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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: DAIFLOIL No.50, 100
Article number: 51
1.2 Relevant identified uses of the substance or mixture and uses advised against:
No further relevant information available.
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
DAIKIN INDUSTRIES, LTD. CHEMICALS DIVISION:
Umeda Center Bldg., 4-12, Nakazaki-Nishi 2-chome, Kita-Ku, Osaka, JAPAN
Phone: (+81) 6-6373-4345 Fax: (+81) 6-6373-4281
Further information obtainable from: http://www.daikin.com/
1.4 Emergency telephone number:
Japan: +81-6-6349-7521
China: +86-512-5-232-0949, +86-21-34151689
South Korea: +82-2-568-1722
Americas: +1-256-306-5000
Europe: +49-211-179 225-0+82-2-568-1722*

SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified, according to the CLP regulation.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008: Not applicable
Signal word: Not applicable*SECTION 3: Composition/information on ingredients
Information on ingredients:
CAS: 9002-83-9 Polychlorotrifluoroethylene

100%

SECTION 4: First aid measures
4.1 Description of first aid measures
General information: Seek immediate medical advice.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: If symptoms persist consult a doctor.
4.2 Most important symptoms and effects, both acute and chronic: No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
*SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
For safety reasons unsuitable extinguishing agents: None
5.2 Special hazards arising from the substance or mixture:
Formation of toxic gases is possible during heating or in case of fire.
Hydrogen chloride (HCl)Hydrogen fluoride (HF)
(Contd. on page 2)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL No.50, 100(Contd. of page 1)

5.3 Advice for firefighters:
Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear fully protective suit.
*SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation before entering the area.
Keep out unauthorized persons.
Wear appropriate protective devices (See Section 8 Exposure Controls/Personal Protection).
Avoid contact with eyes and skin.
Do not inhale the product.
6.2 Environmental precautions: Do not allow product to reach sewage system or any water course.
6.3 Methods and material for containment and cleaning up:
For a small amount of leakage: Absorb with liquid-binding material (sand, diatomite, acid binders, universalbinders) or collect in an empty container that can be sealed tightly.
For a large amount of leakage: Enclose with banks to avoid outflow. Lead the leakage to a safe place and collect.
6.4 Reference to other sections:
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

*SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Do not handle until all safety precautions have been read and understood.
Ensure good ventilation/exhaustion at the workplace.
7.2 Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool and dry location.
Keep containers tightly sealed.
Information about storage in one common storage facility:
See section 10 for information on incompatible materials.
Further information about storage conditions:Store containers in a well ventilated area.
Protect from heat and direct sunlight.
7.3 Specific end use(s): No further relevant information available.

*SECTION 8: Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace: Not required.
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Keep away from tobacco products.
Do not eat or drink while working.
Respiratory protection:
Use respiratory protective device with filters for organic and acid gas (or airline respirators in some cases), if theproduct is heated above 100 ℃ and toxic gases is formed.
Use respiratory protective device with organic gas cartridge.
Protection of hands: Synthetic rubber gloves(Contd. on page 3)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL No.50, 100(Contd. of page 2)

Material of gloves: Rubber
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Safety glasses
Body protection: Protective work clothing*SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
AppearanceSoft wax ~ Wax (at 25℃)
Form:
Semi-transparent
Colour:OdourlessOdour:No further information available.
pH-value:No further information available.
Melting point/freezing point:
Initial boiling point and boiling range: No further information available.
Flash point:
Explosive properties:

Not applicable.
Product does not present an explosion hazard.

Explosion limits:
Lower explosive limit:
Upper explosive limit:

No further information available.
No further information available.
No further information available.

Vapour pressure:No further information available.

Density:

No further information available.

Solubility in / Miscibility withwater:

Not miscible or difficult to mix.

Partition coefficient: n-octanol/water: No further information available.
No further relevant information available.
9.2 Other information:

SECTION 10: Stability and reactivity
10.1 Reactivity No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.
Even at the temperatures reached during the normal hot processing of fluoropolymers, fume that presents a potential
health hazard may be generated.
10.3 Possibility of hazardous reactions: No dangerous reactions known.
10.4 Conditions to avoid: No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: Danger of toxic fluorine based pyrolysis products.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity no data
LD/LC50 values relevant for classification: No further information available.
Primary irritant effectSkin corrosion/irritation Based on available data, the classification criteria are not met.
(Contd. on page 4)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL No.50, 100(Contd. of page 3)

Serious eye damage/irritation Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
Chronic study No further information available.

SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability: No further relevant information available.
Other information: The product is insoluble in water and the biodegradation and ecotoxicity is expected to be low.
12.3 Bioaccumulative potential: No further relevant information available.
12.4 Mobility in soil: No further relevant information available.
12.5 Results of PBT and vPvB assessment
PBT:
No further relevant information available.
Not applicable.
vPvB:
No further relevant information available.
Not applicable.
12.6 Other adverse effects: No further relevant information available.

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation: Disposal must be made according to official regulations.
Uncleaned packaging
Recommendation: Disposal must be made according to official regulations.
*SECTION 14: Transport information
14.1 UN-Number:
ADR, ADN, IMDG, IATA
14.2 UN proper shipping name:
ADR, ADN, IMDG, IATA
14.3 Transport hazard class(es):Not applicableNot applicable

ADR, ADN, IMDG, IATA
Not applicable
Class:
14.4 Packing group:
Not applicable
ADR, IMDG, IATA
14.5 Environmental hazards:
No
Marine pollutant:
Not applicable.
14.6 Special precautions for user:
14.7 Transport in bulk according to Annex II of
Not applicable.
MARPOL73/78 and the IBC Code:
Avoid direct sunlight. Make sure of no damage, corrosion, leaks onTransport/Additional information:
the receptacles.
Take necessary measures for preventing cargo shift.
Not applicable
UN "Model Regulation":(Contd. on page 5)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL No.50, 100(Contd. of page 4)

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Labelling according to Regulation (EC) No 1272/2008 Not applicable
Hazard pictograms Not applicable
Signal word Not applicable
Hazard statements Not applicable15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information
The product is for the industrial use only. We do not guarantee the safety in case the product is used for the otherpurposes. When using the product for health-care application or food/feed application, consult us in advance.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specificproduct features and shall not establish a legally valid contractual relationship.
Department issuing SDS: EHS Department
Contact: http://www.daikin.com/Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriageof Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and ToxicvPvB: very Persistent and very Bioaccumulative* Data compared to the previous version altered.