SAFETY DATA SHEET

1. Identification
Product identifier

Perkins ELC(Extended Life Coolant) Premix 50/50 with Embitterment

Other means of identification
Product code

1002881

Recommended use

Antifreeze / Coolant.

Recommended restrictions

Uses other than the recommended use.

Manufacturer/Importer/Supplier/Distributor information
Supplier

ARTECO NV
Metropoolstraat 25
B-2900 Schoten (Antwerpen)
Belgiume-mail
Product Information

orders@arteco-coolants.com+32 (0) 9 397 06 00

1.4. Emergency telephone
numberTransportation Emergency
Health Emergency

Europe: +44 20 35147487 (24hr) Access code: 335087
Europe: +44 20 35147487 (24hr) Access code: 335087

2. Hazard(s) identification
Physical hazards

Not classified.

Health hazards

Reproductive toxicity (the unborn child)

Category 1BSpecific target organ toxicity, repeatedexposure

Category 2 (kidney)

OSHA defined hazards

Not classified.

Label elements

Signal word

DangerHazard statement

May damage the unborn child. May cause damage to organs (kidney) through prolonged orrepeated exposure.

Precautionary statement
Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Do not breathe mist/vapors. Wear protective gloves/protective clothing/eye
protection/face protection.

ResponseIf swallowed: Immediately call a poison center/doctor. If exposed or concerned: Get medical
advice/attention.

Storage

Store locked up.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwiseclassified (HNOC)

None known.

Supplemental information

None.

3. Composition/information on ingredients
Mixtures
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Chemical nameCAS number%

Ethylene glycol

107-21-1

34 - < 80

Sodium 2-ethylhexanoate

19766-89-3

0.1 - < 3

Methyl-1H-benzotriazole

29385-43-1

0.1 - < 1Composition comments

All concentrations are in percent by weight.
The specific chemical identity and/or exact percentage of component(s) have been withheld as atrade secret.
This product contains a bittering agent.

4. First-aid measures
Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contactWash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact

Rinse with water. Remove contact lenses, if present and easy to do. Get medical attention if
irritation develops and persists.
Rinse mouth. Get medical attention if symptoms occur.

Ingestion
Most important
symptoms/effects, acute anddelayedConvulsions. Dizziness. Nausea, vomiting. Abdominal pain. Edema. Prolonged exposure may
cause chronic effects.

Indication of immediate
medical attention and special
treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.

General information

IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice(show the label where possible). Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. Show this safety data sheet to the doctor inattendance.

5. Fire-fighting measures
Suitable extinguishing media

Alcohol resistant foam. Powder. Carbon dioxide (CO2).

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising fromthe chemical

Thermal decomposition may produce smoke, oxides of carbon and lower molecular weight organic
compounds whose composition have not been characterized.

Special protective equipment
and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting
equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

No unusual fire or explosion hazards noted.

6. Accidental release measures
Personal precautions,protective equipment andemergency procedures
Methods and materials forcontainment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Do not breathe mist/vapors.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot becontained. For personal protection, see section 8 of the SDS.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Absorb in vermiculite, dry sand or earth and place into containers. Following productrecovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground.

7. Handling and storage
Precautions for safe handling

Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Do not breathe mist/vapors. Avoid prolonged exposure. Should be handled inclosed systems, if possible. Provide adequate ventilation. Wear appropriate personal protectiveequipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.

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Conditions for safe storage,including any incompatibilities

Store locked up. Store in tightly closed container. Store away from incompatible materials (seeSection 10 of the SDS).

8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit Values (TLV)
Components
Ethylene glycol (CAS107-21-1)

TypeValue

Form

STEL

10 mg/m3

Aerosol, inhalable.

50 ppmVapor fraction

25 ppmVapor fraction

TWA
Biological limit valuesNo biological exposure limits noted for the ingredient(s).

Appropriate engineering
controls

Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment
Chemical respirator with organic vapor cartridge and full facepiece.
Eye/face protection
Skin protection
Hand protection

Wear appropriate chemical resistant gloves. Neoprene, butyl rubber, nitrile or Viton gloves arerecommended. Full contact: Use gloves classified protection index 6 with breakthrough time of 480
minutes. Minimum glove thickness 0.38 mm.

Skin protection
Other

Wash hands thoroughly after handling. Use of an impervious apron is recommended.

Respiratory protection

Chemical respirator with organic vapor cartridge and full facepiece.

Thermal hazards

Wear appropriate thermal protective clothing, when necessary.

General hygiene
considerations

Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties
Appearance
Physical state

Liquid.

Form

Clear liquid.

Color

Red.

Odor

Mild.

Odor threshold

Not determined.

pH

8.25 - 8.60 (20°C)

Melting point/freezing point

Not determined. / -32.8 °F (-36 °C)

Initial boiling point and boilingrange

228.2 °F (109 °C) (Estimated)Flash point

Does not flash.

Evaporation rate

Not determined.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits
Not determined.
Explosive limit - lower (%)
Explosive limit - upper (%)

Not determined.

Vapor pressure

Not determined.

Vapor density

Not determined.

Relative density

Not determined.

Solubility(ies)
Solubility (water)

Miscible.

Partition coefficient(n-octanol/water)

Not applicable, product is a mixture.

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Auto-ignition temperature

748.4 °F (398 °C) (Ethylene glycol)

Decomposition temperature

Not determined.

Viscosity

Not determined.

Other information
Density

1.070 kg/l (20 °C) (Typical)

Kinematic viscosity

Not determined.

10. Stability and reactivity
Reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability

Material is stable under normal conditions.

Possibility of hazardous
reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid

Contact with incompatible materials.

Incompatible materials

Strong acids. Strong oxidizing agents. Nitrates. Peroxides. Chlorates.

Hazardous decomposition
products

At elevated temperatures: Ketones. Aldehydes.

11. Toxicological information
Information on likely routes of exposure
In high concentrations, mists/vapors may irritate throat and respiratory system and cause
Inhalation
coughing.
Skin contact

Prolonged or repeated contact may dry skin and cause irritation.

Eye contact

Direct contact with eyes may cause temporary irritation.

Ingestion

Ingestion of ethylene glycol may result in nausea, vomiting, abdominal cramps, blindness, liverdamage, irritation, reproductive effects, nerve damage, convulsions, edema of the lung,cardiopulmonary effects (metabolic acidosis), pneumonia and kidney failure which could result indeath. The single lethal dose for humans is about 100 ml. Inhalation of high levels of vapors or
mists for prolonged periods of time may also result in toxic effects.

Symptoms related to thephysical, chemical andtoxicological characteristics

Convulsions. Dizziness. Nausea, vomiting. Abdominal pain. Edema. Prolonged exposure may
cause chronic effects.

Information on toxicological effects
Acute toxicity
Product

Species

Test Results

Perkins ELC(Extended Life Coolant) Premix 50/50 with Embitterment (CAS -)Acute
Dermal
ATEmix1618000 mg/kg bw

Oral
ATEmix3176 mg/kg bw

Components

Species

Test Results

DermalLD50

Mouse> 3500 mg/kg

Inhalation
Aerosol
LC50

Rat> 2.5 mg/l, 6 Hours

Oral
LD50

Cat

1600 mg/kg

Ethylene glycol (CAS 107-21-1)
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ComponentsSpecies

Test Results

Methyl-1H-benzotriazole (CAS 29385-43-1)
Acute
DermalLD50

Rabbit> 2000 mg/kg, 24 Hours

Oral
LD50

Rat

720 mg/kg

Sodium 2-ethylhexanoate (CAS 19766-89-3)
Acute
Dermal
LD50

Rat> 2000 mg/kg, 24 Hours

Oral
LD50

Rat

2043 mg/kg

Skin corrosion/irritation

Prolonged skin contact may cause temporary irritation.

Serious eye damage/eyeirritation

Direct contact with eyes may cause temporary irritation.

Respiratory or skin sensitization
Not a respiratory sensitizer.
Respiratory sensitization
This product is not expected to cause skin sensitization.

Skin sensitization
Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Carcinogenicity

Not classifiable as to carcinogenicity to humans.

IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
May damage the unborn child.
Reproductive toxicity
Reproductivity
Methyl-1H-benzotriazole (CAS 29385-43-1)

30 mg/kg bw/day OECD 414
Result: LOAELSpecies: Rat

Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

May cause damage to organs (kidney) through prolonged or repeated exposure.

Aspiration hazard

Not an aspiration hazard.

Further information

No data available.

12. Ecological information
Ecotoxicity

The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.

Components

Species

Test Results> 100 mg/l, 48 Hours

Ethylene glycol (CAS 107-21-1)
Aquatic
Crustacea

EC50Daphnia magna

Acute
Fish

LC50

Fathead minnow (Pimephales promelas) 72860 mg/l, 96 hours

Methyl-1H-benzotriazole (CAS 29385-43-1)
Aquatic
AcuteAlgae

ECr50

Pseudokirchneriella subcapitata

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Components
Crustacea

EC50Species

Test Results

Daphnia galeata8.58 mg/l, 48 hours

LC50

Arcartia tonsa

55 mg/l, 48 hours

FishLC50

Danio rerio

180 mg/l, 72 hours

ChronicCrustacea

EC10

Daphnia galeata

0.4 mg/l, 21 days

Persistence and degradability

Ethylene glycol: >90% / 10 days (OECD 301A) Readily biodegradable.

Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Ethylene glycol (CAS 107-21-1)-1.36This product is miscible in water and may not disperse in soil.
Mobility in soil
Other adverse effects

No data available.

13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose ofcontents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).
Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.

14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Not established.
Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC Code

15. Regulatory information
US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Ethylene glycol (CAS 107-21-1)
Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Toxic Substances Control Act (TSCA)

One or more components of the mixture are not on the TSCA 8(b) inventory
or are designated “inactive”.

Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substanceNot listed.
SARA 311/312 Hazardous
chemicalClassified hazard
categories

Yes
Reproductive toxicity
Specific target organ toxicity (single or repeated exposure)

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SARA 313 (TRI reporting)Chemical name

CAS number% by wt.

Ethylene glycol

107-21-1

34 - < 80

Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Ethylene glycol (CAS 107-21-1)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Contains component(s) regulated under the Safe Drinking Water Act.
Safe Drinking Water Act(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Ethylene glycol (CAS 107-21-1)
US. New Jersey Worker and Community Right-to-Know Act
Ethylene glycol (CAS 107-21-1)
US. Pennsylvania Worker and Community Right-to-Know Law
Ethylene glycol (CAS 107-21-1)
US. Rhode Island RTK
Ethylene glycol (CAS 107-21-1)
California Proposition 65
WARNING: This product can expose you to Ethylene glycol, which is known to the State of California to cause
birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
California Proposition 65 - CRT: Listed date/Developmental toxin
Ethylene glycol (CAS 107-21-1)
Listed: June 19, 2015

16. Other information, including date of preparation or last revision
Issue date

25-April-2024

Revision date-Version #01

List of abbreviations

DOT: Department of Transportation.
EC50: Effective Concentration, 50%.
IATA: International Air Transport Association.
IBC Code: International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk.
IMDG: International Maritime Dangerous Goods.
LC50: Lethal Concentration, 50%.
LD50: Lethal Dose, 50%.
MARPOL: International Convention for the Prevention of Pollution from Ships.
STEL: Short term exposure limit.
TWA: Time Weighted Average.
ECHA CHEM

References
Disclaimer

ARTECO NV cannot anticipate all conditions under which this information and its product, or theproducts of other manufacturers in combination with its product, may be used. It is the user’s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and toassume liability for loss, injury, damage or expense due to improper use. The information in thesheet was written based on the best knowledge and experience currently available.

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