Safety Data Sheet[Mixture (Paint)]
１． Products and company identification
Product nameSupplier
Address
Section in charge
Phone number
Fax number
Emergency Phone Number
Preparation, revision, and confirmation
Product type
Recommended use

ECO SERIES THINNER
Roval Corporation
6-41-1, Ikuno, Katano, Osaka
Technical service department
072-892-7791
072-892-6391
072-892-9955
Feb. 8, 2021
zincrich paint thinner
Dilution of paint/Cleaning of paint equipment

２． HAZARDS IDENTIFICATION[GHS Classification]
PHYSICAL

Flammable Liquid

Category 2

HAZARDSHEALTH HAZARDS
Acute toxicity

TOST

Oral

DermalInhalation (Gas)

Inhalation (Vapors)

Inhalation (Dust/Mist)

Category 5

Classification not possible

Classification not possible

Classification not possible

Classification not possible

Skin Corrosion/

Serious eye

Respiratory sensitisation

Respiratory sensitisation

Skin sensitisation

Irritation

damage/ irritation(Solid/Liquid)(Gas)

Category 2

Category 2B

Classification not possible

Classification not possible

Germ Cell Mutagenicity

Carcinogenicity

Reproductive toxicity

Effects on or via lactation

Classification not possible

Classification not possible

Classification not possible

Classification not possible

Category 1――――(Single exposure)
TOST

Category 2

Category 1(Repeated exposure)
Aspiration hazard
Category 1

Classification not possible

Category 3――――

Anesthetic effect, respiratory tract irritation

Category 2
――――

――――

Hazardous to the aquatic environment

Hazardous to the aquatic environment(Acute)(Chronic)

Category 2

Classification not possible

Hazardous to the ozone layer
Classification not possible[GHS Symbols]
Pictogram

Signal word
HAZARD
Hazard statement:
・Highly flammable liquids and vapours. ・May be harmful if swallowed .(oral) • Skin and eye irritation.
・May cause drowsiness and dizziness. ・May cause respiratory irritation. ・Fatal if swallowed or if inhaled.
・Toxic to aquatic life.
Precautionary Statement[SAFETY MEASURES]・Do not handle until all safety precautions have been read and understood.
・Do not eating and drinking or smoking while using this material.

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・Keeping away from ignition sources such as heat, sparks, open flames, and high temperatures. No smoking.
・Keep container tightly closed
・Ground the container.
・Use explosion-proof [electrical equipment/ventilators/lighting equipment].
・Use non-sparking tools.
・To take measures against static electricity.
・Avoid inhalation of dust/smoke/gas/vapour/spray.
・Wash hands, eyes, and mouth thoroughly after handling.
・Do not eat, drink or smoke when using this product.
・Use only outdoors or in well-ventilated areas.
・Avoid release to the environment.
・Wear protective gloves/protective clothing/eye protection/face protection[FIRST AID]・IF SWALLOWED: Get immediate medical advice/attention.
・If it gets on the skin (or hair): immediately remove all contaminated clothing. Rinse skin with water/shower.
・IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
・IF IN EYES: Wash carefully with water for several minutes. If the contact lens can be easily removed, remove it and wash it.
If eye irritation persists, seek medical attention.
・Contact a doctor when you feel ill.
・If it gets on the skin: special treatment is necessary. (4.Ref. for first aid)
・Don't induce vomiting.
・If skin irritation occurs: Have a doctor's diagnosis/care.
・If eye irritation persists: Get medical advice/attention.
・Take off contaminated clothing and wash it before reuse.
・In case of fire: Use a suitable extinguisher to extinguish the fire.
[STORAGE]
・Store in a cool, well ventilated place. Put it in a cool place.
・Store locked up.
[DISPOSAL]
・Dispose of contents/containers in accordance with local/national regulations.
３． Composition/information on ingredients
Substance/Mixture: Mixtures
General product description: Paint
Substance name
Mixed organic compounds

Ingredient

CAS No.

100

Non-disclosure

４． First-aid measures
Inhaled:Move the affected person to a place with fresh air and let it rest in a breathable posture.
Get medical advice/attention if you feel unwell.
Skin contact:
To remove contaminated clothing. Wash skin quickly with plenty of water and soap.
If have skin irritation or feel sick, consult a physician for medical treatment. Wash contaminated clothing before reuse.
Eye contact:
Wash carefully with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing. If eye irritation persists or feel sick, consult a physician for diagnosis and treatment.
Swallowed:
Rinse mouth. Do not induce vomiting. Get medical advice/attention.

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The Most Important Sign Symptoms of Acute and Delayed Onset Symptoms:
Inhaled: cough, sore throat, headache, nausea, fatigue, dizziness, confusion, loss of consciousness.
Skin contact: Dry skin, redness.
Eye contact: Redness and pain.
Swallowed: nausea, vomiting, abdominal pain, and diarrhea. Further see Inhalation.
Necessary precautions for the protection of first aid providers:
The rescuer should wear appropriate personal protective equipment in accordance with the specific situation.
Special precautions for physicians:
Symptoms may develop later, and medical follow-up is necessary when overexposed.
５． Fire-fighting measures
Fire extinguishing agents:
Small fire: Carbon dioxide, powdered fire extinguishing agent, water spray, alcohol resistant foam extinguishing agent.
Large fire: watering, spray water, alcohol-resistant antifoaming agent.
Fire extinguishing agents not to be used:
Rod-shaped pouring
Hazards unique to fire:
There is a risk of generating irritating, toxic, or corrosive gases by fire.
Flammable, easily ignited by heat, sparks and flames. The container may explode due to heating.
Flammable liquids and vapours.
Specific fire extinguishing methods:
If there is a risk of fire spreading in the opposite direction due to sprinkling, use appropriate extinguishing agents listed above
other than sprinkling water.
In the case of a large fire that is not extinguished with a fire extinguishing agent other than water sprinkling, sprinkle with water.
Move containers from fire area if not hazardous. If immobile, cool by sprinkling water in the container and surrounding area.
Cool the container thoroughly by using a large amount of water even after extinguishing the fire.
Special protective equipment and preventive measures for those performing fire fighting activities:
Air respirators and chemical protective clothing should be worn during fire extinguishing operations.
Fire extinguishment from the wind.
６． Accidental release measures
Precautions for the Human Body, Protective Equipment, and Emergency Measures:
Workers wear appropriate protective equipment (see section 8. Prevention of exposure and protection measures) and avoid
contact with eyes and skin or inhalation of gases. Do not touch or walk through the spill. Immediately sequester the appropriate
distance in all directions as a leak area.
Irrelevant persons are prohibited to enter.
Wear highly sealable, impervious protective clothing even if the leakage does not occur in the case of fire. Stay upwind. Get outof the low ground. Ventilate before entering a confined space.
Environmental precautions:
Prevent entry into drains, groundwater ditches, underground rooms or closed areas.
Avoid that the spill does not flow out into sewers, rivers, etc. to cause secondary disasters or environment contaminations. Do notrelease into the environment.
Collection:
In small quantities, collect in empty containers that can be absorbed with dry soil, sand or non-flammable material or covered andsealed. Dispose of it later.
In case of small amounts, use a clean antistatic tool when collecting absorbed material.
In the case of large quantities, it is surrounded by filling to prevent runoff, and it is guided to a safe place and recovered.
In the case of large quantities, sprinkling water reduces the vapor concentration. However, there is a possibility that combustion
cannot be suppressed in a sealed place.

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Methods and equipment for containment and purification:
Stop leaking if not dangerous. All equipment used to handle spills shall be grounded.
Vapor inhibition bubbles are used to reduce vapor concentration.
Preventive measures for secondary disasters:
Quickly remove all ignition sources (no smoking in the vicinity, no sparks or flames).
Prevent entry into drains, groundwater ditches, underground rooms or closed areas.
When steam is generated frequently, steam generation is suppressed by spraying water. Notify the relevant areas and seek support.
７． Handling and storage
Handling:■Technical countermeasures
Electrical equipment and tools shall be explosion-proof and precautions shall be taken against electrostatic discharge.
Prohibit the use of hot materials, sparks, or fire in the vicinity. -No smoking.
Implement equipment measures as described in "8. Exposure prevention and protection measures" and wear protective
equipment.
Ensure that the equipment and devices are grounded to prevent static electricity.
■Local exhaust and general ventilation
Conduct local exhaust and general ventilation as described in "8. Exposure prevention and protection measures."
Prevent liquid leakage and vapor dissipation as much as possible.
■Safety precautions
Do not handle until all safety precautions have been read and understood.
Prohibit the use of hot materials, sparks, or fire in the vicinity.
The substance is irritating to the eyes and should not come into contact with the eyes.
Contact, inhalation, or swallowing of this product is not permitted because of the fear of sleepiness or dizziness, respiratory
irritation, or damage to organs. Don't tumble, drop, shock or drag containers, or otherwise handle them.
Do not inhale mists, vapours, or sprays. Do not eating and drinking or smoking while using this material.
Do not put in eyes. Do not absorb and swallow it.
Wash hands after work. Handle in a well ventilated area.
■Contact avoidance
See "10. Safety and Reactivity".
Storage:■Technical countermeasures
To make the walls, columns, and floors of the storage area of fire-resistant structure and to make the girders of incombustible
material.
The roof shall be made of non-combustible material and shall be wiped with metal plates or other lightweight non-combustible
materials and shall not be provided with a ceiling.
The floor of the storage area shall be so constructed that water does not penetrate or penetrate the floor surface.
The floor of the storage area shall be appropriately tilted and provided with an appropriate reservoir.
Storage areas shall be provided with the necessary facilities for light, illumination and ventilation to store or handle hazardous
materials.
■Safe storage conditions
Store away from sources of ignition, such as heat, sparks or open flames. --No smoking.
Store in a cool place or in a well-ventilated place. Store away from oxidants.
Containers should be protected from direct sunlight and fire. Keep containers sealed and well ventilated.
Quantities of one-fifth or more of the designated quantity shall not be stored at any place other than a hazardous materials
storage facility. Store locked.
■Incompatible materials
See "10. Safety and Reactivity".
■Containers and packaging materials
Use containers specified in the Fire Service Law and the UN Transport Law.

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８． Exposure controls/Personal protection
Exposure limits
ACGIH (FY2016)

Substance name

Mixed organic compounds―[Equipment Measures]
Use explosion-proof electrical, ventilating and lighting equipment.
Do preventive measures to electrostatic discharge.
Eyewashers and safety showers should be installed in workplaces where this substance is not stored or handled.
Exhaust ventilation should be used to keep airborne concentrations below the exposure limit.
Post necessary signs such as "fire strict prohibition" and "prohibition of entry other than related persons" in easy-to-see places.
Depending on the situation, gas detectors, etc. shall be installed for safety management.
[Protection]
Respiratory protective equipment:
Wear appropriate respiratory protection (gas mask for organic gases).
Hand protectors:
Wear protective gloves (organic solvent-resistant gloves).
Eye protection:
Wear protective gloves (organic solvent-resistant gloves).
Skin and body protection:
Wear protective shoes (electrostatic shoes), oil-resistant (for measures against impermeability and static electricity), protective
clothing (for measures against static electricity), etc.
[Special precautions]Hygiene measures:
Wash hands, eyes, and mouth well after handling.
９． Physical and Chemical Properties
Physical State:Liquid
Odor: Distinctive odor
Flash point:22.3℃
Vapor pressure:―
Boiling point:105℃

Physical property (color)
Density (g/ml)
Explosion Limits
Auto-ignition temp

:Clear, colorless: 0.872:LEL 1.0vol % UEL 7.0vol %: ≥ 200℃

１０． Stability and Reactivity
Reactivity:
Stable in normal handling.
Chemical Stability:
Under normal conditions, no hazardous reactions occur.
As a result of flow, agitation, etc., electrostatic charges can be generated.
Hazardous reactivity:
Reacts violently with strong oxidants causing fire and explosion hazard.
Conditions to avoid:
Formation of mixed gases within explosion limits with air.
Incompatible Materials:
Oxidants.
Hazardous decomposition products:
Burning produces carbon monoxide, carbon dioxide, etc.

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１１． Toxicological information
ACUTE TOXICITY
Substance name
Oral
Mixed organic compounds

Classification
Category 5

DermalClassification

Classification not possible

ACUTE TOXICITY
Substance name
Mixed organic compounds

Inhalation(Gas)

Classification

Classification not possible

Inhalation(Vapors)

Classification

Classification not possible

Inhalation(Dust/Mist)

Classification

Classification not possible

Substance name

Skin corrosion/irritantSerious eye
damage/eye irritant

Respiratory
sensitisation

Skin sensitisation

Mixed organic compounds

Category 2

Category 2B

Classification not possible

Classification not possible

Substance nameGerm Cell Mutagenicity

Carcinogenicity

Reproductive toxicity

Mixed organic compounds

Classification not possible

Classification not possible

Classification not possible

Substance name
Mixed organic compounds

TOST (Single)
Category 3(anesthetic effect, respiratory tract irritation)

TOST (Repeat)

Aspiration hazard

Classification not possible

Category 1

１２． Ecological information
General Precautions:Handle the product carefully in case of leakage, disposal, etc., as this may affect the environment.
The product may have adverse effect on environment.
In particular, take measures to prevent products and wash water from flowing directly to the ground, rivers and drains.
Ecotoxicity:
Substance name
Acute Aquatic Toxicity
Chronic Aquatic Toxicity
Hazardous to the ozone layer
Mixed organic
Category 2
compounds
Persistence and degradability: ―――
Eco-accumulative: ―――

Classification not possible

Classification not possible

１３． Disposal considerations[Residual Waste, Contamination Containers and Packaging]
Disposal shall be in accordance with relevant laws and regulations as well as the standards of local governments. Waste
paints, waste solvents, containers, and other wastes shall be disposed of by contracting with a licensed industrial waste disposal
contractor. Do not release empty container and wash water into environment.For other wastage arouse in effluent processing or
incineration, dispose of them in accordance with the law or entrust it.Dispose of the empty container after the rest of paintcompletely removed. Empty containers, packaging, etc.Is recommended for recycling.Dispose of the empty container after the
rest of paint completely removed. Empty container should be disposed of by industrial waste disposal contractor after theconsignment contract..
１４． Transport information[Regulations]
UN No. 1263
UN Classification: 3
PG: II
Transport:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is no leaking in the container, and load. Prevent collapse of the container so that there is no falling or
damage.
Land transport:
Follow all regulation on the transport in your country or region.
The consignor shall issue the Carriage Precautions (Yellow Card) to the Carrier.
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Maritime transportation:
The provisions of the Ship Safety Act shall be followed.
Air Transportation:
In accordance with the provisions of the Aeronautical Law.
Safety measures:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is no leaking in the container, and load. Prevent collapse of the container so that there is no falling or
damage.
１５． Regulatory information
Classification and labeling in accordance with Labor Safety and Health Act:See Section 2
Other regulation for foreign countries:
Regulatory information with regards to this preparation in your country or region should be examined by your own
responsibility.
１６． Other information
References:
1) GHS Classification Guidance for Enterprises.
2) SDS from manufacturers of raw materials3) Roval’s own data
The information herein is given in good faith, but no warranty, express or implied, is made.
The information contained herein is, to the best of Roval’s knowledge and belief, accurate and reliable as of the data issued. It is theuser’s responsibility to determine the suitability of this information for the adoption of necessary safety precautions. We reserve theright to revise SDS periodically as new information becomes available.

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