Safety Data Sheet[Mixture (Paint)]
１． Products and company identification
Product nameSupplier
Address
Section in charge
Phone number
Fax number
e-mail address
Emergency Phone Number
Preparation, revision, and confirmation
Product type
Recommended use

ROVAL SILVER ECOTYPE
Roval Corporation
6-41-1, Ikuno, Katano, Osaka
Technical service department
072-892-7791
072-892-6391
jp-info@roval-group.com
072-892-9955
Feb. 8, 2021
One-component organic zincrich paint (high-concentration zinc dust paint)
Anti-corrosion of steel/iron

２． HAZARDS IDENTIFICATION[GHS Classification]
PHYSICAL

Flammable Liquid

Category 2

HAZARDSHEALTH HAZARDS
Acute toxicity

TOSTOralDermal

Inhalation (Gas)

Inhalation (Vapors)

Inhalation (Dust/Mist)

Not classified

Not classified

Classification not possible

Classification not possible

Not classified

Skin Corrosion/

Serious eye

Respiratory sensitisation

Respiratory sensitisation

Skin sensitisation

Irritation

damage/ irritation(Solid/Liquid)(Gas)

Not classified

Category 2

Classification not possible

Classification not possible

Germ Cell Mutagenicity

Carcinogenicity

Reproductive toxicity

Effects on or via lactation

Classification not possible

Classification not possibleClassification not possible

Classification not possible

Category 1―――(Single exposure)
TOST(Repeated exposure)
Aspiration hazard
Classification not possible

Category 1

Category 2

Category 3

respiratory system ,systemic toxicity―――

Not classified

Category 2―――

respiratory system

Hazardous to the aquatic environment

Hazardous to the aquatic environment(Acute)(Chronic)

Category 1

Category 1

Hazardous to the ozone layer
Classification not possible[GHS Symbols]
Pictogram

Signal word

DANGER

Hazard statement
・Highly flammable liquids and vapors ・Intense eye irritation ・May cause damage to organs
・Very strong toxicity to aquatic organisms ・Very strong toxicity to aquatic organisms due to long-term continuous effects
・Causes damage to organs through prolonged or repeated exposure
Precautionary Statement:
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[SAFETY MEASURES]
・Obtain special instruction before use.
・Do not handle until all safety precautions have been read and understood.
・Keeping away from ignition sources, such as heat/sparks/open flames/ hot surfaces. No smoking.
・Keep container tightly closed.
・Ground container and receiving equipment.
・Use explosion-proof electrical/ventilating/light/equipment.
・Use non-sparking tools.
・Take precautionary measures against static discharge.
・Wash hands thoroughly after handling.
・Avoid release to the environment.
・Wear protective gloves/protective clothing/eye protection/face protection.
[FIRST AID]・IF ON SKIN or HAIR: Remove all contaminated clothing immediately Rinse skin with water/shower.
・IF IN EYES: Rinse cautiously with water for several minutes.
If the contact lens is attached and can be easily removed, remove it. Continue rinsing.
・If eye irritation persists: Get medical advice/attention.
・In case of fire: Use carbon dioxide, foam, powder, dry sand, or atomized reinforcing liquid to extinguish the fire.
・Collect spillage.
[STORAGE]
・Store in well-ventilated place. Place in a cool place.
[DISPOSAL]・Appropriately dispose of the contents/containers in accordance with laws and regulations.
３． Composition/information on ingredients
Substance/Mixture: Mixtures
General product description: Paint
Substance name
Aluminum
Zinc
Zinc oxide
Mixed organic compounds

IngredientCAS No.

1~545 ~ 50
1~535 ~ 40

7429-90-5
7440-66-6
1314-13-2
Non-disclosure

４． First-aid measures
Inhaled:If you feel ill after breathing in steam or gas, remove to fresh air and rest in a respirable position. Seek medical attention if
symptoms persist or if unconscious.
Skin contact :Remove all contaminated clothing. Wash the affected area with plenty of water with mild soap. Do not use solvents or thinners. If
irritation is continued, refer to medical attention. Remove all contaminated clothing.
Eye contact:
Gently rinse the affected eyes with clean water for at least 15 minutes lifting upper and lower eyelids occasionally. Remove
contact lenses, if present and easy to do. Do not induce vomiting.
Swallowed:
Get immediate medical advice/attention. Do not induce vomiting.
Emergency measures:
Wear proper protective equipment. Keep ventilation.

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５． Fire-fighting measures
Extinguishing media:
Carbon dioxide, foam, powder, dry sand, and atomized reinforcing liquid
Fire extinguishing agents not to be used:
Water (rod-shaped water, high-pressure water)/rod-shaped reinforcing liquid
Special methods for extinguishing fires, protection of persons who extinguish fires:
Wear proper protective equipment.
Remove sources of ignition.Use specified extinguishing media.
Cool closed containers which may be exposed to heat. Extinguish from windward side.
６． Accidental release measures
Precautions for the Human Body, Protective Equipment, and Emergency Measures:
Use the necessary personal protective equipment when handling. Ventilating firmly indoors. In outdoor cases, working from thewindward. Prevent secondary disasters by prohibiting access to the surrounding area and keeping other people away. Avoidsparks, flames and anything which can cause fire.
Prepare extinguishing media for accidental fire.
Environmental precautions:
Be careful not to cause environmental effects due to discharge into rivers, etc.
Containment and Purification Methods and Equipment:
For small spill, absorb spills with inert materials, then place in a chemical waste containers. Disposal of deposits, waste, etc. shallbe made in accordance with relevant laws and regulations. Collect by using a tool made of a material that does not generate
sparks due to impact or static electricity. Absorb in dry sand, soil, or other non-combustible materials for recovery. A large amountof leakage is prevented by surrounding with embankment.
７． Handling and storage
Handling:
Handle in a well-ventilated place. The container is sealed each time. Keep away any source of flame, sparks, and heat.
Wear antistatic cloths and shoes. Use sparkless equipment.
For countermeasures against static electricity, the equipment, etc. shall be grounded, and explosion-proof type shall be used forthe electrical equipment, etc.
Soak used wiping cloths, paint film, and spray dust in water until disposal.
Handle in a well-ventilated area. Wear personal protective cloths.
Wear protective equipment to keep skin, mucous membranes, or clothing from touching or coming into the eyes.
Wash hands and face completely after the handling.
Storage:
Avoid direct sunlight. Store in a dry, well-ventilated area. Keep locked to prevent theft.
Keep out of reach of children. Keep containers away from fire/flame.
８． Exposure controls/Personal protection
Substance name

Exposure limits
ACGIH (FY2016)

AluminumZinc

1 mg /㎥(TWA)―Zinc oxide

2 mg /㎥(TWA)

Mixed organic compounds―[Equipment Measures]
Use air extractors to prevent fume formation. Use air extractors to prevent fume formation.
Use electrical grounding equipment to transport/pump/stir the liquid.
Equipment shall be installed in the vicinity of the handling site so as not to be subject to high temperatures or ignition sources.
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In indoor painting operation, equipment which can ensure that workers are not exposed directly, such as the automatic spraying
machine or local exhaust facilities, should be installed.
When working in a sealed place such as the inside of a tank, install a device that can sufficiently ventilate to the bottom of thesealed place.
[Protection]
Respiratory protective equipment :Wear gas masks for organic gases. In cases of inadequate ventilation, a respiratory protective device should be worn toprevent overexposure.
Hand protectors:
Wear gloves made of a material that is impermeable to organic solvents or chemicals.
Eye protection:
Wear protective glasses for handling.
Skin and body protection:
When handling, wear clothing that does not expose the skin directly. It is best to wear the clothing made of a material thatcan prevent the penetration of chemical reagents.
Other:
When performing electrostatic painting work, wear shoes that are energized.
９． Physical and Chemical Properties
Physical State:LiquidOdor:Solvent odor
Flash point:22.0℃
Auto-ignition temp
: ≥ 200℃
Explosion Limits: LEL 1. 0 vol %Physical property (color)
Densities (g/ml)
Vapor pressure
Boiling point
UEL 7.6 vol %:Silver:1.60:266Pa(20℃):105℃

１０． Stability and Reactivity
Stability:
Stable in normal handling.
Conditions to avoid:
Heating, high temperature, contact with incompatible hazardous materials.
Forming of mixture with atmosphere within flammable limit.
Incompatible materials: May react with oxidizers.
Hazardous decomposition products:
Thermal decomposition produces carbon monoxide and carbon dioxide. Generate stimulant gas.
１１． Toxicological information
ACUTE TOXICITY
Substance name
Oral
Aluminum
Zinc
Zinc oxide
Mixed organic compounds

Classification

DermalClassification not possible
Not classified> 2.0 g / kg
Not classified> 5.0 g / kg
Category 5

Classification

Classification not possible
Classification not possible
Not classified> 5.0 g / kg
Classification not possible

ACUTE TOXICITY
Substance name
Aluminum
ZincZinc oxide
Mixed organic compounds

C-303-056-SDS(E)-SecoInhalation(Gas)

Classification

Not applicableNot applicableNot applicable
Classification not possible

Inhalation(Vapors)

Classification

Not applicable
Classification not possible

Not applicable
Classification not possible

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Inhalation(Dust/Mist)

Classification

Classification not possible> 5.41 mg / L> 5.7 mg / L

Not classified
Not classified

Classification not possible

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Substance name

Skin corrosion/irritantAluminumClassification not possible

Zinc
Zinc oxide

Not classified
Not classified
Category 2

Mixed organic compounds

Serious eye
damage/eye irritant
Classification notpossible

Category 2B
Not classified
Category 2B

Respiratory
sensitisation

Skin sensitisation

Classification not possible

Classification not possible

Classification not possible
Classification not possible

Not classified
Not classified

Classification not possible

Classification not possible

Substance nameGerm Cell Mutagenicity

Carcinogenicity

Reproductive toxicity

Aluminum
Zinc
Zinc oxide

Classification not possible
Classification not possible
Classification not possible
Classification not possible

Classification not possible
Classification not possible
Classification not possible
Classification not possible

Classification not possible
Classification not possible
Category 2
Classification not possible

Substance nameTOST (Single)

TOST (Repeat)

Aspiration hazard

Aluminum
Zinc

Category 1 (Respiratorys)
Classification not possible
Category 1

Category 1 (Respiratorys)
Classification not possible

Classification not possible
Classification not possible

Classification not possible

Classification not possible

Classification not possible

Category 1

Mixed organic compounds

Zinc oxide
Mixed organic compounds(respiratory, systemic toxicity)

Category 3(anesthetic effect, respiratory tract irritation)

１２． Ecological information
General Precautions:Handle the product carefully in case of leakage, disposal, etc., as this may affect the environment.
The product may have adverse effect on environment.
Ecotoxicity
Substance name
Acute Aquatic Toxicity
Chronic Aquatic Toxicity
Hazardous to the ozone layer
Aluminum
Zinc
Zinc oxide

Classification not possible
Category 1
Category 1
Mixed organic compounds
Category 2
Persistence and degradability:
No rapid degradability (metal compound) <zinc>

Classification not possible
Category 1
Category 1
Classification not possible

Classification not possible
Classification not possible
Classification not possible
Classification not possible

１３． Disposal considerations[Residual Waste, Contamination Containers and Packaging]
In the case of disposal, the relevant laws and regulations and the standards of local governments shall be complied with. Waste
including residue and container should be disposed by licensed industrial waste disposer after the consignment contract. Wash waterused for cleansing containers and equipment must not be released into environment. For other wastage arouse in effluent processing
or incineration, dispose of them in accordance with the law or entrust it. Dispose of the empty container after the rest of paintcompletely removed. It is recommended to recycle empty containers and packaging.
Dispose of the empty container after the rest of paint completely removed. Empty container should be disposed of by industrial
waste disposal contractor after the consignment contract.

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１４． Transport information[Regulations:]
UN No. 1263
UN Classification: 3
PG: II
Transport:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is no leaking in the container, and load. Prevent collapse of the container so that there is no falling ordamage.
Land transport:
Pursuant to the Fire Defense Law, the Industrial Safety and Health Law, and other transportation methods stipulated in therelevant laws. The consignor shall issue the Carriage Precautions (Yellow Card) to the Carrier.
Maritime transportation:
In accordance with the Ship Safety Law.
Air Transportation:
In accordance with the provisions of the Aeronautical Law.
Safety measures:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is no leaking in the container, and load. Prevent collapse of the container so that there is no falling ordamage.
１５． Regulatory information
Classification and labeling in accordance with Labor Safety and Health Act:See Section 2
Other regulation for foreign countries:
Regulatory information with regards to this preparation in your country or region should be examined by your own
responsibility.
１６． Other information
References:
1) GHS Classification Guidance for Enterprises.
2) SDS from manufacturers of raw materials3) Roval’s own data
The information herein is given in good faith, but no warranty, express or implied, is made.
The information contained herein is, to the best of Roval’s knowledge and belief, accurate and reliable as of the data issued. It is theuser’s responsibility to determine the suitability of this information for the adoption of necessary safety precautions. We reserve theright to revise SDS periodically as new information becomes available.

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