The M a te rials R esea rch S o ciety o f Ja p anTransactions of the Materials Research Society of Japan
Volume 29 Number 7 November 2004

CONTENTS
Symposium of Smart Materials and Smart Structures
Preface ………………………………………………………………………………………………………………………………………

2949

Overview of Japanese Smart Materials and Structures System Project ………………………………………………………
Tateo Sakurai, Naoyuki Tajima, Mikio Sasajima, Nobuo Takeda and Teruo Kishi

2951

Recent Development of Smart Materials ……………………………………………………………………………………………
Yoshitake Nishi and Hiromasa Yabe

2955

Development of a Smart Materials Actuated Fuel Injector for Automobile Engines ………………………………………
Yoshio Akimune, Tatsuo Sugiyama, Kazuo Matsuo, Junko Iita and R-J Xie

2959

Shape Memory Properties and Related Transformation Behavior in a Pre-deformed Sample at Room Temperature
in Fe-15Mn-5Si-9Cr-5Ni-0.5NbC Alloy ………………………………………………………………………………………………
Z. Dong, S. Kajiwara, T. Kikuchi and N. Shinya

2965

Effect of Re Addition on Martensitic Transformation Behavior of Ni-Al-Alloys ……………………………………………
Hee Young Kim, Masanori Okada and Shuichi Miyazaki

2969

Evaluation of Nucleation and Propagation Behavior of Phase Transformation on Shape Memory Alloy Plate ……
Makoto Koushinbou, Go Murasawa, Satoru Yoneyama, Toshio Sakuma and Masahisa Takashi

2973

High Temperature Shape Memory Effects in Ternary Ti-Ni-X (X=Pd, Zr) Thin Films ……………………………………
T. Sawaguchi, M. Sato and A. Ishida

2977

Transformation Characteristics of Sputter Deposited SMA Thin Film ………………………………………………………
Yong Liu and Xu Huang

2981

Joule Heat Induced Shape Memory Behavior of Ti-Ni Shape Memory Alloy Thin Films …………………………………
S. Inoue, T. Namazu, A. Hirayama and K. Koterazawa

2985

Effect of Heat Treatments on Microstructures and Shape Memory Effect in TiNi Foils Produced from Ultrafine
Laminates …………………………………………………………………………………………………………………………………
Dacian Tomus, Koichi Tsuchiya, Takeshi Nagano, Akihide Hosokawa, Masahiro Sasaki, Toshiki Ohmori andMinoru Umemoto

2989

Some Considerations on TiNi-based Thin Films for MEMS Applications ……………………………………………………
Yongqing Fu, Hejun Du, Sam Zhang and Yanwei Gu

2993

Characteristics and Application of Ti-Ni Leaf-Spring Actuator ………………………………………………………………
Kazuhiro Kitamura

2997

Site Preference of The Third Element in TiNi ………………………………………………………………………………………
Shoji Ishida, Koutaro Tabata, Sou Mizutani and Setsuro Asano

3001

Transformation Behavior of Ti-Ni-Pt High Temperature Shape Memory Alloys …………………………………………
Yohei Takahashi, Tomonari Inamura, Junpei Sakurai, Hideki Hosoda, Kenji Wakashima and Shuichi Miyazaki

3005

Mechanical and Shape Memory Properties of Ti-Sc-Mo Biomedical Alloys …………………………………………………
Takashi Maeshima, Kiyoshi Yamauchi, Hiroaki Uchiyama and Minoru Nishida

3009

Microstructural Characterization and Shape Memory Effects of Ti-Nb-Al Alloys …………………………………………
Tomonari Inamura, Yusuke Fukui, Hideki Hosoda, Kenji Wakashima and Shuichi Miyazaki

3013

Shape Memory Characteristics of Ti-Nb-Ge Alloy ………………………………………………………………………………
Yusuke Fukui, Tomonari Inamura, Hideki Hosoda, Kenji Wakabayashi and Shuichi Miyazaki

3017

Electronic Structures of Ferromagnetic Shape Memory Alloys with Martensitic 14M Phase ……………………………
Yoshinori Tanaka, Shoji Ishida and Setsuro Asano

3021

Composition Dependence of Structure in Au52.5-x-Cd47.5-Agx Shape Memory Alloys ………………………………………
Yuki Matsuoka, Akiko Nagahara and Toshiharu Suzuki

3025

Effects of Composition and Structure on Mechanical Properties of Polycrystalline Ni2MnGa Alloy …………………
Hiroyuki Ogasawara, Makoto Ohtsuka, Minoru Matsumoto and Kimio Itagaki

3029

Relation between Composition and Shape Memory Effect of the Sputtered Films of Ferromagnetic Shape Memory
Alloy Ni2MnGa ……………………………………………………………………………………………………………………………
Yuya Konno, Makoto Ohtsuka, Minoru Matsumoto and Kimio Itagaki

3033

Design of Smart Composites Based on Polymer and Shape Memory Alloy Powders ………………………………………
H. Hosoda, S. Takeuchi, M. Yamazaki, T. Inamura, K. Wakashima and S. Miyazaki

3037

Progress on Processing and Design of Composites with Embedded Shape Memory Alloy Wires ………………………
V. Michaud and J.-A. E. Månson

3043

Corrosion Behavior of Ti-Ni-Cu Shape Memory Alloys for Heat Engine Actuator in Simulated Geothermal Waters
Yosuke Horiuchi, Akira Ogawa, Yoshihiro Sasaki, Toshio Sakuma, Li-Bin Niu and Hiroshi Takaku

3049

Fatigue Properties of Highelastic Thin Wire and Superelastic Thin Tube of NiTi Alloy …………………………………
Ryosuke Matsui, Hisaaki Tobushi, Hiroshi Horikawa and Yuji Furuichi

3053

Rearrangement of Martensite Variants of Fe-31.2at.%Pd under Magnetic Field …………………………………………
Tatsuaki Sakamoto, Keiichi Yoshinaka, Takashi Fukuda, Tomoyuki Kakeshita and Kohji Kishio

3057

Influence of Magnetic Field Direction on Recoverable Strain Due to Rearrangement of Variants in Fe3Pt …………
Takashi Fukuda, Tatsuaki Sakamoto, Tetsuya Inoue, Tomoyuki Kakeshita and Kohji Kishio

3059

Magnetic Shear Stress for the Rearrangement of Martensite Variants in Stoichiometric Ni2MnGa ……………………
Nariaki Okamoto, Takashi Fukuda, Tomoyuki Kakeshita, Tetsuya Takeuchi and Kohji Kishio3061

Development of High-temperature Shape Memory Alloys in the Ni2+xMn1-xGa System …………………………………
Vladimir V. Khovailo, Toshihiko Abe, Toshiyuki Takagi, Makoto Ohtsuka and Minoru Matsumoto

3063

Self-Crack-Healing under Cyclic Stress of Silicon Nitride Composite ………………………………………………………
Koji Takahashi, Kotoji Ando and Shinji Saito

3067

Fatigue Strength of Crack-Healed Al2O3/SiCw at Elevated Temperature ……………………………………………………
K. Ando, S. K. Lee, M. Yokouchi, K. Takahashi and H. Suenaga

3071

Critical Crack Healing Condition under Stress and Subsequent Strength at the Healing Temperature ………………
Wataru Nakao, Masato Ono, Masahiro Yokouchi, Koji Takahashi and Kotoji Ando

3075

Fabrication of Metallic Closed Cellular Materials by Sintering of Metal Coated Heat Resisting Particles ……………
Satoshi Kishimoto and Norio Shinya

3079

Structures of Tetra-needle Like ZnO Whisker During the Crystal Growth …………………………………………………
Zuowan Zhou, Longsheng Chu, Shuchun Hu and Lixia Gu

3083

Metal-carbon Nanocomposite Films for Temperature Sensing with Enhanced Functionality …………………………
T. Takeno, T. Takagi, A. Bozhko, M. Shupegin3087

Cellular/Dendritic Transition in Directional Solidification of Tb0.27Dy0.73Fe1.95 Alloy ………………………………
Chengchang Ji, Shigen Zhu, Jianguo Li and Yaohe Zhou

3091

Formation of Self-Orientated Nanocrystals in an Amorphous Alloy under Focused-Ion-Beam Irradiation …………
Takuya Kamikawa, Ryuichi Tarumi, Kazuki Takashima and Yakichi Higo

3095

Influence of Grain Boundary on Magnetoresistance in La0.7Ca0.3MnO3 ………………………………………………………
T. Murata, T. Terai, T. Fukuda, T. Kakeshita and K. Kishio3099

γ'-Fe4N Thin Films with Out-of-plane Magnetization ……………………………………………………………………………
Kaoru Higashi and Katsuto Oda

3103

Colossal Magnetoresistance (CMR) Effect in (Fe,Cu)Cr2S4 ……………………………………………………………………
Shintaro Sakai and Katsuro Oda

3107

Symposium of Self-Assembled Materials
Preface ………………………………………………………………………………………………………………………………………

3111

Functional, Nanostructured Materials via the Polymerization of Liquid Crystal Assemblies ……………………………
D. L. Gin, Y. Xu, W. Gu, M. Zhou, T. J. Kidd and A. C. Sentman

3113

Organic Intercalation with Layered Polymer Crystals Consisting of Diisotactic and Disyndiotactic Polymer Chains
Shinya Oshita, Toshihiro Tanaka and Akikazu Matsumoto

3119

Photo-Thermal Effects of Some Cholesterol-Azobenzene Containing Dimesogens …………………………………………
V. Ajay Mallia and Nobuyuki Tamaoki

3123

Control of the Lower Critical Solution Temperature of Poly(acrylamide) with Azobenzene Units ……………………
Haruhisa Akiyama and Nobuyuki Tamaoki

3127

The Construction of Polymeric [2×2] Metal Grids utilizing Supramolecular Initiators …………………………………
Richard Hoogenboom, Daan Wouters and Ulrich S. Schubert

3131

Supramolecular Engineering with Macromolecules: Preparation of Block Copolymers and Nanomaterials ………
Bas G.G. Lohmeijer and Ulrich S. Schubert

3135

Two-Dimensional Manipulation of π-conjugated Polymer by Means of Instant Mass Migration ……………………
Nobuyuki Zettsu, Takashi Ubukata, Masahiko Hara and Takahiro Seki

3139

Ligand-Printed Ion Pore Composed of Polypeptide Assembly in a Lipid Bilayer Membrane ……………………………
Masahiro Higuchi, Tomoyuki Koga, Takatoshi Kinoshita, Yoshiaki Kobuke and Masami Kawaguchi

3143

Preparation of the Novel Sensing System using Structural Color Plate ………………………………………………………
S. Hayashi, Y. Yokogawa, R. Tominaga and T. Kinoshita

3147

Visual Sensing System from Polypeptide Nano-Assembly ………………………………………………………………………
M. Sivakumar, R. Tominaga, T. Koga, T. Kinoshita, M. Sugiyama and K. Yamaguchi

3151

Characterization of Organized Molecular Layers Including Amphiphilic Isothiouronium Derivatives ………………
Yoshihiro Misawa, Yuji Kubo, Sumio Tokita, Hirokazu Ohkuma and Hiroo Nakahara

3155

Odd-Even Effects of Multilayers in Azobenzene-Containing Urea Amphiphiles ……………………………………………
Toru Kobayashi and Takahiro Seki

3159

Concentration-Dependent Structural Transition of Supramolecular Thiacyanine J-Aggregates in Solution …………
Takeshi Isohashi, Hiroshi Yao and Keisaku Kimura

3163

Nonlinear Optical Susceptibility of Tetra-tert-butyl-Vanadyl-phthalocyanine Films Laminated byLangmuir-Blodgett Method ……………………………………………………………………………………………………………
Saburo Uchida, Vijay T. Chitnis, Hideo Furuhashi, Akinori Maeda, Goro Sawa, Kenzo Kojima, Asao Ohashi,Shizuyasu Ochiai, Yoshiyuki Uchida and Teruyoshi Mizutani

3167

Optical Properties of J-aggregates in Vapor Deposited Films of a Bisazomethine Dye ……………………………………
Shinya Matsumoto, Takashi Kobayashi, Tetsuya Aoyama and Tatsuo Wada

3171

Ferroelectric Langmuir-Blodgett Multilayers Incorporating Metallic Cations ……………………………………………
Shuhong Li, Shihong Ma, Bo Li, Jinglan Sun, Genshui Wang, Xiangjian Meng, Junhao Chu and Wencheng Wang

3175

Preparation of Mesoporous Silica Films Filled with Various Amino Acids and Peptides in Their Nanopores ………
Katsuhiko Ariga, Qingmin Zhang, Akihiro Okabe, Makiko Niki, Takuzo Aida, Tomoyuki Koga, Yukihiro Kojima andTakatoshi Kinoshita

3179

Immobilization of One-Dimensional Charge-Transfer Assemblies in Mesoporous Silica Films through Discotic
Molecule Templating ……………………………………………………………………………………………………………………
Akihiro Okabe, Takanori Fukushima, Katsuhiko Ariga and Takuzo Aida

3183Asymmetric Photoreaction in Peptide Assemblies Confined in Mesoporous Silica Nanopores …………………………
Takuji Aimiya, Katsuhiko Ariga, Akihiro Okabe, Takanori Fukushima, Makiko Niki and Takuzo Aida

3187

Soft Templating of Metallic and Metal Oxide Porous Sponges Using Sacrificial Dextran-Based Composites ………
Dominic Walsh, Laura Arcelli, Toshiyuki Ikoma, Junzo Tanaka and Stephen Mann

3191

Preparation of Metal/Metal Oxide Network Using Organic Polymer Gel ……………………………………………………
Yoshimi Seida and Yoshio Nakano

3195

Phthalocyanine-Gold Particle Nanostructured Assemblies for Near-IR Photoelectric Conversion ……………………
Sunao Yamada, Kazuma Inoue, Tsuyoshi Akiyama, Yutaka Kuwahara, Nao Terasaki, Satoshi Nitahara andShinobu Inoue

3199

Preparation of Organic-Inorganic Nanohybrids by Using Self-Assembly Reaction of Amorphous Metal Hydroxides
with Organic Compounds ………………………………………………………………………………………………………………
H. Noguchi, T. Takahashi, B. Hatano and H. Tagaya

3203

Preparation and Intercalation Reactions of Zn-Sn LDH and Zn-Al-Sn LDH ………………………………………………
Osama Saber and Hideyuki Tagaya

3207

Complexation of Dendrimer-protected Silver Nanoparticles with Hydrotalcite ……………………………………………
Alexsandro Santos Costa and Toyoko Imae

3211

Intercalation of Cu2+ with 3-(Aminopropyl) triethoxysilane into Montmorillonite …………………………………………
Toshimi Sugiyama, Emi Noguchi, Takafumi Furuya, Tomohiko Hayashi, Takako Kawamura, Yoshikuni Uchida,
Kazunori Matsui and Yoshiyuki Nakamura

3215

Control of Photochemical Dimerization of Acenaphthylene in Graphite Oxides Intercalated by n-Alkylamines withDifferent Alkyl Chain Lengths …………………………………………………………………………………………………………
Yoshiaki Matsuo, Takahiro Fukunaga, Naoto Tokura, Tomokazu Fukutsuka and Yosohiro Sugie

3219

Adosorption of Cationic Surfactants on Hydrogen-Terminated Si(111) Surfaces Studied by In-situ Atomic ForceMicroscopy …………………………………………………………………………………………………………………………………
A. Imanishi, M. Suzuki and Y. Nakato

3223

Quenching Effects and Conduction Characteristics of Al Doped ZnO Ceramics …………………………………………
T. Tohsophon, N. Sirikulrat and T. Tunkasiri

3227

Symposium of Materials for Membrane Separation
Preface ………………………………………………………………………………………………………………………………………

3231

Inorganic Membranes for Harsh Conditions – Viewpoints on Materials Issues ……………………………………………
Rune Bredesen

3233

Development of Ceramic Support Substrates for Hydrogen Separation Membrane Applications ……………………
S. Yamada, Y. Yoshino, B.N. Nair and H. Taguchi

3239

Preparation of Thin Zeolite Films on Porous Titania-Stainless Steel Composite Substrates ……………………………
Mikihiro Nomura, Leszek Gora, Thomas Maschmeyer, Ben Meester, Joop Schoonman, Freek Kapteijn andJacob A. Moulijn

3243

Transport Properties of Condensable Gases through Microporous Silica Membranes ……………………………………
Tomohisa Yoshioka, Junpei Tanaka, Syougo Furutani, Toshinori Tsuru and Masashi Asaeda

3247

Hydrogen Permeation Characteristics of Melt-Spun Amorphous Alloy Membranes ………………………………………
S. Yamaura, H.M. Kimura, A. Inoue, M. Nishida, Y. Shimpo and H. Okouchi

3251

Preparation and Characterization of SiC Membranes for High Temperature Hydrogen Separation …………………
H. Suda, Y. Uchimaru, I. Fujiwara and K. Haraya

3255

Catalytic Membrane Reactors for Methane Reforming using Hydrogen Permselective Silica Membranes …………
T. Tsuru, K. Yamaguchi, T. Yoshioka and M. Asaeda

3259

Microporous Silica Membrane Prepared using TMOS/O3 CVD in Opposing Reactants Geometry ……………………
G. Suraj, K. Ono, M. Nomura, T. Sugawara, H. Takaba and S. Nakao

3263

Stability of Ni-doped Silica Membranes for H2 Separation at High Temperature …………………………………………
M. Kanezashi, T. Yoshioka, T. Tsuru and M. Asaeda

3267

Microporous Inorganic Membranes for CO2 Separation ………………………………………………………………………
Izumi Kumakiri, Nicolas Lecerf and Rune Bredesen

3271

Gas Permeation Properties of Iron Containing Carbon Molecular Sieve Membranes ……………………………………
H. Suda, I. Fujiwara and K. Haraya

3275

Development of a Design Tool for Gas Separation Membrane Modules using Computational Fluid Dynamics
Simulation …………………………………………………………………………………………………………………………………
Hiromitsu Takaba, Takuro Nishimura, Kimito Funatsu and Shin-ichi Nakao

3279

Effect of Molecular Interactions on Gas Permeation Properties through a Microporous Silica Membrane Studiedwith Molecular Dynamics Simulation ………………………………………………………………………………………………
Tomohisa Yoshioka, Toshinori Tsuru and Masashi Asaeda

3283

A Novel Method for Preparation of SrFeCo0.5Ox Membranes on Porous Substrates for Oxygen Permeation ………
Masayuki Ikeguchi, Masayuki Kaneko, Yasushi Sekine, Eiichi Kikuchi and Masahiko Matsukata

3287

Methanol Permeation Properties of Sulfonated Polyimide Membranes ……………………………………………………
Ken-ichi Okamoto, Liming Yang, Tatsuaki Honda, Yan Yin, Makoto Yoshino, Kazuhiro Tanaka and Hidetoshi Kita

3291

Pervaporation Properties for an Azeotrope of Ethanol/Water through Organic-Inorganic Hybrid Membranes from
Quaternized Chitosan with Tetraethoxysilane ……………………………………………………………………………………
Tadashi Uragami, Takuya Katayama and Takashi Miyata

3295

Gas and Vapor Permeation through Liquid Membrane Using Ionic Liquid …………………………………………………
Nobuhiro Yamanouchi, Shuhong Duan and Akira Ito

3299

Effect of Ultrasound on Membrane Cleaning Processes for Enhancement of its Permeability …………………………
Kyaing Kyaing Latt, Tsuyoshi Kobayashi and Takaomi Kobayashi

3303

A Photocatalytic Membrane Reactor for Liquid-phase Reactions using Porous Titanium Oxide Membranes ………
T. Tsuru, Y. Ohtani, T. Yoshioka and M. Asaeda

3307

Molecularly Imprinted Nylon Membranes Having Amino Acid Selective Binding Properties. Effect of Phase
Inversion Condition on Membrane Characteristics ………………………………………………………………………………
Takaomi Kobayashi, Masanori Abe and Kohei Takeda
Preparation and Characterization of Polymer-Mica Composite Cation-Exchange Membranes ………………………
Ryotaro Kiyono, Kaori Hanai, Masayasu Tasaka, Kunio Kitajima and Tomohiro Yamaguchi
Effect of Thin Fluoro-ionomer Coating by Plasma Polymerization on Methanol Crossover and Proton Conductivityof Membrane for Direct Methanol Fuel Cell ………………………………………………………………………………………
Masao Sudoh, Tomoyoshi Hakamata, Kazuyoshi Furukawa and Keiichi Okajima
Ion-Pairing Effects in Charged Membranes with Low Water Contents ………………………………………………………
Ryotaro Yamamoto, Hidetoshi Matsumoto and Akihiro Tanioka

3311

3315

3319

3323