Safety Data Sheet[Mixture (Paint)]
１． Products and company identification
Product nameSupplier
Address
Section in charge
Phone number
Fax number
e-mail address
Emergency Phone Number
Preparation, revision, and confirmation
Product type
Recommended use

ROVAL ALPHA SPRAY
Roval Corporation
1-1, Nomuramotomachi, Hirakata, Osaka
Technical service department+81-72-894-7590+81-72-894-7593
jp-info@roval-group.com+81-72-894-7191
May 8, 2023
One-component organic zincrich paint (with high-content of zinc powder)
Rust prevention of iron and galvanizing surfaces

２． HAZARDS IDENTIFICATION[GHS Classification]
PHYSICAL HAZARDS

AerosolCategory 2

Oral

DermalInhalation (Gases)

Inhalation (Vapours)

Inhalation (Dust/Mist)

Classification not possible

Classification not possible

Classification not possible

Category 4

Classification not possible

Skin corrosive

Serious eye damage/irritating/eye Irritation

Solid/Liquid

Gas

Skin sensitisation

Category 2

Category 2B

Classification not possible

Classification not possible

Classification not possible

Acute toxicity

Respiratory/Skin sensitization

Germ cell mutagenicity

Carcinogenicity

Reproductive toxicity

Effects on or via lactation

HEALTHClassification not possible

Classification not possible

Category 1A

May cause harm to breast-fed children.

HAZARDS

STOT

Category 1(Single exposure)

Category 2

Category 3―――

Central nervous system,

May cause respiratory irritation
May cause drowsiness and dizziness

STOT

Category 1

Category 2(Repeated exposure)Central nervous system, kidney

Respiratory system, Digestive system

Aspiration hazard
Not classified

Hazardous to the aquatic environment

Hazardous to the aquatic environment(Acute)(Chronic)

Category 2

Category 2

Hazardous to the ozone layer
Classification not possible[GHS Symbols]
Pictogram:

Signal word:

DANGER

Hazard statement:
H223：Flammable aerosol.
H229：Pressurised container: May burst if heated.
H332：Harmful if inhaled.
H315：Causes skin irritation.
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H320：Causes eye irritation.
H360：May damage fertility or the unborn child.
H362：May cause harm to breast-fed children.
H370：Causes damage to organs(central nervous system).
H335：May cause respiratory irritation.
H336：May cause drowsiness or dizziness.
H372：Causes damage to organs (central nervous system, kidney) through prolonged or repeated exposure.
H373：May cause damage to organs (respiratory system, digestive system) through prolonged or repeated exposure.
H411：Toxic to aquatic life with long lasting effects.
Precautionary Statement:[SAFETY MEASURES]
P201：Obtain special instructions before use.
P202：Do not handle until all safety precautions have been read and understood.
P210：Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211：Do not spray on an open flame or other ignition source.
P260：Do not breathe dust/fume/gas/mist/vapours/spray.
P263：Avoid contact during pregnancy/while nursing.
P264：Wash hands thoroughly after handling.
P270：Do not eat, drink or smoke when using this product.
P271：Use only outdoors or in a well-ventilated area.
P273：Avoid release to the environment.
P280：Wear protective gloves/protective clothing/eye protection/face protection.
[FIRST AID]
P302+P352：IF ON SKIN: Wash with plenty water/shower.
P304＋P340：IF INHALED: Remove person to fresh air and Keep comfortable for breathing.
P305+P351+P338：IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if present and eazy to do. Continue rinsing.
P308+P313：IF exposed or concerned: Get medical advice/attention.
P332+P313：If skin irritation occurs: Get medical advice/attention.
P337+P313：If eye irritation persists: Get medical advice/attention.
P362+P364：Take off contaminated clothing and wash it before reuse.
P391：Collect spillage.
[STORAGE]
P405：Store locked up.
P410+P412：Protect from sunlight. Do no expose to temperatures exceeding 40 °C/104°F.
[DISPOSAL]
P501：Appropriately dispose of the contents/containers in accordance with laws and regulations.
３． Composition/information on ingredients
Distinguishing Chemicals and Mixtures: Mixtures (Product Content Weight: 420 ml = 401.3 g/bottle)
Substance name
%WeighCAS No.
XyleneEthylbenzene
TolueneAcetoneZinc
Zinc oxide
Dimethyl ether

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<1
<1
25
5 ～ 1020 ～ 25<1
35 ～ 40

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1330-20-7
100-41-4
108-88-3
67-64-1
7440-66-6
1314-13-2
115-10-6

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４． First-aid measures
Inhaled:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Contact a doctor when you feel ill.
Skin contact:
Wipe off the adherent quickly with a cloth.
Wash the affected area with plenty of water with mild soap.
Do not use solvents or thinners.
If there is any change in appearance, irritation, or pain, consult a physician when mood is bad.
Take off contaminated clothing and Wash it before reuse.
If it gets on the skin (or hair): remove all contaminated clothing immediately.
Wash skin with water or shower.
Eye contact:
Immediately wash with plenty of clean running water for at least 15 minutes.
Remove contact lenses, if present and easy to do.
Thoroughly wash the back of the eyelids.
Seek medical attention immediately.
If eye irritation persists: Get medical advice/attention.
If on clothing:
Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Swallowed:
If swallowed incorrectly, allow the patient to rest and consult a physician immediately.
Do not induce vomiting.
First Aid:
Wear appropriate protective equipment (e.g. protective glasses, protective masks, gloves, etc.).
Ventilation is performed.
５． Fire-fighting measures
Suitable extinguishing agents:
Carbon dioxide, foam and powder
Fire extinguishing agents not to be used:
Water (rod-shaped water, high-pressure water)/rod-shaped reinforcing liquid
Special methods for extinguishing fires, protection of persons who extinguish fires:
Wear proper protective equipment.
Quickly remove flammable materials from the surroundings if safe to deal with.
Use specified extinguishing media.
Cool closed containers which may be exposed to heat.
Extinguish from windward side.
Keep distant during fire fighting, heated container may burst.
６． Accidental release measures
Precautions for the Human Body, Protective Equipment, and Emergency Measures:
Appropriate protective equipment (protective gloves, protective masks, aprons, goggles, etc.) should be worn during work.
Ventilating firmly indoors In outdoor cases, work from the windward as much as possible.
Prevent secondary disasters by prohibiting access to the surrounding area and keeping other people away.
Avoid sparks, flames and anything which can cause fire.
Prepare extinguishing media for accidental fire.
Shaking during leaking may cause the contents to spray.
Handle with care.

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Environmental precautions:
Be careful not to cause environmental effects due to discharge into rivers, etc.
Containment and Purification Methods and Equipment:
For small spill, absorb spills with inert materials, then place in a chemical waste containers.
Disposal of deposits, waste, etc. shall be made in accordance with relevant laws and regulations.
Collect by using a tool made of a material that does not generate sparks due to impact or static electricity.
Absorb in dry sand, soil, or other non-combustible materials for recovery.
A large amount of leakage is prevented by surrounding with embankment.
７． Handling and storage
Handling:
Handle in a well-ventilated area.
The container is sealed each time.
Keep away any source of flame, sparks, and heat.
Wear antistatic cloths and shoes.
Use sparkless equipment.
For countermeasures against static electricity, the equipment, etc. shall be grounded, and explosion-proof type shall be used forthe electrical equipment, etc.
Used waste, paint waste, spray dust, etc. should be kept in water until discarded.
Do not handle this product in a temperature above 40°C.
Do not warm to 40°C or above.
Do not keep spraying for more than 30 seconds.
Wear protective equipment to keep skin, mucous membranes, or clothing from touching or coming into the eyes.
Wash hands and face completely after the handling.
Handle in a well-ventilated area.
Wear personal protective cloths.
Storage:
Avoid direct sunlight. Store in a dry, well-ventilated area.
Take necessary measures to prevent leakage, overflow, or splashing.
Keep locked to prevent theft. Keep out of the reach of children.
Keep containers away from fire/flame.
Do not store in a temperature above 40°C.
When stored around water or in a high humidity place, the container may corrode and rupture, so be careful of the storage place.
８． Exposure controls/Personal protection
Substance name

ACGIH

XyleneEthylbenzene
TolueneAcetoneZinc
Zinc oxide

100 ppm(TWA)
20 ppm(TWA)
20 ppm(TWA)
500 ppm(TWA)―
2 mg /㎥(TWA)

Dimethyl ether―[Equipment Measures]
Use air extractors to prevent fume formation. Use air extractors to prevent fume formation.
Equipment for transporting, pumping, agitation, etc. of liquids shall be equipped to be grounded.
Equipment shall be installed in the vicinity of the handling site so as not to be subject to high temperatures or ignition sources.
In the case of indoor painting work, equipment that does not expose workers directly, such as by using automatic painting
machines, etc., or equipment that avoids workers from exposure by local exhaust ventilation systems, etc., shall be used.
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When working in a sealed place such as the inside of a tank, install a device that can sufficiently ventilate to the bottom of thesealed place.
[Protection]
Respiratory protection:
Wear gas masks for organic gases.
In cases of inadequate ventilation, a respiratory protective device should be worn to prevent overexposure.
Hand protection:
Wear gloves made of organic solvents or chemicals that do not penetrate.
Eye protection:
Wear protective glasses for handling.
Skin and body protection:
When handled, wear clothing that does not directly expose the skin.
Further, it is desirable that the material is a material that does not permeate the chemical.
Other:
No statement.
９． Physical and Chemical Properties
Physical state:Liquid
ColourOdour:Solvent odour
Boiling point
Flammability: Flammable Liquid
Explosion Limits
Auto-ignition temperature :190℃
Relative vapour density
Decomposition temperature: No data
Kinematic viscosity
Vapor pressure:506.6kPa(20.8℃)
Densities (g/ml)
Flash point: Undiluted solution -15.0°C Gas -41.1°C:Silver:-24.8℃~192℃: LEL 0.7 vol% UEL 27.0 vol%:3.66
No data:0.96

１０． Stability and Reactivity
Reactivity: No self-reactivity.
Chemical Stability: Stable in normal handling.
Hazardous Reaction Potential: No data.
Conditions to avoid: Heating, high temperature, contact with incompatible substances.
Forming of mixture with atmosphere within flammable limit.
Incompatible substances: Risk of reacting on contact with oxidizing substances, water, etc.
Hazardous decomposition products: Heat decomposition produces carbon monoxide, carbon dioxide. Generate stimulant gas
１１． Toxicological information
ACUTE TOXICITY
Substance name
Oral
XyleneEthylbenzene
TolueneAcetoneZinc
Zinc oxide
Dimethyl ether

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Classification

3.5 g / kg
Not classified
3.5 g / kg
Not classified
5.0 g / kg
Not classified
5.8 g / kg
Not classified> 2.0 g / kg
Not classified> 5.0 g / kg
Not classified
Classification not possible

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DermalClassification

1.7 g / kg
Category 4
5.0 g / kg
Not classified
12.0 g / kg
Not classified> 7.4 g / kg
Not classified
Classification not possible> 5.0 g / kg
Not classified
Classification not possible

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ACUTE TOXICITY
Substance nameInhalation(Gas)

Inhalation(Vapors)

Classification

Not classified
Not classified
Not classified
Not classified
Not classified
Not classified

Classification

XyleneEthylbenzene
TolueneAcetoneZinc
Zinc oxide
Dimethyl ether

4000 ppm

Category 4
Category 4
Category 432000ppm

Not classified

164000ppm

Substance name

Skin corrosive/Irritating

XyleneEthylbenzene
TolueneAcetoneZinc
Zinc oxide
Dimethyl ether

Category 2
Not classified
Category 2
Not classified
Not classified
Not classified

Serious eye damage/eye Irritation
Category 2
Category 2B
Category 2B
Category 2B
Category 2B
Not classified

Classification not possible

Classification not possible

6350 ppm
4000 ppm

Classification not possible
Not classified
Not classified

Not classified

Inhalation(dust, mist)

Classification

Classification not possible
Classification not possible
Classification not possible
Classification not possible> 5.4 mg / L

Not classified> 5.7 mg / L

Not classified

Not classified

Respiratory
sensitisation

Skin sensitisation

Classification not possible

Classification not possible

Classification not possible

Classification not possible

Classification not possible

Classification not possible

Not classified
Not classified
Not classified
Not classified

Not classified

Classification not possible

Classification not possible
Classification not possible

Substance nameGerm cell mutagenicity

Carcinogenicity

Reproductive toxicity

XyleneEthylbenzene
TolueneAcetoneZinc
Zinc oxide
Dimethyl ether

Classification not possible
Not classified
Not classified
Classification not possible
Classification not possible
Classification not possible
Classification not possible

Classification not possible
Category 2
Classification not possible
Classification not possible
Classification not possible
Classification not possible
Classification not possible

Category 1 B
Category 1 B
Category 1ACategory 2
Classification not possible
Category 2
Classification not possible

Substance name

STOT (Single exposure)

XyleneEthylbenzene

TolueneAcetoneZinc
Zinc oxide
Dimethyl ether

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Category 1 (respiratory, liver,Central nerve system, kidney)
Category 3 (anesthetic effect)
Category 3 (irritating to the respiratory
tract, anesthetic effect)
Category 1 (central nervous system)
Category 3 (irritating to the respiratory
tract, anesthetic effect)
Category 3 (irritating to the respiratory
tract, anesthetic effect)
Classification not possible
Category 1 (respiratory, systemic
toxicity)
Category 3 (anesthetic effect)

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STOT (Repeat exposure)

Aspiration hazard

Category 1 (respiratory,
nervous system)

Category 1

Category 2 (hearing
apparatus)

Category 1

Category 1 (central nervous
system, Kidney)

Category 1

Category 2 (central nervous
system, respiratory system,
digestive tract)
Classification not possible

Classification not possible
Classification not possible

Classification not possible

Classification not possible

Classification not possible

Classification not possible

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１２． Ecological information
General precautions: When leaking or disposing of the product, be careful to handle it because it may affect the environment.
The product may have adverse effect on environment.
Hazardous to the aquatic
Hazardous to the aquatic
Substance name
Hazardous to the ozone layer
environment(Acute)environment (Chronic)
XyleneCategory 2
Category 2
Classification not possible
Ethylbenzene
Category 1
Category 2
Classification not possible
TolueneCategory 2
Category 3
Classification not possible
AcetoneNot classified
Not classified
Classification not possible
Zinc
Category 1
Category 1
Classification not possible
Zinc oxide
Category 1
Category 1
Classification not possible
Dimethyl ether
Not classified
Not classified
Classification not possible
Ecotoxicity:
No datePersistence and degradability:
No rapid degradability (degree of degradation by BOD: 39%)《Xylene》
Has rapid decomposition (degree of degradation by BOD: 81-126%)《Ethylbenzene》
Has rapid decomposition (degree of degradation by BOD: 123%)《Toluene》
No rapid degradability (metal compound)《Zinc》
No rapid degradability (degree of degradation by BOD: 0-1%)《Dimethyl ether》
Bioaccumulation:
May be low potential (log Kow = 3.16)《Xylene》
May be low potential (log Kow = 3.15)《Ethylbenzene》
May be low potential (log Kow = 2.73)《Toluene》
Judged as having no or low bioaccumulation《Dimethyl ether》
Mobility in soil:
No data
１３． Disposal considerations[Residual Waste, Contamination Containers and Packaging]
In the case of disposal, the relevant laws and regulations and the standards of local governments shall be complied with. Waste
including residue and container should be disposed by licensed industrial waste disposer after the consignment contract. Wash
water used for cleansing containers and equipment must not be released into environment. For other wastage arouse in effluent
processing or incineration, dispose of them in accordance with the law or entrust it. Dispose of the empty container after the restof paint completely removed. It is recommended to recycle empty containers and packaging. When there is a possibility ofgenerating toxic gases such as dioxin, enter into a contract with a licensed industrial waste disposal company and dispose of it.
Dispose of the empty container after the rest of paint completely removed. Empty container should be disposed of by industrial
waste disposal contractor after the consignment contract.
Keep away source of flame and do not inhale mist during outgassing. Caution should be exercised with respect to the inhalationof fire and mist, etc., when releasing the gas (until the injection sound is no longer generated).
１４． Transport information
UN Number: 1950 Proper shipping name: Aerosols Hazard class :2.1
PG: ―Special safeguards for transport or means of transport:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is no leaking in the container, and load.
Prevent collapse of the container so that there is no falling or damage.
[Regulations]Land transport:
Follow the transport methods stipulated in the Fire Service Law and the Industrial Safety and Health Law, if applicable.
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The consignor shall issue the Carriage Precautions (Yellow Card) to the Carrier.
Maritime transport:
In accordance with the Ship Safety Law.
Air transport:
In accordance with the provisions of the Aeronautical Law.
Other:
When transporting, keep the container at 40°C or below and be careful not to fall, drop, or damage.
１５． Regulatory information
Classification and labeling in accordance with Labor Safety and Health Act:See Section 2
Other regulation for foreign countries:
Regulatory information with regards to this product in your country or region should be examined on your own
responsibility.
１６． Other information
References:
1) GHS Classification Guidance for Enterprises.
2) SDS from manufacturers of raw materials3) Roval’s own data
The information herein is given in good faith, but does not make any warranty, express or implied.
The information contained herein is, to the best of Roval’s knowledge and belief, accurate and reliable as of the data issued. It is theuser’s responsibility to determine the suitability of this information for the adoption of necessary safety precautions. We reserve theright to revise SDS periodically as new information becomes available.

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