hPa· Density at 20 °C:· Relative density· Vapour density· Evaporation rate

1.2-1.6* g/cm³
Not determined
Not applicable.
Not applicable.
(Contd. on page 6)
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)(Contd. of page 5)· Solubility in / Miscibility withwater:

Fully miscible· Partition coefficient: n-octanol/water:

Not applicable· Viscosity:
Dynamic at 20 °C:
Kinematic:· 9.2 Other information

500-4500* mPas
Not determined* The values are for freshly produced material and maychange with the time.

SECTION 10: Stability and reactivity· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions of storage and use.
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Acids· 10.6 Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed.

SECTION 11: Toxicological information· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
2682-20-4 2-methylisothiazol-3(2H)-one
Oral
LD50 235 mg/kg (rat) (männlich)
183 mg/kg (rat) (weiblich)
Dermal LD50 242 mg/kg (rat) (OECD 402)
· Primary irritant effect:· Skin corrosion/irritation Frequent persistent contact with the skin may cause skin irritation.
· Serious eye damage/irritation In case of longer exposure, irritating effect is possible.
· during inhalation: Irritant effect possible.
· during swallowing: Irritant effect possible· Respiratory or skin sensitisation
Contains MIT. May produce an allergic reaction.
MIT = 2-Methyl-4-isothiazolin-3-one· Other information (about experimental toxicology):
Experimental analysis are not available.

(Contd. on page 7)
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)(Contd. of page 6)

The product was not tested. The statements on toxicology have been derived from the properties of
the individual components.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Not applicable· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information· 12.1 Toxicity· Aquatic toxicity:
2682-20-4 2-methylisothiazol-3(2H)-one
NOEC
2.1 mg/l (fish) (33d)0.04 mg/l (daphnia) (21d)EC 50/72 h
0.158 mg/l (algae) (OECD 201)
LC 50/96 h
4.77 mg/l (Oncorhynchus mykiss) (OECD 203)
LC 50/48h
0.93-1.9 mg/l (daphnia)
LC50/EC50/IC50 <1 mg/l (fish)· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· AOX-indication:
Due to the substance of content which do not include organic jointed halogens, the product can nottake influence on the AOX-load of the waste water.
· General notes:
At present there are no ecotoxicological assessments.
The statements on ecotoxicology have been derived from the properties of the individualcomponents.
Do not allow product to reach ground water, water course or sewage system.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable· vPvB: Not applicable· 12.6 Other adverse effects No further relevant information available.
DEN(Contd. on page 8)50.1.8

Page 8/10

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)(Contd. of page 7)

SECTION 13: Disposal considerations· 13.1 Waste treatment methods· Recommendation
Must not be disposed with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· European waste catalogue
08 01 12 waste paint and varnish other than those mentioned in 08 01 11· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary with cleansing agents.

SECTION 14: Transport information· 14.1 UN-Number· ADR, IMDG, IATA

Void

· 14.2 UN proper shipping name
· ADR, IMDG, IATA

Void

· 14.3 Transport hazard class(es)· ADR, IMDG, IATA
· ClassVoid· 14.4 Packing group· ADR, IMDG, IATA

Void

· 14.5 Environmental hazards:· Marine pollutant:No· 14.6 Special precautions for user

Not applicable· 14.7 Transport in bulk according to Annex IIof Marpol and the IBC CodeNot applicable· Transport/Additional information:

No dangerous good in sense of these transport
regulations.

· UN "Model Regulation":

Void
DEN

(Contd. on page 9)50.1.8

Page 9/10

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)(Contd. of page 8)

SECTION 15: Regulatory information· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture· Labelling according to Regulation (EC) No 1272/2008
For information on labelling please refer to section 2 of this document.
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· National regulations:· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Other regulations, limitations and prohibitive regulations· Please note:
TRGS 200 (Germany)
TRGS 500 (Germany)
TRGS 510 (Germany)
TRGS 900 (Germany)· Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable· Product-Code/Giscode: BSW20· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
· Department issuing SDS: KEIMFARBEN Germany, Product safety department· Abbreviations and acronyms:

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Dangerous Substances, BAuA, Germany)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent(Contd. on page 10)DEN

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Page 10/10

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.03.2020

Version number 1.0

Revision: 17.03.2020

Trade name: ALL KEIM-PAINTS AND -GLAZES in the price groups PG2 and PG3(medium and dark shades)
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
AGW: Arbeitsplatzgrenzwert (Germany)
REACH: Registration, Evaluation and Authorisation of Chemicals (Regulation (EC) No.1907/2006)
Acute Tox. 3: Acute toxicity - oral – Category 3
Acute Tox. 2: Acute toxicity - inhalation – Category 2
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Skin Sens. 1A: Skin sensitisation – Category 1AAquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1(Contd. of page 9)DEN

50.1.8