CONTENTS

Transactions of Materials Research Society of Japan
Volume 28 Number 1 March 2003

Symposium of Fabrication and Characterization of Organic Ultrathin Films
Preface ………………………………………………………………………………………………………………

1

Optical Properties of Polyelectrolyte Multilayers Fabricated by Layer-by-layer Adsorption Processes ……
Shiro Fujita, Toshiki Mima, Jin Ho Kim and Seimei Shiratori

3Foam Morphology as a Higher Order Structure Model of a Layer System ……………………………………
Toshio Ishii, Eiji Hatta and Koichi Mukasa

7Formation and Structure of Organized Molecular Films for Fluorinated Comb Polymers with Various
Chain Lengths ……………………………………………………………………………………………………
Atsuhiro Fujimori, Hiroo Nakahara, Eisuke Ito, Masahiko Hara, Kaname Kanai, Yukio Ouchi andKazuhiko Seki
Photopolymerization and Structural Characterization of Organized Molecular Films of Long-Chain
Diynoic Acid Derivative by Using NEXAFS Spectroscopy ……………………………………………………
Mikako Ishitsuka, Atsuhiro Fujimori, Hiroo Nakahara, Eisuke Ito, Masahiko Hara, Kaname Kanai,Yukio Ouchi and Kazuhiko Seki1115AFM Study of Discrete Surface Functional Group Fabricated by Langmuir-Blodgett Technique …………
Masakazu Nakamura, Kazuhiro Kudo, Aya Shimizu, Youichi Nakayama and Yoshikatsu Nagasawa

19

Fabrication and Evaluation of Nanostructured Conducting Polymer Films …………………………………
Mitsuyoshi Onoda and Kazuya Tada

23

Structural Characterization of Langmuir-Blodgett Films of the Dioctadecyldimethylammonium-Au(dmit)2Salt Studied by Infrared Spectroscopy and Atomic Force Microscopy ………………………………………
Shin-ichi Morita, Yasuhiro F. Miura, Keiichi Ikegami and Michio Sugi

27

Formation of J-Aggregates of an Alkylated Merocyanine Dye Assisted by a Fatty Acid Observed at an
Air-Water Interface ………………………………………………………………………………………………
Keiichi Ikegami

31

Influence of Packing in LB Films on Photoisomerization of Azobenzene Derivative …………………………
Takashi Okuhara, Masashi Takahashi and Koichi Kobayashi

35

Excitations of Multiple Surface Plasmons and Emission Light in Nanostructured LB Films ………………
Futao Kaneko, Toshiharu Sato, Mitsuru Terakado, Kazunari Shinbo, Keizo Kato and Takashi Wakamatsu

39

Evaluation of Structure and Emission Property of Alternate Self-Assembled Ultrathin Films Containing
Azo-Dye by Surface Plasmon Excitation Method ………………………………………………………………
Keizo Kato, Junichi Kawashima, Kazunari Shinbo, Futao Kaneko, Akira Baba and Rigoberto C. Advincula

43

Structure and Orientation Control of Organopolysilane Thin Film Prepared by Vacuum Evaporation
Technique …………………………………………………………………………………………………………
Shoji Furukawa and Hidetaka Ohta

47

Molecular Orientation of Langmuir-Blodgett Films of AlkylDCNQI-Cu and AlkylTCNQ-Cu Complexes
Keiichi Ikegami, Tapas Pal Majumder, Minbo Lan and Takayoshi Nakamura

51

The Structure of the Dye Containing LB Films Investigated by Infrared Spectroscopy ……………………
Yoshiaki Hirano, Shin-ichi Morita, Yasuhiro F. Miura and Michio Sugi

55

Development of LB Molecules Orientation Technology by Electric Field and Ultrasonic Vibration ………
Sadao Uegusa, Masaya Ikeda and Tsutomu Miyasaka

59

Fabrication and Electrochemical Properties of Water-soluble Phthalocyanine Layer-by-layer Deposited

63Films ………………………………………………………………………………………………………………
Kazunari Shinbo, Ken Onishi, Shunsuke Miyabayashi, Keizo Kato, Futao Kaneko andRigoberto C. Advincula

Symposium of Advanced Materials for Fuel Cells
Preface ………………………………………………………………………………………………………………

67

High Temperature Proton Conducting Polymer Electrolytes based on Hydrocarbon-Silicate MolecularHybrids ……………………………………………………………………………………………………………
I. Honma, H. Nakajima, O. Nishikawa, T. Sugimoto and S. Nomura

69Synthesis and Proton Conductivity of Novel Sulfonated Polyimides …………………………………………
Ken-ichi Okamoto, Tatsuya Watari, Yan Yin, Xiaoxia Guo, Jianhua Fang, Kazuhiro Tanaka andHidetoshi Kita.

73

Test Fuel Cell using Hydrogen Storage Alloy ……………………………………………………………………
Shigeru Kachi, Yoshitake Nishi, Shingo Tsubuteishi and Haru-Hisa Uchida77

Preparation of Carbon Supported Pt and Pt alloys Catalysts by Alcohol Reduction For Polymer Electrolyte
Fuel Cells …………………………………………………………………………………………………………
Taeyoon Kim and Koichi Kobayashi

81

Symposium of Domain Structure Related Properties and Materials
Preface ………………………………………………………………………………………………………………

85

A Theory of Ferroelectric 90 Degree Domain Wall ………………………………………………………………
Yoshihiro Ishibashi

87

Colossal Response Induced by Hetero-Structure Fluctuation …………………………………………………
Yoshiaki Uesu, Kei Ishikawa and Yasusada Yamada

91

Sintering and Dielectric Characteristics of Tungsten Bronze Structure Ferroelectric SrxBa1-xNb2O6
Ceramics ……………………………………………………………………………………………………………
Myoung-Sup Kim, Shin-Il Kang, Joon-Hyung Lee, Jeong-Joo Kim, Hee Young Lee and Sang-Hee Cho

97

Phase Transition and Nonliner Susceptibility in SrTi18O3 ………………………………………………………
Mitsuru Itoh, Wolfgang Kleeman, Jan Dec, Ruiping Wang, Miho Narahara and Toru Kyomen

105

Tbit/inch2 Ferroelectric Data Storage Based on Scanning Nonlinear Dielectric Microscopy ………………
Yasuo Cho, Yoshiomi Hiranaga, Kenjiro Fujimoto, Atsushi Onoe, Kazuya Terabe and Kenji Kitamura

109Enhanced Polarization Properties by the Introduction of Cation Vacancies in BaBi4Ti4O15 Polycrystals
Yuji Noguchi, Yu Goshima and Masaru Miyayama

113

Degradation of PLZT Capacitors at Elevated Temperature in Deuterium Gas ………………………………
Jeffrey S. Cross and Mineharu Tsukada

117

Dielectric and Piezoelectric Properties of Pb(Zr0.53Ti0.47)O3-Pb(Mg1/3Nb2/3)O3 Thin Films with Preferred
Orientation …………………………………………………………………………………………………………
Hisao Suzuki, Akira Urayama, Toshitaka Ota and Minoru TakahashiOrientation Dependence of Domain Behaviors in Tetragonal Lead Zirconate Titanate Films ………………
Desheng Fu, Kazumi Kato and Hisao Suzuki
Crystal Orientation Dependence and Aging of Giant Electromechanical Coupling Factor of k31 Mode andPiezoelectric d31 Constant in Pb[(Zn1/3Nb2/3)0.91Ti0.09]O3 Single Crystals ………………………………………
Toshio Ogawa and Yoshiki Numamoto
Elastic Property Distribution of Al2O3 Film Fabricated By Aerosol Deposition Method with Nano-Scale121125129

Resolution …………………………………………………………………………………………………………
Hisato Ogiso, Mikiko Yoshida and Jun Akedo

133

Low Temperature Heat Capacity and Dielectric Relaxation in CaCu3Ti4O12 Ceramics ……………………
Yosuke Moriya, Hitoshi Kawaji, Takeo Tojo and Tooru Atake

137

Electrical Characteristics and Dynamics Adsorbed Argon Domain System on TiO2 Surface due toAngle-Resolved Transmission Current Spectroscopy ……………………………………………………………
K. Mizusako, K. Miyagishi, S. Yoneda, Y. Furasato, N. Terada and K. Obara

141

Domain-Wall Observation in Pb(Zn1/3Nb2/3)O3-PbTiO3 Solid Solutions By AFM ……………………………
M. Iwata, K. Katsuraya, M. Maeda, I. Suzuki, Naohiko Yasuda, Y. Naruse, H. Orihara and Y. Ishibashi

145

Influence of Temperature on Nonlinear Piezoelectricity in a Piezoelectric Ceramic …………………………
Keisuke Ishii, Shinjiro Tashiro and Kunihiro Nagata

149

Crystallization of Bi4-xLaxTi3O12 Films Prepared by the Sol-Gel Technique on IrO2/Ir Multi-Layered
Electrode ……………………………………………………………………………………………………………
Naoki Sugita and Eisuke Tokumitsu
Characterization of PLZT Thick Film Prepared by MOCVD …………………………………………………
Yoshihisa Honda, Shintaro Yokoyama and Hiroshi Funakubo
Domain Observation In Pb (In1/2Nb1/2)O3-PbTiO3 Solid Solutions Near Morphotropic Phase Boundary byPolarizing Microscope ……………………………………………………………………………………………
N. Yasuda, N. Uemura, N. Osaki, H. Ohwa, M. Iwata and Y. Ishibashi

153

157

161

Dielectric and Piezoelectric Properties of Tetragonal PMNT 65/35 Piezoelectric Single Crystal ……………
Kazuhiro Itsumi, Yasuharu Hosono, Yohachi Yamashita and Niels Nijhof

165

High-Frequency Oscillator Using High - Performance Single-Crystal PZNT91/9 ……………………………
Kouchi Harada, Yasuharu Hosono, Tsuyoshi Kobayashi and Yohachi Yamashita

169

Growth of Lanthanum-substituted Bismuth Titanate Single Crystals and Observation of their Domain
Structure ……………………………………………………………………………………………………………
Masayuki Soga, Yuji Noguchi and Masaru Miyayama

173

Imaging and Engineering the Nanoscale-domain Structure of a Sr0.61 Ba0.39Nb2O6 Crystal …………………
Shinji Higuchi, Kazuya Terabe, Masaru Nakamura, Shunji Takekawa, Yoshihiko Gotoh and Kenji Kitamura

177

Synthesis and Characterization of Ba3MeGa3Si2O14 (Me=Nb5+, Ta5+) Crystal ………………………………
Hiroaki Takeda, Takashi Nishida, Soichiro Okamura and Tadashi Shiosaki

181

Differential Vector Poling for Artificial Domain Control of KNbO3 Single Crystals …………………………
Junji Hirohashi, Kazuhiro Yamada, Hiroyuki Kamio and Shiro Shichijyo

185

Domain Observation of Pb(Mg1/3Nb2/3)O3-PbTiO3 Single Crystals in a Vacuum by Contact ResonancePiezoresponse Force Microscopy …………………………………………………………………………………
Hirotake Okino, Takuya Matsushita and Takashi Yamamto
Computer Simulation of P-E Hysteresis of Ferroelectrics ………………………………………………………
Yoichi Kubota, Hirofumi Kakemoto, Satoshi Wada and Takaaki Tsutumi
Growth of Bismuth Layer-Structured Ferroelectrics BaBi4Ti4O15 Single Crystals and Their Piezoelectric
Properties …………………………………………………………………………………………………………
Hiroshi Sawase, Hirofumi Kakemoto, Satoshi Wada and Takaaki Tsurumi

189

193

197

Single-Domain Treatment of Potassium Niobate Single Crystal and Their Piezoelectric Properties ………
Kazuma Muraoka, Hirofumi Kakemoto, Takaaki Tsurumi, Satoshi Wada and Hirohiko Kumagai

201

Piezoelectric Properties of Potassium Niobate Single Crystals with Various Domain Configurations ………
Satoshi Wada, Kazuma Muraoka, Hirofumi Kakemoto, Takaaki Tsurumi and Hirohiko Kumagai205