The M a te rials R esea rch S o ciety o f Ja p an

Transactions of the Materials Research Society of Japan
Volume 30

Number 4

December 2005

CONTENTS
Regular Papers
Adsorption of Aromatic Vapors by Porous Template Carbon Material Synthesized from Polyfurfuryl Alcohol ……
Hironobu Abiko and Yasushi Shinohara
Sintering Control of Ni Internal Electrode for MLCC by using BaTiO3 Resinate and BaTiO3 Ultra fine Powder as
Additives ……………………………………………………………………………………………………………………………………
Ryosuke Ueyama, Kiyoshi Kuribayashi and Kunihiko Koumoto

917

921

Symposium of Ecomaterials in the Next Generation– high-performance energy-materials with eco-compatibility –Preface ……………………………………………………………………………………………………………………………………

925

Research on Application of Decision-making Tool of LCA ………………………………………………………………………
Tomonori Honda, Hong Nguyen, Minako Hara, Koichi Nagashima, Wang Ying and Ryoichi Yamamoto

927

Functions of Eco-materials in the Context of Eco-design ………………………………………………………………………
Hong X. Nguyen, Tomonori Honda, Ying Wang and Ryoichi Yamamoto

931

The Reduction Effect of the Environmental Load by Leasing Personal Computers ………………………………………
Koichi Nagashima, Tomonori Honda, Hong Nguyen Xuan, Ying Wang and Ryoichi Yamamoto

935

Development of Weighting Factors for Time Consumption Method –Comparison of Beverage Containers …………
Minako Hara, Tomonori Honda, Hong X. Nguyen, Katsuhito Nakazawa, Ryoichi Yamamoto and Itaru Yasui

939

Proton Conduction Properties of Crosslinked PTFE Electrolyte Membranes with Different Graft-chain Structures
S. Sawada, T. Yamaki, M. Asano, T. Terai and M. Yoshida943

Densification Behavior and Electrolytic Properties of Nano-structured DyxCe1-xO2-. (x=0.1, 0.15, 0.2 and 0.25) Solid
Electrolytes with High Density ………………………………………………………………………………………………………
Tomoaki Kobayashi, Toshiyuki Mori, Yarong Wang, Toshiyuki Nishimura, John Drennan and Hidehiko Kobayashi

947

Preparation and Characterization of Nano-hetero Pt-pure CeO2 Electrodes Supported by Carbon Materials for
Direct Methanol Fuel Cells Applications ……………………………………………………………………………………………
Motoi Takahashi, Toshiyuki Mori, Ajayan Vinu, Hidehiko Kobayashi, John Drennan and Chikashi Nishimura

951

Fabrication of Dense Gd0.1Ce0.9O1.95 Sintered Bodies with Nano-size Grain and its Conducting Properties …………
Richard Buchanan, Toshiyuki Mori, Yarong Wang, Ding-Rong Ou, Fei Ye and John Drennan

955

Catalytic CO Oxidation Over Oxide Supported Pd Catalysts …………………………………………………………………
Libor Sedláček, Toshiyuki Mori, Motoi Takahashi, Ding-Rong Ou, Iva Matolínová and Vladimír Matolín

959

Study on Thermoelectric Properties of Conductive Polymers …………………………………………………………………
Y. Shinohara, K. Hiraishi, H. Nakanishi, Y. Isoda and Y. Imai

963

Fabrication of Two-component Fullerene Nanotubes and Nanowhiskers by the Liquid-liquid Interfacial
Precipitation Method ……………………………………………………………………………………………………………………
Kun’ichi Miyazawa, Jun-ichi Minato, Tadahiko Mashino, Tetsuro Yoshii and Tadatomo Suga

967

M-N-H Systems for High-Performance Hydrogen Storage (M= Alkaline and Alkaline Earth Metal) …………………
Yuko Nakamori, Gaku Kitahara, Akihito Ninomiya and Shin-ichi Orimo

971

Rare Earth-Nickel Hydrides for High-Pressure Hydrogen Storage Materials ………………………………………………
Hiroshi Senoh, Nobuhiko Takeichi, Hideaki Tanaka, Nobuhiro Kuriyama, Tasuku Yonei and Hiroyuki T. Takeshita

975

Hydrogen States in the Graphite Ball-milled under Hydrogen Atmosphere …………………………………………………
M. Onkawa, H. T. Takeshita, T. Kiyobayashi and N. Kuriyama

979

Structual Change of Zr7Ni10 Caused by Mechanical Grinding …………………………………………………………………
T. Kishida and H. T. Takeshita

983

Small Reformer for Steam Reforming of Methanol Using Ni Nanoparticles on a Ceramic Surface ……………………
K. Harada, T. Fukasawa, T. Suetsuna and S. Suenaga

987

Preparation of Composite Membrane against H2S Poisoning for Hydrogen Separation …………………………………
Jihye Gwak, André Ayral, Masao Komaki and Chikashi Nishimura

991

Symposium of The Cutting Edge of Aerosol Deposition Method
Preface ……………………………………………………………………………………………………………………………………

995

Soft Magnetic Properties of Ferrite based Aerosol Deposition Film …………………………………………………………
Seiichi Miyai, Katsumi Okayama, Kaoru Kobayashi, Toshio Kagotani, Satoshi Sugimoto, Maxim Lebedev and
Jun Akedo

997

Sm-Fe-N Thick Film Magnets Fabricated by Aerosol Deposition Method …………………………………………………
S. Sugimoto, T. Maki, T. Kagotani, K. Inomata and J. Akedo

1001

Molecular Dynamics Study on the Particle Fragmentation in the Aerosol Deposition Method …………………………
Hiroshi Ogawa

1005

Preparation of Transparent Yttrium Oxide Film by Aerosol Deposition Method …………………………………………
Junichi Iwasawa, Ryoichi Nishimizu and Masakazu Kiyohara

1009

Diode Laser Annealing of PZT Films Produced by Aerosol Deposition Method ……………………………………………
Masahiro Tsukamoto, Masakazu Mori, So Baba, Nobuyuki Abe and Jun Akedo

1013

Titania/Hydroxyapatite Composite Multifunction Photocatalyst Film Coating Using a Hybrid Aerosol Beam
Irradiation Coating System ……………………………………………………………………………………………………………
Toshiaki Fujihara, Masahiro Tsukamoto, Nobuyuki Abe, Takayoshi Ohji and Jun Akedo
Effect of Primary Powder in Aerosol Deposition of Aluminum Nitride ………………………………………………………
Atsushi Iwata and Jun Akedo

1017
1021

Symposium of Materials’ FrontierPreface……………………………………………………………………………………………………………………………………

1025

The Effect of Oxygen Partial Pressure on the Magnetoresistance of Co(-Pt)-ITO Thin Films …………………………
Wanti Ekawati, Ji Shi, Yoshio Nakamura and Osamu Nittono

1027

Stabilization of Deposition Rate of Mn Oxide Films by Using SUS Cell ………………………………………………………
Masaaki Isai, Yutaka Nagashio, Tomohiro Tatei and Hiroshi Fujiyasu

1031

Preparation and Biocompatibility of Aromatic Polymides Containing Phosphorylcholine Moiety ……………………
Masataka Oku, Satoshi Nakajima, Yoshinori Tadokoro, Naoya Shimoyamada, Yu Nagase, Yasuhiko Iwasaki and
Kazuhiko Ishihara

1037

Electrochemical Deposition of Stacked Layers of Cu2O/Cu/Cu2O and Rendering of Structural Colors ………………
Masayoshi Fujita, Yasuyuki Miyakita, Norihito Sogoshi, Seiichiro Nakabayashi, Akitsugu Kondo and Masahiko Ishii

1041

Adsorption and Desorption Behavior of Ammonium Ion on Expandable Illite ……………………………………………
Shingo Yokoyama, Yujiro Watanabe, Hikaru Uno, Kenji Tamura, Tsutomu Sato and Hirohisa Yamada

1045

Photoluminescence of Electrochemically-Deposited Granular Cu2O Films …………………………………………………
Yuhei Terui, Masayoshi Fujita, Yasuyuki Miyakita, Norihito Sogoshi and Seiichiro Nakabayashi

1049

Synthesis and Luminescence Properties of New Long Persistent Phosphors ………………………………………………
A. Komeno, Y. Ito, S. Abe, K. Uematsu, K. Toda and M. Sato1053

Synthesis of Fully Aromatic Polysilarylenesiloxanes and Their Thermal Properties ………………………………………
Hitoshi Ito, Eiichi Akiyama, Takashi Kawakami, Yu Nagase, Akiko Yamamoto and Saburo Fukui

1057

Hybrid Films of Metal Complexes and a Clay Mineral Prepared by the Langmuir-Blodgett Method: Effect of the
Alkyl-Chain Length of Amphiphilic Ruthenium (II) Complex …………………………………………………………………
Kenji Tamura, Hirohisa Yamada, Shingo Yokoyama, Hisako Sato and Akihiko Yamagishi

1061

Preparation of LaNiO3 Thin Films by Liquid-Delivery MOCVD ……………………………………………………………
Yuzo Tasaki, Masanori Kabeya, Toshiaki Kanoko and Shuji Yoshizawa
An Investion of Interaction of Transition Metal Complexes Having Oligopeptide Fragment as Ligands throuth
Hydrogen Bonding ………………………………………………………………………………………………………………………
Ryôki Nomura, Hiroshige Terawaki and Osamu Shimomura

1065

1069

Utilization of Aryl Sulfide as a Novel Safety-Catch Linker for Solid Phase Organic Synthesis …………………………
Osamu Shimomura, Kosuke Tayama and Ryôki Nomura

1073

Tissue Compatible Segmented Polyurethane Hollow Fiber as a Scaffold for Hybrid Blood Vessel ……………………
Kayahiko Makita, Sang Ho Ye, Junji Watanabe, Madoka Takai and Kazuhiko Ishihara

1077

Photocrosslinkable and Biocompatible Phospholipid Polymers for Making Microhydrogel in Microfluidic Devices
Jun Yamaguchi, Junji Watanabe, Madoka Takai and Kazuhiko Ishihara

1081

Application of Inverse Gas Chromatography in the Study of PMMA Tacticity and It’s Blending with Cholesteryl
Esters ………………………………………………………………………………………………………………………………………
Michiko Tazaki, Shigeru Satake, Masaru Okabe, Risei Wada and Terutake Homma

1085

Synthesis of Nitride Compound Using Fluidized Bed ……………………………………………………………………………
Yoshiomi Yamanaka, Kenji Toda, Kazuyoshi Uematsu, Mineo Sato and Noriyasu Hotta

1089

Pervaporation Property of Siloxane-Grafted Aromatic Polymer/Silicalite Hybrid Membrane …………………………
Tsuyoshi Sugiyama, Tomonori Ando, Kenichiro Haga, Yu Nagase, Hitoshi Ito and Eiichi Akiyama

1093

Pseudomorphic Amorphism after Zeolite-LTA at Acid Conditions: XRD, SEM and NMR Characterization ………
Hirohisa Yamada, Shingo Yokoyama, Yujiro Watanabe, Junichi Minato, Kenji Tamura, Keisuke Fukushi,
Masashi Ookawa and Atsushi Yamazaki

1097

Separation of Al and Cu Powders in the Magneto-Archimedes Levitation Field …………………………………………
Takayuki Yoshikawa, Kazuhiro Honda, Akira Sato and Seiichiro Nakabayashi

1101

Pervaporation Property of Siloxane-Grafted Aromatic Polyamide Membrane ……………………………………………
Yasumasa Arihara, Tomonori Ando, Tsuyoshi Sugiyama, Kenichiro Haga, Masami Araya and Yu Nagase

1105

Perpendicular Magnetic Anisotropy of Co-Ti-N Films …………………………………………………………………………
Yuuki Yamamoto, Ji Shi and Yoshio Nakamura

1109

Effect of Rapid Thermal Annealing on the Crystal Structure of SrS:Cu Films ……………………………………………
Masaaki Isai, Yuki Inagaki, Tetsuaki Ichikawa, Shinji Higashibata, Takehiro Fujinaga and Hiroshi Fujiyasu

1113

Fabrication of Nanocrystalline ZrO2-Spinel Composite …………………………………………………………………………
K. Morita, B.-N. Kim, K. Hiraga and Y. Sakka

1117

Symposium of Advances in the Application of Biological Resources
Preface ……………………………………………………………………………………………………………………………………

1121

Study on the Cultivation of Apios (Apios Americana Medikus) in the Upland Field Converted from Paddy and its
Carbohydrate Composition ……………………………………………………………………………………………………………
Yasuo Ogasawara and Yoji Kato

1123

Mesoporous Recycled Ceramics for Carrier of Bio-enzyme used in the Water Purification ……………………………
Yoshiyuki Yokogawa, Katsuya Kato, Takao Saito and Sindhu Seelan

1127

Colored Carbon Hybrid Spherical Microbeads Possessing Shell Composed by TiO2 and Iron Oxide using
Cellulose-Inorganic Hybrid-sphering Technique …………………………………………………………………………………
Kenji Arinaga, Shoji Nagaoka, Shigenori Hamaoka, Makoto Takafuji and Hirotaka Ihara

1131

Carbon-TiO2 Hybrid Spherical Microbeads with Photocatalytic Activity Prepared using Cellulose-Inorganic
Hybrid-sphering Technique ……………………………………………………………………………………………………………
Shoji Nagaoka, Kenji Arinaga, Hiromi Kubo, Toshihiko Sakurai, Makoto Takafuji and Hirotaka Ihara

1135

Preparation of Spherical Nano Particles Using Novel Oligosaccharide Pendant Polymers and theirCharacterization …………………………………………………………………………………………………………………………
Takao Satoh, Shoji Nagaoka, Toshihiko Sakurai, Makoto Takafuji and Hirotaka Ihara

1139

Preparation of Insoluble Chitosan Beads Functionalized by Carboxymethylated ß-Cyclodextrin ……………………
Nobuyuki Aoki, Kenji Kinoshita, Ryo Arai, Katsuhiko Mikuni, Katsuyoshi Nakanishi and Kenjiro Hattori

1143

RF Magnetic Shielding Effects Found in the Superposition of a Wood Ceramics Cylinder over a BPSCCO Cylinder
Y. Hotta, A. Omura, K. Yamagata, S. Gokyu, H. Norikane and M. Itoh1147

Hydrogen Absorption and Adsorption Characteristics of Woodceramics ……………………………………………………
Akito Takasaki, Masahisa Otsuka and Toshihiro Okabe

1151

Effect of Carbonization Temperature on Adsorption Isotherms of Wood Charcoals ………………………………………
Shuji Yoshizawa, Takayuki Utsugi, Kazunori Shibano, Sumio Goto and Hirofumi Yajima

1155

Methods for Increasing Quantity Polyphenol Extracts from Apple Lees and the Development of Polyphenol
Extracts for Use as Cosmetics …………………………………………………………………………………………………………
Y. Kitayama, T. Yamamoto, S. Nakamura and T. Okabe

1159

Saturated Adsorption Amount of Chemical Compounds by Charcoal Board as Building Interior Materials ………
Kazunori Shibano, Shuji Yoshizawa, Sumio Goto and Yuu Ogawa

1163

Micro Pore Structures of Woodceramics Prepared by MDF- and Powder-Methods ……………………………………
Masamichi Miki, Takeyuki Kikuchi, Shinji Inada, Michitaka Suzuki and Jun Takada

1167

Germination Control Effect of Bees Wax Preparation Containing Hinokitiol on Garlic Sprout ………………………
Yasuhiro Morita, Yoshihiko Inamori, Shingo Nakamura, Kazunori Narita and Toshihiro Okabe

1173

Precision Cutting Characteristics of Diamond Cutting Wheel to Woodceramics …………………………………………
K. Ogawa, K. Hata, M. Mayuzumi, T. Okabe, M. Ogawa and M. Otsuka

1179

Processing Characteristics of Woodceramics during Vibration Cutting ……………………………………………………
K. Ogawa, M. Sato, K. Hata, M. Mayuzumi, T. Okabe, M. Ogawa and M. Otsuka

1183

Humidity Dependence of Impedance for Woodceramics Made from Waste Paper …………………………………………
Kazuhiko Kakishita and Toshsikazu Suda

1187

Symposium of Smart Materials
Preface ……………………………………………………………………………………………………………………………………

1191

Mass Production of High-Quality Single-Wall Carbon Nanotubes by Electric-Arc Technique …………………………
Yoshinori Ando, Xinluo Zhao, Sakae Inoue, Tomoko Suzuki, Masato Ohkohchi and Takenori Kadoya

1193

Preparation of Dispersed Nickel Oxalate Dihydrate by Aqueous Solution Process and its Thermal Decomposition
Takaeshi Okamoto, Zhihong Liu, Ryoichi Ichino and Masazumi Okido

1199

Perpendicular Magnetic Anisotropy of CoPt/AlN Multilayer ……………………………………………………………………
Y. Hodumi, M. Uyama, J. Shi and Y. Nakamura

1203

Acceleration of Enzymatic Reactions on Phospholipid Polymer Nanoparticles for Diagnosis Device …………………
Junji Watanabe and Kazuhiko Ishihara

1207

Micropatterned Carbohydrate and Protein Display via Self-Assembly of Glyco-Polymers ………………………………
Yoshiko Miura, Hajime Sato, Takahiro Yamauchi, Osamu Takai and Kazukiyo Kobayashi

1211

Fabrication of Sustainable Au Mono-atomic Wire showing Conductance Quantization in Solution ……………………
Manabu Kiguchi, Tatsuya Konishi, Shin-ichi Miura and Kei Murakoshi

1215

Morphology Control of Hollow Ni-P Microfibers …………………………………………………………………………………
Mitsuru Udatsu, Daisuke Ishii, Masaru Nakagawa, Tomokazu Iyoda, Taichi Nagashima and Matsuaki Yamada

1219

Synthesis and Structural Control of Metal-Containing Polyimide Nanocomposite …………………………………………
Hiroyuki Shinkai, Shingo Ikeda, Kensuke Amekura, Hidemi Nawafune and Satoshi Tomita

1223

Surface Functionalization of Mixed Monolayer-Protected Semiconductor Nanocrystals …………………………………
Takaaki Tsuruoka, Kensuke Akamatsu and Hidemi Nawafune

1227

Raman Scattering Analysis of Amorphous Carbon Nitride Thin Films Prepared by Pulsed Laser Deposition at
Various Temperatures ……………………………………………………………………………………………………………………
M. Rusop, T. Soga and T. Jimbo
Properties of ZnO Films by Dip Coating of Sol Gel Method ……………………………………………………………………
M. Rusop, K. Uma, T. Soga and T. Jimbo
Axial Ligand Dependences of the Relaxation Dynamics of the Singlet Excited State of Center-to-Edge
Phosphorus(V)porphyrin Heterodimers ……………………………………………………………………………………………
Kenji Nagao and Hiroshi Segawa

1231
1235

1239

Imaging of Charged Micropatterend Surface on the Organolane Monolayer Using Chemical Force Microscope …
Tomoyuki Koga, Hideyuki Otsuka and Atsushi Takahara

1243

Design of Micro-biosensors in Healthcare Chip for Convenient Blood Diagnostics ………………………………………
Madoka Takai, Hiroki Ogawa, Masao Nagai, Kazuhiko Ishihara and Yasuhiro Horiike

1247

XED Studies on Sol Gel Spin Coating Zn1-xMgxO Thin Films …………………………………………………………………
Kasimayan Uma, Mohamad Rusop, Tetsuo Soga and Takashi Jimbo

1251

Synthesis of Surfactant-stabilized Co/Au Bimetallic Nanoparticles with a Core-shell Structure ………………………
Tetsu Yonezawa, Kazuhiko Shibuya and Hiroshi Nishihara

1255

Non-equilibrium Structures of α-helix Rod Type Hydrophobic Polypeptide Molecules on Mica Surface ……………
Tetsu Yonezawa, Akihiko Miyata, Masayoshi Tanaka and Takatoshi Kinoshita1259