GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

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SECTION 1: IDENTIFICATION OF THE PRODUCT AND OF THE MANUFACTURER/SUPPLIER
1.1

1.2

Product Identifier:

Valve Regulated Lead-Acid (VRLA) Industrial Battery

Classification:

Battery, wet, non-spillable, electric storage (Mixture)
Substance classification: UN 2800

Product Codes:

EN & ENL, NP, NPC, NPH, NPL, NPW, RE, REC, REW, SW, SWL, TEV, FXH, UXH, UXL,
Yucel, YPC and YFT Series of Industrial VRLA Batteries

Relevant Identified Uses Of The
Product And Uses Advised
AgainstRelevant identified uses:
Standby: Telecoms; UPS; alarm and security systems; emergency lighting; utility switching
Cyclic: Golf Trolleys, portable tools, portable lighting, wheelchairs, remote telemetry
Energy storage: Photovoltaic energy systems (PVES); wind turbines
Uses advised against:
Automotive, commercial, and agricultural SLI applications
Reason why uses advised against:
High starting and ignition current demands beyond the design of internal and external current
carrying components

1.3

Details Of The Supplier Of The
Safety Date Sheet

National Contacts:

1.4

Supplier:
Address:

GS Yuasa Battery Europe Ltd,
Unit 22, Rassau Industrial Estate,
Ebbw Vale, NP23 5SD
United Kingdom

Contact:
Tel:e-mail:Language:
Available:

Mike TAYLOR (Product Manager)(+44) 07733 302 242
mike.taylor@yuasaeurope.com
English language only
Office hours only: 8am to 4:30pm (08:00 to 16:30)

France:Contact:
Tel:e-mail:Language:

GS Yuasa Battery France S.A.
Christian RAYNAUD (Technical Manager)(+33) 0474-95-90-95
christian.raynaud@gs-yuasa.fr
French & English

Germany:
Contact:
Tel:e-mail:Language:

GS Yuasa Battery Germany GmbHThomas Wallraff (Manager Reserve & Renewable Energy &Technical)(+49) 02151-82095-27
Thomas.Wallraff@gs-yuasa.de
German & English

Iberia:Contact:
Tel:e-mail:Language:

GS Yuasa Battery Iberia S.A.
Fernando García (Industrial Division Sales Manager)(+34) 091 748 98 19
fernando.garcia@gs-yuasa.es
Spanish & English

Italy:
Contact:
Tel:e-mail:Language:

GS Yuasa Battery Italy Srl.
Marco FILIPPI (Technical Manager)(+39) 02-3800-91-08
marco.filippi@gs-yuasa.it
Italian & English

UK:
Contact:
Tel:e-mailLanguage:

GS Yuasa Battery Sales UK Ltd.
Matt JORDAN (General Manager)(+44) 01793-833-562
Matt.Jordan@gs-yuasa.uk
English language only

Contact:
Tel:
Opening Hours:
Language:
Available:

GS Yuasa Battery Manufacturing UK Ltd.
Mike TAYLOR (Product Manager)(+44) 07733 302 242
Only available during office hours, 8am to 4pm (08:00 to 16:00)
English language only
Office hours only: 8am to 4:30pm (08:00 to 16:30)

Emergency telephone number:If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

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SECTION 2: HAZARDS IDENTIFICATION – In the event of the internal battery components being exposed
2.1

Classification of the substance or mixture

According to Regulation(EC) No. 1272/2008 (CLP)
Full text of H phrases –see section 16

H314

Skin Corr.1A

H360FdRepr.1A

H372

STOT RE1

H400

Aquatic Acute 1

H410

Aquatic Chronic 1

Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label Elements
Labelling according to Regulation (EC) No. 1272/2008 (CLP)
Hazard Pictograms (CLP)

GHS05

GHS08

GHS09

Signal Word (CLP) - DANGER

Hazard Statements(CLP)

Precautionary
Statements (CLP)

H314

Causes severe skin burns and eye damage

H360FdMay damage fertility. Suspected of damaging the unborn child

H372

Causes damage to organs through prolonged or repeated exposure

H400

Very toxic to aquatic life

H410

Very toxic to aquatic life with long lasting effects

P201

Obtain special instructions before use

P202

Do not handle until all safety precautions have been read andunderstoodP260

Do not breathe dust/fume/gas/mists/vapours/spray

P264

Wash …. Thoroughly after handlingP270

Do not eat, drink or smoke when using this product

P273

Avoid release to the environment

2.3 Other Hazards
VRLA Battery

MechanicalElectrical

Chemical

VRLA Batteries can be heavy. Correct manual handling techniques and/or
mechanical lifting aides (e.g. Fork Lift Truck) must be used.
VRLA Batteries can contain large amounts of electrical energy which can give very
high discharge currents and severe electrical shock if the terminals are shortcircuited.
 The VRLA Battery presents no chemical hazards during the normal operation
provided the recommendations for handling, storage, transport and usage areobserved.
 VRLA Batteries emit hydrogen gas which is highly flammable and will form
explosive mixtures in air from approx. 4% to 76%. This can be ignited by a sparkat any voltage, naked flames or other sources of ignition.
 If the battery is broken and the internal components exposed, hazards may exist
which require careful attention.

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

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SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
3.1

Substances present in the productComponents
Classification
Substances
Approximate % Chemical
CAS No.
according toSymbol( W/W )
Regulation*Battery(EC) No.
1272/2008(ELP)1
Plate Grid
Metallic Lead
*40 to 50
Pb7439-92-1
Calcium< 0.1
Ca7440-70-2
Tin
*< 1
Sn
7440-31-5
Active
H360
Lead Monoxide
< 0.1
PbO
1317-36-8
Materials
H372
Lead Dioxide (Lead IV Oxide)*15 to 25
PbO2
1309-60-0
H400
Barium compound*< 2
Ba
7440-39-3
H410
Battery
Dilute Sulphuric Acid
10 to 20H2SO47664-93-9
H314Electrolyte
CaseStandard Grade, UL94:HB
5 to 109003-56-9
Material
 ABS (Acrylonitrile-Butadiene-Styrene
Copolymer)
Flame Retardant (FR) Grade, UL94:V0
5 to 109003-56-9
 ABS (Acrylonitrile-Butadiene-Styrene
Copolymer)*< 1.2%
79-94-7
 *Brominated aromatic compound*< 0.3%1309-64-4
 Antimony trioxide
Separator
Absorbent Glass Matt (AGM) Separator*1 to 365997-17-3
Material(100% Borosilicate Glass Microfibre)
Inorganic lead and battery electrolyte (Dilute Sulphuric Acid) are the main components of VRLA batteries. Other substances may bepresent but in small amounts dependant on battery type. Contact GS Yuasa Battery Manufacturing UK Ltd for further information.

SECTION 4: FIRST AID MEASURES FOR ACUTE EXPOSURE
This information is of relevance only if the VRLA Battery has suffered damage, is broken and persons have direct contact with the internal
components.
4.1
Description of first aid measures
Components
ActionPlate Grids andInhalation:
Remove the person from exposure to fresh air.
Active materials
Seek advice from a medical doctor
Ingestion
Wash out mouth with water and give plenty of water to drink. Do not induce vomiting.
Seek advice from a medical doctor
Skin Contact:
Wash off with plenty of water and soap to prevent accidental ingestion or inhalation
Seek medical advice if pain or rash does not reduce
Immediately irrigate with eyewash solution or clean water for at least 10 minutes, holding
Eye Contact:
the eyelids apart. Then take the person to hospital without further delay
Self-protection
Eye protection (safety glasses or face shield), and heavy-duty gloves are required.
for the first aider
In case of inhalation, a face mask or respirator may be required.
Battery Electrolyte
SPEED IS ESSENTIAL - OBTAIN IMMEDIATE MEDICAL ATTENTION.
Inhalation:
Ingestion

Skin Contact:

Eye Contact:

Case Material

Self-protection
for the first aider
Inhalation:

Remove the person from exposure to fresh air.
If the person continues to feel unwell seek advice from a medical doctor.
Wash out mouth with water and give plenty of water to drink.
Do not induce vomiting.
If the person continues to feel unwell seek advice from a medical doctor.
Drench with large quantities of water.
Remove contaminated clothing and place in water to dilute the acid
Continue to wash the affected area for at least 10 minutes.
Seek advice from a medical doctor
SPEED IS ESSENTIAL - OBTAIN IMMEDIATE MEDICAL ATTENTION
Immediately irrigate with eyewash solution or clean water for at least 10 minutes, holding
the eyelids apart. Then take the person to hospital without further delay
Eye protection (safety glasses or face shield), and heavy-duty gloves are required.
In case of inhalation, a face mask or respirator may be required.
Material can burn in a fire with toxic smoke and decomposition products.
Upon inhalation of decomposition products, keep patient calm, remove to fresh air, andseek advice from a medical doctor. If a large quantity is inhaled take the person tohospital.
Note to physician: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

Ingestion
Skin Contact:

Eye Contact:

Separator Material

Self-protection
for the first aider
Inhalation:
Ingestion
Skin Contact:
Eye Contact:

Self-protection
for the first aider

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Wash out mouth with water and give plenty of water to drink. Do not induce vomiting.
If the person continues to feel unwell seek advice from a medical doctor.
Areas affected by molten material should be quickly placed under cold running water and asterile protective dressing applied.
Seek advice from a medical doctor.
May cause irritation or injury due to mechanical action and traces of Battery Electrolyte.
Immediately irrigate with eyewash solution or clean water for at least 10 minutes, holding
the eyelids apart. Then take the person to hospital without further delay
Eye protection (safety glasses or face shield), and disposable gloves are required.
In case of inhalation, a face mask or respirator may be required.
Remove patient from exposure to fresh air. If irritation persists, seek advice from a medical
doctor
Wash out mouth with water and give plenty of water to drink. Do not induce vomiting. If theperson continues to feel unwell seek advice from a medical doctor.
After contact with skin, wash immediately with plenty of soap and water. If irritation
persists, seek advice from a medical doctor
May cause irritation or injury due to mechanical action and traces of Battery Electrolyte.
Immediately irrigate with eyewash solution or clean water for at least 10 minutes, holding
the eyelids apart. Then take the person to hospital without further delay
Eye protection (safety glasses or face shield), and disposable gloves are required.
In case of inhalation, a face mask or respirator may be required.

SECTION 5: FIRE-FIGHTING AND EXPLOSION HAZARD MEASURES
5

VRLA Battery

General Information:
Explosion Hazard

 VRLA Batteries emit hydrogen gas which is highly flammable and will form
explosive mixtures in air from approx. 4% to 76%. This can be ignited by aspark at any voltage, naked flames or other sources of ignition.
 Batteries in use will be part of an electrical circuit and must be isolated fromthe power source before attempting to put out a fire. Switch the power OFF
before disconnecting the batteries from the power source.
 Damaged batteries may expose negative plates, grey in colour, which may
ignite if allowed to dry out. These plates may be wetted down with water
after the battery has been removed from all electrical circuits.

5.1

Suitable Extinguisher types:

CO2; Foam; Dry Powder.
Water extinguishers must never be used to put out an electrical fire.

5.2

Unsuitable Extinguisher
types
Hazardous combustion &decomposition products:
Advice for fire-fighters

5.3

Carbon monoxide, Sulphur Dioxide, Sulphur Trioxide, Lead fume and vapour,toxic fumes from decomposition of battery case materials.
Full face visor or safety goggles;
Respiratory equipment or self-contained breathing apparatus (SCBA);
Full acid resistant protective clothing must be worn in fire-fighting conditions.

SECTION 6: ACCIDENTAL RELEASE MEASURESThis information is of relevance only if the VRLA Battery has suffered damage and is broken.
6Components
VRLA Battery
VRLA batteries are designed to be safe to handle and not to leak battery
electrolyte under normal conditions.
In case of accidental damage heavy-duty gloves are required to pick-up thebattery to protect against unseen electrolyte leakage
Plate Grids andActive Materials

Personal Precautions:Clean-up Methods:

Environmental Precautions:

Battery Electrolyte:

Personal Precautions:

Eye protection (safety glasses or face shield), and heavy-duty gloves are
required.
If the material is wet, a face mask or respirator is not required
If the material is dry, a face mask or respirator is required
Large, solid pieces may be picked up and bagged for recycling.
Never use a brush to sweep up debris; it may create Lead-dust in the air.
Wet clean the spill area to remove all traces of debris. Battery debris andcleaning materials must be collected and placed in an inert sealed container(e.g. self-seal plastic bag or bucket) for disposal, see Section 13.
Do not allow material to enter a watercourse. Exposed Lead materials must beplaced in an inert sealed container (e.g. self-seal plastic bag or bucket) for
disposal, see Section 13.
Ensure suitable, acid resistant personal protective clothing (including heavyduty gloves, safety glasses and respiratory protection) is worn during removal
and clean-up of spillages.

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

Clean-up Methods:
Small spillages:

Large spillages:

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Neutralise and absorb the spillage using soda ash, sodium bicarbonate(available from supermarkets), sodium carbonate or calcium carbonate
powder.
Wet clean the spill area to remove all traces of debris. Battery debris andcleaning materials must be collected and placed in an inert sealed container(e.g. self-seal plastic bag or bucket) for disposal, see Section 13.
Large amounts of electrolyte spillage are unlikely with VRLA batteries since theelectrolyte is fully absorbed in the active materials and separator.
Bund the spillage area using dry sand, earth, sawdust or other inert material.
Neutralise the electrolyte using soda ash, sodium bicarbonate (available fromsupermarkets), sodium carbonate or calcium carbonate powder.
Wet clean the spill area to remove all traces of debris and electrolyte.
Cleaning materials must be collected and placed in an inert sealed container(e.g. self-seal plastic bag or bucket) for disposal, see Section 13.

Environmental Precautions:

Battery electrolyte must not be allowed to enter any drains or sewage systemor water course.

Case Material:

Clean-up Methods:

Separator Material:

Clean-up Methods:

Assume battery case material is contaminated and proceed as for Plate Grids
and Active Materials above.
Assume battery case material is contaminated and proceed as for Plate Grids
and Active Materials above.

Note: If appropriate refer to 8 and 13

SECTION 7: HANDLING AND STORAGE
7.1

Component:
VRLA Battery

7.2

7.3

Precautions For Safe
Handling:

Conditions For Safe
Storage, Including Any
Incompatibilities:

End-of-Life(EC WEEE Regulations)
Specific End Uses:
Installation:

Only trained operators should be allowed to handle VRLA batteries.
PPE: No specialist protective clothing or equipment is required, except that forhandling heavy weights.
Hygiene: There are no specialist requirements beyond good, standard
workplace practices,
Mechanical lifting aides: (e.g. FLT and pallet trucks) will be required to movepallets of batteries. Weight approximately 1 tonne
Mechanical handling aides: (e.g. trucks and lifters) will be required to handle
individual batteries over 25 kg in weight.
General Safety Considerations:
Do not drop batteries: dents and deformation of the case may be an indicationof internal damage to the battery. Cracks will allow electrolyte to escape.
Do not place VRLA Batteries lid-to-lid so that terminals will short-circuit.
Store VRLA Batteries in a cool, well-ventilated area with a solid, impervious
surface, and adequate containment in the event of accidental acid spillage.
Store under a roof and protect against direct sunlight and adverse weather
conditions including rain, snow and other sources of water.
Storage of large quantities of VRLA batteries may require approval from local
environmental protection agency and/or local water authorities.
Pallets of VRLA Batteries are heavy. Store at ground level or in lower levels of
storage systems (e.g. racking).
Take special care in dry conditions to avoid the risk of electrostatic discharges.
Protect against physical damage and exposure to organic solvents and otherincompatible materials.
Do not store VRLA batteries close to sources of heat, naked flames andsparks.
Store batteries in their original packaging wherever possible. When batteries
are removed from their original packaging (e.g. for transportation of small
quantities), ensure new packaging protects the batteries from damage and therisk of short-circuit of the terminals.
Ensure batteries are removed from equipment at the end of life and arecollected for recycling by an approved contractor.
1. Refer to EN 50272-1:2010, Safety requirements for secondary batteries
and battery installations – Part 1 General safety information.
2. Refer to EN 50272-2:2001, Safety requirements for secondary batteries
and battery installations – Part 2 Stationary batteries.

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

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Issue No:

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SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION
8.1

Components
VRLA Battery

Control Parameters:

8.2

Exposure Control:

8.3

Personal Protection:

There are no special control parameters for the handling, storage, installation of
VRLA Batteries.
VRLA Batteries emit hydrogen gas which is highly flammable and will form
explosive mixtures in air from approximately 4% to 76%. Never install VLRA
Batteries in a gas-tight enclosure during storage, transport or usage.
There are no special exposure controls for the handling, storage, installation or
use of VRLA Batteries.
When there is no evidence of damage or visible traces of liquid (electrolyte) or
solid deposits on the batteries they may be handled safely without extra
personal protective equipment.
Ensure electrical insulation equipment is used when installing batteries.
(e.g. insulated mats and covers; insulated tools)
Remove ALL metallic objects from the person when working with VRLA
Batteries: e.g. Jewellery (rings, watches, bracelets, necklaces), pens, torches,etc.

UL CAUTIONARYSTATEMENT:

Where there are signs of damage or liquid (electrolyte) or solid deposits, rubber
gloves and acid resistant clothing must be worn when handling the batteries
and affected packaging to protect against the effects of any electrolyte that may
be present.
If it is suspected that free electrolyte is present, then safety glasses must be
worn, and if large amounts are present, chemical goggles or face shield should
be used.
“Warning: Risk of fire, explosion, or burns. Do not disassemble; heat above
50°C; or incinerate”.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Components
VRLA Battery

 The main components are listed in SECTION 2 above.
 The undamaged product is a manufactured article in an inert plastic (ABS) case, which will burn if
subjected to high temperatures or sources of ignition. Some battery types are made with Flame Retardant
ABS cases, see technical specification. These batteries carry the suffix ‘FR’ after the battery type; e.g.
NP24-12IFR
The information below refers to the physical and chemical properties of the main VRLA Battery components and substances. This information
is published for reference only.
Plate Grids andAppearance
Safety-related data
Active materials:
Form Solid
Solidification point 327 °C
Colour Grey or brown
Boiling point 1740 °C
Odour Odourless
Solubility in water Very low (0.15mg/l)
Solubility in acid or Yes, dependant on the strength ofalkaline solutions solution.
Density (at 20°C) 11.35 g/cm3
Vapour pressure (at 20°C) *Undetectable
Battery Electrolyte:
Form Liquid
Solidification point -35 to -60 °C
Colour Colourless
Boiling point Approx. 108 to 114 °C
Odour Odourless
Solubility in water Complete
Density (at 20°C) Variable up to 1.350 g/cm3
Vapour pressure (at 20°C) *10-20 mmHg
Case Material:
Appearance
Safety-related data
Form Solid
Softening point > 100 °C (DIN 53460)
Colour Grey or blackFlash Point >330 °C
Odour Slight Odour
Solubility in water Insoluble
Solubility in other solvents Soluble in polar solvents, aromaticsolvents, chlorinated hydrocarbons.
Density (at 20°C) 1.07-1.4 g/cm3 (DIN 53479)
Vapour pressure (at *Undetectable*20°C)
9.1

Separator Material:
Form
ColourOdour

Fibrous material
White
Odourless

Solidification point
Boiling point
Solubility in water
Density (at 20°C)
Vapour pressure (at 20°C)*820°C*>2500°C
Insoluble*2.23g/cm3*Undetectable

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

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SECTION 10: STABILITY AND REACTIVITY
Components
VRLA Battery

Stability:

Within the operational temperature range -20 to +50 °C theundamaged product is stable.

10.4

Plate Grids andActive materials:

Materials & Conditions to
Avoid:

10.3

Battery Electrolyte:

Possibility of Hazardous Reactions

Powdered Lead reacts violently with fused ammonium nitrate andsodium acetylide. Reacts violently when in contact with chlorine
trifluoride.
 Dilution of the higher concentrated grades with water may liberate
excessive heat.
 Highly reactive with metals and organic materials.
 On contact with metals, may generate hydrogen which forms explosive
mixtures with air.
 Destroys organic materials such as cardboard, wood, textiles, etc.
 Vigorous reaction with sodium hydroxide and alkalis.

Sulphur oxides

10.1

10.6
10.1

Case Material:

10.6
10.1

Separator Material:

10.4
10.6

Hazardous Decomposition
Product(s):Materials & Conditions to
Avoid:

 To avoid thermal decomposition, do not overheat.
 Starts to decompose at temperatures >275oC.
 Powerful oxidising agents.

Hazardous decomposition
products:
Stability:

 Monomers, other degradation products, traces of hydrogencyanide.
 Stable material.

Materials & Conditions to
Avoid:
Hazardous decomposition
products:

 Incompatible with Hydrofluoric acid and concentrated Sodium
Hydroxide.
 No hazardous polymerisation expected.

SECTION 11: TOXICOLOGICAL INFORMATIONThis information is of relevance only if the VRLA Battery has suffered damage and is broken.
Components
11
VRLA Battery
 This information does not apply to the undamaged VRLA Battery. It isof relevance if the battery is broken and the components are released
to the environment.
 Exposure limits may vary according to national law and regulations.
11.1
Plate Grids:
Acute Toxicity
 Toxic by ingestion or inhalation
Metallic Lead, Chronic poison
Lead alloys.
 Lead is a poison that affects virtually every system in the body Symptoms include fatigue, headaches, constipation, aching bones andmuscles, gastrointestinal tract disturbances and reduced appetite
 Blood Lead levels of 80 µg/dl and above have been associated withboth acute and chronic effects of Lead poisoning
Active materials:
Lead dioxide.

Acute Toxicity

Battery Electrolyte:

Corrosive

Inhalation:2

 Toxic by ingestion or inhalation
 Chronic poison
 Chronic exposure to Lead compounds may lead to a build-up of Lead in
the body, giving rise to a variety of health problems, including anaemia,
kidney and liver damage, impaired eyesight, memory loss and CNS2
damageCorrosive, the more concentrated solutions can cause serious burns to
the mouth, eyes and skinHarmful by ingestion and through skin contact

Mist is a severe irritant to the respiratory tract. Fluid build-up on the lung(pulmonary oedema) may occur up to 48 hours after exposure and could prove
fatal

CNS = Central Nervous System

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

11.1

Battery Electrolyte:

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Ingestion:Will immediately cause severe corrosion of and damage to the gastrointestinal
tract

Skin Contact:

Causes severe chemical burns

Eye Contact:

Risk of serious damage to eyes. Causes severe burns. May cause prolonged or
permanent damage or even total loss of sight. Mist will cause irritation

Case Material:

According to information available the product is not harmful to healthprovided it is correctly handled and processed according to the given
recommendations.
Based on animal implantation and epidemiologic studies glass microfibers
are thought to have some limited carcinogenic potential and as such aredesignated as Group 2B materials (IARC, US). The material should betreated as a category 3 carcinogen (Europe).
Limited evidence of carcinogenic effect.

Separator Material:

SECTION 12: ECOLOGICAL INFORMATIONThis information is of relevance only if the VRLA Battery has suffered damage and is broken.
Components
12.1
VRLA Battery
This information does not apply to the undamaged VRLA Battery. It is of
relevance if the battery is broken and the components are released to theenvironment.
12.2
Plate Grids andMetallic Lead, Lead alloys andChemical and physical treatment is required for the elimination of Lead
Active materials:
Lead dioxide.
from water. Waste water containing Lead must not be disposed of in an
untreated condition.

Ecotoxicity:

H Phrase H400 &410
Effect in the aquatic
environment:

12.3

12.4

Battery Electrolyte:

Case Material: Lead metal in massive form is not classified as hazardous to theaquatic environment, due to its low solubility and rapid removal from thewater column. Inorganic lead compounds are considered to be acutely
toxic in the environment and also to present a long-term hazard toaquatic organisms.

 Toxicity for fish: Toxicity for daphnia:
 Toxicity for alga:

96 h LC 50 > 100 mg/l
48 h EC 50 > 100 mg/l
72 h IC 50 > 10 mg/l

Persistence and Degradation:

 In order to avoid damage to the sewerage system, the acid has to be
neutralised by means of soda ash, sodium bicarbonate or sodium
carbonate before disposal.
 Ecological damage is possible by change of pH. The electrolyte
solution reacts with water and organic substances, causing damage toflora and fauna.
 The electrolyte may also contain components of Lead that can be toxic
to aquatic environments.
Remains indefinitely in the environment as sulphate.

Elimination information:
Behaviour and environmental
fate:

No data available: insoluble in water
Due to the consistency of the product, and its insolubility in water, it willapparently not be bio-available.

Ecotoxicity:

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

12.5

Separator Material:

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9 of 11No data available: insoluble in waterNot thought to pose any risk to the environment.

SECTION 13: DISPOSAL CONSIDERATIONS
13.1

Components
VRLA Battery

Europe:Worldwide:

13.2

Plate Grids andActive materials:

EuropeWorldwide

13.3

Battery Electrolyte:

EuropeWorldwide
General

13.3

Case Material:

13.4

Separator Material: Spent (used) VRLA Batteries are subject to the requirements of theBatteries Directive 2006/66/EC on batteries and accumulators andwaste batteries and accumulators. Spent (used) VRLA Batteries MUST
be sent for recycling through an authorised contractor at the end-of-life.
 The WEEE Directive 2002/96/EC (Waste Electrical and Electronic
Equipment) applies. Spent (used) VRLA Batteries MUST be removed
from electrical and electronic equipment at the end-of-life.
 VRLA batteries contain inorganic Lead compounds and Sulphuric Acid
which are damaging to the environment.
 Spent (used) batteries must be disposed of in an environmentallyfriendly manner in accordance with local national laws and regulations.
 VRLA batteries must not be dismantled, burnt or incinerated as a meansof disposal.
 At the end of life VRLA batteries may still be electrically ‘live’ and containa large amount of electrical energy. The same care and attention tosafe handling should be taken as when handling new batteries.
Particular care must be taken to avoid short-circuiting the battery
terminals.
 Metallic Lead and active materials (Lead Oxides) must be recycled.
 Disposal must be carried out in accordance with the European
Hazardous Waste Directive 2008/98/EC
 Disposal must be carried out in accordance with the European
Hazardous Waste Directive 2008/98/EC on the protection of theenvironment through criminal law
 Disposal should be in accordance with local, state or national legislation.
 Battery electrolyte is dilute Sulphuric Acid, the strength of which
depends on the state of charge of the batteries. It must be neutralised
before disposal. See SECTION 6 for clean-up and disposal advice.
 Do not dispose of this product into sewers, any ocean or water course inorder to prevent marine animals and birds from ingesting.
 Recycling is encouraged.
 Disposal by controlled incineration or source landfill in accordance withlocal national laws and regulations may be acceptable.
 Constitutes a special waste by virtue of hazardous substance content.
 Dispose of via approved landfill site. Disposal by controlled source
landfill in accordance with local national laws and regulations may be
acceptable.

SECTION 14: TRANSPORT INFORMATION
14.1

Components
VRLA Battery

Land Transport

Sea Transport

Air Transport

Land Transport (ADR / RID)
 UN No: UN2800
 Classification ADR / RID: Class 8
 Proper Shipping Name: BATTERIES, WET, NON-SPILLABLE electric
storage Packing Group ADR: not assigned
 Tunnel code: E ADR / RID: New and spent (used) batteries are exempt from all ADR /RID (special provision 598)
Sea transport (IMDG Code) UN No: UN2800
 Classification: Class 8
 Proper Shipping Name: BATTERIES, WET, NON-SPILLABLE electric
storage
 EmS: F-A, S-B
Non-Spillable batteries meet the requirements of Special Provision 238*parts 1 & 2; they are exempt from all IMDG codes and are not subject tospecial regulation for sea transport
Air Transport (IATA-DGR)
 UN No: 2800
 Classification: Class 8
 Proper Shipping Name: BATTERIES, WET, NON-SPILLABLE electric
storage

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

Document:

SDS 01

Issue No:

18

Issue Date:

02.06.2021

Page:

10 of 11

 Special Provision A48: Packaging test are not considered necessary
 Special Provision A67: Yuasa’s VRLA batteries meet the requirementsof Packing Instruction 872.
The battery has been prepared for transport so as to prevent:a) A short-circuit of the battery’s terminals by packaging in a strong andsturdy carton box; AND/ORb) The battery has been fitted with an insulating cover (made from ABS)
which prevents contact with the terminals.
c) Unintentional activation is thus prevented
The words “NOT RESTRICTED” and the Special Provision (SP) number
must be indicated on all shipping documents
 Special Provision: A164: The battery has been prepared for transport so
as to prevent:a) Short-circuit of the battery’s terminals by packaging in a strong andsturdy carton box; AND/ORb) The battery has been fitted with a cover (made from ABS) which
prevents contact with the terminalsc) Unintentional activation is thus prevented

SECTION 15: REGULATORY INFORMATION
15.1

Components
VRLA Battery

Required Markings:
Crossed-out wheeled bin indicating “SEPARATE COLLECTION” for all
batteries and accumulators. Not to be disposed of with general domestic,
commercial or industrial waste.
Ref: The Batteries Directive 2006/66/EC
The Pb symbol indicates the heavy metal content of the battery andenables the Lead-Acid battery to be sorted for recycling.
Ref: The Batteries Directive 2006/66/EC.
The International Recycling Symbol, required by law in many countries
world-wide to facilitate the identification of secondary batteries andaccumulators for recycling.
Ref: IEC 61429 : 1995, Marking of secondary cells and batteries with theInternational Recycling Symbol ISO 7000-1135.
Directive 2006/66/EC, on batteries and accumulators and waste batteries
and accumulators
Paragraph (Recital) 29 states:“Directive 2002/95/EC of the European Parliament and of the Council of 27
January 2003 on the restriction of the use of certain hazardous substancesin electrical and electronic equipment does not apply to batteries andaccumulators used in electrical and electronic equipment.”

EC Directives

SECTION 16: OTHER INFORMATION
16(a)Components
Revision
Information*Issue18 : 02/06/2021
Amended section 3.1 component % to w/w per battery

16(b)

Abbreviations

Pb – the chemical symbol for Lead
Ba – the chemical symbol for Barium
Ca – the chemical symbol for Calcium
Sn – the chemical symbol for Tin
PbO2 – the chemical formulae for Lead Dioxide
H2SO4 – the chemical formulae for Sulphuric Acid
VRLA – Valve Regulated Lead-Acid battery

16(c)

Key literaturereferences andsources of data

SDS documents from suppliers for components and raw materials

16(d)Full text of Hphrases:Aquatic Acute 1

Hazardous to the aquatic environment — Acute Hazard, Category 1

Aquatic Chronic 1

Hazardous to the aquatic environment — Chronic Hazard, Category 1

Repr. 1A

Reproductive toxicity, Category 1A

Skin Corr. 1A

Skin corrosion/irritation Category 1A

If this document is printed, it is to be considered uncontrolled and for reference only.

GS Yuasa Battery Europe Ltd.
SAFETY DATA SHEETIn accordance with REACH Regulation EC No. 453/2010

16(e)Training Advice

16(f)Further
Information

Document:

SDS 01

Issue No:

18

Issue Date:

02.06.2021

Page:

STOT RE 1

Specific target organ toxicity (repeated exposure) Category 1

H314

Causes severe skin burns and eye damage

H360

May damage fertility or the unborn child

H360FdMay damage fertility. Suspected of damaging the unborn child

H372

Causes damage to organs through prolonged or repeated exposure

H400

Very toxic to aquatic life

H410

Very toxic to aquatic life with long lasting effects

11 of 11 Only trained, competent personnel, who have received special instructions for the hazards and risks, should beallowed to handle VRLA Batteries.
 See Section 7.1 for general advice
To ensure the safe use of VRLA Industrial Batteries supplied by YUASA, the following precautions must be
observed: Warning: Risk of fire, explosion, or burns. Do not disassemble, heat above 50°C, or incinerate.
 Never short-circuit battery terminals, since sparks and arcs produced can injure personnel and are a fire andexplosion hazard.
 Batteries must always be charged on a voltage-regulated charging system with adequate ventilation provided
to avoid the build-up of ignitable gases and to promote good heat dissipation.
 Do not charge VRLA Batteries above + 50 ºC, discharge or store above + 60 ºC.
 Under extreme conditions of charging equipment malfunction and/or battery failure, high voltage and hightemperature conditions may occur causing the evolution of Hydrogen Sulphide (H2S) gas, which is toxic. If
detected by its odour of rotten eggs (at extremely low concentrations), switch off the charging equipment,
evacuate all personnel from the area and ventilate well. Seek advice before attempting to re-start charging
 NEVER PLACE VRLA BATTERIES INSIDE SEALED OR GAS-TIGHT ENCLOSURES DURING
OPERATION, TRANSPORT AND STORAGE
VRLA Batteries emit hydrogen gas which is highly flammable and will form explosive mixtures in air fromapproximately 4% to 76%. This can be ignited by a spark at any voltage, naked flames or other sources ofignition

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product

If this document is printed, it is to be considered uncontrolled and for reference only.