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Safety Data Sheet
1. Products and company identification
Product name:SUISEI ROVAL Part A: Powder

Recommended use:

Anti-corrosion of steel/iron.

Supplier:

Roval Corporation
6-41-1, Ikuno, Katano
Osaka, 5760054, Japan+81-72-892-7791

Emergency phone number:+81-72-892-9955

Date Revised:

March 5, 2018

2. Hazards identification
PHYSICAL HAZARDS:

Spontaneous-ignitable solid:

Not classified

Water-reactive flammable chemical:

Not classified

HEALTH HAZARDS:
Acute Toxicity

Oral:

Not Classified

Dermal:Not Classified

Inhalation (Dust/Mist)

Not ClassifiedSkin Corrosion/Irritation:

Not Classified

Eye Effects/Serious eye damage/Eye irritation:

Category 2

Skin sensitizer:

Not Classified

Reproductive Toxicity:

Category 2

TOST: Single Exposure:

Category 2 (systemic toxicity)

Repeated Exposure:

Not classified

Acute Aquatic Toxicity:

Category 1 (powder)

Chronic Aquatic Toxicity:

Category 1 (powder)

Hazard to Ozone:

Classification not possible*Item without description of classification means “classification not possible” or “not classified”.

SymbolSignal Word
Hazard Statement:：： Warning-Causes serious eye irritation-Suspected of damaging fertility or the unborn child-May causes damage to organs-Very toxic to aquatic life with long lasing effects

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Precautionary Statements:[PREVENTION]-Obtain special instruction before use-Do not handle until all safety precautions have been read and understood-Do not inhale dust
-Wash hands thoroughly after handling-Do not eat, drink or smoke when using this product-Avoid release to the environment-Wear protective gloves/protective clothing/eye protection/face protection[FIRST AID]-IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present
and easy to do. Continue rinsing.
-IF EXPOSED (or possible): Get medical attention.
-If eye irritation persists: Get medical advice/attention.
-Recover the leakage.
[STORAGE]-Keep locked up.
[DISPOSAL]-Follow the regulations of your country when disposing of the container.

3. Composition/information on ingredients
Ingredient Name%

CAS No.

EINECS No.

UN No.

Zinc

93 ~ 98

7440-66-6

231-175-3

1436

Zinc Oxide<5.01314-13-2

215-222-53077

4. First-aid measures
Inhalation:

Slight irritation on upper air passage. Let him/her gargle. Keep rest in fresh air incase of metal fume fever. Get medical attention.

Skin contact:

Rinse with water and soap.

Eye contact:

Gently rinse the affected eyes with clean water for at least 15 minutes lifting upperand lower eyelids occasionally. Remove contact lenses if present and easy to do. Get
immediate medical attention.

Ingestion:

Rinse his/her mouth with water and let him/her vomit. Keep rest in fresh air in case ofzinc chill. Get medical attention.

Symptom expected: Irritation of eye, skin, or respiratory system / headache / chill / boke / diarrhea /languor / metal fume feverProtection for whom does first-aid: Wear appropriate protective equipment.
Special advise to doctor: Metal fume fever may appear in a couple of hours.
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5. Firefighting measures
Extinguishing Media
Unsuitable Extinguishing Media
Unique hazard
Protection for fire-fighter：Powder extinguisher, dry sand：Water (react with zinc and cause gassing): May cause zinc fume by fire: Wear aspirated protective equipment

6. Accidental release measures
Personal precautions:
Use the necessary personal protective equipment (gloves, masks, aprons, and goggles) andavoid contact to eye and skin and inhalation of dust and fume.
Environmental precautions:
Be careful not to affect environment by releasing the product to waterway.
Recovery and neutralization:
Avoid further leakage and contain properly. After containing the leakage into closed container
by broom, shovel, or vacuum, dispose of it in accordance with local regulation. Operate acountermeasure properly in case of the leakage to the environment.
Equipment and method for containment and cleaning-up:
Not regulated but recommended to remove by boring.
Measure against second accident:
Avoid leakage to drain, sewer, basement, or closed area.

7. Handling and Storage[HANDLING]
Technical Precautions ：Install the equipment in accordance with Section 8． Operator must wear protective
equipment.
Ventilation : Local ventilation and entire ventilation necessary.
Handling Precautions :Do not damage the container. Do not swallow or inhale. Avoid direct contact with eyes. Do
not inhale dust or fume. Avoid contact with water or moisture as zinc reacts with water.
Wash hands after handling. Use only outside or ventilated area. Do not eat or smoke
when handling the product.
Contact Avoidance : Refer to Section 10.
[STORAGE]
Technical Precautions ： Store in a closed area. Avoid contact with moisture.
Contact Hazard : Refer to Section 10.
Storage Condition : Avoid direct sunshine. Avoid contact with water.
Container : Closed container without damage.
8. Exposure controls/ Personal protection
Substance

Controlled concentration

ACGIH TLV(2016)

ZincN/AN/A

Zinc Oxide

N/A

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[Equipment]
Install eye washer and shower for safety. Ventilate to keep dust concentration under the exposurelimit.
[Protection]
Respiration protection: Wear proper protective equipment.
Eye protection: Wear proper protective equipment.
Skin and body protection: Wear proper protective gloves and clothes.

9. Physical and Chemical Properties
Physical State:

Solid powder

Color:

GrayOdor:

Odorless

Density (g/ml):

7.1 (20˚C)

Flash Point:>110˚C

Explosion Limits(vol%):

Vapor Pressure:

N/A

Auto-ignition Temp:

Boiling Point:907˚C

Upper: N/ALower: 480g/m3600˚C

10. Stability and Reactivity
Stability:

Generate oxide by reaction with moisture. Generate gas by reaction
with water. Stable in room temperature. Soluble in acid and alkalihydroxide. Generate hydrogen in case of the reaction with large
amount of acid or alkali hydroxide.

Conditions to avoid:
PossibilityofContact with reactive chemical hazards. Moisture, fire, impact.
Hazardous

Reactions:

No possibility of auto-ignition, but generates hydrogen gas by thereaction with water and heat, which may cause the fire in somecondition.

Reactive chemical hazards:

Halogenated hydrocarbon, alkali hydroxide, amine, sulfur, strongoxidation, and strong base.

Hazardous

decomposition

May generate harmful fume by high-heat.

Products:

11. Toxicological information[ACUTE TOXICITY]
Substance

Oral

Class

Zinc

>2.0g/kg

Not classified

Zinc Oxide>5.0g/kg

Not classified

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DermalClassClassification not possible>5.0g/kg

Not classified

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[ACUTE TOXICITY]
Substance
Zinc
Zinc Oxide

Inhalation
Class(gas)Out of classification
Out of classification

Inhalation
Class(vapor)
Classification not possible
Out of classification

Substance

Skin
Corrosion/irritation

Eyedamage/irritation

Zinc

Not classified

Category 2B

Zinc Oxide

Not classified

Not classified

Substance

Carcinogenicity

ZincClassification
not possible

Zinc Oxide

Classification
not possible

Reproductive
Toxicity
Classification
not possible

Category 2

Respiratory
Sensitization
Classification
not possible
Classification
not possible
TOST(single)
Classification
not possible
Category 1(Respiratory organ,systemic toxicity)

Inhalation(dust/mist)>5.41mg/L>5.7mg/L
Skin
sensitization
Not classified
Not classifiedClass
Not classified
Not classified
Germ cellmutagenicityClassification
not possible
Classification
not possible

TOST(repeated)
Classification
not possible

Aspiration
hazardClassification
not possible

Classification
not possible

Classification
not possible

12. Ecological Information
General Precaution: Be careful not to spill or leak product and wash water into river and waterdrain. The product may have adverse effect on environment.
Ecological Toxicity:
Material

Acute Aquatic Toxicity

Chronic Aquatic Toxicity

Hazard to Ozone

Zinc

Category 1

Category 1

Classification not possible

Zinc oxide

Category 1

Category 1

Classification not possible

13. Disposal considerations
Store recovered material in appropriate container and dispose according to your local
environmental regulations．
14. Transport information[Regulation] UN No.: 1436

UN Class: 4.3 (Flammable solid)

PG: III

Sea Transport Regulation: Follow IMO
Air Transport Regulation: Follow ICAO/IATA
Proper Shipping Name: Zinc powder

15. Regulatory Information
Classification and labeling in accordance with Labor Safety and Health Act:See Section 2
Other regulation for foreign countries:
Regulatory information with regards to this preparation in your country or region should be
examined by your own responsibility.
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16. Other Information
References:
1) GHS Classification Guidance for Enterprises. (United Nations 2009)2) SDS from manufacturers of raw materials3) Roval’s own data
The information herein is given in good faith, but no warranty, express or implied, is made.
The information contained herein is, to the best of Roval’s knowledge and belief, accurate and reliable
as of the data issued. It is the user’s responsibility to determine the suitability of this information for
the adoption of necessary safety precautions. We reserve the right to revise SDS periodically as new
information becomes available.

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