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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 12

Revision: 12.04.2017

SECTION 1: Identification of the substance/mixture and of the company/undertaking· 1.1 Product identifier· Trade name: KEIM CONCRETAL-FIXATIV· 1.2 Relevant identified uses of the substance or mixture and uses advised against· Application of the substance / the mixture Sol-Silicate-based ready-to-use diluent or primer· Uses advised against All other uses are not recommended.
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
KEIMFARBEN GMBH
Keimstraße 16 / 86420 Diedorf
Tel. +49 (0)821 4802-0
Fax +49 (0)821 4802-210
www.keim.com / info@keimfarben.de· Further information obtainable from:
Product safety department
Telefon: 49(0)821/4802-138
E-Mail: sdb.info@keimfarben.de· 1.4 Emergency telephone number:
GBK GmbH Global Regulatory Compliance
Emergency number: +49(0)6132/84463

SECTION 2: Hazards identification· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· 2.3 Other hazards Alkaline product. Avoid contact with skin and eyes.
· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients· 3.2 Mixtures· Description: Liquid solution from silicic acid potassium salt, silica sol and organic additives· Dangerous components: VoidDEN(Contd. on page 2)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 12

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-FIXATIV(Contd. of page 1)

SECTION 4: First aid measures· 4.1 Description of first aid measures· General information:
No special measures required.
When seeing the doctor we suggest to present this safety data sheet.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Do not use solvents or thinners.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse mouth and throat well with water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures· 5.1 Extinguishing media· Suitable extinguishing agents:
Product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
· 5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:carbon oxide (COx)acrylic monomers· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
In case of fire do not breathe smoke, fumes and vapours.

SECTION 6: Accidental release measures· 6.1 Personal precautions, protective equipment and emergency procedures
Respect the protection rules (see section 7 a. 8).
Avoid contact with skin and eyes.
Ensure adequate ventilation· 6.2 Environmental precautions:
Do not allow product to reach soil, sewage system or any water course.
Follow local governmental rules and regulations.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 12

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-FIXATIV(Contd. of page 2)· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of the material collected according to regulations.
Clear contaminated areas thoroughly.
Flush rests with sufficient amount of water.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage· 7.1 Precautions for safe handling
Keep receptacles tightly sealed.
Avoid contact with skin and eyes.
Do not inhale aerosols.
See item 8 for information about suitable protective equipment and technical precautions. Respect
the protection rules.
· Information about fire - and explosion protection:
The product is not flammable.
No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Keep in the original containers in a cool and dry place.
Store only in unopened original receptacles.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:Protect from frost.
Store in a cool place.
Protect from heat and direct sunlight.
· Storage class: 12· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Avoid contact with the eyes and skin.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 12

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-FIXATIV(Contd. of page 3)

Do not inhale aerosols.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.
Filter: P· Protection of hands: Protective gloves· Material of gloves
suitable material e.g.:
Nitrile impregnated cotton-gloves
Natural rubber, NR
Recommended thickness of the material:  0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
Value for the permeation: Level  6 (480 min)The determined penetration times according to EN 374 part III are not performed under practicalconditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,is recommended.
The exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.
· Eye protection: Goggles recommended during refilling· Body protection:
Protective work clothing
Light weight protective clothing· Limitation and supervision of exposure into the environment See Section 12 and 6.2*SECTION 9: Physical and chemical properties· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form:
FluidColour:
milky· Odour:
Weak, characteristic· Odour threshold:Not determined.
· pH-value at 20 °C:~11*· Change in condition
Melting point/freezing point:~ 0 °C
Initial boiling point and boiling range: ~100 °C· Flash point:

Not applicable.

· Flammability (solid, gas):

Not applicable.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 12

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-FIXATIV(Contd. of page 4)· Ignition temperature:

Not determined.

· Decomposition temperature:

Not determined.

· Auto-ignition temperature:

Product is not selfigniting.

· Explosive properties:

Product does not present an explosion hazard.

· Explosion limits:
Lower:
Upper:· Oxidising properties

Not applicable.
Not applicable.
Not applicable.

· Vapour pressure at 20 °C:~23 hPa· Density at 20 °C:· Relative density· Vapour density· Evaporation rate

1.0-1.1* g/cm³
Not determined.
Not applicable.
Not applicable.

· Solubility in / Miscibility withwater:

miscible· Partition coefficient: n-octanol/water:

Not applicable.

· Viscosity:
Dynamic:
Kinematic:· 9.2 Other information

Not determined.
Not determined.
* The values are for freshly produced material and maychange with the time.

SECTION 10: Stability and reactivity· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions of storage and use.
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Acids· 10.6 Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed.

SECTION 11: Toxicological information· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:· Skin corrosion/irritation Frequent persistent contact with the skin may cause skin irritation.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 12

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-FIXATIV(Contd. of page 5)· Serious eye damage/irritation In case of longer exposure, slightly irritating effect is possible.
· during inhalation: Irritant effect possible.
· during swallowing: Irritant effect possible· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Other information (about experimental toxicology):Experimental analysis are not available.
The product was not tested. The statements on toxicology have been derived from the properties of
the individual components.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) not applicable· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information· 12.1 Toxicity· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· AOX-indication:
Due to the substance of content which do not include organic jointed halogens, the product can nottake influence on the AOX-load of the waste water.
· According to the formulation contains the following heavy metals and compounds from theEU guideline NO. 2006/11/EC:
According to our current data base the product does not consist of any heavy metals or substancesof EU-directives 76/464/EWG.
· General notes:
Do not allow product to reach ground water, water course or sewage system.
At present there are no ecotoxicological assessments.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations· 13.1 Waste treatment methods· Recommendation
Must not be disposed with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017Version number 12

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-FIXATIV(Contd. of page 6)

Disposal must be made according to official regulations.
· European waste catalogue
06 02 99 wastes not otherwise specified· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary with cleansing agents.

SECTION 14: Transport information· 14.1 UN-Number· ADR, IMDG, IATA

Void· 14.2 UN proper shipping name
· ADR, IMDG, IATA

Void· 14.3 Transport hazard class(es)· ADR, IMDG, IATA
· Class

Void· 14.4 Packing group· ADR, IMDG, IATA

Void· 14.5 Environmental hazards:· Marine pollutant:

No· 14.6 Special precautions for user

Not applicable.

· 14.7 Transport in bulk according to Annex IIof Marpol and the IBC CodeNot applicable.

*· Transport/Additional information:

No dangerous good in sense of these transport
regulations.

· UN "Model Regulation":

VoidSECTION 15: Regulatory information· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· National regulations:· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Other regulations, limitations and prohibitive regulations· Substances of very high concern (SVHC) according to REACH, Article 57 not applicable(Contd. on page 8)DEN

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.04.2017

Version number 12

Revision: 12.04.2017

Trade name: KEIM CONCRETAL-FIXATIV(Contd. of page 7)· Product-Code/Giscode: BSW10· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
*SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Department issuing SDS: KEIMFARBEN Germany, Product safety department· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Dangerous Substances, BAuA, Germany)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
AGW: Arbeitsplatzgrenzwert (Germany)
REACH: Registration, Evaluation and Authorisation of Chemicals (Regulation (EC) No.1907/2006)· * Data compared to the previous version altered.
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