ファーストリテイリング
製造時制限物質リスト (MRSL)-Version 2024-

1/36

改訂履歴
バージョン

改訂内容

発効日

2013

初版

01/04/2013

2014

年度更新

01/01/2014

2015

年度更新

05/15/2015

2015

追加更新

16/11/2015

2016

年度更新

25/04/2016

2017

年度更新

26/04/2017

2018

年度更新

25/07/2018

2019

ZDHC MRSL 反映に伴う大幅改訂

10/05/2019

2020

ZDHC MRSL v2.0 反映に伴う改訂

29/05/2020

2021

年度更新

31/05/2021

2023

ZDHC MRSL v3.1 反映に伴う改訂

31/05/2023

2024

ZDHC MRSL v3.1 反映に伴う改訂

31/05/2024

前バージョンからの変更点
全ての変更点は ZDHC MRSL v3.1 反映に伴うものです。
変更項目
3c. Other
Flameretardants

項目追加

基準値変更

現行基準値

改定内容
ZDHC V3.1 に合わせて新規追加●●

leather: ZDHC V3.1 に合わせて Sum の基準値に except BaP
200
を追記
mg/kg
Textile & Naphthalene
Plastics:
Sum: 200
mg/kg
ZDHC V3.1 に 合 わ せ て Leather: Sum except
BaP&Naphthalene: 200 mg/kg 、 Textile &Polymers: Sum except BaP: 200 mg/kg に変更

13. PAHs●

Acenaphthylene
Sum: 200 Acenaphthene
mg/kg
Fluorene
Phenanthrene
Anthracene
Fluoranthene
PyreneIndeno[1,2,3-cd]pyrene

2/36Benzo[ghi]perylene
Benzo-[a]-anthracene(BaA)
Chrysene(CHR)
Dibenzo-[a,h]-anthracene (DBAhA)
Benzo-[b]-fluoranthene(BbFA)
Benzo-[k]-fluoranthene(BkFA)
Benzo-[e]-pyrene(BeP)
Benzo-[j]-fluoranthene(BjFA)●
14. Pesticides●

Sum: 200 ZDHC V3.1 に 合 わ せ て Sum:200mg/kg をmg/kg
20mg/kg に変更
250
mg/kg

ZDHC V3.1 に合わせて 1000 mg/kg に変更
Borate, zinc salt

3/36

目次
はじめに ....................................................................................................... 5
方法論 ....................................................................................................... 5
適用範囲 .................................................................................................... 5
用語の定義 .................................................................................................. 6
一般要求事項 ............................................................................................... 8
Chapter 1: MRSL ........................................................................................ 9
Chapter 2: MRSL 候補リスト ......................................................................... 30
Chapter 3: アーカイブされた物質....................................................................... 31
追加要求事項 ............................................................................................. 32
Appendix 1. 想定される使用用途 .................................................................... 34

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はじめに
ファーストリテイリングは 2013 年、商品や生産プロセスにおける有害化学物質の排出をゼロにすることにコ
ミットしました。 このコミットメントを遂行するために、ファーストリテイリングは未然防止1と予防原則2に基づき、有害化学物質の排出ゼロを目指し、お客様、工場従業員、調達パートナー、および自然環境を守ります。
当社は、最終商品に含まれる可能性のある物質だけでなく、サプライチェーンにおける生産工程および関連プロセスの中で潜在的に使用され、環境中に排出される有害化学物質に対処することが非常に重要であると認識しています。このアプローチに従い、ファーストリテイリングは、有害化学物質として識別され、生産工程で使用され、環境中に排出される可能性のある物質の基準値と制限を定義する製造時制限物質リスト（MRSL：Manufacturing Restricted Substances List）を作成しました。

方法論
ファーストリテイリング MRSL の目的は、アパレルおよびフットウェアのサプライチェーン内の素材の加工工程における化学物質を管理するために、調和のとれたアプローチをサプライヤーに提供することです。本MRSL は、生産工程での意図的な使用を禁止する優先化学物質を明記したリストであり、市販の化学品中の各物質の許容される限界濃度を明示しています。
ファーストリテイリングは、2019 年に ZDHC グループに加入し、業界標準との整合性を高めるために、
ZDHC MRSL の要求事項をすべて取り入れた MRSL を設定しました。さらに、ファーストリテイリング
MRSL には、業界の専門家による評価に基づき、Oeko-Tex 100 や AFIRM など、ZDHC 以外の基準に沿った追加の物質も含まれています。
ファーストリテイリング MRSL は、素材サプライヤー、ならびにアパレルやフットウェアの製造に関わる下請け

1

未然防止は、解決策がエンドオブパイプの対策やリスク管理ではなく、発生源での使用の廃絶に重点が置かれるべきであることを意味します。危険有害ではない化

学物質への代替、または必要であれば製品の設計そのものや化学物質が機能的に必要かどうか、といった再評価を通して、化学物質を使わない代替案を見つけることが求められます。
2 予防原則は、物質（または活動）と悪影響の因果関係について決定的な科学的証拠が示されるのを待たずに、予防的措置を取ることを意味します。いくつかの有害化学物質はそれを受け入れる側の環境によって無害にすることはできないため（すなわち、「環境的に許容される」/「安全な」使用または排出レベルがない）、完全な科学的根拠がなくても、潜在的に重大または不可逆的な悪影響の防止が必要である、という仮定に基づきます。

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業者や工場に伝達されます。また、当社は、リスト上の物質が化学品中に定められた限度を超えて存在しないよう、素材サプライヤーや工場が、化学品サプライヤーと適切なコミュニケーションをとることを期待し
ています。

適用範囲
テキスタイル、アパレル、フットウェアの素材、皮革、ゴム、フォーム、接着剤、附属/副資材を加工する工場
施設における製造。

用語の定義
化学物質:
化学物質とは、自然状態で存在する、もしくは製造工程で得られる化学元素およびその化合物です。

化学品:
化学品は、いくつかの化学物質からなる化学品サプライヤー独自の調合物で、サプライヤー自身の商品名のもと購入可能なものです。

有害化学物質:有害化学物質とは、本質的に有害な特性を示すものを意味し、難分解性で高蓄積性および毒性を有する物質（PBT）、極めて難分解性、高い生体蓄積性を有する物質（vPvB）、発がん性、変異原
性、または生殖毒性を有する物質（CMR）、内分泌攪乱化学物質（ED）、または他の同等の懸念を有する物質が含まれます。これらは地域で規制または制限されているものだけに限りません。

意図的使用の禁止（No intentional use）:
意図的使用の禁止とは、MRSL に記載された化学物質または物質のグループが、素材または商品の製造において、特定の機能または効果を達成するために使用されてはならないことを示します。化学品中には製造中に生じる不純物が存在するため、制限物質の残留が微量であれば許容されます。基準値を超える制限物質を含む化学品は、ファーストリテイリング MRSL に準拠していないことになります。

6/36

CAS（Chemical Abstracts Service）Number:
化学物質の識別番号。ファーストリテイリング MRSL 上の化学物質は通常 CAS Number とともに記載
され ますが、個別の識別番号 をすべてリストするこ とが実用的ではない物質群については、CAS
Number を表示しない場合もあります。

附属/副資材:
包装資材を除く、全ての製品取付け資材類（縫製糸、ボタン、芯地、裏地、ファスナー、ネーム、ケアラ
ベル等）。

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一般要求事項
Chapter 1: MRSL•“in Manufacturing”のグループ
このグループの化学物質については、素材の加工および最終製品の製造を行う工場施設における意図的使用を禁止しています。

•“in Chemical Formulations”のグループ
このグループの化学物質については、化学品サプライヤーから購入する化学品中の濃度を基準値以下に制限しています。これらの限界値は意図的使用を禁止するものです。製造中に生じることが合理的に予期される不純物があっても、責任ある化学物質製造によって一貫して限界値を達成可能な場合は許容されます。

ZDHC MRSL の欄に”Yes”と表示されている物質は、“in Manufacturing” か “in Chemical Formulations” かに関わらず、ZDHC MRSL と同じ要求
内容の対象となります。
各制限物質に関する詳細情報とガイダンスは、ZDHC MRSL から入手できます。どのような化学品に含まれるか、どのような工程で使用されるか、なぜ制限されているのか、より安全な代替物質は何か、といった情報が含まれます。

Chapter 2: MRSL 候補リスト
MRSLへの追加が提案されており、収載のための基準を満たすものの、安全な代替物質/技術が十分なスケールでまだ確立されていない物質のリストです。候補リ
ストを明示することで、代替の技術革新が促進されます。

Chapter 3: アーカイブされた物質
業界で現在も使用されているという確たる証拠はないものの、過去には使用されていた明確な証拠がある物質です。

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Chapter 1: MRSLFR MRSL v2024
Requirements
Parameter

CAS Number

1. AP / APEOZDHC MRSL
v3.1

in Manufacturingin Chemical formulations

title

title

title

Octylphenol (OP)

Various including 27193-28-8 14066-9 1806-26-4 85771-77-3

No intentional use

100 mg/kg

yes

Nonylphenol (NP)

Various including 25154-52-3 10440-5 84852-15-3 11066-49-2

No intentional use

100 mg/kg

yes

Octylphenolethoxylates, n=2 to n= 16

Various, including 68987-90-6
9036-19-5 9002-93-1

No intentional use

250 mg/kg

yes

Nonylphenolethoxylates, n=2 to n=16

Various including 9016-45-9
26027-38-3 37205-87-1 68412-544 127087-87-0

No intentional use

250 mg/kg

yes

title

title

title

2. Phthalates (ortho-phthalates)
Butyl benzyl Phthalate (BBP)

85-68-7

No intentional use

Sum: 250 mg/kg

yes

Di-n-butyl Phthalate (DBP)

84-74-2

No intentional use

Sum: 250 mg/kg

yes

Bis(2-ethylhexyl) Phthalate (DEHP)

117-81-7

No intentional use

Sum: 250 mg/kg

yes

Di-n-octyl Phthalate (DnOP)

117-84-0

No intentional use

Sum: 250 mg/kg

yes

Di-iso-nonyl Phthalate (DINP)

28553-12-0

No intentional use

Sum: 250 mg/kg

yes

Di-iso-decyl Phthalate (DIDP)

26761-40-0

No intentional use

Sum: 250 mg/kg

yes

Dimethyl phthalate (DMP)

131-11-3

No intentional use

1000 mg/kg*

Diethyl Phthalate (DEP)

84-66-2

No intentional use

Sum: 250 mg/kg

yes

Di-n-propyl Phthalate (DPrP)

131-16-8

No intentional use

Sum: 250 mg/kg

yes

Di-iso-butyl Phthalate (DIBP)

84-69-5

No intentional use

Sum: 250 mg/kg

yes

Di-cyclohexyl Phthalate (DCHP)

84-61-7

No intentional use

Sum: 250 mg/kg

yes

Di-n-hexyl phthalate (DnHP / DHEXP)

84-75-3

No intentional use

Sum: 250 mg/kg

yes

D-inonyl Phthalate (DNP)

84-76-4

No intentional use

Sum: 250 mg/kg

yes

9/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Di-iso-octyl Phthalate (DIOP)

27554-26-3

No intentional use

Sum: 250 mg/kg

yes

Bis(methylglycol) phthalate (DMEP)

117-82-8

No intentional use

Sum: 250 mg/kg

yes

1,2-Benzenedicarboxylic acid, di-C7-11-branched
and linear alkyl esters (DHNUP)

68515-42-4

No intentional use

Sum: 250 mg/kg

yes

Di-iso-heptyl Phthalate (1,2-benzenedicarboxylicacid, di-C6-8-branched alkyl esters, C7-rich)(DIHpP)

71888-89-6

No intentional use

Sum: 250 mg/kg

yes

Di-n-pentylphthalate (DnPP/DPENP)

131-18-0

No intentional use

Sum: 250 mg/kg

yes

Diisopentylphthalate (DiPP)

605-50-5

No intentional use

Sum: 250 mg/kg

yes

N-pentyl-isopentyl phthalate (nPiPP)

776297-69-9

No intentional use

Sum: 250 mg/kg

yes

1,2-Benzenedicarboxylic acid, dipentyl ester,branched and linear standard

84777-06-0

No intentional use

Sum: 250 mg/kg

yes

Di-hexyl Phthalate, branched and linear (DHxP)

68515-50-4

No intentional use

Sum: 250 mg/kg

yes

Di-iso-hexyl Phthalate (DIHxP)

71850-09-4

No intentional use

Sum: 250 mg/kg

yes68515-51-5 / 68648-93-1

No intentional use

1000 mg/kg*

title

title

title

1,2-benzenedicarboxylic acid, di-C6-10-alkyl esters;
1,2-benzenedicarboxylic acid, mixed decyl and hexyl
and octyl diesters with ≥ 0.3% of dihexyl phthalate
3a. Brominated Flame retardants
Polybrominated biphenyls (PBBs)

59536-65-1 various

No intentional use

250 mg/kg

yes

Monobromo biphenyls (MonoBB)

26264-10-8, 2052-07-5, 2113-577, 92-66-0 various

No intentional use

250 mg/kg

yes

Dibromo biphenyls (DiBB)

13029-09-9, 92-86-4, 59080-32-9,
various

No intentional use

250 mg/kg

yes

Tribromo biphenyls (TriBB)

51202-79-0, various

No intentional use

250 mg/kg

yes

Tetrabromo bipenyls (TetraBB)

60044-24-8, 60044-25-9, various

No intentional use

250 mg/kg

yesPentabromo biphenyls (PentaBB)

67888-96-4, 59080-39-6, various

No intentional use

250 mg/kg

yes

10/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Hexabromo biphenyls (HexaBB)

59080-40-9, 36355-01-8, various

No intentional use

250 mg/kg

yes

Heptabromo biphenyls (HeptaBB)-

No intentional use

250 mg/kg

yes

Octabromo biphenyls (OctaBB)

27858-07-7, 61288-13-9, various

No intentional use

250 mg/kg

yes

Nonabromo biphenyls (NonaBB)

27753-52-2, 69278-62-2 11926462-9, 119264-63-0, various

No intentional use

250 mg/kg

yes

Decabromo biphenyls (DecaBB)

13654-09-6

No intentional use

250 mg/kg

yes

Tris(2,3-Dibromopropyl)-Phosphate (TRIS)

126-72-7

No intentional use

250 mg/kg

yes

Polybrominated diphenyl ethers (PBDEs)

various

No intentional use

1000 mg/kg*

Monobromo diphenyl ethers (MonoBDE)

various

No intentional use

250 mg/kg

Dibromo diphenyl ethers (DiBDE)

various

No intentional use

1000 mg/kg*

Tribromo diphenyl ethers (TriBDE)

yes

various

No intentional use

250 mg/kg

yes

Tetrabromo diphenyl ethers (TetraBDE)

40088-47-9

No intentional use

250 mg/kg

yesPentabromo diphenyl ethers (PentaBDE)

32534-81-9

No intentional use

250 mg/kg

yes

Hexabromo diphenyl ethers (HexaBDE)

36483-60-0

No intentional use

250 mg/kg

yes

Heptabromo diphenyl ethers (HeptaBDE)

68928-80-3

No intentional use

250 mg/kg

yes

Octabromo diphenyl ethers (OctaBDE)

32536-52-0

No intentional use

250 mg/kg

yes

Nonabromo diphenyl ethers (NonaBDE)

63936-56-1

No intentional use

250 mg/kg

yes

Decabromo diphenyl ethers (DecaBDE)

1163-19-5

No intentional use

250 mg/kg

yes

Tetrabromo-bisphenol A (TBBPA)

79-94-7

No intentional use

250 mg/kg

yes

No intentional use

250 mg/kg

yes

No intentional use

250 mg/kg

yes

2,2-bis(bromomethyl)-1,3-propanediol (BBMP)

5412-25-9
134237-50-6, 134237-51-7,
134237-52-8, 25637-99-4, 319455-6
3296-90-0

No intentional use

250 mg/kg

yes

Tetrabromobisphenol A bis(dibromopropyl ether)

21850-44-2

No intentional use

250 mg/kg

yes

title

title

title

Bis(2,3-dibromopropyl)phosphate (BIS / BDBPP)
Hexabromocyclododecane (HBCDD)

3b.

Phosphorus Flame retardants

Tris (2-Chloroethyl) Phosphate (TCEP)

115-96-8

No intentional use

250 mg/kg

yes

Tris(1,3-dichloro-2-propyl) phosphate (TDCPP)

13674-87-8

No intentional use

250 mg/kg

yes

11/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Tris(1-aziridinyl)phosphine oxide) (TEPA)

545-55-1

No intentional use

250 mg/kg

yes

Tris(1-chloro-2-propyl) phosphate (TCPP)

13674-84-5

No intentional use

250 mg/kg

yes

Trixylyl phosphate (TXP)

25155-23-1

No intentional use

Sum: 250 mg/kg

yes

Trimethyl phosphate

512-56-1

No intentional use

Sum: 250 mg/kg

yes

Tri-o-cresyl phosphate (TOCP)

78-30-8

No intentional use

Sum: 250 mg/kg

yes

title

title

title

1303-86-2

No intentional use

250 mg/kg

yes10043-35-3, 11113-50-1
1303-96-4, 1330-43-4, 12179-043, 215-540-4 (EINECS No., not
CAS No.)12267-73-1

No intentional use

250 mg/kg

yes

No intentional use

250 mg/kg

yes

No intentional use

250 mg/kg

yes

Disodium octaborate

12008-41-2

No intentional use

250 mg/kg

yes

Zinc borate salts

1332-07-6

No intentional use

250 mg/kg

yes

title

title

title

3c. Other Flame retardants
Diboron trioxide
Boric acid
Disodium Tetraborate, anhydrous
Tetraboron disodium heptaoxide, hydrate

4a. Azo dyes
4-Aminobiphenyl

92-67-1

No intentional use

150 mg/kg

yes

Benzidine

92-87-5

No intentional use

150 mg/kg

yes

4-Chloro-o-toluidine

95-69-2

No intentional use

150 mg/kg

yes

2-Naphtylamine

91-59-8

No intentional use

150 mg/kg

yeso-Aminoazotoluene

97-56-3

No intentional use

150 mg/kg

yes

5-Nitro-o-toluidine

99-55-8

No intentional use

150 mg/kg

yes

4-Chloroaniline

106-47-8

No intentional use

150 mg/kg

yes

2,4-Diaminoanisole

615-05-4

No intentional use

150 mg/kg

yes4,4'-Diaminodiphenylmethane

101-77-9

No intentional use

150 mg/kg

yes3,3'-Dichlorobenzidine

91-94-1

No intentional use

150 mg/kg

yes3,3'-Dimethoxybenzidine

119-90-4

No intentional use

150 mg/kg

yes3,3'-Dimethylbenzidine

119-93-7

No intentional use

150 mg/kg

yes

12/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

3,3'-Dimethyl-4,4'-diaminodiphenylmethane

838-88-0

No intentional use

150 mg/kg

yes

p-Cresidine

120-71-8

No intentional use

150 mg/kg

yes4,4'-Methylene-bis-(2-chloroaniline)

101-14-4

No intentional use

150 mg/kg

yes4,4'-Oxydianiline

101-80-4

No intentional use

150 mg/kg

yes4,4'-Thiodianiline

139-65-1

No intentional use

150 mg/kg

yeso-Toluidine

95-53-4

No intentional use

150 mg/kg

yes

2,4-Toluenediamine

95-80-7

No intentional use

150 mg/kg

yes

2,4,5-Trimethylaniline

137-17-7

No intentional use

150 mg/kg

yeso-Anisidine

90-04-0

No intentional use

150 mg/kg

yes

Aminoazobenzene

60-09-3

No intentional use

150 mg/kg

yes

2,4-Xylidine

95-68-1

No intentional use

150 mg/kg

yes

2,6-Xylidine

87-62-7

No intentional use

yes

Aniline62-53-3

No intentional use

4-chloro-o-toluidinium chloride

3165-93-3

No intentional use

150 mg/kg
Indigo 2000 mg/kg
Other dyes 500 mg/kg
Not Applicable for polymer
150 mg/kg

2-Naphthylammoniumacetate553-00-4

No intentional use

150 mg/kg

yes

4-methoxy-m-phenylene diammonium sulphate; 2,4diaminoanisole sulphate39156-41-7

No intentional use

150 mg/kg

yes

2,4,5-trimethylaniline hydrochloride

21436-97-5

No intentional use

150 mg/kg

yes

title

title

title
yes

4d. Disperse & Carcinogenic Dyes

yes
yes

Acid Red 26

3761-53-3

No intentional use

Textile&leather: 250 mg/kg

Acid Red 114

6459-94-5

No intentional use

1000 mg/kg*

Acid Violet 49

1694-09-3

No intentional use

Textile&Leather: 250 mg/kg

yes

Basic Blue 26

2580-56-5

No intentional use

Textile: 250 mg/kg

yes

Basic Green 4 (malachite green chloride)569-64-2

No intentional use

Textile: 250 mg/kg

yes

Basic Green 4 (malachite green oxalate)2437-29-8

No intentional use

Textile: 250 mg/kg

yes

Basic Green 4 (malachite green)

10309-95-2

No intentional use

Textile: 250 mg/kg

yes

13/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Basic Green 4 leuco base (Leucomalachite green,
N,N,N',N'-tetramethyl-4,4'-benzylidenedianiline)

129-73-7

No intentional use

Textile: 250 mg/kg

yes

Basic Red 9

569-61-9

No intentional use

Textile: 250 mg/kg

yes

Basic Violet 3

548-62-9

No intentional use

Textile: 250 mg/kg

yes

Basic Violet 14632-99-5

No intentional use

Textile: 250 mg/kg

yes

Direct Black 38

1937-37-7

No intentional use

Textile&leather: 250 mg/kg

yes

Direct Blue 62602-46-2

No intentional use

Textile&leather: 250 mg/kg

yes

Direct Blue 15

2429-74-5

No intentional use

1000 mg/kg*

Direct Brown 95

16071-86-6

No intentional use

1000 mg/kg*

Direct Red 28

573-58-0

No intentional use

Textile&leather: 250 mg/kg

yes

Disperse Blue 1

2475-45-8

No intentional use

Textile: 250 mg/kg

yes

Disperse Blue 32475-46-9

No intentional use

Textile: 250 mg/kg

yes

Disperse Blue 73179-90-6

No intentional use

Textile: 250 mg/kg

yes

Disperse Blue 26

3860-63-7

No intentional use

Textile: 250 mg/kg

yes

Disperse Blue 35

12222-75-2, 56524-77-7, 5652476-6

No intentional use

Textile: 250 mg/kg

yes

Disperse Blue 10212222-97-8

No intentional use

Textile: 250 mg/kg

yes

Disperse Blue 10612223-01-7

No intentional use

Textile: 250 mg/kg

yes

Disperse Blue 124

61951-51-7

No intentional use

Textile: 250 mg/kg

yes

Disperse Brown 1

23355-64-8

No intentional use

Textile: 250 mg/kg

yes

Disperse Orange 1

2581-69-3

No intentional use

Textile: 250 mg/kg

yes

Disperse Orange 3

730-40-5

No intentional use

Textile: 250 mg/kg

yes

Disperse Orange 1182-28-0

No intentional use

Textile: 250 mg/kg

yes

13301-61-6, 12223-33-5, 5181142-8

No intentional use

Textile: 250 mg/kg

yes

Disperse Orange 149

85136-74-9

No intentional use

1000 mg/kg*

Disperse Red 1

2872-52-8

No intentional use

Textile: 250 mg/kg

Disperse Orange 37/59/76

yes

14/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Disperse Red 112872-48-2

No intentional use

Textile: 250 mg/kg

yes

Disperse Red 17

3179-89-3

No intentional use

Textile: 250 mg/kg

yes

Disperse Red 151

61968-47-6

No intentional use

1000 mg/kg*

Disperse Yellow 1

119-15-3

No intentional use

Textile: 250 mg/kg

yes

Disperse Yellow 32832-40-8

No intentional use

Textile: 250 mg/kg

yes

Disperse Yellow 96373-73-5

No intentional use

Textile: 250 mg/kg

yes

Disperse Yellow 23

6250-23-3

No intentional use

1000 mg/kg*

Disperse Yellow 3912236-29-2

No intentional use

Textile: 250 mg/kg

yes

Disperse Yellow 49

54824-37-2

No intentional use

Textile: 250 mg/kg

yes

Disperse Yellow 56

54077-16-6

No intentional use

1000 mg/kg*

Pigment Red 104 (Lead chromate molybdate
sulphate red)

12656-85-8

No intentional use

1000 mg/kg*

Pigment Yellow 34 (Lead sulfochromate yellow)

1344-37-2

No intentional use

1000 mg/kg*

title

title

title

5. Organotin Compounds

Dibutyltin, DBT

H based: 1002-53-5,
Cl based: 683-18-1

No intentional use

20 mg/kg
100 mg/kg for PU based
thickeners

yes

Dimethyltin, DMT

Cl based: 753-73-1

No intentional use

5 mg/kg

yes

Dioctyltin, DOT

H based: 94410-05-6,
Cl based: 3542-36-7

No intentional use

5 mg/kg

yes

Diphenyltin, DPhT

H based: 1011-95-6, 6381-06-2
Cl based: 1135-99-5

No intentional use

5 mg/kg

yes

Dipropyltin, DPT

Various

No intentional use

5 mg/kg

yes

Monobutyltin, MBT

H based: 78763-54-9,
Cl based: 1118-46-3

No intentional use

5 mg/kg

yes

Monomethyltin, MMT

Various, including 993-16-8

No intentional use

5 mg/kg

yes

15/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Monooctyltin, MOT

H based: 15231-57-9,
Cl based: 3091-25-6

No intentional use

5 mg/kg

yes

Monophenyltin, MPhT

Cl based: 1124-19-2

No intentional use

5 mg/kgyes

Tetrabutyltin, TeBT

1461-25-2

No intentional use

1 mg/kgyes

Tetraethyltin, TeET

597-64-8

No intentional use

1 mg/kgyes

Tetraoctyltin, TeOT

Various

No intentional use

1 mg/kgyes

H based 36643-28-4,
Cl complex: 56573-85-4,
Cl based: 1461-22-9

No intentional use

5 mg/kgyes

Tricyclohexyltin, TCyHT

H based: 6056-50-4
Cl based: 3091-32-5

No intentional use

1 mg/kgyes

Trimethyltin, TMT

Cl based: 1066-45-1

No intentional use

5 mg/kgyes

Trioctyltin, TOT-

No intentional use

5 mg/kgyes

Triphenyltin, TPhT

H based: 892-20-6,
Cl based: 639-58-7
ion: 668-34-8

No intentional use

5 mg/kg

yes

Tripropyltin, TPT

H based: 761-44-4
Cl based: 2279-76-7

No intentional use

1 mg/kg

yes

title

title

title

Tributyltin, TBT

6a. PFCs

Perfluorooctanoic acid (PFOA) and its salts

335-67-1

No intentional use

PFOA = 0.025 mg/kg
PFOA-related substances = 1
mg/kg

yes

PFOA-related substancesvarious

No intentional use

1 mg/kg

yes

2-Perfluorooctylethanol (8:2 FTOH)

678-39-7

No intentional use

1 mg/kgyes

1H,1H,2H,2H-Perfluorodecyl acrylate (8:2 FTA)

27905-45-9

No intentional use

1000 mg/kg*

Perfluoroctane sulfonate (PFOS)

1763-23-1

No intentional use

2 mg/kg

yes

16/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

Perfluorooctane sulfonamide (PFOSA)

754-91-6

No intentional use

1000 mg/kg*

Perfluorooctane sulfonfluoride (PFOSF)

307-35-7

No intentional use

1000 mg/kg*

N-Methylperfluoro-1-octanesulfonamide (N-MeFOSA)

31506-32-8

No intentional use

1000 mg/kg*

N-Ethylperfluoro-1-octanesulfonamide (N -Et-FOSA)

4151-50-2

No intentional use

1000 mg/kg*

2-(N-Methylperfluoro-1-octanesulfonamido)-ethanol(N-Me-FOSE)

24448-09-7

No intentional use

1000 mg/kg*

2-(N-Ethylperfluoro-1-octanesulfonamido)-ethanol(N-Et-FOSE)

1691-99-2

No intentional use

1000 mg/kg*

Perfluorononanonic acid (PFNA)

375-95-1

No intentional use

1000 mg/kg*

Perfluorododecanoic acid (PFDA)

335-76-2

No intentional use

1 mg/kg

Henicosafluoroundecanoic acid (PFUdA / PFUnA)

2058-94-8

No intentional use

1000 mg/kg*

Tricosafluorododecanoic acid PFDoDA

307-55-1

No intentional use

1000 mg/kg*

Pentacosafluorotridecanoic acid (PFTrDA)

72629-94-8

No intentional use

1000 mg/kg*

Heptacosafluorotetradecanoic acid (PFTeDA)

376-06-7

No intentional use

1000 mg/kg*

172155-07-6

No intentional use

1000 mg/kg*

Perfluorodecane sulfonic acid (PFDS)

335-77-3

No intentional use

1 mg/kg

1H,1H,2H,2H-Perfluorododecylacrylate (10:2 FTA)

17741-60-5

No intentional use

1000 mg/kg*

1H,1H,2H,2H-Perfluoro -1-dodecanol (10:2 FTOH)

865-86-1

No intentional use

1 mg/kg

2H,2H,3H,3H-Perfluoroundecanoic Acid (H4PFUnA)

34598-33-9

No intentional use

1000 mg/kg*

Perfluor+B268:K290+B277:D290o-3,7dimethyloctanoic Acid (PF-3,7-DMOA)

Perfluorohexane sulfonate (PFHxS)ZDHC MRSL
v3.1

yes

yes
yes

355-46-4

No intentional use

1 mg/kgyes375-22-4+C384

No intentional use

1 mg/kg

yes

Perfluorobutane sulfonate (PFBS)

375-73-5

No intentional use

1 mg/kg

yes

Perfluoropentane Acid (PFPeA)

2706-90-3

No intentional use

1000 mg/kg*

yes

Perfluorobutanoic acid (PFBA)

17/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Perfluorohexanoic acid (PFHxA)

307-24-4

No intentional use

PFHxA = 0.025 mg/kg
PFHxA-related substances = 1
mg/kg

Perfluoroheptanoic acid (PFHpA)

375-85-9

No intentional use

1000 mg/kg*

Perfluoroheptanoic acid, sodium salt (PFHpA-Na)

20109-59-5

No intentional use

1 mg/kg

Perfluoroheptane Sulfonate (PFHpS)

375-92-8

No intentional use

1000 mg/kg*

7H-Dodecanefluoroheptane Acid (7HPFHpA)

1546-95-8

No intentional use

1000 mg/kg*

Perfluorooctanesulphonic acid 1H,1H,2H,2H(H4PFOS; 6:2)

27619-97-2

No intentional use

1000 mg/kg*

1H,1H,2H,2H-Perfluorooctylacrylate (6:2 FTA)

17527-29-6

No intentional use

1000 mg/kg*

1H,1H,2H,2H-Perfluoro-1-hexanol (4:2 FTOH)

2043-47-2

No intentional use

1 mg/kgyes

1H,1H,2H,2H-Perfluoro-1-octanol (6:2 FTOH)

647-42-7

No intentional use

1 mg/kg

yes

title

title

title

No intentional use

Quantification limit: 50 mg/kg

yes

title

title

title

6b. PFAS
Total Organic Fluorine - As PFAS indicator

7782-41-4

7. COC (Chlorobenzenes/Chlorotoluenes)

yes

Chlorobenzene

108-90-7

No intentional use

Sum: 200 mg/kg

yes

Dichlorobenzenes

Various include 25321-22-6

No intentional use

Sum: 200 mg/kg

yes

1,2-Dichlorobenzene

95-50-1

No intentional use

500mg/kg

yes

1,3-Dichlorobenzene

541-73-1

No intentional use

Sum: 200 mg/kg

yes

1,4-Dichlorobenzene

106-46-7

No intentional use

Sum: 200 mg/kg

yes

Trichlorobenzenes

Various include 12002-48-1

No intentional use

Sum of substances2 : 200 mg/kg

yes

87-61-6

No intentional use

Sum of substances2 : 200 mg/kg

yes

1,2,3-Trichlorobenzene,

18/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

1,2,4-Trichlorobenzene

120-82-1

No intentional use

Sum of substances2 : 200 mg/kg

yes

1,3,5-Trichlorobenzene,

108-70-3

No intentional use

Sum of substances2 : 200 mg/kg

yes

Tetrachlorobenzenes

Various include 12408-10-5

No intentional use

Sum of substances2 : 200 mg/kg

yes

1,2,3,4-Tetrachlorobenzene

634-66-2

No intentional use

Sum of substances2 : 200 mg/kg

yes

1,2,3,5-Tetrachlorobenzene

634-90-2

No intentional use

Sum of substances2 : 200 mg/kg

yes

1,2,4,5-Tetrachlorobenzene

95-94-3

No intentional use

Sum of substances2 : 200 mg/kg

yesPentachlorobenzene

608-93-5

No intentional use

Sum: 200 mg/kg

yes

Hexachlorobenzene

118-74-1

No intentional use

Sum: 200 mg/kg

yes

Chlorotoluene
2-Chlorotoluene

Various include 25168-05-2

No intentional use

Sum: 200 mg/kg

yes

95-49-8

No intentional use

Sum: 200 mg/kg

yes

3-Chlorotoluene108-41-8

No intentional use

Sum: 200 mg/kg

yes

4-Chlorotoluene

106-43-4

No intentional use

Sum: 200 mg/kg

yes

Dichlorotoluene
2,3-Dichlorotoluene

Various include "29797-40-8

No intentional use

Sum: 200 mg/kg

yes32768-54-0

No intentional use

Sum: 200 mg/kg

yes

2,4-Dichlorotoluene

95-73-8

No intentional use

Sum: 200 mg/kg

yes

2,5-Dichlorotoluene

19398-61-9

No intentional use

Sum: 200 mg/kg

yes

2,6-Dichlorotoluene118-69-4

No intentional use

Sum: 200 mg/kg

yes

3,4-Dichlorotoluene

95-75-0

No intentional use

Sum: 200 mg/kg

yes

25186-47-4

No intentional use

Sum of substances2 : 200 mg/kg
Each: 10 mg/kg

yes

3,5-dichlorotoluene

19/36

FR MRSL v2024
Requirements
Parameter

CAS Number

ZDHC MRSL
v3.1

in Manufacturingin Chemical formulations

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yes

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yes

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yes

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yes

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yes

No intentional use

Sum of substances2 : 200 mg/kg
Each: 10 mg/kg

yesvarious

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yes

2,3,4,5-tetrachlorotoluene

76057-12-0

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yes

2,3,5,6-tetrachlorotoluene

1006-31-1

No intentional use

Sum: 200 mg/kgEach: 10 mg/kg

yes

2,3,4,6-tetrachlorotoluene875-40-1

No intentional use

Sum: 200 mg/kg
Each: 10 mg/kg

yesPentachlorotoluene877-11-2

No intentional use

Sum: 200 mg/kg

yes

title

title

title
yes

Trichlorotoluene

various

2,3,6-Trichlorotoluene

2077-46-5

2,4,5-Trichlorotoluene
2,3,4-trichlorotoluene
2,4,6-trichlorotoluene
3,4,5-trichlorotoluene

Tetrachlorotoluene6639-30-1
7359-72-0
23749-65-7
21472-86-6

8a. Halogenated solvents / VOCs
1,2-Dichloroethane

107-06-2

No intentional use

5 mg/kg

1,1-Dichloroethene75-35-4

No intentional use

1000 mg/kg*

Methylene chloride

75-09-2

No intentional use

5 mg/kg

yes

20/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Trichloromethane (Chloroform)

67-66-3

No intentional use

1000 mg/kg*

1,1,1-Trichloroethane

71-55-6

No intentional use

1000 mg/kg*

Carbon tetrachloride

56-23-5

No intentional use

1000 mg/kg*

Trichloroethene (Trichloroethylene)

79-01-6

No intentional use

40 mg/kg

1,1,2-Trichloroethane79-00-5

No intentional use

1000 mg/kg*

1,1,1,2-Tetrachloroethane630-20-6

No intentional use

1000 mg/kg*

Tetrachloroethene (PERC)

127-18-4

No intentional use

5 mg/kg

1,1,2,2-Tetrachloroethane

79-34-5

No intentional use

1000 mg/kg*

Pentachloroethane76-01-7

No intentional use

1000 mg/kg*

1,2,3-trichloropropane

96-18-4

No intentional use

1000 mg/kg*

Benzylchloride

100-44-7

No intentional use

50 mg/kg and
100 mg/kg for dyesyes

2-(2-methyoxyethoxy)-ethanol

111-77-3

No intentional use

1000 mg/kg*

yes(Candidate)

title

title

title

8b. Other Solvents

yes

yes

Benzene71-43-2

No intentional use

50 mg/kg

yes

N,N-dimethylformamide (N,N-DMF) / DMFa

68-12-2

No intentional use

1000 mg/kg

yes

N,N-dimethylacetamide (N,N-DMAC)

127-19-5

No intentional use

1000 mg/kg

yes

1-methyl-2-pyrrolidone (NMP)

872-50-4

No intentional use

1000 mg/kg

yes

Toluene108-88-3

No intentional use

500 mg/kg

yes

Ethylbenzene

100-41-4

No intentional use

1000 mg/kg*

1330-20-7 (all isomers)
95-47-6, 106-42-3, 108-38-3

No intentional use

500 mg/kg

Styrene100-42-5

No intentional use

1000 mg/kg*

Cresol (all isomers)

1319-77-3

No intentional use

500 mg/kg

Xylene

yes

yes

21/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

o-cresol

95-48-7

No intentional use

500 mg/kg

yes

m-cresol

108-39-4

No intentional use

500 mg/kg

yes

p-cresol

106-44-5

No intentional use

500 mg/kg

yes

Formamide75-12-7

No intentional use

1000 mg/kg*

Carbon disulphide75-15-0

No intentional use

1000 mg/kg*

Acetophenone

98-86-2

No intentional use

1000 mg/kg*

2-Phenyl-2-Propanol

617-94-7

No intentional use

1000 mg/kg*

N-Ethyl-2-pyrrolidone; 1-Ethyl-2-pyrrolidinone (NEP)

2687-91-4

No intentional use

1000 mg/kg

yes

title

title

title

9. Chlorinated Phenols
Pentachlorophenol (PCP), its salts and compounds

87-86-5

No intentional use

5 mg/kgyes

Tetrachlorophenol (TeCP)

25167-83-3

No intentional use

Sum of TeCP: 15 mg/kg

yes

2,3,4,5-Tetrachlorophenol

4901-51-3

No intentional use

Sum of TeCP: 15 mg/kg

yes

2,3,4,6-Tetrachlorophenol

58-90-2

No intentional use

Sum of TeCP: 15 mg/kg

yes

2,3,5,6-Tetrachlorophenol

935-95-5

No intentional use

Sum of TeCP: 15 mg/kg

yes

Trichlorophenol (TriCP)

various

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2,3,4-Trichlorophenol

15950-66-0

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2,3,5-Trichlorophenol

933-78-8

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2,3,6-Trichlorophenol

933-75-5

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2,4,5-Trichlorophenol

95-95-4

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2,4,6-Trichlorophenol

88-06-2

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

22/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations
Sum of TriCP, DCP, MonoCP: 50
mg/kg

ZDHC MRSL
v3.1

3,4,5-Trichlorophenol

609-19-8

No intentional use

DiChlorophenol (DiCP)

various

No intentional use

2,3-Dichlorophenol

576-24-9

No intentional use

2,4-Dichlorophenol

120-83-2

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2,5-Dichlorophenol

583-78-8

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2,6-Dichlorophenol

87-65-0

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

3,4-Dichlorophenol

95-77-2

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

3,5-Dichlorophenol

591-35-5

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

Mono Chlorophenol

various

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

2-Chlorophenol

95-57-8

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

3-Chlorophenol

108-43-0

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

4-Chlorophenol

106-48-9

No intentional use

Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes

title

title

title

10. Chlorinated Paraffins (SCCP / MCCP)Sum of TriCP, DCP, MonoCP: 50
mg/kg
Sum of TriCP, DCP, MonoCP: 50
mg/kg

yes
yes
yes

Short Chain Chlorinated Paraffins (SCCP) with C10–C1385535-84-8

No intentional use

250 mg/kg

yes

Medium Chain Chlorinated Paraffins (MCCP) with
C14 –C1785535-85-9

No intentional use

250 mg/kg

yes

23/36

FR MRSL v2024
Requirements
Parameter

CAS Number

11a.Heavy Metals
Total Heavy metal -(Non-Jewelry)

ZDHC MRSL
v3.1

in Manufacturingin Chemical formulations

title

title

title

title

title

title

Total Cadmium, Cd

7440-43-9

No intentional use

Others: 20 mg/kg
Pigment: 50 mg/kg

yes

Total Lead, Pb

7439-92-1

No intentional use

100 mg/kg

yes

Total Mercury, Hg

7439-97-6

No intentional use

Others: 4 mg/kg
Pigment: 25 mg/kg

yes

Total Cobalt, Co

7440-48-4

No intentional use

500 mg/kg

yes

Total Nickel, Ni

7440-02-0

No intentional use

250 mg/kg

yes

Total Antimony, Sb

7440-36-0

No intentional use

Dye: 50 mg/kg
Pigment: 250 mg/kg

yes

Total Arsenic, As

7440-38-2

No intentional use

50 mg/kg

yes

Total Copper, Cu

7440-50-8

No intentional use

250 mg/kg

yes

Total Chromium, Cr

7440-47-3

No intentional use

100 mg/kg

yes

Total Silver (Ag)7440-22-4

No intentional use

100 mg/kg

yes

Total Barium

7440-39-3

No intentional use

100 mg/kg

yes

Total Selenium

7782-49-2

No intentional use

Dye: 20 mg/kg
Pigment: 100 mg/kg

yes

Total Tin

7440-31-5

No intentional use

250 mg/kg

yes

title

title

title

No intentional use

10 mg/kg

yes

title

title

title

Extractable HM
Extractable Chromium (VI), CrVI

(Non-Jewelry)
18540-29-9

12. Glycols
Bis(2-methoxyethyl)-ether;111-96-6

No intentional use

50 mg/kg

yes

2-methoxyethanol;

109-86-4

No intentional use

50 mg/kg

yes

2-methoxyethylacetate;110-49-6

No intentional use

50 mg/kg

yes

24/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

Ethylene glycol dimethyl ether / 1,2dimethoxyethane

110-71-4

No intentional use

50 mg/kg

yes

2-ethoxyethanol;

110-80-5

No intentional use

50 mg/kg

yes

2-ethoxyethyl acetate;111-15-9

No intentional use

50 mg/kg

yes

yes

2-methoxypropylacetate;70657-70-4

No intentional use

Textile: 50 mg/kg
Leather: 50 mg/kg, 1000 mg/kg(finishing formulations)
Not Applicable for polymer

2-methoxypropanol

1589-47-5

Textile&polymers: No
intentional use
Leather: canditate

Textile & polymers: 50 mg/kg
Leather: candidate

yes

1,2-bis(2-methoxyethoxy)ethane
Triethylene glycol dimethyl ether (TEGDME)

112-49-2

No intentional use

50 mg/kg

yes

title

title

title

No intentional use

leather: 200 mg/kg
Textile & Plastics: Sum except
BaP: 200 mg/kg

yes

13. PAHs

Naphthalene

91-20-3

Acenaphthylene

208-96-8

No intentional use

Acenaphthene83-32-9

No intentional use

Fluorene

86-73-7

No intentional use

Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg

yes

yes

yes

25/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturing

Phenanthrene

1985/1/8

No intentional use

Anthracene120-12-7

No intentional use

Fluoranthene

206-44-0

No intentional use

Pyrene129-00-0

No intentional use

Indeno[1,2,3-cd]pyrene

193-39-5

No intentional use

Benzo[ghi]perylene

191-24-2

No intentional use

Benzo-[a]-anthracene(BaA)

56-55-3

No intentional use

Chrysene(CHR)

218-01-9

No intentional use

in Chemical formulations
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
20 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg

ZDHC MRSL
v3.1

yes

yes

yes

yes

yes

yes

yes

yes

26/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

Benzo-[a]-pyrene (BaP)

50-32-8

No intentional use

Dibenzo-[a,h]-anthracene (DBAhA)

53-70-3

No intentional use

Benzo-[b]-fluoranthene(BbFA)

205-99-2

No intentional use

Benzo-[k]-fluoranthene(BkFA)

207-08-9

No intentional use

Benzo-[e]-pyrene(BeP)

192-97-2

No intentional use

Benzo-[j]-fluoranthene(BjFA)

205-82-3

No intentional use

Cyclopenta[c,d]pyrene

27208-37-3

No intentional use

Sum: 200 mg/kg 20 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
Sum: 200 mg/kg
Leather: Sum except
BaP&Naphthalene: 200 mg/kg
Textile & Polymers: Sum except
BaP: 200 mg/kg
1000 mg/kg*

Dibenzo-[a,e]pyrene

192-65-4

No intentional use

1000 mg/kg*

Dibenzo-[a,h]pyrene

189-64-0

No intentional use

1000 mg/kg*

Dibenzo-[a,i]pyrene
Dibenzo-[a,l]pyrene

189-55-9
191-30-0

No intentional use
No intentional use

1000 mg/kg*
1000 mg/kg*

1-Methylpyrene

2381-21-7

No intentional use

1000 mg/kg*

title

title

14. Pesticides

ZDHC MRSL
v3.1

yes

yes

yes

yes

yes

yes

title

27/36

FR MRSL v2024
Requirements
Parameter

CAS Number
in Manufacturingin Chemical formulations

ZDHC MRSL
v3.1

AEEA [2-(2-aminoethylamino)ethanol]

111-41-1

No intentional use

100 mg/kg

yes

Borate, zinc salt

12767-90-7

No intentional use

250 mg/kg 1000 mg/kg

yes for CAS
No.: 1332-07-6
yesPermethrin

52645-53-1

No intentional use

250 mg/kg(Exemption for
mentioned
processes)

Silica (particles of respirable size)

14464-46-1

No intentional use

No use of Sand Blastingyes

Thiourea

62-56-6

No intentional use

1000 mg/kg

yes

Triclosan

3380-34-5

No intentional use

250 mg/kg

yes

title

title

title

17. Others
Diazene-1,2-dicarboxamide [C,C`-azodi(formamide),
ADCA]

123-77-3

No intentional use

1000 mg/kg

yes

Dimethyl Fumarate (DMFU)

624-49-7

No intentional use

10 mg/kg

yeso-Phenylphenol (OPP)

90-43-7

Textile: No intentional use
Leather:
Use is permitted for chemicalpreservation for transportationand storage of raw hides as aswell as tanned semi-finishedproducts (wet-white, wet- blue).
Chemical preservation ofcoated or uncoated finishedleather shall not be permitted.

Textile: 5000 mg/kg

yes

Bisphenol-A

80-05-7

No intentional use

100 mg/kg
No restriction on polymer

yes

91-22-5

No intentional use

1000 mg/kg

yes

Multiple,
including
11138-47-9,

No intentional use

1000 mg/kg

yes

Quinoline
Perboric acid, sodium salt

28/36

FR MRSL v2024
Requirements
Parameter

CAS Number

ZDHC MRSL
v3.1

in Manufacturingin Chemical formulations

No intentional use

1% (w/w) of TiO2 particles haveaerodynamic diameter ≤10 μm.
(Liquid mixtures or emulsions or
pastes containing TiO2, having
proper GHS/CLP classification,
are allowed for use.)

yes

title

title

title

15120-21-5,
7632-04-04,
16940-66-2,
13517-20-9,
125022-34-6,
90568-23-3
Titanium dioxide particles have aerodynamic
diameter ≤10 μm.

13463-67-7

20. UV stabilizers
2-(2-hydroxy-3,5-di-tert-butylphenyl)benzotriazole (UV 320)

3846-71-7

No intentional use

1000 mg/kg

yes

2-(2-hydroxy-3,5-di-t-butylphenyl)-5chlorobenzotriazol (UV 327)

3864-99-1

No intentional use

1000 mg/kg

yes

2-(2-hydroxy-3-sec-butyl-5-tertbutylphenyl)benzotriazole (UV 350)

36437-37-3

No intentional use

1000 mg/kg

yes

2-(2-hydroxy-3,5-di-tert-pentylphenyl)benzotriazole(UV 328)

25973-55-1

No intentional use

1000 mg/kg

yes

title

title

title

23. Siloxanes
Octamethylcyclotetrasiloxane (D4)556-67-2

No intentional use

1000 mg/kg

yes

Decamethylcyclopentasiloxane (D5)541-02-6

No intentional use

1000 mg/kg

yes

Dodecamethylcyclohexasiloxane (D6)

540-97-6

No intentional use

1000 mg/kg

yes*FR MRSL への収載基準を満たしてはいるものの、最終的な基準値を設定するにはさらなる情報を必要とする物質の暫定基準値です。

29/36

Chapter 2: MRSL 候補リスト
FR MRSL v2023
Parameter

CAS Number
IntentZDHC MRSL
v3.1

8a. Halogenated solvents / VOCs
2-(2-methyoxyethoxy)-ethanol

111-77-3

Methanol

67-56-1

In Version 3 of the ZDHC MRSL, it is intended to place restrictions oncertain solvents with certain specific hazardous properties (e.g.
CMRs). The restrictions are likely to apply to the inclusion of such
solvents in formulations for use by wet processors and productassembly factories - and deliberate use of neat solvents in thosefacilities. Studies on usage patterns, exposure controls, safer
alternatives and the potential effects of restrictions are necessary
before restrictions can beproposed. Any potential ZDHC MRSL limits will need to be establishedcollaboratively with groups who are working in parallel to study
solvents in relation to workplace safety, air emissions, RSL complianceand downstream concerns.

Yes(Candidate)

Yes(Candidate)

15. Formaldehyde

Formaldehyde

50-00-0

The deliberate use of formaldehyde or inclusion of formaldehyde informulations is not permitted. In Version 3 of the ZDHC MRSL, it isintended to place restrictions on the maximum permitted levels offormaldehyde in formulations. The use, presence, and generation offormaldehyde is a complex subject and studies are required todetermine appropriate levels.

Yes(Candidate)

108-95-2

ZDHC is looking for safe limits for phenol as a contaminant in textile
chemical formulations.

Yes(Candidate)

17. Others
Phenol30/36

Chapter 3: アーカイブされた物質

Parameter

CAS Number

ZDHC MRSL
v3.1

1. CAS # 118685-33-9;
2. Not AllocatedYes(Archived)

4c. Navy Blue
Navy Blue

title

4d. Disperse & Carcinogenic Dyes
Basic Yellow 2/ Solvent yellow 34(hydrochloride and free base)60-11-7

Yes(Archived)

Basic Yellow 2

2465-27-2
492-80-8

Yes(Archived)

D&C Red No. 19

81-88-9

Yes(Archived)
title

8a. Halogenated solvents / VOCs
Bis(chloromethyl)ether

542-88-1

Yes(Archived)

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追加要求事項
上記の表で要求されている特定の有害化学物質のほかに、生産においてファーストリテイリングが必要とするいくつかの追加要求事項があります。これらには、アスベ
スト、PVC 材料に関する制限等が含まれます。以下のセクションで詳細を説明します。
1. アスベスト
アスベストの使用は、多くの国や地域において、発がん物質として国内法で禁止されています。アスベストは、スレート、断熱材および保温材に使用されており、アスベスト粒子が人体によって吸入された場合に、肺線維症、悪性中皮腫および肺がんの根本的原因となる可能性があることがわかっています。アスベストが施設内で使用されると、従業員や周囲の環境に深刻な健康影響を与える可能性があります。アスベストは非常に危険な物質であるため、有資格の専門家による調査および処理が必要です。アスベストを含む材料が確認された場合、以下の対策を講じる必要があります。
- 使用されているアスベストの場所を記録し、適切かつ目に見えるようにマークする必要があります。その後の悪影響を防ぐための対策を講じる必要があります。
- 処分が完了するまで潜在的な悪影響をチェックするための目視検査を行ってください。
- アスベストの認知度を高め、アスベストの悪影響が見つかった場合の対応策を習得するために、従業員は訓練を受けなければなりません。
- 廃棄は関連法に従って行わなければなりません。
- 悪影響を起こすアスベストは、資格のある業者によって修理されなければなりません。
2. PVC 素材
ファーストリテイリングは、すべての FR 商品（コンポーネントを含む）での PVC 素材の使用を禁止しています。 PVC は広く使用されている熱可塑性ポリマーであり、それは可塑剤の添加によってより柔軟性をもたせることができます。 最も広く使用されている可塑剤はフタル酸エステル類です。アパレル業
界では、PVC 素材は一般にコート、ジャケット、エプロン、バッグに使用されています。 ファーストリテイリングは、以下の理由により PVC 素材を禁止して
います。

32/36

➢

多くのフタル酸エステル類は生殖毒性があることが知られており、先天性異常またはホルモンレベルの変化を引き起こす可能性があります。 2013年のファーストリテイリングのコミットメントにおいても、フタル酸エステル類は 11 の優先的に廃絶すべき有害化学物質のうちのひとつです。

➢

塩化ビニル製造の副産物として、また家庭ごみ中の廃 PVC の焼却によって、ダイオキシンが生成されると言われています。

33/36

Appendix 1. 想定される使用用途

Chemical Group

1. APs / APEOs

2. Phthalates (ortho-Phthalates)

Potential Uses in Apparel and Footwear Textile Processing

APEOs can be used as or found in:
Detergents, scouring agents, spinning oils, wetting agents, softeners, emulsifier/dispersing agents for dyes andprints, impregnating agents, degumming for silk production, dyes and pigment preparations, polyester padding anddown/feather fillings.
Esters of ortho-phthalic acid (phthalates) are a class of organic compounds commonly added to plastics to increase
flexibility. They sometimes are used to facilitate moulding of plastic by decreasing its melting temperature.
Phthalates can be found in:•
Flexible plastic components (e.g., PVC)•
Print pastes•
Adhesives•
Plastic buttons•
Plastic sleevings•
Polymeric coatings

3a. Brominated Flame Retardants
3b. Chlorinated Flame Retardants

Flame retardant chemicals are rarely used to meet flammability requirements in children’s clothing and adultproducts. They should no longer be used in apparel and footwear.

4a. Azo Dyes

Azo dyes and pigments are colourants that incorporate one or several azo groups (-N=N-) bound with aromaticcompounds. Thousands of azo dyes exist, but only those that degrade to form the listed cleavable amines are
restricted. Azo dyes that release these amines are regulated and should no longer be used for dyeing of textiles.

4b. Navy Blue

Navy Blue colourants are regulated and should no longer be used for dyeing of textiles.
Most of Carcinogenic dyes are regulated and should no longer be used for dyeing of textiles.

4c. Disperse & Carcinogenic Dyes

Disperse dyes are a class of water-insoluble dyes that penetrate the fibre system of synthetic or manufactured fibres
and are held in place by physical forces without forming chemical bonds. Disperse dyes are used in synthetic fibre

34/36

Chemical Group

Potential Uses in Apparel and Footwear Textile Processing(e.g., polyester, acetate, polyamide). Restricted disperse dyes are suspected of causing allergic reactions andshould no longer be used for dyeing of textiles.

5. Organotin Compounds

6. PFCs

Organotins are a class of chemicals combining tin and organics such as butyl and phenyl groups. Organotins are
predominantly found in the environment as antifoulants in marine paints, but they can also be used as biocides (e.g.,
antibacterials), catalysts in plastic and glue production and heat stabilisers in plastics/rubber. In textiles and apparel,organotins are associated with plastics/rubber, inks, paints, metallic glitter, polyurethane products and heat transfer
material.
Durable water, oil and stain repellent finishes and soil release finishes (fluorinated polymers) based on long-chain
technology are banned from intentional use. Long-chain compounds according to the Organisation for Evonomic Cooperation and Development (OECD) definition (https://www.oecd.org/ehs/pfc/) are based on long-chain
perfluorocarboxylic acids (C8 and higher) and on long-chain perfluoroalkyl sulfonates (C6 and higher).
The main contaminants of this technology include:
Perfluoroalkyl sulfonates (PFSAs) with carbon chain lengths C6 and higher (e.g., PFOS, perfluorooctane sulfonate)
Perfluorocarboxylic acids with carbon chain lengths C8 and higher (e.g., PFOA, perfluorooctanoic acid)PFOA and PFOS may be present as unintended by-products in long-chain commercial water, oil and stain repellent
agents. PFOA also may be in use for polymers like polytetrafluoroethylene (PTFE).

7. COC (Chlorobenzenes/Chlorotoluenes)

Chlorobenzenes and chlorotoluenes (chlorinated aromatic hydrocarbons) can be used as carriers in the dyeing
process of polyester or wool/polyester fibres. They can also be used as solvents.

8a. Halogenated Solvents / VOCs

In apparel and footwear, solvents are used as finishing/cleaning and printing agents, for dissolving and diluting fats,oils and adhesives (e.g., in degreasing or cleaning operations).

8b. Other Solvents

These volatile organic compounds should not be used in textile auxiliary chemical preparations. They are associatedwith solvent-based processes like solvent-based polyurethane coatings and glues/adhesives. They should not be
used for any kind of facility cleaning or spot cleaning.

9. Chlorinated Phenols / OPP

Chlorophenols are poly chlorinated compounds used as preservatives or pesticides.
Pentachlorophenol (PCP) and tetrachlorophenol (TeCP) have been used in the past to prevent mould when storing /transporting, raw hides and leather. They are now regulated and should not be used.

35/36

Chemical Group

10. Chlorinated Paraffins (SCCP / MCCP)

Potential Uses in Apparel and Footwear Textile Processing

Short-chain chlorinated paraffins can be found as contaminants within long-chain chlorinated paraffins and sulfochlorinated paraffins, used as fat liquoring agents.
••

11. Heavy Metals•••

Arsenic and its compounds can be used in some preservatives, pesticides and defoliants for cotton. It isalso associated with synthetic fibres, paints, inks, trims and plastics.
Cadmium compounds are found in or used as: pigments (particularly red, orange, yellow and green), a
stabilizer for PVC plastic and in fertilisers, biocides and paints (e.g., surface paints on zippers andbuttons).
Mercury compounds can be present in pesticides and can be found as contamination in caustic soda
(NaOH). Mercury compounds may be used in paints (e.g., surface paints on zippers and buttons).
In apparel and footwear, lead may be associated with plastics, paints, inks, pigments and surface
coatings.
Although typically associated with leather tanning, chromium VI also may be used in the dyeing of wool
(after the chroming process).

12. Glycols

In apparel and footwear, glycols have a wide range of uses including as solvents for finishing/cleaning, printing
agents, and dissolving and diluting fats, oils and adhesives (e.g., in degreasing or cleaning operations).

13. PAHs

Polycyclic aromatic hydrocarbons (PAHs) are natural components of crude oil and are a common residue from oil
refining. PAHs have a characteristic smell similar to the smell of car tires or asphalt. Oil residues containing PAHs
are added to rubber and plastics as a softener or extender and may be found in rubber, plastics, lacquers andcoatings. PAHs are often found in the outsoles of footwear and in printing pastes of screen prints. PAHs can bepresent as impurities in Carbon Black. They also may be formed from thermal decomposition of recycled materials
during reprocessing.

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