iBou Inc.

Diluted Alkydresin Paint

2022/7/22

P300022722GB-4
Issue date: 2022/7/22

Safety Data Sheet

Revision date: 2022/7/22
Version: 4

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product Identifier
Diluted Alkydresin Paint
Substance or Mixture name：EC No.
：
REACH No.
：CAS No.
：1.2. Relevant identified uses of the substance or mixture and uses advised against
Industrial uses
Sector of uses [SU]：Coatings and paints, fillers, putties, thinners
Use of the substance/mixture：
Do not use for products which come into contact with the food stuffs.
Uses advised against：
1.3 Details of the Supplier of the Safety Data Sheet
Supplier
iBou Inc.
：
81 Nakao, Nago city, Okinawa pref., Japan
Address：
905-1153
P.O.Box：123-4567
Telephone：123-5678
Telefax：
iboughs@yahoo.co.jp
E-Mail：1.4 Emergency telephone number
234-5678
Emergency telephone number：
Only available during office hours.
Remark：SECTION 2: Hazards identification
2.1. Classification of the substance or mixture：
Flammable liquids:Flam. Liq. 2
Acute toxicity oral:Not classified
Acute toxicity Dermal:Not classified
Acute toxicity inhalation:Acute Tox. 4Skin corrosion/irritation:Skin Corr. 2
Serious eye damage/eye irritation:Eye Irrit. 2
Respiratory sensitization:Not classified
Skin sensitization:Not classified
Germ cell mutagenicity:Muta. 1B
Carcinogenicity:Carc. 1B
Reproductive toxicityv:Repr. 1ASpecific target organ toxicity - Single exposure:STOT SE3(Narc.-effects)
Specific target organ toxicity -Repeated exposure:STOT RE 2 (Respiratory system)
Aspiration hazard:Not classified
Hazardous to the aquatic environment-Acute hazard:Not classified
Chronic aquatic hazard:Aquatic Chronic 2
Hazardous to the ozone layer:Classification not possible
Reproductive toxicity (Effects on or via lactation):Classification not possible

2.2. Label elements：
Hazard pictograms：
Notapplicable

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Diluted Alkydresin Paint
Signal word：

P300022722GB-4

2022/7/22

DangerHazard statements：
H225· Highly flammable liquid and vapour
H315· Causes skin irritation
H319· Causes serious eye irritation
H332· Harmful if inhaled
H336· May cause drowsiness or dizziness
H340· May cause genetic defects
H350· May cause cancer
H360· May damage fertility or th unborn child
H373· May cause damage to organs through prolonged or repeated exposure (Respiratory system)
H411· Toxic to aquatic life with long lasting effects

Precautionary statement：【Prevention】·Obtain special instructions before use
P201·Do not handle until all safety precautions have been read and understood
P202·Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P210·Keep container tightly closed.
P233·Ground/bond container and receiving equipment.
P240·Use explosion-proof electrical/ventilating/lighting equipment.
P241·Use only non-sparking tools.
P242·Take precautionary measures against static discharge.
P243·Do not breathe dust/fume/gas/mist/vapours/spray.
P260·Avoid breathing dust/fume/gas/mist/vapours/spray.
P261·Wash hands thoroughly after handling.
P264·Use only outdoors or in a well-ventilated area.
P271·Avoid release to the environment.
P273·Wear protective gloves/protective clothing/eye protection/face protection.
P280

P302+P352
P303+P361+P353
P304+P340
P305+P351+P338
P308+P313
P312
P314
P321
P332+P313
P337+P313
P362+P364
P370+P378
P391

P403+P233
P403+P235
P405

P501

【Response】·IF ON SKIN: Wash with plenty of water and soap
·IF ON SKIN(or hair): Take off immedately all contaminated clothing. Rinse skin with water/shoewer.
·IF INHALED: Remove person to fresh air and keep comfortable for breathing·IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
·IF exposed or concerned: Get medical advice/attention.
·Call a POISON CENTER/doctor if you feel unwell.
·Get medical advice/attention if you feel unwell.
·Specific treatment (see this label)·If skin irritation occurs, Get medical advice/attention.
·If eye irritation persists, Get medical advice/attention.
·Take off contaminated clothing and wash it before reuse.
· In case of fire: Use appropriate extinguisher to extinguish.
·Collect spillage.

【Storage】·Store in a well-ventilated place. Keep container tightly closed.
·Store in a well-ventilated place. Keep cool.
·Store locked up.

【Disposal】·Dispose of contents/container in accordance with local regulations.

Supplemental Hazard information (EU) :EUH201 EUH208 EUH210 H225 H226 H304 H312 H315 H318 H319 H332 H335 H336 H340 H350
H360Df H361d H373 H400 H410
91.90% of the mixture consists of components of unknown toxicity-oral 92.10% of the mixture consists of componentsof unknown toxicity-dermal 85.58% of the mixture consists of components of unknown toxicity-inhalation

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Diluted Alkydresin Paint

P300022722GB-4： Mixtures

SECTION 3: Composition / information on ingredients
Substance

REACH Reg. No.

2022/7/22%（weight) Type of No

No.

Hazard class,category, H code
Flam. Liq. 2,STOT SE 3,Eye
Irrit. 2 H225,H336,H319

Ethyl acetate

Not available

0～5%

CAS

141-78-6

n-Propyl acetate

Not available

0～5%

CAS

109-60-4

n-Amyl acetate

Not available

0～5%

CAS

628-63-7Ethylbenzene

123-570～5%CAS100-41-4

White spirit, max 20% aromates

Not available

0～5%

CAS

8052-41-3

TolueneNot available

CAS

108-88-3

Flam. Liq. 2,Repr. 2,Asp. Tox.
1,STOT SE 3,STOT RE 2,Skin
Irrit. 2 H225,H361d,H304,H336,H373 ,H315
Carc. 1B,Muta. 2,Acute Tox.
3,Acute Tox. 3,Acute Tox. 3,Skin
Corr. 1B,Skin Sens. 1
H350,H341,H331,H311,H301,H3
14,H317

Formaldehyde

Not available

Isomelamine
Alkyd resins

5～10%

0～5%

CAS

50-00-0

15～20%
0～5%

CAS
CAS

108-78-1
63148-69-6

Flam. Liq. 2,STOT SE 3,Eye
Irrit. 2 H225,H336,H319
Flam. Liq. 3 H226
Flam. Liq. 2,Acute Tox. 4,Asp.
Tox. 1,STOT RE 2
H225,H332,H304,H373 (hearing
Carc. 1B,Muta. 1B,Asp. Tox.
1,STOT RE 1
H350,H340,H304,H372 (central
nervous system)

Butan-2-one

Not available

0～5%

CAS

78-93-3

Flam. Liq. 2,STOT SE 3,Eye
Irrit. 2 H225,H336,H319

Xylene, or mixed isomers

Not available

0～5%

CAS

1330-20-7

Flam. Liq. 3,Acute Tox. 4,AcuteTox. 4,Skin Irrit. 2
H226,H332,H312,H315

Titanium dioxide
lead sulphate
n-Butyl acetate

Not available

0～5%
0～5%
0～5%

CAS
CAS
CAS

13463-67-7
7446-14-2
123-86-4

2-Methylpropan-1-ol

Not available

0～5%

CAS

78-83-1

Flam. Liq. 3,STOT SE 3,STOTSE 3,Skin Irrit. 2,Eye Dam. 1
H226,H335,H336,H315,H318

Propan-2-ol

Not available

45～50%

CAS

67-63-0

Flam. Liq. 2,STOT SE 3,Eye
Irrit. 2 H225,H336,H319

7758-97-6

Carc. 1B,Repr. 1A,STOT RE
2,Aquatic Acute 1,Aquatic
Chronic 1 H350,H360Df,H373,H400,H410

Lead chromate (as Cr)

Not available

Additional information :Full text of H-statements to be referred in SDS Section 16

5～10%

CAS

Flam. Liq. 3,STOT SE 3 H226,H336

SECTION 4: First aid measures
4.1. Description of first aid measures
General information :Medical treatment necessary. Call a physician in any case! Call a physician immediately. Seek medical advice
immediately. In case of allergic symptoms, especially in the breathing area, seek medical advice immediately.
Observe risk of aspiration if vomiting occurs. Remove affected person from the danger area and lay down. Transport
affected person in flat position. Do not leave affected person unattended. Remove victim out of the danger area. In
case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if
possible). Remove contaminated, saturated clothing immediately. Wash thoroughly the body (shower or bath).
Symptoms may develop several hours following exposure; medical observation therefore necessary for at least 48
hours. When in doubt or if symptoms are observed, get medical advice. Never give anything by mouth to an
unconscious person or a person with cramps. If unconscious place in recovery position and seek medical advice.

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P300022722GB-4
Following inhalation：
Remove casualty to fresh air and keep warm and at rest. No mouth-to-mouth or mouth-to-nose resuscitation. Use
Ambu bag or ventilator. If breathing is irregular or stopped, administer artificial respiration. After inhaling vapours,
first symptoms of poisoning may develop hours later, so always consult a doctor. In case of inhaling spray mist,
consult a doctor immediately and show him packing or label. In case of respiratory tract irritation, consult a physician.
Provide fresh air. In case of inhaling spray mist, consult a physician. Consult a doctor immediately in the case of
inhaling spray mist and show him packing or label.
Following skin contact
Wash immediately with : Water and soap
In the case of contact with hot melt, treat skin with :Water and soap
Do not wash with : Cleaning agent, acidic Cleaning agent, alkaline Solvents/Thinner
After eye contact：
In case of eye irritation consult an ophthalmologist. In case of contact with eyes flush immediately with plenty offlowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Rinse immediately andcautiously with water. Remove contact lenses if it is easy to do. Rinse with running water for 10 to 15 minutes. Rinse
immediately and cautiously with water. Remove contact lenses if it is easy to do. Rinse with running water for 10 to 15
minutes. Then get a medical attention of an ophthalmologist.
After ingestion :Do NOT induce vomiting. Give sodium sulfate as laxative (1 tablespoon in 1 glass of water) with plenty of activatedcoal. If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain
immediate medical attention. Induce vomiting when the affected person is not unconscious.
If swallowed immediately drink :Water, to which activated charcoal may be added
Self-protection of the first aider :No mouth-to-mouth or mouth-to-nose resuscitation. Use Ambu bag or ventilator. No direct artificial respiration to begiven by first aider. First aider: Pay attention to self-protection!

4.2. Most important symptoms and effects, both acute and delayed
Symptoms
The following symptoms may occur :Cerebral oedema Cough Allergic anaphylactic shock Allergic reactions Asthmatic complaints Dyspnoea
Respiratory complaints Vomiting Fever Pulmonary oedema Pulmonary irritation Pneumonia Nausea Dry skin,redness, pain Skin burns, blisters Redness, pain and burns in the eyes Blurred vision Allergic inflammation (rash)

Effects :Allergic anaphylactic shock Allergic reactions Asthmatic complaints Dyspnoea Respiratory complaints DrowsinessImpaired consciousness Pulmonary oedema Nausea Lung irritation Pneumonia Dry skin, redness, pain Skin burns,
blisters Redness, pain and burns in the eyes Blurred vision Allergic inflammation (rash)4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor :Recovery usually happens spontaneously. First Aid, decontamination, treatment of symptoms. First Aid. Where
appropriate artificial ventilation. After decontamination of the skin pain treatment and shock prophylaxis. Subsequent
observance for pneumonia and lung oedema. Treat symptomatically. Treat symptomatically. Antidotal dispensation.
Special treatment :In the case of bluish discoloration (lips, earlobes, finger nails) give oxygen as soon as possible. In the case of lung
irritation: Primary treatment using corticoide spray, eg. Auxiloson spray, Pulmicort-dosage-spray. (Auxiloson andPulmicort are registered trademarks). Treat skin and mucous membrane with antihistamines and corticosteroid
preparations.

SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media ：Use an appropriate extinguishing agent depending on a cause of the fire Nitrogen alcohol resistant foam BC-powder
ABC-powder Carbon dioxide (CO2) Dry sand Water mist
Unsuitable extinguishing media：
Full water jet Strong water jet Sand (wet) Water spray jet
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products :Carbon dioxide (CO2) Nitrogen oxides (NOx) Carbon monoxide. Pyrolysis products, toxic
5.3. Advice for firefighters

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2022/7/22
P300022722GB-4
Special protective equipment for firefighters:
Use suitable breathing apparatus. Protective clothing. Rubber boots rubber gloves. In case of fire: Wear selfcontained breathing apparatus. Protective gloves
5.4. Additional information:
Do not inhale explosion and combustion gases. Burning produces heavy smoke. Use water spray jet to protect
personnel and to cool endangered containers. Do not allow run-off from fire-fighting to enter drains or water courses.
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Remove
product from area of fire. Remove heat to avoid pressure rise. Stop and contain spill/release if it can be done safely. If
this cannot be done, allow fire to burn under control. Move undamaged containers from immediate hazard area if it canbe done safely. Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen.

SECTION 6: Accidental release measures
6.1. Personal precautions,protective equipment and emergency procedures
Personal precautions :Avoid generation of dust. Use personal protection equipment. Be aware that gases can spread at ground level(heavier than air) and pay attention to the wind direction. Beware of reignition.
Protective equipment :Wear breathing apparatus if exposed to vapours/dusts/aerosols. Use appropriate respiratory protection. Wearprotective gloves/protective clothing. Wear appropriate eye protection. Wear appropriate body protection.
Emergency procedures :Remove all sources of ignition. Provide adequate ventilation. Remove persons to safety.
6.2. Enviromental precautions :Cover drains. Suppress gases/vapours/mists with water spray jet. Do not allow to enter into soil/subsoil. Do notallow to enter into surface water or drains. Prevent spread over a wide area (e.g. by containment or oil barriers).
Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains,
inform the responsible authorities. Use foam on spills to minimise vapours. Use water spray jet to minimise ordisperse vapours. Ensure waste is collected and contained. Make sure spills can be contained, e.g. in sump pallets or
kerbed areas. Ensure all waste water is collected and treated via a waste water treatment plant.

6.3. Methods and materials for containment and cleaning up
For containment
Suitable material for taking up:
Sand Absorbing material, organic Kieselguhr Earth Sawdust Water (with cleaning agent)
For cleaning up
Suitable material for diluting or neutralising :No data available
6.4. Reference to other sections :Safe handling: see section 7 Disposal: see section 13 Personal protection equipment: see section 8

SECTION 7: Handling and storage
7.1. Precautions for safe handlingProtective measure
Advice on safe handling
Inhalation Inhalation of vapours or spray/mists Inhalation of dust/particles Skin contact Eye contact
Avoid : Generation/formation of mist Generation/formation of dust Dust deposits
Handle under (gas) : Nitrogen Carbon dioxide (CO2) Protective gas
Handle under (liquid) : No data available

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If local exhaust ventilation is not possible or not sufficient, the entire working area must be ventilated
by technical means. Handle and open container with care. Avoid exposure - obtain special instructions
before use. Working places should be designed to allow cleaning at any time. Do not breathe dust. Do
not breathe gas/fumes/vapour/spray. The danger areas must be delimited and identified using relevant
warning and safety signs. Use only in well-ventilated areas. Remove fume condensates periodicallyfrom extraction hoods, leads and other surfaces (wear personal protective clothing!) as there is a risk ofRemark : catching fire. Do not spray on naked flames or any incandescent material. Only use the material inplaces where open light, fire and other flammable sources can be kept away. Wear personal protection
equipment (refer to section 8). Always close containers tightly after the removal of product. Never usepressure to empty container. Restrict access while emptying or maintaining the unit. Put lids on
containers immediately after use.

Measures to prevent fire
Keep wet with : Not applicable
Do not mix with : No data available
Keep away from : Oxidising agent
Take precautionary measures against static discharges. Keep away from sources of ignition. - No
smoking. Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Provide earthingof containers, equipment, pumps and ventilation facilities. Use explosion-proof machinery, apparatus,
ventilation facilities, tools etc. Use only antistatically equipped (spark-free) tools. Wear anti-static
Remark : footwear and clothing Emergency cooling must be provided for in case of a fire in the vicinity. Vapours
can form explosive mixtures with air. Due to danger of explosion, prevent leakage of vapours intocellars, flues and ditches. When hot, product develops flammable vapours. When using do not smoke.

Measures to prevent aerosol and dust generation
During filling,metering and sampling should be used if possible :Splashproof grounded devices Devices with local exhaust
Use the following local exhaust ventilation type :Receptor hood for dust. Receptor hood for fumes/vapours Hand tool with integrated exhaust
Environmental precaution :No ground outlets on containers. See section 8. Shafts and sewers must be protected from entry of the
product.
Special requirements or handling rules :Floors, walls and other surfaces in the hazard area must be cleaned regularly. Carry out filling
operations only at stations with exhaust ventilation facilities. Observe and take care for properconditions of sealings and connection threads. Ensure that fresh air is supplied to the breathing zone ofthe operator and exhaust air is removed in his back! Re-circulation of exhaust air is not recommended.
Do not put any product-impregnated cleaning rags into your trouser pockets.
Advice on general occupational hygiene :Avoid contact with skin, eyes and clothes. When using do not eat, drink, smoke, sniff. Work in well-ventilated zones
or use proper respiratory protection. Wash contaminated clothing prior to re-use. Wash hands before breaks and afterwork. Thorough skin-cleansing after handling the product. Used working clothes should not be worn outside the workarea. Immediately remove any contaminated clothing, shoes or stockings. Street clothing should be stored separatelyfrom work clothing. Contaminated materials should be removed from the workplace at the end of each working day
and be stored outside.

7.2. Conditions for safe storage, including any incompatibilities
Packaging materials
Metal Material, solvent-resistant Polyolefine Polytetrafluoroethylene (PTFE)
Suitable container/equipment material :Polyethylene (PE)No data available
Unsuitable container/equipment material :Hints on joint storage
Storage class :Materials to avoid :Flammable liquids
Oxidising agent
Keep only in the original container in a cool, well-ventilated place. Keep locked up.
Further information on storage conditions : Protect containers against damage. Keep container tightly closed in a cool, well-ventilated
place. Store detached.

SECTION 8: Exposure controls/personal protection
8.1. Control parameters

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Occupational exposure limit values
Ingredient2022/7/22

P300022722GB-4

CAS NO. EC NoCountryppm

Lead chromate (as Cr)
TolueneXylene, or mixed isomers
Ethylbenzene
Propan-2-ol
Ethyl acetate
n-Propyl acetate
n-Butyl acetate
Butan-2-one
Formaldehyde
2-Methylpropan-1-ol
Titanium dioxide

7758-97-6
108-88-3
1330-20-7
100-41-4
67-63-0 200-661-7
141-78-6 205-500-4
109-60-4 203-686-1
123-86-4 204-658-1
78-93-350-00-0
78-83-1 201-148-0
13463-67-7 236-675-5

Biological limit values
IngredientLead chromate (as Cr)
Xylene, or mixed isomers

CAS NO. EC NoCountry
7758-97-6 231-846-0
GB1330-20-7 215-535-7
GB

GB
GB
GB
GB
GB
GB
GB
GB
GB
GB
GB
GB

50
50
100
400
200
200
150
200
2
50

TWA
mg/m3
0.01
191
220
441
999
730
849
724
600
2.5
154
4

ppm
100
100
125
500
400
250
200
300
2
75

STEL
mg/m3
384
441
552
1250
1460
1060
966
899
2.5
231

Unit
Limit value
Parameter
chromium (VI) compoundsµmol/mol creatinine 10
mmol/mol creatinine 650
methyl hippuric acid8.2. Exposure controls
Appropriate engineering controls
See section 7. No additional measures necessary. Personal protective equipment (protective glasses, protective
Initial Remarks :gloves, masks, etc.) should be inspected regularly and recorded in the record book. Regularly inspect eye washers,
exhaust equipment, etc. used in an emergency and record them in the record book. In order to keep the airconcentration below the recommended control concentration / allowable concentration, take measures such as sealing
the process, local exhaust ventilation, and other equipment.
Substance/mixture related mesures to privent exposure during identified users :Equipment such as a gas detector is required. Fresh air (open windows and doors) is necessary.
Technical mesures to provent exposure :Reduce exposure to fume by keeping operating temperatures as low as possible taking into account occupational
exposure limits and safe handling temperatures (see Section 7). Where practicable handle within an enclosed process.
Alternatively local exhaust Install an explosion-proof local exhaust system. Use explosion-proof
electrical/ventilating/lighting/equipment. Use a ventilation system under high temperature or when mist is generated.
Install an eyewash and safety shower in the workplace where this substance is stored or handled.

Personal protection equipment
Eye/face protection
Suitable eye protection : Eye glasses Eye glasses with side protection
Remark: No data available
Skin protection
Hand protection
Suitable gloves type : Protective gloves Gloves with long cuffs
PVC (Polyvinyl chloride) PE (polyethylene) NR (natural rubber, natural latex) CR (polychloroprene,
Suitable material : chloroprene rubber) NBR (Nitrile rubber) Butyl caoutchouc (butyl rubber) FKM (fluoro rubber) PVA(Polyvinyl alcohol)
Required properties : antistatic liquid-tight gas-tight dust-tight cut-resistant
The quality of the protective gloves resistant to chemicals must be chosen as a function of the specificworking place concentration and quantity of hazardous substances. For special purposes, it isRemark : recommended to check the resistance to chemicals of the protective gloves mentioned above together
with the supplier of these gloves.
Body protection
Protective gloves/protective clothing/eye protection/face protection. complete head, face and neck
Suitable protective clothing : protection. Protective sleeves Protective apron
Required properties : antistatic flame-resistant with conductible sole Type 3 Liquid-tight
Recommended material : No data available
Respiratory protection
Respiratory protection necessary at :exceeding exposure limit values insufficient ventilation insufficient exhaust prolonged exposure Handling larger
quantities aerosol or mist formation high concentrations dust formation
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According to experience this refers to the following tasks :Weighing and metering activities Sampling Filling and transfer charging of mixers Cleaning work emptying thedust collector
Suitable respiratory protection apparatus :ABEK-P1
Remarks :Observe the wear time limits as specified by the manufacturer. If technical exhaust or ventilation measures are notpossible or insufficient, respiratory protection must be worn. The filter class must be suitable for the maximum
contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If theconcentration is exceeded, self-contained breathing apparatus must be used. Check leak tightness/impermeability prior
to use. For the protection against direct skin contact, body protective clothing is essential (in addition to the usual
working clothes). Only wear fitting, comfortable and clean protective clothing.
Environmental exposure controls
Technical measures to prevent exposure
Use the following filter types for cleaning waste gases :No data available
Use the following recovery and/or abatement technique for cleaning waste gases :Gas scrubber Exhaust air scrubber Adsorption Condensation
Use the follwoing chemical treatment methods for waste water :Thermal treatment-Distillation/Rectification Precipitation Oil-water separation Adsorption

SECTION 9: Physical and chemical properties
Physical state
Color
Odour
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability
Upper/lower flammability or explosive
limits
Vapour pressure
Vapour density
Density
Solubility(ies)
Partition coefficient: n-octanol/water
Auto-ignition temperature
Decomposition temperature
Viscosity
Explosive properties
Oxidising properties

liquidopaquepungent
No data available
No data available
82.00℃～110.60℃
19.5℃
No data available
No data available
No data available
No data available
No data available
No data available
Insoluble
No data available
200℃
No data available
20.5000m㎡/s
No data available
No data available

SECTION 10: Stability and reactivity
10.1. Reactivity :No data available
10.2. Chemical stability :The product is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardius reactions
In case of melting :Not applicable
In case of vaporization :Hazard of catch fire Danger of explosion
In case of freezing :Deformation of the container due to volume change
10.4. Condition to avoid
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In dry state :Not applicable
In an isolated state :No data available
In fine dispersion/spraying/misting :Danger of explosion
In case of warming :No data available
In case of light influence :No data available
In case of impact or pressure influence :No data available
In case of air intake :No data available
In case of exceeding the storage time :No data available
In case of exceeding the storage temperature :Danger of bursting container.
10.5. Incompatible materials
Materials to avoid
Peroxide Oxidising agent, strong Oxidising agent
10.6. Hazardous decomposition products:
Does not decompose when used for intended uses.
10.7. Additional information
No data available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity oral
Formaldehyde(Acute Tox. 3)
Acute toxicity Dermal
Formaldehyde(Acute Tox. 3) /Xylene, or mixed isomers(Acute Tox. 4)
Acute toxicity inhalation
Formaldehyde(Acute Tox. 3) /Xylene, or mixed isomers(Acute Tox. 4) /Ethylbenzene(Acute Tox. 4)
Skin corrosion/irritation
Toluene(Skin Corr. 2) /Formaldehyde(Skin Corr. 1B) /2-Methylpropan-1-ol(Skin Corr. 2) /Xylene, or mixed isomers(Skin Corr. 2)
Serious eye damage/eye irritation
Propan-2-ol(Eye Irrit. 2) /Ethyl acetate(Eye Irrit. 2) /n-Propyl acetate(Eye Irrit. 2) /Butan-2-one(Eye Irrit. 2) /2-Methylpropan-1-ol(EyeDam.1)
Skin sensitization
Formaldehyde(Skin. Sens. 1)
Germ cell mutagenicity
Formaldehyde(Muta. 2) /White spirit, max 20% aromates(Muta. 1B)
Carcinogenicity
Formaldehyde(Carc. 1B) /Lead chromate (as Cr)(Carc. 1B) /lead sulphate(Carc. 1B) /Titanium dioxide(Carc. 2) /White spirit, max 20%
aromates(Carc. 1B)
Reproductive toxicityv
Toluene(Repr. 2) /Lead chromate (as Cr)(Repr. 1A) /lead sulphate(Repr. 1A)Specific target organ toxicity - Single exposure
Toluene(STOT SE3(Narc.-effects)) /Propan-2-ol(STOT SE3(Narc.-effects)) /Ethyl acetate(STOT SE3(Narc.-effects)) /n-Propyl
acetate(STOT SE3(Narc.-effects)) /n-Butyl acetate(STOT SE3(Narc.-effects)) /lead sulphate(STOT SE 1) /Butan-2-one(STOT SE3(Narc.effects)) /2-Methylpropan-1-ol(STOT SE3(Respir.-Irrit.)) /2-Methylpropan-1-ol(STOT SE3(Narc.-effects))
Specific target organ toxicity -Repeated exposure
Toluene(STOT RE 2) /Lead chromate (as Cr)(STOT RE 2) /lead sulphate(STOT RE 1) /Titanium dioxide(STOT RE 1) /White spirit, max
20% aromates(STOT RE 1) /Ethylbenzene(STOT RE 2)
Aspiration hazard
Toluene(Asp. Tox. 1) /White spirit, max 20% aromates(Asp. Tox. 1) /Ethylbenzene(Asp. Tox. 1)
11.2. Symptoms related to the physical, chemical and toxicological characteristics
In case of ingestion :No data available
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In case of skin contact :Has degreasing effect on the skin.
In case of inhalation :When inhaled, the lungs and trachea are affected.

P300022722GB-4

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11.3. Additional information :Use suitable breathing apparatus. Protective clothing. Rubber boots rubber gloves. In case of fire: Wear selfcontained breathing apparatus.

SECTION 12: Ecological information
12.1. Toxicity：
Méthodes de traitement des déchets
108-88-3、Toluene：
Algae：Chlorella vulgaris EC50( mg/L ) 245(24-h)
Scenedesmus subspicatus EC50( mg/L ) 160(48h), Selenastrum capricornutum EC50( mg/L )> 433(96-h):
Crustacean：Daphnia magna EC50( mg/L ) 19.6(48-h):Swimming inhibition
Fish：Brachydanio rerio LC50( mg/L ) 25(48-h)Cyprinodon
variegatus LC50( mg/L ) 13(96-h)Gambusia affinis LC50( mg/L ) 1,180(96-h),Lepomis macrochirus LC50( mg/L )24(96-h)Poecilia reticulata LC50( mg/L ) 59
.3(96-h)Others:Photobacterium phosphoreum EC50( mg/L) 19.7(30-min)
50-00-0、Formaldehyde：
Algae:Scnedesmus. sp. EC50( mg/L ) 0.3(－)
Crustacean：Cypridopsis sp. shrimp LC50( mg/L ) 1.05(96-h),Daphnia magna LC50( mg/L ) 2.0(48-h)
Fish：Oncorhynchus mykiss LC50( mg/L ) 73.5(96-h), Lepomis macrochirus LC50( mg/L ) 100(96-h), Mornesaxatilis (Striped bass) LC50( mg/L ) 6.7(96-h) O
hters：Chilomonas paramecium LC50( mg/L ) 4.5(48-h) Corbicula sp LC50( mg/L ) 126(96-h),Notonecta sp. LC50(
mg/L ) 835(96-h), E.coli LC50( mg/L ) about 1(－)
100-41-4、Ethylbenzene：
Algae： Selenastrum capricornutum EC50(mg/L ) 4.6(72-h): Proliferation inhibition, Selenastrum： Daphnia magna
EC50(mg /L) 2.1(48-h) Swimming inhibition, Artemia salina EC50(mg /L ) 9.2(48-h), Fish： Morone saxatillised bass
LC50(mg /L ) 4.0(96-h, ), Oncorhynchus Mykiss LC50(mg / L) 4.2(96-h)

67-63-0、Isopropyl alcohol：
Algae：Scenedesmus Subspicatus EC50( mg/L ) >1,000(72-h) : Proliferation inhibition, Selenastru： Daphnia magna
EC50( mg/L ) 9,714(24-h) : swimming inhibition, Crangon crangon LC50( mg/L ) 903(96-h), Fish：Rasbora
Heteomorpha LC50( mg/L ) 4,200(96-h), Pimephales promelas LC50( mg/L ) 6,120(96-h)
108-78-1、Melamine：
Algae: Scenedesmus pannonicus EC50(mg/L) 940(96-h) : Proliferation inhibition, Selenastru: Daphnia magna
EC50(mg/L) >2,000(48-h) : swimming inhibition, Fish: Poecilia reticulata LC50(mg/L) >3,000(96-h)12.2. Persistence
Méthodes deandtraitement
degradability
des déchets:
108-88-3、Toluene：
Aerobic: good. test period 2 weeks, 100mg/L, decomposition rate by BOD 112～129 %, Anaerobic:no report
Abiotic: Reactivity with OH radical:
in troposphere air reaction rate constant 6.1*10E-12 cm3/mol.sec half time under OH radical concentration 5.0*10E5～
1*10E6mol./cm3 is calculated 1～3 days
50-00-0、Formaldehyde：
Aerobic: good. decomposition rate by BOD 91 %,,Anaerobic: no report
Abiotic: Reactivity with OH radical: in clear air half time is reported 19 hours, in durty air, half time is reported 19/2
hours. reactivity by direct photodecomposition: half time is reported 6.0 hours
100-41-4、Ethylbenzene：
Aerobic: good, decomposition rate by BOD 81～126 %,Aerobic: by aerobic reactor, not decomposed afte 110 days reported. under condition of aerobic aquifer environment,
survival rate after 120 weeks is less than 1 %, Ethylbenzene is supposed to be aerobic decomposed completely.

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P300022722GB-4
Abiotic: reactivity with OH radical; in ratetroposphere air, half time is reported, 5.5 hours in summer time, 24 hours
in winter time. as reaction products, Eethylphenol, Benzaldehyde, Acetophenone and m -,p- Ethylnitrobenzene arereported. Photodecomposition in water; photodecomposed under Acetophenone by sensitizer, 1-Phenylethanol, 1Phenylethanone and Benzaldehyde are reported to be produced.
67-63-0、Isopropyl alcohol：
Aerobic: good, decomposition rate by BOD 86 %,Anaerobic: no report.
Abiotic: Reactivity with OH radical; in ratetroposphere air, reaction rate, 6.2*10E-12 cm3/mol.sec(room temp.), OH
radical conc. 5.0*10E5～1*10E6 mol/cm3, half time is calculated 1.1-～2.3 days.
Reactivity with NO3 radical; reaction rate 2.3*10E-15 m3/mol.sec.(25 deg.C), in ratetroposphere air, NO3 radical
conc. 2.4*10E8 mol./cm3 in night, half time is reported 145 days.
108-78-1、Melamine：
Aerobic: difficult, Decomposition rate by BOD 0 %.
Anaerobic: no report.
Abiotic: no report

12.3. Bioaccumulative
Méthodes de traitement
potentialdes: déchets
108-88-3、Toluene： No report
50-00-0、Formaldehyde： No report100-41-4、Ethylbenzene： Logistic number of concentration factor: 1.9(golden fish), 0.67(clam)
67-63-0、Isopropyl alcohol： No
report108-78-1、Melamine： Low concentration,
test period 6 weeks, No.1section:test conc 2 mg/L, concentration factor < 0.38 No.2 section: conc. 0.2 mg/L,
concentration factor < 3.8
12.4. Mobility
Méthodesin desoiltraitement:
des déchets
108-88-3、Toluene： None50-00-0、Formaldehyde： None
100-41-4、Ethylbenzene： None
67-63-0、Isopropyl alcohol： None
108-78-1、Melamine： None
12.5. Hazardous
Méthodes deto thetraitementozone layer
des déchets:
108-88-3、Toluene： Not applicable
50-00-0、Formaldehyde： Not applicable
100-41-4、Ethylbenzene： Not applicable
67-63-0、Isopropyl alcohol： Not applicable108-78-1、Melamine： Not applicable
12.6. Other
Méthodesadversede traitement
effects : des déchets
Observe local regulations concerning effluent treatment. If product enters soil, it will be mobile and may contaminate
groundwater. Discharge into the environment must be avoided. The ecotoxicological properties of this mixture aredetermined by the ecotoxicological properties of the single components (see section 3).

SECTION 13: Disposal considerations
13.1. Waste treatment methods
Product/packaging disposal
Properties of waste which render it hazardous :Mutagenic Toxic for reproduction carcinogenic Toxic Harmful Irritant Highly flammable Sensitising
Waste treatment option
Appropriate disposal/Product :Dispose of waste according to applicable legislation.
Appropriate disposal/Package :Completely emptied packages can be recycled. Return IBCs to supplier. Non-contaminated packages may berecycled. Handle contaminated packages in the same way as the substance itself.
Remarks :Waste for disposal is to be classified and labelled. Consult supplier about waste disposal. Consult the appropriate
authorities about waste disposal. Do not mix with other wastes. Delivery to an approved waste disposal company.
Dispose according to legislation.

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SECTION 14: Transport information
14.1 UN number
Land transport(ADR/RID)
1263
Inland waterway transport(ADN)1263
Sea transportation(IMDG)
1263
Air transportationICAO-TI/IATA-DGR
1263
14.2. UN proper shipping name
Paint or Paint related material
Land transport(ADR/RID)
Paint or Paint related material
Inland waterway transport(ADN)
Paint or Paint related material
Sea transportation(IMDG)
Paint or Paint related material
Air transportationICAO-TI/IATA-DGR
14.3. Transport hazard class(es)Land transport(ADR/RID)
3
Inland waterway transport(ADN)3
Sea transportation(IMDG)
3
Air transportationICAO-TI/IATA-DGR
3
14.4. Packing group
Land transport(ADR/RID)II
Inland waterway transport(ADN)II
Sea transportation(IMDG)II
Air transportationICAO-TI/IATA-DGR
II
14.5. Environmental hazards
Land transport(ADR/RID)
Not applicable
Inland waterway transport(ADN)
Not applicable
Sea transportation(IMDG)
Not applicable
Air transportationICAO-TI/IATA-DGR
Not applicable
Transport in bulk according to MARPOL73/78
14.6.
Not applicableand the IBC CodeNot applicable
14.7. Marine pollutant ：SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulation
Authrisations and/or restrictions on use
Lead chromate,CAS 7758-97-6;
Authorisations :by REACH TITLE VII
Ethylbenzene,;
Toluene,;n-Propyl acetate,;
n-Butyl acetate,;
Xylene, or mixed isomers,;
Ethyl acetate,;
Formaldehyde,;n-Amyl acetate,;
Restrictions on use : Propan-2-ol,;
Lead sulphate PbSO4,;
Lead chromate,;
2-Methylpropan-1-ol,;
Butan-2-one,;White spirit, max 20% aromates,;by REACH TITLE VIII

Restriction of occupation :Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant
or nursing mothers.

Other regulations (EU)
Directive 2004/42/CE on the limitation of emissions of volatile organic compounds
VOC product category : Paints and varnishes
VOC subcategory of the product : Special finishes
VOC content(g/L), ready to use condition :VOC content(g/L), delivery state :VOC-value(in g/L) :Method : No data available
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Remak : This chemical is a VOC according to 2004/42/EC.

2022/7/22

Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances [Seveso-III-Directive]

P5b orP5c FLAMMABLE LIQUIDSClassification according to Annex I, Part I : E2 Hazardous to the Aquatic Environment
Entry in Annex I, Part 2
Number :CAS No 50-00-0;

Named dangerous substances : Formaldehyde (concentration ≥ 90 %)Remark : No data available
Lead chromate,CAS No 7758-97-6；
Candidate of SVHC
15.2. Chemical Safety Assessment :Chemical safety assessments were performed on some of the substances contained in this mixture.

SECTION 16: Other information
Relevant H-phrases in Section 3 and EUH-phrases in Section 2 (Number and full text) :EUH201 Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
EUH208 Contains sensitising substance May produce an allergic reaction.
EUH210 Safety data sheet available on request.
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H301 Toxic if swallowed
H302 Harmful if swallowed
H304 May be fatal if swallowed and enters airways
H311 Toxic in contact with skin
H312 Harmful in contact with skinH314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H331 Toxic if inhaled
H332 Harmful if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H341 Suspected of causing genetic defects
H350 May cause cancer
H351 Suspected of causing cancer
H360Df May damage the unborn child. Suspected of damaging fertility.
H361d Suspected of damaging the unborn child.
H362 May cause harm to breast-fed children
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
Data sources:
The descriptions in this Safety Data Sheet are based on the materials, information, and data available at this moment, but may be revised due
to revisions to laws and regulations or new findings. When handling this product, please refer to the descriptions and take safety measures inline with the actual situation at your own risk. This Safety Data Sheet is not a guarantee of safety or quality.

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