PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 03/29/2019

Revision date: 09/01/2019

Version: 2.0

SECTION 1: Identification
1.1.

Identification

Product form

: Mixture

Product name: PennGrade1 Classic Gear Oil GL-4 SAE 80W-90

1.2.

Recommended use and restrictions on use

Use of the substance/mixture: Lubricant

Restrictions on use: No additional information available

1.3.

Supplier

D-A Lubricant Company, Inc.
801 Edwards Dr
Lebanon, IN 46052
T 317-923-5321, Toll Free 1-800-873-2582
www.dalube.com
1.4.

Emergency telephone number

Emergency number: 1-800-899-9004 Toll-Free USA/CAN 24 hours

SECTION 2: Hazard(s) identification
2.1.

Classification of the substance or mixture

GHS classification
Not classified
2.2.

GHS Label elements, including precautionary statements

GHS labelling
No labelling applicable
2.3.

Other hazards which do not result in classification

No additional information available
2.4.

Unknown acute toxicity (GHS_US)

Not applicable

SECTION 3: Composition/information on ingredients
3.1.

SubstancesNot applicable
3.2.

Mixtures

NameProduct identifier%

GHS classification

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO< 3%)(CAS-No.) 64742-54-7

40 - 50

Asp. Tox. 1, H304

Long-chain alkyl amine(CAS-No.) trade secret0.1 - 0.5

Acute Tox. 4 (Oral), H302
Acute Tox. 3 (Dermal), H311
Acute Tox. 2 (Inhalation), H330
Skin Corr. 1B, H314
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410

*Chemical name, CAS number and/or exact concentration have been withheld as a trade secret

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures
4.1.

Description of first aid measures

First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).

First-aid measures after inhalation: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable forbreathing. Give oxygen or artificial respiration if necessary.

First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse. Wash skin thoroughly with mild soap and water.

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PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsFirst-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persists.

First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2.

Most important symptoms and effects (acute and delayed)

Symptoms/effects after inhalation
4.3.

: Inhalation of vapours may cause respiratory irritation.

Immediate medical attention and special treatment, if necessary

Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media: Do not use a heavy water stream.

5.2.

Specific hazards arising from the chemical

Fire hazard: Burning produces irritating, toxic and noxious fumes.

Reactivity: No dangerous reactions known.

5.3.

Special protective equipment and precautions for fire-fighters

Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.

Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Wear fire/flame resistant/retardant clothing. Wear recommended personal protectiveequipment.

SECTION 6: Accidental release measures
6.1.

Personal precautions, protective equipment and emergency procedures

General measures

6.1.1.

: Avoid all eye and skin contact and do not breathe vapour and mist. Use personal protective
equipment as required.

For non-emergency personnel

Protective equipment: Refer to section 8.2.

Emergency procedures: Evacuate unnecessary personnel.

6.1.2.

For emergency responders

Protective equipment: Refer to section 8.2.

Emergency procedures: Ventilate area.

6.2.

Environmental precautions

Prevent entry to sewers and public waters.
6.3.

Methods and material for containment and cleaning up

For containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers orstreams.

Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Onland, sweep or shovel into suitable containers. Collect spillage. Minimise generation of dust.
Store away from other materials.

6.4.

Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage
7.1.

Precautions for safe handling

Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formationof vapour.

Hygiene measures: Contaminated work clothing should not be allowed out of the workplace. Wash contaminatedclothing before reuse.

7.2.

Conditions for safe storage, including any incompatibilities

Storage conditions: Keep only in the original container in a cool well ventilated place.

Incompatible products: Strong bases. Strong acids. Strong oxidizers.

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PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Incompatible materials: Sources of ignition. Direct sunlight.

SECTION 8: Exposure controls/personal protection
8.1.

Control parameters

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
ACGIH
ACGIH TWA (mg/m³)

5 mg/m³

ACGIH

ACGIH STEL (mg/m³)

10 mg/m³

OSHA

OSHA PEL (TWA) (mg/m³)

5 mg/m³

Long-chain alkyl amine (trade secret)Not applicable

8.2.

Appropriate engineering controls

Appropriate engineering controls

8.3.

: Avoid creating mist or spray. Avoid splashing. Emergency eye wash fountains and safety
showers should be available in the immediate vicinity of any potential exposure. Provide local
exhaust or general room ventilation.

Individual protection measures/Personal protective equipment

Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear suitable gloves resistant to chemical penetration. nitrile rubber gloves. natural rubber gloves
Eye protection:
Chemical goggles or safety glasses
Respiratory protection:
In case of inadequate ventilation wear respiratory protection. Use an approved respirator equipped with oil/mist cartridges.
Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties
9.1.

Information on basic physical and chemical properties

Physical state: LiquidColour: GreenOdour: petroleum

Odour threshold: No data available

pH: No data available

Melting point: No data available

Freezing point: No data available

Boiling point: No data available

Flash point: > 222 °C

Relative evaporation rate (butylacetate=1): No data availableFlammability (solid, gas)

: Non flammable.

Vapour pressure: No data available

Relative vapour density at 20 °C: No data available

Relative density: No data available

Solubility: No data available

Log Pow: No data available

Auto-ignition temperature: No data available

Decomposition temperature: No data available

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PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Viscosity, kinematic: 140 mm²/s @ 40°C

Viscosity, dynamic: No data available

Explosive limits: No data available

Explosive properties: No data available

Oxidising properties: No data available

9.2.

Other information

No additional information available

SECTION 10: Stability and reactivity
10.1.

Reactivity

No dangerous reactions known.
10.2.

Chemical stability

Stable under normal conditions.
10.3.

Possibility of hazardous reactions

Hazardous polymerization will not occur.
10.4.

Conditions to avoid

Direct sunlight. Extremely high or low temperatures.
10.5.

Incompatible materials

Strong acids. Strong bases. Strong oxidizers.
10.6.

Hazardous decomposition products

Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information
11.1.

Information on toxicological effects

Acute toxicity (oral): Not classified

Acute toxicity (dermal): Not classified

Acute toxicity (inhalation): Not classified

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
LD50 oral rat> 5000 mg/kg
LD50 dermal rabbit> 2000 mg/kg
LC50 inhalation rat (mg/l)> 5.53 mg/l/4h
Long-chain alkyl amine (trade secret)
LD50 oral rat
LD50 dermal rat
LC50 inhalation rat (ppm)
ATE (oral)
ATE (dermal)
ATE (gases)
ATE (vapours)
ATE (dust,mist)

612 mg/kg
251 mg/kg
157 ppm/4h
612 mg/kg bodyweight
251 mg/kg bodyweight
157 ppmv/4h
0.5 mg/l/4h
0.05 mg/l/4h

Skin corrosion/irritation: Not classified

Serious eye damage/irritation: Not classified

Respiratory or skin sensitisation: Not classified. (Long-chain alkyl amine not sensitziing <1.5%)

Germ cell mutagenicity: Not classified

Carcinogenicity: Not classified

Reproductive toxicity: Not classified

STOT-single exposure: Not classifiedSTOT-repeated exposure: Not classified

Aspiration hazard: Not classified

Viscosity, kinematic: 140 mm²/s @ 40°C

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PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Likely routes of exposure: Inhalation. Skin and eye contact.

Symptoms/effects after inhalation: Inhalation of vapours may cause respiratory irritation.

SECTION 12: Ecological information
12.1.

Toxicity

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
EC50 crustacea> 10000 mg/l
12.2.

Persistence and degradability

PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Persistence and degradability
Not established.
12.3.

Bioaccumulative potential

PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Bioaccumulative potential
Not established.
12.4.

Mobility in soil

No additional information available
12.5.

Other adverse effects

Other information: Avoid release to the environment.

SECTION 13: Disposal considerations
13.1.

Disposal methods

Sewage disposal recommendations: Do not dispose of waste into sewer.

Waste disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials: Avoid release to the environment.

SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Not regulated.
Transport by sea
Not regulated.
Air transport
Not regulated.

SECTION 15: Regulatory information
15.1. US Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
15.2. International regulationsCANADADistillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
Listed on the Canadian DSL (Domestic Substances List) inventory.
Long-chain alkyl amine (trade secret)
Listed on the Canadian DSL (Domestic Substances List) inventory.
EU-Regulations
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PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Long-chain alkyl amine (trade secret)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
National regulations
Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on KECI (Korean Existing Chemicals Inventory)
Listed on the TCSI (Taiwan Chemical Substance Inventory)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on NZIoC (New Zealand Inventory of Chemicals)Long-chain alkyl amine (trade secret)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on KECI (Korean Existing Chemicals Inventory)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on Taiwan National Chemical Inventory
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
15.3. US State regulations
WARNING:

This product can expose you to Ethylene oxide, which is known to the State of California to cause cancer and birth defects
or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

Component

Carcinogenicity

Developmental
toxicity

Reproductive
toxicity male

Reproductive
toxicity
femaleNo significant
risk level (NSRL)

Naphthalene(91-20-3)X

Ethylene oxide(75-218)

X

Propylene oxide(7556-9)

X

1,4-dioxane(123-91-1)

X

30 µg/day

Ethyl acrylate(140-885)

Xnot determined

Maximumallowable
dose level(MADL)

5.8 µg/day
XXX

2 µg/day20 µg/day

SECTION 16: Other informationaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Revision date

: 09/01/2019

Data sources: European Chemicals Agency (ECHA) C&L Inventory database. Accessed at
http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database. Krister
Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing", Fifth
Edition. National Fire Protection Association. Fire Protection Guide to Hazardous Materials;
10th edition. OSHA 29CFR 1910.1200 Hazard Communication Standard. TSCA Chemical
Substance Inventory. Accessed at
http://www.epa.gov/oppt/existingchemicals/pubs/tscainventory/howto.html.

Other information: None.

Full text of H-statements:
H302

Harmful if swallowed.

H304

May be fatal if swallowed and enters airways.

H311

Toxic in contact with skin.

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PennGrade1 Classic Gear Oil GL-4 SAE 80W-90
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H330

Fatal if inhaled.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Abbreviations and acronyms:
ATE: Acute Toxicity Estimate
CAS (Chemical Abstracts Service) number
EC50: Environmental Concentration associated with a response by 50% of the test population.
GHS: Globally Harmonized System (of Classification and Labeling of Chemicals).
LD50: Lethal Dose for 50% of the test population
STEL: Short Term Exposure Limits
TSCA: Toxic Substances Control Act
TWA: Time Weighted Average
WEL: Workplace Exposure Limit
NFPA health hazard: 1 - Materials that, under emergency conditions, can causesignificant irritation.

NFPA fire hazard: 1 - Materials that must be preheated before ignition canoccur.

NFPA reactivity: 0 - Normally stable, even under fire exposure conditions,and not reactive with water.

Indication of changes:
Composition/information on ingredients. Classification.
SDS prepared by The Redstone Group6077 Frantz Rd.
Suite 206
Dublin, OH USA 43017+1.614.923.7472
www.redstonegrp.com
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

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