The M a te rials R esea rch S o ciety o f Ja p an

Transactions of the Materials Research Society of Japan
Volume 29 Number 6 September 2004

CONTENTS
Symposium of Materials For Living -Environment・Medicine・WelfarePreface ………………………………………………………………………………………………………………………………………

2539

Synthesis and Properties of Novel Sulfonated Polyimides for Fuel Cell Application ………………………………………
Jianhua Fang, Xiaoxia Guo and Morton Litt2541

GaN Epitaxial Growth on Sapphire Substrates by NH3 Source Molecular Beam Epitaxy ………………………………
Naoki Ohshima, Akihiro Sugihara, Naoya Yoshida and Naohiko Okabe

2547

Fabrication of Thin YIG Ferrite Platelet Using SPS Method ……………………………………………………………………
Setsuo Yamamoto, Naoyuki Oki, Hiroki Kurisu and Mitsuru Matsuura

2551

Thermoelectric Properties and Electronic Structure of Mg2Si System ………………………………………………………
Naoki Arita, Kenji Koga, Koji Akai, Hiroki Kurisu, Setsuo Yamamoto and Mitsuru Matsuura

2555

High Resolution TEM Study of Li2NiMn3O8 and Li2MnNiO4 for Advanced Lithium Batteries …………………………
Noriaki Nakayama, Tadato Mizota, Tsutomu Ohzuku and Yutaka Ueda

2559

Separation Organics/Water Mixtures by Pervaporation with Silicalite Membranes ………………………………………
Xiangshu Chen, Hidetoshi Kita and Kenichi Okamoto

2563

Synthesis of Zeolite Beta Membrane and its Pervaporation Properties ………………………………………………………
Xiansen Li, Hidetoshi Kita and Kenichi Okamoto

2567

CO2 Removal by Branched Polyether Membranes ………………………………………………………………………………
Makoto Yoshino, Hidetoshi Kita, Kenichi Okamoto, Masato Tabuchi and Takaaki Sakai

2571

Rechargeable Lithium Polymer Battery ……………………………………………………………………………………………
Yasuo Matoba, Shohei Matsui, Masato Tabuchi and Takaaki Sakai

2575

Novel Proton Conducting Polyimides from Sulfonated Sulfonyl-Containing Diamine Monomer ………………………
Xiaoxia Guo, Jianhua Fang and Ken-ichi Okamoto

2579

Growth Process of GaN Layer on ZrB2 Substrate by Gas Source Molecular Beam Epitaxy ……………………………
Naoki Ohshima, Akihiro Sugihara, Naohiko Okabe, Naoya Yoshida and Shigeki Ohtani

2583

Thermal Stability and Decomposition Products of Mg-exchanged Na-LTA Zeolite for Heat Pump Use ………………
Noriaki Nakayama, Yasuhiro Hayashi, Keiko Fujiwara and Tadato Mizota

2587

Transport Phenomena through Zeolite NaA and T-type Membranes …………………………………………………………
Masakazu Kondo, Yoshiyuki Kumazawa, Tadafumi Yamamura, Jun Abe, Hidetoshi Kita and Ken-ichi Okamoto

2591

Preparation of Anatase Film by the Solution Process ……………………………………………………………………………
Yoko Ohba, Hiroaki Ashizawa, Etsuo Sakai, Masaki Daimon and Yoshikazu Kameshima

2595

Permselectivity of Anions through Gel Membranes Prepared from N-isopropylacrylamide and Poly(vinyl alcohol)
Tomoko Yamakawa, Chika Miyamoto, Shinya Ishida, Mitsuru Higa and Koji Matsusaki

2599

CO 2 Selective Membranes Prepared from Hyper-branched Graft Polymers by Atom Transfer Radical
Polymerization ……………………………………………………………………………………………………………………………
Mitsuru Higa, Satsuki Egashira and Yukiko Fujino

2603

Preparation and Characterization of Temperature-responsive Gel Actuators by in situ Polymerization of
N-isopropylacrylamide and Poly (vinyl alcohol) …………………………………………………………………………………
Mitsuru Higa, Yohei Kurose, Ayumu Matsuoka, Kentaro Hatemura, Koji Matsusaki and Nobutaka Endo

2607

Synthesis and Characterization of a Hyper-branched Graft Polymer for Solid Polymer Electrolytes …………………
Mitsuru Higa, Taihei Koumoto, Ryousuke Kitani, Nobutaka Endo and Koji Matsusaki

2611

Characterization of Polyelectrolyte Complex Films Composed of Cys-PEOMA and Chitosan as a Drug Carrier …
T. Tsurumi, T. Yoshizawa, Y. Shin-ya, K. J. Hong, S. Hirose and T. Kajiuchi

2615

Preparation and Characterization of Modified Polyvinylalcohol-hydroxyapatite Composites …………………………
Hiromori Tsutsumi, Yoshiaki Shibasaki, Kenjiro Onimura and Tsutomu Oishi

2619

Transparent Hydroxyapatite and β-Tricalcium Phosphate Ceramics Prepared by Spark Plasma Sintering …………
Daisuke Kawagoe, Daishiro Nomura, Hirotaka Fujimori, Seishi Goto, Yan-Sheng Kang and Koji Ioku

2623

Analysis of Inorganic Substance Deposited In vivo ………………………………………………………………………………
Giichiro Kawachi, Yoji Tamura, Hirotaka Fujimori, Seishi Goto and Koji Ioku

2627

Preparation and Stimuli-Sensitive Characterization of Polyelectrolyte Complex Films Derived from Chitosan andPolyalkyleneoxide-Maleic Acid Copolymer …………………………………………………………………………………………
Toru Yoshizawa, Yoshitune Shin-ya, K. J. Hong and Toshio Kajiuchi

2631

Chemical Modification of Anion-Exchange Resin with Chrome Azurol S ……………………………………………………
Koji Matsusaki, Naohiro Iwatani, Mitsuru Higa and Nobutaka Endo

2635

Surface-Resistance- Type Humidity Sensor Based on Sulfonated Polyimide ………………………………………………
Masahiro Ueda, Kazumasa Nakamura, Yan Yin, Kazuhiro Tanaka, Hidetoshi Kita and Ken-ichi Okamoto

2639

Collection of Trace Ions by Use of Conducting Polymer Colloid ………………………………………………………………
Nobutaka Endo, Shinji Takaoka, Mitsuru Higa and Koji Matsusaki

2643

Theoretical Study on Mechanism of Asymmetric Anionic Polymerization of N-Substituted Maleimide by using a Zn
Complex with a Chiral Bisoxazoline ligand …………………………………………………………………………………………
Hidetoshi Ohno, Kazuaki Yoshimura and Kenzi Hori

2647

Inner Surface Modification of a Polymer Bottle by Plasma-based Ion Implantation ………………………………………
N. Sakudo, H. Endo, R. Yoneda, Y. Ohmura and N. Ikenaga

2651

Construction and Characterization of Solid-state Ion Flux Controller ………………………………………………………
Hiromori Tsutsumi, Toru Kitagawa, Kenjiro Onimura and Tsutomu Oishi

2655

A Novel Fabrication Technique of Porous Hydroxyapatite Ceramics …………………………………………………………
Norio Yamaguchi, Ryota Isobe and Osamu Ohashi

2659

Biocompatibility of Hydroxyapatite Films Formed on Various Metals by a Surface Treatment Using an Enzyme
Reaction ……………………………………………………………………………………………………………………………………
J. Nozaki, H. Uchida, K. Itatani, I. Okada, S. Koda, M. Aizawa, M. Matsumoto, H. Matsumoto and Y. Toyama

2663

Transport Properties of Ions through pH Memorizable Charged Membranes Prepared from Poly (vinyl alcohol)
Mitsuru Higa, Tomoichi Watabe and Koji Matsusaki

2667

In vitro Platelet Adhesion and Protein Adsorption of Biomedical Implant Modified with Polysaccharide ……………
Tomohiko Yoshioka, Kanji Tsuru, Satoshi Hayakawa and Akiyoshi Osaka

2671

Novel Techniques of Hydroxyapatite Coating on Titanium Utilizing Hydrothermal Hot-pressing ……………………
Takamasa Onoki, Kazuyuki Hosoi and Toshiyuki Hashida

2675

Simulation of Permselectivity of Ions with Different Valence through a Charged Membrane …………………………
Mitsuru Higa and Tomoko Yamakawa

2679

SBF Evaluation of Bioactivity of Polarized Ceramic Apatite Solid Solutions ………………………………………………
Keiichirou Shinohara, Satoshi Nakamura, Nobuo Kieda and Kimihiro Yamashita

2683

Symposium of Photocatalysis
Preface ………………………………………………………………………………………………………………………………………

2687

Change in the Concentration of Dissolved Oxygen in the Suspensions of Anatase and Rutile TiO2 Powders under
UV Irradiation and Their Photoluminescence Properties ………………………………………………………………………
Hiromitsu Nakajima, Toshiyuki Mori and Mamoru Watanabe

2689

Photo-oxidation Property of Nitrogen and Fluorine Co-doped SrTiO3 Made by Mechanochemical Method ………
Jinshu Wang, Shu Yin, Masakazu Komatsu, Qiwu Zhang, Fumio Saito and Tsugio Sato

2693

Effect of Noble Metal Nanoparticles on Photocatalytic Activity of TiO2 ………………………………………………………
A. M. Orlov, D. A. Jefferson and R. M. Lambert

2697

Preparation of Highly Oriented TiO2/ZnO Films by Pulsed Laser Deposition ………………………………………………
S. Yamamoto, Y. Choi, T. Umebayashi and M. Yoshikawa

2701

Theoretical Investigation of the Photocatalysis Processes for Several Chlorinous Organic Compounds on the
Anatase TiO2 Surface using an Accelerated Quantum Chemical Molecular Dynamics Method …………………………
Chen Lv, Xiaojing Wang, Tomonori Kusagaya, Akira Endou, Momoji Kubo, Akira Imamura and Akira Miyamoto

2705

Photocatalytic Activity of TiO2 Thin Films Prepared by the Sol-Gel Method : Primary Particle Size as a
Predominant Factor ……………………………………………………………………………………………………………………
H. -J. Nam, T. Amemiya, M. Murabayashi and K. Itoh

2709

Air Purification Using Titanium Functionally Graded Materials Produced by Progressive Lamination Method …
Yoshihisa Uchida, Kumiko Kato, Shuntaro Higa, Niichi Hayashi and Yoshiyuki Uchida

2713

Doped Nanoparticles for Photocatalytically Active Surfaces ……………………………………………………………………
H. Schmidt, M. Akarsu, M. Naumann and Th. S. Müller

2717

Symposium of Advanced Thermoelectric Materials for Environment-Friendly Energy Systems
Preface ………………………………………………………………………………………………………………………………………

2725

Enhanced Thermoelectric Performance of ZnO-based Oxide Materials ……………………………………………………
Michitaka Ohtaki, Shinichirou Shige and Sayaka Maehara

2727

Thermoelectric Properties of Ni-based Oxides ……………………………………………………………………………………
R. Funahashi, M. Mikami, S. Urata, T. Kouuchi, K. Mizuno and K. Chong2731

Successive Magnetic Transitions in Thermoelectric Layered Cobaltite, [Ca2CoO3]0.62[CoO2] …………………………
J. Sugiyama, J. H. Brewer, E. J. Ansaldo, H. Itahara, K. Dohmae, Y. Seno, C. Xia and T. Tani

2737

Magnetic Field Effects on Thermoelectric Properties of [(Bi,Pb)2Sr2O4]yCoO2 Single Crystals …………………………
T. Fujii and I. Terasaki

2741

Magnetism in Na0.75CoO2 Investigated by µSR ……………………………………………………………………………………
J. Sugiyama, H. Itahara, J. H. Brewer, E. J. Ansaldo, T. Motohashi, M. Karppinen and H. Yamauchi

2745

Thermoelectric Misfit-Layered Cobalt Oxides(I): Oxygen Nonstoichiometry and Cobalt Valence ……………………
Y. Motira, K. Sakai, I. Asako, T. Konno, T. Motohashi, S. Sugihara, T. Fujii, I. Terasaki, H. Yamauchi and
M. Karppinen

2749

Thermoelectric Misfit-Layered Cobalt Oxides(Ⅱ): Properties of Oxygen-Controlled Samples of Ca3Co3.95O9+δ ……
Teruki Motohashi, Takuya Konno, Toyomi Aoyama, Maarit Karppinen and Hisao Yamauchi

2753

Physics in the Hexagonal CoO2 Block in NaCo2O4 ………………………………………………………………………………
Ichiro Terasaki

2757

Theory of The Nonparabolic Effects of The Thermoelectric Properties ………………………………………………………
Mitsuru Matsuura, Kenji Koga, Kazunori Oshiro and Koji Akai

2763

Thermoelectric Property of Ladder-type Oxide [(Sr1-xCax)2CuO3] γ [Cu1-yCoyO2] …………………………………………
Shunsuke Tayama, Yuzuru Miyazaki and Tsuyoshi Kajitani

2767

High Temperature Thermoelectric Properties of the One-Dimensional Ca3Co2O6 Compound …………………………
M. Mikami and R. Funahashi

2773

Thermoelectric Properties of (R, Sr)CoO3 (R=La, Pr, Nd, Sm) …………………………………………………………………
Tsuyoshi Takami, Hiroshi Ikuta and Uichiro Mizutani

2777

Thermoelectric Properties of Hot-Pressed GaN and InN ………………………………………………………………………
Atsushi Yamamoto and Shigeo Yamaguchi

2781

Transport Properties of Undoped and Sb-doped Half-Heusler Compounds NbCoSn ……………………………………
Yasuhiro Ono, Shingo Inayama, Satoshi Yotsuhashi, Hideaki Adachi, Yuzuru Miyazaki and Tsuyoshi Kajitani

2785

Thermoelectric Properties of Bi-Te Based Materials Prepared by Bulk Mechanical Alloying and Shear Extrusion
Sang Seok Kim, Shigeo Yamamoto and Tatsuhiko Aizawa

2789

Thermoelectric Properties of Ba8PdxGe46-x Clathrate Compounds ……………………………………………………………
Masahiro Hokazono, Masaki Kawamura, Hiroaki Anno and Kakuei Matsubara

2793

Thermoelectric Properties of AlPdRe Quasicrystalline Thin Films ……………………………………………………………
Kazuhiro Kurihara, Kenji Kawaguchi, Naoto Koshizaki and Kaoru Kimura

2797

The Study for the Annealing Effects on the Si and Ge Amorphous Thin Film by using Photoacoustic Spectroscopy
Akiko Miyata, Yoichi Okamoto, Hiroaki Takiguchi, Toshio Kawahara and Jun Morimoto

2801

Thermoelectric Properties of MnSi〜1.73 Produced by Cold Pressing and Sintering ………………………………………
T. Iizuka, M. Kato, I.J. Ohsugi, T. Kojima, I.A. Nishida, H. Kohri, I. Shiota and T. Suzuki

2805

Crystal Structure, Electric and Magnetic Properties in NaxCoO2 ………………………………………………………………
K. Nagasawa and H. Nakatsugawa

2809

Thermoelectric Properties of Y2Mo2O7-based Pyrochlore Solid Solutions …………………………………………………
Hidero Unuma, Satoshi Kawasumi, Norio Kawamura, Kunio Watanabe and Michio Sugawara

2813

Negative Thermopower Induced by Entropy Backflow …………………………………………………………………………
W. Kobayashi, I. Terasaki, M. Mikami and R. Funahashi

2817

Thermoelectric Properties of Ca-doped γ-NaxCoO2 ………………………………………………………………………………
Yasuhiro Ono, Nobuhiko Kato, Yuzuru Miyazaki and Tsuyoshi Kajitani

2821

Thermoelectric Properties of Several Strontium Ferrites, SrFe12O19, SrFeO3-x and Sr4Fe6O13+x ………………………
Shin Nishiyama, Junichi Nagaoka and Takeo Hattori

2825

Synthesis and Thermoelectric Properties of Doped NaCo2O4 with Transition Metal Cations ……………………………
Yoshihiro Nojiri and Michitaka Ohtaki

2829

Characterization of Post-Annealed CoSb3 Grown by Vertical Bridgman Method …………………………………………
S. Furuyama, T. Iida, M. Noda, S. Matsui, M. Ota and Y. Takanashi

2833

Effect of Filling Fraction on Thermoelectric Properties of YbyFe4-xNixSb12 Compounds …………………………………
Hiroaki Anno and Kakuei Matsubara

2837

Thermoelectric Properties of n-type Ni-doped CoSb3 Semiconductors ………………………………………………………
Machiko Wakatsuki, Hiroyuki Kitagawa, Hisanori Nagaoka and Yasutoshi Noda

2841

Thermoelectric Power of Kondo Insulators and Kelvin’s Relations at Low Temperatures ………………………………
Tetsuro Sano

2845

Magnetic Field Effect for Thermoelectric Conversion : A Proposal for Nernst-Seebeck Element ………………………
Shin Yamamoto, Makoto Hamabe, Hideaki Takahashi, Satarou Yamaguchi, Haruhiko Okumura, Ichiro Yonenaga,
Takako Sasaki and Kazuo Watanabe

2849

Symposium of Nano-medical Materials I -Bioinspired Materials and SystemsPreface ………………………………………………………………………………………………………………………………………

2853

Improved Intracellular Uptake of Self-Targeting Nanoparticles to Canter Cells by Combination of Non-Specificand Receptor Mediated Endocytosis …………………………………………………………………………………………………
Yong Zhang and Jing Zhang

2855

Bone Formation by Cryopreserved Human Bone Marrow-Derived Mesenchymal Stem Cells In Vitro –Preliminary
Results using Human Marrow Cells from Two Cases- ……………………………………………………………………………
Motohiro Hirose, Noriko Kotobuki, Hiroko Machida, Shigeyuki Kitamura, Yoshinori Takakura and Hajime Ohgushi

2859

Effects of Bioconjugation with Novel Phospholipid Polymers on Enzymatic Activity and Stability ……………………
Daisuke Miyamoto, Junji Watanabe and Kazuhiko Ishihara

2863

Development of the Tendon Chitosan Tube and its Application to Nerve Conduit …………………………………………
S. Itoh, I. Yamaguchi, K. Takakuda, H. Kobayashi, K. Shinomiya and J. Tanaka

2867

Physicochemical Properties and Bio-degradation of Segmented Polyurethane and Poly(urethane-urea) Derived
from Lysine-Based Diisocyanate ……………………………………………………………………………………………………
Tomohiro Yamaguchi, Hideyuki Otsuka, Satoru Kidoaki, Takehisa Matsuda and Atsushi Takahara

2873

Colloidal Chitosan Nanospheres ………………………………………………………………………………………………………
Rangrong Yoksan, Mitsuru Akashi and Suwabun Chirachanchai

2877

Nano-Hydroxyapatite/Collagen/PLA bone Scaffold Reinforced by Chitosan Fibres ………………………………………
Q. L. Feng and X. M. Li

2881

Symposium of Nano-Medical Materials II –BioceramicsPreface ………………………………………………………………………………………………………………………………………

2885

Bioactivated Nano-Space in the Vicinity of Polarized Hydroxyapatite Surface in SBF ……………………………………
Kimihiro Yamashita, Satoshi Nakamura, Masashi Tanaka, Toshinori Okura and Hideki Monma

2887

Hydroxyapatite Formation on CaSiO3 Ceramics in Simulated Body Fluid …………………………………………………
Kiyoshi Okada, Punnama Siriphannon, Yoshikazu Kameshima and Shigeo Hayashi

2891

Collagen Immobilized PVA Hydrogel-Hydroxyapatite Composites for Keratoprosthesis ………………………………
Hisatoshi Kobayashi, Masafumi Kato, Atsushi Matsuda, Tetsushi Taguchi, Kazunori Kataoka and Junzo Tanaka

2897

Novel Hydrogels of Malic Acid and Zinc; Their Synthesis and Characterization …………………………………………
Norifumi Azuma, Toshiyuki Ikoma, Akiyoshi Osaka and Junzo Tanaka

2901

Concept of Functionally Graded Apatites and Their Application to Biomaterials …………………………………………
Masayuki Okazaki

2905

Preparation of Hydroxyapatite/Chondroitin Sulfate Nanocomposite and its Spherical Porous Microparticle ………
Toshiyuki Ikoma, Norifumi Azuma and Junzo Tanaka

2911

Role of Electron Beam Irradiation-Induced Surface Nanostructure Changes on the Multi-functional Properties ofCeramics ……………………………………………………………………………………………………………………………………
Yoshitake Nishi and Kazuya Oguri

2915

Construction of Interconnected Pore Network Using Hydroxyapatite Small Components ………………………………
Kay Teraoka, Yoshiyuki Yokogawa and Tetsuya Kameyama

2919

Control of Bioresorption of Porous α –Tricalcium Phosphate by Coating with Silk Sericin ……………………………
Toshiki Miyazaki, Chikara Ohtsuki, Akari Takeuchi, Masanobu Kamitakahara, Shin-ichi Ogata, Masao Tanihara,
Hiromi Tanaka, Yoshiaki Furutani and Hisao Kinoshita

2923

Development of Bioactive Paste with Improved Handling ………………………………………………………………………
Chikara Ohtsuki, Toshiki Miyazaki, Hirofumi Inada, Masanobu Kamitakahara and Masao Tanihara

2927

GD-OES Analysis of the Interface between Titanium and Hydroxyapatite Ceramics Produced by Hydrothermal
Hot-pressing Method ……………………………………………………………………………………………………………………
Takamasa Onoki, Kazuyuki Hosoi and Toshiyuki Hashida

2929

Surface Modification of Bioactive Calcium Pyrophosphate Glass-Ceramics ………………………………………………
Toshihiro Kasuga and Masayuki Nogami

2933

Osteoconductive Mechanism of Electrically Poled Hydroxyapatite Ceramics ………………………………………………
Satoshi Nakamura, Miho Nakamura, Takayuki Kobayashi, Yasutaka Sekijima and Kimihiro Yamashita

2939

Bone Regeneration with Organic/Inorganic Composite Materials ……………………………………………………………
Kazuo Takakuda, Yoshihisa Koyama, Hiroko Matsumoto, Noriaki Shirahama, Kazumi Akita, Daisuke Shoji,
Tesuro Ogawa, Masanori Kikuchi and Junzo Tanaka

2943