Zinc standard solution 0.1mg Zn/mL (100ppm)
Hayashi Pure Chemical Ind.,Ltd.
Date of issue: 4/4/2017

Revision date: 8/31/2022

SDS code: W4-08

Version: 05

Safety Data Sheet
1. Chemical product and company identification
Product nameSDS code::

Zinc standard solution 0.1mg Zn/mL (100ppm)
W4-08

Company/undertaking:
identification
HAYASHI PURE CHEMICAL IND.,LTD.
Address : 3-2-12 Uchihiranomachi, Chuo-ku, Osaka, Osaka, Japan
Telephone : 06-6910-7305
E-mail : shiyaku_kikaku@hpc-j.co.jp
URL : https://www.hpc-j.co.jp/
Emergency numberRecommended use
Restrictions on use:::06-6910-7305
For research and experimental use only.
Do not use on a human body or for animal medicines, foods, householdproducts, cosmetics, etc.

2. Hazards identification
GHS classification
Physical hazards

Health hazards

Explosives
Flammable gases
AerosolOxidizing gases
Gases under pressure
Flammable liquids
Flammable solids
Self-reactive substances andmixtures
Pyrophoric liquids
Pyrophoric solids
Self-heating substances andmixtures
Substances and mixtures which incontact with water emit flammablegases
Oxidizing liquids
Oxidizing solids
Organic peroxides
Corrosive to metals
Desensitized eplosives
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (inhalation:gas)
Acute toxicity (inhalation:vapors)
Acute toxicity (inhalation:dust/mist)
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity (singleexposure)classification not possible
No classification
classification not possible
No classification
No classification
classification not possible
No classification
classification not possibleclassification not possible
No classification
classification not possibleclassification not possibleclassification not possible
No classification
classification not possible
Category 1classification not possibleclassification not possibleclassification not possible
No classification
Category 3classification not possible
Category 1
Category 1classification not possibleclassification not possibleclassification not possibleclassification not possibleclassification not possibleclassification not possible

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Hayashi Pure Chemical Ind.,Ltd.

Zinc standard solution 0.1mg Zn/mL (100ppm)
Revision date: 8/31/2022

Environmental
hazards

Specific target organ toxicity(repeated exposure)
Aspiration hazardHazardous to the aquatic
environment, short-term (acute)Hazardous to the aquatic
environment, long-term (chronic)
Hazardous to the ozone layer

SDS code: W4-08

Version: 05

classification not possibleclassification not possible
No classification
No classification
classification not possible

Hazardpictograms(GHS JP)

GHS06

GHS05

Signal word (GHS JP):

DangerHazard statements (GHS JP):

May be corrosive to metals (H290)
Causes severe skin burns and eye damage (H314)
Toxic if inhaled (H331)

Prevention:

Response:

Storage:

Disposal:

Keep only in original container. (P234)
Do not breathe dust/fume/gas/mist/vapors/spray. (P260)
Wash hands, forearms and face thoroughly after handling. (P264)
Use only outdoors or in a well-ventilated area. (P271)
Wear protective gloves/protective clothing/eye protection/face protection.
(P280)IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
(P301+P330+P331)
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water . (P303+P361+P353)
IF INHALED: Remove person to fresh air and keep comfortable forbreathing (P304+P340)
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
(P305+P351+P338)
Immediately call a POISON CENTER or doctor. (P310)
Wash contaminated clothing before reuse. (P363)
Absorb spillage to prevent material-damage. (P390)
Store in a well-ventilated place. Keep container tightly closed.
(P403+P233)
Store locked up. (P405)
Store in corrosive resistant container with a resistant inner liner. (P406)
Dispose of contents/container to hazardous or special waste collection
point, in accordance with local, regional, national and/or international
regulation. (P501)

Precautionary statements (GHS JP)

3. Composition/information on ingredients
Distinction of substance or mixture
Name:Mixture

Concentration orConcentration
range

Kanpo number
FormulaCSCL no

ISHL noCAS RN

Zinc

About 0.01％

Zn

Excluded(element)-7440-66-6

Nitric acid

About 0.63％

HNO3(1)-394

Existing
ChemicalSubstance

7697-37-2

Water

About 99.36％

H2O--7732-18-5

The above concentration or concentration range are not product specification.
All percentages listed in the above concentration or concentration range are wt%, unless otherwise specified.

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Hayashi Pure Chemical Ind.,Ltd.

Zinc standard solution 0.1mg Zn/mL (100ppm)
Revision date: 8/31/2022

SDS code: W4-08

Version: 05

4. First aid measures
First aid measures
First-aid measures after inhalation:

First-aid measures after skincontact:

First-aid measures after eye
contact:

First-aid measures after ingestion:

Remove person to fresh air and keep comfortable for breathing.
Get immediate medical advice/attention.
Remove/Take off immediately all contaminated clothing.
Gently wash with plenty of soap and water.
Get immediate medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Get immediate medical advice/attention.
Do NOT induce vomiting.
Drink plenty of water.
Rinse mouth.
Get immediate medical advice/attention.

5. Fire fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Explosion hazard
Hazardous decomposition products
in case of fire
Firefighting instructions::::

Water spray, Alcohol-resistant foam, Dry powder, Carbon dioxide, Sand.
Do not use a heavy water stream.
May induce explosion of containers by heating.
In case of fire, product may produce irritative or toxic fumes/gases.

:

Protection during firefighting:

If ignited, for the initial fire-fighting, cut off combustion sources, extinguishfire at a stroke using appropriate fire-extinguishers.
In the case of peripheral fire, quickly remove movable containers to safe
places.
If unable to be moved containers, sprinkle water to containers andsurrounding equipment, etc. to cool.
Avoid (reject) fire-fighting water to enter environment.
Even after extinguishing fire, thoroughly cool containers by using plenty ofwater.
Wear appropriate fire-resistant clothing including self containedcompressed air breathing apparatus.

6. Accidental release measures
Personal Precautions, Protective Equipment and Emergency Procedures
General measures: Before entering, ventilate the area.
Do not let unauthorized persons come close to the area.
Immediately place the leakage area in isolation, with taking proper
distances for all directions.
Wear appropriate personal protective devices to prevent inhalation andcontact with eye, skin, and clothing, and never attempt to work on the lee.
Environmental precautions
Environmental precautions:

Avoid release to the environment.
Prevent entry to sewers and public waters.

Methods and Equipment for Containment and Cleaning up
Methods for cleaning up: Clean up any spills as soon as possible, using an absorbent material tocollect it.
Collect leaking and spilled liquid in sealable containers as far as possible.
Wash out the spilled area with large amounts of water.
If possible, neutralize with slaked lime, soda ash, etc. before washing out.

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Hayashi Pure Chemical Ind.,Ltd.

Zinc standard solution 0.1mg Zn/mL (100ppm)
Revision date: 8/31/2022

SDS code: W4-08

Version: 05

7. Handling and storage
Handling
Technical measures:

Precautions for safe handling:

Prevents handling of incompatible
substances or mixtures:

Storage
Storage conditions:

Material used inpackaging/containers
Technical measures
Storage temperature

Work with appropriate personal protective equipment to prevent inhalationor contact to eyes, skin, and clothing.
Handle with care to prevent leakage, overflowing, or scattering, minimize
generation of mist or vapor, and thoroughly ventilate.
Do not eat, drink or smoke when using this product.
Thoroughly wash your hands and gargle after handling.
Ensure good ventilation of the work station.
Do not contact, breathe or swallow.
Avoid prolonged or repeated exposure.

:Store locked up.
Store in a well-ventilated place, away from direct sunlight. Keep container
tightly closed and keep away from fire and heat sources.
Store in corrosive resistant container with a resistant inner liner.
Light shielding airtight container.

::

Comply with applicable regulations.
Cool and dark place

8. Exposure controls / Personal protection equipment
Exposure limit values
Nitric acid
Exposure limits (JSOH)
Exposure limits (ACGIH)

2ppm(5.2mg/m3)
TWA 2 ppm,STEL 4 ppm

Appropriate engineering controls

Protective equipment
Respiratory protection
Hand protection
Eye protection
Skin and body protection: Cover up tightly the generation source at the handling place or install local
exhaust equipment or overall ventilation equipment. Install safety showers
and eye-fountains near a handling place. Clearly indicate the location.
: Gas mask for acid gases: Impervious protective gloves: Protective glasses (general glasses, glasses with side-shields, goggles): Impervious aprons, Impervious work clothing, Protective long boots

9. Physical and chemical properties
Physical stateAppearance
ColorOdor
pH

:
:
:
:
:

LiquidLiquidcolorless transparent
Odorless

Melting point
Freezing point
Boiling point
Flash point
Auto-ignition temperature
Decomposition temperature
Flammability (solid, gas)
Vapor pressure
Relative density
Density

:
:
:
:
:
:
:
:
:
:

No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available

Relative gas density
Solubility::

No data available
No data available

1.1 （25℃）

1.00 g/cm³ （20℃）

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Hayashi Pure Chemical Ind.,Ltd.

Zinc standard solution 0.1mg Zn/mL (100ppm)
Revision date: 8/31/2022

Partition coefficient noctanol/water (Log Pow)
Explosive limits (vol %)Viscosity, kinematic
Particle characteristics

SDS code: W4-08

Version: 05:

No data available:::

No data available
No data available
No data available

Reactivity
Chemical stability
Possibility of hazardous reactions:::

Conditions to avoid:

Incompatible materials
Hazardous decomposition
products::

No data available
Stable under normal handling conditions.
Corrodes many metals and generates hydrogen. When it contacts withreducing substances, organic compounds and powdered metals, it reacts
violently or explosively.
Sunlight, heat. Contact with reducing substances, organic compounds,bases and metals.
Reducing substances, Organic compounds, Bases, Metals
Nitrogen oxides, Hydrogen

10. Stability and reactivity

11. Toxicological information
The information in this section is based on the "GHS Classification Results" by NITE.
As a productAcute toxicity (oral)classification not possible
Acute toxicity (dermal)
classification not possible
Acute toxicity (inhalation)
vapors:Category 3
Gases:No classification
dust, mist:classification not possible
Skin corrosion/irritation
Category 1
Serious eye damage/irritation
Category 1
Respiratory sensitization
classification not possible
Skin sensitization
classification not possible
Germ cell mutagenicity
classification not possible
Carcinogenicity
classification not possible
Reproductive toxicity
classification not possible
STOT-single exposure
classification not possible
STOT-repeated exposure
classification not possible
Aspiration hazardclassification not possible
Zinc
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (gas)Acute toxicity (vapour)
Acute toxicity (inhalation:dust/mist)
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity

No classification
classification not possible
No classification
classification not possible
No classification
No classification
Category 2Bclassification not possible
No classification
classification not possibleclassification not possible

Reproductive toxicity

classification not possible

STOT-single exposure

classification not possible

STOT-repeated exposure

classification not possible

Aspiration hazard

classification not possible

Nitric acid
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (gas)Acute toxicity (vapour)
Acute toxicity (inhalation:dust/mist)
Skin corrosion/irritation

classification not possibleclassification not possible
No classification
Category 1classification not possible
Category 1
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Hayashi Pure Chemical Ind.,Ltd.

Zinc standard solution 0.1mg Zn/mL (100ppm)
Revision date: 8/31/2022

Nitric acid
Serious eye damage/irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity

Category 1classification not possibleclassification not possibleclassification not possibleclassification not possible

Reproductive toxicity

classification not possible

STOT-single exposure

Category 1

STOT-repeated exposure

Category 1

Aspiration hazard

classification not possible

Water
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (gas)Acute toxicity (vapour)
Acute toxicity (inhalation:dust/mist)
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity

No classification
No classification
No classification
No classification
No classification
No classification
No classification
No classification
No classification
No classification
No classification

Reproductive toxicity

No classification

STOT-single exposure

No classification

STOT-repeated exposure

No classification

Aspiration hazard

No classification

SDS code: W4-08

Version: 05

12. Ecological information
The information in this section is based on the "GHS Classification Results" by NITE.
As a productHazardous to the aquatic environment,
No classification
short-term (acute)Hazardous to the aquatic environment,
No classification
long-term (chronic)
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Ozone
classification not possible
Zinc
Hazardous to Aquatic Environment Acute Hazard
Hazardous to Aquatic Environment Chronic Hazard
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Hazardous to the ozone layer
Nitric acidHazardous to Aquatic Environment Acute Hazard
Hazardous to Aquatic Environment Chronic Hazard
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Hazardous to the ozone layer

Category 1
Category 1
No data available
No data available
No data available
No data available
Category 3
No classification
No data available
No data available
No data available
classification not possible
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Hayashi Pure Chemical Ind.,Ltd.

Zinc standard solution 0.1mg Zn/mL (100ppm)
Revision date: 8/31/2022

WaterHazardous to Aquatic Environment Acute Hazard
Hazardous to Aquatic Environment Chronic Hazard
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Hazardous to the ozone layer

SDS code: W4-08

Version: 05

No classification
No classification
No data available
No data available
No data available
classification not possible

13. Disposal considerations
Ecology - waste materials:

Contaminated container andpackaging:

With the detail information of the waste, subcontract its disposal to awaste disposer authorized by a Prefectural Governor.
Empty the packaging completely prior to disposal.
Empty containers should be taken for recycle, recovery or waste inaccordance with local regulation.

:::
:
:
:
:
:
:
:
:
:
:
:

3264
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
II
888274P001
IBC02
T11TP2, TP27
B
Causes burns to skin, eyes and mucous membranes.
154

UN-No. (IATA)
Proper Shipping Name (IATA)
Packing group (IATA)
Transport hazard class(es) (IATA)
Hazard labels (IATA)Class (IATA)
PCA Excepted quantities (IATA)
PCA Limited quantities (IATA)
PCA limited quantity max netquantity (IATA)
PCA packing instructions (IATA)
PCA max net quantity (IATA)
CAO packing instructions (IATA)
CAO max net quantity (IATA)
Special provision (IATA)ERG code (IATA)

:::
:
:
:
:
:
:

3264
Corrosive liquid, acidic, inorganic, n.o.s.
II
88
8
E2
Y840
0.5L

:
:
:
:
:
:

851
1L
855
30L
A3, A803
8L

Marine pollutant:

Not applicable

Regulations in Japan
Regulatory information by sea
Regulatory information by air
MFAG-NoSpecial transport precautions::::

Conform to the provisions of the Ship Safety Law.
Conform to the provisions of the Civil Aeronautics Law.
154
When transporting, load containers so that they do not tip over,damage, drop or collapse. Make sure there is no leak in containers.

14. Transport information
International Regulations
Transport by sea(IMDG)
UN-No. (IMDG)
Proper Shipping Name (IMDG)
Packing group (IMDG)
Transport hazard class(es) (IMDG)
Hazard labels (IMDG)Class (IMDG)
Special provision (IMDG)
Packing instructions (IMDG)
IBC packing instructions (IMDG)Tank instructions (IMDG)
Tank special provisions (IMDG)
Stowage category (IMDG)
Properties and observations (IMDG)
MFAG-No
Air transport(IATA)

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Hayashi Pure Chemical Ind.,Ltd.

Zinc standard solution 0.1mg Zn/mL (100ppm)
Revision date: 8/31/2022

SDS code: W4-08

Version: 05

15. Regulatory information
National law
Industrial Safety and Health Law:

Japanese Poisonous andDeleterious Substances Control Law
Water Pollution Prevention Law:

Fire Service Law
Air Pollution Control Law
Foreign Exchange and Foreign
Trade Control Act
Ship Safety Act:::

Civil Aeronautics Law:

Port Regulation Law:

Waste Management on Public
Cleansing Law
Waterworks Law:

Sewerage Law:

Japanese Pollutant Release andTransfer Register Law (PRTR Law)
Labor Standards Act::::

Corrosive Liquids (Ordinance on Industrial Safety and Health Law Art.
326)
Substances on dental health checkup (Act, Art.66, Para.3,
Enforcement Order, Art.22 Item 3)
Not applicable
Hazardous Substances (Act, Art.2, Enforcement Order Art.2,
Ministerial Ordinance to Provide for Effluent Standards, Art.1)
Designated Chemical Substances (Law Article 2, Paragraph 4,
Enforcement Order Article 3-3)
Living Environment Pollution Itemes (Act, Art.2, Enforcement Oder,Art.3, Ministerial Ordinance to Provide for Effluent Standards, Art.1,Appended Table 2)
Not applicable
Hazardous Air Pollutants (Central Environment Council Report No. 9)
Export Trade Control Ordinance appendix 1-16
Corrosive substances (Dangerous Goods Notification Schedule firstsecond and third Article Dangerous Goods Regulations)
Corrosive substances (Hazardous materials notice Appended Table 1
Article 194 of the Enforcement Regulations)
Corrosive substances (Article 21, Paragraph 2 of Law, Article 12 rule,
notice attached table that defines the type of dangerous goods)
Specially Controlled Industrial Wastes (Act Art.2, para 5, Enfothment
Order Art.2-4 )Hazardous Substances (Act Article 4 paragraph 2), Standard for
Water Quality (Ministry Order No.101 of 2003)
Substances for Water Quality Standard (Act Art.12-2 Para.2,Enforcement Order Art.9-4)
Not applicable:

Chemical Substances Causing Occupational Illnesses (Act Art.75,Para.2, Ordinance Attached Table 1-2, Item 4-1,MHLW Nortification
No.36 of 1978

Data sources:

Other information:

Handbook of 17322 Chemical Products, The Chemical Daily Co, Ltd.
International Chemical Safety Cards.
National Institute of Technology and Evaluation (NITE).
2020 Emergency Response Guidebook (ERG 2020).
The SDS is copyrighted material of Hayashi Pure Chemical Ind, Ltd.
This Safety Data Sheet is intended to be provided for business
operators who handle chemical substance products of the relevant
product and is not intended to assure safety in any way. The Safety
Data Sheet does not verify all the information on the applicablechemical substance in the present time. With the recognition in that
unknown danger constantly exists in the relevant chemical substance,
the product shall be used in the principle of self-responsibility of theuser with the highest priority to safety from transport and unpacking todisposal. When the relevant chemical substance is used, the user
him/herself shall collect safety information and shall investigate laws
and regulations at the place, organizations, countries, etc. where thesubstance is actually used and give the highest priority to them. TheCompany shall take no responsibility for investigating state and local
regulations and the user shall handle this problem on his/her own
responsibility. In the event that SDS in Japanese and SDS translated
into other languages exist, the document described in Japanese isprior to all other documents whether or not there is any difference incontents, and documents in other languages shall be references.

16. Other information

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