ProgramNovember 20 (Mon)
Room A

16:00-16:45 Opening Ceremony
Chair: Satoshi Minakata						Opening Remarks/Addresses
16:45-17:00 IKCOC Prize Ceremony			Prize Winner: Stuart L. Schreiber
Presenter: Masahiko Yoshida			
17:00-18:00 OL									Opening Lecture (IKCOC Prize Lecture)
Stuart L. Schreiber
The Rise of Molecular Glues and Bifunctional Compounds
Chair: Koichi Fukase

18:00-20:00		
Reception (Rooms B and C)

November 21 (Tue)Room A

9:00-10:00		 PL-1 Stephen L. Buchwald			
Pd and Cu Catalysts for C–Heteroatom Bond Formation
Chair: Tamejiro Hiyama						–Coffee Break–10:30-11:10 IL-01 Ilan Marek			
Stereoselective SN1 at Non-Classical Carbocation
Chair: Hajime Ito			
11:10-11:50 IL-02 Laurel L. Schafer			Green Chemistry with Early Transition Metal Complexes. The Catalytic			
Addition of Amines to Alkenes in Small Molecules and Materials
Chair: Norbert Krause			
11:50-12:30 IL-03 Masahiro Terada			
Enantioselective Catalysis by Higher Order Organosuperbase
Chair: Toshiaki Murai						–Lunch–5

14:00-14:40 IL-04 Matthew S. Sigman			
Data Science Tools for Organic Reaction Development
Chair: Seijiro Matsubara			
14:40-15:20 IL-05 François P. Gabbaï			Sensing and Transporting Anions with Organo-Main-Group Lewis Acids
Chair: Shigehiro Yamaguchi			
15:20-16:00 IL-06 Jonathan R. Nitschke			
Organic Molecules in Metal Boxes
Chair: Shuhei Furukawa			
16:00-16:40 IL-07 Kenichiro Itami			
Molecular Nanocarbon Synthesis and Beyond
Chair: Takashi Kubo			

Room B

Chair: Aiko Fukazawa			
10:30-10:45 OP-01 Yumi Yakiyama, Hidehiro Sakurai
Bowl and Butterfly-like Shape Effects on the Formation and the Property of			
Molecular Crystalline Materials
10:45-11:00 OP-02 Takumi Nakazato, Haruka Takekoshi, Takahiro Sakurai,			Hiroshi Shinokubo, Yoshihiro MiyakeN–Coordination and Methylation of 2,7-Diazapyrenes			
11:00-11:15 OP-03 Tsuyoshi Nishikawa, Makoto Ouchi			Chain-Growth Polymerization of Vinylboronic Acid Derivatives:			
Boron as a Replaceable Side Chain for Overcoming the Limitation			in Polymer Synthesis
11:15-11:30 OP-04 Fumitaka Ishiwari
Efficient Synthesis and Gas Absorption/Separation Properties of			Diazacyclooctane-Containing Ladder Polymers
Chair: Akihiro Orita			
11:30-11:45 OP-05 Daiki Shimizu, Hikaru Sotome, Hiroshi Miyasaka, Kenji Matsuda			
Optically Distinguishable Electronic Spin Isomers Based on a Stable			Organic Diradical11:45-12:00 OP-06 Tomohiko Nishiuchi			Mechano-stimuli-responsive Biradical Composed of Anthracene-Basedπ-Cluster
12:00-12:15 OP-07 Yosuke Tani, Kiyoshi Miyata, Erika Ou, Yuya Oshima, Mao Komura,			Morihisa Terasaki, Shuji Kimura, Takumi Ehara, Koki Kubo,			Ken Onda, Takuji Ogawa
Organic 1,2-Diketones for Fast, Efficient, Narrowband Organic			
Room-Temperature Phosphorescence in Solution
6

12:15-12:30 OP-08 Masayuki Gon, Kazuo Tanaka
Synthesis and Evaluation of π-Conjugated Systems Based on			
Hypervalent Compounds			–Lunch–

Chair: Hiroki Oguri			
14:00-14:15 OP-09 Hirofumi Ueda, Kosuke Okada, Ken-ichi Ojima, Hidetoshi Tokuyama			
Total Syntheses of (+)-Pleiocarpamine, (+)-Voacalgine A, and			(+)-Bipleiophylline
14:15-14:30 OP-10 Chihiro Tsukano, Hidetaka Kuroiwa, Soichiro Suzuki, Kazuhiro Irie			
Total Synthesis and Structure Revision of (+)-Lancilactone C
14:30-14:45 OP-11 Dawen Niu			
Radical Pathway Glycosylation
14:45-15:00 OP-12 Takanori Matsumaru, Kana Okubo, Kasumi Sakuratani,			Kodai Sueyoshi, Shusuke Fujii, Juri Takayama, Sho Yamasaki,			Yukari Fujimoto			
Glycolipid Ligands of C-Type Lection Receptor Mincle; Synthesis and			Biological Functions
15:00-15:15 OP-13 Atsushi Shimoyama, Haruki Yamaura, Koichi Fukase			
Synthesis and Functions of Acetic Acid Bacteria Acetobacter pasteurianus			
Lipid A
Chair: Fumitoshi Kakiuchi			
15:15-15:30 OP-14 Akira Yada			
Machine Learning Approach for Predicting Catalytic Activity Accounting			
for Reaction Time
15:30-15:45 OP-15 Gavin Chit Tsui			
Stereoselective Palladium-Catalyzed C–F Bond Activation ofgem-Difluoroalkenes for Multifarious C–C and C–Heteroatom						Bond Construction
15:45-16:00 OP-16 Koji Kubota, Tamae Seo, Hajime Ito			Development of High-Performance Phosphine Ligands for			
Mechanochemical Suzuki-Miyaura Cross-Coupling Reactions
16:00-16:15 OP-17 Yasushi Nishihara			
Nickel or Palladium-Catalyzed Decarbonylative Transformations of			Acyl Halides
16:15-16:30 OP-18 Hayato Tsurugi, Kohei Nishi, Kazushi Mashima			
Low-Valent Chromium-Catalyzed Ring-opening Arylation of			
7-Oxabenzonorbornadiene Derivatives with Aryl Grignard Reagents7

16:40-18:40		
Poster Session A (Room C, Room D and Room E)				
PA(C)-01–PA(C)-84 (Room C)				
PA(D)-01–PA(D)-46 (Room D)				PA(E)-01–PA(E)-57 (Room E)
November 22 (Wed)Room A

9:00-10:00		 PL-2 E.W. “Bert” Meijer			Non-Covalent Synthesis of Supramolecular Systems and Materials
Chair: Takuzo Aida						–Coffee Break–

10:30-11:10 IL-08 Stefan Hecht			Illuminating Materials, Devices, and Manufacturing with Photoswitches
Chair: Kenji Matsuda			
11:10-11:50 IL-09 Yan Xia			
May the Force Be With the Molecules: Designing Force-Induced Molecular			
Reactivities and Adaptive Materials
Chair: Makoto Ouchi			
11:50-12:30 IL-10 Tanja Weil			Synthesis of Peptide Nanostructures in Living SystemsChair: Keiji Numata						–Lunch–

14:00-14:40 IL-11 Thomas R. Ward
Artificial Metalloenzymes for in vivo Catalysis: Challenges and			Opportunities
Chair: Takashi Hayashi			
14:40-15:20 IL-12 Richmond Sarpong			Break-it-to-Make-it Strategies for Chemical Synthesis Inspired by Complex			
Natural Products
Chair: Satoshi Yokoshima			
15:20-16:00 IL-13 John L. Wood			
Recent Progress in the Total Synthesis of Natural Products
Chair: Hidetoshi Tokuyama			

8Chair: Richmond Sarpong			
16:00-16:15 OP-35 Tohru Oishi, Yuma Wakamiya, Yusuke Mita, Yuki Yamashita,			
Yoko Yasuno			Total Synthesis and Structure-Activity Relationship Study of Amphidinol 3
16:15-16:30 OP-36 Toshiaki Wayama, Gavin Tay, Soushi Nishimura, Hiroki Oguri			
Biogenetically Inspired Syntheses of Alkaloidal Scaffolds through			
Activation of Dihydropyridines

Room B

Chair: Naohiko Yoshikai			
10:30-10:45 OP-19 Kei Muto, Yota Uwabe, Junichiro Yamaguchi			Catalytic Dearomative Azaspirocyclization of Bromoarenes with
N-Tosylhydrazones and Synthesis of Cephalotaxus Alkaloids			
10:45-11:00 OP-20 Sobi Asako, Yushu Jin, Boobalan Ramadoss, Laurean Ilies			Spirobipyridine Enables Remote Steric Control and Rate Acceleration			in Iridium-Catalyzed Aromatic C–H Borylation
11:00-11:15 OP-21 Tsuyoshi Mita, Yong You, Wataru Kanna, Hideaki Takano,			Hiroki Hayashi, Satoshi Maeda			
Electrochemical Dearomative Carboxylation of (Hetero)aromatics with CO2
11:15-11:30 OP-22 Hiroshi Naka, Moeko Itoga, Masako Yamanishi, Taro Udagawa,			Ayane Kobayashi, Keiko Maekawa, Yoshiji Takemoto
Iridium-Catalyzed α-Selective Hydrogen−Deuterium Isotope Exchange of			Alcohols
Chair: Gavin Chit Tsui			
11:30-11:45 OP-23 Takanori Iwasaki, Kazuki Tsuge, Naoki Naito, Kyoko Nozaki			Chemoselectivity Change in Catalytic Hydrogenolysis: Ureas to			Formamides and Amines
11:45-12:00 OP-24 Zhongxing Huang			
Access Molecular Complexity by Breaking Symmetry of Dicarbonyl			Compounds
12:00-12:15 OP-25 Masamichi Ogasawara			
Enantioselective Synthesis of Planar-Chiral Ferrocene Derivatives by			
Asymmetric Metathesis Dimerization of Vinylferrocenes
12:15-12:30 OP-26 Toshimichi Ohmura, Kaito Yagi, Satoshi Kusaka, Yunhao Song,			
Michinori Suginome			Iridium-Catalyzed Dehydrogenative Cyclization: Use of Simple Alkyl			Groups in Construction of N- and O-Heterocycles			–Lunch–9Chair: Yasushi Nishihara			
14:00-14:15 OP-27 Chisaki Arakawa, Kazuya Kanemoto, Katsuya Nakai, Chen Wang,			Shunya Morohashi, Eunsang Kwon, Shingo Ito, Naohiko Yoshikai			Carboiodanation of Arynes: Organoiodine(III) Compounds as Nucleophilic			
Organometalloids
14:15-14:30 OP-28 Kensuke Kiyokawa, Daichi Okumatsu, Manabu Abe, Satoshi Minakata			Photo-Induced Radical Carboamination of Styrenes with Carboxylic Acids			
and (Diarylmethylene)aminobenziodoxolones
14:30-14:45 OP-29 Sena Toyofuku, Gen Onodera, Tsutomu Fukuda, Masanari Kimura			
Stereoselective Synthetic Method Using Cu-Catalyzed Coupling Reaction			of Alkynylborates and Aldehydes
14:45-15:00 OP-30 Fumitoshi Shibahara, Mayu Suganuma, Takuya Sonoda			
Imidazo[1,5-a]pyridylidene Ligands for π-Acidic Catalyst
15:00-15:15 OP-31 Zhi-Bin Li, Chia-Chi Lin, Yu-Chieh Chen, Chin-Chau Chen,			
Xin-Cheng Li, Ming-Jung Wu			
Electronic Effects on the Cyclization Reactions of Arene-1,2-diynes
Chair: Ken Kamikawa			
15:15-15:30 OP-32 Itaru Nakamura, Hiroki Tashiro, Keiryo Kubota, Masahiro Teradaπ-Lewis Acidic Metal-Catalyzed Reactions via N-S bond Cleavage
15:30-15:45 OP-33 Nobukazu Taniguchi, Kenji Kitayama			Zinc-Catalyzed Regioselective Hydrothiolation of Alkenes by Using Thiols
15:45-16:00 OP-34 Yoshihiro Sohtome, Mikiko Sodeoka			Dynamics in Ni(II)-Catalyzed Diastereoconvergent (3 + 2) Cycloaddition ofα-Ketoester Enolates with C-CN Nitrones
16:00-16:15 OP-37 Jen-Chieh Hsieh			
Denitrogenative Transannulation Reactions of 1,2,3,4-Benzothiatriazin			
1,1(2H)-dioxides with Arynes to Synthesize Biaryl Sultams
16:15-16:30 OP-38 Masato Ohashi, Kota Ando, Shoichi Murakami, Kenichi Michigami,			Sensuke Ogoshi
N-Heterocyclic Carbenes with Polyfluorinated Groups at the 4- and						5-Positions from [3 + 2] Cycloadditions between Formamidinates andcis-1,2-Difluoroalkene Derivatives			
16:40-18:40		
Poster Session B (Room C, Room D and Room E)				
PB(C)-01–PB(C)-85 (Room C)				
PB(D)-01–PB(D)-46 (Room D)				
PB(E)-01–PB(E)-53 (Room E)

10

November 23 (Thu)
Room A

9:00-9:40		 IL-14 Paolo Melchiorre			
Photochemistry & Organocatalysis: New Radical Opportunities
Chair: Takashi Ooi			
9:40-10:20		 IL-15 Thorsten Bach			Catalytic Photochemical Deracemization Reactions
Chair: Masahiro Terada			
Chair: Mamoru Tobisu			
10:20-10:35 OP-45 Naoki Ishida, Tairin Kawasaki, Masahiro Murakami			
Dehydrogenative Coupling of Alkylamines with Primary Alcohols Forming
α-Amino Ketones with Liberation of H2
10:35-10:50 OP-46 Kai Chen, Yunzhi Lin, Wenqiang Wu, Hang Shi
Transition-Metal-Catalyzed Arene Functionalization via π-Coordination
10:50-11:05 OP-47 Junqiang Wei, Ivan Keng Wee On, Mingfeng Li, Ye Zhu			Ionic Ligand-Substrate Interactions Enable Electrostatic Catalysis: Long			Range Stereocontrol in Palladium-Catalyzed Cross-Coupling Reactions
11:05-11:20 OP-48 Shunsuke Onodera, Soya Ishikawa, Ryo Togashi, Ryosuke Ueda,			Takuya Kochi, Fumitoshi Kakiuchi			Chelation-Assisted Rhodium-Catalyzed Alkenylation and Alkylation of			Allylbenzene and Styrene Derivatives via C–C Bond Cleavage
11:20-11:35 OP-49 Timothée Cadart, Martin Kotora
Synthesis of [5], [7], and [9]Helical Indenofluorenes: Asymmetric Induction,			Applications, and Mechanistic Aspects
11:35-11:50 OP-50 Ken Kamikawa, AyakaYubuta, Shun Nakayama, Akihiro Tsurusaki			
Asymmetric Synthesis of Non-Central Chiral Molecules Using Aryne			Intermediates			–Lunch–

13:10-13:50 IL-16 Zhen Xi			Genome Therapy: A New Approach for Tumor Growth Inhibition
Chair: Hiroshi Sugiyama			
13:50-14:30 IL-17 Shang-Cheng Hung			“One-pot Strategies” for Synthesis of Carbohydrates and their			
Bioevaluations
Chair: Yukari Fujimoto			11			–Coffee Break–

15:00-16:00 PL-3 Mikiko Sodeoka
Development of Chemical Methods for Imaging and Target Identification
Chair: Itaru Hamachi			
16:00-16:15		

Closing Remarks

Room B

Chair: Hiroshi Shinokubo			
9:00-9:15		 OP-39 Rui Shang, Eiichi Nakamura			
Iron-Catalyzed New Reactions and Their Application for Electronic			Materials
9:15-9:30		 OP-40 Masahito Murai
Alignment of Azulene-Based Cationic π-Skeletons toward Functionalπ-Materials
9:30-9:45		 OP-41 Marie-Aude Hiebel			Mild and Versatile Synthesis of Polynitrogen Containing Tricyclic 6-5-5 and			
6-5-6 Derivatives and their Fluorescent Properties
Chair: Tadashi Ema			
9:45-10:00		 OP-42 Akiko Yagi, Takaku Yoshihara, Yoshifumi Toyama, Miyuka Ogawa,			
Hiroki Shudo, Hideto Ito, Kenichiro Itami			
Adamantane-Annulation to Arenes: A Strategy for Property Modulation ofAromatic π-Systems
10:00-10:15 OP-43 Akihiro Shimizu, Shinobu Arikawa, Daisuke Shiomi, Kazunobu Sato,			Takeji Takui, Hikaru Sotome, Hiroshi Miyasaka, Masahito Murai,			Shigehiro Yamaguchi, Ryo Shintani			Near-Infrared Fluorescent Hydrocarbon-Based Triplet Diradical Cation
10:15-10:30 OP-44 Amit K. Jaiswal, Priya Saha, Kimichi Suzuki, Anna Jasny,			Bernd M. Schmidt, Satoshi Maeda, Stefan Hecht,			Dennis Chung-Yang Huang			Construction of Functionalized Red-Light Photoswitches by Selective			
Copper-Catalyzed Indigo N-ArylationChair: Tomonori Tamura			
10:30-10:45 OP-51 Jie Sheng, Kelly Koh Kar Yun, Zhaoyang Li, Qi Shi, Ruyi Zhu			Towards Enzyme-Like DNA Catalysts for Asymmetric Catalysis
10:45-11:00 OP-52 Kazuya Kanemoto, Haruka Machida, Naohiko Yoshikai			Cu-Catalyzed [3+2] Cycloaddition for the N-Terminal-Specific Modification			of Peptides

1211:00-11:15 OP-53 Anuchit Phanumartwiwath, Chatchai Kesornpun,			Daranee Chokchaichamnankit, Amnart Khongmanee,			Penchatr Diskul-Na-Ayudthaya, Theetat Ruangjaroon,			Chantragan Srisomsap, Prasat Kittakoop, Jisnuson Svasti,			Somsak Ruchirawat			
Nitrile Oxide Chemistry Cycloaddition Approach for Protein Bioconjugation			and Apoptotic Detection
11:15-11:30 OP-54 Koji Miki, Masahiro Oe, Kanae Suzuki, Huiying Mu, Kouichi Ohe
Turn-on Fluorescent Probes for Cancer Stem Cell-Specific Visualization
11:30-11:45 OP-55 Kazuma Amaike, Erika Kato, Miu Fukatsu, Dominik Zetschok,			Luca Hagemeyer, Atsushi Usami, Hayato Yamada, Kenichiro Itami			
Nucleic Acid Delivery Using Cationic Polycyclic Aromatic Hydrocarbons			–Lunch–

Chair: Masamichi Ogasawara			
13:15-13:30 OP-56 Mario Waser			Chiral Isothio(seleno)urea-Catalyzed Activation of Allenoates
13:30-13:45 OP-57 Seiji Shirakawa, Ryuichi Nishiyori, Taiki Mori			Asymmetric CO2 Utilization Reaction via Chiral Bifunctional			
Chalcogenide-Catalyzed Bromocyclizations
13:45-14:00 OP-58 Muhammet Uyanik, Takehiro Kato, Naoto Sahara, Sho Akagawa,			Kazuaki Ishihara			
Oxidative Dearomative Coupling of Low-Reactive Arenols Using			Hypohalite Catalysis
14:00-14:15 OP-59 Franz-Lucas Haut, Riccardo S. Mega, Joan V. Estornell, Ruben Martín
Sulfinate-Catalyzed, Intramolecular C(sp3)–C(sp3) Fragment Coupling via			
CO2-Extrusion
14:15-14:30 OP-60 Akira Matsumoto, Natsumi Maeda, and Keiji Maruoka			
Modular Synthesis of 1,4-Dicarbonyl Compounds via Sequential			
Photocatalysis Using Ambiphilic Radical Linchpin			–Coffee Break–

18:30-20:30		

Banquet (Room A)

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