Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________SAFETY DATA SHEETSECTION 1

PRODUCT AND COMPANY IDENTIFICATIONPRODUCT
Product Name:PERKINS DIESEL ENGINE OIL 15W-40
Product Description:
Base Oil and Additives
Product Code:
170290-80, 202020400810
Recommended Use:
Engine oil

COMPANY IDENTIFICATION
Supplier:

ExxonMobil (China) Investment Co., Ltd.
17/F., Metro Tower
30 Tian Yao Qiao Road
Shanghai 200030
China

24 Hour Environmental / Health Emergency
Telephone
Supplier General Contact
E-MailFAXSECTION 2(+86) 0532-83889090(+86) 021-24076000
lubricants-sds@exxonmobil.com
400 1200 526

HAZARDS IDENTIFICATIONEMERGENCY OVERVIEW:
Physical State:

LiquidColour:Brown

Odour:

Characteristic

This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15).
High-pressure injection under skin may cause serious damage.
or respiratory irritation.

Excessive exposure may result in eye, skin,This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15).

Page 1 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________

Contains: ORGANO MOLY-SULFUR COMPLEX

May produce an allergic reaction.

Other hazard information:

PHYSICAL / CHEMICAL HAZARDSNo significant hazards.
HEALTH HAZARDS
High-pressure injection under skin may cause serious damage.
eye, skin, or respiratory irritation.

Excessive exposure may result in

ENVIRONMENTAL HAZARDSNo significant hazards.

NOTE:
This material should not be used for any other purpose than the intended use in Section 1 without
expert advice. Health studies have shown that chemical exposure may cause potential human health risks
which may vary from person to person.
SECTION 3

COMPOSITION / INFORMATION ON INGREDIENTSThis material is defined as a mixture.
Hazardous Substance(s) or Complex Substance(s) required for disclosure
Name

CAS#

Concentration*

GHS Hazard Codes

ORGANO MOLY-SULFUR COMPLEXZINC ALKYL DITHIOPHOSPHATECONFIDENTIAL
113706-15-3

0.1 - < 1%
1 - 2.5%

H315, H317, H402, H412
H303, H315, H318, H401,
H411* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent
by volume.
SECTION 4

FIRST AID MEASURESFIRST AID:INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself orothers. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or
unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist
ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any
part of the body, regardless of the appearance of the wound or its size, the individual should be
evaluated immediately by a physician as a surgical emergency. Even though initial symptoms fromPage 2 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________

high pressure injection may be minimal or absent, early surgical treatment within the first few
hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water.

If irritation occurs, get medical assistance.

INGESTIONFirst aid is normally not required. Seek medical attention if discomfort occurs.
IMPORTANT SYMPTOMS AND HEALTH EFFECTS
Local necrosis as evidenced by delayed onset of pain and tissue damage a few hours after injection.
ADVICE TO PROTECT RESCUER
Please refer to Section 8 for personal protection information.
NOTE TO PHYSICIAN
The need to have special means for providing specific and immediate medical treatment available in
the workplace is not expected.

SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media:
extinguish flames.

Use water fog, foam, dry chemical or carbon dioxide (CO2) toInappropriate Extinguishing Media:

Straight streams of water

SPECIAL HAZARD WHEN ON FIRE
In case of fire, see below for hazardous combustion products.
from a fire may rupture.

Containers exposed to excessive heat

FIRE FIGHTING INSTRUCTIONS AND PROTECTIVE MEASURES

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution fromentering streams, sewers or drinking water supply. Fire-fighters should use standard protective
equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray tocool fire exposed surfaces and to protect personnel.
Hazardous Combustion Products:
Smoke, Fume, Sulphur oxides

Aldehydes, Incomplete combustion products, Oxides of carbon,

Page 3 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________FLAMMABILITY PROPERTIES
Flash Point [Method]: >225 C (437 F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air):
LEL:
Autoignition Temperature: N/D

0.9

UEL: 7.0

SECTION 6 ACCIDENTAL RELEASE MEASURESNOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with allapplicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard
Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8
for advice on the minimum requirements for personal protective equipment. Additional protective
measures may be necessary, depending on the specific circumstances and/or the expert judgment of
the emergency responders.
For emergency responders: Respiratory protection: respiratory protection will be necessary only in
special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for
dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the sizeof spill and potential level of exposure. If the exposure cannot be completely characterized or an
oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that areresistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not waterresistant and are not suitable for emergency use. Chemical goggles are recommended if splashes orcontact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate.
Large spills: full body suit of chemical resistant, antistatic material is recommended.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal.
waterways, sewers, basements or confined areas.
SPILL MANAGEMENTLand Spill:absorbent.

Stop leak if you can do so without risk.

Prevent entry into

Recover by pumping or with suitable

Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms.
Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek theadvice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for thismaterial; however, geographic conditions, wind, temperature, (and in the case of a water spill)wave and current direction and speed may greatly influence the appropriate action to be taken. For

Page 4 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________

this reason, local experts should be consulted.
action to be taken.

Note:

Local regulations may prescribe or limit

SECTION 7 HANDLING AND STORAGE
HANDLING
Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material
can accumulate static charges which may cause an electrical spark (ignition source). When thematerial is handled in bulk, an electrical spark could ignite any flammable vapors from liquids orresidues that may be present (e.g., during switch-loading operations). Use proper bonding and/or
earthing procedures. However, bonding and earthing may not eliminate the hazard from static
accumulation. Consult local applicable standards for guidance. Additional references include
American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning
and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static
Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of
hazards due to static electricity).
Static Accumulator:

This material is a static accumulator.

STORAGE
The type of container used to store the material may affect static accumulation and dissipation.
Do not store in open or unlabelled containers.
SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE LIMIT VALUES
Exposure limits/standards (Note: Exposure limits are not additive)
Substance Name
ORGANO MOLY-SULFUR COMPLEXORGANO MOLY-SULFUR COMPLEX

Form
Limit/Standard
10 mg/m3
Inhalabl TWA
efraction.
3 mg/m3
Respirab TWA
lefraction.

Note

Source
ACGIH

Year
2016

ACGIH

2016

Exposure limits/standards for materials that can be formed when handling this product:
When mists /aerosols can occur, the following are recommended: 5 mg/m3 - ACGIH TLV (inhalable fraction).

NOTE: Limits/standards shown for guidance only.

Follow applicable regulations.

Page 5 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________ENGINEERING CONTROLSThe level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as
applications, handling practices, concentration and ventilation. Information on the selection ofprotective equipment for use with this material, as provided below, is based upon intended, normal
usage.
Respiratory Protection:
If engineering controls do not maintain airborne contaminantconcentrations at a level which is adequate to protect worker health, an approved respirator may beappropriate. Respirator selection, use, and maintenance must be in accordance with regulatory
requirements, if applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
Particulate filter when appropriate.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive
pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen
levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter
capacity/rating may be exceeded.
Hand Protection:
Any specific glove information provided is based on published literature andglove manufacturer data. Glove suitability and breakthrough time will differ depending on thespecific use conditions. Contact the glove manufacturer for specific advice on glove selection andbreakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The typesof gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use. Nitrile,Viton
Eye Protection:

If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection:
Any specific clothing information provided is based on publishedliterature or manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordancewith good industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures:
Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing
and protective equipment to remove contaminants. Discard contaminated clothing and footwear thatcannot be cleaned. Practice good housekeeping.

ENVIRONMENTAL CONTROLS

Page 6 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________

Comply with applicable environmental regulations limiting discharge to air, water andsoil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.

SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations
only and may not fully represent product specifications. Contact the Supplier for additional
information.
GENERAL INFORMATION
Physical State:
LiquidColour:Brown
Odour:
Characteristic
Odour Threshold:
N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 60 F):
0.884
Flash Point [Method]:>225 C (437 F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air):
LEL: 0.9
UEL: 7.0
Flammability (Solid, Gas): N/A
Autoignition Temperature: N/D
Boiling Point / Range:> 316 C (600 F)
Vapour Density (Air = 1):> 2 at 101 kPa
Vapour Pressure:< 0.013 kPa (0.1 mm Hg) at 20 °C
Evaporation Rate (n-butyl acetate = 1):
N/D
pH:
N/A
Log Pow (n-Octanol/Water Partition Coefficient):> 3.5
Solubility in Water:
Negligible
Viscosity:
109 cSt (109 mm2/sec) at 40 C | 14.5 cSt (14.5 mm2/sec) at 100 C
Freezing Point:
N/D
Melting Point:
N/A
Decomposition Temperature: N/D
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Pour Point:-27 C (-17 F)
DMSO Extract (mineral oil only), IP-346:
SECTION 10
STABILITY:< 3 %wt

STABILITY AND REACTIVITY

Material is stable under normal conditions.

POSSIBILITY OF HAZARDOUS REACTIONS:

Hazardous polymerization will not occur.

Page 7 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________

CONDITIONS TO AVOID:

Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID:

Strong oxidisers

HAZARDOUS DECOMPOSITION PRODUCTS:

Material does not decompose at ambient temperatures.

SECTION 11

TOXICOLOGICAL INFORMATIONINFORMATION ON TOXICOLOGICAL EFFECTS
Hazard Class

Conclusion / Remarks

Inhalation
Acute Toxicity: No end point data formaterial.
Irritation: No end point data formaterial.
Ingestion

Minimally Toxic. Based on assessment of the components.

Acute Toxicity: No end point data formaterial.
Skin

Minimally Toxic. Based on assessment of the components.

Acute Toxicity: No end point data formaterial.
Skin Corrosion/Irritation: No end point
data for material.
Eye

Minimally Toxic. Based on assessment of the components.

Serious Eye Damage/Irritation: No end
point data for material.
Sensitisation

May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.

Respiratory Sensitization: No end point
data for material.
Skin Sensitization: No end point data
for material.
Aspiration: Data available.

Not expected to be a respiratory sensitizer.

Germ Cell Mutagenicity: No end point
data for material.
Carcinogenicity: No end point data formaterial.
Reproductive Toxicity: No end point
data for material.
Lactation: No end point data formaterial.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data formaterial.
Repeated Exposure: No end point data

Negligible hazard at ambient/normal handling temperatures.

Negligible irritation to skin at ambient temperatures.
Based on assessment of the components.

Not expected to be a skin sensitizer. Based on assessmentof the components.
Not expected to be an aspiration hazard. Based on physicochemical properties of the material.
Not expected to be a germ cell mutagen. Based on assessmentof the components.
Not expected to cause cancer. Based on assessment of thecomponents.
Not expected to be a reproductive toxicant. Based on
assessment of the components.
Not expected to cause harm to breast-fed children.

Not expected to cause organ damage from a single exposure.
Not expected to cause organ damage from prolonged orPage 8 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________

for material.

repeated exposure. Based on assessment of the components.

OTHER INFORMATION
For the product itself:
Component concentrations in this formulation would not be expected to cause skin sensitization, based on
tests of the components, this formulation, or similar formulations.
Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce
any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines
may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations
in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) fromcombustion products of gasoline and/or thermal degradation products.
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346,
Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects;lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not
sensitising in test animals.

The following ingredients are cited on the lists below:

1 = NTP CARC
2 = NTP SUS

None.

--REGULATORY LISTS SEARCHED-3 = IARC 1
4 = IARC 2A

SECTION 12

5 = IARC 2B
6 = OSHA CARCECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material,and similar materials.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component --Expected to be inherently biodegradable

BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physicalproperties may reduce the bioconcentration or limit bioavailability.

Page 9 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________MOBILITY
land.

Base oil component -- Low solubility and floats and is expected to migrate from water to the
Expected to partition to sediment and wastewater solids.

SECTION 13

DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current
applicable laws and regulations, and material characteristics at time of disposal.
NATIONAL CATALOGUE OF HAZARDOUS WASTES
HW08 - Waste Mineral Oils

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal bysupervised incineration at very high temperatures to prevent formation of undesirable combustion
products.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue
and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty
drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty
containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed
contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER,DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14

TRANSPORT INFORMATION

China List of Dangerous Goods (GB 12268 - 2012) :Not Regulated for Land Transport

INTERNATIONAL CLASSIFICATION FOR TRANSPORTSEA (IMDG):
Not Regulated for Sea Transport according to IMDG-CodeMarine Pollutant:

AIR (IATA):No

Not Regulated for Air Transport

Page 10 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________SECTION 15

REGULATORY INFORMATIONThis material is not considered hazardous according to The General Rule for Classification and Hazard
Communication of Chemicals (GB 13690-2009).
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONSThe General Rules for preparation of precautionary label for Chemicals (GB 15258-2009):
Regulated

Not

Law of the People's Republic of China on Prevention and Control of Environmental Pollution by
Solid Waste: See Disposal Considerations section.
Listed or exempt from listing/notification on the following chemical inventories:
ENCS, IECSC, KECI, PICCS, TCSI, TSCASECTION 16

AICS, DSL,OTHER INFORMATION

N/D = Not determined, N/A = Not applicable
KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H303: May be harmful if swallowed; Acute Tox Oral, Cat 5
H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
H317: May cause allergic skin reaction; Skin Sensitization, Cat 1
H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1
H401: Toxic to aquatic life; Acute Env Tox, Cat 2
H402: Harmful to aquatic life; Acute Env Tox, Cat 3
H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
H412: Harmful to aquatic life with long lasting effects; Chronic Env Tox, Cat 3
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Layout Reformatted with SDS compilation requirements.

---------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge andbelief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that thisdocument is the most current available from ExxonMobil. The information and recommendations are offered
for the user's consideration and examination. It is the user's responsibility to satisfy itself that the
product is suitable for the intended use. If buyer repackages this product, it is the user's
responsibility to insure proper health, safety and other necessary information is included with and/or on
the container. Appropriate warnings and safe-handling procedures should be provided to handlers andPage 11 of 12Referring to GB/T 16483 and GB/T 17519
Product Name:PERKINS DIESEL ENGINE OIL 15W-40

Revision Date: 09 Mar 2017
Issue Date: 11 Jan 2017

SDS Number:7141093XCN
Version:1.01______________________________________________________________________________________________________________________

users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term,"ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company,
Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest.
(AP Core)---------------------------------------------------------------------------------------------------------------------------------------------------DGN: 7141093XCN (1021970)----------------------------------------------------------------------------------------------------------------------------------------------------

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