Transactions of Materials Research Society of Japan
Volume 28 Number 2 June 2003

CONTENTS
Regular Papers
Surface Modification of Molding Silica Gel Using Dielectric Barrier Discharge ………………………………………
T. Sakoda, K. Imagawa and K. Furukawa

209

Temperature Dependence of Oxygen Electroreduction Properties on Pt and Pt Alloy Particles ……………………
Takako Toda and Itaru Honma

215

Symposium of Control of Structures, Morphologies and Properties of Materials by Magnetic Fields
Preface ………………………………………………………………………………………………………………………

221

Effect of High Magnetic Field on Alignment of Reverse-transformed Structure in Fe-based Alloys …………………
Xinjiang Hao, Hideyuki Ohtsuka and Hitoshi Wada

223

Effect of High Magnetic Field on Alignment of Ferrite Grains in Fe-based Alloys ……………………………………
Patricia DE Rango , Xinjiang Hao, Hideyuki Ohtsuka and Hitoshi Wada

225

Effective Parameters on the Magnetic Alignment Process of Nonmagnetic Inorganic Micro-Crystals Dispersed in a
Fluid Medium Including the Inert Gas ……………………………………………………………………………………
Chiaki Uyeda and Kenta Tanaka

227

Control of Alignment of Feeble Magnetic Particles Utilizing Induced Magnetic Dipole Interactions ………………
Tomohiro Takayama, Yasuhiro Ikezoe, Hiroyuki Uetake, Noriyuki Hirota and Kohichi Kitazawa

231

Martensitic Transformation of γ- FeN in High Magnetic Field Generated by a Hybrid Magnet ……………………
Tamotsu Koyano, Takahiro Nomiyama, Hiroshi Ikeda, Naoko Kanoh, Takuya Ohba, Hideyuki Ohtsuka andHitoshi Wada

235

Change of Magnetic Domain Structure of MnAs Thin Film on GaAs(001) ……………………………………………
Hiromi Kuramochi, Jun Okabayashi, Takashi Manago and Hiroyuki Akinaga

239

Magnetoresistance of La0.7Ca0.3MnO3 Single Crystal and Polycrystalline ……………………………………………
Tomoyuki Terai, Hiromi Fujita, Takeshi Murata, Tomoyuki Kakeshita, Takashi Fukuda and Kohji Kishio

243

Magnetic Field-induced Strain of Ferromagnetic Ni2MnGa Shape Memory Alloy ……………………………………
Nariaki Okamoto, Yuki Nakamura, Takashi Fukuda, Tomoyuki Kakeshita, Tetsuya Takeuchi and Kohji Kishio

245

Crystallographic Orientation Dependence of Magnetic Field-Induced Strain in an Fe-31.2at.%Pd Alloy …………
Tatsuaki Sakamoto, Takashi Fukuda, Tomoyuki Kakeshita, Tetsuya Takeuchi and Kohji Kishio247

Temperature Dependence of Magnetic Field-Induced Strain of Fe3Pt …………………………………………………
Takashi Fukuda, Tetsuya Inoue, Tomoyuki Kakeshita, Tetsuya Takeuchi and Kohji Kishio

249

Diamagnetically Induced Structure Changes in Cellular Assembly and Cytoskeletons ………………………………
Masakazu Iwasaka, Shoogo Ueno and Junji Miyakoshi

251

Refinement of Sn-Pb Alloy by Local Imposition of Electromagnetic Force ……………………………………………
Takashi Kameyama, Kento Sugiura, Satoru Kawai and Kazuhiko Iwai

255

Effect of Strong Magnetic Field on Strain Age Hardening of Co-based Alloy …………………………………………
Akihiko Chiba, Kazuya Kimijima, Akinori Morikawa and Koushichi Noto259

Application of a High Magnetic Field in a Carbonization Process of Pitch ……………………………………………
Mun Gyu Sung, Takeshi Torii, Kensuke Sassa and Shigeo Asai

263

Magnetic and Martensitic Phase Transitions in the Ni-Al-Fe Shape Memory Alloys …………………………………
Katsunari Oikawa, Takuya Ota, Yuki Tanaka, Toshihiro Omori, Ryosuke Kainuma and Kiyohito Ishida

265

Effect of Rare Earth Elements Addition on Properties of Ni-Mn-Ga Ferromagnetic Shape Memory Alloys ………
K.Tsuchiya, A. Tsutsumi, N. Ina, M. Umemoto and H. Ohtsuka

269

Preparation of Magnetic Tunnel Junctions Using Fe3O4 …………………………………………………………………
Kenji Kawaguchi, Woochul Kim, Naoto Koshizaki, Mitsugu Sohma and Tetsuro Matsumoto271

Gas-phase Chemical Reaction of Laser Ablated Copper Atom with Carbon Tetrafluoride in Electric and MagneticFields …………………………………………………………………………………………………………………………
Hironari Tanaka, Taichi Hirano and Akiyoshi Matsuzaki

275

Development of Regular Structure of the Monotectic Alloys Under a Magnetic Field ………………………………
Hideyuki Yasuda, Yoshinori Hayashi, Masayuki Yamamoto, Itsuo Ohnaka and Kohji Kishio279

Stable Levitation of the Metallic Melt by Simultaneous Imposition of Alternative and High Static Magnetic Field
Yuhki Ninomiya, Hideyuki Yasuda, Itsuo Ohnaka, Rintaro Ishii, Satoru Fujita and Kohji Kishio283

Sintering Behaviors and Microstructure of Apatite-based Materials under a High Magnetic Field …………………
Atushi Nakahira, Shinji Konishi, Yukako Honda, Hideyuki Yasuda and Itsuo Ohnaka

287

Synthesis of Carbon Nanotubes by Thermal CVD under High Magnetic Field ………………………………………
Haruo Yokomichi, Fumiko Sakai, Masaki Ichihara and Naoki Kishimoto

291

Ferromagnetic Domain Structure in Colossal Magnetoresistive Manganite；La1-xSrxMnO3(x=0.12) ………………
Shigeo Mori, Tohru Asaka, Yoshio Matsui, K.Okuyama, K.Takenaka and S.Mizukai

295

Symposium of Soft Solution Process
Preface ………………………………………………………………………………………………………………………

299

Synthesis and UV Shielding Properties of Layered Double Hydroxide/2-Hydroxy-4-Methoxy- Benzophenone-5Sulfonic Acid ………………………………………………………………………………………………………………
Qing-Lin He, Shu Yin and Tsugio Sato

301

Preparation and Pyrolysis of Polyphosphosilazane ………………………………………………………………………
Yusuke Mori, Ryoji Toyoda, Satoshi Kitaoka and Yoshiyuki Sugahara

305

Synthesis and Characterization of Colored Titania by Soft Solution Process …………………………………………
Shu Yin, Yohei Aita, Qinglin He, Qing Tang and Tsugio Sato309

Low Temperature Synthesis of Titanium Oxide …………………………………………………………………………
Kenji Toda, Masato Kawakami, Kazuyoshi Uematsu and Mineo Sato

313

Hydroxyapatite Formation Reaction between Calcium Carbonate and Diammonium Hydrogenphosphate ………
Michiyo Kamiya, Chika Asou, Eriko Shimada, Yasuro Ikuma and Masahiro Yoshimura

317

Effect of Seed Crystal on Zirconium Oxide Formation From Aqueous Solution ………………………………………
Naoshi Ozawa and Takeshi Yao

321

Preparation Condition of Lead Zirconate Titanate (PZT) Thin Film from Liquid Phase by Hydrothermal
Electrodeposition ……………………………………………………………………………………………………………
Dai Matsushiro, Jun Tamaki, Yoshifumi Yamamoto and Masao Matsuoka

325

Crystal Phase Control for Metal Oxide Films Grown in Aqueous Solutions …………………………………………
Satoshi Yamabi and Hiroaki Imai

329

Patterning of TiO2 Thin Film on UV Irradiated Organic Polymer Substrates …………………………………………
Naoshi Ozawa, Masayuki Sakata and Takeshi Yao

333

Room Temperature Ferromagnetic ZnO Films Prepared by Solution Chemical Reactions …………………………
Masanobu Izaki, Atsushi Takino, Tsutomu Shinagawa and Akimasa Tasaka

337

A Softer and Efficient Route for the Synthesis of Lithium Niobate Powder ……………………………………………
Deepa Dey and Masato Kakihana341

Rare-Earth Oxide Substituted LiNbO3 Nanopowders Obtained by Polymerizable Complex Method ………………
Monica Popa and Masato Kakihana345

Fluorination of LaBa2Cu3O6+x Superconductor Prepared by Polymerizable Complex Method ………………………
Valery Petrykin, Masato Kakihana, Petr Krtil and Eugene Goodilin

349

Synthesis of KNbO3 in Water ………………………………………………………………………………………………
Kenji Toda, Saori Tokuoka, Naotaka Ohtake, Kazuyoshi Uematsu and Mineo Sato

353

Electrochemical Intercalation of Li Ions in Highly Orientated Layered Cesium (CsxTi2-x/4□x/4O4) Film ……………
Michio Koinuma and Yasumichi Matsumoto

357

Electrophoretic Deposition of Alumina on Stainless Steel Wire Net ……………………………………………………
Atsushi Kaneda, Fumikazu Hasegawa, Yoshikazu Kameshima, Atsuo Yasumori and Kiyoshi Okada

361

Synthesis of NaTaO3 Photocatalysts for Efficient Water Splitting From Amorphous Metal-Complex Method ……
Yukinari Tanaka, Valery Petrykin and Masato Kakihana

365

Preparation of High Resistive and Low Coercive Force Magnetite Films by Chemical Reaction from an AqueousSolution ………………………………………………………………………………………………………………………
Atsushi Takino, Masanobu Izaki and Akimasa Tasaka

369

Chemical Synthesis of Ba2MnWO6 by Polymerizable Complex Method ………………………………………………
Yukari Fujioka and Masato Kakihana

373Synthesis of SrTiO3 from Aqueous Solution Using Lactate Titanium Complex ………………………………………
Koji Tomita and Masato Kakihana

377

Cathodic Electrodeposition of Metal Oxide Thin Films from Non-Aqueous Solutions ………………………………
Seiichi Sawatani, Shirou Ogawa, Naohide Yamada, Mitsuteru Kamiya, Tukasa Yoshida and Hideki Minoura

381

Control of Composition Gradient in Functionally Graded Ti/Fe Oxide Film Prepared by the Liquid Phase
Deposition Method …………………………………………………………………………………………………………
Sachihiko Iizuka, Minoru Mizuhata, Akihiko Kajinami and Shigehito Deki

385

The Effect of EDTA and EDTA Rare Earth Metal Complex on TiO2 Film Deposition by the Liquid Phase
Deposition (LPD) Method …………………………………………………………………………………………………
Kentaro Kuratani, Minoru Mizuhata, Akihiko Kajinami and Shigehito Deki

389

Low Temperature Synthesis of Sr5Ta4O15 by Polymerizable Complex Method ………………………………………
Kohtaro Yoshioka, Mayu Yoshino, Valery Petrykin and Masato Kakihana

393

Phase Formation from Calcium Aluminosilicate Gels by Soft Hydrothermal Treatment ……………………………
Vinay Kumar Jha, Yoshikazu Kameshima and Kiyoshi Okada

397

Platinum-Silica Aerogel Nanocomposite via Supercritical Impregnation: Effect of Silica Surface Properties ………
Satoshi Yoda, Yoshihiro Takebayashi, Tsutomu Sugeta and Katsuto Otake

401

Symposium of Innovative Materials Using Ion Technology
Preface ……………………………………………………………………………………………………………………

405

Novel Preparation of Thin Films and Powders by Pulsed Ion Beam Ablation Plasma ………………………………
Kiyoshi Yatsui, Weihua Jiang, Hisayuki Suematsu, Tsunetoshi Arikado, Tsuneo Suzuki and Makoto Hirai

407

Experimental Evidence for No Beam Force Effect on a Foil Deformation by Irradiation of Heavy Ions at MeV
Energies ……………………………………………………………………………………………………………………
Hidetsugu Tsuchida, Ichiro Katayama, Sunchan Jeong, Hidemi Ogawa, Naoki Sakamoto, and Akio Itoh413

Surface Modification of Highly Oriented Pyrolytic Graphite Targets by Intense Pulsed Ion Beam Irradiation ……
Kenji Kashine, Tsuneo Suzuki, Hisayuki Suematsu, Weihua Jiang, Kiyoshi Yatsui and Yasuhiro Tanabe

417

Mechanical Properties and Oxidation Behavior of Cr-N-O Thin Films Prepared by Pulsed Laser Deposition ……
Jun Inoue, Hajime Saito, Makoto Hirai, Tsuneo Suzuki, Hisayuki Suematsu, Weihua Jiang and Kiyoshi Yatsui421

Preparation of Compositionally Gradient Si1-xGex Thin Films by Ion-Beam Evaporation ……………………………
Hisayuki Suematsu, Takehiko Honzawa, Makoto Hirai, Tsuneo Suzuki, Weihua Jiang and Kiyoshi Yatsui425Preparation of Polycrystalline Si1-xGex Thin Films by Ion-Beam Evaporation ………………………………………
Ryuma Iwashita, Tsunetoshi Arikado, Makoto Hirai, Naotaka Uchitomi, Koji Kimoto, Masanori Mitome,Yoshio Matsui, Minoru Osada, Hisayuki Suematsu, Weihua Jiang and Kiyoshi Yatsui429

Preparation of TiFe Hydrogen Storage Alloy Thin Films by Intense Pulsed Ion-Beam Evaporation ………………
Tsuneo Suzuki, Takeshi Saikusa, Hisayuki Suematsu, Weihua Jiang, Nobuyuki Nishimiya and Kiyoshi Yatsui

433

Characteristics of Ti-Ni-N-O Thin Films Prepared by Pulsed Laser Deposition ………………………………………
Akiji Sayama, Izumi Nakamura, Makoto Hirai, Tsuneo Suzuki, Hisayuki Suematsu, Weihua Jiang and Kiyoshi Yatsui

437

Synthesis of Carbon Nanotubes by Pulsed Wire Discharge ……………………………………………………………
Ryouta Kobayashi, Hisayuki Suematsu, Tsuneo Suzuki, Weihua Jiang and Kiyoshi Yatsui

441

Improvement of the Oxidation Resistance of TiAl Alloys by Metal Plasma-Based Ion Implantation ………………
Takaya Ishii, Kazutugu Murakami, Kazuhisa Fujita and Yutaka Hibino

445

Preparation of Thick DLC Coating on a Trench Surface ………………………………………………………………
Yoshimi Nishimura, Ryouiti Ohkawa, Yoshihiro Oka, Kingo Azuma, Etsuo Fujiwara and Mitsuyasu Yatsuzuka

449

Characteristic of DLC Films Formed by PBII Using Hydrocarbon Gases ……………………………………………
Kaoru Awazu, Takeshi Kawabata, Yuuji Hasegawa, Haruyuki Yasui and Noriyuki Sakudo

453

Carbon and CNx Films Prepared by Using Mass-Separated Low Energy Ion Beam …………………………………
Kazuhiro Yamamoto and Yoshinori Koga

457

Synthesis of Sulfur-Doped TiO2 by Ion Implantation ……………………………………………………………………
Tsutomu Umebayashi, Tetsuya Yamaki, Syunya Yamamoto, Sigeru Tanaka and Keisuke Asai

461

Size and Depth Distributions of Nickel Nanoparticles in SiO2 Fabricated by High-Flux Negative-Ion Implantationof 60 keV ……………………………………………………………………………………………………………………
Hiroshi Amekura, N. Umeda, Hideaki Kitazawa, Yoshihiko Takeda and Naoki Kishimoto

465

Three-dimensional Observation of Metallic Nanoparticles Formed in Insulators by Ion Implantation ……………
Tomohiro Kobayashi and Masaya Iwaki

469

Silver Nanoparticle Formation in SiO2 Film by Negative-Ion Implantation for Single Electron Device ……………
Hiroshi Tsuji, Nobutoshi Arai, Takuya Matsumoto, Yasuhito Gotoh and Junzo Ishikawa

473

Negative Cu Ion Implantation of Insulators and In-Situ Time-Resolved Optical Spectroscopy ………………………
Oleg A. Plaksin, Hiroshi Amekura, Kenichiro Kono, Yoshihiko Takeda, Takeo Suga, Naoki Umeda andNaoki Kishimoto

477

Secondary Ion Emission From Fullerene Films Bombarded by Fast Heavy Ions ……………………………………
Akio Itoh and Akifumi Yogo

481

Cluster Size Effect on Surface Modification Process Using Cluster Ion Beam …………………………………………
Takaaki Aoki, Toshio Seki, Atsuko Nakai, Jiro Matsuo and Gikan Takaoka

485

Cell Induction Technique by Ion Irradiated Collagen for Development of a Small Diameter Artificial Graft ………
Kimi Kurotobi

489

Mechanical Adhesive Strength, XPS and AES Studies of Ion Beam Immobilized Collagen …………………………
Yoshiaki Suzuki, Kimi Kurotobi, Masaya Iwaki, Akiko Yamamoto and Takao Hanawa

495

Improvement of Blood Compatibility of Titanium with Helium Ion - Beam Irradiation ……………………………
Satoo Nakajima, Takeyo Tukamoto, Yoshiaki Suzuki, Masaya Iwaki, Takao Hanawa and Akiko Yamamoto

499

Surface Analysis of Ion-Beam Irradiated poly-L-Lactic Acid ……………………………………………………………
Tasuku Yotoriyama, Yoshiaki Suzuki, Masaya Iwaki and Takeyo Tsukamoto

503

The Morphological Changes and Adhesion Strength in Ion Bombarded Collagen ……………………………………
Yoshiro Yokoyama, Takeyo Tsukamoto, Tomohiro Kobayashi and Masaya Iwaki

507