年 報2023

北海道大学触媒科学研究所
Institute for Catalysis, Hokkaido University

Annual Report 2023

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prefaceࠕ໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᖺሗ2023ࠖࡢห⾜࡟࠶ࡓࡗ࡚

 ࠕᖺሗ2023ࠖࡢห⾜࡟࠶ࡓࡾ㸪ࡈᣵᣜ⏦ࡋୖࡆࡲࡍ㸬ᮏ◊✲ᡤࡢタ❧ࡣ㸪᫛࿴18ᖺ㸦1943ᖺ㸧ࡢゐ፹◊✲ᡤࡢタ❧࡟㐳ࡾ㸪ᖹᡂඖᖺ㸦1989ᖺ㸧࡟ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮࡜ࡋ
࡚㸪ࡉࡽ࡟ᖹᡂ27ᖺ㸦2015ᖺ㸧࡟௒᪥ࡢゐ፹⛉Ꮫ◊✲ᡤ࡜ࡋ࡚ᨵ⤌ࡉࢀࡲࡋࡓ㸬㠉᪂ⓗゐ፹ࡢ㛤Ⓨ࡜Ꮫ⌮㏣✲ࢆᢸ࠺ᇶ♏◊✲⣔8㒊㛛㸪◊✲ᡂᯝࡢᐇ⏝໬࠾ࡼࡧ⏘ᴗ⏺ࢽ࣮ࢬࡢᢏ⾡ࢩ࣮ࢬ໬ࢆᢸ࠺㛤Ⓨ⣔1㒊㛛ࡀᇶ┙ⓗ◊✲㛤Ⓨࢆ᥎㐍ࡋ࡚࠸ࡲࡍ㸬ࡲࡓ㸪ࢱ࣮ࢤࢵࢺ◊✲㒊ࡣ7ࢡࣛࢫࢱ࣮࡛
ᵓᡂࡉࢀ㸪࣮ࣜࢲ࣮࡛࠶ࡿ෸ᩍᤵࡀ୺యⓗ࡟ᅜෆእࡢ◊✲⪅ࢆ஺࠼࡚㐠Ⴀࡋ㸪≉ᐃࡢ㔜せ◊✲ㄢ㢟ࡢゎỴࢆ┠ᣦࡋࡓ◊✲ࢆ⾜ࡗ࡚࠸ࡲࡍ㸬㝃ᒓࡢ◊✲᪋タ࡛࠶ࡿ㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮࡟ࡣ㸪ࣘࢽࢵࢺ࡜࿧ࡤࢀࡿ6ࡘࡢ⤌⧊ࡀ࠶ࡾ㸪ࡓ࠼ࡎኚ໬ࡍࡿ♫఍ⓗせㄳ࡟ᑐᛂࡍࡿࡓࡵ࡟㸪ᰂ㌾࠿ࡘᡓ␎ⓗ࡟እ㒊࡜ࡢ㐃ᦠࢆ⤌⧊໬ࡋ࡚࠸ࡲࡍ㸬᭱ඛ➃ࡢ◊✲ࢆᨭ࠼ࡿ◊✲ᨭ᥼ᢏ⾡㒊ࡣ㸪࢞ࣛࢫຍᕤ㸪㔠ᒓຍᕤ㸪ヨᩱᐃ࡞࡝࡛◊✲ࢆᢏ⾡ⓗ࡟ࢧ࣏࣮ࢺࡋࡲࡍ㸬ࡲࡓ㸪ᅜእࡢゐ፹◊✲ᣐⅬ࡜ࡣ◊✲࣭ᩍ⫱άືࡢ㐃ᦠࣃ࣮ࢺࢼ࣮࡜ࡋ࡚㸪✚ᴟⓗ࡟Ꮫ⾡஺ὶ༠ᐃࢆ⥾⤖ࡋ࡚࠸ࡲࡍ㸬ᮏ◊✲ᡤࡢ㐠Ⴀ࡟ࡘ࠸࡚ࡣ㸪ゐ፹◊✲ࢥ࣑ࣗࢽࢸ࢕࣮ࡢ௦⾲࡛࠶ࡿ㐠Ⴀ༠㆟఍࠿ࡽࡢពぢ⫈ྲྀࢆ⾜࠸㸪ᨵၿ࡟ດࡵ࡚࠾ࡾࡲࡍ㸬ゐ፹⛉Ꮫ◊✲ᡤࡢ◊✲άືࡣዲㄪࢆಖࡗ࡚࠸ࡲࡍ㸬➨୕ᮇ୰ᮇィ⏬ᮇ㛫ࡢᖹᆒ࡛ࡣ㸪ᩍဨ୍ேᙜࡓࡾࡢㄽᩥᩘࡣ4ᮏ௨ୖࢆಖࡗ࡚࠾ࡾ㸪⿕ᘬ⏝ᩘtop10%ㄽᩥࡢ๭ྜࡣ20%ࢆ
㉸࠼࡚࠸ࡲࡍ㸬ගゐ፹㸪ࣂ࢖࣐࢜ࢫኚ᥮ゐ፹㸪⎔ቃゐ፹,᭷ᶵྜᡂゐ፹㸪࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫ࡟㛵ࡍࡿㄽᩥࡢ⿕ᘬ⏝ᩘࡣᴫࡋ࡚㧗࠸≧ἣ࡟࠶ࡾࡲࡍ㸬ࡲࡓ㸪እ㒊࡜ࡢඹྠ◊✲࡟ࡼࡿᡂᯝ࡜ࡋ࡚ฟ∧ࡉࢀࡓㄽᩥࡢ୰࡟ࡶ㉁ࡢ㧗࠸ㄽᩥࡀከࡃ㸪⾲㠃ᵓ㐀ゎᯒ㸪⌮ㄽィ⟬࡟ࡼࡿࢳ࣮࣒
◊✲ࡢᡂᯝࡀ⾲ࢀ࡚࠸ࡲࡍ㸬௻ᴗ࡜ࡢ㛵ಀ࡟࠾࠸࡚ࡣ㸪⎔ቃゐ፹㸪㧗ศᏊᶵ⬟ᛶᮦᩱ㸪ࣂ࢖࣐࢜ࢫኚ᥮࡞࡝࡟࠾࠸࡚
✚ᴟⓗ࡞ඹྠ◊✲ࡀ⾜ࢃࢀ࡚࠸ࡲࡍ㸬 ᮏ◊✲ᡤࡣ㸪ᖹᡂ22ᖺ㸦2010ᖺ㸧࡟ᩥ㒊⛉Ꮫ┬࠿ࡽඹྠ฼⏝ඹྠ◊✲ᣐⅬ࡜ࡋ࡚ㄆᐃࢆཷࡅ㸪ᅜෆࡢゐ፹◊✲࡟ᚑ஦ࡍࡿ◊✲⪅ࡢ฼⏝࡟౪ࡍ࡭ࡃᣐⅬάືࢆ⾜ࡗ࡚ཧࡾࡲ
ࡋࡓ㸬௧࿴4ᖺ㸦2022ᖺ㸧ᗘࡼࡾ㸪ᮏ◊✲ᡤ㸪኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮࡜࡜ࡶ࡟ࢿࢵࢺ࣮࣡ࢡᆺࡢࠕゐ፹⛉Ꮫィඹྠ◊✲ᣐⅬࠖ࡜ࡋ࡚ᩥ㒊⛉Ꮫ┬࠿ࡽㄆᐃࢆཷࡅࡲࡋ
ࡓ㸬ᮏ◊✲ᡤࡣᮏᣐⅬࡢ௦⾲࡛࠶ࡾ㸪ᣐⅬࡢ㐠Ⴀጤဨ఍㸪ㄢ㢟➼ᑂᰝᑓ㛛ጤဨ఍࡟ࡼࡿࡈᨭ᥼ࡢࡶ࡜ᣐⅬάືࢆᐇ᪋ࡋ࡚ཧࡾࡲࡋࡓ㸬ᣐⅬෆࡢ◊✲⪅ࡀᣢࡘࢩ࣮ࢬ࡜㸪ᣐⅬእࡢ◊✲⪅ࡢࢽ࣮ࢬࡢ࣐ࢵࢳࣥࢢࢆᅗࡾ㸪ᣐⅬ඲య࡛264௳㸦ᮏ◊✲ᡤ࡛ࡣ193௳㸧ࡢබເඹྠ◊✲ࢆ௧࿴5ᖺ㸦2023
ᖺ㸧ᗘ࡟ᐇ᪋ࡋࡲࡋࡓ㸬බເඹྠ◊✲ࡢ7%ࡀᅜ㝿ඹྠ◊✲࡛࠶ࡾ㸪ᾏእࡢ◊✲⪅࡜ࡢඹྠ◊✲ࡢᡂᯝ࡟ࡼࡗ࡚㉁ࡢ
㧗࠸ㄽᩥࢆฟ∧ࡍࡿࡇ࡜ࡀ࡛ࡁࡲࡋࡓ㸬⿕ᘬ⏝top10%ㄽ
ᩥࡢ33%ࡀᾏእࡢඹྠ◊✲⪅࡜ࡢඹⴭㄽᩥ࡛ࡍ㸬ేࡏ࡚㸪ᅜෆࡢඃࢀࡓ◊✲ᡂᯝࢆᾏእ࡟࿘▱ࡍࡿࡓࡵࡢ᝟ሗⓎಙᆺࢩ࣏ࣥࢪ࣒࢘㸪ᅜෆእࡢ◊✲⪅࡬ࡢᢏ⾡ᣦᑟࡸ♫఍࡬ࡢ㈉⊩ࢆ┠ⓗ࡜ࡍࡿゐ፹㧗ᗘᐇ㊶◊ಟࣉࣟࢢ࣒ࣛࢆᐇ᪋ࡋ㸪◊✲ᡂᯝࡢ♫఍㑏ඖ࡟ດࡵ࡚ࡲ࠸ࡾࡲࡋࡓ㸬ᮏ◊✲ᡤࡣ㸪ྡྂᒇ኱Ꮫ≀㉁⛉Ꮫᅜ㝿◊✲ࢭࣥࢱ࣮㸪ி㒔኱Ꮫ໬Ꮫ◊✲ᡤ㝃ᒓඖ⣲⛉Ꮫᅜ㝿◊✲ࢭࣥࢱ࣮㸪஑ᕞ኱Ꮫඛᑟ≀㉁໬Ꮫ◊✲ᡤ࡜ඹ࡟Ꮫ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓ࡟ཧ⏬ࡋ࡚࠸ࡲࡍ㸬ࡇࢀࡽ◊✲ᡤ㛫ࡢඹྠ◊✲ࢆ㏻ࡋ࡚㸪໬Ꮫ࣭≀⌮࣭⏕≀࡟ࡲࡓࡀࡿ≀㉁㝵ᒙ࡜ྜᡂᴫᛕࢆ⤫ྜࡍࡿ᪂Ꮫ⾡ᇶ┙ࢆ๰ᡂࡋ㸪ྠ᫬࡟ⱝᡭ◊✲⪅ࡢ⫱ᡂࢆᅗࡗ࡚࠸ࡲࡍ㸬 ௧࿴6ᖺ㸦2024ᖺ㸧ᗘࡣ㸪➨4ᮇ୰ᮇィ⏬ᮇ㛫ࡢ3ᖺᗘ┠࡛ࡍ㸬ᾆཱྀ๪ᡤ㛗㸪୰㔝ࢭࣥࢱ࣮㛗ࢆࡣࡌࡵ◊✲ᡤᵓᡂဨ୍୸࡜࡞ࡗ࡚㸪◊✲ᡤ࡜ᣐⅬࡢ㐠Ⴀ࡟ᑾຊࡍࡿᡤᏑ࡛ࡍ㸬ࡇࢀࡲ࡛࡟ࡶቑࡋ࡚㸪ⓙᵝ࠿ࡽࡢࡈ༠ຊ࡞ࡽࡧ࡟ࡈᣦᑟ࡜
ࡈ㠴᧡ࢆ㈷ࡾࡲࡍࡼ࠺࠾㢪࠸⏦ࡋୖࡆࡲࡍ㸬ゐ፹⛉Ꮫ◊✲ᡤ㛗
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⤌⧊
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ᩍᤵ఍㐠Ⴀ༠㆟఍ཷク◊✲➼ཷධࢀᑂᰝጤဨ఍ホ౯ጤဨ఍ᖖ⨨ጤဨ఍◊✲ဨ࣭኱Ꮫ㝔⏕࡞࡝ࡢཷධࢀ㈈ົ
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ᡤᅾᆅᘓ≀ᩍ⫱ேᮦ⫱ᡂ♫఍㐃ᦠ㐍㊰≧ἣゐ፹໬Ꮫࡢࣇࣟࣥࢸ࢕࢔ Principles ofCatalytic Chemistry: Theory and Application/ CSE
SummerSchooland
ALP
International
Symposium ᖺ໭ࡢᅜゐ፹ሿゐ፹⛉Ꮫ◊✲ᡤᾏእὴ㐵ไᗘᏛ⏕஺ὶጤဨ఍
ᅗ᭩Ꮫ⾡᝟ሗ
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‫ڦ‬ᅜ㝿࣭ᅜෆ஺ὶ࡜ඹྠ◊✲஺ὶ༠ᐃ
ඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬ஦ᴗ
⟶⌮㐠Ⴀබເせ㡯ᖺᗘࡢඹྠ฼⏝࣭ඹྠ◊✲᥇ᢥㄢ㢟ᩘ
௧࿴ᖺᗘ㹼௧࿴ᖺᗘᩥ㒊⛉Ꮫ┬≉ู⤒㈝ࠕᏛ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓࠖ̿໭ᾏ㐨኱Ꮫ㸪ྡྂᒇ኱Ꮫ㸪ி㒔኱Ꮫ㸪஑ᕞ኱Ꮫ㹼኱Ꮫࡢ㐃ᦠ࡟ࡼࡾ≀㉁๰〇໬Ꮫࡢୡ⏺ⓗࢿࢵࢺ࣮࣡ࢡࢆ⠏ࡁ㸪ᮍ᮶ࢆࡅࢇᘬࡍࡿⱝᡭ
୰᰾◊✲⪅ࢿࢵࢺ࣮࣡ࢡࢆᵓ⠏
ㅮ₇఍࣭◊✲఍࡞࡝ICAT International Symposium on Catalysis 2023:
Novel theoretical and experimental approaches fordesigninghomogeneous
catalysisICAT-FHI
Symposium : Approaching to the Catalysis Reality 
TU/e-ICAT Joint International Symposium on
Catalysis:Advanced Technologies for Sustainable
Society / ᝟ሗⓎಙᆺᅜ㝿ࢩ࣏ࣥࢪ࣒࢘ ゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘

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‫ڦ‬ሗ࿌࣭ᐇ⏝໬᥎㐍⣔◊✲㛤Ⓨ㒊㛛

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‫ڦ‬ሗ࿌࣭㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮
ࣇࣜࢵࢶ࣭ࣁ࣮ࣂ࣮◊✲ᡤࣘࢽࢵࢺᏛ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ࣘࢽࢵࢺ໭኱ゐ፹࢔ࣛ࢖࢔ࣥࢫࣘࢽࢵࢺ/᪂ᨺᑕග※ゐ፹ィ ⛉Ꮫࣘࢽࢵࢺ࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐
ࢸ࢕ࢡࢫࣘࢽࢵࢺ࢔࢖ࢩࣥ໭኱5㸤'ࣛ࣎ࣘࢽࢵࢺ

‫ڦ‬ሗ࿌࣭◊✲ᨭ᥼ᢏ⾡㒊
‫ࡢࡑڦ‬௚ࡢᴗ⦼

ಶே⦅

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‫ڦ‬ಶேࢹ࣮ࢱ
ಶேࢹ࣮ࢱ
ᩍ⫋ဨࡢ≉チ
ᩍ⫋ဨࡢཷ㈹
ᖺᗘᢸᙜㅮ⩏
ᖺᗘᏛ఩ᑂᰝ
ᖺᗘጤဨ࣭ㅮᖌ࡞࡝
ᖺᗘእ㒊㈨㔠࡞࡝

⦅㞟ᚋグ



‫⦅ڦ‬㞟ᚋグ
‫ڦ‬᭩ㄅ᝟ሗ

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2

ᖺሗ࣭◊✲ᡤ⦅‫ە‬ಒᙲểኵጢᴾ
abstract and organizationṔྐᩍ⫱◊✲⌮ᛕ ゐ፹ࡢ♫఍ⓗ㔜せᛶ࡟㚷ࡳ㸪ゐ፹◊✲ᡤ㸦᫛࿴18ᖺ1᭶
30᪥タ⨨㸧ࡀタ❧ࡉࢀࡓ㸬ᖹᡂඖᖺ5᭶29᪥࡟㸪ゐ፹◊✲ᡤࢆẕయ࡜ࡋ㸪ࠕゐ፹໬Ꮫ࡟㛵ࡍࡿ◊✲࡞ࡽࡧ࡟඲ᅜ኱Ꮫ
➼࡜ࡢඹྠ◊✲㸪ඹྠ฼⏝࡟౪ࡍࡿࠖࡇ࡜ࢆ┠ⓗ࡜ࡍࡿ඲ᅜඹྠ฼⏝᪋タ㸪ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࡀタ⨨ࡉࢀࡓ㸬ࡑࡢ᫬㝈ࡣ10ᖺ㸦1998ᖺᗘ㸧࡜ࡉࢀ࡚࠸ࡓࡀ㸪ᖹᡂ10ᖺ࡟ࡣ㸪
3㒊㛛9ศ㔝࡜ࡋ࡚ᣑ඘ᨵ⤌ࡉࢀ㸪ᖹᡂ19ᖺ࠿ࡽ7◊✲㒊㛛యไࡢゐ፹ᇶ♏◊✲㒊࡜㸪ࡇࢀࡽ㒊㛛࡜Ꮫෆእࡢ◊✲⪅ࡀᶓ᩿ⓗ࡟㐃ᦠࡍࡿ7ࡘࡢ◊✲ࢡࣛࢫࢱ࣮ࢆ᧦ࡋࡓゐ፹ࢱ࣮ࢤࢵࢺ◊✲࢔ࢭࣥࣈࣜయไ࠿ࡽ࡞ࡿ᪂⤌⧊ࢆጞືࡉࡏࡓ㸬ᖹᡂ22ᖺ࡟ࡣ㸪ᩥ㒊⛉Ꮫ┬ࠕඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬࠖ࡟᥇ᢥࡉࢀ㸪ᅜෆ၏୍ࡢゐ፹◊✲ᣐⅬ࡜ࡋ࡚ㄆᐃࡉࢀࡓ㸬᭦࡟㸪ᖹᡂ24ᖺ௨㝆ࡢᣑ඘ᨵ⤌࡛ࡣ㸪᪂ࡓ࡟2㒊㛛―ゐ፹⌮ㄽ໬Ꮫ◊✲㒊㛛࡜ᐇ⏝໬ᇶ┙ᢏ⾡㛤Ⓨ㒊ࡀࡑࢀࡒࢀ๰タࡉࢀࡓ㸬ࡑࡋ࡚㸪ᖹᡂ27ᖺ10᭶1᪥㸪໭ᾏ㐨኱Ꮫࡢᙉࡳ࡛࠶ࡿゐ፹⛉Ꮫࢆࡉࡽ࡟Ⓨᒎࡉࡏࡿ࡭ࡃ㸪ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮࠿ࡽゐ፹⛉Ꮫ◊✲ᡤ࡟ᨵ⤌ࡋࡓ㸬௧࿴4ᖺ4᭶1᪥ࡼࡾ㸪ᮏ◊✲ᡤ㸪኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮࡜࡜ࡶ࡟
ࢿࢵࢺ࣮࣡ࢡᆺࡢࠕゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬࠖࢆ㛤ጞࡋ
ࡓ㸬

タ⨨┠ⓗ



 ゐ፹⛉Ꮫ◊✲ᡤࡣゐ፹⛉Ꮫ࡟㛵ࡍࡿ◊✲ࢆ⾜࠸㸪࠿ࡘ㸪ᅜ❧኱Ꮫࡢᩍဨࡑࡢ௚ࡢ⪅࡛ࡇࡢศ㔝ࡢ◊✲࡟ᚑ஦ࡍࡿ
ࡶࡢࡢ฼⏝࡟౪ࡍࡿࡇ࡜ࢆ┠ⓗ࡟タ⨨ࡉࢀࡓ㸬┠ᶆ࡜౑࿨ ᣢ⥆ྍ⬟♫఍ࡢᐇ⌧ࡀᙉࡃᮃࡲࢀ࡚࠸ࡿ㸬ᣢ⥆ྍ⬟♫఍ᐇ⌧ࡢࡓࡵ࡟ࡣ㸪≀㉁࣭࢚ࢿࣝࢠ࣮⏕⏘࣭ኚ᥮࣭฼⏝ࢆ㧗ຠ⋡࡛ᐇ⌧ࡋ㸪ከᵝ࡞㈨※ࢆ᭷ຠά⏝ࡍࡿࡓࡵࡢᇶ♏⛉Ꮫ࡜ᇶ♏⛉Ꮫ࡟ᇶ࡙ࡃᐇ⏝໬ࡢࡓࡵࡢᛂ⏝ᕤᏛ࡜ᢏ⾡㛤Ⓨ
ࡀᚲせ࡛࠶ࡿ㸬ゐ፹⛉Ꮫࡣࡇࡢᣢ⥆ྍ⬟♫఍ࡀᚲせ࡜ࡍࡿ⛉Ꮫ࣭ᢏ⾡ࢆᨭ࠼ࡿ᰾ᚰⓗᏛၥศ㔝࡛࠶ࡾ㸪ゐ፹⛉Ꮫࡢᇶ♏◊✲ࢆⓎᒎࡉࡏ㸪ゐ፹࡟㛵ࡍࡿᇶ♏◊✲ࡢᡂᯝࢆᐇ⏝໬࡟ࡘ࡞ࡆ࡚ᆅ⌫つᶍࡢ࢖ࣀ࣮࣋ࢩࣙࣥࢆಁ㐍ࡍࡿࡇ࡜ࡣ
♫఍ࡢᙉ࠸せㄳ࡛࠶ࡿ㸬 ᮏ◊✲ᡤࡣ㸪໭኱࡟࠾ࡅࡿୡ⏺ࢺࢵࣉࢡࣛࢫࡢゐ፹◊✲ࢆ୍ᒙ᥎㐍ࡋ㸪⏘ᴗ໬࡟ࡘ࡞ࡆ࡚♫఍ࡢᙉ࠸せㄳ࡟⟅࠼ࡿ㸬ᮏ◊✲ᡤࡣ␗ศ㔝ࢆ⼥ྜࡋࡓ᪂ࡓ࡞ゐ፹⛉Ꮫࢆ๰㐀ࡋ㸪ᅜෆእࡢ◊✲⪅࡜ࡢࢿࢵࢺ࣮࣡ࢡᣐⅬ࡜࡞ࡗ࡚㸪"࢚ࢿࣝࢠ࣮࣭㈨※ࡢከᵝ໬࡜㧗ᗘ฼⏝࡟㈨ࡍࡿゐ፹ࡢཎ⌮ゎ᫂࠾ࡼࡧ᪂ゐ፹ྜᡂᢏ⾡ࡢ㛤Ⓨࢆ㐍ࡵ㸪᪂つゐ፹ࡢᐇ⏝໬ࢆ᥎㐍ࡋ࡚㸪ゐ፹ඛᑟ࢖ࣀ࣮࣋ࢩࣙࣥࢆ㉳ࡇࡋ㸪ᣢ⥆ྍ⬟♫఍ࢆᐇ⌧ࡍࡿࡇ࡜"ࢆ౑࿨࡜┠ᶆ࡜ࡋ࡚άືࢆ࠾ࡇ࡞࠺㸬‫ە‬ᖺሗ ࣭◊✲ᡤ⦅ ᅜෆእࡢ◊✲⪅ࢥ࣑ࣗࢽࢸ࢕࡜㐃ᦠࡋ㸪≀㉁⛉Ꮫ࡟㏻ᗏ
ࡍࡿ໬Ꮫ཯ᛂࡢ཯ᛂᶵస࡜཯ᛂไᚚཎ⌮࡟㛵ࡍࡿᇶ♏ᴫᛕࢆ᫂ࡽ࠿࡟ࡍࡿ㸬ࡇࡢᇶ♏ᴫᛕ࡟ᇶ࡙ࡁ㸪᪂ࡋ࠸ゐ፹ࡢ๰㐀࡜ᐇ⏝໬ࢆ㐍ࡵ㸪ゐ፹ඛᑟ࢖ࣀ࣮࣋ࢩࣙࣥࢆᐇ⌧ࡋ࡚㸪ᣢࡗ࡚♫఍ࡢ㈇ク࡟ᛂ࠼ࡿ㸬 ཪ㸪ࡇࡢάືࢆỌ⥆ⓗ࡟⾜࠸㸪ゐ፹࡟㛵ࡍࡿ▱㆑࡜ᢏ⾡ࢆᗈࡵ㸪♫఍ࡢⓎᒎ࡟㈨ࡍࡿேᮦ࡜࣮ࣜࢲ࣮ࡢ⫱ᡂࢆ㐍ࡵࡿ㸬

᪂ࡋ࠸ゐ፹⛉ᏛⓎᒎࡢࡓࡵࡢ᪋⟇ ゐ፹⛉Ꮫ◊✲ᡤࡣゐ፹⛉Ꮫ◊✲Ⓨᒎࡢࡓࡵ࡟5ࡘࡢ᪋⟇ࢆᥖࡆࡿ㸬
1㸬ゐ፹⛉Ꮫࡢᇶ♏◊✲ࡢ᥎㐍࡜ࡇࢀࢆᇶ࡟ࡋࡓᐇ⏝໬ࡍࡿࡓࡵࡢ⤌⧊ᩚഛ ゐ፹⾲㠃◊✲㒊㛛㸪ゐ፹⌮ㄽ◊✲㒊㛛㸪ゐ፹཯ᛂ◊✲㒊㛛㸪≀㉁ኚ᥮◊✲㒊㛛㸪ゐ፹ᮦᩱ◊✲㒊㛛㸪ศᏊゐ፹◊✲㒊㛛㸪㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛ࢆタ⨨ࡋ㸪ᖜᗈ࠸ゐ፹ࡢྛศ㔝࡟ᑐᛂࡍࡿ࡜࡜ࡶ࡟㸪ࢱ࣮ࢤࢵࢺ◊✲㒊࡟タ⨨ࡋࡓࢡࣛࢫࢱ࣮࡟࠾࠸࡚㸪෸ᩍᤵࢆ୰ᚰ࡟ᅜෆእࡢ◊✲⪅࡜ⴌⱆⓗ㸪Ⓨᒎⓗ◊✲ࢆ㐙⾜ࡍࡿ㸬୍᪉࡛㸪ᇶ♏◊✲ࡢᡂᯝࢆᇶ
࡟◊✲㛤Ⓨ㒊㛛࡛ࡣ㸪ᐇ⏝໬᥎㐍ࢆ⾜࠺㸬ࡇ࠺ࡋࡓ௙⤌ࡳ࡟ࡼࡾ㸪Ꮫ⾡ࢆᇶ┙࡜ࡋࡓゐ፹ඛᑟ࢖ࣀ࣮࣋ࢩࣙࣥࢆᐇ⌧ࡋ㸪ᣢ⥆ྍ⬟♫఍ࢆᐇ⌧ࡍࡿ㸬
2㸬ゐ፹࡟㛵ࡍࡿ▱㆑ࡢ⵳✚࡜ά⏝ ゐ፹ࢹ࣮ࢱ࣮࣋ࢫࢆࡉࡽ࡟ᣑ඘ࡋ㸪ゐ፹࡟㛵ࡍࡿ▱㆑ࢆ㞟✚ࡍࡿ.୍᪉࡛㸪ேᕤ▱⬟ࡸ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࢆ㥑౑ࡋ࡚㸪ࡇࡢ㞟✚ࡉࢀࡓ▱㆑ࢆά⏝ࡋ㸪▱㆑ࡢ♫఍㑏ඖࢆ㐍ࡵࡿ㸬3㸬␗ศ㔝⼥ྜ ≀㉁ࢆኚ᥮ࡋ㸪໬Ꮫ཯ᛂ㏿ᗘࢆไᚚࡍࡿゐ፹ࡣ໬Ꮫࡢ㔜せ࡞ศ㔝࡛࠶ࡿ㸬ࡋ࠿ࡋ㸪௒᪥ࡢᛴ㏿࡞⛉Ꮫᢏ⾡ࡢ㐍Ṍࡣゐ፹ࢆ༢࡟ゐ፹໬Ꮫࡢ୰࡛㛢ࡌࡿࡇ࡜ࢆチࡉࡎ㸪᪂ࡓ࡞ㄢ㢟ゎỴࡢࡓࡵ㸪␗ศ㔝ࡢཧධࢆᚲせ࡜ࡍࡿ㸬ゐ፹⛉Ꮫ◊✲ᡤࡣ㸪ᚑ᮶ࡢศ㔝࡟࡜࡝ࡲࡿࡇ࡜࡞ࡃ㸪✚ᴟⓗ࡟␗ศ㔝࡜ࡢ㆟ㄽ࣭㐃ᦠࢆ㏻ࡌ࡚㸪᪂ࡋ࠸ゐ፹⛉Ꮫࢆ๰㐀ࡍࡿ㸬
4㸬⤌⧊㛫㐃ᦠ ゐ፹⛉Ꮫ◊✲ᡤࡣ20ྡᙉࡢᑠࡉ࠸㞟ᅋ࡛࠶ࡿࡀ㸪ᅜෆእࡢ◊✲ᡤ,◊✲ࢭࣥࢱ࣮࡜㐃ᦠࡍࡿࡇ࡜࡛㸪ࡑࡢຊࢆቑᖜ
ࡍࡿ㸬ලయⓗ࡟ࡣ㸪⏘ᴗ໬ࢆ࣑ࢵࢩࣙࣥ࡜ࡍࡿ⏘ᴗ⥲ྜ◊✲ᡤࡸ㔞Ꮚࣅ࣮࣒ࢆ⏝࠸࡚ゐ፹ᵓ㐀ࢆㄪ࡭ࡿ㧗࢚ࢿࣝ
ࢠ࣮ຍ㏿ჾ◊✲ᶵᵓ࡜ࡢ㐃ᦠࢆ᥎㐍ࡋ㸪ྡྂᒇ኱Ꮫ≀㉁⛉Ꮫᅜ㝿◊✲ࢭࣥࢱ࣮㸪ி㒔኱Ꮫ໬Ꮫ◊✲ᡤ㝃ᒓඖ⣲⛉Ꮫᅜ㝿◊✲ࢭࣥࢱ࣮㸪஑ᕞ኱Ꮫඛᑟ≀㉁໬Ꮫ◊✲ᡤ࡜࡜ࡶ࡟㸪Ꮫ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓ࡟ཧ⏬ࡍࡿ㸬ࡇࡢ௚࡟ࡶ㐃ᦠඛࢆ᥈ࡾ㸪ࡑࡢ⤌⧊㛫㐃ᦠࡢ୰࡛㸪୙㊊ࡋࡓຊࢆ⿵࠸㸪ᡃࡀᅜ඲యࡢゐ፹⛉Ꮫࡢ᥎㐍࡜ⱝᡭேᮦ⫱ᡂࢆ⾜࠺㸬ࡇࡢ㐃ᦠ
ࡢᣐⅬ࡟࡞ࡿࡢࡀ㸪᪂タࡉࢀࡓ㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮࡛࠶ࡿ㸬㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮࡟㐃ᦠඛࡢࣘࢽࢵࢺࢆ
సࡾ㸪◊✲ࢫ࣮࣌ࢫࢆᥦ౪ࡍࡿࡇ࡜࡛㸪㐃ᦠඛ࡜ࡢ⥭ᐦ࡞

3㛵ಀࢆసࡾ࠶ࡆࡿ㸬ࡉࡽ࡟᫖ᖺᗘ࠿ࡽࡣ㸪໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ(ICAT)㸪኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮(ReCAP)㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹⛉Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮(IRC3)㸪ᮾ໭኱Ꮫᅜ㝿ᨺᑕග࢖ࣀ࣮࣋ࢩ࣭ࣙࣥࢫ࣐࣮ࢺ◊✲ࢭࣥࢱ࣮(SRIS㸪Ꮫ⾡༠ຊᶵ㛵࡜ࡋ࡚ཧ⏬) ࢿࢵࢺ࣮࣡
ࢡᆺඹྠ฼⏝࣭◊✲ᣐⅬࢆᵓ⠏ࡋ㸪᪂ࡓ࡞⤌⧊㛫㐃ᦠάືࢆጞࡵࡓ㸬5㸬ᅜ㝿ࢿࢵࢺ࣮࣡ࢡࡢᵓ⠏ ゐ፹⛉Ꮫ◊✲ᡤࡣᵝࠎ࡞ᅜࡢ኱Ꮫ࣭◊✲ᶵ㛵࡜✚ᴟⓗ࡟Ꮫ⾡஺ὶ༠ᐃࢆ⥾⤖ࡋ࡚࠸ࡿ㸬௒ᚋࡉࡽ࡟༠ᐃ⥾⤖ࢆ㐍ࡵ㸪඲ୡ⏺࡜ࡢࢿࢵࢺ࣮࣡ࢡᵓ⠏ࢆᣑ඘ࡍࡿ㸬ࡲࡓ㸪᪂タࡉࢀࡓ㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮࡛ࡣ㸪࠸ࡃࡘ࠿ࡢ◊✲ᡤࡢࣘࢽࢵࢺ㸦FHIࣘࢽࢵࢺ࡞࡝㸧ࢆࢭࣥࢱ࣮ෆ࡟タ⨨ࡋ࡚㸪◊✲ࢫ࣮࣌ࢫࢆᥦ౪ࡋ㸪㛗ᮇ⁫ᅾᆺ◊✲⪅ࡢᣍ࡬࠸ࢆ㐍ࡵࡿ㸬ࡲࡓ㸪◊✲ᡤ࡛ࡣ20ᖺ࡟ࢃࡓࡗ࡚ᾏእὴ㐵ไᗘࢆᐇ᪋
ࡋ࡚ࡁࡓ㸬ࡇࡢࣉࣟࢢ࣒࡛ࣛࡣ㸪኱Ꮫ㝔⏕࣭ⱝᡭᩍဨࢆୡ
⏺࡟㏻⏝ࡍࡿᚋ⥅⪅࡟⫱ᡂࡍ࡭ࡃ㸪ᾏእࡢࢺࢵࣉࢡࣛࢫࡢ
ᩍဨ࡜ࡢඹྠ◊✲ࢆᢸᙜࡉࡏ࡚㸪ୡ⏺つᶍࡢᏛ⾡ࣞ࣋ࣝ࡬ࡢྥୖ࠾ࡼࡧⱝᡭ⫱ᡂ࡟㈉⊩ࡍࡿ㸬ࡲࡓ㸪ࡇࡢࡼ࠺࡞άື
ࢆ㏻ࡌ࡚ᅜ㝿◊✲ᣐⅬࡢᵓ⠏ࢆ⾜࠺㸬⤌⧊ 2015ᖺ10᭶ࡢᨵ⤌ᚋࡢᮏ◊✲ᡤࡣ㸪ゐ፹ศ㔝࡟᪂ࡋ࠸ࢥ
࢔໬Ꮫࢆ⏕ࡳฟࡍࡇ࡜ࢆ┠ⓗ࡟ᇶ♏◊✲ࢆ᥎㐍ࡍࡿᇶ♏
◊✲⣔ࡢ8◊✲㒊㛛࡜ᇶ♏◊✲ࡢᡂᯝࢆᇶ࡟ᐇ⏝໬᥎㐍ࢆ⾜࠺◊✲㛤Ⓨ㒊㛛㸪࠾ࡼࡧゐ፹ࢆᶵ㍈࡜ࡋࡓ⛉Ꮫ࣭ᢏ⾡ࡢ࢖ࣀ࣮࣋ࢩࣙࣥࢆ┠ⓗ࡜ࡍࡿ⮬❧㞟ྜᆺࡢ◊✲ࢡࣛࢫࢱ࣮࠿ࡽ࡞ࡿࢱ࣮ࢤࢵࢺ◊✲㒊࡛ᵓᡂࡉࢀ࡚࠸ࡿ㸬ࡲࡓ㸪◊✲ᨭ᥼ᢏ⾡㒊ࢆ᧦ࡋ࡚࠸ࡿ㸬஦ົࡣ໭࢟ࣕࣥࣃࢫྜྠ஦
ົ㒊ࡀ⾜ࡗ࡚࠸ࡿ㸬 ᮏ◊✲ᡤࡢᖖ໅ᩍ⫋ဨ㸦ࢱ࣮ࢤࢵࢺ◊✲㒊ࡣᡤᒓᩍဨ࡞
࡝㸧࠾ࡼࡧ໭࢟ࣕࣥࣃࢫྜྠ஦ົ㒊ࡢ㓄⨨ࡣ௨ୗࡢ࡜࠾ࡾ
㸦◊✲ဨ/እᅜே◊✲ဨ/኱Ꮫ㝔⏕࡟ࡘ࠸࡚ࡣேᩘࡢࡳ⾲♧㸧㸬㠀ᖖ໅⫋ဨ࡜኱Ꮫ㝔⏕࡞࡝ࡣࠕ◊✲ᐊ⦅ࠖࡢྛ◊✲ᐊࡢ㡯┠ࢆཧ↷㸬ᡤ㛗ᇶ♏◊✲⣔

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ゐ፹⌮ㄽ◊✲㒊㛛ゐ፹⾲㠃◊✲㒊㛛ゐ፹ᵓ㐀◊✲㒊㛛ゐ፹཯ᛂ◊✲㒊㛛≀㉁ኚ᥮◊✲㒊㛛ゐ፹ᮦᩱ◊✲㒊㛛ศᏊゐ፹◊✲㒊㛛㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛ᐇ⏝໬᥎㐍⣔

4

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ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮
ᶵ⬟ᛶྜ㔠ゐ፹◊✲ࢡࣛࢫࢱ࣮
㑄⛣㔠ᒓㄏ㉳㧗ศᏊྜᡂኚ᥮◊✲ࢡࣛࢫࢱ࣮
ࢼࣀ⏺㠃཯ᛂሙ◊✲ࢡࣛࢫࢱ࣮
⏕యศᏊᶆ㆑ゐ፹◊✲ࢡࣛࢫࢱ࣮
ࢹ࣮ࢱ㥑ືᆺゐ፹◊✲ࢡࣛࢫࢱ࣮
ኳ↛Ⅳ⣲㈨※ά⏝፹◊✲ࢡࣛࢫࢱ࣮
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㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮
ࣇࣜࢵࢶ࣭ࣁ࣮ࣂ࣮◊✲ᡤࣘࢽࢵࢺ㻌Ꮫ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ࣘࢽࢵࢺ໭኱ゐ፹࢔ࣛ࢖࢔ࣥࢫࣘࢽࢵࢺ
᪂ᨺᑕග※ゐ፹ィ ⛉Ꮫࣘࢽࢵࢺ
࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࣘࢽࢵࢺ
࢔࢖ࢩࣥ໭኱5㸤'ࣛ࣎ࣘࢽࢵࢺ

◊✲ᨭ᥼ᢏ⾡㒊໭࢟ࣕࣥࣃࢫྜྠ஦ົ㒊‫ڦ‬ᡤ㛗
ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒΎỈ◊୍‫ู≉ڦ‬ᣍ࡬࠸ᩍᤵ
ࠑ໭ᾏ㐨኱Ꮫྡ㄃ᩍᤵ/≉ูᣍ࡬࠸ᩍᤵࠒ㕥ᮌ❶‫ڦ‬ᇶ♏◊✲⣔ゐ፹⌮ㄽ◊✲㒊㛛 ࠑᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑ෸ᩍᤵࠒ㣤⏣೺஧࣭ࠑຓᩍࠒᐑᓮ⋹㹙㹼㹛࣭ࠑᮾᾏᅜ❧኱Ꮫ
ᶵᵓྡྂᒇ኱Ꮫ≉௵ᩍᤵ≉௵ຓᩍࠒᒣ⏣᪩ே࣭◊✲ဨྡ࣭኱Ꮫ㝔⏕ྡ࣭Ꮫ㒊Ꮫ⏕ྡゐ፹⾲㠃◊✲㒊㛛 ࠑᩍᤵࠒᮅ಴Ύ㧘࣭ࠑ◊✲ဨ㸦◊✲᥎㐍ᨭ᥼ᩍᤵ㸧
ࠒᒣᮏ㈆࣭᫂◊✲ဨྡ࣭እᅜே◊✲ဨྡ࣭኱Ꮫ㝔⏕ྡ࣭Ꮫ㒊Ꮫ⏕ྡゐ፹ᵓ㐀◊✲㒊㛛  ࠑᩍᤵࠒ㧘ⲡᮌ㐩࣭ࠑຓᩍࠒ㩃㑥㹙㹼㹛ゐ፹཯ᛂ◊✲㒊㛛 ࠑᩍᤵࠒ୰ᓥΎ㝯࣭ࠑ෸ᩍᤵࠒⳢ἟Ꮫ
ྐ࣭ࠑຓᩍࠒ኱㡲㈡㑈ኴ࣭እᅜே◊✲ဨྡ࣭኱Ꮫ㝔⏕ྡ࣭◊✲⏕ྡ
≀ ㉁ ኚ ᥮ ◊ ✲ 㒊 㛛  ࠑ ᩍ ᤵࠒ ⚟ ᒸ ῟ ࣭ࠑ ຓ ᩍ ࠒ Abhijit
SHROTRI࣭ࠑ≉௵ຓᩍࠒDaniele PADOVAN 㹙
㹼㹛࣭ࠑᮾிᕤ⛉኱Ꮫᩍᤵᐈဨᩍᤵࠒཎ㈼஧࣭
ࠑᮾி኱Ꮫ෸ᩍᤵᐈဨ෸ᩍᤵࠒᑠᯘᗈ࿴࣭◊✲ဨྡ࣭኱Ꮫ㝔⏕ྡゐ፹ᮦᩱ◊✲㒊㛛 ࠑᩍᤵࠒΎỈ◊୍࣭ࠑ෸ᩍᤵࠒྂᕝ᳃
ஓ㹙㹼㹛㫽ᒇᑿ㝯㹙㹼㹛࣭ࠑຓᩍࠒ㫽ᒇᑿ㝯㹙㹼㹛࣭ࠑ኱㜰኱Ꮫᩍᤵᐈဨᩍᤵࠒྂ ᕝ ᳃ ஓ 㹙  㹼 㹛࣭ࠑ ≉ ௵ ᩍ ᤵ ࠒ Evgeny
Alexandrovich PIDKO 㹙㹼㹛࣭ࠑ≉௵ ຓ ᩍ ࠒ Nazmul Hasan Mohammad Dostagir SHAIKH㹙㹼㹛Zhang NINGQIANG㹙㹼㹛࣭ࠑᢏ⾡ᑓ㛛⫋ဨࠒୗ⏣࿘ᖹ࣭እᅜே◊✲ဨྡ࣭኱Ꮫ㝔⏕ྡ࣭Ꮫ㒊Ꮫ⏕ྡ࣭◊✲⏕ྡศᏊゐ፹◊✲㒊㛛 ࠑᩍᤵࠒᾆཱྀ኱㍜࣭ࠑ෸ᩍᤵࠒὸ㔝ᆂభ ࣭ࠑ ຓ ᩍ ࠒ ㉿ ᙉ ࣭ࠑ ≉ ௵ ᩍ ᤵ ࠒ Ying Yeung
YEUNG 㹙㹼㹛࣭኱Ꮫ㝔⏕ྡ࣭Ꮫ
㒊Ꮫ⏕ྡ࣭◊✲⏕ྡ㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛 ࠑᩍᤵࠒ୰㔝⎔࣭ࠑ෸ᩍᤵࠒZhiyi
SONG࣭ࠑຓᩍࠒᆏᮾṇె࣭◊✲ဨྡ࣭እᅜே◊✲ဨྡ࣭኱Ꮫ㝔⏕ྡ

‫ڦ‬ᐇ⏝໬᥎㐍⣔◊✲㛤Ⓨ㒊㛛 ࠑᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑ◊✲ဨ㸦◊✲᥎㐍ᨭ᥼ᩍᤵ㸧ࠒす⏣ࡲࡺࡳ࣭ࠑᐈဨᩍᤵ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒబ⸨୍ᙪᐩỌ೺୍ὸᕝ┿⃈ྜྷ⏣຾⏿୰㞞㝯࣭ࠑᐈဨᩍᤵ࢙࢘ࢫࢺࢥ࣮ࢼ࣮ࠒ㝮⏣ᩄ㞝ᖺሗ࣭◊✲ᡤ⦅‫ە‬‫✲◊ࢺࢵࢤ࣮ࢱڦ‬㒊ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮㸺ᣐⅬᆺ㸼 ࠑ࣮ࣜࢲ࣮ᩍ
ᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᩍᤵࠒᮅ಴Ύ㧘୰ᓥΎ㝯⚟ᒸ῟ΎỈ◊୍ᾆཱྀ኱㍜୰㔝⎔㧘ⲡᮌ㐩ᶵ⬟ᛶྜ㔠ゐ፹◊✲ࢡࣛࢫࢱ࣮㸺ᒎ㛤ᆺ㸼 ࠑ࣮ࣜࢲ࣮/෸ᩍᤵࠒྂᕝ᳃ஓ㹙㹼2023/04/30㹛
࣭ࠑᩍᤵࠒᮅ಴Ύ㧘㹙㹼
2023/04/30㹛/㛗㇂ᕝ῟ஓ㹙㹼2023/04/30㹛
࣭ࠑᏛእ◊✲༠ຊ
ᩍဨ/ᮾ໭኱Ꮫࠒடᒸ⪽㹙㹼2023/04/30㹛
࣭ࠑᏛእ◊✲༠ຊ
ᩍဨ/㧗▱኱ᏛࠒᑠἙ⬶ᖹ㹙㹼2023/04/30㹛
࣭ࠑᏛእ◊✲༠
ຊᩍဨ/ࢩ࣏࣮ࣥ࢞ࣝᅜ❧኱ᏛࠒNing YAN㹙㹼2023/04/30㹛
㑄⛣㔠ᒓㄏ㉳㧗ศᏊྜᡂኚ᥮◊✲ࢡࣛࢫࢱ࣮㸺ᒎ㛤ᆺ㸼 ࠑ࣮ࣜࢲ࣮෸ᩍᤵࠒZhiyi SONGࠑᏛእ◊✲༠ຊᩍဨᚨᓥ኱Ꮫࠒᑠ➟ཎṇ㐨࣭ࠑᏛእ◊✲༠ຊᩍဨRenmin
University of China ࠒ Zhiping LI ࠑ Ꮫ እ ◊ ✲ ༠ ຊ ᩍ ဨ/University of Chinese Academy of Scienceࠒ⋤ᚘὒࢼࣀ⏺㠃཯ᛂሙ◊✲ࢡࣛࢫࢱ࣮㸺ᒎ㛤ᆺ㸼 ࠑ࣮ࣜࢲ࣮/෸ᩍᤵࠒ㣤⏣೺஧࣭ࠑ෸ᩍᤵࠒྂᕝ᳃ஓ㹙㹼2023/04/30㹛
࣭ࠑᐈဨ෸ᩍᤵ/ி㒔኱Ꮫࠒᮾ㞞኱㹙㹼2023/08/30㹛
࣭ࠑᐈဨ
෸ᩍᤵ/ྡྂᒇ኱Ꮫࠒᮾ㞞኱㹙2023/09/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/⟃Ἴ኱Ꮫࠒ▮ⰼ୍ᾈ࣭ࠑᏛእ◊✲༠ຊᩍဨ/ி㒔኱Ꮫࠒᑎす฼἞࣭
ࠑᏛእ◊✲༠ຊᩍဨ/ᮾி⌮⛉኱Ꮫࠒ᰿ᓊ㞝୍࣭ࠑᏛእ◊✲༠ຊᩍဨ/㇏ᶫᢏ⛉኱ࠒඵ஭ᓫ࣭
ࠑᏛእ◊✲༠ຊᩍဨ/࢔ࣝࣂ࣮ࢱ኱ᏛࠒAndriy KOVALENKO⏕యศᏊᶆ㆑ゐ፹◊✲ࢡࣛࢫࢱ࣮㸺ᒎ㛤ᆺ㸼ࠑ࣮ࣜࢲ࣮
෸ᩍᤵࠒὸ㔝ᆂభ࣭ࠑᐈဨᩍᤵ❧ᩍ኱Ꮫࠒᒣ୰ṇᾈ࣭ࠑᏛእ◊✲༠ຊᩍဨ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒ⏕㛗ᖾஅຓ࣭ࠑᏛእ◊✲༠ຊᩍဨ/኱㜰኱Ꮫࠒ┿㘠Ⰻᖾ࣭ࠑᏛእ◊✲༠
ຊᩍဨ/஑ᕞ኱Ꮫࠒᇼ㞝୍㑻࣭ࠑᏛእ◊✲༠ຊᩍဨ/ி㒔኱Ꮫࠒୖ⏣ၿᘯ㹙㹼2023/04/30㹛
࣭ࠑᏛእ◊✲༠ຊᩍဨ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒୖ⏣ၿᘯ㹙2023/05/01㹼㹛໭኱ゐ፹࢔ࣛ࢖࢔ࣥࢫࣘࢽࢵࢺ ࠑࣘࢽࢵࢺ㛗/ᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᏛෆ◊✲༠ຊᩍဨ/㎰Ꮫ◊✲㝔ᩍᤵࠒ᳃᫓ⱥ࣭
ࠑᏛෆ◊✲༠ຊᩍဨ/⌮Ꮫ◊✲㝔ᩍᤵࠒ⃝ᮧṇஓ㹙2023/05/01㹼㹛/Ṋḟᚭஓ࣭ࠑᏛෆ◊✲༠ຊᩍဨ/ᕤᏛ◊✲㝔ᩍᤵࠒᛅỌΎ἞㹙2023/05/01㹼㹛/ᖜᓮᾈᶞ/ྥ஭⤀࣭ࠑᏛෆ◊✲༠ຊᩍဨ/ᕤᏛ◊✲㝔෸ᩍᤵࠒᆏཱྀ⣖ྐ࣭ࠑᏛෆ◊✲༠ຊᩍဨ/⸆Ꮫ◊✲㝔ᩍᤵࠒబ⸨⨾ὒ㹙2023/05/01㹼㹛࣭ࠑᏛෆ◊✲༠ຊᩍဨ/ᆅ⌫⎔ቃ⛉Ꮫ◊✲㝔ᩍᤵࠒᑠすඞ᫂/⚄㇂⿱୍
᪂ᨺᑕග※ゐ፹ィ ⛉Ꮫࣘࢽࢵࢺ ࠑࣘࢽࢵࢺ㛗/ᩍᤵࠒᮅ಴Ύ㧘࣭ࠑᩍᤵࠒΎỈ◊୍/⚟ᒸ῟/୰ᓥΎ㝯/㧘ⲡᮌ㐩࣭ࠑ෸ᩍᤵࠒྂᕝ᳃ஓ㹙㹼2023/04/30㹛࣭ࠑຓᩍࠒ㫽ᒇᑿ㝯
㹙㹼2023/10/31㹛࣭ࠑ෸ᩍᤵࠒ㫽ᒇᑿ㝯㹙2023/11/01㹼㹛࣭ࠑຓᩍࠒAbhijit SHROTRIࠑᐈဨᩍᤵ/ᮾ໭኱Ꮫࠒᮧᯇ῟ྖ/すᇼ㯞⾰Ꮚ/㧘ᶫᖾ⏕࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࣘࢽࢵࢺࠑࣘࢽࢵࢺ㛗/ᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᩍᤵࠒΎỈ◊୍/㧘ⲡᮌ㐩࣭ࠑຓᩍࠒ㫽ᒇᑿ㝯㹙㹼2023/10/31㹛࣭ࠑ෸ᩍᤵࠒ㫽ᒇᑿ㝯㹙2023/11/01㹼㹛࣭ࠑᐈဨᩍᤵ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒ▮⏣㝧࣭ࠑᏛෆ◊✲༠ຊᩍဨ/⌮Ꮫ◊✲㝔ᩍᤵࠒ㧘ᶫၨ௓࣭ࠑி㒔኱Ꮫ≉௵ᩍᤵࠒ℧ᕝ୍Ꮫ
࢔࢖ࢩࣥ໭኱R㸤Dࣛ࣎ࣘࢽࢵࢺ ࠑࣘࢽࢵࢺ㛗/ᩍᤵࠒ⚟ᒸ῟࣭ࠑᩍᤵࠒΎỈ◊୍/୰ᓥΎ㝯࣭ࠑຓᩍࠒ㫽ᒇᑿ㝯㹙㹼
2023/10/31㹛࣭ࠑ෸ᩍᤵࠒ㫽ᒇᑿ㝯㹙2023/11/01㹼㹛࣭ࠑຓᩍࠒAbhijit SHROTRIࠑᏛෆ◊✲༠ຊᩍဨ/㎰Ꮫ◊✲㝔ᩍᤵࠒ㈗ᓥ♸἞࣭ࠑᏛෆ◊✲༠ຊᩍဨ/ᕤᏛ◊✲㝔෸ᩍᤵࠒ⏣ᓥ೺ḟ࣭ࠑᣍ࡬࠸ᩍဨ/࢖࣒ࣛࢪࣕࣃࣥᰴᘧ఍♫ࠒᴮཎ┿஧࣭ࠑᣍ࡬࠸ᩍဨ/ᰴᘧ఍♫࢔࢖ࢩࣥࠒ㧗㔝୍ྐ‫✲◊ڦ‬ᨭ᥼ᢏ⾡㒊ࢹ࣮ࢱ㥑ືᆺゐ፹◊✲ࢡࣛࢫࢱ࣮㸺ᒎ㛤ᆺ㸼ࠑ࣮ࣜࢲ࣮
/ຓᩍࠒ㫽ᒇᑿ㝯㹙㹼2023/10/31㹛࣭ࠑ࣮ࣜࢲ࣮/෸ᩍᤵࠒ㫽ᒇ ᑿ 㝯 㹙 2023/11/01 㹼 㹛࣭ࠑ Ꮫ እ ◊ ✲ ༠ ຊ ᩍ ဨ /Delft
University of Technology㸦࢜ࣛࣥࢲ㸧
ࠒᾆᕝ⠜࣭
ࠑᏛእ◊✲
༠ຊᩍဨ/Paul Scherrer Institut㸦ࢫ࢖ࢫ㸧
ࠒDavide FERRIࠑᏛእ◊✲༠ຊᩍဨ/⚄ዉᕝ኱Ꮫࠒ▼ᕝ⌮ྐ࣭ࠑᏛእ◊✲༠ຊᩍဨ/៞᠕⩏ሿ኱Ꮫࠒ㇏ᓥ㑈ࠑ⌜㛗ࠒ▼ᕝ຾ஂ

ኳ↛Ⅳ⣲㈨※ά⏝◊✲ࢡࣛࢫࢱ࣮㸺ᒎ㛤ᆺ㸼ࠑ࣮ࣜࢲ࣮
/෸ᩍᤵࠒⳢ἟Ꮫྐ㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ
/ᮾிᕤᴗ኱Ꮫࠒ໭㔝ᨻ᫂㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠
ຊᩍဨ/኱㜰኱Ꮫࠒ᳃ᾈு㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠
ຊᩍဨ/ᮾ໭኱Ꮫࠒຍ⸨ⱥᶞ㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/㫽ྲྀ኱Ꮫࠒ㔝ୖᩄᮦ㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/ᮾிᕤᴗ኱Ꮫࠒ㔝ᮧ῟Ꮚ㹙2023/06/01㹼㹛ࠑ◊✲ᨭ᥼᥎㐍ဨࠒᚋ⸨ឡ࣭
ࠑ≉ᐃᑓ㛛⫋ဨࠒஂಖ⏣ள⨾‫ڦ‬㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮
ࣇࣜࢵࢶ࣭ࣁ࣮ࣂ࣮◊✲ᡤࣘࢽࢵࢺ ࠑࣘࢽࢵࢺ㛗/ᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᩍᤵࠒᮅ಴Ύ㧘࣭ࠑᐈဨᩍᤵ/Fritz Haber
Institute of the Max Planck Society ࠒ Hans-Joachim
FREUND/Matthias SCHEFFLERࠑᐈဨ෸ᩍᤵ/ศᏊ⛉Ꮫ◊✲ᡤࠒ⇃㇂ᓫ
Ꮫ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ࣘࢽࢵࢺ ࠑࣘࢽࢵࢺ㛗ᩍᤵࠒ୰
㔝⎔࣭ࠑᩍᤵࠒᮅ಴Ύ㧘㧘ⲡᮌ㐩㛗㇂ᕝ῟ஓ୰ᓥΎ㝯⚟ᒸ῟ΎỈ◊୍ᾆཱྀ኱㍜➨୍◊✲ᶵჾ㛤Ⓨ⌜ࠑᢏ⾡୺௵ࠒ㛗㇂ᕝ㈗ᙪ
➨஧◊✲ᶵჾ㛤Ⓨ⌜ ࠑᢏ⾡ᑓ㛛⫋ဨࠒྥ஭ៅ࿃࣭ࠑᢏ⾡୺௵ࠒᕝᮧ⿱௓
◊✲ᶵჾ⟶⌮⌜ࠑᢏ⾡୺௵ࠒᒣᓊኴᖹ

‫ڦ‬ᡤ㛗ᐊ

‫ڦ‬໭࢟ࣕࣥࣃࢫྜྠ஦ົ㒊ࠑ஦ົ㛗ࠒᑠ⏣ษ࿴༤⥲ົᢸᙜ ࠑಀ㛗ࠒᒾ㒊ࡶࡺࡳ࣭ࠑ୺௵ࠒᩔ㈡༓ెᏊ࣭
ࠑಀဨࠒ἟಴᫂⣪⨾/ᑠཎᜨ⨾⌮/ఀ⸨᮶⨾/ᯇᆏ▱㔛/஬༑ᔒౡᏊ࣭ࠑ஦ົ⿵బဨࠒ㥖஭ிᏊ/⳥ᆅ஽㹙㹼2023/12/31㹛/୰ᶫ⏤㤶㔛㹙2024/01/01㹼2024/01/31㹛
◊✲༠ຊᢸᙜ ࠑಀ㛗ࠒྜྷἨ⥤࣭ࠑ୺௵ࠒᒸᆏ┤ᐶ࣭ࠑ஦ົ⿵ຓဨࠒ㉥ሯṇカ࣭ࠑ஦ົ⿵బဨࠒᑠᯘ᲍Ụ࣭ࠑ◊✲ᨭ᥼᥎㐍ဨࠒ኱⁪ᕼᚿᏊ఍ィᢸᙜ ࠑಀ㛗ࠒᲚᰤ἞/㉺ᬛ஽࣭ࠑಀဨࠒᕷཎ◁▱㹙㹼
2023/04/17㹛/୰⃝㯇ⰼ/஧ࣀୖ㝧ኴ㹙㹼2023/06/30㹛/ᴮᮏ㯞ᙬ㹙2023/07/01㹼㹛/➉ෆࡋࡎ࠿/㕥ᮌ᱈⳹࣭ࠑ஦ົ⿵బဨ ࠒ ᒸ ෆ ၨ Ꮚ / ྜྷ ᮧ ∾ Ꮚ 㹙 㹼 2023/08/31 㹛 / 㛗 ᓥ ዉ ⨾㹙2023/09/01㹼㹛/ᑠᯘ㯞⣖Ꮚ࣭ࠑ◊✲ᨭ᥼᥎㐍ဨࠒἙᮧክ
஀໭࢟ࣕࣥࣃࢫᅗ᭩ᐊࠑಀ㛗ࠒᖹ⏣ᰤኵ‫ە‬ᖺሗ ࣭◊✲ᡤ⦅5⟶⌮㐠Ⴀ ᮏ◊✲ᡤࡣゐ፹⛉Ꮫ࡟㛵ࡍࡿᡃࡀᅜࡢ◊✲ࡢ୰ᚰ࡜ࡋ
࡚㸪ඹྠ฼⏝࣭ඹྠ◊✲ࢆ᥎㐍ࡋ࡚࠸ࡿ㸬⌧ᅾ㸪ᩍᤵ఍ࢆ᭱㧗ពᛮỴᐃᶵ㛵࡜ࡋ࡚࠸ࡿ㸬ᅜෆእࡢࢥ࣑ࣗࢽࢸ࢕ࡢព
ぢࢆ㞟⣙ࡋ㸪◊✲ᡤࡢ⟶⌮㐠Ⴀ࣭㐠Ⴀィ⏬࣭ே஦࡟ຓゝࢆ⾜࠺㐠Ⴀ༠㆟఍㸪◊✲ᡤࡢάື࡟ᑐࡋ࡚㸪ᖺሗࢆࡶ࡜࡟㸪ẖᖺホ౯࡜⮬ᕫⅬ᳨ࢆ⾜࠺ホ౯ጤဨ఍ࡀタ⨨ࡉࢀ㸪ᡤ㛗࡟ᑐࡋ࡚㸪㐺ษ࡞ࢥ࣓ࣥࢺࢆࡍࡿࡇ࡜࡛㸪㛤࠿ࢀࡓゐ፹⛉Ꮫ◊✲ᣐⅬࢆ┠ᣦࡋ࡚࠸ࡿ㸬 ࡇ࠺ࡋࡓእ㒊ࡶྵࡵࡓពぢࡣᡤ㛗࡟㞟⣙ࡋ㸪ᩍᤵ఍࡟ࣇ࢕࣮ࢻࣂࢵࢡࡍࡿ㸬ᐇ㝿࡟⟶⌮㐠Ⴀࢆࡍࡿ⤌⧊࡜ࡋ࡚ࡣ㸪➨୍㸦ฟ∧ᗈሗ㸧➨஧㸦⎔ቃᏳ඲㸧࠾ࡼࡧ➨୕㸦ィ⏬
⟇ᐃ࣭ண⟬㸧ࡢ୕ᖖ⨨ጤဨ఍ࡀ࠾࠿ࢀ࡚࠸ࡿ㸬ࡲࡓ㸪እ㒊࡜ࡢ㐃ᦠࢆ᥎㐍ࡍࡿࡓࡵࡢ㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮ࡀ
࠶ࡿ㸬ࡉࡽ࡟෸ᩍᤵࢆ୰ᚰ࡜ࡋ࡚άືࡍࡿࢱ࣮ࢤࢵࢺ◊✲㒊ࡢ఍㆟ࡶᡤ㛗ࡀᣦ᥹ࡋ㸪ⱝᡭேᮦࡀά㌍ࡋࡸࡍ࠸⎔ቃᙧᡂ࡟ᑾຊࡋ࡚࠸ࡿ㸬ᩍᤵ఍ᡤ㛗      ᖖ⨨ጤဨ఍       ➨୍ᖖ⨨ጤဨ఍๪ᡤ㛗    ➨஧ᖖ⨨ጤဨ఍       ➨୕ᖖ⨨ጤဨ఍      㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮㛗         ࣘࢽࢵࢺ㐃⤡఍㆟      ࢱ࣮ࢤࢵࢺ◊✲㒊఍㆟㐠Ⴀ༠㆟఍  ホ౯ጤဨ఍

‫ڦ‬ᩍᤵ఍
ᮅ಴Ύ㧘㹙2015/10/01㹼㹛㛗㇂ᕝ῟ஓ㹙2015/10/01㹼㹛⚟ᒸ
῟㹙2015/10/01 㹼㹛ΎỈ◊୍㹙 2015/10/01 㹼㹛ᾆཱྀ኱㍜
㹙 2020/11/01 㹼 㹛 ୰ 㔝 ⎔ 㹙 2015/10/01 㹼 㹛 ୰ ᓥ Ύ 㝯㹙2022/04/01㹼㹛㧘ⲡᮌ㐩㹙2023/04/01㹼㹛‫ڦ‬㐠Ⴀ༠㆟఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ࠒΎỈ◊୍ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒ⚟ᒸ῟㹙2022/04/01㹼2024/03/31㹛ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒᾆ
ཱྀ኱㍜㹙2022/04/01㹼2024/03/31㹛
ࠑᆅ⌫⎔ቃ⛉Ꮫ◊✲㝔ᩍᤵࠒᑠすඞ᫂㹙2022/04/01㹼2024/03/31㹛
ࠑ⌮Ꮫ◊✲㝔ᩍᤵࠒṊḟᚭஓ㹙2022/04/01㹼2024/03/31㹛
ࠑ⸆Ꮫ◊✲㝔ᩍᤵࠒబ⸨⨾ὒ㹙2023/04/01㹼2024/03/31㹛
ࠑ㎰Ꮫ◊✲㝔ᩍᤵࠒ᳃᫓
ⱥ㹙2022/04/01㹼2024/03/31㹛
ࠑᕤᏛ◊✲㝔ᩍᤵࠒᛅỌΎ἞㹙2023/04/01㹼2024/03/31㹛ࠑᕤᏛ◊✲㝔ᩍᤵࠒᰘᒣ⎔ᶞ
㹙2022/04/01㹼2024/03/31㹛
ࠑ஑ᕞ኱Ꮫඛᑟ≀㉁໬Ꮫ◊✲ᡤᩍᤵࠒྜྷ⃝୍ᡂ㹙2022/04/01㹼2024/03/31㹛
ࠑி㒔኱Ꮫྡ㄃
ᩍᤵࠒỤཱྀᾈ୍㹙2022/04/01㹼2024/03/31㹛
ࠑி㒔኱Ꮫ኱Ꮫ㝔 ⸆ Ꮫ ◊ ✲ ⛉ ≉ ௵ ᩍ ᤵ ࠒ ୸ ᒸ ၨ ஧ 㹙 2022/04/01 㹼
2024/03/31㹛
ࠑྡྂᒇ኱Ꮫ≀㉁⛉Ꮫᅜ㝿◊✲ࢭࣥࢱ࣮ᩍᤵࠒ
၏⨾ὠᮌ㹙2022/04/01㹼2024/03/31㹛
ࠑᮾி኱Ꮫ≉ูᩍᤵ࣭ಙ ᕞ ኱ Ꮫ ≉ ู ≉ ௵ ᩍ ᤵ ࠒ ᇽ ච ୍ ᡂ 㹙 2022/04/01 㹼
2024/03/31㹛
ࠑ஑ᕞ኱Ꮫ࣮࢝࣎ࣥࢽ࣮ࣗࢺ࣭࢚ࣛࣝࢿࣝࢠ࣮
ᅜ㝿◊✲ᡤ 㝃ᒓ୕஭໬Ꮫ࣮࢝࣎ࣥࢽ࣮ࣗࢺࣛࣝ◊✲ࢭࣥࢱ࣮≉௵ᩍᤵࠒ୰ᮧ₶ඣ㹙2022/04/01㹼2024/03/31㹛
ࠑ୕⳻ࢣ࣑࢝ࣝᰴᘧ఍♫Science & Innovation Center ࢚ࢢࢮࢡࢸ࢕ࣈࣇ࢙࣮ࣟࠒ℩ᡞᒣ஽㹙2022/04/01㹼2024/03/31㹛
ࠑᮾ

6໭኱Ꮫ๪⌮஦ᅜ㝿ᨺᑕග࢖ࣀ࣮࣋ࢩ࣭ࣙࣥࢫ࣐࣮ࢺ◊✲ࢭࣥࢱ࣮㛗ࠒᮧᯇ῟ྖ㹙2022/04/01㹼2024/03/31㹛ࠑ㸦ᰴ㸧㇏⏣୰ኸ◊✲ᡤࣅࣚࣥࢻ㹖◊✲㒊㛛⌮஦ࠒ✄ᇉఙ஧㹙2022/04/01
㹼2024/03/31㹛‫ཷڦ‬ク◊✲➼ཷධࢀᑂᰝጤဨ఍
ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ࠒΎỈ◊୍ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒᾆ
ཱྀ኱㍜㹙2021/10/01㹼2023/09/30㹛
ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒ୰ᓥΎ㝯㹙2023/10/01㹼2025/09/30㹛
ࠑ⌮Ꮫ◊✲㝔ᩍᤵࠒṊḟᚭஓ㹙2017/04/01㹼2024/03/31㹛
ࠑᕤᏛ◊✲㝔ᩍᤵࠒᛅỌΎ἞㹙2023/04/01㹼2024/03/31㹛
ࠑᆅ⌫⎔ቃ⛉Ꮫ◊✲㝔ᩍᤵࠒᑠすඞ᫂㹙2017/10/01㹼2023/09/30㹛
ࠑᆅ⌫⎔ቃ⛉Ꮫ◊✲㝔ᩍᤵࠒ⚄㇂⿱୍㹙2023/10/01㹼2025/09/30㹛

‫ڦ‬ホ౯ጤဨ఍
ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ࠒΎỈ◊୍ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒ㛗㇂ᕝ῟ஓࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒᮅ಴Ύ㧘ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒ㧘ⲡᮌ㐩ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒ୰ᓥΎ㝯ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒ⚟ᒸ῟ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒᾆཱྀ኱㍜ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒ୰㔝⎔ࠑி㒔኱Ꮫྡ㄃ᩍᤵࠒỤཱྀᾈ୍㹙2018/04/01㹼2024/03/31㹛
ࠑ⸆Ꮫ◊✲㝔ᩍᤵࠒబ⸨⨾ὒ㹙2023/04/01㹼2024/03/31㹛ࠑ㎰Ꮫ◊✲㝔ᩍᤵࠒ᳃᫓ⱥ
㹙2017/10/01㹼2024/03/31㹛ࠑᕤᏛ◊✲㝔ᩍᤵࠒᰘᒣ⎔ᶞ
㹙2017/10/01㹼2024/03/31㹛
ࠑᮾி኱Ꮫ≉ูᩍᤵ࣭ಙᕞ኱Ꮫ
≉ู≉௵ᩍᤵࠒᇽච୍ᡂ㹙2018/04/01㹼2024/03/31㹛

‫ڦ‬ᖖ⨨ጤဨ఍
➨୍ᖖ⨨ጤဨ఍ ࠑᩍᤵࠒᮅ಴Ύ㧘㸦ጤဨ㛗㸧ࠑᩍᤵࠒ㛗㇂ᕝ῟ஓ㸦๪ጤဨ㛗㸧ࠑᩍᤵࠒ㧘ⲡᮌ㐩ࠑ෸ᩍᤵࠒⳢ἟
Ꮫྐࠑᩍᤵࠒ⚟ᒸ῟ࠑ෸ᩍᤵࠒྂᕝ᳃ஓࠑᩍᤵࠒᾆཱྀ኱
㍜ࠑᩍᤵࠒ୰㔝⎔ࠑᢏ⾡ᑓ㛛⫋ဨࠒᒣᓊኴᖹࠑ≉ᐃᑓ㛛⫋ဨࠒஂಖ⏣ள⨾➨஧ᖖ⨨ጤဨ఍ ࠑᩍᤵࠒ୰ᓥΎ㝯㸦ጤဨ㛗㸧ࠑᩍᤵࠒ㧘ⲡᮌ㐩㸦๪ጤဨ㛗㸧ࠑᩍᤵࠒ㛗㇂ᕝ῟ஓࠑᩍᤵࠒᮅ಴Ύ
㧘ࠑຓᩍࠒ኱㡲㈡㑈ửࠑຓᩍࠒ6+5275,$%+,-,7ࠑຓᩍࠒ㫽ᒇᑿ㝯ࠑᩍᤵࠒᾆཱྀ኱㍜ࠑᩍᤵࠒ୰㔝⎔ࠑᢏ⾡ᑓ㛛⫋ဨࠒ▼ᕝ຾ஂ
➨୕ᖖ⨨ጤဨ఍ ࠑᩍᤵࠒ୰㔝⎔㸦ጤဨ㛗㸧ࠑᩍᤵࠒ⚟ᒸ῟㸦๪ጤဨ㛗㸧
ࠑᩍᤵࠒ㛗㇂ᕝ῟ஓࠑᩍᤵࠒᮅ಴Ύ㧘ࠑᩍᤵࠒ㧘ⲡᮌ㐩ࠑᩍᤵࠒ୰ᓥΎ㝯ࠑᩍᤵࠒΎỈ◊୍ࠑᩍᤵࠒ
ᾆཱྀ኱㍜‫✲◊ڦ‬ဨ࣭኱Ꮫ㝔⏕࡞࡝ࡢཷධࢀ ᮏ◊✲ᡤ࡛ࡣ㸪◊✲ဨཬࡧእᅜே◊✲ဨࡢཷධࢀ࡟㛵ࡍࡿෆつࢆᐃࡵ㸪ከᩘࡢᅜෆእࡢ◊✲ဨࢆཷධࢀ㸪ᮏ◊✲ᡤᩍဨ࡜ࡢඹྠ◊✲ࢆᐇ᪋ࡍࡿ࡜࡜ࡶ࡟㸪Ꮫෆ࡟࠾࠸࡚ࡣ㸪኱Ꮫ㝔ᩍ⫱࡟ࡶཧ⏬ࡋከᩘࡢᏛ⏕ࢆཷධࢀᣦᑟࢆ⾜ࡗ࡚࠸ࡿ㸬◊✲ဨ 㸦1㸧ෆᆅ◊✲ဨ㸪⚾Ꮫ◊ಟဨ㸪ᑓಟᏛᰯ◊ಟဨ㸪බ❧኱Ꮫ◊ಟဨཬࡧཷク◊✲ဨ➼ࡢไᗘ࡟ࡼࡾὴ㐵ࡉࢀࡿ◊✲⪅ 㸦2㸧ᅜ❧኱Ꮫἲே໭ᾏ㐨኱Ꮫඹྠ◊✲ྲྀᢅつ⛬࡟ࡼࡾཷධࢀࡿ◊✲⪅ 㸦3㸧᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ࡟᥇⏝ࡢ◊✲⪅ 㸦4㸧ᮏᏛཪࡣ௚኱Ꮫࢆ㏥⫋ࡋࡓᩍဨཬࡧ௻ᴗ➼࡟࠾࠸࡚ඃࢀࡓ◊✲ᴗ⦼ࢆ᭷ࡋᙜヱ௻ᴗ➼ࢆ
㏥⫋ࡋࡓ◊✲⪅࡛㸪ᮏ◊✲ᡤࡢ◊✲ࡢ᥎㐍ᨭ᥼ࢆ┠ⓗ࡜ࡋ࡚ཷධࢀࡿ⪅ 㸦5㸧➇தⓗ◊✲㈨㔠࡟ࡼࡾཷධࢀࡿ◊✲⪅(㠀ṇつ⫋ဨ࡜ࡋ࡚㞠⏝ࡍࡿሙྜࢆ㝖ࡃ) 㸦6㸧ᮏᏛࡢ኱ᖺሗ࣭◊✲ᡤ⦅‫ە‬Ꮫ㝔༤ኈㄢ⛬ࢆಟ஢ᚋ㸪1ᖺᮍ‶࡛ṇつࡢ⫋ࢆ᭷ࡋ࡞࠸⪅
㸦7㸧௚኱Ꮫࡢ኱Ꮫ㝔⏕(≉ู◊✲Ꮫ⏕➼ࡢṇつᏛ⏕ࢆ㝖ࡃ) 㸦8㸧ࡑࡢ௚ᮏ◊✲ᡤ࡟࠾࠸࡚◊✲➼ࢆ⾜࠺ࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚ཷධࢀࡿ◊✲⪅㈈ົ

እᅜே◊✲ဨ 㸦1㸧ᨻᗓ࡜እᅜᨻᗓ㛫ࡢ༠ᐃ➼࡟ࡼࡾᣍ࡬࠸ࡢእᅜே◊✲⪅ 㸦2㸧᪥ᮏᏛ⾡᣺⯆఍㸪ᅜ㝿஺ὶᇶ㔠㸪ᅜ㝿༠ຊᶵᵓ➼ࡢබⓗᶵ㛵࡟ࡼࡾᣍ࡬࠸ࡢእᅜே◊✲⪅ 㸦3㸧ᮏᏛ࡟࠾ࡅࡿᅜ㝿஺ὶࡢࡓࡵࡢᇶ㔠➼࡟ࡼࡾᣍ࡬࠸ࡢእᅜே◊✲⪅ 㸦4㸧ࡑࡢ௚ᮏ◊✲ᡤ࡟࠾࠸࡚◊✲➼ࢆ⾜࠺ࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚ゼࢀࡲࡓࡣᣍ࡬࠸ࡍࡿእᅜே
◊✲⪅ࠓ2023ᖺᗘࠔ 㸦๓ᖺẚ㸸1.186/2003ᖺᗘẚ㸸2.413㸧
㐠Ⴀ㈝஺௜㔠
96,427༓෇⛉Ꮫ◊✲㈝⿵ຓ㔠
120,175༓෇㛫᥋⤒㈝㸦⛉Ꮫ◊✲㈝⿵ຓ㔠㸧
13,399༓෇⏘Ꮫ㐃ᦠ⤒㈝
8,671༓෇
ཷク◊✲
224,802༓෇Ẹ㛫➼࡜ࡢඹྠ◊✲
73,794༓෇ዡᏛᐤ௜㔠
3,430༓෇
ࡑࡢ௚◊✲ຓᡂ
2,175༓෇㛫᥋⤒㈝㸦ࡑࡢ௚◊✲ຓᡂ㸧
19,521༓෇
ྜィ
562,394༓෇㹙⛉Ꮫ◊✲㈝⿵ຓ㔠⥲஺௜㢠㸦௚ᶵ㛵࡬ࡢศᢸ㔠㸪㛫᥋⤒㈝㸦30㸣㸧ࢆྵࡴ㸧ࡢෆヂ㸻ᇶ┙◊✲㸦A㸧㸸1௳/ᇶ┙◊✲
㸦C㸧㸸3௳/ᣮᡓⓗⴌⱆ◊✲㸸7௳/ᣮᡓⓗ◊✲㸦㛤ᣅ㸧
㸸1௳/ⱝᡭ◊✲㸸2௳/ⱝᡭ◊✲㸦A㸧
㸸2௳/ⱝᡭ◊✲㸦B㸧
㸸1௳/ዡບ◊✲㸸1௳/ྜィ7௳࣭115,970 ༓෇㹛኱Ꮫ㝔⏕࣭Ꮫ㒊Ꮫ⏕ ᇶ♏◊✲⣔ࡢྛ◊✲㒊㛛࡟࠾࠸࡚ཷ
ࡅධࢀ࡚࠸ࡿ㸬ᡤᒓ◊✲⛉➼ࡣ௨ୗࡢ࡜࠾ࡾ㸬኱Ꮫ㝔ᕤᏛ㝔/ᕤᏛ㒊㸸 ゐ፹⾲㠃◊✲㒊㛛㸦ᮅ಴◊✲ᐊ㸧኱Ꮫ㝔⥲ྜ໬Ꮫ㝔/ᕤᏛ㒊㸸 ゐ፹ᮦᩱ◊✲㒊㛛㸦ΎỈ◊✲ᐊ㸧኱Ꮫ㝔⎔ቃ⛉Ꮫ㝔㸸 ゐ፹཯ᛂ◊✲㒊㛛㸦୰ᓥ◊✲ᐊ㸧࣭ゐ፹ᵓ㐀◊✲㒊㛛㸦㧘ⲡᮌ◊✲ᐊ㸧኱Ꮫ㝔⏕࿨⛉Ꮫ㝔/⸆Ꮫ㒊㸸 ศᏊゐ፹◊✲㒊㛛㸦ᾆཱྀ◊✲ᐊ㸧኱Ꮫ㝔⥲ྜ໬Ꮫ㝔/⌮Ꮫ㒊: ≀㉁ኚ᥮◊✲㒊㛛㸦⚟ᒸ◊✲ᐊ㸧࣭㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛㸦୰㔝◊✲ᐊ㸧࣭ゐ፹⌮ㄽ◊✲㒊㛛㸦㛗㇂ᕝ◊✲ᐊ㸧ཷධ≧ἣ㸦࠿ࡗࡇෆࡣ␃Ꮫ⏕࡛ෆᩘ㸧
ࠓ2023ᖺᗘࠔ◊✲ဨ6ྡ࣭እᅜே◊✲ဨ17ྡ࣭኱Ꮫ㝔⏕34㸦20㸧ྡ࣭Ꮫ㒊Ꮫ⏕13ྡ࣭◊✲⏕8㸦4㸧ྡ‫ڦ‬እ㒊㈨㔠ࢆྵࡴ2023ᖺᗘࡢண⟬᪋タ‫ڦ‬ᡤᅾᆅ ᪧゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࡣ㸪2003ᖺ10᭶ࡲ࡛㸪⛣㌿㏵୰ࡢ୰㛫ẁ㝵ࢆࡢࡒࡁ㸪໭ᾏ㐨኱Ꮫ༡࢟ࣕࣥࣃࢫෆࡢゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮Ჷ࡟ᡤᅾ㸦⌧ᅾࡣ⌮Ꮫ㒊8ྕᲷ㸧㸬2003ᖺ11᭶ࡼࡾ໭ᾏ㐨኱Ꮫᵓෆ໭࢟ࣕࣥࣃࢫෆࡢ๰ᡂ⛉Ꮫ◊✲Ჷ
㸦001-0021 ᮐᖠᕷ໭༊໭21᮲す10୎┠㸧࡟⛣ࡾ㸪ゐ፹⛉Ꮫ◊✲ᡤ࡟ᨵ⤌ࡋࡓᚋࡶྠᆅ࡟ᡤᅾࡍࡿ㸬‫ڦ‬ᘓ≀2,435ᖹ᪉࣓࣮ࢺࣝ㸦໭ᾏ㐨኱Ꮫ๰ᡂ⛉Ꮫ◊✲Ჷෆࡢ༨
᭷㠃✚㸧

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‫ە‬ᖺሗ ࣭◊✲ᡤ⦅7ᩍ⫱/ேᮦ⫱ᡂ/♫఍㐃ᦠ ゐ፹⛉Ꮫ◊✲ᡤࡣ◊✲ᶵ㛵࡛࠶ࡿࡀ㸪ྛ◊✲㒊㛛ࡀᒓࡍࡿᕤᏛ㝔㸪⎔ቃ⛉Ꮫ㝔㸪⥲ྜ໬Ꮫ㝔࠾ࡼࡧ⏕࿨⛉Ꮫ㝔࡟࠾࠸࡚኱Ꮫ㝔ᩍ⫱ࢆ⾜࠺࡜࡜ࡶ࡟㸪඲Ꮫᩍ⫱⛉┠࠾ࡼࡧ㛵㐃ࡍࡿᏛ㒊ࡢᑓ㛛⛉┠ࡢᢸᙜ㸪ゐ፹໬Ꮫ࡟㛵㐃ࡍࡿ◊✲఍ࡢ
ᐇ᪋ࢆ㏻ࡌᗈࡃᩍ⫱άືࢆ⾜ࡗ࡚࠸ࡿ㸬㸦ᢸᙜㅮ⩏࠾ࡼࡧᮏ◊✲ᡤ࡟ᡤᒓࡢᏛ⏕➼ࡢᏛ఩ᑂᰝ࡟ࡘ࠸࡚ࡣࠓಶே⦅ࠔ
ࢆཧ↷ࡉࢀࡓ࠸㸬㸧 ࡲࡓ㸪ࠕゐ፹⛉Ꮫ◊✲ᡤᾏእὴ㐵ไᗘࠖ࡟ࡼࡿ኱Ꮫ㝔⏕࡜ⱝᡭᩍဨࡢᾏእㅖእᅜ࡟࠾ࡅࡿ◊✲ࡢಁ㐍㸪ࠕゐ፹㧗➼
ᐇ㊶◊ಟࣉࣟࢢ࣒ࣛࠖ࡟ࡼࡿゐ፹ࢆᑓ㛛࡜ࡍࡿ◊✲⪅࣭Ꮫ⏕ࡢ࡯࠿㸪௻ᴗ㸪◊✲ᶵ㛵㸪኱Ꮫ㸪㧗ᰯ➼࡟ᡤᒓࡍࡿᚲࡎࡋࡶゐ፹ࢆᑓ㛛࡜ࡋ࡞࠸◊✲⪅㸪ᢏ⾡⪅㸪ᩍ⫱⪅࡟ᑐࡍࡿゐ፹◊✲ࡢ◊ಟᶵ఍ࡢᥦ౪㸪ࡉࡽ࡟㸪Ꮫ⏕஺ὶጤဨ఍࡟ࡼ
ࡿ◊✲ᐊࢆࡇ࠼ࡓࢭࣥࢱ࣮ෆࡢ஺ὶࢆࡍࡍࡵ࡚࠸ࡿ㸬‫ڦ‬㐍㊰≧ἣ ゐ፹⛉Ꮫ◊✲ᡤ㓄ᒓᏛ⏕ࡢ࠺ࡕ2023ᖺᗘಟ஢⪅ࡢ㐍㊰≧ἣࡣ௨ୗࡢ࡜࠾ࡾ㸬㐍㊰ಟኈ༤ኈ㐍Ꮫ኱Ꮫබⓗ◊✲ᶵ㛵
ᐁබᗇ
Ẹ㛫௻ᴗ
ࡑࡢ௚
ྜィ

༤ኈಟ஢
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3
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4
0
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ಟኈಟ஢
1
0
0
0
6
0
7

Ꮫ㒊༞ᴗ
7
0
0
1
1
0
9

‫ڦ‬ゐ፹໬Ꮫࡢࣇࣟࣥࢸ࢕࢔ ඲Ꮫᩍ⫱⛉┠㸦⥲ྜ⛉┠㸧ࡢࠕゐ፹໬Ꮫࡢࣇࣟࣥࢸ࢕࢔ࠖ
ࡣゐ፹⛉Ꮫ◊✲ᡤࡀᢸᙜࡋ㸪ᩍဨࡢ࠺ࡕ㸪ᩍᤵ࠾ࡼࡧ෸ᩍ
ᤵ඲ဨ࡟ࡼࡿ࣒࢜ࢽࣂࢫᙧᘧࡢㅮ⩏࠾ࡼࡧ᭱⤊ᅇࡢゐ፹⛉Ꮫ◊✲ᡤぢᏛ఍ࢆ⾜ࡗ࡚࠸ࡿ㸬ࢩࣛࣂࢫࢹ࣮ࢱ࡜ྛᅇࡢ
ㅮ⩏ᢸᙜࡣ௨ୗࡢ࡜࠾ࡾ㸬㛤ㅮ᪥㸸 ➨1Ꮫᮇ㔠᭙᪥➨5ᰯ᫬㸦16㸸30㹼18㸸30㸧ᩍᐊ㸸㧗➼ᩍ⫱᥎㐍ᶵᵓE301ᐊ
ཷㅮ⪅ᩘ㸸 25ே௨ୗ㈐௵ᩍဨ㸸ᾆཱྀ኱㍜࣮࣮࢟࣡ࢻ㸸 ゐ፹㸪໬Ꮫ≀㉁㸪⎔ቃ࡜࢚ࢿࣝࢠ࣮㸪ᣢ⥆ⓗ࡞Ⓨᒎᤵᴗࡢ┠ᶆ㸸 ゐ፹ࡣ㸪ࡑࢀ⮬㌟ࡣኚ໬ࡏࡎ࡟≉ᐃࡢ໬Ꮫ≀㉁ࡔࡅࡢ⏕ᡂࢆಁ㐍ࡋࡓࡾ㸪᭷ᐖࡸ᭷ẘࡢ໬Ꮫ≀㉁ࢆ↓ᐖ໬ࡍࡿࡇ࡜ࡀ࡛ࡁࡲࡍ㸬ゐ፹ࡣ௒ࡸ໬Ꮫࢆᨭ࠼ࡿࡶࡗ࡜ࡶ㔜せ࡞ᴫᛕࡢࡦ࡜ࡘ࡛࠶ࡾ㸪ᣢ⥆ⓗ࡞໬ᏛᕤᴗࡢⓎᒎࡢࡓࡵ࡟ࡣ୙ྍḞ࡞໬Ꮫ≀㉁࡛ࡍ㸬ࡲࡓḟୡ௦ࡢ࢚ࢿࣝࢠ࣮
ᇶ┙࡜⪃࠼ࡽࢀ࡚࠸ࡿỈ⣲ࡢ〇㐀ࡶゐ፹↓ࡃࡋ࡚ࡣ⪃࠼ࡽࢀࡲࡏࢇ㸬࢚ࢿࣝࢠ࣮ࢆ⏕ࡴ㐣⛬࡛ࡶゐ፹ࡣḞ࠿ࡏࡲࡏࢇ㸬ࡇࡢࡓࡵ㸪ୡ⣖ࡣゐ፹ࡢ᫬௦࡟࡞ࡿ࡜⪃࠼ࡽࢀ࡚࠸ࡲࡍ㸬ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮࡛ࡣ㸪ゐ፹࡟ࡼࡿ໬Ꮫ཯ᛂࡢ
ࡋࡃࡳࢆ᫂ࡽ࠿࡟ࡋࡓࡾ㸪᪂ࡋ࠸ゐ፹ࡢ㛤Ⓨࢆࡵࡊࡋ࡚࠸ࢁ࠸ࢁ࡞ゅᗘ࠿ࡽ◊✲ࢆ㐍ࡵ࡚࠸ࡲࡍ㸬ᮏㅮ⩏࡛ࡣ㸪ゐ፹ࡢ◊✲ࡢ᭱ඛ➃࡛ࡣ࡝ࡢࡼ࠺࡞ࡇ࡜⾜ࢃࢀ࡚࠸ࡿࡢ࠿㸪ᑗ᮶࡝ࡢࡼ࠺࡞ࡇ࡜ࡀᐇ⌧࡛ࡁࡿ࡜ᮇᚅࡉࢀ࡚࠸ࡿࡢ࠿ࢆ
ࡸࡉࡋࡃゎㄝࡋࡲࡍ㸬฿㐩┠ᶆ㸸 ゐ፹໬Ꮫࡢ᭱ඛ➃ࡢࢺࣆࢵࢡࢫࢆᏛࡪࡇ࡜ࢆ
㏻ࡌ࡚㸪ṇࡋ࠸≀㉁ほ࡟ࡶ࡜࡙࠸ࡓ⛉Ꮫⓗ࡞⪃࠼᪉ࢆ㌟࡟

8

ࡘࡅ㸪㈨※࡜࢚ࢿࣝࢠ࣮㸪⎔ቃ࡜໬Ꮫ≀㉁㸪♫఍ࡢ࠶ࡾ᪉
࡞࡝࡟ࡘ࠸࡚ࡢ⪃࠼᪉ࢆᏛࢇ࡛ࡶࡽ࠺ࡇ࡜ࢆ┠ᶆ࡜ࡋࡲࡍ㸬ᤵᴗィ⏬㸸ゐ፹ࡢᇶ♏࠿ࡽ⎔ቃゐ፹㸪⇞ᩱ㟁ụࡲ࡛ࡢ᭱᪂
ࡢᛂ⏝◊✲ࡲ࡛㸪ྛᩍဨࡀᣢࡕᅇࡾ࡛㸪᭱᪂ࡢࢺࣆࢵࢡࢆ
ㅮ⩏ࡋࡲࡍ㸬᭱⤊ᅇࡣ㸪໭࢟ࣕࣥࣃࢫ࡟࠶ࡿゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࡢぢᏛࢆ⾜࠸ࡲࡍ㸬‽ഛᏛ⩦㸦ண⩦࣭᚟⩦㸧➼ࡢෆᐜ࡜ศ㔞㸸 ᚟⩦ࢆවࡡ࡚ㄢ㢟࣏࣮ࣞࢺࢆฟࡍሙྜࡀ࠶ࡾࡲࡍ㸬ᡂ⦼ホ౯ࡢᇶ‽࡜᪉ἲ㸸 ฟᖍ≧ἣ࡜ྛᢸᙜᩍᐁ࠿ࡽฟࡉ
ࢀࡿㄢ㢟࡬ࡢ࣏࣮ࣞࢺ➼࡟ࡼࡾホ౯ࡋࡲࡍ㸬ഛ⪃㸸ㅮ⩏ࡣ⤫୍ࡋ࡚ᾮᬗࣉࣟࢪ࢙ࢡࢱ࣮ࢆ⏝࠸㸪ẖᅇㅮ⩏ࡢᴫせࢆ♧ࡍ㈨ᩱࢆ㓄௜ࡋࡲࡍ㸬ᤵᴗ࢔ࣥࢣ࣮ࢺホ౯㸦ᅇ⟅㸸ே᭱㧗㸧㸸ྛᅇࡢㅮ⩏㸸 ➨1ᅇ㸦2023/4/14㸧ᾆཱྀ኱㍜ࠕ࢞࢖ࢲࣥࢫ
࡜ศᏊࡢ࠿ࡓࡕࢆỴࡵࡿศᏊゐ፹࣭ࠖ➨2ᅇ㸦2023/4/22㸧ὸ㔝ᆂభࠕ᭷ᶵゐ፹ࢆ฼⏝ࡋࡓศᏊࡢྜᡂ࡜ほᐹ࣭ࠖ➨3ᅇ
㸦2023/4/28㸧ྂᕝ᳃ஓࠕ㔠ᒓゐ፹ࡢタィ࡜㛤Ⓨ࣭ࠖ➨4ᅇ
㸦2023/5/12㸧ᮅ಴Ύ㧘ࠕ⾲㠃཯ᛂࡢࢼࣀ࣐ࢵࣆࣥࢢ࣭ࠖ➨5ᅇ㸦2023/5/19㸧㧘ⲡᮌ㐩ࠕ㉮ᰝᆺࢺࣥࢿࣝ㢧ᚤ㙾㸸ཎᏊ࣭ศᏊࡢ┤᥋ほᐹ࡜ไᚚࠖ
࣭➨6ᅇ㸦2023/5/26㸧㣤⏣೺஧ࠕゐ፹཯ᛂࢆ⌮ゎࡍࡿࡓࡵࡢศ㔝ࢆ㉸࠼ࡓ⌮ㄽࡢ⼥ྜ࣭ࠖ➨7ᅇ
㸦2023/6/9㸧୰ᓥΎ㝯ࠕᅛయゐ፹࡟ࡼࡿࣂ࢖࣐࢜ࢫࡢ㈨※໬࣭ࠖ➨8ᅇ㸦2023/6/16㸧Ⳣ἟Ꮫྐࠕ㈨※ࢆ᭷ຠά⏝ࡍࡿࡓ
ࡵࡢゐ፹ᢏ⾡ࡢ㛤ᣅ࣭ࠖ➨9ᅇ㸦2023/6/23㸧⚟ᒸ῟ࠕ㔝࣭⳯ᯝ≀ࡢ㩭ᗘࢆಖࡘゐ፹ࡢ໬Ꮫ࣭ࠖ➨10ᅇ㸦2023/6/30㸧୰㔝⎔ࠕ㧗ศᏊࡢ❧యᵓ㐀࡜ᶵ⬟࣭ࠖ➨11ᅇ㸦2023/7/7㸧㛗㇂ᕝ῟ஓࠕ⌮ㄽ࣭ィ⟬໬Ꮫ࡟ࡼࡿゐ፹཯ᛂ◊✲࣭ࠖ➨12 ᅇ
㸦2023/7/14㸧ΎỈ◊୍ࠕ㔠ᒓࢼࣀ⢏Ꮚࡢゐ፹స⏝࣭ࠖ➨13
ᅇ㸦2023/7/21㸧ᏵᚿẎࠕࢡࣟࢫ࢝ࢵࣉࣜࣥࢢ཯ᛂ୰ࡢࣃࣛࢪ࣒࢘ゐ፹࣭ࠖ➨14ᅇ㸦2023/7/28㸧ᾆཱྀ኱㍜ࠕゐ፹⛉Ꮫ◊✲ᐊࡢぢᏛ㸦◊✲ᐊ⤂௓㸧࣭ࠖ➨15ᅇ㸦2023/8/1㸧ᾆཱྀ኱㍜ࠕゐ፹⛉Ꮫ◊✲ᐊࡢぢᏛ㸦኱Ꮫ㝔⏕࣭ⱝᡭ◊✲⪅࡜ࡢᑐヰ㸧ࠖ‫ڦ‬Principles of Catalytic Chemistry: Theory andApplication
୺ദ㸸Hokkaido Summer Institute㛤ㅮ᪥᫬㸸2023ᖺ7᭶26᪥㸦Ỉ㸧㹼8᭶1᪥㸦ⅆ㸧఍ሙ㸸࢜ࣥࣛ࢖ࣥ
ཷㅮⓏ㘓⪅ᩘ㸸21ྡᴫ␎㸸Hokkaido Summer Instituteࡣ㸪໭ᾏ㐨኱Ꮫ࡟ୡ⏺ࡢ➨୍⥺࡛ά㌍ࡍࡿඃࢀࡓᩍ⫱◊✲ᴗ⦼࣭άືṔࢆ᭷ࡍࡿ◊✲⪅ࢆᣍ⪸ࡋ㸪ᮏᏛᩍဨ࡜༠ാ࡛ᩍ⫱άືࢆᐇ᪋ࡍࡿࣉࣟࢢ
࣒࡛ࣛ࠶ࡿ㸬ᤵᴗࡣⱥㄒ࡛⾜ࢃࢀ㸪ᾏእࡢ኱Ꮫ࠿ࡽࡢཷㅮ
⏕ࡶཷࡅධࢀ࡚࠸ࡿ㸬௒ᖺᗘࡶ㸪ࡍ࡭࡚࢜ࣥࣛ࢖ࣥㅮ⩏࡜࡞ࡗࡓ㸬ᮏㅮ⩏࡛ࡣ㸪ゐ፹⛉Ꮫ◊✲ᡤࡢ㣤⏣೺஧෸ᩍᤵ࡟
ຍ࠼㸪Delft University of Technology࠿ࡽEvgeny A. PidkoẶ
ࢆ㸪The Chinese University of Hong Kong࠿ࡽYing Yeung
YeungẶࢆ㸪Uppsala University࠿ࡽMarcus LundbergẶࢆ㸪
Georgia Institute of Technology࠿ࡽCarsten SieversẶࢆᣍ⪸ࡋࡓ㸬ࡑࡋ࡚㸪ゐ፹ࡢ㟁Ꮚ≧ែ⌮ㄽ㸪㟁Ꮚㄽ࡟᰿ᕪࡋࡓゐ፹స⏝ᶵᵓ㸪ゐ፹ࡢタィ⌮ㄽ㸪ゐ፹཯ᛂࡢ㛤Ⓨ࡞࡝࡟㛵ࡋ࡚ゎㄝࡀ⾜ࢃࢀࡓ㸬ゐ፹ࡢཎ⌮ࡸᶵᵓࢆゎ᫂ࡍࡿࡓࡵࡢᡭ
ἲ࠿ࡽලయⓗ࡞ᆒ୍⣔࠾ࡼࡧ୙ᆒ୍⣔ゐ፹཯ᛂࡢ࣓࢝ࢽ
ࢬ࣒ࡸ㛤Ⓨ࡟ࡘ࠸࡚ࡲ࡛Ꮫࡪࡇ࡜ࡀ࡛ࡁࡿㅮ⩏࡜࡞ࡗࡓ㸬ᮏㅮ⩏ࡣ㸪Ꮫ⏕࡟࡜ࡗ࡚ゐ፹ࡢᇶ♏࠿ࡽᛂ⏝ࡲ࡛ࢆࣞࣅ࣮࡛ࣗࡁࡿⰋ࠸ᶵ఍࡜࡞ࡾ㸪㧗࠸ᩍ⫱ຠᯝࡀ࠶ࡗࡓ࡜ᮇ

ᖺሗ࣭◊✲ᡤ⦅‫ە‬ᚅ࡛ࡁࡿ㸬
ྛᅇࡢㅮ⩏㸸‫ۑ‬Dr. Ying Yeung Yeung (The Chinese Universityof Hong Kong): Different approaches of halogenation reactions
including halide substitution, electrophilic halogenation andradical halogenation/ Applications of halogenation reactions inthe synthesis of different building blocks, ‫ ۑ‬Dr. Evgeny A.
Pidko (Delft University of Technology): Computations,modeling and catalysis/ Chemical complexity and performance
metrics in catalysis, ‫ۑ‬Dr. Kenji Iida (Institute for Catalysis,
Hokkaido University): Basic of quantum mechanical method toinvestigate catalysis, ‫ ۑ‬Dr. Marcus Lundberg (Uppsala
University): Insights into molecular catalysts from X-ray
spectroscopy, ‫ ۑ‬Dr. Carsten Sievers (Georgia Institute ofTechnology ): Structure-performance relationships of zeolites incatalysis/ Fundamentals and opportunities of mechanocatalysis

17:30 ̽ 19:00 Break time (Dinner)
19:00 ̽ 20:30 Poster Presentation
20:30 ̽ Social gathering
September 1st (Fri.)
9:00 – 9:30 Special lecture 3(Prof. Dr. Masaki Matsui)
9:35 – 10:05 Special lecture 4(Prof. Dr. Abhijit Shrotri)
10:05 – 10:15 Break time
10:15 – 11:15 Oral presentation
10:15 – 10:30 Shinji Noguchi
10:30 – 10:45 Bon Leif Amalla
10:45 – 11:00 Tong Fang
11:00 – 11:15 Md. Menhazul Abedin
11:30 – 11:40 Closing session
11:40 – 12:40 Lunch time
14:50
Arrival at Hokkaido University‫ ڦ‬CSE Summer School and ALP International
Symposium୺ദ㸸CSE-ALP International Summer School ᐇ⾜ጤဨ఍ඹദ㸸ゐ፹⛉Ꮫ◊✲ᡤ㸪⥲ྜ໬Ꮫ㝔㸪≀㉁⛉Ꮫࣇࣟࣥࢸ࢕
࢔ࢆ㛤ᣅࡍࡿ Ambitious ࣮ࣜࢲ࣮⫱ᡂࣉࣟࢢ࣒ࣛ㸪ࣇࣟࣥࢸ࢕࢔໬Ꮫᩍ⫱◊✲ࢭࣥࢱ࣮㸪ᅜ㝿ඛ➃≀㉁⛉Ꮫ኱Ꮫ㝔㸪ࢫ࣐࣮ࢺ≀㉁⛉Ꮫࢆᣅࡃ࢔ࣥࣅࢩࣕࢫࣉࣟࢢ࣒ࣛ
᪥᫬㸸2023ᖺ8᭶31᪥㸦ᮌ㸧㹼9᭶1᪥㸦㔠㸧఍ሙ㸸⛛∗ูἨ ࡕࡗ࡫࣭ࡺ࠺㸤ࡺேᩘ㸸ᐇ⾜ጤဨ8ྡ㸪Ⓨ⾲⪅18ྡ㸦ᣍᚅㅮ₇4㸪୍⯡ཱྀ㢌4㸪
࣏ࢫࢱ࣮14௳㸧ͤཧຍⓏ㘓ຍ⪅26ྡࡢෆヂ:༤ኈㄢ⛬Ꮫ⏕11ྡ㸪ಟኈㄢ⛬Ꮫ⏕6ྡ㸪Ꮫ㒊⏕0ྡ㸪◊✲ဨ࣭ᩍဨ9ྡᴫ␎㸸ᮏ࢖࣋ࣥࢺࡣ⥲ྜ໬Ꮫ㝔㸦CSE㸧ࡢ༤ኈᏛ⏕࡟ࡼࡗ࡚⤌⧊ࡉࢀࡓᐇ⾜ጤဨ఍࡟ࡼࡾ௻⏬࣭㐠Ⴀࡉࢀࡿᅜ㝿ࢩ࣏ࣥࢪ࣒࢘࡜ࡋ࡚㸪⥲ྜ໬Ꮫ㝔ࡀタ❧ࡉࢀࡓ2010ᖺ࠿ࡽ⥅⥆ࡋ࡚ᐇ᪋ࡉࢀࡓ㸬ᙜึ㸪໭ᾏ㐨኱Ꮫࢢ࣮ࣟࣂࣝCOEࡢ༤ኈ
⫱ᡂࣉࣟࢢ࣒ࣛࡢ୍⎔࡜ࡋ࡚ᐇ᪋ࡉࢀࡓࡀ㸪2012ᖺࡢࢢ࣮ࣟࣂࣝCOE⤊஢࡟క࠸㸪⥲ྜ໬Ꮫ㝔ࡀ୺ദࡋ㸪ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮㸦⌧:ゐ፹⛉Ꮫ◊✲ᡤ㸧ࡀඹദࡍࡿᙧ࡛ࠕ⥲ྜ໬Ꮫ㝔 ኟࡢᏛᰯࠖࢆ⥅⥆ࡋࡓ㸬2013ᖺࡣྠᖺኟ࡟㛤ദࡉ
ࢀࡓISHHC-16㸦ᪧゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮୺ദ㸧ࡢ࣏ࢫࢺࢩ
࣏ࣥࢪ࣒࢘࡜ࡋ࡚ᐇ᪋ࡋࡓ㸬2019ᖺ࠿ࡽࡣ≀㉁⛉Ꮫࣇࣟࣥࢸ ࢕ ࢔ ࢆ 㛤 ᣅ ࡍ ࡿ Ambitious ࣜ ࣮ ࢲ ࣮ ⫱ ᡂ ࣉ ࣟ ࢢ ࣛ ࣒㸦ALP㸧࡛ᐇ᪋ࡉࢀ࡚ࡁࡓᅜ㝿ࢩ࣏ࣥࢪ࣒࢘࡜ྜྠ㛤ദࡋࡓ 㸬 ALP ⏕ ࡀ ຍ ධ ࡋ ࡑ ࢀ ࡟ క ࠸ 㸪 ྡ ⛠ ࢆ ࠕ CSE-ALPInternational Summer Schoolࠖ࡟ኚ᭦ࡋࡓ㸬2020㸪2021ᖺࡣ
ࢥࣟࢼࡢࣃࣥࢹ࣑ࢵࢡࡢࡓࡵ㸪᏶඲࢜ࣥࣛ࢖ࣥ㛤ദ࡛࠶ࡗࡓࡀ㸪2022ᖺࡣ㐠Ⴀጤဨ఍࡟ࢫ࣐࣮ࢺ≀㉁⛉Ꮫࢆᣅࡃ࢔ࣥ
ࣅࢩࣕࢫࣉࣟࢢ࣒ࣛ㸦SMatS㸧⏕ࡀຍࢃࡾ㸪ึࡢ⌧ᆅ࣭࢜ࣥࣛ࢖ࣥࣁ࢖ࣈࣜࢵࢻᙧᘧ࡛㛤ദࡋࡲࡋࡓ㸬2023ᖺࡣᐇ࡟
4ᖺࡪࡾ࡜࡞ࡿ⌧ᆅ㛤ദ࡟ࡇࡂࡘࡅ㸪Ἡࡲࡾ㎸ࡳ࡛ᐇ᪋ࡋ
ࡓ㸬ᙜ◊✲ᡤ࠿ࡽࡣᐑᓮ⋹ຓᩍࡀᩍဨഃᐇ⾜ጤဨ࡜ࡋ࡚ཧ
ຍࡋࡓ㸬ࣉࣟࢢ࣒ࣛ㸸
August 31st (Thu.)
12:20
Meet at the south entrance of entrance of
Hokkaido University Faculty of Engineering
12:30
Departure from Hokkaido University
14:30 ̽ 14:35 Opening Session
14:35 ̽ 15:05 Special lecture 1(Prof. Dr. Taiga Yurino)
15:10 ̽ 15:40 Special lecture 2(Prof. Dr. Wei Li)
16:00 ̽ 17:30 Recreation‫ە‬ᖺሗ ࣭◊✲ᡤ⦅


㞟ྜ෗┿

‫ڦ‬2023ᖺ໭ࡢᅜゐ፹ሿ୺ദ㸸ゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊ඹദ㸸໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ༠㈶㸸᪥ᮏ໬Ꮫ఍
᪥᫬㸸2023ᖺ6᭶10᪥㸦ᅵ㸧08:50-17:30
఍ሙ㸸໭ᾏ㐨⤎Ꮫゐ፹⛉Ꮫ◊✲ᡤ 5F ⤎఍㆟ᐊ㸦ࣁ࢖ࣈࣜࢵࢻ㛤ദ㸧
ཧຍ⪅㸸95ྡ㸦࠺ࡕ14ྡࡣ௻ᴗ࠿ࡽࡢ୍⯡ཧຍ㸧ᴫ␎㸸ゐ፹⛉Ꮫ◊✲ᡤ࡛ࡣ㸪ゐ፹Ꮫ఍ࡀ㛤ദࡍࡿࠕ໭ࡢᅜ
ゐ፹ሿࠖࢆඹദࡋ࡚࠸ࡿ㸬ࡇࡢㅮ⩦఍ࡢ┠ⓗࡣ㸪ゐ፹ࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿ◊✲ᐊ࡟㓄ᒓࡉࢀࡓ኱Ꮫ㝔⏕࣭Ꮫ㒊Ꮫ⏕㸪࠾ࡼࡧ୍⯡ࡢ᪉࡟ゐ፹ࡢᇶ♏ࢆᏛࢇ࡛ࡶࡽ࠺ࡇ࡜࡛࠶ࡿ㸬ᮏᖺࡣゐ፹ᮦᩱ◊✲㒊㛛ࡢ㣤⏣೺஧෸ᩍᤵࡀ஦ົᒁࢆᢸ
ᙜࡋ㸪6᭶10᪥࡟ࣁ࢖ࣈࣜࢵࢻᙧᘧ࡛㛤ദࡉࢀࡓ㸬 ゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊㛗ࡢ⚄㇂⿱୍ඛ⏕㸦໭኱㝔ᆅ⌫⎔ቃ㸧࠿ࡽ㛤ሿᣵᣜ࡜ᴫせㄝ᫂ࡀ⾜ࢃࢀ㸪ᆏୖᩄᐶඛ⏕㸦໭ぢᕤᴗ኱Ꮫ㸧࡟ࡼࡾゐ፹ᮦᩱ࡜ゐ፹ㄪ〇ἲ㸪ⴗ㔝໏ඛ⏕㸦໭኱㝔ᕤ㸧࡟ࡼࡾゐ፹ࡢᵓ㐀ゎᯒ(I)㸪⚄⏣ᗣᬕඛ⏕㸦ᐊ⹒ᕤ኱㸧࡟ࡼࡾゐ፹ࡢᵓ㐀ゎᯒ(ϩ)㸪୰ᓥΎ㝯ඛ⏕㸦໭኱ゐ፹◊㸧࡟ࡼࡾ㓟ሷᇶゐ፹ࡢ཯ᛂ࡜ゎᯒ㸪ΎỈ◊୍ඛ⏕㸦໭኱ゐ፹◊㸧࡟ࡼࡾ㔠ᒓࢼࣀ⢏Ꮚ࣭㑄⛣㔠ᒓ㓟໬≀ࡢゐ፹స⏝㸪⚄㇂⿱୍ᩍᤵ㸦໭኱㝔ᆅ⌫⎔ቃ㸧࡟ࡼࡾᅛయゐ፹཯ᛂࡢ཯
ᛂ㏿ᗘㄽ㸪⚟ᒸ῟ඛ⏕㸦໭኱ゐ፹◊㸧࡟ࡼࡾゐ፹ࡢᐇ⏝໬㸸ᴫㄽ࡜ࢣ࣮ࢫࢫࢱࢹ࢕࡟ࡘ࠸࡚ㅮࡌࡽࢀࡓ㸬 ࣁ࢖ࣈࣜࢵࢻ㛤ദࡢࡓࡵ඲ᅜࡢ኱Ꮫ࣭௻ᴗ࠿ࡽ኱ໃࡢཧ
ຍ⪅ࡀ࠶ࡾ㸪┒ἣࡢᵝ┦ࢆ࿊ࡋࡓ㸬▷᫬㛫࡟⃰ᐦ࡞ෆᐜࡢ
ㅮ⩏ࡀ࡞ࡉࢀ㸪ࡲࡓࢳࣕࢵࢺᶵ⬟ࢆά⏝ࡋࡓࡇ࡜࡟ࡼࡾ㸪

9࢜ࣥࣛ࢖ࣥ࠿ࡽࡶከࡃࡢ㉁ၥࡀཧຍ⪅࠿ࡽ࡞ࡉࢀࡓ㸬ࣁ࢖ࣈࣜࢵࢻ㛤ദࡢ࣓ࣜࢵࢺࡀⰋ࠸ᙧ࡛⌧ࢀࡓ඾ᆺⓗ࡞ᡂຌ౛࡛࠶ࡗࡓ࡜ᛮࢃࢀࡿ㸬
8:50-09:00

㛤ሿᘧ࣭ᴫせㄝ᫂

9:00-10:00

ゐ፹ᮦᩱ࡜ゐ፹ㄪ〇ἲ ᆏୖᩄᐶ/໭ぢᕤᴗ኱Ꮫ

10:05-11:05

ゐ፹ࡢᵓ㐀ゎᯒ(I) Ⲷ㔝໏/໭ᾏ㐨኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉

11:10-12:10

ゐ፹ࡢᵓ㐀ゎᯒ(II) ⚄⏣ᗣᬕ/ᐊ⹒ᕤᴗ኱
Ꮫ

13:00-14:00

㓟ሷᇶゐ፹ࡢ཯ᛂ࡜ゎᯒ ୰ᓥΎ㝯/໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ

14:05-15:05

㔠ᒓࢼࣀ⢏Ꮚ࣭㑄⛣㔠ᒓ㓟໬≀ࡢゐ፹స⏝ΎỈ◊୍/໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ

15:15-16:15

ᅛయゐ፹཯ᛂࡢ཯ᛂ㏿ᗘㄽ ⚄㇂⿱୍/໭ᾏ㐨኱Ꮫ኱Ꮫ㝔ᆅ⌫⎔ቃ⛉Ꮫ◊✲㝔࣭⎔ቃ⛉Ꮫ㝔

16:20-17:20

ゐ፹ࡢᐇ⏝໬㸸ᴫㄽ࡜ࢣ࣮ࢫࢫࢱࢹ࢕ ⚟ᒸ῟/໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ

17:25-17:30

㛢ሿᘧ‫ڦ‬ゐ፹⛉Ꮫ◊✲ᡤᾏእὴ㐵ไᗘ ᮏไᗘࡣᪧゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮㸦⌧ゐ፹⛉Ꮫ◊✲ᡤ㸧ෆつ࡜ࡋ࡚2004ᖺ12᭶24᪥࡟༠㆟ဨ఍࡟࠾࠸࡚ไᐃࡉࢀ㸪
2ᗘࡢᨵṇࢆ࡬࡚⌧ᅾ࡟࠸ࡓࡗ࡚࠸ࡿ㸬ෆᐜࡣ௨ୗࡢ࡜࠾
ࡾ㸬
㸦1㸧ὴ㐵ඛ㸸 ᮏ◊✲ᡤࡀ◊✲஺ὶࢆ⾜ࡗ࡚࠸ࡿᶵ㛵࡜ࡍࡿ㸬㸦2㸧ὴ㐵ேᩘ㸸 ẖᖺ3ྡ⛬ᗘ 㸦3㸧ὴ㐵ᑐ㇟⪅㸸ゐ፹⛉Ꮫ◊✲ᡤᡤᒓࡢ኱Ꮫ㝔⏕࠾ࡼࡧᩍဨ 㸦4㸧ὴ㐵ᮇ㛫㸸 2㹼3࠿᭶㛫 㸦5㸧ὴ㐵⤒㈝㸸◊✲ᡤ⤒㈝࠿ࡽ஺㏻㈝ཬࡧ⁫ᅾ㈝ࢆᨭ⤥ࡍࡿ㸦⁫ᅾ㈝ࢆὴ㐵ඛࡢ኱Ꮫ࡞࡝ࡀ㈇ᢸࡍࡿሙྜࡣ㸪ࡇࡢ㝈ࡾ࡛ࡣ࡞࠸㸧㸬ὴ㐵⤒㈝ࡣ1ྡ࠶ࡓࡾ
600༓෇ࢆ㝈ᗘ࡜ࡍࡿ㸬ᅗ᭩Ꮫ⾡᝟ሗ

‫ڦ‬ᅗ᭩ ᪧゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᅗ᭩ᐊࡣ2003ᖺ11᭶࡟໭ᾏ㐨኱Ꮫᵓෆ໭࢟ࣕࣥࣃࢫෆ๰ᡂ⛉Ꮫ◊✲Ჷ࡟⛣㌿ࡋࡓᚋ㸪ྡ⛠ࡣኚ᭦ࡏࡎ࡟๰ᡂ⛉Ꮫ◊✲Ჷ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮/๰ᡂ⛉Ꮫ◊✲ᶵᵓ/㟁Ꮚ⛉Ꮫ◊✲ᡤ㸧ࡢඹ㏻ࡢᅗ᭩ᐊ࡜ࡋ
࡚㐠⏝ࡉࢀ࡚ࡁࡓࡀ㸪2005ᖺ࠿ࡽࡣྡ⛠ࢆࠕ໭࢟ࣕࣥࣃࢫ
ᅗ᭩ᐊࠖ࡜ࡋࡓ㸬2010ᖺ࡟㟁Ꮚ⛉Ꮫ◊✲ᡤࡢ⛣㌿࡟࡜ࡶ࡞࠸㸪2008ᖺ8᭶11᪥࡟ྠ◊✲ᡤᅗ᭩ᐊ࡜⤫ྜࡉࢀࡓ㸦ྡ⛠ࡣࠕ໭࢟ࣕࣥࣃࢫᅗ᭩ᐊࠖ
㸬໭࢟ࣕࣥࣃࢫ⥲ྜ◊✲Ჷ5ྕ㤋㹙㟁Ꮚ⛉Ꮫ◊✲Ჷ㹛1㝵㸧㸬ᅗ᭩ண⟬㸦2023ᖺᗘ㸧㸸 84༓෇
ⶶ᭩ᩘ࡜ᡤⶶ㞧ㄅ㸦ゐ፹⛉Ꮫ◊✲ᡤศ㸧㸸 ⶶ᭩㸦࿴᭩㸧
4,820෉/࿴㞧ㄅ87✀㢮࣭ⶶ᭩㸦ὒ᭩㸧16,803෉/ὒ㞧ㄅ379✀
㢮࣭ྜィ㸸ⶶ᭩21,623෉/㞧ㄅ466✀㢮‫ڦ‬Ꮫ⾡᝟ሗ
ฟ∧≀ࠓゐ፹⛉Ꮫ◊✲ᡤฟ∧≀㸦ᐃᮇห⾜≀㸧ࠔ(1)໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᖺሗ2023㸦2024ᖺ8᭶ห⾜/A4ุ/84࣮࣌ࢪ㸧ࢹ࣮ࢱ࣮࣋ࢫ
(1)ゐ፹≀㉁ࢹ࣮ࢱ࣮࣋ࢫ㸦ゐ፹໬Ꮫ◊✲⪅ࡀ⮬ࡽ㑅ࡧฟࡋࡓゐ፹≀㉁࣭ゐ፹స⏝࡟㛵ࡍࡿࠕ☜ᐇ࡞ࠖ᝟ሗࢆ㞟✚ࡋ㸪᪂ࡓ࡞▱ࡢ๰ᡂࡸ▱ࡢඹ᭷ࢆࡵࡊࡍ࣭1203௳࣭ᢸᙜ㸸Ύ Ỉ ◊ ୍ 㸧 https://www.cat.hokudai.ac.jp/catdb/index.php
ࠓ2023ᖺᗘ㸸㏣ຍ/᭦᪂0௳ࠔ(2)XAFSࢹ࣮ࢱ࣮࣋ࢫ㸦ࡉࡲࡊࡲ࡞໬ྜ≀ࡢXAFSࢹ࣮ࢱࢆfoil࡞࡝ࡢඹ㏻ⓗ࡞ࢹ࣮ࢱ࡜࠶ࢃࡏ࡚ᥖ㍕ࡍࡿࡇ࡜࡟
ࡼࡾ㸪࢚ࢿࣝࢠ࣮㍈ࢆ⤫୍ࡋࡓࢹ࣮ࢱ࣮࣋ࢫࢆᵓ⠏࣭
1019௳࣭ᢸᙜ㸸ΎỈ◊୍㸧https://www.cat.hokudai.ac.jp/
catdb/index.phpࠓ2023ᖺᗘ㸸㏣ຍ/᭦᪂5௳ࠔ

ᴾ

2023ᖺᗘᐇ⦼㸸ᐇ᪋࡞ࡋ‫ڦ‬Ꮫ⏕஺ὶጤဨ఍ ᡤᒓ኱Ꮫ㝔ࡀࡇ࡜࡞ࡿゐ፹⛉Ꮫ◊✲ᡤ㓄ᒓᏛ⏕㛫㸪◊✲ᐊ㛫ࡢ஺ὶࢆ῝ࡵࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚タ⨨ࡉࢀࡿጤဨ఍
࡛㸪ẖᖺᗘྛ◊✲ᐊ࠿ࡽጤဨࢆฟࡋ࡚ᵓᡂࡋ࡚࠸ࡿ㸬ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ㄯヰ఍㸦2010ᖺᗘ㏵୰࠿ࡽゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࢥ࣒ࣟ࢟࢘㸪2015ᖺ10᭶࠿ࡽゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘㸧ࡀ୺ദࡋ࡚ᖺᗘᮎ࡟㛤ദࡋ࡚࠸ࡓࠕゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮኱Ꮫ㝔⏕ࡢ஺ὶⓎ⾲఍/㏦ู఍㸦Ḽ㏦఍㸧ࠖ㸦➨1ᅇ
ࡣ1995ᖺᗘ㸧ࡣ2006ᖺᗘ࠿ࡽ㸪ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮᭷ᚿ
ࡀୡヰࢆࡋ࡚࠸ࡓࠕゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࢯࣇࢺ࣮࣎ࣝ኱
఍/ࢪࣥࢠࢫ࢝ࣥࣃ࣮ࢸ࢕ࠖࡣ2008ᖺᗘ࠿ࡽᏛ⏕஺ὶጤဨ఍ࡀᢸᙜࡋ࡚࠸ࡿ㸬2015ᖺ10᭶ࡼࡾྡ⛠ࢆࡑࢀࡒࢀࠕゐ፹⛉Ꮫ◊✲ᡤ኱Ꮫ㝔⏕ࡢ஺ὶⓎ⾲఍/㏦ู఍㸦Ḽ㏦఍㸧ࠖࠕゐ፹⛉Ꮫ◊✲ᡤࢯࣇࢺ࣮࣎ࣝ኱఍/ࢪࣥࢠࢫ࢝ࣥࣃ࣮ࢸ࢕ࠖ࡜
ࡋࡓ㸬2023ᖺᗘࡢάືࡣ௨ୗࡢ࡜࠾ࡾ㸬ࢯࣇࢺ࣮࣎ࣝ኱఍ࢪࣥࢠࢫ࢝ࣥࣃ࣮ࢸ࢕୰Ṇゐ፹⛉Ꮫ◊✲ᡤ➨ᅇ኱Ꮫ㝔⏕ࡢ஺ὶⓎ⾲఍Ḽ㏦఍୰Ṇ

10ᖺሗ࣭◊✲ᡤ⦅‫ە‬

ᴾ‫׎‬ᨥὉ‫׎‬ϋʩ්ểσӷᄂᆮᴾinternational and domestic exchange and collaboration୰ᅜ࣭ேẸ኱Ꮫ໬Ꮫ⣔ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸
2016/11/18࣭ᮇ㝈㸸2026/11/18ࠓ⮬ື᭦᪂ࠔ㸧 ୡ⏺ࡢゐ፹◊✲⪅࡜ࡢ㐃ᦠࢆ㐍ࡵ㸪ୡ⏺ⓗ࡛ࣞ࣋ࣝࡢゐ፹◊✲᪉ྥࢆᐃࡵ㸪ゐ፹◊✲ࢆάⓎ໬ࡉࡏࡿࡇ࡜ࢆᮏ◊✲ᡤࡢ┠ᶆ࡜ࡋ࡚࠸ࡿ㸬ࡑࡢ୍⎔࡜ࡋ࡚㸪ࡉࡲࡊࡲ࡞ᅜࡢゐ፹◊✲ᶵ㛵࡜✚ᴟⓗ࡟Ꮫ⾡஺ὶ༠ᐃࢆ⥾⤖ࡋ࡚࠸ࡿ㸬ࢱ࢖࣭ࣦ࢕ࢹࣕࢩ࣓ࣜࢹ࢕⛉Ꮫᢏ⾡኱Ꮫ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2017/02/27࣭ᮇ㝈㸸2027/02/27ࠓ⮬ື᭦᪂ࠔ㸧‫ڦ‬2022ᖺᗘࡲ࡛࡟⥾⤖ࡉࢀ࡚2023ᖺᗘ࡟᭷ຠ࡞
༠ᐃ࢜ࣛࣥࢲ࣭࢔࢖ࣥࢺ࣮࣍ࣇ࢙ࣥᕤ⛉኱Ꮫ໬ᏛᕤᏛ࣭໬Ꮫ⛉㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2018/08/07࣭ᮇ㝈㸸
2028/08/07ࠓ⮬ື᭦᪂῭ࠔ
㸧

஺ὶ༠ᐃ

୰ᅜ࣭▼Ἔ኱Ꮫ㸦໭ி㸧໬ᕤᏛ㝔 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸1999/12/07࣭ᮇ㝈㸸2024/12/07ࠓ⮬ື᭦᪂ࠔ㸧୰ᅜ࣭⛉Ꮫ㝔኱Ꮫ ኱Ꮫ㛫཭ዲᏛ⾡஺ὶ༠ᐃࠑ㛵ಀ㒊ᒁࠒ㸦⥾⤖㸸2017/12/12࣭ᮇ㝈㸸2027/12/12ࠓ⮬ື᭦᪂ࠔ㸧୰ᅜ࣭໭ி኱Ꮫ ኱Ꮫ㛫Ꮫ⾡஺ὶ࡟㛵ࡍࡿ༠ᐃࠑ㛵ಀ㒊ᒁࠒ㸦⥾⤖㸸2003/02/19࣭ᮇ㝈㸸2028/02/19ࠓ⮬ື᭦᪂ࠔ㸧ࢻ࢖ࢶ࣭ࣇ࣮ࣜࢻࣜࣄ࣭࢔ࣞࢡࢧࣥࢲ࣮኱Ꮫ࢚࢔ࣛࣥࢤࣥ
㸻ࢽࣗࣝࣥ࣋ࣝࢡ໬Ꮫ཯ᛂᕤᏛ◊✲ᡤ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2018/09/17࣭ᮇ㝈㸸2028/09/17ࠓ⮬ື᭦᪂῭ࠔ㸧୰ᅜ࣭⳹ᮾᖌ⠊኱Ꮫ໬Ꮫ⣔ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2005/03/18࣭ᮇ㝈㸸2025/03/18ࠓ⮬ື᭦᪂ࠔ㸧୰ᅜ࣭⳹୰ᖌ⠊኱Ꮫ໬ᏛᏛ㝔 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2018/11/28࣭ᮇ㝈㸸2028/11/28ࠓ⮬ື᭦᪂῭ࠔ㸧ࢻ࢖ࢶ࣭࣐ࢵࢡࢫࣉࣛࣥࢡ༠఍ࣇࣜࢵࢶࣁ࣮ࣂ◊✲ᡤ 㒊ᒁ 㛫 ཭ ዲ Ꮫ ⾡ ஺ ὶ ༠ ᐃ 㸦 ⥾ ⤖ 㸸 2005/12/26 ࣭ ᮇ 㝈 㸸2025/12/26ࠓ⮬ື᭦᪂ࠔ㸧ࢪ࣮ࣙࢪ࢔࣭ࢺࣅࣜࢩᅜ❧་⛉኱Ꮫ࢖࢜࣋ࣝࢡࢱࢸ࣮ࣛ
ࢮ⸆໬Ꮫ◊✲ᡤ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸
2019/02/25࣭ᮇ㝈㸸2029/02/25ࠓ⮬ື᭦᪂῭ࠔ㸧୰ᅜ࣭ན㛛኱Ꮫᅛయ⾲㠃≀⌮໬Ꮫᅜᐙ㔜Ⅼᐇ㦂ᐊ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2007/10/09࣭ᮇ㝈㸸2027/10/09
ࠓ⮬ື᭦᪂ࠔ
㸧‫ڦ‬2023ᖺᗘ࡟⥾⤖ࡉࢀࡓ༠ᐃ

୰ᅜ࣭Ύ⳹኱Ꮫ ኱Ꮫ㛫Ꮫ⾡஺ὶ࡟㛵ࡍࡿ༠ᐃࠑ㈐௵㒊ᒁࠒ㸦⥾⤖㸸2008/06/30࣭ᮇ㝈㸸2028/06/30ࠓ⮬ື᭦᪂῭ࠔ㸧࢖ࣥࢻ࣭࢖ࣥࢻᕤ⛉኱Ꮫ࢖ࣥࢻ࣮ࣝᰯ 㒊ᒁ㛫ぬ᭩㸦⥾⤖㸸
2023/12/19࣭ᮇ㝈㸸2028/12/19ࠓ⮬ື᭦᪂῭ࠔ㸧࣏࣮ࣛࣥࢻ࣭࣏࣮ࣛࣥࢻ⛉Ꮫ࢔࢝ࢹ࣑࣮ゐ፹࣭⾲㠃໬Ꮫ◊✲ᡤ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2010/03/15࣭ᮇ
㝈㸸2025/03/15ࠓ⮬ື᭦᪂ࠔ㸧ࢪ࣮ࣙࢪ࢔࣭ࢪ࣮ࣙࢪ࢔㎰ᴗ኱Ꮫ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2024/01/29࣭ᮇ㝈㸸2029/01/29ࠓ⮬ື᭦᪂῭ࠔ㸧࣏࣮ࣛࣥࢻ࣭す࣏࣓ࣛࢽ࢔ࣥᕤ⛉኱Ꮫ໬Ꮫ࣭⎔ቃᕤᏛ◊✲ᡤ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2010/03/17࣭ᮇ㝈㸸
2025/03/17ࠓ⮬ື᭦᪂ࠔ㸧ඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬ஦ᴗ࣏࣮ࣛࣥࢻ࣭ࢢࢲࣥࢫࢡᕤ⛉኱Ꮫ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2010/03/18࣭ᮇ㝈㸸2025/03/18ࠓ⮬ື᭦᪂ࠔ㸧୰ᅜ࣭ན㛛኱Ꮫ ኱Ꮫ㛫Ꮫ⾡஺ὶ࡟㛵ࡍࡿ༠ᐃࠑ㈐௵㒊ᒁࠒ㸦⥾⤖㸸2010/11/25࣭ᮇ㝈㸸2025/11/25ࠓ⮬ື᭦᪂ࠔ㸧ࣇࣛࣥࢫ࣭ࣜࣝ➨኱Ꮫ㸫ࣜࣝ୰ኸᏛ㝔ゐ፹࣭ᅛయ໬Ꮫ◊✲ࣘࢽࢵࢺ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸
2011/01/17࣭ᮇ㝈㸸2026/01/17ࠓ⮬ື᭦᪂ࠔ㸧࣏࣮ࣛࣥࢻ࣭ࢢࢲࣥࢫࢡ኱Ꮫ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2013/02/01࣭ᮇ㝈㸸2028/02/01ࠓ⮬ື᭦᪂ࠔ㸧࢔࣓࣭ࣜ࢝ࣃ࣮ࢹ࣮ࣗ኱Ꮫࢧ࢖࢚ࣥࢫᏛ㒊 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2014/04/26࣭ᮇ㝈㸸2024/04/26ࠓ⮬ື᭦᪂ࠔ㸧࢔࣓࣭ࣜ࢝ࢧ࢘ࢫ࢟ࣕࣟࣛ࢖ࢼ኱Ꮫ໬ᏛᕤᏛ⛉ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2016/03/24࣭ᮇ㝈㸸2026/03/24ࠓ⮬ື᭦᪂ࠔ㸧࣏࣮ࣛࣥࢻ࣭ࣖࢠ࢙࣎኱Ꮫ໬Ꮫ⛉ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2016/05/11࣭ᮇ㝈㸸2026/05/11ࠓ⮬ື᭦᪂ࠔ㸧ࣟࢩ࢔࣭࣎ࣞࢫࢥࣇゐ፹◊✲ᡤ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2016/10/11࣭ᮇ㝈㸸2026/10/11ࠓ⮬ື᭦᪂ࠔ㸧࢔࣓࣭ࣜ࢝ࢧࣥ࢟ࣕࢵࢺࢭࣥࢱ࣮ 㒊ᒁ㛫཭ዲᏛ⾡஺ὶ༠ᐃ㸦⥾⤖㸸2016/11/02࣭ᮇ㝈㸸2026/11/02ࠓ⮬ື᭦᪂ࠔ㸧‫ە‬ᖺሗ ࣭◊✲ᡤ⦅ ゐ፹⛉Ꮫ◊✲ᡤ㸦ᪧゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮㸧ࡣ㸪2009ᖺᗘࡲ࡛ゐ፹໬Ꮫ࡟㛵ࡍࡿඹྠ◊✲㸪ඹྠ฼⏝࡞࡝ࢆ⾜࠺ࠕ඲ᅜඹྠ฼⏝᪋タࠖ࡜ࡋ࡚άືࡋ࡚ࡁࡓ㸬2010ᖺᗘ࠿ࡽࡣྡ⛠ࢆࠕඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬࠖ㸪ゐ፹㛵㐃ศ㔝ࡢⓎ
ᒎ࡟㈉⊩ࡋ㸪Ꮫ⾡᝟ሗ཰㞟࣭Ⓨಙࡢ୰ᚰⓗ࡞ᙺ๭ࢆᯝࡓࡍ
౑࿨ࢆᢸࡗ࡚ࡁࡓ㸬2022ᖺᗘࡼࡾ㸪ᮏ◊✲ᡤ㸪኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮࡜࡜ࡶ࡟㐃ᦠࢿࢵࢺ࣮࣡ࢡᆺඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬࠕゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬࠖ࡜ࡋ࡚ᩥ㒊⛉Ꮫ┬࠿ࡽㄆᐃࢆཷࡅ㸪ᮏ◊✲ᡤࡣᮏᣐⅬࡢ௦⾲࡜ࡋ࡚ᣐⅬάືࢆ≌ᘬࡋ࡚࠸ࡿ㸬ゐ፹ࡸேᕤගྜᡂ࡞࡝ࡢ୰᰾㡿ᇦ࡟࠾ࡅࡿඹྠ◊✲࡟ຍ࠼㸪␗ศ㔝㛫ࡢ⼥ྜ࣭㐃ᦠࢆ୍ᒙಁ㐍ࡍࡿࡓࡵ࡟㸪ᅛయゐ፹㸪ศᏊゐ፹㸪⏕≀ゐ፹ศ㔝㛫ࡢඹྠ◊✲ࢆࡣࡌࡵ࡜ࡍࡿከᵝᛶࡢ࠶ࡿᏛ㝿ඹྠ◊✲ࢆ᥎㐍ࡍࡿ㸬ࡲࡓ㸪SRISࡢ༠ຊ࡟ࡼࡾḟୡ௦ᨺᑕග※ࢆά⏝ࡍࡿィ⛉Ꮫศ㔝࡜ࡢඹྠ◊✲ࢆಁ㐍ࡍࡿ㸬‫⌮⟶ڦ‬㐠Ⴀゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬᣐⅬᮏ㒊ጤဨ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ࠒΎỈ◊୍㹙2022/04/01㹼㹛ࠑ኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮ᡤ㛗ࠒኳᑿ㇏㹙2022/04/01㹼㹛ࠑ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮㛗ࠒ11బ⸨୍ᙪ㹙2022/04/01㹼2022/12/31㹛
ࠑྜྷ⏣຾㹙2023/01/01㹼㹛ゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬᣐⅬ᥎㐍ጤဨ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ࠒΎỈ◊୍㹙2022/04/01㹼㹛ࠑ኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮ᡤ㛗ࠒኳᑿ㇏㹙2022/04/01㹼㹛ࠑ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮㛗ࠒబ⸨୍ᙪ㹙2022/04/01㹼2022/12/31㹛ྜྷ⏣຾㹙2023/01/01㹼㹛ࠑゐ፹⛉Ꮫ◊✲ᡤᩍᤵࠒᾆཱྀ኱㍜㹙2022/04/01㹼㹛ࠑ኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮๪ᡤ㛗ࠒᒣ⏣⿱௓
㹙2022/04/01㹼㹛ࠑ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭ ࣥ ࢱ ࣮ ๪ ࢭ ࣥ ࢱ ࣮ 㛗 ࠒ ྜྷ ⏣ ຾ 㹙 2022/04/01 㹼
2022/12/31㹛బ⸨๛୍㹙2023/01/01㹼㹛ゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬ㐠Ⴀጤဨ఍
ࠑ ゐ ፹ ⛉ Ꮫ ◊ ✲ ᡤ 㛗 ࠒ Ύ Ỉ ◊ ୍ 㹙 2022/04/01 㹼
2024/03/31㹛ࠑ኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮ᡤ
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㹼2022/12/31㹛ྜྷ⏣຾㹙2023/01/01㹼2024/03/31㹛ࠑᮾிᕤᴗ኱Ꮫ⌮Ꮫ㝔ᩍᤵࠒ▼㇂἞㹙2022/04/01㹼2024/03/31㹛
ࠑྡྂᒇ኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲⛉ᩍᤵࠒᩪ⸨㐍㹙2022/04/01㹼
2024/03/31㹛ࠑ᪩✄⏣኱Ꮫඛ㐍⌮ᕤᏛ㒊ᩍᤵࠒ㛵᰿Ὀ
㹙2022/04/01㹼2024/03/31㹛
ࠑ኱㜰኱Ꮫ኱Ꮫ㝔⸆Ꮫ◊✲⛉≉௵ᩍᤵࠒ┿ᓥ࿴ᚿ㹙2022/04/01㹼2024/03/31㹛
ࠑ኱㜰኱Ꮫ ኱ Ꮫ 㝔 ᕤ Ꮫ ◊ ✲ ⛉ ᩍ ᤵ ࠒ ᒣ ୗ ᘯ ᕭ 㹙 2022/04/01 㹼
2024/03/31㹛
ࠑ⮬↛⛉Ꮫ◊✲ᶵᵓศᏊ⛉Ꮫ◊✲ᡤᩍᤵࠒᶓ
ᒣ฼ᙪ㹙2022/04/01㹼2024/03/31㹛ゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬㄢ㢟➼ᑂᰝጤဨ఍
ࠑ ゐ ፹ ⛉ Ꮫ ◊ ✲ ᡤ ᩍ ᤵ ࠒ ᮅ ಴ Ύ 㧘 㹙 2022/04/01 㹼
2024/03/31㹛
ࠑ኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮෸ᩍ
ᤵࠒ⏣ᮧṇ⣧㹙2022/04/01㹼2024/03/31㹛
ࠑ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮⥲ᣓ◊✲୺ᖿࠒ⸨㇂ᛅ
༤㹙2022/04/01㹼2024/03/31㹛
ࠑி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ᩍᤵࠒ㜿㒊❳㹙2022/04/01㹼2024/03/31㹛
ࠑ⚄ᡞ኱Ꮫ኱
Ꮫ㝔⌮Ꮫ◊✲⛉ᩍᤵࠒ኱すὒ㹙2022/04/01㹼2024/03/31㹛
ࠑ㛵す኱Ꮫ໬Ꮫ⏕࿨ᕤᏛ㒊ᩍᤵࠒ኱ὝᗣႹ㹙2022/04/01
㹼 2024/03/31 㹛ࠑ ᡂ ㋣ ኱ Ꮫ ⌮ ᕤ Ꮫ 㒊 ᩍ ᤵ ࠒ 㔛 ᕝ 㔜 ኵ㹙2022/04/01㹼2024/03/31㹛
ࠑᒸᒣ኱ᏛᏛ⾡◊✲㝔⮬↛⛉ᏛᏛᇦᩍᤵࠒᒣ᪉ၨ㹙2022/04/01㹼2024/03/31㹛ࠑ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ໬Ꮫࣉࣟࢭࢫ◊✲㒊㛛◊✲ࢢ࣮ࣝࣉ㛗ࠒᒣཱྀ᭷᭸㹙2022/04/01㹼2024/03/31㹛‫ڦ‬බເせ㡯ᮏᣐⅬࡣ㸪ୗグࡢ࡜࠾ࡾඹྠ฼⏝࣭ඹྠ◊✲ࡢබເࢆ⾜ࡗ࡚࠸ࡿ㸬ⱝᡭ◊✲⪅㸪ዪᛶ◊✲⪅࠿ࡽࡢ◊✲ᥦ᱌ࢆ✚ᴟⓗ࡟ᨭ᥼ࡋ࡚࠸ࡿ㸬
1 බເ༊ศ
ᮏᣐⅬእࡢ◊✲⪅ࡀ◊✲௦⾲⪅࡜࡞ࡾ㸪ཷධ◊✲⪅࡛࠶ࡿ
ᮏᣐⅬࡢ◊✲⪅ࡀ◊✲ศᢸ⪅࡜࡞ࡾඹྠ◊✲ࢆᐇ᪋ࡍࡿ㸬
ᮏᣐⅬࢆᵓᡂࡍࡿ◊✲ᶵ㛵࡟ᡤᒓࡍࡿ」ᩘࡢ◊✲⪅ࢆ◊✲ศᢸ⪅࡜ࡍࡿ◊✲ᥦ᱌ࢆḼ㏄ࡍࡿ㸬⏦ㄳ⪅ࡣ◊✲ㄢ㢟࡞࡝࡟ࡘ࠸࡚ཷධ◊✲⪅࡜ࡢ㛫࡛༑ศ࡞ᡴࡕྜࢃࡏࢆ⾜ࡗࡓ࠺࠼࡛⏦ㄳࢆ⾜࠺ࡇ࡜࡜ࡍࡿ㸬ࡲࡓ㸪ᮏᣐⅬࡣࢥࣛ࣎ࢼ
ࣅࢤ࣮ࢱࢆタ⨨ࡋ࡚࠾ࡾ㸪ཷධ◊✲⪅࡞࡝࡟ࡘ࠸࡚┦ㄯࡀ࡛ࡁࡿ㸬බເ༊ศࡣୗグࡢ㏻ࡾ㸬㸦1㸧ᥦ᱌ᆺ㸸⮬⏤࡞Ⓨ᝿࡟ᇶ࡙࠸ࡓ㸪ⴌⱆⓗ㸪ヨ㦂ⓗ㸪‽ഛⓗ࡞◊✲ㄢ㢟ࡢබເࢆ⾜࠺㸬ᖺ㸰ᅇࡢබເ᫬ᮇࢆタᐃࡋ࡚࠸ࡿ㸬
㸦2㸧Ⓨᒎᆺ㸸
ᮏᣐⅬ࡜ࡢඹྠ◊✲ᡂᯝ㸪࠶ࡿ࠸ࡣ⊂⮬࡟㐍ࡵࡓ◊✲ᡂᯝ

12

ࢆⓎᒎࡉࡏࡿࡓࡵࡢ◊✲ㄢ㢟ࡢබເࢆ⾜࠺㸬࡞࠾㸪ඹྠ◊✲ᡂᯝ࡟ࡣ௧࿴㸱ᖺᗘࡲ࡛ࡢ໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᣐ
Ⅼ㸪኱㜰ᕷ❧኱Ꮫேᕤගྜᡂ◊✲ᣐⅬࢆ฼⏝ࡋࡓ◊✲ᡂᯝࢆྵࡴ㸬࡞࠾㸪ᥦ᱌ᆺ࡜ࡢ㔜」⏦ㄳࡀྍ⬟࡛࠶ࡿ㸬㔜」⏦ㄳࡍࡿ࡜Ⓨᒎᆺࡢ⏦ㄳ᭩ࡣᥦ᱌ᆺ࡜ࡋ࡚ࡶᑂᰝࡉࢀࡿ㸬㸦3㸧Fostering-Young-ResearcherS(FYRES)ᆺ
ᮏᣐⅬ࡜ࡢඹྠ◊✲ᡂᯝࢆ୍ᒙⓎᒎࡉࡏࡿࡓࡵࡢⱝᡭ◊✲⪅㸦40ṓᮍ‶㸸2024ᖺ3᭶31᪥᫬Ⅼ㸧࠿ࡽࡢ◊✲ㄢ㢟ࢆබເࡍࡿ㸬◊✲⪅ࡀᮏᣐⅬ࡟⁫ᅾࡋ㸪◊✲タഛ࡞࡝ࢆ฼⏝ࡋࡘࡘᮏᣐ
Ⅼࡢ◊✲⪅࡜ᐦᗘࡢ㧗࠸ඹྠ◊✲ࢆᐇ᪋࡛ࡁࡿ㸬」ᩘࡢ◊✲ᶵ㛵㸦ᾏእࢆྵࡴ㸧࠿ࡽࡢ◊✲⪅ࡢཧ⏬ࡀྍ⬟࡛࠶ࡿ㸬FYRESᆺ࡛ࡣ㸪ᮏᣐⅬࡢ࢖࣋ࣥࢺ࡞࡝ࢆ㏻ࡋ࡚㸪᥇ᢥࡉࢀࡓⱝᡭ◊✲⪅ࡢά㌍ࢆᨭ᥼ࡍࡿ㸬࡞࠾㸪ᥦ᱌ᆺ࡜ࡢ㔜」⏦ㄳࡀྍ⬟࡛࠶ࡿ㸬㔜」⏦ㄳࡍࡿ࡜FYRESᆺࡢ⏦ㄳ᭩ࡣᥦ᱌ᆺ࡜ࡋ࡚ࡶᑂᰝࡉࢀࡿ㸬㸦4㸧࢜ࣥࢹ࣐ࣥࢻᆺ㸸
ᮏᣐⅬࡢ◊✲⪅ࡀ❆ཱྀ࡜࡞ࡾᣐⅬෆࡢඹ㏻⿦⨨ࡸྛ◊✲⪅ࡢಖ᭷ࡍࡿ⿦⨨ࡀ฼⏝࡛ࡁࡿ㸬ᑓ㛛ⓗ࣭ᢏ⾡ⓗ࡞┦ㄯࡸヨ㦂ⓗ࡞ᐇ㦂ࡸศᯒ࡟㛵ࡍࡿ౫㢗ࢆ㝶᫬ཷࡅ௜ࡅ࡚࠸ࡿ㸬
ᮏᣐⅬࡣ⤒㈝ࢆ㈇ᢸࡋ࡞࠸㸬
㸦5㸧ⱝᡭᣍᚅㅮ₇ᆺ(Young Lectureship Azuma Award)㸸
ⱝᡭゐ፹◊✲⪅࡟ᑐࡋᅜ㝿⯙ྎ࡛ࡢά㌍ࢆᨭ᥼ࡋ㸪ゐ፹◊✲ࡢ୰᰾࡜࡞ࡗ࡚ά㌍࡛ࡁࡿⱝᡭ◊✲⪅ࡢ⫱ᡂ࣭άᛶ໬ࢆ
┠ᣦࡍ㸬ᾏእࡢⴭྡ࡞◊✲ᶵ㛵࡟࠾࠸࡚◊✲ᡂᯝࡢⓎ⾲ࢆᕼᮃࡍࡿⱝᡭ◊✲⪅ࢆᑐ㇟࡟㸪ᮏᣐⅬࡀ୺ദࡍࡿ᝟ሗⓎಙᆺᅜ㝿ࢩ࣏ࣥࢪ࣒࢘ࡢᣍᚅㅮ₇ᯟࢆᥦ౪ࡍࡿ࡜࡜ࡶ࡟㸪Ώ⯟㈝ࡢ୍㒊ࢆ⿵ຓࡍࡿ㸬ᮏබເ༊ศࡣゐ፹Ꮫ఍࡜ࡢඹྠ௻
⏬࡛࠶ࡿ㸬㸦6㸧ᐈဨ◊✲ဨ㸸
ᮏᣐⅬ◊✲⪅࡜⥅⥆ⓗ࣭⤌⧊ⓗ࡟༠ຊࡋ࡚㸪ඹྠ฼⏝࣭ඹྠ◊✲ࢆ㐍ࡵࡿពḧⓗ࡞◊✲⪅ࢆᐈဨ◊✲ဨ࡜ࡋ࡚ⱝᖸ
ྡເ㞟ࡍࡿ㸬
㸦7㸧ᐇ㊶◊ಟ㸸
ᣐⅬእࡢ◊✲⪅㸪Ꮫ⏕࡟ᑐࡋ࡚ゐ፹࡟㛵ࡍࡿ◊ಟࡢሙࢆᥦ
౪ࡋ࡚࠸ࡿ㸬ᮏ◊✲ᡤ࡛ࡣ㸪ㄢ㢟ព㆑ࢆࡶࡗࡓ◊✲⪅࡟ᑐࡋ࡚ゐ፹ࡢᐇ㊶ⓗᩍ⫱ࡢሙࢆᥦ౪ࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚㸪ゐ፹㧗➼ᐇ㊶◊ಟࣉࣟࢢ࣒ࣛࢆᖹᡂ24ᖺᗘࡼࡾ㛤ጞࡋࡓ㸬௻ᴗ㸪◊✲ᶵ㛵㸪኱Ꮫ㸪㧗ᰯ➼࡟ᡤᒓࡍࡿ㸪ᚲࡎࡋࡶゐ፹ࢆᑓ㛛࡜ࡋ࡞࠸◊✲⪅㸪ᢏ⾡⪅㸪ᩍ⫱⪅࠿ࡽࡢ✚ᴟⓗ࡞ᛂເࢆḼ㏄ࡋ࡚࠸ࡿ㸬
㸦8㸧◊✲㞟఍ᨭ᥼㸸ゐ፹࡟㛵ࡍࡿ◊✲㞟఍ࡢ㛤ദ࡟ࡘ࠸࡚㸪㛤ദ⤒㈝ࡢ୍㒊ࢆ
ᮏᣐⅬࡀᨭ᥼ࡍࡿ㸬ᮏᣐⅬ࡜ࡢඹྠ㛤ദ࡜࡞ࡿ㸬
2 ᥦ᱌ᆺ㸪Ⓨᒎᆺ㸪FYRESᆺ㸪࢜ࣥࢹ࣐ࣥࢻᆺࡢヲ⣽
2-1 ஦๓┦ㄯඹྠ฼⏝࣭ඹྠ◊✲ࡢཷධ◊✲⪅ࡀ◊✲ศᢸ⪅࡜࡞ࡿ㸬࡞࠾㸪⏦ㄳ࡟ᙜࡓࡗ࡚ࡣ㸪ཷධࢆᕼᮃࡍࡿ◊✲⪅࡜ㄢ㢟タᐃཬࡧ◊✲ィ⏬࡟ࡘ࠸࡚஦๓┦ㄯࡀᚲせ࡛࠶ࡿ㸬ᮏᣐⅬࡣᒃᐊ㸪◊✲⎔ቃ࡞࡝ࢆᥦ౪ࡍࡿ㸬2-2 ◊✲ᮇ㛫◊✲ᮇ㛫ࡣ⾲1グ㍕ࡢᮇ㛫࡜ࡍࡿ㸬࡞࠾㸪⥅⥆⏦ㄳࡀྍ⬟࡛࠶ࡿࡀ㸪᥇ྰࡣᖺᗘࡈ࡜࡟ᑂᰝ࡟ࡼࡗ࡚Ỵᐃࡍࡿ㸬ࡲࡓ㸪
Ⓨᒎᆺࢆ⥅⥆ࡋ࡚ᐇ᪋࡛ࡁࡿᖺᩘࡣ㸰ᖺࢆ㝈ᗘ࡜ࡍࡿ㸬2-3 ◊✲⤒㈝
ඹྠ฼⏝࣭ඹྠ◊✲ࡢ⤒㈝ࡣ㸪ண⟬ࡢ⠊ᅖෆ㸦⾲1㸧࡟࠾࠸࡚ᮏᣐⅬࡀ㈇ᢸࡍࡿ㸬࢜ࣥࢹ࣐ࣥࢻᆺ࡟ࡘ࠸࡚ࡣ㸪ᙜᣐⅬࡢ⤒㈝㈇ᢸࡣ࡞࠸㸬㉎ධྍ⬟࡞≀ရࡣ㸪⏦ㄳㄢ㢟ࡢ㐙⾜ୖ┤᥋ⓗ࡟ᚲせ࡞ࡶࡢᖺሗ࣭◊✲ᡤ⦅‫ە‬

2-8 ᥇ྰࡢ㏻▱࡟㝈ࡿ㸬ཎ๎㸪᪑㈝ࡣ㸪ᮏᣐⅬ࡬ࡢࡶࡢ࡜ࡋ㸪⏦ㄳ᭩࡟グ㍕ࡢ࠶ࡿ◊✲௦⾲⪅㸪ᣐⅬእࡢ◊✲ศᢸ⪅ཬࡧ◊✲༠ຊ⪅࡟ࡘ࠸࡚ᨭ⤥࡛ࡁࡿ㸬

ᮏᣐⅬࡼࡾ㸪┤᥋⏦ㄳ⪅࡬㏻▱ࡍࡿ㸬᥇ᢥᚋ㸪ᣐⅬ⏦ㄳࢩࢫࢸ࣒ࢆ㏻ࡋ࡚㏿ࡸ࠿࡟ࠕඹྠ฼⏝࣭ඹྠ◊✲ᢎㅙ᭩ࠖࢆ
ᥦฟࡍࡿࡶࡢ࡜ࡍࡿ㸬࢜ࣥࢹ࣐ࣥࢻᆺ࡟ࡘ࠸࡚ࡣཷධ◊✲⪅ࡼࡾ㸪┤᥋㸪⏦ㄳ⪅
࡬㏻▱ࡍࡿ㸬ࠕඹྠ฼⏝࣭ඹྠ◊✲ᢎㅙ᭩ࠖࡢᥦฟࡣ୙せ࡛࠶ࡿ㸬࡞࠾㸪⤒㈝ࡢᇳ⾜ᡭ⥆ࡁ࡟ࡘ࠸࡚ࡣ㸪ཷධ◊✲⪅ࡢᡤᒓࡍࡿ஦ົᢸᙜ࡬☜ㄆࡍࡿࡇ࡜㸬
2-4 ⏦ㄳ㈨᱁
⏦ㄳࢆࡍࡿ◊✲௦⾲⪅ࡣ㸪ᅜ⡠ࢆၥࢃࡎ㸪Ꮫእࡢᅜබ⚾❧኱Ꮫ㸪බⓗ◊✲ᶵ㛵ཬࡧẸ㛫௻ᴗ࡟ᡤᒓࡋ࡚࠸ࡿ◊✲⪅ཪࡣࡇࢀ࡟‽ࡎࡿ◊✲⪅࡛࠶ࡿ࡜ᮏ◊✲ᡤ㛗ࡀㄆࡵࡓ⪅࡜ࡋ㸪ᾏእࡢ◊✲ᶵ㛵࡟ᡤᒓࡍࡿ◊✲⪅ࡶྵࡲࢀࡿ㸬◊✲௦⾲⪅ࡣ㸪ᙜヱ◊✲ࢆ㐙⾜ࡍࡿࡓࡵ㸪ᮏ◊✲ᡤཷධᩍဨ࡛࠶ࡿ◊✲ศᢸ⪅ࡢእ㸪ୖグ㈨᱁ࢆ᭷ࡍࡿᅜෆእࡢ◊✲⪅ࢆࠕ◊✲ศᢸ⪅ࠖ࡜ࡋ࡚ຍ࠼ࡿࡇ࡜ࡀ࡛ࡁࡿ㸬ࡲࡓ㸪◊✲௦⾲⪅ࡀᣦᑟࡋ࡚࠸ࡿ኱Ꮫ㝔⏕㸦Ꮫ㒊Ꮫ⏕ࡣ㝖ࡃ㸧ࢆࠕ◊✲༠ຊ⪅ࠖ࡜ࡋ࡚ຍ࠼㸪◊✲ࢆᐇ᪋ࡍࡿࡇ࡜ࡀ࡛ࡁࡿ㸬࡞࠾㸪ศᢸ⪅ࡸ༠ຊ⪅࡟ຍ࠼ࡿሙྜ࡟ࡣ㸪஦๓࡟ཷࡅධࢀᩍ
ဨࡢᢎㅙࢆᚓ࡞ࡅࢀࡤ࡞ࡽ࡞࠸㸬2-5 ⏦ㄳ᪉ἲ
ᣐⅬ⏦ㄳࢩࢫࢸ࣒㸦https://kyoten-gw.cat.hokudai.ac.jp/users/
login㸧ࢆ㏻ࡋ࡚㸪⥾ษ᪥ࡲ࡛࡟⏦ㄳࡍࡿࡶࡢ࡜ࡍࡿ㸬࡞࠾㸪࢜ࣥࢹ࣐ࣥࢻᆺ࡟㛵ࡋ࡚ࡣ⏦ㄳ᭩ࡢ㟁Ꮚ࣓࣮ࣝ㏦ಙ࡟ࡼࡿ⏦ㄳࡶྍ⬟࡜ࡍࡿ㸬
2-6 ⏦ㄳ᭩ᥦฟᮇ㝈⾲㸯࡟グ㍕ࡢᛂເ⥾ษࢆཝᏲࡋ࡞ࡅࢀࡤ࡞ࡽ࡞࠸㸬࢜ࣥࢹ࣐ࣥࢻᆺ࡟ࡘ࠸࡚ࡣ㸪㝶᫬⏦ㄳྍ⬟࡛࠶ࡿ㸬
2-7 㑅⪃
᥇ྰ㸪᥇ᢥ㢠࡟ࡘ࠸࡚ࡣ㸪ᮏᣐⅬㄢ㢟➼ᑂᰝᑓ㛛ጤဨ఍ࡢ㆟ࢆ⤒࡚㸪ᮏᣐⅬᮏ㒊㛗ࡀỴᐃࡍࡿ㸬

2-9ඹྠ฼⏝࣭ඹྠ◊✲ሗ࿌ࡢᥦฟ㸪ㄽᩥⓎ⾲࡞࡝㸦1㸧ඹྠ฼⏝࣭ඹྠ◊✲ሗ࿌᭩ඹྠ◊✲ᐇ᪋ᮇ㛫⤊஢ᚋ10᪥௨ෆ࡟㸪ࠕඹྠ฼⏝࣭ඹྠ◊✲ሗ࿌᭩ࠖࢆసᡂࡋ㸪ᣐⅬ⏦ㄳࢩࢫࢸ࣒ࢆ㏻ࡋ࡚ᥦฟࡍࡿ
ࡶࡢ࡜ࡍࡿ㸬ሗ࿌᭩ࡣ2025ᖺ3᭶࡟ᮏᣐⅬ࢙࢘ࣈࢧ࢖ࢺ࡟
ᥖ㍕ࡋ㸪බ㛤ࡍࡿணᐃ࡛࠶ࡿ㸬
㸦2㸧ㄽᩥⓎ⾲ඹྠ◊✲࡟ࡼࡗ࡚ᚓࡓᡂᯝࢆㄽᩥ➼࡛බ⾲ࡍࡿሙྜࡣ㸪ᮏ
ᣐⅬࡢඹྠ฼⏝࣭ඹྠ◊✲࡛ᚓࡽࢀࡓᡂᯝ࡛࠶ࡿ᪨ࢆㅰ㎡࡜ࡋ࡚ḟࡢࡼ࠺࡟ㄽᩥ➼࡟᫂グࡋ㸪Ⓨ⾲ᚋࡣᮏᣐⅬࡢᣐⅬ⏦ㄳࢩࢫࢸ࣒ࢆ㏻ࡋ࡚ሗ࿌ࡍࡿࡶࡢ࡜ࡍࡿ㸬㸦࿴ᩥ㸧ゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬඹྠ฼⏝࣭ඹྠ◊✲࡟ᇶ࡙ࡁᐇ᪋ࡉࢀࡓ㸦ㄢ㢟␒ྕ...㸧㸬㸦ⱥᩥ㸧This study was supported by the Joint Usage/ResearchCenter for Catalysis. (Proposal#.........)㸬
㸦3㸧▱ⓗ㈈⏘ᶒࡢྲྀࡾᢅ࠸࡟ࡘ࠸࡚
ᮏඹྠ฼⏝࣭ඹྠ◊✲࡟ࡼࡗ࡚⏕ࡌࡓ▱ⓗ㈈⏘ᶒࡢྲྀᢅ࠸
࡟ࡘ࠸࡚ࡣ㸪㏿ࡸ࠿࡟ᡤᒓᶵ㛵࡜ࡢ㛫ู࡛㏵༠㆟ࡍࡿࡶࡢ࡜ࡍࡿ㸬
3 ᥦฟඛ࣭࠾ၥ࠸ྜࢃࡏඛ‫ ۍ‬බ ເ ඲ ⯡ 㸪 ⏦ ㄳ ࢩ ࢫ ࢸ ࣒ ࡟ 㛵 ࡍ ࡿ ࡇ ࡜ 㸸 colabnavigator@cat.hokudai.ac.jp
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⾲㸯㸬ᥦ᱌ᆺ㸪Ⓨᒎᆺ㸪FYRESᆺࡢ◊✲ᮇ㛫㸪㓄ศ◊✲㈝ୖ㝈㢠㸪ᛂເ⥾ษ
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2023ᖺᗘ᥇ᢥㄢ㢟ࡢ࠺ࡕ㸪ゐ፹⛉Ꮫ◊✲ᡤࡢᩍဨࡀཷࡅ
ධࢀᩍဨ࡜࡞ࡗࡓㄢ㢟ᩘࡣ௨ୗࡢ࡜࠾ࡾ㸬
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ࡸ㸪ᶵ⬟ࡢⓎ⌧ࡢࡓࡵࡢ≀㉁ᵓ⠏ㄽ࡞࡝ࢆ᥈ồࡍࡿᴟࡵ࡚
ᇶ♏ⓗ࡞ᇶ┙Ꮫ⾡࡛࠶ࡿ㸬ຍ࠼࡚㸪ࡑࡢᡂᯝࡣ㸪᪂ゐ፹ࡸ᪂ᮦᩱ㛤Ⓨࡣࡶࡕࢁࢇ㸪࢖ࣀ࣮࣋ࢩࣙࣥ๰ᡂࢆ㏻ࡌ࡚࢚ࢿ
ࣝࢠ࣮࣭㈨※࠿ࡽ⎔ቃ࣭๰⸆࡟⮳ࡿᴟࡵ࡚ᗈ࠸⠊ᅖ࡟㐺⏝ࡉࢀࡿ㸬≀㉁๰〇໬Ꮫ࠾ࡼࡧࡑࢀ࡟㛵㐃ࡍࡿ⛉Ꮫࡣ㸪᪂≀㉁ࡢ๰ฟࢆᇶ㍈࡟⏕࿨⛉Ꮫࡸᮦᩱ⛉Ꮫ࡞࡝ࡢ࿘㎶ศ㔝ࢆኚ㠉ࡋ㸪SDGs➼ࡢ㔜せㄢ㢟ࡢゎỴ࡟㈨ࡍࡿࡇ࡜ࡀ࡛ࡁࡿ
⛉Ꮫࡢ୰ᚰ࡛࠶ࡿ㸬SDGsࢆ㐩ᡂࡋ㸪ᣢ⥆ⓗ♫఍ࡢᐇ⌧࡟㈨ࡍࡿ≀㉁⛉Ꮫ◊✲ࢆ㸪ᅜ㝿ⓗどㄆᛶࢆࡶࡗ࡚≌ᘬࡍࡿ࡟ࡣ㸪」ᩘࡢ◊✲⤌⧊ࡢ◊✲㈨※ࡢᙉࡳࢆ⧅࠸࡛㸪᫬௦࡟㐺ࡋࡓඛ㐍ⓗ㐃ᦠࡢ௙⤌ࡳࢆᩚ࠼㸪⼥ྜ◊✲ࡢ᥎㐍࡜ேᮦ⫱ᡂ࡟୍యⓗ࡟ྲྀࡾ⤌ࡴࡇ࡜ࡀồࡵࡽࢀࡿ㸬ᡃࡀᅜࡢ≀㉁๰
ᡂ◊✲ࡣ㸪㔝౫㸪ୗᮧ㸪ⓑᕝ㸪㕥ᮌ㸪᰿ᓊࡽࡢࣀ࣮࣋ࣝ㈹ཷ㈹⪅ࡸ㸪ᅜ㝿໬Ꮫ㐃ྜ㸦IUPAC㸧఍㛗ࡢᕴࢆ㍮ฟࡋࡓࡇ
࡜࠿ࡽ᫂ࡽ࠿࡞㸪ᴟࡵ࡚㧗࠸ᅜ㝿➇தຊࢆᣢࡘ࡟ࡶ࠿࠿ࢃ
ࡽࡎ㸪᪂≀㉁๰〇ࢆ⥲ྜⓗ࠿ࡘᡓ␎ⓗ࡟㐍ࡵࡿᶵ㛵࣭⤌⧊ࡣᡃࡀᅜ࡟ࡣᮍࡔᏑᅾࡏࡎ㸪ࡇࡢഃ㠃ࡢᙉ໬ࡣᴟࡵ࡚㔜せ࡛࠶ࡿ㸬 ᮏ஦ᴗࡣ㸪ᮏᏛ࡜ྡྂᒇ኱Ꮫ㸪ி㒔኱Ꮫ㸪஑ᕞ኱Ꮫࡀᵓ
⠏ࡋ࡚ࡁࡓ⥭ᐦ࡞኱Ꮫ㛫㐃ᦠࢆᇶ┙࡟㸪ࣜࢧ࣮ࢳࢺࣛࣥࢫ
ࣇ࢛࣮࣓࣮ࢩࣙࣥࢆᐇ㊶ࡋ㸪⤫ྜⓗ࡟Ꮫ㝿◊✲ࢆ᥎㐍ࡍࡿ㸬≉࡟㸪ゐ፹࣭࣐ࢸࣜ࢔࣭ࣝࣂ࢖࢜ᶵ⬟࡟↔Ⅼࢆᙜ࡚㸪ࡇࢀࡽ࡟㛵ࡍࡿ㔜せㄢ㢟ࡢᡓ␎ⓗᢳฟ࡜ゎỴ࡟ᣮࡴ㸬ḟୡ௦ࡢ◊✲ᇶ┙࡜࡞ࡿⰋ㉁࡞ࢹ࣮ࢱ࣮࣋ࢫࡢᵓ⠏࡜㸪ⱝᡭேᮦࡀᆅ⌮ⓗไ⣙ࢆ㉸࠼࡚ከᴟⓗ࡟ඹ๰࡛ࡁࡿඹྠ◊✲యไࢆᩚഛࡋᐇ㊶ࡍࡿ㸬ࡇࡢᅄ኱Ꮫ㛫ࡢ㐃ᦠ࡜㸪⏘Ꮫ࣭ᅜ㝿࣭༤ኈᩍ⫱㐃ᦠ࡜ࡢ┦஌ⓗ࡞᥎㐍࡟ࡼࡾ㸪ಶࡢඃ⚽ேᮦࡢⅬ࡜ࡋ࡚ࡢ⫱ᡂࢆ㉸࠼㸪ᡃࡀᅜࡢḟୡ௦ࢆᢸ࠺ேᮦࢆࢳ࣮࣒
ࡈ࡜⫱࡚ୖࡆࡿ㠃ⓗ࡞⫱ᡂࢆ㐩ᡂࡍࡿ㸬཯ᛂ࣭᪂ᶵ⬟ࡢ㛤ᣅ࡟㸪⥲ྜⓗほⅬ࠿ࡽྲྀࡾ⤌ࡴࡇ࡜ࡢ࡛ࡁࡿᙉຊ࡞◊✲⤌⧊ࡀᩚഛࡉࢀࡿ㸪◊✲ᶵ㛵㛫ࡢ⦆ࡸ࠿࡞㐃ᦠࡣḢ⡿ඛ㐍ㅖᅜ࡛ࡶᐇ᪋ࡉࢀ࡚࠸ࡿࡀ㸪ࡑࢀࡽࡢከࡃࡣ≉ᐃࢸ࣮࣐࡟㝈ᐃⓗ࡛࠶ࡿ㸬≀㉁๰〇໬Ꮫ◊✲ࢆ㠉᪂ࡋ㸪␗࡞ࡿ≀㉁㝵ᒙ࠾ࡼࡧ␗࡞ࡗࡓ≀㉁ኚ᥮ᴫᛕࢆໟᣓⓗ࡟᥎㐍ࡍࡿᮏ㐃ᦠ஦ᴗࡣ௚࡟㢮౛ࢆぢ࡞࠸ࡶࡢ࡛࠶ࡿ㸬࡟࠾࠸࡚ࡶᮏ஦ᴗ࡟㛵ࢃࡿඛᑟⓗ◊✲ࢆ᥎㐍ࡋ㸪ඃࢀࡓ◊✲ ᡂ ᯝ ࢆ ୖ ࡆ ࡚ ࠸ ࡿ 㸬 ࡇ ࢀ ࡽ ࡢ ᡂ ᯝ ࡣ Journal of theAmerican Chemical Society㸪Angewandte Chemie International
Edition㸪Chemical Communications࡞࡝ࡢ୍ὶᏛ⾡ㄅ࡟ከᩘㄽᩥ࡜ࡋ࡚Ⓨ⾲ࡉࢀࡓ㸬ᮏᖺᗘࡢᡂᯝ࡟ࡣ㸪ࠕ⏥Ẇ㢮࡜᳜≀ࡢ⣽⬊ቨ⏤᮶ࡢ࢜ࣜࢦ⢾ࢆ⏝࠸ࡓࣂ࢖࢜ࢫࢸ࢕࣑ࣗࣛ
ࣥࢺ㸦᳜≀ᡂ㛗ࡸච␿ࡢάᛶ໬㈨ᮦ㸧ࡢ〇ရ໬ࠖ㸦⚟ᒸ῟ᩍᤵ㸧㸪ࠕ࢔ࣥࣔࢽ࢔ࢆྜᡂࡍࡿᴟᚤ㔠ᒓࢡࣛࢫࢱ࣮ゐ፹㸫❅⣲ศᏊࡢษ᩿࡜࢔ࣥࣔࢽ࢔ࡢᣢ⥆ⓗྜᡂࢆ ࿴࡞᮲௳࡛ᐇ⌧㸫ࠖ㸦ΎỈ◊୍ᩍᤵ㸧㸪ࠕゐ፹⾲㠃࡟྾╔ࡋࡓศᏊࡢືࡁ࡜ศᏊኚ᥮㐣⛬ࢆྍど໬㹼ศᏊࡢືࡁࡀゐ፹ᛶ⬟࡟୚࠼ࡿᙳ㡪ࢆゎ᫂㹼ࠖ㸦㧘ⲡᮌ 㐩ᩍᤵ㸧➼ࡀ࠶ࡿ㸬 ຍ࠼࡚㸪ᮏᶵᵓࡢᨭ᥼ࢆཷࡅࡓ◊✲ࡀ᪂⪺࡛ሗ㐨ࡉࢀࡓ㸦୰㔝 ⎔ᩍᤵ㸪᪥หᕤᴗ᪂⪺㸪ࠕ୙つ๎࡛↓ᐃᙧ࡞㧗ศᏊ㸪㧗ຠ⋡࡞෇೫ගⓎග ໭኱ࡀゎ᫂ࠖ㸧㸬 ࡲࡓ㸪⤫ྜ◊✲ࣇ࢙࣮ࣟ࠾ࡼࡧᮏ஦ᴗࡢᨭ᥼ࢆཷࡅࡓ◊✲⪅ࡀ᪥ᮏࡢ୺せᏛ఍➼ࡢᏛ఍㈹ࢆཷ㈹ࡋࡓ㸦᪥ᮏ໬Ꮫ఍
➨ᅇᏛ⾡㈹㸦ΎỈ◊୍ᩍᤵ㸧㸦ᖺ᭶᪥㸧㸪National
Institute of Technology, Raipur, India 2023 Young Achiever
Alumnus Award㸦ࢩࣗࣟࢺࣜ࢔ࣅࢪࢵࢺຓᩍ㸧㸦ᖺ
᭶᪥㸧㸧㸬 ௨ୖࡢ◊✲࢔ࢡࢸ࢕ࣅࢸ࢕࣮ࢆᇶ┙࡜ࡋࡓⱝᡭ◊✲⪅ࡢ⫱ᡂ࡟ࡼࡾ㸪ே஦஺ὶࡀάⓎ࡟⾜ࢃࢀ㸪ⱝᡭ◊✲⪅ྡࡀ໭ᾏ㐨኱Ꮫᩍᤵ࡜ࡋ࡚㸪ⱝᡭ◊✲⪅ྡࡀ኱㜰኱Ꮫᩍᤵ࡜ࡋ࡚㸪ࡲࡓ㸪ⱝᡭ◊✲⪅ྡࡀ໭ᾏ㐨኱Ꮫ෸ᩍᤵ࡜ࡋ࡚
᪼㐍ࡋࡓ㸬ຍ࠼࡚㸪ⱝᡭ◊✲⪅㸰ྡࡀ໭ᾏ㐨኱Ꮫຓᩍ࡟᥇
⏝ࡉࢀࡓ㸬ࡲࡓ㛵㐃◊✲ᐊࡢ◊✲ᡂᯝࡀࡉࡲࡊࡲ࡞࣓ࢹ࢕
࢔ࢆ㏻ࡋ࡚㸪♫఍࡟ሗ㐨ࡉࢀࡓ ᖺ᭶㹼᪥࡟ࡣ㸪ᡂᯝሗ࿌఍࣭⏘Ꮫ࣮࣡ࢡࢩࣙࢵ
ࣉࡀ஑ᕞ኱Ꮫ⟃⣸࢟ࣕࣥࣃࢫ࡟࡚㛤ദࡉࢀ㸪ゐ፹⛉Ꮫ◊✲ᡤ࠿ࡽὸ㔝ᆂభ෸ᩍᤵࡀ◊✲ሗ࿌ࢆ⾜࠸㸪ຍ࠼࡚㸪௳ࡢ
࣏ࢫࢱ࣮Ⓨ⾲ࢆ⾜ࡗࡓ㸬ࡲࡓ㸪ᖺ᭶㹼᪥࡟ࡣ㸪➨㸰ᅇⱝᡭࡢ఍ࡀ኱㜰ᗓụ⏣ᕷ୙Ṛ⋤㛶࡟࡚㛤ദࡉࢀࡓ㸬ࡇࡢ఍㆟࡟ࡣⱝᡭᩍဨ㸪◊✲ဨ㸪኱Ꮫ㝔⏕ࡢࡳࡀฟᖍࡋ㸪」ᩘ኱Ꮫࡢⱝᡭ◊✲⪅㛫࡛ࡢ⮬ᚊⓗඹྠ◊✲ࢆ๰ฟࡍࡿ
ࡓࡵࡢ㆟ㄽ࠾ࡼࡧ᪂つ◊✲ࣉࣟࢪ࢙ࢡࢺࡢ๰᱌ࢆ⾜ࡗࡓ㸬ゐ፹⛉Ꮫ◊✲ᡤ࠿ࡽࡣ㸪㣤⏣೺஧෸ᩍᤵ㸪Ⳣ἟Ꮫྐ෸ᩍᤵ
ࡀฟᖍࡋࡓ㸬

IRCCS ᡂᯝሗ࿌఍࣭⏘Ꮫ࣮࣡ࢡࢩࣙࢵࣉ 2024 ᖺ 1 ᭶ 30 ᪥‫ࡢ࡛ࡲࢀࡇڦ‬ᡂᯝ ୺௵◊✲ဨྡ㸪⤫ྜ◊✲ࣇ࢙࣮ࣟྡࡢ㐃ᦠ◊✲యไ࡟ࡼࡾ㸪⤫ྜ≀㉁ᇶ┙◊✲㸦௳㸧࠾ࡼࡧⱝᡭ◊✲⪅ࢆ୰ᚰ
࡜ࡍࡿ⼥ྜ๰Ⓨ◊✲ࢆᐇ᪋ࡋ࡚࠸ࡿ㸬ᮏ஦ᴗ࡟ࡼࡿࢡࣟࢫ
࢔࣏࢖ࣥࢺ࣓ࣥࢺ≉௵ຓᩍ࡜ࡋ࡚ࡣᒣ⏣᪩ே༤ኈࡀ᥇⏝ࡉࢀࡓ㸦ゐ፹⌮ㄽ◊✲㒊㛛㸧࡜ࡋ࡚ຍ࠼࡚㸪㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮࡟㛤タࡋࡓᏛ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ࣘࢽࢵࢺ
IRCCS ➨㸰ᅇⱝᡭࡢ఍ 2023 ᖺ 5 ᭶ 15 ᪥‫ە‬ᖺሗ ࣭◊✲ᡤ⦅

15ㅮ₇఍࣭◊✲఍࡞࡝‫ ڦ‬ICAT International Symposium on Catalysis
2023: Novel theoretical and experimental
approaches for designing homogeneous catalysis
୺ദ㸸໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤඹദ㸸ゐ፹⛉Ꮫィඹྠ◊✲ᣐⅬ᪥᫬㸸2023ᖺ7᭶18᪥㸦ⅆ㸧㹼2023ᖺ7᭶19᪥㸦Ỉ㸧఍ሙ㸸໭ᾏ㐨኱Ꮫ๰ᡂ⛉Ꮫ◊✲Ჷ5㝵኱఍㆟ᐊᴫ␎㸸໭኱ゐ፹⛉Ꮫ◊✲ᡤ࡛ẖᖺᜏ౛ࡢ࢖࣋ࣥࢺ࡛࠶ࡿ➨10ᅇゐ፹⛉Ꮫ◊✲ᡤᅜ㝿ࢩ࣏ࣥࢪ࣒࢘ࢆ㛤ദࡋࡓ㸬௒ᅇࡶゐ፹࡟㛵㐃ࡍࡿᵝࠎ࡞ศ㔝ࢆ⼥ྜࡋࡓ◊✲ືྥ࡟ὀ┠ࡋ㸪༟㉺ࡋࡓ▱㆑࡜๰㐀ⓗ࡞◊✲ᡂᯝࢆࡶࡘࢺࢵࣉ◊✲⪅࡟ࡼࡿ᭱᪂ࡢ◊✲Ⓨ⾲ࢆ㏻ࡋ࡚㸪◊✲⪅㛫ࡢ஺ὶࢆᅗࡿࡇ࡜
ࢆ┠ⓗ࡜ࡋ࡚㛤ദࡋࡓ㸬௒ᖺᗘࡣ㸪ᆒ୍⣔ゐ፹࡟↔Ⅼࢆᙜ࡚ࠊᐇ㦂⛉Ꮫศ㔝࠾ࡼࡧィ⟬⛉Ꮫศ㔝࡟࠾ࡅࡿࢺࢵࣉࣛࣥ
ࢼ࣮ࡢ◊✲⪅8ྡ㸦ᾏእ2ྡ㸪ᅜෆ6ྡ㸧ࢆᣍ⪸ࡋ࡚㸪᭱᪂ࡢゐ፹◊✲࡟ࡘ࠸࡚ㅮ₇ࡋ࡚࠸ࡓࡔ࠸ࡓ㸬ᾏእ࠿ࡽࡣThe
Chinese University of Hong KongࡢYing Yeung Yeungᩍᤵ㸪Uppsala UniversityࡢMarcus Lundberg෸ᩍᤵ㸪ᅜෆ࠿ࡽࡣி
㒔኱Ꮫࡢᴬⱱዲᩍᤵ㸪❧ᩍ኱Ꮫࡢᒣ୰ṇᾈᩍᤵ㸪⌮໬Ꮫ◊✲ᡤࡢᶫᮏ༟ஓ୺௵◊✲ဨ㸪ி㒔኱Ꮫࡢᮾ㞞኱෸ᩍᤵ㸪໭ᾏ㐨኱Ꮫࡢቑ⏣ౡுຓᩍ㸪໭ᾏ㐨኱Ꮫࡢᯇᒸ࿴ຓᩍࢆ࠾ᣍ
ࡁࡋ㸪᭱ඛ➃ࡢゐ፹⛉Ꮫ࡟ࡘ࠸࡚ウㄽࡀ࡞ࡉࢀࡓ㸬ཧຍ⪅ࡣᾏእ࠿ࡽ3ྡ㸪ᅜෆ࠿ࡽ70ྡࡢྜィ73ྡ࡜࡞ࡗࡓ㸬

࠙July19th,2023ࠚ
09:00-09:40 Takuya Hashimoto (Chief Scientist, RIKEN)"Catalytic C-N bond formation enabled by a fluorosulfonylgroup"
09:50-10:30 Masahiro Higashi (Associate Professor, Kyoto
University)"Theoretical analysis of hybrid catalysis "10:30-10:50 Wataru Matsuoka (Assistant Professor, Hokkaido
University)"Virtual ligand-assisted screening toward computational
design of transition metal catalysts "11:00-11:40 Ying Yeung Yeung (Professor, The Chinese
University of Hong Kong)"Catalytic asymmetric halogenations and their synthetic
applications "11:40-11:50 Closing remark by Jun-ya Hasegawa (Professor,
ICAT)ㅮ₇఍ࡢᵝᏊ㸸2023ᖺ7᭶18᪥㹼7᭶19᪥ࡢ2᪥㛫࡟ࢃࡓࡾᑐ㠃ᙧᘧ࡛㛤ദࡉࢀ㸪┒఍ࡢ࠺ࡕ࡟⤊࠼ࡿࡇ࡜ࡀ࡛ࡁࡓ㸬ୖグࡢඛ⏕᪉࠿ࡽࡢᣍᚅㅮ₇࡟ຍ࠼࡚㸪Ꮫ⏕ࢆྵࡴⱝᡭ◊✲⪅࠿ࡽࡢ࣏ࢫࢱ࣮Ⓨ⾲ࡶࣞ࣋ࣝࡀ㧗ࡃ㸪άⓎ࡞㆟ㄽࡀ࡞ࡉࢀࡓ㸬ᡤឤ㸸ࢥࣟࢼ⚝ࢆ⤒࡚᪥ᖖࢆྲྀࡾᡠࡋࡘࡘ࠶ࡿ୰࡛㸪ࢺࢵࣉ◊✲⪅ࡀᮐᖠ࡟㞟ࡲࡾ㛤ദࡉࢀࡓᮏࢩ࣏ࣥࢪ࣒࡛࢘ࡣ㸪࣐ࢫࢡࢆእࡋ࡚ཧຍࡍࡿㅮ₇⪅࣭⫈ㅮ⪅ࡶከࡃぢࡽࢀ㸪⾲᝟㇏࠿࡞◊✲⪅࡟ࡼࡿ⇕㔞ࡢ࠶ࡿㅮ₇ࡸ࣏ࢫࢱ࣮Ⓨ⾲࡜ࡑࢀ࡟࿧ᛂࡍࡿάⓎ࡞㉁␲ࡀ⥆࠸ࡓ㸬ᅜෆእࡢ᭱ඛ➃⛉Ꮫ
ࢆⓎಙࡍࡿ࡜࡜ࡶ࡟㸪ᅜ㝿ⓗ࡞ேࡢ஺ὶࢆ⏕ࡳฟࡍ㈗㔜࡞ᶵ఍ࢆᥦ౪࡛ࡁࡓ㸬
ㅮ₇⪅࣭₇㢟㸸
࠙July 18th, 2023ࠚ
14:00-14:05 Opening remark by Ken-ichi Shimizu (Director,
ICAT)
14:10-14:50 Masahiro Yamanaka (Professor, Rikkyo
University)"Interplay between computation and experiment: design andunderstanding of conformationally-flexible asymmetriccatalysts"
15:00-15:40 Marcus Lundberg (Associate Professor, Uppsala
University)"Fingerprinting electronic structure of reaction intermediates
through X-ray spectroscopy simulations"
15:40-16:00 Yusuke Masuda (Assistant Professor, Hokkaido
University )"Photocatalytic transformation of organophosphorus
compounds through distonic radical cation intermediates"
16:10-16:50 Shigeyoshi Sakaki (Professor, Kyoto University)"Catalysis of transition metal complexes and related
compounds: theoretical approach to fundamental
understanding and prediction"
17:00-18:20 Poster presentation16‫ ڦ‬ICAT-FHI Symposium : Approaching to theCatalysis Reality୺ദ㸸໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ᪥᫬㸸2023ᖺ9᭶11᪥㸦᭶㸧11:00-15:00
఍ሙ㸸໭ᾏ㐨኱Ꮫ๰ᡂ⛉Ꮫ◊✲Ჷࢭ࣑ࢼ࣮࣮࣒ࣝB࣭Cᴫ␎㸸ࢻ࢖ࢶ࣭࣐ࢵࢡࢫࣉࣛࣥࢡ◊✲༠఍ࡢࣇࣜࢵࢶ࣭ࣁ࣮
ࣂ࣮◊✲ᡤ㸦௨ୗ㸪FHI㸧ࡣ๓㌟ࡢKaiser-Wilhelm Institutefor Physical Chemistry and Electrochemistryࡀ1911ᖺ࡟タ❧ࡉࢀ࡚௨᮶110ᖺࡢṔྐࢆࡶࡘ◊✲ᡤ࡛࠶ࡿ㸬ᮏ◊✲ᡤࡢ
๓㌟࡛࠶ࡿゐ፹◊✲ᡤࡢタ❧ࢆ୺ᑟࡉࢀࡓᇼෆᑑ㑻༤ኈ㸦➨㸰௦ᡤ㛗㸧ࡀ1932ᖺ࠿ࡽ◊✲ဨ࡜ࡋ࡚␃Ꮫࡋ㸪࣏ࣛࣥࢽ࣮༤ኈ࡜ඹྠ◊✲ࢆ⾜ࡗࡓࡇ࡜ࡀ㸪ᮏ◊✲ᡤ࡜FHIࡢ᭱ᖺሗ࣭◊✲ᡤ⦅‫ە‬ึࡢࡘ࡞ࡀࡾ࡟࡞ࡿ㸬ゐ፹⛉Ꮫ◊✲ᡤࡢ๓㌟࡛࠶ࡿゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࡣ㸪2005ᖺ࡟FHI࡜Ꮫ⾡஺ὶ༠ᐃࢆ⥾⤖ࡋ㸪௨᮶ᩘᖺ࠾ࡁ࡟ࢩ࣏ࣥࢪ࣒࢘ࡢ㛤ദࡸ◊✲⪅ࡢ ᮶ࢆ
㏻ࡋ࡚㸪◊✲ᡤ㛫ࡢᏛ⾡஺ὶࢆ῝ࡵ࡚ࡁࡓ㸬௒ᅇࡣ㸪FHI
ࡢKarsten Reuterᡤ㛗ࡀᮐᖠࢆ᮶ゼࡉࢀࡓࡇ࡜ࢆᶵ࡟ゐ፹◊࡬࠾ᣍࡁࡋ㸪ICAT-FHIࢩ࣏ࣥࢪ࣒࢘ࢆ㛤ദࡍࡿࡇ࡜࡜
࡞ࡗࡓ㸬Reuterᩍᤵࡣ2020ᖺࡼࡾ⌮ㄽ㒊㛛ࢆ୺ᐓࡉࢀ࡚࠸
ࡿ㸬ᮏࢩ࣏ࣥࢪ࣒࡛࢘ࡣ㸪Approaching to the Catalysis Realityࢆ୺㢟࡜ࡋ㸪ゐ፹཯ᛂࡢᐇീ࡟㏕ࡿࡇ࡜ࢆ┠ᶆ࡟ᥖࡆࡓ⌮ㄽ◊✲࡜⾲㠃ほᐹ࠾ࡼࡧゐ፹ᮦᩱタィ࡬ࡢᒎ㛤ࢆࢸ࣮࣐
࡜ࡋ࡚㸪Reuterᡤ㛗࡜ゐ፹◊㸱ྡࡢ◊✲⪅࡟ࡼࡿㅮ₇ࡀ࠶ࡗࡓ㸬Reuterᡤ㛗࠿ࡽࡣࢹ࣮ࢱ⛉Ꮫࢆ㥑౑ࡋࡓ᭱᪂ࡢࢩ
࣑࣮ࣗࣞࢩࣙࣥ࡟㛵ࡍࡿඛ㐍ⓗ࡞Ⓨ⾲ࡀ࠶ࡾ㸪ィ⟬࡟ࡼࡗ࡚ᑟ࠿ࢀࡿゐ፹⾲㠃ࡢ᪂ࡋ࠸ᥥീࡀ♧ࡉࢀࡓ㸬ゐ፹◊࠿ࡽࡣ㸪㧘ⲡᮌᩍᤵ㸪㣤⏣෸ᩍᤵ㸪㫽ᒇᑿຓᩍࡽ࡟ࡼࡿ᭱᪂ࡢ
◊✲⤂௓ࡀ࠶ࡾ㸪Reuterᡤ㛗࠿ࡽከࡃࡢ㉁ၥࡀᐤࡏࡽࢀ
ࡓ㸬
ㅮ₇఍ࡢᵝᏊ㸸2023ᖺ9᭶11᪥࡟ᑐ㠃ᙧᘧ࡛㛤ദࡉࢀ㸪┒఍ࡢ࠺ࡕ࡟⤊࠼ࡿࡇ࡜ࡀ࡛ࡁࡓ㸬ㅮ₇ࡢỈ‽ࡣᴟࡵ࡚㧗ࡃ㸪άⓎ࡞㆟ㄽࡀ࡞ࡉࢀࡓ㸬⣙50ྡࡢཧຍࡀ࠶ࡗࡓ㸬ᡤឤ㸸COVID-19ࡢឤᰁᣑ኱௨᮶㸪ゐ፹◊࡟࠾ࡅࡿᏛ⾡஺ὶ࢖࣋ࣥࢺࡀไ㝈ࡉࢀ࡚ࡁࡓࡀ㸪௒ᅇ㸪Reuterᡤ㛗ࢆ࠾ᣍ
ࡁࡋ࡚FHI࡜ࡢᏛ⾡஺ὶࢆ෌ጞື࡛ࡁࡓࡇ࡜ࢆ㠀ᖖ࡟႐ࡤࡋࡃឤࡌࡓ㸬FHI࡜ࡢඹྠ◊✲࡟Ⓨᒎࡋ࠺ࡿ◊✲ᡂᯝࢆ஺᥮ࡍࡿࡇ࡜ࡀ࡛ࡁࡓ㸬௒ᚋ㸪ᵝࠎ࡞ࢳࣕࣥࢿ࡛ࣝඹྠ◊✲㸪◊✲஺ὶࡀ㐍ᒎࡍࡿࡇ࡜ࢆᮇᚅࡋ࡚࠸ࡿ㸬
ㅮ₇⪅࣭₇㢟㸸
Chair: Jun-ya Hasegawa (Professor, ICAT)
11:00-11:05 Greeting, Prof. Ken-ichi SHIMIZU Director,
ICAT)
11:05-12:05 Prof. Karsten REUTER, Director, Theory
Department, Fritz-Haber- Institute(FHI) of Max-PlanckSociety(MPS)Out of the Crystalline Comfort Zone: ML-Empowered
Modelling of Operando Energy Conversion Systems
13:00-13:40 Prof. Satoru TAKAKUSAGI (ICAT)
Atomic-level visualization of surface catalytic reactions byin situ/operando surface science techniques
13:40-14:20 Associate Prof. Kenji IIDA (ICAT)The Effect of Bias Voltage on the Interface between an
Electrode Catalyst and an Electrolyte Solution Revealed by
Theoretical and Computational Approach
14:20-15:00 Assistant Prof. Takashi TOYAO (ICAT)
Data-driven catalyst design for CO2 hydrogenation reactions
15:00
Closing remark, Prof. Kiyotaka ASAKURA(ICAT)

‫ ڦ‬TU/e-ICAT Joint International Symposium on
Catalysis:Advanced Technologies for Sustainable
Society / ᝟ሗⓎಙᆺᅜ㝿ࢩ࣏ࣥࢪ࣒࢘
୺ ദ : ໭ ᾏ 㐨 ኱ Ꮫゐ ፹ ⛉ Ꮫ◊ ✲ ᡤ 㸪 Inorganic Materials
Chemistry, Eindhoven University of Technology (TU/e)ඹദ: ゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬ
༠㈶: ゐ፹Ꮫ఍
᪥᫬: 2023ᖺ11᭶1᪥㸦Ỉ㸧㹼2023ᖺ11᭶2᪥㸦ᮌ㸧఍ሙ: Zwarte Doos, Eindhoven,Tu/e, The Netherlansds
ᴫ␎࣭ㄽⅬ࡜ᡂᯝ㸸ᮏᅜ㝿ࢩ࣏ࣥࢪ࣒࢘ࡣ㸪᪥ᮏࡀ㄂ࡿゐ፹⛉Ꮫࡢ◊✲ᡂᯝࢆࠗ᪥ᮏࡢ◊✲ᶵ㛵ࡢ୺ᑟ࡛࠘ᾏእ࡟࠾࠸࡚᝟ሗⓎಙࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚௻⏬࣭㛤ദࡉࢀ࡚ࡁ
ࡓ㸬᪂ᆺࢥࣟࢼឤᰁᣑ኱ࡢண㜵ᥐ⨨ࡀ᏶඲᧔ᗫ࡜࡞ࡗࡓࡇ

‫ە‬ᖺሗ ࣭◊✲ᡤ⦅

࡜ࢆ㋃ࡲ࠼㸪࢜ࣛࣥࢲ㸪࢔࢖ࣥࢺ࣮࣍ࣇ࢙ࣥᕤ⛉኱Ꮫ࡟࡚2023ᖺ11᭶1-2᪥ࡢࢫࢣࢪ࣮࡛ࣗࣝᑐ㠃ᙧᘧ࡟࡚㛤ദࡋࡓ㸬ゐ፹⛉Ꮫ◊✲ᡤ࠾ࡼࡧゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬࡢⱝᡭ ◊ ✲ ⪅ ᨭ ᥼ ஦ ᴗ ࢆ ⥅ ⥆ ࡋ ࡚ ࠾ ࡾ 㸪 ᮏ ᖺ ᗘ ࡢ Young
Lectureship Azuma awardཷ㈹⪅ࡣ⸭ୗ⍞ᕹ༤ኈ㸦ᮾ໭኱Ꮫ㸧࡜Ᏻᮧ㥴స༤ኈ㸦ᮾி኱Ꮫ㸧࡛࠶ࡿ㸬ࡲࡓ㸪ᮏᖺᗘᮎ࡛ゐ፹⛉Ꮫ◊✲ᡤࢆᐃᖺ㏥ᐁࡉࢀࡿ⚟ᒸ῟ᩍᤵ࠾ࡼࡧᮅ಴Ύ
㧘ᩍᤵࡢゐ፹⛉Ꮫศ㔝࡟࠾ࡅࡿຌ⦼࣭㈉⊩ࢆグᛕࡋ࡚㸪ࡑࢀࡒࢀࡢඛ⏕᪉ࡢ㛵㐃ㅮ₇࡛⤌⧊ࡉࢀࡓࢭࢵࢩࣙࣥࢆཱྀ
㢌Ⓨ⾲ࣉࣟࢢ࣒ࣛ࡟タᐃࡋࡓ㸬㛤఍ᣵᣜ࡛ࡣ㸪୰ᓥᩍᤵ࠿ࡽᮾᕷ㑻ඛ⏕ࡢᴗ⦼࡜Young
Lectureship Azuma awardࡢタ❧ࡢ⤒⦋࡟ࡘ࠸࡚⤂௓ࡀ࠶ࡗࡓ㸬ึ᪥ࡢࣉࣟࢢ࣒ࣛࡣ㸪ゐ፹ἲࣂ࢖࣐࢜ࢫኚ᥮ࢆ୰ᚰ࡜
ࡋࡓㅮ₇ࡀタᐃࡉࢀࡓ㸬ලయⓗ࡟ࡣ㸪2௳ࡢPlenaryㅮ₇㸦⚟ᒸᩍᤵ㸪Bert Selsᩍᤵ㸧㸪3௳ࡢKeynoteㅮ₇㸦Moniek Trompᩍᤵ㸪ᾆᕝ⠜ᩍᤵ㸪၏⨾ὠᮌᩍᤵ㸧㸪2௳ࡢ౫㢗ㅮ₇㸦⸭ୗ⍞ᕹ༤ኈ㸪Michael Boot༤ኈ㸧࡛࠶ࡿ㸬2᪥┠ࡢࢭࢵࢩࣙ
ࣥࡣ㸪ᅛయゐ፹ࡢᵓ㐀ゎᯒࢆᚿྥࡋࡓ⾲㠃⛉Ꮫ࡟㛵ࡍࡿㅮ₇ࡀタᐃࡉࢀࡓ㸬ලయⓗ࡟ࡣ㸪2௳ࡢPlenaryㅮ₇㸦ᮅ಴ᩍᤵ㸪Bert Weckhuysenᩍᤵ㸧㸪3௳ࡢKeynoteㅮ₇㸦Kevin Wu
ᩍᤵ㸪Pieter Bruijnincxᩍᤵ㸪Harry Bitterᩍᤵ㸧㸪2௳ࡢ౫㢗ㅮ₇㸦Ᏻᮧ㥴స༤ኈ㸪Nikolay Kosinov༤ኈ㸧࡛࠶ࡿ㸬ᮏࢩ࣏ࣥࢪ࣒࢘ࡢཧຍ⪅⥲ᩘࡣ85ྡ㸪ゐ፹◊࠿ࡽࡢ9ྡࢆྵࡴ᪥ᮏேཧຍ⪅ࡢ⥲ᩘࡀ13ྡ࡛࠶ࡗࡓ㸬࣮ࣚࣟࢵࣃᆅᇦࡢゐ፹◊✲ࢆࡅࢇᘬࡍࡿ࢜ࣛࣥࢲ࣭࣋ࣝࢠ࣮࠿ࡽࡢཧຍ⪅ࡀከࡃ㸪㉁␲ᛂ⟅࡟࠾ࡅࡿάⓎ࡞㆟ㄽࢆ㏻ࡋ࡚ᅜෆእࡢᗈ࠸ୡ
௦ࡢᏛ⾡஺ὶࡀ㐩ᡂࡉࢀࡓ㸬
ㅮ₇⪅࣭₇㢟㸸
Day1: 1st November
13:00-13:05 Opening address Kiyotaka Nakajima (ICAT,
Hokkaido University)
13:05-13:10 Welcome address Emiel J.M. Hensen (TU/e)
13:10-13:40 Keynote Lecture Kevin C.-W. Wu (National
Taiwan University)"Catalytic Lignocellulos Biomass Conversion over MetalOrganic Frameworks (MOFs): Design of Catalysts andInvestigation of Reaction Mechanism "13:40-14:10 Keynote Lecture Pieter Bruijnincx (Utrecht
University)"Towards Molecular Redesign: On Biobased, Circular and
Safe Chemicals and Materials"
14:10-15:00 Plenary Lecture Atsushi Fukuoka (Hokkaido
University)"Depolymerization of cellulose and chitin by heterogeneous
catalysts"
15:30-16:20 Plenary Lecture Bert Sels (KU Leuven)“Lignin valorization using heterogeneous catalysts”
16:20-16:50 Keynote Lecture Harry Bitter (Wageningen
University & Research)“(Poly)saccharide conversion from thermal catalysis toelectro-catalysis”
16:50-17:10 Invited Talk
Mizuho Yabushita (Tohoku
University)"CeO2-Catalyzed Transformation of CO2-Captured Amines
into Value-Added Chemicals "17:10-17:30 Invited Talk Michael Boot (Vertoro)"Commercialization of Biomass Conversion – from Lab to
Pilot!!"
17:30-19:00 Poster session (20 posters) with borrel
Day2: 2nd November
09:00-09:30 Keynote Lecture Moniek Tromp (Universityof Groningen)“In Situ Spectroscopy for Catalysis and Energy Storage(batteries)”17

09:30-10:20 Plenary Lecturer Bert Weckhuysen (Utrecht
University)“Catalysts at the Level of Single Particles, Molecules andAtoms: Seeing is Believing?”
10:20-10:40 Invited Talk Nikolay Kosinov (TU/e)"Transient/operando Spectroscopy for Catalysis "11:10-11:40 Keynote Lecture Atsushi Urakawa (TU Delft)"Spatiotemporal operando methodologies on the reactor
scale for mechanistic and kinetic studies"
11:40-12:00 Invited Talk Shunsaku Yasumura (The
University of Tokyo)"Development of Low Temperature Methane Combustion
Catalysis using Automated Reaction Route Mapping"
13:00-13:30 Keynote Lecture Mizuki Tada (Nagoya
University)
͆Reaction Infography for Heterogeneous Catalysis͇
13:30-14:30 Plenary Lecture Kiyotaka Asakura (Hokkaido
University)
͆XAFS analysis on bimetallic particle catalysts - old but
still challenging targets”
14:30-15:00 Closing remarks‫ڦ‬ゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘
୺ദ㸸໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤෆእࡢ◊✲⪅࣭Ꮫ⏕㛫ࡢ◊✲ୖࡢ஺ὶࢆᅗࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚᭶1ᅇ⛬ᗘ㛤ദࡉࢀ࡚࠸ࡿࡶࡢ࡛࠶ࡿ㸬2005ᖺᗘ࠿ࡽ⥅⥆ⓗ࡟ᐇ᪋ࡋ㸪ⱝᡭ◊✲⪅ࡢ⫱ᡂࡢሙ࡜ࡋ࡚ࡢᙺ๭ࢆᯝ
ࡓࡋ࡚࠸ࡿ㸬2010ᖺᗘ㏵୰ࡼࡾྡ⛠ࢆࠕゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࢥ࣒ࣟ࢟࢘㸦Catalysis Research Center Colloquium㸧ࠖ࡜࠶ࡽࡓࡵ㸪࣓࣮ࣝ㓄ಙ࠾ࡼࡧ࢙࢘ࣈ࣮࣌ࢪ࡛ࡢ᱌ෆࢆࡼ
ࡾ඘ᐇࡉࡏ࡚࠸ࡿ㸬2015ᖺ10᭶࠿ࡽࡣᨵ⤌࡟క࠸ྡ⛠ࢆࠕゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘㸦Institute for Catalysis (ICAT)
Colloquium㸧ࠖ࡜ࡋ࡚࠸ࡿ㸬2023ᖺᗘࡣ➨446ᅇ࠿ࡽ➨463
ᅇࡲ࡛ࡢྜィ18ᅇ㛤ദࡋࡓ㸦㛤ദ⏦ㄳࡢ᫬ᮇࡢࡎࢀࡸㅮ₇⪅ࡢ㒔ྜ࡞࡝࡟ࡼࡿᘏᮇ➼ࡢࡓࡵ㸪ᅇᩘࡢ㡰ᗎ࡜᪥᫬ࡢ㡰ᗎࡣ␗࡞ࡗ࡚࠸ࡿሙྜࡀ࠶ࡿ㸬㸧㸬෗┿ࡣ㸪2023ᖺᗘࡢ᭱ึࡢࢥ࣒࡛ࣟ࢟࢘࠶ࡿ➨446ᅇࡢ࣏ࢫࢱ࣮㸬ࠓࠔෆࡣᢸᙜ
ᩍဨ㸬⏝࠸ࡓࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBࠓ㛗㇂ᕝ῟ஓࠔ
➨449ᅇࢥ࣒ࣟ࢟࢘ 2023/06/02 Ⳣ἟Ꮫྐ㸦໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ࣭෸ᩍᤵ㸧ࠕ࢔࣑ࣀ㓟ࡢỈ⣲໬࡟ࡼࡿྵ
❅⣲໬Ꮫရࡢཎᩱྜᡂࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊ
BCࠓ୰ᓥΎ㝯ࠔ
➨450ᅇࢥ࣒ࣟ࢟࢘ 2023/06/02 㔝ᮧ῟Ꮚ㸦ᮾிᕤᴗ኱
Ꮫ࣭௻⏬ᮏ㒊࣭ࢲ࢖ࣂ࣮ࢩࢸ࢕᥎㐍ᐊ࣭ᩍᤵ㸧ࠕ㉥እศගἲ࡟ࡼࡿゐ፹཯ᛂ࡟㛵ࡍࡿᐃ㔞ⓗ࡞ゎᯒࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBCࠓ୰ᓥΎ㝯ࠔ
➨451ᅇࢥ࣒ࣟ࢟࢘ 2023/06/05 ⚟⏣ఙ㸦໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ࣭㠀ᖖ໅◊✲㸧ࠕ኱Ꮫ࡛ࡢࠕ◊✲ࠖ࡜௻ᴗ࡛
ࡢࠕ㛤Ⓨࠖࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBCࠓᮅ಴Ύ㧘ࠔ➨452ᅇࢥ࣒ࣟ࢟࢘ 2023/06/05 㧘ⲡᮌ㐩㸦໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ࣭ᩍᤵ㸧ࠕࡑࡢሙ/࢜࣌ࣛࣥࢻ⾲㠃⛉Ꮫィ࡟ ࡼ ࡿ ゐ ፹ ཯ ᛂ ࡢ ཎ Ꮚ ࣞ ࣋ ࣝ ྍ ど ໬ , Atomic Level
Visualization of Surface Reaction by in situ / Operando
Surface Sicentific measurements ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑
ࢼ࣮ᐊ%&ࠓᮅ಴Ύ㧘ࠔ
➨453ᅇࢥ࣒ࣟ࢟࢘ 2023/06/12 ୖᮧὒᖹ 㸦European
XFEL GmbH࣭Dr.㸧ࠕStudying dynamics of photoexcitedmaterials using fs x-ray spectroscopies at XFELsࠖ๰ᡂ⛉Ꮫ◊✲Ჷ5㝵኱఍㆟ᐊࠓ㣤⏣೺஧ࠔ
➨454ᅇࢥ࣒ࣟ࢟࢘ 2023/06/20 Evgeny A. Pidko㸦TU
Delft࣭Professor㸧
ࠕChemistry automation to reduce expert
bias and navigate the mechanistic maze towards rational
catalyst designࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBCࠓ㫽ᒇᑿ 㝯ࠔ
➨455ᅇࢥ࣒ࣟ࢟࢘ 2023/07/26 ᮏ⏣ᗣ㸦HPCࢩࢫࢸ࣒ࢬ
ᰴᘧ఍♫࣭࢔ࢩࢫࢱࣥࢺ࣐ࢿ࣮ࢪ࣮ࣕ㸧ࠕ㔞Ꮚࢥࣥࣆ࣮ࣗࢱࡢᇶ♏▱㆑ 㹼㔞Ꮚࢥࣥࣆ࣮ࣗࢱࡢ≉ᚩ࣭ᇶ♏
⌮ㄽ࡜㔞Ꮚ໬Ꮫ࡬ࡢᛂ⏝㹼ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ5㝵኱఍㆟ᐊࠓ㛗㇂ᕝ῟ஓࠔ➨456ᅇࢥ࣒ࣟ࢟࢘ 2023/08/28 ୕Ꮿ⏤ᐶ 㸦රᗜ┴❧኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲⛉࣭ᩍᤵ㸧ࠕ࣊ࢸࣟཎᏊྵ᭷ȧඹᙺ໬ྜ≀ࡢྜᡂ࡜ᶵ⬟㹼࣋ࣥࢮࣥ⎔(ṇභゅᙧ)ࢆ࣊ࢸࣟ⎔ࡸṇከゅᙧ࡟⨨ࡁ᥮࠼ࡿ㹼ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBCࠓᾆཱྀ኱㍜ࠔ
➨457ᅇࢥ࣒ࣟ࢟࢘ 2023/09/11 ࣮࢝ࢫࢸࣥ ࣟ࢖ࢱ࣮
㸦 Fritz-Haber-Institut der Max-Planck-Gesellschaft ࣭
Director of the Theory Department㸧ࠕᶵᲔᏛ⩦ࢆά⏝ࡋࡓ࢚ࢿࣝࢠ࣮ኚ᥮ࢩࢫࢸ࣒ࡢ⌮ㄽࣔࢹࣝࠖ๰ᡂ⛉Ꮫ◊✲
Ჷ4㝵ࢭ࣑ࢼ࣮ᐊCࠓ㛗㇂ᕝ῟ஓࠔ
➨458ᅇࢥ࣒ࣟ࢟࢘ 2023/10/13 ໭ᕝᏹ㸦ி㒔኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲⛉࣭ᩍᤵ㸧ࠕከඖ⣲ࢼࣀྜ㔠ࡢ㛤Ⓨ࡜ᛂ⏝ᒎ㛤ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ5㝵኱఍㆟ᐊࠓ⚟ᒸ῟ࠔ➨446ᅇࢥ࣒ࣟ࢟࢘ 2023/04/07 ㇂ᇉಇ᫂㸦ᰴᘧ఍♫᪥❧〇సᡤ ◊✲㛤Ⓨࢢ࣮ࣝࣉ࣭୺௵◊✲ဨ㸧ࠕཎᏊศゎ⬟࣭࣍ࣟࢢࣛࣇ࢕࣮㟁Ꮚ㢧ᚤ㙾࡟ࡼࡿゐ፹ࢼࣀ⢏Ꮚࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBCࠓ⚟ᒸ῟ࠔ➨447ᅇࢥ࣒ࣟ࢟࢘ 2023/05/09 ᒣ⏣᪩ே㸦ྡྂᒇ኱ᏛᏛ
㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓ (IRCCS)࣭≉௵ຓᩍ㸧ࠕ࢝࢖ࢥఇ╀࡜ࣄࢺච␿ࡢࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBࠓ㛗㇂ᕝ῟ஓࠔ➨448ᅇࢥ࣒ࣟ࢟࢘ 2023/05/09 ኳụ୍┿㸦ྡྂᒇ኱Ꮫ≀㉁⛉Ꮫᅜ㝿◊✲ࢭࣥࢱ࣮࣭ຓᩍ㸧ࠕศᏊࢼࣀ࣮࢝࣎ࣥࢆ

18ᖺሗ࣭◊✲ᡤ⦅‫ە‬➨459ᅇࢥ࣒ࣟ࢟࢘ 2023/10/19 ᳃⏣ᑗྖ㸦ᮾி㎰ᕤ኱Ꮫ࣭ຓᩍ㸧
ࠕMOF࣭ᒙ≧ࢩࣜࢣ࣮ࢺࢼࣀ✵㛫ࢆ฼⏝ࡋࡓ⎔ቃ࣭࢚ࢿࣝࢠ࣮ᮦᩱタィ㹼௻ᴗ◊✲ࠊ࢔࢝ࢹ࣑࢔ࢆ㏻
ࡌ࡚㹼ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBࠓ㫽ᒇᑿ㝯ࠔ➨ 460 ᅇ ࢥ ࣟ ࢟ ࢘ ࣒  2023/11/14  Piyasan Praserthdam㸦 Chulalongkorn University ࣭ Professor 㸧ࠕ Catalyst
Deactivation in Selective Oxidation at Low Temperatureࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊAࠓ୰ᓥΎ㝯ࠔ
➨461ᅇࢥ࣒ࣟ࢟࢘ 2023/11/21 Feng-Shou Xiao㸦College
of Chemical Engineering, Zhejiang University, Hangzhou,
China࣭Professor㸧
ࠕGreen Synthesis of Zeolites and Rational
Preparation of Zeolite-Based Catalystsࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBࠓ⚟ᒸ῟ࠔ➨462ᅇࢥ࣒ࣟ࢟࢘ 2023/12/19 ṊᏳගኴ㑻㸦⟃Ἴ኱Ꮫᩘ⌮≀㉁⣔≀㉁ᕤᏛᇦ࣭ຓᩍ㸧ࠕ⾲㠃⛉Ꮫ࡟ᇶ࡙࠸ࡓ୙ᆒ୍⣔ゐ፹཯ᛂ࡜⏕యෆ཯ᛂ⣔ࡢ┦஌ⓗ⌮ゎࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBࠓ㧘ⲡᮌ㐩ࠔ➨ 463 ᅇ ࢥ ࣟ ࢟ ࢘ ࣒  2024/01/11  ๓ ⏣ ಟ Ꮥ 㸦 Kyushu
University, WPI-I2CNER-CESD࣭෸ᩍᤵ㸧ࠕࡑࡢሙ࣭࢜࣌
ࣛࣥࢻศගἲ 㹼೫ᕪ್㸲㸮࠿ࡽࡢᾏእ◊✲⏕ά㹼ࠖ๰ᡂ⛉Ꮫ◊✲Ჷ4㝵ࢭ࣑ࢼ࣮ᐊBCࠓ㫽ᒇᑿ㝯ࠔ‫ە‬ᖺሗ ࣭◊✲ᡤ⦅ᴾ

19ඝ᪃ểᚡ᥵ᴾ
history and recordἢ㠉 ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮㸦⌧ゐ፹⛉Ꮫ◊✲ᡤ㸧タ⨨௨㝆2023ᖺᗘࡲ࡛ࡢἢ㠉㸬
1989/05/29ࠓ
ࠓタ⨨ᨵᗫࠔ ゐ፹◊✲ᡤࢆᗫṆࡋࠕᅜ❧Ꮫᰯタ⨨ἲ᪋⾜つ๎ࠖࡢ୍㒊ᨵṇ࡟ࡼࡾ໭ᾏ㐨኱Ꮫ࡟඲ᅜඹྠ
฼⏝᪋タࡢࠕゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࠖ
㸦6◊✲㒊㛛࣭1ᐈဨ◊✲㒊㛛㸧ࡀタ⨨࣭ࠕ⾲㠃ᵓ㐀≀ᛶ㒊㛛ࠖ㸦ᐃဨ㸸ᩍᤵ1࣭
ຓᩍᤵ1࣭ຓᡭ2㸧ࡣᖹᡂඖᖺ࠿ࡽ2ࣨᖺ࡟ࢃࡓࡾᒸᓮᅜ❧ඹྠ◊✲ᶵᵓ࣭ศᏊ⛉Ꮫ◊✲ᡤࡢὶື◊✲㒊㛛࡜ࡋ࡚ྠ◊✲ᡤ㺀ศᏊ㞟ᅋ◊✲⣔࣭⏺㠃ศᏊ⛉Ꮫ◊✲㒊㛛㺁࡟㌿᥮
1989/05/29ࠓࢭࣥࢱ࣮㛗ࠔ ึ௦ࢭࣥࢱ࣮㛗࡟኱㔝බ⏨㸦⌮Ꮫ㒊ᩍᤵ㸧ᑵ௵
1990/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨2௦ࢭࣥࢱ࣮㛗࡟㔠ᒸ♸୍㸦⸆Ꮫ㒊ᩍᤵ㸧ᑵ௵
1991/04/01ࠓタ⨨ᨵᗫࠔࠕ⾲㠃ᵓ㐀≀ᛶ㒊㛛ࠖ㸦ᐃဨ㸸ຓᩍ
ᤵ1࣭ຓᡭ2㸧ࡀᖹᡂ3ᖺᗘ࠿ࡽࡉࡽ࡟2ࣨᖺ࡟ࢃࡓࡾᒸᓮ
ᅜ❧ඹྠ◊✲ᶵᵓ࣭ศᏊ⛉Ꮫ◊✲ᡤࡢὶື◊✲㒊㛛࡜ࡋ࡚ྠ◊✲ᡤࠕᴟ➃⣸እග⛉Ꮫ◊✲⣔࣭⏺㠃ศᏊ⛉Ꮫ◊✲㒊㛛ࠖ࡟㌿᥮
1991/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨3௦ࢭࣥࢱ࣮㛗࡟ᯇỌ⩏ኵ㸦⌮Ꮫ㒊ᩍᤵ㸧ᑵ௵
1992/04/01ࠓࢭࣥࢱ࣮㛗ࠔ ➨4௦ࢭࣥࢱ࣮㛗࡟ᘏ⯅୕▱ኵ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧ᑵ௵
1993/04/01ࠓタ⨨ᨵᗫࠔ ࠕ⾲㠃ᵓ㐀≀ᛶ㒊㛛ࠖࡀᒸᓮᅜ❧ඹྠ◊✲ᶵᵓ࣭ศᏊ⛉Ꮫ◊✲ᡤࡢὶື◊✲㒊㛛ࠕᴟ➃⣸እග⛉Ꮫ◊✲⣔࣭⏺㠃ศᏊ⛉Ꮫ◊✲㒊㛛ࠖ࠿ࡽ᚟ᖐ
1994/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨5௦ࢭࣥࢱ࣮㛗࡟ᮾᕷ㑻㸦ච␿⛉Ꮫ◊✲ᡤᩍᤵ㸧ᑵ௵
1996/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨6௦ࢭࣥࢱ࣮㛗࡟ᮾᕷ㑻㸦ච␿⛉Ꮫ◊✲ᡤᩍᤵ㸧෌௵
1997/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨7௦ࢭࣥࢱ࣮㛗࡟ᒾᮏṇ࿴㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧ᑵ௵
1998/04/09ࠓタ⨨ᨵᗫࠔ ᇶᖿ◊✲㒊㛛3㒊㛛9ศ㔝࣭ᐈဨ◊✲㒊㛛1㒊㛛2ศ㔝࡟ᣑ඘ᨵ⤌1999/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨8௦ࢭࣥࢱ࣮㛗࡟ᒾᮏṇ࿴㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧෌௵
2000/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨9௦ࢭࣥࢱ࣮㛗࡟㨶ᓮᾈᖹ㸦⌮Ꮫ◊✲⛉ᩍᤵ㸧ᑵ௵
2002/04/01ࠓࢭࣥࢱ࣮㛗ࠔ ➨10௦ࢭࣥࢱ࣮㛗࡟㧗ᶫಖ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧ᑵ௵
2004/04/01ࠓࢭࣥࢱ࣮㛗ࠔ ➨11௦ࢭࣥࢱ࣮㛗࡟㧗ᶫಖ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧෌௵
2006/04/01ࠓࢭࣥࢱ࣮㛗ࠔ ➨12௦ࢭࣥࢱ࣮㛗࡟ୖ⏣΅㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧ᑵ௵
2007/04/01ࠓタ⨨ᨵᗫࠔ ゐ፹ࢱ࣮ࢤࢵࢺ◊✲࢔ࢭࣥࣈࣜゐ፹ᇶ♏◊✲㒊7㒊㛛࡟ᣑ඘ᨵ⤌2008/04/01ࠓࢭࣥࢱ࣮㛗ࠔ ➨13௦ࢭࣥࢱ࣮㛗࡟ୖ⏣΅㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧෌௵
2010/04/01ࠓࢭࣥࢱ࣮㛗ࠔ ➨14௦ࢭࣥࢱ࣮㛗࡟⚟ᒸ῟㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧ᑵ௵

20

2012/04/01ࠓࢭࣥࢱ࣮㛗ࠔ ➨15௦ࢭࣥࢱ࣮㛗࡟⚟ᒸ῟㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧෌௵
2012/04/01ࠓ⤌⧊ࠔ ゐ፹ᇶ♏◊✲㒊࡟ゐ፹⌮ㄽ໬Ꮫ◊✲㒊㛛タ⨨
2013/04/01ࠓ⤌⧊ࠔ ᐇ⏝໬ᇶ┙ᢏ⾡㛤Ⓨ㒊タ⨨
2014/04/01ࠓࢭࣥࢱ࣮㛗ࠔ➨16௦ࢭࣥࢱ࣮㛗࡟ᮅ಴Ύ㧘㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ㸧ᑵ௵
2015/10/01ࠓ⤌⧊ࠔ ゐ፹⛉Ꮫ◊✲ᡤ࡟ᨵ⤌
2015/10/01ࠓᡤ㛗ࠔ ึ௦ᡤ㛗࡟ᮅ಴Ύ㧘㸦ゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸧ᑵ௵
2016/04/01ࠓᡤ㛗ࠔ➨2௦ᡤ㛗࡟ᮅ಴Ύ㧘㸦ゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸧෌௵
2018/04/01ࠓᡤ㛗ࠔ ➨3௦ᡤ㛗࡟㛗㇂ᕝ῟ஓ㸦ゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸧ᑵ௵
2020/04/01ࠓᡤ㛗ࠔ ➨4௦ᡤ㛗࡟㛗㇂ᕝ῟ஓ㸦ゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸧෌௵
2022/04/01ࠓᡤ㛗ࠔ➨௦ᡤ㛗࡟ΎỈ◊୍㸦ゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸧ᑵ௵
2023/01/01ࠓ⤌⧊ࠔ⏘ᴗ๰ฟㅮᗙ➼ࠕ࢔࢖ࢩࣥ໭኱5 'ࣛ࣎ࠖタ⨨㸦タ⨨ᮇ㛫㸸ᖺ᭶᪥ࡲ࡛㸧2023ᖺᗘࡢグ㘓᪥௜ࡢ࠶࡜ࡢ㸦㸧ࡘࡁᩘᏐࡣദ஦࡞࡝ࡢ㛤ദ᪥ᩘ㸬ࢥࣟ࢟
࣒࢘ࡢヲ⣽࡟ࡘ࠸࡚ࡣࠕㅮ₇఍࣭◊✲఍࡞࡝ࠖཧ↷㸬
2023/04/01ࠓே஦ࠔゐ፹ᵓ㐀◊✲㒊㛛࡟㧘ⲡᮌ㐩ᩍᤵ㸦ゐ፹⾲㠃◊✲㒊㛛෸ᩍᤵ㸧᪼௵
2023/04/01ࠓே஦ࠔゐ፹཯ᛂ◊✲㒊㛛Ⳣ἟Ꮫྐ෸ᩍᤵ㸦㫽ྲྀ኱Ꮫ෸ᩍᤵ㸧╔௵
2023/04/20ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2023/04/26ࠓ㐠Ⴀ༠㆟఍ࠔ➨ᅇ㐠Ⴀ༠㆟఍㸦ᣢࡕᅇࡾ㸧
2023/04/30ࠓே஦ࠔྂᕝ᳃ஓ෸ᩍᤵ㸦ゐ፹ᮦᩱ◊✲㒊㛛㸧㎡⫋㸦኱㜰኱Ꮫᩍᤵ㸧
2023/05/08ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍㸦ᣢࡕᅇࡾ㸧
2023/05/18ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2023/05/30ࠓ㐠Ⴀ༠㆟఍ࠔ➨ᅇ㐠Ⴀ༠㆟఍㸦ᣢࡕᅇࡾ㸧
2023/06/01ࠓே஦ࠔゐ፹⌮ㄽ◊✲㒊㛛ᐑᓮ⋹ຓᩍ㸦Fritz
Haber Institute of the Max Planck Society ࣭ postdoctoral
researcher㸧╔௵2023/06/15ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2023/07/20ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2023/09/06ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍㸦ᣢࡕᅇࡾ㸧
2023/09/11ࠓ㐠Ⴀ༠㆟఍ࠔ➨ᅇ㐠Ⴀ༠㆟఍ࠑ๰ᡂ⛉Ꮫ◊✲Ჷ㝵኱఍㆟ᐊ ZHE఍㆟ే⏝ ࠒ
2023/09/21ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑ࢜ࣥࣛ࢖ࣥ =RRP ࠒ
2023/09/22ࠓ㐠Ⴀ༠㆟఍ࠔ➨ᅇ㐠Ⴀ༠㆟఍㸦ᣢࡕᅇࡾ㸧ᖺሗ࣭◊✲ᡤ⦅‫ە‬

2023/10/19ࠓࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2023/10/24ࠓ㐠Ⴀ༠㆟఍ࠔ➨ᅇ㐠Ⴀ༠㆟఍㸦ᣢࡕᅇࡾ㸧
2023/10/30ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍㸦ᣢࡕᅇࡾ㸧
2023/11/01ࠓே஦ࠔゐ፹ᵓ㐀◊✲㒊㛛㩃㑥ຓᩍ㸦ゐ፹ᵓ㐀◊✲㒊㛛༤ኈ◊✲ဨ㸧╔௵
2023/11/01ࠓே஦ࠔゐ፹ᮦᩱ◊✲㒊㛛࡟㫽ᒇᑿ㝯෸ᩍᤵ㸦ゐ፹ᮦᩱ◊✲㒊㛛ຓᩍ㸧᪼௵
2023/11/16ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2023/12/19ࠓദ஦ࠔ࢖ࣥࢻᕤ⛉኱Ꮫ࢖ࣥࢻ࣮ࣝᰯ࡜㒊ᒁ㛫༠ᐃࢆ⥾⤖
2023/12/21ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍㸦ᣢࡕᅇࡾ㸧‫ە‬ᖺሗ ࣭◊✲ᡤ⦅

2024/01/23ࠓ㐠Ⴀ༠㆟఍ࠔ➨ᅇ㐠Ⴀ༠㆟఍ࠑ๰ᡂ⛉Ꮫ◊✲Ჷ㝵኱఍㆟ᐊ ZHE఍㆟ే⏝ ࠒ
2024/01/23ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2024/01/29ࠓദ஦ࠔࢪ࣮ࣙࢪ࢔㎰ᴗ኱Ꮫ࡜㒊ᒁ㛫༠ᐃࢆ⥾⤖
2024/02/05ࠓ㐠Ⴀ༠㆟఍ࠔ➨ᅇ㐠Ⴀ༠㆟఍㸦ᣢࡕᅇࡾ㸧
2024/02/15ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2024/03/21ࠓᩍᤵ఍ࠔ➨ᅇᩍᤵ఍ࠑゐ፹⛉Ꮫ◊✲ᡤ㛗ᐊࠒ2024/03/31ࠓே஦ࠔᮅ಴Ύ㧘ᩍᤵ㸦ゐ፹⾲㠃◊✲㒊㛛㸧㏥
௵2024/03/31ࠓே஦ࠔ⚟ᒸ῟ᩍᤵ㸦≀㉁ኚ᥮◊✲㒊㛛㸧㏥௵

21‫إ‬ԓὉؕᄽᄂᆮኒ
report: Department of Fundamental Researchゐ፹⌮ㄽ◊✲㒊㛛/Catalysis Theory
Research Division‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑ෸ᩍᤵࠒ㣤⏣೺஧࣭ࠑຓᩍࠒᐑᓮ
⋹[2023/06/01㹼]࣭ࠑᮾᾏᅜ❧኱Ꮫᶵᵓྡྂᒇ኱Ꮫ≉௵ຓᩍ≉௵ຓᩍࠒᒣ⏣᪩ே[2023/04/01㹼㸦ྡྂᒇ኱Ꮫ࡜ࡢࢡࣟ
ࢫ࢔࣏࢖ࣥࢺ࣓ࣥࢺᩍဨ㸧 ]ࠑ༤ኈ◊✲ဨࠒ Manussada
RATANASAK/ Sarinya HADSADEE࣭ࠑ-636 ≉ู◊✲ဨ3' ࠒⓑ⏨ᕝ㈗ྐ㹙㹼㹛࣭ࠑ⥲ྜ໬Ꮫ㝔/኱Ꮫ㝔༤ኈᚋᮇㄢ⛬ࠒᐑᕝ⩧/኱ᇛᾏ࣭ࠑ⥲ྜ໬Ꮫ㝔/኱Ꮫ㝔ಟኈㄢ⛬ࠒᖹ℩ࡦࡢࡁࠑ⌮Ꮫ㒊/Ꮫ㒊Ꮫ⏕ࠒຍ⸨๰/ᯈ಴ኸዉ
[2024/2/01㹼]࣭ࠑᏛ⾡◊✲ဨࠒ┒⏣⃈Ꮚ

ࡼ࠺࡞ゐ፹཯ᛂ⣔ࣔࢹࣝࡢලయ໬࡜ᢳ㇟໬㐣⛬ࢆ㏻ࡋ࡚㸪ゐ፹⌮ㄽ໬ᏛࢆᏛ⾡ⓗ࡟Ⓨᒎࡉࡏࡓ࠸㸬 ࡲࡓ㸪ࡇࢀࡽࡢ◊✲ࢆ㏻ࡋ࡚㸪⎔ቃゐ፹㸪࢚ࢿࣝࢠ࣮ࡢ
⏕⏘࡜ኚ᥮㸪໬ᡂရࡢ㧗ຠ⋡ྜᡂ࡞࡝㸪ᣢ⥆ྍ⬟࡞♫఍࡬ࡢኚ㠉࡟㈉⊩ࡋࡓ࠸࡜⪃࠼࡚࠸ࡿ㸬
1. CeO2ゐ፹࡟ࡼࡿ࢔ࣥࣔࢽ࢔SCR࡟࠾࠸࡚࢔ࣝ࢝ࣜ㔠ᒓ⿕ẘࢆ⦆࿴ࡍࡿFe/H2SO4ࢻ࣮ࣉࡢᙺ๭࡟㛵ࡍࡿ◊✲኱Ẽ୰ࡢ❅⣲㓟໬≀ࢆ㝖ཤࡍࡿゐ፹ࣉࣟࢭࢫ࡟ࡣ㸪⪏࢔ࣝ࢝ࣜ㔠ᒓᛶࢆഛ࠼ࡓ㑅ᢥゐ፹㑏ඖ㸦SCR㸧ࡢ㛤Ⓨࡀ୙ྍḞࡢㄢ㢟࡛࠶ࡿ㸬Fe ࠾ࡼࡧ H2SO4 ࢆࢻ࣮ࣉࡋࡓ CeO2 ゐ፹ࡣ㸪❅⣲㓟໬≀ࡢ㌿᥮⋡ࢆ㧗ࡃ⥔ᣢࡋ࡞ࡀࡽ㸪Ⰻዲ࡞࢔ࣝ
࢝ࣜ⪏ᛶࢆ♧ࡍࡇ࡜ࡀሗ࿌ࡉࢀ࡚࠸ࡿ (Khan, M.N.; Han,
L.: Wang. P.; and Zhang, D. iScience, 2020. 23(6), 101173㸧㸬ᮏ◊✲࡛ࡣ㸪⪏࢔ࣝ࢝ࣜ㔠ᒓᛶࢆ᭷ࡍࡿゐ፹ࡢ⥅⥆ⓗ࡞㛤Ⓨ࡟㈨ࡍࡿࡓࡵ࡟㸪ࢻ࣮ࣉࡉࢀࡓ Fe ࡜ H2SO4 ࡢᙳ㡪ࢆ⌮ゎࡍࡿࡇ࡜࡟↔Ⅼࢆᙜ࡚ࡓ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ࢔ࣝ࢝ࣜ㔠ᒓ⿕ẘࡢ㜵Ṇ࡟࠾ࡅࡿFe࡜H2SO4ࡢᙺ๭ࢆ᫂ࡽ࠿࡟ࡍࡿࡓࡵ࡟㸪ᐦᗘỗ㛵ᩘ⌮ㄽィ⟬ࢆ౑⏝ࡋ࡚ㄪᰝࡋࡓ㸬࣒࢝ࣜ࢘✀ࡀ CeO2⾲㠃ࡢ᱁Ꮚ㓟⣲ࢧ࢖ࢺࢆ༨᭷ࡍࡿࡇ࡜࡛ࣈࣞࣥࢫࢸࢵࢻ㓟ࢧ࢖ࢺࡢᙧᡂࢆጉࡆ㸪㑏ඖ๣࡛࠶ࡿ NH3ࡢ྾╔ࢆ㜼ᐖࡍࡿࡇ࡜ࡀ
᫂ࡽ࠿࡟࡞ࡗࡓ㸬ࢻ࣮ࣉࡉࢀࡓFe࡜H2SO4ࡣ㓟⣲✵Ꮝࡢᙧᡂࢆಁ㐍ࡍࡿ࡜࡜ࡶ࡟㸪」ᩘࡢ࣒࢝ࣜ࢘ཎᏊࢆᒁᅾ໬ࡍࡿ
ࡢࡓࡵࡢ≉ᚩⓗ࡞྾╔ࢧ࢖ࢺ(SO4/Fe_CeO2_Vo)ࢆ⏕ᡂࡋ‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
2023ᖺ4᭶࡟ᒣ⏣᪩ேࡀྡྂᒇ኱Ꮫ࡜ࡢࢡࣟࢫ࢔࣏࢖ࣥ
ࢺ࣓ࣥࢺᩍဨ࡜ࡋ࡚╔௵ࡋࡓ. 2023ᖺ6᭶࡟ᐑᓮ⋹ࡀຓᩍ࡜ࡋ࡚╔௵ࡋࡓ. 2024ᖺ2᭶Ꮫ㒊Ꮫ⏕ࡢᯈ಴ኸዉ㸦⌮Ꮫ㒊໬Ꮫ⛉㸧ࡀศᒓࡉࢀࡓ㸬2024ᖺ3᭶࡟ᐑᕝ⩧ࡀ༤ኈᚋᮇㄢ⛬ࢆ༢఩ྲྀᚓ㏥Ꮫࡋ㸪ᖹ℩ࡦࡢࡁࡀಟኈㄢ⛬ࢆಟ஢ࡋ㸪ຍ⸨๰ࡀ໬Ꮫ⛉ࢆ༞ᴗࡋࡓ㸬‫✲◊ڦ‬ㄢ㢟 ゐ፹཯ᛂࡢ࣓࢝ࢽࢬ࣒ࢆ⌮ㄽィ⟬࡟ᇶ࡙ࡃゎᯒ࡟ࡼࡗ࡚᫂ࡽ࠿࡟ࡋ㸪ゐ፹ཎ⌮࡟㛵ࡍࡿ᪂ࡋ࠸ᴫᛕࢆᥦ♧ࡍࡿࡇ࡜㸪ཬࡧ⌮ㄽゎᯒ࡟ᇶ࡙ࡃゐ፹タィࡸ཯ᛂタィ࡟㛵ࡍࡿᥦ᱌ࢆ⾜࠺ࡇ࡜ࢆ┠ᶆ࡜ࡋ࡚◊✲άືࢆ⾜ࡗ࡚࠸ࡿ㸬 ࡇࡢ┠ᶆࢆ㐩ᡂࡍࡿࡓࡵ࡟㸪ᐇ㦂ࢢ࣮ࣝࣉ࡜ࡢඹྠ◊✲ࢆ᥎㐍ࡋ㸪ゐ፹཯ᛂ⣔ࡢᮏ㉁ࢆ✲᫂ࡍࡿ㸬ྠ᫬࡟㸪」㞧࡞ゐ፹཯ᛂ⣔࡟࠾ࡅࡿ⌮ㄽⓗ◊✲ࡢ㐺⏝⠊ᅖࢆᣑ኱ࡍࡿࡇ࡜ࢆ㔜せ࡞ㄢ㢟࡜ࡋ࡚ᤊ࠼࡚࠾ࡾ㸪᪤Ꮡࡢ⌮ㄽィ⟬ᡭἲࢆ㉺࠼ࡓ㸪᪂ࡋ࠸ᡭἲࡢ㛤Ⓨࢆ┠ᣦࡋ࡚࠸ࡿ㸬 άᛶ࡞ゐ፹཯ᛂ⣔ࡣ㸪㟁Ꮚ≧ែ㸪ศᏊᵓ㐀㸪⁐፹࡞࡝ࡢ࿘㎶⎔ቃ࡜ࡢ┦஫స⏝㸪ືຊᏛ࡞࡝ᵝࠎ࡞ഃ㠃࡟࠾࠸࡚ᴟ
ࡵ࡚」㞧࡞⣔࡛࠶ࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿ㸬ࡇࡢࡼ࠺࡞」㞧
࡞ゐ፹཯ᛂ⣔ࡢᮏ㉁ࢆ᫂ࡽ࠿࡟ࡍࡿࡓࡵ࡟ࡣ㸪ヲ⣽࡞⌮ㄽィ⟬ࣔࢹࣝ࡟ᇶ࡙ࡃ௬᝿⌧ᐇࡢࣜ࢔ࣜࢸ࢕࣮ࢆ㏣✲ࡍࡿࡇ࡜ࡀᚲせ࡛࠶ࡿ㸬௚᪉࡛㸪ゐ፹⣔ࡢ≀⌮໬Ꮫⓗᮏ㉁ࢆᤊ
࠼ࡓࢩࣥࣉࣝ࡞⌮ㄽࣔࢹࣝࢆᵓ⠏ࡍࡿࡇ࡜࡛㸪ᐇ⏝ⓗ࠿ࡘᮏ㉁ⓗ࡞ィ⟬ࢆẚ㍑ⓗᐜ᫆࡟⾜࠺ࡇ࡜ࡀྍ⬟࡛࠶ࡿ㸬ࡇࡢ

2222

Fig. 1. A schematic illustration of H2SO4/Fe-doped CeO2
catalysts for NH3-SCR reaction. The K atoms are locallyadsorbed close to the H2SO4/Fe site, and more CeO2 sites areavailable for the NO reduction.

ࡓ㸬ࡇࢀ࡟ࡼࡾ㸪Fe࡜H2SO4ࡢ┦஌ຠᯝ࡟ࡼࡾ㸪CeO2⾲㠃
ࡢNH3 ྾╔ࢧ࢖ࢺࡀ࣒࢝ࣜ࢘⿕ẘ࠿ࡽචࢀࡿ㸬ࡇࢀࡽࡢ⤖ᯝࡣ㸪◲㓟࢖࢜ࣥࢆྵࡴ㔠ᒓ㓟໬≀ゐ፹࡟࠾ࡅࡿ࢔ࣝ࢝
ࣜ⿕ẘ⪏ᛶࢆ⌮ゎࡍࡿ࠺࠼࡛᭷⏝࡛㸪NH3-SCR ⏝ࡢ࢔ࣝ࢝ࣜ㔠ᒓ⪏ᛶࢆ᭷ࡍࡿゐ፹タィࡢᣦ㔪࡜࡞ࡾ࠺ࡿ㸬ᮏ◊✲ᡂᯝࡣ㸪J. Phys. Chem. Cㄅ࡟࡚බ⾲ࡋࡓ㸬
ࠓㄽᩥ6ࠔ
2. ࣇ࢙ࣀ࢟ࢩ࢖࣑ࣥ㓄఩Ꮚࢆ᭷ࡍࡿゐ፹࡟ࡼࡿ࢚ࢳࣞࣥ
㔜ྜ཯ᛂ࡟㛵ࡍࡿ◊✲
DFT ィ⟬ࢆ౑⏝ࡋ࡚㸪࢚ࢳࣞࣥ㔜ྜࢆಁ㐍ࡍࡿゐ፹཯ᛂࡢ࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ◊✲ࢆ⾜ࡗ࡚࠸ࡿ㸬ࡇࢀࡲ࡛㸪࢔ࣝ࢝ࣜ㔠ᒓ࢖࢜ࣥࢆ㓄఩ࡉࡏࡓࢡ࢚࣮ࣛ࢘ࣥࢸࣝࢆ᭷ࡍ
ࡿ Ni 㘒య࡞࡝࡟࠾ࡅࡿ㔜ྜ࣓࢝ࢽࢬ࣒ࡢ◊✲ࢆ⾜ࡗ࡚ࡁࡓ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ࣇ࢙ࣀ࢟ࢩ࢖࣑ࣥ (FI) 㓄఩Ꮚࢆ᭷ࡍࡿ㔠ᒓ㘒యࡣ࢚ࢳࣞࣥ㔜ྜࢆゐ፹ࡍࡿ㸬5ࡘࡢྍ⬟࡞ᖺሗ࣭◊✲ᐊ⦅‫ە‬␗ᛶయࡢ୰࡛㸪ඵ㠃యᙧ≧࡜ cis-N/trans-O/cis-Cl 㓄⨨ࢆ᭷ࡍࡿ␗ᛶయAࡣ㸪཯ᛂ๓ࡢTi-FI஧ሷ໬≀㘒య࡜ࡋ࡚᭱ࡶ
Ᏻᐃ࡛࠶ࡿ㸬άᛶ໬ࡉࢀࡓAࡣ㸪Ti-FI࡟ࡼࡿ㔜ྜ࣓࢝ࢽࢬ
࣒ࢆ◊✲ࡋࡓ㸬2␒┠ࡢ࢚ࢳࣞࣥᤄධࡀ㸪࢚ࢳࣞࣥ㔜ྜࡢᚊ㏿ẁ㝵࡛࠶ࡿ㸬IVB᪘㑄⛣㔠ᒓ(M=Ti㸪Zr㸪Hf)⨨᥮ࡢຠᯝࢆㄪ࡭ࡿࡓࡵ࡟㸪ᚊ㏿ẁ㝵ࡢάᛶ໬࢚ࢿࣝࢠ࣮
(EaRDS)ࢆẚ㍑ࡋࡓ㸬ィ⟬್ࡣ㸪Zr<Hf<Ti࡜࡞ࡾ㸪ゐ፹άᛶ࡟㛵ࡍࡿᐇ㦂⤖ᯝ࡜୍⮴ࡋࡓ㸬ࡉࡽ࡟㸪Ti-FIゐ፹ࡢ(O,X)㓄఩Ꮚ࡟ᑐࡍࡿ⨨᥮ࡢᙳ㡪ࢆㄪ࡭ࡓ㸬ࡑࡢ⤖ᯝ㸪EaRDS
ࡣ(O,N)>(O,O)>(O,P)>(O,S)࡛࠶ࡿࡇ࡜ࡀุ᫂ࡋࡓ㸬ࡋࡓࡀࡗ࡚㸪(O,S)㓄఩Ꮚࡣ㸪Ti-FIゐ፹ࡢゐ፹άᛶࢆྥୖࡉࡏࡿ
ྍ⬟ᛶࡀ᭱ࡶ㧗࠸࡜⪃࠼ࡽࢀࡿ㸬ࡲࡓ㸪άᛶ໬࢚ࢿࣝࢠ࣮
ࡀTi-X㊥㞳࡟┦㛵ࡍࡿࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡗࡓ㸬ࡉࡽ࡟㸪᪂
ࡋ࠸Ni࣮࣋ࢫࡢゐ፹࡟ࡘ࠸࡚ࡶ◊✲ࡋࡓ㸬ࡑࡢ⤖ᯝ㸪ᖹ㠃ṇ᪉ᙧᙧ≧ࡢFI(O,N)㓄఩Ꮚࢆ᭷ࡍࡿࢽࢵࢣࣝ(II)㘒య࡟ゐ፹άᛶࡀ࠶ࡿࡇ࡜ࢆ♧ࡋࡓ㸬ࡇࡢ◊✲ࡣ㸪ET㔜ྜ⏝ࡢMFIゐ፹ࡢタィ࡜㛤Ⓨ࡟౑⏝࡛ࡁࡿᇶ♏ⓗ▱ぢࢆᥦ౪ࡍࡿ
ࡶࡢ࡛࠶ࡿ㸬ᮏᡂᯝࡣ㸪J. Mol. Graph. Model.ㄅ࡟࡚බ⾲ࡋࡓ㸬ࠓㄽᩥࠔ

Fig. 2. Structure of M-FI catalyst for ethylene polymerization.

Screening and Sparsifying Operator (SISSO) ἲࢆ⏝࠸࡚ᵓ⠏ࡋࡓ. ୧ࢹ࣮ࢱࢆ⤌ࡳྜࢃࡏࡿࡇ࡜࡛, ࡑࢀࡒࢀࢆ༢⊂࡛⏝࠸ࡿࡼࡾࡶAIࡢண ᛶ⬟ࡀྥୖࡍࡿࡇ࡜ࢆぢฟࡋࡓ.
ࡲࡓ, AIࣔࢹࣝࡢᵓ⠏࡟౑⏝ࡉࢀࡓゐ፹ࡢ≉ᚩ㔞ࢆゎᯒࡍࡿࡇ࡜࡛, ࢥࣂࣝࢺࢩࣜࢣ࣮ࢺࡸࢥࣂࣝࢺࡢ㑏ඖᛶࡀ
CH3OH㑅ᢥ⋡࡟ᑐࡋ࡚㔜せ࡞ᙺ๭ࢆᣢࡘࡇ࡜ࡀ♧၀ࡉࢀ
ࡓ. ຍ࠼࡚, ྲྀᚓࢥࢫࢺࡀప࠸≉ᚩ㔞ࡢࡳࢆ⏝࠸࡚ᵓ⠏ࡋ
ࡓAI࡟ࡼࡗ࡚, CH3OH㑅ᢥ⋡ࢆྥୖࡉࡏࡿࢩࣜ࢝ᢸయ࡬
ࡢῧຍ㔠ᒓࢆண ࡋࡓ. ᮏ◊✲ᡂᯝࡣJ. Am. Chem. Soc. ㄅ࡟࡚බ⾲ࡋࡓ㸬ࠓㄽᩥ1ࠔ
4. ❅⣲ᯫᶫ」᰾ࣛࣥࢱࣀ࢖ࢻ㘒యࡢ☢໬⋡ࡢ⌮ㄽィ⟬࡟㛵ࡍࡿ◊✲ ༢୍ศᏊ☢▼ (SMM) ࡣ㸪ḟୡ௦ࡢ㧗ᐦᗘ᝟ሗグ᠈࠾ࡼࡧศᏊࢫࣆࣥࢺࣟࢽࢡࢫ࡟᭷ᮃ࡞ᮦᩱ࡛࠶ࡿ㸬㧗࠸ࣈࣟࢵ࢟ࣥࢢ ᗘࢆ♧ࡍᮦᩱ㛤Ⓨࡀồࡵࡽࢀ࡚࠾ࡾ㸪☢Ẽ≉ᛶ࡟ࡘ࠸࡚㸪㟁Ꮚᵓ㐀࡟ᇶ࡙ࡃྜ⌮ⓗ࡞⌮ゎࢆ☜❧ࡍࡿᚲせࡀ࠶ࡿ㸬ࡋ࠿ࡋ㸪ࡑࡢ㟁Ꮚᵓ㐀ࡣ」㞧࡛࠶ࡾ㸪༢⣧࡞DFTィ⟬࡟ࡼࡿ⌮ㄽⓗ◊✲࡛ࡣᅔ㞴࡞≧ἣ࡛࠶ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 N23̽ᯫᶫ」᰾ࢪࣛࣥࢱࢽࢻ㘒య㸪
{[(Me3Si)2N]2Ln(THF)( ȣ ̽ Ȟ 2: Ȟ 2-N2)(THF)Ln[(Me3Si)1̽ᗘࢆ♧ࡋ㸪ᛂ⏝ࡀ᭷ᮃどࡉ2N]2} ࡣ㸪㧗࠸ࣈࣟࢵ࢟ࣥࢢ
ࢀ࡚࠸ࡿ㸬ᮏ◊✲࡛ࡣ㸪㧗⢭ᗘἼື㛵ᩘ⌮ㄽ࡛࠶ࡿ
CASPT2/CASSCFἲ࠾ࡼࡧࢫࣆࣥ㌶㐨⤖ྜィ⟬࡟ᇶ࡙࠸࡚㸪」᰾ࣛࣥࢱࣀ࢖ࢻSMMࡢ☢໬⋡ࢆ⌮ㄽⓗ࡟◊✲ࡋࡓ㸬☢໬⋡ࡢ ᗘ౫Ꮡᛶ㸦ȮmT-T᭤⥺㸧ࡣ⌮ㄽィ⟬࡟ࡼࡾᐃ㔞ⓗ࡟෌⌧ࡉࢀ࡛ࡁࡓ㸬ࡇࢀࡽ㘒యࡢ㟁Ꮚ≧ែࡢ」㞧ࡉࡣ㸪ࣛࣥࢱࣀ࢖ࢻ4f࠾ࡼࡧN2ȧ*㌶㐨࡟࠾ࡅࡿ㠀ᖖ࡟ᙉ࠸㟼ⓗ㟁Ꮚ┦㛵࡜ࢫࣆࣥ㌶㐨┦஫స⏝࡟㉳ᅉࡍࡿࡇ࡜ࡀ᫂ࡽ࠿
࡟࡞ࡗࡓ㸬☢໬⋡ࡢ ᗘ౫Ꮡᛶࡣ㸪పບ㉳≧ែࡢ࢚ࢿࣝ
ࢠ࣮‽఩࡜☢Ẽ≉ᛶ࡟⏤᮶ࡍࡿ㸬50 K ᮍ‶ࡢȮmT್ࡣᇶᗏ≧ែ࡟ࡼࡗ࡚ᨭ㓄ࡉࢀࡿࡀ㸪పບ㉳≧ែࡢ⇕ศᕸࡣ50 Kࢆ㉸࠼ࡿȮmT ್࡟ᙳ㡪ࡍࡿ㸬ప ࡛ࡢ㣬࿴☢໬ࡶホ౯ࡉࢀ㸪⤖ᯝࡣᐇ㦂ほᐹ࡜ࡼࡃ୍⮴ࡋࡓ㸬ᮏ◊✲ࡢᡂᯝࡣ㸪J.
Phys. Chem. Aㄅ࡟࡚Ⓨ⾲ࡋࡓ㸬
ࠓㄽᩥ4ࠔ

3㸬
㸬AIࢆ⏝࠸ࡓ୙ᆒ୍⣔ゐ፹཯ᛂࡢࣔࢹࣝ໬ ୙ᆒ୍⣔ゐ፹཯ᛂࡣᵝࠎ࡞࣐ࣝࢳࢫࢣ࣮ࣝࣉࣟࢭࢫࡀ
⤡ࡳྜ࠺」㞧⣔࡛࠶ࡾ, ⌮ㄽ࠶ࡿ࠸ࡣᐇ㦂ⓗ࡞࢔ࣉ࣮ࣟ
ࢳࡀ༢⊂࡛⿵㊊࡛ࡁࡿࣉࣟࢭࢫࡣ㝈ࡽࢀ࡚࠸ࡿ. ࡑࡇ࡛ᡃࠎࡣ, ᐇ㦂࣭⌮ㄽࢹ࣮ࢱ࡟ྵࡲࢀࡿ᝟ሗࢆேᕤ▱⬟(AI)
࡟ࡼࡗ࡚⤫ྜࡍࡿࡇ࡜࡛, ࡍ࡭࡚ࡢゐ፹ࣉࣟࢭࢫࢆ࠶ࡽ
ࢃ࡟ྲྀࡾᢅ࠺ࡇ࡜࡞ࡃ, ゐ፹ᛶ⬟ࢆグ㏙ࡍࡿࣃ࣓࣮ࣛࢱ
ࢆ┤᥋ぢฟࡍ࢔ࣉ࣮ࣟࢳࡢ㛤Ⓨ࣭㐺⏝ࢆ㐍ࡵ࡚࠸ࡿ.
2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ࢩࣜ࢝ᢸᣢࢥࣂࣝࢺゐ፹࡟ࡼࡿ
CO2 Ỉ⣲໬཯ᛂࡢCH3OH㑅ᢥ⋡ࢆࢱ࣮ࢤࢵࢺ࡜ࡋ࡚, ᐇ㦂 ࣭ ⌮ ㄽ ࢹ ࣮ ࢱ ࢆ ⤌ ࡳ ྜ ࢃ ࡏ ࡓ AI ࢆ Sure-Independence

Fig. 4. Temparature dependence of magnetic susceptibility ofdilanthanide complexes. Theoretical results are given in lines,
and experimental data are given in parenthesis.

5. እሙୗ࡟࠾ࡅࡿゐ፹཯ᛂࡢ⌮ㄽⓗ◊✲Fig. 3. AI with experimental and theoretical data toward
identifying the key descriptive parameters for the CO 2hydrogenation by modified-silica supported cobalt catalysts.

‫ە‬ᖺሗ࣭◊✲ᐊ⦅ 㔠ᒓ㓟໬≀ୖ࡟ᢸᣢࡋࡓ㔠ᒓࢼࣀ⢏Ꮚࢆゐ፹࡜ࡍࡿỈ⵨Ẽᨵ㉁཯ᛂ࡟ࡘ࠸࡚㸪㟁ᅽࡢ༳ຍ࡛άᛶࡀྥୖࡍࡿࡇ࡜
ࡀሗ࿌ࡉࢀ࡚࠸ࡿ㸬ࡑࡇ࡛ᡃࠎࡣ㸪㟁ᅽࡢᙺ๭ࢆ᫂ࡽ࠿࡟
ࡍࡿ࡭ࡃ⌮ㄽィ⟬◊✲ࢆ㐍ࡵ࡚ࡁࡓ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ࡇࢀࡲ࡛ࡢ◊✲࠿ࡽ㸪㟁ᴟ㟁ሙ࡟ࡼࡗ࡚㔠ᒓ㓟໬≀⾲㠃ୖࢆ⛣ືࡋࡓࣉࣟࢺ࡛ࣥ཯ᛂࡀά

23ᛶ໬ࡉࢀࡿ࡜⪃࠼ࡽࢀ࡚࠸ࡿ㸬ࡑࡇ࡛ᡃࠎࡣ㸪TiO2ⷧ⭷⾲㠃࡟࠾࠸࡚Ỉ࠿ࡽゎ㞳ࡋࡓࣉࣟࢺࣥࡀ㟁ሙ࡟ࡼࡗ࡚⛣ືࡍࡿ㐣⛬ࡢ⌮ㄽィ⟬ࢆ⾜ࡗࡓ㸬ࡑࡢ⤖ᯝ㸪TiO2࡜ỈศᏊ࡜ࡢ㛫ࡢ໬Ꮫ⤖ྜࡢᙧᡂ࣭ษ᩿࡟ᨭ㓄ࡉࢀࡿ㔞ᏊຊᏛⓗ࡞┦஫స⏝ࡀ㟁ሙ࡟ࡼࡿ࢚ࢿࣝࢠ࣮ኚ໬ࢆỴᐃ࡙ࡅ࡚࠸ࡿࡇ
࡜ࡀ᫂ࡽ࠿࡟࡞ࡗࡓ㸬ࡇࡢᡂᯝࡣPhys. Chem. Chem. Phys.
ㄅ࡟࡚Ⓨ⾲ࡋࡓ㸬
ࠓㄽᩥ15ࠔ

 

Fig. 5. Proton transfer on the TiO2 surface induced by an external
electric field.

6. Alchemical perturbation DFTࢆࢆ⏝࠸ࡓᶵ⬟ᛶศᏊࡢタィἲ࡟㛵ࡍࡿ◊✲
 ೃ⿵࡜࡞ࡿศᏊࡀᏑᅾࡍࡿ໬Ꮫ✵㛫࡟࠾࠸࡚㸪ᡤᮃࡢᶵ⬟ᛶࢆᣢࡘศᏊࢆ᥈⣴ࡍࡿศᏊタィἲࢆ◊✲ࡋ࡚࠸ࡿ㸬᥈⣴ၥ㢟ࢆ໬Ꮫ✵㛫࡟࠾ࡅࡿ᭱㐺໬ၥ㢟࡜ࡋ࡚ᤊ࠼ࡿ࢔ࣉ
࣮ࣟࢳ࡟ࡣ࢜ࣜࢪࢼࣜࢸ࢕ࡀ࠶ࡿ㸬ຍ࠼࡚㸪᥈⣴㐣⛬࡛ศᏊᵓ㐀ࡢᏳᐃᛶࢆ⪃៖ࡍࡿࡇ࡜ࡣ㸪⌧ᐇⓗ࡞ศᏊࢆタィࡍࡿୖ࡛ᴟࡵ࡚㔜せ࡛࠶ࡾ㸪ᮏ◊✲ࡢ≉ᚩ࡛࠶ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ᖹ⾮ᵓ㐀࡟࠾ࡅࡿ໬Ꮫ⤌ᡂࢆኚ᭦ࡍࡿࡇ࡜࡟ࡼࡗ࡚ศᏊ≉ᛶࢆ᭱㐺໬ࡍࡿ㏫タィἲࢆᑟධࡋࡓ㸬ᡃࠎࡀ᭱㏆㛤ⓎࡋࡓศᏊタィἲࡢ᭱㐺໬࢔ࣝࢦࣜࢬ
࣒࡛ࡣ㸪ప࠸ィ⟬ࢥࢫࢺ୍࡛⯡ⓗ࡞≉ᛶࡢศᏊタィࢆྍ⬟࡟ࡍࡿಟṇࡀ࡞ࡉࢀࡓ㸬ᥦ᱌ࡉࢀࡓ᪉ἲࡣ࠸ࢃࡺࡿ
Quantum Alchemy࡟ᇶ࡙࠸࡚࠾ࡾ㸪⤒㦂ⓗࢹ࣮ࢱࢆᚲせ࡜ࡋ࡞࠸㸬(BF, CO)㸪(N2, CO), BNࢻ࣮ࣉ࣋ࣥࢮࣥㄏᑟయ, ࠾ࡼࡧ BNࢻ࣮ࣉࣈࢱࣥㄏᑟయࡢ࡞࡝㸪ᑠࡉ࡞໬Ꮫ✵㛫࡟࠾࠸࡚㟁Ẽ཮ᴟᏊ࣮࣓ࣔࣥࢺ࡜࢖࢜ࣥ໬࢚ࢿࣝࢠ࣮ࡢ᭱㐺໬࡟࠾ࡅࡿᮏᡭἲࡢ㐺⏝ᛶ࡜㝈⏺ࢆ◊✲ࡋࡓ㸬ศᏊ✀ࡢ᭦᪂࡟᥇⏝ࡉࢀࡓࢫ࣮࣒࢟࡟ࡼࡾ㸪᭱㐺໬ࡢ཰᮰ࡀ㏿ࡃ࡞ࡾ㸪ᚲせ࡞ィ⟬ࢥࢫࢺࢆపῶ࡛ࡁࡓ㸬ࡉࡽ࡟㸪㟁Ẽ཮ᴟᏊ࣮࣓ࣔࣥࢺ࡬ࡢQuantum Alchemyࡢ㐺⏝ྍ⬟ᛶ࡟ࡘ࠸࡚ࡶ
㆟ㄽࡋ㸬ᮏ◊✲ᡂᯝࡣ㸪J. Phys. Chem. Aㄅ࡟࡚බ⾲ࡋࡓ㸬ࠓㄽᩥࠔ

Fig. 6. Molecular design method for obtaining a functional
molecule by molecular optimization in a given chemical
space.

‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧ࣇࣜࢵࢶ࣭ࣁ࣮ࣂ࣮◊✲ᡤ M. Scheffler ᩍᤵ࣭L. Poppa ༤ኈࠕ୙ᆒ୍⣔ゐ፹཯ᛂ࡟ᑐࡍࡿ AI ࢔ࣉ࣮ࣟࢳࡢ㛤Ⓨࠖ/୰ᅜ ୖ ᾏ ኱ Ꮫ Zhang Dengsong ᩍ ᤵ ࠕ Selective Catalytic

2424

Reduction of NOx with NH3 by solid catalystࠖ/໭ᾏ㐨኱Ꮫ⌮Ꮫ◊✲㝔໬Ꮫ㒊㛛⃝ᮧṇஓᩍᤵࠕ㖡ゐ፹࡟ࡼࡿග୙ᩧ࢔ࢩ
ࣝ໬཯ᛂ࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ◊✲ࠖ/ᮾி኱Ꮫ኱Ꮫ㝔ᕤᏛ⣔◊✲⛉Ỉ㔝ဴᏕᩍᤵ࣭ᒣཱྀ࿴ஓᩍᤵࠕᢸᣢ㔠ࢡࣛࢫࢱ࣮
࡟ࡼࡿ C-H άᛶ໬ࡢ࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ◊✲ࠖ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࣭୰ᓥ⏤⨾Ꮚࢳ࣮࣒࣮ࣜࢲ࣮ࠕ࢔ࣝ࢟ࣝᇶ㌿⛣ࡢ཯ᛂᶵᵓ࡟㛵ࡍࡿ⌮ㄽⓗ◊✲ࠖ/ᮾிᕤᴗ኱Ꮫ≀㉁⌮ᕤᏛ㝔ᒣ୰୍㑻ᩍᤵࠕ࣓ࢱࣥάᛶ໬࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ◊✲ࠖࠕ஧㓟໬Ⅳ⣲ࡢ㟁ゎ㑏ඖ࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ◊✲ࠖ/ྡྂ
ᒇ኱ᏛᕤᏛ◊✲⛉▼ཎ୍ᙲᩍᤵࠕ᭷ᶵゐ፹࡟ࡼࡿ୙ᩧ
[2+2]⎔໬཯ᛂࡢ࣓࢝ࢽࢬ࣒ࠖ/ி㒔኱ᏛᕤᏛ◊✲⛉ᮡ㔝┠㐨⣖ᩍᤵࠕࡽࡏࢇ㧗ศᏊゐ፹࡟ࡼࡿࣄࢻࣟࢩࣜࣝ໬࡟㛵ࡍࡿ⌮ㄽⓗ◊✲ࠖ/ி㒔኱ᏛᕤᏛ◊✲⛉⸨ཎဴᬗᩍᤵࠕࣃࣛࢪ࣒࢘ゐ፹࡟ࡼࡿศᏊ㛫Ⅳ⣲-Ỉ⣲⤖ྜ࢔࣮ࣜࣝ໬཯ᛂ࡟࠾
ࡅࡿ࢝ࣝ࣎࢟ࢩࣛࢺ㓄఩Ꮚࡢ❧యຠᯝࠖ/኱㜰኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ᯘ㧗ྐᩍᤵࠕ෌ᵓᡂ࣑࢜ࢢࣟࣅࣥ࡟ࡼࡿࢩࢡࣟ
ࣉࣟࣃࣥ໬཯ᛂ࡟㛵ࡍࡿ⌮ㄽⓗ◊✲ࠖ/኱㜰኱Ꮫ኱Ꮫ㝔⸆Ꮫ◊✲⛉᭷⃝ගᘯᩍᤵࠕ㔠ᒓ㘒యゐ፹࡟ࡼࡿศᏊෆ⎔໬཯ᛂ࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ◊✲ࠖ/໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ⚟ᒸ῟ᩍᤵࠕ࢟ࢳࣥࡢຍỈศゎᶵᵓ࡟㛵ࡍࡿ⌮ㄽⓗ◊✲ࠖ/໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᮅ಴Ύ㧘ᩍᤵࠕ஧㓟໬Ⅳ⣲ࡢ㟁ゎ㑏ඖࢆಁ㐍ࡍࡿࢥࣂࣝࢺゐ፹ࡢᵓ㐀࡟㛵ࡍࡿ◊✲ࠖ/኱㜰኱ᏛᕤᏛ◊✲⛉ྂᕝ᳃ஓᩍᤵࠕ㟁ຊࢆ฼⏝ࡍࡿゐ፹཯ᛂࡢᶵᵓࠖ/⟃Ἴ኱Ꮫィ⟬⛉Ꮫ◊✲ࢭࣥࢱ࣮▮ⰼ୍ᾈᩍᤵ
ࠕࢼࣀᵓ㐀యࡢගບ㉳㟁Ꮚࢲ࢖ࢼ࣑ࢡࢫࠖ/ி㒔኱Ꮫ໬Ꮫ◊✲ᡤᑎす฼἞ᩍᤵ࣭బ⸨Ⰻኴຓᩍࠕࣉࣛࢬࣔࢽࢵࢡྜ㔠ࢼࣀ⢏Ꮚࡢ๰ᡂࠖ/㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫඵ஭ᓫᩍᤵ࣭ᮾி⌮⛉኱Ꮫ᰿ᓊ㞝୍ᩍᤵ࣭ᮾி⌮⛉኱Ꮫᕝ⬥ᚨஂㅮᖌࠕᢸᣢࡋࡓ
᭷ᶵ㔠ᒓ㘒యࡸ㔠ᒓࢼࣀࢡࣛࢫࢱ࣮ࢆ⏝࠸ࡿゐ፹ࡢ㛤Ⓨࠖ/࢔ࣝࣂ࣮ࢱ኱Ꮫ Andriy KOVALENKO ᩍᤵࠕ㟁ᴟゐ፹཯ᛂࡢ⌮ㄽィ⟬ᡭἲࡢ㛤Ⓨࠖ/ Uppsala ኱Ꮫ Marcus Lundberg ෸ᩍᤵ࣭European XFEL ୖᮧὒᖹ༤ኈࠕෆ᰾ X ⥺Ⓨගࢫ࣌ࢡࢺࣝ࡟㛵ࡍࡿ◊✲ࠖ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦඲࡚ᑂᰝࡘࡁ㸧(1) Miyazaki, R.; Belthle, K. S.; Tüysüz, H.; Foppa, L.;
Scheffler, M. Materials Genes of CO2 Hydrogenation on
Supported Cobalt Catalysts: an AI Approach Integrating
Theoretical and Experimental Data. J. Am. Chem. Soc., 2024,
146, 5433–5444.
(2) Dostagir, N. H. M.; Tomuschat, C. R.; Oshiro, K.; Gao, M.;
Hasegawa, J.; Fukuoka, A.; Shrotri, A. Mitigating the
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Methanol over Co-Containing Dual-Atom Oxide Catalysts.
JACS Au 2024, 4, 1048-1058.
(3) Takekuma, H.; Sato, R.; Iida, K.; Kawawaki, T.; Haruta, M.;
Kurata, H.; Nobusada, K.; Teranishi, T. Intrinsic Visible
Plasmonic Properties of Colloidal PtIn2 Intermetallic
Nanoparticles. Adv. Sci. 2024, 11, 2307055.
(4) Chen, Y.; Miyazaki, R.; Sakaki, S.; Hasegawa, J. A MultiConfigurational Wave Function Theoretical Study on
Electronic Structure and Magnetic Susceptibility ofDilanthanide Single Molecule Magnet. J. Phys. Chem. A,
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ᖺሗ࣭◊✲ᐊ⦅‫ە‬

additives. J. Phys. Chem. C 2023, 127, 18914–18925.
(7) Deng, J.; Cai, S.; Gao, M.; Hasegawa, J.; Yao, H.; Shen, Y.;
Si, .; Song, J.; Zhang, D. Crystal-in-amorphous Vanadate
Catalysts for Universal Poison-Resistant Elimination of Nitric
Oxide. ACS Catal. 2023, 13, 12363-12373.
(8) Iida, K.; Takeuchi, T.; Katsumi, R.; Yatsui, T. Variations in
Photoexcitation Mechanism of an Adsorbed Molecule on aGold Nanocluster Governed by Interfacial Contact. J. Phys.
Chem. A 2023, 127, 7718–7726.
(9) Liu, C.; Lu, B.; Ariga-Miwa, H.; Ogura, S.; Ozawa, T.;
Fukutani, K.; Gao, M.; Hasegawa, J.; Shimizu, K.; Asakura,
K.; Takakusagi, S. Dynamic Behavior of Intermediate
Adsorbates to Control Activity and Product Selectivity in
Heterogeneous Catalysis: Methanol Decomposition on
Pt/TiO2(110). J. Am. Chem. Soc. 2023, 145, 19953-19960.
(10) Apilardmongkol, P.; Ratanasak, M.; Hasegawa, J.; Parasuk,
V. DFT insight into metals and ligands substitution effects onreactivity of phenoxy-imine catalysts for ethylene
polymerization. J. Mol. Graph. Model. 2023, 125, 108586.
(11) Ohmura, S.; Katagiri, K.; Kato, H.; Horibe, T.; Miyakawa,
S.; Hasegawa, J.; Ishihara, K. Highly Enantioselective Radical
Cation [2+2] and [4+2] Cycloadditions by Chiral Iron(III)Photoredox Catalysis. J. Am. Chem. Soc. 2023, 145, 1505415060.
(12) Yamashita, K.; Sato, K.; Tanji, Y.; Hasegawa, J.; Fujihara,
T. Paddle-Wheel Dirhodium Complexes Bearing Bulky
Carboxylate Ligands: Synthesis and Catalysis in Carbene
Insertion Reactions. Chem Asian J. 2023, 18, e202300223.
(13) Shiraogawa, T.; Hasegawa, J. Optimization of General
Molecular Properties in the Equilibrium Geometry Using
Quantum Alchemy: An Inverse Molecular Design Approach.
J. Phys. Chem. A, 2023, 127, 4345-4353.
(14) Kawawaki, T.; Mitomi, Y.; Nishi, N.; Kurosaki, R.; Oiwa,
K.; Tanaka, T.; Hirase, H.; Miyajima, S.; Niihori, Y.; Osborn,
D. J.; Koitaya, T.; Metha, G. F.; Yokoyama, T.; Iida, K.;
Negishi, Y. Pt17 Nanocluster Electrocatalysts: Preparation andOrigin of High Oxygen Reduction Reaction Activity.
Nanoscale 2023, 15, 7272-7279.
(15) Chiba, T.; Iida, K.; Furukawa, S.; Hasegawa, J. FirstPrinciples Study on Unidirectional Proton Transfer on Anatase
TiO2 (101) Surface Induced by External Electric Fields. Phys.
Chem. Chem. Phys. 2023, 25, 9454-9460.
(16) Zhao, X.; Ratanasak, M.; Kon, K.; Hasegawa, J.; Ishihara,
K. Bulky magnesium(II) and sodium(I) bisphenoxide catalysts
forchemoselective
transesterificationof
methyl‫ە‬ᖺሗ࣭◊✲ᐊ⦅(meth)acrylates. Chem. Sci. 2023, 14, 566-572.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟(1)Ratanasak, M.; Ishihara, K.; Hasegawa, J.: “Elucidating the
Chemoselective Transesterification Mechanism of Novel
Mg(II) and Na(I) Bisphenoxide Catalysts for Industrial
Applications”, The 8th Japan-Thai Workshop on Theoreticaland Computational Chemistry 2023 & The 8th International
Workshop on Quantum Chemistry, Yokohama City University,
Yokohama, Japan, (2024/1/19-21). [Invited talk](2) Hasegawa, J.: "Computational Chemistry with External
Force for Investigation of Reaction Mechanisms", The Path ofQuantum Chemistry into the 21st Century, ETH Zurich,
Switzerland, (2024/1/16-18). [Invited talk](3) Iida, K.: "The Effect of Bias Voltage on the Interface between
an Electrode Catalyst and an Electrolyte Solution Revealed by
Theoretical and Computational Approach", ICAT-FHI
Symposium: Approaching to the Catalysis Reality, Institute for
Catalysis, Sapporo, Japan, (2023/9/11). [Invited talk](4) 㛗㇂ᕝ῟ஓ:ࠕእຊࢆᑟධࡋࡓィ⟬໬Ꮫ࡟ࡼࡿ཯ᛂᶵᵓ
◊✲ࠖ㸪➨㸶ᅇ FlowST ࢩ࣏ࣥࢪ࣒࢘㸪࢖࢖ࣀ࣮࣍ࣝ,(2024/2/9). [Invited talk](5) ᐑᓮ⋹:ࠕ⌮ㄽィ⟬࡜ AI ࢆά⏝ࡋࡓゐ፹཯ᛂ࡬ࡢ࢔ࣉ
࣮ࣟࢳࠖ㸪◊✲఍ࠕจ⦰⣔ࡢ⌮ㄽ໬Ꮫࠖ㸪Ἀ⦖┴ᕷ⏫ᮧ⮬἞఍㤋, (2024/3/26-27).[Invited talk](6) 㛗㇂ᕝ῟ஓ:ࠕ⣔㛫஺ᕪࢆ⤒⏤ࡍࡿ໬Ꮫ཯ᛂᶵᵓࠖ㸪
QCRI ࢭ࣑ࢼ࣮㸪㔞Ꮚ໬Ꮫ◊✲༠఍, (2023/11/20). [Invitedtalk](7) 㛗㇂ᕝ῟ஓ:ࠕィ⟬໬Ꮫ࡟ࡶ࡜࡙ࡃ≀ᛶไᚚ࣭཯ᛂไ
ᚚࠖ㸪ࢹ࣮ࢱ㥑ືᆺᮦᩱタィᢏ⾡฼⏝᥎㐍ࢥࣥࢯ࣮ࢩ࢔࣒ ➨ 11 ᅇࢭ࣑ࢼ࣮㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ㸦⮫ᾏ๪㒔ᚰࢭࣥࢱ࣮㸧, (2023/11/17). [Invited talk]ཷ㈹
(1) 㣤⏣೺஧ࡽ㸪
ࠕSALMON㸦Scalable Ab-initio Light-Matter
simulator for Optics and Nanoscience㸧ࠖ㸦2023/5/19㸧
ࠓ2023
ᖺᗘ HPCI ࢯࣇࢺ࢙࢘࢔㈹ዡບ㈹ࠔ
(2) Oshiro, K., ࠕ Mechanistic study of the alkali tolerance
mechanism of H2SO4/Fe_CeO2 catalyst for NH3-SCRࠖ, The
5th conference of Theory and Applications of Computational
Chemistry (TACC2023), Hokkaido University (2023/9/4-9)
ࠓPoster Prize by HPC Systems Inc.ࠔ

25ゐ፹⾲㠃◊✲㒊㛛/ Catalyst Surface
Research Divisio(a)‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒᮅ಴Ύ㧘࣭ࠑ༤ኈ◊✲ဨࠒCan LIU/Qing WANG࣭ࠑJSPSእᅜே≉ู◊✲ဨࠒWeiren CHENG[㹼2024/2/25] ࠑ㠀ᖖ໅◊✲ဨࠒ⚟⏣ఙ࣭ࠑእᅜே◊✲ဨࠒDaniela Maria PIZZONE
㹙2023/05/01㹼2023/06/05㹛/Shuowen BO㹙2024/03/01㹼㹛࣭ࠑᕤᏛ㝔/኱Ꮫ㝔༤ኈㄢ⛬ࠒBang LU[㹼2023/9/30]/ Chorong KIM/
Kiyue DONGࠑᕤᏛ㝔/኱Ꮫ㝔ಟኈㄢ⛬ࠒChenhao YANG㹙㹼
2023/09/30㹛/ᐩᡤ⪽୍࣭ࠑᕤᏛ㒊/Ꮫ㒊Ꮫ⏕ࠒ஭ཱྀ཭㈗/๓⏣࡯ࡢ࠿/ᶓᒣᬛ⣖࣭ࠑ◊✲ဨ(◊✲᥎㐍ᨭ᥼ᩍᤵ)ࠒᒣᮏ㈆࣭᫂
ࠑ஦ົ⿵ຓဨࠒ℈ୖඃᏊ[㹼2023/4/30]/⚄ཎ༓ᫍ[2023/7/1㹼](b)‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
2023 ᖺ 4 ᭶஭ཱྀ཭㈗㸪๓⏣࡯ࡢ࠿㸪ᶓᒣᬛ⣖ࡀ᪂ 4 ᖺ⏕࡜ࡋ࡚ຍࢃࡗࡓ㸬 Bang LU ࡀ 9 ᭶࡟༤ኈྕࢆྲྀᚓ㸪Chenhao Yang㸦ಟኈ㸧࡜࡜ࡶ࡟༞ᴗࡋࡓ㸬Chorong Kim ࡣ༤ኈྕࢆ 3 ᭶࡟ྲྀᚓ㸪Kaiyue Dong ࡶ 2024 ᖺ 6 ᭶Ꮫ఩ྲྀᚓࢆ┠ᣦࡋ࡚࠸ࡿ㸬㛗ᖺ⛎᭩ࢆ࠾㢪࠸ࡋ࡚࠸ࡓ ℈ୖඃᏊࡉࢇࡀ㎡⫋ࡋ㸪ᚋ௵࡟⚄ཎ༓ᫍࡉࢇࡀຍࢃࡗࡓ㸬

ᅗ1(a) in situ XAFS࡟ࡼࡾάᛶᵓ㐀ࡀNi2P࡛࠶ࡿࡇ࡜ࢆ
᫂ࡽ࠿࡟ࡋࡓ㸬(b)άᛶ࡜άᛶᵓ㐀㸪Ni2P ࡀάᛶࢆ♧ࡍ㸬‫✲◊ڦ‬ㄢ㢟ᵓ㐀ࡢつᐃࡉࢀࡓ༢⤖ᬗ࡞࡝ࡢᖹᆠᇶᯈࢆ⏝࠸࡚㸪ࡑࡢ⾲㠃ࡢᵓ㐀ࡸ཯ᛂ≀ᛶࢆㄪ࡭㸪ゐ፹ࡢཎ⌮ࡢゎ᫂ࢆ⾜࡞ࡗ࡚࠸ࡿ㸬ࡉࡽ࡟ࡩࡉࢃࡋ࠸ゎᯒᡭẁࢆ㛤Ⓨࡋ㸪≀⌮ⓗᡭἲ࡛ไᚚࡉࢀࡓ⾲㠃ࢆㄪ〇ࡋ࡚㸪⾲㠃ࢆᶵᲔࡢࡼ࠺࡟ື࠿ࡋ㸪⾲㠃཯ᛂࢆไᚚࡍࡿࡇ࡜ࢆ┠ᣦࡋ࡚࠸ࡿ㸬1㸬㸬㑄⛣㔠ᒓ࡜඾ᆺඖ⣲ࡢ໬ྜ≀ゐ፹ࡢᵓ㐀࡜ゐ፹཯ᛂ ప౯ᩘ㑄⛣㔠ᒓ࡜඾ᆺඖ⣲ࡢ໬ྜ≀㸦LVTMC㸻Low
valent Transition metal- Main group element compound㸧࡛࠶ࡿⅣ໬≀㸦IV ᪘㸧㸪❅໬≀㸪ࣜࣥ໬≀㸦V ᪘㸧㸪࢝ࣝࢥࢤࣥ㸦VI ᪘㸧ࡣ㸪ඹ᭷⤖ྜ㸪࢖࢜ࣥ⤖ྜ㸪㔠ᒓ⤖ྜࡍ࡭࡚ࡀ
ᐇ⌧ࡋ㸪≉␗࡞ゐ፹άᛶࢆ♧ࡍ㸬౛࠼ࡤ㸪Fischer-Tropschྜᡂゐ፹ࡢ MoCx㸪Mo2N㸪⬺◲ゐ፹ Ni2P㸪࢔ࢭࢺ࢟ࢩ໬ゐ፹ࡢ PdTe ࡞࡝࡛࠶ࡿ㸬ࡲࡓ㸪➨ 3 ᡂศࢆῧຍࡍࡿ࡜㸪3 ࡘࡢ⤖ྜᛶࡢࣂࣛࣥࢫࢆኚ໬ࡉࡏ㸪LVTMC ࡢゐ፹άᛶࢆኚ
໬ࡉࡏࡿࡇ࡜ࡀ࡛ࡁࡿ㸬⚾ࡓࡕࡣ㸪Ỉ⣲໬⬺◲཯ᛂ㸪Ỉ⣲໬⬺❅⣲཯ᛂ㸪⬺ሷ⣲཯ᛂ㸪Ỉ⣲໬⬺㓟⣲཯ᛂ㸪᭦࡟㸪࣓ࢱࣥ࢝ࢵࣉࣜࣥࢢỈ⣲⏕ᡂ཯ᛂ࡟ᑐࡋ࡚㧗άᛶࢆ♧ࡍ
Ni2P ࢆ୰ᚰ࡟◊✲ࢆ⾜ࡗ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ: ࢽࢵࢣࣝࣜࣥ໬≀ࡣ࣓ࢱࣥ࠿ࡽ
C2,C3 ࡢⅣ໬Ỉ⣲ࢆ⏕ᡂࡍࡿ཯ᛂ࡟㧗࠸άᛶࢆࡋࡵࡍ㸬
SiO2ୖ࡟ᵝࠎ࡞Ni:Pẚࡢࡶࡢࢆᢸᣢࡋࡑࡢᵓ㐀ࢆXAFS࡜⌮ㄽゎᯒ࡟ࡼࡾ⾜ࡗࡓ㸬 (ᩥ⊩(7))㸬
2㸬ከᵝ࡞㔞Ꮚࣅ࣮࣒ࢆ⏝࠸ࡓゐ፹ゎᯒᡭἲࡢ☜❧ ⾲㠃ࡢ」㞧࡞⌧㇟ࢆゎ᫂ࡍࡿࡓࡵ㸪ຍ㏿ჾ࣮࣋ࢫࡢᨺᑕ
ග㸪୰ᛶᏊ㸪࣑ࣗ࢜ࣥࡸ㝧㟁Ꮚ㸪ࡉࡽ࡟㸪XFEL㸦x-ray freeelectron laser)࡞࡝ࡢ㔞Ꮚࣅ࣮࣒ࡀ᭷ຊ࡞Ṋჾ࡟࡞ࡗ࡚࠸
ࡿ㸬ᡃࠎࡣ㸪ゐ፹ࡸ⾲㠃◊✲࡟㐺ࡋࡓ᪂ࡋ࠸㔞Ꮚࣅ࣮࣒ᡭ
ἲࢆ㛤Ⓨࡋ㸪ゐ፹◊✲࡟ᛂ⏝ࡋࡓ㸬άᛶⅬ࿘ࡾࡢ 3 ḟඖᵓ㐀ࡸ㟁Ꮚ≧ែ㸪ගゐ፹ࡢගບ㉳࣓࢝ࢽࢬ࣒࡞࡝ࢆ᫂ࡽ࠿࡟
ࡍ࡭ࡃゎᯒᡭἲࡢ☜❧ࢆ┠ᣦࡋࡓ㸬
2023ᖺᗘࡢࢺࣆࢵࢡ㸸 WO3ࡢpump probe EXAFSࡢゎᯒࢆᣊ᮰ࢧ࣮ࣛࢧ࣮ࢳἲ㸦CTSἲ㸧࡛⾜ࡗࡓ⤖ᯝࢆ࢔࣓ࣜ࢝໬
Ꮫ఍࡛Ⓨ⾲ࡋࡓ㸬ࡲࡓ㸪Pump-Flow-Probeἲࢆ㛤Ⓨࡋ㸪CoOOH㓟໬≀༙ᑟయ࠿ࡽⓑ㔠࡬ࡢ㟁Ꮚ⛣ືࡢほ ࡟ᡂຌࡋࡓ㸬㸦ᩥ⊩(9)㸧

2626

ᅗ2 Pump-Flow-Probe XAFS⿦⨨࡜ࡑࢀ࡟ࡼࡾ࡜ࡽ࠼ࡓⓑ㔠࡬ࡢ㟁Ꮚ⛣ື㸱㸬⇞ᩱ㟁ụゐ፹ࡢ⾲㠃ᵓ㐀ゎᯒᡭἲࡢ㛤Ⓨ ⇞ᩱ㟁ụࡣ㸪㐠㌿᫬࡟ CO2 ࢆฟࡉ࡞࠸ࡇ࡜࠿ࡽ㸪᪂ࡋ࠸࢚ࢿࣝࢠ࣮ኚ᥮ჾ࡜ࡋ࡚㸪⮬ື㌴㸪ᐙᗞ⏝Ⓨ㟁ᶵ➼࡟ᐇ⏝໬ࡀ㐍ࢇ࡛࠸ࡿ㸬୍᪉࡛㸪ຠ⋡ࡼࡃ㸪⇞ᩱ࠿ࡽ㟁ຊࢆྲྀࡾฟࡍࡓࡵࡢゐ፹㛤Ⓨࡀ㔜せ࡞◊✲ࢱ࣮ࢤࢵࢺ࡜࡞ࡗ࡚࠸
ࡿ㸬ከࡃࡢ⇞ᩱ㟁ụ࡟࠾࠸࡚ࡣ㸪⇞ᩱࡸ㓟⣲ࢆάᛶ໬ࡍࡿ
ࡓࡵ࡟㔠ᒓᚤ⢏Ꮚࡀ⏝࠸ࡽࢀ࡚࠾ࡾ㸪ࡑࡢ㔠ᒓᚤ⢏Ꮚࡢᵓ㐀ࡸᢸయ࡛࠶ࡿⅣ⣲࡜ࡢ┦஫స⏝࡟㛵ࡍࡿ▱ぢࢆᚓࡿࡇ࡜ࡀ㸪⇞ᩱ㟁ụࡢ㧗ᗘ໬࠾ࡼࡧ㛗ᑑ࿨໬࡟ᚲせ࡛࠶ࡿ㸬⇞ᩱ㟁ụ࡟ᐇ㝿࡟౑ࢃࢀ࡚࠸ࡿ㔠ᒓᚤ⢏Ꮚࡢᵓ㐀ࢆ XAFSἲ࡛Ỵᐃࡍࡿ࡜࡜ࡶ࡟㸪ᵓ㐀ࡢつᩚࡉࢀࡓ HOPG㸦highlyoriented pyrolytic graphite㸧ୖࡢ Pt ࢼࣀࢡࣛࢫࢱ࣮ࡢᵓ㐀Ỵᐃἲࡢ㛤Ⓨࢆ㐍ࡵ࡚࠸ࡿ㸬ᖺሗ࣭◊✲ᐊ⦅‫ە‬

2023ᖺ
ᖺᗘࡢࢺࣆࢵࢡ㸸 BCLA-BI-XAFS࠾ࡼࡧHERFD-BIXANES࡟ࡼࡾHOPGୖ࡟ᒎ㛤ࡋࡓࢼࣀ⢏ᏊPt ࡢᵓ㐀࡜⾲㠃྾╔ࡋࡓH2Oࢿࢵࢺ࣮࣡ࢡᵓ㐀ࢆ᫂ࡽ࠿࡟ࡋࡓ㸬(ᩥ⊩(6))
4㸬XAFSࢹ࣮ࢱ࣮࣋ࢫXAFS ἲࡣ㸪ゐ፹ᵓ㐀ゎᯒࡢ࡛ࡁࡿᡭẁ࡛࠶ࡿ㸬
ࡇࡢ XAFSࢹ࣮ࢱࢆ㞟ࡵࢹ࣮ࢱ࣮࣋ࢫࢆᵓ⠏ࡋ㸪ᶵᲔᏛ⩦࡜⤌ࡳྜࢃࡏࡿࡇ࡜࡛㸪ࢫ࣌ࢡࢺࣝ࠿ࡽᵓ㐀ࢆண᝿ࡍࡿࢩࢫࢸ࣒ᵓ⠏ࢆ㐍ࡵ࡚࠸ࡿ㸬2011 ᖺࡼࡾゐ፹⛉Ꮫ◊✲ᡤ࡜ XAFS ◊✲఍ࡀඹྠࡋ࡚㐠Ⴀࡋ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸ࡇࢀࡲ࡛㐠Ⴀࡋ࡚ࡁࡓXAFSࢹ࣮ࢱ࣮࣋ࢫࡢᣑ඘ࢆ⾜ࡗࡓ㸬 NIMSࡢ⤫ྜࢹ࣮ࢱ࣮࣋ࢫMDR࡜ࡢ㐃ᦠࢆᙉࡵࡓ㸬㸦ᩥ⊩㸦1㸧㸧

‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧
ETHZ ୖᮧὒᖹ༤ኈ
ࠕ㉸㧗㏿ XAFS ἲ࡟ࡼࡿගゐ፹ࡢほᐹࠖ/ᮾிᕤᴗ኱Ꮫᒣ୰୍㑻ᩍᤵࠕ࣓ࢱࣥάᛶ໬ゐ፹ࡢ
operando ほᐹࠖ/㧗࢚ࢿࣝࢠ࣮≀⌮Ꮫ◊✲ᶵᵓ≀㉁ᵓ㐀◊✲ᡤᮌᮧṇ㞝ᩍᤵࠕ೫ග඲཯ᑕ⺯ග XAFS ἲࡢ㛤Ⓨ㸪ከ⣲Ꮚ⺯ග⏝ SSD ࡢィ ࢩࢫࢸ࣒ࡢ㛤Ⓨ㸪㧗㏿ XAFS ἲࡢ㛤Ⓨ㸪XAFS ࢹ࣮ࢱ࣮࣋ࢫࡢ㛤Ⓨࠖ/ᮾி㟁Ẽ㏻ಙ኱Ꮫ᭷㈡㸦୕㍯㸧ᐶᏊ࣭ᒾ⃝ᗣ⿱ᩍᤵࠕ೫ග඲཯ᑕ⺯ග AFS ἲࡢ㛤Ⓨ㸪ከ⣲Ꮚ⺯ග⏝ SSD ࡢィ ࢩࢫࢸ࣒ࡢ㛤Ⓨ㸪EXPEEMࡢ㛤Ⓨࠖ/ᮾி་⛉ṑ⛉኱Ꮫ་ṑᏛ⥲ྜ◊✲⛉Ᏹᑿᇶᘯᩍ
ᤵ࣭࿴⏣ᩗᗈຓᩍࠕ࢖ࣥࣉࣛࣥࢺ⾲㠃ฎ⌮ᒙ࠾ࡼࡧ㦵⤖ྜ⏺ 㠃 ࡢ ῝ ࡉ ศ ゎ XAFS ゎ ᯒ ࠖ /Dipartimento DICEAM,
Università Mediterranea di Reggio Calabria1 ࣭ AssistantProfessor Francesco MAURIELLO ࠕ Exploring the Catalytic
Properties of Supported Palladium Catalysts in the Transfer
Hydrogenolysis of Glycerolࠖ/ན㛛኱Ꮫ⿁཭⌔ᩍᤵࠕEfficient
Ru-Fe Catalyzed Selective Hydrogenolysis of Carboxylic Acids
to Alcoholic Chemicalsࠖ/JASRI Ᏹ␃㈡᭸ஓᩍᤵࠕ⇞ᩱ㟁ụゐ፹ࡢ㛤Ⓨࠖ/⌮◊▮ᶫ∾ྡ༤ኈ࣭∦ᒣဴ༤ኈࠕXFEL-XAFSࡢ㛤Ⓨࠖ/໭ᾏ㐨኱Ꮫ኱Ꮫ㝔ᆅ⌫⎔ቃ⛉Ꮫ◊✲㝔ඵᮌ୍୕ᩍᤵ࣭ຍ⸨ඃຓᩍࠕXAFS ࡟ࡼࡿ Bio-inspired 㟁ᴟゐ፹ࡢᵓ㐀ゎ᫂ࠖ/ ᮾ໭኱Ꮫ኱Ꮫ㝔⎔ቃ⛉Ꮫ◊✲⛉࿴⏣ᒣᬛṇᩍᤵ࣭㎘┤ேຓᩍࠕin-situ ⺯ගศග XAFS ᐃ࡟ࡼࡿᅛయ㧗ศᏊᙧ⇞ᩱ㟁ụ⏝ Pt 㑄⛣㔠ᒓ❅໬≀ࢥ࢔ࢩ࢙ࣝࢼࣀᚤ⢏Ꮚࡢᚤ⣽ᵓ㐀ゎᯒࠖ/⌮໬Ꮫ◊✲ᡤୖཱྀ㈼༤ኈࠕMo ࢡࣛࢫࢱ࣮ࡢᵓ㐀◊✲ࠖ/ᒣཱྀ኱Ꮫྜྷ⏣┿᫂෸ᩍᤵࠕග㟁Ẽ⎔ቃୗࡢ㓟໬≀ⷧ⭷ᵓ㐀ኚ໬ࡢ◊✲ࠖ/ South Carolina University,
Prof.Jochen LAUTERBACH, ࠕNi-P ໬ྜ≀ࡢ⾲㠃ᵓ㐀ࠖ
/Cambridge Uniersity Prof. Maria OLEAࠕከᏍ㉁ᮦᩱ୰ࡢ Auࡢᵓ㐀◊✲ࠖ/ ᒣ᪉ၨ ㇏⏣ᕤᴗ኱Ꮫ“WO3 ගゐ፹ࡢ㧗㏿ගᛂ⟅”/ෆ⸨ಇ㞝“ගᛂ⟅㟁Ẽ≀ᛶ࡜ᵓ㐀ࡢ◊✲” /▼஭┿ྐ㸦≀㉁ᮦᩱᶵᵓ㸧࣭ᯇᮏᓫ༤㸦JASRI㸧࣭✄⏣ᗣᏹ㸦❧࿨㤋㸧⏣ῲ㞞ኵࠕXAFS Database ᵓ⠏஦ᴗࠖ‫ڦ‬2023 ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦ࡍ࡭࡚ᑂᰝࡘࡁ㸧(1) Ishii, M.; Tanabe, K.; Matsuda, A.; Ofuchi, H.; Matsumoto,T.; Yaji, T.; Inada, Y.; Nitani, H.; Kimura, M.; Asakura, K.,
Integration of X-ray absorption fine structure databases fordata-driven materials science. STAM, Methods 2023, 3,2197518.
(2) Iwasawa, Y.; Asakura, K.; Kondoh, H.; Tada, M., Surfaces.
Int.Table Cryst. I, 2023, published on line.
(3) Kim, C. R.; Maeda, H.; Lu, B.; Nakamura, Y.; Lin, Y.;
Wakisaka, Y.; Kido, D.; Asakura, K.; Takakusagi, S., Can
amine ligands atomically disperse Cu atoms on TiO2(110)? :Cu deposition on TiO2(110) premodified with o-anthranilic
acid. Chem. Lett. 2024, 53, published on line.

‫ە‬ᖺሗ࣭◊✲ᐊ⦅(4) Liu, C.; Lu, B.; Ariga-Miwa, H.; Ogura, S.; Ozawa, T.;
Fukutani, K.; Gao, M.; Hasegawa, J.-y.; Shimizu, K.-i.;
Asakura, K., Dynamic Behavior of Intermediate Adsorbates toControl Activity and Product Selectivity in Heterogeneous
Catalysis: Methanol Decomposition on Pt/TiO2 (110). J. Am.
Chem. Soc. 2023, 145, 19953-19960.
(5) Wada, T.; Kashaboina, U.; Nishikawa, Y.; Wakisaka, Y.;
Bao, D.; Takakusagi, S.; Inami, Y.; Kuriyama, F.; Dipu, A. L.;
Ogihara, H.; Iguchi, S.; Yamanaka, I.; Kido, D.; Kimura, M.;
Uo, M.; Asakura, K., The Effect of Structural Change during
the Activation Process on the Catalysis of In/SiO2
Nonoxidative Coupling of Methane: An Operando XAFSStudy. J.Phys.Chem.C 2023, 127, 24211-24222.
(6) Dong, K.; Hu, B.; Rashid, M. H. A.; Lu, B.; Miyabayashi,K.; Higashi, K.; Uruga, T.; Iwasawa, Y.; Kido, D.; Takakusagi,S.; Asakura, K., In situ Study on Structure of a Diluted
Pt/HOPG Model Catalyst System Prepared by the Two-phase
Liquid Reduction Method Using a Novel BCLA/HERFD+BIXAFS Method. e-J. Surf.Sci.Nanotech. 2024, published online.
(7) Wang, Q.; Iguchi, S.; Yamanaka, I.; Ota, J.; Wada, Takahiro;
Uo, M.; Kido, D.; Kimura, M.; Asakura, K., What is the Active
Structure for High-Temperature Direct Dehydrogenative
Conversion of Methane by the Supported NiP Catalysts—An
in Situ XAFS Study. J.Phys. Chem.C 2024, 128,3242-3249.
(8) Kamiguchi, S.; Asakura, K.; Shibayama, T.; Yokaichiya, T.;
Ikeda, T.; Nakayama, A.; Shimizu, K.-i.; Hou, Z., Catalytic
Ammonia Synthesis on HY-Zeolite-Supported Angstrom-Size
Molybdenum Cluster. Chem. Sci., 2024,15, 2914-2922.
(9) Cheng, W.; Kido, D.; Niwa, Y.; Bo, S.; Kimura, M.; Ota, R.;
Shibayama, T.; Asakura, K., In situ Pump-Flow-Probe XAFSStudy of Photoexcited Electron Transfer over Single AtomPt/CoOOH Photocatalysts. Chem. Lett. 2024, 53, upae012(10) Kido, D.; Wada, T.; Asakura, K., Automatic collection andvisualization of the models given by Thorough Search
Analysis and its application to the MoO3 EXAFS analysis. eJ.Surf. Sci. Nanotech 2023, 21, 231-235.
(11) ᇛᡞ኱㈗, ᮌᮧṇ㞝, ᮅ಴Ύ㧘, "ゎᯒ⪅ࡢ⤒㦂࡟ࡼࡽ
࡞࠸ EXAFS ゎᯒ࡬ࡢᣮᡓ ̿Constrained Thorough Searchἲࡢ㛤Ⓨ̿", ⾲㠃࡜┿✵, 2023, 66, 399-404
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟
(1) Asakura, K.: “In situ XAFS analysis of PtAu nanoparticles
deposited on a flat HOPG surface”, International Conferenceon Sustainable Energy Materials, (Sapporo,2023/4/10㸧.
(2) Asakura, K.: “The Structure and Catalysis of Single Crystal
Metal Oxides and Other Compounds: How Can We UnderstandIts Complexity 㸽 ”, The 19th Korea-Japan Symposium on
Catalysis (Seoul, 2023/05/16).
(3) ⚟⏣ఙ㸪ࠕ኱Ꮫࡢ◊✲࡜௻ᴗࡢ㛤Ⓨࠖ, ➨ 451 ᅇゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘ᮐᖠ,㸦2023/6/5㸧.
(4) ᮅ಴Ύ㧘㸪ࠕPhoton-in Photon-out ศග࡛࡞࡟ࡀࢃ࠿ࡿ
࠿㸽-㧗㍤ᗘග※࡬ࡢᮇᚅࠖ➨ 1 ᅇ ඛ➃ᨺᑕගά⏝◊✲఍ ࠕᨺᑕගࢆ⏝࠸ࡓゐ፹࢟ࣕࣛࢡࢱࣜࢮ࣮ࢩࣙࣥࡢ⌧ᅾ࡜ᮍ᮶ࠖ㸪ᮐᖠ,㸦2023/7/23㸧.
(5) Asakura, K.; Kido, D.; Uemura, Y., Kiyotaka Asakura, Daiki
Kido, and Yohei Uemura.: “Pump-Probe EXAFS Study on
the Structure of Metastable WO3 Photo-ExcitedSpecies”, ACS Fall Meeting 2023, San Francisco, USA(2023/8/14).
(6) Asakura, K.; Ishii, M.; Kimura, M.; Matsumoto, T.; Inada,Y.; Tabuchi, M.; Kobayashi E.: “An Attempt to Integrate theOpen Databases in Japan”, Q2XAFS2023, ANST, Australia(2023/8/18).
(7) Asakura, K.: “Summary of Q2XAFS2023”, Q2XAFS2023,

27

Melbourne, Australia (2023/8/19).
(8) Asakura, K.: “ Bent Crystal Laue Analyzer Combined with
Polarization-dependence Total Reflection Fluorescence X-ray
Absorption Fine Structure (BCLA-PTRF-XAFS) and its
Application to Electrode Surface”, 26th IUCr, Melbourne,
Australia (2023/8/28).
(9) Dong, K.; Kido, D.; Yang, C.; Hu, B.; Tomidokoro, S.;
Wada, T.; Takakusagi, S.; Asakura, K.: “In-situ PTRF-XAFS
application for Pt model catalyst structure investigation toward
ORR”, Q2XAFS2023, ANST, Australia (2023/8/18).
(10) ᮅ಴Ύ㧘㸪ࠕ㔠ᒓ㛫໬ྜ≀ゐ፹ࡢ⾲㠃⛉Ꮫ࡜ゐ፹స⏝
̿Ni2P ࢆ౛࡟ࡋ࡚ࠖ, ࣮࢝࣎ࣥࢽ࣮ࣗࢺࣛࣝᐇ⌧ࡢࡓࡵࡢゐ፹ᢏ⾡㸪௝ྎ, (2023/9/28).
(11) ᮅ಴ Ύ㧘㸪ࠕ᪋タ㛫ඹ㏻࣓ࢱࢹ࣮ࢱࡢ≺࠸࡜௒ᚋ̿
ᅜ㝿ᶆ‽ࢆࡵࡊࡋ࡚ࠖ㸪 XAFS ⤫ྜࢹ࣮ࢱ࣮࣋ࢫࡢ➨஧Ṍ, ᮾி (2023/10/18).
(12) Asakura, K.: “XAFS analysis on bimetallic particle
catalysts - old but still challenging targets”, TU/e-ICAT
Joint International Symposium on Catalysis: Advanced
Technologies for Sustainable Society, Eindhoven (2023/11/2).
(13) Kim, C. R.; Maeda, H.; Lu, B.; Nakamura, Y.; Lin, Y.;
Wakisaka, Y.; Kido, D.; Asakura, K.: “Can amine ligand

2828

atomically disperse Cu atoms on TiO2(110)?: Cu deposition on
TiO2(110) premodified with o-anthranilic acid”, NanoThailand
2023, Dusit Thani Pattaya, Thailand (2023/11/29).
(14) ᒣᮏ㈆᫂㸪ࠕゐ፹◊✲ᡤࡢ༙ୡ⣖ࠖ㸪ゐ◊ 80 ࿘ᖺグᛕࢩ࣏ࣥࢪ࣒࢘㸪ᮐᖠ (2023/12/21).
(15) ⚟⏣ఙ,ࠕゐ፹◊✲ᡤ࡟ࡳࡿ⤌⧊タィࡢㄢ㢟ࠖ, ゐ◊ 80࿘ᖺグᛕࢩ࣏ࣥࢪ࣒࢘㸪ᮐᖠ (2023/12/21).
(16) Asakura, K.: “X-ray absorption near edge structure(XANES) –past, present, and future–”, ➨ 1908 ᅇᮾி኱Ꮫ
⌮Ꮫ㒊໬Ꮫᩍᐊ㞧ㄅ఍㸪ᮾி (2023/12/23).
(18)ᮅ಴Ύ㧘㸪ࠕ࣓ࢱࢹ࣮ࢱᅜ㝿ᶆ‽໬ࡢືࡁࠖ, XAFS ࢹ࣮ࢱ࣮࣋ࢫ఍ྜ㸪ጲ㊰ (2024/1/11).
(19) ᮅ಴Ύ㧘㸪ࠕᨺᑕගࡢゐ፹ᛂ⏝ ࢸࣥࢲ࣮࠿ࡽࢯࣇࢺ
ࡢ᪂ࡋ࠸ྍ⬟ᛶࠖ, ゐ፹⛉Ꮫ࡜ᨺᑕග SoftࠥTender X ⥺ࡢ᪂ࡓ࡞ᒎ㛤㸪⁠㈡ (2024/1/26).
ཷ㈹
(1) Kim Chorong, NanoThailand 2023, Dusit Thani
Pattaya,Thailand (2023/11/29). <<Best Poster Awards>>(2) Kim Chorong, Ꮫ⏕ㅮ₇㈹,᪥ᮏ⾲㠃┿✵Ꮫ఍ᮾ໭໭ᾏ
㐨ᨭ㒊Ꮫ⾡ㅮ₇఍, ᮐᖠ (2023/3/7㸧

ᖺሗ࣭◊✲ᐊ⦅‫ە‬ゐ፹ᵓ㐀◊✲㒊㛛 Catalyst Structure
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◊✲㝔ຓᩍ࡜ࡋ࡚㌿ฟࡋࡓ㸬2024ᖺ3᭶ᮎ࡛బ⸨Ⰻ᫛Ặ㸦Ꮫ⾡◊✲ဨ㸧ࡀ㏥⫋ࡋࡓ㸬‫✲◊ڦ‬ㄢ㢟 㓟໬≀༢⤖ᬗ⾲㠃ࢆ㔠ᒓࢼࣀࢡࣛࢫࢱ࣮ࡸᶵ⬟ᛶศᏊ࡛ಟ㣭ࡍࡿࡇ࡜࡛⢭ᐦ࡟ᵓ㐀ไᚚࡉࢀࡓࣔࢹࣝゐ፹⾲㠃ࢆ๰ᡂࡋ㸪཯ᛂᶵᵓࡢゎ᫂࡜᪂ࡋ࠸ゐ፹స⏝ࡢ๰ฟࢆ⾜࠺㸬ࡲࡓ㸪཯ᛂ୰ࡢゐ፹⾲㠃ࢆཎᏊ࡛ࣞ࣋ࣝࡑࡢሙ/࢜࣌ࣛࣥࢻᵓ㐀ゎᯒࡍࡿࡓࡵࡢ᪂ࡋ࠸⿦⨨ࡸᡭἲࡢ㛤Ⓨࢆ⾜࠺㸬ලయⓗ࡟ࡣ㸪ࡇࢀࡲ࡛㉸㧗┿✵ୗ࡛ࡢ㟼ⓗ࡞ᵓ㐀ほᐹ࡟㝈ࡽࢀ࡚࠸ࡓ✀ࠎࡢ⾲㠃⛉Ꮫィ ᡭἲࢆᨵⰋ࣭㧗ᗘ໬ࡋ㸪Ẽ┦࢞ࢫᏑᅾୗ㧗 ࡛㸪ᐇ㝿࡟ゐ፹཯ᛂࡀ㐍⾜ࡋ࡚࠸ࡿ≧ἣୗ࡛άᛶࢧ࢖ࢺࡢ୕ḟඖᵓ㐀ゎᯒࡸ㟁Ꮚ≧ែホ౯ࢆྍ⬟࡜ࡍࡿ㸬ࡇ࠺ࡋࡓ࢔ࣉ࣮ࣟࢳ࡟ࡼࡗ࡚㸪ᵓ㐀୙ᆒ୍ᛶࡢ኱ࡁ࠸ᐇゐ፹࡛ࡣᅔ㞴࡞㸪ཝᐦ࡞ᵓ㐀-άᛶ┦㛵࡟㛵ࡍࡿ᝟ሗࡢྲྀᚓࢆᐇ⌧ࡋ㸪ᐇゐ፹ࡢ㧗ᛶ⬟໬࡬ࡢᣦ㔪ࢆᚓࡿ㸬ࡲࡓ㸪ᚑ᮶ࡢ⇕࡟ࡼࡿάᛶ໬ࡢࡳ࡟㢗ࡿゐ፹཯ᛂࡔࡅ࡛ࡣ࡞ࡃ㸪ࣉࣛࢬ࣐ࡸ㟁ሙ࡟ࡼࡿእ㒊άᛶ໬ࡶే⏝ࡋࡓ㠀ᅾ᮶ᆺゐ፹ࣉࣟࢭࢫࡢᶵᵓゎ᫂࡜Ꮫ⌮ᵓ⠏ࢆྠᵝ࡞࢔ࣉ࣮ࣟࢳ࡟
ࡼࡾᐇ⌧ࡍࡿ㸬1㸬㸬೫ග඲཯ᑕ⺯ග XAFS ἲ࡟ࡼࡿ㓟໬≀⾲㠃ୖ㔠ᒓ✀ࡢ୕ḟඖᵓ㐀Ỵᐃ࡜࢜࣌ࣛࣥࢻ ᐃ࡬ࡢᒎ㛤 ᅛయ⾲㠃࡟㧗ศᩓࡋࡓゐ፹άᛶⅬࡢᵓ㐀㸦ཎᏊ㓄ิ㸧ࢆᅛయ⾲㠃࡟㧗ศᩓࡋࡓゐ፹άᛶⅬࡢᵓ㐀㸦ཎᏊ㓄ิ㸧ࢆㄪ࡭ࡿࡇ࡜ࡣᐜ࡛᫆ࡣ࡞࠸㸬STM/AFM ࡟ࡼࡾᅛయ⾲㠃ࡢཎᏊീࢆ┤᥋ほᐹ࡛ࡁࡿࡼ࠺࡟࡞ࡗࡓࡀ㸪STM/AFM ࡢศゎ⬟࡛ࡣ㸪ࡼࡾᚤ⣽࡞⤖ྜ᝟ሗࡸ୕ḟඖᵓ㐀᝟ሗࢆᚓࡿࡇ࡜
ࡣ㞴ࡋ࠸㸬୍᪉㸪XAFS ἲࡣ㸪X ⥺྾཰ཎᏊ࿘㎶ࡢ⤖ྜཬࡧᵓ㐀᝟ሗࢆ୚࠼ࡿࡀ㸪ᇶᯈ⾲㠃࡟ᛂ⏝ࡍࡿ࡟ࡣ㸪ឤᗘࡀ୙༑ศ࡛࠶ࡿ㸬ᡃࠎࡣ㸪㉸㧗┿✵ୗ࡛ヨᩱㄪ〇࣭ ᐃࡀྍ‫ە‬ᖺሗ࣭◊✲ᐊ⦅⬟࡞೫ග඲཯ᑕ⺯ග XAFS ἲࢆ㛤Ⓨࡋ㸦Fig.1㸧㸪඲཯ᑕἲ࡜⺯ගἲ࡟ࡼࡗ࡚㧗ឤᗘ໬ࡍࡿ࡜࡜ࡶ࡟㸪೫ග౫Ꮡ ᐃࢆ⾜࠺ࡇ࡜࡛㸪ᢸᣢ㔠ᒓ✀ࡢ୕ḟඖᵓ㐀Ỵᐃࢆྍ⬟࡟ࡋࡓ㸬㓟໬≀༢⤖ᬗ⾲㠃ୖࡢᵝࠎ࡞㔠ᒓ༢ཎᏊ࣭ࢼࣀࢡࣛࢫࢱ࣮
࡟㐺⏝ࡋ㸪⏺㠃ࢆྵࡴ୕ḟඖཎᏊ㓄ิࡢỴᐃ࡜㔠ᒓ/㓟໬≀┦஫స⏝࡟㛵ࡍࡿᇶ♏ⓗ▱ぢࡢྲྀᚓࢆ⾜ࡗ࡚࠸ࡿ㸬ࡉࡽ࡟ᮏᡭἲࢆ࢜࣌ࣛࣥࢻ໬ࡋ㸪኱Ẽᅽୗ࡛ࡢゐ፹཯ᛂ୰ࡢ㔠ᒓάᛶⅬ୕ḟඖᵓ㐀Ỵᐃࡶྍ⬟࡟ࡋ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ᢸᣢ㔠ᒓゐ፹࡛ࡣ㔠ᒓ✀ࡢࢧ࢖ࢬࡸᵓ㐀࣭ᙧ≧ࡢไᚚࡀ㔜せ࡛࠶ࡿ㸬㏻ᖖ㸪㓟໬≀༢⤖ᬗ⾲㠃࡟㔠ᒓࢆᑟධࡋࡓሙྜ㸪㔠ᒓཎᏊࡣ⾲㠃ࢆᐜ᫆࡟ᣑᩓ࣭
จ㞟ࡍࡿࡓࡵ㸪༢ཎᏊࢆࡣࡌࡵ࡜ࡋࡓ1 nm௨ୗࡢᚤᑠࢼࣀ
ᵓ㐀యࢆᚓࡿࡇ࡜ࡣ㞴ࡋ࠸㸬ࡑࡇ࡛㓟໬≀༢⤖ᬗ⾲㠃ࢆ࠶ࡽ࠿ࡌࡵᶵ⬟ᛶศᏊ࡛ಟ㣭ࡋ㸪ࡑࡢᚋ㔠ᒓࢆᑟධࡍࡿࡇ࡜
࡛㸪ศᏊ࡜ࡢ┦஫స⏝ࢆ฼⏝ࡋࡓศᩓ≧ែ࡜୕ḟඖᵓ㐀ࡢไᚚࢆヨࡳ࡚࠸ࡿ㸦Fig.2㸧㸬ࡇࡢ࡜ࡁ⁐ᾮࣉࣟࢭࢫࢆ⏝࠸ࡿ࡜㸪㉸㧗┿✵ୗ࡛ࡢㄪ〇࡟ẚ࡭ཎᏊ࡛ࣞ࣋ࣝᖹᆠ࡞TiO2
༢⤖ᬗ⾲㠃ࡀᐜ᫆࡟ᚓࡽࢀ㸪ࡲࡓ⵨Ẽᅽࡢไ㝈ࢆཷࡅࡎ࡟
ከ✀㢮ࡢศᏊࢆ㑅ᢥ࡛ࡁࡿ࣓ࣜࢵࢺࡀ࠶ࡿ㸬ᡃࠎࡣ㸪
TiO2(110) ⾲ 㠃 ࢆ ࣓ ࣝ ࢝ ࣉ ࢺ Ᏻ ᜥ 㤶 㓟 (o-mercaptobenzoic
acid㸪o-MBA)࡛ಟ㣭ࡋ㸪Cu㸪Au㸪Niࢆ┿✵⵨╔ࡍࡿ࡜㸪㔠ᒓ-◲㯤ཬࡧ㔠ᒓ-㓟⣲㸦TiO2ࡢ᱁Ꮚ㓟⣲㸧⤖ྜࡢᙧᡂ࡟
ࡼࡾ㸪㔠ᒓࢆ༢ཎᏊ≧࡟ศᩓ໬࡛ࡁࡿࡇ࡜ࢆぢฟࡋ㸪ࡑࢀࡽࡢ୕ḟඖᵓ㐀Ỵᐃ࡜␗ᛶయࢆ⏝࠸ࡓᵓ㐀ไᚚ࡟ࡘ࠸࡚
ሗ࿌ࡋ࡚࠸ࡿ㸦౛࠼ࡤChem. Rec. 2019, 19, 1157-1165㸧.

)LJ 7L2  ⾲㠃ୖ࡛ࡢᶵ⬟ᛶศᏊࢆ⏝࠸ࡓ㔠ᒓ✀ࡢศᩓ≧ែཬࡧ୕ḟඖᵓ㐀ࡢไᚚ

ᮏᖺᗘࡣ௚ࡢᶵ⬟ᛶ᭷ᶵศᏊࢆ⏝࠸ࡓሙྜࡢ㔠ᒓࡢศᩓᣲື࡜୕ḟඖᵓ㐀ࢆㄪ࡭ࡓ㸬ලయⓗ࡟ࡣ㸪࢔ࣥࢺࣛࢽࣝ
㓟㸦o-anthranilic acid㸪o-AA㸧ࢆಟ㣭ศᏊ࡜ࡋ࡚⏝࠸㸪Cuࢆ⵨╔ࡋࡓሙྜࡢᵓ㐀ࢆㄪ࡭ࡓ㸬ࡑࡢ⤖ᯝ㸪࣓ࣝ࢝ࣉࢺᏳ
ᜥ㤶㓟ࢆ⏝࠸ࡓሙྜ࡜ྠᵝ࡟Cuࡣจ㞟ࡏࡎ㸪࢔ࣥࢺࣛࢽ
ࣝ㓟ࡢN࡜TiO2ࡢO㸦᱁Ꮚ㓟⣲㸧࡜ࡢ⤖ྜᙧᡂ࡟ࡼࡗ࡚㸪༢ཎᏊ≧࡟ᵓ㐀Ᏻᐃ໬ࡍࡿࡇ࡜ࡀࢃ࠿ࡗࡓ㸦Fig. 3㸧㸬ࡇࡢࡼ࠺࡞␗࡞ࡿಟ㣭ศᏊ࡛ࡢ㔠ᒓ㧗ศᩓ໬ࡢヨࡳࡣ㸪㔠ᒓ✀ࡢ㟁Ꮚ≧ែࡸᒁᡤᵓ㐀ࢆኚㄪࡋ㸪ゐ፹཯ᛂ≉ᛶࢆไᚚࡍࡿୖ࡛㔜せ࡛࠶ࡿ㸬ࡉࡽ࡟㸪ࡇࢀࡲ࡛⾜ࡗ࡚ࡁࡓ㓟໬≀⾲㠃࡛

29ࡢྛ㔠ᒓࡢศᩓ≧ែࡢ⤖ᯝࢆᇶ࡟㸪㔠ᒓࢆ༢ศᩓ໬ࡉࡏࡿ
せᅉࢆ⤖ྜᙧᡂ࢚ࢿࣝࢠ࣮ࡢほⅬ࠿ࡽ⪃ᐹࡋ㸪༢ཎᏊศᩓ

)LJ  ೫ ග ඲ ཯ ᑕ ⺯ ග ;$)6 ἲ ࡟ ࡼ ࡾ Ỵ ᐃ ࡋ ࡓ &XR$$7L2  ࡢ୕ḟඖᵓ㐀࠿㸪จ㞟࠿ࢆண

ࡍࡿᣦᶆࢆᥦ᱌ࡋࡓ㸬ࠓㄽᩥࠔ

2㸬㸬 ᢸᣢ㔠ᒓゐ፹࡟࠾ࡅࡿ୰㛫య྾╔✀ࡢືⓗᣲື࡜άᛶ࣭㑅ᢥᛶ࡜ࡢ┦㛵 㔠ᒓࢼࣀ⢏Ꮚࢆ㓟໬≀⾲㠃࡟ᢸᣢࡋࡓᢸᣢ㔠ᒓゐ፹ࡣᐇ⏝ⓗ࡟᭱ࡶࡼࡃ⏝࠸ࡽࢀ࡚࠸ࡿ㸬ゐ፹཯ᛂࡣ㔠ᒓࢼࣀ⢏Ꮚ⾲㠃ࡸ㔠ᒓ࡜㓟໬≀࡜ࡢ⏺㠃㸪㓟໬≀⾲㠃࡟Ꮡᅾࡍࡿ㔠ᒓ࢝ࢳ࢜ࣥࢧ࢖ࢺࡸ㓟⣲Ḟ㝗࡛㐍⾜ࡍࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠾ࡾ㸪ࡇࢀࡽࡀゐ፹ᛶ⬟㸦άᛶ࣭㑅ᢥᛶ㸧ࢆỴᐃࡍࡿ኱ࡁ࡞せᅉ࡛࠶ࡿ࡜ࡉࢀ࡚࠸ࡿ㸬୍᪉㸪྾╔ࡋࡓ཯ᛂศᏊ㸦୰㛫య྾╔✀㸧ࡢືⓗ࡞ᣲື㸪ࡍ࡞ࢃࡕ㸪୰㛫྾╔✀ࡀ࡝ࡢࡼ࠺࡟⾲㠃ࢆᣑᩓࡋ࡚άᛶࢧ࢖ࢺ࡟฿㐩ࡋ㸪ศᏊኚ᥮ࡀ⾜ࢃࢀࡿࡢ࠿㸽࡟ࡘ࠸࡚ࡣ㸪ゐ፹ᛶ⬟࡟ᙳ㡪ࢆ୚࠼ࡿ㔜せ࡞ᅉᏊ࡛࠶ࢁ࠺࡜ࡢㄆ㆑࡟ࡶ㛵ࢃࡽࡎ㸪ᐇ㝿࡟ィ ࣭ホ౯ࡍࡿᐇ㦂ᡭἲࡀஈࡋ࠸ࡓࡵ㸪༑ศ࡞⌮ゎࡀ࡞ࡉࢀ࡚࡞࠸㸬ࡑࡇ࡛㸪ಶࠎࡢ྾╔✀ࡢືࡁࢆᤊ࠼ࡿࡇ࡜࡛ࡁࡿSTMࢆ⏝࠸㸪୰㛫య྾╔✀ࡢᣑᩓࡸࢫࣆ࣮ࣝ࢜ࣂ࣮㸪㏫ࢫࣆ࣮ࣝ࢜
ࣂ࣮ࡢ⤒㊰ࡢヲ⣽ࢆ᫂ࡽ࠿࡟ࡋ㸪ࡇ࠺ࡋࡓືⓗᣲືࡀゐ፹ᛶ⬟࡟୚࠼ࡿᙳ㡪ࡢゎ᫂ࢆ⾜ࡗ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 Pt/TiO2(110)ࣔࢹࣝゐ፹⾲㠃࡛ࡢ࣓ࢱࣀ࣮ࣝศゎ཯ᛂ࡟ὀ┠ࡋࡓ㸬ᡃࠎࡣ௨๓ࡢ◊✲࡛㸪࣓ࢱ
ࣀ࣮ࣝࡣPtୖ࡛ゎ㞳྾╔ᚋ㸪࣓ࢺ࢟ࢩ୰㛫య࡜ࡋ࡚TiO2⾲
㠃ࡢTi4+ ࢧ࢖ࢺ࡬ࢫࣆ࣮ࣝ࢜ࣂ࣮ࡍࡿࡇ࡜ࢆSTM㐃⥆ࡑࡢሙほᐹ࡟ࡼࡾぢฟࡋ࡚࠸ࡿ㸦Fig. 4㸧㸬ࡋ࠿ࡋ㸪ࢫࣆ࣮ࣝ࢜
ࣂ࣮ᚋࡢTiO2⾲㠃ୖ࡛ࡢᣑᩓ㐣⛬ࡢヲ⣽ࡸ㸪 ᗘࢆୖࡆࡓ
࡜ࡁ࡟࡝ࡢࡼ࠺࡞άᛶࢧ࢖ࢺ࡟ࡓ࡝ࡾ╔ࡁ㸪࡝ࢇ࡞ศᏊ࡟

)LJ3W7L2  ⾲㠃ୖࡢ࣓ࢺ࢟ࢩ୰㛫యኚ᥮ࡉࢀࡿࡢ࠿㸪ࡣ୙࡛᫂࠶ࡗࡓ㸬ࡑࡇ࡛ࡲࡎTiO2⾲㠃࡛ࡢᣑᩓ㐣⛬ࡢヲ⣽ࢆ᫂ࡽ࠿࡟ࡍ
ࡿࡓࡵ࡟㸪STMࢆ⏝࠸࡚ಶࠎࡢ࣓ࢺ࢟ࢩ୰㛫యࡢືࡁࢆ㏣㊧ࡋࡓ㸬࣓ࢺ࢟ࢩ୰㛫యࡣTiO2⾲㠃ୖࢆ≉ᐃࡢ2᪉ྥ㸦[001]᪉ྥ࡜ሾͳͳതͲሿ᪉ྥ㸧࡟ἢࡗ࡚ᣑᩓࡋ㸪⾲㠃඲యࢆືࡅࡿࡇ
࡜ࡀࢃ࠿ࡗࡓ㸬➨୍ཎ⌮ィ⟬ࡢ⤖ᯝ㸪[001]᪉ྥࡢᣑᩓ࡟࠾
࠸࡚㸪TiO2 ⾲㠃ࡢTi4+ ࢧ࢖ࢺ࡟྾╔ࡋࡓ࣓ࢺ࢟ࢩ୰㛫య

3030

㸦CH3O-Ti㸧ࡣ㸪㞄ࡢ㓟⣲ཎᏊ࡟྾╔ࡋࡓH㸦Ỉ㓟ᇶࡢỈ⣲ཎᏊ㸧ࢆྲྀࡾ㎸ࡳ㸪ศᏊ≧྾╔ࡢ≧ែࢆ⤒⏤ࡋ࡚㞄ࡢTi4+ࢧ࢖ࢺ࡟⛣ືࡍࡿࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡗࡓ㸬ሾͳͳതͲሿ᪉ྥ࡟㛵ࡋ࡚ࡶྠᵝ࡟ศᏊ≧྾╔ࢆ⤒࡚ᣑᩓࡍࡿࡇ࡜ࡀࢃ࠿ࡗࡓ㸬ࡇࡢࡼ࠺࡟ゎ㞳ᆺ྾╔࡜ศᏊ≧྾╔ࡢ≧ែࢆ⧞ࡾ㏉ࡋ࡞ࡀࡽ㸪࣓ࢱࣀ࣮ࣝศᏊࡀᅛయ⾲㠃ࢆືࡃ࣓࢝ࢽࢬ࣒ࡣᮏ◊✲࡛ึࡵ࡚ぢฟࡉࢀࡓ㸬ࡉࡽ࡟㸪 ᗘࢆୖࡆࡓ࡜ࡁࡢ࣓ࢺ
࢟ࢩ୰㛫యࡢศゎᣲືࢆ᪼ ⬺㞳ἲ㸦TPD㸧࡟ࡼࡾㄪ࡭ࡓ㸬ᣑᩓ࡟ࡼࡿศゎᣲືࡢኚ໬ࡢ᭷↓ࢆㄪ࡭ࡿࡓࡵ࡟㸪Ptࢼࣀ⢏Ꮚࡢᐦᗘࡀ␗࡞ࡿ2ࡘࡢヨᩱ࡟ᑐࡋ࡚ ᐃࢆ⾜ࡗࡓ㸬ࡑࡢ⤖ᯝ㸪Ptࢼࣀ⢏Ꮚᐦᗘ࡟ࡼࡾ㸪ศゎ⏕ᡂ≀ࡢẚࡀ኱ࡁࡃ␗࡞ࡗࡓ㸬ࡇࢀࡣ㸪ศゎ཯ᛂࡀ㉳ࡇࡿ୺࡞άᛶࢧ࢖ࢺࡀ
TiO2⾲㠃࡛ࡣ࡞ࡃPt࡛࠶ࡾ㸦㏫ࢫࣆ࣮ࣝ࢜ࣂ࣮⌧㇟㸧㸪࠿ࡘᣑᩓࡀศゎᣲື࡟ᙳ㡪ࢆ୚࠼ࡿࡇ࡜ࢆ♧ࡋ࡚࠸ࡿ㸬CH4ࡢ
CO࡟ᑐࡍࡿ⏕ᡂẚࡀ㸪Ptࢼࣀ⢏Ꮚ㧗ᐦᗘ࡟ẚ࡭࡚పᐦᗘ
ࡢ᪉ࡀ኱ࡁࡃ࡞ࡗ࡚࠸ࡿࡓࡵ㸪Pt࡜TiO2ࡢ⏺㠃ࡀCH4ࡢ⏕ᡂࢧ࢖ࢺ࡛࠶ࡾ㸪௚ࡢPtࢧ࢖ࢺࡀCO⏕ᡂࢧ࢖ࢺ࡜ࡋ࡚ᶵ
⬟ࡋ࡚࠸ࡿ࡜⤖ㄽࡋࡓ㸦Fig. 5㸧㸬ᮏ◊✲࡟ࡼࡗ࡚㸪୰㛫య྾╔✀ࡢ͆ືࡁ͇㸦ᣑᩓࡸ㏫ࢫࣆ࣮ࣝ࢜ࣂ࣮㸧ࡀゐ፹ᛶ⬟ࡢไᚚᅉᏊ࡜࡞ࡿࡇ࡜ࢆ᫂☜࡟♧ࡋࡓ㸬ㄽᩥⓎ⾲ࢆ⾜࠺࡜࡜ࡶ࡟㸪໭ᾏ㐨኱Ꮫࡼࡾࣉࣞࢫ࣮ࣜࣜࢫࢆ⾜ࡗࡓ㸬ࠓㄽᩥࠔ

)LJ 3W7L2  ⾲㠃࡟࠾ࡅࡿ࣓ࢺ࢟ࢩ୰㛫యࡢ㏫ࢫࣆࣝ
࣮࢜ࣂ࣮࡜&+㸪&2ࡢ⏕ᡂ

3㸬ࣉࣛࢬ࣐ゐ፹཯ᛂࡢᶵᵓゎ᫂࡜Ꮫ⌮ᵓ⠏ᬮ໬࢞ࢫ࡛࠶ࡿCO2ࡢ㑏ඖ࡟ࡼࡿ෌㈨※໬ࡣ࣮࢝࣎ࣥ
ࢽ࣮ࣗࢺࣛࣝࢆᐇ⌧ࡍࡿୖ࡛ࡢ࣮࢟ࢸࢡࣀࣟࢪ࣮࡛࠶ࡿ㸬⌧ᅾ㸪ୡ⏺୰ࡢ◊✲⪅ࡀ㸪CO2ࢆྜᡂ࢞ࢫࡢཎᩱ࡛࠶ࡿCOࡸኳ↛࢞ࢫࡢ୺ᡂศ࡛࠶ࡿCH4㸪໬Ꮫཎᩱ࡜࡞ࡿ࢔ࣝࢥ࣮
ࣝ㸦CH3OH㸪C2H5OH㸧࡞࡝࡟㧗ຠ⋡࡛ኚ᥮ࡍࡿゐ፹㛤Ⓨࢆ㐍ࡵ࡚࠸ࡿ㸬ࡋ࠿ࡋ࡞ࡀࡽCO2ࡣ໬Ꮫⓗ࡟Ᏻᐃ࡛࠶ࡾ㸪ࡑࡢኚ᥮࡟ࡣ㏻ᖖ㸪㧗 㧗ᅽ᮲௳ࡀᚲせ࡛࠶ࡿ㸬୍᪉㸪㏆
ᖺ㸪CO2ࢆࣉࣛࢬ࣐࡟ࡼࡾάᛶ໬ࡍࡿࡇ࡜࡛㸪ప పᅽ࡛཯ᛂࡀ㐍⾜ࡍࡿࡇ࡜ࡀሗ࿌ࡉࢀ㸪“ࣉࣛࢬ࣐ゐ፹཯ᛂ”࡜ࡋ࡚Ḣ⡿ࡸ୰ᅜ㸪㡑ᅜ࡛άⓎ࡟◊✲ࡀ࡞ࡉࢀ࡚࠸ࡿ㸬ࣉࣛࢬ
࣐ゐ፹཯ᛂ࡜㏻ᖖࡢ⇕㥑ື࡟ࡼࡿゐ፹཯ᛂࡢ㢮ఝⅬ࣭┦㐪
Ⅼࢆ⌮ゎࡋ㸪ࣉࣛࢬ࣐ゐ፹཯ᛂ࡟㐺ࡋࡓゐ፹ᮦᩱࢆ㛤Ⓨࡍࡿ࡜࡜ࡶ࡟㸪෌㏦ྍ⬟࢚ࢿࣝࢠ࣮ࢆࣉࣛࢬ࣐㥑ືࡢ㟁ຊ࡜ࡍࡿࡇ࡜࡛㸪௒ᚋᐇ⏝໬࡬ࡢ㐨ࡶ㛤ࡅࡿ࡜ᮇᚅࡉࢀࡿ㸬ࡋ࠿ࡋ࡞ࡀࡽ㸪ࣉࣛࢬ࣐୰࡛Ⓨ⏕ࡍࡿ㟁Ꮚࡸ࢞ࢫάᛶ✀㸦᣺ືບ㉳✀㸪㟁Ꮚບ㉳✀㸪ࣛࢪ࢝ࣝ㸪ゎ㞳✀㸪ṇ࣭㈇࢖࢜ࣥ
✀࡞࡝㸧࡜ゐ፹⾲㠃࡜ࡢ┦஫స⏝ࡸ㸪ࡑࡢ⤖ᯝ⏕ࡌࡿゐ፹ࡢ౯ᩘ࣭ᵓ㐀ኚ໬࡞࡝࡟ࡘ࠸࡚୙᫂࡞Ⅼࡀከࡃ㸪཯ᛂᶵᵓࡣ༑ศ࡟ゎ᫂ࡉࢀ࡚࠸࡞࠸㸬཯ᛂᶵᵓࡢゎ᫂࡟ࡣ㸪ゐ፹ࡢࡑࡢሙ/࢜࣌ࣛࣥࢻィ ࡀ୙ྍḞ࡛࠶ࡿ㸬ᡃࠎࡣ㸪ࣉࣛࢬ࣐ゐ፹཯ᛂ୰ࡢ࢜࣌ࣛࣥࢻXAS ᐃࢆྍ⬟࡜ࡍࡿࢭࣝ㸦㏱㐣ἲ㸧ࢆ᪂ࡓ࡟㛤Ⓨࡍࡿ࡜࡜ࡶ࡟㸪⾲㠃⛉Ꮫィ ࡶ㥑౑ࡍࡿࡇ࡜࡛཯ᛂᶵᵓࡢゎ᫂࡜Ꮫ⌮ࡢᵓ⠏ࢆ㐍ࡵ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 Ni/Al2O3ゐ፹ࢆ⏝࠸ࡓCO2Ỉ⣲໬཯ᖺሗ࣭◊✲ᐊ⦅‫ە‬ᛂ㸦࣓ࢱࢿ࣮ࢩࣙࣥ㸧࡟࠾࠸࡚㸪ࣉࣛࢬ࣐࡟ࡼࡗ࡚άᛶࡀ
๻ⓗ࡟ቑຍࡍࡿࡇ࡜ࢆぢฟࡋࡓ㸬in situ XAFS ᐃ࡛ࡣࣉࣛࢬ࣐ࡢ᭷↓࡛ゐ፹ᵓ㐀࡟ኚ໬ࡀ࡞࠸ࡇ࡜ࢆ☜ㄆࡋࡓ㸬insitu IR ᐃࡸ➨୍ཎ⌮ィ⟬ࡢ⤖ᯝࢆࡶ࡜࡟㸪୰㛫య࡛࠶ࡿ
formate࡜Ẽ┦࠿ࡽ౪⤥ࡉࢀࡿࣉࣛࢬ࣐Ỉ⣲㸦ཎᏊ≧Ỉ⣲㸧ࡀEley-Ridealᆺ࡛཯ᛂࡍࡿpathࡀ࡛ࡁ㸪ࡇࢀ࡟ࡼࡗ࡚㞀ቨࡀపୗࡋ㸪άᛶࡀୖ᪼ࡋࡓ࡜⤖ㄽࡋࡓ㸬ࠓㄽᩥ‽ഛ୰ࠔ

(4) Dong, K.; Hu, B.; Harun Al Rashid, M.; Lu, B.; Miyabayashi,K.; Higashi, K.; Uruga, T.; Iwasawa, Y.; Kido, D.; Takakusagi,S.; Asakura, K. In situ Study on Structure of a Diluted
Pt/HOPG Model Catalyst System Prepared by the Two-phase
Liquid Reduction Method Using a Novel BCLA/HERFD+BIXAFS Method. eJSSNT, 2023, 22, DOI: 10.1380/ejssnt.2024004.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧(1) 㧘ⲡᮌ㐩㸸ࠕࡑࡢሙ/࢜࣌ࣛࣥࢻ⾲㠃⛉Ꮫィ ࡟ࡼࡿゐ፹཯ᛂࡢཎᏊࣞ࣋ࣝྍど໬ࠖ,➨ 452 ᅇゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘㸪ᮐᖠ, 㸦2023/6/5㸧.㹙ᣍᚅㅮ₇㹛
(2) Takakusagi, S.: “Atomic-level visualization of surface
catalytic reactions by in situ/operando surface science
techniques”, ICAT-FHI Symposium: Approaching to theCatalysis Reality, Sapporo (2023/9/11). [Invited㹛ᮾிᕤᴗ኱Ꮫ㔝ᓮᩍᤵ㸪㔠ຓᩍ㸪኱㜰኱Ꮫྂᕝᩍᤵ㸪ᕤᏛ◊✲㝔బࠎᮌᩍᤵ㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ㔠◊✲ࢢ࣮ࣝࣉ㛗ࠕࣉࣛࢬ࣐ゐ፹཯ᛂࡢᶵᵓゎ᫂࡜Ꮫ⌮ᵓ⠏ࠖ/ྡྂᒇ኱Ꮫ
ᒣ⏣෸ᩍᤵࠕ࣏ࣝࣇ࢕࣭ࣜࣥࣇࢱࣟࢩ࢔ࢽࣥ࠿ࡽ࡞ࡿ㉸ศᏊ㞟ྜయࡢ࢔ࣝ࢝ࣥάᛶ໬ゐ፹࡬ࡢᛂ⏝/ゐ፹⛉Ꮫ◊✲ᡤΎỈᩍᤵ࣭㛗㇂ᕝᩍᤵ࣭ᮅ಴ᩍᤵ㸪໬Ꮫ཯ᛂ๰ᡂ◊✲ᣐⅬ
㸦ICReDD㸧㧗෸ᩍᤵ㸪ᮾி኱Ꮫ⏕⏘ᢏ⾡◊✲ᡤ⚟㇂ᩍᤵ㸪ᑠ⃝ຓᩍ㸪ᮾி㟁ᶵ኱Ꮫᑠ಴෸ᩍᤵ㸪㟁Ẽ㏻ಙ኱Ꮫ୕㍯≉
௵෸ᩍᤵࠕᢸᣢ㔠ᒓゐ፹࡟࠾ࡅࡿ୰㛫య྾╔✀ࡢືⓗᣲື࡜άᛶ࣭㑅ᢥᛶ࡜ࡢ┦㛵࡟㛵ࡍࡿ◊✲ࠖ㸦ㄽᩥ 1㸧/ゐ፹⛉Ꮫ◊✲ᡤᮅ಴ᩍᤵࠕ࣓ࢱࣥࡢ㠀㓟໬࢝ࢵࣉࣜࣥࢢ࡟άᛶࢆ
♧ࡍ In/SiO2 ゐ፹ࡢ࢜࣌ࣛࣥࢻ XAFS ᵓ㐀ゎᯒࠖ㸦ㄽᩥ 3㸧
/ゐ፹⛉Ꮫ◊✲ᡤᮅ಴ᩍᤵࠕ⇞ᩱ㟁ụࣔࢹࣝゐ፹⾲㠃ࡢ insitu XAFS ᵓ㐀ゎᯒࠖ㸦ㄽᩥ 4㸧

‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦ࡍ࡭࡚ᑂᰝࡘࡁ㸧(1) Liu, C.; Lu, B.; Ariga-Miwa, H.; Ogura, S.; Ozawa, T.;
Fukutani, K.; Gao, M.; Hasegawa, J.; Shimizu, K.; Asakura,
K.; Takakusagi, S. Dynamic Behavior of Intermediate
Adsorbates to Control Activity and Product Selectivity in
Heterogeneous Catalysis: Methanol Decomposition on
Pt/TiO2(110). J. Am. Chem. Soc., 2023, 145, 19953–19960.
[Selected as a supplement cover, ໭ᾏ㐨኱Ꮫࡼࡾࣉࣞࢫࣜ
࣮ࣜࢫ](2) Kim, C-.R.; Maeda, H.; Lu, B.; Nakamura, Y.; Lin, Y.;
Wakisaka, Y.; Kido, D.; Asakura, K.; Takakusagi, S. Can
amine ligands atomically disperse Cu atoms on TiO2(110)? :Cu deposition on TiO2(110) premodified with o-anthranilic
acid. Chem. Lett., 2023, 53, upad045.
(3) Wada, T.; Kashaboina, U.; Nishikawa, Y.; Wakisaka, Y.;
Bao, D.; Takakusagi, S.; Inami, Y.; Kuriyama, F.; Dipu, A. L.;
Ogihara, H.; Iguchi, S.; Yamanaka, I.; Kido, D.; Kimura, M.;
Uo, M.; Asakura, K. The Effect of Structural Change during
the Activation Process on the Catalysis of In/SiO2
Nonoxidative Coupling of Methane: An Operando XAFSStudy. J. Phys. Chem. C, 2023, 127, 24211–24222.

‫ە‬ᖺሗ࣭◊✲ᐊ⦅(3) 㧘ⲡᮌ㐩㸸ࠕ୙ᆒ୍࡞ᵓ㐀ࢆ᭷ࡍࡿᅛయゐ፹ࡢᨺᑕග
ࢆ⏝࠸ࡓᵓ㐀ゎᯒ㸸୙ᆒ୍ᛶ࡬ࡢᣮᡓࠖ,➨ 132 ᅇゐ፹ウㄽ఍㸪ᮐᖠ,㸦2023/9/13㸧.㹙ᣍᚅㅮ₇㹛
(4) Takakusagi, S.: “Dynamic Behavior of Intermediate
Adsorbates to Control Activity and Product Selectivity in
Heterogeneous Catalysis: Methanol Decomposition on
Pt/TiO2(110)”, MIRAI 2.0 Research and Innovation Week
2023 Materials Science TEG, Umeå (2023/11/13). [Invited㹛(5) Takakusagi, S.: “Development of synchrotron X-ray andsurface science techniques for characterizing plasma catalysis”,
2023 Australia-Japan Symposium on Plasma Catalysis,
Adelaide (2023/11/23). [Invited㹛(6) Lu, B.; Xu, H.; Asakura, K.; Takakusagi, S.: “Plasmaassisted nitrogen fixation and ammonia synthesis on Co surface
at room temperature”, 2023 Australia-Japan Symposium on
Plasma Catalysis (AJSPC2023), Adelaide (2023/11/23).
(7) Lu, B.; Kido, D; Xu, H.; Asakura, K.; Takakusagi, S.:“Operando PTRF-XAFS technique for elucidating relationshipbetween 3D structure of active metal sites under working
conditions”, International Symposium on Atomic Level
Characterizations in Winter 2024 (ALC-W 2024), Furano(2024/1/18).
(8) 㧘ⲡᮌ㐩㸸ࠕᨺᑕග࡜⾲㠃⛉Ꮫࢆ⏝࠸ࡓゐ፹άᛶⅬࡢཎᏊࣞ࣋ࣝᵓ㐀ゎᯒࠖ, ໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ࣭❧࿨㤋኱Ꮫ SR ࢭࣥࢱ࣮ඹദࢩ࣏ࣥࢪ࣒࢘ࠕゐ፹⛉Ꮫ࡜ᨺᑕග㸫Soft㹼Tender X ⥺ࡢ᪂ࡓ࡞ᒎ㛤ࠖ㸪ⲡὠ㸪 (2024/1/26).
㹙ᣍᚅㅮ₇㹛
(9) 㧘ⲡᮌ㐩㸸ࠕ୙ᆒ୍࡞ᵓ㐀ࢆ᭷ࡍࡿゐ፹ᮦᩱ࡟࠾ࡅࡿ
ᵓ㐀-άᛶ┦㛵ࡢホ౯㸸༢⤖ᬗࣔࢹࣝゐ፹ࢆ⏝࠸ࡓ࢔ࣉ࣮ࣟࢳࠖ, 2023 ᖺᗘ㔞Ꮚࣅ࣮࣒ࢧ࢖࢚ࣥࢫࣇ࢙ࢫࢱ㸪Ỉᡞ (2024/3/6).㹙ᣍᚅㅮ₇㹛31

ゐ፹཯ᛂ◊✲㒊㛛/Catalytic Reaction
Research Division‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒ୰ᓥΎ㝯࣭ࠑ෸ᩍᤵࠒⳢ἟Ꮫྐ࣭ࠑຓᩍࠒ኱㡲㈡㑈ኴ࣭ࠑ༤ኈ◊✲ဨࠒJan J. WIESFELD࣭ࠑ㠀ᖖ໅◊✲ဨࠒNavya Subray BHAT㹙2023/06/01㹼㹛࣭ࠑJSPS እᅜே≉ู◊✲ဨࠒDaniele PADOVAN 㹙㹼2023/08/31㹛
࣭ࠑእᅜே◊✲
ဨࠒZhihao YU㹙2024/01/01㹼㹛࣭ࠑᏛ⾡◊✲ဨࠒఀ⸨᫓
ዉ࣭ࠑ⎔ቃ໬Ꮫ㝔኱Ꮫ㝔༤ኈㄢ⛬ࠒ▼ἨSusanta Kumar
SAHOO࣭ࠑ⎔ቃ໬Ꮫ㝔኱Ꮫ㝔ಟኈㄢ⛬ࠒ᪂஭┤⿁ಛ᭏ᩊ᳿ὒ࣭ࠑ◊✲⏕ࠒ᳿Ύ㹙㹼2024/03/06㹛࡚ࡶᅛయゐ፹ࡢ฼⏝ࡀ㐍ࡵࡽࢀ࡚ࡁࡓࡀ㸪ࣂ࢖࣐࢜ࢫᇶ㉁ࡀࡶࡘከ㔞ࡢྵ㓟⣲ᐁ⬟ᇶࡀᘬࡁ㉳ࡇࡍ๪཯ᛂࢆᢚไࡍ
ࡿ㠉᪂ⓗ࡞࢔࢖ࢹ࢕࢔ࡀ࡞ࡃ㸪ᅛయゐ፹ࣉࣟࢭࢫࡢᮏ᮶ࡢ
≉Ⰽ࡛࠶ࡿ㧗࠸⏕⏘ᛶ࡜⎔ቃప㈇Ⲵࡢᕤᴗࣉࣟࢭࢫࡢᇶ
♏Ꮫ⌮ࡀᵓ⠏ࡉࢀ࡚࠸࡞࠸㸬ࡑࡇ࡛ᙜ㒊㛛࡛ࡣ㸪ࣂ࢖࣐࢜ࢫ⏤᮶ࡢ⢾㢮࠿ࡽከᵝ࡞ᇶᖿ໬Ꮫရཎᩱ࡜࡞ࡿࣇࣛࣥ㢮ࡢྜᡂࢆ┠ᣦࡋ㸪ࡑࡢ⎔ቃప㈇Ⲵኚ᥮ࣉࣟࢭࢫࢆᵓ⠏ࡍࡿࡓࡵ࡟ᚲ㡲࡜࡞ࡿᅛయゐ፹཯ᛂࣉࣟࢭࢫࡢ㛤Ⓨ࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿ㸦Fig. 1㸧㸬ࣇࣛࣥ㢮ࡢኚ᥮཯ᛂ࡛ࡣ㸪๪཯ᛂࢆᢚไࡍࡿᡭẁ࡜ࡋ࡚ࡢ࢔ࢭࢱ࣮
ࣝಖㆤᇶࡢά⏝ࢆ㐍ࡵ࡚࠸ࡿ㸬᪂ࡋ࠸ᅛయゐ፹ࡢ㛤Ⓨ࡜ᇶ㉁ࡢ཯ᛂᛶไᚚࢆᇶ┙࡜ࡋࡓゐ፹཯ᛂࣉࣟࢭࢫࡢタィ࡟ࡼࡾ㸪ᚑ᮶ᆺࡢ༢⣧࡞཯ᛂ᮲௳ࡢ᭱㐺໬◊✲࡜ࡣ୍⥺ࢆ⏬
ࡋࡓ◊✲ࢆ᥎㐍ࡍࡿ㸬‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
2023ᖺ4᭶࡟Ⳣ἟Ꮫྐ෸ᩍᤵࡀゐ፹⛉Ꮫ◊✲ᡤ࡟╔௵ࡋ㸪Susanta Kumar Sahooྩ㸦༤ኈ㸯ᖺ㸧ࡀຍࢃࡗࡓ㸬6᭶࡟
Bhat Navya Subrayࡉࢇ㸦㠀ᖖ໅◊✲ဨ㸧ࡀຍࢃࡗࡓᚋ㸪9᭶
࡟Daniele Padovan༤ኈࡀ⚟ᒸ◊✲ᐊ࡬≉௵ຓᩍ࡜ࡋ࡚␗
ືࡋࡓ㸬10᭶࡟ᩊ᳿ὒྩ㸦ಟኈ1ᖺ㸧࡜᳿ Ύࡉࢇ㸦◊✲⏕㸧㸪
2024ᖺ1᭶࡟Zhihao Yu༤ኈ㸦እᅜே◊✲ဨ㸧ࡀຍࢃࡗࡓ㸬‫✲◊ڦ‬ㄢ㢟෌⏕ྍ⬟࡞Ⅳ⣲㈨※࠿ࡽࡢ࢚ࢿࣝࢠ࣮࣭໬Ꮫရ〇㐀ࢆ☜❧ࡍࡿࡇ࡜ࡣ㸪ᣢ⥆ྍ⬟࡞ᮍ᮶♫఍ࡢᇶ♏࡜࡞ࡿ㸬ゐ፹཯ᛂ◊✲㒊㛛࡛ࡣ㸪ࡇࡢ͆ࣅࢪ͇ࣙࣥࢆᐇ⌧ࡍࡿࡓࡵࡢ◊✲άື࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿ㸬ලయⓗ࡟ࡣ㸪࠶ࡾࡩࢀࡓ᳜≀㈨※ࢆ͆෌⏕ྍ⬟࡞ᚠ⎔ᆺⅣ⣲㈨※͇࡜఩⨨௜ࡅ㸪ࡑࢀࢆ฼⏝ࡋࡓ࢚ࢿࣝࢠ࣮࣭໬Ꮫရ〇㐀ࡢࡓࡵࡢせ⣲ᢏ⾡ࢆ㛤Ⓨࡍࡿ㸬໬Ꮫ཯ᛂࢆᨭ㓄ࡍࡿ͆ゐ፹͇ࢆ㏣ồࡋ㸪͆㧗࠸⏕⏘ᛶ࡜⎔ቃ㈇Ⲵࡀᴟ㝈ࡲ࡛ᑡ࡞࠸ḟୡ௦໬Ꮫ཯ᛂࣉࣟࢭࢫ࡟
ࡼࡿᣢ⥆ྍ⬟࡞ࡶࡢ࡙ࡃࡾ͇ࡢᐇ⌧࡟㈉⊩ࡍࡿ㸬ᣢ⥆ྍ⬟࡞㈨※ᚠ⎔ᆺ♫఍ࡢᵓ⠏ࢆ┠ᣦࡋ㸪෌⏕ྍ⬟࡞͆ࣂ࢖࣐࢜ࢫ㈨※͇ࢆⅣ⣲㈨※࡟฼⏝ࡋࡓ⇞ᩱ࠾ࡼࡧᇶ
ᖿ໬Ꮫရࡢ㛤Ⓨࡀὀ┠ࡉࢀ࡚࠸ࡿ㸬✵Ẽ୰࡟Ꮡᅾࡍࡿ஧㓟
໬Ⅳ⣲ࢆ฼⏝ࡋࡓ⇞ᩱ࣭ᇶᖿ໬Ꮫရ〇㐀ࣉࣟࢭࢫࡶ᭷ᮃ࡞
࢔ࣉ࣮ࣟࢳ࡛࠶ࡿࡀ㸪㏆ᮍ᮶࡟࠾ࡅࡿᚠ⎔ᆺⅣ⣲㈨※ࢆ฼⏝ࡋࡓ໬Ꮫ⏘ᴗࢆ✌ാࡉࡏࡿࡓࡵ࡟ࡣ㸪ࣂ࢖࣐࢜ࢫ㈨※ࡢ฼ά⏝ࡀᚲせ୙ྍḞ࡛࠶ࡿ㸬ࡇࢀࡲ࡛࡟ࣂ࢖࣐࢜ࢫ໬Ꮫရ
ࢆ⏝࠸࡚໬▼㈨※໬Ꮫရࡢ௦᭰ࡸ᪂ࡋ࠸ỗ⏝ᮦࡢ๰ฟࡀ
ከᩘᥦ᱌ࡉࢀ࡚࠸ࡿࡀ㸪ࡑࡢ኱㒊ศࡀỗ⏝໬࣭ᬑཬࢆ᝿ᐃ
࡛ࡁࡿࣞ࣋ࣝࡲ࡛⮳ࡗ࡚࠸࡞࠸㸬ࡑࡢ᭱኱ࡢ⌮⏤ࡣ㸪ỗ⏝ᮦࡢ኱つᶍ⏕⏘࡟ᚲせ࡞͆㧗࠸⏕⏘ᛶ͇࡜͆⎔ቃప㈇Ⲵ͇
ࢆేࡏᣢࡘࣂ࢖࣐࢜ࢫኚ᥮ࣉࣟࢭࢫࡀᵓ⠏ࡉࢀ࡚࠸࡞࠸
ࡇ࡜࡟࠶ࡿ㸬࢚ࢿࣝࢠ࣮ᾘ㈝ࡢ኱ࡁ࡞ศ㞳ᅇ཰ࣉࣟࢭࢫࢆᚲせ࡜ࡏࡎ㸪⧞ࡾ㏉ࡋ౑⏝࡛ࡁࡿᏳᐃ࡛㧗άᛶ࡞ᅛయゐ፹ࡢ฼⏝ࡣ㸪ࡇࢀࡲ࡛ࡢ໬▼㈨※ࢆ฼⏝ࡋࡓ͆పࢥࢫࢺ࣭ప
࢚ࢿࣝࢠ࣮࣭ప⎔ቃ㈇Ⲵ࡛ᣢ⥆ྍ⬟࡞ࡶࡢ࡙ࡃࡾ͇࡜࠸࠺
⏘ᴗࡢ⌮᝿ീࢆᐇ⌧ࡍࡿࡓࡵ࡟኱ࡁ࡞ᙺ๭ࢆᯝࡓࡋ㸪ᩘከࡃࡢᇶᖿ໬Ꮫရ〇㐀㸦࢔ࣥࣔࢽ࢔〇㐀ࡸ▼Ἔࡢ⢭〇࣭ᨵ㉁㸧
ࡢᇶ┙ᢏ⾡࡜࡞ࡗ࡚ࡁࡓ㸬ࣂ࢖࣐࢜ࢫኚ᥮ࣉࣟࢭࢫ࡟࠾࠸

3232

Fig.1. ࢭ࣮ࣝࣟࢫ࠿ࡽᇶᖿ໬Ꮫရࡢཎᩱ࡬ࡢㄏᑟ⤒㊰

1㸬㔠ᒓ㓟໬≀ゐ፹࡟ࡼࡿ⢾㢮ࡢኚ᥮཯ᛂ
㠀ᬗ㉁ࡢ㓟໬ࢽ࢜ࣈ㸦ྵỈࢽ࢜ࣈ㓟㸧ࡣỈ୰࡛ᶵ⬟ࡍࡿࣝ࢖ࢫ㓟ゐ፹࡛࠶ࡾ㸪ࡑࡢ⬺Ỉస⏝࡟ࡼࡗ࡚ࢢࣝࢥ࣮ࢫࢆ
Ỉ⁐ᾮෆ࡛ከᵝ࡞ᇶᖿ໬Ꮫရ࡬ㄏᑟࡍࡿࡓࡵࡢ㘽࡜࡞ࡿ
5-ࣄࢻࣟ࢟ࢩ࣓ࢳࣝࣇࣝࣇ࣮ࣛࣝ㸦HMF㸧࡬࡜ኚ᥮ࡍࡿࡇ
࡜ࡀ࡛ࡁࡿ㸦Fig. 1㸧㸬୍᪉㸪ప⤖ᬗᛶࡢ㓟໬ࢳࢱࣥࡣỈ୰࡛ᶵ⬟ࡍࡿࣝ࢖ࢫ㓟ሷᇶࢧ࢖ࢺࢆࡶࡕ㸪ࡑࡢ༠ዌⓗ⬺Ỉస⏝࡟ࡼࡗ࡚ࢢࣝࢥ࣮ࢫ࠿ࡽ HMF ࢆ⏕ᡂࡍࡿࡇ࡜ࡀ࡛ࡁࡿ㸬ࢽ࢜ࣈࡸࢳࢱࣥࢆ࣮࣋ࢫ࡜ࡋࡓ᪂ࡋ࠸⢾ኚ᥮⏝ᅛయゐ፹ࡢ๰⏕ࡍࡿᡭἲ࡜ࡋ࡚㸪ձ」ྜ㓟໬≀࡬ࡢᣑᙇ࡟ࡼࡿ㓟ᛶ㉁࠾ࡼࡧሷᇶᛶ㉁ࡢไᚚ㸪ղ⤖ᬗ໬ᗘࡢኚ໬࡟ࡼࡿ㓟ᐦᗘ࣭㓟ᙉᗘࡢไᚚ㸪ࡀ㔜せ࡜࡞ࡿ㸬
2023ᖺᗘࡢࢺࣆࢵࢡ㸸1) YNbO4ࡢ㓟ሷᇶᛶ㉁࡜ࡑࢀࢆ฼⏝ࡋࡓ⢾ኚ᥮཯ᛂࢰࣝࢤࣝἲ࡛ㄪ〇ࡋࡓ㠀ᬗ㉁ࡢྵỈ㓟໬ࢽ࢜ࣈ࡟࢔ࣥ
ࣔࢽ࢔Ỉ࡜㐣㓟໬Ỉ⣲Ỉࢆຍ࠼࡚⤖ᬗ≧ࡢ㐣㓟໬≀㘒య㸦 (NH4)3[Nb(O2)4] 㸧 ࢆ ⏕ ᡂ ࡉ ࡏ 㸪 ࡑ ࡢ Ỉ ⁐ ᾮ ࡟ ➼ 㔞 ࡢ
Y(NO3)3 ࡀ⁐ゎࡋࡓỈ⁐ᾮࢆࡺࡗࡃࡾ࡜⁲ୗࡍࡿ࡜⁐ᾮෆ࡟ⓑⰍỿẊࡀ⏕ᡂࡍࡿ㸬ࡇࡢ๓㥑యࢆ✵Ẽ୰࡛↝ᡂࡍࡿࡇ࡜࡟ࡼࡗ࡚ YNbO4 ࡀᚓࡽࢀࡿ㸬
700 ºC ࡛↝ᡂࡋࡓヨᩱࡣṇ᪉ᬗ YNbO4 ࡢ⤖ᬗᛶ㓟໬≀࡛࠶ࡾ㸪ࡑࡢ୺せ࡞ᵓ㐀ࣘࢽࢵࢺࡣ 4 㓄఩ࢽ࢜ࣈ✀࡛࠶ࡿ
㸦Fig. 2㸧㸬」ྜ㓟໬≀ࡢྜᡂ࡛ࡣ୍⯡ⓗ࡞ᅛ┦ἲࡀ᥇⏝ࡉࢀ࡚࠾ࡾ㸪2 ✀㢮ࡢ㓟໬≀ࢆΰ⦎ࡋ࡚㧗 ↝ᡂࡍࡿࡇ࡜
࡟ࡼࡗ࡚┠ⓗࡢ」ྜ㓟໬≀ࢆྜᡂࡍࡿ㸬㛗᫬㛫ࡢ㧗 ↝ᡂ࡟ࡼࡾᚓࡽࢀࡿ㧗⤖ᬗᛶ㓟໬≀ࡢ⾲㠃✚ࡣ㠀ᖖ࡟ᑠࡉࡃ㸪୍⯡ⓗ࡟ࡣᅛయゐ፹࡜ࡋ࡚᭷ຠ࡛ࡣ࡞࠸㸬୍᪉㸪ᾮ┦ỿẊἲ࡟ࡼࡗ࡚ᚓࡽࢀࡿ๓㥑యࡣ 2 ✀㢮ࡢ㔠ᒓ✀㸦Y ࡜ Nb㸧ࡀཎᏊ࡛ࣞ࣋ࣝᆒ୍ΰྜࡋࡓ≧ែ࡛࠶ࡾ㸪㠀ᬗ㉁ࡢ≧ែ࠿ࡽ」ྜ㓟໬≀࡟≉᭷ࡢᵓ㐀≉ᛶࢆ᭷ࡋ㸪700 ºC ࡢ⤖ᬗ໬ࡋࡓᚋࡶ 10-20 m2 g-1 ⛬ᗘࡢ኱ࡁ࡞⾲㠃✚ࢆಖᣢࡋ࡚࠸
ࡿ㸬ᖺሗ࣭◊✲ᐊ⦅‫ە‬

Fig. 2 ṇ᪉ᬗYNbO4ࡢᵓ㐀ᅗṇ᪉ᬗ YNbO4 ࡢ⾲㠃࡟ࡣࣝ࢖ࢫ㓟ሷᇶࢧ࢖ࢺࡀᏑᅾࡋ
࡚࠾ࡾ㸪ࡑࡢゐ፹స⏝ࢆࢢࣝࢥ࣮ࢫࡢ⬺Ỉ཯ᛂ࡛ホ౯ࡋࡓ㸬ゐ፹⾲㠃ࢆࣜࣥ㓟࡛ฎ⌮ࡋ࡚๪཯ᛂࢆㄏ㉳ࡍࡿሷᇶᛶ
ࢧ࢖ࢺࢆ୙άᛶ໬ࡍࡿ࡜㸪┠ⓗ⏕ᡂ≀࡛࠶ࡿ HMF ࡢ཰⋡࣭㑅ᢥ⋡ࡀ኱ᖜ࡟ྥୖࡋࡓ㸬ࡑࡢάᛶࡣ⤖ᬗᛶ㓟໬ࢽ࢜ࣈࢆ
ྵࡴẚ㍑ゐ፹࡟ẚ࡭࡚ࡶ㧗࠸ࡔࡅ࡛ࡣ࡞ࡃ㸪౑⏝ᚋࡢゐ፹ࢆ༢⣧࡟✵Ẽ↝ᡂࡍࡿࡇ࡜࡟ࡼࡾ෌฼⏝࡛ࡁࡓ㸬ྵỈ㓟໬ࢽ࢜ࣈࡢࡼ࠺࡞㠀ᬗ㉁యࡸ㓟໬ࢳࢱࣥࡢࡼ࠺࡞ప⤖ᬗయ
࡛ࡣ⧞ࡾ㏉ࡋ౑⏝ࡢ㝿ࡢ↝ᡂฎ⌮࡟ࡼࡾ⤖ᬗ໬ࡀ㉳ࡇࡾ㸪ᮏ᮶ࡢ㧗࠸άᛶ࣭㑅ᢥᛶࡀపୗࡍࡿࡇ࡜ࡀከ࠸㸬୍᪉㸪
YNbO4 ࡢゐ፹స⏝ࡣᏳᐃ࡞⤖ᬗᵓ㐀⾲㠃࡟ᙧᡂࡉࢀࡓ㓟ሷᇶᛶࢧ࢖ࢺ࡟ᇶ࡙ࡃࡓࡵ㸪↝ᡂฎ⌮࡟ࡼࡿάᛶపୗࡣ㉳ࡇࡽ࡞࠸㸬࡞࠾㸪1) Y2O3 ⏤᮶ࡢࣝ࢖ࢫ㓟ᛶ㉁ࡀᮏ཯ᛂ࡟
᭷ຠ࡛࡞࠸ࡇ࡜㸪2) Nb2O5 ࡟ࡣሷᇶᛶࢧ࢖ࢺࡀ࡞࠸ࡢ࡛㸪
YNbO4 ࡢሷᇶᛶ㉁ࡣሷᇶᛶ㓟໬≀ࢆᙧᡂࡍࡿ࢖ࢵࢺࣜ࢘
࣒࡟⏤᮶ࡍࡿࡇ࡜㸪3) ࣜࣥ㓟ฎ⌮࡟ࡼࡗ࡚ሷᇶᛶ㉁ࡀ኱
ᖜ࡟పୗࡋ࡚᪂ࡋ࠸ࣝ࢖ࢫ㓟ࢧ࢖ࢺࡀᙧᡂࡉࢀࡿࡇ࡜ࢆ
㋃ࡲ࠼㸪ࣜࣥ㓟ฎ⌮ࡋࡓ YNbO4-ࡢࢽ࢜ࣈ⏤᮶ࡢ୺࡞άᛶ
ࢧ࢖ࢺࢆ௨ୗࡢࡼ࠺࡟ᥦ᱌ࡋࡓ㸬

2.HMF࢔ࢭࢱ࣮ࣝࡢኚ᥮཯ᛂ
ࣜࢢࣀࢭ࣮ࣝࣟࢫ࠿ࡽㄏᑟࡉࢀࡿHMFࡣ㸪ࣇࣛࣥ⎔ࢆᇶ┙࡜ࡋࡓᵝࠎ࡞᭷⏝࣏࣐࣮ࣜࡢཎᩱ࡜࡞ࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿ㸦Fig. 1㸧㸬ࡑࡢ୰࡛ࡶࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟ࡣ▼Ἔ⏤᮶ࡢࢸࣞࣇࢱࣝ㓟ࢆ⨨ࡁኚ࠼ࡿ᪂ࡓ࡞᳜≀⏤᮶࣏࢚ࣜࢫࢸࣝࡢཎᩱ࡜ࡋ࡚ὀ┠ࡉࢀ࡚࠸ࡿ㸬᳜≀⏤᮶ࡢࣂ࢖࢚࢜
ࢳࣞࣥࢢࣜࢥ࣮ࣝ࡜ࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟࠿ࡽྜᡂࡉࢀࡿ
PEFࡣ㸪▼Ἔ࠿ࡽసࡽࢀࡿ࣏࢚ࣜࢳࣞࣥࢸࣞࣇࢱ࣮ࣞࢺ
㸦PET㸧ࢆୖᅇࡿᵝࠎ࡞ඃࢀࡓ≀ᛶ㸦࢞ࢫ㏱㐣ᛶࡸ㧗࠸ᘬᙇᙉᗘ࡞࡝㸧ࢆࡶࡘ㸬ࡑࡢࡓࡵ㸪BASFࡸDupont࡞࡝ᾏእࡢ኱ᡭ໬Ꮫ࣓࣮࣮࢝ࡶࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟ࡢ኱つᶍྜᡂࢆ㐍ࡵ࡚࠸ࡿࡀ㸪⌧≧࡛ࡣ⏕⏘ᛶࡢ㧗࠸ࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟ࡢ኱つᶍྜᡂࡣ㐩ᡂࡉࢀ࡚࠸࡞࠸㸬ࡑࡢ᭱኱ࡢせᅉࡣ㸪
HMFࢆ㧗⃰ᗘ᮲௳ୗ࡛ຠ⋡ࡼࡃࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟࡬ኚ᥮ࡍࡿࡇ࡜ࡀ࡛ࡁ࡞࠸ࡇ࡜࡟࠶ࡿ㸬ࡑࡇ࡛ᡃࠎࡣ๪཯ᛂࡢ
ཎᅉ࡜࡞ࡿHMFࡢ࣑࣍ࣝࣝᇶࢆ1,3-ࣉࣟࣃࣥࢪ࣮࡛࢜ࣝ
ಖㆤࡋ㸪ࡑࡢᚋ࡟6ဨ⎔࢔ࢭࢱ࣮ࣝࢆྵࡴHMF㸦௨ୗ࡛ࡣ
PD-HMF࡜♧ࡍ㸧ࢆ㓟໬ࡍࡿࡇ࡜࡟ࡼࡾ㧗⃰ᗘ⁐ᾮෆ࡛ࡶ๪཯ᛂࢆᢚไࡋࡘࡘࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟ࢆྜᡂࡍࡿᡭἲ
ࢆ⪃᱌ࡋࡓ㸦Fig. 4㸧㸬
Step 2

Step 1
HO

O

O
H

HMF

O

Acetalization
HO

HO(CH2)3OH(1,3-propanediol)O

PD-HMF

O

OxidationO

Au/CeO2

HO

O

O
OH

FDCA



Fig. 4 PD-HMFࢆ฼⏝ࡋࡓࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟ྜᡂ

2023ᖺᗘࡢࢺࣆࢵࢡ㸸1) ㏲ḟ཯ᛂ࡟ࡼࡿPD-HMF࠿ࡽࡢMFDCྜᡂ
ࢭࣜ࢔ᢸᣢAuゐ፹㸦Au/CeO2㸧ࢆ౑⏝ࡋࡓPD-HMFࡢ㓟໬཯ᛂ࡟࠾࠸࡚ࡣ㸪㧗⃰ᗘ⁐ᾮ୰㸦10-20 wt%㸧࡛ࡶ๪཯ᛂࢆᢚไࡋࡘࡘࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟㸦FDCA㸧ࢆ㧗཰⋡࡛ྜᡂ࡛ࡁࡿࡇ࡜ࢆぢฟࡋ࡚࠸ࡿ㸬୍᪉࡛㸪┠ⓗ≀ࢆFDCA
࡟タᐃࡍࡿሙྜ㸪FDCAࡢ୰࿴ࡢࡓࡵ࡟ከ㔞ࡢሷᇶࢆຍ࠼ࡿᚲせࡀ࠶ࡿࡓࡵ㸪ᕤᴗᒎ㛤ࢆぢᤣ࠼ࡓ㝿࡟㧗࠸ࣁ࣮ࢻࣝ
࡜࡞ࡿ㸬ࡑࡇ࡛ᡃࠎࡣ㸪PD-HMFࡢ㓟໬ⓗ࢚ࢫࢸࣝ໬཯ᛂ
࡟ࡼࡿࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟࣓ࢳࣝ㸦MFDC㸧ࡢྜᡂ࡟ྲྀࡾ
⤌ࢇࡔ㸦Fig.5㸧
㸬

Fig. 3 ࣜࣥ㓟ฎ⌮࡟ࡼࡗ࡚ṇ᪉ᬗ YNbO4 ⾲㠃࡟⏕ᡂࡍࡿࣝ࢖ࢫ㓟ࢧ࢖ࢺࡢ᥎ᐃᵓ㐀
2)

MNb2O5ࡢ㸦M=Ba, Sr, Ca㸧ࡢྜᡂ࡜⢾㢮ࡢ⬺Ỉ཯ᛂ⤖ᬗ≧ࡢ Nb 㐣㓟໬≀㘒య࠿ࡽྜᡂࡉࢀࡿỈ⁐ᛶங㓟ࢽ࢜ࣈ㘒యࢆ฼⏝ࡋࡓ࢔ࣔࣝࣇ࢓ࢫ㔠ᒓ㘒యἲ࡟࡚㸪࢔ࣝ࢝ࣜᅵ㢮㔠ᒓࢆ➨஧ᡂศ࡜ࡋࡓࢽ࢜ࣈ⣔」ྜ㓟໬≀ࡢྜᡂ࡜ࡑࡢ㓟ゐ፹స⏝ࢆ᳨ウࡋࡓ㸬๓㥑యࡢ 700 °C ↝ᡂ࡟ࡼࡗ࡚༢୍┦ࡢ⤖ᬗᛶ」ྜ㓟໬≀ࡀᚓࡽࢀ㸪ࡑࡢ⾲㠃✚ࡣ
15~30 m2 g-1 ࡛࠶ࡗࡓ㸬ヨᩱࢆ࢟ࢩ࣮ࣟࢫࡢ⬺Ỉ཯ᛂ࡟㐺⏝ࡋࡓ࡜ࡇࢁ㸪ẚ㍑ⓗ࡟Ⰻዲ࡞཰⋡࣭㑅ᢥ⋡࡛ࣇࣝࣇ࣮ࣛ
ࣝࡀྜᡂ࡛ࡁࡿࡇ࡜㸪ࡉࡽ࡟⧞ࡾ㏉ࡋ౑⏝ᛶ࡟ඃࢀࡿࡇ࡜
ࢆ☜ㄆࡋࡓ㸬ࡲࡓ㸪๓㥑య⁐ᾮࢆD-Al2O3 ࡟ྵᾐᢸᣢࡋ㸪ࡑࢀࢆ 700 ºC ↝ᡂࡍࡿ࡜」ྜ㓟໬≀ࡢᚤ⢏Ꮚࡀᢸయ⾲㠃࡟ᙧᡂࡋ㸪༢఩㔜㔞ᙜࡓࡾࡢゐ፹άᛶࡀ኱ᖜ࡟ྥୖࡍࡿࡇ
࡜ࡶ☜ㄆࡋ࡚࠸ࡿ㸬ࡇࡢ࢔ࣉ࣮ࣟࢳࢆⓎᒎࡉࡏ㸪ࡼࡾ㧗άᛶ࡞ゐ፹㛤Ⓨࢆ⥅⥆ࡋ࡚࠸ࡿ㸬‫ە‬ᖺሗ࣭◊✲ᐊ⦅

Fig. 5 Au/CeO2ゐ፹ࢆ⏝࠸ࡓPD-HMF࠿ࡽࡢMFDCྜᡂ
ᮏ཯ᛂ࡛ࡣ㸪ඛࡎ㸪Au/CeO2࡟ࡼࡾ㸪PD-HMFࢆ2-࣑࣍ࣝࣝࣇࣛࣥ-5-࢝ࣝ࣎ࣥ㓟࣓ࢳࣝࡢ࢔ࢭࢱ࣮ࣝయ㸦PD-MFFC㸧࡬࡜ኚ᥮ࡋࡓ㸦཰⋡: 95%㸧㸬ḟ࡟㸪㓟ゐ፹࡟ࡼࡗ࡚PD-MFFC
ࢆMFFC࡜ಖㆤ๣࡛࠶ࡿ1,3-ࣉࣟࣃࣥࢪ࣮࢜ࣝ࡬࡜ຍỈศゎࡋࡓ㸦཰⋡: 99%㸧㸬1,3-ࣉࣟࣃࣥࢪ࣮࢜ࣝࡣࡇࡢẁ㝵࡛཯ᛂ⣔୰࠿ࡽᅇ཰ࡉࢀࡿ㸦ᅇ཰⋡: 92%㸧㸬᭱ᚋ࡟㸪ᮍಖㆤ
ࡢMFFCࡢ㓟໬ⓗ࢚ࢫࢸࣝ໬཯ᛂ࡟ࡼࡗ࡚MFDCࢆᚓࡓ33㸦཰⋡: 97 %㸧㸬ࡇࢀࡲ᳨࡛ウࡋ࡚ࡁࡓFDCAྜᡂࡢሙྜ㸪
ᇶ㉁࡟ᑐࡋ࡚350 mol%ࡢሷᇶࢆࣉࣟࢭࢫ඲య࡛౑⏝ࡋ࡚࠸ࡓࡀ㸪ᮏ཯ᛂ⣔࡛ࡣ㸪ࢃࡎ࠿7.5 mol%ࡲ࡛๐ῶࡍࡿࡇ࡜
ࡀ࡛ࡁࡓ㸬ࡇࢀࡲ࡛࡟ぢฟࡋ࡚ࡁࡓ࢔ࢭࢱ࣮ࣝಖㆤ࠾ࡼࡧ
㏲ḟ཯ᛂ⣔ࡢ࢚ࢵࢭࣥࢫ࡟ຍ࠼࡚㸪┠ⓗ⏕ᡂ≀ࡢ≉ᛶࢆ⪃
៖ࡋࡓゐ፹཯ᛂ⣔ࢆࢹࢨ࢖ࣥࡋࡓࡇ࡜࡛ᚑ᮶ࡼࡾࡶ⎔ቃㄪ࿴ᛶࡀ㧗࠸ゐ፹཯ᛂࣉࣟࢭࢫࡢ㛤Ⓨ࡟ᡂຌࡋࡓ㸬ḟ࡟㸪ゐ፹཯ᛂࣉࣟࢭࢫຠ⋡ࡢ᭦࡞ࡿྥୖࢆ┠ᣦࡋ࡚㸪࢔ࢭࢱ࣮ࣝ໬๣ࡢᅇ཰ࢆᚲせ࡜ࡋ࡞࠸ゐ፹཯ᛂ⣔ࡢᵓ⠏ࢆヨࡳࡓ㸬ᮏ཯ᛂ⣔࡛ࡣ㸪཯ᛂ⁐፹࡜ࡋ࡚⏝࠸࡚࠸ࡿ࣓ࢱ
ࣀ࣮ࣝࢆHMFࡢ࢔ࢭࢱ࣮ࣝ໬๣࡟᥇⏝ࡋࡓ㸬Au/CeO2ࢆゐ፹࡜ࡋ࡚㸪HMFࡢࢪ࣓ࢳࣝ࢔ࢭࢱ࣮ࣝయࡢ㓟໬ⓗ࢚ࢫࢸࣝ໬཯ᛂࢆ๓㏙ࡋࡓPD-HMF࡜ྠᵝࡢ㏲ḟ཯ᛂ⣔࡛ᐇ᪋ࡋࡓ⤖ᯝ㸪ࣉࣟࢭࢫ඲య཰⋡85%࡛MFDCࢆྜᡂࡍࡿࡇ࡜ࡀ࡛ࡁࡓ㸬2) 㑏ඖⓗ࢔࣑ࣀ໬࡟ࡼࡿ࣏ࣜ࢔࣑ࢻཎᩱࡢྜᡂ
HMFࡢ㒊ศ㓟໬≀࡛࠶ࡿ2,5-ࢪ࣑࣍ࣝࣝࣇࣛࣥ㸦DFF㸧
ࡢ࣑࣍ࣝࣝᇶࢆ㑏ඖⓗ࢔࣑ࣀ໬࡟ࡼࡗ࡚➨1⣭࢔࣑ࣥ࡬࡜
㏲ḟⓗ࡟ኚ᥮ࡍࡿ࡜㸪ࢪ࢔࣑ࣥయ㸦2,5-ࢪ࢔࣑ࣀ࣓ࢳࣝࣇ
ࣛࣥ㸪 AMF㸧ࢆྜᡂࡍࡿࡇ࡜ࡀ࡛ࡁࡿ㸬୍᪉࡛㸪ᮏ཯ᛂ⣔࡟࠾࠸࡚ࡶ㸪࣑࣍ࣝࣝᇶࡀᘬࡁ㉳ࡇࡍ๪཯ᛂࡀ῝้࡞ㄢ㢟࡜࡞ࡗ࡚࠾ࡾ㸪㧗⃰ᗘ⣔ࡢᐇ⌧ࢆጉࡆ࡚࠸ࡿ㸬ᮏ◊✲࡛ࡣ㸪1,3-ࣉࣟࣃࣥࢪ࣮࡛࢜ࣝಖㆤࡋࡓDFF㸦PD-DFF㸧ࡢ㑏ඖⓗ࢔࣑ࣀ໬཯ᛂࢆ᳨ウࡋࡓ㸦Fig. 6㸧㸬ゐ፹࡟ࡣ㸪㜰኱‶
␃G࡟ࡼࡗ࡚㛤ⓎࡉࢀࡓCo2Pࢼࣀࣟࢵࢻ㸦NRs㸧ࢆ⏝࠸ࡓ㸬ᮏ◊✲ࡢ≉ᚩࡣ㸪ࣂ࢖࣐࢜ࢫ⏤᮶ᇶ㉁ࢆᑐ㇟࡜ࡋࡓゐ፹཯ᛂ࡛࠶ࡿࡇ࡜࡟ຍ࠼㸪✵Ẽ୰࡛ࡶྲྀࡾᢅ࠸ࡀᐜ᫆࡞Co2Pࢼࣀࣟࢵࢻゐ፹࡟ࡼࡿ཯ᛂ⣔࡛࠶ࡿࡇ࡜㸪࢔ࢭࢱ࣮ࣝ໬࡟ࡼ
ࡿ๪཯ᛂไᚚࢆά⏝ࡋࡓ཯ᛂ⣔ࡢࢹࢨ࢖ࣥ࡟ྲྀࡾ⤌ࡴࡇ࡜࡛࠶ࡿ㸬

Fig 6. HMF࠿ࡽㄏᑟࡉࢀࡿ࢔ࣝࢹࣄࢻᇶ㉁ࡢ࢔ࢭࢱ࣮ࣝ
య㸦PD-DFF㸧࠿ࡽࡢ࢔࣑ࣥ㢮ྜᡂࡇࢀࡲ࡛࡟㸪࢔ࢭࢱ࣮ࣝᇶࢆᑟධࡍࡿࡇ࡜࡛๪཯ᛂࢆ኱
ᖜ࡟ᢚไ࡛ࡁࡿࡇ࡜ࢆぢฟࡋࡓ㸬ᮏ཯ᛂ⣔࡛ࡣ㸪ᇶ㉁⃰ᗘ
10 wt%࡟࠾࠸࡚ࡶ⣙90%ࡢ┠ⓗ⏕ᡂ≀཰⋡ࡀᚓࡽࢀ࡚࠸
ࡿ㸬ࡲࡓ㸪Co2P NRsゐ፹ࡢ෌฼⏝ᛶࡶ☜ㄆ࡛ࡁ࡚࠸ࡿ㸬‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧ᮾ໭኱Ꮫຍ⸨ⱥᶞᩍᤵࠕ⢾㢮㌿໬ࡢࡓࡵࡢ㧗ᶵ⬟ᅛయ㓟ሷᇶゐ፹ᵓ⠏ࠖ/ᶓ὾ᅜ❧኱Ꮫᮏ಴೺ᩍᤵࠕᅛయ⾲㠃࡟࠾ࡅࡿ㔠ᒓ㘒య࣭㔠ᒓࢼࣀ⢏Ꮚࡢ༠ዌⓗゐ፹స⏝ࡢゎ᫂ࠖ/༓ⴥ኱Ꮫ୍ᅧఙஅᩍᤵࠕ༝㔠ᒓ㓟໬≀ࢼࣀࢡࣛࢫࢱ࣮ゐ፹࡟ࡼࡿ࢔ࣝࢥ࣮ࣝࡢ㓟໬ⓗ⬺Ỉ⣲཯ᛂࠖ/኱㜰኱Ꮫᒣཱྀ΅ຓᩍࠕ㔠ᒓⅣ໬≀ࡢࢼࣀ⢏Ꮚ໬࡟ࡼࡿ᪂ወゐ፹స⏝๰ฟ࡜ࡑࢀ࡟
ᇶ࡙ࡃᾮ┦ศᏊኚ᥮཯ᛂࡢ㛤Ⓨࠖ/ᮾ໭኱Ꮫ⸭ୗ⍞ᕹຓᩍࠕࢮ࢜ࣛ࢖ࢺ㦵᱁୰࡟ᵓ⠏ࡋࡓ㏆᥋άᛶⅬࡢᛶ㉁࣭ゐ፹స⏝ࡢゎ᫂ࠖ/ᮾ໭኱Ꮫྜྷ஭୔ᬕຓᩍࠕ┿✵㧗 TPD࡟ࡼࡿࢮ࢜ࣛ࢖ࢺ୰Ỉ㓟ᇶࡢᐃᛶ࣭ᐃ㔞ศᯒἲࡢ☜❧ࠖ/ᮾ໭኱Ꮫ஧
ᐑ⩧ຓᩍࠕᨺᑕගX⥺ศග࡟ࡼࡿࢮ࢜ࣛ࢖ࢺ㦵᱁୰࣊ࢸࣟ
ཎᏊ㸫྾╔Ỉ㛫┦஫స⏝ࡢゎ᫂ࠖ/ᮾி㒔❧኱Ꮫᮧᒣᚭ≉௵ᩍᤵࠕࣂ࢖࣐࢜ࢫ㌿᥮཯ᛂ࡟᭷ຠ࡞㔠ࢼࣀ⢏Ꮚᢸᣢゐ፹ࡢ㛤Ⓨࠖ/ᚨᓥ኱Ꮫ㟖⏣┤ᏹຓᩍࠕᄇ㟝෾⤖㐀⢏஝⇱ἲ࡟ࡼ
ࡿNi/Al2O3ゐ፹ࡢㄪ〇ཬࡧCO2࣓ࢱࣥ໬཯ᛂ≉ᛶࠖ/໭஑ᕞ኱Ꮫ௒஭⿱அ෸ᩍᤵࠕࢮ࢜ࣛ࢖ࢺࢆᇶ┙࡜ࡋࡓ」ྜ㔠ᒓゐ
፹ࡢྜᡂࠖ

3434

‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦඲࡚ᑂᰝࡘࡁ㸧(1) Shunichi Sakai, Shingo Hasegawa, Siming Ding, Ryota
Osuga, Kiyotaka Nakajima, Shinji Tanaka, Wang-Jae Chun,
Ken Motokura, Low Temperature N-Allylation of Allylic
Alcohols via Synergistic Pd/Cu Catalysis: a Silica-Supported
Dual Metal Complex Strategy. ACS Catal., 2024, 14, 48354846.
(2) Takumi Kaneko, Mizuho Yabushita, Ryota Osuga, Kei Sato,
Ben Liu, Yoshinao Nakagawa, Kiyotaka Nakajima, Keiichi
Tomishige, Formation of paired Ga sites in CHA-type zeolite
frameworks via transcription-induced method. Chem.
Commun., 2024, 60, 3681-3684.
(3) Jan J. Wiesfeld, Ryota Osuga, Satoshi Suganuma, Takayuki
Aoshima, Emiel J.M. Hensen, Kiyotaka Nakajima, Oxidative
Esterification of Acetal-Protected 5-Hydroxymethylfurfural to
Dimethyl Furan-2,5-dicarboxylate with High Recovery ofProtecting Agent. ACS Sustain. Chem. Eng., 2024, 12, 450-458.
(4) Nirupama Sheet, Ryota Osuga, Nao Arai, Jan J. Wiesfeld,
Satoshi Suganuma, Takayuki Aoshima, Atsushi Fukuoka,
Emiel J.M. Hensen, Kiyotaka Nakajima, A Protection Strategy
for High-yield Synthesis of Dimethyl Furan2,5-dicarboxylate
from 5-Hydroxymethylfurfural Using Methanol as an
Acetalizing Agent. ChemCatChem, 2024, e202301259.
(5) Peipei Xiao, Kengo Nakamura, Yao Lu, Jun Huang, Lizhuo
Wang, Ryota Osuga, Maiko Nishibori, Yong Wang, Hermann
Gies, Toshiyuki Yokoi, One-Pot Synthesized Fe-AEI Zeolite
Catalysts Contribute to Direct Oxidation of Methane. ACS
Catal., 2023, 13, 16168-16178.
(6) Zijian Deng, Ryota Osuga, Masaki Matsubara, Kiyoshi
Kanie, Atsushi Muramatsu “Effect of contact mode of TiO2/γC3N4 heterojunction on photocatalytic performance for dye
degradation. Mater. Trans., 2023, 64, 2782-22791.
(7) Yoshiyasu Imanishi, Ryota Osuga, Atsushi Muramatsu,
Mizuho Yabushita, Construction of paired Al sites in high-silica
MFI-type zeolite framework via transcription-induced method.
J. Jpn. Petrol. Inst., 2023, 66, 246-253.
(8) Naonobu Katada, Nobuki Ozawa, Etsushi Tsuji, Keigo
Kanehara, Akiho Otsuka, Taiga Sakamoto, Kirari Umezawa,
Hitoshi Matsubara, Satoshi Suganuma, Momoji Kubo,
Methylation of benzene with methane induced by strong
adsorption of benzene on Co ion at α-position in zeolite withmoderate Al-Al distance. Microporous Mesoporous Mater.,
2024, 364, 112855.
(9) Peipei Xiao, Yong Wang, Kengo Nakamura, Yao Lu, TressDe Baerdemaeker, Andrei-Nicolae Pavulescu, Ulrich Muller,
Dirk De Vos, Xiangju Meng, Feng-Shou Xiao, Weiping Zhang,
Bernd Marler, Ute Kolb, Ryota Osuga, Maiko Nishibori,Hermann Gies, Toshiyuki Yokoi, Highly Effective Cu/AEI
Zeolite Catalysts Contribute to Continuous Conversion ofMethane to Methanol. ACS Catal., 2023, 13, 11057-11068.
(10) Satoshi Suganuma, Naonobu Katada, Selective Conversion
of Polycyclic Aromatic Hydrocarbons in Practical Heavy Oil.
J. Jpn. Petrol. Inst., 2023, 66, 95-100.
(11) Keisuke Tashiro, Masato Kobayashi, Kiyotaka Nakajima,
Tetsuya Taketsugu, Computational survey of humin formationfrom 5-(hydroxymethyl)furfural under basic conditions. RSC
Adv., 2023, 13, 16293-16299.
⥲ㄝ࣭ゎㄝ
(1) Daniele Padovan, Kiyotaka Nakajima, Ordered andDisordered Metal Oxide for Biomass Conversion.
Hyperordered Structures in Materials, pp. 433-451, Springer
Singapore, (2023).
(2) Ⳣ἟Ꮫྐ, ⢾࠿ࡽ⾰᭹ࢆࡘࡃࡿ㸪໬Ꮫ࡜ᕤᴗ㸪2023, 7610, 708-709.
(3) ኱㡲㈡㑈ኴ, ୰ᓥΎ㝯, 㔠ᒓ㓟໬≀⾲㠃ࡢ㉸⛛ᗎᵓ㐀ࢆ฼⏝ࡋࡓゐ፹཯ᛂ㸸෌⏕ྍ⬟Ⅳ⣲㈨※ࡢ฼ά⏝, ࢭᖺሗ࣭◊✲ᐊ⦅‫ە‬࣑ࣛࢵࢡࢫ, 2023, 58, 531-534.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟(1) ኱㡲㈡㑈ኴ:ࠕin-situ ㉥እศගἲࢆ㥑౑ࡋࡓᅛయゐ፹⾲㠃ࡢάᛶⅬᵓ㐀ゎᯒࠖ, ➨ 8 ᅇࣇࣟࣥࢸ࢕࢔ゐ፹タィࢭ࣑ࢼ࣮, ኱㜰኱Ꮫ, ኱㜰 (2023/12/15). [ᣍᚅㅮ₇](2) Kiyotaka Nakajima: “Chemocatalytic valorization of
biomass-derived furanics to monomers for biobased polymers”,
2023 International IRCCS-ILR-IRTG Symposium on “New
Horizons of Molecular Functions, Nagoya, Japan (2023/12/1).
[ᣍᚅㅮ₇](3) ୰ᓥΎ㝯:ࠕ࢔ࢭࢱ࣮ࣝಖㆤࢆά⏝ࡋࡓᅛయゐ፹࡟ࡼࡿࣂ࢖࣐࢜ࢫኚ᥮ࠖ
㸪▼ἜᏛ఍ ௧࿴ 5 ᖺᗘᮾ໭ᨭ㒊ㅮ₇఍,⛅⏣኱Ꮫ㸪⛅⏣ (2023/11/24). [ᣍᚅㅮ₇](4) Satoshi Suganuma: “Selective conversion of polycyclicaromatic hydrocarbons in petroleum”, ➨ 53 ᅇ▼Ἔ࣭▼Ἔ໬‫ە‬ᖺሗ࣭◊✲ᐊ⦅Ꮫウㄽ఍, ኱㜰⛉Ꮫᢏ⾡ࢭࣥࢱ࣮㸪኱㜰 (2023/10/26). [ᣍᚅㅮ₇](5) Kiyotaka Nakajima: “A protection strategy for the synthesisof biomass-derived and furan-based monomers for theapplication of biobased polymers”, The 4th International
Symposium on Catalytic Science and Technology in
Sustainable Energy and Environment, Beijing, China(2023/10/16). [ᣍᚅㅮ₇](6) Ⳣ἟Ꮫྐ㸸ࠕ࢔࣑ࣀ㓟ࡢỈ⣲໬࡟ࡼࡿྵ❅⣲໬Ꮫရࡢཎᩱྜᡂࠖ㸪➨ 449 ᅇゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘, ໭ᾏ㐨኱Ꮫ㸪໭ᾏ㐨 (2023/6/2). [ᣍᚅㅮ₇]
ཷ㈹(1) ୰ᓥΎ㝯㸸ࠕࢽ࢜ࣈ⣔」ྜ㓟໬≀࡟ࡼࡿ⢾ኚ᥮཯ᛂࠖ,➨ 5 ᅇ≀㉁࣭ࢹࣂ࢖ࢫඹྠ◊✲㈹, ≀㉁࣭ࢹࣂ࢖ࢫ㡿ᇦඹྠ◊✲ᣐⅬ (2023/5).

35≀㉁ኚ᥮◊✲㒊㛛/Catalytic Transformation
Research Division‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒ⚟ᒸ῟࣭ࠑຓᩍࠒAbhijit SHROTRI࣭≉௵ຓᩍ!
Danilele PADVAN㹙2023/09/01㹼㹛ࠑᮾிᕤ⛉኱Ꮫᩍᤵᐈ
ဨᩍᤵࠒཎ㈼஧࣭
ࠑᮾி኱Ꮫ෸ᩍᤵᐈဨ෸ᩍᤵࠒᑠᯘᗈ࿴࣭
ࠑ༤ኈ◊✲ဨࠒShaikr Nazmul Hasan Mohammad DOSTAGIR
㹙㹼2023/10/31㹛
࣭Yayati Naresh PALAI࣭ࠑᏛ⾡◊✲ဨࠒVuong
Bui Thi SINH 㹙2023/08/01㹼㹛/㟷ᰗⰋ࿴㹙2024/02/01㹼㹛࣭ࠑ◊✲ဨࠒᒣᮏὈ୕/㛗℈ᫀಇ࣭ࠑ஦ົ⿵ຓဨࠒᶓᒣ♸⨾Ꮚ࣭ࠑ⥲ྜ໬Ꮫ㝔኱Ꮫ㝔༤ኈㄢ⛬ࠒNirupama SHEETZijian
WANG‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
 2023ᖺ8᭶࡟Vuong Bui Thi SINH༤ኈࡀᏛ⾡◊✲ဨ࡜ࡋ࡚╔௵ࡋࡓ㸬ྠᖺ9᭶࡟Daniele PADOVAN༤ኈࡀ≉௵ຓᩍ࡜ ࡋ ࡚ ╔ ௵ ࡋ ࡓ 㸬 ྠ ᖺ 11 ᭶ ࡟ Shaikr Nazmul Hasan
Mohammad DOSTAGIR༤ኈ◊✲ဨࡀ≉௵ຓᩍ࡜ࡋ࡚ΎỈ◊࡟␗ືࡋࡓ㸬2024ᖺ2᭶࡟㟷ᰗⰋ࿴ẶࡀᏛ⾡◊✲ဨ࡜ࡋ࡚╔௵ࡋࡓ㸬ྠᖺ3᭶࡟Nirupama SHEETࡉࢇࡀ༤ኈྕࢆྲྀ
ᚓࡋࡓ㸬ྠᖺ3᭶࡟Yayati Naresh PALAI༤ኈ◊✲ဨࡀ㏥⫋ࡋࡓ㸬‫✲◊ڦ‬ㄢ㢟
1㸬ᅛయゐ፹࡟ࡼࡿࢭ࣮ࣝࣟࢫࡢゎ㔜ྜ ෌⏕ྍ⬟࡞ࣂ࢖࣐࢜ࢫࢆཎᩱ࡟ࡍࢀࡤ㸪໬Ꮫရྜᡂࡢప
Ⅳ⣲໬࡟㈨ࡍࡿ㸬ᮌ㉁ࣂ࢖࣐࢜ࢫࡢ୺ᡂศࡣࢭ࣮ࣝࣟࢫ࡛
࠶ࡾ㸪ゎ㔜ྜࡍࢀࡤ໬Ꮫရࡢཎᩱ࡟࡞ࡿࡀ㸪ࢭ࣮ࣝࣟࢫࡣ
ᙉᅛ࡞⤖ᬗᵓ㐀ࢆࡶࡕゎ㔜ྜࡀᅔ㞴࡛࠶ࡿ㸬ࡉࡽ࡟㸪⏕ᡂࡍࡿࢢࣝࢥ࣮ࢫࡀ๪཯ᛂࢆ㉳ࡇࡋࡸࡍ࠸࡜࠸࠺ၥ㢟ࡀ࠶ࡿ㸬ᡃࠎࡣ㸪ࢭ࣮ࣝࣟࢫゎ㔜ྜ࡟ᅛయゐ፹ࢆ⏝࠸ࡿࡇ࡜ࢆ
╔᝿ࡋ㸪ᢸᣢ㔠ᒓゐ፹ࢆ⏝࠸࡚ຍᅽỈ⣲ୗ࡛཯ᛂࢆ⾜࠺࡜㸪ࢭ࣮ࣝࣟࢫࡢຍỈศゎỈ⣲໬ࡀ㐍⾜ࡋࢯࣝࣅࢺ࣮ࣝࡀ
ᚓࡽࢀࡿࡇ࡜ࢆぢ࠸ࡔࡋࡓ(Fig. 1)㸬ࡇࢀࡣᅛయゐ፹࡟ࡼࡿึࡢࢭ࣮ࣝࣟࢫゎ㔜ྜ࡛࠶ࡾ㸪ከࡃࡢ㢮ఝ◊✲ࡀ⾜ࢃࢀࡿዎᶵ࡜࡞ࡗࡓ㸬 ḟ࡟ࢭ࣮ࣝࣟࢫຍỈศゎ࡟ྲྀࡾ⤌ࡳ㸪࢝ࣝ࣎࢟ࢩᇶ࡞࡝
ࡢᙅ㓟ⅬࢆࡶࡘⅣ⣲ゐ፹ࢆ⏝࠸㸪ゐ፹࡜ࢭ࣮ࣝࣟࢫࢆΰྜ
࣑ࣝฎ⌮ࡍࡿ᪂ࡓ࡞᪉ἲㄽࢆᥦ♧ࡋࡓ㸬ࡇࢀ࡟ࡼࡾ㸪ᅛయゐ፹㸫ᅛయᇶ㉁㛫ࡢ᥋ゐࡀቑຍࡋ㸪ࢭ࣮ࣝࣟࢫࢆⅣ⣲⾲㠃ୖ࡟྾╔ࡉࡏᙅ㓟Ⅼ࡟ࡼࡾș-1,4-ࢢࣜࢥࢩࢻ⤖ྜࢆຍỈศゎࡉࡏࡿࡇ࡜ࡀྍ⬟࡟࡞ࡗࡓ(Fig. 2)㸬ᮏᡭἲ࡟ࡼࡾࢢࣝ
ࢥ࣮ࢫࡢ㧗㏿ྜᡂࢆ㐩ᡂࡍࡿ࡜࡜ࡶ࡟㸪Ỉ⁐ᛶࢭࣟ࢜ࣜࢦ
⢾㸦3㹼6㔞య㸧ࢆⰋዲ࡞཰⋡࡛ྜᡂࡍࡿࡇ࡜࡟ࡶᡂຌࡋࡓ㸬ࡇࢀࡽࡢ཯ᛂࡣ㸪㧗⪏ஂᛶ࡜࠸࠺ᅛయゐ፹ࡢ≉㛗ࢆά࠿ࡋ㸪཯ᛂ᮲௳ࡢ㐺⏝⠊ᅖࢆᗈࡃࡍࡿࡇ࡜࡛ึࡵ࡚ᐇ⌧ࡋࡓ㸬Ỉ⁐ᛶࢭࣟ࢜ࣜࢦ⢾ࡣ௜ຍ౯್ࡀ㧗ࡃ㸪᳜≀࡟ᑐࡋ࡚ࣂ࢖࢜ࢫࢸ࢕࣑ࣗࣛࣥࢺ࡜ࡋ࡚ᶵ⬟ࡍࡿ㸬

Fig. 2 Adsorption of cellulose through CH-S bonding andhydrolysis by weak acid site on carbon
2023ᖺᗘࡢࢺࣆࢵࢡ㸸ࣜࣥ㓟࡟ࡼࡿࢭ࣮ࣝࣟࢫ⁐ゎ࡜Ⅳ⣲ゐ፹ࡢ྾╔ࢆ฼⏝ࡍࡿࢭ࣮ࣝࣟࢫ⢾໬ἲࢆ᱌ฟࡋ㸪ࣛ࢖ࣇࢧ࢖ࢡࣝ࢔ࢭࢫ࣓ࣥࢺ࡟࠾࠸࡚ࢢ࣮ࣜࣥࣁ࢘ࢫ࢞ࢫࡢ᤼
ฟࡀప࠸ࡇ࡜ࢆ♧ࡋࡓࠓㄽᩥ4ࠔ㸬
2㸬ᅛయゐ፹࡟ࡼࡿ࢟ࢳࣥࡢゎ㔜ྜ ᡃࠎࡣ㸪ᾏὒࣂ࢖࣐࢜ࢫࡢ୍ࡘ࡛❅⣲ࢆྵࡴ࢟ࢳࣥࡢゎ㔜ྜ࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿ㸬࢟ࢳࣥࡣN-࢔ࢭࢳࣝࢢࣝࢥࢧ࣑ࣥ
㸦NAG㸧ࡀș-1,4-ࢢࣜࢥࢩࢻ⤖ྜ࡟ࡼࡗ࡚㐃⤖ࡋࡓ㧗ศᏊ࡛࠶ࡾ㸪ࢭ࣮ࣝࣟࢫ࡜ྠᵝࡢᵓ㐀ࢆࡶࡘ(Fig. 3)㸬࢟ࢳࣥࡣ࢚ࣅࡸ࢝ࢽࡢ⏥⨶࡟ྵࡲࢀ࡚࠾ࡾ㸪ࣂ࢖࣐࢜ࢫࡢ୰࡛ࢭࣝ
࣮ࣟࢫ࡟ḟࡄ㈨※㔞ࢆࡶࡘࡀ㸪ศゎࡀᅔ㞴࡛࠶ࡿࡓࡵ࡯࡜
ࢇ࡝฼⏝ࡉࢀ࡚࠸࡞࠸㸬ࡲࡓ㸪ゎ㔜ྜࡢ㝿࡟ࢢࣜࢥࢩࢻ⤖ྜ࡟ຍ࠼࢔࣑ࢻ⤖ྜࡶຍỈศゎࡉࢀࡿྍ⬟ᛶࡀ࠶ࡿࡀ㸪⬺࢔ࢭࢳࣝ໬≀ࡣNAGࡼࡾࡶ౯್ࡀప࠸㸬

Fig. 3 Structures of chitin and cellulose, and hydrolysis ofchitin to NAG.
 ᡃࠎࡣ㸪ࢭ࣮ࣝࣟࢫゎ㔜ྜἲࢆⓎᒎࡉࡏࡓ࣓࢝ࣀ࢟ࣕࢱ
ࣜࢩࢫ࡟ࡼࡾ࢟ࢳࣥࢆຠ⋡ࡼࡃゎ㔜ྜ࡛ࡁࡿࡇ࡜ࢆ♧ࡋࡓ㸬ࡍ࡞ࢃࡕ㸪࢟ࢳࣥ⢊ᮎ࡜◲㓟࠶ࡿ࠸ࡣⅣ⣲ゐ፹ࢆΰྜ࣑ࣝฎ⌮ࡍࡿ࡜㸪㓟Ⅼ࡟ࡼࡾࢢࣜࢥࢩࢻ⤖ྜࡀษ᩿ࡉࢀࡿ
ࡀ࢔࣑ࢻᇶࡣಖᣢࡉࢀ㸪㧗㑅ᢥ⋡࡛࢟ࢳࣥ࢜ࣜࢦ⢾ࢆྜᡂ࡛ࡁࡿ(Fig. 4)㸬
Fig. 1 Hydrolytic hydrogenation of cellulose to sorbitol.

3636ᖺሗ࣭◊✲ᐊ⦅‫ە‬ⓑ㔠㞄᥋ࢧ࢖ࢺࡀάᛶⅬ࡜࡞ࡿࡇ࡜㸪ࢩࣜ࢝ୖࡢࢩࣟ࢟ࢧ
ࣥ࡞࡝ࡢ␯ỈᛶሙࡀỈࢆຠᯝⓗ࡟㝖ཤࡋ࡚ᐃᖖάᛶࢆಖ
ࡘࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓ㸬

Fig. 4 Hydrolysis of chitin with acid under mechano-catalysis
conditions.
 ࡲࡓ㸪཯ᛂᶵᵓࢆヲ⣽࡟᳨ウࡋ㸪࣮࣑࣎ࣝࣝࡢ࣐ࢡࣟ࡞
ຊࡀࢢࣜࢥࢩࢻ⤖ྜࢆ㑅ᢥⓗ࡟άᛶ໬ࡋ㸪ࣉࣟࢺࣥ໬࡜ᘬ
ࡁ⥆ࡃࢢࣜࢥࢩࢻ⤖ྜ㛤⿣ࡢ୧᪉ࢆಁ㐍ࡍࡿࡇ࡜ࢆ᫂ࡽ
࠿࡟ࡋࡓ㸬࢜ࣜࢦ⢾࠿ࡽࡣຍỈศゎ࡟ࡼࡾNAGࡀᐜ᫆࡟ᚓࡽࢀࡿ㸬࢟ࢳࣥ࢜ࣜࢦ⢾ࡣࢭࣟ࢜ࣜࢦ⢾࡜ྠᵝ࡟㧗࠸௜ຍ౯್ࢆࡶࡘ㸬 ࡉࡽ࡟㸪NAGࡢኚ᥮཯ᛂࢆ᳨ウࡋ㸪NAGࢆ㑏ඖࡋ࡚⢾࢔ࣝࢥ࣮ࣝ㸦ADS㸧ࢆᚓࡿ࡜࡜࡜ࡶ࡟㸪ADSࡢ⬺Ỉ࡟ࡼࡾ஧⎔⦰ྜ࢔࣑ࢻ࢔ࣝࢥ࣮ࣝ㸦ADI㸧ࢆ᪂つ࡟ྜᡂࡋࡓ(Fig. 5)㸬
ࡇࡢࡼ࠺࡟࢟ࢳࣥࢆゎ㔜ྜࡋ࡚NAGࢆᚓࡓᚋ࡟㸪NAG࠿
ࡽྛ✀ࡢ᭷ᶵ❅⣲໬ྜ≀ࢆྜᡂࡍࡿ᪂ࡓ࡞཯ᛂࣉࣟࢭࢫ
ࢆ♧ࡋࡓ㸬࢟ࢳࣥࢆฟⓎཎᩱ࡜ࡍࡿࡇ࡜࡛Ⅳ⣲࡟ຍ࠼࡚❅⣲ࡶ෌⏕ྍ⬟࡜࡞ࡿ㸬

Fig. 5 Synthesis of organonitrogen compounds from NAG.
2023ᖺᖺᗘࡢࢺࣆࢵࢡ㸸ᙅ㓟ⅬࢆࡶࡘⅣ⣲ゐ፹ࡣ㸪࣓࢝ࣀࢣ࣑࢝ࣝ᮲௳ୗ࡛࢟ࢳࣥࢆ࢜ࣜࢦ⢾࡟㑅ᢥⓗ࡟ຍỈศゎࡍࡿ㸬ᮏࢩࢫࢸ࣒ࡣ㸪ᑠࡉ࡞࢜ࣜࢦ࣐࣮ࡼࡾࡶ኱ࡁ࡞ศᏊࢆ
ඃඛⓗ࡟ษ᩿ࡍࡿࡓࡵ㸪࢟ࢳࣥ࢜ࣜࢦ⢾ࡢ㑅ᢥᛶ࡜཰⋡ࡀ᭱኱࡟࡞ࡿ㸬࢟ࢳࣥ࢜ࣜࢦ⢾ࡣ㸪ࣂ࢖࢜ࢫࢸ࢕࣑ࣗࣛࣥࢺ
࡜ࡋ࡚㎰ᴗศ㔝࡛ࡢᛂ⏝ࡀᮇᚅࡉࢀࡿࠓㄽᩥ1ࠔ㸦Fig. 6㸧㸬

Fig. 6 Selective synthesis of oligosaccharides
mechanochemical hydrolysis of chitin.

 ࡉࡽ࡟㸪ᮏゐ፹ࢆ㟷ᯝ≀ࡢ㩭ᗘಖᣢ࡟ᛂ⏝ࡋ㸪཰✭ᚋࡢ㔝࣭⳯ᯝ≀࠿ࡽᨺฟࡉࢀࡿᚤ㔞ࡢ࢚ࢳࣞࣥࢆ㓟໬㝖ཤࡋ࡚㸪⇍ᡂࢆᢚไ࡛ࡁࡿࡇ࡜ࢆ♧ࡋࡓ㸬ᮏゐ፹ࡣ㸪ࠕࣉࣛࢳࢼゐ፹ࠖ࡜࿨ྡࡉࢀ㸪෭ⶶᗜࡢ㔝⳯ᐊࡸ㔝⳯㈓ⶶᗜ࡛ᐇ㝿࡟౑ࢃࢀ࡚࠾ࡾ㸪㔝⳯ࡢṌ␃ࡲࡾྥୖ࣭ࣇ࣮ࢻࣟࢫ๐ῶ࡟኱ࡁ
ࡃ㈉⊩ࡋ࡚࠸ࡿ㸬2020 ᖺ࡟ࣇ࣮ࢻࣟࢫ๐ῶࢥࣥࢯ࣮ࢩ࢔
࣒ࢆ❧ࡕୖࡆ㸪ᮏゐ፹ᢏ⾡ࡢᬑཬࢆ⾜ࡗ࡚࠸ࡿ㸬኱ᆺ㔝⳯㈓ⶶᗜ࡟タ⨨ࡋࡓゐ፹ࡣ㸪3 ᖺ௨ୖ࡟ࢃࡓࡾ㩭ᗘಖᣢຠᯝ
࡜Ṍ␃ࡲࡾྥୖࢆ♧ࡋ࡚࠸ࡿ㸬ࡇࡢࡇ࡜ࡣࣉࣛࢳࢼゐ፹ࡢ㧗࠸⪏ஂᛶ࡟㉳ᅉࡍࡿ㸬
2023ᖺᗘࡢࢺࣆࢵࢡ㸸ࣇ࣮ࢻࣟࢫ๐ῶࢥࣥࢯ࣮ࢩ࢔࣒ࡣ௧
࿴5ᖺᗘࡲ࡛࡟20ἲேࡀ఍ဨ࡜ࡋ࡚ຍධࡋᢏ⾡ᑟධࢆ㐍ࡵࡓ㸬ࡲࡓ㸪ၨⓎάືࡢ୍⎔࡜ࡋ࡚ゐ፹ᢏ⾡ࡢᒎ㛤࡟ࡘ࠸࡚㧗ᰯ⏕࢔࢖ࢹ࢔ࢥࣥࢸࢫࢺࢆ⾜࠸㸪㧗ᑓࢆྵࡴ8ᰯ12ࢢ࣮ࣝࣉࡀཧຍࡋ࢔࢖ࢹ࢕࢔ࢆ➇ࡗࡓ㸬
4㸬CO2㑅ᢥ㑏ඖゐ፹ࡢ㛤Ⓨ Ỉ⣲໬ࢆ⤒⏤ࡋࡓCO2ࡢ໬Ꮫရཎᩱ࡜ࡋ࡚ࡢ฼ά⏝ࡀᮇᚅࡉࢀ࡚࠾ࡾ㸪ࡑࡢ᭷ᮃ࡞୰㛫య࡜ࡋ࡚࣓ࢱࣀ࣮ࣝ࡜
COࡀᣲࡆࡽࢀࡿ㸬ࡋ࠿ࡋ㸪ࡇࢀࡲ࡛࡟ሗ࿌ࡉࢀ࡚࠸ࡿゐ፹⣔࡟ࡣ㸪CO2㧗㌿໬⋡᫬࡟࠾ࡅࡿ⏕ᡂ≀㑅ᢥᛶࡀప࠸࡜
࠸ࡗࡓၥ㢟ࡀ࠶ࡿ㸬ࡇࢀࢆゎỴࡍࡿࡓࡵ࡟㸪ᡃࠎࡣ㸪ᢸᣢ㔠ᒓࡲࡓࡣ㔠ᒓࢻ࣮ࣉࡋࡓ㓟໬≀ゐ፹ࡢ⏺㠃ࢧ࢖ࢺࡀ᭷ࡍࡿゐ፹άᛶ࣭㑅ᢥᛶ࡟╔┠ࡋ࡚◊✲ࢆ⾜ࡗ࡚࠸ࡿ㸬≉࡟㸪㓟⣲✵Ꮝ(VO∙∙)࡜ࡑࢀ࡟㞄᥋ࡍࡿ㔠ᒓཎᏊ(MM)ࡢస⏝࡟ࡼࡿᅛ᭷ࡢCO2྾╔࣭άᛶ໬⬟࡟⯆࿡ࢆᣢࡗ࡚࠸ࡿ㸬ࡇࡢࡼ࠺࡞ほⅬ࠿ࡽ㸪⌧ᅾ㸪㓟⣲✵Ꮝࢆ᭷ࡍࡿ✀ࠎࡢ㓟໬≀ゐ፹ࢆタィࡋ㸪CO2Ỉ⣲໬࡟ࡼࡿ࣓ࢱࣀ࣮ࣝ࡜COࡢ㑅ᢥⓗ࡞ྜᡂࢆ┠ᣦࡋ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸Co-In-ZrO2ゐ፹ୖ࡛ࡢCO2Ỉ⣲໬࡟ࡼࡿ࣓ࢱࣀ࣮ࣝྜᡂ࡟࠾࠸࡚㸪H2ゎ㞳࡜࣓࣮࣍ࣝࢺ୰㛫యࡢ྾╔ࡢࢧ࢖ࢺࢆศ㞳ࡍࡿࡇ࡜࡟ࡼࡾ㸪H2ゎ㞳࡟ᑐࡍࡿ୰
㛫యࡢ⿕ẘຠᯝࢆᡴࡕᾘࡍࡇ࡜ࡀ࡛ࡁࡿࡇ࡜ࢆ♧ࡋࡓࠓㄽ
ᩥ10ࠔ(Fig. 8㸧㸬by3㸬ࢩࣜ࢝ゐ፹ᢸᣢⓑ㔠ゐ፹࡟ࡼࡿప ࢚ࢳࣞࣥ㓟໬࡜㟷ᯝ≀㩭ᗘಖᣢ࡬ࡢᛂ⏝ ᡃࠎࡣⓑ㔠ࢼࣀ⢏Ꮚ࡜ከᏍ㉁ࢩࣜ࢝ࢆ⤌ࡳྜࢃࡏࡓゐ፹࡟ࡼࡿ㓟໬཯ᛂࢆ᳨ウࡋ㸪࢚ࢳࣞࣥࡀΥࡢప ࡛ࡶ஧㓟໬Ⅳ⣲࡜Ỉ࡟㓟໬ࡉࢀࡿࡇ࡜ࢆぢ࠸ࡔࡋࡓ(Fig. 7)㸬ࡇࡢప 㓟໬ࡣ㸪ⓑ㔠࡜ࢩࣜ࢝ࡢ⤌ࡳྜࢃࡏࡢ࡜ࡁ࡟㉳ࡇࡾ㸪‫ە‬ᖺሗ࣭◊✲ᐊ⦅
Fig. 7 Low-temperature oxidation of ethylene by silicasupported Pt catalyst.

Fig. 8 CO2 hydrogenation to methanol over Co-In-ZrO2
catalyst.

‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧ᮾி኱Ꮫᑠᯘᗈ࿴෸ᩍᤵࠕࣂ࢖࣐࢜ࢫࡢゐ፹ኚ᥮࡟㛵ࡍࡿ◊✲ࠖᮾிᕤ⛉኱Ꮫཎ㈼஧ᩍᤵࠕᮍ฼⏝ࣂ࢖࣐࢜ࢫ㈨※37ࡢ࢔ࢵࣉࢢ࣮ࣞࢻ฼⏝࡟㛵ࡍࡿゐ፹◊✲ࠖᮾி⌮⛉኱Ꮫబᕝᣅ▮ຓᩍࠕ࢟ࢳࣥࢆཎᩱ࡜ࡋࡓ❅⣲ྵ᭷࣏࣐࣮ࣜ๓㥑య ࡢ ຠ ⋡ ⓗ ྜ ᡂ ἲ ࡢ 㛤 Ⓨ ࠖ  ࣔ ࢼ ࢵ ࢩ ࣗ ኱ Ꮫ Akshat
TANKSALE෸ᩍᤵࠕCatalyst development for conversion of
CO2 to acetic acidࠖCSIR-࢖ࣥࢻᕤ⛉኱Ꮫ, John MONDAL୺௵◊✲ဨࠕDesign of Advanced metalated porous-organicpolymer for photocatalytic CO2 reductionࠖ/ࣂ࣮ࢪࢽ࢔ᕤ⛉኱
ᏛAyman KARIM෸ᩍᤵࠕStabilizing Rh Single Atoms using
Small Metal Oxide Nanoparticles for CO/CO2 Hydrogenationࠖ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦඲࡚ᑂᰝࡘࡁ㸧(1) Kobayashi, H.; Suzuki, Y.; Sagawa, T.; Saito, M.; Fukuoka,
A.
Selective
Synthesisof
Oligosaccharides
byMechanochemical Hydrolysis of Chitin over a Carbon-Based
Catalyst. Angew. Chem. Int. Ed. 2023, 62, e202214229.
(2) Dostagir, N. H. M.; Fukuoka, A.; Shrotri, A. Redox Behavior
of In-O-Ti Interface for Selective Hydrogenation of CO2 to CO
in Doped In-TiO2 Catalyst. ChemCatChem 2023, e202201348.
(3) Harako, A.; Shimoda, S.; Suzuki, K.; Fukuoka, A.; Takada,T. Effects of the electron-beam-induced modification of g-C3N4
on its performance in photocatalytic organic dye
decomposition. Chem. Phys. Lett. 2023, 813, 140320.
(4) Shrotri, A.; Eguchi, K.; Mahardiani, L.; Kobayashi, H.;
Yamashita, M.; Yagita, H.; Fukuoka, A. Solvent-Assisted
Adsorption of Cellulose on a Carbon Catalyst as a Pretreatment
Method for Hydrolysis to Glucose. Chemistry 2023, 5, 381392.
(5) Ono, R.; Shimoda, S.; Fukuoka, A.; Takada, T. Fluoride
removal from water using Zr-modified meso- and macroporous
carbons: Effect of pore structure and adsorption conditions.
Chem. Eng. J. Adv. 2023, 15, 100512.
(6) Li, L.; Shrotri, A.; Kato, K.; Fukuoka, A.; Kobayashi, H.
Mordenite-stabilised rhenium catalyst for partial oxidation of
methane to syngas. Catal. Sci. Technol. 2023, 13, 5190-5196.
(7) Pring, S.; Kato, H.; Imano, S.; Camagna, M., Tanaka, A.;
Kimoto, H.; Chen, P.; Shrotri, A.; Kobayashi, H.; Fukuoka, A.;
Saito, M.; Suzuki, T.; Terauchi, R.; Sato, I.; Chiba, S.;
Takemoto, D. Induction of plant disease resistance by mixed
oligosaccharide elicitors prepared from plant cell wall andcrustacean shells. Physiol. Plant. 2023, 175, e14052.
(8) Sheet, N.; Osuga, R.; Arai, N.; Wiesfeld, J. J.; Suganuma, S.;
Aoshima, T.; Fukuoka, A.; Hensen, E. J. M., Nakajima, K. A
Protection Strategy for High-yield Synthesis of Dimethyl
Furan-2,5-dicarboxylate from 5-Hydroxymethylfurfural Using
Methanol as an Acetalizing Agent. ChemCatChem 2024,
e202301259.
(9) Palai, Y. N.; Fukuoka, A.; Shrotri, A. Unlocking the Potentialof 5-Hydroxy-2(5H)-furanone as a Platform for Bio-Based
Four Carbon Chemicals. ACS Catal. 2024, 14, 2545-2551.
(10) Dostagir, N. H. MD.; Tomuschat, C. R.; Oshiro, K.; Gao,M.; Hasegawa, J.; Fukuoka, A.; Shrotri, A. Mitigating the
Poisoning Effect of Formate during CO2 Hydrogenation to
Methanol over Co-Containing Dual-Atom Oxide Catalysts,
JACS Au 2024, 4, 1048-1058.
⥲ㄝ࣭ゎㄝ
(1) Fukuoka, A.; Kobayashi, H. Valorization of Cellulose andChitin into Valuable Chemicals by Heterogeneous Catalysis. J.
Jpn. Petrol. Inst. 2023, 66, 48-56.
(2) Kobayashi, H.; Sagawa, T.; Fukuoka, A. Catalytic conversionof chitin as a nitrogen-containing biomass. Chem. Commun.
2023, 59, 6301-6313.
(3) Fukuoka, A. From Basic Research on Supported-Metal
Catalysts to their Practical Applications for Reduction of Food
Waste. Bull. Chem. Soc. Jpn. 2023, 96, 1071-1076.
(4)Palai, Y. N.; Fukuoka, A.; Shrotri, A. Reaction Pathways for

3838

Synthesis of Four Carbon Chemicals from Sugars and Sugar
Derived Platform Chemicals. ChemCatChem 2023,15,b202300766.
(5) ⚟ᒸ῟ ࣇ࣮ࢻࣟࢫࢆῶࡽࡍᅛయゐ፹. ໬Ꮫ, 2024, 79,
14-16.
ᣍᚅᇶㄪ౫㢗ㅮ₇(1) ⚟ᒸ῟:ࠕᅛయゐ፹࡟ࡼࡿࢭ࣮ࣝࣟࢫ࡜࢟ࢳࣥࡢゎ㔜ྜࠖ, 2022 ᖺᗘ኱㜰බ❧኱Ꮫேᕤගྜᡂ◊✲ࢭࣥࢱ࣮άືሗ࿌఍, ࢜ࣥࣛ࢖ࣥ㛤ദ (2023/3/13). [Plenary](2) ⚟ᒸ῟:ࠕࢭ࣮ࣝࣟࢫ⣔ࣂ࢖࣐࢜ࢫࡢゎ㔜ྜ࡜㟷ᯝ≀㩭ᗘಖᣢࡢࡓࡵࡢᅛయゐ፹ࡢ㛤Ⓨࠖ, ᪥ᮏ໬Ꮫ఍➨ 103 ᅇ᫓Ꮨᖺ఍, 㔝⏣ (2023/3/23). [Award Lecture](3) ⚟ᒸ῟:ࠕࢭ࣮ࣝࣟࢫ⣔ࣂ࢖࣐࢜ࢫࡢゎ㔜ྜ࡜㟷ᯝ≀㩭ᗘಖᣢࡢࡓࡵࡢᅛయゐ፹ࡢ㛤Ⓨࠖ, ៞ᛂ኱Ꮫ⌮ᕤᏛ㒊, ᶓ὾ (2023/4/15). [Invited](4) ⚟ᒸ῟:ࠕᅛయゐ፹࡟ࡼࡿࢭ࣮ࣝࣟࢫ࡜࢟ࢳࣥࡢゎ㔜ྜࠖ㸪ࢼࣀᏛ఍➨ 21 ᅇ኱఍, ภ㤋 (2023/5/12). [Plenary](5) ⚟ᒸ῟:ࠕࣇ࣮ࢻࣟࢫࢆῶࡽࡍゐ፹ࠖ㸪໭ᾏ㐨኱Ꮫ◊✲ᡤࢭࣥࢱ࣮➼୍⯡බ㛤, ᮐᖠ (2023/6/3). [Invited](6) ⚟ᒸ῟:ࠕゐ፹ࡢᐇ⏝໬㸸ᴫㄽ࡜ࢣ࣮ࢫࢫࢱࢹ࢕ࠖ, 2023
ᖺ໭ࡢᅜゐ፹ሿ,࢜ࣥࣛ࢖ࣥ㛤ദ (2023/6/10). [Invited](7) ⚟ᒸ῟:ࠕᅛయゐ፹࡟ࡼࡿࢭ࣮ࣝࣟࢫ࡜࢟ࢳࣥࡢኚ᥮ࠖ,ゐ፹Ꮫ఍➨ 1 ᅇ᭷ᶵ㈨※ᚠ⎔ゐ፹ࢭ࣑ࢼ࣮, ᮾி(2023/7/29). [Invited](8) Fukuoka, A.: “Depolymerization of chitin to chitinoligosaccharides over carbon catalysts”, ACS Fall 2023, San
Francisco (2023/8/15). [Invited](9) ⚟ᒸ῟࣭ཎ㈼஧࣭ྜྷ㔝ṇ๎:ࠕゐ፹ࡀᐇ⌧ࡍࡿ࢔ࢵࣉࢧ
࢖ࢡࣝ࡜ࣇ࣮ࢻࣟࢫ๐ῶࠖ, ➨ 5 ᅇᚠ⎔๰㐀Ꮫࢭ࣑ࢼ࣮,࢜ࣥࣛ࢖ࣥ㛤ദ (2023/8/25). [Invited](10) ⚟ᒸ῟:ࠕࣂ࢖࣐࢜ࢫゎ㔜ྜ࡜㟷ᯝ≀㩭ᗘಖᣢࡢࡓࡵࡢᅛయゐ፹ࡢ㛤Ⓨࠖ, ᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊 2023 ᖺኟᏘ◊✲Ⓨ⾲఍㸦໭ᾏ㐨ᨭ㒊๰❧ 75 ࿘ᖺグᛕ኱఍㸧, ᪫ᕝ(2023/9/3). [Invited](11) Shrotri, A.: “Hydrogenation of carbon dioxide over mixed
metal oxide catalysts containing oxygen vacant sites”, ➨ 132ᅇゐ፹ウㄽ఍, ᮐᖠ (2023/9/14). [Award Lecture](12) ⚟ᒸ῟:ࠕࣉࣛࢳࢼゐ፹࡟ࡼࡿ㟷ᯝ≀ࡢ㩭ᗘಖᣢࠖ,ࣇ ࣮ ࢻ ࣟ ࢫ ๐ ῶ ࣇ ࢛ ࣮ ࣛ ࣒ TOMAKOMAI, Ɫ ᑠ ∾(2023/9/19). [Invited](13) ⚟ᒸ῟:ࠕゐ፹࡟ࡼࡿࣂ࢖࣐࢜ࢫኚ᥮࡜㟷ᯝ≀㩭ᗘಖᣢࠖ㸪➨ 50 ᅇゐ፹Ꮫ఍࢜ࣝ࢞ࣀ࣓ࢱࣜࢵࢡࢭ࣑ࢼ࣮, ᑠ㔠஭ (2023/9/25). [Invited](14) ⚟ᒸ῟:ࠕᅛయゐ፹࡟ࡼࡿࢭ࣮ࣝࣟࢫ࣭࢟ࢳࣥࡢゎ㔜ྜ࡜㟷ᯝ≀㩭ᗘಖᣢࠖ, ◊✲఍ࠕ࣮࢝࣎ࣥࢽ࣮ࣗࢺࣛࣝᐇ
⌧ࡢࡓࡵࡢゐ፹ᢏ⾡ࠖ, ኱ᓮ (2023/9/28). [Invited](15) Fukuoka, A.: “Valorization of Cellulose and Chitin by
Heterogeneous Catalysts”, 2nd International Conference on
Plantation Technology (ICPTech2023), Malaysia (2023/10/10).
[Keynote](16) Fukuoka, A.: “Depolymerization of cellulose and chitin byheterogeneous catalysts”, TU/e-ICAT Joint International
Symposium on Catalysis: Advanced Technologies for
Sustainable Society, Eindhoven (2023/11/1). [Plenary](17) Fukuoka, A.: “Heterogeneous Catalysis for a Sustainable
Future”, Zasshikai seminar 1907th, Department of Chemistry,
The University of Tokyo, Tokyo (2023/11/24). [Invited](18) ⚟ᒸ῟:ࠕࢮ࢜ࣛ࢖ࢺ࣭࣓ࢯከᏍయᢸᣢ㔠ᒓࡢゐ፹≉ᛶ࡜ࣇ࣮ࢻࣟࢫ๐ῶ࡬ࡢᛂ⏝ࠖ, ➨ 39 ᅇࢮ࢜ࣛ࢖ࢺ◊✲Ⓨ⾲఍, ᮾி (2023/11/30). [Invited](19) Fukuoka, A.; Kobayashi, H.: “Selective Synthesis of
Oligosaccharides by Depolymerization of Chitin over Carbonᖺሗ࣭◊✲ᐊ⦅‫ە‬

Catalysts”, MRM2023/IUMRS-ICA2023, Kyoto (2023/12/14).
[Keynote]‫ە‬ᖺሗ࣭◊✲ᐊ⦅ཷ㈹(1㸧Abhijit SHROTRI㸸National Institute of Technology, Raipur,
India (2023/12/01).ࠓ2023 Young Achiever Alumnus Awardࠔ

39ゐ፹ᮦᩱ◊✲㒊㛛/ Catalyst Material
Research Division‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒΎỈ◊୍࣭ࠑ෸ᩍᤵࠒྂᕝ᳃ஓ㹙㹼2023/04/30㹛/㫽ᒇᑿ㝯㹙2023/11/01㹼㹛࣭ࠑຓᩍࠒ㫽ᒇᑿ㝯㹙㹼2023/10/31㹛࣭ࠑ኱㜰኱Ꮫᩍᤵ/ᐈဨᩍᤵࠒྂᕝ᳃ஓ㹙2023/05/01㹼㹛࣭ࠑ≉௵ ᩍ ᤵ ࠒ Evgeny Alexandrovich PIDKO 㹙 2023/06/16 㹼
2023/08/17㹛࣭ࠑ≉௵ຓᩍࠒNazmul Hasan Mohammad Dostagir
SHAIKH㹙2023/11/01㹼㹛/ZHANG Ningqiang㹙2023/11/01㹼㹛࣭ࠑ༤ኈ◊✲ဨࠒAbdellah AIT EL FAKIR㹙㹼2023/08/31㹛
/Fangyi YAO㹙㹼2023/05/15㹛࣭ࠑᏛ⾡◊✲ဨࠒబ⸨Ⰻ᫛㹙㹼
2023/04/30 㹛࣭ࠑ JSPS ≉ ู ◊ ✲ ဨ ࠒ Yuan JING 㹙 㹼
2023/09/30 㹛࣭ࠑ JSPS እ ᅜ ே ≉ ู ◊ ✲ ဨ ࠒ Ningqiang
ZHANG 㹙㹼2023/10/31㹛/Lingcong LI /Jiahuan TONG 㹙㹼
2024/01/13㹛/ Abdellah AIT EL FAKIR 㹙2023/09/01㹼㹛࣭ࠑእᅜே◊✲ဨࠒJiacheng BAO /Alisa PHUEKPHONG 㹙㹼
2023/09/30 㹛 /Tan LI 㹙 㹼 2023/06/30 㹛 /Xie Yuxuan
㹙 2023/11/26 㹼 㹛 /Bo WU 㹙 2023/12/01 㹼 㹛 /Hongli PAN
㹙 2023/11/01 㹼 㹛࣭ࠑ ◊ ✲ ⏕ ࠒ ୰ ᮏ ⸅ /Weiyang ZHANG
㹙2023/10/01㹼㹛/Xiupeng ZHANG㹙2023/10/01㹼㹛/Jialei
ZHANG㹙2023/10/01㹼㹛࣭ࠑ⥲ྜ໬Ꮫ㝔/኱Ꮫ㝔༤ኈㄢ⛬ࠒ
Ke LIU 㹙㹼2023/12/25㹛/Mengwen HUANG/Jiamin MA㹙㹼
2023/09/30㹛/୰㇂ຬᕼ㹙㹼2023/12/25㹛/ୗ⏣ග♸/ᐑᓮ┾ኴ /Pengfei DU 㹙 2023/10/01 㹼 㹛 /Duotian CHEN/Chenxi
HE/Yucheng QIAN/Shirun ZHAOࠑ⥲ྜ໬Ꮫ㝔/኱Ꮫ㝔ಟኈㄢ⛬ ࠒ Ọ ஭ ೺ / 㛵 ᰿ ୍ ⩧ / ᐩ ᐊ ὒ ௓ / ྜྷ ཎ 㞞 ㈗ /Chenyang
ZHANG /Li WAN/ᐑᬒ⌶඘࣭ࠑᕤᏛ㒊/Ꮫ㒊Ꮫ⏕ࠒ⏣ᓥ኱ᆅ/Ᏻ⸨᭷㔛Ꮚ㹙2023/10/01㹼㹛࣭ࠑᢏ⾡⿵బဨࠒṊ⏣㈗Ꮚ࣭
ࠑᢏ⾡ᑓ㛛⫋ဨࠒୗ⏣࿘ᖹ࣭ࠑ◊✲ᨭ᥼᥎㐍ဨࠒᚋ⸨ឡ࣭ࠑ≉ᐃᑓ㛛⫋ဨࠒஂಖ⏣ள⨾ 

2㸬ゐ፹࢖ࣥࣇ࢛࣐ࢸ࢕ࢵࢡࢫࡢ๰ᡂ࡟ྥࡅ࡚ ᅛయゐ፹ศ㔝࡟࠾ࡅࡿ࣐ࢸࣜ࢔ࣝࢬ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡ
ࢫ㸦MI㸧ࡢⴌⱆⓗྲྀࡾ⤌ࡳ࡜ࡋ࡚㸪ゐ፹⣲㐣⛬࡜ࡋ࡚㓟⣲Ḟ㝗⏕ᡂ㸪 Lewis㓟ሷᇶ┦஫స⏝࡟↔Ⅼࢆ⤠ࡾ㸪ゐ፹⾲㠃࣭཯ᛂศᏊࡢᵓ㐀࣭㟁Ꮚ≧ែ࡜ྛ⣲㐣⛬ࡢ⇕ຊᏛⓗ࡞㉳ࡇࡾࡸࡍࡉࢆ⥙⨶ⓗ࡟⌮ㄽィ⟬ࡋ㸪ᶵᲔᏛ⩦ࢆే⏝ࡋࡓࢹ࣮ࢱ
ゎᯒࢆ⾜ࡗ࡚ࡁࡓ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸ኳ↛࢞ࢫ࡟ࡼࡿ⇞↝ࡣ⯪⯧ࡸⓎ㟁ᡤ࡛ᗈࡃ฼⏝ࡉࢀ࡚࠸ࡿࡀ㸪᤼࢞ࢫ୰ࡢᮍ⇞CH4ࡢᨺฟࡀㄢ
㢟࡛࠶ࡿ㸬᤼ฟ㔞ࡢᢚไࡢࡓࡵ㸪᤼࢞ࢫࡢୗὶ࡛CH4ࢆప᏶඲㓟໬࡛ࡁࡿゐ፹ࡀᚲせ࡛࠶ࡿ㸬᭷ຠ࡞ゐ፹࡜ࡋ࡚㓟໬࢔࣑ࣝࢽ࣒࢘ᢸᣢPd(Pd/Al2O3)ࡀᗈࡃ▱ࡽࢀ࡚࠸ࡿࡀ㸪(i)350Υ௨ୖࡢ㧗 㸪(ii)኱㔞ࡢⓑ㔠᪘ඖ⣲(PGM)ࡀᚲせ࡛࠶ࡿࡇ࡜ࡸ㸪(iii)H2OࡸSO2࡟ࡼࡿኻά࡞࡝ࡀㄢ㢟࡛࠶ࡿ.
㏻ᖖࡢ㑄⛣≧ែィ⟬࡛ࡣ㸪ᮍ㋃཯ᛂࢆ᥈⣴ࡍࡿࡇ࡜ࡣ㞴ࡋ
࠸.࡞ࡐ࡞ࡽ㸪ィ⟬⪅ࡣάᛶ໬࢚ࢿࣝࢠ࣮(Ea)ࢆぢ✚ࡶࡿࡓࡵ࡟㸪ጞᵓ㐀࡜⤊ᵓ㐀ࢆ᝿ᐃࡋ࡞ࡅࢀࡤ࡞ࡽ࡞࠸࠿ࡽ࡛࠶
ࡿ㸬ᮏ◊✲࡛ࡣ㸪୚࠼ࡽࢀࡓጞᵓ㐀࠿ࡽ཯ᛂ⤒㊰ࢆ⮬ື࡛᥈⣴ࡍࡿ཯ᛂ⤒㊰⮬ື᥈⣴ἲࢆά⏝ࡋ㸪ࠕ㈗㔠ᒓࣇ࣮࡛ࣜ㧗࠸ప άᛶࢆᣢࡘᅛయゐ፹⣔ࠖࡢ㛤Ⓨ࡟ྲྀࡾ⤌ࢇࡔ.
཯ᛂ⤒㊰᥈⣴ࡣ㸪Global Reaction Route Mapping (GRRM)ࣉ ࣟ ࢢ ࣛ ࣒ ෆ ࡟ ᑟ ධ ࡉ ࢀ ࡚ ࠸ ࡿ 㸪 Single-Component
Artificial Force Induced Reaction (SC-AFIR)ἲ࡟ࡼࡾᐇ᪋ࡋ
ࡓ㸬཯ᛂ≀(CH4 and O3)ࢆࢱ࣮ࢤࢵࢺཎᏊ࡜ࡋ㸪γ = 1000
kJ/mol࡛཯ᛂࢆㄏ㉳ࡋࡓ㸬࢚ࢿࣝࢠ࣮ィ⟬࡟ࡣVASPࣉࣟ
ࢢ࣒ࣛࢆ⏝࠸ࡓ㸬ỗ㛵ᩘ࡟ࡣGGA-PBEࢆ⏝࠸㸪kⅬࡣǻⅬࡢࡳ㸪࢝ࢵࢺ࢜ࣇ࢚ࢿࣝࢠ࣮ࡣ500 eV࡜ࡋࡓ㸬Becke–
Johnson damping࡟ࡼࡾᣑᩓຊ⿵ṇࢆ⾜ࡗࡓ(DFT-D3)㸬Ẽ┦཯ᛂࢆ᳨ウࡍࡿ㝿࡟ࡣ15Åࡢ❧᪉యࡢ୰࡛ィ⟬ࢆᐇ᪋ࡋࡓ㸬Hᆺβࢮ࢜ࣛ࢖ࢺ(Hβ; Si/Al = 8.5)ࡣ㸪NH4ᆺࢮ࢜ࣛ࢖ࢺ
ࢆ኱Ẽୗ500°C࡛↝ᡂࡍࡿࡇ࡜࡟ࡼࡾᚓࡓ㸬Pd/Al2O3ࡣྵ
ᾐἲ࡛ㄪ〇ࡋࡓ㸬࣓ࢱࣥ⇞↝ヨ㦂ࡣᅛᐃᗋὶ㏻ᘧ཯ᛂჾ࡟

‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
2024ᖺ5᭶1᪥࡟ྂᕝ᳃ஓ෸ᩍᤵࡀ኱㜰኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉࡟ᩍᤵ࡜ࡋ࡚␗ືࡋࡓ㸬⥲ྜ໬Ꮫ㝔༤ኈㄢ⛬ࡢ3ྡࡀ༤ኈྕࢆྲྀᚓ࣭༞ᴗࡋ㸪ಟኈᏛኈㄢ⛬ࡢ6ྡࡀಟ஢༞ᴗ
ࡋ㸪ᕤᏛ㒊Ꮫኈㄢ⛬ࡢ2ྡࡀ༞ᴗࡋࡓ㸬‫✲◊ڦ‬ㄢ㢟 ᐇ㦂࣭⌮ㄽ࣭ࢹ࣮ࢱ⛉Ꮫࡢ3ࡘࡢ࢔ࣉ࣮ࣟࢳ࡟ࡼࡾ㸪㈨※࣭⎔ቃ࣭࢚ࢿࣝࢠ࣮㛵㐃ࡢ♫఍ㄢ㢟ゎỴ࡟㈨ࡍࡿ㧗ᛶ⬟ゐ፹ࡢ㛤Ⓨ㸪ཬࡧゐ፹タィࡢ᪉ἲㄽ㛤ᣅࢆ┠ᣦࡍ㸬
1㸬㸬ᅛయゐ፹࡟ࡼࡿప⣭࢔ࣝ࢝ࣥ㸪CO2ኚ᥮
໬▼㈨※ࡢ࣑ࢽ࣐࣒฼⏝࡟㈨ࡍࡿᅛయゐ፹ἲࡢ㛤Ⓨ࡜
ゐ፹タィ࡟ྥࡅࡓᇶ♏◊✲ࢆ⾜ࡗ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ⌮ㄽ࣭ᐇ㦂ࡢ┦⿵ⓗ࡞᳨ウ࡟ࡼࡾ㸪࢔ࣝ࢝ࣥ⬺Ỉ⣲࡟᭷ຠ࡞㔠ᒓࣄࢻࣜࢻ⣔ゐ፹ࡢᏛ⌮ࢆ๰⏕ࡋࡓ㸦ࠓ⥲ㄝ/ゎㄝ1ࠔ㸧㸬

4040

Fig. 1 (a) Calculated reaction pathway of CH4 + O3, as well as
the values of relative energies (ΔE). The values written indark red represent activation barriers. (b) Energy profile ofCH4 combustion to yield CO2. The reaction path shown by
the red lines is the most plausible for CO2 formation pathway.
ΔE are provided under each bar, and the activation barriers
are described employing the bold italic style (Unit: kJ/mol).

ᖺሗ࣭◊✲ᐊ⦅‫ە‬཯ᛂ࢞ࢫ(0.1% CH4 + 0.7% O3 + 5.95% O2)ࢆὶ㏻ࡉࡏᐇ᪋
ࡋࡓ㸬O3ࡣ㸪O2ࢆ࢜ࢰࢼ࢖ࢨ࣮࡟ὶ㏻ࡉࡏࡿࡇ࡜࡛౪⤥ࡋࡓ㸬ฟཱྀ࢞ࢫࡣIR࢞ࢫࢭࣝࢆ⏝࠸࡚ศᯒࡋࡓ㸬
SC-AFIRἲ࡟ࡼࡿ཯ᛂ⤒㊰᥈⣴࡛㸪CH4⇞↝࡟᭱ࡶ㐺ࡋࡓ㓟໬๣ࢆ᳨ウࡋࡓ㸬Fig. 1a࡟CH4 + O3ࡢ཯ᛂ⤒㊰᥈⣴ࡢ⤖ᯝࢆ♧ࡍ㸬CH4 + O3 ཯ᛂ࠿ࡽண᝿ࡉࢀࡿ⏕ᡂ≀ࡣ㸪
CH3OH㸪CH2O㸪CH2O2㸪CO㸪CO2࡛࠶ࡿࡇ࡜ࡀࢃ࠿ࡗࡓ㸬ࡑࡢ௚ࡢ཯ᛂ⤒㊰᥈⣴(e.g. CH3OH + O3㸪CH2O + O3㸪andCO + O3)ࡢ⤖ᯝࡶྜࢃࡏ㸪CH4࠿ࡽCO2ࡲ࡛ࡢ඲యࣃࢫࢆ
సᡂࡋࡓ(Fig. 1b). ࡑࡢ⤖ᯝ࠿ࡽ㸪O3ࢆ⏝࠸ࡓ࣓ࢱࣥ⇞↝ࡢᚊ㏿ẁ㝵ࡣCH3OH⏕ᡂ཯ᛂ(CH4 + O3 → CH3OH + O2)࡛࠶ࡿࡇ࡜ࡀࢃ࠿ࡗࡓ㸬ࡑࡢ௚ࡢ㓟໬๣ೃ⿵࡜ࡋ࡚㸪㐣㓟໬Ỉ⣲(H2O2)ࡸ୍㓟໬❅⣲(N2O)࡛ࡶྠᵝࡢ᳨ウࢆ⾜ࡗࡓࡀ㸪CH3OH⏕ᡂࡢEaࡀࡑࢀࡒࢀ177 kJ/mol࡜269 kJ/mol࡜ぢ✚ࡶࡽࢀ㸪O3ࡀ᭱ࡶຠᯝⓗ࡞㓟໬๣࡛࠶ࡿࡇ࡜ࡀ♧ࡉࢀࡓ.
๓㡯࡛♧ࡉࢀࡓO3࡟ࡼࡿCH4⇞↝ࡢᚊ㏿ẁ㝵(CH4 + O3
→ CH3OH + O2)ࡢ཯ᛂࢆಁ㐍ࡍࡿάᛶⅬ࡟ࡘ࠸᳨࡚ウࡋࡓ㸬㔠ᒓ✀㸪ࣛࢪ࢝ࣝ✀ࡢࣔࢹࣝάᛶⅬ࡜ࡋ࡚㸪CuཎᏊ㸪NOศᏊࢆ⣔ෆ࡟ᑟධࡋ㸪ࡑࢀࡒࢀ཯ᛂ⤒㊰᥈⣴ࢆ⾜ࡗࡓ(Fig. 2)㸬CuཎᏊࢆάᛶⅬ࡜ࡋࡓሙྜ㸪Cuࡢ㓟໬࡟క࠸
CH2Oࡢ⏕ᡂࡀᥦ᱌ࡉࢀࡓࡀ㸪Eaࡀ㧗࠿ࡗࡓ㸬NO ศᏊࡢሙྜ㸪άᛶⅬ࡞ࡋࡢሙྜࡼࡾࡶప࠸Eaࡀぢ✚ࡶࡽࢀࡓࡀ(123kJ/mol vs 143 kJ/mol)㸪㏫཯ᛂࡢEaࡀ㠀ᖖ࡟పࡃ(2 kJ/mol)᭷
ᮃ࡞άᛶⅬ࡜ࡣゝ࠼࡞࠿ࡗࡓ㸬ḟ࡟㸪ሷᇶⅬ࡜B㓟ⅬࡢࣔࢹࣝάᛶⅬ࡜ࡋ࡚C5H5N࡜H2SO4ࢆࡑࢀࡒࢀ⣔ෆ࡟ᑟධࡋ
ྠᵝࡢ᳨ウࢆ⾜ࡗࡓ(Fig. 3a and b)㸬୧άᛶⅬ࡜ࡶ࡟άᛶⅬࡀ࡞࠸ሙྜࡼࡾࡶప࠸Ea࡛CH3OHࢆ⏕ᡂྍ⬟࡛࠶ࡿࡇ࡜
ࡀࢃ࠿ࡗࡓ㸬≉࡟B㓟ⅬࡣEaࢆẼ┦ࡼࡾࡶ⣙17 kJ/molపୗࡉࡏ࡚࠾ࡾ(126 kJ/mol vs 143 kJ/mol)㸪᭱ࡶ᭷ᮃ࡞άᛶⅬ࡛࠶ࡿྍ⬟ᛶࡀ♧၀ࡉࢀࡓ㸬ḟ࡟㸪H2SO4࡟ຍ࠼㸪HClO4㸪
HNO3㸪H3PO4ୖࡢ཯ᛂ⤒㊰᥈⣴ࢆᐇ᪋ࡋࡓ㸬ࡲࡓ㸪ྛB㓟
Ⅼࡢ㓟ᙉᗘࢆぢ✚ࡶࡿࡓࡵࣆࣜࢪࣥ྾╔࢚ࢿࣝࢠ࣮(Epyr)ࢆィ⟬ࡋ㸪CH3OH⏕ᡂࡢEaࢆ⦪㍈࡟ࣉࣟࢵࢺࡋࡓ(Fig. 4a)㸬ࡑࡢ⤖ᯝ㸪Epyrࡀ㈇࡟኱ࡁ࠸⛬㸪ࡘࡲࡾ㸪B㓟Ⅼࡢ㓟ᙉᗘࡀ㧗࠸࡯࡝CH3OH⏕ᡂ཯ᛂࡢEaࡀప࠿ࡗࡓ.
ࡇࡇࡲ࡛ࡢ᳨ウ࠿ࡽ㸪ᙉB㓟Ⅼࢆᣢࡘᅛయ㓟ࡀ୙ᆒ୍ゐ፹࡜ࡋ࡚᭷ᮃ࡛࠶ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓ㸬ࡑࡇ࡛㸪ᙉᅛయ㓟࡜ࡋ࡚ࢮ࢜ࣛ࢖ࢺࢆ⏝࠸㸪ࡉࡽ࡞ࡿ᳨ウࢆ⾜ࡗࡓ㸬βᆺࢮ࢜ ࣛ ࢖ ࢺ ෆ ࡢ B 㓟 Ⅼ ࡟ ࡘ ࠸ ࡚ 㸪 Epyr ࢆ ィ ⟬ ࡍ ࡿ ࡜ −199
kJ/mol࡜ぢ✚ࡶࡽࢀ㸪᳨ウࡋࡓ㓟ศᏊ(⣙−64 kJ/mol)ࡼࡾࡶ
㈇࡟኱ࡁ࡞್࡜࡞ࡗࡓ㸬๓㏙ࡢ㓟ศᏊࡢEa࡜Epyrࡢ⥺ᙧ┦㛵ࡢእᤄ࠿ࡽࢮ࢜ࣛ࢖ࢺෆB㓟ⅬࡢEaࢆぢ✚ࡶࡗࡓ࡜ࡇࢁ
⣙60 kJ/mol࡜ぢ✚ࡶࡽࢀࡓ(Fig. 4a)㸬ᐇ㝿࡟㸪ࢮ࢜ࣛ࢖ࢺ
ෆB㓟Ⅼୖ࡛཯ᛂ⤒㊰᥈⣴ࢆᐇ᪋ࡍࡿ࡜㸪CH3OH⏕ᡂ཯ᛂࡢEaࡣ71 kJ/molࢆぢ✚ࡶࡽࢀ㸪㠀ᖖ࡟ప࠸್࡜࡞ࡗࡓ(Fig.
3c)㸬
⌮ㄽⓗ᳨ウ࠿ࡽᚓࡽࢀࡓ㓟ᙉᗘ࡜CH4⇞↝άᛶࡢ┦㛵ࢆ㸪ゐ፹ヨ㦂࡟ࡼࡾᐇ㦂ⓗ࡟᳨ドࡋࡓ㸬ྛ㓟⁐ᾮࢆ⏝࠸࡚
SiO2ୖ࡟㓟ࢆྵᾐᢸᣢ(3 wt%)ࡋ㸪O3Ꮡᅾୗ࡛CH4⇞↝ヨ㦂ࢆᐇ᪋ࡋࡓ㸬⌮ㄽⓗ᳨ウ࡜ྠᵝ࡟Epyrࢆᶓ㍈࡟CH4ᾘ㈝㏿ᗘࢆࣉࣟࢵࢺࡋࡓ࡜ࡇࢁ㸪Ea vs Epyrࣉࣟࢵࢺ(Fig. 4a)࡜ྠ
ᵝࡢ┦㛵㸪ࡘࡲࡾᙉ࠸B㓟Ⅼࢆᣢࡘゐ፹࡯࡝㧗࠸CH4⇞↝άᛶࢆ♧ࡋࡓ(Fig. 4b)㸬᭷ᮃ࡞άᛶⅬ࡛࠶ࡿᙉᅛయ㓟ࡀ㸪ᐇ㝿࡟㧗࠸CH4⇞↝άᛶࢆ♧ࡍࡇ࡜ࢆᐇ㦂ⓗ࡟෌⌧࡛ࡁࡓ㸬

Fig. 3. Calculated reaction pathways of CH4 + O3 over (a)C5H5N molecule, (b) H2SO4 molecule and (c) Acid site inzeolite. The values of ΔE and the Ea (dark red) are shown
together (Unit: kJ/mol).

Fig. 2. Calculated reaction pathways of CH4 + O3 over a Cu
atom (top) and NO molecule (bottom). The values of ΔE andthe Ea (dark red) are shown together (Unit: kJ/mol).

‫ە‬ᖺሗ࣭◊✲ᐊ⦅

Fig. 4 (a) Plot of Ea of the CH4 + O3 reaction as a function of
the C5H5N adsorption energy (Epyr) of the acids. (b)Experimental CH4 consumption rate of the samples in 0.1%
CH4 + 0.7% O3 at 250 °C (He balance, total flow: 100 ml/min)as a function of Epyr.

41

w ith O3
w ithout O3

w ith O3
w ithout O3

80
60
40

HE8.5
Pd5Al 2O3

20
0

(c)
100
80

200
400
Temperature (°C)
HE8.5

60
40
20
0
0

Pd5Al 2O3

5
10
15
Reaction time (h)(b)
ln[VCH4(mmolg–1h–1)]

CH4 Conversion (%)

(a)
100

CH4⇞↝ᛶ⬟ࢆᣢࡘゐ፹⣔ࡢ㛤Ⓨ࡟ᡂຌࡋ

5
HE8.5 Ea: 75 kJmol –1
VCH4: 57.7 mmol h -1 gcat-1

0
-5

–1
Pd5Al 2O3 Ea: 94 kJmol
VCH4: 0.13 mmol h -1 gcat-1

0.2
(d)
100

CH4 Conversion (%)

࠿࡟෽ࡄప
ࡓ.

CH4 Conversion (%)ᙉ࠸B㓟Ⅼ࡟ࡼࡿCH4 + O3཯ᛂࡢάᛶ໬࣓࢝ࢽࢬ࣒ࢆ⪃ᐹࡍࡿࡓࡵ㸪Ꮩ❧O3ࡢศᏊ㌶㐨ࢆpCOHP analysis࡟ࡼࡾゎᯒࡋࡓ (Fig. 5a)㸬Ꮩ❧O3ศᏊࡢࣇ࢙࣑ࣝ‽఩(EF)㏆ഐ࡟ࡣ㸪
O–O⤖ྜࡢ཯⤖ྜᛶ㌶㐨ࡀᏑᅾࡋ࡚࠸ࡿ㸬ࡘࡲࡾ㸪ࡇࡢ㌶
㐨࡟㟁ᏊࡀὀධࡉࢀࢀࡤO–O⤖ྜࡣᙅࡲࡿࡇ࡜࡟࡞ࡿ㸬Epyrࢆᶓ㍈࡟㸪㑄⛣≧ែ୰ࡢB㓟Ⅼ࡜┦஫స⏝ࡋ࡚࠸ࡿ㓟⣲ཎᏊ(O1ཎᏊ)ࡢBader㟁Ⲵࢆࣉࣟࢵࢺࡋࡓ(Fig. 5b)㸬ࡑࡢ⤖ᯝ㸪B㓟Ⅼࡢ㓟ᙉᗘࡀቑࡍ(Epyrࡀ㈇࡟ቑ኱ࡍࡿ)࡯࡝㸪O1
ཎᏊࡢ㟁Ⲵᐦᗘࡀቑຍࡋ࡚࠸ࡿࡇ࡜ࡀࢃ࠿ࡗࡓ㸬Epyrࢆᶓ㍈㸪㑄⛣≧ែ୰ࡢO1ཎᏊ࡜ࡑࡢ㞄ࡢ㓟⣲ཎᏊ(O2ཎᏊ)࡜
ࡢ⤖ྜ㊥㞳ࢆ⦪㍈࡟ࣉࣟࢵࢺࡋࡓ(Fig. 5c)㸬㓟ᙉᗘࡀቑࡍ
࡯࡝㸪㑄⛣≧ែ୰ࡢO1–O2⤖ྜ㊥㞳ࡀఙ㛗ࡋ࡚࠸ࡿࡇ࡜ࡀ
ࢃ࠿ࡗࡓ㸬௨ୖࡢ⤖ᯝ࠿ࡽ㸪CH4 + O3཯ᛂࡢ࣓࢝ࢽࢬ࣒ࡣ௨ୗࡢࡼ
࠺࡟⪃ᐹ࡛ࡁࡿ(Fig. 5d and e)㸬(i) ᙉB㓟ⅬୖࡢO1ཎᏊ࡟㸪㟼㟁┦஫స⏝࡟ࡼࡿ㈇ࡢ㟁Ⲵࡀ㞟ࡲࡿ㸪(ii) O3ศᏊࡢO1–
O2⤖ྜ࡟㟁Ꮚࡀὀධࡉࢀ㸪⤖ྜࡀᙅࡲࡿ㸪(iii)㑄⛣≧ែ୰
ࡢO1–O2⤖ྜࡀࡼࡾ㛗࠸⤖ྜ㊥㞳࡛Ᏻᐃ໬ࡉࢀ㸪㑄⛣≧ែࡢ࢚ࢿࣝࢠ࣮ࡀୗࡀࡿ㸬ࡇࡢࡼ࠺࡟㸪ᙉB㓟Ⅼࡢᙉ࠸㟼㟁┦஫స⏝ࡀCH4 + O3཯ᛂࡢάᛶ໬࡟ᐤ୚ࡋ࡚࠸ࡿࡇ࡜ࡀ
ศᏊ㌶㐨࡛ࣞ࣋ࣝ᫂ࡽ࠿࡟࡞ࡗࡓ㸬

0.25 0.3
1000/RT

0.35

80
60

10mg HE8.5

40
20
0
0

50 100 150
Reaction time (h)Fig. 6 (a) CH4 conversions over 40 mg of the Hβ zeolite witha Si/Al ratio of 8.5 (Hß8.5) and 40 mg of 5wt% Pd-loaded
Al2O3 (Pd5Al2O3) in 0.1% CH4 + 5.95% O2 + 0.7% O3 and
0.1% CH4 + 10% O2 flows as functions of the reaction
temperature. (b) Arrhenius plots for the combustions of CH4
over Hß8.5 in 0.1% CH4 + 5.95% O2 + 0.7% O3 at 160–
190 °C, as well as over Pd5Al2O3 in 0.1% CH4 +10% O2 at
170–220 °C. The reaction rates (VCH4) at 190 °C over Hβ8.5
and Pd5Al2O3 are shown together (R2 = 0.99 for both
catalysts). (c) Time course of CH4 conversion over 40 mg of
Pd5Al2O3 (at 400 °C) and Hβ8.5 (at 200 °C) in 0.1% CH4 +3% H2O + 40ppm SO2 + 10% O2 or 5.95% O2 + 0.7% O3 for
Pd5Al2O3 and Hβ8.5, respectively, with He balance (total
flow: 100 ml/min). (d) Long-term reaction test for 10 mg of
Hβ8.5 in 0.1% CH4 + 5.95% O2 + 0.7% O3 + 3% H2O +40ppm SO2 at 200 °C.

Fig. 5 (a) The projected crystal orbital Hamilton population(pCOHP) curve for the O–O bond in the isolated O3
molecule. (b) Bader charge of O1 atom and (c) O1–O2 bondlength in TS structures against Epyr. (d) TS structure of CH4+ O3 reaction over H2SO4 molecule. Bader charge of O1 atomand bond lengths are shown together. (e) The schematic
description of O–O bond activation scheme.

3㸬㸬᤼࢞ࢫί໬⏝ゐ፹ࡢタィᣦ㔪 ⮬ື㌴᤼࢞ࢫࡢί໬࡟᭷ຠ࡞ᅛయゐ፹ࡢ㛤Ⓨ࡜ゐ፹タィ࡟ྥࡅࡓᇶ♏◊✲ࢆ⾜ࡗ࡚ࡁࡓ㸬᭱ᚋ࡟㸪ィ⟬ඛᑟ࡛ᑟ࠿ࢀࡓࢮ࢜ࣛ࢖ࢺゐ፹ࡢゐ፹ᛶ⬟
ࢆ᪤ሗゐ፹࡜ᐇ㦂ⓗ࡟ẚ㍑ࡋࡓ㸬᪤ሗゐ፹࡜ࡋ࡚5wt% Pdloaded Al2O3 (Pd5Al2O3)ࢆㄪ〇ࡋ㸪Hβ࡜࡜ࡶ࡟CH4⇞↝ヨ㦂ࢆ⾜࡞ࡗࡓ(Fig. 6a)㸬O3Ꮡᅾୗ㸪Hβࡀ200°C࡛㧗࠸CH4㌿໬⋡ ࢆ ♧ ࡋࡓ 㸬 Pd5Al2O3 ࡛ྠᵝ ࡢ CH4 ㌿ ໬ ⋡ࢆ ᚓ ࡿ࡟ ࡣ
400°C௨ୖࡀᚲせ࡛࠶ࡾ㸪200°Cࡢ኱ᖜ࡞ప ໬ࢆᐇ⌧ࡋࡓ㸬O3㠀Ꮡᅾୗ࡛ࡣ㸪Hβࡣ࡯࡜ࢇ࡝άᛶࢆ♧ࡉ࡞࠸ࡇ࡜࠿
ࡽ㸪O3ࡀ㓟໬๣࡜ࡋ࡚CH4⇞↝࡟ᐤ୚ࡋ࡚࠸ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓ㸬ྛゐ፹ࡢぢ࠿ࡅࡢEaࢆ࢔ࣞࢽ࢘ࢫࣉࣟࢵࢺ࡛ぢ✚ࡶࡗࡓ(Fig. 6b)㸬Hβ࡜Pd5Al2O3ࡢEaࡣࡑࢀࡒࢀ75 kJ/mol ࡜
94 kJ/mol࡜ぢ✚ࡶࡽࢀࡓ㸬≉࡟㸪190°C࡛ࡢHβࡢ཯ᛂ㏿ᗘࡣPd5Al2O3ࡢ⣙442ಸ࡛࠶ࡗࡓ㸬᤼࢞ࢫ୰࡟ྵࡲࢀࡿH2O
࡜SO2 ࢆᑟධࡋゐ፹⪏ஂヨ㦂(15h)ࢆᐇ᪋ࡋࡓ(Fig. 6c)㸬Pd5Al2O3ࡀ10h࡛࡯࡜ࢇ࡝άᛶࢆ♧ࡉ࡞ࡃ࡞ࡗࡓࡢ࡟ᑐࡋ㸪Hβࡣ15hࡢ㛫άᛶࢆ⥔ᣢࡋࡓࡲࡲࡔࡗࡓ㸬ゐ፹㔞ࢆῶࡽࡋCH4㌿໬⋡ࢆ80%࡟ㄪ⠇ࡋ࡚㸪170hࡢ㛗᫬㛫ゐ፹ヨ㦂ࢆᐇ᪋ࡋࡓ(Fig. 6d)㸬H2OࡸSO2ࡀඹᏑࡋ࡚࠸ࡿࡢ࡟ࡶ㛵ࢃࡽࡎ኱ࡁ࡞ኻάࡣぢࡽࢀ࡞࠿ࡗࡓ㸬ィ⟬ඛᑟ࡛㸪᪤ሗゐ፹ࢆ㐶ᖺᗘࡢࢺࣆࢵࢡ㸸Lean⬺◪࡟࠾ࡅࡿᒀ⣲ࣇ࣮ࣜ࡜ⓑ㔠᪘㔠ᒓ㸦PGM㸧ࣇ࣮ࣜࡢ㐩ᡂࡣᣮᡓⓗ࡞ㄢ㢟࡛࠶ࡿ㸬Rich᮲௳࡛㐣Ώⓗ࡟⏕ᡂࡍࡿNH3 ࢆLean᫬࡟SCRࡢ㑏ඖ๣࡟⏝࠸ࡿ㠀ᐃᖖ⬺◪ࡀPGM࡜ࢮ࢜ࣛ࢖ࢺࢆ⏝࠸ࡓゐ፹ࢆ⏝࠸᳨࡚ウࡉࢀ࡚ࡁࡓ㸬ᮏ◊✲࡛ࡣ㸪ୖグࡢ㠀ᐃᖖ⬺◪࡟᭷
ຠ࡞PGM ࣇ࣮ࣜゐ፹࡟ࡘ࠸࡚ሗ࿌ࡍࡿ㸬཯ᛂᶵᵓࡢゎ᫂ࢆ┠ᣦࡋ࡚operandoศග◊✲ࡶ⾜ࡗࡓ㸬
Cu/CeO2(Cu = 5 wt%)ࡣྵᾐἲ࡛ㄪ〇ࡋࡓ㸬Cr࢖࢜ࣥ஺᥮
mordenite(CrMOR)ࡣ◪㓟CrỈ⁐ᾮࢆ⏝࠸ࡓ࢖࢜ࣥ஺᥮࡟ࡼࡾㄪ〇ࡋࡓ(Si/Al = 10㸪Cr = 0.21 wt%)㸬CrMOR(32 mg)
࡜Cu/CeO2(8 mg)ࡢ≀⌮ΰྜయ(CrMOR+Cu/CeO2) ࢆ཯ᛂ(350 °C)࡟⏝࠸ࡓ㸬In situ IR࡛ࡣゐ፹disk࡟࢞ࢫὶ㏻ࡋࡓ᫬ࡢศග ᐃ࡜ྠ᫬࡟ฟཱྀ࢞ࢫࡢIR࣭㉁㔞ศᯒࢆ⾜ࡗࡓ㸬 Cu/CeO2ࡣỈᛶ࢞ࢫࢩࣇࢺ཯ᛂ(CO + H2O Ѝ CO2 + H2)
࡜NO+H2཯ᛂࢆ⤒⏤ࡍࡿ࡟ࡼࡿNH3⏕ᡂ࡟᭷ຠ࡛࠶ࡿࡇ
࡜ࡀ▱ࡽࢀ࡚࠸ࡿ㸬ᮏ◊✲࡛ࡶCu/CeO2ࡀNO+CO+H2O཯
ᛂ࡟ࡼࡿNH3 ⏕ᡂ࡟᭷ຠ࡛࠶ࡿࡇ࡜ࢆ☜ㄆࡋࡓ 㸬Rich(0.1% NO + 0.5% CO + 1% H2O㸪660 s)㸪Lean (0.1% NO +4242ᖺሗ࣭◊✲ᐊ⦅‫ە‬

2% O2 + 1% H2O㸪300 s) ࢞ࢫࢆCu/CeO2+CrMORゐ፹࡟஺஫࡟ὶ㏻ࡉࡏࡓ࡜ࡇࢁ(Fig. 7)㸪Rich᫬ࡢึᮇ௨እ࡛NOx⃰ᗘࡢపୗ(200 ppm௨ୗ)ࡀほ ࡉࢀࡓ㸬ᖹᆒ⬺◪⋡ࡣ73%࡛
࠶ࡾ㸪N2㑅ᢥ⋡ࡣ95%࡛࠶ࡗࡓ㸬ᮏ㠀ᐃᖖ⬺◪ἲࡣᗈ࠸
ᗘᇦ(200-500Υ)࡛┦ᙜࡍࡿᐃᖖ཯ᛂ(0.1% NO + 0.35% CO+ 0.6% O2 + 1% H2O)ࡼࡾࡶ㧗࠸⬺◪⋡ࢆ♧ࡋࡓ(Fig. 8)㸬
࿘ᮇⓗ࡞Rich/Lean⬺◪᮲௳ୗࡢoperando IRࢆ⾜ࡗࡓ࡜ࡇࢁ㸪Rich᮲௳࡛ࢮ࢜ࣛ࢖ࢺୖ࡟⏕ᡂࡍࡿNH4+ࡀLean᮲௳࡛
ᾘ㈝ࡉࢀࡿ཯ᛂࡀ࿘ᮇⓗ࡟ほ ࡉࢀࡓ㸬௚ࡢ⤖ᯝ࡜ేࡏ࡚
Fig. 9ࡢ཯ᛂᶵᵓࢆᥦ᱌ࡋࡓ㸬௨ୖࡼࡾ㸪Rich/Leanࢧ࢖ࢡ࡛ࣝࡢNH3⏕ᡂ/฼⏝࡟ࡼࡾ㥑ືࡍࡿ㠀ᐃᖖ⬺◪࡟᭷ຠ࡞PGM ࣇ࣮ࣜゐ፹ࢆ㛤Ⓨࡋ㸪཯ᛂᶵᵓࢆᥦ᱌ࡋࡓ㸬
NO+CO+H2O (660 s, Rich)Rich

Gas concentration (ppm)

1000

Rich
Lean

Lean

CO2x1/5

NO+O2+H2O (300 s, Lean)

Rich

Rich
Lean

Rich
Lean

Rich
Lean

Lean

NO
500

0
0

1000

2000

t (s)

3000

4000

5000

Fig. 7 Unsteady-state de-NOx by Cu/CeO2+CrMOR.

NOx conversion (%)

100
80

periodic rich/lean

60
40
20
0
200

steady-state
300

400

Temperature ( oC)

500

Fig. 8 Unsteady-stare and steady-state de-NOx by
Cu/CeO2+CrMOR.

t (s)Fig. 9 Mechanism of unsteady-stare De-NOx.

‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦ࡍ࡭࡚ᑂᰝࡘࡁ㸧(1) Kamiguchi, S.; Asakura, K.; Shibayama, T.; Yokaichiya, T.;
Ikeda, T.; Nakayama, A.; Shimizu, K.; Hou, Z. Catalyticammonia synthesis on HY-zeolite supported angstrom-size
molybdenum cluster, Chem. Sci., 2024, 15, 2914-2922.
(2) Jablonska, M.; Suharbiansah, R. SR; Zhang, N.; Shimizu, K.;
Lukman, M.; Bertmer, M.; Lei, H.; Poppl, A.; Simon, U.;
Glaser, R. Disclosing the enhanced NH3-SCR-DeNOx activityof Cu-containing zeolite Y prepared with 15-Crown-5, Catal.
Today, 2024, 432, 114611.
(3) Zhang, N.; He, C.; Jing, Y.; Qian, Y.; Toyao, T.; Shimizu, K.
Enhanced N2O decomposition on Rh/ZrO2 catalysts through‫ە‬ᖺሗ࣭◊✲ᐊ⦅the promotional effect of palladium, Surfaces and Interfaces,
2024, 46, 104120(4) Miyazaki, S.; Chen, D.; Jiacheng, B.; Toyao, T.; Kanda, Y.;
Shimizu, K. In Situ Spectroscopic Study of CO2 Capture andMethanation over Ni,Chem Asian J. 2024, e202301003.
(5) Tada, S.; Jinushizono, T.; Ishikawa, K.; Miyazaki, S.; Toyao,T.; Shimizu, K.; Nishijima, M.; Yamauchi, N.; Kobayashi, Y.;
Kikuchi, R. Low-Temperature CO2 Methanation over Ru
Nanoparticles Supported on Monoclinic Zirconia, Energy
Fuels, 2024, 38, 2296-2304.
(6) Huang, M.; Hu, X.; Chen, D.; Maeno, Z.; Tsunoji, N.; Toyao,T.; Shimizu, K. Anaerobic Ammodehydrogenation of Ethaneto Acetonitrile over Ga-Loaded H‑FER Zeolite Catalysts, ACS
Catal. 2024, 14, 1013-1020.
(7) Zhang, N.; Qian, Y.; Toyao, T.; Shimizu, K. Continuous
Unsteady-State De-NOx System via Tandem Water-Gas Shift,
NH3 Synthesis, and NH3-SCR under Periodic Lean/Rich
Conditions, Environ. Sci. Technol. 2023, 57, 19584-19593.
(8) Zhang, N.; Tong, J.; Miyazaki, S.; Zhao, S.; Kubota, H.; Jing,Y.; Mine, S.; Toyao, T.; Shimizu, K. Mechanism of NH3‑SCR
over P/CeO2 Catalysts Investigated by Operando
Spectroscopies, Environ. Sci. Technol. 2023, 57, 16289-16295.
(9) Miyazaki, S.; Yoshihara, M.; Toyao, T.; Maeno, Z.; Shimizu,
K. Continuous production of O2-free enriched CO2 fromambient air using moisture swing sorbents, Next
Nanotechnology, 2023, 3-4, 100029.
(10) Tashiro, K.; Saito, T.; Goto, K.; Masuda, J.; Miyakage, T.;
Shimoda, S.; Toyao, T.; Tsunoji, N.; Shimizu, K.; Matsumoto,
H.; Satokawa, S. Proton Conduction over the Zeolite with
Surface Water Cluster for the Water Electrolysis at Neutral
Condition, ChemCatChem 2023, e202301297.
(11) Hinuma, Y.; Yasumura, S.; Toyao, T.; Kamachi, T.;
Shimizu, K. Two descriptors avoiding explicit bondconsideration on relative surface energies of various
terminations in a crystal, Sci. Technol. Adv. Mater. Meth. 2023,
3, 2278323.
(12) Ito, H.; Nakahira, Y.; Ishimatsu, N.; Goto, Y.; Yamashita,A.; Mizuguchi, Y.; Moriyoshi, C.; Toyao, T.; Shimizu, K.;
Oike, H.; Enoki, M.; Navarro, N.; Miura, A. Stability andMetastability of Li3YCl6 and Li3HoCl6, Kiyoharu Tadanaga,
Bull. Chem. Soc. Jpn. 2023, 96, 1262-1268.
(13) Liu, K.; Shimizu, K.; Furukawa, S. Enhanced CO2
Utilization in Dry Reforming of Benzene over Intermetallic
Ni3Ga Catalyst, J. Jpn. Petrol. Inst. 2023, 66, 254-257.
(14) Ma, J.; Shimizu, K.; Furukawa, S. Co-modification
Improves the Stability of In2O3 Catalyst in Acetylene
Semihydrogenation, J. Jpn. Petrol. Inst. 2023, 66, 149-153(15) Li, L.; Zhang, N.; Wu, Z.; Miyazaki, S.; Toyao, T.; Maeno,Z.; Shimizu, K. Rb-Ni/Al2O3 as dual functional material forcontinuous CO2 capture and selective hydrogenation to CO,
Chem. Eng. J. 2023, 477, 147199.
(16) Huang, M.; Kinjo, T.; Yasumura, S.; Toyao, T.; Matsumura,
D.; Saitoh, H.; Shimizu, K.; Namiki, N.; Maeno, Z. In situ Ga
K-edge XANES study of Ga-exchanged zeolites at hightemperatures under different atmospheres including vacuum,
CO, and pressurized H2, Catal. Sci. Technol. 2023, 13, 6832.
(17) Huang, H.; Tomimuro, Y.; Miyazaki, S.; Mine, S.; Toyao,T.; Hinuma, Y.; Kanda, Y.; Kitano, M.; Shimizu, K.; Maeno, Z.
Propane metathesis and hydrogenolysis over titanium hydride
catalysts,Catal. Sci. Technol. 2023, 13, 6247-6253.
(18) Jing, Y.; He, C.; Zhang, N.; Murano, Y.; Toyoshima, R.;
Kondoh, H.; Kageyama, Y.; Inomata, H.; Toyao, T.; Shimizu,
K. Promotional Effect of Ag on the Catalytic Decomposition of
N2O in the Presence of O2 over the Al2O3‑Supported Rh
Catalyst, ACS Catal. 2023, 13, 12983-12993.
(19) Liu, C.; Lu, B.; Ariga-Miwa, H.; Ogura, S.; Ozawa, T.;
Fukutani, K.; Gao, M.; Hasegawa, J.; Shimizu, K.; Asakura, K.;
Takakusagi, S. Dynamic Behavior of Intermediate Adsorbates
to Control Activity and Product Selectivity in Heterogeneous

43Catalysis: Methanol Decomposition on Pt/TiO2(110), J. Am.
Chem. Soc. 2023, 145, 19953-19960.
(20) Mine, S.; Toyao, T.; Shimizu, K.; Hinuma, Y. Comparisonof Matlantis and VASP Bulk Formation and Surface Energies
in Metal Hydrides, Carbides, Nitrides, Oxides, and Sulfides,
Chem. Lett. 2023, 52, 757-759.
(21) Yasumura, S.; Kamachi, T.; Toyao, T.; Shimizu, K.;
Hinuma, Y. Prediction of Stable Surfaces of Metal Oxides
through the Unsaturated Coordination Index, ACS Omega 2023,
8, 29779-29788.
(22) Wang, G.; Mine, S.; Chen, D.; Jing, Y.; Ting, K.-W.;
Yamaguchi, T.; Takao, M.; Maeno, Z.; Takigawa, I.;
Matsushita, K.; Shimizu, K.; Toyao, T. Accelerated discovery
of multi-elemental reverse water-gas shift catalysts using
extrapolative machine learning approach, Nature Commun.
2023, 14, 5861.
(23) Phongprueksathat, N.; Ting, K.-W.; Mine, S.; Jing, Y.;
Toyoshima, R.; Kondoh, H.; Shimizu, K. Toyao, T.; Urakawa,
A. Bifunctionality of Re Supported on TiO2 in Driving
Methanol Formation in Low-Temperature CO2 Hydrogenation,
ACS Catal. 2023, 13, 10734-10750.
(24) Li, L.; Miyazaki, S.; Wu, Z.; Toyao, T.; Selyanchyn, R.;
Maeno, Z.; Fujikawa, S.; Shimizu, K. Continuous direct air
capture and methanation using combined system of membranebased CO2 capture and Ni-Ca based dual functional materials,
Appl. Catal. B 2023, 339, 123151.
(25) Yasumura, S.; Saita, K.; Miyakage, T.; Nagai, K.; Kon, K.;
Toyao, T.; Maeno, Z.; Taketsugu, T.; Shimizu, K. Designing
main-group catalysts for low-temperature methane combustionby ozone, Nature Commun. 2023, 14, 3926.
(26) Miyazaki, S.; Li, Z.; Li, L.; Toyao, T.; Nakasaka, Y.;
Nakajima, Y.; Shimizu, K.; Maeno, Z. Chemical Looping Dry
Reforming of Methane over Ni-Modified WO3/ZrO2:
Cooperative Work of Dispersed Tungstate Species and Ni overthe ZrO2 Surface, Energy Fuels 2023, 37, 7945-7957.
(27) Kubota, H.; Jing, Y.; Wan, L.; Tong, J.; Zhang, N.; Mine,S.; Toyao, T.; Toyoshima, R.; Kondoh, H.; Ferri, D.; Shimizu,
K. Operando Spectroscopic Study of Reduction and Oxidation
Half-Cycles in NH3-SCR over CeO2‑Supported WO3, ACS
Catal. 2023, 13, 9274-9288.
(28) Zhang, N.; Miyazaki, S.; Qian, Y.; Jing, Y.; Toyao, T.;
Shimizu, K. Mechanism of the Periodic Unsteady-State Water
Gas Shift Reaction on Highly Dispersed Cu-Loaded CeO2
Catalysts,ACS Catal. 2023, 13, 8503-8515.
(29) Zhang, J.; Nakaya, Y.; Shimizu, K.; Furukawa, S.Surface
Engineering of Titania Boosts Electroassisted Propane
Dehydrogenation at Low Temperature,Angew. Chem. Int. Ed.
2023, 62, e202300744.
(30) Shibata, G.; Shibayama, N.; Araki, K.; Kobashi, Y.; Ogawa,
H.; Nakasaka, Y.; Shimizu, K. Steady-state kinetic modeling of
NH3-SCR by monolithic Cu-CHA catalysts, Catal. Today,
2023, 411-412, 113797.
(31) Nakasaka, Y.; Kushima, K.; Yasumura, S.; Shimizu, K.;
Totani, K.; Shibata, G.; Masuda, T. Experimental studies on
intracrystalline diffusion of NO and NH3 in Cu-CHA, Catal.
Today 2023, 411-412, 113823.
(32) Huang, H.; Maeno, Z.; Toyao, T.; Shimizu, K. Ga speciationand ethane dehydrogenation catalysis of Ga-CHA and MOR:
Comparative investigation with Ga-MFI, Catal. Today 2023,
411-412, 113824.
(33) Yasumura, S.; Nagai, K.; Qian, Y.; Toyao, T.; Maeno, Z.;
Shimizu, . Multi-functionality of rhodium-loaded MOR
zeolite: production of H2 via the water gas shift reaction and its
use in the formation of NH3, Catal. Sci. Technol. 2023, 13,2994-3000.
(34) Shimoda, K.; Ishikawa, S.; Miyasawa, M.; Shimizu, K.;
Ueda, W. Molybdenum Oxide Constructed by {Mo6O21}6−4444

Pentagonal Unit Assembly and Its Redox Properties, Inorg.
Chem. 2023, 62, 11446-11455.
⥲ㄝゎㄝ
(1) Mengwen, H.; Yasumura, S.: Toyao, T.; Shimizu, K.; Maeno,
Z. In- and Ga-oxo clusters/hydrides in zeolites: speciation andcatalysis for light-alkane activations/transformations, Phys.
Chem. Chem. Phys., 2023, 25, 10211-10230.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟(1) ΎỈ◊୍㸸ࠕゐ፹ศ㔝࡟࠾ࡅࡿ⌮ㄽ࣭ࢹ࣮ࢱ⛉Ꮫά⏝౛ࠖ, ໬Ꮫ⏘ᴗࢆᨵ㠉ࡍࡿ᭱᪂DX㸦AI࣭IoT㸧ᢏ⾡(໬Ꮫᕤ Ꮫ ఍ 㛵 す ᨭ 㒊 ୺ ദ ), ኱ 㜰 ⛉ Ꮫ ᢏ ⾡ ࢭ ࣥ ࢱ ࣮㸦2023/6/29㸧. [Invited](2) ΎỈ◊୍㸸ࠕ୙ᆒ୍⣔ゐ፹タィࡢࡓࡵࡢィ⟬࣭ࢹ࣮ࢱ⛉Ꮫ࣭ศගᏛ◊✲ࠖ㸪➨43ᅇ ᪥ᮏ㟁ᏊMS࣮ࣘࢨ࣮ࢬ࣑࣮ࢸ ࢕ ࣥ ࢢ ( ኱ 㜰 ), ᱵ ⏣ ࢫ ࢝ ࢖ ࣅ ࣝ ࢫ ࢸ ࣛ ࣍ ࣮ ࣝ㸦2023/10/27㸧. [Invited](3) ΎỈ◊୍㸸ࠕᅛయゐ፹ศ㔝࡟࠾ࡅࡿ⌮ㄽ࣭ࢹ࣮ࢱ⛉Ꮫά⏝౛ࠖ㸪➨11ᅇࢹ࣮ࢱ㥑ືࢥࣥࢯ࣮ࢩ࢔࣒ࢭ࣑ࢼ࣮, ⏘ᴗᢏ ⾡ ⥲ ྜ ◊ ✲ ᡤ ⮫ ᾏ ๪ 㒔 ᚰ ࢭ ࣥ ࢱ ࣮ 㸦 2023/11/17 㸧 .
[Invited](4) ΎỈ◊୍㸸ࠕ୙ᆒ୍⣔ゐ፹タィࡢࡓࡵࡢィ⟬࣭ࢹ࣮ࢱ⛉Ꮫ㸪ศගᏛ◊✲ࠖ㸪➨46ᅇ ᪥ᮏ㟁ᏊMS࣮ࣘࢨ࣮ࢬ࣑࣮
ࢸ࢕ࣥࢢ (ᮾி), ࣄ࣮ࣗࣜࢵࢡὸⲡᶫࣅࣝ㸦2023/12/7㸧
[Invited](5) ΎỈ◊୍㸸ࠕゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬࡢ⤂௓࡜ᨺᑕග฼⏝஦౛ࠖ
㸪໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ࣭❧࿨㤋኱ᏛSRࢭࣥࢱ࣮ඹദࢩ࣏ࣥࢪ࣒࢘ࠕゐ፹⛉Ꮫ࡜ᨺᑕග㸫Softࠥ
Tender X⥺ࡢ᪂ࡓ࡞ᒎ㛤ࠖ❧࿨㤋኱Ꮫࡧࢃࡇ࣭ࡃࡉࡘ࢟ࣕ
ࣥࣃࢫ㸦2024/1/26㸧
㸬[Invited](6) ΎỈ◊୍㸸ࠕ཯ᛂᶵᵓゎᯒ࠾ࡼࡧᶵᲔᏛ⩦ࢆά⏝ࡋࡓ୙ᆒ୍⣔ゐ፹ࡢ㛤Ⓨࠖ, ᪥ᮏ໬Ꮫ఍➨104᫓Ꮨᖺ఍㸦Ꮫ⾡㈹ ཷ ㈹ ㅮ ₇ 㸧㸪 ᪥ ᮏ ኱ Ꮫ ⌮ ᕤ Ꮫ 㒊 ⯪ ᶫ ࢟ ࣕ ࣥ ࣃ ࢫ㸦2024/3/19㸧
㸬[Invited](7) Shimizu, K.: ͆ Computational, data science, andspectroscopic studies for design of heterogeneous catalysis”,
2023 International Conference on Advanced Nano-Micro
Materials, Suzuki Lecture Hall, Hokkaido University㸦2023/5/15㸧. [Keynote](8) Shimizu, K.:͆NH3̽SCR Mechanism for Cu-CHA, Feș,V2O5, and WO3/CeO2 Catalysts by Operando Spectroscopy andDFT ͇ , The International Symposium on Environmental
Functional Materials and Catalysis, Nanjing Normal University㸦2023/10/31㸧. [Invited](9) Shimizu, K.: ͆ Computational, data science, andspectroscopic studies for design of heterogeneous catalysis͇,
KAIST CBE International Symposium on Catalysis, KAIST,
Daejeon, Korea㸦2023/11/3㸧. [Invited](10) Shimizu, K.: ͆ Computational, Data Science, andSpectroscopic Studies for Design of Heterogeneous Catalysis͇,
MANA International Symposium 2023 (Nanoarchitectonics
and Quantum Materials), NIMS, Tsukuba 㸦 2023/11/10 㸧 .
[Invited](11) Shimizu, K.: ͆ Computational, Data Science, andSpectroscopic Studies for Design of Heterogeneous Catalysis͇,International Symposium on Catalysis and Fine Chemicals(C&FC2023) will be held at Tokyo Metropolitan University㸦2023/12/4㸧. [Invited](12) 㫽ᒇᑿ㝯㸸ࠕࢹ࣮ࢱ㥑ືᆺᅛయゐ፹㛤Ⓨ࡜ᨺᑕගࢆ⏝࠸ࡓゐ፹స⏝ᶵᵓ◊✲ࠖ, ➨1ᅇ ඛ➃ᨺᑕගά⏝◊✲఍ᖺሗ࣭◊✲ᐊ⦅‫ە‬ࠕᨺᑕගࢆ⏝࠸ࡓゐ፹࢟ࣕࣛࢡࢱࣜࢮ࣮ࢩࣙࣥࡢ⌧ᅾ࡜ᮍ᮶ࠖ, ໭ᾏ㐨኱Ꮫ㸦2023/7/22㸧. [Invited](13) 㫽ᒇᑿ㝯㸸ࠕࢹ࣮ࢱ⛉Ꮫࢆ฼⏝ࡋࡓᅛయゐ፹㛤Ⓨࠖ, ➨132ᅇゐ፹ウㄽ఍, ໭ᾏ㐨኱Ꮫ㸦2023/9/15㸧. [Invited](14) 㫽ᒇᑿ㝯㸸ࠕᶵᲔᏛ⩦࡟ࡼࡿከඖ⣲ゐ፹ࡢ㛤Ⓨ࡜insitu/operandoศග࡟ࡼࡿస⏝ᶵᵓㄪᰝࠖ, ➨9ᅇSPring-8ඛ
➃ᨺᑕගᢏ⾡࡟ࡼࡿ໬Ꮫ࢖ࣀ࣮࣋ࢩࣙࣥ◊✲఍, ᮾி㸦2023/9/18㸧. [Invited](15) Toyao, T.: ͆Machine-learning-assisted discovery of multielemental RWGS catalyst and its mechanistic study using insitu/operando spectroscopies ͇ , Operando VII - the 7th‫ە‬ᖺሗ࣭◊✲ᐊ⦅International Congress on Operando Spectroscopy, Switzerland
㸦2023/5/8㸧. [Keynote](16) Toyao, T.: ͆ Data-driven catalyst design for CO2hydrogenation reactions ͇ , ICAT-FHI Symposium:
Approaching to the Catalysis Reality, Sapporo㸦2023/9/11㸧.
[Invited]
ཷ㈹
(1) ΎỈ◊୍㸸ࠕ཯ᛂᶵᵓゎᯒ࠾ࡼࡧᶵᲔᏛ⩦ࢆά⏝ࡋࡓ୙ᆒ୍⣔ゐ፹ࡢ㛤Ⓨࠖ᪥ᮏ໬Ꮫ఍㸦2024/3/19㸧ࠓ᪥ᮏ໬
Ꮫ఍➨ᅇᏛ⾡㈹ࠔ

45

ศᏊゐ፹◊✲㒊㛛/Molecular Catalyst
Research Divisionࢃࡏࡓゎᯒ࡟ࡼࡾ㸪཯ᛂᶵᵓࢆ᫂ࡽ࠿࡟ࡍࡿணᐃ࡛࠶ࡿ㸬‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒᾆཱྀ኱㍜࣭ࠑ෸ᩍᤵࠒὸ㔝ᆂభ࣭ࠑຓᩍࠒ㉿ᙉ࣭≉௵ᩍᤵ!᳿ⱥὒ>2023/7/10㹼2023/8/10@࣭ࠑ⏕࿨⛉Ꮫ㝔኱Ꮫ㝔༤ኈㄢ⛬ࠒᮧ⏣❳୍࣭ࠑ⏕࿨⛉Ꮫ㝔኱Ꮫ㝔ಟኈㄢ⛬ࠒᆏཱྀⳀஂྜྷ⏣ᴦே኱ሯ㝯㤿࣭ࠑ⸆Ꮫ㒊Ꮫ㒊Ꮫ⏕ࠒୗ⃝΅ụᮏᐇ⣪Ꮚ⋢⃝᪼ኴ⸨ᒸ㈼୍㑻㜿ஂὠኸ㹙 2023/10/01 㹼 㹛  ᒸ ⏣ ಇ ♸ 㹙 2023/10/01 㹼 㹛  ∦ ᒸ ஂ ៞㹙2023/10/01㹼㹛‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
 2023ᖺ3᭶࡟㛗㔝೔Ặࡀ༤ኈᚋᮇㄢ⛬ࢆಟ஢ࡋ㸪Ꮫ఩ࢆᤵ୚ࡉࢀࡓ2023ᖺ4᭶࡟ᮧ⏣❳୍Ặࡀ༤ኈᚋᮇㄢ⛬3ᖺ⏕࡬ᆏཱྀⳀஂẶ࠾ࡼࡧྜྷ⏣ᴦேẶࡀಟኈㄢ⛬2ᖺ⏕࡬㸬኱ሯ㝯㤿Ặࡀಟኈㄢ⛬㸯ᖺ⏕࡬㸬ụᮏᐇ⣪ᏊẶ࣭⋢⃝᪼ኴẶ࣭⸨ᒸ㈼୍㑻ẶࡀᏛ㒊ᖺ⏕࡬㸬2023ᖺ7᭶࠿ࡽ᳿ⱥὒඛ⏕㸦㤶 ୰ᩥ኱Ꮫ㸧ࡀ≉௵ᩍᤵ࡜ࡋ࡚ᙜ◊✲ᐊ࡟ࣨ᭶㛫⁫ᅾࡋࡓ㸬2023ᖺ10᭶࡟⸆Ꮫ㒊⸆⛉Ꮫ⛉3ᖺࡢ㜿ஂὠኸẶ࣭ᒸ⏣ಇ♸Ặ࣭∦ᒸஂ៞Ặࡀ◊✲ᐊ࡟ཧ⏬ࡋࡓ㸬

Fig. 1. N-Selective alkylation of indole under thephotocatalysis of a coordination saturated borenium salt.
2023ᖺᗘࡢࢺࣆࢵࢡ㸸ィ⟬⛉Ꮫⓗゎᯒ࡟ࡘ࠸࡚ᶓᕝ኱㍜෸ᩍᤵ㸦ᮾி኱Ꮫ㸧࡜ඹྠ◊✲ࢆ㛤ጞࡋࡓ㸬
2. ࢪ࢔࣮ࣜࣝ࣍ࢫࣇ࢕ࣥࢫࣝࣇ࢕ࢻࡢỈ⣲ཎᏊ౪୚ゐ፹⬟ࡢ๰ฟග㓟໬㑏ඖゐ፹⣔࡟࠾࠸࡚ࡣࡋࡤࡋࡤ㸪Ỉ⣲ཎᏊࡢᤵཷ
ࢆ፹௓ࡍࡿඹゐ፹㸦HATゐ፹㸧ࡢ㑅ᢥࡀ㸪཯ᛂࢆ෇⁥࡟㐍ࡵࡿࡓࡵ࡟㔜せ࡜࡞ࡿ㸬᪤Ꮡࡢ཯ᛂ⣔࡛ࡣ୺࡟㸪ࢳ࣮࢜ࣝ
㢮ࡀHATゐ፹࡜ࡋ࡚฼⏝ࡉࢀ࡚᮶ࡓ㸬ࡇࢀࡣ㸪ࢳ࣮࢜ࣝࡀ
୰⛬ᗘࡢ㓟ᛶᗘ࡜S-H⤖ྜ஋㞳࢚ࢿࣝࢠ࣮ࢆࡶࡕ㸪ඹᙺሷᇶ࡛࠶ࡿࢳ࣮࢜ࣛࢺ࢖࢜ࣥࡀ㐺ᗘ࡞㓟໬㑏ඖάᛶࢆ♧ࡍࡇ࡜࡟㉳ᅉࡍࡿ㸬ࡋ࠿ࡋ㸪ࢳ࣮࢜ࣝศᏊࡢᵓ㐀ⓗ࡞≉ᚩ࡟ࡼࡾ㸪ࣛࢪ࢝ࣝᛶࡢ཯ᛂ୰㛫య࡟Ỉ⣲ཎᏊࢆ౪୚ࡍࡿ㝿࡟ࡑࡢᵓ㐀᝟ሗࡀఏࢃࡽ࡞࠸࡜࠸࠺ၥ㢟ࡀ࠶ࡗࡓ㸬ᮏ◊✲࡛ࡣ㸪ࢳ࣮࢜ࣝ࡟㢮ఝࡋࡓ≀ᛶࢆഛ࠼ࡘࡘࡶᵓ㐀⮬⏤ᗘࡢ㧗࠸ࢪ࢔࣮ࣜࣝ࣍ࢫࣇ࢕ࣥࢫࣝࣇ࢕ࢻ࡟╔┠ࡋ㸪ࡑࡢHATゐ፹⬟ࡢ๰ฟ࡟ྲྀࡾ⤌ࢇࡔ㸬࣓ࢩࢳࣝ࢔ࢡࣜࢪࢽ࣒࢘ሷࢆග
ゐ፹࡜ࡍࡿ⎔≧࢚ࣥ࢝ࣝࣂ࣓࣮ࢺࡢࣄࢻࣟ࢔ࢭࢺ࢟ࢩ໬
཯ᛂࢆࣔࢹࣝ࡟᳨ウࢆ㔜ࡡࡓ⤖ᯝ㸪ᐇ㝿㸪㐺ษ࡞ᵓ㐀ࢆࡶࡘࢪ࢔࣮ࣜࣝ࣍ࢫࣇ࢕ࣥࢫࣝࣇ࢕ࢻࡀ᭷ຠ࡞HATゐ፹࡜ࡋ࡚ാࡃࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓ㸦Fig. 2㸧㸬ࡲࡓ㸪ࢪ࢔ࢫࢸࣞ
࣐࣮࢜ΰྜ≀ࡀ⏕ࡌࡿศᏊࢆᇶ㉁࡜ࡋࡓሙྜ࡟㸪᪤Ꮡࡢࢳ࣮࢜ࣝࢆ⏝࠸ࡿ཯ᛂ࡜ࡣ㏫ࡢ㑅ᢥᛶࢆⓎ⌧ࡍࡿࡇ࡜ࢆぢ࠸ࡔࡋࡓ㸬HATゐ፹࡟ࡼࡿග㓟໬㑏ඖ཯ᛂࡢ❧యไᚚࡢ౛
ࡀ㠀ᖖ࡟㝈ࡽࢀ࡚࠸ࡿ୰࡛㸪ᮏゐ፹⣔࡛㧗࠸㑅ᢥᛶࡀⓎ⌧ࡋࡓࡇ࡜ࡢྜᡂ໬Ꮫⓗ౯್ࡣ᫂☜࡛࠶ࡿ㸬୍᪉࡛㸪㑅ᢥᛶࡢ㉳※࡟ࡘ࠸࡚ࡣᐇ㦂໬Ꮫⓗ࡟᳨ドࡍࡿࡇ࡜ࡀᅔ㞴࡛࠶ࡾ㸪௒ᚋ㸪㔞Ꮚ⛉Ꮫィ⟬࡟ࡼࡿゎᯒࢆ㐍ࡵࡿᚲせࡀ࠶ࡿ㸬‫✲◊ڦ‬ㄢ㢟
1. ගゐ፹άᛶࢆഛ࠼ࡓ㓄఩㣬࿴࣎ࣞࢽ࣒࢘ሷࡢ๰〇ගゐ፹ࢆ⏝࠸ࡿ᪂ࡓ࡞᭷ᶵྜᡂ཯ᛂࡢ㛤Ⓨ◊✲࡟ὀ┠ࡀ㞟ࡲࡿ୍᪉㸪ࡑࡢ཯ᛂࡢゐ፹ⓗไᚚ࡬ࡢヨࡳࡣ㞴ࡋ࠸ㄢ㢟࡜ࡋ࡚ṧࡉࢀ࡚࠸ࡿ㸬ࡇࢀࡣ㸪ࣛࢪ࢝ࣝ✀࡞࡝ࡢ཯ᛂάᛶ✀࡜ゐ፹ศᏊ࡜ࡢ㛫࡟┦஫స⏝ࡀ࡞࠸ሙྜࡀከࡃ㸪ᇶ㉁ࡀᮏ᮶ⓗ࡟ࡶࡘᛶ㉁ࢆ཯ᫎࡋࡓ㑅ᢥᛶ࡛཯ᛂࡀ㐍⾜ࡋࡸࡍ࠸ࡇ࡜࡟㉳ᅉࡍࡿ㸬ᡃࠎࡣ㸪ᇶ㉁࡜ゐ፹ࡀ⤖ྜᙧᡂẁ㝵࡟࠾࠸࡚┦஫స⏝ࡍࡿࢩࢫࢸ࣒ࡢᵓ⠏ࢆᛕ㢌࡟㸪᪂ࡓ࡞ගゐ፹࡜ࡋ࡚㓄఩㣬࿴ᆺ࣎ࣞࢽ࣒࢘ሷࡢ๰〇࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿ㸬ᮏᖺᗘࡣ㸪᭷ᶵ⺯ගⰍ⣲࡜ࡋ࡚ỗ⏝ࡉࢀࡿBODIPY࠾ࡼࡧ㢮⦕యࡢᵓ㐀ࢆཧ⪃࡟ࡋࡓࢫࣆࣟᆺ࣎ࣞࢽ࣒࢘ሷ
ࢆタィ࣭ྜᡂࡋ㸪ࡑࡢගゐ፹⬟ࢆ฼⏝ࡋࡓ᪂ࡓ࡞ศᏊኚ᥮
࡜ࡋ࡚㸪࢖ࣥࢻ࣮ࣝࡢ❅⣲㑅ᢥⓗ࢔ࣝ࢟ࣝ໬཯ᛂࢆᐇ⌧ࡋࡓ㸦Fig. 1㸧
㸬࢖ࣥࢻ࣮ࣝࡣ㸪᪤Ꮡࡢồ᰾ⓗ཯ᛂ⣔࡟࠾࠸࡚
3఩Ⅳ⣲ୖ࡛ࡢࡳ཯ᛂࡍࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠾ࡾ㸪๓౛ࡢ࡞࠸ᣲືࢆ♧ࡍゐ፹⣔ࢆぢฟࡋࡓࡇ࡜࡟࡞ࡿ㸬௒ࡢ࡜ࡇࢁ཯
ᛂᶵᵓࡢヲ⣽ࡣ୙࡛᫂࠶ࡿࡀ㸪ග↷ᑕ࠾ࡼࡧ࣎ࣞࢽ࣒࢘ሷ
ࡢῧຍࡣᚲ㡲࡛࠶ࡿࡇ࡜㸪᪤Ꮡࡢගゐ፹࡛ࡣ཯ᛂຠ⋡ࡀⴭࡋࡃపୗࡍࡿࡇ࡜㸪ࡀ᪤࡟᫂ࡽ࠿࡟࡞ࡗ࡚࠾ࡾ㸪ᮏゐ፹⣔࡟≉ᚩⓗ࡞ග཯ᛂ⣔࡛࠶ࡿࡇ࡜ࡀᙉࡃ♧၀ࡉࢀ࡚࠸ࡿ㸬ḟᖺᗘ௨㝆㸪ィ⟬⛉Ꮫⓗᡭἲ࡜ศග≀⌮⛉Ꮫⓗᡭἲࢆ⤌ࡳྜ

4646

Fig. 2. Diarylphosphinesulfide-mediated, diastereoselective
phtocatalytic hydroacetoxylation of cyclic enecarbamates.
2023ᖺᗘࡢࢺࣆࢵࢡ㸸ィ⟬⛉Ꮫⓗゎᯒ࡟ࡘ࠸࡚໭ᾏ㐨኱Ꮫ໬Ꮫ཯ᛂ๰ᡂ◊✲ᣐⅬ㸦WPI-ICReDD㸧࡜ඹྠ◊✲ࢆ㛤ጞࡋࡓ㸬
3. Ⅳ⣲–Ⅳ⣲஧㔜⤖ྜࡢ᭷ᶵゐ፹ᶵ⬟㛤ᣅ⏕య㐺ྜ໬Ꮫ཯ᛂࡢ㛤Ⓨࡣ⏕࿨⛉Ꮫ◊✲ࡢ㐍ᒎ࡟኱ࡁࡃ㈉⊩ࡋ㸪2022ᖺࡢࣀ࣮࣋ࣝ໬Ꮫ㈹ࡀࢡࣜࢵࢡࢣ࣑ࢫࢺࣜ ࣮ ࡜ ⏕ య ┤ ஺ ཯ ᛂ ࡟ 㛵 ࡍ ࡿ ᴗ ⦼ ࡟ ᑐ ࡋ ࡚ Bertozzi 㸪Meldal㸪Sharpless࡟୚࠼ࡽࢀࡓࡇ࡜ࡣグ᠈࡟᪂ࡋ࠸㸬௦⾲ⓗ࡞ࢡࣜࢵࢡ཯ᛂ࡜ࡋ࡚㸪࢔ࣝ࢟ࣥ࡜࢔ࢪࢻ࡟ࡼࡿ
Huisgen⎔໬཯ᛂࡸ࢔ࣝࢣࣥ࡜ࢸࢺࣛࢪࣥ࡟ࡼࡿ㏫㟁ᏊせㄳᆺDiels–Alder཯ᛂࡀ࠶ࡾ㸪ࡇࢀࡽࡢ฼Ⅼࡣ㸪཯ᛂࡀ㏿࠸ࡇ࡜ࡸ཰⋡ࡀ㧗࠸ࡇ࡜࡟ຍ࠼࡚㸪໬Ꮫ㑅ᢥᛶࡀ㧗࠸ࡇ࡜࡟࠶ࡿ㸬ࡲࡓ㸪๪཯ᛂࡀᑡ࡞ࡃᇶ㉁㸭⏕ᡂ≀ࡢẘᛶࡀప࠸ࡇ
࡜ࡣ⏕య㐺ྜᛶ࡟ࡶࡘ࡞ࡀࡿ㸬ࡇࡢࡼ࠺࡟࢔ࣝ࢟ࣥࡸ࢔ࣝ
ࢣࣥ࡞࡝ࡢⅣ⣲–Ⅳ⣲୙㣬࿴⤖ྜࢆᣢࡘศᏊࡀ཯ᛂࢱࢢ࡜

ᖺሗ࣭◊✲ᐊ⦅‫ە‬ࡋ࡚⏕య㐺ྜ໬Ꮫ཯ᛂ࡟㢖⦾࡟฼⏝ࡉࢀࡿ⌮⏤ࡣࡑࡢ㌾ࡽ࠿࠸཯ᛂᛶ࡟࠶ࡿ࡜⪃࠼ࡽࢀ㸪ᵝࠎ࡞ᐁ⬟ᇶࡀΰᅾࡍࡿ
ዃ㞧⣔࡟࠾࠸࡚ࡶ๪཯ᛂࢆ㉳ࡇࡋ࡟ࡃ࠸࡜࠸࠺㛗ᡤࡀ࠶ࡿ㸬ࡍ࡞ࢃࡕ㸪࢔࣑ࣥࡸ࢔ࣝࢥ࣮ࣝ㸪Ỉ㸪ࣉࣟࢺࣥ࡞࡝㸪⏕యศᏊࡸ⏕య⎔ቃ࡟ྵࡲࢀࡿᐁ⬟ᇶࡢ኱㒊ศࡣ◳࠸཯ᛂᛶࢆ♧ࡋ㸪ࡇࢀࡽ࡟ᑐࡋ࡚⪏ᛶࢆᚓࡿࡓࡵ࡟㸪㌾ࡽ࠿࠸ᐁ⬟ᇶ࡟↔Ⅼࢆᙜ࡚࡚཯ᛂࢆタィࡍࡿࡇ࡜ࡣྜ⌮ⓗ࡛࠶ࡿ㸬ࡋ࠿ࡋ㸪ከࡃࡢ཯ᛂࢱࢢࡀ㛤Ⓨࡉࢀ࡚ࡁࡓ୍᪉࡛㸪ࡇࡢ⪃࠼࡟ᇶ࡙ࡃゐ፹໬ᏛࡣⓎᒎࡋ࡚࠸࡞࠿ࡗࡓ㸬ࡑࡇ࡛ᡃࠎࡣ㸪࢔ࣝࢣࣥࡀᣢࡘ㌾ࡽ࠿࠸཯ᛂᛶࢆ฼⏝ࡋࡓ᭷ᶵゐ፹ࢆ㛤Ⓨࡍࡿࡇ࡜ࡀ࡛ࡁࢀࡤ㸪⏕య㐺ྜ໬Ꮫ࡟࠾࠸࡚᪂ࡋ
࠸ศ㔝ࢆ㛤ᣅ࡛ࡁࡿ࡜⪃࠼㸪⮯⣲໬཯ᛂࢆ฼⏝ࡋࡓᶆ㆑ἲ
ࡢ㛤Ⓨࢆ㐍ࡵ࡚࠸ࡿ㸦Fig. 3㸧㸬ࣔࢽ࣒࢘ሷ࡜ࡢ཯ᛂࠖ/ி㒔኱Ꮫ㸦ி㒔㸧ᯇཎㄔ஧㑻ᩍᤵ
ࠕⅣ⣲–Ⅳ⣲஧㔜⤖ྜࡢ᭷ᶵゐ፹ᶵ⬟㛤ᣅࠖ/஑ᕞ኱Ꮫ㸦⚟ᒸ㸧ᇼ㞝୍㑻ᩍᤵࠕ⣽⬊⭷ࢱࣥࣃࢡ㉁࡟࠾ࡅࡿ㏆᥋⮯⣲໬ᶆ㆑ἲࡢ㛤Ⓨࠖ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ㸦Ⲉᇛ㸧⏕㛗ᖾஅຓ◊✲ࢳ࣮࣒㛗ࠕගゐ፹ⓗࢺࣜࣉࢺࣇ࢓ࣥಟ㣭ࡢࡓࡵࡢ཯ᛂ๣
㛤Ⓨࠖ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ㸦Ⲉᇛ㸧ୖ⏣ၿᘯ୺௵◊✲ဨࠕගゐ፹ⓗࢳࣟࢩࣥ⮯⣲໬཯ᛂࡢᶵᵓゎ᫂ࠖ/኱㜰኱Ꮫ㸦኱㜰㸧┿㘠Ⰻᖾຓᩍࠕ㠀ኳ↛⢾ࢱࣥࣃࢡ㉁ྜᡂἲࡢ㛤Ⓨࠖ/❧ᩍ኱Ꮫ㸦ᮾி㸧ᒣ୰ṇᾈᩍᤵࠕィ⟬໬Ꮫ࡟ࡼࡿࢩࢡࣟ࢜ࢡࢸࣥゐ፹཯ᛂࡢᶵᵓゎᯒࠖ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦ࡍ࡭࡚ᑂᰝ௜ࡁ㸧(1) Murata, R.; Shitamichi, K.; Hiramatsu, M.; Matsubara, S.;
Uraguchi, D.; Asano, K. trans-Cyclooctenes as Scavengers ofBromine Involved in Catalytic Bromination. Chem.—Eur. J.,
2024, 30, e202303399.
⥲ㄝ/ゎㄝ/ሗ࿌(1) ᾆཱྀ኱㍜, ࣛࢪ࢝ࣝ࢖࢜ࣥࡢゐ፹ⓗ❧యไᚚ. ໬Ꮫ࡜ᩍ⫱, 2023, 71, 392-395.

Fig. 3. Bromination labeling of biomolecules based onorganocatalysis of alkenes.

2023ᖺᗘࡢࢺࣆࢵࢡ㸸ࢩࢡࣟ࢜ࢡࢸࣥㄏᑟయࡀ⮯⣲໬཯ᛂࡢ㧗άᛶゐ፹࡟࡞ࡾ㸪࢜ࣞࣇ࢕ࣥ㒊఩ࡢ⨨᥮ᇶࡀゐ፹άᛶ࡟኱ࡁࡃᙳ㡪ࡍࡿࡇ࡜ࢆ᪤࡟ぢ࠸ࡔࡋ࡚࠸ࡓ㸬2023ᖺᗘࡣ㸪ࡉࡽ࡟㧗ᶵ⬟࡞ゐ፹ࢆ㛤Ⓨࡍࡿࡓࡵࡢᇶ┙࡟࡞ࡿ⨨᥮ࢩࢡࣟ࢜ࢡࢸࣥྜᡂἲ࡜ࡋ࡚㸪ࢡࣟࢫ࢝ࢵࣉࣜࣥࢢ཯ᛂࢆ
฼⏝ࡍࡿ᪉ἲࢆ㛤Ⓨࡋࡓ㸬ࡲࡓ㸪⨨᥮ࢩࢡࣟ࢜ࢡࢸࣥࢆ฼
⏝ࡋ࡚Br2ᤕᤊ๣ࢆ㛤Ⓨࡋ㸪⮯⣲໬ゐ፹⣔ࡢ㛤Ⓨ࡟ᚲせ࡞ᶵᵓゎᯒࢶ࣮ࣝ࡟࡞ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓ㸬ࠓㄽᩥ1࣭ཷ㈹2ࠔ‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧㛗ᓮ኱Ꮫ㸦㛗ᓮ㸧ⓑᕝㄔྖ෸ᩍᤵ㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ㸦Ⲉᇛ㸧Ọ⦖཭つ୺௵◊✲ဨ㸪኱㜰බ❧኱㸦኱㜰㸧⏣ᮧṇ⣧෸ᩍᤵࠕ⢭ᐦタィゐ፹཯ᛂࢆ㥑౑ࡋࡓ஧㓟໬Ⅳ⣲ࡢ㧗ᗘ≀㉁ኚ᥮ࠖ/᪂₲኱㸦᪂₲㸧⏣ᒣⱥ἞෸ᩍᤵࠕࣅࢫ࢘ࣞ࢔᭷ᶵゐ፹࡟ࡼࡿ࢟ࣛࣝࣇࢵ໬≀࢖࢜ࣥࡢⓎ⏕࠾ࡼࡧ➨ᅄ⣭࢔ࣥ‫ە‬ᖺሗ࣭◊✲ᐊ⦅ⴭ᭩(1) ᾆཱྀ኱㍜, ᭷ᶵ࢖࢜ࣥᑐࡢゐ፹໬Ꮫ. ᭷ᶵ໬Ꮫ࢖ࣀ
࣮࣋ࢩࣙࣥ, ᒣᮏᑦ⦅, ᮾி໬Ꮫྠே, 2023, 97–109.
ᣍᚅ/ᇶㄪ/౫㢗ㅮ₇࣭ᅜ㝿఍㆟(1) ᾆཱྀ኱㍜㸸ࠕศᏊෆ࢖࢜ࣥᑐᆺ᭷ᶵศᏊゐ፹ࡢ๰〇࡜ᶵ⬟ࠖ㸪➨54ᅇᵓ㐀᭷ᶵ໬Ꮫⱝᡭࡢ఍ ኟࡢᏛᰯ㸪ᮐᖠ
㸦2023/08/02㸧.㹙ᣍᚅㅮ₇㹛(2) ὸ㔝ᆂభ㸸ࠕ㑅ᢥⓗゐ፹཯ᛂ✵㛫ࢆᣑᙇࡍࡿ཯ᛂࢶ࣮ࣝࡢ๰〇ࠖ㸪Ꮫ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓ㸦IRCCS㸧ᡂᯝሗ࿌఍࣭⏘Ꮫ࣮࣡ࢡࢩࣙࢵࣉ㸪஑ᕞ኱Ꮫ㸦2024/01/30㸧.㹙ᣍᚅㅮ₇㹛
ཷ㈹
(1) ྜྷ⏣ᴦே㸸ࠕ⏕య㐺ྜ໬Ꮫࢆᣦྥࡋࡓ⮯⣲໬๣BODNࡢ
㛤Ⓨࠖ㸪➨35ᅇ୓᭷ᮐᖠࢩ࣏ࣥࢪ࣒࢘㸦2023/07/01㸧
ࠓBest
Poster㈹ࠔ
(2) ᮧ⏣❳୍㸸ࠕゐ፹཯ᛂࡢࣂࢵࢡࢢࣛ࢘ࣥࢻ⤒㊰ࢆᢚไࡍࡿῧຍ๣ࡢ㛤Ⓨࠖ㸪➨9ᅇ໭኱࣭㒊ᒁᶓ᩿ࢩ࣏ࣥࢪ࣒࢘
㸦2023/10/11㸧ࠓ࣋ࢫࢺ࣏ࢫࢱ࣮㈹ࠔ

47

㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛/ Macromolecular
Science Research Division ‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒ୰㔝 ⎔࣭ࠑ෸ᩍᤵࠒZhiyi SONG࣭ࠑຓᩍࠒᆏᮾ
ṇె࣭ࠑ◊✲ဨࠒPengfei WU㹙2023/4/1㹼2023/6/30㹛࣭⡿἟㑈㹙2024/1/5㹼2024/1/19㹛ࠑ/ ⥲ྜ໬Ꮫ㝔/኱Ꮫ㝔ಟኈㄢ⛬ࠒ
Weiben DUࠑ◊✲⏕ࠒ/
Jiaying GUO㹙2023/11/15㹼2024/1/15㹛
ࠑ஦ົ⿵ຓဨࠒྜྷᮧ෇

ᮦᩱࡢ㛤Ⓨ࡬࡜⧅ࡆࡿ◊✲ࢆ⾜ࡗ࡚࠸ࡿ㸬
ࠓㅮ₇1ࠔ
2㸬ࡽࡏࢇᵓ㐀ࢆ᭷ࡍࡿ㧗ศᏊ ࡽࡏࢇᵓ㐀ࡣኳ↛ࡢ㧗ศᏊ࡟ࡋࡤࡋࡤぢࡽࢀࡿ୙ᩧᵓ
㐀࡛࠶ࡿ㸬ࡽࡏࢇ࡟ࡣྑᕳࡁ࡜ᕥᕳࡁࡢ㙾ീయࡀ࠶ࡾ㸪࡝ࡕࡽ࠿୍᪉ࢆ㑅ᢥⓗ࡟ྜᡂࡍࡿ࡜ගᏛάᛶ㧗ศᏊࢆᚓࡿ
ࡇ࡜ࡀ࡛ࡁࡿ㸬ගᏛάᛶࡽࡏࢇ≧㧗ศᏊࡣ㸪་⸆ရࡢศ㞳Fig.1.

‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
 2023ᖺ4᭶࡟Weiben DUẶࡀಟኈㄢ⛬㸯ᖺ⏕࡬㐍Ꮫࡋࡓ㸬2023ᖺ4᭶1᪥-5᭶31᪥ࡢᮇ㛫࡟Pengfei WU༤ኈ㸦Purdue኱Ꮫ㸧ࡀ◊✲ဨ࡜ࡋ࡚㸪2024ᖺ1᭶5᪥-2024ᖺ1᭶19ࡢᮇ㛫࡟◊✲ဨ࡜ࡋ࡚⡿἟㑈Ặ㸦ᒣᙧ኱Ꮫ㸧㸪ࡲࡓ㸪2023ᖺ11᭶
15᪥-2024ᖺ1᭶15᪥ࡢᮇ㛫࡟◊✲⏕࡜ࡋ࡚Jiaying GUOẶ㸦⸽ᕞ኱Ꮫ㸧ࡀᅾ⡠ࡋࡓ㸬ᶵ⬟㸪୙ᩧゐ፹ᶵ⬟㸪㠀⥺ᙧගᏛ≉ᛶ࡞࡝㸪ᵝࠎ࡞࢟ࣛࣝ
ᶵ⬟ࢆⓎ⌧ࡍࡿᴟࡵ࡚᭷⏝࡞≀㉁࡛࠶ࡿ㸬ࡇࡢࡓࡵ㸪ᖜᗈ࠸໬Ꮫᵓ㐀ࢆ᭷ࡍࡿ㧗ศᏊ࡟ᑐࡍࡿࡽࡏࢇᵓ㐀ไᚚࡣ㸪㧗ศᏊ❧యᏛࡢᇶ♏ⓗ࡞❧ሙ࠿ࡽ⯆࿡῝࠸ࡔࡅ࡛ࡣ࡞ࡃ㸪௜ຍ౯್ࡢ㧗࠸≀㉁๰ᡂࡢほⅬ࠿ࡽ㔜せ࡞ㄢ㢟࡛࠶ࡿ㸬⚾㐩ࡣ㸪✀ࠎࡢேᕤ㧗ศᏊ࡟ᑐࡋ࡚ࡽࡏࢇᵓ㐀ไᚚࢆ⾜ࡗ࡚࠸ࡿ㸬ࠓㅮ₇1,2㸪ㄽᩥ1㸫4ࠔ‫✲◊ڦ‬ㄢ㢟 ඛ➃ᶵ⬟ࢆ᭷ࡍࡿ㧗ศᏊᮦᩱࡢ㛤Ⓨࢆ┠ᣦࡋ࡚㸪㧗ศᏊ໬ྜ≀ࡢタィ࡜ྜᡂࢆ⾜ࡗ࡚࠸ࡿ㸬㧗ศᏊᮦᩱࡢ≀ᛶ࣭ᶵ⬟ࡣ㸪ཎᩱ࡛࠶ࡿ㧗ศᏊ㙐ࡢ໬Ꮫᵓ㐀࠾ࡼࡧ❧యᵓ㐀࡟ᙉࡃ౫Ꮡࡍࡿࡓࡵ㸪ࡇࢀࡽᵓ㐀ࡢ⢭ᐦ࡞ไᚚ࡜ゎᯒࡀ㔜せ࡛࠶ࡿ㸬ࡇࡢほⅬ࠿ࡽ㸪⚾㐩ࡣ✀ࠎࡢ≉ᚩⓗᵓ㐀ࢆ᭷ࡍࡿ㧗ศᏊࢆྜᡂࡋ࡚࠸ࡿ㸬ຍ࠼࡚㸪᭱㏆㉸ศᏊᮦᩱ㛤Ⓨ࡟ࡶ╔ᡭࡋࡓ㸬ࡇࢀࡽࡢྲྀࡾ⤌ࡳࢆ㏻ࡌ㸪ᵓ㐀࡜≀ᛶࡢ┦㛵ࢆ᫂ࡽ࠿࡟ࡋ㸪㧗ᗘ࡞ᶵ⬟ࢆ♧ࡍ㧗ศᏊ࣭㉸ศᏊᮦᩱࢆ๰ฟࡋ
ࡓ࠸࡜⪃࠼࡚࠸ࡿ㸬1㸬㸬π-ࢫࢱࢵࢡᆺ࣭π㟁Ꮚ㞟✚ᆺ㧗ศᏊ π㟁Ꮚ⣔ࡀつ๎ṇࡋࡃ✚ᒙࡋࡓᵓ㐀ࢆ᭷ࡍࡿ㧗ศᏊࢆࠕπ-ࢫࢱࢵࢡᆺ㧗ศᏊࠖ࡜࿧ࡪ㸬π-ࢫࢱࢵࢡᆺ㧗ศᏊ࡟ࡣ㸪✚ᒙࡋࡓπ㟁Ꮚ⣔࡟ᇶ࡙ࡃ㟁Ꮚ≀ᛶࡀᮇᚅࡉࢀࡿ㸬 ⚾㐩ࡣ㸪ᮦᩱ࡜ࡋ࡚ࡢᛂ⏝ࡀࡋࡸࡍ࠸π-ࢫࢱࢵࢡᆺ㧗ศᏊࢆ┠ᣦࡋ࡚㸪㧗ศᏊࡢ୰࡛ࡶࡗ࡜ࡶỗ⏝ᛶࡀ㧗࠸ࣅࢽ࣏࣐࣮ࣝࣜࡢᵓ㐀ไᚚࢆ⾜࠸㸪᭱ึࡢπ-ࢫࢱࢵࢡᆺࣅࢽ࣏ࣝ
࣐࣮࡛ࣜ࠶ࡿ࣏ࣜࢪ࣋ࣥࢰࣇࣝ࣋ࣥ㸦poly㸦DBF㸧㸧ࡢྜᡂ࡟ᡂຌࡋࡓ(Fig.1)㸬DBFࣔࣀ࣐࣮ࡣ㸪࠿ࡉ㧗࠸ᵓ㐀࡟ࡶ࠿࠿ࢃࡽࡎࢫࢳࣞࣥࡸ࢔ࢡࣜࣝ⣔ࣔࣀ࣐࣮࡞࡝ࡼࡾ㐶࠿࡟཯ᛂᛶࡀ㧗ࡃ㸪࢔ࢽ࢜ࣥ㔜ྜ㸪ࣛࢪ࢝ࣝ㔜ྜ㸪࢝ࢳ࢜ࣥ㔜ྜࡢ࠸ࡎࢀࡢ᪉ἲ࡛ࡶπ-ࢫࢱࢵࢡᆺ㧗ศᏊࢆ୚࠼ࡿ㸬ᙜ◊✲ᐊ࡛ࡣ㸪ᵝࠎ࡞π-ࢫࢱࢵࢡᆺ㧗ศᏊࡢᵓ㐀タィࢆ⾜ࡗ࡚࠾ࡾ㸪ᵝࠎ࡞ᶵ⬟ࡢⓎ⌧࡟ࡘ࠸᳨࡚ウࡋ࡚࠸ࡿ㸬㟁Ꮚᶵ⬟ࡣ㸪ᚑ᮶㸪୺㙐ඹᙺᆺ㧗ศᏊࢆ⏝࠸࡚◊✲ࡉࢀ࡚ࡁࡓࡀ㸪୺㙐ඹᙺᆺ㧗ศᏊࡣᮏ㉁ⓗ࡟⁐ゎࡋ㞴ࡃᙉࡃ╔Ⰽࡋ࡚࠸ࡿ㸬π-ࢫࢱࢵࢡᆺࣅࢽ࣏࣐࣮ࣝࣜࡣࡇࢀࡽࡢᙅⅬࢆඞ᭹ࡍࡿ㧗ศᏊᮦᩱ࡜ࡋ࡚ᮇᚅࡉࢀࡿ㸬᭱㏆㸪poly㸦DBF㸧㙐ࢆࣈࣟࢵࢡඹ㔜ྜయࡢࢭࢢ࣓ࣥࢺ࡜ࡋ࡚ᵓ⠏ࡋ㸪᪂つ㧗ศᏊ

4848



Fig.2. ෇೫ගⓎගᶵ⬟࠾ࡼࡧ୙ᩧ㆑ูᶵ⬟ࢆ♧ࡍࡽࡽࡏࢇ≧≧࣏ࣜ(p-ࣇࣇ࢙ࢽࣞࣥ)ㄏ
ㄏᑟయ୍౛࡜ࡋ࡚ഃ㙐࡟࢟ࣛࣝ࡞⨨᥮ᇶཬࡧ࠿ࡉ㧗࠸⨨᥮ᇶࢆ᭷ࡍࡿ࣏ࣜ(p-ࣇ࢙ࢽࣞࣥ)ㄏᑟయࢆ⣔⤫ⓗ࡟ྜᡂࡋ㸪୍᪉ྥᕳࡁࡢࡽࡏࢇᵓ㐀ࡢᙧᡂ࡟ཬࡰࡍ㧗ศᏊࡢᵓ㐀࡟ࡘࡘ࠸࡚ࡢヲ⣽࡞▱ぢࢆᚓࡓ㸬࣏ࣜ(p-ࣇ࢙ࢽࣞࣥ)ㄏᑟయࡣ
⁐ᾮ୰࡛ࡣᏳᐃ࡞ࢥ࣓࣮ࣥ࣍ࢩࣙࣥࢆᣢࡓ࡞࠸ࡀ㸪ᅛయⷧ⭷୰࡛ࡣ୍᪉ྥᕳࡁࡢࡽࡏࢇᵓ㐀ࢆᙧᡂࡋ㸪ᴫࡡࡼࡾ࠿ࡉ
㧗࠸ഃ㙐ᇶࢆ᭷ࡍࡿ㧗ศᏊࡀࡼࡾ㧗࠸ᕥྑࡢ೫ࡾࢆ᭷ࡍ
ࡿࡽࡏࢇᵓ㐀ࢆᙧᡂࡍࡿ㸬࠿ࡉ㧗࠸ࣔࣀ࣐࣮༢఩࡜࢟ࣛࣝ
࡞ࣔࣀ࣐࣮༢఩ࡀࣛࣥࢲ࣒࡟୪ࢇࡔ㧗ศᏊ࠾ࡼࡧ஺஫࡟
୪ࢇࡔ㧗ศᏊࢆྜᡂࡋ㸪ࣔࣀ࣐࣮㓄ิࡀࡽࡏࢇᵓ㐀ᙧᡂ࡟ᙳ㡪ࡍࡿࡇ࡜ࡶ᫂ࡽ࠿࡟ࡋࡓ㸬஺஫ඹ㔜ྜయ࡟ࡘ࠸࡚ࡣ㸪ศᏊືຊᏛィ⟬ࡼࡾ✀ࠎࡢྍ⬟࡞ࢥ࣓࣮ࣥ࣍ࢩࣙࣥࡢ୰
࡛ᕥᕳࡁࡽࡏࢇᵓ㐀ࡀࡼࡾᏳᐃ࡛࠶ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓ㸬ࡉࡽ࡟㸪ᅛయ୰࡛ࡽࡏࢇᵓ㐀ࢆㄏ㉳ࡋࡓ㧗ศᏊࡣࢫࢳࣝ
࣋ࣥ࢜࢟ࢩࢻ㸪ࢺ࣮ࣞ࢞ሷᇶ㸪ࣇࣛࣂࣀࣥ࡟ᑐࡋ࡚୙ᩧ㆑
ู⬟ࢆࡋ㸪ຍ࠼࡚㸪㧗ຠ⋡࡞෇೫ගⓎගࢆ♧ࡍࡶࡢࡀ࠶ࡿ
ࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓ㸬࣏ࣜ(p-ࣇ࢙ࢽࣞࣥ)ㄏᑟయࡣᑟ㟁ᛶ㧗ศᏊࡢ௦⾲ⓗ࡞ࡶࡢࡔࡀ㸪ࡇࢀࡲ࡛ࡽࡏࢇᵓ㐀ᙧᡂ࠾ࡼࡧࡽࡏࢇ࡟ᇶ࡙ࡃᶵ⬟ࢆ⣔⤫ⓗ࡟◊✲ࡋࡓ౛ࡣ↓࠿ࡗࡓ㸬ᮏ◊✲ࡢᡂᯝࢆᇶ♏࡜ࡋ࡚㸪ࡼࡾᖜᗈ࠸ඹᙺᆺ㧗ศᏊࡢࡽࡏࢇᙧᡂ࡟ࡘ࠸᳨࡚ウࢆ⾜ࡗ࡚࠸ࡿ㸬ࠓㄽᩥ3ࠔᖺሗ࣭◊✲ᐊ⦅‫ە‬

3. ග࡛ࡽࡏࢇࢆసࡿ㹼ග࡟ࡼࡿ㧗ศᏊࡢᵓ㐀ኚ໬㹼 ୙ᩧ࢔ࢽ࢜ࣥ㔜ྜ࡟ࡼࡾྜᡂࡋࡓ୍᪉ྥᕳࡢࡽࡏࢇᵓ
㐀ࢆ᭷ࡍࡿPoly(BBPFA)ࡣ⇕่⃭࡟ᑐࡋ࡚ࡣᏳᐃࡔࡀ㸪ග㸦㠀೫ග㸧࡟ࡼࡾࡽࡏࢇ཯㌿ࢆ㉳ࡇࡍ㸬ᚑ᮶㸪ග࡛໬ྜ≀ࡢᵓ㐀ኚ໬ࢆ㉳ࡇࡍ࡟ࡣࣇ࢛ࢺࢡ࣑ࣟࢵࢡᇶࡀᚲせ࡜⪃࠼ࡽࢀ࡚ࡁࡓࡀ㸪Poly(BBPFA)ࡣࣇ࢛ࢺࢡ࣑ࣟࢵࢡᇶᣢࡓ
ࡎ㸪ගᵓ㐀㌿⛣ࡣഃ㙐ࣅࣇ࢙ࢽࣝṧᇶࡢࠕࡡࡌࢀ࣭ඹᖹ㠃㌿⛣ࠖ࡟ᇶ࡙ࡃ㸦Fig.3㸧
㸬ࡽࡏࢇ㌿⛣ࡣ㙐ࡢ➃࠿ࡽ㛤ጞࡋ㸪ᕥྑࡽࡏࢇࢆ⧅ࡄkinkࡀ㙐࡟ἢࡗ࡚⛣ືࡋ࡚཯ᑐࡢᮎ➃࡟⮳ࡗ࡚ࡽࡏࢇ཯㌿ࡀ᏶஢ࡍࡿࡇ࡜ࡀ㸪ࡽࡏࢇ㌿⛣ࡢヲ⣽࡟ࡘ࠸࡚㸪࢝ࢱࣥࢨࣟ኱Pietropaolo෸ᩍᤵ࡜ࡢඹྠ◊✲ࢆ
㏻ࡌࡓ኱つᶍ࡞࣓ࢱࢲ࢖ࢼ࣑ࢡࢫࢩ࣑࣮ࣗࣞࢩࣙࣥ࡟ࡼ
ࡾ♧ࡉࢀ࡚࠸ࡿ㸦Fig.4㸧㸬
ࠓㅮ₇1,2ࠔ



ZͲW>

>ͲW>

WͲ,Ğůŝǆ

ZĂŶĚŽŵ;ƌĂĐĞŵŝĐͿ

>ͲW>

ZͲW>

DͲ,Ğůŝǆ

Fig.5㸬ග࡟ࡼࡿࡽࡏࢇࡢࢫ࢖ࢵࢳࣥࢢ

 ௨ୖ࡟ຍ࠼࡚㸪㧗ศᏊゐ፹㸪㧗ศᏊ་⸆ရ࡟㛵ࡍࡿ◊✲ࡶ⾜ࡗ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸ᯞศ࠿ࢀᆺගᏛάᛶ࣏ࣜࣇࣝ࢜ࣞࣥ
ࣅࢽࣞࣥㄏᑟయࡢྜᡂ㸪ᵓ㐀㸪≉ᛶ࡟ࡘ࠸᳨࡚ウࡋ㸪ࡇࡢ㧗ศᏊࡀⓎගᛶࡢ࢔࢟ࣛࣝ࡞పศᏊ໬ྜ≀࡜」ྜయࢆᙧᡂࡋ㸪ᴟࡵ࡚㧗࠸ຠ⋡ࡢ෇೫ගⓎගࢆ♧ࡍࡇ࡜ࢆぢฟࡋࡓ(Fig. 6)㸬ග࡟ࡼࡿࡽࡏࢇ཯㌿

Fig.3㸬
㸬ගᵓ㐀㌿⛣ࡢࢺ࣮ࣜ࢞㸸ࣅ࢔࣮ࣜࣝᵓ㐀ࡢࡡࡌࢀ-ᖹᖹ㠃 ㌿⛣

Fig.4㸬ගࡽࡏࢇ཯㌿ࡢ࣓࢝ࢽࢬ࣒

 ୖ㏙ࡢᡂᯝ࡟ᇶ࡙࠸࡚㸪㠀೫ග࡟ࡼࡿࡽࡏࢇࡢࣛࢭ࣑໬
◊✲࠿ࡽ㸪࢟ࣛࣝග࡛࠶ࡿ෇೫ග㸦CPL㸧࡟ࡼࡿ୍᪉ྥᕳ
ࡁࡽࡏࢇࡢᵓ⠏࡬࡜Ⓨᒎࡉࡏࡿ◊✲ࢆ⾜ࡗ࡚࠸ࡿ㸦Fig.5㸧㸬᭱ึࡢᐇ㦂ᑐ㇟࡜ࡋ࡚㸪㟁Ⲵ㍺㏦ᮦᩱ࡜ࡋ࡚ᐇ⏝໬ࡉࢀ࡚࠸ࡿ࣏ࣜࢪ࢜ࢡࢳࣝࣇࣝ࢜ࣞࣥ㸦PDOF㸧ࢆ㑅ࡧ㸪ⷧ⭷≧ែ࡛෇೫ගࢆ↷ᑕࡍࡿࡇ࡜࡟ࡼࡾᕥྑࡢࡽࡏࢇᵓ㐀ࢆㄏ㉳ࡍࡿࡇ࡜࡟ᡂຌࡋࡓ.ࡉࡽ࡟㸪CPLἲࡢᑐ㇟ࢆつ๎ⓗ࡞ᯞศ࠿ࢀᵓ㐀ࢆ᭷ࡍࡿᏊศᏊ࡜ࡋ࡚ࡢ᭷ᶵᵓ㐀య(Covalent
Organic Framework: COF)࡬࡜ᣑᙇࡍࡿࡇ࡜࡟ᡂຌࡋ㸪ࡉࡽ࡟㸪పศᏊ⣔࡬ࡶᛂ⏝ࡋ࡚࠸ࡿ㸬OLED⏝࡟㛤Ⓨࡉࢀࡓ㧗ຠ⋡࡞㟷ⰍⓎගࢆ♧ࡍ࢝ࣝࣂࢰ࣮ࣝྵ᭷ศᏊ࡟ᑐࡋ࡚
CPLἲ࡟ࡼࡾ୍᪉ྥᕳࡁࡢࡡࡌࢀᵓ㐀ࢆᑟධࡋ࡚ගᏛά
ᛶࢆᑟධࡋ㸪ࡑࡢ⤖ᯝ㸪ࡇࡢศᏊࡀ㧗ຠ⋡࡞㟷Ⰽ෇೫ගⓎගࢆ♧ࡍࡇ࡜ࢆሗ࿌ࡋ࡚࠸ࡿ㸬⌧ᅾ㸪ከᵝ࡞㧗ศᏊ࠾ࡼࡧ
పศᏊ⣔࡬ࡢCPL࡟ࡼࡿ୙ᩧㄏ㉳࡟ࡘ࠸࡚◊✲ࢆ⥆ࡅ࡚࠸ࡿ㸬
ࠓㅮ₇1,2ࠔ‫ە‬ᖺሗ࣭◊✲ᐊ⦅

Fig. 6. ᯞศ࠿ࢀᆺගᏛάᛶ࣏ࣜࣇࣝ࢜ࣞࣥࣅࢽࣞࣥㄏᑟయࡢ໬
Ꮫᵓ㐀㸦ᕥ㸧࠾ࡼࡧศᏊືຊᏛィ⟬࡛ᚓࡽ࠼ࡓ❧యᵓ㐀㸦ྑ㸧ᮏගᏛάᛶ㧗ศᏊࡣࣇࣝ࢜ࣞࣥ9఩ࡢ୙ᩧⅣ⣲ࡢ㓄⨨࠾ࡼࡧࣇࣝ࢜ࣞࣥ༢఩ࡢ2,4,7-఩㛫ࡢ㐃⤖࡟ࡣつ๎ᛶࡀ↓ࡃ㸪ഃ㙐࡟࢟ࣛࣝ※࡜ࡋ࡚ࡢᑟධࡋࡓࢿ࣓࢜ࣥࢳࣝᇶ௨እ
ࡢ㒊ศ࡟ࡣไᚚᵓ㐀ࢆᣢࡓࡎ㸪↓ᐃᙧ࡛࢔ࣔࣝࣇ࢓ࢫ࡞≀㉁࡛࠶ࡿ㸬ࡋ࠿ࡋ㸪ࡇࡢ㧗ศᏊࡣᅛయ≧ែ࡛࢔ࣥࢺࣛࢭࣥ
➼ࡢⓎගᛶపศᏊࢆ኱㐣๫࡟ྲྀࡾ㎸ࢇ࡛」ྜయࢆᙧᡂࡋ㸪ྲྀࡾ㎸ࡲࢀࡓపศᏊ࡟ᑐࡋ࡚ᾮᬗ࡟ఝࡓศᏊ㓄ิࢆㄏ㉳ࡍࡿ㸬ࡑࡢ⤖ᯝ㸪ྲྀࡾ㎸ࡲࢀࡓపศᏊࡣᴟࡵ࡚㧗࠸㠀ᑐ⛠ᛶ࡛෇೫ගⓎගࢆ♧ࡋ㸪࢔ࣥࢺࣛࢭࣥࡢሙྜ㸪㠀ᑐ⛠ᛶࡣ
glum = 10-2࣮࢜ࢲ࣮࡟㐩ࡍࡿ㸬ᯞศ࠿ࢀᆺ㧗ศᏊ࡟ࡼࡿప
ศᏊࡢྲྀࡾ㎸ࡳࡣ⁐ᾮ୰࡛ࡶ᭷ຠ࡛࠶ࡾ㸪㧗ศᏊ㹼పศᏊ㛫࡟ࡣ≉␗ⓗ࡞┦஫స⏝ࡣ↓࠸ࡀྲྀࡾ㎸ࡲࢀࡓపศᏊ࡟
ࡣ࢟ࣛࣝගᏛ≉ᛶࡀほ ࡉࢀࡿ㸬୍⯡࡟㸪ගᏛάᛶ㧗ศᏊࡢ㢧ⴭ࡞࢟ࣛࣝᶵ⬟ࡣ㧗ᗘ࡟つไࡉࢀࡓࡽࡏࢇᵓ㐀➼ࡢ⢭ᐦ❧యᵓ㐀ไᚚ࡟ᇶ࡙࠸࡚ࡢࡳྍ⬟࡛࠶ࡿ࡜⪃࠼ࡿࡢࡀᖖ㆑࡜ࡉࢀ࡚ࡁࡓࡢ࡟ᑐࡋ㸪ᮏ◊✲ࡢᡂᯝࡣ㸪ඃࢀࡓ࢟ࣛࣝ㧗ศᏊᮦᩱࡢ㛤Ⓨࡣไᚚᵓ㐀↓ࡋ࡛ࡶᐇ⌧࡛ࡁࡿࡇ࡜ࢆึࡵ࡚♧ࡋࡓࡶࡢ࡛࠶ࡿ㸬ࠓㄽᩥ2ࠔ‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧Catanzaro University (Italy) Associate Professor Adriana
Pietropaoloࠕ㧗ศᏊࡢ෇೫ගⓎග࡟㛵ࡍࡿ⌮ㄽⓗゎᯒࠖ /Ⱚᾆᕤᴗ኱ᏛᕤᏛ㒊Ọ┤ᩥ෸ᩍᤵࠕ࣏࢚ࣜࢳࣞࣥ࢖࣑ࣥࢆ
ᇶ♏㦵᱁࡜ࡍࡿ4⣭ሷᆺ㧗ศᏊከᏍ㉁ࡢྜᡂࠖ/ Universityof Queensland (Australia) Dr. Pingping Hanࠕ⣽⬊እᑠ⬊ࡢࣂ࢖࢜ࣉࣜࣥࢸ࢕ࣥࢢ࡟㛵ࡍࡿ◊✲ࠖ/ Tbilisi State Medical
University (Georgia) Senior Scientist Maia Merlaniࠕ㧗ศᏊ་⸆ရࡢ◊✲ࠖ/ Agricultural University of Georgia (Georgia)
Lecturer Nino Zavradashviliࠕ㑇ఏᏊ㍺㏦ᢏ⾡ࡢࡓࡵࡢ࢔࣑
ࣀ㓟ྵ᭷㧗ศᏊࡢ≉ᛶ◊✲ࠖ/㔠ἑ኱Ꮫ ๓⏣຾ᾈᩍᤵࠕ࢟
ࣛࣝᯞศ࠿ࢀᆺ㧗ศᏊࡢཎᏊ㛫ຊ㢧ᚤ㙾࡟ࡼࡿᵓ㐀ゎᯒࠖ

49

/ᒣᙧ኱Ꮫ ᳃⚽ᬕ ᩍᤵࠕ࢔࣑ࣀ㓟࡟ᇶ࡙ࡃ෇೫ගⓎගᛶ㧗ศᏊࡢྜᡂ࡜≉ᛶࠖ/The British University in Egypt(Egypt) Dr. Nageh Hassanࠕ㧗ศᏊࣇ࢓࢖ࣂ࣮ࡢゐ፹໬Ꮫ࡬ࡢᛂ⏝/ University of Alexandria (Egypt) assistant Professor
Elsayed Elbayoumiࠕ㧗ศᏊࢤࣝゐ፹ࡢ◊✲ࠖ/ Academy of
National Food and Strategic Reserves Administration (China)
Associate Professor Yue Wangࠕ᭷ᐖ㔜㔠ᒓᤕᤊ࣭ศᯒࡢࡓࡵ
ࡢ㧗ศᏊᮦᩱ㛤Ⓨࠖ/㟷ᒣᏛ㝔኱Ꮫ 㛗㇂ᕝ⨾㈗ ᩍᤵࠕ෇೫ගⓎගᛶEu㘒యࡢ◊✲ࠖ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦*㸸ᑂᰝࡘࡁ㸧(1) Wang, Y.; Nakano, T.; Chen, X.; Xu, Y.-L.; He, Y.-J.; Wu,
Y.-X.; Zhang, J.-Q.; Tian, W.; Zhou, M.-H.; Wang, S.-X.
Studies on adsorption properties of magnetic composite
prepared by one-pot method for Cd2+, Pb2+, Hg2+, and As3+:
Mechanism and practical application in food. J. Hazard. Mater.
2024, 466, 133437.*(2) Wu, P.; Pietropaolo, A.; Fortino, M.; Bando, M.; Maeda, K.;
Nishimura, T.; Shimoda, S.; Sato, H.; Naga, N.; Nakano, T.
Amplified Chirality Transfer to Aromatic Molecules throughNon̺specific Inclusion by Amorphous, Hyperbranched Poly(fluorenevinylene) Derivatives. Angew. Chem. Int. Ed. 2023,
62 (29), e202305747.*(3) Naga, N.; Yamashita, T.; Toyama, K.; Nakano, T. Synthesisof network polymers by means of ring-opening addition
reaction of a tri-aziridine and dicarboxylic acid compounds.
Polymer 2023, 276, 125948.*

5050(4) Naga, N.; Yamada, K.; Nakamura, H.; Shishido, A.; Nakano,
T. Photo-initiated thiol-ene reaction of multi-functional thioland olefinic organosilicon compounds leading to porous
polymers: Solution polymerization and photolithography.
Polymer 2023, 293, 126629.*(5) Naga, N.; Inagaki, A.; Narita, T.; Nakano, T. Quaternaryammonium ionene porous polymers via Menschutkin reactionof methylated polyethyleneimine and dibromoalkanes. Mater.
Chem. Phys. 2023, 297, 127409.*(6) Jiao, K.; Liu, C.; Basu, S.; Raveendran, N.; Nakano, T.;
Ivanovski, S.; Han, P. Bioprinting extracellular vesicles asa'cell-free'regenerative medicine approach. Extracellular
Vesicles and Circulating Nucleic Acids 2023, 4 (2), 218-239.*
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟(1) Nakano, T.: “Higher-order Structural Control of Synthetic
Macromolecules: Toward Amorphous Chirality Including
Non-uniform Chain Folding Beyond Simple Helix”, UQ
COR3 Regenerative Dentistry Symposium, The University of
Queensland, Herston, Brisbane, Australia (2023/6/2).
(2) Nakano, T.: “Non-Uniform Self-folding of HelicalPoly(fluorenevinylene) Derivatives Leading to Amplified
Circular Dichroism and Circularly Polarized Light Emission”,
2nd International Scientific Conference:͆Science, Education,
Innovations and Chemical Technologies From Idea to
Implementation”, Iv. Javakhishvili Tbilisi State University,
Tbilisi, Gergia (2023/11/23).
(3) Nakano, T.: “Polymer Chemistry From Scratch to Finish”,
Seasonal School at Tbilisi State University, Tbilisi, Gergia(2023/11/23).

ᖺሗ࣭◊✲ᐊ⦅‫ە‬‫إ‬ԓὉܱဇ҄ਖ਼ᡶኒᴾ
report: Department of Practical Applications◊✲㛤Ⓨ㒊㛛/Research and Development
Division‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑ◊✲ဨ㸦◊✲᥎㐍ᨭ᥼ᩍᤵ㸧ࠒす⏣ࡲࡺࡳ࣭ࠑᐈဨᩍᤵ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒబ⸨୍ᙪྜྷ⏣຾ᐩỌ೺୍ὸᕝ┿⃈⏿୰㞞㝯ࠑᐈဨᩍᤵ࢚࢘ࢫࢺࢥ࣮
ࢼ࣮ࠒ㝮⏣ᩄ㞝‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ๓௵ࡢす⏣ࡲࡺࡳᩍᤵࡢ㏥⫋࡟క࠸㸪㛗㇂ᕝࡀᚋ௵࡜ࡋ
࡚㒊㛛ࢆ㐠Ⴀࡋࡓ㸬ྠ㒊㛛ࡢ࣑ࢵࢩ࡛ࣙࣥ࠶ࡿ⏘Ꮫᐁ㐃ᦠάືࢆᐇ᪋ࡍࡿࡓࡵ࡟㸪⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࠿ࡽ5ྡࡢᐈဨᩍᤵࢆ㸪㸦ᰴ㸧࢚࢘ࢫࢺࢥ࣮ࢼ࣮࠿ࡽ1ྡࡢᐈဨᩍᤵࡀ╔௵ࡋࡓ㸬‫ڦ‬2023ᖺᗘࡢࢺࣆࢵࢡ
(1) ⏘ᐁ࠿ࡽࡢ◊✲⪅ࢆㅮᖌࡋ࡜ࡋ࡚ᣍ⪸ࡋ㸪⥲ྜ໬Ꮫ㝔࡟࠾࠸࡚ࠕ໬Ꮫ⏘ᴗᐇᏛࠖࢆ㞟୰ㅮ⩏࡜ࡋ࡚㛤ㅮࡋࡓ㸬(2) 㛗㇂ᕝࡀ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࡜ࢡࣟࢫ࢔࣏࢖ࣥࢺ࣓
ࣥࢺࡋ㸪ྠゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮࣭≉ᐃࣇ࢙࣮ࣟ࡜ࡋ
࡚໅ົࡋ㸪ඹྠ◊✲ࢆᐇ᪋ࡋࡓ㸬

  



‫ە‬ᖺሗ࣭◊✲ᐊ⦅ᴾ

51

‫إ‬ԓὉἑὊἄἕἚᄂᆮᢿᴾ
report: Department of Target Researchࢡࣛࢫࢱ࣮ࡢタ⨨࡜⤊஢ ࢱ࣮ࢤࢵࢺ◊✲㒊ࡣ㸪ྛ◊✲㒊㛛࡜ࡣู࡟㸪ゐ፹ࢆᶵ㍈࡜ࡋࡓ⛉Ꮫ࣭ᢏ⾡ࡢ࢖ࣀ࣮࣋ࢩࣙࣥࢆ┠ⓗ࡜ࡋࡓ◊✲⤌⧊࡛㸪⮬❧㞟ྜᆺࡢᣐⅬᆺ࠾ࡼࡧᒎ㛤ᆺࡢ◊✲ࢡࣛࢫࢱ࣮࠿ࡽᵓᡂࡉࢀࡿ㸬ᣐⅬᆺ◊✲ࢡࣛࢫࢱ࣮ࡣ࠾ࡶ࡟ゐ፹⛉Ꮫ◊✲ᡤෆࡢᩍဨ࡟ࡼࡗ࡚ᵓᡂࡉࢀ㸪ゐ፹࠾ࡼࡧ㛵㐃ศ㔝ࡢࢥ࣑ࣗࢽࢸ࢕࡟࠾ࡅࡿᖜᗈ࠸㐃ᦠ◊✲άືࢆ⾜࠺ࡇ࡜ࢆ┠ⓗ࡜ࡋ㸪ᒎ㛤ᆺ◊✲ࢡࣛࢫࢱ࣮ࡣ෸ᩍᤵࢆࣜ
࣮ࢲ࣮࡜ࡋ࡚Ꮫෆእࡢ◊✲⪅࠿ࡽᵓᡂࡉࢀ㸪ゐ፹࡟㛵㐃ࡍࡿࢺࣆࢵࢡࢆ◊✲ࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚࠸ࡿ㸦ᒎ㛤ᆺ



5252

◊✲ࢡࣛࢫࢱ࣮ࡢ࣮ࣜࢲ࣮࡛࠶ࡿ෸ᩍᤵࡣᇶ♏◊✲⣔ࡢྛ◊✲㒊㛛࡜ව௵㸧㸬 ◊✲ࢡࣛࢫࢱ࣮ࡢタ⨨࡜⤊஢ࡣࢱ࣮ࢤࢵࢺ◊✲㒊఍㆟࡟࠾࠸࡚ᑂ㆟㸪Ỵᐃࡉࢀࡿ㸬2007ᖺ4᭶࡟๓㌟࡛࠶ࡿゐ፹ࢱ࣮ࢤࢵࢺ◊✲࢔ࢭࣥࣈࣜࡀタ⨨ࡉࢀ࡚௨᮶㸪ᣐⅬᆺ2㸪
ᒎ㛤ᆺ20ࡢྜィ22ࡢ◊✲ࢡࣛࢫࢱ࣮ࡀタ⨨ࡉࢀ㸪࣮ࣜࢲ࣮ࡢ␗ື࡞࡝࡟࡜ࡶ࡞ࡗ࡚㸪2023ᖺᗘࡲ࡛࡟ᣐⅬᆺ1㸪ᒎ㛤
ᆺ15ࡢྜィ16ࡢ◊✲ࢡࣛࢫࢱ࣮ࡢάືࡀ⤊஢ࡋࡓ㸬ࡇࢀࡲ࡛ࡢ◊✲ࢡࣛࢫࢱ࣮ࡣୗ⾲ࡢ࡜࠾ࡾ㸦2023ᖺᗘࡲ࡛࡟⤊஢ࡋࡓࢡࣛࢫࢱ࣮ࡣࢢ࣮࡛ࣞ⾲♧㸧
㸬


ศ㢮

◊✲ࢡࣛࢫࢱ࣮ྡ

࣮ࣜࢲ࣮

タ⨨᪥

⤊஢᪥

ᣐⅬᆺ

ゐ፹ࢿࢵࢺ࣮࣡ࢡ

኱㇂ᩥ❶

2007/4/1

2009/9/30

ᣐⅬᆺゐ፹◊✲ᇶ┙㛤Ⓨ㛗㇂ᕝ῟ஓ

2009/10/1ᒎ㛤ᆺ୙ᩧ཯ᛂሙ

ᑠ➟ཎṇ㐨

2007/4/1

2016/3/31ᒎ㛤ᆺつไ⾲㠃ሙᮦᩱྜᡂ

Wang Jae CHUN㸦ᮅ಴Ύ㧘㸧

2007/4/1

2009/3/31ᒎ㛤ᆺつᩚ⾲㠃ࢼࣀᵓ㐀㧘ⲡᮌ㐩

2008/10/1

2023/3/31ᒎ㛤ᆺ⤖ᬗᶵ⬟໬

㜿㒊❳

2007/4/1

2012/3/31

ᒎ㛤ᆺ࢚ࢿࣝࢠ࣮ኚ᥮ሙ

➉ཱྀ❳ᘺ

2007/4/1

2014/3/31

ᒎ㛤ᆺࣂ࢖࢜ኚ᥮⚟ᒸ῟

2007/4/1

2010/3/31

ᒎ㛤ᆺࣂ࢖࢜࢖ࣥࢱ࣮ࣇ࢙࣮ࢫ

Shen YE

2007/4/1

2017/3/31ᒎ㛤ᆺศᏊ㞟✚཯ᛂሙ

ཎ㈼஧

2009/4/1

2015/3/31ᒎ㛤ᆺ⛛ᗎᵓ㐀཯ᛂሙ

ᒣෆ⨾✑

2009/4/1

2011/12/31ᒎ㛤ᆺᶵ⬟」ྜᆺࢢ࣮ࣜࣥゐ፹ΎỈ◊୍

2010/10/1

2015/3/31

ᒎ㛤ᆺࣉࣛࢬࣔࣥගゐ፹཯ᛂ

Ewa KOWALSKA

2013/2/1

2023/3/31

ᒎ㛤ᆺࣂ࢖࣏࣐࣮࢜ࣜ

ᑠᒣ㟹ே

2013/10/1

2016/3/31ᒎ㛤ᆺ⏺㠃ࢩ࣑࣮ࣗࣞࢩࣙࣥ

୰ᒣဴ

2014/8/1

2019/3/31ᒎ㛤ᆺ㓟ሷᇶゐ፹

୰ᓥΎ㝯

2015/8/1

2022/3/31ᒎ㛤ᆺᶵ⬟ᛶྜ㔠ゐ፹ྂᕝ᳃ஓ

2016/11/1

2023/4/30ᒎ㛤ᆺ㑄⛣㔠ᒓㄏ㉳㧗ศᏊྜᡂኚ᥮

Zhiyi SONG

2018/1/15

 

ᒎ㛤ᆺ

ࢼࣀ⏺㠃཯ᛂሙ

㣤⏣೺஧

2020/2/1ᒎ㛤ᆺ⏕యศᏊᶆ㆑ゐ፹ὸ㔝ᆂభ

2022/7/1ᒎ㛤ᆺࢹ࣮ࢱ㥑ືᆺゐ፹㫽ᒇᑿ㝯

2022/8/1

ᒎ㛤ᆺኳ↛Ⅳ⣲㈨※ά⏝Ⳣ἟Ꮫྐ2023/6/1

ᖺሗ࣭◊✲ᐊ⦅‫ە‬ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮Research
Cluster for Sustainable Catalyst‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑ࣮ࣜࢲ࣮ᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᩍᤵࠒᮅ಴Ύ㧘㧘ⲡᮌ㐩୰ᓥΎ㝯⚟ᒸ῟ΎỈ◊୍ᾆཱྀ኱㍜୰㔝⎔ ‫✲◊ڦ‬ㄢ㢟
1㸬㸬ࢧࢫࢸࢼࣈࣝゐ፹஦ᴗ᥎㐍 ᣢ⥆ྍ⬟࡞♫఍࡟ྥࡅࡓᢏ⾡㠉᪂ࢆྍ⬟࡜ࡍࡿ᪂ࡋ࠸
࢚ࢿࣝࢠ࣮࣭㈨※࣭≀㉁ኚ᥮ࡢゐ፹໬Ꮫ࣭ᢏ⾡◊✲ࡢ᥎㐍ࢆ┠ⓗ࡟ྛ✀άືࢆᨭ᥼ࡋࡓ㸬࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐
ࢸ࢕ࢡࢫ஦ᴗࢆࢧ࣏࣮ࢺࡋࡓ㸬
2023ᖺᗘࡢࢺࣆࢵࢡ㸸ゐ፹Ꮫ఍ᮐᖠㅮ₇఍ࠕ㏆ᮍ᮶⣔≀㉁ྜᡂ࣭ᮦᩱ᥈⣴: ࢹ࣮ࢱ㥑ືᆺ◊✲ࡣ࡝ࡇ࡟ྥ࠿࠺ࡢ࠿ࠖ
ࢆࢧ࣏࣮ࢺࡋࡓ㸬  ‫ە‬ᖺሗ࣭◊✲ᐊ⦅

2㸬ゐ፹㧗ᗘゎᯒ஦ᴗ᥎㐍 ⌮ㄽ࣭ࢩ࣑࣮ࣗࣞࢩࣙࣥศ㔝ࡢᇶ┙ᩚഛࢆ⾜ࡗ࡚࠸ࡿ.
ලయⓗ࡟ࡣ㸪gaussian࡜vaspࢆᐇ⾜࡛ࡁࡿィ⟬⎔ቃࢆ◊✲ᡤෆ࡟ᥦ౪ࡋ࡚࠸ࡿ㸬௒ᚋࡶ࣮ࣘࢨ࣮IDࡣ㝶᫬Ⓨ⾜ࡍࡿ.
2023ᖺᗘࡢࢺࣆࢵࢡ㸸 *DXVVLDQ⏝ࡢィ⟬ࢧ࣮ࣂࡢᥦ౪
ࢧ࣮ࣅࢫࢆ⤊஢ࡋࡓ㸬ࡲࡓ㸪9$63ィ⟬ࢧ࣮ࣂࡢ⟶⌮≧ἣࢆᨵၿࡍࡿࡓࡵ࡟㸪ࢧ࣮ࣂࣛࢵࢡࢆᐊ࡟⛣ືࡋ㸪ࢿࢵࢺ࣮࣡ࢡࢆ෌ᵓ⠏ࡋࡓ㸬
3㸬ゐ፹ࢹ࣮ࢱ࣮࣋ࢫ஦ᴗ ゐ፹࡟㛵ಀࡍࡿ⭾኱࡞⛉Ꮫᢏ⾡᝟ሗࡢయ⣔໬ࢆ┠ⓗ࡟㸪webୖ࡟ゐ፹ࢹ࣮ࢱ࣮࣋ࢫ㸦ゐ፹≀㉁㸪XAFS㸧ࢆᵓ⠏ࡋ㐠Ⴀࡋ࡚࠸ࡿ㸬
2023ᖺᗘࡢࢺࣆࢵࢡ㸸ゐ፹≀㉁ࡢࢹ࣮ࢱ࣮࣋ࢫࡀ1200௳㸪
XAFS databaseࡀ1000௳࡟฿㐩ࡋࡓ㸬 53㑄⛣㔠ᒓㄏ㉳㧗ศᏊྜᡂ/ኚ᥮◊✲ࢡࣛࢫ
ࢱ࣮/ Research Cluster of Transitionmetals-induced Synthesis andTransformation of Polymer‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑ࣮ࣜࢲ࣮෸ᩍᤵࠒᏵᚿẎ࣭ࠑᏛእ◊✲༠ຊᩍဨᚨᓥ኱
Ꮫࠒᑠ➟ཎṇ㐨࣭ࠑᏛእ◊✲༠ຊᩍဨRenmin Universityof China㸦୰ᅜ㸧ࠒZhiping LI࣭ࠑᏛእ◊✲༠ຊᩍဨ
University of Chinese Academy of Science㸦୰ᅜ㸧ࠒ⋤ᚘὒ‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ ୖグ㸲ྡࡀᮏࢡࣛࢫࢱ࣮࡟ཧ⏬ࡋࡓ㸬⾜ࡗࡓ㸬≉࡟ࢳࢱࣀࢭࣥ㘒యࡢࢩࢡࣟ࣌ࣥࢱࢪ࢚ࢽࣝ㓄఩Ꮚࡣ㸪ྠࡌࢳࢱࣥୖ࡟࠶ࡿ࢔ࣝࢣࢽࣝⅣ⣲࡜࢝ࢵࣉࣜ
ࣥࢢ཯ᛂࢆ᳨ウࡋࡓ㸬ࡇࢀࡲ࡛࡟ᙜ◊✲ᐊ࡛ࡣ㸪ࢳࢱࢼࢩࢡࣟ࣌ࣥࢱࢪ࢚ࣥ࠾ࡼࡧࢳࢱࢼࢩࢡࣟ࣌ࣥࢸࣥࡀ㸪ศᏊෆ࡟࠶ࡿࢩࢡࣟ࣌ࣥࢱࢪ࢚ࢽࣝ㓄఩Ꮚ࡜࢝ࢵࣉࣜࣥࢢ
཯ᛂࢆ㉳ࡇࡋ㸪ࢪࣄࢻࣟ࢖ࣥࢹࣥ㸪࢔ࣝࢣࢽࣝࢩࢡࣟ࣌
ࣥࢱࢪ࢚ࣥ㸪ࢫࣆࣟ[4.4] ࣀࢼࢺ࢚ࣜࣥㄏᑟయࢆ୚࠼ࡿࡇ࡜ࢆぢฟࡋ࡚ሗ࿌ࡋ࡚࠸ࡿ㸬ᮏ◊✲࡛ࡣ㸪ࢳࢱࢼࢩࢡࣟ
࣌ࣥࢸࣥ㘒య࡟ࣚ࢘໬ࣅࢫ࣐ࢫ(III)ࢆ཯ᛂࡉࡏࡿ࡜㸪ࢩࢡࣟࣉࣟࣃࢽ࣓ࣝࢳࣞࣥࢩࢡࣟ࣌ࣥࢸࣥࡀᚓࡽࢀࡿࡇ࡜ࢆぢฟࡋࡓ㸬⏕ᡂ≀ࡣࢸࢺࣛࢩ࢔ࣀ࢚ࢳࣞࣥ㸦TCNE㸧ࢆ⏝࠸࡚ㄏᑟ໬ࡋ㸪TCNE ௜ຍయࡢ X ⥺ᵓ㐀ゎᯒ࡟ࡼࡗ࡚⏕ᡂ≀ࡢᵓ㐀ࢆỴᐃࡋࡓ㸬ᮏ཯ᛂ࡛ࡣ㸪ࢩࢡࣟࣉࣟࣃ
ࣥ໬ࢆ⤒࡚ࢩࢡࣟ࣌ࣥࢱࢪ࢚ࢽࣝ㓄఩Ꮚ࡜࢔ࣝࢣࢽࣝⅣ⣲ࡢ࢝ࢵࣉࣜࣥࢢࡀ㐍⾜ࡍࡿ࡜᝿ᐃࡉࢀࡿ㸬‫✲◊ڦ‬ㄢ㢟 ๓࿘ᮇ㑄⛣㔠ᒓୖ࡟࠾ࡅࡿ᭷ᶵศᏊࡢศᏊ㦵᱁ኚ᥮཯ᛂࢆ⏝࠸ࡿࡇ࡜࡟ࡼࡾ㸪᪂ࡋ࠸᭷ᶵྜᡂᡭἲࡢ㛤Ⓨࢆ

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5454

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ᖺሗ࣭◊✲ᐊ⦅‫ە‬ࢼࣀ⏺㠃཯ᛂሙ◊✲ࢡࣛࢫࢱ࣮/ Research
Cluster for Nano-Interface Reaction Field‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑ࣮ࣜࢲ࣮/෸ᩍᤵࠒ㣤⏣೺஧࣭ࠑ෸ᩍᤵࠒྂᕝ᳃ஓ㹙㹼
2023/04/30㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/⟃Ἴ኱Ꮫࠒ▮ⰼ୍ᾈ࣭ࠑᏛእ◊✲༠ຊᩍဨ/ி㒔኱Ꮫࠒᑎす฼἞࣭ࠑᏛእ◊✲༠ຊ
ᩍဨ/ᮾி⌮⛉኱Ꮫࠒ᰿ᓊ㞝୍࣭ࠑᏛእ◊✲༠ຊᩍဨ/㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫࠒඵ஭ᓫ࣭ࠑᏛእ◊✲༠ຊᩍဨ/ University ofAlberta㸦࢝ࢼࢲ㸧ࠒAndriy KOVALENKO࣭ࠑᐈဨ෸ᩍᤵ/ྡྂᒇ኱Ꮫࠒᮾ 㞞኱‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
2023ᖺᗘࡣ㸪㔜Ⅼࢡࣛࢫࢱ࣮࡜ࡋ࡚᫖ᖺᗘ࠿ࡽࡢ7ྡ࡟ຍ࠼࡚ྡྂᒇ኱Ꮫࡢᮾ㞞኱ᩍᤵࡀᮏࢡࣛࢫࢱ࣮࡟ཧ⏬ࡋ࡚㸪ඹྠ◊✲ࢆ⢭ຊⓗ࡟᥎㐍ࡋࡓ㸬‫✲◊ڦ‬ㄢ㢟ཎᏊ㛫⤖ྜ࠿ࡽ⏺㠃ࡲ࡛ࡢᵝࠎ࡞ࢧ࢖ࢬࢫࢣ࣮ࣝࡢᗄ
ఱⓗ≉ᛶࢆ฼⏝ࡋ࡚ゐ፹⬟ࢆไᚚࡍࡿࡓࡵࡢᣦ㔪ࢆᵓ⠏ࡍࡿ㸬ࡑࡋ࡚㸪ࢼࣀ⢏Ꮚ/ᢸయࡸᅛయ/ᾮయ࡜࠸ࡗࡓ⏺㠃ࢆ཯ᛂሙ࡜ࡍࡿගゐ፹ࡸ㟁ᴟゐ፹ࢆ㛤Ⓨࡍࡿ㸬ࡑࡢࡓࡵ࡟㸪ᅛᾮ⏺㠃ࡸᢸᣢࢼࣀ⢏Ꮚࡢእሙᛂ⟅ࢆᢅ࠺ࡇ࡜ࡀ࡛ࡁࡿ
⌮ㄽィ⟬ᡭἲࢆᵓ⠏ࡋ㸪ࡑࡢᡭἲࢆ⏝࠸࡚ゐ፹཯ᛂࡢ࣓࢝
ࢽࢬ࣒ࢆ᫂ࡽ࠿࡟ࡍࡿ㸬ィ⟬࠿ࡽᚓࡽࢀࡓ▱ぢ࡟ᇶ࡙ࡁ㸪ᐇ㦂ࢢ࣮ࣝࣉ࡜ࡢඹྠ◊✲ࢆ㏻ࡋ࡚ゐ፹ࡢタィࢆ㐍ࡵࡿ㸬㸬㔠ᒓࢼࣀ⢏Ꮚࢆ⏝࠸ࡓගゐ፹཯ᛂ㈗㔠ᒓࢼࣀ⢏Ꮚࢆ⏝࠸ࡿ࡜ప࢚ࢿࣝࢠ࣮ࡢග࡛Ỉศゎ
ࡸCO2ศゎࢆ⾜࠺ࡇ࡜ࡀྍ⬟࡞ࡓࡵ㸪ኴ㝧ගࢆ฼⏝ࡋࡓගゐ፹ࡢ㛤Ⓨ࡟ࡴࡅ࡚◊✲ࡀ⾜ࢃࢀ࡚࠸ࡿ㸬㛤Ⓨࢆ㐍ࡵࡿࡓ
ࡵ࡟ගゐ፹స⏝ࡢᇶ♏ⓗ⌮ゎࡀồࡵࡽࢀ࡚࠸ࡿࡀ㸪༙ᑟయࡸ㔠ᒓࢼࣀ⢏Ꮚ࡜ศᏊ࠿ࡽ࡞ࡿ」㞧࡞⣔ࡢගᛂ⟅ࡢᶵᵓࢆ᫂ࡽ࠿࡟ࡍࡿࡇ࡜ࡣᐜ࡛᫆ࡣ࡞࠸㸬ࡑ࠺ࡋࡓ࡞࠿࡛ᡃࠎ
ࡣ㸪㧗࠸୪ิ໬ຠ⋡ࢆ᭷ࡍࡿ➨୍ཎ⌮ィ⟬ࣉࣟࢢ࣒ࣛSALMONࡢ㛤Ⓨࢆ㐍ࡵ࡚ࡁࡓ㸬ࡑࡋ࡚㸪SALMONࢆ⏝࠸ࡓ኱つᶍィ⟬࡟ࡼࡾ㸪ࢼࣀ≀㉁⣔ࡢගບ㉳࡟ࡘ࠸࡚◊✲ࢆ⾜ࡗ࡚ࡁࡓ㸬
ࠓཷ㈹ࠔ
ගゐ፹స⏝࡟ࡘ࠸࡚⌮ゎࢆ῝ࡵࡿ࡭ࡃ㸪ࡇࢀࡲ࡛㸪㈗㔠
ᒓࢼࣀ⢏Ꮚ࡜ศᏊࡸ༙ᑟయࡢ⏺㠃࡟࠾ࡅࡿගㄏ㉳㟁Ꮚ⛣ືࡢᶵᵓࢆ᫂ࡽ࠿࡟ࡋ࡚ࡁࡓ㸬ྠ᫬࡟㸪ᐇ㦂ࢢ࣮ࣝࣉ࡜㐃ᦠࡋ࡚㸪᪂つࢼࣀᮦᩱࡢ㛤Ⓨࡸ㸪㈗㔠ᒓࢡࣛࢫࢱ࣮ࢆ⏝࠸
ࡓCO2ศゎගゐ፹ࡢ◊✲࡞࡝ࢆ㐍ࡵ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ㈗㔠ᒓࢡࣛࢫࢱ࣮࡜ศᏊࡢ᥋ゐ⏺
㠃ࡀගᏛᛂ⟅࡛ᢸ࠺ᙺ๭ࢆཎᏊࢫࢣ࣮࡛ࣝ᫂ࡽ࠿࡟ࡍࡿ

Fig. 1. Variations in the electron occupation of the Au147azobenzene complex by applying a laser field of energy 2.2
eV when the azobenzene molecule is (a) physisorbed and (b)chemisorbed on the Au147 surface.ࠓㄽᩥ ࠔ‫ە‬ᖺሗ࣭◊✲ᐊ⦅࡭ࡃ㸪㔠ࢼࣀࢡࣛࢫࢱ࣮࡟࢔ࢰ࣋ࣥࢮࣥࡀ྾╔ࡋࡓ⣔ࡢගບ㉳࡟ࡘ࠸࡚◊✲ࢆ⾜ࡗࡓ㸬ࡑࡢ⤖ᯝ㸪ගㄏ㉳㟁Ꮚ⛣ືࡢᶵᵓࡀ࢔ࢰ࣋ࣥࢮࣥࡢ྾╔ᙧែ࡟ᙉࡃ౫Ꮡࡍࡿࡇ࡜ࡸ㸪࢔ࢰ࣋ࣥࢮࣥࡢࢩࢫయ࠾ࡼࡧࢺࣛࣥࢫయ࡜㔠ࢼࣀࢡࣛࢫ
ࢱ࣮࡜ࡢ㛫ࡢ྾╔ᙉᗘࡢ㐪࠸࡟ᛂࡌࡓගㄏ㉳㟁Ꮚ⛣ືࡢᶵᵓࡢኚ໬ࢆ᫂ࡽ࠿࡟ࡋࡓ㸬ࠓㄽᩥ2ࠔ ࡲࡓ㸪᪂つ࡞ࣉࣛࢬࣔࢽࢵࢡྜ㔠ࢼࣀ⢏Ꮚࢆ㛤Ⓨࡍࡿ࡭ࡃ◊✲ࢆ⾜ࡗࡓ㸬ྍどᇦ࡟ᒁᅾ⾲㠃ࣉࣛࢬࣔࣥඹ㬆(LSPR)྾཰ࢆ♧ࡍᮦᩱ࡜ࡋ࡚ࡣ㸪࿘ᮇ⾲11᪘ࡢ㔠ᒓ(Cu㸪Ag㸪Au)ࡢࡳࡀ౑ࢃࢀ࡚ࡁࡓ㸬ࡑ࠺ࡋࡓ࡞࠿࡛㸪ி኱໬◊ࡢᑎす◊✲ᐊ࡟࡚㸪C1ᆺࡢPtIn2ྜ㔠ࢼࣀ⢏Ꮚࡀྍどᇦ࡟LSPR྾཰ࢆ♧ࡍࡇ࡜ࡀぢ࠸ࡔࡉࢀࡓ㸬ࡑࡇ࡛㸪LSPRࡢⓎ⌧ᶵᵓࢆ᫂ࡽ࠿࡟ࡍࡿ࡭ࡃ㸪 Pt249In432 ࡢගບ㉳ࡢ➨୍ཎ⌮ィ⟬ࢆ⾜ࡗࡓ㸬ࡑࡢ⤖ᯝ㸪C1ᆺࡢẚ㍑ⓗ␯࡞ᗄఱⓗ≉ᛶ࡜㟁Ꮚᵓ㐀࡟ࡼࡗ࡚LSPRࡢἼ㛗ࡸᙉᗘࡀỴᐃࡉࢀ࡚࠸ࡿࡇ࡜ࡀ᫂
ࡽ࠿࡟࡞ࡗࡓ㸬ࣉࣛࢬࣔࢽࢵࢡࢼࣀᮦᩱࡢග≀ᛶࡣ㸪ࢼࣀ⢏Ꮚࡢࢧ࢖ࢬࡸᙧ≧࡜࠸ࡗࡓ࣐ࢡࣟ࡞ᗄఱⓗᵓ㐀ࢆᨵኚࡍࡿࡇ࡜࡛ไᚚࡉࢀ࡚ࡁࡓ㸬ࡑ࠺ࡋࡓ࡞࠿࡛ᮏ◊✲࡟ࡼࡗ࡚㸪ཎᏊࢫࢣ࣮ࣝࡢᗄఱⓗ≉ᛶ࡟ࡼࡗ࡚ไᚚ࡛ࡁࡿࡇ࡜ࡀ
᫂ࡽ࠿࡟࡞ࡗࡓ㸬
ࠓㄽᩥ1ࠔ

Fig. 2. (a) Pt249In432 and (b) Au561 nanoparticles.ࠓㄽᩥ ࠔ㸬୙ᆒ୍⣔ゐ፹ࢆ⏝࠸ࡓ㟁ᴟ཯ᛂ㟁ụࡸ㟁Ẽศゎ཯ᛂ࡬ࡢ⯆࿡࠿ࡽ㸪㟁ᴟゐ፹ࡢ㛤Ⓨࡀ┒ࢇ࡟⾜ࢃࢀ࡚࠸ࡿ㸬ࡋ࠿ࡋ㸪୙ᆒ୍⣔ゐ፹࡜㟁ゎ㉁⁐ᾮ࠿ࡽ࡞ࡿ」㞧࡞㟁Ẽ໬Ꮫ⣔ࢆ⌮ㄽィ⟬ᡭἲ࡛ᢅ࠺ࡇ࡜ࡣᐜ
࡛᫆ࡣ࡞ࡃ㸪⌮ㄽⓗ◊✲ࡣ࠶ࡲࡾ㐍ࢇ࡛ࡇ࡞࠿ࡗࡓ㸬ࡑࡇ࡛ᡃࠎࡣ㸪୙ᆒ୍⣔ゐ፹ࢆ⏝࠸ࡓ㟁ᴟ཯ᛂࡢᶵᵓࢆ᫂ࡽ࠿
࡟ࡍࡿ࡭ࡃ㸪㔞ᏊຊᏛ࡜⤫ィຊᏛࡢᯟ⤌ࡳࢆ⼥ྜࡋࡓ⌮ㄽィ⟬ᡭἲࢆ㛤Ⓨࡋ㸪㛤Ⓨࡋࡓᡭἲࢆ⏝࠸࡚㟁ᅽࡸ⁐ᾮࡢᙺ๭࡟ࡘ࠸࡚◊✲ࢆ㐍ࡵ࡚࠸ࡿ㸬ྠ᫬࡟㸪ᐇ㦂ࢢ࣮ࣝࣉ࡜㐃ᦠࡋ࡚㸪᪂つ࡞㟁ᴟゐ፹ᮦᩱࡢ㛤Ⓨࢆ㐍ࡵ࡚࠸ࡿ㸬ࡇࢀࡽࡢ◊✲ࢆ㏻ࡋ࡚㸪㟁ᴟゐ፹࡜㟁ゎ㉁ࡢ⏺㠃࡟㟁ᅽࡀ࠿࠿ࡿ
ࡇ࡜࡛Ⓨ⌧ࡍࡿ཯ᛂሙࡢタィᣦ㔪ࢆ᫂ࡽ࠿࡟ࡍࡿࡇ࡜ࢆ
┠ᣦࡋ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸Pt17ࢡࣛࢫࢱ࣮ࢆ㟁ᴟゐ፹࡜ࡋ࡚⏝࠸ࡿ࡜㸪Ptᚤ⢏Ꮚࡼࡾࡶ㧗࠸㓟⣲㑏ඖάᛶࢆ♧ࡍࡇ࡜ࡀᮾ
ி⌮⛉኱ࡢ᰿ᓊ◊✲ᐊ࡟࠾࠸࡚ぢ࠸ࡔࡉࢀࡓ㸬ᡃࠎࡣ㸪Pt17
ࢡࣛࢫࢱ࣮ࡢ㟁ᴟゐ፹స⏝ࢆ᫂ࡽ࠿࡟ࡍࡿ࡭ࡃ➨୍ཎ⌮ィ⟬ࢆ⾜ࡗࡓ㸬ࡑࡢ⤖ᯝ㸪 Pt17ࢡࣛࢫࢱ࣮ࢆ⏝࠸ࡿ࡜㸪O=O⤖ྜࡀ㛤⿣ࡋࡸࡍ࠸࡟ࡶ࠿࠿ࢃࡽࡎ㸪O2ࡢPt17ࢡࣛࢫࢱ࣮

Fig. 3. O2 adsorption sites of a graphite supported Pt 17
cluster.ࠓㄽᩥ ࠔ55࡬ࡢ྾╔࢚ࢿࣝࢠ࣮ࡣPtⷧ⭷࡜ྠ⛬ᗘ࡟࡞ࡿࡇ࡜ࡀ᫂ࡽ
࠿࡟࡞ࡗࡓ㸬Ptⷧ⭷ࡼࡾࡶPt17ࢡࣛࢫࢱ࣮ࡢ᪉ࡀ㧗࠸άᛶࢆ♧ࡍ࡜࠸࠺ᐇ㦂⤖ᯝ࡜୍㈏ࡍࡿ⤖ᯝࡀᚓࡽࢀࡓ㸬ࡑࡇ࡛᭦࡟㟁Ꮚ≧ែࢆゎᯒࡋࡓ㸬ࡑࡢ⤖ᯝ㸪Pt17ࢡࣛࢫࢱ࣮࡛ࡣ㸪ྛPtཎᏊࡢ㟁Ⲵࡀ኱ࡁࡃ␗࡞ࡗ࡚࠸ࡿࡇ࡜࠿ࡽ㸪㧗࠸άᛶࢆ♧ࡍࢧ࢖ࢺࡀ⌧ࢀࡿࡇ࡜ࡀศ࠿ࡗࡓ㸬ࠓㄽᩥࠔ㸬㟁ຊࢆ฼⏝ࡍࡿゐ፹཯ᛂ㔠ᒓ㓟໬≀ୖ࡟ᢸᣢࡋࡓ㔠ᒓゐ፹ࢆ⏝࠸ࡓⅣ໬Ỉ⣲ࡢ⬺Ỉ⣲໬཯ᛂ࡟ࡘ࠸࡚㸪㟁ᅽࡢ༳ຍ࡛άᛶࡀྥୖࡍࡿࡇ࡜
ࡀሗ࿌ࡉࢀ࡚࠸ࡿ㸬ࡋ࠿ࡋ㟁ᅽࡢᙺ๭ࡣࡼࡃศ࠿ࡗ࡚࠸࡞
࠸㸬ࡑࡇ࡛ᡃࠎࡣ㸪㟁ᅽࡢ༳ຍࡀゐ፹཯ᛂ࡛ᢸ࠺ᙺ๭ࢆ᫂
ࡽ࠿࡟ࡍࡿ࡭ࡃ◊✲ࢆ㐍ࡵ࡚࠸ࡿ㸬2023ᖺᗘࡢࢺࣆࢵࢡ㸸 ࡇࢀࡲ࡛ࡢ◊✲࠿ࡽ㸪㟁ᴟ㟁ሙ࡟ࡼࡗ࡚㔠ᒓ㓟໬≀⾲㠃ୖࢆ⛣ືࡋࡓࣉࣟࢺࣥ࡟ࡼࡗ࡚཯
ᛂࡀάᛶ໬ࡉࢀࡿ࡜⪃࠼ࡽࢀ࡚࠸ࡿ㸬ࡑࡇ࡛ᡃࠎࡣ㸪TiO2
ⷧ⭷⾲㠃࡟࠾࠸࡚Ỉ࠿ࡽゎ㞳ࡋࡓHཎᏊࡀ㟁ሙ࡟ࡼࡗ࡚
⛣ືࡍࡿ㐣⛬ࡢ⌮ㄽィ⟬ࢆ⾜ࡗࡓ㸬ࡑࡢ⤖ᯝ㸪HཎᏊࡢ⛣ື㔞࡜㟁ሙ࡟ࡼࡿ࢚ࢿࣝࢠ࣮ኚ໬ࡢ㛫࡟┦㛵ࡀṤ࡝↓࠸ࡇ࡜ࡀศ࠿ࡗࡓ㸬ࡇࢀࡣ㸪TiO2⾲㠃ࢆ⛣ືࡍࡿHཎᏊࡢ᣺ࡿ⯙࠸ࡣ㸪Ⅼ㟁Ⲵࢆᣢࡘࣉࣟࢺࣥ࡜ࡣ኱ࡁࡃ␗࡞ࡿࡇ࡜ࢆ
♧ࡍ㸬ࡑࡇ࡛㸪HཎᏊࡢ⛣ື࡟࡜ࡶ࡞࠺㟁Ꮚᐦᗘศᕸࡢኚ
໬ࢆゎᯒࡋࡓ㸬ࡑࡢ⤖ᯝ㸪 HཎᏊ࡜TiO2⾲㠃࡜ࡢ໬Ꮫ⤖ྜࡢᙧᡂ࣭㛤⿣࡞࡝ࡢ㔞Ꮚ໬Ꮫⓗ࡞┦஫స⏝࡟ࡼࡗ࡚㸪㟁ᴟ㟁ሙ࡟ࡼࡿ࢚ࢿࣝࢠ࣮ኚ໬ࡀỴᐃ࡙ࡅࡽࢀ࡚࠸ࡿࡇ࡜ࡀ
᫂ࡽ࠿࡟࡞ࡗࡓ㸬ࠓㄽᩥࠔ

Fig. 3. Variation in the electron density owing to (a) the
proton transfer and (b) OH group rotation indicated by theblue arrow.ࠓㄽᩥ ࠔ





5656

‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧኱㜰኱ᏛᕤᏛ◊✲⛉ྂᕝ᳃ஓᩍᤵࠕ㟁ຊࢆ฼⏝ࡍࡿゐ፹཯ᛂࡢᶵᵓࠖ/ ⟃Ἴ኱Ꮫィ⟬⛉Ꮫ◊✲ࢭࣥࢱ࣮▮ⰼ୍ᾈᩍᤵࠕࢼࣀᵓ㐀యࡢගບ㉳㟁Ꮚࢲ࢖ࢼ࣑ࢡࢫࠖ/ ி㒔኱Ꮫ໬Ꮫ◊✲ᡤᑎす฼἞ᩍᤵ࣭బ⸨Ⰻኴຓᩍࠕࣉࣛࢬࣔࢽࢵࢡྜ
㔠ࢼࣀ⢏Ꮚࡢ๰ᡂࠖ/ ㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫඵ஭ᓫᩍᤵ࣭ᮾி
⌮⛉኱Ꮫ᰿ᓊ㞝୍ᩍᤵ࣭ᮾி⌮⛉኱Ꮫᕝ⬥ᚨஂㅮᖌࠕᢸᣢ
ࡋࡓ᭷ᶵ㔠ᒓ㘒యࡸ㔠ᒓࢼࣀࢡࣛࢫࢱ࣮ࢆ⏝࠸ࡿゐ፹ࡢ㛤Ⓨࠖ/ Alberta኱ᏛAndriy KOVALENKOᩍᤵࠕ㟁ᴟゐ፹཯ᛂ ࡢ ⌮ ㄽ ィ ⟬ ᡭ ἲ ࡢ 㛤 Ⓨ ࠖ / Uppsala ኱ Ꮫ Marcus
LUNDBERG෸ᩍᤵ࣭European XFELୖᮧὒᖹ༤ኈࠕෆ᰾X⥺Ⓨගࢫ࣌ࢡࢺࣝ࡟㛵ࡍࡿ◊✲ࠖ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦඲࡚ᑂᰝࡘࡁ㸧(1) Takekuma, H.; Sato, R.; Iida, K.; Kawawaki, T.; Haruta, M.;
Kurata, H.; Nobusada, K.; Teranishi, T. Intrinsic Visible
Plasmonic Properties of Colloidal PtIn2 Intermetallic
Nanoparticles. Adv. Sci. 2024, 11, 2307055.
(2) Iida, K.; Takeuchi, T.; Katsumi, R.; Yatsui, T. Variations in
Photoexcitation Mechanism of an Adsorbed Molecule on aGold Nanocluster Governed by Interfacial Contact. J. Phys.
Chem. A 2023, 127, 7718–7726.
(3) Kawawaki, T.; Mitomi, Y.; Nishi, N.; Kurosaki, R.; Oiwa,
K.; Tanaka, T.; Hirase, H.; Miyajima, S.; Niihori, Y.; Osborn,
D. J.; Koitaya, T.; Metha, G. F.; Yokoyama, T.; Iida, K.;
Negishi, Y. Pt17 Nanocluster Electrocatalysts: Preparation andOrigin of High Oxygen Reduction Reaction Activity.
Nanoscale 2023, 15, 7272-7279.
(4) Chiba, T.; Iida, K.; Furukawa, S.; Hasegawa, J. FirstPrinciples Study on Unidirectional Proton Transfer on Anatase
TiO2 (101) Surface Induced by External Electric Fields. Phys.
Chem. Chem. Phys. 2023, 25, 9454-9460.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟
(1) Iida, K.: "The Effect of Bias Voltage on the Interface between
an Electrode Catalyst and an Electrolyte Solution Revealed by
Theoretical and Computational Approach", ICAT-FHI
Symposium: Approaching to the Catalysis Reality, Institute for
Catalysis, Sapporo, Japan (2023/9/11). [Invited talk]ཷ㈹
(1) 㣤⏣೺஧ࡽ㸪
ࠕSALMON㸦Scalable Ab-initio Light-Matter
simulator for Optics and Nanoscience㸧ࠖ㸦2023/5/19㸧.ࠓ2023
ᖺᗘ HPCI ࢯࣇࢺ࢙࢘࢔㈹ዡບ㈹ࠔ

ᴾ

ᖺሗ࣭◊✲ᐊ⦅‫ە‬⏕యศᏊᶆ㆑ゐ፹◊✲ࢡࣛࢫࢱ࣮
Research Cluster for Catalytic Labeling of
Biomolecules‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑ࣮ࣜࢲ࣮෸ᩍᤵࠒὸ㔝ᆂభ࣭ࠑᐈဨᩍᤵ❧ᩍ኱Ꮫࠒᒣ
୰ṇᾈ࣭ࠑᏛእ◊✲༠ຊᩍဨ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒ⏕㛗ᖾஅຓ࣭ࠑᏛእ◊✲༠ຊᩍဨ኱㜰኱Ꮫࠒ┿㘠Ⰻᖾ࣭ࠑᏛእ◊✲༠ຊᩍဨ஑ᕞ኱Ꮫࠒᇼ㞝୍㑻࣭ࠑᏛእ◊✲༠ຊᩍဨ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒୖ⏣ၿᘯ‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
ᒣ୰ṇᾈᩍᤵࡀᮏࢡࣛࢫࢱ࣮࡟ཧ⏬ࡋࡓ㸬‫✲◊ڦ‬ㄢ㢟⏕యศᏊࡢືⓗᣲືࢆほᐹࡍࡿࡇ࡜ࡣ⏕࿨⌧㇟ࡢ⌮ゎ࡟ࡘ࡞ࡀࡿ㸬ࡇࡢࡓࡵࢱࣥࣃࢡ㉁ࡸ⢾㙐㸪ࡲࡓࡑࢀࡽࡀ┦஫స⏝ࡍࡿศᏊࢆ᳨ฟࡍࡿ໬Ꮫⓗᡭἲࡀᚲせ࡛࠶ࡿ㸬ࡋ࠿ࡋ㸪≉␗ⓗᶆ㆑཯ᛂࢶ࣮ࣝࡣ㑅ᢥ⫥ࡀࡲࡔ㝈ࡽࢀ࡚࠾ࡾ㸪᳨ฟ⢭ᗘ㸪⏕య౵くᛶ࡞࡝ࡢほⅬ࡛ࡶㄢ㢟ࡀ࠶ࡿ㸬ᮏ◊✲ࢡࣛࢫࢱ࣮࡛ࡣ㸪⏕యศᏊᣲືࢆ㧗⢭ᗘ࠿ࡘప⏕య౵くⓗ࡟ᶆ㆑ࡍࡿࡓࡵࡢ᪂ࡓ࡞཯ᛂࢶ࣮ࣝ࡟࡞ࡿศᏊゐ፹⣔ࢆ㛤Ⓨࡍࡿ㸬ࡲࡓ㸪⺯ගࣉ࣮ࣟࣈ࡟ࡼࡿྍど໬ゎᯒᢏ⾡ࡸ⏕యศᏊࡢ໬Ꮫྜᡂ࣭ಟ㣭ᢏ⾡ࢆ⼥ྜࡋ࡚㸪⏕యศᏊࡢືⓗᣲືࢆከゅⓗ࡟㏣㊧ࡋ㸪⏕࿨ᶵ⬟ࡢ⌮ゎ࡟ࡘ࡞ࡆࡿ㸬ࡇࢀࡽࡢ┠ᶆࢆ㐩ᡂࡍࡿࡓࡵ࡟㸪ࡑࡢᇶ┙࡟࡞ࡿ᭷ᶵゐ፹㸪ගゐ፹㸪཯ᛂ๣࡞࡝ࡢ໬Ꮫ཯ᛂࢶ࣮ࣝࡢ㛤Ⓨ࡜㸪⣽⬊⣔ࢆᑐ㇟࡜ࡋࡓ⏕య㐺ྜ໬Ꮫ࡟฼⏝࡛ࡁࡿゐ፹཯ᛂᢏ⾡ࡢ๰ฟࢆ୪⾜ࡋ࡚᥎㐍ࡋ࡚࠸ࡿ㸬
2023ᖺᖺᗘࡢࢺࣆࢵࢡ㸸Ⅳ⣲–Ⅳ⣲஧㔜⤖ྜ㸦࢜ࣞࣇ࢕ࣥ㸧ࡀᣢࡘ㌾ࡽ࠿࠸཯ᛂᛶࢆ฼⏝ࡋࡓ᭷ᶵゐ፹ࢆ㛤Ⓨࡋ㸪⮯⣲໬཯ᛂࢆ฼⏝ࡋࡓᶆ㆑ἲࡢ㛤Ⓨࢆ㐍ࡵ࡚࠸ࡿ㸦Fig. 1㸧㸬
2023ᖺᗘࡣ㸪࢜ࣞࣇ࢕ࣥゐ፹㛤Ⓨࡢᇶ┙࡟࡞ࡿ⨨᥮ࢩࢡࣟ࢜ࢡࢸࣥྜᡂἲࡢ㛤Ⓨ࡟ྲྀࡾ⤌ࢇࡔ㸬ࡲࡓ㸪⨨᥮ࢩࢡࣟ࢜
ࢡࢸࣥࢆ฼⏝ࡋ࡚Br2ᤕᤊ๣ࢆ㛤Ⓨࡋ㸪⮯⣲໬ゐ፹⣔ࡢ㛤Ⓨ࡟ᚲせ࡞ᶵᵓゎᯒࢶ࣮ࣝ࡟࡞ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓ㸬)LJ  ࢜ࣞࣇ࢕ࣥࡢ᭷ᶵゐ፹ᶵ⬟࡟ᇶ࡙ࡃ⏕యศᏊ⮯⣲໬ᶆ㆑཯ᛂ
㸦㸧ࢡࣟࢫ࢝ࢵࣉࣜࣥࢢ཯ᛂ࡟ࡼࡿ⨨᥮ࢩࢡࣟ࢜ࢡࢸࣥ㸬ࡢ㧗ຠ⋡ྜᡂࠓ⌧ᅾ⤖ᯝࢆㄽᩥ࡟ࡲ࡜ࡵ࡚࠸ࡿࠔ
ࢩࢡࣟ࢜ࢡࢸࣥㄏᑟయࡀ⮯⣲໬཯ᛂࡢ㧗άᛶゐ፹࡟࡞ࡾ㸪࢜ࣞࣇ࢕ࣥ㒊఩ࡢ⨨᥮ᇶࡀゐ፹άᛶ࡟኱ࡁࡃᙳ㡪ࡍࡿࡇ࡜ࢆ᪤࡟ぢ࠸ࡔࡋ࡚࠸ࡓ㸬ࡋ࠿ࡋ㸪ࡇࢀࡲ࡛࡟฼⏝ࡋ࡚࠸ࡓ⨨᥮ࢩࢡࣟ࢜ࢡࢸࣥࡢྜᡂἲࡣ㝈ᐃⓗ࡛ຠ⋡ࡀᝏ࠿ࡗࡓ㸬ࡑࡇ࡛㸪ࢡࣟࢫ࢝ࢵࣉࣜࣥࢢ཯ᛂࢆ฼⏝ࡋࡓ⨨᥮ࢩࢡࣟ࢜ࢡࢸࣥࡢ㧗ຠ⋡ྜᡂἲࢆ㛤Ⓨࡋࡓ㸦Fig. 2㸧㸬ᚑ᮶ἲࡼࡾࡶ▷ᕤ⛬࡟࡞ࡾ㸪ࡇࢀࡲ࡛ྜᡂ࡛ࡁ࡞࠿ࡗࡓㄏᑟయ
ࡢྜᡂࡶྍ⬟࡟ࡋࡓ㸬౛࠼ࡤ㸪1,2-஧⨨᥮ࢺࣛࣥࢫࢩࢡࣟ
࢜ࢡࢸࣥࡸࣁࣟࢤࣥᇶࡀ⨨᥮ࡋࡓࢩࢡࣟ࢜ࢡࢸࣥㄏᑟయ
ࢆึࡵ࡚ྜᡂࡋ㸪ࡑࢀࡽࡢゐ፹άᛶホ౯࡟ࡘ࡞ࡆࡓ㸬‫ە‬ᖺሗ࣭◊✲ᐊ⦅)LJ⨨᥮ࢩࢡࣟ࢜ࢡࢸࣥࡢࢡࣟࢫ࢝ࢵࣉࣜࣥࢢྜᡂ
㸦㸧%Uࡀ㛵୚ࡍࡿ⮯⣲໬཯ᛂ⤒㊰ࡢ㜼ᐖ๣࣭ࣉ࣮ࣟࣈ๣
ࡢ㛤Ⓨࠓㄽᩥ࣭Ꮫ఍Ⓨ⾲࣭ཷ㈹ࠔ
㸬⮯⣲໬࡟࠾࠸࡚ప 㸪↓ゐ፹࡛ࡶ㐍⾜ࡍࡿࣂࢵࢡࢢࣛ࢘
ࣥࢻ཯ᛂࡢཎᅉࡀ㸪཯ᛂ๣ NBS ࠿ࡽᚤ㔞⏕ᡂࡍࡿ Br2 ࡛࠶ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋ㸪ࡇࢀࢆᢚไࡍࡿᤕᤊ๣࡜ࡋ࡚ 2-ࣆࣜࢪ࢚ࣝࢳࣝ-1-ࢺࣛࣥࢫࢩࢡࣟ࢜ࢡࢸࣥࢆ㛤Ⓨࡋࡓ㸦Fig.
3㸧㸬ࡲࡓ㸪ᮏᤕᤊ๣ࢆゐ፹ⓗ⮯⣲໬཯ᛂ࡟ῧຍࡍࡿࡇ࡜࡛㸪㑅ᢥᛶࢆྥୖࡉࡏࡿࡇ࡜ࡀ࡛ࡁࡓ㸬ࡉࡽ࡟㸪ᮏᤕᤊ๣ࡣ
ࣂࢵࢡࢢࣛ࢘ࣥࢻ཯ᛂࡔࡅ࡛ࡣ࡞ࡃ Br2 ࡀ㛵୚ࡍࡿゐ፹཯ᛂࡢᢚไ࡟ࡶ฼⏝࡛ࡁ㸪ゐ፹ⓗ⮯⣲໬཯ᛂࡢᶵᵓ࡟ Br2 ࡀ㛵୚ࡋ࡚࠸ࡿ࠿࡝࠺࠿ࢆ᳨ฟࡍࡿࣉ࣮ࣟࣈ࡟ࡶ࡞ࡿࡇ࡜
ࢆ᫂ࡽ࠿࡟ࡋࡓ㸬)LJ%Uᤕᤊ๣
2023 ᖺᗘ࡟㛤Ⓨࡋࡓୖグࡢゐ፹ྜᡂἲ࠾ࡼࡧ໬Ꮫ཯ᛂ
ࢶ࣮ࣝࡣ㸪௒ᚋࡢ⏕యศᏊᶆ㆑ゐ፹⣔ࡢ㛤Ⓨࢆຍ㏿ࡍࡿᇶ┙ᢏ⾡࡟࡞ࡿ㸬‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧ி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ ᯇཎㄔ஧㑻ᩍᤵࠕⅣ⣲–Ⅳ⣲஧㔜⤖ྜࡢ᭷ᶵゐ፹ᶵ⬟㛤ᣅࠖ/஑ᕞ኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲㝔 ᇼ㞝୍㑻ᩍᤵࠕ⣽⬊⭷ࢱࣥࣃࢡ㉁࡟࠾ࡅࡿ㏆᥋⮯⣲໬ᶆ㆑ἲࡢ㛤Ⓨࠖ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮ ⏕㛗ᖾஅຓ◊✲ࢳ࣮࣒㛗ࠕගゐ፹ⓗࢺࣜࣉࢺࣇ࢓
ࣥಟ㣭ࡢࡓࡵࡢ཯ᛂ๣㛤Ⓨࠖ/⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬
Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮ ୖ⏣ၿᘯ୺௵◊✲ဨࠕගゐ፹ⓗࢳࣟࢩࣥ⮯⣲໬཯ᛂࡢᶵᵓゎ᫂ࠖ/኱㜰኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲⛉┿㘠Ⰻᖾຓᩍࠕ㠀ኳ↛⢾ࢱࣥࣃࢡ㉁ྜᡂἲࡢ㛤Ⓨࠖ/❧ᩍ኱Ꮫ⌮Ꮫ㒊 ᒣ୰ṇᾈᩍᤵࠕィ⟬໬Ꮫ࡟ࡼࡿࢩࢡࣟ࢜ࢡࢸࣥ
ゐ፹཯ᛂࡢᶵᵓゎᯒࠖ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼⥲ㄝゎㄝሗ࿌
(1) Murata, R.; Shitamichi, K.; Hiramatsu, M.; Matsubara, S.;
Uraguchi, D.; Asano, K. trans-Cyclooctenes as Scavengers ofBromine Involved in Catalytic Bromination. Chem.—Eur. J.
2024, 30, e202303399.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟(1) ὸ㔝ᆂభ㸸ࠕ㑅ᢥⓗゐ፹཯ᛂ✵㛫ࢆᣑᙇࡍࡿ཯ᛂࢶ࣮ࣝࡢ๰〇ࠖ㸪Ꮫ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓ㸦IRCCS㸧ᡂᯝሗ࿌఍࣭⏘Ꮫ࣮࣡ࢡࢩࣙࢵࣉ㸪஑ᕞ኱Ꮫ㸦2024/01/30㸧.㹙ᣍ
ᚅㅮ₇㹛

57

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(1) ྜྷ⏣ᴦே㸸ࠕ⏕య㐺ྜ໬Ꮫࢆᣦྥࡋࡓ⮯⣲໬๣BODNࡢ
㛤Ⓨࠖ㸪➨35ᅇ୓᭷ᮐᖠࢩ࣏ࣥࢪ࣒࢘㸦2023/07/01㸧
ࠓBest

5858

Poster㈹ࠔ
(2) ᮧ⏣❳୍㸸ࠕゐ፹཯ᛂࡢࣂࢵࢡࢢࣛ࢘ࣥࢻ⤒㊰ࢆᢚไࡍࡿῧຍ๣ࡢ㛤Ⓨࠖ㸪➨9ᅇ໭኱࣭㒊ᒁᶓ᩿ࢩ࣏ࣥࢪ࣒࢘
㸦2023/10/11㸧ࠓ࣋ࢫࢺ࣏ࢫࢱ࣮㈹ࠔ

ᖺሗ࣭◊✲ᐊ⦅‫ە‬ࢹ࣮ࢱ㥑ືᆺゐ፹◊✲ࢡࣛࢫࢱ࣮
Research Cluster of Data-Driven Catalyst
Developments‫ڦ‬2023ᖺᗘࡢᵓᡂဨ

ゐ ፹ (Pt(3)/Rb(1)-Ba(1)-Mo(0.6)-Nb(0.2)/TiO2) ࡟ ࡣ 㸪 ึ ᮇࢹ࣮ࢱࢭࢵࢺ࡟ࡣྵࡲࢀ࡚࠸࡞࠿ࡗࡓඖ⣲(Nb)ࡶ౑⏝ࡉࢀ࡚࠸ࡓ㸬ࡇࢀࡣ㸪㛤Ⓨࡋࡓᡭἲࡀእᤄⓗ᥈⣴ࢆຠ⋡ࡼࡃ⾜࠼ࡿ⏬ᮇⓗ࡞ᶵᲔᏛ⩦ࣔࢹ࡛ࣝ࠶ࡿࡇ࡜ࢆ➃ⓗ࡟♧ࡋ࡚࠸ࡿ㸬ࠑ࣮ࣜࢲ࣮෸ᩍᤵࠒ㫽ᒇᑿ㝯࣭ࠑᏛእ◊✲༠ຊᩍဨDelft
University of Technology㸦࢜ࣛࣥࢲ㸧ࠒᾆᕝ⠜࣭ࠑᏛእ◊✲༠
ຊᩍဨPaul Scherrer Institut㸦ࢫ࢖ࢫ㸧
ࠒDavide FERRI࣭ࠑᏛእ◊✲༠ຊᩍဨ⚄ዉᕝ኱Ꮫࠒ▼ᕝ⌮ྐ࣭ࠑᏛእ◊✲༠ຊᩍ
ဨ៞᠕⩏ሿ኱Ꮫࠒ㇏ᓥ㑈㻌‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ ᫖ᖺᗘ࡟ᘬࡁ⥆ࡁୖグྡࡀཧ⏬ࡋ࡚◊✲ࢆ⾜ࡗࡓ㸬‫✲◊ڦ‬ㄢ㢟 ゐ፹ࢆࡣࡌࡵ࡜ࡍࡿᮦᩱ⛉Ꮫ◊✲ࡣᮍࡔࠕ⤧Ẩ⇿ᧁⓗ࡞ࢫࢡ࣮ࣜࢽࣥࢢࠖ࠿ࡽ⬺༷࡛ࡁ࡚࠸࡞࠸㸬◊✲⪅ࡣࡇࢀࡲ࡛㸪኱㔞ࡢᐇ㦂ࢹ࣮ࢱ࣭ᩥ⊩▱࣭⤒㦂▱ࢆ⤫ྜࡋ࡚㸪ண ࣭௬ㄝࡢᙧᡂࢆ⾜ࡗ࡚ࡁࡓࡀ㸪ᖺࠎቑ࠼⥆ࡅࡿ⭾኱࡞ࢹ࣮ࢱ࣭▱ぢࢆ࿪ᄮࡋ㸪┠ⓗ࡟ᑐࡋ࡚㐺ษ࡞௬ㄝࢆᥦ౪࡛ࡁࡿ
ேᮦࡣⓙ↓࡛࠶ࡿ㸬ே▱࡟ᇶ࡙ࡃ◊✲ࡣ㝈⏺ࢆ㏄࠼࡚࠾ࡾ㸪ࢹ࣮ࢱ⛉Ꮫࡢඛ㐍ᢏ⾡ࢆᑟධࡋ࡚ᮦᩱ⛉Ꮫ◊✲ࡢᅾࡾ᪉ࢆๅ᪂ࡍࡿࡇ࡜ࡀồࡵࡽࢀ࡚࠸ࡿ㸬ᮏࢡࣛࢫࢱ࣮◊✲࡛ࡣ㸪ᐇ㦂࣭⌮ㄽ࣭ࢹ࣮ࢱ⛉Ꮫࢆ⼥ྜࡋࡓ᪂ࡋ࠸ゐ፹◊✲ࡢ᪉ἲㄽࢆ☜❧ࡍࡿࡇ࡜ࢆ┠ᣦࡍ㸬ᮏ◊✲࡟ࡼࡾ㞟✚ࡉࢀࡓᐇ㦂ࢹ࣮ࢱ㸪ィ⟬⛉Ꮫ࡟ࡼࡿ▱ぢࢆ⤫ྜࡋ࡚ᑐ㇟࡜ࡍࡿゐ፹཯ᛂ࣭ศ㔝ࡢ⌮ㄽࢆయ⣔໬ࡍࡿ㸬ࡲࡓ㸪㛤Ⓨࡋࡓ᪂つゐ፹ࢆ༢࡞ࡿ1ᡂຌ౛࡟⤊ࢃࡽࡏࡿࡇ
࡜࡞ࡃ㸪ࡑࡢ㧗ᛶ⬟せᅉࢆᢳฟࡋ୍⯡໬ࡍࡿࡇ࡜࡛㸪ࡉࡽ࡞ࡿ㧗άᛶゐ፹㛤Ⓨࡢ♏࡜ࡍࡿ㸬
2023ᖺᖺᗘࡢࢺࣆࢵࢡ㸸እᤄⓗ᥈⣴ࡀྍ⬟࡞ᶵᲔᏛ⩦ᡭἲ㸬
࡟ࡼࡿ&2ኚ᥮ゐ፹㛤Ⓨࠓㄽᩥ1ࠔ࣮ࣝࣝ࡜ࢦ࣮ࣝࡀ᫂☜࡞͆᭱㐺໬◊✲͇࡟࠾࠸࡚ࡣ㸪ᶵᲔᏛ⩦ࢆ୰ᚰ࡜ࡋࡓேᕤ▱⬟(AI)ᢏ⾡ࡣᅽಽⓗ࡞ຊࢆⓎ᥹ࡋ㸪໬Ꮫ࣭ᮦᩱศ㔝࡟࠾࠸࡚ࡶࡍ࡛࡟ᡂຌ౛ࡀฟጞࡵ࡚
࠸ࡿ㸬୍᪉㸪┿࡟㠉᪂ⓗ࡞ᮦᩱ࣭ゐ፹ࡢ㛤Ⓨࡣᮍࡔ㐩ᡂࡉࢀ࡚࠸࡞࠸㸬㠉᪂ⓗ࡞ᮦᩱ࣭ゐ፹ࡢⓎぢࡣ௒ࡲ࡛ࡢࢹ࣮ࢱ
୰࡟↓࠸ඖ⣲㸪ࡶࡋࡃࡣ౑⏝㢖ᗘࡢᴟࡵ࡚ᑡ࡞࠸ඖ⣲ࡢά⏝࠿ࡽ⏕ࡲࢀࡿࡶࡢ࡛࠶ࡿࡀ㸪ᚑ᮶ᆺࡢ AI ᢏ⾡࡛ࡣࢹ࣮ࢱࡢ୰࡟ྵࡲࢀ࡚࠸࡞࠸᝟ሗࡣᥦ᱌࡛ࡁ࡞࠸ࡓࡵ࡛࠶ࡿ㸬ࡘࡲࡾ㸪AI ࡀᥦ᱌ࡍࡿゐ፹ೃ⿵ඖ⣲ࡣ᪤ฟࡢࡶࡢ࡜࡞ࡾ
(ෆᤄⓗᥦ᱌)㸪ᮍ᥈⣴ࡢඖ⣲ࢆᥦ᱌(እᤄⓗᥦ᱌)ࡍࡿࡇ࡜
ࡣ࡞࠸㸬 ᡃࠎࡢࢢ࣮ࣝࣉ࡛ࡣ㸪ࡇࡢእᤄⓗᥦ᱌ࢆᐇ⌧ࡍࡿࡇ࡜ࢆ
┠ⓗ࡜ࡋࡓ ML ࣔࢹࣝࢆ㛤Ⓨࡋ࡚ࡁࡓࡓ㸬ᮏࣔࢹ࡛ࣝࡣ㸪ゐ፹ᵓᡂඖ⣲ࡑࡢࡶࡢࢆᏛ⩦࡟౑࠺ࡢ࡛ࡣ࡞ࡃ㸪ࡑࡢ≉ᚩ㔞(㟁Ẽ㝜ᛶᗘ㸪⼥Ⅼ➼)࡜ᵓᡂẚࡢ✚ࢆண グ㏙Ꮚ࡜ࡋ࡚⏝࠸ࡿࡇ࡜࡛㸪ඖࠎࡢࢹ࣮ࢱࢭࢵࢺ࡟ྵࡲࢀ࡚࠸ࡿඖ⣲࡟⦡ࡽࢀࡿࡇ࡜࡞ࡃ᭷ᮃ࡞ゐ፹ೃ⿵ඖ⣲ࢆᥦ᱌ࡍࡿࡇ࡜ࡀ
ྍ⬟࡛࠶ࡿ㸬
ᮏ◊✲࡛ࡣ, ࡇࡢ ML ᡭἲࢆά⏝ࡋ㸪CO2 Ỉ⣲໬཯ᛂࡢ1 ࡘ ࡛ ࠶ ࡿ ㏫ Ỉ ᛶ ࢞ ࢫ ࢩ ࣇ ࢺ (Reverse Water Gas Shift:
RWGS; CO2+H2 ЍCO+H2O)཯ᛂ࡟᭷ຠ࡞ከඖ⣲ྵ᭷ゐ፹ࢆ㛤Ⓨࡋࡓ.ලయⓗ࡟ࡣ㸪45 Ⅼࡢึᮇࢹ࣮ࢱࢭࢵࢺ࠿ࡽ㸪ᶵᲔᏛ⩦ண +ᐇ㦂ࡢࢧ࢖ࢡࣝࢆ 44 ᅇ⧞ࡾ㏉ࡍࡇ࡜࡟ࡼ
ࡾ㸪ྜィ 300 ௳ࡢゐ፹ࡢάᛶࢆホ౯ࡋࡓ(Fig. 1)㸬ࡑࡢ⤖ᯝ㸪
250 Υ௨ୗ࡛ࡢ᪤ሗ RWGS ゐ፹࡜ࡋ࡚᭱ࡶ㧗࠸ CO ⏕ᡂ㏿ᗘࢆ♧ࡍ Pt(3)/Mo(10)/TiO2 (ᩘ್༢఩ࡣ wt%)ࡼࡾࡶ㧗࠸άᛶࢆ♧ࡍゐ፹ࢆ 100 ௳௨ୖぢฟࡋࡓ㸬⌧≧ࡢ᭱㧗άᛶ‫ە‬ᖺሗ࣭◊✲ᐊ⦅)LJᶵᲔᏛ⩦ࢆ฼⏝ࡋࡓ5:*6ゐ፹ࡢ㛤Ⓨ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦ࡍ࡭࡚ᑂᰝࡘࡁ㸧(1) Wang, G.; Mine, S.; Chen, D.; Jing, Y.; Ting, K.-W.;
Yamaguchi, T.; Takao, M.; Maeno, Z.; Takigawa, I.;
Matsushita, K.; Shimizu, K.; Toyao, T. Accelerated discovery
of multi-elemental reverse water-gas shift catalysts using
extrapolative machine learning approach, Nature Commun.
2023, 14, 5861.
(2) Jing, Y.; He, C.; Zhang, N.; Murano, Y.; Toyoshima, R.;
Kondoh, H.; Kageyama, Y.; Inomata, H.; Toyao, T.; Shimizu,
K. Promotional Effect of Ag on the Catalytic Decomposition of
N2O in the Presence of O2 over the Al2O3‑Supported Rh
Catalyst, ACS Catal. 2023, 13, 12983-12993.
(3) Mine, S.; Toyao, T.; Shimizu, K.; Hinuma, Y. Comparisonof Matlantis and VASP Bulk Formation and Surface Energies
in Metal Hydrides, Carbides, Nitrides, Oxides, and Sulfides,
Chem. Lett. 2023, 52, 757-759.
(4) Phongprueksathat, N.; Ting, K.-W.; Mine, S.; Jing, Y.;
Toyoshima, R.; Kondoh, H.; Shimizu, K. Toyao, T.; Urakawa,
A. Bifunctionality of Re Supported on TiO2 in Driving
Methanol Formation in Low-Temperature CO2 Hydrogenation,
ACS Catal. 2023, 13, 10734-10750.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟(1) 㫽ᒇᑿ㝯㸸ࠕࢹ࣮ࢱ㥑ືᆺᅛయゐ፹㛤Ⓨ࡜ᨺᑕගࢆ⏝࠸ࡓゐ፹స⏝ᶵᵓ◊✲ࠖ, ➨1ᅇ ඛ➃ᨺᑕගά⏝◊✲఍ࠕᨺᑕගࢆ⏝࠸ࡓゐ፹࢟ࣕࣛࢡࢱࣜࢮ࣮ࢩࣙࣥࡢ⌧ᅾ࡜ᮍ᮶ࠖ, ໭ᾏ㐨኱Ꮫ㸦2023/7/22㸧
㸬[Invited](2) 㫽ᒇᑿ㝯㸸ࠕࢹ࣮ࢱ⛉Ꮫࢆ฼⏝ࡋࡓᅛయゐ፹㛤Ⓨࠖ, ➨132ᅇゐ፹ウㄽ఍, ໭ᾏ㐨኱Ꮫ㸦2023/9/15㸧
㸬[Invited](3) 㫽ᒇᑿ㝯㸸ࠕᶵᲔᏛ⩦࡟ࡼࡿከඖ⣲ゐ፹ࡢ㛤Ⓨ࡜insitu/operandoศග࡟ࡼࡿస⏝ᶵᵓㄪᰝࠖ, ➨9ᅇSPring-8ඛ
➃ᨺᑕගᢏ⾡࡟ࡼࡿ໬Ꮫ࢖ࣀ࣮࣋ࢩࣙࣥ◊✲఍, ᮾி㸦2023/9/18㸧
㸬[Invited](4) Toyao, T.; ͆Machine-learning-assisted discovery of multielemental RWGS catalyst and its mechanistic study using insitu/operando spectroscopies ͇ , Operando VII - the 7thInternational Congress on Operando Spectroscopy, Switzerland
㸦2023/5/8㸧
㸬[Keynote](5) Toyao, T.; ͆Data-driven catalyst design for CO2 hydrogenation reactions͇, ICAT-FHI Symposium: Approaching
to the Catalysis Reality, Sapporo㸦2023/9/11㸧
㸬[Invited]59ኳ↛Ⅳ⣲㈨※ά⏝◊✲ࢡࣛࢫࢱ࣮/Research Cluster for for Utilization of
Natural Carbon Resources‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑ࣮ࣜࢲ࣮/෸ᩍᤵࠒⳢ἟Ꮫྐ㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/ᮾ໭኱Ꮫࠒຍ⸨ⱥᶞ㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/ᮾிᕤᴗ኱Ꮫࠒ໭㔝ᨻ᫂㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/㫽ྲྀ኱Ꮫࠒ㔝ୖᩄᮦ㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/ᮾிᕤᴗ኱Ꮫࠒ㔝ᮧ῟Ꮚ㹙2023/06/01㹼㹛࣭ࠑᏛእ◊✲༠ຊᩍဨ/኱㜰኱Ꮫࠒ᳃ᾈு㹙2023/06/01㹼㹛

‫ڦ‬2023ᖺᗘࡢ࠺ࡈࡁ
ୖグ 6 ྡࡀᮏࢡࣛࢫࢱ࣮࡟ཧ⏬ࡋࡓ㸬‫✲◊ڦ‬ㄢ㢟ᮏࢡࣛࢫࢱ࣮࡛ࡣ㸪」ᩘࡢάᛶࢧ࢖ࢺࢆࡶࡘᅛయゐ፹ࡢ༠ാᶵ⬟ࢆ฼⏝ࡋ࡚㸪ኳ↛Ⅳ⣲㈨※ࢆᇶᖿ໬Ꮫရ࡬㌿᥮ࡍࡿゐ፹཯ᛂࢆࢹࢨ࢖ࣥࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚࠸ࡿ㸬ከᵝ࡞ᴟᛶᐁ⬟ᇶࢆ᭷ࡍࡿኳ↛Ⅳ⣲㈨※ࢆᇶᖿ໬Ꮫရ࡬ኚ᥮ࡍ
ࡿࡓࡵ࡟ࡣ㸪ᴟᛶᐁ⬟ᇶࡢC-O⤖ྜ㸪C-N⤖ྜ㸪C-C⤖ྜ㸪
C-H⤖ྜࢆ⮬ᅾ࡟㛤⿣ࡍࡿゐ፹཯ᛂࢆᵓ⠏ࡍࡿᚲせࡀ࠶ࡿ㸬ࡇࢀࡲ࡛࡟㈗㔠ᒓࢼࣀ⢏Ꮚ࡜పཎᏊ౯㓟໬≀✀ࡢ༠ാస⏝࡟ࡼࡾ㸪࢝ࣝ࣎ࣥ㓟࣭࢔࣑ࢻࡢỈ⣲໬㸪Ỉ㓟ᇶࡸ࢚࣮
ࢸࣝࡢC-O⤖ྜ㛤⿣ࡀಁ㐍ࡉࢀࡿࡇ࡜ࢆぢฟࡋ࡚ࡁࡓ㸬༢୍ࡢάᛶࢧ࢖ࢺ࡛ࡣ୙ྍ⬟࡞ᐁ⬟ᇶኚ᥮཯ᛂ࡟ᑐࡋ࡚」ᩘࡢάᛶࢧ࢖ࢺࢆࡶࡘ༠ാᶵ⬟ゐ፹ࢆࢹࢨ࢖ࣥࡋ㸪ኳ↛Ⅳ⣲㈨※ࡢከᵝ࡞ᐁ⬟ᇶࢆ⮬ᅾ࡟㛤⿣࣭⤖ྜࡍࡿゐ፹཯ᛂࣉࣟࢭࢫࢆᵓ⠏ࡍࡿ㸬ࢱ࣮ࢤࢵࢺ࡜ࡍࡿᇶ㉁ࡣࣂ࢖࣐࢜ࢫ⏤᮶ࡢᑠࡉ࡞᭷ᶵศᏊ࡟㝈ᐃࡏࡎ㸪ࢭ࣮ࣝࣟࢫࡸ࢟ࢳࣥ࡞࡝
ࡢኳ↛㧗ศᏊࡸᗫࣉࣛࢫࢳࢵࢡ࡞࡝ࡢゎ㔜ྜ࣭ศゎ࡟ࡘ࠸࡚ࡶ◊✲ࢆ⾜ࡗ࡚࠸ࡿ㸬1㸬㸬࢔࣑ࣀ㓟࠿ࡽྵ❅⣲໬Ꮫရཎᩱࢆྜᡂࡍࡿࣉࣟࢭࢫࡢ
ᵓ⠏⁐๣㸪࣏࣐࣮ࣜ㸪་㎰⸆ရ࡞࡝ࡢ㔜せ࡞໬Ꮫရཎᩱࡣ࢔
࣑ࣥ㸪࢔࣑ࢻ㸪ࢽࢺࣜࣝࡢࡼ࠺࡞ྵ❅⣲ᐁ⬟ᇶࢆ᭷ࡍࡿ㸬ࡇࢀࡽࡣ▼Ἔ⏤᮶ࡢⅣ໬Ỉ⣲࡟❅⣲ࢆᤄධࡋ࡚ྜᡂࡉࢀ㸪ࡑࡢ❅⣲※࡜ࡋ࡚ NH3 ࡀ୺࡟౑ࢃࢀࡿ㸬ỗ⏝ⓗ࡟ධᡭྍ⬟࡞࢔࣑ࣀ㓟ࢆྵ❅⣲໬ྜ≀ཎᩱ࡜ࡋ࡚฼⏝࡛ࡁࢀࡤ㸪
NH3 ࢆᚲせ࡜ࡋ࡞࠸⎔ቃప㈇Ⲵᆺࣉࣟࢭࢫࢆᵓ⠏࡛ࡁࡿ㸬⢾㢮ࡢⓎ㓝࡟ࡼࡾ〇㐀ࡉࢀࡿࢢࣝࢱ࣑ࣥ㓟ࢆ⬺Ỉ࣭⬺Ⅳ㓟ࡍࡿ࡜໬Ꮫᕤᴗ⁐๣ࡸ⏕ศゎᛶ㧗ศᏊཎᩱ࡟฼⏝ྍ⬟
࡞ 2-ࣆࣟࣜࢻࣥࡀᚓࡽࢀࡿ㸦ᅗ 1㸧㸬❅⣲㞺ᅖẼࡢỈ⁐ᾮ୰࡛ࢢࣝࢱ࣑ࣥ㓟ࢆ⬺Ỉ⎔໬ࡋ㸪࢝ࣝ࣎࢟ࢩᇶࡢ┤᥋ⓗ⬺Ⅳ㓟࡟ࡼࡾ 2-ࣆࣟࣜࢻࣥ࡬ኚ᥮ࡍࡿሗ࿌౛ࡀ࠶ࡿ㸬୍᪉㸪
ᡃࠎࡣ Ru/Al2O3 ࢆ฼⏝ࡋ㸪࢝ࣝ࣎࢟ࢩᇶࡢỈ⣲໬࡜ࡑࡢᚋࡢ⬺࢝ࣝ࣎ࢽࣝ໬࡟ࡼࡿ͆㛫᥋ⓗ࡞⬺Ⅳ㓟཯ᛂ͇࡟ࡼࡾ㸪࿴࡞཯ᛂ ᗘ࡟࡚ࢢࣝࢱ࣑ࣥ㓟࠿ࡽ 2-ࣆࣟࣜࢻࣥࢆ⏕ᡂࡍࡿࡇ࡜ࡀ࡛ࡁࡓ㸬ࡲࡓ㸪ࢮ࢜ࣛ࢖ࢺᢸᣢ Ru ゐ፹ࢆ฼⏝ࡍࡿ࡜㸪୰㛫యࡀࡶࡘ࢝ࣝ࣎ࢽࣝᇶࡢỈ⣲໬ࡀ㐍⾜ࡋ࡚ࣆࣟࢢࣝࢱ࣑ࣀ࣮ࣝࡀ㑅ᢥⓗ࡟⏕ᡂࡍࡿࡇ࡜ࡶぢฟࡋࡓ㸬- H2O࢔࣑ࣀ㓟ࡢỈ⣲໬ࡣ㠀ᖖ࡟㔜せ࡞཯ᛂ࡛࠶ࡿ㸬౛࠼ࡤ㸪࢔࣑ࣀ㓟ࡢගᏛάᛶࢆಖᣢࡋ࡚Ỉ⣲໬࡛ࡁࢀࡤ㸪་㎰⸆ရࡢཎᩱ࡜ࡋ࡚฼⏝ྍ⬟࡞࢔࣑ࣀ࢔ࣝࢥ࣮ࣝࡀྜᡂ࡛ࡁࡿ㸬㏻ᖖ㸪࢔࣑ࣀ࢔ࣝࢥ࣮ࣝࡢỈ⣲໬࡛ࡣ⎔ቃ㈇Ⲵࡢ୺せᅉ࡜࡞ࡿᙉຊ࡞㑏ඖ๣࡛࠶ࡿ LiAlH4 ࢆ฼⏝ࡋ࡞ࡅࢀࡤ࡞ࡽ࡞
࠸㸬ࡑࡇ࡛ᡃࠎࡣ㸪Ỉ⣲ศᏊࢆ㑏ඖ๣࡜ࡋỈ⁐ᾮ୰࡛ࡢᅛయゐ፹࡟ࡼࡿ࢔࣑ࣀ㓟ࡢỈ⣲໬ࣉࣟࢭࢫࢆ᳨ウࡋࡓ㸬࢔࣑ࣀ㓟ࡢ୰࡛ࣉࣟࣜࣥࡣ၏୍ࡢ❅⣲࣊ࢸࣟ⎔໬ྜ≀࡛࠶ࡾ㸪Ỉ⣲໬ࡋࡓ L-ࣉࣟࣜࣀ࣮ࣝࡣගᏛάᛶࢆࡶࡘ࣊ࢸࣟ⎔ࣅࣝࢹ࢕ࣥࢢࣈࣟࢵࢡ࡜ࡋ࡚⏕⌮άᛶ໬ྜ≀ࡢྜᡂ࡟᭷⏝࡛࠶ࡿ㸬Pt-MoOx/Al2O3 ࡟ࡼࡿ L-ࣉࣟࣜࣥࡢỈ⣲໬㸦ᅗ 2㸧࡛ࡣ㸪L-ࣉࣟࣜࣀ࣮ࣝࢆ㑅ᢥ⋡ 75%㸪㙾ീయ㐣๫⋡ 99.9%
௨ୖ࡛ᚓࡽࢀࡓ㸬ࡇࢀࡲ࡛ࡢᅛయゐ፹ࡢሗ࿌౛࡟ẚ࡭ࡿ࡜㸪▷᫬㛫࡛⏕⌮άᛶࢆ♧ࡍ⎔≧஧⣭࢔࣑ࣥࡢ L-ࣉࣟࣜࣀ࣮
ࣝࢆ⏕ᡂ࡛ࡁ࡚࠾ࡾ㸪≉࡟ᴟࡵ࡚㧗࠸㙾ീయ㐣๫⋡ࡣ≉➹ࡍ࡭ࡁ⤖ᯝ࡛࠶ࡿ㸬ࡲࡓ㸪୍⣭࢔࣑ࣥࢆ᭷ࡍࡿ L-ࣂࣜࣥࡢỈ⣲໬㸦ᅗ 2㸧࡟࠾࠸࡚ࡶ Pt-MoOx/Al2O3 ࡣ㧗άᛶࢆ♧ࡋ㸪ගᏛάᛶࢆಖᣢࡋ࡚ L-ࣂࣜࣀ࣮ࣝࢆ⏕ᡂࡋࡓ㸬୍⣭࣭஧⣭࢔࣑ࣥࢆ᭷ࡍࡿ࢔࣑ࣀ࢔ࣝࢥ࣮ࣝࡀᴟࡵ࡚㧗࠸㙾ീయ㐣๫⋡࡛ྜᡂ࡛ࡁࡿࡇ࡜ࢆぢฟࡋࡓ㸬Pt-MoOx/Al2O3 ࡢ≉ᚩࡣ㸪MoOx ୖ࡛άᛶ໬ࡉࢀࡓ࢝ࣝ࣎ࢽࣝᇶࡀ Pt ୖ࡛୙ᆒ୍
㛤⿣ࡋࡓỈ⣲✀࡟ࡼࡾ㑅ᢥⓗ࡟Ỉ⣲໬ࡉࢀࡿࡇ࡜࡟࠶ࡿ㸬⏕ᡂ≀ࡢࣛࢭ࣑໬ࡣ L-ࣉࣟࣜࣀ࣮ࣝࡢ-CH2OH ᇶࡢάᛶ໬࡟ࡼࡗ࡚ㄏ㉳ࡉࢀ࡚࠾ࡾ㸪Pt-MoOx/Al2O3 ࡢ㧗࠸㙾ീయ㐣๫⋡ࡣ Pt ࢼࣀ⢏Ꮚ࡟ࡼࡗ࡚-CH2OH ᇶࡢάᛶ໬ࡀ㉳ࡇࡽ࡞࠸ࡇ࡜࡟㉳ᅉࡋ࡚࠸ࡿ㸬
+ 2H2

+ 2H2

- H2O
L-ἩἿἼὅ

- H2O
L-ἩἿἼἠὊἽ

L-ἢἼὅ

L-ἢἼἠὊἽ

ᅗ 2. L-࢔࣑ࣀ㓟࠿ࡽ L-࢔࣑ࣀ࢔ࣝࢥ࣮ࣝࡢྜᡂ
2023ᖺᗘࡢࢺࣆࢵࢡ㸸ࣆࣟࢢࣝࢱ࣑ࣥ㓟ࡢỈ⣲໬⏕ᡂ≀࡛࠶ࡿࣆࣟࢢࣝࢱ࣑ࣀ࣮ࣝࡣከᵝ࡞ᴟᛶᐁ⬟ᇶࢆࡶࡕ㸪ගᏛάᛶࡶ᭷ࡍࡿࡓࡵ2-ࣆࣟࣜࢻࣥࡼࡾࡶ௜ຍ౯್ࡢ㧗࠸໬ྜ≀࡜ࡋ࡚฼⏝ྍ⬟࡛࠶ࡿ㸬ࡑࡇ࡛㸪ࣆࣟࢢࣝࢱ࣑ࣥ㓟ࡢỈ⣲໬࡛ࣆࣟࢢࣝࢱ࣑ࣀ࣮ࣝ㑅ᢥ⋡ࢆቑࡸࡍࡓࡵ࡟㸪ࢮ࢜ࣛ࢖ࢺୖ࡛Ru✀ࡢࢧ࢖ࢬࡸᙧែࢆไᚚࡍࡿゐ፹タィࢆヨࡳࡓ㸬ࢮ࢜ࣛ࢖ࢺࢆᢸᣢRuゐ፹ࡢᢸయ࡟⏝࠸ࡿሙྜ㸪ࣆࣟࢢࣝࢱ࣑ࣥ㓟ࡢ࢝ࣝ࣎࢟ࢩᇶࡀỈ⣲໬ࡉࢀࡸࡍ࠸྾╔≧ែࢆᙧᡂ࡛ࡁ㸪Ruδ+ୖ࡛Ỉ⣲ศᏊࡢ㛤⿣ࡀಁ㐍ࡉࢀࡿࡢ࡛
Ỉ⣲໬άᛶࡀ㧗࠸࡜⪃࠼ࡽࢀࡿ㸬≉࡟㸪YFIᢸయ࡛ࡣRuࡢᖹᆒ⢏Ꮚᚄࡀᑠࡉࡃ㸪㔠ᒓࡢ㟢ฟ㠃✚ࡀ኱ࡁ࠸ࡓࡵỈ⣲໬άᛶࡀ㧗࠸ࡇ࡜ࡀ♧၀ࡉࢀࡓ㸬- CO22-ἦἿἼἛὅ

L-ἂἽἑἱὅᣠ

+ H2
- H2O

ᅗ 1. ࢢࣝࢱ࣑ࣥ㓟ࡢ㌿᥮

6060

- CO

ἦἿἂἽἑἱἠὊἽ

ᅗ 3㸬ࣆࣟࢢࣝࢱ࣑ࣥ㓟ࡢỈ⣲໬࡟࠾ࡅࡿᢸᣢ Ru ゐ፹ࡢᢸయࡢᙳ㡪ᖺሗ࣭◊✲ᐊ⦅‫ە‬‫ڦ‬Ꮫෆእࡢ◊✲⪅࡜ࡢඹྠ◊✲㸦2023ᖺᗘ㸧኱㜰኱Ꮫᒣཱྀ΅ຓᩍࠕ㔠ᒓⅣ໬≀ࡢࢼࣀ⢏Ꮚ໬࡟ࡼࡿ᪂ወ
ゐ፹స⏝๰ฟ࡜ࡑࢀ࡟ᇶ࡙ࡃᾮ┦ศᏊኚ᥮཯ᛂࡢ㛤Ⓨࠖ/ᚨᓥ኱Ꮫ㟖⏣┤ᏹຓᩍࠕᄇ㟝෾⤖㐀⢏஝⇱ἲ࡟ࡼࡿ
Ni/Al2O3 ゐ፹ࡢㄪ〇ཬࡧ CO2 ࣓ࢱࣥ໬཯ᛂ≉ᛶࠖ/໭஑ᕞ኱Ꮫ௒஭⿱அ෸ᩍᤵࠕࢮ࢜ࣛ࢖ࢺࢆᇶ┙࡜ࡋࡓ」ྜ㔠ᒓゐ፹ࡢྜᡂࠖ‫ڦ‬2023ᖺᗘࡢ◊✲ᴗ⦼ཎⴭㄽᩥ㸦ࡍ࡭࡚ᑂᰝࡘࡁ㸧(1) Jan J. Wiesfeld, Ryota Osuga, Satoshi Suganuma, Takayuki
Aoshima, Emiel J.M. Hensen, Kiyotaka Nakajima, Oxidative
Esterification of Acetal-Protected 5-Hydroxymethylfurfural to
Dimethyl Furan-2,5-dicarboxylate with High Recovery ofProtecting Agent. ACS Sustain. Chem. Eng., 2024, 12, 450-458.
(2) Nirupama Sheet, Ryota Osuga, Nao Arai, Jan J. Wiesfeld,
Satoshi Suganuma, Takayuki Aoshima, Atsushi Fukuoka,
Emiel J.M. Hensen, Kiyotaka Nakajima, A Protection Strategy
for High-yield Synthesis of Dimethyl Furan2,5-dicarboxylate
from 5-Hydroxymethylfurfural Using Methanol as an
Acetalizing Agent. ChemCatChem, 2024, e202301259.

‫ە‬ᖺሗ࣭◊✲ᐊ⦅(3) Naonobu Katada, Nobuki Ozawa, Etsushi Tsuji, Keigo
Kanehara, Akiho Otsuka, Taiga Sakamoto, Kirari Umezawa,
Hitoshi Matsubara, Satoshi Suganuma, Momoji Kubo,
Methylation of benzene with methane induced by strong
adsorption of benzene on Co ion at α-position in zeolite withmoderate Al-Al distance. Microporous Mesoporous Mater.,
2024, 364, 112855.
(4) Satoshi Suganuma, Naonobu Katada, Selective Conversion
of Polycyclic Aromatic Hydrocarbons in Practical Heavy Oil.
J. Jpn. Petrol. Inst., 2023, 66, 95-100.
⥲ㄝ࣭ゎㄝ(1) Ⳣ἟Ꮫྐ, ͆⢾࠿ࡽ⾰᭹ࢆࡘࡃࡿ͇
㸪໬Ꮫ࡜ᕤᴗ㸪2023,
76-10, 708-709.
ᣍᚅᇶㄪ౫㢗ㅮ₇࣭ᅜ㝿఍㆟
(1) Satoshi Suganuma: “Selective conversion of polycyclicaromatic hydrocarbons in petroleum”, ➨ 53 ᅇ▼Ἔ࣭▼Ἔ໬Ꮫウㄽ఍, ኱㜰⛉Ꮫᢏ⾡ࢭࣥࢱ࣮㸪኱㜰 (2023/10/26)㸬
[ᣍᚅㅮ₇](2) Ⳣ἟Ꮫྐ㸸ࠕ࢔࣑ࣀ㓟ࡢỈ⣲໬࡟ࡼࡿྵ❅⣲໬Ꮫရࡢཎᩱྜᡂࠖ㸪➨ 449 ᅇゐ፹⛉Ꮫ◊✲ᡤࢥ࣒ࣟ࢟࢘, ໭ᾏ㐨኱Ꮫ㸪໭ᾏ㐨 (2023/6/2)㸬[ᣍᚅㅮ₇]61‫إ‬ԓὉ᧽‫ޓ‬ᚑ‫ۥ‬ᡲઃᄂᆮἍὅἑὊ
report: Catalysis Collaborative Research Centerࣇࣜࢵࢶ࣭ࣁ࣮ࣂ࣮◊✲ᡤࣘࢽࢵࢺ/ Unitof Fritz-Haber-Institute‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑࣘࢽࢵࢺ㛗/ᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᐈဨᩍᤵ/Fritz Haber
Institute of the Max Planck Society ࠒ Hans-Joachim
FREUNDMatthias SCHEFFLER࣭ࠑᐈဨ෸ᩍᤵศᏊ⛉Ꮫ◊✲ᡤࠒ⇃㇂ᓫ࣭ࠑᩍᤵࠒᮅ಴Ύ㧘‫ڦ‬2023ᖺᗘࡢάືෆᐜ࣭◊✲ᡂᯝ ᮏࣘࢽࢵࢺࡣ㸪㒊ᒁ㛫Ꮫ⾡஺ὶ༠ᐃࢆ⥾⤖ࡋ࡚࠸ࡿࣇ
ࣜࢵࢶ࣭ࣁ࣮ࣂ࣮◊✲ᡤ㸦௨ୗ㸪FHI㸧࡜Ꮫ⾡஺ὶࢆ⥔ᣢ࣭
Ⓨᒎࡉࡏ㸪◊✲࡜ᩍ⫱࡟㛵ࡍࡿ㐃ᦠࢆᙉ໬ࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚㸪ᖹᡂ 28 ᖺ 4 ᭶ 1 ᪥࡟タ⨨ࡋࡓ㸬FHI ࡼࡾ HansJoachim FREUND ༤ኈ࡜ྠࡌࡃ Matthias SCHEFFLER ༤ኈ(Theory Department)ࢆᐈဨᩍᤵ࡜ࡋ࡚㸪⇃㇂ᓫࢢ࣮ࣝࣉ
࣮ࣜࢲ࣮(Physical Chemistry Department)ࢆᐈဨ෸ᩍᤵ࡜ࡋ
࡚ᣍࡁ㸪ᡤෆ࠿ࡽࡣᮅ಴Ύ㧘ᩍᤵ㸪㛗㇂ᕝ῟ஓᩍᤵࡀཧ⏬
ࡋ࡚࠸ࡿ㸬 2023 ᖺ 9 ᭶ 11 ᪥࡟㸪ICAT-FHI Symposium: Approaching
to the Catalysis Reality ࢆ㛤ദࡋ㸪Reuter FHI ᩍᤵࢆᣍ⪸ࡋ࡚ゐ፹⾲㠃ᵓ㐀࡟㛵ࡍࡿ㆟ㄽࢆ⾜ࡗࡓ㸬ᮏ◊✲ᡤ࠿ࡽ㧘ⲡᮌᩍᤵ㸪㣤⏣෸ᩍᤵ㸪㫽ᒇᑿ෸ᩍᤵࡀㅮ₇ࡋ㸪㛤ദ࡟༠ຊࡋࡓ㸬ࡲࡓ㸪ゐ፹⌮ㄽ◊✲㒊㛛ࡢᐑᓮ༤ኈࡀ2021ᖺ3᭶ࡼࡾ2023
ᖺ5᭶ࡲ࡛FHIࢩ࢙ࣇ࣮ࣛᩍᤵࡢୗ࡛༤ኈ◊✲ဨ࡜ࡋ࡚◊✲ࢆᐇ᪋ࡋ࡚࠸ࡿ㸬ࢩ࢙ࣇ࣮ࣛᩍᤵࡀ௻⏬ࡍࡿFUNCATࣉࣟࢪ࢙ࢡࢺ࡟ᐑᓮ㸪㛗㇂ᕝࡀཧ⏬ࡋ࡚࠸ࡿ㸬࢔ࡢᣢ⥆ⓗྜᡂࢆ ࿴࡞᮲௳࡛ᐇ⌧ࡍࡿᴟᚤ㔠ᒓࢡࣛࢫࢱ࣮ゐ፹ࡢ㛤Ⓨ㸪ゐ፹⾲㠃࡟྾╔ࡋࡓศᏊࡢືࡁ࡜ศᏊኚ
᥮㐣⛬ࢆྍど໬ࡍࡿᢏ⾡ࡢ㛤Ⓨ࡟ࡼࡿゐ፹཯ᛂᶵᵓࡢゎ᫂㸪୙つ๎࡛↓ᐃᙧ࡞ᯞศ࠿ࢀᆺ㧗ศᏊ࡟ᇶ࡙ࡃ❧యᵓ㐀ไᚚ࡟౫Ꮡࡋ࡞࠸㧗ຠ⋡࡞෇೫ගⓎගయࡢ㛤Ⓨ➼ࡢᡂᯝࢆᣲࡆ㸪ㄽᩥⓎ⾲ࢆ⾜ࡗࡓ㸬‫ڦ‬᮶ᖺᗘάືィ⏬ ࠕᏛ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓࠖࣉࣟࢪ࢙ࢡࢺࡢᯟ⤌ࡳࡢ୰࡛ྡྂᒇ኱Ꮫ㸪ி㒔኱Ꮫ㸪஑ᕞ኱Ꮫ࡜༠ຊࡋ࡚◊✲άືࢆ⾜࠸㸪ຍ࠼࡚㸪ᖺḟሗ࿌఍㸪ࢩ࣏ࣥࢪ࣒࢘➼࡟࡚◊✲ሗ࿌ࢆ⾜࠺㸬໭኱ゐ፹࢔ࣛ࢖࢔ࣥࢫࣘࢽࢵࢺ/ HU
Alliance for Catalysis Research‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑࣘࢽࢵࢺ㛗ᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᏛෆ◊✲༠ຊᩍဨᩍ
ᤵࠒ᳃᫓ⱥṊḟᚭஓᖜᓮᾈᶞྥ஭⤀ᑠすඞ᫂⚄㇂⿱୍⃝ᮧṇஓᛅỌΎ἞బ⸨⨾ὒࠑᏛෆ◊✲༠ຊᩍဨ෸ᩍ
ᤵࠒᆏཱྀ⣖ྐ

‫ڦ‬2023ᖺᗘࡢάືෆᐜ࣭◊✲ᡂᯝࠑࣘࢽࢵࢺ㛗ᩍᤵࠒ୰㔝⎔࣭ࠑᩍᤵࠒᮅ಴Ύ㧘㛗㇂ᕝ῟ஓ⚟ᒸ῟ΎỈ◊୍୰ᓥΎ㝯ᾆཱྀ኱㍜㧘ⲡᮌ㐩 ᮏࣘࢽࢵࢺࡣ㸪ඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬ஦ᴗࢆ㏻ࡋ࡚໭ᾏ㐨኱Ꮫࡢᶵ⬟ᙉ໬࡟㈉⊩ࡍࡿࡇ࡜㸪໭ᾏ㐨኱Ꮫࡢᙉࡳ࡛
࠶ࡿᒙࡢཌ࠸ゐ፹㛵㐃◊✲⪅ࡢ༠ຊࢆᚓ࡚㸪ඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬࢆᙉ໬ࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚࠸ࡿ㸬ᣐⅬ஦ᴗࡣᏛእࡢ◊✲⪅࡜ࡢඹྠ◊✲ࢆᨭ᥼ࡍࡿ஦ᴗ࡛࠶ࡿࡓࡵ㸪Ꮫෆࡢゐ፹◊✲⪅࡟࠾ࡅࡿ࣓ࣜࢵࢺࡀᑠࡉ࠸ḞⅬࡀ࠶ࡗࡓ㸬ࡑࡇ࡛㸪໭኱ゐ፹࢔ࣛ࢖࢔ࣥࢫࣘࢽࢵࢺࢆ㏻ࡋ࡚㸪Ꮫෆࡢゐ፹◊✲⪅ࢆඹྠ◊✲ཷධ◊✲⪅࡜ࡋ࡚ᣐⅬάື࡟ཧ⏬
ࡋ࡚࠸ࡓࡔࡁ㸪Ꮫእ࡜ࡢඹྠ◊✲ࢆ㈨㔠ⓗ࡟ࢧ࣏࣮ࢺ࡛ࡁ
ࡿࡼ࠺࡞యไࢆタࡅࡓ㸬ࡲࡓ㸪ࡇࡢࣘࢽࢵࢺࡢタ⨨ࢆ࡜࠾ࡋ࡚ᣐⅬࡢཷධ◊✲⪅ࡢࢫ࣌ࢡࢺࣝࢆᣑ኱ࡍࡿࡇ࡜ࡀ࡛
ࡁࡿࡢ࡛㸪Ꮫእࡢ◊✲⪅ࢥ࣑ࣗࢽࢸ࢕࣮ࡢ㑅ᢥ⫥ࡀᣑ኱ࡋ㸪ᣐⅬࡢᙉ໬࡟ࡘ࡞ࡆࡿࡇ࡜ࡀྍ⬟࡛࠶ࡿ㸬 ➨㸲ᮇ୰ᮇィ⏬ᮇ㛫࡟࠾ࡅࡿᣐⅬάືࡀㄆᐃࡉࢀࡓࡇ
࡜࡟క࠸㸪ᮏࣘࢽࢵࢺࡶタ⨨ࢆᘏ㛗ࡋ㸪Ꮫෆࡢゐ፹㛵㐃◊✲⪅ࢆඹྠ◊✲ࡢཷධ◊✲⪅࡜ࡋ࡚㸪άືࢆ⥅⥆ࡍࡿࡇ࡜࡜࡞ࡗࡓ㸬᫖ᖺᗘ࡟ᘬࡁ⥆ࡁ㸪ඹྠ฼⏝㸪ඹྠ◊✲ࡢබເ◊✲࡟࠾࠸࡚㸪ᮏࣘࢽࢵࢺ࡛ࡢඹྠ◊✲ࢆཷࡅධࢀࡓ㸬‫ڦ‬2023ᖺᗘࡢάືෆᐜ࣭◊✲ᡂᯝ‫ڦ‬᮶ᖺᗘάືィ⏬ᙜ◊✲ᡤࡀཧ⏬ࡍࡿࠕᏛ㝿⤫ྜ≀㉁๰〇໬Ꮫ᥎㐍ᶵᵓࠖ஦ᴗࡢ୍⎔࡜ࡋ࡚㸪ᅜ㝿ⓗ໬Ꮫ◊✲ᣐⅬ࡜༠ྠࡋ࡚␗✀Ꮫ⾡㡿ᇦࢆໟྵࡍࡿ᪂ࡓ࡞≀㉁ྜᡂᴫᛕࢆ๰ฟࡍࡿࡇ࡜࡟
ࡼࡾඛᑟⓗ◊✲ࢆ᥎㐍ࡋ㸪⛉Ꮫ࡜⛉Ꮫᢏ⾡ࡢ㠉᪂࡜᪂⏘ᴗࡢ๰ฟࢆಁࡍ᪂Ꮫ⾡ᇶ┙ࡢᵓ⠏࠾ࡼࡧḟୡ௦୰᰾◊✲⪅ࡢ⫱ᡂࢆᅗࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚㸪ࠕ᪂཯ᛂ࣭᪂ゐ፹◊✲ࠖ㸪ࠕ࣐ࢸࣜ࢔ࣝ◊✲ࠖ㸪ࠕ࢚ࢿࣝࢠ࣮࣭㈨※◊✲ࠖ㸪ࠕࢣ࣒ࣂ࢖࢜◊✲ࠖ࠾ࡼࡧࠕ⼥ྜ◊✲ࠖࡢ5ศ㔝࡛άືࢆ⾜ࡗ࡚࠸ࡿ㸬ᮏᖺᗘࡢ◊✲άືࢆ㏻ࡌ࡚㸪❅⣲ศᏊࡢษ᩿࡜࢔ࣥࣔࢽ

᮶ᖺᗘࡶඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬࡢ୍⩼࡜ࡋ࡚㸪Ꮫእ࡜ࡢඹྠ◊✲ࢆಁ㐍ࡍࡿ㸬‫ڦ‬᮶ᖺᗘάືィ⏬ᘬࡁ⥆ࡁ㸪Ꮫ⾡஺ὶࢆ᥎㐍ࡍࡿ㸬ᩍဨࡸᏛ⏕ࡢὴ㐵㸪᝟
ሗⓎಙᆺᅜ㝿ࢩ࣏ࣥࢪ࣒࢘ࡢ㛤ദࢆィ⏬ࡍࡿ㸬Ꮫ㝿 ⤫ྜ≀㉁⛉Ꮫ◊✲ࣘࢽࢵࢺ/ Unit on
Integrated Research Consortium on
Chemical Sciences‫ڦ‬2023ᖺᗘࡢᵓᡂဨ

6262

᪂ᨺᑕග※ゐ፹ィ ⛉Ꮫࣘࢽࢵࢺ/ Unit of
Catalyst Characterization by the New
Synchrotron Radiation‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑࣘࢽࢵࢺ㛗ᩍᤵࠒᮅ಴Ύ㧘࣭ࠑᐈဨᩍᤵᮾ໭኱Ꮫࠒᮧᯇ

ᖺሗ࣭◊✲ᐊ⦅‫ە‬῟ྖすᇼ㯞⾰Ꮚ㧘ᶫᖾ⏕࣭ࠑᩍᤵࠒΎỈ◊୍⚟ᒸ῟㧘ⲡᮌ㐩୰ᓥΎ㝯࣭ࠑ෸ᩍᤵࠒྂᕝ᳃ஓ㹙㹼2023/04/30㹛㫽ᒇᑿ㝯࣭ࠑຓᩍࠒShrotri ABHIJIT࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࣘࢽࢵࢺ
/ Unit of Catalyst Informatic‫ڦ‬2023ᖺᗘࡢάືෆᐜ࣭◊✲ᡂᯝ‫ڦ‬2023ᖺᗘࡢᵓᡂဨ

໭኱ࡢࢼࣀࢸࣛࢫά⏝ࢆ㐍ࡵࡿࡓࡵ㸪ゐ፹Ꮫ఍ෆ࡟᪂
ࡋ࠸◊✲఍࡛࠶ࡿඛ➃ᨺᑕගά⏝◊✲఍ࢆ㧘ⲡᮌ㐩ᩍᤵࡀᖿ஦࡜ࡋ࡚ඛᑟࡋ㸪2023ᖺ7᭶21᪥㸦㔠㸧13㸸00-2023
ᖺ7᭶22᪥㸦ᅵ㸧12㸸20 (JST) ๰ᡂ⛉Ꮫ◊✲Ჷ5㝵࡟࡚ ኱఍㆟ᐊ➨1ᅇඛ➃ᨺᑕගά⏝◊✲఍ࠕᨺᑕගࢆ⏝࠸ࡓゐ፹࢟ࣕࣛࢡࢱࣜࢮ࣮ࢩࣙࣥࡢ⌧ᅾ࡜ᮍ᮶ࠖࢆ㛤ദࡋࡓ㸬ࣉࣟࢢ࣒ࣛࡣ
https://www.cat.hokudai.ac.jp/news/news20230721.pdf࡟ᥖ㍕ࡋࡓ㸬ࡲࡓ㸪ඹྠ฼⏝࣭ඹྠ◊✲ᣐⅬ ゐ፹⛉Ꮫィ ඹྠ◊✲ᣐⅬ࡟࠾࠸࡚㸪ḟୡ௦ᨺᑕගࡢゐ፹࠾ࡅࡿ฼⏝ࢆぢᤣ࠼ࡓㄢ㢟ࢆ᥇⏝ࡋࡓ㸬ࡉࡽ࡟㸪2024ᖺ1᭶26᪥࡟❧࿨㤋SRࢭࣥࢱ࣮࡜ࡢྜྠࢩ࣏ࣥࢪ࣒࢘ࢆᐇ᪋ࡋࡓ㸬ࠑࣘࢽࢵࢺ㛗ᩍᤵࠒ㛗㇂ᕝ῟ஓ࣭ࠑᩍᤵࠒΎỈ◊୍㧘ⲡᮌ㐩࣭ࠑ෸ᩍᤵࠒ㫽ᒇᑿ㝯࣭ࠑᐈဨᩍᤵ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤࠒ▮⏣㝧ࠑᏛෆ◊✲༠ຊᩍဨᩍᤵࠒ㧗ᶫၨ௓࣭ࠑி㒔኱Ꮫ≉௵ᩍᤵࠒ℧ᕝ୍Ꮫ‫ڦ‬2023ᖺᗘࡢάືෆᐜ࣭◊✲ᡂᯝ࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫ࡟㛵ࡍࡿ᭱㏆ࡢືྥ࡟ࡘ࠸࡚᝟ሗ஺᥮ࢆ⾜࠺࡜࡜ࡶ࡟㸪᮶ᖺᗘࡢ࢔ࢡࢸ࢕ࣅ
ࢸ࢕࡟ࡘ࠸࡚㆟ㄽࡋࡓ㸬℧ᕝ㸪㫽ᒇᑿ㸪ΎỈࡽࡢඹྠ◊✲ᡂᯝㄽᩥࡀⓎ⾲ࡉࢀࡓ㸬ࡲࡓ㸪▮⏣㸪㛗㇂ᕝࡀゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊ᮐᖠㅮ₇఍ࡢୡヰேࢆົࡵ㸪࢟ࣕࢱࣜࢫࢺ
࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࡸࢹ࣮ࢱ㥑ືᆺ◊✲ࡢᑗ᮶ᒎ㛤࡟㛵ࡍࡿㅮ₇఍ࢆ௻⏬ࡋࡓ㸬‫ڦ‬᮶ᖺᗘάືィ⏬ゐ፹ศ㔝࡟࠾࠸࡚᝟ሗ⛉Ꮫ㸪ࢹ࣮ࢱ⛉Ꮫࢆά⏝ࡍࡿ◊✲⪅ࢥ࣑ࣗࢽࢸ࢕࣮ࢆᙧᡂࡍࡿ㸬⏘⥲◊㸪ி㒔኱Ꮫ㸪≀㉁࣭
ᮦᩱ◊✲ᶵᵓ࡜ඹ࡟࢟ࣕࢱࣜࢫࢺ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࢩ
࣏ࣥࢪ࣒࢘ࢆ௻⏬ࡍࡿ㸬ศ㔝᣺⯆࡜⏘Ꮫ㐃ᦠࡢ┠ⓗ࡛௻ᴗ◊✲⪅ࢆྵࡵࡓᖜᗈ࠸◊✲⪅ࢆ㞟ࡵ࡚ྠศ㔝ࡢ᝟ሗ஺᥮
࡜◊✲ၨⓎάືࢆᐇ᪋ࡍࡿ㸬࢔࢖ࢩࣥ໭኱R㸤Dࣛ࣎ࣘࢽࢵࢺ/ AISINHOKUDAI R㸤D Lab. UNIT‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑࣘࢽࢵࢺ㛗ᩍᤵࠒ⚟ᒸ῟࣭ࠑᩍᤵࠒΎỈ◊୍୰ᓥΎ㝯࣭ࠑ෸ᩍᤵࠒ㫽ᒇᑿ㝯ࠑຓᩍࠒShrotri ABHIJIT࣭ࠑᏛෆ◊✲༠
ຊᩍဨᩍᤵࠒ㈗ᓥ♸἞࣭ࠑᏛෆ◊✲༠ຊᩍဨ෸ᩍᤵࠒ⏣ᓥ೺ḟ࣭ࠑᣍ࡬࠸ᩍဨࠒ㧗㔝୍ྐᴮཎ┿஧‫ڦ‬2023ᖺᗘࡢάືෆᐜ࣭◊✲ᡂᯝ
ICAT̿❧࿨㤋SRࢭࣥࢱ ඹྠࢩ࣏ࣥࢪ࣒࣏࢘ࢫࢱ࣮

‫ڦ‬᮶ᖺᗘάືィ⏬ᮏࣘࢽࢵࢺࡣ㸪ᮾ໭኱Ꮫᅜ㝿ᨺᑕග࢖ࣀ࣮࣋ࢩ࣭ࣙࣥࢫ
࣐࣮ࢺ◊✲ࢭࣥࢱ࣮㸦65,6㸧࡜࡜ࡶ࡟㸪᭱ඛ➃ᨺᑕග※㸦ࢼࣀࢸࣛࢫ㸧ࡢゐ፹࡬ࡢᛂ⏝ྍ⬟ᛶࢆ᥈ࡿࡇ࡜ࢆ┠ⓗ࡜ࡍࡿ㸬ࡇࡢࡓࡵ㸪ࡼࡾ౑࠸຾ᡭࡢࡼ࠸㉸ᑠᆺᨺᑕග※࡛࠶ࡿ❧࿨㤋65ࢭࣥࢱ࣮ࢆά⏝ࡋ࡚㸪ࢼࣀࢸࣛࢫࡢᚓព࡜ࡍࡿࢯ
ࣇࢺ;⥺㡿ᇦ࡟࠾ࡅࡿ᪂ࡓ࡞ゐ፹◊✲࡟ᚲせ࡞ᢏ⾡ࡢᵓ⠏ࡸᑐ㇟ࡢ㑅ᐃࢆ⾜࠺㸬ࡇ࠺ࡋࡓάືࢆ㏻ࡋ࡚ࢼࣀࢸࣛࢫࡢ
᭷ຠ฼⏝ࢆᅗࡗ࡚࠸ࡃ㸬ࡲࡓ㸪඲ᅜࡢゐ፹◊✲⪅࡜㐃ᦠࡍࡿࡓࡵ㸪ゐ፹Ꮫ఍ෆࡢ◊✲఍ࢆ฼⏝ࡋ࡚㸪ඹྠ฼⏝ࢆ᥎㐍ࡍࡿ㸬ḟᖺᗘࡣ㸪ゐ፹ウㄽ఍ࡸゐ፹Ꮫ఍ࡢ◊✲఍ࢆ୺ദࡋ㸪ࢼࣀࢸࣛࢫࡢά⏝ࢆ㆟ㄽࡍࡿ㸬ࡲࡓ❧࿨㤋65ࢭࣥࢱ࣮࡛ࡢ
ࢸࢫࢺᐇ㦂ࢆࡍࡍࡵࡿ㸬‫ە‬ᖺሗ࣭◊✲ᐊ⦅㠀ྍ㣗⣔ࣂ࢖࣐࢜ࢫ࠿ࡽᅛయゐ፹ࢆ⏝࠸ࡓ㧗཰⋡⢾໬ᢏ⾡ࡢ᳨ウ࡟࠾࠸࡚ࡣ㸪ࣂ࢖࣐࢜ࢫࡢ⢊○࡜ྍ⁐໬ᾮࡢゐ፹ⓗຍỈศゎ࡟ࡼࡾ㸪༢⢾ࡀ཰⋡ࡼࡃᚓࡽࢀࡿࡇ࡜ࢆぢฟࡋࡓ㸬ࡇࡢᡂᯝࡣ㸪➨ᅇゐ፹ウㄽ఍㸦໭ᾏ㐨኱Ꮫ㸧࡟
࠾࠸࡚Ⓨ⾲ࡋࡓ㸬ࡲࡓ㸪Ỉ⣲࡜஧㓟໬Ⅳ⣲ࢆཎᩱ࡜ࡋࡓ࢚
ࢱࣀ࣮ࣝྜᡂゐ፹ࡢ◊✲㸪ࢢࣝࢥ࣮ࢫ⏤᮶ࡢࣉࣟࣆࣞࣥྜᡂゐ፹ࡢ◊✲࡟ࡘ࠸࡚ࡶ᳨ウࢆ㛤ጞࡋ㸪ゐ፹タィ㸪཯ᛂ⿦⨨ࡢ⤌ࡳ❧࡚࡞࡝◊✲ࢆ᥎㐍ࡋ࡚࠸ࡿ㸬ᖺᗘ࠿ࡽࡣ᪂
◊✲ࢸ࣮࣐ࢆຍ࠼㸪᪂ࡓ࡟ຍࢃࡗࡓ࣓ࣥࣂ࣮ࢆྵࡵ㸪◊✲ィ⏬࡟ἢࡗ࡚άືࢆ⾜࠺㸬‫ڦ‬᮶ᖺᗘάືィ⏬࣮࢝࣎ࣥࢽ࣮ࣗࢺࣛࣝࢆ┠ⓗ࡜ࡋࡓ◊✲ࢸ࣮࣐ࡢ๰ฟ
ཬࡧ⏘ᴗ໬ࢆ᥎㐍ࡍࡿ㸬ලయⓗ࡟ࡣ㸪㠀ྍ㣗⣔ࣂ࢖࣐࢜ࢫ
࠿ࡽᅛయゐ፹ࢆ⏝࠸ࡓ㧗཰⋡⢾໬ᢏ⾡ࡢ☜❧㸪Ỉ⣲࡜஧㓟໬Ⅳ⣲ࢆཎᩱ࡜ࡋࡓ࢚ࢱࣀ࣮ࣝྜᡂゐ፹ࡢ◊✲㸪ࢢࣝࢥ࣮ࢫ⏤᮶ࡢࣉࣟࣆࣞࣥྜᡂゐ፹ࡢ◊✲㸪㧗ࣂ࢖࣐࢜ࢫ㈨※᳜≀సฟࡢ◊✲㸪㛗㙐ࣂࢡࢸࣜ࢔ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮
ྜᡂࡢ◊✲㸪ࣉࣛࢫࢳࢵࢡࢆཎᩱ࡜ࡋࡓⅣ໬Ỉ⣲࢞ࢫྜᡂゐ፹ࡢ◊✲㸪ࣂ࢖࢜ࣉࣛࢫࢳࢵࢡཎᩱྜᡂゐ፹ࡢࢩ࣑ࣗ
࣮ࣞࢩࣙࣥᢏ⾡㛤Ⓨࢆ⾜࠺㸬63‫إ‬ԓὉᄂᆮૅੲ২ᘐᢿ
report: Technical Division ᮏ◊✲ᡤࡢᢏ⾡⫋ဨࡢ⤌⧊໬࡟ࡘ࠸࡚ࡣ㸪ྠ⫋ဨࡢ⬟
ຊ࣭㈨㉁➼ࡢྥୖ࡜ฎ㐝ࡢᨵၿࢆᅗࡿ࡜࡜ࡶ࡟㸪ඃࢀࡓேᮦࢆ☜ಖࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚㸪ᖹᡂ3ᖺ4᭶1᪥࡟タ⨨ࡉࢀࡓ㸬‫⯡୍ڦ‬බ㛤 ୍⯡ᕷẸྥࡅ࡟࢞ࣛࢫᕤసࡀ࡝ࡢࡼ࠺࡟◊✲࡟ᙺ❧ࡗ࡚࠸ࡿ࠿ࢆ㸪ᕤసయ㦂ࢆ㏻ࡋ⤂௓ࡋ࡚࠸ࡿ㸬‫ڦ‬2023ᖺᗘࡢᵓᡂဨ
ࠑ㒊㛗ࠒΎỈ◊୍࣭ࠑ⌜㛗ࠒ▼ᕝ຾ஂ
➨୍◊✲ᶵჾ㛤Ⓨ⌜ ࠑᢏ⾡୺௵ࠒ㛗㇂ᕝ㈗ᙪ
➨஧◊✲ᶵჾ㛤Ⓨ⌜ ࠑᢏ⾡୺௵ࠒᕝᮧ⿱௓࣭
ࠑᢏ⾡⫋ဨࠒྥ஭ៅ࿃
◊✲ᶵჾ⟶⌮⌜ ࠑᢏ⾡୺௵ࠒᒣᓊኴᖹ

‫➨୍࣭➨ڦ‬஧◊✲ᶵჾ㛤Ⓨ⌜ ➨୍࠾ࡼࡧ➨஧◊✲ᶵჾ㛤Ⓨ⌜࡛ࡣ㸪ࡑࢀࡒࢀ࢞ࣛࢫ࠾
ࡼࡧ㔠ᒓᕤసࢆ୺య࡜ࡋࡓ⿦⨨㛤Ⓨࢆ⾜ࡗ࡚࠸ࡿ㸬ͤ2019 ᖺᗘࡢ୍⯡බ㛤෗┿‫ڦ‬ゐ፹⛉Ꮫ◊✲ᡤᢏ⾡㒊ㅮ⩦఍‫ڦ‬ᥖ㍕ㄅཬࡧᥖ㍕ㄽᩥ ゐ፹⛉Ꮫ◊✲ᡤᢏ⾡㒊ㅮ⩦఍ࡣ㸪ྛ◊✲ᐊࡢࡳ࡞ࡉࢇ࡟
ᕤసᶵᲔ࣭࢞ࣛࢫ〇ရ࣭◊✲ᶵჾࡢྲྀࡾᢅ࠸᪉࡞࡝ࢆ▱ࡗ࡚ࡶࡽ࠸㸪Ᏻ඲࡟◊✲ࡋ࡚࠸ࡓࡔࡃࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚㛤ദࡋ࡚࠸ࡿ㸬 ୺࡞ෆᐜ࡜ࡋ࡚ࡣ㸪㸦1㸧ᢏ⾡㒊ࡢ௙஦ෆᐜ࡜〇ရࡢὀᩥ㸪ಟ⌮౫㢗࡟㛵ࡍࡿㄝ᫂㸪㸦2㸧ᐇ㦂ࡍࡿ㝿ࡢ࢞ࣛࢫ࣭
㔠ᒓ〇ရࡢྲྀࡾᢅ࠸࡟ࡘ࠸࡚㸪㸦3㸧࢞ࣛࢫ࣭㔠ᒓᕤసᐊࡢㄝ᫂࡜ᐇ⩦㸦4㸧ᢏ⾡㒊⟶⌮⿦⨨ࡢㄝ᫂㸦5㸧ᛂᛴฎ⨨࡛࠶ࡿ㸬 ㅮ⩦ࢆጞࡵ࡚࠿ࡽᶵᲔ࣭࢞ࣛࢫࡢಟ⌮ࡢᩘࡣῶᑡࡋࡓࡓ
ࡵ㸪⥅⥆ࡍࡿࡇ࡜࡛ᐇ㦂࡟ࡼࡿ஦ᨾࡶῶࡾ,◊✲⎔ቃࡢྥୖ࡟ࡶࡘ࡞ࡀࡗ࡚࠸ࡿ㸬(1) Kim, C. R.; Maeda, H.; Lu, B.; Nakamura, Y.; Lin, Y. L.;
Wakisaka, Y.; Kido, D.; Asakura, K.; Takakusagi, S. Can
amine ligands atomically disperse Cu atoms on TiO2 (110)? Cu
deposition on TiO2(110) premodified with o-anthranilic acid.
Chemistry Letters 2024, 2. DOI: 10.1093/chemle/upad045.
(2) Liu, C.; Lu, B.; Ariga-Miwa, H.; Ogura, S.; Ozawa, T.;
Fukutani, K.; Gao, M.; Hasegawa, J. Y.; Shimizu, K.; Asakura,K.; et al. Dynamic Behavior of Intermediate Adsorbates toControl Activity and Product Selectivity in Heterogeneous
Catalysis: Methanol Decomposition on Pt/TiO2(110). J. Am.
Chem. Soc. 2023, 36, 19953-19960.
(3) Murata, R.; Shitamichi, K.; Hiramatsu, M.; Matsubara, S.;
Uraguchi, D.; Asano, K. trans-Cyclooctenes as Scavengers ofBromine Involved in Catalytic Bromination. Chemistry-a
European Journal 2023. DOI: 10.1002/chem.202303399.
(4) Ogawa, M.; Suzuki, H.; Ogawa, K.; Tomita, O.; Abe, R.
Synthesis of multi-layered perovskite oxyiodides: Impact ofnumber of perovskite layers and type of halide layer for band
levels and photocatalytic properties. Solid State Sci. 2023, 141.
DOI: 10.1016/j.solidstatesciences.2023.107221.
(5) Wada, T.; Kashaboina, U.; Nishikawa, Y.; Wakisaka, Y.; Bao,
D. L.; Takakusagi, S.; Inami, Y.; Kuriyama, F.; Dipu, A. L.;
Ogihara, H.; et al. The Effect of Structural Change during the
Activation Process on the Catalysis of In/SiO2 Nonoxidative
Coupling of Methane: An Operando XAFS Study. J. Phys.
Chem. C 2023, 50, 24211-24222.
(6) Zhuang, Y.; Iguchi, Y.; Li, T. C.; Kato, M.; Hutapea, Y. A.;
Hayashi, A.; Watanabe, T.; Yagi, I. Platinum-Nickel Alloy
Nanowire Electrocatalysts Transform into Pt-Skin Beads-onNanowires Keeping Oxygen Reduction Reaction Activity
During Potential Cycling. Acs Catalysis 2024, 3, 1750-1758.

ͤ2019 ᖺᗘࡢᢏ⾡㒊ㅮ⩦఍෗┿‫✲◊ڦ‬ᶵჾ⟶⌮⌜ ◊✲ᶵჾ⟶⌮⌜࡛ࡣ㸪ゐ፹⛉Ꮫ◊✲ᡤࡀಖ᭷ࡍࡿྛ✀ࡢ◊✲ᶵჾࡢ⟶⌮ࢆ⾜ࡗ࡚࠸ࡿ㸬
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ᖺሗ࣭◊✲ᐊ⦅‫ە‬Ẹỉ˂ỉಅጚ
activities of ICAT‫ڦ‬ㄽᩥ
㏥⫋ࡉࢀࡓඛ⏕᪉➼࡛ᮏ◊✲ᡤᡤᒓ࡜ࡋ࡚ฟ∧ࡉࢀࡓㄽᩥ(1) Yang, Y.; Wang, Q.; Mei, B.; Han, Z.; Sun, F.; Shang, L.;
Yang, S.; Wei, Y.; Wu, D.; Jiang, Z. Theory-guided Design ofAtomically Dispersed Dual-Metal Catalysts for Superior
Oxygen Reduction Reaction Activity. ChemCatChem, 2023, e
202300534.

‫ە‬ᖺሗ࣭◊✲ᐊ⦅(2) Kageshima, Y.; Inuzuka, H.; Kumagai, H.; Ohtani, B.;
Teshima, K.; Nishikiori, H. Photothermal Boosting of
Photocatalytic Hydrogen Evolution Induced by Defects andCocatalysts on TiO2. J. Phys. Chem. C 2023, 37, 18327–18339.
(3) Long, J.; Zhuang, k.; Liao, W.; An, Y.; Wang, B.; Wu, C.; Cao,J.; Wang, Q.; Chen, J.; Wang, J. Electronegativity-assisted
optimized electronic structure of functionalized-Pt catalysts
for boosting oxygen reduction kinetics. Rare Metal, 2024, 43.
1965-1976.

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personal dataᴾ̾ʴἙὊἑᴾಶேࢹ࣮ࢱ

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ᩍဨࡢ50㡢㡰㸬╔௵᫬ࡢ⫋ྡࡀ⌧ᅾࡢࡶࡢ࡜ࡇ࡜࡞ࡿሙྜ
࡟ࡣࡑࢀࡀ⾲♧ࡉࢀ࡚࠸ࡿ㸬ᮅ಴Ύ㧘࠶ࡉࡃࡽࡁࡼࡓ࠿
Kiyotaka ASAKURA


⫋ྡ㸸ᩍᤵ
╔௵㸸1999ᖺ4᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮/㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮㸸ゐ፹⾲㠃◊✲㒊㛛/ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮࣭ᶵ⬟ᛶྜ㔠ゐ፹◊✲ࢡࣛࢫࢱ࣮/ࣇࣜࢵࢶ࣭ࣁ࣮ࣂ࣮◊✲ᡤࣘࢽࢵࢺ࣭⤫ྜ≀㉁๰〇໬Ꮫ◊✲᥎㐍ࣘࢽࢵࢺ࣭᪂ᨺᑕග※ゐ፹ィ ⛉Ꮫࣘࢽࢵࢺᢸᙜ኱Ꮫ㝔㸦Ꮫ㒊㸧㸸ᕤᏛ㝔㸦ᕤᏛ㒊㸧◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ02 312-2
㟁ヰ㸸011-706-9113࣭ࣇࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9113࣭㟁㟁Ꮚ࣓࣮ࣝ㸸askr@cat.hokudai.ac.jp◊✲ศ㔝㸸≀⌮໬Ꮫ/ᅛయࡢ⾲㠃ᵓ㐀/⏺㠃໬Ꮫ/ᶵ⬟≀㉁໬
Ꮫ/཯ᛂ㏿ᗘㄽ࡜ゐ፹/ⷧ⭷࣭⾲㠃⏺㠃≀ᛶ/ィ ᕤᏛ/ࢼࣀᵓ㐀⛉Ꮫ/⎔ቃ㛵㐃໬Ꮫ/㔞Ꮚࣅ࣮࣒◊✲ㄢ㢟㸸⇞ᩱ㟁ụゐ፹㸦2007-2024㔠ᒓ࣮඾ᆺඖ⣲໬ྜ≀⾲㠃ࡢ໬Ꮫ࡜≀⌮㸦2000-2024ἲ࡟ࡼࡿᐇ✵㛫ᐇ᫬㛫⾲㠃ほᐹ㸦1999-2020㸧/㧗㏿XAFS࡟ࡼࡿάᛶ⾲㠃ࡢᵓ㐀࡜タィ࡜㢧ᚤἲ࡟ࡼࡿᐇ✵㛫ᐇ᫬㛫⾲㠃ほᐹ㸦1999-2024FSࢹ
࣮ࢱ࣮࣋ࢫࡢᵓ⠏㸦2018-㸧/ከඖ⣲ඹ㬆࣐ࣛࣥ㸦2018-2024࣮࣮࢟࣡ࢻ㸸⾲㠃໬Ꮫ/཯ᛂ໬Ꮫ/ᵓ㐀໬Ꮫ/XAFSศගᏛ/ග㟁Ꮚ㢧ᚤ㙾/⾲㠃㢧ᚤศග/㓟໬≀⾲㠃/ゐ፹⾲㠃⛉Ꮫ/⬺◲ゐ፹/⇞ᩱ㟁ụ/MARX-RAMAN/CTS࣭MRMC/Uniform Prior
Probabilty/TSᏛṔ㸸1981ᖺ3᭶ᮾி኱Ꮫ⌮Ꮫ㒊໬Ꮫ⛉༞ᴗ/1983ᖺ3᭶ᮾி኱Ꮫ⌮Ꮫ⣔◊✲⛉໬Ꮫᑓᨷಟኈㄢ⛬ಟ஢/1984ᖺ9᭶ᮾி኱Ꮫ⌮Ꮫ⣔◊✲⛉໬Ꮫᑓᨷ༤ኈㄢ⛬୰㏥
Ꮫ఩㸸1983ᖺ3᭶⌮Ꮫಟኈ㸦ᮾி኱Ꮫ㸧/1987ᖺ9᭶⌮Ꮫ༤ኈ㸦ᮾி኱Ꮫ㸧
ࠕEXAFS Studies on the Local Structures of Metal
Dispersed in Polyacetylene and Attached Metal Catalystsࠖ
⫋Ṕ㸸1984ᖺ10᭶ᮾி኱Ꮫຓᡭ㸦⌮Ꮫ㒊໬Ꮫ⛉㸧/1992ᖺ10᭶ᮾி኱Ꮫㅮᖌ㸦⌮Ꮫ㒊໬Ꮫᩍᐊ㸧/1994ᖺ6᭶ᮾி኱Ꮫຓ
ᩍᤵ㸦⌮Ꮫ㒊ࢫ࣌ࢡࢺࣝ໬Ꮫ◊✲ࢭࣥࢱ࣮㸧/1999ᖺ4᭶໭ᾏ㐨኱Ꮫᩍᤵ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ゐ፹⾲㠃໬Ꮫ㒊㛛⾲㠃άᛶᵓ㐀≀ᛶศ㔝㸧/2015ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸦ゐ፹⾲㠃◊✲㒊㛛㸧/2014ᖺ4᭶ゐ፹໬Ꮫࢭࣥࢱ
࣮㛗/2015ᖺ10᭶-2018ᖺ3᭶ゐ፹⛉Ꮫ◊✲ᡤ㛗ᅾእ◊✲Ṕ㸸1991ᖺ10᭶-1991ᖺ10᭶࡟Ꮫ᣺᪥⡿༠ຊ⡿ᅜ
Delaware኱Ꮫ࡟▷ᮇὴ㐵㸦Japan-US cooperative Fellowshipof JSPS㸧/1993ᖺ3᭶-1994ᖺ4᭶Fritz-Habor Institute der Max
Planck Gezellschaft㸦AvH Research Fellow㸧/1997ᖺ1᭶-1997
ᖺ2᭶⡿ᅜUC Davis㸦ඹྠ◊✲㸧ᡤᒓᏛ఍: ᪥ᮏ໬Ꮫ఍/᪥ᮏ⾲㠃┿✵Ꮫ఍/᪥ᮏXAFS◊✲఍/ゐ፹Ꮫ఍/᪥ᮏᨺᑕගᏛ఍/PF̿UA/ᛂ⏝≀⌮Ꮫ఍/᪥ᮏ໬ Ꮫ ఍ ⏺ 㠃 ཬ ࡧ ࢥ ࣟ ࢖ ࢻ㒊఍ / ᪥ ᮏ ≀ ⌮ Ꮫ ఍ /American

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Chemical Society/Royal Society of Chemistry 㸦FELLOW㸧
/International XAFS Society㸦IXAS㸧Ꮫ఍άື㸸PF᠓ㄯ఍㐠Ⴀጤဨ఍ጤဨ㸦1997-2003㸧/➨2ᅇ
XAFSウㄽ఍ࣉࣟࢢ࣒ࣛጤဨ㸦1999㸧/XAFS XI executive
committee㸦1999-2000㸧/XAFS XI Program committee member
㸦1999-2000㸧/ゐ፹Ꮫ఍ウㄽ఍ጤဨ㸦2000-2001㸪2012-2013㸧/᪥ᮏ໬Ꮫ఍⦅㞟ጤဨ㸦2000-2002㸧/XAFS◊✲఍ᖿ஦㸦20012003㸧/᪥ᮏ⾲㠃⛉Ꮫ఍ホ㆟ဨ㸦2001-2004㸧/᪥ᮏ໬Ꮫ఍໭
ᾏ㐨ᨭ㒊ᖿ஦㸦2003-2005㸧/᪥ᮏ⾲㠃⛉Ꮫ఍⌮஦㸦20032006㸧/᪥ᮏ໬Ꮫ఍ᖿ஦㸦2003-2006㸧/᪥ᮏᨺᑕගᏛ఍ᖿ஦
㸦2003-2006㸧/IUCr XAFS commission㸦2004-2010㸧/᪥ᮏ⾲㠃⛉ᏛᏛ఍ᨺᑕග⾲㠃⛉Ꮫ◊✲㒊఍ᖿ஦㸦2005-2012㸧/᪥ᮏ⾲㠃⛉Ꮫ఍Ꮫ఍ㄅ⦅㞟ጤဨ㸦2006㸧/᪥ᮏ⾲㠃⛉ᏛᏛ఍ᮾ໭࣭໭ᾏ㐨ᨭ㒊௻⏬ᖿ஦㸦2006㸧/᪥ᮏXAFS◊✲఍ᖿ஦
㸦2006㸧/ゐ፹Ꮫ఍Ꮫ⾡ጤဨ㸦2006-2008㸧/ゐ፹Ꮫ఍௻⏬࣭ᩍ⫱ጤဨ఍㸦2009-2013㸧/᪥ᮏ⾲㠃⛉ᏛᏛ఍ᮾ໭࣭໭ᾏ㐨ᨭ㒊ᖿ஦㸦2007-2012㸧/ゐ፹Ꮫ఍௦㆟ဨ㸦2007-2011㸪20142016 㸧 / ゐ ፹ Ꮫ ఍ ໭ ᾏ 㐨 ᨭ 㒊 ᖿ ஦ 㸦 2008-2009 㸧 /IXAS
executive committee㸦2009-2015㸧/᪥ᮏXAFS◊✲఍఍㛗
㸦2009-2014㸧/PF᠓ㄯ఍఍㛗㸦2010-2012㸧/᪥ᮏ⾲㠃⛉Ꮫ఍ゐ፹⾲㠃⛉Ꮫ◊✲㒊఍㒊఍㛗㸦2011-2012㸧/ゐ፹Ꮫ఍ᩍ⫱ጤဨ㸦2011-2014㸧/PF-UA㐠Ⴀጤဨ㸦2012-㸧/SPRUCホ㆟ဨ
㸦2012-㸧/ISHHC-16 Conference Secretary㸦2012-2013㸧/PFUAᗢົᖿ஦㸦2012-2015㸧/᪥ᮏ⾲㠃⛉ᏛᏛ఍ᮾ໭࣭໭ᾏ㐨ᨭ㒊๪ᨭ㒊㛗㸦2013-2014㸧/᪥ᮏ⾲㠃⛉ᏛᏛ఍ᨺᑕග⾲㠃⛉Ꮫ◊✲㒊఍㒊఍㛗㸦2013-2016㸧/᪥ᮏ⾲㠃⛉ᏛᏛ఍ᮾ໭࣭
໭ᾏ㐨ᨭ㒊ᨭ㒊㛗㸦2015-2016㸧/᪥ᮏ⾲㠃⛉ᏛᏛ఍๪఍㛗
㸦2015-2016㸧/PF-UAᡓ␎࣭ᑗ᮶ィ⏬ᢸᙜᖿ஦㸦2015-2018㸧/᪥ᮏᨺᑕගᏛ఍ホ㆟ဨ㸦2016-2017,2019㸧/Royal Chemical
Soceity PCCP ⦅㞟ጤဨ2016-㸧/FRSC㸦2018-㸧/International
XAFS Society vice president㸦2018-2022㸧/ゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊఍㛗㸦2018-2020㸧/᪥ᮏᨺᑕගᏛ఍఍㛗㸦2019-2021㸧/ ゐ፹Ꮫ఍๪఍㛗㸦2020㸧/IVC2022 Vice Chair㸦2020-2022㸧 /ゐ፹Ꮫ఍఍㛗㸦2021-2022㸧/IXAS ఍㛗㸦2022-㸧᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊ᨭ㒊㛗(2023-2024)
୺せ࡞◊✲ᴗ⦼㸸(1)Wada, T.; Kashaboina, U.; Nishikawa, Y.;
Wakisaka, Y.; Bao, D.; Takakusagi, S.; Inami, Y.; Kuriyama, F.;
Dipu, A. L.; Ogihara, H.; Iguchi, S.; Yamanaka, I.; Kido, D.;
Kimura, M.; Uo, M.; Asakura, K., The Effect of Structural
Change during the Activation Process on the Catalysis of
In/SiO2 Nonoxidative Coupling of Methane: An Operando
XAFS Study. J.Phys.Chem.C 2023, 127, 24211-24222.(2) Dong,
K.; Hu, B.; Rashid, M. H. A.; Lu, B.; Miyabayashi, K.; Higashi,K.; Uruga, T.; Iwasawa, Y.; Kido, D.; Takakusagi, S.; Asakura,K., In situ Study on Structure of a Diluted Pt/HOPG Model
Catalyst System Prepared by the Two-phase Liquid Reduction
Method Using a Novel BCLA/HERFD+BI-XAFS Method. e-J.
Surf.Sci.Nanotech. 2024, published on line.(3) Wang, Q.; Iguchi,
S.; Yamanaka, I.; Ota, J.; Wada, Takahiro; Uo, M.; Kido, D.;
Kimura, M.; Asakura, K., What is the Active Structure for HighTemperature Direct Dehydrogenative Conversion of Methane by
the Supported NiP Catalysts—An in Situ XAFS Study. J.Phys.
Chem.C 2024, 128, 3242-3249. (4) Kido, D.; Uemura, Y.;
Wakisaka, Y.; Koide, A.; Uehara, H.; Niwa, Y.; Nozawa, S.;
Ichiyanagi, K.; Fukaya, R.; Adachi, S.-I.; Sato, T.; Jenkins, H.;
Yokoyama, T.; Takakusagi, S.; Hasegawa, J.-Y.; Asakura, K.
Metastable Structure of Photoexcited WO3 Determined by the
Pump-Probe Extended X-Ray Absorption Fine Structure
Spectroscopy and Constrained Thorough Search Analysis. Chem.
Lett. 2022, 51, 1083-1086. (5) Hu, B.; Bharate, B.; Jimenez, J.

ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬

D.; Lauterbach, J.; Todoroki, N.; Wadayama, T.; Higashi, K.;
Uruga, T.; Iwasawa, Y.; Ariga-Miwa, H.; Takakusagi, S.;
Asakura, K. Abnormal Metal Bond Distances in Ptau Alloy
Nanoparticles: In Situ Back-Illumination Xafs Investigations of
the Structure of Ptau Nanoparticles on a Flat Hopg Substrate
Prepared by Arc Plasma Deposition. J. Phys. Chem. C 2022, 126,
1006-1016. (6) Wakisaka, Y.; Uehara, H.; Yuan, Q.; Kido, D.;
Wada, T.; Uo, M.; Uemura, Y.; Yokoyama, T.; Kamei, Y.; Kuroda,
S.; Ohira, A.; Takakusagi, S.; Asakura, K. Extracting the Local
Electronic States of Pt Polycrystalline Films Surface underElectrochemical Conditions Using Polarization-Dependent Total
Reflection Fluorescence X-Ray Absorption near Edge Structure
Spectroscopy. Electronic Structure 2021, 2, 044003.
Ꮫ⾡㛵ಀࡢཷ㈹㸸ゐ፹Ꮫ఍ዡບ㈹ࠕin-situ EXAFSἲ࡟ࡼࡿゐ፹άᛶ⾲㠃ࡢືⓗゎᯒࠖ㸦1993/04㸧࣭᪥ᮏ໬Ꮫ఍BCSJ㈹ࠕIn Situ Time-Resolved Energy-Dispersive XAFS Study on the
Reduction Processes of Cu-ZSM-5 Catalysisࠖ
㸦2001/09㸧࣭ᖹᡂ26ᖺᗘ㸦➨19ᅇ㸧᪥ᮏ⾲㠃⛉Ꮫ఍Ꮫ఍㈹ࠕ᭱ඛ➃X⥺྾཰ศගᡭἲࡢ㛤Ⓨ࡜ゐ፹ࢼࣀ≀㉁ࡢᏛ⌮ࡢ᥈ồࠖ
㸦2015/03㸧࣭᪥ ᮏ ໬ Ꮫ ఍ BCSJ ㈹ ࠕ Investigation of the Cleanliness ofTransferred Graphene: The First Step toward Its Application asa Window Material for Electron Microscopy and Spectroscopyࠖ㸦2015/08㸧
࣭ᖹᡂ27ᖺᗘ໭ᾏ㐨Ⓨ᫂༠఍໭ᾏ㐨Ⓨ᫂༠఍఍㛗㈹ࠕ⾲㠃ࡢ㟁Ꮚ≧ែࢆほᐹࡍࡿ≉Ṧ࡞㢧ᚤ㙾ࠖ
㸦2015/10㸧࣭ᖹᡂ27ᖺᗘ ゐ፹Ꮫ఍Ꮫ఍㈹㸦Ꮫ⾡㒊㛛㸧
ࠕOperando XAFSἲ࡟ࡼࡿゐ፹ᵓ㐀ࡢࡑࡢሙほᐹ࡜ゐ፹స⏝ᶵᵓ࡟㛵ࡍࡿ◊✲ࠖ
㸦2016/03㸧࣭௧࿴2ᖺᗘ ᪥ᮏ໬Ꮫ఍
Ꮫ⾡㈹ࠕin situ XAFS ࡟ࡼࡿືⓗゐ፹⾲㠃ゎᯒࡢ☜❧ࠖ
㸦2021/03㸧ὸ㔝ᆂభ࠶ࡉࡢࡅ࠸ࡍࡅ
Keisuke ASANO⫋ྡ㸸෸ᩍᤵ
╔௵㸸2022ᖺ5᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮/㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮㸸ศᏊゐ፹◊✲㒊㛛/⏕యศᏊᶆ㆑ゐ፹◊✲ࢡࣛࢫࢱ࣮
ᢸᙜ኱Ꮫ㝔㸦Ꮫ㒊㸧㸸⏕࿨⛉Ꮫ㝔㸦⸆Ꮫ㒊㸧◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05 312-1
㟁ヰ㸸011-706-9151࣭㟁㟁Ꮚ࣓࣮ࣝ㸸asano@cat.hokudai.ac.jp◊✲ศ㔝㸸᭷ᶵ໬Ꮫ/ྜᡂ໬Ꮫ/཯ᛂ໬Ꮫ/ศᏊゐ፹໬Ꮫ/᭷ᶵศᏊゐ፹/ගゐ፹/㑅ᢥⓗศᏊኚ᥮/ࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ
࣮◊✲ㄢ㢟㸸⏕యศᏊࡢྜᡂ࠾ࡼࡧゎᯒ࣭᧯సࢆᐇ⌧ࡍࡿศᏊゐ፹ᢏ⾡ࡢ㛤Ⓨ◊✲࣮࣮࢟࣡ࢻ㸸᭷ᶵ໬Ꮫ/ゐ፹໬Ꮫ/஧ᐁ⬟ᛶゐ፹/୙ᩧྜ
ᡂ/ศᏊࣉ࣮ࣟࣈ
ᏛṔ㸸2007ᖺ3᭶ி㒔኱ᏛᕤᏛ㒊ᕤᴗ໬Ꮫ⛉༞ᴗ/2009ᖺ3᭶ி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ᮦᩱ໬Ꮫᑓᨷ༤ኈ๓ᮇㄢ⛬ಟ஢/2012ᖺ3᭶ி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ᮦᩱ໬Ꮫᑓᨷ
༤ኈᚋᮇㄢ⛬ಟ஢Ꮫ఩㸸009ᖺ3᭶ಟኈ㸦ᕤᏛ㸧㸦ி㒔኱Ꮫ㸧/2012ᖺ3᭶༤ኈ㸦ᕤᏛ㸧㸦ி㒔኱Ꮫ㸧
ࠕ㠀ඹ᭷⤖ྜᛶ┦஫స⏝ࢆά⏝ࡋࡓ᭷ᶵศᏊゐ፹཯ᛂ࡟㛵ࡍࡿ◊✲ࠖ⫋Ṕ㸸2008ᖺ5–7᭶BASFᾏእ࢖ࣥࢱ࣮ࣥࢩࢵࣉ㸦⊂㸪
Ludwigshafenᮏ♫㸧/2010ᖺ4᭶᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ
㸦DC2㸧/2012ᖺ4᭶ி㒔኱Ꮫ≉ᐃຓᩍ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉ᖺሗ ࣭ಶே⦅‫ە‬ྜᡂ࣭⏕≀໬Ꮫᑓᨷ㸧/2013ᖺ4᭶ி㒔኱Ꮫຓᩍ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉ᮦᩱ໬Ꮫᑓᨷ㸧/2022ᖺ5᭶໭ᾏ㐨኱Ꮫ෸ᩍᤵ㸦ゐ፹⛉Ꮫ◊✲ᡤ㸧ᅾእ◊✲Ṕ㸸2008ᖺ5᭶–2008ᖺ7᭶⊂ᅜBASF㸦ᾏእ࢖ࣥࢱ
࣮ࣥࢩࢵࣉ㸧
ᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍/᭷ᶵྜᡂ໬Ꮫ༠఍/㏆␥໬Ꮫ༠఍/ࣚ࢘⣲Ꮫ఍୺せ࡞◊✲ᴗ⦼㸸(1) Murata, R.; Shitamichi, K.; Hiramatsu,
M.; Matsubara, S.; Uraguchi, D.; Asano, K. trans-Cyclooctenes
as Scavengers of Bromine Involved in Catalytic Bromination.
Chem.—Eur. J. 2024, 30, e202303399. (2) Nagano, T.;
Matsumoto, A.; Yoshizaki, R.; Asano, K.; Matsubara, S. Nonenzymatic catalytic asymmetric cyanation of acylsilanes.
Commun. Chem. 2022, 5, 45. (3) Einaru, S.; Shitamichi, K.;
Nagano, T.; Matsumoto, A.; Asano, K.; Matsubara, S. transCyclooctenes as Halolactonization Catalysts. Angew. Chem., Int.
Ed. 2018, 57, 13863–13867. (4) Yoneda, N.; Fujii, Y.;
Matsumoto, A.; Asano, K.; Matsubara, S. Organocatalytic
enantio- and diastereoselective cycloetherification via dynamic
kinetic resolution of chiral cyanohydrins. Nat. Commun. 2017, 8,1397. (5) Fukata, Y.; Asano, K.; Matsubara, S. Facile Net
Cycloaddition
ApproachtoOptically
Active1,5-Benzothiazepines. J. Am. Chem. Soc. 2015, 137, 5320−5323.
Ꮫ ⾡ 㛵 ಀ ࡢ ཷ ㈹ 㸸 The 5th ChemComm International
Symposium, The ChemComm Poster Prize ࠕ Asymmetric
Syntheses of Heterocycles via Cyclization with Bifunctional
Organocatalystsࠖ
㸦2011/05㸧
࣭᪥ᮏ໬Ꮫ఍➨92᫓Ꮨᖺ఍Ꮫ⏕ㅮ₇㈹ࠕ஧ᐁ⬟ᛶ᭷ᶵศᏊゐ፹࡟ࡼࡿ⎔໬ࢆ฼⏝ࡋࡓ୙ᩧ」⣲⎔ྜᡂ཯ᛂࠖ
㸦2012/04㸧࣭➨30ᅇ஭ୖ◊✲ዡບ㈹ࠕ㠀ඹ᭷⤖ྜᛶ┦஫స⏝ࢆά⏝ࡋࡓ᭷ᶵศᏊゐ፹཯ᛂ࡟㛵ࡍࡿ◊✲ࠖ㸦2014/02㸧࣭᭷ᶵྜᡂ໬Ꮫ༠఍࢚࣮ࢨ࢖◊✲௻⏬㈹ࠕ㠃୙ᩧ᭷ᶵ࢜ࣞࣇ࢕ࣥゐ፹ࡢ๰〇ࠖ㸦2014/12㸧࣭➨29ᅇ᪥
ᮏ໬Ꮫ఍ⱝ࠸ୡ௦ࡢ≉ูㅮ₇ࠕ᭷ᶵゐ፹࡟ࡼࡿከⅬάᛶ໬ࡀᣅࡃከᙬ࡞୙ᩧ」⣲⎔ྜᡂࠖ
㸦2015/03㸧࣭➨39ᅇෆ⸨ࢥࣥ
ࣇ࢓ࣞࣥࢫ࣏ࢫࢱ࣮㈹ࠕFacile cycloaddition approach to
optically active 1,5-benzothiazepinesࠖ
㸦2015/07㸧࣭➨68ᅇ᪥ᮏ
໬Ꮫ఍㐍Ṍ㈹ࠕ᭷ᶵゐ፹ࢆ฼⏝ࡋࡓศᏊ㓄ᗙࡢከⅬㄆ㆑࡟ᇶ࡙ࡃ୙ᩧྜᡂ཯ᛂࠖ
㸦2019/03㸧
࣭Thieme Chemistry Journals
Award 2020㸦2020/01㸧࣭➨12ᅇ஭ୖࣜࢧ࣮ࢳ࢔࢛࣮࢘ࢻࠕ㧗㏿཯ᛂࡢゐ፹ⓗ୙ᩧㄏᑟᢏ⾡࡟ᇶ࡙ࡃࣁࣟࢤࣥᇶ⨨᥮Ⅳ⣲⎔㦵᱁ᵓ⠏ἲࡢ㛤Ⓨࠖ㸦2020/02㸧࣭➨10ᅇ᪂໬Ꮫᢏ⾡◊✲
ዡບ㈹ࠕῶ㏿ᆺゐ፹࡟ࡼࡿゐ፹ⓗ୙ᩧ཯ᛂࢫ࣮࣌ࢫࡢᣑ
ᙇࠖ
㸦2021/06㸧㣤⏣೺஧࠸࠸ࡔࡅࢇࡌ
Kenji IIDA
⫋ྡ㸸෸ᩍᤵ
╔௵㸸2020ᖺ1᭶1᪥㒊㛛/ࢡࣛࢫࢱ࣮㸸ゐ፹⌮ㄽ◊✲㒊㛛/ࢼࣀ⏺㠃཯ᛂሙ◊✲ࢡࣛࢫࢱ࣮◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05 217-C
㟁ヰ㸸011-706-9145࣭ࣇ
ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9145࣭㟁㟁Ꮚ࣓࣮ ࣝ 㸸 k-iida@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
https://www.cat.hokudai.ac.jp/hasegawa/◊✲ศ㔝㸸⌮ㄽィ⟬໬Ꮫ/㔞Ꮚ໬Ꮫ/ゐ፹໬Ꮫ/⁐ᾮ໬Ꮫ◊✲ㄢ㢟㸸୙ᆒ୍࡞ᅛᾮ⏺㠃ࢆグ㏙ࡍࡿࡓࡵࡢ⌮ㄽィ⟬ᡭ

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ἲࡢ㛤Ⓨ࣭ගࡸ㟁ᅽࢆ฼⏝ࡍࡿゐ፹཯ᛂࡢ⌮ㄽゎᯒ◊✲࣮࣮࢟࣡ࢻ㸸ゐ፹⌮ㄽ/㉸୪ิ➨୍ཎ⌮ィ⟬/ᾮయ⤫ィຊᏛ/ගບ㉳㟁Ꮚࢲ࢖ࢼ࣑ࢡࢫ/㟁ᅽ༳ຍᏛṔ㸸2007ᖺி㒔኱ᏛᕤᏛ㒊ᕤᴗ໬Ꮫ⛉༞ᴗ/2009ᖺி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ศᏊᕤᏛᑓᨷಟኈㄢ⛬ಟ஢/2012ᖺி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ศᏊᕤᏛᑓᨷ༤ኈᚋᮇㄢ⛬ಟ஢Ꮫ఩㸸2009ᖺ3᭶ಟኈ㸦ᕤᏛ, ி㒔኱Ꮫ㸧/2012ᖺ3᭶༤ኈ㸦ᕤᏛ, ி㒔኱Ꮫ㸧⫋Ṕ㸸2009ᖺ᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸦DC1㸧/2012ᖺศ
Ꮚ⛉Ꮫ◊✲ᡤ⌮ㄽ࣭ィ⟬ศᏊ⛉Ꮫ◊✲㡿ᇦ༤ኈ◊✲ဨ
㸦IMSࣇ࢙࣮ࣟ㸧/2013ᖺ᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸦PD㸧
/ྠᖺศᏊ⛉Ꮫ◊✲ᡤ⌮ㄽ࣭ィ⟬ศᏊ⛉Ꮫ◊✲㡿ᇦຓᩍ
/2020ᖺ໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ෸ᩍᤵ㸦ゐ፹⌮ㄽ◊✲㒊㛛㸧ᡤᒓᏛ఍㸸⌮ㄽ໬Ꮫ఍/ゐ፹Ꮫ఍/ศᏊ⛉Ꮫ఍/᪥ᮏ໬Ꮫ఍
Ꮫ఍άື㸸ศᏊ◊◊✲఍ࠕග࡜ࢼࣀ≀㉁ࡢ┦஫స⏝㸸ศᏊ⛉Ꮫࡢᮍ᮶࡟ࡴࡅ࡚ࠖୡヰே㸦2018㸧࣭➨21ᅇ⌮ㄽ໬Ꮫウㄽ఍ᐇ⾜ጤဨ㸦2018㸧࣭➨15ᅇศᏊ⛉Ꮫウㄽ఍㸦2019㸧࣭2021ᖺ 㟁Ẽ໬Ꮫ⛅Ꮨ኱఍㸦2021㸧࣭ศᏊ⛉Ꮫ఍ᗈሗጤဨ㸦20212022㸧୺ せ ࡞ ◊ ✲ ᴗ ⦼ 㸸 (1) Chiba, T.; Iida, K.; Furukawa, S.;
Hasegawa, J. First-Principles Study on Unidirectional Proton
Transfer on Anatase TiO2(101) Surface Induced by ExternalElectric Fields. Phys. Chem. Chem. Phys. 2022, 25, 9454-9460.
(2) Iida, K. Atomic-Scale Picture of the Electric Double Layeraround a Heterogeneous Solid-Liquid Interface Based on 3DRISM-SCF Theory. J. Phys. Chem. C 2022, 126, 9466-9474.
(3) Iida, K.; Noda, M. Electron Transfer Governed by Light–
Matter Interaction at Metal–Semiconductor Interface. npj
Comput. Mater. 2020, 6, 5-1-5-8. (4) Iida, K.; Noda, M.;
Nobusada, K. Interface Electronic Properties Between a Gold
Core and Thiolate Ligands: Effects on an Optical Absorption
Spectrum in Au133(SPh-tBu)52. J. Phys. Chem. C, 2016, 120,2753-2759. (5) Iida, K.; Noda, M.; Ishimura, K.; Nobusada, K.
First-Principles Computational Visualization of Localized
Surface Plasmon Resonance in Gold Nanoclusters. J. Phys.
Chem. A 2014, 118, 11317-11322.
Ꮫ⾡㛵ಀࡢཷ㈹㸸2019ᖺᗘศᏊ⛉Ꮫ఍ዡບ㈹࣭
ࠕࢼࣀ⏺㠃⣔ࡢගࡸ㟁ᅽ࡟ᑐࡍࡿᛂ⟅ᶵᵓࡢゎ᫂ࠖ㸪 2022ᖺᗘ᪥ᮏ໬
Ꮫ఍໭ᾏ㐨ᨭ㒊ዡບ㈹࣭ࠕගࡸ㟁ᅽ࡟ᑐࡍࡿࢼࣀ⏺㠃ࡢᛂ⟅ᶵᵓࡢゎ᫂ࠖ
㸪2023ᖺᗘHPCIࢯࣇࢺ࢙࢘࢔㈹㛤Ⓨ㒊㛛㈹ዡບ㈹࣭
ࠕSALMON㸦Scalable Ab-initio Light-Matter simulator
for Optics and Nanoscience㸧
ࠖ

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ᾆཱྀ኱㍜
࠺ࡽࡄࡕࡔ࠸ࡍࡅ
Daisuke URAGUCHI
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⫋ྡ㸸ᩍᤵ
╔௵㸸2020ᖺ11᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮/㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮㸸ศᏊゐ፹◊✲㒊㛛/ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮
ᢸᙜ኱Ꮫ㝔㸦Ꮫ㒊㸧㸸⏕࿨⛉Ꮫ㝔㸦⸆Ꮫ㒊㸧◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05 311
㟁ヰ㸸011-706-9149࣭㟁Ꮚ࣓࣮ࣝ㸸uraguchi@cat.hokudai.ac.jpⓗศᏊኚ᥮◊✲ㄢ㢟㸸᭷ᶵศᏊゐ፹㸦2020-㸧/ගゐ፹㸦2020-㸧/◊✲࣮࣮࢟࣡ࢻ㸸᭷ᶵ໬Ꮫ/ゐ፹໬Ꮫ/࢖࢜ࣥᑐ/୙ᩧྜᡂ/ග໬Ꮫ/ᏛṔ㸸1997ᖺ3᭶໭ᾏ㐨኱Ꮫ⌮Ꮫ㒊໬Ꮫ⛉༞ᴗ/1999ᖺ3᭶໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲⛉໬Ꮫᑓᨷ༤ኈ๓ᮇㄢ⛬ಟ஢
/2002ᖺ3᭶໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲⛉໬Ꮫᑓᨷ༤ኈᚋ
ᮇㄢ⛬ಟ஢Ꮫ఩㸸1999ᖺ3᭶ಟኈ㸦⌮Ꮫ㸧㸦໭ᾏ㐨኱Ꮫ㸧/2002ᖺ3᭶༤ኈ㸦⌮Ꮫ㸧㸦໭ᾏ㐨኱Ꮫ㸧ࠕ࣮࢟ࣞࢺᆺ㧗㓄఩࢔࣑ࣝࢽ࣒࢘ࠊ
࣍࢘⣲ࡢ໬Ꮫ㸸㑅ᢥⓗ᭷ᶵྜᡂ࡬ࡢά⏝ࠖ⫋Ṕ㸸2002ᖺ4᭶᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨPD㸦ி㒔኱Ꮫ࣭⡿࢖ࣥࢹ࢕࢔ࢼ኱Ꮫ࣭ᮾ໭኱Ꮫ㸧/2004ᖺ10᭶┦ᶍ୰ኸ໬Ꮫ
◊✲ᡤ/2006ᖺ5᭶ྡྂᒇ኱Ꮫຓᡭ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉໬Ꮫ⏕≀ᕤᏛᑓᨷ㸧/2007ᖺ4᭶ྡྂᒇ኱Ꮫຓᩍ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉໬Ꮫ⏕≀ᕤᏛᑓᨷ㸧/2008ᖺ1᭶ྡྂᒇ኱Ꮫㅮᖌ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉໬Ꮫ⏕≀ᕤᏛᑓᨷ㸧/2011ᖺ10᭶ྡྂᒇ኱Ꮫ
෸ᩍᤵ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉໬Ꮫ⏕≀ᕤᏛᑓᨷ㸧/2017ᖺ4᭶ྡྂᒇ኱Ꮫ෸ᩍᤵ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉᭷ᶵ㧗ศᏊ໬Ꮫᑓ
ᨷ㸧/2020ᖺ11᭶໭ᾏ㐨኱Ꮫᩍᤵ㸦ゐ፹⛉Ꮫ◊✲ᡤ㸧ᅾእ◊✲Ṕ㸸2000ᖺ7᭶-2000ᖺ9᭶⡿ᅜMIT࡟▷ᮇ␃Ꮫ
/2002ᖺ5᭶-2003ᖺ4᭶⡿ᅜIndiana኱㸦᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸧ᡤ ᒓ Ꮫ ఍ 㸸 ᪥ ᮏ ໬ Ꮫ ఍ / ᭷ ᶵ ྜ ᡂ ໬ Ꮫ ༠ ఍ /American
Chemical Society୺せ࡞◊✲ᴗ⦼㸸(1) Uraguchi, D.; Kimura, Y.; Ueoka, F.; Ooi,
T. Urea as a Redox-active Directing Group under AsymmetricPhotocatalysis of Iridium-Chiral Borate Ion Pairs. J. Am. Chem.
Soc. 2020, 142, 19462-19467. (2) Uraguchi, D.; Ueoka, F.;
Tanaka, N.; Kizu, T.; Takahashi, W.; Ooi, T. A Structurally
Robust Chiral Borate Ion: Molecular Design, Synthesis, andAsymmetric Catalysis. Angew. Chem. Int. Ed. 2020, 59, 1145611461. (3) Uraguchi, D.; Yamada, K.; Sato, M.; Ooi, T. CatalystDirected Guidance of Sulfur-Substituted Enediolates to
Stereoselective Carbon-Carbon Bond Formation with Aldehydes.
J. Am. Chem. Soc. 2018, 140, 5110-5117. (4) D. Uraguchi, R.
Shibazaki, N. Tanaka, K. Yamada, K. Yoshioka, T. Ooi, CatalystEnabled Site-divergent Stereoselective Michael Reactions:
Overriding Intrinsic Reactivity of Enynyl Carbonyl Acceptors,
Angew. Chem. Int. Ed. 2018, 57, 4732-4736. (5) Uraguchi, D.;
Sasaki, H.; Kimura, Y.; Ito, T.; Ooi, T. Molecular Design,
Synthesis, and Asymmetric Catalysis of a HexacoordinatedChiral Phosphate Ion, J. Am. Chem. Soc. 2018, 140, 2765-2768.
Ꮫ⾡㛵ಀࡢཷ㈹㸸᭷ᶵྜᡂ໬Ꮫ༠఍◊✲௻⏬㈹㸦Ṋ⏣⸆ရᕤᴗ㸧ࠕගᏛάᛶ࢔ࣥࣔࢽ࣒࢘࣋ࢱ࢖ࣥࡢ໬Ꮫ㸸ゐ፹ⓗศᏊෆ࢔ࢩࣝ㌿఩ࢆ฼⏝ࡍࡿᅄ⣭୙ᩧⅣ⣲ᵓ⠏ࠖ
㸦2008/12㸧࣭᪥ᮏ໬Ꮫ఍➨60ᅇ㐍Ṍ㈹ࠕ࢔ࢽ࢜ࣥㄆ㆑ᆺ࢟ࣛࣝ࢜ࢽ࣒࢘ሷࡢ๰〇࡜ゐ፹ⓗ୙ᩧྜᡂ࡬ࡢᛂ⏝ࠖ
㸦2011/03㸧࣭⛉Ꮫᢏ⾡ศ㔝ࡢᩥ㒊⛉Ꮫ኱⮧⾲ᙲⱝᡭ⛉Ꮫ⪅㈹ࠕศᏊㄆ㆑ᆺ࢟ࣛࣝ
᭷ᶵ࢖࢜ࣥᑐゐ፹ࡢ๰〇࡜ᛂ⏝ࡢ◊✲ࠖ
㸦2011/04㸧
࣭BanyuChemist Award㸦BCA 2012㸧ࠕ཯ᛂᛶ࢖࢜ࣥ✀ࡢไᚚࢆᚿྥ
ࡋࡓ࢟ࣛࣝ᭷ᶵ࢖࢜ࣥᑐゐ፹ࡢ๰〇࡜ᛂ⏝ࠖ㸦2012/10㸧࣭
Lectureship Award MBLA㸦MBLA2013㸧ࠕ཯ᛂᛶ࢖࢜ࣥ✀ࡢไᚚࢆᚿྥࡋࡓ࢟ࣛࣝ᭷ᶵ࢖࢜ࣥᑐゐ፹ࡢ๰〇࡜ᛂ⏝ࠖ㸦2014/02㸧
࣭Thieme Chemistry Journal Award 2014㸦2014/01㸧◊✲ศ㔝㸸᭷ᶵ໬Ꮫ/ྜᡂ໬Ꮫ/᭷ᶵศᏊゐ፹/ගゐ፹/㑅ᢥ68ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬኱㡲㈡㑈ኴ
࠾࠾ࡍࡀࡾࡻ࠺ࡓ
Ryota OSUGA
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⫋ྡ㸸ຓᩍ
╔௵㸸2023ᖺ2᭶1᪥㒊㛛㸸ゐ፹཯ᛂ◊✲㒊㛛◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ04 310-1
㟁ヰ㸸011-706-9130
㟁Ꮚ࣓࣮ࣝ㸸osuga@cat.hokudai.ac.jp࢙࢘ࣈ࣮࣌ࢪ㸸https://www.cat.hokudai.ac.jp/nakajima/◊✲ศ㔝㸸ゐ፹໬Ꮫ◊✲ㄢ㢟㸸✀ࠎࡢศගἲࢆ⏝࠸ࡓᅛయゐ፹ࡢゎᯒ/ከᏍ㉁ᮦᩱࡢྜᡂ࡜ゐ፹ᛂ⏝◊✲࣮࣮࢟࣡ࢻ㸸ᅛయゐ፹/ศගἲ/ከᏍ㉁ᮦᩱ
ᏛṔ㸸2015ᖺ3᭶Ⲉᇛᕤᴗ㧗➼ᑓ㛛Ꮫᰯ⏘ᴗࢩࢫࢸ࣒ࢹࢨ
࢖ࣥᕤᏛᑓᨷಟ஢/2017ᖺ3᭶ᮾிᕤᴗ኱Ꮫ኱Ꮫ㝔⥲ྜ⌮ᕤᏛ◊✲⛉≀㉁㟁Ꮚ໬Ꮫᑓᨷಟኈㄢ⛬ಟ஢/2019ᖺ12᭶ᮾிᕤᴗ኱Ꮫ≀㉁⌮ᕤᏛ㝔ᛂ⏝໬Ꮫ⣔ᛂ⏝໬Ꮫࢥ࣮ࢫ༤ኈ
ㄢ⛬ಟ஢Ꮫ఩㸸2017ᖺ3᭶ಟኈ㸦⌮Ꮫ㸧㸦ᮾிᕤᴗ኱Ꮫ㸧/2019ᖺ12᭶༤ኈ㸦⌮Ꮫ㸧
㸦ᮾிᕤᴗ኱Ꮫ㸧ࠕࢮ࢜ࣛ࢖ࢺࡢゐ፹ᶵ⬟ゎ᫂࡟ྥࡅࡓ㉥እศගἲ࡟ࡼࡿ✀ࠎࡢゐ፹≉ᛶホ౯ࠖ⫋Ṕ㸸2020ᖺ1᭶ᮾிᕤᴗ኱Ꮫ㸪༤ኈ◊✲ဨ㸦໬Ꮫ⏕࿨⛉Ꮫ◊✲ᡤ㸧/2020ᖺ4᭶ᮾிᕤᴗ኱Ꮫ㸪≉௵ຓᩍ㸦ࢼࣀ✵㛫ゐ፹◊✲ࣘࢽࢵࢺ㸧/2020ᖺ11᭶ᮾ໭኱Ꮫ㸪ຓᩍ㸦ከඖ≀㉁⛉Ꮫ◊✲ᡤ㸧/2023ᖺ2᭶໭ᾏ㐨኱Ꮫ㸪ຓᩍ㸦ゐ፹⛉Ꮫ◊✲ᡤ㸧ᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍/ゐ፹Ꮫ఍/᪥ᮏࢮ࢜ࣛ࢖ࢺᏛ఍/▼ἜᏛ఍Ꮫ఍άື㸸໬Ꮫ⣔Ꮫ༠఍໭ᾏ㐨ᨭ㒊෤Ꮨ◊✲Ⓨ⾲఍ᐇ⾜ጤဨ㸦2023-⌧ᅾ㸧ゐ፹Ꮫ఍ⱝᡭ఍ጤဨ㸦2020-⌧ᅾ㸧࣭▼ἜᏛ఍ࢪࣗࢽ࢔࣭ࢯࢧ࢖࢔ࢸ࢕ ᖿ஦㸦2020-⌧ᅾ㸧࣭ゐ፹Ꮫ఍ⱝᡭ ఍ ➨ 32 ᅇ ࣇ ࣞ ࢵ ࢩ ࣗ ࣐ ࣥ ࢮ ࣑ ࢼ ࣮ ࣝ 㐠 Ⴀ ጤ ဨ 㛗
㸦2021㸧
࣭Post Symposium of TOCAT9 in Sendai, Organizing
Committee㸦2022㸧୺せ࡞◊✲ᴗ⦼㸸(1) Osuga, R.; Yokoi, T.; Doitomi, K.; Hirao,
H.; Kondo, N. J. Infrared Investigation of Dynamic Behavior of
Brønsted Acid Sites on Zeolites at High Temperatures. J. Phys.
Chem. C 2017, 121, 25411-25420. (2) Osuga, R.; Yokoi, T.;
Kondo, N. J. Probing the basicity of lattice oxygen on H-form
zeolites using CO2. J. Catal. 2019, 371, 291-297. (3) Osuga, R.;
Saikhantsetseg, B.; Yasuda, S.; Manabe, R.; Shima, H.;
Tsutsuminai, S.; Fukuoka, A.; Kobayashi, H.; Yokoi, T. Metal
cation-exchanged zeolites with the location, state, and size ofmetal species controlled. Chem. Commun. 2020, 56, 5913-5916.
(4) Osuga, R.; Takeuchi, T.; Sawada, M.; Kunitake, Y.;
Matsumoto, T.; Yasuda, S.; Onozuka, H.; Tsutsuminai, S.;
Kondo, N. J.; Gies, H.; Yokoi, T. Fabrication of AEI-type
aluminosilicate catalyst with sheet-like morphology for directconversion of propene to butenes. Catal. Sci. Technol. 2021, 11,5839-5848. (5) Osuga, R.; Yabushita, M.; Matsumoto, T.;
Sawada, M.; Yokoi, T.; Kanie, K.; Muramatsu, A. Fluoride-freesynthesis of high-silica CHA-type aluminosilicates by seedassisted aging treatment for starting gel. Chem. Commun. 2022,
58, 11583-11586
Ꮫ⾡㛵ಀࡢཷ㈹㸸ࢮ࢜ࣛ࢖ࢺᏛ఍㸪➨33ᅇ◊✲Ⓨ⾲఍ ⱝᡭඃ⚽ㅮ₇㈹ࠕࣉࣟࢺࣥᆺࢮ࢜ࣛ࢖ࢺࡢ᱁Ꮚ㓟⣲ࡢሷᇶᛶ࡜ゐ፹཯ᛂ࡜ࡢ㛵ࢃࡾࠖ
㸦2017/12㸧
࣭Taiwan-Japan-US Jointᖺሗ ࣭ಶே⦅‫ە‬Workshop on Energy Materials and Sustainable Development,
Excellent poster awards,ࠕIR investigation of curvature effect of
mesoporous silica for acetalization of cyclohexanone ࠖ㸦2018/9㸧࣭▼ἜᏛ఍㸪๰❧60࿘ᖺグᛕᮾி኱఍㸦➨48ᅇ▼Ἔ࣭▼Ἔ໬Ꮫウㄽ఍㸧㸪 Best Presentation AwardࠕInfrared
investigation of dehydration of ethanol over zeolites ࠖ㸦2018/10㸧
࣭ࢮ࢜ࣛ࢖ࢺᏛ఍㸪➨35ᅇ◊✲Ⓨ⾲఍ ⱝᡭඃ⚽
ㅮ₇㈹ࠕ㉥እศගἲࢆ⏝࠸ࡓࢮ࢜ࣛ࢖ࢺୖࡢάᛶ໬࢚࣮ࢸ
ࣝ✀࡟㛵ࡍࡿ᳨ウࠖ
㸦2019/12㸧
࣭ࢮ࢜ࣛ࢖ࢺᏛ఍㸪➨38ᅇ◊✲Ⓨ⾲఍ ⱝᡭඃ⚽ㅮ₇㈹ࠕࣇࢵ⣲ࢆ⏝࠸࡞࠸ࣁ࢖ࢩࣜ࢝
CHAᆺ࢔࣑ࣝࣀࢩࣜࢣ࣮ࢺࡢྜᡂ࡜MTO཯ᛂάᛶホ౯ࠖ
㸦2022/12㸧▼ἜᏛ఍㸪ㄽᩥ㈹ࠕ࣓࢝ࣀࢣ࣑࢝ࣝἲࢆ⏝࠸ࡓ
Fe⨨᥮MWWᆺࢮ࢜ࣛ࢖ࢺࡢྜᡂࠖ
㸦2023/5㸧ΎỈ◊୍ࡋࡳࡎࡅࢇ࠸ࡕ
Ken-ichi SHIMIZU
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
⫋ྡ㸸ᩍᤵ
╔௵㸸2015ᖺ4᭶1᪥㒊㛛ࢡࣛࢫࢱ࣮㝃ᒓゐ፹㐃ᦠ◊✲ࢭࣥࢱ࣮㸸ゐ፹ᮦᩱ◊✲㒊㛛/ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮/つᩚ⾲㠃ࢼࣀᵓ㐀◊✲ࢡࣛࢫࢱ࣮/⏺㠃ࢩ࣑࣮ࣗࣞࢩࣙࣥ◊✲ࢡࣛࢫࢱ࣮/⏘Ꮫᐁ㐃ᦠゐ፹◊✲ࣘࢽࢵࢺ࣭⤫ྜ≀㉁๰〇໬Ꮫ◊✲᥎㐍ࣘࢽࢵࢺᢸᙜ኱Ꮫ㝔㸦Ꮫ㒊㸧㸸⥲ྜ໬Ꮫ㝔◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ04-312-2
㟁ヰ㸸011-706-9164࣭ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9163࣭㟁Ꮚ࣓࣮ࣝ㸸kshimizu@cat.hokudai.ac.jp࢙࢘ࣈ࣮࣌ࢪ㸸http://www.cat.hokudai.ac.jp/shimizu/◊✲ศ㔝㸸ゐ፹࣭㈨※໬Ꮫࣉࣟࢭࢫ/≀⌮໬Ꮫ/ྜᡂ໬Ꮫ◊✲࣮࣮࢟࣡ࢻ㸸ゐ፹タィ/ᶵᲔᏛ⩦/᭷ᶵྜᡂ/⮬ື㌴᤼࢞ࢫί໬ᏛṔ㸸1994ᖺ3᭶ྡྂᒇ኱ᏛᕤᏛ㒊ᛂ⏝໬Ꮫ⛉༞ᴗ/1997ᖺ
3᭶ྡྂᒇ኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ಟኈㄢ⛬ಟ஢/2000ᖺ3᭶ྡྂᒇ኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉༤ኈㄢ⛬ಟ஢Ꮫ఩㸸2000ᖺ3᭶༤ኈ㸦ᕤᏛ㸧㸦ྡྂᒇ኱Ꮫ㸧⫋Ṕ㸸2000ᖺ4᭶᪂₲኱Ꮫ኱Ꮫ㝔⮬↛⛉Ꮫ◊✲⛉ຓᡭ/2004
ᖺ4᭶ྡྂᒇ኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ຓᡭ/2007ᖺ4᭶ྡྂᒇ኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ຓᩍ/2010ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮෸ᩍᤵ/2015ᖺ4᭶1᪥໭ᾏ㐨኱Ꮫゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ/2015ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸦ゐ፹ᮦᩱ◊✲㒊㛛㸧ᡤᒓᏛ఍㸸ゐ፹Ꮫ఍/᪥ᮏ໬Ꮫ఍/▼ἜᏛ఍Ꮫ఍άື㸸ゐ፹Ꮫ఍⦅㞟ጤဨ㸦2002-2004㸧࣭ゐ፹Ꮫ఍㛵ᮾᆅ༊ᖿ஦㸦2003㸧࣭▼ἜᏛ఍ࢪࣗࢽ࢔ࢯࢧ࢖࢔ࢸ࢕࣮௦⾲ᖿ஦㸦2007-2009㸧࣭ゐ፹Ꮫ఍ウㄽ఍ጤဨ㸦2008-2010㸧࣭ゐ፹Ꮫ఍ᗈሗጤဨ㸦2009㸧࣭▼ἜᏛ఍ㄽᩥㄅ⦅㞟ጤဨ㸦20092010㸧࣭▼ἜᏛ఍໭ᾏ㐨ᨭ㒊㛗㸦2018-2019㸧࣭ゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊㛗㸦2020-2021㸧୺せ࡞◊✲ᴗ⦼㸸(1) Miyazaki, S.; Chen, D.; Jiacheng, B.;
Toyao, T.; Kanda, Y.; Shimizu, K. In Situ Spectroscopic Studyof CO2 Capture and Methanation over Ni, Chem Asian J. 2024,
e202301003. (2) Huang, M.; Hu, X.; Chen, D.; Maeno, Z.;
Tsunoji, N.; Toyao, T.; Shimizu, K. Anaerobic
Ammodehydrogenation of Ethane to Acetonitrile over GaLoaded H-FER Zeolite Catalysts, ACS Catal. 2024, 14, 1013-

69

1020. (3) Zhang, N.; Qian, Y.; Toyao, T.; Shimizu, K.
Continuous Unsteady-State De-NOx System via Tandem WaterGas Shift, NH3 Synthesis, and NH3-SCR under Periodic
Lean/Rich Conditions, Environ. Sci. Technol. 2023, 57, 1958419593. (4) Yasumura, S.; Saita, K.; Miyakage, T.; Nagai, K.;
Kon, K.; Toyao, T.; Maeno, Z.; Taketsugu, T.; Shimizu, K.
Designing main-group catalysts for low-temperature methane
combustion by ozone, Nature Commun. 2023, 14, 3926. (5)Kubota, H.; Jing, Y.; Wan, L.; Tong, J.; Zhang, N.; Mine, S.;
Toyao, T.; Toyoshima, R.; Kondoh, H.; Ferri, D.; Shimizu, K.
Operando Spectroscopic Study of Reduction and Oxidation
Half-Cycles in NH3-SCR over CeO2-Supported WO3, ACS
Catal. 2023, 13, 9274-9288.
Ꮫ⾡㛵ಀࡢཷ㈹㸸▼ἜᏛ఍ዡບ㈹ࠕ᪂つ㔠ᒓ㓟໬≀⣔NOx㝖ཤゐ፹ࡢ㛤Ⓨ࡜స⏝ᶵᵓࡢゎ᫂ࠖ
㸦2007/05㸧࣭ゐ፹Ꮫ఍ዡ
ບ㈹ࠕ㖟ࢡࣛࢫࢱ࣮ゐ፹࡟ࡼࡿ⬺◪࠾ࡼࡧ⎔ቃㄪ࿴ᆺ᭷ᶵ
ྜᡂ࡟㛵ࡍࡿ◊✲ࠖ㸦2010/03㸧࣭ᮾᾏ໬Ꮫᕤᴗ఍㈹Ꮫ⾡㈹ࠕ⎔ቃㄪ࿴ᆺ཯ᛂ⏝㖟ࢡࣛࢫࢱ࣮ゐ፹ࡢ㛤Ⓨ࡜స⏝ᶵᵓ࡟㛵ࡿ◊✲ࠖ
㸦2010/05㸧
࣭ᖹᡂ25ᖺᗘ໭ᾏ㐨኱Ꮫ◊✲⥲㛗㈹㸦2014/03/04㸧࣭ᖹᡂ26ᖺᗘ໭ᾏ㐨኱Ꮫ◊✲⥲㛗㈹ዡບ㈹㸦2015/03/11㸧࣭ᖹᡂ28ᖺᗘ໭ᾏ㐨኱Ꮫ◊✲⥲㛗㈹ዡບ㈹㸦2017/01/31㸧࣭௧࿴4ᖺᗘ໭ᾏ㐨኱Ꮫᩍ⫱◊✲⥲㛗⾲ᙲ
㸦2023/2/22㸧
࣭᪥ᮏ໬Ꮫ఍➨41ᅇᏛ⾡㈹㸦2024/3/19㸧ࢩࣗࣟࢺࣜ࢔ࣅࢪࢵࢺ
ࡋࡹࢁ࡜ࡾ࠶ࡧࡌࡗ࡜
Abhijit SHROTRI


⫋ྡ㸸ຓᩍ
╔௵㸸2016ᖺ6᭶16᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸≀㉁ኚ᥮◊✲㒊㛛◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ04 309-2
㟁ヰ㸸011-706-9137࣭ࣇ
ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9139࣭㟁㟁Ꮚ࣓࣮ ࣝ 㸸 ashrotri@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
http://www.cat.hokudai.ac.jp/fukuoka/◊✲ศ㔝㸸ゐ፹࣭㈨※໬Ꮫࣉࣟࢭࢫ/ᶵ⬟≀㉁໬Ꮫ/ࢢ࣮࣭ࣜࣥ⎔ቃ໬Ꮫ
◊✲ㄢ㢟㸸ᅛయゐ፹࡟ࡼࡿࣂ࢖࣐࢜ࢫ࡜CO2ࡢኚ᥮◊✲࣮࣮࢟࣡ࢻ㸸ゐ፹/ࣂ࢖࣐࢜ࢫ/ࢭ࣮ࣝࣟࢫ/CO2
ᏛṔ㸸 Bachelor of Engineering, June, 2006, Department ofChemical Engineering, National Institute of Technology, Raipur,
India/ PhD (Chemical Engineering), April, 2014, AustralianInstitute of Bioengineering and Nanotechnology, University of
QueenslandᏛ఩㸸PhD, Chemical Engineering (University of Queensland)ࠕ Catalytic conversion of lignocellulosic biomass into sugar
alcoholsࠖ⫋ Ṕ 㸸 Process Engineer, Sep 2006-Dec 2009, RelianceIndustries Limited, Mumbai, India/ Postdoctoral Research
Fellow, May 2014-Sep 2015, Catalysis Research Centre,
Hokkaido University/ Postdoctoral Research Fellow, Oct 2015June 2016, Institute for Catalysis, Hokkaido University/
Assistant Professor, June 2016-present Institute for Catalysis,
Hokkaido UniversityᡤᒓᏛ఍㸸ゐ፹Ꮫ఍/᪥ᮏ໬Ꮫ఍/▼ἜᏛ఍୺せ࡞◊✲ᴗ⦼㸸(1) Dostagir, N. H. Md.; Tomuschat, C. R.;
Oshiro, K.; Gao, M.; Hasegawa, J.; Fukuoka, A.; Shrotri, A.,
Mitigating the Poisoning Effect of Formate during CO2
Hydrogenation to Methanol over Co-Containing Dual-Atom70

Oxide Catalysts, JACS Au, 2024, 4, 1048-1058. (2) Palai, Y. N.;
Fukuoka, A.; Shrotri, A.; Unlocking the Potential of 5-Hydroxy2(5H)-furanone as a Platform for Bio-Based Four Carbon
Chemicals, ACS Catal., 2024, 14, 2545-2551. (3) Dostagir, N.
H. M.; Fukuoka, A. Redox Behavior of In−O−Ti Interface for
Selective Hydrogenation of CO2 to CO in Doped In−TiO2
Catalyst. ChemCatChem. 2023, 15, e202201348. (4) Palai, Y. N.;
Shrotri, A.; Fukuoka. A. Selective Oxidation of Furfural to
Succinic Acid over Lewis Acidic Sn-Beta. ACS Catal. 2022, 12,3534-3542. (5) Dostagir, N. H. Md.; Rattanawan, R.; Gao, M.;
Ota, J.; Hasegawa, J.; Asakura, K.; Fukuoka, A.; Shrotri, A. Co
single atoms in ZrO2 with inherent oxygen vacancies forselective hydrogenation of CO2 to CO. ACS Catal. 2021, 11,9450-9461. (6) Dostagir, N. H. Md.; Thompson, C.; Kobayashi,H.; Karim, A. M.; Fukuoka, A.; Shrotri, A. Rh promoted In 2O3
as a highly active catalyst for CO2 hydrogenation to methanol.
Catal. Sci. Technol. 2020, 10, 8196-8202.
Ꮫ⾡㛵ಀࡢཷ㈹㸸National Institute of Technology, Raipur,
India “2023 Young Achiever Alumnus Award” (2023/12/01)࣭
2022ᖺᗘゐ፹Ꮫ఍ዡບ㈹, ୍⯡♫ᅋἲேゐ፹Ꮫ఍,ࠕ஧㓟໬Ⅳ⣲࠾ࡼࡧࣂ࢖࣐࢜ࢫ㈨※ά⏝ࡢࡓࡵࡢゐ፹㛤Ⓨࠖ㸦2023/03/16㸧
࣭➨10ᅇ᪂໬Ꮫᢏ⾡◊✲ዡບ㈹,  ᪂໬Ꮫᢏ⾡᥎㐍༠఍, ࠕ⤖ᬗᛶࢭ࣮ࣝࣟࢫࡢ┤᥋ຍỈศゎࢆྍ⬟࡟ࡍ ࡿ ࢝ ࣮ ࣎ ࣥ ゐ ፹ ࡢ 㛤 Ⓨ ࠖ㸦 2021/06/10 㸧࣭ Best Oralpresentation award at APCAT-7 conference, Mumbai, India(2017/1/26) ࣭University of Queensland International Research
Tution Award, University of Queensland, Australia(2010/03/15)࣭University of Queensland Research Scholarship,
University of Queensland, Australia (2010/03/15)

Ⳣ἟Ꮫྐࡍࡀࡠࡲࡉ࡜ࡋ
Satoshi SUGANUMA⫋ྡ㸸෸ᩍᤵ
╔௵㸸2023ᖺ4᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸ゐ፹཯ᛂ◊✲㒊㛛/ኳ↛Ⅳ⣲㈨※ά⏝◊✲ࢡࣛࢫࢱ࣮
◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ03 310-2
㟁ヰ㸸011-706-9131
㟁Ꮚ࣓࣮ࣝ㸸suganuma@cat.hokudai.ac.jp࢙࢘ࣈ࣮࣌ࢪ㸸https://www.cat.hokudai.ac.jp/nakajima/◊✲ศ㔝㸸ゐ፹࣭㈨※໬Ꮫࣉࣟࢭࢫ/ᶵ⬟≀㉁໬Ꮫ
◊✲ㄢ㢟㸸ᅛయゐ፹࡟ࡼࡿኳ↛Ⅳ⣲㈨※ࡢኚ᥮◊✲࣮࣮࢟࣡ࢻ㸸㓟ሷᇶゐ፹/༠ാᶵ⬟ゐ፹/ࣂ࢖࣐࢜ࢫኚ
᥮ᏛṔ㸸2007ᖺ3᭶ᮾி⌮⛉኱Ꮫ⌮Ꮫ㒊ᛂ⏝໬Ꮫ⛉༞ᴗ/2009
ᖺ3᭶ᮾிᕤᴗ኱Ꮫ኱Ꮫ㝔⥲ྜ⌮ᕤᏛ◊✲⛉≀㉁㟁Ꮚ໬Ꮫᑓᨷಟኈㄢ⛬ಟ஢/2012ᖺ3᭶ྠ༤ኈㄢ⛬ಟ஢Ꮫ఩㸸2009ᖺ3᭶ಟኈ㸦⌮Ꮫ㸧㸦ᮾிᕤᴗ኱Ꮫ㸧/2012ᖺ3᭶༤ ኈ 㸦 ⌮ Ꮫ 㸧㸦 ᮾ ி ᕤ ᴗ ኱ Ꮫ 㸧ࠕ Studies on Catalysis of
Amorphous Carbon with Sulfonic Acid Groupsࠖ⫋Ṕ㸸2010ᖺ4᭶᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸦DC2㸧/2012
ᖺ4᭶ᰴᘧ఍♫࢟ࣕࢱ࣮ࣛ/2014ᖺ3᭶㫽ྲྀ኱Ꮫ㸪ࢸࢽࣗ࢔ࢺࣛࢵࢡຓᩍ㸦ᕤᏛ㒊㸧/2018ᖺ4᭶ྠㅮᖌ/2021ᖺ1᭶ྠ෸
ᩍᤵ/2023ᖺ4᭶໭ᾏ㐨኱Ꮫ෸ᩍᤵ㸦ゐ፹⛉Ꮫ◊✲ᡤ࣭ゐ፹཯ᛂ◊✲㒊㛛㸧

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ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬ᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍/ゐ፹Ꮫ఍/᪥ᮏࢮ࢜ࣛ࢖ࢺᏛ఍/▼ἜᏛ఍Ꮫ఍άື㸸ゐ፹Ꮫ఍ⱝᡭ఍ᖿ஦㸦2010-2012㸧/᪥ᮏ໬Ꮫ఍
࠾ࡶࡋࢁ࣡ࢡ࣡ࢡ໬Ꮫࡢୡ⏺2015㫽ྲྀ໬Ꮫᒎᐇ⾜ጤဨ㸦2015㸧/ࢮ࢜ࣛ࢖ࢺᏛ఍➨31ᅇࢮ࢜ࣛ࢖ࢺ◊✲Ⓨ⾲఍㸦㫽ྲྀ㸧ᐇ⾜ጤဨ㸦2015㸧/ゐ፹Ꮫ఍ཧ↷ゐ፹ࢮ࢜ࣛ࢖ࢺ㹙MFIᆺ㸦ZSM-5㸧௨እ㹛㓄ᕸᢸᙜ㸦2015-2021㸧/ゐ፹Ꮫ఍➨36ᅇཧ↷ゐ፹ウㄽ఍ᐇ⾜ጤဨ㸦2016㸧/᪥ᮏ໬Ꮫ఍ᅄᅜᨭ㒊኱఍㸦㫽ྲྀ㸧ᐇ⾜ጤဨ㸦2017㸧/▼ἜᏛ఍➨47ᅇ୰ᅜ▼Ἔ࣭▼Ἔ໬Ꮫウㄽ఍㸦㫽ྲྀ㸧ᐇ⾜ጤဨ㸦2017㸧/▼ἜᏛ఍୰ᅜᅄᅜ
ᨭ㒊ᖿ஦㸦2018-2023㸧/▼ἜᏛ఍ࢪࣗࢽ࢔࣭ࢯࢧ࢖࢔ࢸ࢕㸦JPIJS㸧ᖿ஦㸦2019-2023㸧/▼ἜᏛ఍➨38ᅇ୰ᅜᅄᅜᨭ㒊
ㅮ₇఍ᖿ஦㸦2020㸧/ゐ፹Ꮫ఍す᪥ᮏᨭ㒊௦㆟ဨ㸦20212023 㸧 /ゐ ፹ Ꮫ ఍ ࢟ ࣕ ࣛ ࢡ ࢱࣜ ࢮ ࣮ ࢩ ࣙ ࣥ ㅮ ⩦ ఍ ᖿ ஦㸦2022㸧/ゐ፹Ꮫ఍➨132ᅇゐ፹ウㄽ఍㸦໭ᾏ㐨኱Ꮫ㸧⌧ᆅᐇ⾜ጤဨ㸦2023㸧/ゐ፹Ꮫ఍఍ㄅ⦅㞟ጤဨ఍㸦2023-㸧/ゐ፹Ꮫ఍ᗈሗጤဨ఍㸦2023-㸧/ゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊ᗢົᖿ஦
㸦2024-㸧/ࢮ࢜ࣛ࢖ࢺᏛ఍௻⏬࣭ᗈሗጤဨ఍㸦2024-㸧୺せ࡞◊✲ᴗ⦼㸸(1) Suganuma, S.; Nakajima, K.; Kitano, M.;
Yamaguchi, D.; Kato, H.; Hayashi, S.; Hara, M. Hydrolysis of
Cellulose by Amorphous Carbon Bearing SO3H, COOH, andOH Groups, J. Am. Chem. Soc., 2008, 130, 12787–12793. (2)Suganuma, S.; Nakamura, K.; Okuda, A.; Katada, N.
Enhancementof
Catalytic
ActivityforTolueneDisproportionation by Loading Lewis Acidic Nickel Species on
ZSM-5 Zeolite, Mol. Catal., 2017, 435, 110-117. (3) Suganuma,
S; Otani, A.; Joka, S.; Asako, H.; Takagi, R.; Tsuji E.; Katada, N.
One-step Conversion of Glutamic Acid into 2-Pyrrolidone on
Supported Ru Catalyst in Hydrogen Atmosphere: Remarkable
Effect of CO Activation, ChemSusChem, 2019, 12, 1381-1389.
(4) Nakano, F.; Goma, T.; Suganuma, S.; Tsuji, E.; Katada, N.
Selective dealkylation of alkyl polycyclic aromatichydrocarbons towards innovative upgrading process of practicalheavy oil, Catal. Sci. Technol., 2021, 11 239-249. (5)Kaku, C.;
Suganuma, S.; Nakajima, K.; Tsuji, E.; Katada, N. Selective
Hydrogenation of L-proline to L-prolinol over Al2O3-supported
Pt-MoOx Catalyst, ChemCatChem, 2022, 14, e202200399.
Ꮫ⾡㛵ಀࡢཷ㈹㸸▼ἜᏛ఍ዡບ㈹㸦ฟග⯆⏘㈹㸧ࠕᐇἜ୰ࡢከ⎔ⰾ㤶᪘㢮㑅ᢥⓗ㌿᥮ࡢࡓࡵࡢᅛయ㓟ゐ፹࠾ࡼࡧ㛵㐃ᢏ⾡ࡢ㛤Ⓨࠖ
㸦2022/5㸧 


ᏵᚿẎ
ࡑࢇࡘ࠸
Zhiyi SONG⫋ྡ㸸෸ᩍᤵ
╔௵㸸2018ᖺ9᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛/㑄⛣㔠ᒓㄏ㉳㧗ศᏊྜᡂ/ኚ᥮◊✲ࢡࣛࢫࢱ࣮
ᢸᙜ኱Ꮫ㝔㸦Ꮫ㒊㸧㸸⌮Ꮫ㒊◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ02-111
㟁ヰ㸸011-706-9207࣭
㟁Ꮚ࣓࣮ࣝ㸸songzhiyi@cat.hokudai.ac.jp◊✲ศ㔝㸸㧗ศᏊᶵ⬟ᮦᩱ◊✲࣮࣮࢟࣡ࢻ㸸᭷ᶵྜᡂ/᭷ᶵ㔠ᒓ໬Ꮫ/ࢼࣀ࣮࢝࣎ࣥ/᭷ᶵ༙ᑟయᮦᩱ
ᏛṔ㸸୰ᅜ༡㛤኱Ꮫ໬ᏛᏛ㝔᭷ᶵ໬Ꮫᑓᨷ໬Ꮫᑓᨷ
Ꮫ఩㸸⌮Ꮫ༤ኈᖺሗ ࣭ಶே⦅‫ە‬⫋Ṕ㸸2006ᖺ9᭶໭ᾏ㐨኱Ꮫ,⛉Ꮫᢏ⾡᣺⯆ᶵᵓ◊✲ဨ/2008
ᖺ9᭶໭ᾏ㐨኱Ꮫゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮≉௵ຓᩍ/2011ᖺ3᭶໭ᾏ㐨኱Ꮫゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ຓᩍ/2015ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤຓᩍ㸦ศᏊゐ፹◊✲㒊㛛㸧/2017ᖺ7᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ෸ᩍᤵ㸦ศᏊゐ፹◊✲㒊㛛㸧/2018ᖺ9᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ෸ᩍᤵ㸦㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛㸧
ᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍㸪ඛ➃㘒యᕤᏛ◊✲఍୺せ࡞◊✲ᴗ⦼㸸(1) Song, Z.; Sato, H.; Pietropaolo, A.; Wang,
Q.; Shimoda, S.; Dai, H.; Imai, Y.; Toda, H.; Harada, T.;
Shichibu, Y.; Konishi, K.; Bando, M.; Naga, N.; Nakano, T.
Aggregation-induced Chirality Amplification of Optically
Active Fluorescent Polyurethane and Cyclic Dimer in the
Ground and Excited States. Chem. Commun. 2022, 58, 10291032. (2) Zhang, Z.; Harada, T.; Pietropaolo, A.; Wang, Y.; Wang,Y.; Hu, X.; He, X.; Chen, H.; Song, Z.; Bando, M.; et al. Bluecircularly polarized luminescent amorphous molecules withsingle-handed propeller chirality induced by circularly polarized
light irradiation. Chem. Commun. 2021, 57 (14), 1794-1797. (3)Wang, Y.; Zavradashvili, N.; Wang, Y.; Pietropaolo, A.; Song,Z.; Bando, M.; Katsarava, R.; Nakano, T. Optically Active
Polymers with Cationic Units Connected through Neutral
Spacers: Helical Conformation and Chirality Transfer toExternal Molecules. Macromolecules 2020, 22, 9916-9928.
(4)Vishwakarma, S.; Kumari, A.; Mitra, K.; Singh, S.; Song, Z.;
Bando, M.; Nakano, T.; Gupta, S. K. S.; Ray, B. Effect of LMenthol Chain-end on the Optical Rotation, Chirality, Tacticity
and Thermal Properties of Polystyrene Prepared by ATRP and
Polyvinylacetates Prepared by RAFT Polymerization: A
Molecular Weight Dependence Study. Materials Today
Commun. 2020, 26, 101705. (5) Dai, H.; Shichibu, Y.; Imai, Y.;
Hara, N.; Konishi, K.; Wang, Y.; Song, Z.; Nakano, T. Synthesis
and stereochemistry of helical polyurethanes based on 2,2′dihydroxy-1,1′-binaphthyl and diisocyanatobenzenes. Polym.
Chem. 2020, 11, 1134-1144.
㧘ⲡᮌ㐩ࡓ࠿ࡃࡉࡂࡉ࡜ࡿ
Satoru TAKAKUSAGI



⫋ྡ㸸ᩍᤵ
╔௵㸸2023ᖺ4᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮/㝃ᒓ㐃ᦠ◊✲ࢭࣥࢱ࣮㸸ゐ፹ᵓ㐀◊✲㒊㛛/ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮/Ꮫ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ࣘࢽࢵࢺ/᪂ᨺᑕග※ゐ፹ィ ⛉Ꮫࣘࢽࢵࢺ/࢟ࣕࢱࣜࢫࢺ࢖
ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࣘࢽࢵࢺ
◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ02 309-1
㟁ヰ㸸011-706-9123࣭ࣇࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9123࣭㟁㟁Ꮚ࣓࣮ࣝ㸸takakusa@cat.hokudai.ac.jp◊✲ศ㔝㸸ࢼࣀᵓ㐀⛉Ꮫ/⏺㠃໬Ꮫ/ࢼࣀᮦᩱ࣭ࢼࣀࣂ࢖࢜
ࢧ࢖࢚ࣥࢫ/཯ᛂ㏿ᗘㄽ࡜ゐ፹/≀⌮໬Ꮫ/㟁Ẽ໬Ꮫ/ᶵ⬟≀㉁໬Ꮫ/ᶵ⬟ᮦᩱ࣭ࢹࣂ࢖ࢫ
◊✲ㄢ㢟㸸ࣉࣛࢬ࣐ゐ፹཯ᛂࡢᶵᵓゎ᫂㸦2019-㸧/࢜࣌ࣛࣥࢻ⾲㠃⛉Ꮫィ ᡭἲࡢ㛤Ⓨ࡜ゐ፹άᛶⅬࡢ⢭ᐦᵓ㐀ゎᯒ㸦2018-㸧/೫ග඲཯ᑕ⺯ගXAFSἲ࡟ࡼࡿ㓟໬≀ୖ༢ཎᏊ㔠ᒓ✀ࡢ୕ḟඖᵓ㐀ゎᯒ㸦2008-㸧/⾲㠃X⥺ᩓ஘ἲ࡜㟁Ẽ໬Ꮫ㉮ᰝᆺࢺࣥࢿࣝ㢧ᚤ㙾࡟ࡼࡿᅛᾮ⏺㠃ᵓ㐀ゎᯒ
㸦2002-2008㸧◊✲࣮࣮࢟࣡ࢻ㸸≀⌮໬Ꮫ/ᶵ⬟≀㉁໬Ꮫ/ᶵ⬟ᮦᩱᏛṔ㸸1998ᖺ3᭶ᮾி኱Ꮫ⌮Ꮫ㒊໬Ꮫ⛉༞ᴗ/2000ᖺ3᭶ᮾ

71ி኱Ꮫ⌮Ꮫ⣔◊✲⛉໬Ꮫᑓᨷಟኈㄢ⛬ಟ஢/2002ᖺ9᭶ᮾி኱Ꮫ⌮Ꮫ⣔◊✲⛉໬Ꮫᑓᨷ༤ኈㄢ⛬୰㏵㏥Ꮫ
Ꮫ఩㸸2000ᖺ3᭶ಟኈ㸦⌮Ꮫ㸧㸦ᮾி኱Ꮫ㸧/2003ᖺ4᭶༤ኈ㸦⌮Ꮫ㸧㸦ᮾி኱Ꮫ㸧
ࠕTiO2(110)༢⤖ᬗ⾲㠃ୖࡢࢼࣀᵓ㐀యᙧᡂᶵᵓ࡜ศᏊ྾╔࣭཯ᛂ㐣⛬ࡢSTMほᐹࠖ⫋Ṕ㸸2001ᖺ4᭶᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸦DC2㸧㸦2002
ᖺ9᭶ࡲ࡛㸧/2002ᖺ9᭶໭ᾏ㐨኱Ꮫຓᡭ㸦኱Ꮫ㝔⌮Ꮫ◊✲⛉໬Ꮫᑓᨷ㸧/2008ᖺ4᭶໭ᾏ㐨኱Ꮫ෸ᩍᤵ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮㸧/2015ᖺ10᭶໭ᾏ㐨኱Ꮫ෸ᩍᤵ㸦ゐ፹⛉Ꮫ◊✲ᡤ㸧
/2023ᖺ4᭶໭ᾏ㐨኱Ꮫᩍᤵ㸦ゐ፹⛉Ꮫ◊✲ᡤ㸧ᅾእ◊✲Ṕ㸸2007ᖺ5᭶- 9᭶௖ᅜ࢚ࢥ࣮࣭࣏ࣝࣜࢸࢡࢽࢵ
ࢡᡤᒓᏛ఍㸸ゐ፹Ꮫ఍/㟁Ẽ໬Ꮫ఍/᪥ᮏ໬Ꮫ఍/᪥ᮏ⾲㠃⛉Ꮫ
఍/᪥ᮏXAFS◊✲఍/࢔࣓ࣜ࢝໬Ꮫ఍
Ꮫ఍άື㸸ゐ፹Ꮫ఍௻⏬࣭ᩍ⫱ጤဨ఍ጤဨ㸦2023-㸧/ゐ፹Ꮫ఍ඛ➃ᨺᑕග฼ά⏝◊✲఍ᖿ஦㸦2022-㸧/᪥ᮏ໬Ꮫ఍໭
ᾏ㐨ᨭ㒊ᗢົᖿ஦㸦2022-2023㸧/᪥ᮏ໬Ꮫ఍௦⾲ṇ఍ဨ
㸦2010-㸧/㟁Ẽ໬Ꮫ఍໭ᾏ㐨ᨭ㒊ᖿ஦㸦2003-㸧/᪥ᮏ⾲㠃┿✵Ꮫ఍ᮾ໭࣭໭ᾏ㐨ᨭ㒊ᖿ஦㸦2013-㸧/ゐ፹Ꮫ఍ḟୡ௦ᨺᑕග࣮࣡࢟ࣥࢢࢢ࣮ࣝࣉጤဨ㸦2021-2022㸧/㟁Ẽ໬Ꮫ఍⦅㞟ጤဨ఍㸦2018-2019㸧/ゐ፹Ꮫ఍ウㄽ఍ጤဨ఍ጤဨཬࡧ⥲ົጤဨ఍ጤဨ㸦2013-2014㸧/᪥ᮏ⾲㠃⛉Ꮫ఍໭ᾏ㐨ᨭ㒊ᖿ஦㸦2014-2016㸧/᪥ᮏXAFS◊✲఍௻⏬ᖿ஦㸦2015-2017㸧୺せ࡞◊✲ᴗ⦼㸸(1) Liu, C.; Lu, B.; Ariga-Miwa, H.; Ogura,S.; Ozawa, T.; Fukutani, K.; Gao, M.; Hasegawa, J.; Shimizu,
K.; Asakura, K.; Takakusagi, S. Dynamic Behavior ofIntermediate Adsorbates to Control Activity and ProductSelectivity
in
Heterogeneous
Catalysis:
MethanolDecomposition on Pt/TiO2(110). J. Am. Chem. Soc. 2023, 145,
19953–19960. (2) Kim, D.Y.; Ham, H.; Chen, X.; Liu, S.; Xu,
H.; Lu, B.; Furukawa, S.; Kim, H.H.; Takakusagi, S.; Sasaki, K.;
Nozaki, T. Cooperative catalysis of vibrationally excited CO2
and alloy catalyst breaks the thermodynamic equilibrium
limitation. J. Am. Chem. Soc. 2022 144, 14140-14149. (3) Lu,
B.; Kido, D.; Sato, Y.; Xu, H.; Chun, W. J.; Asakura, K.;
Takakusagi, S. Development of Operando Polarizationdependent Total Reflection Fluorescence X‑ray Absorption Fine
Structure Technique for Three-Dimensional Structure
Determination of Active Metal Species on a Model Catalyst
Surface under Working Conditions. J. Phys. Chem. C 2021, 125,
12424-12432. (4) Takakusagi, S.; Iwasawa, Y.; Asakura, K.
Premodified Surface Method to Obtain Ultra-highly Dispersed
Metals and their 3D Structure Control on an Oxide Single-crystal
Surface. Chem. Rec. 2019, 18, 1244-1255. (5) Takakusagi, S.;
Kunimoto, A.; Sirisit, N.; Uehara, H.; Ohba, T.; Uemura, Y.;
Wada, T.; Ariga, H.; Chun, Wang-Jae; Iwasawa, Y.; Asakura, K.
A New Indicator for Single Metal Dispersion on a TiO2(110)
Surface Premodified with a Mercapto Compound. J. Phys.
Chem. C 2016, 120, 15785-15791.
Ꮫ ⾡ 㛵 ಀ ࡢ ཷ ㈹ 㸸 Pacifichem 2000 Student Poster Award
㸦2000/12㸧࣭᪥ᮏ⾲㠃⛉Ꮫ఍ISSS-5 Best Poster AwardࠕEffectof Electrode Potential on Ag Deposition on a Reconstructed
Au(111) Surface Studied by In situ Scanning TunnelingMicroscopyࠖ㸦2008㸧
࣭᪥ᮏ໬Ꮫ఍➨88᫓Ꮨᖺ఍ඃ⚽ㅮ₇㈹㸦Ꮫ⾡㸧ࠕ㉮ᰝᆺࢺࣥࢿࣝ㢧ᚤ㙾㸦STM㸧࡟ࡼࡿ෌ᵓᡂࡋ
ࡓAu(111)⾲㠃ୖ࡬ࡢ㟁Ẽ໬ᏛⓗAgᯒฟ㐣⛬ࡢࡑࡢሙ㏣㊧ࠖ㸦2008/04㸧
࣭᪥ᮏ໬Ꮫ఍➨90᫓Ꮨᖺ఍ⱝ࠸ୡ௦ࡢ≉ูㅮ
₇఍ࠕᐇ⏝ⓗ࡟⯆࿡࠶ࡿᅛẼ࣭ᅛᾮ⏺㠃ࣉࣟࢭࢫࡢཎᏊ࣭
ศᏊࣞ࣋ࣝほᐹ࡜ᶵᵓゎ᫂ࠖ
㸦2010/03㸧࣭᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊ዡບ㈹ࠕ༢⤖ᬗ⾲㠃ୖ࡟ᵓ⠏ࡋࡓ㔠ᒓࢼࣀᵓ㐀యࡢ㧗ศゎ⬟ィ ࡜⾲㠃໬ᏛࣉࣟࢭࢫࡢཎᏊࣞ࣋ࣝほᐹࠖ㸦2014/01㸧࣭໭ᾏ㐨኱Ꮫ◊✲⥲㛗㈹ዡບ㈹㸦2015/03/11㸧
࣭᪥ ᮏ ໬ Ꮫ ఍ BCSJ ㈹ ࠕ Investigation of the Cleanliness ofTransferred Graphene: The First Step toward Its Application as72

a Window Material for Electron Microscopy and Spectroscopyࠖ㸦2015/08㸧
࣭American Vacuum Society (AVS) VTD Shop Note
AwardsࠕPortable ultrahigh-vacuum sample storage system forpolarization-dependent total-reflection fluorescence X-ray
absorption fine structure spectroscopyࠖ(2017/06)࣭᪥ᮏ⾲㠃┿✵Ꮫ఍ㄽᩥ㈹ࠕThorough Search Analysis of Extended X-ray
Absorption Fine Structure Data for Complex Molecules andNanomaterials Applicationsࠖ(2021/11)㉿ᙉࡕࡷ࠾ࡕࡷࢇ
Qiang ZHAO


⫋ྡ㸸ຓᩍ
╔௵㸸2021ᖺ10᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸ศᏊゐ፹◊✲㒊㛛◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05 111
㟁ヰ㸸011-706-9151࣭ࣇ
ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9149࣭㟁㟁Ꮚ࣓࣮ ࣝ 㸸 qiang@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
https://www.cat.hokudai.ac.jp/bunshishokubai.html◊✲ศ㔝㸸᭷ᶵ໬Ꮫ/ྜᡂ໬Ꮫ/ศᏊゐ፹໬Ꮫ◊✲ㄢ㢟㸸ࣛࢪ࢝ࣝゐ፹࡜ࡋ࡚ാࡃ࢟ࣛࣝࣜࣥ㓟㸦Ⅲ㸧ゐ፹ࡢ๰〇◊✲࣮࣮࢟࣡ࢻ㸸ࣛࢪ࢝ࣝゐ፹/❧య໬Ꮫไᚚ
ᏛṔ㸸2016ᖺ3᭶ி㒔኱Ꮫྜᡂ࣭⏕≀໬Ꮫᑓᨷಟኈㄢ⛬ಟ
஢/2019ᖺ3᭶ி㒔኱Ꮫྜᡂ࣭⏕≀໬Ꮫᑓᨷ༤ኈㄢ⛬ಟ஢Ꮫ఩㸸2016ᖺ3᭶ಟኈ㸦ᕤᏛ㸪ி㒔኱Ꮫ㸧/2019ᖺ3᭶༤ኈ㸦ᕤᏛ㸪ி㒔኱Ꮫ㸧⫋Ṕ㸸2012ᖺ2᭶୰ᅜ⛉Ꮫ㝔ୖᾏ᭷ᶵ໬Ꮫ◊✲ᡤ◊✲⿵ຓ
ဨ/2016ᖺ4᭶⊂❧⾜ᨻἲே᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ
/2019ᖺ4᭶࢔࣓࣭ࣜ࢝ࣃࢹ࣮ࣗ኱Ꮫ໬Ꮫ⣔༤ኈ◊✲ဨ/2022
ᖺ10᭶ࡼࡾ⌧⫋ᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍/᪥ᮏ⸆Ꮫ఍
Ꮫ఍άື㸸࡞ࡋ
୺ せ ࡞ ◊ ✲ ᴗ ⦼㸸 (1) Zhao, Q.; Miura, T.; Murakami, M.
Cyclization Reaction of 4-Acyl-1,2,3-triazoles Possessing
Phenyl Rings through Generation of Electron-Deficient
Carbenoids. Chem. Lett. 2019, 48, 510-512. (2) Miura, T.; Zhao,
Q.; Murakami, M. Selective Functionalization of AromaticC(sp2)–H Bonds in the Presence of Benzylic C(sp3)–H Bonds byElectron-Deficient Carbenoid Generated from 4-Acyl-1sulfonyl-1,2,3-triazoles. Angew. Chem. Int. Ed. 2017, 56, 1664516649. (3) Miura, T.; Zhao, Q.; Funakoshi, Y.; Murakami, M.
Site-Selective Introduction of an Enamido Group at the C(3)Position of Indoles. Heterocycles 2015, 91, 1579-1584. (4)Miura, T.; Zhao, Q.; Funakoshi, Y.; Murakami, M. Thermal
Reaction of 4-(p-Aminophenyl)-1-sulfonyl-1,2,3-triazoles
Furnishing Benzoyl Cyanides Through N-Sulfinyl Imine
Intermediates. Chem. Lett. 2015, 44, 967-969.

ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬

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㫽ᒇᑿ㝯

୰ᓥΎ㝯

࡜ࡸ࠾ࡓ࠿ࡋ
Takashi TOYAO࡞࠿ࡌࡲࡁࡼࡓ࠿
Kiyotaka NAKAJIMA⫋ྡ㸸෸ᩍᤵ
╔௵㸸2023ᖺ11᭶1᪥㒊㛛ࢡࣛࢫࢱ࣮㸸ゐ፹ᮦᩱ◊✲㒊㛛/ࢹ࣮ࢱ㥑ືᆺゐ፹◊✲ࢡࣛࢫࢱ࣮
ᢸᙜ኱Ꮫ㝔㸦Ꮫ㒊㸧㸸⥲ྜ໬Ꮫ㝔◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ04 111
㟁ヰ㸸011-706-9165࣭ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9163࣭㟁Ꮚ࣓࣮ ࣝ 㸸 toyao@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
http://www.cat.hokudai.ac.jp/shimizu/◊✲ศ㔝㸸ゐ፹࣭㈨※໬Ꮫࣉࣟࢭࢫ/≀⌮໬Ꮫ/ྜᡂ໬Ꮫ◊✲࣮࣮࢟࣡ࢻ㸸Ỉ⣲໬/⮬ື㌴᤼࢞ࢫί໬/CO2㈨※໬/ィ
⟬⛉Ꮫ/࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫ
ᏛṔ㸸2011ᖺ3᭶኱㜰ᗓ❧኱ᏛᕤᏛ㒊ᛂ⏝໬Ꮫ⛉༞ᴗ/2013
ᖺ3᭶኱㜰ᗓ❧኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ಟኈㄢ⛬ಟ஢/2015
ᖺ9᭶኱㜰ᗓ❧኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉༤ኈㄢ⛬ಟ஢Ꮫ఩㸸2015ᖺ9᭶༤ኈ㸦ᕤᏛ㸧㸦኱㜰ᗓ❧኱Ꮫ㸧⫋Ṕ㸸2013ᖺ4᭶⊂❧⾜ᨻἲே᪥ᮏᏛ⾡᣺⯆఍ ≉ู◊✲ဨ
㸦DC1㸧/2015ᖺ10᭶⊂❧⾜ᨻἲே᪥ᮏᏛ⾡᣺⯆఍ ≉ู◊✲ဨ㸦PD㸧/2015ᖺ12᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤຓᩍ/2023ᖺ11᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ෸ᩍᤵᡤᒓᏛ఍㸸ゐ፹Ꮫ఍/᪥ᮏ໬Ꮫ఍/▼ἜᏛ఍Ꮫ఍άື㸸ゐ፹Ꮫ఍ⱝᡭጤဨ㸦2012-㸧/▼ἜᏛ఍໭ᾏ㐨ᨭ㒊ᖿ஦㸦2016-㸧/ゐ፹Ꮫ఍ཧ↷ゐ፹ጤဨ㸦2022-㸧୺せ࡞◊✲ᴗ⦼㸸(1) Jing, Y.; He, C.; Zhang, N.; Murano, Y.;
Toyoshima, R.; Kondoh, K.; Kageyama, Y.; Inomata, H.; Toyao,
T.Promotional Effect of Ag on the Catalytic Decomposition of
N2O in the Presence of O2 over the Al2O3-Supported Rh Catalyst.
ACS Catal. 2023, 13, 12983–12993. (2) Wang, G.; Mine, S.;
Chen, D.; Jing, Y.; Ting, K. W.; Yamaguchi, T.; Takao, M.;
Maeno, M.; Takigawa, I.; Matsushita, K.; Shimizu, K.; Toyao, T.
Accelerated discovery of multi-elemental reverse water-gas shiftcatalysts using extrapolative machine learning approach. Nature
Communications. 2023, 14, 5861. (3) Phongprueksathat, N.;
Ting, K.W.; Mine, S.; Jing, Y.; Toyoshima, R.; Kondoh, H.;
Shimizu, K. Toyao, T.; Urakawa, A. Bifunctionality of Re
Supported on TiO2 in Driving Methanol Formation in LowTemperature CO2 Hydrogenation. ACS Catal. 2023, 13, 10734–
10750. (4) Toyao, T.; Maeno, Z.; Takakusagi, S.; Kamachi, T.;
Takigawa, I.; Shimizu, K. Machine Learning for Catalysis
Informatics: Recent Applications and Prospects. ACS Catal. C
2020, 10, 2260–2297. (5) Jing. Y.; Cai. Z.; Liu, C.; Toyao, T.;
Maeno, Z.; Asakura, H.; Hiwasa, S.; Nagaoka, S.; Kondoh, H.;
Shimizu, K. Promotional Effect of La in the Three-Way
Catalysis of La-Loaded Al2O3-Supported Pd Catalysts(Pd/La/Al2O3). ACS Catal. 2020, 10, 1010–1023.
Ꮫ⾡㛵ಀࡢཷ㈹㸸᪥ᮏ໬Ꮫ఍➨ᅇ㐍Ṍ㈹ࠕእᤄⓗ᥈⣴ࡀྍ⬟࡞ᶵᲔᏛ⩦ࢆ⏝࠸ࡓCO2ኚ᥮ゐ፹㛤Ⓨࠖ㸦2023/03/24㸧

ᖺሗ ࣭ಶே⦅‫ە‬

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╔௵㸸2022ᖺ4᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸ゐ፹཯ᛂ◊✲㒊㛛◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ03 311-2
㟁ヰ㸸011-706-9132
㟁Ꮚ࣓࣮ࣝ㸸nakajima@cat.hokudai.ac.jp࢙࢘ࣈ࣮࣌ࢪ㸸https://www.cat.hokudai.ac.jp/nakajima/◊✲ศ㔝㸸ゐ፹࣭㈨※໬Ꮫࣉࣟࢭࢫ/ᶵ⬟≀㉁໬Ꮫ/◊✲ㄢ㢟㸸Ỉ୰࡛ᶵ⬟ࡍࡿᅛయ㓟ሷᇶゐ፹ࡢ㛤Ⓨ/ᅛయゐ፹࡟ࡼࡿࣂ࢖࣐࢜ࢫኚ᥮
◊✲࣮࣮࢟࣡ࢻ㸸㓟ሷᇶゐ፹/㔠ᒓ㓟໬≀/ࣂ࢖࣐࢜ࢫኚ᥮
ᏛṔ㸸2001ᖺ3᭶᫂἞኱Ꮫ⌮ᕤᏛ㒊ᕤᴗ໬Ꮫ⛉༞ᴗ/2003ᖺ
3᭶ᮾிᕤᴗ኱Ꮫ኱Ꮫ㝔⥲ྜ⌮ᕤᏛ◊✲⛉≀㉁㟁Ꮚ໬Ꮫᑓᨷಟኈㄢ⛬ಟ஢/2006ᖺ3᭶ྠ༤ኈㄢ⛬ಟ஢Ꮫ఩㸸2003ᖺ3᭶ಟኈ㸦⌮Ꮫ㸧㸦ᮾிᕤᴗ኱Ꮫ㸧/2006ᖺ3᭶༤ኈ㸦⌮Ꮫ㸧㸦ᮾிᕤᴗ኱Ꮫ㸧ࠕStudies on the syntheses,
structural characteristics, and applications of organic-inorganic
hybrid mesoporous materialsࠖ⫋Ṕ㸸2006ᖺ4᭶ᰴᘧ఍♫㇏⏣୰ኸ◊✲ᡤ㸪ᐈဨ◊✲ဨ
/2007ᖺ4᭶ᮾிᕤᴗ኱Ꮫ㸪≉௵ຓᩍ㸦ᛂ⏝ࢭ࣑ࣛࢵࢡࢫ◊✲ᡤ㸧/2009ᖺ2᭶ྠຓᩍ/2015ᖺ4᭶໭ᾏ㐨኱Ꮫ෸ᩍᤵ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮㸧/2015ᖺ10᭶໭ᾏ㐨኱Ꮫ෸ᩍᤵ㸦ゐ፹⛉Ꮫ◊✲ᡤ࣭≀㉁ኚ᥮◊✲㒊㛛㸧/2022ᖺ4᭶໭ᾏ㐨኱Ꮫᩍᤵ㸦ゐ፹⛉Ꮫ◊✲ᡤ࣭ゐ፹཯ᛂ◊✲㒊㛛㸧ᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍/ゐ፹Ꮫ఍/᪥ᮏࢮ࢜ࣛ࢖ࢺᏛ఍/▼ἜᏛ఍Ꮫ఍άື㸸ゐ፹Ꮫ఍ⱝᡭ఍ᖿ஦㸦2004-2006㸧࣭ゐ፹Ꮫ఍ⱝ
ᡭ఍௦⾲ᖿ஦㸦2005-2006㸧࣭ゐ፹Ꮫ఍࢟ࣕࢱࣜࢩࢫࢫࢡ࣮
ࣝ㐠Ⴀጤဨ㸦2008-2011㸧
࣭ゐ፹Ꮫ఍ウㄽ఍ጤဨ㸦2011-2013㸧࣭ࢮ࢜ࣛ࢖ࢺᏛ఍ࢮ࢜ࣛ࢖ࢺ◊✲Ⓨ⾲఍ᐇ⾜ጤဨ㸦2008,2010,2012㸧࣭᪥ᮏ໬Ꮫ఍᫓Ꮨᖺ఍㸪ࣉࣟࢢ࣒ࣛ⦅ᡂ
ጤဨ㸦2011,2013㸧࣭➨7ᅇ㓟ሷᇶゐ፹ᅜ㝿఍㆟㸦ABC-7㸧ᐇ⾜ጤဨ㸦2011-2013㸧࣭▼ἜᏛ఍఍ㄅ⦅㞟ጤဨ㸦2014-2015㸧࣭ゐ፹Ꮫ఍௦㆟ဨ㸦2014-2016㸧࣭ゐ፹Ꮫ఍໭ᾏ㐨ᆅ༊ᖿ஦
㸦2016-2018㸧࣭▼ἜᏛ఍໭ᾏ㐨ᨭ㒊ᖿ஦㸦2016-2018㸧࣭ゐ፹Ꮫ఍௻⏬ᩍ⫱ጤဨ㸦2019-2023㸧
࣭᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊ᖿ஦㸦2016-2022㸧࣭ゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊㛗㸦2024-㸧࣭ゐ፹Ꮫ఍ᅜ㝿஺ὶጤဨ㸦2024-㸧୺ せ ࡞ ◊ ✲ ᴗ ⦼ 㸸 (1) Nakajima, K.; Baba, Y.; Noma, R.;
Kitano, M.; Kondo, J. N.; Hayashi, S.; Hara, M. Nb2O5·nH2O asa Heterogeneous Catalyst with Water-Tolerant Lewis Acid Sites.
J. Am. Chem. Soc. 2011, 133, 4224-4227. (2) Gupta, N. K.;
Fukuoka, A.; Nakajima, K. Amorphous Nb2O5 as a Selective andReusable Catalyst for Furfural Production from Xylose inBiphasic Water and Toluene. ACS Catal. 2017, 7, 2430-2436. (3)Kim, M.; Su, Y.; Fukuoka, A.; Hensen, E. J. M.; Nakajima, K.
Aerobic Oxidation of 5-(Hydroxymethyl)furfural Cyclic Acetal
Enables Selective Furan-2,5-dicarboxylic Acid Formation with
CeO2-Supported Gold Catalyst. Angew. Chem. Int. Ed. 2018, 57,
8235-8239. (4) Kim, M.; Su, Y.; Aoshima, T.; Fukuoka, A.;
Hensen, E. J. M.; Nakajima, K. Effective Strategy of Furan
Dicarboxylate Production for Biobased Polyester Applications.
ACS Catal. 2019, 9, 4277-4285. (5) Wiesfeld, J. J.; Kim, M.;
Nakajima, K.; Hensen, E. J. M. Selective Hydrogenation of 5Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan Using73

Supported Rhenium-promoted Nickel Catalysts in Water. Green
Chem. 2020, 22, 1229-1238.
Ꮫ⾡㛵ಀࡢཷ㈹㸸▼ἜᏛ఍ዡບ㈹㸦ฟග⯆⏘㈹㸧ࠕỈ୰࡛ᶵ⬟ࡍࡿ㓟໬ࢽ࢜ࣈ࠾ࡼࡧࢫࣝ࣍ࣥ໬࣮࢝࣎ࣥᅛయ㓟ゐ፹ࡢ㛤Ⓨ࡜ࣂ࢖࣐࢜ࢫኚ᥮཯ᛂ࡬ࡢᛂ⏝ࠖ
㸦2012/5㸧࣭ᮾிᕤᴗ኱Ꮫ㸪ᣮᡓⓗ◊✲㈹ࠕ᪂つ࡞Ỉ୰ᶵ⬟ゐ፹ࢆ⏝࠸ࡓ᳜≀⏤᮶Ⅳ໬Ỉ⣲࠿ࡽࡢᚲ㡲໬Ꮫရཎᩱࡢ⎔ቃప㈇Ⲵྜᡂࠖ
㸦2014/10㸧࣭ゐ፹Ꮫ఍ዡບ㈹ࠕỈ୰࡛ᶵ⬟ࡍࡿᅛయࣝ࢖ࢫ
㓟ࡢ㛤Ⓨ࡜⢾ኚ᥮཯ᛂ࡬ࡢᛂ⏝ࠖ
㸦2015/3㸧
࣭᪥ᮏ໬Ꮫ఍㸪ⱝ࠸ୡ௦ࡢ≉ูㅮ₇఍㸪ㅮ₇㈹ࠕ㓟໬ࢳࢱࣥࡢỈ୰ࣝ࢖ࢫ㓟≉ᛶ࡜ࢢࣜࢭ࣮ࣟࣝỈ⁐ᾮ࠿ࡽࡢங㓟ྜᡂ࡬ࡢᛂ⏝ࠖ
㸦2015/03/11㸧࣭ᖹᡂ28ᖺᗘ໭ᾏ㐨኱Ꮫ◊✲⥲㛗㈹ዡບ㈹㸦2017/1/31㸧
࣭➨5ᅇ≀㉁࣭ࢹࣂ࢖ࢫඹྠ◊✲㈹, ≀㉁࣭ࢹࣂ࢖ࢫ㡿ᇦඹྠ◊✲ᣐⅬࠕࢽ࢜ࣈ⣔」ྜ㓟໬≀࡟ࡼࡿ⢾ኚ᥮཯ᛂࠖ㸦2023/5㸧୰㔝⎔࡞࠿ࡢࡓࡲࡁ
Tamaki NAKANO⫋ྡ㸸ᩍᤵ╔௵㸸2012ᖺ4᭶1᪥㒊㛛ࢡࣛࢫࢱ࣮㸸㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛/ゐ፹◊✲ᇶ┙
㛤Ⓨࢡࣛࢫࢱ࣮
◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05 309-1
㟁ヰ㸸011-706-9155࣭ࣇࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9156࣭㟁㟁Ꮚ࣓࣮ࣝ 㸸tamaki.nakano@cat.hokudai.ac.jp ࣭࢘࢘ ࢙ࣈ࣮࣌ࢪ 㸸
http://polymer.cat.hokudai.ac.jp/◊✲ศ㔝㸸㧗ศᏊ໬Ꮫ◊✲ㄢ㢟㸸ࡽࡏࢇ㧗ศᏊࡢྜᡂ࣭㧗ศᏊࡢ㠀ࡽࡏࢇᆺ࢔ࣔ
ࣝࣇ࢓ࢫ㧗ḟᵓ㐀ไᚚ࣭㧗ศᏊࡢບ㉳≧ែ࢟ࣛࣜࢸ࢕࣮ไ
ᚚ࣭㧗ศᏊ་⸆ရࡢ㛤Ⓨ◊✲࣮࣮࢟࣡ࢻ㸸ග/୙ᩧ/࢟ࣛࣝ/ࡽࡏࢇ/π㟁ᏊᏛṔ㸸1986ᖺ3᭶኱㜰኱Ꮫᇶ♏ᕤᏛ㒊ྜᡂ໬Ꮫ⛉༞ᴗ/1988
ᖺ3᭶኱㜰኱Ꮫ኱Ꮫ㝔ᇶ♏ᕤᏛ◊✲⛉༤ኈ๓ᮇㄢ⛬໬Ꮫᑓ
ᨷಟ஢/1990ᖺ8᭶኱㜰኱Ꮫ኱Ꮫ㝔ᇶ♏ᕤᏛ◊✲⛉༤ኈᚋᮇㄢ⛬໬Ꮫᑓᨷ㏥Ꮫ
Ꮫ఩㸸1988ᖺ3᭶ᕤᏛಟኈ㸦኱㜰኱Ꮫ㸧/1991ᖺ6᭶ᕤᏛ༤ኈ㸦 ኱ 㜰 ኱ Ꮫ 㸧ࠕ Asymmetric Polymerization of Bulky
Methacrylates and Stereomutaion of Helical Polymersࠖ⫋Ṕ㸸1990ᖺ9᭶ྡྂᒇ኱Ꮫຓᡭ㸦ᕤᏛ㒊ᛂ⏝໬Ꮫ⛉ᶵ⬟㧗ศᏊ໬Ꮫㅮᗙ㸧/1997ᖺ4᭶ྡྂᒇ኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ᛂ⏝໬Ꮫᑓᨷຓᡭ/1998ᖺ4᭶ྠຓᩍᤵ/1999ᖺ4᭶ዉⰋඛ➃⛉Ꮫᢏ⾡኱Ꮫ㝔኱Ꮫຓᩍᤵ㸦≀㉁๰ᡂ⛉Ꮫ◊✲⛉཯ᛂไᚚ⛉Ꮫㅮᗙ㸧/2006ᖺ4᭶໭ᾏ㐨኱Ꮫᩍᤵ㸦኱Ꮫ㝔ᕤ◊✲㝔⏕≀ᶵ⬟㧗ศᏊ㒊㛛㸧/2012ᖺ4᭶ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ᩍᤵ
㸦㞟ྜᶵ⬟໬Ꮫ◊✲㒊㛛㒊㛛㸧/2015ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸦㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛㸧ᅾእ◊✲Ṕ㸸1993ᖺ9᭶-1994ᖺ8᭶ࢥ࣮ࢿࣝ኱Ꮫᐈဨ◊✲ဨᡤᒓᏛ఍㸸㧗ศᏊᏛ఍/᪥ᮏ໬Ꮫ఍/ග໬Ꮫ༠఍/ゐ፹Ꮫ఍/᭷ᶵྜᡂ໬Ꮫ༠఍/࢔࣓ࣜ࢝໬Ꮫ఍
Ꮫ఍άື㸸㧗ศᏊᏛ఍㛵すᨭ㒊ᖿ஦㸦2002-2006㸧࣭ྠ໭ᾏ㐨ᨭ㒊⌮஦㸦2008-㸧࣭᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊ᖿ஦㸦20102012㸧࣭㧗ศᏊᏛ఍㧗ศᏊ࿨ྡἲጤဨ఍ጤဨ㸦2004-㸧ጤဨ㛗㸦2019-㸧࣭ࠕ㧗ศᏊࠖㄅ⦅㞟ጤဨ఍ᨭ㒊ጤဨ㸦2010-2012㸧
࣭
IUPAC Division IV IUPAC Subcommittee for Polymer

74

Terminology (SPT) member㸦2010-㸧
࣭᪥ᮏ໬Ꮫ఍࿨ྡἲᑓ㛛ጤဨ఍ጤဨ㸦2016-㸧࣭㧗ศᏊᏛ఍⌮஦㸦2019-2022㸧
࣭᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊௦㆟ဨ㸦2021-㸧୺せ࡞◊✲ᴗ⦼㸸୺せ࡞◊✲ᴗ⦼㸸(1) Wu, P.; Pietropaolo,A.; Fortino, M.; Bando, M.; Maeda, K.; Nishimura, T.; Shimoda,
S.; Sato, H.; Naga, N.; Nakano, T. Amplified Chirality Transfer
to Aromatic Molecules through Non ̺ specific Inclusion by
Amorphous,
HyperbranchedPoly(fluorenevinylene)
Derivatives. Angew. Chem. Int. Ed. 2023, 62 (29), e202305747.
DOI: 10.1002/anie.202305747. (2) Wu, P.; Pietropaolo, A.;
Fortino, M.; Shimoda, S.; Maeda, K.; Nishimura, T.; Bando, M.;
Naga, N.; Nakano, T. Non-uniform Self-folding of HelicalPoly(fluorenevinylene) Derivatives in the Solid State Leading to
Amplified Circular Dichroism and Circularly Polarized Light
Emission. Angew. Chem. Int. Ed. Engl. 2022, 61, e202210556.
(3) Wang, Q. Y.; Song, Z. Y.; Bando, M.; Harada, T.; Imai, Y.;
Toda, H.; Naga, N.; Nakano, T. Optically Active Poly(benzene1,4-diyl)s with Random and Alternating Copolymer Sequences
Composed of Chiral and Achiral, Bulky Monomeric Units: A
Systematic Study on Side-Chain Bulkiness Effects on GroundState and Excited-State Chiroptical Properties and Chiral
Recognition Ability. Macromolecules 2022, 55, 5390–5402. (4)Wang, Y.; Harada, T.; Phuong, L. Q.; Kanemitsu, Y.; Nakano, T.
Helix Induction to Polyfluorenes Using Circularly PolarizedLight: Chirality Amplification, Phase-Selective Induction, andAnisotropic Emission. Macromolecules 2018, 51, 6865-6877.
(5) Pietropaolo, A.; Nakano, T. Molecular Mechanism of
Polyacrylate Helix Sense Switching across Its Free Energy
Landscape. J. Am. Chem. Soc. 2013, 135, 5509−5512.
Ꮫ⾡㛵ಀࡢཷ㈹㸸ᖹᡂ20ᖺᗘ㧗ศᏊᏛ఍Ꮫ఍㈹㸦⛉Ꮫ㸧ࠕπ-ࢫࢱࢵࢡᆺ㧗ศᏊࡢྜᡂ㸪ᵓ㐀࠾ࡼࡧᶵ⬟ࠖ㸦2009/05/27㸧
࣭ᖹᡂ6ᖺᗘ㧗ศᏊᏛ఍࣏࣐࣮ࣜࢪ࣮ࣕࢼࣝ
ㄽᩥ㈹ࠕAsymmetric Polymerization of Triphenylmethyl
Methacrylate Using 9-Alkyl-9-fluorenyllithium-(-)-Sparteine
Complexes. Influence of Organolithium Structure on the
Propagation Stereochemistryࠖ㸦1995/05/28㸧

㛗㇂ᕝ῟ஓࡣࡏࡀࢃࡌࡹࢇࡸ
Jun-ya HASEGAWA


⫋ྡ㸸ᩍᤵ
╔௵㸸2012ᖺ10᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸ゐ፹⌮ㄽ◊✲㒊㛛/ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮/㓟ሷᇶゐ፹◊✲ࢡࣛࢫࢱ࣮/ᶵ⬟ᛶྜ㔠ゐ፹◊✲ࢡࣛࢫࢱ࣮◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05 217-C
㟁ヰ㸸011-706-9145࣭ࣇ
ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9145࣭㟁㟁Ꮚ࣓࣮ ࣝ 㸸 hasegawa@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
https://www.cat.hokudai.ac.jp/hasegawa/◊✲ศ㔝㸸ゐ፹⌮ㄽ/ィ⟬໬Ꮫ/㔞Ꮚ໬Ꮫ/◊✲ㄢ㢟㸸」㞧⣔࡟࠾ࡅࡿ㟁Ꮚᵓ㐀⌮ㄽ࡜ィ⟬ࣔࢹࣝࡢ㛤Ⓨ࣭ゐ፹⣔ࡢ཯ᛂ࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ⌮ㄽゎᯒ࣭⺮ⓑ㉁ࡸ
⁐ᾮ୰࡟࠾ࡅࡿ໬Ꮫ཯ᛂࡢ⌮ㄽゎᯒ◊✲࣮࣮࢟࣡ࢻ㸸ゐ፹⌮ㄽ/ゐ፹཯ᛂゎᯒ/࣐ࣝࢳࢫࢣ࣮ࣝ
ࣔࢹࣝ/㟁Ꮚ≧ែ⌮ㄽ/ບ㉳≧ែᏛṔ㸸1993ᖺ3᭶ி㒔኱ᏛᕤᏛ㒊ྜᡂ໬Ꮫ⛉༞ᴗ/1995ᖺ3᭶ி㒔኱ᏛᕤᏛ◊✲⛉ྜᡂ࣭⏕≀໬Ꮫᑓᨷಟኈㄢ⛬ಟ஢
/1998ᖺ3᭶ி㒔኱ᏛᕤᏛ◊✲⛉ྜᡂ࣭⏕≀໬Ꮫᑓᨷ༤ኈㄢ


ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬⛬ಟ஢Ꮫ఩㸸1995ᖺ3᭶ಟኈ㸦ᕤᏛ㸪ி㒔኱Ꮫ㸧/1998ᖺ3᭶༤ኈ㸦ᕤᏛ㸪ி㒔኱Ꮫ㸧
ࠕTheoretical Study on the Excited States andElectron Transfer Reactions in Photosynthetic Reaction Centerࠖ⫋Ṕ㸸1997ᖺ4᭶᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸦DC2㸧/1999
ᖺ4᭶ࣝࣥࢻ኱Ꮫ༤ኈ◊✲ဨ㸦⌮ㄽ໬Ꮫ⛉㸧/1999ᖺ11᭶ி㒔኱Ꮫຓᡭ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉ྜᡂ࣭⏕≀໬Ꮫᑓᨷྜᡂ໬
Ꮫㅮᗙ㔞Ꮚ≀⌮໬Ꮫศ㔝㸧/2007ᖺ4᭶ி㒔኱Ꮫຓᩍ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉ྜᡂ࣭⏕≀໬Ꮫᑓᨷྜᡂ໬Ꮫㅮᗙ㔞Ꮚ≀⌮໬Ꮫศ㔝㸧/2008ᖺ12᭶ி㒔኱Ꮫㅮᖌ㸦኱Ꮫ㝔ᕤᏛ◊✲⛉ྜᡂ࣭⏕≀໬Ꮫᑓᨷྜᡂ໬Ꮫㅮᗙ≀⌮᭷ᶵ໬Ꮫศ㔝㸧/2011ᖺ
10᭶ி㒔኱Ꮫ෸ᩍᤵ㸦ி㒔኱Ꮫ⚟஭ㅬ୍グᛕ◊✲ࢭࣥࢱ࣮⥲ྜ◊✲㒊㛛㸧/2012ᖺ4᭶⮬↛⛉Ꮫ◊✲ᶵᵓศᏊ⛉Ꮫ◊✲ᡤᐈဨ෸ᩍᤵ/2012ᖺ10᭶໭ᾏ㐨኱Ꮫᩍᤵ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ゐ፹ᇶ♏◊✲㒊ゐ፹⌮ㄽ໬Ꮫ◊✲㒊㛛㸧/2012ᖺ10᭶-2014ᖺ3᭶⮬↛⛉Ꮫ◊✲ᶵᵓศᏊ⛉Ꮫ◊✲ᡤᐈဨᩍ
ᤵ/2015ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸦ゐ፹⌮ㄽ◊✲㒊㛛㸧/2022ᖺ4᭶-2024ᖺ3᭶ྡྂᒇ኱Ꮫᐈဨᩍᤵ/2022
ᖺ4᭶⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮≉ᐃࣇ࢙࣮ࣟᅾእ◊✲Ṕ㸸1998ᖺ4᭶-1999ᖺ3᭶᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸦ࣝࣥࢻ኱Ꮫ㸧/1999ᖺ4᭶-10᭶ࣝࣥࢻ኱Ꮫ༤ኈ◊✲ဨᡤᒓᏛ఍㸸⌮ㄽ໬Ꮫ఍/ゐ፹Ꮫ఍/ศᏊ⛉Ꮫ఍/᪥ᮏ໬Ꮫ఍/⡿ᅜ໬Ꮫ఍Ꮫ఍άື㸸᪥ᮏ໬Ꮫ఍㏆␥ᨭ㒊ࠕ໬Ꮫ࡬ࡢᣍᚅࠖጤဨ఍ጤ
ဨ㸦2008-2009㸧࣭㔞Ꮚ໬Ꮫ◊✲༠఍⌮஦㸦2007-㸧࣭ḟୡ௦ࢫࣃࢥࣥᡓ␎ᶵ㛵ࣉࣟࢢ࣒ࣛࠕィ⟬≀㉁⛉Ꮫ࢖ࢽࢩ࢔ࢳ
ࣈࠖᡓ␎ㄢ㢟ᑠጤဨ఍ጤဨ㸦2011-2015㸧࣭Chemistry Letterㄅ⦅㞟ጤဨ㸦2013-㸧࣭ゐ፹Ꮫ఍௻⏬ᩍ⫱ጤဨ㸦2014-2015㸧࣭ゐ፹Ꮫ఍௦㆟ဨ㸦2016-㸧
୺せ࡞◊✲ᴗ⦼㸸(1) Oshiro, K.; Gao, M.; Han, L.; Zhang, D.;
Hasegawa, J. Theoretical investigation of the alkali metal
poisoning tolerance mechanism of CeO2 containing Fe andH2SO4 additives. J. Phys. Chem. C 2023, 127, 18914–18925. (2)Ohmura, S.; Katagiri, K.; Kato, H.; Horibe, T.; Miyakawa, S.;
Hasegawa, J.; Ishihara, K. Highly Enantioselective Radical
Cation [2+2] and [4+2] Cycloadditions by Chiral Iron(III)Photoredox Catalysis. J. Am. Chem. Soc. 2023, 145, 1505415060. (3) Shiraogawa, T.; Hasegawa, J. Optimization ofGeneral Molecular Properties in the Equilibrium Geometry
Using Quantum Alchemy: An Inverse Molecular Design
Approach. J. Phys. Chem. A 2023, 127, 4345-4353. (4) Chiba,
T.; Iida, K.; Furukawa, S.; Hasegawa, J. First-Principles Studyon Unidirectional Proton Transfer on Anatase TiO2 (101) Surface
Induced by External Electric Fields. Phys. Chem. Chem. Phys.
2023, 25, 9454-9460. (5) Zhao, X.; Ratanasak, M.; Kon, K.;
Hasegawa, J.; Ishihara, K. Bulky magnesium(II) and sodium(I)bisphenoxide catalysts for chemoselective transesterification of
methyl (meth)acrylates. Chem. Sci. 2023, 14, 566-572.
Ꮫ⾡㛵ಀࡢཷ㈹㸸Asian Rising Star Award, The 15-th Asian
Chemical Congress 㸦 2013/8/20 㸧࣭ Centre de Mecanique
Ondulatoire Appliquee QSCP Promising Scientist Award
㸦2011/9/14㸧
࣭ᖹᡂ21ᖺᗘศᏊ⛉Ꮫ఍ዡບ㈹࣭
ࠕග⏕≀Ꮫࢩ
ࢫࢸ࣒ࡢບ㉳≧ែ࡜ᶵ⬟㸸㧗⢭ᗘ㟁Ꮚ⌮ㄽࡢ㛤Ⓨࢆᇶ┙࡜ࡍࡿ⌮ㄽⓗ◊✲ࠖ
㸦2009/09/22㸧

ᖺሗ ࣭ಶே⦅‫ە‬ᆏᮾṇెࡤࢇ࡝࠺ࡲࡉࡼࡋ
Masayoshi BANDO


⫋ྡ㸸ຓᩍ
╔௵㸸2020ᖺ4᭶1᪥㒊㛛㸸㧗ศᏊᶵ⬟⛉Ꮫ◊✲㒊㛛ᢸᙜ኱Ꮫ㝔ʤָ෨ʥ㸸⌮Ꮫ㒊◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05-310㟁ヰ㸸011-706-9157࣭ࣇ
ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9156࣭㟁㟁Ꮚ࣓࣮ࣝ㸸masayoshi.bando@cat.hokudai.ac.jp◊✲ศ㔝㸸᭷ᶵ㔠ᒓ໬Ꮫ/㧗ศᏊ໬Ꮫ◊✲࣮࣮࢟࣡ࢻ㸸୙ᩧ/࢟ࣛࣝ/ࡽࡏࢇᏛṔ㸸໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⏕࿨⛉Ꮫ㝔Ꮫ఩㸸༤ኈ㸦⸆⛉Ꮫ㸧⫋Ṕ㸸2020ᖺ 4᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤຓᩍᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍, 㧗ศᏊᏛ఍୺ せ ࡞ ◊ ✲ ᴗ ⦼ 㸸 (1) Bando, M.; Zhu, W.; Shimoda, S.;
Hamanishi, E.; Sano, N.; Trombini, C.; Naga, N.; Haraguchi, N.;
Itsuno, S.; Nishida, M.; Nakano, T. Amorphous Porous
Polyurethanes as Macromolecular Ligands for Palladium
Catalysts. Chem. Lett. 2023, 52, 5–9. (2) Wang, Q.; Song, Z.;
Bando, M.; Harada, T.; Imai, Y.; Toda, H.; Naga, N.; Nakano, T.
Macromolecules 2022, 55, 5390-5402. (3) Elbayoumy, E.;
Wang, Y.; Rahman, J.; Trombini, C.; Bando, M.; Song, Z.; Diab,
M. A.; Mohamed, F. S.; Naga, N.; Nakano, T. Pd NanoparticlesLoaded Vinyl Polymer Gels: Preparation, Structure andCatalysis. Catalysts 2021, 11, 137. (4) Wang, Y.; Zavradashvili,
N.; Wang, Y.; Pietropaolo, A.; Song, Z.; Bando, M.; Katsarava,
R.; Nakano, T. Optically Active Polymers with Cationic Units
Connected through Neutral Spacers: Helical Conformation andChirality Transfer to External Molecules. Macromolecules 2020,
53, 9916-9928. (5) Bando, M.; Nakajima, K.; Song, Z.;
Takahashi, T. Coming Back to the Starting Position of Carbons
Traveling in Organic Molecules on Titanium: Merry-Go-Round
Reaction. Organometallcs 2019, 38, 731-734.

75



⚟ᒸ῟
ࡩࡃ࠾࠿࠶ࡘࡋ
Atsushi FUKUOKA


⫋ྡ㸸ᩍᤵ
╔௵㸸2007ᖺ4᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸≀㉁ኚ᥮◊✲㒊㛛/ゐ፹◊✲ᇶ┙㛤Ⓨࢡࣛࢫࢱ࣮◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ04 310-2
㟁ヰ㸸011-706-9140࣭ࣇࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9139࣭㟁㟁Ꮚ࣓࣮ ࣝ 㸸 fukuoka@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
http://www.cat.hokudai.ac.jp/fukuoka/◊✲ศ㔝㸸ゐ፹࣭㈨※໬Ꮫࣉࣟࢭࢫ/ᶵ⬟≀㉁໬Ꮫ/ࢢ࣮࣭ࣜࣥ⎔ቃ໬Ꮫ
◊✲ㄢ㢟㸸ゐ፹ἲࣂ࢖࣐࢜ࢫኚ᥮࣭㩭ᗘಖᣢࡢࡓࡵࡢゐ፹◊✲࣮࣮࢟࣡ࢻ㸸ゐ፹/ࣂ࢖࣐࢜ࢫ/ࢭ࣮ࣝࣟࢫ/ࢼࣀ⢏Ꮚ/࢚ࢳࣞࣥ㓟໬/㩭ᗘಖᣢᏛṔ㸸1982ᖺ3᭶ᮾி኱ᏛᕤᏛ㒊ྜᡂ໬Ꮫ⛉༞ᴗ/1984ᖺ3᭶ᮾி኱ᏛᕤᏛ⣔◊✲⛉ᕤᴗ໬Ꮫᑓᨷಟኈㄢ⛬ಟ஢/1985
ᖺ12᭶ྠ༤ኈㄢ⛬୰㏥
Ꮫ఩㸸1984ᖺ3᭶ᕤᏛಟኈ㸦ᮾி኱Ꮫ㸧/1989ᖺ12᭶ᕤᏛ༤ኈ㸦ᮾி኱Ꮫ㸧
ࠕA Study on Homogeneous and Heterogeneous
Bimetallic Cluster Catalystsࠖ
⫋Ṕ㸸1986ᖺ1᭶໭ᾏ㐨኱Ꮫຓᡭ㸦ゐ፹◊✲ᡤ㸧/1991ᖺ4᭶ᮾி㎰ᕤ኱Ꮫㅮᖌ㸦ᕤᏛ㒊㸧/1995ᖺ8᭶ྠຓᩍᤵ/1997ᖺ4᭶໭ᾏ㐨኱Ꮫຓᩍᤵ㸦ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮㸧/2007ᖺ4᭶
ྠᩍᤵ/2010ᖺ4᭶ྠࢭࣥࢱ࣮㛗/2014ᖺ4᭶໭ᾏ㐨኱Ꮫ⥲㛗
⿵బ/2015ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᩍᤵ㸦≀㉁ኚ
᥮◊✲㒊㛛㸧
ᅾእ◊✲Ṕ㸸1988ᖺ11-12᭶ࣀ࣮ࢫ࢙࢘ࢫࢱࣥ኱Ꮫ/2003ᖺ
7-8᭶࢜ࣞࢦࣥᕞ❧኱Ꮫ/2003ᖺ8-10᭶ࢽ࣮࣓ࣗ࢟ࢩࢥ኱Ꮫ
ᡤᒓᏛ఍㸸᪥ᮏ໬Ꮫ఍/ゐ፹Ꮫ఍/ࢮ࢜ࣛ࢖ࢺᏛ఍/▼ἜᏛ఍/࢔࣓ࣜ࢝໬Ꮫ఍
Ꮫ఍άື㸸ࢮ࢜ࣛ࢖ࢺᏛ఍⌮஦㸦2004-2005㸧
࣭ࢮ࢜ࣛ࢖ࢺ
Ꮫ఍ZMPC2009⤌⧊ጤဨ㸦2007-2009㸧࣭ゐ፹Ꮫ఍TOCAT6/APCAT5⤌⧊ጤဨ㸦2008-2011㸧
࣭ゐ፹Ꮫ఍ࣂ࢖࣐࢜ࢫኚ᥮
ゐ፹◊✲఍ୡヰே௦⾲㸦2008-2012㸧࣭ゐ፹Ꮫ఍TOCAT7⤌
⧊ጤဨ㸦2011-2014㸧
࣭ゐ፹Ꮫ఍⌮஦㸦2012-2014㸧࣭➨16ᅇᆒ୍⣔୙ᆒ୍⣔ゐ፹ᅜ㝿఍㆟⤌⧊ጤဨ㛗㸦2012-2013㸧࣭ᅜ㝿ゐ፹Ꮫ఍ホ㆟ဨ㸦2012-2016㸧࣭ᅜ㝿ゐ፹Ꮫ఍࢜ࣇ࢕ࢧ࣮
㸦2016-㸧࣭ゐ፹Ꮫ఍఍㛗㸦2018-2019㸧࣭᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊㛗㸦2019-2020㸧࣭᪥ᮏ໬Ꮫ఍⌮஦㸦2020-2023㸧
࣭ࣇ࣮ࢻࣟࢫ๐ῶࢥࣥࢯ࣮ࢩ࢔࣒௦⾲㸦2020-㸧୺せ࡞◊✲ᴗ⦼㸸(1) Dostagir, N. H. MD; Tomuschat, C. R.;
Oshiro, K.; Gao, M.; Hasegawa, J.; Fukuoka, A.; Shrotri. A.
Mitigating the Poisoning Effect of Formate during CO2
Hydrogenation to Methanol over Co-Containing Dual-Atom
Oxide Catalysts. JACS Au 2024, 4, 1048-1058. (2) Kobayashi,
H.; Suzuki, Y.; Sagawa, T.; Saito, M.; Fukuoka, A. Selective
Synthesis of Oligosaccharides by Mechanochemical Hydrolysis
of Chitin over a Carbon-Based Catalyst. Angew. Chem. Int. Ed.
2023, 62, e202214229. (3) Jiang, C.; Hara, K.; Fukuoka, A. LowTemperature Oxidation of Ethylene over Platinum Nanoparticles
Supported on Mesoporous Silica. Angew. Chem. Int. Ed. 2013,
52, 6265-6268. (4) Kobayashi, H.; Yabushita, M.; Komanoya, T.;
Hara, K.; Fujita, I.; Fukuoka, A. High-Yielding One-Pot
Synthesis of Glucose from Cellulose Using Simple ActivatedCarbons and Trace Hydrochloric Acid. ACS Catal. 2013, 3, 581-

76

587. (5) Fukuoka, A.; Dhepe, P. L. Catalytic Conversion of
Cellulose into Sugar Alcohols. Angew. Chem. Int. Ed. 2006, 45,
5161-5163.
Ꮫ⾡㛵ಀࡢཷ㈹㸸ゐ፹Ꮫ఍ዡບ㈹ࠕ␗✀㔠ᒓࢡࣛࢫࢱ࣮ᢸᣢゐ፹ࡢᵓ㐀࡜཯ᛂ≉ᛶ࡟㛵ࡍࡿ◊✲ࠖ㸦1994/04/02㸧࣭ᒣୗኴ㑻㢧ᙲ⫱ᡂ఍Ꮫ⾡◊✲ዡບ㈹ࠕ㔠ᒓࢡࣛࢫࢱ࣮ࡢゐ፹స⏝࡟㛵ࡍࡿ◊✲ࠖ㸦1995/05/26㸧࣭ྎ‴ᅜᐙ⛉Ꮫጤဨ఍໬
Ꮫ◊✲᥎ື୰ᚰࣞࢡࢳ࣮ࣕࢩࢵࣉ㸦2008/11/20㸧࣭໭ᾏ㐨኱Ꮫ◊✲⥲㛗㈹ඃ⚽㈹㸦2015/03/11㸧
࣭ゐ፹Ꮫ఍Ꮫ఍㈹㸦Ꮫ⾡㒊 㛛 㸧ࠕ ᅛ య ゐ ፹ ࡟ ࡼ ࡿ ࢭ ࣝ ࣟ ࣮ ࢫ ศ ゎ ࡢ ◊ ✲ ࠖ㸦2015/03/23㸧
࣭ࢢ࣮࣭ࣜࣥࢧࢫࢸ࢕ࢼࣈ࣭ࣝࢣ࣑ࢫࢺ࣮ࣜ
㸦GSC㸧㈹࣭ᩥ㒊⛉Ꮫ኱⮧㈹ࠕᅛయゐ፹࡟ࡼࡿࢭ࣮ࣝࣟࢫ
⣔ࣂ࢖࣐࢜ࢫศゎࡢඛᑟⓗ◊✲ࠖ㸦2015/07/07㸧࣭໭ᾏ㐨኱Ꮫ◊✲⥲㛗㈹ඃ⚽㈹㸦2017/01/31㸧
࣭஭ୖ᫓ᡂ㈹ࠕ㟷ᯝ≀㩭ᗘಖᣢ⏝ࣉࣛࢳࢼゐ፹ࡢ㛤Ⓨࠖ㸦2020/09/16㸧
࣭➨ 75 ᅇ᪥ᮏ໬Ꮫ఍㈹ࠕࢭ࣮ࣝࣟࢫ⣔ࣂ࢖࣐࢜ࢫࡢゎ㔜ྜ࡜㟷ᯝ≀㩭ᗘಖᣢࡢࡓࡵࡢᅛయゐ፹ࡢ㛤Ⓨࠖ㸦2023/03/23㸧

ྂᕝ᳃ஓࡩࡿ࠿ࢃࡋࢇࡸ
Shinya FURUKAWA⫋ྡ㸸෸ᩍᤵ
╔௵㸸2016ᖺ7᭶15᪥
㏥௵㸸2023ᖺ4᭶30᪥㒊㛛ࢡࣛࢫࢱ࣮㸸ゐ፹ᮦᩱ◊✲㒊㛛/ᶵ⬟ᛶྜ㔠ゐ፹◊✲ࢡࣛࢫࢱ࣮ᢸᙜ኱Ꮫ㝔㸦Ꮫ㒊㸧㸸⥲ྜ໬Ꮫ㝔◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ04-311-1
㟁ヰ㸸011-706-9162࣭ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9163࣭㟁Ꮚ࣓࣮ ࣝ 㸸 furukawa@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
http://www.cat.hokudai.ac.jp/shimizu/member_3.html
◊✲ศ㔝㸸ゐ፹࣭㈨※໬Ꮫࣉࣟࢭࢫ/≀⌮໬Ꮫ/ィ⟬໬Ꮫ◊✲࣮࣮࢟࣡ࢻ㸸ྜ㔠ゐ፹/㔠ᒓ㛫໬ྜ≀/Ỉ⣲໬⬺Ỉ⣲ᏛṔ㸸2007ᖺ3᭶ ி㒔኱ᏛᕤᏛ㒊ᕤᴗ໬Ꮫ⛉༞ᴗ/2009ᖺ3᭶ ி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉ಟኈㄢ⛬ಟ஢/2012ᖺ3᭶ி㒔኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉༤ኈㄢ⛬ಟ஢Ꮫ఩㸸2012ᖺ3᭶ ༤ኈ㸦ᕤᏛ㸧㸦ி㒔኱Ꮫ㸧
⫋Ṕ㸸2009ᖺ4᭶ ᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ㸦DC1㸧/ 2012
ᖺ4᭶ ᮾிᕤᴗ኱Ꮫ⌮Ꮫ㝔໬Ꮫ⣔ ຓᩍ / 2016ᖺ7᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ෸ᩍᤵ㸦ゐ፹ᮦᩱ◊✲㒊㛛㸧/ 2019
ᖺ8᭶ ᩥ㒊⛉Ꮫ┬◊✲᣺⯆ᒁ Ꮫ⾡ㄪᰝᐁ㸦ව௵㸧/ 2019
ᖺ10᭶ ⛉Ꮫᢏ⾡᣺⯆ᶵᵓࡉࡁࡀࡅ◊✲⪅㸦ව௵㸧 ᡤᒓᏛ఍㸸ゐ፹Ꮫ఍/▼ἜᏛ఍/㔠ᒓᏛ఍/᪥ᮏ໬Ꮫ఍/Ꮫ఍άື㸸ゐ፹Ꮫ఍ᮾ᪥ᮏᨭ㒊ᖿ஦㸦2013-15㸧࣭▼ἜᏛ఍ࢪࣗࢽ࢔ࢯࢧ࢖࢔ࢸ࢕࣮ᖿ஦㸦2013-㸧࣭ゐ፹Ꮫ఍௻⏬ᩍ⫱ጤဨ㸦2014-2016㸧
࣭ゐ፹Ꮫ఍ⱝᡭ఍ጤဨ㛗㸦2014-2016㸧࣭ゐ፹Ꮫ఍ᗈሗጤဨ㸦2015-2016㸧
࣭ゐ፹Ꮫ఍ᮾ᪥ᮏᨭ㒊௦㆟
ဨ㸦2015-2017㸧
࣭ゐ፹Ꮫ఍࢟ࣕࢱࣜࢩࢫࢫࢡ࣮ࣝ㐠Ⴀጤဨ
㸦2016㸧࣭ゐ፹Ꮫ఍໭᪥ᮏᨭ㒊ᖿ஦㸦2017-㸧࣭ゐ፹Ꮫ఍ウㄽ఍ጤဨ㸦2018-2020㸧
࣭ゐ፹Ꮫ఍⦅㞟ጤဨ㸦2022-㸧࣭᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊ᖿ஦㸦2018-㸧
୺せ࡞◊✲ᴗ⦼㸸(1) Xing, F.; Nakaya, Y.; Yasumura, S.;
Shimizu, K.; Furukawa, S. Ternary platinum–cobalt–indium
nanoalloy on ceria as a highly efficient catalyst for the oxidative
dehydrogenation of propane using CO2. Nat. Catal. 2022, 5, 5565. (2) Xing, F.; Ma, J.; Shimizu, K.; Furukawa, S. High-entropyᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬intermetallics on ceria as efficient catalysts for the oxidative
dehydrogenation of propane using CO2. Nat. Commun. 2022, 13,5065. (3) Nakaya, Y.; Hayashida, E.; Asakura, H.; Takakusagi,S.; Yasumura, S.; Shimizu, K.; Furukawa, S. High-Entropy
Intermetallics Serve Ultrastable Single-Atom Pt for Propane
Dehydrogenation. J. Am. Chem. Soc. 2022, 144, 15944-15953.
(4) Nakaya, Y.; Xing, F.; Ham, H.; Shimizu, K.; Furukawa S.
Doubly Decorated Platinum–Gallium Intermetallics as Stable
Catalysts for Propane Dehydrogenation. Angew. Chem. Int. Ed.
2021, 60, 19715-19719. (5) Nakaya, Y.; Hirayama, J.; Yamazoe,
S.; Shimizu, K.; Furukawa, S. Single-atom Pt in intermetallics
as an ultrastable and selective catalyst for propane
dehydrogenation. Nat. Commun. 2020, 11, 2838.
࣭ゐ፹Ꮫ఍ዡ
Ꮫ⾡㛵ಀࡢཷ㈹㸸㔠ᒓᏛ఍ዡບ㈹㸦2016/09㸧
ບ㈹ࠕⓑ㔠᪘ඖ⣲ࢆ୺ᡂศ࡜ࡍࡿ㔠ᒓ㛫໬ྜ≀ゐ፹ࡢ๰〇࡜ᒎ㛤ࠖ㸦2017/03㸧࣭▼ἜᏛ఍ዡບ㈹ࠕྜ㔠ᮦᩱࢆᇶ┙࡜ࡋࡓ㧗ຠ⋡NOx㑏ඖ࠾ࡼࡧ࢔ࣝ࢝ࣥ⬺Ỉ⣲ゐ፹ࡢ㛤Ⓨࠖ㸦2021/03㸧࣭ᩥ㒊⛉Ꮫ኱⮧⾲ᙲⱝᡭ⛉Ꮫ⪅㈹ࠕྜ㔠཯ᛂሙタィ࡟ᇶ࡙ࡃ㧗ຠ⋡ゐ፹⣔ࡢ㛤Ⓨ࡟㛵ࡍࡿ◊✲ࠖ
㸦2021/04㸧ᐑᓮ⋹ࡳࡸࡊࡁࢀ࠸
Ray MIYAZAKI
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⫋ྡ㸸ຓᩍ
╔௵㸸2023ᖺ6᭶1᪥㒊㛛ࢡࣛࢫࢱ࣮㸸ゐ፹⌮ㄽ◊✲㒊㛛◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ05 217-C
㟁ヰ㸸011-706-9145࣭ࣇ
ࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9145࣭㟁㟁Ꮚ࣓࣮ ࣝ 㸸 ray_miyazaki@cat.hokudai.ac.jp ࣭ ࢘ ࢙ ࣈ ࣌ ࣮ ࢪ 㸸
https://www.cat.hokudai.ac.jp/hasegawa/◊✲ศ㔝㸸⌮ㄽ໬Ꮫ/ゐ፹໬Ꮫ◊✲ㄢ㢟㸸⌮ㄽィ⟬࣭AI࡟ࡼࡿゐ፹཯ᛂ࣓࢝ࢽࢬ࣒ࡢゎᯒ◊✲࣮࣮࢟࣡ࢻ㸸ゐ፹⌮ㄽ໬Ꮫ/AIᏛṔ㸸2015ᖺ3᭶໭ᾏ㐨኱Ꮫ⌮Ꮫ㒊໬Ꮫ⛉༞ᴗ/2017ᖺ3᭶໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ಟኈㄢ⛬ಟ஢/2020ᖺ3᭶໭ᾏ㐨኱Ꮫ኱Ꮫ㝔⥲ྜ໬Ꮫ㝔༤ኈᚋᮇㄢ⛬ಟ஢Ꮫ఩㸸2017ᖺ3᭶ಟኈ㸦⌮Ꮫ㸪໭ᾏ㐨኱Ꮫ㸧/2020ᖺ3᭶༤ኈ㸦⌮Ꮫ㸪໭ᾏ㐨኱Ꮫ㸧⫋Ṕ㸸2020ᖺ4᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ༤ኈ◊✲ဨ
/2021ᖺ3᭶Fritz Haber Institute of the Max Planck Society ༤ኈ◊✲ဨ/2023ᖺ6᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤຓᩍᅾእ◊✲Ṕ㸸2017ᖺ7᭶-9᭶Fritz Haber Institute of the Max
Planck Society ゼၥ኱Ꮫ㝔⏕, 2021ᖺ3᭶-2023ᖺ6᭶Fritz
Haber Institute of the Max Planck Society ༤ኈ◊✲ဨᡤᒓᏛ఍㸸⌮ㄽ໬Ꮫ఍/ゐ፹Ꮫ఍/᪥ᮏ໬Ꮫ఍/ࢻ࢖ࢶ≀⌮Ꮫ఍Ꮫ఍άື㸸ゐ፹Ꮫ఍ⱝᡭ఍ጤဨ㸦2023-㸧୺せ࡞◊✲ᴗ⦼㸸(1) Miyazaki, R.; Belthle, K. S.; Tüysüz, H.;
Foppa, L.; Scheffler, M. Materials Genes of CO2 Hydrogenation
on Supported Cobalt Catalysts: an AI Approach Integrating
Theoretical and Experimental Data. J. Am. Chem. Soc. 2024,
146, 5433-5444. (2) Miyazaki, R.; Iida, K.; Ohno, S.; Matsuzaki,T.; Suzuki, T.; Arisawa, M.; Hasegawa, J. Substrate-Assisted
Reductive Elimination Determining the Catalytic Cycle: A
Theoretical Study on the Ni-Catalyzed 2,3-Disubstituted
Benzofuran Synthesis via C–O Bond Activation.
Organometallics 2022, 41, 3581-3588. (3) Miyazaki, R.; Jin, X.;ᖺሗ ࣭ಶே⦅‫ە‬

Yoshii, D.; Yatabe, T.; Yabe, T.; Mizuno, N.; Yamaguchi, K.;
Hasegawa, J. Mechanistic study of C‒H bond activation by O2
on negatively charged Au clusters: α,β-dehydrogenation of 1methyl-4-piperidone by supported Au catalysts. Catal. Sci.
Technol. 2021, 11, 3333-3346. (4) Miyazaki, R.; Nakatani, N.;
Levchenko, S. V.; Yokoya, T.; Nakajima, K.; Hara, K.; Fukuoka,A.; Hasegawa, J. DFT Mechanistic Study on the Complete
Oxidation of Ethylene by the Silica-Supported Pt Catalyst: C═C
Activation via the Ethylene Dioxide Intermediate. J. Phys.
Chem. C 2019, 123, 12706-12715. (5) Maeda, C.; Shimonishi,J.; Miyazaki, R.; Haseagwa, J.; Ema, T. Highly Active andRobust Metalloporphyrin Catalysts for the Synthesis of Cyclic
Carbonates from a Broad Range of Epoxides and Carbon
Dioxide. Chem. Eur. J. 2016, 22, 6556-6563.
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㩃㑥
ࢁ࡯࠺
Bang LU⫋ྡ㸸ຓᩍ╔௵㸸2023ᖺ11᭶1᪥
㒊㛛/ࢡࣛࢫࢱ࣮㸸ゐ፹ᵓ㐀◊✲㒊㛛◊✲ᐊ㸸๰ᡂ⛉Ꮫ◊✲Ჷ02 112
㟁ヰ㸸011-706-9115࣭ࣇࣇ࢓ࢡࢩ࣑ࣜ㸸011-706-9115࣭㟁㟁Ꮚ࣓࣮ࣝ㸸lub@cat.hokudai.ac.jp◊✲ศ㔝㸸ࢼࣀᵓ㐀⛉Ꮫ/㔞Ꮚࣅ࣮࣒/཯ᛂ㏿ᗘㄽ࡜ゐ፹/≀⌮໬Ꮫ/⾲㠃⛉Ꮫ◊✲࣮࣮࢟࣡ࢻ㸸XAFSศගᏛ/ࣉࣛࢬ࣐ゐ፹཯ᛂ/༢ཎᏊゐ፹ᏛṔ㸸2020ᖺ9᭶໭ᾏ㐨኱Ꮫ㔞Ꮚ⌮ᕤᑓᨷಟኈㄢ⛬ಟ஢
/2023ᖺ9᭶໭ᾏ㐨኱Ꮫ㔞Ꮚ⌮ᕤᑓᨷ༤ኈㄢ⛬ಟ஢Ꮫ఩㸸2020ᖺ9᭶ಟኈ㸦ᕤᏛ㸧㸦໭ᾏ㐨኱Ꮫ㸧/2023ᖺ9᭶༤ኈ㸦ᕤᏛ㸧㸦໭ᾏ㐨኱Ꮫ㸧ࠕin situ/operando ⾲㠃⛉Ꮫᡭἲ࡟ࡼࡿ୙ᆒ୍ゐ፹ᵓ㐀άᛶ┦㛵ࡢゎ᫂ࠖ⫋Ṕ㸸2023ᖺ10᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ༤ኈ◊✲ဨ
/2023ᖺ11᭶໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤຓᩍ㸦ゐ፹ᵓ㐀◊✲㒊㛛㸧ᡤᒓᏛ఍㸸ゐ፹Ꮫ఍/᪥ᮏ໬Ꮫ఍/᪥ᮏ⾲㠃┿✵Ꮫ఍/᪥ᮏᨺᑕගᏛ఍୺せ࡞◊✲ᴗ⦼㸸(1) Lu, B.; Kido, D.; Sato, Y.; Xu, H.; Chun,
W. J.; Asakura, K.; Takakusagi, S. Development of Operando
Polarization-Dependent Total Reflection Fluorescence X‑ray
Absorption Fine Structure Technique for Three-Dimensional
Structure Determination of Active Metal Species on a Model
Catalyst Surface under Working Conditions. J. Phys. Chem. C
2021, 125, 12424-12432. (2) Dong, K.; Hu, B.; Al Rashid, M.H.;
Lu, B.; Miyabayashi, K.; Higashi, K.; Uruga, T.; Iwasawa, Y.;
Kido, D.; Takakusagi, S.; Asakura, K. In situ Study on Structureof a Diluted Pt/HOPG Model Catalyst System Prepared by theTwo-phase Liquid Reduction Method Using a Novel
BCLA/HERFD+BI-XAFS Method. e-Journal of Surface
Science and Nanotechnology. 2024, Accepted. (3) Kim, C.R.;
Maeda, H.; Lu, B.; Nakamura, Y.; Lin, Y.; Wakisaka, Y.; Kido,
D.; Asakura, K.; Takakusagi, S. Can amine ligands atomicallydisperse Cu atoms on TiO2(110)? Cu deposition on TiO2(110)premodified with o-anthranilic acid. Chem. Lett. 2024, 53,
upad045. (4) Liu, C.; Lu, B.; Ariga-Miwa, H.; Ogura, S.; Ozawa,
T.; Fukutani, K.; Gao, M.; Hasegawa, J.Y.; Shimizu, K.I.;
Asakura, K.; Takakusagi, S. Dynamic Behavior of Intermediate
Adsorbates to Control Activity and Product Selectivity in

77Heterogeneous Catalysis: Methanol Decomposition on
Pt/TiO2(110). J. Am. Chem. Soc. 2023, 145, 19953-19960. (5)Kim, D.Y.; Ham, H.; Chen, X.; Liu, S.; Xu, H.; Lu, B.;
Furukawa, S.; Kim, H.H.; Takakusagi, S.; Sasaki, K.; Nozaki, T.
Cooperative catalysis of vibrationally excited CO2 and alloy
catalyst breaks the thermodynamic equilibrium limitation. J. Am.

78

Chem. Soc. 2022 144, 14140-14149.
Ꮫ ⾡㛵ಀࡢཷ㈹㸸IVC22 IUVSTA-Elsevier Student Award
ࠕElucidating the relationship between 3D structure and CO
oxidation activity of Pt clusters on α-Al2O3(0001) using
operando PTRF-XAFSࠖ (2022/9/15)

ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬‫ڦ‬Ꮫኈㄢ⛬࣭⌮Ꮫ㒊ᩍ⫋ဨࡢ≉チࠓ≉チ␒ྕ࣭Ⓨ᫂⪅ࠕⓎ᫂ࡢྡ⛠ࠖ≉チᶒ⪅㸦Ⓩ㘓᪥㸧ࠔ‫ڦ‬2023ᖺᗘ࡟Ⓩ㘓ࡉࢀࡓ≉チ‫ڦ‬Ꮫኈㄢ⛬࣭⸆Ꮫ㒊‫ڦ‬2023ᖺᗘࡢཷ㈹
୍ ⯡♫ᅋἲே +3&,ࢥࣥࢯ࣮ࢩ࢔࣒ᖺᗘ+3&,ࢯࣇࢺ
࢘ ࢙ ࢔ ㈹ 㛤 Ⓨ 㒊 㛛 ㈹ ዡ ບ ㈹  㣤 ⏣ ೺ ஧ ࠕ SALMON㸦 Scalable Ab-initio Light-Matter simulator for Optics andNanoscience㸧ࠖ≀㉁࣭ࢹࣂ࢖ࢫ㡿ᇦඹྠ◊✲ᣐⅬ➨ᅇ≀㉁࣭ࢹࣂ࢖ࢫඹ
ྠ◊✲㈹୰ᓥΎ㝯ࠕࢽ࢜ࣈ⣔」ྜ㓟໬≀࡟ࡼࡿ⢾ኚ᥮཯ᛂࠖ㸦2023/06/29㸧
BITS Pilani 2023 Young Achiever Alumnus Award (National
Institute of Technology, Raipur, India)Abhijit Shrotri
ࠕHeterogeneous Catalysis on Carbon Dioxide Conversionࠖ㸦2023/11/30㸧᪥ᮏ໬Ꮫ఍➨ᅇᏛ⾡㈹ΎỈ◊୍ࠕ཯ᛂᶵᵓゎᯒ࠾ࡼࡧᶵᲔᏛ⩦ࢆά⏝ࡋࡓ୙ᆒ୍⣔ゐ፹ࡢ㛤Ⓨࠖ㸦2023/12/21㸧

2023ᖺᗘᢸᙜㅮ⩏‫ڦ‬Ꮫኈㄢ⛬࣭ᕤᏛ㒊ᛂ⏝໬ᏛᏛ⏕ᐇ㦂,,㹙1㹛㸦ᵽཱྀᖿ㞝㸧㸦㫟ῲ཭἞㸧㸦㛗὾ኴ㑻㸧㫽ᒇᑿ㝯㸦ᶓ಴⪷ஓ 㸧㸦୕ᾆ❶㸧≀㉁ኚ᥮ᕤᏛ㹙2㹛㸦బ⸨ಙ୍㑻㸧㸦▼ᒣ❳⏕㸧㸦అぢබᚿ㸧㸦ᯇᮏㅬ୍㑻㸧㸦ᑠ➟ཎὈᚿ㸧㸦☾㔝ᣅஓ㸧㸦໭ᕝ⿱୍㸧㸦ᶓ಴⪷ஓ㸧㸦ᓥ⏣ᩄᏹ㸧ΎỈ◊୍㸦୕ᾆ❶㸧㸦኱⇃Ẏ㸧㸦ྥ஭⤀㸧⾲㠃ᕤᏛ㹙2㹛ᮅ಴Ύ㧘⾲㠃ᕤᏛ㹙2㹛ᮅ಴Ύ㧘㔞ᏊຊᏛ㹙2㹛㸦ᯇᾆጁᏊ 㸧ᮅ಴Ύ㧘㔞ᏊຊᏛ㹙2㹛㸦ᯇᾆጁᏊ 㸧ᮅ಴Ύ㧘

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ゐ፹໬Ꮫ㹙2㹛⚟ᒸ῟ ୰㔝⎔㛗㇂ᕝ῟ஓᢸᙜᩍဨ࡛ࠕ ࠖࡣ㈐௵ᩍဨ㸪㸦㸧ࡣゐ፹⛉Ꮫ◊✲ᡤ௨እࡢᡤᒓᩍဨࢆ࠶ࡽࢃࡍ㸬㹙㹛ෆࡣ༢఩ᩘ㸬‫ڦ‬Ꮫኈㄢ⛬࣭඲Ꮫᩍ⫱୍⯡ᩍ⫱₇⩦㸦ࣇࣞࢵࢩ࣐ࣗࣥࢭ࣑ࢼ࣮㸧ࠕ㔞Ꮚࣅ࣮࣒࡜
ࣉࣛࢬ࣐ᛂ⏝ࡢୡ⏺ࠖ㹙2㹛㸦ཬᕝಇ୍㸧㸦ᖹ㈡ᐩኈኵ㸧㸦ᐩᒸᬛ㸧㸦ຍ⨾ᒣ㝯㸧㸦ᒣෆ᭷஧ 㸧㸦㔠Ꮚ⣧୍㸧㸦ಙኴ♸஧㸧㸦బ⸨༤㝯㸧㸦኱἟ṇே㸧㸦ᯇᾆጁᏊ㸧㸦ⓑ஭┤ᶵ㸧㸦ᰘᒣ⎔ᶞ㸧ᮅ಴Ύ㧘㸦ᐩ⏣೺ኴ㑻㸧⎔ቃ࡜ே㛫ࠕゐ፹໬Ꮫࡢࣇࣟࣥࢸ࢕࢔ࠖ㹙2㹛ᾆཱྀ኱㍜୍⯡ᩍ⫱₇⩦㸦ࣇࣞࢵࢩ࣐ࣗࣥࢭ࣑ࢼ࣮㸧ࠕ㧗ศᏊ໬Ꮫࡢ
ᇶ♏ࠖ㹙2㹛୰㔝⎔໬Ꮫ,㹙2㹛㣤⏣೺஧㛗㇂ᕝ῟ஓ໬Ꮫ,,㹙2㹛ᾆཱྀ኱㍜ ὸ㔝ᆂభ᭷ᶵ໬Ꮫ,㹙2㹛ᾆཱྀ኱㍜↓ᶵ໬Ꮫ㹙1㹛ὸ㔝ᆂభ᭷ᶵ໬Ꮫᐇ⩦,㹙1㹛㸦຾ᒣᙯ㸧㸦ྜྷᮧᙬ 㸧㉿ᙉ㸦୰ᮧ㢧ᩯ㸧᭷ᶵ໬Ꮫᐇ⩦,,㹙1㹛㸦຾ᒣᙯ㸧㸦ྜྷᮧᙬ 㸧㉿ᙉ㸦୰ᮧ㢧ᩯ㸧᭷ᶵ໬Ꮫᐇ⩦9㹙1㹛㸦⸆ᖌᑎᩥ⳹㸧ὸ㔝ᆂభ㸦᳃㷂୍ᏹ㸧᭷ᶵ໬Ꮫᐇ⩦9,㹙1㹛㸦⸆ᖌᑎᩥ⳹㸧ὸ㔝ᆂభ㸦᳃㷂୍ᏹ㸧᭷ᶵ໬Ꮫၥ㢟₇⩦㹙1㹛㉿ᙉ㸦୰ᮧ㢧ᩯ㸧㸦᳃㷂୍ᏹ 㸧‫ڦ‬ಟኈㄢ⛬࣭⎔ቃ⛉Ꮫ㝔㸦⎔ቃ≀㉁⛉Ꮫᑓᨷ㸧ࢼࣀ⎔ቃᮦᩱ໬Ꮫ≉ㄽ,㹙1㹛㸦⚄㇂⿱୍ 㸧㸦ᘅᕝ῟㸧୰ᓥΎ㝯㸦኱཭ு୍㸧⎔ቃゐ፹໬Ꮫ≉ㄽ,㹙2㹛୰ᓥΎ㝯 ኱㡲㈡㑈ኴⳢ἟Ꮫྐ
⎔ቃ≀㉁⛉Ꮫ≉ูㅮ⩏,,,㹙ㅮ⩏㹛୰ᓥΎ㝯୰ᓥΎ㝯㸦ᒣᯇ⠇⏨㸧
⎔ቃ≀㉁⛉Ꮫ≉ูㅮ⩏,9ࠕ↓ᶵᮦᩱ㹼ගゐ፹ᶵ⬟࡜ྜᡂ࠾ࡼࡧ⤖ᬗࡢᗄఱᏛࡢᇶ♏ࠖ
㹙1㹛୰ᓥΎ㝯 㸦ຍ⸨ⱥᶞ㸧‫ڦ‬ಟኈㄢ⛬࣭⏕࿨⛉Ꮫ㝔㸦⏕࿨⛉Ꮫᑓᨷ㸧๰⸆᭷ᶵྜᡂ໬Ꮫ≉ㄽ㹙1㹛ᾆཱྀ኱㍜ ὸ㔝ᆂభ‫ڦ‬ಟኈㄢ⛬࣭ᕤᏛ㝔⾲㠃ࢼࣀᮦᩱ⛉Ꮫ≉ㄽ㹙1㹛㧘ⲡᮌ㐩ᮅ಴Ύ㧘⾲㠃ࢼࣀゎᯒ⛉Ꮫ≉ㄽ㹙1㹛㧘ⲡᮌ㐩ᮅ಴Ύ㧘‫ڦ‬ಟኈㄢ⛬࣭⥲ྜ໬Ꮫ㝔ᐇ㊶ⓗィ⟬໬Ꮫ㹙2㹛㸦Ṋḟᚭஓ 㸧㸦ఀ⸨⫕㸧㸦ᓥ⏣ᩄᏹ㸧㛗㇂ᕝ῟ஓ
ศᏊ໬Ꮫ㸦㧗ศᏊᶵ⬟⛉Ꮫ㸧㹙1㹛୰㔝⎔‫ڦ‬ಟኈㄢ⛬࣭⥲ྜ໬Ꮫ㝔 ศᏊ໬Ꮫࢥ࣮ࢫ⛉┠㸧ศᏊ໬Ꮫ㸦≀㉁ኚ᥮໬Ꮫ㸧㹙1㹛⚟ᒸ῟ 㛗㇂ᕝ῟ஓ$EKLMLW
6+5275,ศᏊ໬Ꮫ㸿㸦ศᏊ⌮ㄽ໬Ꮫ㸧
㹙2㹛㸦Ṋḟᚭஓ 㸧㛗㇂ᕝ῟ஓ㸦๓⏣⌮㸧㣤⏣೺஧㸦ᑠᯘṇே㸧㸦ᒾబ㇦㸧㸦0LQ*$2㸧ᛂ⏝ศᏊ໬Ꮫ㸿㸦ゐ፹タィ㸧㹙2㹛ΎỈ◊୍ 㫽ᒇᑿ㝯‫ڦ‬ಟኈㄢ⛬࣭⥲ྜ໬Ꮫ㝔 ඹ㏻⛉┠㸧໬Ꮫ⏘ᴗᐇᏛ㹙1㹛㛗㇂ᕝ῟ஓᖺሗ ࣭ಶே⦅‫ە‬79⥲ྜ໬Ꮫ≉ㄽ,㹙1㹛㸦ᯇ஭㞞ᶞ 㸧㸦᱓⏣┤᫂㸧㸦㟷ᮌⰾᑦ㸧㣤⏣೺஧㸦⚟ᓥ▱ᏹ㸧㸦ዉ㡲⁞㸧ᛂ⏝໬Ꮫ≉ูㅮ⩏㹙1㹛ΎỈ◊୍ 㣤⏣೺஧㫽ᒇᑿ㝯୰ᓥΎ㝯ὸ㔝ᆂభ‫ڦ‬ಟኈㄢ⛬࣭኱Ꮫ㝔ඹ㏻ᤵᴗ⛉┠㸦⮬↛⛉Ꮫ࣭ᛂ⏝⛉Ꮫ⣔㸧
኱Ꮫ㝔ඹ㏻ᤵᴗ⛉┠㸦୍⯡⛉┠㸧㸸⮬↛⛉Ꮫ࣭ᛂ⏝⛉Ꮫࠕ໬Ꮫ⏘ᴗᐇᏛࠖ㹙1㹛㛗㇂ᕝ῟ஓ኱Ꮫ㝔ඹ㏻ᤵᴗ⛉┠㸦୍⯡⛉┠㸧㸸⮬↛⛉Ꮫ࣭ᛂ⏝⛉Ꮫࠕୡ⏺ࢆඛᑟࡍࡿศᏊ໬Ꮫ,%㸦ゐ፹໬Ꮫࡢཎ⌮㸸⌮ㄽ࡜ᛂ⏝㸧ࠖ㹙1㹛ΎỈ◊୍ ୰ᓥΎ㝯㣤⏣೺஧ὸ㔝ᆂభ㫽ᒇᑿ㝯኱Ꮫ㝔ඹ㏻ᤵᴗ⛉┠㸦୍⯡⛉┠㸧㸸⮬↛⛉Ꮫ࣭ᛂ⏝⛉Ꮫࠕୡ⏺ࢆඛᑟࡍࡿศᏊ໬Ꮫ,,,$㸦⥲ྜ໬Ꮫ≉ㄽ,㸦↓ᶵ໬Ꮫ࣭㸦ᯇ஭㞞ᶞ 㸧㸦㟷ᮌⰾᑦ㸧㸦᱓⏣┤
≀⌮໬Ꮫ㸧
㸧ࠖ㹙1㹛
᫂㸧㣤⏣೺஧㸦⚟ᓥ▱ᏹ㸧㸦ዉ㡲⁞㸧

2023ᖺᗘᏛ఩ᑂᰝ ゐ፹⛉Ꮫ◊✲ᡤࡢᩍဨࡀᑂᰝ࡟࠶ࡓࡗࡓࡶࡢ㸬㸦㸧ࡣゐ፹⛉Ꮫ◊✲ᡤ௨እࡢᡤᒓᏛ⏕኱Ꮫ㝔⏕ᩍဨࢆ࠶ࡽࢃࡍ㸬㸦ἙᮧᘺᏘ㸧ࠕከඖྜ㔠ゐ፹࡟ࡼࡿ㟁Ẽ໬Ꮫⓗள㓟໬❅⣲㑏ඖࠖ୺ᰝ㸸㸦ຍ⸨ඃ㸧࣭๪ᰝ㸸㸦ඵᮌ୍୕㸧/୰ᓥΎ㝯/㸦኱཭ு୍㸧㸦㰻⸨㥴㸧ࠕ㖡࣭㕲࣭❅⣲ࢻ࣮ࣉከᏍ㉁࣮࢝࣎ࣥ㟁ᴟゐ፹ࡢ㓟⣲㑏ඖάᛶࠖ୺ᰝ㸸㸦ඵᮌ୍୕㸧࣭๪ᰝ㸸㸦ᑠすඞ᫂㸧
/㸦ຍ⸨ඃ㸧/Ⳣ἟Ꮫྐ㸦బ⸨ຍዉ㸧ࠕ ᐊຠᯝ࢞ࢫࡢ๐ῶࢆ┠ᣦࡋࡓᢸᣢ࢖ࣜࢪ࣒࢘ゐ፹࡟ࡼࡿள㓟໬❅⣲ࡢỈ⣲໬ศゎࠖ୺ᰝ㸸㸦⚄㇂⿱୍㸧࣭๪ᰝ㸸୰ᓥΎ㝯/Ⳣ἟Ꮫྐ/㸦኱཭ு୍㸧㸦బ⸨ᮍᝆ㸧
ࠕTi2O3ᢸᣢࣔࣜࣈࢹࣥ㓟໬≀ࡢㄪ〇࡜ᅛయ㓟ゐ፹࡜ࡋ࡚ࡢᛂ⏝ࠖ୺ᰝ㸸㸦኱཭ு୍㸧
࣭๪ᰝ㸸㸦⚄㇂⿱୍㸧
/㧘ⲡᮌ㐩/኱㡲㈡㑈ኴ㸦୰ᐟᮒ㔛㸧ࠕᅛ┦ΰྜἲ࡟ࡼࡿ୰✵ᆺ࣏ࣜ㓟ෆ㒊࡬ࡢࢤࢫࢺໟ᥋࡜㛢ࡌ㎸ࡵᶵ⬟ࠖ୺ᰝ㸸㸦ᑠすඞ᫂㸧࣭๪ᰝ㸸㸦⚄㇂⿱୍㸧/୰ᓥΎ㝯/㸦୐ศຬ຾㸧㸦 ẁ 㞾 㸧ࠕ Exciton recombination rate control in MAPbBr3
perovskite single crystals with different sizesࠖ୺ᰝ㸸㸦ࣅࢪࣗ ࣂࢫࢹࣂࣥ ࣆࣛ࢖㸧࣭๪ᰝ㸸୰ᓥΎ㝯/㸦ຍ⸨ඃ㸧/㸦ᒸᮏᣅஓ㸧኱Ꮫ㝔⥲ྜ໬Ꮫ㝔‫ڦ‬༤ኈ

኱Ꮫ㝔⌮Ꮫ◊✲㝔㸦 SHEET Nirupama 㸧ࠕ Studies on Catalytic Conversion of
Biomass-derived C6-Furanicsfor Polymer Applicationsࠖ୺ᰝ㸸㸦㛗㇂ᕝ῟ஓ㸧࣭๪ᰝ㸸ΎỈ◊୍୰㔝⎔⚟ᒸ῟୰ᓥΎ㝯Eindhoven University of Technology, Eindhoven, The
Netherlands㸦Ferdy J.A.G. Coumans㸧ࠕAmorphous SilicaAlumina Catalysts for the Conversion of Renewable
Feedstocks ࠖ ୺ ᰝ 㸸㸦 A.P.H.J. Schenning 㸧࣭ ๪ ᰝ 㸸㸦 K.
Nakajima㸧/㸦 P.C.A. Bruijnincx㸧/㸦 P.P. Pescarmona㸧/㸦 R.A.T.M. van Benthem㸧/㸦 F. Gallucci㸧‫ڦ‬ಟኈ

኱Ꮫ㝔⥲ྜ໬Ꮫ㝔ྜྷཎ㞞㈗ࠕ⇞↝ᶍᨃ᤼࢞ࢫ࡜H2࠿ࡽࡢCOཬࡧCH4ࡢ㐃⥆ྜᡂࠖ୺ᰝ㸸ΎỈ◊୍࣭๪ᰝ㸸㸦Ⲷ㔝໏㸧/㸦ᏵᚿẎ㸧Ọ஭೺ࠕCoβゐ፹࡟ࡼࡿ࢜ࢰࣥࢆ⏝࠸ࡓ࣓ࢱࣥࡢᐊ
↝ࠖ୺ᰝ㸸ΎỈ◊୍࣭๪ᰝ㸸㸦୰ᆏభኴ㸧/㣤⏣೺஧㸦Ᏻ㰻₶୍㑻㸧ࠕ㞴㑏ඖᛶ␗✀㔠ᒓ࡛㒊ศ⨨᥮ࡉࢀࡓ㕲⣔࣌ࣟࣈࢫ࢝࢖ࢺᆺ㓟໬≀ࢆ⏝࠸ࡓN2Oࡢ┤᥋ศゎࠖ୺ᰝ㸸㸦኱཭ு୍㸧
࣭๪ᰝ㸸㸦⚄㇂⿱୍㸧/୰ᓥΎ㝯/㸦㇏⏣࿴ᘯ㸧⇞㛵᰿୍⩧ࠕCO2ࢆ⏝࠸ࡓ㓟໬ⓗࣉࣟࣃࣥ⬺Ỉ⣲࡟᭷ຠ࡞Pt⣔ྜ㔠ゐ፹ࡢ㛤Ⓨࠖ୺ᰝ㸸ΎỈ◊୍࣭๪ᰝ㸸㸦୰ᆏభኴ㸧
/㣤⏣೺஧ᖹ℩ࡦࡢࡁࠕ㔠ᒓࢧࣈࢼࣀࢡࣛࢫࢱ࣮࡜ศᏊࡢ┦஫స⏝࡟㛵ࡍࡿ⌮ㄽⓗ࡞◊✲ࠖ୺ᰝ㸸㛗㇂ᕝ῟ஓ࣭๪ᰝ㸸㸦Ṋḟᚭஓ㸧ΎỈ◊୍㣤⏣೺஧኱Ꮫ㝔⏕࿨⛉Ꮫ㝔㸦⦩⚽ᘺ㸧ࠕࣟࢲࢧ࢖ࢡࣝࡢᙧᡂࢆᘬࡁ㔠࡜ࡍࡿⅣ⣲−Ⅳ⣲⤖ྜษ᩿཯ᛂࠖ୺ᰝ㸸㸦బ⸨⨾ὒ㸧
࣭๪ᰝ㸸㸦ᾆཱྀ኱㍜㸭኱すⱥ༤㸧㸦㕥ᮌᬗᙪ㸧
ࠕග㓟໬㑏ඖゐ፹/ࢥࣂࣝࢺゐ፹ࡢ༠ാ࡟ࡼࡿ
DATࢆ㉳Ⅼ࡜ࡋࡓ࢔ࣝࢣࣥࡢከᵝ࡞㔜Ỉ⣲໬ᡭἲࡢ㛤Ⓨࠖ୺ᰝ㸸㸦ྜྷ㔝㐩ᙪ㸧
࣭๪ᰝ㸸㸦ᾆཱྀ኱㍜㸭ᯇỌⱱᶞ㸧㸦ᑠᓥ㝣㸧ࠕTETRADࢆ⏝࠸ࡓ࣊ࢸࣟⰾ㤶᪘໬ྜ≀࡬ࡢ⬺ⰾ㤶᪘໬཯ᛂ࠾ࡼࡧࢫࢸ࣮ࣉࣝ࣌ࣉࢳࢻ(Stapled peptide)࡬ࡢ฼⏝ࢆᣦྥࡋࡓ᪂つ໬ྜ≀ࡢ᥈⣴ࠖ୺ᰝ㸸㸦ྜྷ㔝㐩ᙪ㸧࣭๪ᰝ㸸㸦ὸ㔝ᆂభ㸭ᯇỌⱱᶞ㸧‫ڦ‬Ꮫኈ
ᕤᏛ㒊Ᏻ⸨᭷㔛ᏊࠕHZSM-5ࢆ⏝࠸ࡓHeẼὶୗ࡛ࡢ࣏ࣜࣉࣟࣆࣞࣥࡢ᥋ゐศゎࠖ୺ᰝ㸸ΎỈ◊୍⏣ᓥ኱ᆅࠕᶵᲔᏛ⩦ࢆ⏝࠸ࡓ࣓ࢱࣥ⇞↝ゐ፹ࡢ㛤Ⓨ࡜⤫ィゎᯒࠖ୺ᰝ㸸ΎỈ◊୍ᐩᐊὒ௓ࠕ㔠ᒓỈ⣲໬≀ゐ፹࡟ࡼࡿ࢔࣓ࣝ࢝ࣥࢱࢭࢩࢫ཯
ᛂࠖ୺ᰝ㸸ΎỈ◊୍࣭๪ᰝ㸸㸦Ⲷ㔝໏㸧/㸦ᏵᚿẎ㸧㸦஭ཱྀ཭㈗㸧ࠕࣜࣂ࣮ࢫࣔࣥࢸ࢝ࣝࣟἲ࡟ࡼࡿ࢖ࣥࢪ࣒࢘
⼥ゎ㐣⛬ࡢEXAFSᵓ㐀ゎᯒࠖ୺ᰝ㸸ᮅ಴Ύ㧘኱Ꮫ㝔⎔ቃ⛉Ꮫ㝔㸦ᶓᒣᬛ⣖㸧ࠕᅇ㌿ࢹ࢕ࢫࢡ㟁ᴟἲ࡟ࡼࡿPt/Pdn/Auࢧࣥࢻ࢖ࢵࢳゐ፹ࡢάᛶ࡜ᵓ㐀࡟㛵ࡍࡿ◊✲ࠖ୺ᰝ㸸ᮅ಴Ύ㧘

㸦WITONO Aditya Irfan㸧ࠕNitrate anion separation from waterusing metal-organic frameworksࠖ୺ᰝ㸸㸦㔝࿅┿୍㑻㸧࣭๪ᰝ㸸㸦⚄㇂⿱୍㸧㧘ⲡᮌ㐩Ⳣ἟Ꮫྐ㸦XING Sihao㸧ࠕSynthesis and CO2 adsorption properties of
one-dimensional copper coordination polymers with paddlewheel dimer unitsࠖ୺ᰝ㸸㸦㔝࿅┿୍㑻㸧
࣭๪ᰝ㸸୰ᓥΎ㝯㸦୐ศຬ຾㸧㸦࿋ె෦㸧᪂஭┤ࠕᢸᣢAuゐ፹࡟ࡼࡿHMF࢔ࢭࢱ࣮ࣝࡢ㓟໬ⓗ࢚ࢫࢸࣝ໬཯ᛂࠖ୺ᰝ㸸୰ᓥΎ㝯࣭๪ᰝ㸸㸦⚄㇂⿱୍㸧Ⳣ἟Ꮫྐ/㸦኱཭ு୍㸧80⌮Ꮫ㒊㸦ຍ⸨๰㸧ࠕPt༢ཎᏊ㟁ᴟゐ፹ࢆ⏝࠸ࡓ㓟⣲㑏ඖ཯ᛂ࡟ࡘ
࠸࡚ࡢ⌮ㄽⓗ◊✲ࠖ୺ᰝ㸸㛗㇂ᕝ῟ஓ⸆Ꮫ㒊㸦ụᮏᐇ⣪Ꮚ㸧ࠕ࢔࣑ࣀ㓟⏤᮶ࡢ୙ᩧ⮯⣲໬ゐ፹࡟࠾ࡅࡿ
࢚ࢼࣥࢳ࢜㑅ᢥᛶࡢ㏫㌿ࠖ୺ᰝ㸸ᾆཱྀ኱㍜㸦⋢⃝᪼ኴ㸧ࠕࢪ࢔࣮ࣜࣝ࣍ࢫࣇ࢕ࣥࢫࣝࣇ࢕ࢻࡢỈ⣲ཎᏊ⛣ືゐ፹ᶵ⬟๰ฟ㸸࢚ࢼ࣑ࣥࡢࢪ࢔ࢫࢸࣞ࢜㑅ᢥⓗࣄࢻࣟ࢔ࢭࢺ࢟ࢩ໬཯ᛂࠖ୺ᰝ㸸ᾆཱྀ኱㍜
ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬㸦⸨ᒸ㈼୍㑻㸧ࠕ㓄఩㣬࿴ᆺ࣎ࣞࢽ࣒࢘ሷࢆගゐ፹࡜ࡍࡿ࢖ࣥࢻ࣮ࣝN-࢔ࣝ࢟ࣝ໬཯ᛂࡢ㛤Ⓨࠖ୺ᰝ㸸ᾆཱྀ኱㍜㸦ୗ⃝΅㸧ࠕ஧ᐁ⬟ᛶࢳ࢜࢘ࣞ࢔ゐ፹࡟ࡼࡿ୙ᩧ1,3-ࢪ࢜࢟ࢧࣥྜᡂࠖ୺ᰝ㸸ᾆཱྀ኱㍜

2023ᖺᗘጤဨ࣭ㅮᖌ࡞࡝
‫ڦ‬඲Ꮫጤဨ఍➼ࢧ ࢫ ࢸ ࢖ ࢼ ࣅ ࣜ ࢸ ࢕ ᥎ 㐍 ဨ  ᾆ ཱྀ ኱ ㍜ 㹙 2023/04/01 㹼
2025/03/31㹛ࣁ ࣛ ࢫ ࣓ ࣥ ࢺ ண 㜵 ᥎ 㐍 ဨ  㣤 ⏣ ೺ ஧ 㹙 2022/04/01 㹼
2024/03/31㹛඲Ꮫ㐠⏝ᩍဨᑂᰝ఍ ΎỈ◊୍㹙2023/04/01㹼2024/03/31㹛
໬ Ꮫ ≀ ㉁ ➼ ⟶ ⌮ ጤ ဨ ఍  ୰ ᓥ Ύ 㝯 㹙 2022/04/01 㹼
2024/03/31㹛ᢏ ⾡ ᨭ ᥼ ᮏ 㒊 㐠 Ⴀ ጤ ဨ ఍  Ύ Ỉ ◊ ୍ 㹙 2022/04/01 㹼
2024/03/31㹛ᨺᑕᛶྠ఩ඖ⣲➼⟶⌮ጤဨ఍ ᮅ಴Ύ㧘㹙2022/04/01㹼
2024/03/31㹛ᩍົጤဨ఍ ΎỈ◊୍㹙2022/04/01㹼2024/03/31㹛ᩍ⫱◊✲ホ㆟఍ ΎỈ◊୍㹙2022/04/01㹼2024/03/31㹛⏘ Ꮫ 㐃 ᦠ ᮏ 㒊 ▱ ⓗ ㈈ ⏘ ጤ ဨ ఍  ୰ 㔝 ⎔㹙 2023/04/01 㹼
2025/03/31㹛⥲㛗⿵బ ⚟ᒸ῟㹙2022/04/01㹼2024/03/31㹛
࣭㛗㇂ᕝ῟ஓ
㹙2022/04/01㹼2024/03/31㹛㒊ᒁ㛗➼㐃⤡఍㆟ ΎỈ◊୍㹙2022/04/01㹼2024/03/31㹛‫ڦ‬බⓗᶵ㛵➼ࡢጤဨ㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍⛉Ꮫ◊✲㈝ጤဨ఍ᑓ㛛ጤဨࠕᇶ┙◊✲㹀ࠖ 㧘ⲡᮌ㐩㹙2022/11/01㹼2023/10/31㹛஑ᕞ኱Ꮫ࣮࢝࣎ࣥࢽ࣮ࣗࢺ࣭࢚ࣛࣝࢿࣝࢠ࣮ᅜ㝿◊✲ᡤ㝃ᒓ࢚ࢿࣝࢠ࣮ࢩࢫࢸ࣒ࢹࢨ࢖ࣥ◊✲ࢭࣥࢱ࣮㐠Ⴀጤဨ఍ཬࡧᩍဨ㑅⪃ጤဨ఍ጤဨ ΎỈ◊୍㹙2022/11/01㹼
2024/03/31㹛ி㒔኱Ꮫ࣮࢜ࣉࣥ࢖ࣀ࣮࣋ࢩࣙࣥᶵᵓ࢔ࢻࣂ࢖ࢨ࣮
ᮅ಴Ύ㧘㹙2023/04/01㹼2024/03/31㹛࣭⚟ᒸ῟㹙2023/12/01
㹼2024/03/31㹛ྡྂᒇ኱Ꮫ *75༟㉺኱Ꮫ㝔ࣉࣟࢢ࣒ࣛ ࢲࣈ࣓ࣝࣥࢱ࣮㛗㇂ᕝ῟ஓ㹙2024/02/20㹛ྡྂᒇ኱ᏛᏛ㝿⤫ྜ≀㉁⛉Ꮫ◊✲ᶵᵓ㐠Ⴀጤဨ఍ጤဨ㛗 ㇂ ᕝ ῟ ஓ 㹙 2022/07/01 㹼 2024/03/31 㹛࣭ 㛗 ㇂ ᕝ ῟ ஓ㹙2023/04/01㹼2024/03/31㹛ᅜ❧◊✲ἲே᪂࢚ࢿࣝࢠ࣮࣭⏘ᴗᢏ⾡⥲ྜ㛤Ⓨᶵᵓ1('2ᢏ⾡ጤဨ ΎỈ◊୍㹙2023/05/01㹼2025/03/31㹛ᅜ❧◊✲㛤Ⓨἲே⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ໭ᾏ㐨ࢭࣥࢱ࣮
⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ໭ᾏ㐨ࢭࣥࢱ࣮㐠Ⴀ᠓ヰ఍ጤဨ㛗㇂ᕝ῟ஓ㹙2023/10/05㹼2023/10/20㹛ᅜ㝿⣧ṇᛂ⏝໬Ꮫ㐃ྜ㸦,83$&㸧㧗ศᏊ⏝ㄒἲᑠጤဨ఍ጤ
ဨ㸦637㸧 ୰㔝⎔㹙2023/04/01㹼2024/03/31㹛ᅜ㝿ゐ፹Ꮫ఍ 2IILFHU㸦ᙺဨ㸧 ⚟ᒸ῟㹙2020/06/20㹼
2024/07/14㹛ᩥ㒊⛉Ꮫ┬⛉Ꮫᢏ⾡࣭Ꮫ⾡ᨻ⟇◊✲ᡤ⛉Ꮫᢏ⾡ண ࣭ᨻ⟇ᇶ┙ㄪᰝ◊✲ࢭࣥࢱ࣮ᑓ㛛ㄪᰝဨ ୰ᓥΎ㝯
㹙2023/04/01㹼2024/03/31㹛᪥ ᮏ ᨺ ᑕ ග Ꮫ ఍  ホ ㆟ ဨ  ᮅ ಴ Ύ 㧘 㹙 2022/10/01 㹼
2024/03/31㹛❧࿨㤋኱Ꮫ⥲ྜ⛉ᏛᏛᢏ⾡◊✲ᶵᵓ65ࢭࣥࢱ࣮❧࿨㤋኱Ꮫ⥲ྜ⛉Ꮫᢏ⾡◊✲ᶵᵓ◊✲㢳ၥཬࡧ65ࢭࣥࢱ࣮㐠Ⴀጤဨ ᮅ಴Ύ㧘㹙2023/04/01㹼2024/03/31㹛ᖺሗ ࣭ಶே⦅‫ە‬ㄆ ᐃ 132 ἲ ே 㔞 Ꮚ ໬ Ꮫ ◊ ✲ ༠ ఍  ⌮ ஦  㛗 ㇂ ᕝ ῟ ஓ㹙2022/06/10㹼2023/06/09㹛㸦୍♫㸧ゐ፹Ꮫ఍ཧ↷ゐ፹ጤဨ఍ጤဨ 㫽ᒇᑿ㝯
㹙 2022/05/13 㹼 2023/05/12 㹛࣭ 㫽 ᒇ ᑿ 㝯 㹙 2023/05/12 㹼
2024/05/10㹛㸦୍♫㸧㏆␥໬Ꮫ༠఍➨ᅇᅜ㝿᭷ᶵ໬Ꮫி㒔఍㆟⤌⧊ጤဨ 㛗㇂ᕝ῟ஓ㹙2023/05/26㹼2023/11/23㹛㸦බ㈈㸧໭ᾏ㐨⛉Ꮫᢏ⾡⥲ྜ᣺⯆ࢭࣥࢱ࣮ᑂᰝጤဨ఍ጤဨ ⚟ᒸ῟㹙2023/04/26㹼2024/03/31㹛㸦බබ㈈㸧໭ᾏ㐨⛉Ꮫᢏ⾡⥲ྜ᣺⯆ࢭࣥࢱ࣮◊✲㛤Ⓨຓᡂ஦ ᴗ ᑂ ᰝ ጤ ဨ ఍ ᑓ 㛛 ጤ ဨ  ⚟ ᒸ ῟ 㹙 2023/06/09 㹼
2024/03/31㹛㸦ᅜ◊㸧᪥ᮏ⛉Ꮫᢏ⾡᣺⯆ᶵᵓᮍ᮶♫఍๰㐀஦ᴗ እ㒊ᑓ㛛ᐙ ⚟ᒸ῟㹙2023/04/01㹼2024/03/31㹛㸦ᅜ◊㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ๰Ⓨⓗ◊✲ᨭ᥼஦ᴗ஦๓ホ౯እ㒊ᑓ㛛ᐙ ΎỈ◊୍㹙2023/10/25㹼2025/06/30㹛㸦ᅜ◊㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ๰Ⓨⓗ◊✲ᨭ᥼஦ᴗ࢔ࢻࣂ࢖
ࢨ࣮㸦๰Ⓨ㸿㹂㸧 ⚟ᒸ῟㹙2023/10/01㹼2024/03/31㹛㸦ᅜ◊㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓᡓ␎ⓗ๰㐀◊✲᥎㐍஦ᴗඛ➃ⓗ࣮࢝࣎ࣥࢽ࣮ࣗࢺࣛࣝᢏ⾡㛤Ⓨ㸦$/&$1H[W㸧␆࢚ࢿࣝࢠ࣮࢚ࢿࣝࢠ࣮ኚ᥮㈨※ᚠ⎔㡿ᇦእ㒊ᑓ㛛ᐙ ΎỈ◊୍㹙2023/07/26㹼2023/11/30㹛㸦ᅜ◊㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ㠉᪂ⓗ*;ᢏ⾡๰ฟ஦ᴗ *WH;ࣂ࢖࢜ࡶࡢ࡙ࡃࡾ㡿ᇦ 㡿ᇦ࢔ࢻࣂ࢖ࢨ࣮  ⚟ᒸ῟
㹙2023/07/01㹼2024/03/31㹛㸦ᅜ◊㸧㔞Ꮚ⛉Ꮫᢏ⾡◊✲㛤Ⓨᶵᵓ 1DQR7HUDVXඹ⏝ࣅ࣮࣒ࣛ࢖ࣥᩚഛ᳨ウጤဨ఍ጤဨ ᮅ಴Ύ㧘㹙2023/09/25ʛ
2024/03/31㹛㸦 ᰴ 㸧 ࣃ ࢯ ࢼ ᭩ 㠃ᑂ ᰝ ጤ ဨ  ୰ᓥ Ύ㝯 㹙2022/07/01 ʛ

2023/03/31㹛
࣭୰ᓥΎ㝯㹙2023/04/01ʛ2024/03/31㹛㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍ 5ඛ➃ィ ᢏ⾡ࡢᑗ᮶タィጤဨ఍ ᮅ಴Ύ㧘㹙2023/06/05㹼2024/03/31㹛㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍ࠕᇶ┙◊✲ 㹑 ࠖࡢᑂᰝ࡟ಀࡿᑂᰝពぢ᭩ࡢసᡂ⪅ ᮅ಴Ύ㧘㹙2023/07/24㹼2023/08/18㹛࣭ΎỈ◊୍㹙2023/07/24㹼2023/08/18㹛㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍⛉Ꮫ◊✲㈝ຓᡂ஦ᴗࠕᅜ㝿ඛᑟ◊✲ࠖࡢᑂᰝ࡟ಀࡿᑂᰝពぢ᭩㸦᭩㠃㸧ࡢసᡂ⪅ 㫽ᒇᑿ㝯㹙2023/06/01㹼2023/06/22㹛㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍⛉Ꮫ◊✲㈝ጤဨ఍ᑓ㛛ጤဨ 㛗㇂ᕝ῟ஓ㹙2022/11/01㹼2023/10/31㹛㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍⛉Ꮫ◊✲㈝ጤဨ఍ᑓ㛛ጤဨࠕᅜ㝿ඹྠ◊✲ᙉ໬ཬࡧᖐᅜⓎᒎ◊✲ࠖ ⚟ᒸ῟㹙2023/10/01㹼
2024/03/31㹛㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍⛉Ꮫ◊✲㈝ጤဨ఍ᑓ㛛ጤဨࠕᅜ㝿ඹྠ◊✲ᙉ໬㸦㸿㸧ཬࡧᖐᅜⓎᒎ◊✲ࠖ ᮅ಴Ύ㧘
㹙2022/09/27㹼2023/08/31㹛㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍⛉Ꮫ◊✲㈝ጤဨ఍ᑓ㛛ጤဨࠕᇶ┙◊✲㸿ࠖ ᾆཱྀ኱㍜㹙2022/10/01㹼2023/09/30㹛㸦♫㸧᪥ᮏ໬Ꮫ఍ ᖺᗘ໭ᾏ㐨ᨭ㒊ᖿ஦ 㛗㇂ᕝ῟ஓ
㹙2023/03/01㹼2024/02/29㹛㸦 ♫ 㸧 ᪥ ᮏ ໬ Ꮫ ఍ ௦㆟ ဨ  㛗㇂ᕝ ῟ஓ 㹙2022/10/29 㹼
2023/10/27㹛㸦♫㸧᪥ᮏ໬Ꮫ఍௧࿴ᖺ㏿ሗㄅ⦅㞟ጤဨ఍ጤဨ 㛗㇂ᕝ῟ஓ㹙2023/01/01㹼2023/12/31㹛㸦♫㸧᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊㛗 ᮅ಴Ύ㧘㹙2023/03/01㹼
2024/02/29㹛㸦♫㸧᪥ᮏ໬Ꮫ఍࿨ྡἲᑓ㛛ጤဨ఍ጤဨ ୰㔝⎔㹙2023/03/01㹼2024/02/28㹛㸦♫㸧᪥ᮏ໬Ꮫ఍᪥ᮏ໬Ꮫ఍໭ᾏ㐨ᨭ㒊 ᖿ஦ ୰㔝⎔㹙2024/03/01㹼2025/02/28㹛81㸦♫㸧᪥ᮏ໬Ꮫ఍⌮஦ ⚟ᒸ῟㹙2021/05/26㹼R5.5᭶⥲఍㛤ദ᪥㹛㸦♫㸧᪥ᮏ໬Ꮫ఍㏿ሗㄅ⦅㞟ጤဨ఍ጤဨ 㛗㇂ᕝ῟ஓ
㹙2024/01/01㹼2024/12/31㹛㸦♫㸧⌮ㄽ໬Ꮫ఍ᖿ஦ ๪఍㛗㸧 㛗㇂ᕝ῟ஓ㹙2021/10/01
㹼2023/09/30㹛㸦♫㸧ゐ፹Ꮫ఍ ᖺᗘ ໭ᾏ㐨ᨭ㒊ᖿ஦ ୰ᓥΎ㝯
㹙2023/05/12㹼2024/05/10㹛㸦♫㸧ゐ፹Ꮫ఍ ᖺᗘ ⤒Ⴀ࣭ண⟬ጤဨ఍ጤဨ ୰ᓥΎ㝯㹙2023/05/12㹼2024/05/10㹛㸦 ♫ 㸧 ゐ ፹ Ꮫ ఍  ௦ ㆟ ဨ  㛗 ㇂ ᕝ ῟ ஓ 㹙 2023/03/01 㹼
2024/02/29㹛
࣭㛗㇂ᕝ῟ஓ㹙2024/03/01㹼2025/02/28㹛
࣭⚟ᒸ῟ 㹙 2023/03/01 㹼 2024/02/29 㹛࣭ ⚟ ᒸ ῟ 㹙 2024/03/01 㹼
2025/02/28㹛㸦♫㸧ゐ፹Ꮫ఍௻⏬࣭ᩍ⫱ጤဨ఍ጤဨ 㧘ⲡᮌ㐩
㹙 2023/05/12 㹼 2024/05/10 㹛࣭ ୰ ᓥ Ύ 㝯 㹙 2022/05/13 㹼
2023/05/12㹛㸦♫㸧ゐ፹Ꮫ఍໭ᾏ㐨ᨭ㒊ᖿ஦ ୰ᓥΎ㝯㹙2022/05/13㹼
2023/05/12㹛㸦♫㸧ゐ፹Ꮫ఍ᅜ㝿஺ὶጤဨ఍ጤဨ ⚟ᒸ῟㹙023/05/12
㹼2024/05/10㹛㸦♫㸧㧗ศᏊᏛ఍㧗ศᏊ࿨ྡἲጤဨ఍ጤဨ㛗 ୰㔝⎔㹙2023/04/01㹼2024/03/31㹛㸦㈈㸧㧗㍤ᗘග⛉Ꮫ◊✲ࢭࣥࢱ࣮኱Ꮫ㝔⏕฼⏝ᑂᰝጤဨ఍ጤဨ ᮅ಴Ύ㧘㹙2023/04/01㹼2024/03/31㹛‫ڦ‬㛵㐃㒊ᒁ➼ྛ✀ጤဨ఍ࠓ࢔࢖ࢯࢺ࣮ࣉ⥲ྜࢭࣥࢱ࣮ࠔ㐠Ⴀጤဨ఍ ᏵᚿẎ㹙2022/04/01㹼2024/03/31㹛ࠓ஦ົᒁ㸦᝟ሗ௻⏬ㄢ㸧ࠔ᝟ሗᇶ┙ࢭࣥࢱ࣮༠㆟ဨ఍ 㛗㇂ᕝ῟ஓ㹙2023/04/01㹼2025/03/31㹛ࠓ஦ົᒁ㸦᝟ሗ᥎㐍ㄢ㸧ࠔ᝟ሗࢭ࢟ࣗࣜࢸ࢕ጤဨ఍ 㛗㇂ᕝ῟ஓ㹙2022/04/01㹼2024/03/31㹛ࠓ஦ົᒁ㸦◊✲᥎㐍㒊㸧ࠔ◊✲タഛ࣭ᶵჾࡢ⤌⧊ෆእ࡬ࡢඹ
⏝᪉㔪ࡢ⟇ᐃ➼సᴗ㒊఍࣮࣡࢟ࣥࢢࢢ࣮ࣝࣉጤဨ ΎỈ◊୍㹙2022/07/01㹼2024/03/31㹛ࠓ஦ົᒁ㸦◊✲᥎㐍㒊㸧ࠔ⥲ྜ࢖ࣀ࣮࣋ࢩࣙࣥ๰Ⓨᶵᵓ㸦௬⛠㸧タ⨨࡟ྥࡅࡓ᳨ウጤဨ఍ጤဨ ⚟ᒸ῟㹙2023/10/23㹼㹛ࠓ஦ົᒁ㸦◊✲ᨭ᥼ㄢ㸧ࠔ๰ᡂ◊✲ᶵᵓᇳ⾜఍㆟ጤဨ ΎỈ◊୍㹙2022/04/01㹼2024/03/31㹛ࠓಖ೺ࢭࣥࢱ࣮ࠔ㐠Ⴀጤဨ఍ 㧘ⲡᮌ㐩㹙2023/04/01㹼
2025/03/31㹛ࠓ ༤ ≀ 㤋 ࠔ ⥲ ྜ 㐠 Ⴀ ጤ ဨ ఍  ᾆ ཱྀ ኱ ㍜ 㹙 2023/04/01 㹼
2025/03/31㹛ࠓᅗ᭩㤋ࠔጤဨ఍ 㣤⏣೺஧㹙2022/04/01㹼2024/03/31㹛ࠓᕤᏛ◊✲㝔ࠔᏛෆඹྠ฼⏝᪋タ㐠Ⴀጤဨ఍ጤဨ㸦ࢼࣀ࣭࣐࢖ࢡ࣐ࣟࢸࣜ࢔ࣝศᯒ◊✲ᐊ㐠Ⴀጤဨ఍㸧 㧘ⲡᮌ㐩
㹙2021/04/01㹼2024/03/31㹛ࠓᕤᏛ◊✲㝔ࠔᏛෆඹྠ฼⏝᪋タ㐠Ⴀጤဨ఍ጤဨ㸦ග㟁Ꮚศගศᯒ◊✲ᐊ㐠Ⴀጤဨ఍㸧 㧘ⲡᮌ㐩㹙2023/04/01㹼
2026/03/31㹛ࠓᕤᏛ◊✲㝔ࠔᏛෆඹྠ฼⏝᪋タ㐠Ⴀጤဨ఍ጤဨ㸦㉸㧗ᅽ㟁Ꮚ㢧ᚤ㙾◊✲ᐊ㐠Ⴀጤဨ఍㸧 ᮅ಴Ύ㧘㹙2022/04/01
㹼2024/03/31㹛ࠓᕤᏛ◊✲㝔ࠔᏛෆඹྠ฼⏝᪋タ㐠Ⴀጤဨ఍ጤဨ㸦㧗࢚ࢿࣝࢠ࣮㉸ᙉຊ;⥺ᅇᯒᐊ㐠Ⴀጤဨ఍㸧 㧘ⲡᮌ㐩
㹙2022/04/01㹼2024/03/31㹛ࠓ᝟ሗ⛉Ꮫ㝔ࠔ㔞Ꮚ㞟✚࢚ࣞࢡࢺࣟࢽࢡࢫ◊✲ࢭࣥࢱ࣮㐠Ⴀጤဨ఍ 㧘ⲡᮌ㐩㹙2023/04/01㹼2025/03/31㹛82ࠓ⌮Ꮫ◊✲㝔ࠔඖ⣲ᡓ␎ᩍ⫱◊✲ࢭࣥࢱ࣮㐠Ⴀጤဨ఍ ⚟ᒸ῟㹙2022/04/01㹼2024/03/31㹛࣭ΎỈ◊୍㹙2022/04/01㹼
2024/03/31㹛ࠓ⌮Ꮫ◊✲㝔ࠔᆅ⌫ᝨᫍᅛయ≀㉁ゎᯒࢩࢫࢸ࣒◊✲ᐊ㐠Ⴀጤဨ఍ 㧘ⲡᮌ㐩㹙2023/08/16㹼2025/08/15㹛ࠓ⌮Ꮫ◊✲㝔ࠔᴟప ᾮ໬ࢭࣥࢱ࣮㐠Ⴀጤဨ఍ ୰ᓥΎ㝯
㹙2022/04/01㹼2024/03/31㹛ࠓ⌮Ꮫ◊✲㝔ࠔ㧗ศゎ⬟᰾☢Ẽඹ㬆⿦⨨◊✲ᐊ㐠Ⴀጤဨ఍
ᾆཱྀ኱㍜㹙2023/06/01㹼2025/05/31㹛ࠓ㧗➼ᩍ⫱᥎㐍ᶵᵓࠔ໭ᾏ㐨኱Ꮫ኱Ꮫ㝔≀㉁⛉Ꮫࣇࣟࣥࢸ
࢕࢔ࢆ㛤ᣅࡍࡿ$PELWLRXV࣮ࣜࢲ࣮⫱ᡂࣉࣟࢢ࣒ࣛ㐠Ⴀጤဨ఍ጤဨ ᮅ಴Ύ㧘㹙2022/04/01㹼2024/03/31㹛‫ڦ‬㠀ᖖ໅ㅮᖌ࣭◊✲ဨ➼㈈ ྡྂᒇ⏘ᴗ⛉Ꮫ◊✲ᡤ㠀ᖖ໅ᡤဨ ୰㔝⎔㹙2021/04/01㹼2025/03/31㹛஑ᕞ኱Ꮫ࣮࢝࣎ࣥࢽ࣮ࣗࢺ࣭࢚ࣛࣝࢿࣝࢠ࣮ᅜ㝿◊✲ᡤ㝃ᒓ࢚ࢿࣝࢠ࣮ࢩࢫࢸ࣒ࢹࢨ࢖ࣥ◊✲ࢭࣥࢱ࣮㐃ᦠᩍဨ㸦◊✲ᣦᑟ⪅㸧 ΎỈ◊୍㹙2023/04/01㹼2024/03/31㹛ி 㒔 ኱ Ꮫ  ඹ ྠ ◊ ✲ ⪅  YEUNG YING YEUNG
㹙2023/07/13㹛ྡྂᒇ኱ Ꮫࢭ࣑ࢼ࣮ㅮᖌࠊ◊✲ᣦ ᑟ YEUNG YINGYEUNG㹙2023/07/14㹼2023/07/15㹛ᅜ❧◊✲㛤Ⓨἲே⏘ᴗᢏ⾡⥲ྜ◊✲ᡤㅮ₇⪅ 㛗㇂ᕝ῟ஓ㹙2023/11/17㹛኱Ꮫඹྠ฼⏝ᶵ㛵ἲே⮬↛⛉Ꮫ◊✲ᶵᵓศᏊ⛉Ꮫ◊✲ᡤࠕ௧࿴㸳ᖺᗘ;36ㅮ⩦఍ࠖㅮᖌ ୗ⏣࿘ᖹ㹙2023/07/14㹛኱ 㜰 ኱ Ꮫ  㠀 ᖖ ໅ ㅮ ᖌ  YEUNG YING YEUNG
㹙2023/07/12㹛Ꮫ ⩦ 㝔 ኱ Ꮫ  ඹ ྠ ◊ ✲ ⪅  YEUNG YING YEUNG
㹙2023/07/27㹛ᮾ ໭ ኱ Ꮫ  㠀 ᖖ ໅ ㅮ ᖌ  YEUNG YING YEUNG
㹙2023/07/28㹛ᶓ὾ᕷ❧኱Ꮫㅮᖌ Ratanasak Manussada㹙2024/01/19㹛⇃ᮏ኱Ꮫ ⏘ᴗࢼࣀ࣐ࢸࣜ࢔ࣝ◊✲ᡤㅮᖌ ᮅ಴Ύ㧘
㹙2024/03/26㹛ゐ፹ᕤᴗ༠఍ࠊゐ፹Ꮫ఍ㅮᖌ Shrotri Abhijit㹙2023/12/08㹛㸦ᅜ◊㸧≀㉁࣭ᮦᩱ◊✲ᶵᵓ㸦1,06㸧ࢼࣀ࢔࣮࢟ࢸࢡࢺࢽ
ࢡࢫᮦᩱ◊✲ࢭࣥࢱ࣮㸦:3,0$1$㸧ㅮ₇⪅ ΎỈ◊୍㹙2023/11/10㹛㸦ᅜ◊㸧⏘ᴗᢏ⾡⥲ྜ◊✲ᡤゐ፹໬Ꮫ⼥ྜ◊✲ࢭࣥࢱ࣮ࣇ
࣮ࣟ⢭ᐦྜᡂࢥࣥࢯ࣮ࢩ࢔࣒㸦)ORZ67㸧ㅮ₇⪅ 㛗㇂ᕝ῟ஓ㹙2024/02/09㹛㸦 ኱ 㸧 ி 㒔 ኱ Ꮫ 㠀ᖖ ໅ ㅮ ᖌ ὸ㔝 ᆂభ 㹙2023/06/01 㹼
2024/03/31㹛㸦 ኱ 㸧 ༓ ⴥ ኱ Ꮫ 㠀ᖖ ໅ ㅮ ᖌ ᮅ಴ Ύ㧘 㹙2023/04/01 㹼
2024/03/31㹛㸦኱㸧ྡྂᒇ኱Ꮫ㠀ᖖ໅ㅮᖌ 㛗㇂ᕝ῟ஓ㹙2023/04/11㹼
2024/03/31㹛㸦኱㸧ᮾி኱Ꮫㅮᖌ ⚟ᒸ῟㹙2023/11/24㹛㸦♫㸧ゐ፹Ꮫ఍ ᮾ᪥ᮏᨭ㒊ㅮᖌ ⚟ᒸ῟㹙2024/01/26㹛㸦 ♫ 㸧 ゐ ፹ Ꮫ ఍  ㅮ ᖌ  ⚟ ᒸ ῟ 㹙 2023/07/28 㹛࣭ ⚟ ᒸ ῟
㹙2023/09/25㹛2023ᖺᗘእ㒊㈨㔠࡞࡝‫⛉ڦ‬Ꮫ◊✲㈝ຓᡂ஦ᴗ㸦⿵ຓ㔠㸧Ꮫ⾡ኚ㠉㡿ᇦ◊✲ B 㸸 ෸ᩍᤵὸ㔝ᆂభࠕ⢾㙐ࢱࣥࣃࢡ㉁┦஫స⏝ࢆࠕࡳࡿࠖࡓࡵࡢග㥑ື࣮ࣜࣞゐ፹཯ᛂࠖ


ᖺሗ2021◊✲ᐊ⦅‫ە‬ᖺሗ࣭ಶே⦅‫ە‬ᇶ┙◊✲ A 㸸 ᩍᤵᮅ಴Ύ㧘ࠕ㉸㧗ឤᗘ඲཯ᑕ⺯ග ;$)6ࡢ㛤Ⓨ࡜⇞ᩱ㟁ụⓑ㔠ゐ፹ࡢྜ㔠ຠᯝᶵᵓࡢゎ࣭᫂ࠖᩍᤵΎỈ◊୍ࠕ࢜࣌ࣛࣥࢻศග࡟ࡼࡿάᛶ✀ࡢືⓗᣲືゎᯒࢆᇶ┙࡜ࡍࡿ㠀ᐃᖖ࣭㐃⥆ゐ፹཯ᛂࡢ㛤ᣅ࣭ࠖ෸ᩍᤵྂᕝ᳃ஓࠕከඖ⣲໬࡜⛛ᗎᵓ㐀ࡢ୧❧࡟ࡼࡿ㠉᪂ⓗྜ㔠཯ᛂሙࡢ๰ᡂࠖ
ᇶ┙◊✲ B 㸸 ᩍᤵ㛗㇂ᕝ῟ஓࠕຊᏛ่⃭⎔ቃࢆྲྀࡾᢅ
࠺⌮ㄽ໬Ꮫィ⟬ᡭἲࡢ㛤Ⓨ࡜᪂ࡋ࠸཯ᛂࢥࣥࢭࣉࢺࡢ
ᵓ⠏࣭ࠖᩍᤵ⚟ᒸ῟ࠕᅛయゐ፹࡟ࡼࡿ⤖ᬗࢭ࣮ࣝࣟࢫศ
ゎ࣭ࠖᩍᤵ㧘ⲡᮌ㐩ࠕάᛶⅬ❧యᵓ㐀࡜⾲㠃྾╔✀ࡢ࢜࣌ࣛࣥࢻ」ྜィ ࡟ࡼࡿゐ፹཯ᛂᶵᵓࡢཎᏊࣞ࣋ࣝゎ࣭᫂ࠖᩍᤵ୰ᓥΎ㝯ࠕỈ୰⢾ኚ᥮཯ᛂࡢ⮬ᅾไᚚࢆྍ⬟࡜ࡍࡿᅛయࣝ࢖ࢫ㓟ሷᇶゐ፹ࡢ㛤Ⓨ࣭ࠖᩍᤵᾆཱྀ኱㍜ࠕࣛࢪ࢝ࣝࡢ┤᥋ไᚚࢆᚿྥࡋࡓ඾ᆺඖ⣲࢝ࢳ࢜ࣥゐ፹ࡢ๰〇࣭ࠖ෸ᩍᤵὸ㔝ᆂభࠕ஧ᐁ⬟ᛶ᭷ᶵゐ፹࡟ࡼࡾ᫬✵㛫ࢆไᚚࡍࡿ㠀ᖹ⾮໬Ꮫ⣔ࡢ㛤ᣅ࣭ࠖ෸ᩍᤵ㫽ᒇᑿ㝯ࠕࢧࢫࢸࢼࣈࣝⅣ⣲㈨※ࡢ㑏ඖⓗ໬Ꮫ㈨※໬ࢆᐇ⌧ࡍ
ࡿᅛయゐ፹ࡢ㛤Ⓨࠖ‫⛉ڦ‬Ꮫ◊✲㈝ຓᡂ஦ᴗ㸦ᇶ㔠㸧ᇶ┙◊✲ C 㸸 ຓᩍ Shrotri AbhijitࠕDevelopment of mixed
oxide catalyst for carbon dioxide hydrogenation to methanol.ࠖ
ᅜ㝿ඹྠ◊✲ຍ㏿ᇶ㔠㸦ᅜ㝿ඹྠ◊✲ᙉ໬ % 㸧㸸 ෸ᩍᤵ
㫽ᒇᑿ㝯ࠕOperando ME ศග࡟❧⬮ࡋࡓᅛయゐ፹཯ᛂሙࡢタィ࡜๰ฟࠖ
ᣮᡓⓗ◊✲㸦㛤ᣅ㸧㸸 ෸ᩍᤵ㫽ᒇᑿ㝯ࠕ໬Ꮫ࡟࠾ࡅࡿእ
ᤄ᥈⣴ࢆྍ⬟࡜ࡍࡿᶵᲔᏛ⩦ᡭἲࡢ㛤Ⓨ࡜ᐇド࣭ࠖ෸ᩍᤵྂᕝ᳃ஓࠕࣉࣛࢬ࣐⛉Ꮫ࡜ከඖ⣲ྜ㔠཯ᛂሙࡢ༠ዌ
࡟ࡼࡿ㠉᪂ⓗศᏊኚ᥮ᢏ⾡ࡢ๰⏕ࠖᣮᡓⓗ◊✲㸦ⴌⱆ㸧㸸 ᩍᤵ㛗㇂ᕝ῟ஓࠕἼື㛵ᩘ⌮ㄽࢆά⏝ࡍࡿ໬Ꮫ཯ᛂ࣏ࢸࣥࢩࣕࣝ㠃ࡢ㧗⢭ᗘ໬㸸཯ᛂᗙᶆศ㞳࢔ࣉ࣮ࣟࢳࠖ
࣭ᩍᤵᾆཱྀ኱㍜ࠕⅣ⣲⤖ྜᙧᡂࡢゐ፹ไᚚ࡟ࡼࡿ࣓࢟ࣛࣝࢱࣟࢭࣥࡢ༢ẁ㝵ྜᡂࠖⱝᡭ◊✲㸸 ຓᩍ㉿ᙉࠕỈ⣲ཎᏊ⛣ື㸦HAT㸧ゐ፹࡜ࡋ࡚ാࡃ࢟ࣛࣝࣜࣥ㓟㸦Ϫ㸧ゐ፹ࡢ๰〇ࠖ≉ู◊✲ဨዡບ㈝㸸 ≉ู◊✲ဨ(PD) ⓑ⏨ᕝ㈗ྐࠕ㟁Ꮚ≧ែ⌮ㄽ࡟ᇶ࡙ࡃ⌮ㄽゐ፹タィἲࡢ㛤Ⓨ࡜㧗ᶵ⬟ศᏊ
ゐ፹タィ࣭㛤Ⓨ࡬ࡢᛂ⏝࣭ࠖ≉ู◊✲ဨ(PD) JIN GYUAN
ࠕእᤄⓗᶵᲔᏛ⩦ᡭἲ࡟ࡼࡿᮍ㋃ゐ፹ᮦᩱࡢタィ࡜๰ฟ࣭ࠖᩍᤵ ΎỈ◊୍ࠕ᥈⣴ⓗᶵᲔᏛ⩦ᡭἲࢆ⏝࠸ࡓ CO2Ỉ⣲໬ゐ፹ࡢ㛤Ⓨࠖ≉ูู◊✲ဨዡບ㈝㸦እᅜே㸧㸸 ᩍᤵ ୰ᓥΎ㝯ࠕ஧㓟໬Ⅳ⣲ࢆ฼⏝ࡋࡓ࢝ࣝ࣎࢟ࢩࣝ໬࡟ࡼࡿࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟ྜᡂ࣭ࠖᩍᤵ ΎỈ◊୍ࠕࣂࣝࢡ࣭ࢼࣀ㔠ᒓࡢ㧗ศᩓ໬⌧㇟ࡢᶵᵓゎ᫂࡜༢ཎᏊゐ፹ࡢタィ㛤Ⓨ࡬ࡢᒎ㛤࣭ࠖᩍᤵ ΎỈ◊୍ࠕእᤄⓗ᥈⣴ࡀྍ⬟࡞ᶵᲔᏛ⩦ᡭἲࢆ⏝࠸ࡓከඖ⣲ゐ፹ࡢ㛤Ⓨ࣭ࠖᩍᤵ ᮅ಴Ύ㧘ࠕ㉸㧗㏿㹖⥺྾཰ศග࡟ࡼࡿ㸯ཎᏊᒙ㓟໬≀ᢸᣢⓑ㔠ගゐ፹ࡢගບ㉳㟁Ⲵ⛣ືࢲ࢖ࢼ࣑ࢡࢫࠖNEDO ጤク◊✲㸸 ᩍᤵ ΎỈ◊୍ࠕ“ࣅࣚࣥࢻ࣭ࢮࣟ”♫࣭ᩍᤵ 㛗఍ᐇ⌧࡟ྥࡅࡓ CO2 ᚠ⎔ࢩࢫࢸ࣒ࡢ◊✲㛤Ⓨࠖ㇂ᕝ῟ஓࠕCO2 ࡢẼ┦㟁ゎ㑏ඖ࡟ࡼࡿⅣ໬Ỉ⣲⇞ᩱࡢ┤᥋ྜᡂྍ⬟࡞㟁ᴟゐ፹ࡢ◊✲㛤Ⓨ࣭ࠖ෸ᩍᤵ Ⳣ἟Ꮫྐࠕ࢔࣑ࣀ㓟࠿ࡽ࣏ࣜ࢔࣑ࢻ࣭࣏࢚ࣜࢫࢸࣝࢆ〇㐀ࡍࡿࡓࡵࡢᅛయゐ፹ࢩࢫࢸ࣒ࡢ㛤Ⓨ࣭ࠖ෸ᩍᤵ 㫽ᒇᑿ㝯ࠕCO2
࡜ H2 ࠿ࡽࡢ㧗௜ຍ౯್໬Ꮫရྜᡂ࡟㛵ࡍࡿඛᑟⓗ◊✲࣭ࠖ෸ᩍᤵ 㫽ᒇᑿ㝯ࠕCO2 ࡜ H2 ࠿ࡽࡢప ࣓ࢱࣀ࣮ࣝ
ྜᡂ࡟㛵ࡍࡿ◊✲㛤Ⓨ࣭ࠖ෸ᩍᤵ 㫽ᒇᑿ㝯ࠕ࣓ࢱࣥ⇞↝⏝ᅛయゐ፹ࡢ㛤Ⓨ࣭ࠖ෸ᩍᤵ ྂᕝ᳃ஓࠕྜ㔠཯ᛂሙタィ࡟ᇶ࡙ࡃ㉸㧗⪏ஂ࢔ࣝ࢝ࣥ⬺Ỉ⣲ゐ፹ࢩࢫࢸ࣒ࡢ㛤Ⓨࠖ
NEDO ጤク◊✲㸦෌ጤク㸧㸸 ෸ᩍᤵ㣤⏣೺஧ࠕ㹼㸯㸫㹬㹫ⓑ㔠⣔ゐ፹ࡢᵓ㐀࣭⤌ᡂไᚚ࡟ᇶ࡙ࡃ㹎㹃㹄㹁࢝ࢯ࣮ࢻゐ፹ࡢ㧗άᛶ໬ࠖ㸦ࡑࡢ௚㸧㸸 ᩍᤵ୰㔝⎔ࠕ໭ᾏ㐨኱Ꮫᶵᵓ◊✲᥎㐍ࣘࢽࢵࢺ࡟࠾ࡅࡿ◊✲᥎㐍ࠖ‫ڦ‬Ẹ㛫➼࡜ࡢඹྠ◊✲ᩍᤵ ΎỈ◊୍㸦2 ௳㸧࣭ᩍᤵ ୰ᓥΎ㝯㸦4 ௳㸧࣭ᩍᤵ ୰㔝
⎔㸦1 ௳㸧࣭ᩍᤵ ⚟ᒸ῟㸦2 ௳㸧࣭෸ᩍᤵ 㣤⏣೺஧㸦1 ௳㸧࣭෸ᩍᤵ 㫽ᒇᑿ㝯㸦5 ௳㸧࣭෸ᩍᤵ ྂᕝ᳃ஓ㸦6 ௳㸧‫ڦ‬Ꮫ⾡ࢥࣥࢧࣝࢸ࢕ࣥࢢ
ᩍᤵ㛗㇂ᕝ῟ஓ㸦1 ௳㸧‫ཷڦ‬ク◊✲JST ጤク◊✲㸸 ᩍᤵ 㧘ⲡᮌ㐩ࠕゐ፹㛤Ⓨ࡜ཎᏊࣞ࣋ࣝ
ᵓ㐀ゎᯒ࡟ࡼࡿ཯ᛂᶵᵓゎ࣭᫂ࠖᩍᤵ ୰ᓥΎ㝯ࠕࣃ࣮࣒ṧ´≀࠿ࡽࡢ໬Ꮫရ࣭ࣂ࢖࢜⇞ᩱ〇㐀ࢆྍ⬟࡟ࡍࡿᅛయ
ゐ፹ࣉࣟࢭࢫࡢ㛤Ⓨ࣭ࠖᩍᤵ ୰ᓥΎ㝯ࠕHMF ࢔ࢭࢱ࣮ࣝ
ࢆ⤒⏤ࡋࡓࢢࣝࢥ࣮ࢫ࠿ࡽࡢࣇࣛࣥࢪ࢝ࣝ࣎ࣥ㓟࢚ࢫࢸࣝయྜᡂࠖ
࣭෸ᩍᤵ 㫽ᒇᑿ㝯ࠕእᤄⓗ᥈⣴ࡀྍ⬟࡞ᶵᲔᏛ⩦ࢆ⏝࠸ࡓᮍ㋃ゐ፹✵㛫ࡢ᥈⣴࣭ࠖ෸ᩍᤵ ྂᕝ᳃ஓ
ࠕCO2 ࢆ฼⏝ࡋࡓࣉࣟࣃࣥ㓟໬⬺Ỉ⣲࡟᭷ຠ࡞ከඖ⣲ྜ㔠ゐ፹ࡢ㛤Ⓨࠖᖺሗ ࣭ಶே⦅‫ە‬

83ዻᨼࢸᚡᴾ
editorial note and colophonᴾ
⦅㞟ᚋグ

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2023ᖺᗘࡢゐ፹⛉Ꮫ◊✲ᡤᖺሗࡀ⧳ࡲࡾࡲࡋࡓ㸬◊✲ᡤ㸪㒊㛛㸪ࢡࣛࢫࢱ࣮㸪ࣘࢽࢵࢺ㸪ᢏ⾡㒊㸪◊✲⪅ಶே࡜ࡋ࡚ࡢ◊✲㸪ᩍ⫱㸪Ꮫ⾡᣺⯆㸪⏘ᴗ᣺⯆࡬ࡢ㈉⊩ࡢ㞟኱ᡂ࡛ࡍ㸬ࡇࢀࡣࡦ࡜࠼࡟ஂಖ⏣ள⨾Ặ㸪ᚋ⸨ឡẶࡢࡈᑾຊ࡟
ࡼࡿ࡜ࡇࢁࡀ኱࡛࠶ࡾ㸪῝ࡃឤㅰࡋࡲࡍ㸬ᖺᗘᮎ࠿ࡽᖺᗘጞࡵ࡟࠿ࡅ࡚ࡣ㸪ྛ✀ሗ࿌᭩ࡢ࢜ࣥࣃࣞ
࣮ࢻ࡛ࡍ㸬⚾ࡢሙྜ࡛ࡍࡀ㸪ሗ࿌᭩సᡂࡢ㝿ࡣ࠸࠿࡟ຠ⋡ⓗ࡟సᴗࡍࡿ࠿࡟ὀពࡀྥࡁࡲࡍ㸬ࡓࡔ㸪ᙜヱᖺᗘࡢ᭱ึ
ࡢሗ࿌᭩ࡢཎ✏ࢆ᭩ࡃ࡜ࡁࡔࡅࡣ㸪⮬ศࡢ௙஦ࡪࡾࢆ᣺ࡾ
㏉ࡾ཯┬࣮ࣔࢻ࡟࡞ࡾࡲࡍ㸬௒ᖺᗘࡣ◊✲ᡤᖺሗࡀࢺࢵࣉ
ࣂࢵࢱ࣮࡛ࡋࡓ㸬౛እ࡞ࡃ㸪௒ᖺᗘࡶ෭ࡸờࢆ࠿ࡁ࡞ࡀࡽ
ᇳ➹ࡋࡲࡋࡓࡀ㸪኱ᬉ᪥ࡢᚰᆅ࡛㸪ᛶᠬࡾࡶ࡞ࡃ᪂ᖺᗘࡢ
㣕㌍ࢆㄋࡗࡓ࡜ࡇࢁ࡛ࡍ㸬ࡉ࡚㸪௒ᖺᗘࡣ㸪ᮅ಴ඛ⏕㸪⚟ᒸඛ⏕ࡢᚚ㏥⫋ࡢᖺ࡛ࡋࡓ㸬ゐ፹໬Ꮫ◊✲ࢭࣥࢱ࣮ࡢᒇྎ㦵࡜࡞ࡗ࡚㸪㝧࡟㝜࡟ࡈᑾຊ࠸ࡓࡔࡁ㸪ゐ፹⛉Ꮫ◊✲ᡤ࡬ࡢ᪼᱁ࢆ㐩ᡂࡋ㸪ࡑࡢ㐠Ⴀࢆ㌶㐨࡟஌ࡏࡿ኱௙஦ࢆᡂࡋ㐙ࡆࡽࢀࡓ࠾஧ேࡢ㏥⫋
ࡣ㇟ᚩⓗ࡞࢖࣋ࣥࢺ࡛ࡋࡓ㸬◊✲ᡤ㐠Ⴀࡢࣂࢺࣥࢆᡃࠎୡ
௦ࡀᘬࡁ⥅࠸ࡔࢃࡅ࡛ࡍࡀ㸪࠸࠿࡟ඃࢀࡓ◊✲ᡂᯝ࡜㸪◊✲ᡤࡢᏑᅾឤࢆⓎಙࡋ⥆ࡅࡿࡇ࡜ࡀ࡛ࡁࡿ࠿㸪㌟ࡀᘬࡁ⥾ࡲࡿᛮ࠸࡛ࡍ㸬2024ᖺࡣ⬟Ⓩ༙ᓥᆅ㟈࠿ࡽጞࡲࡾࡲࡋࡓ㸬⚾ࡢᨾ㒓ࡣ㟈※ᆅࡢ⌔Ὢᕷ࡛ࡍࡀ㸪Ⓨ⅏ᚋ⣙㸱࢝᭶ࡍࡂ࡚ᖐ┬ࡍࡿᚲせࡀ⏕ࡌࡲࡋࡓ㸬㦫࠸ࡓࡢࡣ㸪㌺୪ࡳಽቯࡋࡓᐙᒇࡢ᧔ཤࡣ
඲ࡃ㐍ࢇ࡛࠾ࡽࡎ㸪ࡲࡓ㸪᧔ཤࡍࡿᵝᏊࡶ࡞࠸ࡇ࡜࡛ࡍ㸬ࡀࢀࡁ᧔ཤ࡟ᚑ஦࡛ࡁࡿே㊊ࡀ࠸࡞࠸࡜ࡢࡇ࡜࡛ࡍ㸬ᩥᏐ
㏻ࡾேᡭࡀ࡞࠸࡜࠸࠺✲ᴟⓗ࠿ࡘ㇟ᚩⓗ࡞≧ἣࢆ┠ࡢᙜࡓࡾ࡟ࡋࡓヂ࡛ࡍࡀ㸪ࡇࡢ≧ἣࡣ⿕⅏ᆅ࡟㝈ࡽࡎ㸪ྛᡤ࡛
ࡶྠᵝࡢ஦㇟ࡀ㐍⾜ࡋࡘࡘ࠶ࡿࡇ࡜ࡣ㸪ࢽ࣮ࣗࢫ➼࡛ሗ㐨ࡉࢀ࡚࠸ࡲࡍ㸬◊✲⌧ሙ࡟࠾࠸࡚ࡶ౛እ࡛ࡣ࡞࠸࡛ࡋࡻ
࠺㸬◊✲ࡢᢸ࠸ᡭࡀ₞ῶࡋ㸪ࡲࡍࡲࡍୡ⏺ⓗ➇தࡀཝࡋࡃ
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ᡂAIࢆ౑ࡗ࡚ሗ࿌᭩ࡢᵝᘧ࡟ྜࢃࡏ࡚࠸ࡲࡍ㸬᭱ึ࡟᭩࠸
ࡓཎ✏ࢆ㐺ᙜ࡞ᩥᏐᩘ࡟せ⣙ࡍࡿ┠ⓗ࡛౑⏝ࡋࡲࡋࡓ㸬ࡲࡔ㸪HIࡀᚲせ࡛ࡋࡓࡀ⏕ᡂAIࡣ࠿࡞ࡾࢱ࢖ࣃࡀⰋ࠸࡜ឤ
ࡌࡲࡋࡓ㸬⧞ࡾ㏉ࡋ࡟࡞ࡾࡲࡍࡀ㸪ࡇࡢᖺሗࡣゐ፹◊ࡢ࢔ࢡࢸ࢕ࣅ
ࢸ࢕ࡢ㞟኱ᡂ࡛࠶ࡾ㸪ᙧᘧⓗ࡞ሗ࿌᭩࡜ࡋ࡚ࡢᙺᅇࡾ࡟⤊ጞࡍࡿࡢࡣࡶࡗࡓ࠸࡞࠸࡜ឤࡌ࡚࠸ࡲࡍ㸬ᖺሗࢆ㉳Ⅼ࡜ࡋ࡚᪂ࡓ࡞ᶵ఍๰ฟ࡟ࡘ࡞ࡀࡿࡓࡵࡢ࢔࢖ࢹ࢔ࡣ࡞࠸ࡶࡢ
࡛ࡋࡻ࠺࠿㸬
㸦2024ᖺ4᭶࣭㛗㇂ᕝ῟ஓ㸧᭩ㄅ᝟ሗࠕᖺሗ2023ࠖ໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤᖺሗ2023
ISSN㸸2432-7018Ⓨ⾜᪥㸸 2024ᖺ8᭶Ⓨ⾜⦅㞟㸸໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ➨୍ᖖ⨨ጤဨ఍㸦ᅗ᭩ฟ∧㛵ಀ㸧࣭໭ᾏ㐨኱Ꮫ໭࢟ࣕࣥࣃࢫྜྠ஦ົ㒊⦅㞟㈐௵⪅㸸㛗㇂ᕝ῟ஓ㸦ゐ፹⛉Ꮫ◊✲ᡤᩍᤵ/2024ᖺᗘゐ፹⛉Ꮫ◊✲ᡤ➨୍ᖖ⨨ጤဨ఍ጤဨ㛗㸧Ⓨ⾜⪅㸸໭ᾏ㐨኱Ꮫゐ፹⛉Ꮫ◊✲ᡤ
㸦001-0021 ᮐᖠᕷ໭༊໭21᮲す10୎┠/㟁ヰ㸸011-7069302/ ࣇ ࢓ ࢡ ࢩ ࣑ ࣜ 㸸 011-706-9110/ 㟁 Ꮚ ࣓ ࣮ ࣝ 㸸 kshomu@jimu.hokudai.ac.jp㸧Institute for Catalysis, Hokkaido
University, Sapporo 001-0021, Japan༳ๅ㸸ᰴᘧ఍♫ࣉࣜࣥࢺࣃࢵࢡ㸦617-0003 ி㒔ᗓྥ᪥ᕷ᳃
ᮏ⏫㔝⏣ 3-1/㟁ヰ㸸0120-977-920㸧

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ᖺሗ࣭⦅㞟ᚋグ᭩ㄅ᝟ሗ‫ە‬