Safety Data Sheet

According to Regulation (EC) No 1907/2006, Annex II,Amended by COMMISSION REGULATION (EU) 2015/830,
According to REGULATION (EC) No 1272/2008
PolyDissolve™ S1Version 1.0
Issue date: 09-07-2019
Revision date: 09-07-2019

SDS Record Number: CSSS-TCO-010-131603

Section 1 Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier:Identification on the label/Trade name:

PolyDissolve™ S1

Additional identification:

Not available

Identification of the product:

See section 3

Index Number:

See section 3

REACH registration No.:See section 3

1.2 Relevant identified uses of the substance or mixture and uses advised against:
1.2.1 Identified uses:
3D Printing Filament.
1.2.2 Uses advised against:
Not available.

1.3 Details of the supplier of the safety data sheet:
Supplier(Only representative):-Supplier(Manufacturer):

JF Polymers (Suzhou) Co., Ltd.

Address:

Building 6&7&11, No.2, Hai Cheng Road, Chang Shu Economic &Technological Development Zone, 215513, People’s Republic of China

Contact person(E-mail):zhenggang.cai@polymaker.com

Telephone:

0086-512-52058005Fax:-1.4 Emergency telephone Number:
0086-512-52058005 Only available during office hours (9:00a.m.-17:30p.m. Beijing Time Zone)
Available outside office hours?

YESNOXSection 2 Hazards Identification
2.1 Classification of the substance or mixture:
2.1.1 Classification:
The mixture is classified as following according to REGULATION (EC) No 1272/2008:
REGULATION (EC) No 1272/2008
Hazard classes/Hazard categories

Hazard statement

Eye Irrit. 2H319

For full text of H- phrases: see section 2.2.

2.2 label elements:
Hazard Pictograms:

Product name: PolyDissolve™ S1Version #: 1.0
Issue date: 09-07-2019.

Revision date: 09-07-2019.

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Signal Word(S):WarningHazard Statement:

H319: Causes serious eye irritation.
P264: Wash hands thoroughly after handling.

Precautionary statement:

P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313: If eye irritation persists: Get medical advice/attention.

2.3 Other hazards:
Not applicable.

Section 3 Composition/information on ingredients
MixtureSubstance/Mixture:
Ingredient(s):Chemical Name

RegistrationNo.

CAS No.

EC No.

Concentration

Classification

Poly(vinyl alcohol)

N/A

25213-24-5

N/A

> 80%

H319

Poly(ethylene glycol)

N/A

25322-68-3

N/A

> 3%

Not Classified

Calcium chloride

N/A

10043-52-4

233-140-8< 0.5%

H319

Section 4 First aid measures
4.1 Description of first aid measures:
In all cases of doubt, or when symptoms persist, seek medical attention.
4.1.1 In case of inhalation:
Remove to fresh air. Get medical attention for any breathing difficulty.
4.1.2 In case of skin contact:
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. Keep warm and in aquiet place. Call a physician or poison control center immediately. Wash contaminated clothing before re-use.
4.1.3 In case of eyes contact:
Immediately flush eyes with plenty of water, lifting upper and lower eyelids occasionally. Get medical attention if irritation
persists.
4.1.4 In case of ingestion:
Call a physician or poison control centre immediately. Take victim immediately to hospital. If swallowed, rinse mouth withwater (only if the person is conscious). Do NOT induce vomiting. Artificial respiration and/or oxygen may be necessary.

4.2 Most important symptoms and effects, both acute and delayed:
Causes serious eye irritation.

4.3 Indication of any immediate medical attention and special treatment needed:
If skin irritation or rash occurs, get medical advice/attention.

Section 5 Firefighting measures
5.1 Extinguishing media:
Suitable extinguishing media:

Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment.

Unsuitable extinguishing media:

5.2 Special hazards arising from theProduct name: PolyDissolve™ S1Version #: 1.0
Issue date: 09-07-2019.

Not available.
No further relevant information available.
Revision date: 09-07-2019.

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substance or mixture
5.3 Advice for firefighters:

In the event of fire, wear self-contained breathing apparatus. Use personal
protective equipment. Wear chemical resistant oversuit. Cool containers / tankswith water spray.

Section 6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
6.1.1 For non-emergency personnel:

Avoid dust formation.

6.1.2 For emergency responders:

Wear an appropriate NIOSH/MSHA approved respirator if dust is generated.

6.2 Environmental Precautions:

Do not let large amount of product enter drains.

6.3 Methods and material for Containment
and Cleaning up:

Sweep up and shovel into suitable containers for disposal. Avoid dust formation.
Keep in properly labelled containers. Keep in suitable, closed containers fordisposal.

6.4 Reference to other sections:See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

Section 7 Handling and storage
7.1 Precautions for safe handling:
7.1.1 Protective measures:

Provide appropriate exhaust ventilation at places where dust is formed.

7.1.2 Advice on general occupational

Do not eat, drink and smoke in work areas. Wash hands after use. Remove

hygiene:

7.2 Conditions for safe storage, including
any incompatibilities:

contaminated clothing and protective equipment before entering eating areas.
Store in original container. Keep in a well-ventilated place. Keep in a dry place.
Keep in properly labelled containers. Keep container closed. Avoid dust
formation. Keep away from incompatible products.

7.3 Specific end use(s):Not applicable.

Section 8 Exposure Controls/Personal Protection
8.1 Control parameters:
8.1.1 Occupational exposure limits:

Poly(ethylene glycol)(CAS# 25322-68-3): TWA-average:1000 mg.m-3; shortterm- category: IV.( Slovakia 2007)

8.1.2 Additional exposure limits under theNot available.

conditions of use:
8.1.3 DNEL/DMEL and PNEC-Values:

Not available.

8.2 Exposure controls:
8.2.1Appropriate engineering controls:

Ensure adequate ventilation. Apply technical measures to comply with theoccupational exposure limits.

8.2.2 Individual protection measures, such as personal protective equipment:
Eye/face protection:

Safety goggles.

Hand protection:

Wear protective gloves.

Body protection:

Wear protective clothing.

Respiratory protection:

Use with adequate ventilation. In case of insufficient local exhaust ventilation,wear protective mask.

Thermal hazards:
8.2.3 Environmental exposure controls:

Wear suitable protective clothing to prevent heat.
Avoid discharge into the environment.
According to local regulations, Federal and official regulations.

Section 9 Physical and chemical properties
Product name: PolyDissolve™ S1Version #: 1.0
Issue date: 09-07-2019.

Revision date: 09-07-2019.

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9.1 Information on basic physical and chemical properties:
Appearance:

SolidColour:

White translucent

Odour:

Not available

Odour threshold:Not available

pH:

Not available

Melting point/range (°C):

178°C

Boiling point/range (°C):

Not available

Flash point (°C):

Not available

Evaporation rate:

Not available

Flammability limit - lower (%):

Not available

Flammability (solid, gas):

Not available

Ignition temperature (°C):

Not available

Upper/lower explosive limits:

Not available

Vapour pressure (20°C):

Not available

Vapour density:

Not available
1.08

Relative Density:
Bulk density (kg/m3):

Not available

Water solubility (g/l):

Soluble in watern-Octanol/Water (log Po/w):

Not available

Auto-ignition temperature:

Not available

Decomposition temperature:

Not available

Viscosity, dynamic (mPa.s):

Not available

Explosive properties:

Not available

Oxidising properties:

Not available

9.2. Other information:
Fat solubility(solvent-oil to be specified)

Not available

etc:
Surface tension:

Not available

Dissociation constant in water( pKa):

Not available

Oxidation-reduction Potential:

Not available

Section 10 Stability and reactivity
10.1 Reactivity:
10.2 Chemical stability:

The substance is stable under normal storage and handling conditions.
Stable at room temperature in closed containers under normal storage andhandling conditions.

10.3 Possibility of hazardous reactions:10.4 Conditions to avoid:No dangerous reactions known.
Incompatible materials. Keep away from direct sunlight. To avoid thermal
decomposition, do not overheat.

10.5 Incompatible materials:
10.6 Hazardous decomposition products:

Strong oxidizing agents.
Carbon oxides.

Section 11 Toxicological information
11.1 Information on toxicological effects:
Acute toxicity:
ATEmix(oral):
Product name: PolyDissolve™ S1Version #: 1.0
Issue date: 09-07-2019.

Not available

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ATEmix(inhalation):

Not available

ATEmix(Dermal):

Not available

Calcium chloride (CAS: 10043-52-4)
LD50(Oral, Rat):

2301 mg/kg bw

LC50(Inhalation, Rat):

Not available

LD50(Dermal, Rabbit):> 5 000 mg/kg bw

Skin corrosion/Irritation:

Not classified

Serious eye damage/irritation:

Causes serious eye irritation.

Respiratory or skin sensitization:

Not classified

Germ cell mutagenicity:

Not classified

Carcinogenicity:

Not classified

Reproductive toxicity:

Not classified

STOT- single exposure:

Not classified

STOT-repeated exposure:

Not classified

Aspiration hazard:

Not classified

Section 12 Ecological information
12.1 Toxicity:
Calcium chloride (CAS: 10043-52-4)
Acute (short-term) toxicity:
LC50(96h, Fish):4630 mg/L

LC50(48h, Crustacea):

2400 mg/L

EC50(72h, Algae/aquatic plants):

2900 mg/L

Chronic (long-term) toxicity:
NOEC(Fish):

Not available.

NOEC(Crustacea):

Not available.

EC50(Algae/aquatic plants):

Not available.

12.2 Persistence and degradability:

Not available.

12.3 Bioaccumulative potential:

Not available.

12.4 Mobility in soil:

Not available.

12.5 Results of PBT and vPvB assessment:

Not applicable12.6 Other adverse effects:

Not available.

Section 13 Disposal considerations
13.1 Waste treatment methods:

Dispose of in accordance with all applicable local and national regulations. Use
recovery/recycling where feasible, otherwise incineration is the recommended
method of disposal. Empty containers may contain hazardous residues. Do not
cut, puncture or weld on or near to the container. Labels should not be removed
from containers until they have been cleaned. Contaminated containers mustnot be treated as household waste. Containers should be cleaned byappropriate methods and then re-used or disposed of by landfill or incineration
as appropriate. Do not incinerate closed containers.

Section 14 Transport information
Product name: PolyDissolve™ S1Version #: 1.0
Issue date: 09-07-2019.

Revision date: 09-07-2019.

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Land transport

Inland waterways

Sea transport

Air transport(ADR/RID)(ADN)(IMDG)(ICAO/IATA)

UN number

Not regulated

Not regulated

Not regulated

Not regulated

UN Proper shipping nameNot regulated

Not regulated

Not regulated

Not regulated

Transport hazard Class(es)Not regulated

Not regulated

Not regulated

Not regulated

Packing group

Not regulated

Not regulated

Not regulated

Not regulatedNoNoNoNo

See section 2.2

See section 2.2

See section 2.2

See section 2.2

Not regulated

Not regulated

Not regulated

Not regulated

Environmental hazards
Special precautions for user
Transport in bulk according
to Annex II of Marpol andthe IBC CodeSection 15 Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Relevant information regarding authorization:

Not applicable.

Relevant information regarding restriction:

Not applicable.
Employment restrictions concerning young person must be observed.

Other EU regulations:

For use only by technically qualified individuals.
Other National regulations:Not applicable15.2 Chemical safety assessment

YESNOX

Section 16 Other information
16.1 Indication of changes:
Version 1.0

Amended by (EU) 2015/830

16.2 Abbreviations and acronyms:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation for rail International transportation of Dangerous goods
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: Code international maritime dangerous goods code
ICAO: International Civil Aviation Organization
IATA: International Air Transport AssociationLC50: median lethal concentration
EC50: The effective concentration of substance that causes 50% of the maximum response.
NOEC: No Observed Effect Concentration
DNEL: derived no-effect level
PNEC: predicted no-effect concentration

16.3 Key literature references and sources for data
ECHA Registered substances data

16.4 Classification and procedure used to derive the classification for mixtures according to Regulation (EC)1272/2008 [CLP]Classification according to Regulation (EC) No. 1272/2008

Classification procedure

Eye Irrit. 2Calculation method

H319

16.5 Relevant H-statements (number and full text):
H319: Causes serious eye irritation.

16.6 Training instructions:Not applicable.
Product name: PolyDissolve™ S1Version #: 1.0
Issue date: 09-07-2019.

Revision date: 09-07-2019.

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16.7 Further information:
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for thisproduct.

16.8 Notice to reader:
Employers should use this information only as a supplement to other information gathered by them, and should makeindependent judgment of suitability of this information to ensure proper use and protect the health and safety of employees. This
information is furnished without warranty, and any use of the product not in conformance with this Safety Data Sheet, or incombination with any other product or process, is the responsibility of the user.
Author: Hangzhou C&K Testing Technic Co.,Ltd Website:www.cirs-ck.com

Product name: PolyDissolve™ S1Version #: 1.0
Issue date: 09-07-2019.

Revision date: 09-07-2019.

Tel:0571-89900715 Email:test@cirs-group.com

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