Safety Data Sheet
1.Products and company identification
Product name

AQUA ROVAL Cold Galvanizing Compound (Powder)

Supplier NameSHANGHAI ROVAL ZINC RICH PAINT CORPORATION

Supplier Address

NO.393 Fenggong RD, Jiading Malu Shanghai, China

Telephone number+86-21-69156584

FAX+86-21-69156593

Emergency Telephone number+86-532-8388-9090

E-mailsh-info@roval.cn

Recommended use

Galvanizing Repair and Anti-corrosion of steel

Date of revision

Aug 1st, 2023

2. Hazards identification
2.1 Classification of the substance or mixture
ENVIRONMENTAL HAZARDS:Acute aquatic toxicity: Category 1
Chronic aquatic toxicity: Category 1(Note) GHS classification without description: Not classified/Classification not possible
2.2 Label elements

Signal word: WARNING
HAZARD STATEMENT
H410: Very toxic to aquatic life with long-lasting effects.
PRECAUTIONARY STATEMENT
Prevention
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response
P391: Collect spillage.
Disposal
P501: Dispose of contents/container in accordance with local/national regulation.

< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 1 of 93. Composition /information on ingredients
Mixture / Substance selection: Mixture
Chemical identity% WeighCAS number

Zinc

90~1007440-66-6

Zinc oxide

1~101314-13-2

4. First-aid measures
GENERAL ADVICE
Do not leave the victim unattended.
IF INHALED
If symptoms persist, call a physician.
If unconscious, place in recovery position and get medical attention immediately.
IF IN EYES
Remove contact lenses.
Flush eyes with water as a precaution. Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
IF SWALLOWED
Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
5. Fire-fighting measures
5.1 Suitable extinguishing media
Foam Carbon dioxide (CO2) Dry chemical
5.2 Unsuitable extinguishing media
Water High volume water jet.
5.3 Specific hazards during fire- fighting
May form explosive mixtures in air.
Original packaging can be wetted using water for extinguishing surrounding fire in well ventilated areas.
The product reacts with water and generates heat.
Isolate wetted packaging and powder from combustible mate- rials and dry powder and store in an excellent
ventilated area. Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in thepresence of an ignition source is a potential dust explosion hazard.
Warning: water promotes the spread of fire.
Do not allow run-off from firefighting to enter drains or water courses.
5.4 Hazardous combustion prod-products
No hazardous combustion products are known.
5.5 Specific extinguishing methods
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.Fireresidues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
5.6 Special protective equipment for firefighters
Wear self-contained breathing apparatus for firefighting if necessary< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 2 of 9

6. Accidental release measures
6.1 Personnel precautions, protective equipment and emergency procedures
Avoid dust formation.
6.2 Environmental precautions
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
6.3 Methods and materials for containment and cleaning up
Keep in suitable, closed containers for disposal.
6.4 Preventive measures for secondary accident
Collect spillage.
Prepare extinguishers before catching fire.
Stop leak if safe to do so.
7. Handling and storage
7.1 Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap- plication area.
Dispose of rinse water in accordance with local and national regulations.
Avoidance of contact: Acids, Oxidizing agents
7.2 Storage
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Electrical installations / working materials must comply with the technological safety standards.
To maintain product quality, do not store in heat or direct sunlight.
Do not store near acids
8. Exposure controls / personal protection
8.1 Control parameters
Chemical identity
Zinc oxide

ACGIH_TLV (2016)
2mg/m³ (TWA)
10mg/m³ (STEL)

8.2 Exposure controls
Engineering measures
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Eye/face protection
Safety glasses with side-shields conforming to EN166
Skin and body protection
Choose body protection according to the amount and concentration of the dangerous substance at thework place.
Hygiene measures
Wash hands before breaks and at the end of workday.

< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 3 of 99. Physical and chemical properties
Physical state: Metal powder

Color: GrayOdor: odorless

Melting point/range: 420°C Boiling

Point/boiling range: 908°C

Flammability (solid, gas) : May be combustible at high temperature.
Solubility (ies)
Water solubility: insoluble

10. Stability and Reactivity
10.1 Reactivity
In contact with water releases flammable gases.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Wetted powder will heat and release gases (hydrogen)No decomposition if stored and applied as directed.
10.4 Conditions to avoid
Heat, flames and sparks.
Isolate wetted packaging and powder from combustible mate- rials and dry powder and store in an excellent
ventilated area. Avoid generation of dust.
Exposure to moisture10.5 Incompatible materials
Acids, Oxidizing agents
11. Toxicological information
Acute toxicity
Product:
Acute oral toxicity
LD50 (Rat): > 2,000 mg/kg
Assessment: The substance or mixture has no acute oral toxicity
Acute inhalation toxicity
LC50 (Rat): > 5.4 mg/l, Exposure time:4h, Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhalation toxicity
Acute dermal toxicity
Assessment: The substance or mixture has no acute dermal toxicity
Remarks: No data available
Skin corrosion/irritation Product:
Result: No skin irritation
Serious eye damage/eye irritation
Result: No eye irritation
Respiratory or skin sensitisation
Result: Does not cause skin sensitisation.
Germ cell mutagenicity< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 4 of 9

Genotoxicity in vitro: Remarks: No data available
Carcinogenicity
Remarks: No data available
Reproductive toxicity
Effects on fertility: Remarks: No data available
STOT - single exposure
Remarks: No data available
STOT - repeated exposure
Remarks: No data available
Further information
Remarks: No data available
Zinc:
Acute oral toxicity
LD50 (Rat): > 2,000 mg/kg
Assessment: The substance or mixture has no acute oral toxicity
Acute inhalation toxicity
LC50 (Rat): > 5.4 mg/l, Exposure time:4h, Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhalation toxicity
Acute dermal toxicity
Assessment: The substance or mixture has no acute dermal toxicity
Zinc oxide:
Acute oral toxicity
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
LC50 (Rat): > 5.7 mg/l, Exposure time:4h, Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhalation toxicity
Acute dermal toxicity
LD50 (Rat): > 5,000 mg/kg
Assessment: The substance or mixture has no acute dermal toxicity
Serious eye damage/eye irritation
Result: No eye irritation
Respiratory or skin sensitisation
Exposure routes: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406 Result: Does not cause skin sensitisation.
Genotoxicity in vitro
Species: Bacteria
Method: OECD Test Guideline 471 Result: negative
Genotoxicity in vivo
Species: Mammalian-Animal Method: OECD Test Guideline 475 Result: negative
Remarks: Based on read across from structural related sub- stance: zinc sulphate
Further information
Remarks: No data available< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 5 of 9

12. Ecological information
12.1 Ecotoxicity
Zinc:
Toxicity to fish
LC50 (Pimephales promelas (fathead minnow)): 0.238 - 0.269 mg/l
Exposure time: 96 h Remarks: Fresh water
Toxicity to daphnia and other aquatic invertebrates
EC50 (Daphnia magna (Water flea)): 0.356 mg/l, Exposure time: 48h, Remarks: Fresh water
Toxicity to algae
EC50 (Pseudokirchneriella subcapitata (green algae)): 0.106 mg/l, Exposure time: 72h, Remarks: Freshwater
Zinc oxide:
Toxicity to fish
LC50 (Lepomis macrochirus (Bluegill sunfish)): 320 mg/l, Exposure time: 96h, Remarks: Fresh water
NOEC (Pseudokirchneriella subcapitata (green algae)): 0.017 mg/l, Exposure time: 72h, Remarks:
Fresh water
12.2 Persistence and degradative
No data available
12.3 Mobility in soil
No data available
13. Disposal considerations
13.1 Waste treatment methods
The product should not be allowed to enter drains, water courses or the soil.
Dispose of in accordance with the European Directives on waste and hazardous waste.
In accordance with local and national regulations.
Do not contaminate ponds, waterways or ditches with chemical or used container.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Send to a licensed waste management company.
13.2 Contaminated packaging
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
14. Transport information
International Regulation
UNRTDGUN number: UN 3077
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc.,zinc oxide)
Class: 9Packing group: III
Labels: 9< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 6 of 9

Marine pollutant: Yes
IATA-DGR
UN/ID number: UN 3077
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc.,zinc oxide)
Class: 9Packing group: III
Labels: Miscellaneous

Packing instruction (cargo aircraft): 956
Maximum quantity: 400.00 KG
Packing instruction (jpassenger aircraft): 956
Maximum quantity: 400.00 KG
IMDG-CodeUN number: UN 3077
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc.,zinc oxide)
Class: 9Packing group: III
Labels: 9EMS Code: F-A, S-F
Marine pollutant: Yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable for productas supplied.
GB 6944/12268
UN number: UN 3077
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc.,zinc oxide)
Class: 9Packing group: III
Labels: 9< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 7 of 9

Marine pollutant: Yes
Remarks:
Effective 1st of January 2015, when carried in single packaging or inner packaging of 5 kg or less, thismaterial is not subject to the transport regulations dangerous goods. The single packaging or outer
packaging must not be UN- approved but must be a good quality packaging
Special precautions for user
Remarks:
Effective 1st of January 2015, when carried in single packaging or inner packaging of 5 kg or less, thismaterial is not subject to the transport regulations dangerous goods. The single packaging or outer
packaging must not be UN- approved but must be a good quality packaging.
The product qualities covered by this MSDS have been tested according to the criteria for classes 4.1,4.2
and 4.3 of “UN Recommendations on the Transport of Dangerous Goods.
Model Regulations
15th revised edition” and “GB6944-2005 Classification and code of dangerous goods”. The test results
show that Zinc Metal Pigment DOES NOT belong to dangerous goods: National Registration Center for
Chemicals, SAWS; Report 2008051601 & 2008051602
15. Regulatory information
National regulatory informationLaw on the Prevention and Control of Occupational Diseases
The components of this product are reported in the following inventories:
CH INV: On the inventory, or in compliance with the inventory
TSCA: On TSCA Inventory
DSL: All components of this product are on the Canadian DSL
AICS: On the inventory, or in compliance with the inventory
NZIoC: On the inventory, or in compliance with the inventory
ENCS: Not in compliance with the inventory
ISHL: Not in compliance with the inventory
KECI: On the inventory, or in compliance with the inventory
PICCS: On the inventory, or in compliance with the inventory
IECSC: On the inventory, or in compliance with the inventory
16. Other information
Full text of other abbreviations(Q)SAR - (Quantitative) Structure Activity Relationship; ANTT - National Agency for Transport by Landof Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CPR - Controlled
Products Regulations; DIN - Standard of the German Institute for Standardisation; ECx - oncentration
associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS Globally Harmonized System; IARC - International Agency for Research on Cancer; IATA - International
Air Transport Association; IBC - Interna- tional Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International CivilAviation Organization; IMDG - International Maritime Dangerous Goods; IMO - International MaritimeOrganization; ISO - International Organisation for Standardization; LC50 - Lethal Concentration to 50 % ofa test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL < AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 8 of 9International Convention for the Prevention of Pollution from Ships; N.O.S. - Not Otherwise Specified; Nch- Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed(Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm;
NTP - National Toxicology Program; OECD - Organization for Economic Cooperation and Development;
OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxicsubstance; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT – Self
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TDG - Transportation of DangerousGoods; UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of DangerousGoods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials
Information System; DSL - Domestic Substances List (Canada); KECI - Korea Existing Chemicals
Inventory; TSCA - Toxic Substances Control Act (United States); AICS - Australian Inventory of ChemicalSubstances; IECSC - Inventory of Existing Chemical Substances in China; ENCS - Existing and New
Chemical Substances (Japan); ISHL - Industrial Safety and Health Law (Japan); PICCS - Philippines
Inventory of Chemicals and Chemical Substances; NZIoC - New Zealand Inventory of Chemicals; TCSI Taiwan Chemical Substance Inventory; CMR - Carcinogen, Mutagen or Reproductive Toxicant; GLP - Good
Laboratory PracticeDate format: yyyy/mm/ddDisclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for suchmaterial used in combination with any other materials or in any process, unless specified in the text.

< AQUA ROVAL Cold Galvanizing Compound (Powder) >Page 9 of 9