The M a te rials R esea rch S o ciety o f Ja p anTransactions of the Materials Research Society of Japan
Volume 29 Number 2 March 2004

CONTENTS
Symposium of Nanostructure CoatingPreface ………………………………………………………………………………………………………………………………………

375

Microstructure and Sintering Behavior of Hafnia-based Thermal Barrier Coating by EB-PVD Process ………………
Kazuhide Matsumoto, Yoshiyasu Itoh, Yutaka Ishiwata and Takeharu Kato

377

A New Laser CVD Process for Thermal Barrier Coatings ………………………………………………………………………
Takashi Goto, Teiichi Kimura and Hidetoshi Miyazaki

381

Thermal Conductivity of Yttria-stabilized Zirconia Films Measured by a Laser-heating AC Method …………………
Teiichi Kimura and Takashi Goto

385

Microstructure of YSZ Films Prepared by MOCVD ………………………………………………………………………………
Rong Tu, Teiichi Kimura and Takashi Goto

389

New Oxide Compounds for Thermal Barrier Coating ……………………………………………………………………………
I. Nagano, K. Akiyama, M. Shida, S. Ohta and Y. Murakami

393

Microstructure Modification of YSZ Layers Prepared by EB-PVD ……………………………………………………………
Norio Yamaguchi, Kazushige Kimura and Hideaki Matsubara

397

Alumina-Zirconia Composite Coating Fabricated from Nano-size Powders …………………………………………………
Satoshi Sodeoka, Masato Suzuki and Takahiro Inoue

401

Alumina-besed Nano Composite Coating Prepared by Plasma Spray …………………………………………………………
Masato Suzuki, Satoshi Sodeoka and Takahiro Inoue

405

Design of Thin Films with Tailored Nano-morphology ……………………………………………………………………………
Motofumi Suzuki, Kenji Kimura and Yasunori Taga

409

The Effect of Processing Temperature on the Columnar Structure of ZrO2-4mol%Y2O3 Thermal Barrier Coatings
Fabricated by Electron Beam Physical Vapor Deposition …………………………………………………………………………
Kunihiko Wada, Norio Yamaguchi and Hideaki Matsubara

413

Analysis of Thermal Conductivity and Thermal Diffusivity of EB-PVD Coating Materials ………………………………
Byung-Koog Jang and Hideaki Matsubara

417

TEM and XPS Analysis of (Ti,Cr)CN/DLC Superhard Nanocomposite Coatings ……………………………………………
Yongqing Fu, Sam Zhang and Hejun Du

421

Stress Depth Profile in Ceramic Films on Different Interfacial Layers ………………………………………………………
Shin Tsuchiya, Takatoshi Oshika, Fumio Tsushima and Akio Nishiyama

425

Symposium of Scanning Probe Nanotechnology
Preface ………………………………………………………………………………………………………………………………………

429

Nanolithography and Nanochemistry Utilizing Scanning Probe Techniques: Directed Self-Assembly of
Sub-Micrometer-Sized Structures by Scanning Probe Lithography Defined Templates ……………………………………
Daan Wouters, Jordy P. E. Sturms and Ulrich S. Schubert

431

Self-Organized Nanostructure Formation on High-Index Si Surfaces Induced by Ga ………………………………………
Hitoshi Nakahara, Hidetoshi Suzuki and Ayahiko Ichimiya

435

Designer DNA: Design and Synthesis of DNA Nanostructures …………………………………………………………………
Rika Mizuno, Hirotaka Haruta, Takashi Morii, Takao Okada, Kenichi Nakashi, Takeshi Asakawa and Hayashi Kenshi

439

UHV-STM/STS Studies of Lanthanum Endohedral Metallofullerenes …………………………………………………………
Atsushi Taninaka, Haruhito Kato, Kazuhiro Shino, Toshiki Sugai, Seiji Heike, Yasuhiko Terada, Tomihiro Hasizumeand Hisanori Shinohara

443

Symposium of Preparation and Characterization of Nanohelical / Spiral Substances
Preface ………………………………………………………………………………………………………………………………………

447

Microstructure of Carbon Coils …………………………………………………………………………………………………………
T. Hashishin, H. Iwanaga, Y. Furuya, S. Motojima and Y. Hishikawa

449

Electric and Mechanical Properties of Carbon Coils ………………………………………………………………………………
T. Hashishin, H. Iwanaga, S. Motojima and Y. Hishikawa

453

Preparation and Properties of Super-Elastic Carbon Microcoils by Ni-catalyzed CVD ……………………………………
S. Yang, H. Aoki, X. Chen and S. Motojima

457

Electromagentic Wave Absorption Properties of Carbon Microcoils/Nanocoils ………………………………………………
S. Motojima, D. Nagahara, T. Kuzuya and Y. Hishikawa

461

Preparation of Ceramics/Carbon Microcoils Composites using Carbon Microcoils as a Template ………………………
S. Motojima, T. Muraki, T. Suzuki, S. Yang, X. Chen, T. Hashishin, H. Iwanaga and Y. Hishikawa

465

Structure of Carbon Coils Observed by Neutron Diffraction ……………………………………………………………………
T. Fukunaga, K. Itoh, T. Kuzuya, Y. Hishikawa and S. Motojima

469

Graphite Nanofibers-A Unique Catalyst Support Media …………………………………………………………………………
N. M. Rodriguez, J. Ma and T. K. Baker

473

Cosmo-mimetic Helical/Spiral Materials and Their Potential Applications ……………………………………………………
S. Motojima, X. Chen, S. Yang, H. Iwanaga, Y. Hayashi, C. Kuzuya and Y. Hishikawa

477

Morphologies, Microstructure and Growth Mechanism of Carbon Nanocoils over Stainless Steel Catalysts …………
S. Yang, X. Chen, T. Hashishin, H. Iwanaga and S. Motojima

481

Preparation and Morphologies of Elastic Carbon Microcoils/nanocoils by Various Catalysts ……………………………
S. Yang, X. Chen and S. Motojima

485

Preparation of Carbon Microcoils/Nanocoils and Their Morphologies …………………………………………………………
S. Motojima, S. Yang, X. Chen, T. Muraki, K. Takeuchi and H. Iwanaga

489

Hydrogen Absorption of Carbon Micro Coils ………………………………………………………………………………………
Y. Furuya, K. Himeshima, Y. Inoue, S. Izumi, T. Hashishin, H. Iwanaga, S. Motojima and Y. Hishikawa

493

Effects of Mechanical Milling on Hydrogen Absorption Behavior of Carbon Micro Coils …………………………………
Y. Furuya, S. Izumi, M. Saikawa, K. Himeshima, T. Hashishin H. Iwanaga, S. Motojima and Y. Hishikawa

497

Synthesis of Twisted Carbon Nanofiber by Catalytic CVD Method ……………………………………………………………
Takashi Katsumata, Youhei Fujimura, Makoto Nagayama, Hiroshi Tabata, Hirofumi Takikawa, Yoshihiko Hibi,Takeki Sakakibara and Shigeo Itoh501

Car bo n Nano he lica l Coils a nd Nanotube s P re parati on Usi ng Me tal Cl uster s Synt he size d b y
Plasma-Gas-Condensation ………………………………………………………………………………………………………………
T. Hihara, S. Hirako, S. Motojima, Y. Yamamoto, T. Mizuno, M. Tanemura and K. Sumiyama

505

Morphology and Helical Growth Mechanism of Plasmalemma in Cotton Fiber ……………………………………………
Krakhmalev V. A. and Paiziev A. A.

509

Direct Observation of the Growth of Helical and Spiral Graphite Nanofibers ………………………………………………
R. Terry K. Baker

515

Vapor Phase Preparation of Carbon Nanocoils by Noble Metal Catalysts ……………………………………………………
S. Motojima, S. Hirako, T. Kuzaya and X. Chen

519

Symposium of Nano-Carbons and Related Structures
Preface ………………………………………………………………………………………………………………………………………

523

Solubilization of Carbon Nanotubes with a Pyrene-carrying Polymer in Water ……………………………………………
Naotoshi Nakashima, Shingo Okuzono, Yasuhiko Tomonari and Hiroto Murakami

525

Nanohorns Particle Including Metal-Nanocapsule Formed by Arc Discharge in Liquid Nitrogen ………………………
Noriaki Sano, Jun Nakano, Takeyuki Kikuchi and Tatsuo Kanki

529

Selective Formations of Fe-Included Carbon Nanocapsules and Nanotubes by Pyrolysis of Ferrocene …………………
Noriaki Sano, Hiroshi Akazawa, Matsuto Uehara, Takeyuki Kikuchi and Tatsuo Kanki

533

Liquid Phase Synthesis of the Nanowhiskers of Fullerene Derivatives …………………………………………………………
Kun’ichi Miyazawa, Tadahiko Mashino and Tadatomo Suga

537

Cap-Formation Process of a Carbon Nanotube ……………………………………………………………………………………
Ayumu Yasuda and Wataru Mizutani

541

Preparation of Fullerodendrimers by the Use of a Diels-Alder Reaction ………………………………………………………
Yutaka Takaguchi, Yasushi Yanagimoto, Sadao Tsuboi, Takatsugu Wakahara and Takeshi Akasaka545

Continuous Synthesis of Nanocarbons Using an Induction Plasma Reactor …………………………………………………
German Cota, Gervais Soucy, Andrej Huczko and Hubert Lange

549

Quasiparticle Band Structure of Carbon Nanotubes ………………………………………………………………………………
Takashi Miyake and Susumu Saito

553

Effect of Multi-Catalysts on Carbon Nanofiber Synthesis in CVD ………………………………………………………………
Beibei Chen, Youhei Fujimura, Takashi Katsumata, Hirofumi Takikawa, Yoshihiko Hibi, Tateki Sakakibara andShigeo Itoh559

Application of Density Functional Heaviside-Fermi Level Operator Formalism to Large Molecules and Nanoscale
Materials ……………………………………………………………………………………………………………………………………
Kin-ichi Masuda-Jindo, Vu Van Hung and Shuji Obata563

Symposium of Innovative Nanomaterials Using Ion Technology
Preface ………………………………………………………………………………………………………………………………………

567

Nanotech Net Working of New Materials using Pulsed Power Technology ……………………………………………………
Kiyoshi Yatsui, Hisayuki Suematsu, Chuhyun Cho, Makoto Hirai, Tsuneo Suzuki and Weihua Jiang

569

Improvement of Nerve-Cell Affinity of Silicone Rubber by Carbon-Negative-Ion Implantation and Its Application toRat Sciatic Nerve Regeneration …………………………………………………………………………………………………………
Hiroshi Tsuji, Masayoshi Izukawa, Yoshiyuki Utagawa, Ryosuke Ikeguchi, Ryosuke Kakinoki, Hiroko Sato,
Yasuhiro Gotoh and Junzo Ishikawa

575

Observation of Ion Implanted Materials Using 3D Electron Microscope ………………………………………………………
Tomohiro Kobayashi and Masaya Iwaki

581

Formation of Patterned Cellular Chips by Ion-beam Irradiation into Biodegradable Polymer …………………………
Tasuku Yotoriyama, Yoshiaki Suzuki, Takeo Tsukamoto and Masaya Iwaki

587

Ion Beam Irradiated ePTFE Remarkably Improving Fibrin Glue and Tissue Adhesion …………………………………
N. Takahashi, Y. Suzuki, H. Ujiie, T. Hori and M. Iwaki

591

Ion-Beam Modification of Coronary Stent Grafts …………………………………………………………………………………
Kenji Kyo, Yoshiaki Suzuki, Makoto Kaibara, Youichi Sugita, Shiho Nakamura, Akira Ogawa and Masaya Iwaki

595

Ion Implantation into ePTFE for Therapy of Broad-based Brain Aneurysms ………………………………………………
Y. Ono, T. Tsukamoto, N. Takahashi, T. Yotoriyama, Y. Suzuki, M. Iwaki, H. Ujiie and T. Hori

599

Effects of Ion Microbeam Irradiation on Silica Glass ………………………………………………………………………………
H. Nishikawa, K. Fukagawa, T. Yanagi, Y. Ohki, E. Watanabe, M. Oikawa, T. Kamiya and K. Arakawa

603

Iron Nano-Clusters in SiO2 Synthesized by Ion Implantation and the Magnetic Properties ………………………………
T. Moriwaki, N. Hayashi, I. Sakamoto, H. Tanoue, T. Toriyama and H. Wakabayashi

607

Size Distribution Control of Alpha-ion Nano-particles in Ion-implanted Al2O3 by Multi-step Implantation Combinedwith Moderate Annealing …………………………………………………………………………………………………………………
Shinichiro Mochizuki, Hidehiko Wakabayashi, Tamotsu Toriyama, Isao Sakamoto and Nobuyuki Hayashi

611

Magneto-optical Kerr Effect of Nickel Nanoparticles in SiO2 Fabricated by Negative-ion Implantation of 60 keV
H. Amekura, Y. Takeda, K. Kono and N. Kishimoto

615

Nonlinear Optical Response of Metal Nanoparticle Composites for Optical Applications …………………………………
Yoshihiko Takeda, Jing Lu, Nariaki Okubo, Kenichiro Kono, Oleg A. Plaksin and Naoki Kishimoto

619

Optical Transitions in Silica Glass During Heavy Ion Implantation ……………………………………………………………
Oleg A. Plaksin, Nariaki Okubo, Yoshihiko Takeda, Hiroshi Amekura, Kenichiro Kono, Naoki Umeda andNaoki Kishimoto

623

The Dielectric Constant and Crystalline Size of TiO2 Films Deposited on Silicon by Use of Ionized Oxygen …………
Katsuhiro Yokota, Kazuhiro Nakamura, Masami Ohnishi and Fumiyoshi Miyashita

627

Hardness of DLC Film Prepared Using Toluene Plasma and Hybrid Process of Plasma-based Ion Implantation andDeposition ……………………………………………………………………………………………………………………………………
Yoshihiro Oka, Yoshimi Nishimura, Kingo Azuma and Mitsuyasu Yatsuzuka

631

Effects of Si Content in DLC Films on Their Friction and Wear Properties …………………………………………………
M. Ikeyama, S. Nakao, Y. Miyagawa, K. Yoshimura and S. Miyagawa

635

Ion Beam Modification of Al-Doped ZnO Thin Films ………………………………………………………………………………
O. Fukuoka, N. Matsunami, T. Shimura, M. Tazawa and M. Sataka

639

Reaction between Si Substrates and High-Density, High-Temperature Zr Plasma Produced by Ion-Beam
Evaporation …………………………………………………………………………………………………………………………………
Takehiro Kishi, Tsuneo Suzuki, Hisayuki Suematsu, Weihua Jiang and Kiyoshi Yatsui

643

Elucidation of Droplet Development Process in Al Thin Films Prepared by Ion-Beam Evaporation ……………………
Hideki Kawahara, Hiroaki Shishido, Hideki Yanagi, Takeshi Yunogami, Tsuneo Suzuki, Hisayuki Suematsu,Weihua Jiang and Kiyoshi Yatsui

647

Enlargement of Compositionally Gradient Area in Si-Ge Thin Films Prepared by Ion-Beam Evaporation ……………
Takehiko Honzawa, Tsuneo Suzuki, Makoto Hirai, Takashi Yunogami, Hisayuki Suematsu, Weihua Jiang andKiyoshi Yatsui

651