ᐇ㦂ሗ࿌᭩ᵝᘧ䠄୍⯡฼⏝ㄢ㢟䞉ᡂᯝබ㛤฼⏝䠅㻌䠄 䈜ᮏሗ࿌᭩䛿ⱥㄒ䛷グ㏙䛧䛶䛟䛰䛥䛔䚹䛯䛰䛧䚸⏘ᴗ฼⏝ㄢ㢟䛸䛧䛶᥇ᢥ䛥䜜䛶䛔䜛᪉䛿᪥ᮏㄒ䛷グ㏙䛧䛶䛔䛯䛰䛔䛶䜒⤖ᵓ䛷䛩䚹 䠅㻌

承認日DateApprovalᥦฟ᪥
DateofofReport㻌2015/01/04

Experimental Report㻌

承認者Approver Jun-ichi Suzuki

㻌提出日Date of Report 2014/09/03

ㄢ㢟␒ྕ㻌 Project No.㻌⿦⨨㈐௵⪅ Name of responsible person㻌㻞㻜㻝㻞㻭㻜㻜㻠㻝㻌㕥ᮌ῟ᕷ㻌ᐇ㦂ㄢ㢟ྡ㻌 Title of experiment㻌⿦⨨ྡ Name of Instrument/䠄BL No.䠅㻌

୰ᛶᏊᑠゅᩓ஘ἲ䛻䜘䜛⪏ೃᛶ㗰ᮦ䛾⏕ᡂ䛥䜃䛾ホ౯㻌㼀㻭㻵㻷㻭㻺㻌㻔㻮㻸㻝㻡㻕㻌㻭㼚㼍㼘㼥㼟㼕㼟㻌㼛㼒㻌㼞㼡㼟㼠㻌㼘㼍㼥㼑㼞㼟㻌㼛㼒㻌㼣㼑㼍㼠㼔㼑㼞㼕㼚㼓㻌㼟㼠㼑㼑㼘㻌㼎㼥㻌㻿㻭㻺㻿㻌ᐇ᪋᪥᫬ Date and time of Experiment㻌ᐇ㦂㈐௵⪅ྡ㻌 Name of principal investigator㻌㻞㻜㻝㻞㻛㻝㻝㻛㻡㻌㻭㻹㻥㻦㻜㻜㻌䇵㻌㻝㻝㻛㻣㻌㻭㻹㻥㻦㻜㻜㻌୰ᒣ㻌 Ṋ඾㻌㻔㻠㻤 ᫬㛫㻕㻌ᡤᒓ㻌 Affiliation㻌ᰴᘧ఍♫⚄ᡞ〇㗰ᡤ㻌㻌ヨᩱ䚸ᐇ㦂᪉ἲ䚸฼⏝䛾⤖ᯝᚓ䜙䜜䛯୺䛺䝕䞊䝍䚸⪃ᐹ䚸⤖ㄽ➼䜢䚸グ㏙䛧䛶ୗ䛥䛔䚹䠄㐺ᐅ䚸ᅗ⾲ῧ௜䛾䛣䛸䠅㻌
Please report your samples, experimental method and results, discussion and conclusions. Please add figures andtables for better explanation.
㻝㻚㻌 ヨᩱ Name of sample(s) and chemical formula, or compositions including physical form.㻌
┠ⓗࡉࡧᒙࡢ೺඲ᛶ㸦ಖㆤᛶᶵ⬟㸧ࡣࡉࡧ⢏Ꮚࡢᑍἲ࣭ᙧ≧ࠊ࠶ࡿ࠸ࡣࡉࡧᒙ୰ࡢ࣎࢖ࢻࡸḞ㝗࡞࡝ࡀ㛵ಀࡍࡿ࡜࡜ࡶ࡟ࠊ኱Ẽ୰ࡢỈศ㸦⤖㟢ࡸ㞵Ỉ࡟ࡼࡿ⃿ࢀ㸧ࡢᙳ㡪ࡀ⪃࠼ࡽࢀࡿࠋࡑࡢࡓࡵࠊホ౯ࡸ࣓࢝ࢽࢬ࣒✲᫂࡟ࡣࠊཎ⌮ⓗ࡟ࠊ㠀◚ቯ࠿ࡘ᫬⣔ิ࡛ࣂࣝࢡᵓ㐀య࡟࠾ࡅࡿࠊᚤ⣽⢏Ꮚࡸᮦᩱ⤌⧊ࠊ࠶ࡿ࠸ࡣỈ࣭Ỉ⣲࡞࡝ࢆほᐹྍ⬟࡞୰ᛶᏊᑠゅᩓ஘ἲࡀ᭷ຠᡭẁࡢ୍ࡘ࡜⪃࠼ࡽࢀࡿࠋᮏ◊✲࡛ࡣࠊ⪏ೃᛶ㗰࠾ࡼࡧᬑ㏻㗰ୖ࡟⏕ᡂࡉࢀࡓࡉࡧ࡟ᑐࡋ࡚ࠊ⃿ࢀ≧ែ࠿ࡽ஝⇱≧ែࠊ஝⇱≧ែ࠿ࡽ⃿ࢀ≧ែ࡟࠾ࡅࡿ᫬ศ๭ࡑࡢሙ୰ᛶᏊᑠゅᩓ஘ ᐃࢆ⾜࠸ࠊࡉࡧᒙࡢಖㆤᛶᶵ⬟ゎ᫂࡟㈨ࡍࡿࠋヨᩱ-,6 ⪏ೃᛶ㗰࠾ࡼࡧᬑ㏻㗰ࢆ PP ゅࠊཌࡉ PP ࡟ษࡾฟࡋࠊࡑࢀࡒࢀࡢ㗰ᮦ࡟ᑐࡋ࡚ࠊ୧㠃ࢆ 
ࡢ 1D&O Ỉ⁐ᾮ࡛  ᫬㛫⃿ࡽࡋࠊࡑࡢᚋ  ᫬㛫஝⇱ࡉࡏࡿ࡜࠸࠺ᡭ㡰ࢆ  ࣨ᭶㛫⧞㏉ࡋ⾜࠸ࠊ⾲㠃࡟ࡉࡧࢆ⏕ᡂࡉࡏࠊヨᩱ࡜ࡋࡓࠋ-,6 ⪏ೃᛶ㗰ࠊᬑ㏻㗰࡜ࡶ࡟⏕ᡂࡋࡓࡉࡧᒙࡢཌࡉࡣࠊ࣐࢖ࢡ࣓࣮ࣟࢱ࡟ࡼࡿィ ࠿ࡽࠊ୰ᚰ㒊௜㏆࡛∦㠃࠶ࡓࡾ࠾ࡼࡑ  ੇ࡜ぢ✚ࡶࡽࢀࡿࠋ ᐃ࡟ࡣࠊྛヨᩱࢆࡑࢀࡒࢀ ᯛࡎࡘ⏝࠸࡚ࠊྜィཌࡉ⣙ PP ྜィࡉࡧᒙཌࡉ࠾ࡼࡑ  ੇ ࡜ࡋࡓࠋ;5' ࡢ ᐃ⤖ᯝ࠿ࡽࠊ-,6 ⪏ೃᛶ㗰ࠊᬑ㏻㗰࡟⏕ᡂࡋࡓࡉࡧࡣ୺࡟ș)H22+ ࡛ᵓᡂࡉࢀ࡚࠸ࡓࠋ ᐃ๓ࡢヨᩱࡢᵝᏊࢆ෗┿ ࠊ෗┿  ࡟♧ࡍࠋ㻌㻌㻌㻌㻌㻌㻌㻌෗┿ 㸸ᬑ㏻㗰㸦60㸧෗┿ 㸸-,6 ⪏ೃᛶ㗰㸦6$8㸧
1㻞㻚㻌 ᐇ㦂᪉ἲཬ䜃⤖ᯝ㻌 䠄ᐇ㦂䛜䛖䜎䛟䛔䛛䛺䛛䛳䛯ሙྜ䚸䛭䛾⌮⏤䜢グ㏙䛧䛶䛟䛰䛥䛔䚹䠅㻌
Experimental method and results. If you failed to conduct experiment as planned, please describe reasons.
ᐇ㦂᪉ἲ㸦㸯㸧⿦⨨኱ᙉᗘ㝧Ꮚຍ㏿ჾ᪋タ -3$5& ≀㉁࣭⏕࿨⛉Ꮫᐇ㦂᪋タ 0/) ෆ࡟タ⨨ࡉࢀ࡚࠸ࡿ኱ᙉᗘᆺᑠ୰ゅᩓ஘⿦⨨ %/7$,.$1 ࢆ⏝࠸ࡓࠋ⿦⨨᮲௳ࢆ௨ୗ࡟♧ࡍࠋ࣭ᐃ᮲௳฼⏝Ἴ㛗ύȢύࣞࣥࢪ4ύA༳ຍ☢ሙ% 7 㸦㸰㸧 ᐃ᪉ἲ

ᐃࡣ᪂ࡓ࡟సᡂࡋࡓࢸࣇࣟࣥ〇ᐃࢭࣝࢆ⏝࠸ࠊୗグࡢ㡰ᗎ࡛ᐇ᪋ࡋࡓࠋᐃࡣ㟁☢▼ࢆ⏝࠸࡚% 7 ࡢ☢ሙࢆỈᖹ᪉ྥ࡟༳ຍࡋ࡚⾜ࡗࡓࠋ ᐃࡢᵝᏊࢆ෗┿  ࡟♧ࡍࠋ 㸯㸬 ᐃ๓࡟࣮ࣟࢱ࣮࣏ࣜࣥࣉࢆ⏝࠸ࠊヨᩱࢆ༑ศ࡟஝⇱ࡉࡏ࡚ ᐃࢆ⾜ࡗࡓࠋ ᐃ᫬㛫ࡣ  ᫬㛫࡜ࡋࡓࠋ㸦௨ୗ GU\LQLWLDO ࡜ࡍࡿ㸧 㸰㸬GU\LQLWLDO ࡢ ᐃᚋࠊ+2 ࢆ༑ศྵࡲࡏࡓ࣋ࣥࢥࢵࢺ࡛ヨᩱࢆそ࠸ࠊヨᩱ࡟ +2 ࢆྵࡲࡏࡓࠋࡑࡢᚋࠊ࣋ࣥࢥࢵࢺࢆྲྀࡾ㝖ࡁࠊヨᩱࢆᐃࢭࣝ࡟タ⨨ࡋࡓࠋ஝⇱✵Ẽࢆࣇ࣮ࣟࡉࡏ࡞ࡀࡽࠊ⃿ࢀ≧ែ࠿ࡽ஝⇱≧ែ࡬ࡢ⛣⾜ࡢ㐣⛬ࢆ ᐃࡋࡓࠋ ᐃ᫬㛫ࡣ  ᫬㛫࡜ࡋࠊ ᫬㛫ẖ࡟ࢹ࣮ࢱࢆ༊ษࡗ࡚ྲྀࡾฟࡋࡓ㸦௨ୗ ZHWЍGU\ ࡜ࡍࡿ㸧ࠋࡇࡢ ᐃ࡟࠾࠸࡚ࠊヨᩱ࡟ +2 ࢆྵࡲࡏ࡚࠿ࡽ⤒㐣ࡋ࡚࠸ࡿࠋࡇࡢࡓࡵࠊᐃࡲ࡛࡟⣙  ᫬㛫ࡀᐃ⤖ᯝࡣ஝⇱᫬㛫ࡀձKࠊղKࠊճKࠊմKࠊյK ࡜ࡋ࡚⾲ࡍࠋ 㸱㸬ZHWЍGU\ ࡢ ᐃᚋࠊ㣬࿴Ỉ⵨Ẽࢆసᡂࡋࡓࢹࢩࢣ࣮ࢱ࡜ ᐃࢭࣝࢆࡘ࡞ࡂࠊ஝⇱≧ែ࠿ࡽ⃿ࢀ≧ែ࡬ࡢ⛣⾜㐣⛬ࡢ ᐃࢆ⾜ࡗࡓࠋ ᐃ᫬㛫ࡣ  ᫬㛫࡜ࡋࠊ ᫬㛫ẖ࡟ࢹ࣮ࢱࢆ༊ษࡗ࡚ྲྀࡾฟࡋࡓ㸦௨
ୗ GU\ЍZHW ࡜ࡍࡿ㸧ࠋࡇࡢᐃ⤖ᯝࡣնKࠊշK ࡜ࡋ࡚⾲ࡍࠋ 㸲㸬ሷ㓟ࠊ࣊࢟ࢧ࣓ࢳࣞࣥࢸࢺ࣑ࣛࣥࠊࣄࣅࣟࣥࢆΰྜࡋࡓࡉࡧⴠ࡜ࡋ⏝ᾮࢆ⏝࠸ࠊヨᩱ⾲㠃ࡢࡉࡧࢆ㝖ཤࡋࡓࡢࡕࠊ㗰ᮦヨᩱࡢᇶᮦ㒊ศࡢ ᐃࢆ⾜ࡗࡓࠋ ᐃ᫬㛫ࡣ  ᫬㛫࡜ࡋࡓࠋ㸦௨ୗ EDVH ࡜ࡍࡿ㸧FP෗┿ ᐃ᫬ࡢᵝᏊ

2㻞㻚㻌 ᐇ㦂᪉ἲཬ䜃⤖ᯝ䠄䛴䛵䛝䠅㻌 Experimental method and results (continued)ᐃ⤖ᯝ࠾ࡼࡧ⪃ᐹ䠍䠊㻶㻵㻿 ⪏ೃᛶ㗰䛾 ᐃ⤖ᯝ㻌ᐃ᪉ἲ࡛♧ࡋࡓ 㹼 ࡢྛᡭ㡰࡟࠾ࡅࡿ᰾ᩓ஘㒊ศࡢ ᐃ⤖ᯝࢆᅗ D ࡟♧ࡍࠋࡲࡓࠊᙉᗘኚ໬ࡢ
౛࡜ࡋ࡚ࠊT ࠊࠊ ࡟࠾ࡅࡿᙉᗘኚ໬ࢆᅗ E ࡟♧ࡍࠋ᰾ᩓ஘࡜☢Ẽᩓ஘ࡢศ㞳࡟ࡘ࠸࡚ࡣࠊ' ࣄࢫࢺࢢ࣒ࣛࢆ⏝࠸ࠊᐇ✵㛫࡟࠾࠸࡚Ỉᖹ᪉ྥ࠿ࡽsrࢆ᰾ᩓ஘ࠊ㖄┤᪉ྥ࠿ࡽsrࢆ☢Ẽ㸩᰾ᩓ஘ࡢຠᯝ࡜⪃࠼࡚ศ㞳ࡋࡓࠋ ᐃࡢ⤖ᯝࠊୗグࡢ㏻ࡾ࡛࠶ࡗࡓࠋ
࣭GU\LQLWLDO ࡣ EDVH ࡼࡾࡶᙉᗘࡀ㧗ࡃほ ࡉࢀࡓࠋ
࣭ZHWЍGU\ ࡛ࡣࠊձK ࡛ GU\LQLWLDO ࡼࡾࡶᙉᗘࡀ㧗ࡃ࡞ࡗ࡚࠸ࡓࠋࡲࡓࠊ஝⇱᫬㛫ࡢ⤒㐣࡟ࡼࡗ࡚඲యࡢᙉᗘࡀୖ᪼ࡋ࡚࠾ࡾࠊ≉࡟ձK ࠿ࡽղK ࡟࠾࠸࡚ࠊ኱ࡁࡃᙉᗘࡀୖ᪼ࡋ࡚࠸ࡓࠋճKࠊմKࠊյK ࡛ࡣᙉᗘࡣ࡯࡜ࢇ࡝ኚ໬ࡋ࡞࠿ࡗࡓࠋ࣭GU\ЍZHW ࡛ࡣࠊZHWЍGU\ ࡟࠾ࡅࡿյK ࡜ẚ㍑ࡋࠊնK ࡜շK ࡜ࡶ࡟ᙉᗘࡀపୗࡋ࡚࠾ࡾࠊT! ࡛ࡣ ZHWЍGU\ ࡢձK ࡜࡯ࡰྠࡌ࡜࡞ࡗࡓࠋࡲࡓࠊT ࡢᙉᗘࡣ ZHWЍGU\ ࡢձKࡼࡾࡶ㧗ࡃ࡞ࡗ࡚࠸ࡓࠋࡋ࠿ࡋࠊ⃿ࢀ᫬㛫ࡢ⤒㐣࡟ࡼࡿᙉᗘኚ໬ࡣほ ࡛ࡁ࡞࠿ࡗࡓࠋ ௒ᅇࡢ ᐃ⤖ᯝ࠿ࡽࠊEDVH ࡜ GU\LQLWLDO ࢆẚ㍑ࡍࡿ࡜ࠊ⪏ೃᛶ㗰ୖ࡟ࡣᩘ QP ࢧ࢖ࢬࡢࡉࡧ⢏Ꮚࡀ⏕ᡂࡋ࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋࡲࡓࠊZHWЍGU\ ࡢ ᐃ࡟࠾࠸࡚ࠊ᫬㛫⤒㐣࡟ࡼࡗ࡚ᙉᗘࡀୖ᪼ࡋ࡚࠸ࡿࡇ࡜࠿ࡽࠊヨᩱࡢ஝⇱ࡀ㐍ࡴࡇ࡜࡛ࠊࡉࡧࡀ⏕ᡂࠊᡂ㛗ࡋ࡚࠸ࡿࡲࡓࡣࠊࡉࡧ⢏Ꮚࡢᡂศࡀኚ໬ࡋ࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋࡋ࠿ࡋࠊGU\ЍZHW ࡢ ᐃ࡛ࡣᙉᗘࡀపୗࡋ࡚࠾ࡾࠊࡇࡢ ᐃ࡛ࡣࡉࡧ࡟྾╔ࡋࡓỈศᏊࡶྵࡵ࡚ᐃࡋ࡚࠸ࡿࡓࡵࠊࡇࢀࡽࡢኚ໬ࡣỈศᏊ࡟ࡼࡿࢥࣥࢺࣛࢫࢺኚ໬ࢆྵࢇ࡛࠸ࡿྍ⬟ᛶࡀ࠶ࡿࠋ㻌㻌䢵㻌䢴㻌䢳䢲䣋䣰䣶䣧䣰䣵䣫䣶䣻䢢䢪䣣䣴䣤䢰䢢䣷䣰䣫䣶䣵䢫㻌㻌㻌㻌㻌㻌䣌䣋䣕⪏ೃᛶ㗰䢹䢸䢷䢶䢵䢴䢸䢳䢲䢢䣳䢢䢿䢢䢲䢰䢲䢷䢢䣳䢢䢿䢢䢲䢰䢳䢢䣳䢢䢿䢢䢲䢰䢴䢸䢷䢶㻌䢵㻌㻌䣹䣧䣶䢯䣦䣴䣻䷻䢳䢯䢴䣪䷺䢲䢯䢳䣪䷹䢷䢯䢸䣪䷸䢶䢯䢷䣪䷷䢵䢯䢶䣪䷶䢴䢯䢵䣪䷵䢳䢯䢴䣪㻌䣦䣴䣻䢢䣫䣰䣫䣶䣫䣣䣮䣤䣣䣵䣧䢴䣦䣴䣻䢯䣹䣧䣶㻌ᅗ䠍㼍䠖㻶㻵㻿 ⪏ೃᛶ㗰䛾୰ᛶᏊᑠゅᩓ஘ ᐃ⤖ᯝ㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 ᅗ 㻝㼎䠖㼝㻩㻌㻜㻚㻜㻡㻘㻌㻜㻚㻝㻘㻌㻜㻚㻞 䛷䛾ᙉᗘኚ໬㻌㻌㻌㻌3㻌䠎䠊ᬑ㏻㗰䛾 ᐃ⤖ᯝ㻌ᐃ᪉ἲ࡛♧ࡋࡓ 㹼 ࡢྛᡭ㡰࡟࠾ࡅࡿ᰾ᩓ஘㒊ศࡢ ᐃ⤖ᯝࢆᅗ D ࡟♧ࡍࠋࡲࡓࠊᙉᗘኚ໬ࡢ౛
࡜ࡋ࡚ࠊT ࠊࠊ ࡟࠾ࡅࡿᙉᗘኚ໬ࢆᅗ E ࡟♧ࡍࠋ᰾ᩓ஘࡜☢Ẽᩓ஘ࡢศ㞳࡟ࡘ࠸࡚ࡣࠊ
' ࣄࢫࢺࢢ࣒ࣛࢆ⏝࠸ࠊᐇ✵㛫࡟࠾࠸࡚Ỉᖹ᪉ྥ࠿ࡽsrࢆ᰾ᩓ஘ࠊ㖄┤᪉ྥ࠿ࡽsrࢆ☢Ẽ㸩᰾ᩓ஘ࡢຠᯝ࡜⪃࠼࡚ศ㞳ࢆ⾜ࡗࡓࠋ ᐃࡢ⤖ᯝࠊୗグࡢ㏻ࡾ࡛࠶ࡗࡓࠋ
࣭GU\LQLWLDO ࡣ EDVH ࡼࡾࡶᙉᗘࡀ㧗ࡃほ ࡉࢀࡓࠋ
࣭ZHWЍGU\ ࡛ࡣࠊձK ࡟࠾࠸࡚ࠊGU\LQLWLDO ࡼࡾࡶᙉᗘࡀ㧗ࡃ࡞ࡗ࡚࠸ࡓࠋࡋ࠿ࡋ࡞ࡀࡽࠊ஝⇱᫬㛫ࡢ⤒㐣࡟ࡼࡿᙉᗘኚ໬ࡣ࡯࡜ࢇ࡝ほ ࡉࢀ࡞࠿ࡗࡓࠋ࣭GU\ЍZHW ࡛ࡣࠊZHWЍGU\ ࡢձK ࡜࡯ࡰྠࡌᙉᗘ࡛࠶ࡾࠊ⃿ࡽࡋ᫬㛫ࡢ⤒㐣࡟ࡼࡿᙉᗘኚ໬ࡣ࡯࡜ࢇ࡝ほ ࡉࢀ࡞࠿ࡗࡓࠋ㻌௒ᅇࡢ ᐃ⤖ᯝ࠿ࡽࠊEDVH ࡜ GU\LQLWLDO ࢆẚ㍑ࡍࡿ࡜ࠊᬑ㏻㗰ୖ࡟ࡶ⪏ೃᛶ㗰࡜ྠᵝ࡟ᩘ QP ࢧ࢖ࢬࡢࡉࡧ⢏Ꮚࡀ⏕ᡂࡋ࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋZHWЍGU\ࠊGU\ЍZHW ࡢ ᐃ࡛ࡣᙉᗘࡀ࡯࡜ࢇ࡝ኚ໬ࡋ࡚
࠸࡞࠸ࡇ࡜࡟ࡘ࠸࡚ࡣࠊGU\LQLWLDO ࡢ ᐃᚋࠊヨᩱࢆ⃿ࡽࡋ࡚࠿ࡽ ZHWЍGU\ ࡢ ᐃࡲ࡛࡟  ᫬㛫ࡀ⤒㐣ࡋ࡚࠸ࡿࡓࡵࠊヨᩱࡢ஝⇱ࡀ㐍⾜ࡋࡓྍ⬟ᛶࡀ⪃࠼ࡽࢀࡿࠋࡲࡓࠊヨᩱࢆ⃿ࡽࡋࡓ㝿ࠊ࣋ࣥࢥࢵࢺࢆྲྀࡾ㝖ࡃ᫬࡟ヨᩱୖࡢࡉࡧࡶࡣࡀࢀࡓྍ⬟ᛶࡀ࠶ࡿࠋࡇࡢࡓࡵ GU\LQLWLDO ࡟ẚ࡭࡚ࡉࡧ㔞ࡀᑡ࡞ࡃ࡞ࡾࠊኚ໬ࡀᑠࡉࡃ࡞ࡗࡓྍ⬟ᛶࡀ⪃࠼ࡽࢀࡿࠋࡇࡢᐃ࡛ࡣࡉࡧ࡟྾╔ࡋࡓỈศᏊࡶྵࡵ࡚ᐃࡋ࡚࠸ࡿࡓࡵࠊࡇࢀࡽࡢኚ໬ࡣỈศᏊ࡟ࡼࡿࢥࣥࢺࣛࢫࢺኚ໬ࢆྵࢇ࡛࠸ࡿྍ⬟ᛶࡀ࠶ࡿࠋ㻌㻌㻌䢵㻌䢴䢳䢲䢸㻌䢵㻌䢴㻌㻌䣹䣧䣶䢯䣦䣴䣻䷻䢳䢯䢴䣪䢸䢷䢶䣤䣣䣵䣧㻌䷺䢲䢯䢳䣪䢳䢲䷹䢷䢯䢸䣪㻌䢴䷸䢶䢯䢷䣪㻌䢵䷷䢵䢯䢶䣪㻌䢸䢷䢶䷶䢴䢯䢵䣪㻌䷵䢳䢯䢴䣪䣋䣰䣶䣧䣰䣵䣫䣶䣻䢢䢪䣣䣴䣤䢰䢢䣷䣰䣫䣶䣵䢫㻌䢢䣳䢢䢿䢢䢲䢰䢲䢷䢢䣳䢢䢿䢢䢲䢰䢳䢢䣳䢢䢿䢢䢲䢰䢴䢹䣦䣴䣻䢢䣫䣰䣫䣶䣫䣣䣮㻌ᬑ㏻㗰䣦䣴䣻䢯䣹䣧䣶ᅗ 㻞㼍䠖ᬑ㏻㗰䛾୰ᛶᏊᑠゅᩓ஘ ᐃ⤖ᯝ㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 ᅗ 㻞㼎䠖㼝㻩㻌㻜㻚㻜㻡㻘㻌㻜㻚㻝㻘㻌㻜㻚㻞 䛷䛾ᙉᗘኚ໬㻌4ࡲ࡜ࡵ௒ᅇࡢᐇ㦂ࡢ⤖ᯝࠊ-,6 ⪏ೃᛶ㗰࠾ࡼࡧᬑ㏻㗰ୖࡢࡉࡧࡢ⃿ࢀ࣭஝ࡁ࡟࠾ࡅࡿ LQVLWX ୰ᛶᏊᑠゅᩓ஘ᐃࢆ⾜ࡗࡓࠋ-,6 ⪏ೃᛶ㗰࡛ࡣࠊZHWЍGU\ ࡢ ᐃ࡟࠾࠸࡚ࠊࡉࡧࡀ஝⇱ࡋ࡚࠸ࡃ㐣⛬ࡢ᫬㛫ኚ໬ࡀほ ࡛ࡁࡓࠋࡋ࠿ࡋ GU\ЍZHW ࡟࠾ࡅࡿࡉࡧࡢ⃿ࢀ㐣⛬࡛ࡣࠊ᫬㛫ኚ໬ࡣほ ࡉࢀ࡞࠿ࡗࡓࠋ
ࡲࡓࠊᬑ㏻㗰࡛ࡣ஝⇱㐣⛬㸦ZHWЍGU\㸧ࠊ⃿ࢀ㐣⛬㸦GU\ЍZHW㸧࡟࠾࠸࡚ࠊᙉᗘࡢ᫬㛫ኚ໬ࡣほ ࡛ࡁ࡞࠿ࡗࡓࠋ
㻌௒ᚋ࡟ࡘ࠸࡚ヨᩱࡢ஝⇱㐣⛬㸦ZHWЍGU\㸧࡛ࡣࠊヨᩱࡢ‽ഛ࠿ࡽ ᐃࡲ࡛࡟⣙  ᫬㛫ࡀ⤒㐣ࡋ࡚࠸ࡿࡓࡵࠊᮏ᮶ࡢ஝⇱᫬㛫࠿ࡽࡣ␗࡞ࡗ࡚࠾ࡾࠊヨᩱࡢ஝⇱ࡀ㐍ࢇ࡛࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋࡇࡢࡓࡵࠊヨᩱ࡟ྵࡲࢀࡿỈࡢ㔞ࡶぢ✚ࡶࡾࠊ⪃ᐹࢆ㐍ࡵࡿᚲせࡀ࠶ࡿࠋࡲࡓࠊヨᩱࡢ‽ഛࡢ㝿࡟ࠊࡉࡧࡀ๤㞳ࡋࡉࡧࡢ⥲㔞ࡀኚ໬ࡋ࡚࠸ࡿྍ⬟ᛶࡀ࠶ࡿࡓࡵࠊ௒ᚋࡢᐃ࡛ࡣࠊ๤㞳ࡋ࡞࠸᪉ἲ࡛ࡢヨᩱㄪᩚ᪉ἲࢆ᳨ウࡋ࡚࠸ࡃࠋᐃࡢ㝿࡟ࡣࠊࡉࡧෆ㒊࡟ࢺࣛࢵࣉࡉࢀࡓ +2 ࡢຠᯝࡶྠ᫬࡟ ᐃࡋ࡚࠸ࡿࡓࡵࠊ ᐃ⤖ᯝ࠿ࡽࡉࡧࡢ⢏Ꮚࢧ࢖ࢬࠊᙧ≧ࢆồࡵࠊࡑࡢ᫬㛫ኚ໬ࢆ㆟ㄽࡋ࡚࠸ࡃࠋࡲࡓࠊ;5' ࡟ࡼࡿ⤖ᬗᵓ㐀ࡢኚ໬ࡶྜࢃࡏ࡚㆟ㄽࡋࠊࡉࡧ⢏Ꮚࡢᡂศࡢኚ໬࡟ࡘ࠸࡚ࡶ⪃ᐹࢆ㐍ࡵ࡚࠸ࡃࠋ௒ᅇࡢ⤖ᯝ࡜ẚ㍑ࡍࡿࡓࡵࠊ㔜Ỉࢆ⏝࠸ࡓྠᵝࡢ ᐃࡸࠊᐇ㗰ᯈୖ࡟⮬↛࡟⏕ᡂࡋࡓࡉࡧࡢ ᐃ࡟ࡘ࠸࡚ࡶ᳨ウࢆ⾜ࡗ࡚࠸ࡃࠋ㻌5