Flame Retardants
Non-Halogen Phosphoric Acid Esters
ProductsFormula

Color
APHA

Colorlessclear liquid≦30

1.215±0.005≦0.2

Colorlessclear liquid≦20

1.071±0.003≦0.05

Appearance

O=P(OCH3)3

25

TEP

O=P(OC2H5)3［ mPa・s /25˚C ］

Containers

Description—

220kg
Drum

Relatively low boiling point.
Completely soluble in water.
Low viscosity.
High phosphorus content.
Good compatibility with various synthetic resins.
Purity Wt % ≧99.0

111

210kg
Drum

Soluble in organic solvent as well as water.
Low viscosity.

22525kg
Paper bag
*1 500kg

Uses

180 ~ 195《101kPa》

≦-70
[2.0]

22.1

1.403±0.002

—

—

216
《101kPa》

-56
[1.6]

17.0

—

—

Chloride
not cause
turbidness

Melting
Point ˚C
≧48.5

399
《101kPa》—

Color after
heated150˚C ×1hr･APHA≦60

Volumeresistivity
30˚C Ω cm≧5x109241 ~ 255
《0.53kPa》

≦-20
[58]

8.4

240

220kg
Drum

—
*2 0.27kPa《240 ~ 260》

〕

-15
[172]

7.6

253

220kg
Drum

—
*2 0.53kPa
《245》

〕

-30
[36]

9.1

240

220kg
Drum

Effective in polyvinylchloride.
Plasticizer with flame retarding forBringing cold resistance and stain resistance.
polyvinylchloride, phenolic resin, epoxy resin
Higher phosphorus content, lower viscosityand various engineering plastics.
and better flame retarding than TCP.
Solid at room temperature, easily impregnated in polyester fiber, anddoes not bleed out easily after impregnation. Higher concentration
Flame retardant for same bath treatment ofof flame retardant to be impregnated in flame proofing in same bathpolyester fiber.
treatment helps increase the concentration of flame retardant to beimpregnated. This provides excellent flame resistance for polyester fiber.
Used in a wide range of thermosetting resins
Excellent hydrolysis resistance results in highsuch as phenol, epoxy and polyurethane resin
insulation.
or various engineering plastics.

——

Plasticizer with flame retarding for thermosetting resins such as rigid polyurethane foam
and unsaturated polyester resins.

182

TPP

Triphenyl phosphate

White
flake

—

—

Colorlessto light
O=P(OC6H4CH3)3
yellowish
368 clear liquid≦50

1.170±0.010

≦0.05

≦0.10

1.557±0.003

Colorless toyellowishclear liquid≦200

1.145±0.025

≦0.1

≦0.15

1.552±0.003——

Colorless tolightyellowish
OC6H4CH3
clear liquid
340

≦50

1.210±0.005≦0.05≦0.15———

Melting
Point ˚C(≧125)—

1299.6254

20kg
Paper bag

Viscosity
mPa・s /25˚C
1,200 ~ 1,800

—

-14

7.8

256

220kg
Drum

O=P(OC6H5)3

≦0.03

326

TCP

Tricresyl phosphate

TXP

Trixylenyl phosphate

O=P[OC6H3(CH3)2]3

CDP

O=P

―

Cresyl diphenylphosphate―

410

DAIGUARD-1000(Whitepowder)——(≦0.5)——

Water
Content %(≦0.5)〔OC6H3(CH3)2〕2 Colorless toyellowish
clear liquid
OC6H4CH3—

1.160±0.020≦0.10——Water
Content %≦0.10—―

Non-halogen
phosphoric acid ester

PX-110(OC6H5)2―

Cresyl, di-2,6-xylenyl O=P
phosphate

396

〔〔9.5

Aromatic
polyphosphate

CR-741(BDP)
Aromatic
polyphosphate

PX-200(RDX)
Aromatic
polyphosphate

O=P(OC6H5)2|O
C6H4O|

O=P(OC6H5)2 

Principal
ingredient(C6H5O)2P(O)OC6H4C(CH3)2
C6H4OP(O)(OC6H5)2
Principal
ingredient[(CH3)2C6H3O]2P(O)OC6H4OP(O)[OC6H3(CH3)2]2

Specifications
Acid
Watervalue
Content
KOH mg/g%

Others

CR-733S(RDP)

FormulaBringing heat resistance and electric insulation
property to polyvinylchloride.
Flame retarding.
Very high performance for extreme pressure Plasticizer with flame retarding for agricultural
polyvinylchloride film, phenol resin, epoxy
in addition to lubrication.
resin and various engineering plastics.
Low volatility.
Non-flammable hydraulic oil.
High performance for water resistance.
Additive for extreme pressure lubricant oil.
Flame retarding.
Good extreme pressure lubrication same asTCP.

*1 Flexible container bag*2 Vapor pressure

Non-Halogen Phosphoric Acid Polyesters (1)ProductsFlaky solid material.
Good compatibility with nitrocellulose, Plasticizer with flame retarding for phenolic
acetylcellulose and polyvinylchloride.
resin, epoxy resin, various engineering
Low volatility.
plastics, acetate plastics and synthetic rubber.
Bringing water resistance and oil resistance.

Resin Modifiers

P%
≧21.0

Metal Extractants

Water
Content %≦0.2

Flame Retardants

FlashPoint
˚C

1.395±0.002

140

Triethyl phosphate

Typical Properties
Freezing PointP
˚C
Viscosity%

Boiling
Point˚C》: Measurement condition

Plasticizers
and Solvents

TMPSpecifications
Heating Loss Refractive
Acid%value
KOH mg/g 125˚C ×3hrs Index n D

SpecificGravity
20/20˚C

mol.weight

Trimethyl phosphate《Typical PropertiesAppearance

ColorAPHA

SpecificGravity
20/20˚C

Colorless tolightyellowish
clear liquid≦801.306±0.010

≦0.5

≦0.15

Viscosity
mPa・s /25˚C
500 ~ 800P%
≧10.5-13—

10.9

Colorless toyellowish
clear liquid—1.260±0.010≦0.2≦0.10——

4~52,300《40 ˚C》

White
powderto granule*≦100—≦0.5≦0.5

Melting
point ˚C
≧92P%
≧8.7——Freezing
Point˚C

Viscosity
mPa・s /25˚CP%FlashPoint˚CContainers

Description

Uses

302

220kg
Drum

High performance for heat resistance andlower volatility than TPP and TXP, due to its
condensed structure.

8.9334220kg
DrumHigh hydrolytic stability and heat resistance Flame retardant for various engineeringand bringing high insulation property, due to plastics and synthetic fiber.
its condensed structure.
TPP Content % ≦1.00

9.030825kg
Paper bagHigh hydrolytic stability and heat resistance.

* Xylene dissolved color

1112Flame Retardants
Halogen Containing Phosphoric Acid EsterProductsFormulaColorAPHA)―(―Tris(chloropropyl)
phosphate

CH3

Colorlessto lightyellowish
clear liquid

CH2Cl 3

O=P OCH≦50

1.293±0.005

328

Specifications
AcidWatervalue
Content
KOH mg/g%≦0.10≦0.10》: Measurement condition）: Typical value

Typical Properties
Heating Loss%
105˚C ×3hrs

RefractiveIndex n D≦0.30

1.463±0.003

25

˚C

ViscositymPa・s /25˚CP%Halogen%

Flash
Point
˚C-40

69

9.5Cl
32.5

210

Freezing
Point

Containers

250kg
Drum

DescriptionUses

Flame retardant for polyvinylchloride,
rigid polyurethane foam, polyester andepoxy resin.

High hydrolytic stability.
Low volatility.

Products

FormulaSpecifications
SpecificAcid
Gravityvalue
20/20˚C KOH mg/g—

Colorless to lightyellowish clear liquid≦801.330±0.010—

Colorless to lightyellowish clear liquid—

1.326±0.010

Chlorine containing
aliphatic polyphosphate

CR-570Chlorine containing aliphatic
polyphosphate-phosphonate

≦0.30

≦0.10

≦0.10

800 ~
1,100

≦0.10

2,000 ~
6,000

≦-20

Viscosity
mPa・s /25˚CP%

Freezing
Point

2,500 ~
5,500——

˚CP%

Halogen%FlashPoint
˚C-1010.8Cl
23.5236250kg
Drum

High performance for scorch resistance and Flame retardant for various urethane resins
high hydrolytic stability.
such as flexible polyurethane foam, elastomer,Extremely low volatility.
paint and molded article.

12.5

Cl
26.2

214250kg
Drum

Flame retardant for urethane resins such
Fine containing proportion of phosphorus
as flexible and rigid polyurethane foam,and halogen.
elastomer, paint, molded article, as well asHigh performance for flame retarding andunsaturated polyester, epoxy resin and acryl
scorch resistance.
resin.

Containers

Description

Uses

Non-Halogen Phosphoric Acid Polyesters (2)ProductsDAIGUARD-580

ColorAPHA

Colorless toyellowish
brown liquid—

1.235±0.015

≦0.30

—

*Colorlessto lightyellowish
clear liquid≦100

1.125±0.005

≦0.2

≦0.5

150 ~ 350

≧14.8-415.5—

Non-Halogen aliphatic poly
phosphonate phosphate

DAIGUARD-850—

Whitepowder

—

—

—

—

—

≧16.0

258.5

17.1

—

Aliphatic phosphoramidate

—

≦0.20

˚C12≦151

FlashPoint˚CContainers

Description

220kg
Drum

Non-halogen type flame retardant containinghydroxy group with high performance offlame retardancy.

217200kg
Drum

Non-halogen type flame retardant with.
Low viscosity.
High phosphorus content and highperformance of flame retarding.

22210kg
Paper bag

193

Uses

Flame retardant for urethane resins in general,such as flexible polyurethane foam, elastomer,
paint and processed article.

OthersDAIGUARD-880

Typical Properties
Hydroxyl
P
Value%
KOH mg/g

Appearance

Formulamol.weight

Non-Halogen aliphatic poly
phosphate

Specifications
Acid
Water
value
Content
KOH mg/g%

SpecificGravity
20/20˚C

Resin Modifiers

Viscosity
mPa・s /25˚C

Freezing
Point

Metal Extractants

Color
APHACR-504L

Appearance

Typical Properties
WaterContent%

Flame RetardantsHalogen Containing Phosphoric Acid Polyesters

Plasticizers
and Solvents

Appearance

SpecificGravity
20/20˚C

mol.weight

TMCPP《（Non-halogen flame retardant that contains
Flame retardant for backside coating ofphosphorous and nitrogen atoms. Solid atpolyester fiber, synthetic leather and foamed
room temperature. High boiling point and low
urethane.
solubility in water and organic solvents.

*DAIGUARD-880 might be crystallized below 10 ˚C.

1314