IIၥ 1 㸦⟅㸧࢔㸸༢㔞య㸦ࡲࡓࡣࣔࣀ࣐࣮㸧 ࢖㸸㔜ྜయ㸦ࡲࡓࡣ࣏࣐࣮ࣜ㸧 ࢘㸸᭷ᶵ࢝㸸ྜᡂ ࢟㸸࣊࢟ࢧ࣓ࢳࣞࣥࢪ࢔࣑ࣥ ࢡ㸸࢔ࢪࣆࣥ㓟 ࢣ㸸⦰㸦ྜ㸧࢚㸸↓ᶵ࢜㸸ኳ↛

ၥ 2 㸦⟅㸧ၥ 3 ồࡵࡿศᏊ㔞ࢆ x ࡜ࡍࡿ࡜㸪ࣇ࢓ࣥࢺ࣍ࢵࣇࡢἲ๎ࡼࡾồࡵࡽࢀࡿࠋ
1.00 g702 Pa × 0.100 L =× 8.31 × 103 Pa · L/(mol · K) × 300 Kx g/mol··㸦· ⟅㸧! x = 3.55 × 104
ၥ 4 ࢼ࢖ࣟࣥ 66 ࡢศᏊ㔞ࡣᖹᆒ㔜ྜᗘ n ࢆ⏝࠸࡚ 226n + 18 ࡜⾲ࡏࡿࡢ࡛㸪

226n + 18 = 3.551 × 104! n = 157.0

࠙໬Ꮫ㸦ゎ⟅㸧ࠚ࡜࡞ࡿࠋࡼࡗ࡚㸪ồࡵࡿ࢔࣑ࢻ⤖ྜࡢᖹᆒಶᩘࡣḟࡢࡼ࠺࡟࡞ࡿࠋ

Iၥ 1 ཎᏊ౯ࡣ୙ᑐ㟁Ꮚࡢಶᩘ࡟➼ࡋ࠸ࠋ㸦⟅㸧࢔㸸5 ࢖㸸3 ࢘㸸㠀ඹ᭷㟁Ꮚᑐ㸦ࡲࡓࡣᏙ❧㟁Ꮚᑐ㸧 ࢚㸸㓄఩⤖ྜࠕM ࡢཎᏊ౯ࢆ l ࡜ࡍࡿ࡜㸪l ࡣ M=O ࡢᩘࢆ 2 ಸࡋࡓࡶࡢ࡜ MOH ࡢᩘࡢ࿴࡟➼ࡋ࠸ࠖ࠾ࡼࡧࠕ▮༳ࡢ⤖ྜࡣ❅⣲ࡢཎᏊ౯࡟↓㛵ಀ࡜࡞ࡿࠖ࡜࠸࠺グ㏙ࡼࡾ㸦࠙ὀࠚཧ↷㸧㸪࢜࢟ࢯ㓟 M(OH)m On ࡟ࡘ࠸࡚㸪M=O ࡢᩘࢆ a㸪M O ࡢᩘࢆ b ࡜ࡍࡿ࡜㸪l = 2a + m,lm!a=,2n=a+blmb=n2࡜࡞ࡿࡇ࡜ࡀศ࠿ࡿࠋ㢟ពࡼࡾ㸪M O ࡢᩘ b ࡀ኱ࡁ࠸࡯࡝ MOH ࡢ O ࡜ H ࡀษࢀࡸࡍࡃ࡞ࡗ࡚㓟ᛶࡀᙉࡃ࡞ࡾ㸪MOH ࡢᩘ m ࡀ኱ࡁ࠸࡯࡝ O ࡜ H ࡀษࢀ࡟ࡃࡃ࡞ࡗ࡚㓟ᛶࡀᙅࡃ࡞ࡿࠋࡼࡗ࡚㸪b  m ࡀ኱ࡁ࠸࡯࡝O ࡜ H ࡀษࢀࡸࡍࡃ࡞ࡿࡓࡵ㸪ᙉ࠸㓟࡟࡞ࡿࠋlmlm㸦⟅㸧࢜㸸࢝㸸n ࢟㸸ࡸࡍ22࠙ὀࠚ౯㟁Ꮚࡀ࢜ࢡࢸࢵࢺ๎ࢆ‶ࡓࡍ࡜࠸࠺๓ᥦ࡛ฟ㢟⪅ࡀ⪃࠼࡚࠸ࡿࡇ࡜ࡀศ࠿ࡿࠋ౛࠼ࡤ㸪H3 PO4 ࡢ P ࡣ 3ಶࡢ OH ࡜⤖ྜࡋ㸪ࡶ࠺ 1 ಶࡢ O ࡜ࡣ㓄఩⤖ྜࡋ࡚࠸ࡿ࡜⪃࠼࡚ (HO)3 P O ࡜⾲ࡍ᪉ἲ࡜㸪࢜ࢡࢸࢵࢺ๎ࢆ‶ࡓࡉࡎ (HO)3 P=O ࡜⾲ࡍ᪉ἲ࡜ࡀ࠶ࡿࡀ㸪๓⪅ࢆ᥇⏝ࡋ࡚࠸ࡿ࡜࠸࠺ࡇ࡜࡛࠶ࡿࠋ
ၥ 2 㸦⟅㸧2n  1 = 2 × 157.0  1 = 313 ᮏ··㸦· ⟅㸧

ၥ 5 㸦⟅㸧ࢱࣥࣃࢡ㉁㸪ࢼ࢖ࣟࣥ 6III
ၥ 1 1 mol ࡢࢢࣝࢥ࣮ࢫࡀ㓟໬ࡉࢀ࡚ 38 mol ࡢ ATP ࡀྜᡂࡉࢀࡓሙྜ࡟ࡘ࠸࡚⪃࠼ࢀࡤࡼ࠸ࠋ
38 mol × 30 kJ/mol
× 100 % = 41 %··㸦· ⟅㸧
1 mol × 2800 kJ/molၥ 2 ồࡵࡿ⇕໬Ꮫ᪉⛬ᘧࢆḟࡢࡼ࠺࡟⨨ࡃࠋ

C6 H12 O㸦ᅛ㸧
+ 2 ADP + 2 H3 PO4 = 2 CH3 CH(OH)COOH㸦ᾮ㸧+ 2 ATP + 2 H2 O㸦ᾮ㸧+ x kJ
6(1)ATP ࡀຍỈศゎࡉࢀ࡚ ADP ࡜ H3 PO4 ࡟ኚࢃࡿ࡜ࡁࡢ⇕໬Ꮫ᪉⛬ᘧࡣ
ATP + H2 O㸦ᾮ㸧= ADP + H3 PO4 + 30 kJ(2)࡜⾲ࡏࡿࡢ࡛㸪(2) ᘧࢆ (1) ᘧ࡟௦ධࡋ࡚

C6 H12 O㸦ᅛ㸧
= 2 CH3 CH(OH)COOH㸦ᾮ㸧+ (x + 60) kJ
6(3)ࢆᚓࡿࠋࡇࡇ࡛ CO㸦Ẽ㸧㸪H2 O㸦ᾮ㸧㸪O㸦Ẽ㸧ࡢ࢚ࢿࣝࢠ࣮ࢆ 0 kJ ࡜ࡍࡿ࡜㸪(3) ᘧࡼࡾḟࡢ㛵ಀࡀᡂࡾ❧ࡘࠋ
222800 = 2 × 1300 + (x + 60)! x kJ = 140 kJ㸦⟅㸧C6 H12 O㸦ᅛ㸧
+ 2 ADP + 2 H3 PO4 = 2 CH3 CH(OH)COOH㸦ᾮ㸧+ 2 ATP + 2 H2 O㸦ᾮ㸧+ 140 kJ6

ၥ 3 6 ಶࡢ࢜࢟ࢯ㓟࡟ࡘ࠸࡚ᵓ㐀ᘧ㸪b㸪m㸪b  m ࡢ್ࢆ♧ࡍ࡜ḟࡢࡼ࠺࡟࡞ࡿࠋb  m ࡢ್ࡀ኱ࡁ࠸࡯࡝ᙉ࠸㓟࡛࠶ࡿࠋ

ၥ 3 G1P ࡀ y mol/L ⏕ᡂࡋࡓ࡜ࡁ㸪G6P ࡢࣔࣝ⃰ᗘࡣయ✚ࡀኚ໬ࡋ࡞࠸࡜ࡋ࡚ (1  y) mol/L ࡛࠶ࡿࠋ␗ᛶ໬཯ᛂ࡟㛵ࡍࡿᖹ⾮ᐃᩘࢆ K3 = 5.3 × 102 ࡜⨨ࡃ࡜㸪㉁㔞స⏝ࡢἲ๎ࡼࡾ y ࡀồࡵࡽࢀࡿࠋ
[G1P]
K3 =(4)= 5.3 × 102[G6P]y mol/L=(1  y) mol/L! y mol/L = 5.0 × 102 mol/L··㸦· ⟅㸧ၥ 4 ၥ㢟࡛୚࠼ࡽࢀࡓᖹ⾮ᐃᩘࢆḟࡢࡼ࠺࡟⨨ࡃࠋ[ADP][H3 PO4 ]K1 == 2.2 × 105[ATP][H2 O][G6P][H2 O]= 3.8 × 103K2 =[C6 H12 O6 ][H3 PO4 ]㸦⟅㸧M O ࡢᩘ㸸㡰࡟ 0㸪3㸪0㸪1㸪1㸪2 㓟ࡢᙉࡉࡢ㡰␒㸸㡰࡟ 4㸪1㸪3㸪2㸪3㸪2
࠙ὀࠚH3 BO3㸦࣍࢘㓟㸧ࡣᘧ࠿ࡽண᝿ࡉࢀࡿ 3 ౯ࡢ㓟࡛ࡣ࡞ࡃ㸪1 ౯ࡢ㓟࡛࠶ࡿࠋB ࡟࠶ࡿ✵ࡢ㟁Ꮚ㌶㐨࡟ OHࢆ 1 ಶཷࡅධࢀࡿࡇ࡜࡟ࡼࡾ㓟ᛶࢆ♧ࡍࡓࡵ࡛࠶ࡿࠋ

(5)(6)

ồࡵࡿᖹ⾮ᐃᩘࢆ K4 ࡜ࡍࡿ࡜㸪(5) ᘧ࡜ (6) ᘧࡼࡾḟࡢࡼ࠺࡟ồࡵࡽࢀࡿࠋ
[G6P][ADP]
K4 =··㸦· ⟅㸧= K2 K1 = 3.8 × 103 × 2.2 × 105 = 8.4 × 102[C6 H12 O6 ][ATP]ၥ 5 ồࡵࡿᖹ⾮ᐃᩘࢆ K5 ࡜ࡍࡿ࡜㸪(4) ᘧ࡜ (6) ᘧࡼࡾḟࡢࡼ࠺࡟ồࡵࡽࢀࡿࠋ
[C6 H12 O6 ][H3 PO4 ]11K5 === 5.0 × 103=[G1P][H2 O]
K3 K2
5.3 × 102 × 3.8 × 103··㸦
· ⟅㸧

IV
ၥ 1 ศᏊ㔞࡜ඖ⣲⤌ᡂࡼࡾ㸪໬ྜ≀ A 㹼 H ࡢศᏊ㔞ࡣḟࡢࡼ࠺࡟ࡋ࡚ồࡵࡽࢀࡿࠋ
74 × 0.649
74 × 0.135
74 × 0.216= 4, H := 10, O :=1
IV C :
12116
㸦⟅㸧C4 H10 Oၥ 1 ศᏊ㔞࡜ඖ⣲⤌ᡂࡼࡾ㸪໬ྜ≀ A 㹼 H ࡢศᏊ㔞ࡣḟࡢࡼ࠺࡟ࡋ࡚ồࡵࡽࢀࡿࠋ
74 × 0.649 OH  CH
74 3×CH0.135
74 × 0.216
ၥ 2 㸦⟅㸧
2 OCHC : 2 CH3 CH2=4, H := 10, 2 CHO : 3 + H2 O = 1
12116ၥ 3㸦⟅㸧(b) ࡼࡾ㸪໬ྜ≀A 㹼 E ࡣ࢔ࣝࢥ࣮ࣝ㸪໬ྜ≀ F 㹼 H ࡣ࢚࣮ࢸ࡛ࣝ࠶ࡿࠋ(c) ࡼࡾ㸪໬ྜ≀ A ࡜ B ࡣ➨ 1 ⣭C4 H10 O
࢔ࣝࢥ࣮࡛ࣝ 1-ࣈࢱࣀ࣮ࣝ࡜ 2-࣓ࢳࣝ-1-ࣉࣟࣃࣀ࣮ࣝࡢ࠸ࡎࢀ࠿㸪໬ྜ≀ C ࡜ D ࡣ➨ 2 ⣭࢔ࣝࢥ࣮࡛ࣝ 2-ࣈ
ၥ 2 㸦⟅㸧
2 CH3 CH2 OH  CH3 CH2 OCH+ ࡣ➨
H2 O 3 ⣭࢔ࣝࢥ࣮࡛ࣝ 2-࣓ࢳࣝ-2-ࣉࣟࣃࣀ࣮࡛ࣝ࠶ࡿࠋ
2 CH3 Eࢱࣀ࣮ࣝ㸦஫࠸࡟ගᏛ␗ᛶయࡢ㛵ಀ࡟࠶ࡿ㸧㸪໬ྜ≀໬ྜ≀J ࡣ 2-ࣈࢱࣀࣥ㸦࢚ࢳ࣓ࣝࢳࣝࢣࢺࣥ㸧࡛࠶ࡿࠋ໬ྜ≀A ࢆศᏊෆ࡛⬺Ỉࡋ࡚ᚓࡽࢀࡿ࢔ࣝࢣࣥ࡜ࡋ࡚
ၥ 3 (b)ࡼࡾ㸪໬ྜ≀A 㹼 E ࡣ࢔ࣝࢥ࣮ࣝ㸪໬ྜ≀ F 㹼 H ࡣ࢚࣮ࢸ࡛ࣝ࠶ࡿࠋ(c) ࡼࡾ㸪໬ྜ≀ A ࡜ B ࡣ➨ 1 ⣭ࡣ 1-ࣈࢸࣥ CH2-࣓ࢳࣝࣉࣟ࣌ࣥCH2 =CH(CH3 )2 ࡢ࠸ࡎࢀ࠿ࡀ⪃࠼ࡽࢀࡿࡀ㸪Br2 ࢆ௜ຍࡋ2 =CHCH2 CH3࢔ࣝࢥ࣮࡛ࣝ
1-ࣈࢱࣀ࣮ࣝ࡜2-࡜࣓ࢳࣝ-1-ࣉࣟࣃࣀ࣮ࣝࡢ࠸ࡎࢀ࠿㸪໬ྜ≀C ࡜ D ࡣ➨ 2 ⣭࢔ࣝࢥ࣮࡛ࣝ
2-ࣈࡓ໬ྜ≀࡟୙ᩧⅣ⣲ཎᏊࡀ࠶ࡿࡢࡣ๓⪅ࡢ᪉࡛࠶ࡿࠋࡼࡗ࡚㸪໬ྜ≀A ࡣ 1-2ࣈࢱࣀ࣮ࣝ㸪໬ྜ≀B ࡣ 2-࣓ࢳࢱࣀ࣮ࣝ㸦஫࠸࡟ගᏛ␗ᛶయࡢ㛵ಀ࡟࠶ࡿ㸧㸪໬ྜ≀ E ࡣ➨ 3 ⣭࢔ࣝࢥ࣮࡛ࣝ
࣓ࢳࣝ-2-ࣉࣟࣃࣀ࣮࡛ࣝ࠶ࡿࠋ
ࣝ-1-ࣉࣟࣃࣀ࣮ࣝ࡜Ỵࡲࡾ㸪໬ྜ≀L ࡣ 1-ࣈࢸ࡛ࣥ࠶ࡿࠋ(e) ࡼࡾ໬ྜ≀F ࡣࢪ࢚ࢳ࢚࣮ࣝࢸࣝ㸪(f) ࡼࡾ໬ྜ໬ྜ≀J ࡣ 2-ࣈࢱࣀࣥ㸦࢚ࢳ࣓ࣝࢳࣝࢣࢺࣥ㸧࡛࠶ࡿࠋ໬ྜ≀A ࢆศᏊෆ࡛⬺Ỉࡋ࡚ᚓࡽࢀࡿ࢔ࣝࢣࣥ࡜ࡋ࡚
≀Hࡣ࢖ࢯࣉࣟࣆ࣓ࣝࢳ࢚࣮ࣝࢸࣝ࡜ศ࠿ࡿࡢ࡛㸪໬ྜ≀Gࡣ࣓ࢳࣝࣉࣟࣆ࢚࣮ࣝࢸ࡛ࣝ࠶ࡿࠋ
ࡣ 1-ࣈࢸࣥ CH2 =CHCH2 CH3 ࡜ 2-࣓ࢳࣝࣉࣟ࣌ࣥ CH2 =CH(CH3 )2 ࡢ࠸ࡎࢀ࠿ࡀ⪃࠼ࡽࢀࡿࡀ㸪Br2 ࢆ௜ຍࡋ㸦⟅㸧ࡓ໬ྜ≀࡟୙ᩧⅣ⣲ཎᏊࡀ࠶ࡿࡢࡣ๓⪅ࡢ᪉࡛࠶ࡿࠋࡼࡗ࡚㸪໬ྜ≀ A ࡣ 1-ࣈࢱࣀ࣮ࣝ㸪໬ྜ≀ B ࡣ 2-࣓ࢳ
ࣝ-1-ࣉࣟࣃࣀ࣮ࣝ࡜Ỵࡲࡾ㸪໬ྜ≀ L ࡣ 1-ࣈࢸ࡛ࣥ࠶ࡿࠋ(e) ࡼࡾ໬ྜ≀ F ࡣࢪ࢚ࢳ࢚࣮ࣝࢸࣝ㸪(f) ࡼࡾ໬ྜ≀ H ࡣ࢖ࢯࣉࣟࣆ࣓ࣝࢳ࢚࣮ࣝࢸࣝ࡜ศ࠿ࡿࡢ࡛㸪໬ྜ≀ G ࡣ࣓ࢳࣝࣉࣟࣆ࢚࣮ࣝࢸ࡛ࣝ࠶ࡿࠋ
ၥ 4㸦⟅㸧
㸦⟅㸧C㸪D࠙ὀࠚ໬ྜ≀ K㸦2-ࣈࢱࣀࣥ㸧ࡶ࣮ࣚࢻ࣒࣍ࣝ཯ᛂࡀ㝧ᛶࡔࡀ㸪໬ྜ≀ A 㹼 H ࡟ࡘ࠸࡚⟅࠼ࡿࡢ࡛ヱᙜࡋ࡞࠸ࠋ
ၥ 5 ྠⅣ⣲ᩘࡢ࢔ࣝࢥ࣮࡛ࣝẚ㍑ࡍࡿ࡜㸪ἛⅬࡢ㧗࠸㡰࡟㸪➨ 1 ⣭㸦໬ྜ≀ A ࡜ B㸧㸪➨ 2 ⣭㸦໬ྜ≀ C ࡜ D㸧㸪
ၥ 4 㸦⟅㸧
㸪D➨ 3C⣭㸦໬ྜ≀E㸧࡜࡞ࡿࠋࡇࢀࡣᚋࡢࡶࡢ࡯࡝ᯞศ࠿ࢀࡀከࡃ㸪ศᏊ㛫ࡢỈ⣲⤖ྜࡢᙧᡂࢆጉࡆࡿࡓࡵ࡛࠶ࡿ࠙ὀࠚ໬ྜ≀K㸦2-ࣈࢱࣀࣥ㸧ࡶ࣮ࣚࢻ࣒࣍ࣝ཯ᛂࡀ㝧ᛶࡔࡀ㸪໬ྜ≀A 㹼CH࡜࡟ࡘ࠸࡚⟅࠼ࡿࡢ࡛ヱᙜࡋ࡞࠸ࠋ
㸦ṇ☜࡟ࡣ࢔ࣝ࢟ࣝᇶࡢ㟁Ꮚ౪୚ᛶࡢᙉࡉࢆ⪃៖ࡍࡿᚲせࡀ࠶ࡿ㸧ࠋ໬ྜ≀D ࡣ஫࠸࡟ගᏛ␗ᛶయ࡞ࡢ࡛ἛⅬࡣ➼ࡋ࠸ࠋ໬ྜ≀ A ࡜ B ࡣ࡜ࡶ࡟➨ 1 ⣭࢔ࣝࢥ࣮࡛ࣝ࠶ࡿࡀ㸪ᯞศ࠿ࢀࡀ࠶ࡿศࡔࡅ໬ྜ≀B ࡢ᪉ࡀἛⅬ1 ⣭㸦໬ྜ≀ A ࡜ B㸧㸪➨ 2 ⣭㸦໬ྜ≀C ࡜ D㸧㸪
ၥ 5 ྠⅣ⣲ᩘࡢ࢔ࣝࢥ࣮࡛ࣝẚ㍑ࡍࡿ࡜㸪ἛⅬࡢ㧗࠸㡰࡟㸪➨ࡀపࡃ࡞ࡿࠋ
➨ 3 ⣭㸦໬ྜ≀ E㸧࡜࡞ࡿࠋࡇࢀࡣᚋࡢࡶࡢ࡯࡝ᯞศ࠿ࢀࡀከࡃ㸪ศᏊ㛫ࡢỈ⣲⤖ྜࡢᙧᡂࢆጉࡆࡿࡓࡵ࡛࠶ࡿ㸦⟅㸧A > B > C = D > E㸦ṇ☜࡟ࡣ࢔ࣝ࢟ࣝᇶࡢ㟁Ꮚ౪୚ᛶࡢᙉࡉࢆ⪃៖ࡍࡿᚲせࡀ࠶ࡿ㸧ࠋ໬ྜ≀ C ࡜ D ࡣ஫࠸࡟ගᏛ␗ᛶయ࡞ࡢ࡛ἛⅬࡣ➼ࡋ࠸ࠋ໬ྜ≀ A ࡜ B ࡣ࡜ࡶ࡟➨ 1 ⣭࢔ࣝࢥ࣮࡛ࣝ࠶ࡿࡀ㸪ᯞศ࠿ࢀࡀ࠶ࡿศࡔࡅ໬ྜ≀ B ࡢ᪉ࡀἛⅬ
౛ᖺ㏻ࡾ㸪኱ၥ
ࡀపࡃ࡞ࡿࠋ4 㢟ࡢฟ㢟࡛࠶ࡗࡓࠋၥ㢟ᵓᡂࡣ኱㜰་⛉኱࡛ࡼࡃぢࡽࢀࡿࡶࡢ࡛࠶ࡾ㸪㐣ཤၥࢆࡼࡃ◊✲ࡋࡓேࡀᑡࡋ᭷฼࡛࠶ࢁ࠺ࠋᇶᮏၥ㢟࣭ᶆ‽ၥ㢟ࡀ୰ᚰ࡛࠶ࡾ㸪᫖ᖺᗘࡼࡾࡶゎࡁࡸࡍ࠸ၥ㢟ࡀከࡃ㸪ศ㔞࡟ࡶవ⿱ࡀ࠶ࡗࡓࠋ㸦⟅㸧A > B > C = D > E࠙໬Ꮫ㸦ㅮホ㸧ࠚ࠙໬Ꮫ㸦ㅮホ㸧ࠚI ໬Ꮫ⤖ྜ࡟㛵ࡍࡿၥ㢟࡛㸪࢜࢟ࢯ㓟ࡢᵓ㐀࡜㓟ᛶᗘࡢ኱ᑠ࡟ࡘ࠸࡚⪃ᐹࡋ࡚࠸ࡿࠋ࢜࢟ࢯ㓟ࡣ㔜せ࡛࠶ࡿ࡟ࡶ࠿
౛ᖺ㏻ࡾ㸪኱ၥ
4 㢟ࡢฟ㢟࡛࠶ࡗࡓࠋၥ㢟ᵓᡂࡣ኱㜰་⛉኱࡛ࡼࡃぢࡽࢀࡿࡶࡢ࡛࠶ࡾ㸪㐣ཤၥࢆࡼࡃ◊✲ࡋࡓேࡀ࠿ࢃࡽࡎ㸪ᵓ㐀࡟ࡘ࠸࡚ࡣ᭕᫕࡞ேࡀከ࠸ࠋ
YMS ࡛ࡣ࢜࢟ࢯ㓟ࡢ㟁Ꮚᘧ㸪ᵓ㐀ᘧ㸪࠾ࡼࡧ㓟ᛶᗘࡢẚ㍑࡟ࡘ࠸
ᑡࡋ᭷฼࡛࠶ࢁ࠺ࠋᇶᮏၥ㢟࣭ᶆ‽ၥ㢟ࡀ୰ᚰ࡛࠶ࡾ㸪᫖ᖺᗘࡼࡾࡶゎࡁࡸࡍ࠸ၥ㢟ࡀከࡃ㸪ศ㔞࡟ࡶవ⿱ࡀ࠶ࡗࡓࠋ࡚ࡣࢸ࢟ࢫࢺ࡛⧞ࡾ㏉ࡋᢅࡗ࡚࠸ࡿࡢ࡛㸪ゎ⟅ࡣᐜ࡛᫆࠶ࡗࡓࠋI ໬Ꮫ⤖ྜ࡟㛵ࡍࡿၥ㢟࡛㸪࢜࢟ࢯ㓟ࡢᵓ㐀࡜㓟ᛶᗘࡢ኱ᑠ࡟ࡘ࠸࡚⪃ᐹࡋ࡚࠸ࡿࠋ࢜࢟ࢯ㓟ࡣ㔜せ࡛࠶ࡿ࡟ࡶ࠿II㧗ศᏊ໬ྜ≀࡟㛵ࡍࡿᇶᮏⓗ࡞ฟ㢟࡛ᖹ࡛᫆࠶ࡗࡓࠋィ⟬ၥ㢟ࡶ㞴ࡋࡃ࡞࠸ࠋ᭷ຠᩘᏐࡢᣦᐃ࡟ὀពࡋࡓ࠸ࠋ࠿ࢃࡽࡎ㸪ᵓ㐀࡟ࡘ࠸࡚ࡣ᭕᫕࡞ேࡀከ࠸ࠋYMS ࡛ࡣ࢜࢟ࢯ㓟ࡢ㟁Ꮚᘧ㸪ᵓ㐀ᘧ㸪࠾ࡼࡧ㓟ᛶᗘࡢẚ㍑࡟ࡘ࠸
III ࡚ࡣࢸ࢟ࢫࢺ࡛⧞ࡾ㏉ࡋᢅࡗ࡚࠸ࡿࡢ࡛㸪ゎ⟅ࡣᐜ࡛᫆࠶ࡗࡓࠋ⏕యෆࡢ໬Ꮫ཯ᛂ࡜࢚ࢿࣝࢠ࣮࡟㛵ࡍࡿၥ㢟࡛㸪ၥ㢟ᩥࢆࡼࡃㄞࡵࡤၥ㢟࡞ࡃゎ⟅࡛ࡁࡿࡶࡢ࡛࠶ࡿࠋATP ࡟㛵ࡍࡿၥ㢟ࡣ௚ࡢ་኱࡛ࡶࡼࡃぢࡽࢀࡿࡢ࡛ᑐ⟇ࡣ୓඲࡛࠶ࢁ࠺ࠋከࡃࡢᖹ⾮཯ᛂࢆᢅࡗ࡚࠸ࡿࡢ࡛ΰ஘ࡋ࡞࠸
II 㧗ศᏊ໬ྜ≀࡟㛵ࡍࡿᇶᮏⓗ࡞ฟ㢟࡛ᖹ࡛᫆࠶ࡗࡓࠋィ⟬ၥ㢟ࡶ㞴ࡋࡃ࡞࠸ࠋ᭷ຠᩘᏐࡢᣦᐃ࡟ὀពࡋࡓ࠸ࠋࡇ࡜࡜㸪ຠ⋡ࡼࡃ࢚ࢿࣝࢠ࣮ࡢィ⟬ࢆࡍࡿࡇ࡜ࡀ኱ษ࡛࠶ࡿࠋࡇࢀࡶ᭷ຠᩘᏐࡢᣦᐃ࡟ὀពࡍࡿࡇ࡜ࠋ
IIIATP ࡟IV ⏕యෆࡢ໬Ꮫ཯ᛂ࡜࢚ࢿࣝࢠ࣮࡟㛵ࡍࡿၥ㢟࡛㸪ၥ㢟ᩥࢆࡼࡃㄞࡵࡤၥ㢟࡞ࡃゎ⟅࡛ࡁࡿࡶࡢ࡛࠶ࡿࠋ
C4 H10 O ࡢ␗ᛶయ࡜ࡑࡢ཯ᛂ࡟㛵ࡍࡿၥ㢟࡛㸪᫖ᖺᗘࡢᵓ㐀Ỵᐃ࡟ẚ࡭࡚ࡣࡿ࠿࡟ᖹ࡛᫆ᇶᮏⓗ࡛࠶ࡿࠋ࣑ࢫࡣ㛵ࡍࡿၥ㢟ࡣ௚ࡢ་኱࡛ࡶࡼࡃぢࡽࢀࡿࡢ࡛ᑐ⟇ࡣ୓඲࡛࠶ࢁ࠺ࠋከࡃࡢᖹ⾮཯ᛂࢆᢅࡗ࡚࠸ࡿࡢ࡛ΰ஘ࡋ࡞࠸チࡉࢀ࡞࠸ࡀ㸪ၥ 5 ࡢἛⅬࡣ⪃ᐹࡋࡓࡇ࡜ࡀ࡞࠸࡜ᡞᝨ࠺࠿ࡶࡋࢀ࡞࠸ࠋYMS ࡛ࡣࡶࡕࢁࢇᤵᴗ࡛῝ࡃྲྀࡾᢅࡗࡇ࡜࡜㸪ຠ⋡ࡼࡃ࢚ࢿࣝࢠ࣮ࡢィ⟬ࢆࡍࡿࡇ࡜ࡀ኱ษ࡛࠶ࡿࠋࡇࢀࡶ᭷ຠᩘᏐࡢᣦᐃ࡟ὀពࡍࡿࡇ࡜ࠋ
࡚࠸ࡿࠋIV᫖ᖺᗘࡼࡾᖹ᫆࡟࡞ࡾ㸪ཷ㦂⏕ࡢࣞ࣋ࣝࢆ⪃࠼ࡿ࡜‶Ⅼ㏆ࡃࢆྲྀࢀࡓேࡀከᩘ࡛ࡣ࡞࠸࠿ࠋ኱ၥ
C4 H10 O ࡢ␗ᛶయ࡜ࡑࡢ཯ᛂ࡟㛵ࡍࡿၥ㢟࡛㸪᫖ᖺᗘࡢᵓ㐀Ỵᐃ࡟ẚ࡭࡚ࡣࡿ࠿࡟ᖹ࡛᫆ᇶᮏⓗ࡛࠶ࡿࠋ࣑ࢫࡣ
II࣭IV ࡣ඲ၥṇチࡉࢀ࡞࠸ࡀ㸪ၥ 5I࣭
ࡢἛⅬࡣ⪃ᐹࡋࡓࡇ࡜ࡀ࡞࠸࡜ᡞᝨ࠺࠿ࡶࡋࢀ࡞࠸ࠋゎࡍ࡭ࡁ࡛࠶ࡾ㸪኱ၥIII ࡢṇ⟅⋡࡛຾㈇ࡀỴࡲࡿࡔࢁ࠺ࠋᚓⅬ⋡࡟ࡋ࡚ YMS
90 %࡛ࡣࡶࡕࢁࢇᤵᴗ࡛῝ࡃྲྀࡾᢅࡗࢆྲྀࢀࢀࡤᏳᚰ࡛࠶ࡿࠋ࡚࠸ࡿࠋ᫖ᖺᗘࡼࡾᖹ᫆࡟࡞ࡾ㸪ཷ㦂⏕ࡢࣞ࣋ࣝࢆ⪃࠼ࡿ࡜‶Ⅼ㏆ࡃࢆྲྀࢀࡓேࡀከᩘ࡛ࡣ࡞࠸࠿ࠋ኱ၥ II࣭IV ࡣ඲ၥṇゎࡍ࡭ࡁ࡛࠶ࡾ㸪኱ၥ I࣭III ࡢṇ⟅⋡࡛຾㈇ࡀỴࡲࡿࡔࢁ࠺ࠋᚓⅬ⋡࡟ࡋ࡚ 90 % ࢆྲྀࢀࢀࡤᏳᚰ࡛࠶ࡿࠋ