PennGrade 1® High Performance SAE 30,
PennGrade 1® High Performance SAE 40,
PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60,
PennGrade 1® High Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date ofissue: 07/09/2019

Version: 1.1

Revision Date: 07/30/2019

SECTION 1: Identification
1.1.

Identification

Product form

: Mixture

Product name: PennGrade 1® High Performance SAE 30, PennGrade 1® High Performance SAE 40, PennGrade 1®
High Performance SAE 50, PennGrade 1® High Performance SAE 60,
PennGrade 1® High Performance Nitro 70

1.2.

Recommended use and restrictions on use

Use of the substance/mixture: Lubricant

Restrictions on use: No additional information available

1.3.

Supplier

D-A Lubricant Company, Inc.
801 Edwards Dr
Lebanon, IN 46052
T 317-923-5321, Toll Free 1-800-873-2582
www.dalube.com
1.4.

Emergency telephone number

Emergency number: 1-800-899-9004 Toll-Free USA/CAN 24 hours

SECTION 2: Hazard(s) identification
2.1.

Classification of the substance or mixture

GHS-US classification
Repr. 2

H361

Suspected of damaging fertility or the unborn child.

Full text of hazard classes and H-statements : see section 16
2.2.

GHS Label elements, including precautionary statements

GHS US labelling
Hazard pictograms (GHS US):

Signal word (GHS US): Warning

Hazard statements (GHS US): H361 - Suspected of damaging fertility or the unborn child.

Precautionary statements (GHS US): P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 - If exposed or concerned: Get medical advice/attention.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation

2.3.

Other hazards which do not result in classification

No additional information available
2.4.

Unknown acute toxicity (GHS US)

4.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)
4.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)
4.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist))

07/30/2019

EN (English)

Page 1

PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 3: Composition/information on ingredients
3.1.

Substances

Not applicable
3.2.

Mixtures

Name

Product identifier%

GHS-US classification

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO< 3%)(CAS-No.) 64742-54-7

10 - 60

Asp. Tox. 1, H304

Zinc alkyl dithiophosphate(CAS-No.) 113706-15-3

1-2

Skin Irrit. 2, H315
Eye Dam. 1, H318

tetrapropenylphenol(CAS-No.) 74499-35-7

0.01 - 0.2

Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Repr. 2, H361
Aquatic Acute 1, H400
Aquatic Chronic 1, H410

*Chemical name, CAS number and/or exact concentration have been withheld as a trade secret

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures
4.1.

Description of first aid measures

First-aid measures general: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).

First-aid measures after inhalation: If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing.

First-aid measures after skin contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse. Take off contaminated clothing and wash it before reuse.

First-aid measures after eye contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persists.

First-aid measures after ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2.

Most important symptoms and effects (acute and delayed)

Symptoms/effects: Suspected of damaging fertility or the unborn child.

Symptoms/effects after skin contact: Prolonged or repeated contact may cause skin to become dry or cracked.

4.3.

Immediate medical attention and special treatment, if necessary

Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media: Do not use a heavy water stream.

5.2.

Specific hazards arising from the chemical

Fire hazard: Burning produces irritating, toxic and noxious fumes.

Reactivity: No dangerous reactions known.

5.3.

Special protective equipment and precautions for fire-fighters

Firefighting instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.

Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Wear a self contained breathing apparatus. Wear fire/flame resistant/retardant clothing.

SECTION 6: Accidental release measures
6.1.

Personal precautions, protective equipment and emergency procedures

General measures

07/30/2019: Avoid all eye and skin contact and do not breathe vapour and mist.

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PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.1.1.

For non-emergency personnel

Protective equipment: Refer to section 8.2.

Emergency procedures: Evacuate unnecessary personnel.

6.1.2.

For emergency responders

Protective equipment: Refer to section 8.2.

Emergency procedures: Ventilate area.

6.2.

Environmental precautions

Prevent entry to sewers and public waters.
6.3.

Methods and material for containment and cleaning up

For containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or
streams.

Methods for cleaning up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On
land, sweep or shovel into suitable containers. Collect spillage. Minimise generation of dust.
Store away from other materials.

6.4.

Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage
7.1.

Precautions for safe handling

Precautions for safe handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formationof vapour.

Hygiene measures: Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or
smoke when using this product.

7.2.

Conditions for safe storage, including any incompatibilities

Storage conditions: Keep only in the original container in a cool well ventilated place.

Incompatible products: Strong bases. Strong acids. Strong oxidizers.

Incompatible materials: Sources of ignition. Direct sunlight.

SECTION 8: Exposure controls/personal protection
8.1.

Control parameters

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
ACGIH
ACGIH TWA (mg/m³)

5 mg/m³

ACGIH

ACGIH STEL (mg/m³)

10 mg/m³

OSHA

OSHA PEL (TWA) (mg/m³)

5 mg/m³

Zinc alkyl dithiophosphate (113706-15-3)
Not applicable
tetrapropenylphenol (74499-35-7)
Not applicable

8.2.

Appropriate engineering controls

Appropriate engineering controls: Avoid creating mist or spray. Avoid splashing. Emergency eye wash fountains should beavailable in the immediate vicinity of any potential exposure. Either local exhaust or generalroom ventilation is usually required. Industrial and professional. Perform risk assessment prior
to use.

Environmental exposure controls: Avoid release to the environment. Prevent leakage or spillage. Prevent contaminated waterrun-off.

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PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

8.3.

Individual protection measures/Personal protective equipment

Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear suitable gloves resistant to chemical penetration. Natural rubber. nitrile rubber gloves
Eye protection:
In case of splashing or aerosol production: protective goggles.
Respiratory protection:
Industrial and professional. Perform risk assessment prior to use. In case of inadequate ventilation wear respiratory protection. Approved organic
vapour respirator
Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties
9.1.

Information on basic physical and chemical properties

Physical state: Liquid

Colour: GreenOdour: No data available

Odour threshold: No data available

pH: No data available

Melting point: No data available

Freezing point: No data available

Boiling point: No data available

Flash point: > 185 °C ASTM D92

Relative evaporation rate (butylacetate=1): No data available

Flammability (solid, gas)

: Non flammable.

Vapour pressure: No data available

Relative vapour density at 20 °C: No data available

Relative density: No data available

Solubility: No data available

Log Pow: No data available

Auto-ignition temperature: No data available

Decomposition temperature: No data available

Viscosity, kinematic: 97 - 315 mm²/s @ 40 °C

Viscosity, dynamic: No data available

Explosive limits: No data available

Explosive properties: No data available

Oxidising properties: No data available

9.2.

Other information

No additional information available

SECTION 10: Stability and reactivity
10.1.

Reactivity

No dangerous reactions known.

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PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

10.2.

Chemical stability

Stable under normal conditions.
10.3.

Possibility of hazardous reactions

Hazardous polymerization will not occur.
10.4.

Conditions to avoid

Direct sunlight. Extremely high or low temperatures.
10.5.

Incompatible materials

Strong acids. Strong bases. Strong oxidizers.
10.6.

Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information
11.1.

Information on toxicological effects

Acute toxicity (oral): Not classified

Acute toxicity (dermal): Not classified

Acute toxicity (inhalation): Not classified

Unknown acute toxicity (GHS US)

4.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)
4.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)
4.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation(Dust/Mist))

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
LD50 oral rat> 5000 mg/kg
LD50 dermal rabbit> 2000 mg/kg
LC50 inhalation rat (mg/l)> 5.53 mg/l/4h
Zinc alkyl dithiophosphate (113706-15-3)
LD50 oral rat
LD50 dermal rabbit
ATE US (oral)

2600 mg/kg> 3160 mg/kg
2600 mg/kg bodyweight

Skin corrosion/irritation: Not classified

Serious eye damage/irritation: Not classified. (Zinc alkyl dithiophosphate not irritating <10%.)

Respiratory or skin sensitisation: Not classified

Germ cell mutagenicity: Not classified

Carcinogenicity: Not classified

Reproductive toxicity: Suspected of damaging fertility or the unborn child.

STOT-single exposure: Not classified

STOT-repeated exposure: Not classified

Aspiration hazard: Not classified

Viscosity, kinematic: 97 - 315 mm²/s @ 40 °C

Likely routes of exposure: Skin and eye contact. Inhalation.

Symptoms/effects: Suspected of damaging fertility or the unborn child.

Symptoms/effects after skin contact: Prolonged or repeated contact may cause skin to become dry or cracked.

SECTION 12: Ecological information
12.1.
07/30/2019

Toxicity
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PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
EC50 Daphnia 1> 10000 mg/l
Zinc alkyl dithiophosphate (113706-15-3)
LC50 fish 1

4.5 mg/l 96 h Rainbow trout

tetrapropenylphenol (74499-35-7)
NOEC (chronic)

0.002 mg/l

12.2.

Persistence and degradability

PennGrade 1® High Performance SAE 30, PennGrade 1® High Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High Performance Nitro 70
Persistence and degradability
Not established.
Zinc alkyl dithiophosphate (113706-15-3)
Persistence and degradability

Not readily biodegradable.

tetrapropenylphenol (74499-35-7)
Persistence and degradability

Product persists.

12.3.

Bioaccumulative potential

PennGrade 1® High Performance SAE 30, PennGrade 1® High Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High Performance Nitro 70
Bioaccumulative potential
Not established.
Zinc alkyl dithiophosphate (113706-15-3)
Log Pow

0.9

tetrapropenylphenol (74499-35-7)
Log Pow

7.17

12.4.

Mobility in soil

Zinc alkyl dithiophosphate (113706-15-3)
Ecology - soil
12.5.

Absorbs to soil particles and will not be mobile.

Other adverse effects

Other information: Avoid release to the environment.

SECTION 13: Disposal considerations
13.1.

Disposal methods

Sewage disposal recommendations: Do not dispose of waste into sewer.

Waste disposal recommendations: Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials: Avoid release to the environment. Hazardous waste due to toxicity.

SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Not regulated.
Transport by sea
Not regulated.
Air transport
Not regulated.
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PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 15: Regulatory information
15.1. US Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory

Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of
1986 and 40 CFR Part 372.

Zinc alkyl dithiophosphate (113706-15-3)
EPA TSCA Regulatory Flag

P - P - indicates a commenced Premanufacture Notice (PMN) substance.

15.2. International regulations
CANADA
Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
Listed on the Canadian DSL (Domestic Substances List) inventory.
Zinc alkyl dithiophosphate (113706-15-3)
Listed on the Canadian DSL (Domestic Substances List) inventory.
tetrapropenylphenol (74499-35-7)
Listed on the Canadian NDSL (Non-Domestic Substances List)
EU-Regulations
Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Zinc alkyl dithiophosphate (113706-15-3)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
tetrapropenylphenol (74499-35-7)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
National regulations
Distillates (petroleum), hydrotreated heavy paraffinic (DMSO < 3%) (64742-54-7)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on KECI (Korean Existing Chemicals Inventory)
Listed on the TCSI (Taiwan Chemical Substance Inventory)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on NZIoC (New Zealand Inventory of Chemicals)
tetrapropenylphenol (74499-35-7)
Not listed on the AICS (Australian Inventory of Chemical Substances)
Listed on Taiwan National Chemical Inventory
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on KECI (Korean Existing Chemicals Inventory)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Not listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
15.3. US State regulations
WARNING:

07/30/2019

This product can expose you to Benzene, which is known to the State of California to cause cancer and birth defects orother reproductive harm. For more information go to www.P65Warnings.ca.gov.

EN (English)

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PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Component

Carcinogenicity

Developmental
toxicity

Reproductive
toxicity male

Benzene(71-43-2)

X

X

X

Toluene(108-88-3)Xethylene glycol(10721-1)

X

lead/leadcompounds()

X

Naphthalene(91-20-3)

X

X

X

Reproductive
toxicity
femaleNo significant
risk level (NSRL)

6.4 µg/day (oral);
13 µg/day(inhalation)X

15 µg/day

Maximumallowable
dose level(MADL)
24 µg/day(oral); 49µg/day(inhalation)
7000 µg/day(oral); 13000µg/day(inhalation)
8700 µg/day(oral)
0.5 µg/day

5.8 µg/day

SECTION 16: Other informationaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Data sources: ACGIH (American Conference of Government Industrial Hygienists). European Chemicals
Agency (ECHA) C&L Inventory database. Accessed at
http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database. Krister
Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing", Fifth
Edition. National Fire Protection Association. Fire Protection Guide to Hazardous Materials;
10th edition. OSHA 29CFR 1910.1200 Hazard Communication Standard. TSCA Chemical
Substance Inventory. Accessed at
http://www.epa.gov/oppt/existingchemicals/pubs/tscainventory/howto.html.

Other information: Revised Product Names with Copyright symbols.

Full text of H-statements:
Aquatic Acute 1

Hazardous to the aquatic environment — Acute Hazard, Category 1

Aquatic Chronic 1

Hazardous to the aquatic environment — Chronic Hazard, Category 1

Asp. Tox. 1

Aspiration hazard, Category 1

Eye Dam. 1

Serious eye damage/eye irritation, Category 1

Eye Irrit. 2A

Serious eye damage/eye irritation, Category 2A

Repr. 2

Reproductive toxicity, Category 2

Skin Irrit. 2

Skin corrosion/irritation, Category 2

H304

May be fatal if swallowed and enters airways.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H361

Suspected of damaging fertility or the unborn child.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Abbreviations and acronyms:

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PennGrade 1® High Performance SAE 30, PennGrade 1® High
Performance SAE 40, PennGrade 1® High Performance SAE 50,
PennGrade 1® High Performance SAE 60, PennGrade 1® High
Performance Nitro 70
Safety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

ATE: Acute Toxicity Estimate
CAS (Chemical Abstracts Service) number
CLP: Classification, Labelling, Packaging.
EC50: Environmental Concentration associated with a response by 50% of the test population.
GHS: Globally Harmonized System (of Classification and Labeling of Chemicals).
LD50: Lethal Dose for 50% of the test population
OSHA: Occupational Safety & Health Administration
STEL: Short Term Exposure Limits
TSCA: Toxic Substances Control Act
TWA: Time Weighted Average
NFPA health hazard: 1 - Materials that, under emergency conditions, can causesignificant irritation.

NFPA fire hazard: 1 - Materials that must be preheated before ignition canoccur.

NFPA reactivity: 0 - Normally stable, even under fire exposure conditions,and not reactive with water.

SDS prepared by The Redstone Group
6077 Frantz Rd.
Suite 206
Dublin, OH USA 43017+1.614.923.7472
www.redstonegrp.com
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

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