The M a te rials R esea rch S o ciety o f Ja p an

Transactions of the Materials Research Society of Japan
Volume 30

Number 3

June 2005

CONTENTS
Regular Papers
Plasma Surface Texturing of Single-Crystal Silicon Using Dielectric Barrier Discharge ………………………
Tatsuya Sakoda, Toshiyuki Hamada and Kunihiro Matsukuma

595

Water Repellency of Water-Base-Pigment Inkjet Ink Containing Amphiphilic Copolymers …………………
Juntira Komasatitaya, Shinya Takahashi and Tomoyuki Kasemura

599

Adsorption of Organic Solvents’ Vapors by Porous Carbon Materials Synthesized by Template Method
Hironobu Abiko and Yasushi Shinohara

607

Symposium of Structure Control and Dynamic Functional Properties of Dimensionally-controlled
Polymeric Materials
Preface ………………………………………………………………………………………………………………………………………

615

Evolution of Microphase-Separated Structures upon High Temperature Annealing in Block Copolymer
Thin Films Studied by Transmission Electron Microtomography ………………………………………………………
Ken-ichi Niihara, Yukihiro Nishikawa, Toshio Nishi and Hiroshi Jinnai

617

Fine-Control of Metal Ion Assembly in Novel Topological Poly(phenylazomethine)s ……………………………
Masayoshi Higuchi and Kimihisa Yamamoto

623

Effects of Saturation Pressure of CO2 on Nanofoams nucleated from Block Copolymer Nanodomains …
Hideaki Yokoyama, Lei Li, Taichi Nemoto and Kenji Sugiyama

627

Site Specific Fabrication of Polystyrene Ultrathin Films onto the Patterned Organosilane Monolayer
Surfaces by the Ink-Jet Method ……………………………………………………………………………………………………
Masamichi Morita, Shigekazu Yasutake, Hirotaka Ishizuka, Yousuke Sakai, Jun Fukai andAtsushi Takahara

631

Surface Structure and Properties of (Oligourethane with Fluoroalkyl End Groups / Polyurethane) BlendThin Films …………………………………………………………………………………………………………………………………
Masafumi Horiuchi, Ken Kojio and Mutsuhisa Furukawa

635

Fabrication and Spectroscopic Properties of Hybrid Nanoassemblies Consisting of Metal Nanoparticles
and Polymer Nanosheets ………………………………………………………………………………………………………………
Masaya Mitsuishi, Hiroyuki Tanaka and Tokuji Miyashita

639

Film Thickness Dependence of Photoisomerization for Azobenzene Chromophores Tagged to Polystyrene
with Various Molecular Weights ……………………………………………………………………………………………………
Yohei Tateishi, Keiji Tanaka and Toshihiko Nagamura

643

Synthesis and Frictional Properties of Poly(2,3-dihydroxypropyl methacrylate) Brush Prepared by
Surface Initiated Polymerization on Silicon Wafer …………………………………………………………………………
Motoyasu Kobayashi and Atsushi Takahara

647

Photo-patternable Catalyst Surface for Electroless Deposition …………………………………………………………
Jae-Young Lee, Dehui Yin and Shin Horiuchi
Construction and Photocurrent of Light-harvesting Core Complexes of Photosynthetic Bacteria in Lipid
Bilayers ……………………………………………………………………………………………………………………………………
Morio Nagata, Yukari Nakamura, Emi Nishimura, Katsunori Nakagawa, Yoshiharu Suemori, Kouji Iida andMamoru Nango

651

655

2D Nanophase Separation in Monolayers of Triblock Copolymer Having Azobenzene Moiety ……………
Sohei Kadota, Kenji Aoki, Shusaku Nagano and Takahiro Seki

659

Ideal Spread Monolayer of Fully Hydrophobic Polysilane, Poly(methyloctylsilane), with the Assist of
Liquid Crystal Monolayer ……………………………………………………………………………………………………………
Shusaku Nagano and Takahiro Seki

663

Ethanol Macroclusters Adsorbed on Glass Spheres in Ethanol/Cyclohexane Binary Liquids Studied by
1
H-NMR Spectroscopy …………………………………………………………………………………………………………………
Yasuhiro Nakagawa, Satoshi Endo, Masashi Mizukami and Kazue Kurihara

667

Fabrication of Silver Nanowires Based on DNA Stretched by the LB Method ……………………………………
Yuichi Hashimoto, Yasutaka Matsuo and Kuniharu Ijiro
Bilayer Structure Fluctuation of Amphiphilic Compounds during Self-Assemble Polymerization in Two
Dimensional Anisotropic Field ………………………………………………………………………………………………………
Takeshi Yamada, Tomoko Yoshii, Nobuya Ozawa, Youhei Kawabata, Tadashi Kato and Hirohisa Yoshida
Assembly of Metal Nanoparticles in Multiscales and Multi-Dimensions in Polymer Films ……………………
Shin Horiuchi, Dehui Yin and Jae Young Lee
Synthesis of Ceramic Particles by Micellization, Cross-Linking, and Pyrolysis of Carbosilane Block
Copolymers ………………………………………………………………………………………………………………………………
Kozo Matsumoto, Takashi Nishiya and Hideki Matsuoka

671

675
679

683

Photofunctional Ultrathin Films Prepared by High-Density Graft Polymerization ………………………………
Shinzaburo Ito, Junpei Kuno, Katsuhiro Yamashita, Masataka Ohoka, Hideo Ohkita, Yoshinobu Tsujii andTakeshi Fukuda

687

Polyrotaxane-Film Formation Observed by Surface Plasmon Spectroscopy ………………………………………
Keiko Tawa, Norihito Kuboyama, Ahmed Saleh and Mutsuo Tanaka

691

Thickness Control of Polycationic Single-Layer Adsorption Films by Mix Proportion of Poor Solvent toGood Solvent ………………………………………………………………………………………………………………………………
Yuji Suzuki, Motonori Komura, Masaru Nakagawa and Tomokazu Iyoda

695

Macromolecular Radical Crossover Reaction of Disulfide-Containing Polyester Triggered byFree-Radical Generators ……………………………………………………………………………………………………………
Yasuharu Kobashi, Hideyuki Otsuka and Atsushi Takahara

699

Solid Lublicant Properties of the Supramolecular Assembled Films of Fullerene C60 ……………………………
Kenji Hisada, Kiyofumi Tanaka, Misato Miyake, Akihiro Inaba, Teruo Hori and Yuji Tokunaga

703

Photoelectrochemical Properties of Nano-Structured Polymer Ultrathin Films on Conductive Substrates
Hideo Ohkita, Kuniaki Sakai and Shinzaburo Ito

707

Theoretical Study of Conformation-dependent Spectroscopic Property of Helical ConjugatedPolyisocyanide Derived from L-phenylalanine ………………………………………………………………………………
Yuki I. Yamada and Tomokazu Iyoda

711

Polymer Scrambling by Macromolecular Olefin Metathesis ……………………………………………………………
Takatoshi Muta, Hideyuki Otsuka and Atsushi Takahara

715

Dynamic Transformation of Polymer Structure by Radical Crossover Reaction …………………………………
Yuji Higaki, Hideyuki Otsuka and Atsushi Takahara

719

Preparation and Properties of Polymer Hybrids Containing Nanoparticles with Controlled Interfacial
Structure ……………………………………………………………………………………………………………………………………
Ryosuke Matsuno, Hideyuki Otsuka and Atsushi Takahara

723

Aggregation Structure and Functional Properties of (Inorganic Nanofiber/ Pepsin) Hybrid Hydrogel
Nozomi Inoue, Kazuya Yamamoto, Hideyuki Otsuka, Shin-Ichiro Wada and Atsushi Takahara

727

Vectrorial Electron Transport at a Long Distance by Helical Peptides ………………………………………………
Tomoyuki Morita, Kazuya Kitagawa and Shunsaku Kimura

731

Well-Controlled Nanobiointerface Generated from Phosphorylcholine Block Copolymers Brushes via a"Grafting From" Process ……………………………………………………………………………………………………………
Ryoko Iwata, Yasuhiko Iwasaki, Kazunari Akiyoshi and Atsushi Takahara

735

Spin Alignment of Orthogonal π-Radicals of Directly meso-meso Linked Porphyrin Dimer, Trimer, andTetramer ……………………………………………………………………………………………………………………………………
Jotaro Nakazaki, Yutaka Senshu, Daiki Machida and Hiroshi Segawa

739

Chiral BEDOT-based Copolymers Prepared by Chemical and Electrochemical Polymerization ……………
Yong Soo Jeong, Hiromasa Goto, Shuji Iimura, Toshiyuki Asano and Kazuo Akagi

743

Symposium of Innovative Material Technologies Utilizing Ion Beam
Preface ………………………………………………………………………………………………………………………………………

747

Fabrication of Cu2O Nanoparticles in SiO2 by Ion Implantation Combined with Low-Oxygen-Pressure
Oxidation and Reduction in Ar-Gas ………………………………………………………………………………………………
Hiroshi Amekura, Kenichiro Kono, Oleg A. Plaksin, Yoshihiko Takeda and Naoki Kishimoto

749

Optical Responses of Negative-Copper-Ion Implanted Al2O3 ……………………………………………………………
Oleg A. Plaksin, Yoshihiko Takeda, Hiroshi Amekura, Kenichiro Kono, Naoki Umeda andNaoki Kishimoto

753

Cu Nanoparticle Grating Fabricated by Negative Heavy-Ion Implantation ………………………………………
Haisong Wang, Oleg A. Plaksin, Jing Lu and Naoki Kishimoto

757

Control of Step and Terrace Structures of LSMO Thin Films by IBS Deposition ………………………………
Michi Ogata, Ajay K. Sarkar, Hidetaka Nakashima, Masahito Matsui, Yasushi Kurosaki, Md. Motin Seikh,
Kazuhiro Endo, Hirofumi Yamasaki and Tamio Endo

761

A Model of Large Droplet Behavior in Ablation Plasma Produced by Intense Pulsed Light Ion Beam
Hiroaki Shishido, Hideki Yanagi, Tsuneo Suzuki, Takashi Yunogami, Hisayuki Suematsu, Weihua Jiang
and Kiyoshi Yatsui765

Preparation of Compositionally Gradient Ba-Sr-Al-O Thin Film by Ion-Beam Evaporation ………………
Naoya Honda, Tsuneo Suzuki, Takashi Yunogami, Hisayuki Suematsu, Weihua Jiang and Kiyoshi Yatsui769

Surface Modification of Titanium-Based Alloy with Ti/C Compositionally Graded Film Deposited by
Sputtering …………………………………………………………………………………………………………………………………
Tsutomu Sonoda, Akira Watazu, Kiyotaka Katou, Takahiko Yamada and Tadashi Asahina

773

Preparation of ITO Films with Smooth Surface and Low Resistivity Using Reactive Ion-BeamSputtering …………………………………………………………………………………………………………………………………
Satoshi Iwatsubo

777

Microstructure and Mechanical Properties of Si-DLC Films Deposited by PBII with Bipolar Pulses ……
Junho Choi, Soji Miyagawa, Setsuo Nakao, Masami Ikeyama and Yoshiko Miyagawa

781

Visible and UV Raman Spectra of Diamond-Like Carbon Films Prepared by a PBII System ………………
Setsuo Nakao, Junho Choi, Soji Miyagawa, Yoshiko Miyagawa, Masami Ikeyama and Kazuo Tsugawa

785

Blister Formation in Rutile TiO2 (100) Thin Films by Helium Ion Implantation …………………………………
Shunya Yamamoto, Shinji Nagata, Akinori Takayama and Masahito Yoshikawa

789

Catalytic Effect of Cu Precipitates for the Growth of ZnO Rods ………………………………………………………
Akinori Takeyama, Shunya Yamamoto, Hiroshi Itoh and Masahito Yoshikawa

793

A Comparison of Ions with Neutrals Emitted from Semiconductors Bombarded by MeV Si Ions …………
Yoshihiko Nakata, Satoshi Ninomiya, Takaaki Aoki, Hidetsugu Tsuchida, Jiro Matsuo and Akio Itoh

797

Fatigue Property of Stainless Steel by Ion Implantation …………………………………………………………………
Kiichiro Kono, Masashi Nemoto, Haruo Ishikawa, Qing Wang, Shizuka Nakano and Hisato Ogiso

801

The 3-D Nano-Manipulator Fabrication by FIB-CVD ……………………………………………………………………
Reo Kometani, Takayuki Hoshino, Kazuhiro Kanda, Yuichi Haruyama and Shinji Matsui

805

Ion Beam Modification of Avidin Coated SiO2 Substrate for Protein Micropatterning ………………………
Kazumasa Sato, Yuji Segawa, Ken-ichi Yamakoshi, Yoshiaki Suzuki and Tasuku Yotoriyama

809

Symposium of Diversity of Materials where Soft, Nano, and Multicomponent Meet
– An interdisiplinary approach to innovation in soft materials –Preface ………………………………………………………………………………………………………………………………………

813

Regulation of Quorum Sensing in Serratia marcescens by Adsorption of N-Acylhomeserine Lactones of
Cyclodextrin Immobilized Gel ………………………………………………………………………………………………………
Norihiro Kato, Tomohiro Morohoshi, Hitomi Matsumoto, Toru Tanaka and Tsukasa Ikeda

815

Estimation of Gel Point in the Sol-Gel Transition : A molecular model for the network formation of
Diglysidyle Ether of Bisphenol A and Propylene Glycol Diamino Ether ……………………………………………
Yutaka Tanaka

819

Utilization of Gels for the Environment Purification ………………………………………………………………………
Kazuhiro Hara, Misako Yoshigai and Tetsuaki Nishida823

Uptake of Signal Molecules for Gram-Negative Bacterial Cell-Cell Communication on Polymer Gels …
Norihiko Kato, Hitomi Matsumoto, Tomoyo Nozawa, Tomohiro Morohoshi and Tsukasa Ikeda

827

Freezing Effects of PEG-Modified Poly(N-isopropylacrylamide) Gel on Deswelling Acceleration …………
Norihiro Kato, Wakaaki Murai, Tomohiro Morohoshi and Tsukasa Ikeda

831

Design of Biocompatible Hydrogels with Attention to Structure of Water Surrounding Polar Groups inPolymer Chains …………………………………………………………………………………………………………………………
Toshinori Morisaku, Takayuki Ikehara, Junji Watanabe, Madoka Takai and Kazuhiro Ishihara

835

nm-Scale Assembly of Phospholipid and Detergent Mixture ……………………………………………………………
Kenji Kubota, Tomohiko Sato, Hidemi Kawai, Yoshihiko Inaoka and Kaori Wakamatsu

839

Mechanical Behavior of NIPA Gels in Low Water Content below Freezing Point ………………………………
Atsushi Nakamura, Kazuhiro Hara and Nobuyasu Hiramatsu

843

Investigation on Nano-Structure of Nafion Film with Metal Ion ………………………………………………………
Yoshinori Akai, Masaaki Sugiyama, Keiji Ito, Kazuhiro Mori and Toshiharu Fukunaga

847

Structural Change in Polymer Chains of Sodium Gellan Gums Studied by Circular Dichroism ……………
Etsuyo Ogawa, Rheo Takahashi, Hirofumi Yajima and Katsuyoshi Nishinari

851

Application of Small-Angle X-ray Scattering Utilizing X-ray Anomalous Dispersion to Nano-Structure
Analysis ……………………………………………………………………………………………………………………………………
Masaaki Sugiyama, Yuji Soejima, Kazuhiro Hara, Fumie Takei, Keiji Itoh, Kazuhiro Mori and
Toshiharu Fukunaga

855

Structural Effect for Fe-doping in LaGa1-xFexO3-δ ……………………………………………………………………………
Kazuhiro Mori, Toshiharu Fukunaga, Koji Shibata, Keiji Itoh, Kenji Iwase, Masao Yonemura and
Masaaki Sugiyama

859

Symposium of Recent Advances in Computational Materials Science
Preface ………………………………………………………………………………………………………………………………………

863

Computer Simulation of Grain Growth in Three Dimensions by Phase Field and Monte Carlo Methods
Yoshihiro Suwa and Yoshiyuki Saito

865

Simulation of the Growth of Cu Critical Nucleus in Fe-Cu Alloys ……………………………………………………
Takatoshi Nagano and Masato Enomoto

869

Full-potential KKR Calculations for Point-defect Interaction Energies in Al, Based on the
Generalized-gradient Approximation: two-body and many-body interactions ……………………………………
F. Nakamura, T. Hoshino, S. Tanaka, K. Hirose, S. Hirosawa and T. Sato873

Full-potential KKR Calculations for Point Defect in Al, Based on the Generalized-gradientApproximation: chemical interaction and lattice distortion ………………………………………………………………
T. Hoshino, M. Asato, N. Fujita and N. Papanikolaou

877

Phonon Dispersion Curves and Structural Stability for CuZr Alloys using a New Modified Embedded
Atom Method Potential ………………………………………………………………………………………………………………
Keiko Nakatani, Rodney. J. Clifton and Mike I. Baskes

881

Glass Transition within Cluster Variation Method …………………………………………………………………………
Tetsuo Mohri

885

First-Principles Study on Dielectric Response of Amorphous Al2O3 ……………………………………………………
Hiroyoshi Momida, Takenori Yamamoto, Tomoyuki Hamada, Yoshiteru Takagi, Tsuyoshi Uda and
Takahisa Ohno

889

First-Principles Study of Hg under High-Pressure …………………………………………………………………………
Kazuaki Kobayashi, Masao Arai and Kenichi Takemura

893

Electronic Structure Calculations of Various Graphite Sheets …………………………………………………………
Shuji Obata

897

First Principles Calculations for the New Ferrimagnet Sr8CaRe3Cu4O24 ……………………………………………
Xiangang Wan, Masanori Kohno and Xiao Hu

901

Molecular-dynamics Study for the Effects of Stacking Fault Tetrahedron on the Shear Resistance of Cu
Crystals ……………………………………………………………………………………………………………………………………
Katsuyuki Kusunoki

905

Atomistic Studies on High-Temperature Elasticity and Auxetic Behavior in SiO2 Polymorphs ………………
Hajime Kimizuka, Shigenobu Ogata and Yoji Shibutani

909

Molecular Orbital Study of Interfacial Strength between Silica Cluster and Polyimide Surface ……………
Akinori Fujinami, Shigenobu Ogata, Yoji Shibutani, Kenichi Yamamoto and Manabu Kakino

913