SDS ESLON BV

Implementation: Sep. 20, 2011
Issue date: Jun. 1, 2024

SAFETY DATA SHEET
1. Product and company (manufacturer) identification
Product:
Manufacturer:
Address:
Responsible section:
Telephone:
Urgent telephone:
Fax:
Urgent contact:
Application & restriction
Document number:
2. Hazards identification
GHS Classification
Physicochemical hazards:

Health hazards:

Environmental hazards:

ESLON BV
Sekisui Chemical Co., Ltd.
Toranomon 2-10-4, Minato-ku, Tokyo 105-8566
Urban Infrastructure & Environmental Products Company
Pipe Systems Division+81-3-6748-6492+81-3-6748-6492+81-3-6748-6564
Same as above
Adhesive for polyvinyl chloride piping system
Other applications are prohibited.
#BV

Explosives
Not classified
Flammable gases
Not classified
Aerosols and chemicals under
Not classified
pressure
Oxidizing gases
Not classified
Gases under pressure
Not classified
Flammable liquids
Not classified
Flammable solids
Category 1
Self-reactive substances andNot classified
mixtures
Pyrophoric liquids
Not classified
Pyrophoric solids
Not classified
Self-heating substances and mixtures Classification not possible
Substances and mixtures which, in
Not classified
contact with water, emit flammablegases
Oxidizing liquids
Not classified
Oxidizing solids
Not classified
Organic peroxides
Not classified
Corrosive to metals
Not classified
Desensitized explosives
Classification not possible
Acute toxicity (oral)
Classification not possible
Acute toxicity (dermal)
Classification not possible
Acute toxicity (inhalation: gas)
Not classified
Acute toxicity (inhalation: vapor)
Category 4
Acute toxicity (inhalation: dust andClassification not possible
mist)
Skin corrosion/irritation
Classification not possible
Eye damage/irritation
Category 2B
Respiratory sensitization
Classification not possible
Skin sensitizationClassification not possible
Germ cell mutagenicity
Classification not possible
Carcinogenicity
Classification not possible
Reproductive toxicity
Classification not possible
Specific target organ toxicity (single Category 3 (narcotic effect, respiratory tractexposure)irritancy)
Specific target organ toxicity
Not classified(repeated exposure)
Aspiration hazard
Not classified
Hazard to the aquatic environment
Not classified(Acute hazard)
Hazard to the aquatic environment
Not classified(Long-term hazard)
Hazard to the ozone layer
Classification not possible

Pictogram or symbol:
Signal word:
Hazard statement:

Danger(H228) Flammable solid(H320) Eye irritation(H332) Harmful if inhaled.
(H335) May cause respiratory irritation.
(H336) May cause drowsiness or dizziness.

Precautionary statement:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. (P210)
Ground/bond container and receiving equipment. (P240)
Use explosion-proof electrical/ventilating/lighting equipment. (P241)
Avoid breathing gas/mist/vapors/spray/dust/fume. (P261)
Wash hands and eyes thoroughly after handling. (P264)
Use only outdoors or in a well-ventilated area. (P271)
Wear protective gloves/protective clothing/eye protection/face protection. (P280)
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortablefor breathing. (P304+P340)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. (P305+P351+P338)
Call a POISON CENTER or doctor/physician if you feel unwell. (P312)
If eye irritation persists: Get medical advice/attention. (P337+P313)
In case of fire: Use for extinction: (P370+P378)
Store in a well-ventilated place. Keep container tightly closed. (P403+P233)
Store locked up. (P405)
Dispose of contents/container in accordance withlocal/regional/national/international regulations. (P501)

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3. Composition/information on ingredients
Nature of composition:
MixtureChemical or common name:
Adhesive, containing vinyl chloride-vinyl acetate copolymer
Component

Content

CAS Number

Ethyl acetate
61%
141-78-6
Resin (VC-VAc copolymer, etc.)
30～35%
9003-22-9
Silica (Amorphous)
1～5%
Registered
Tin compound
Less than 0.5%68109-88-6※The content is listed as a range as it is confidential information.
4. First-aid measures
If vapor is inhaled:
If touched to skin:
If gets in eye:If swallowed:
Anticipated acute & chronic symptoms:

Protection of first-aid provider:
Special note to physician:
5. Fire-fighting measures
Extinguishing agents:
Prohibited extinguishing agent:Specific hazards:

Proper extinguishing method:

Reference Number in Gazetted
List in Japan

Others(2)-726(6)-76
Registered(2)-3019

Take the affected person to a clean-air space and give him rest in a easybreathing pose.
Seek physician's counsel as may be needed.
Wash the skin immediately with a lot of water and soap.
Take off the contaminated clothing's for cleaning.
Seek physicians counsel if he suffers from irritation or drowsiness.
Thoroughly wash the eye with clean water for a several minutes. Remove contact
lens if easily removable. Continue washing after removal.
Seek physician's counsel.
Immediately wash the mouth with water.
Immediately seek physician's counsel.
Do not compel the victim to vomit.
Irritation to respiratory organs, cough and gasp, when inhaled.
Irritation to digestive organs, nausea, vomit and diarrhea, when swallowed.
Skin irritation, defatting, eye irritation, reddening and ache, when contacted.
Anesthesia, headache, drowsiness, restricted vision, vomit, diarrhea and loss ofconsciousness, when over-exposed to vapor.
First-aid provider should use protective wears such as organic solvent mask, when
the circumstances require.
No information
Carbon dioxide, powder agent, foam agent
Water flux
Fire may cause to generate irritant, toxic or erosive gas.
Easily flammable. It will readily be ignited by heat, spark or flame.
Heating of container may cause explosion.
Easily inflammable liquid and vapor.
Remove surrounding combustibles and use extinguishing agents.
Use foam agent to choke a large scale fire.
Spray water over the neighborhood to cool and prevent fire spread.
Fight against fire standing to its windward as much as possible and wear Respirator
if necessary.

6. Accidental release measures
Health hazard precaution, protective wear and first- Workers should use protective wears (See Chapter 8) to prevent contact with theaidspilt adhesive and inhalation of its vapor.
Rope off the crowd from the leak spot.
Work from the windward and evacuate the leeward crowd.
In case of indoor leakage, ventilate as much as possible until the cleaning iscompleted.
Environmental hazard precaution:
Prevent flow out to rivers, etc. so as not to badly affect the environment.
Recovery and neutralization:
For small scale leakage, use absorbent (sawdust, dirt, sand, waste rug) to remove
most of the spill and wipe off the rest using waste rug.
For large scale leakage, build bank around the spill and lead the liquid to a safer
place for recovery.
Prevention of secondary casualty:
Quickly remove all the combustibles from around the leak spot and provide
extinguishers ready for use.
7. Handling and storage precautions
Handling
Technical measures:
Local & total ventilation:
Safe handling:

Use protective wears if inhalation or skin contact is foreseen.
No open flames.
Handling work must be practiced in a room where local or total ventilation facility isfunctioning.
Ban of high temperature substance, sparking and fire at nearby points.
Prohibition of eating, drinking and smoking while the product is used.
Wash hands well after handling.
Avoid contact of the product with eye, skin and clothing.
Do not inhale vapor, mist and spray of the product.
Handle it only after reading and understanding all the precautions.
Use the product only in a well ventilated room or outdoors.

Storage
Storing conditions:

8. Exposure controls and personal protection
Facility measures:

Control concentration:
Permissible concentration (Exposure limit, Biological
exposure guide line)
Japan society for occupational health.
ACGIH TLV-TWA

Store in a remote room from heat, sparks and naked flame. No smoking in thestorage room.
Store in a cool, ventilated room.
Lock the storage room.
Local ventilation of closed work room or total proper ventilation to prevent vapor
inhalation.
Ethyl acetate
200 ppm
200 ppm
400 ppm

Protective wears:
Respiratory protection:
Hand protection:
Eye protection:
Skin and body protection:
Hygienic measures:

Use aspirator with appropriate filter.
Impermeable gloves
Solvent-resistant goggles
Long-sleeve fatigue uniform
Wash hands well after handling.

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9. Physical and chemical properties
Physical state, form:
Color:
Odor:
Melting point/freezing point:
Bp, initial bp & boiling range:
Flammability:

PasteBlack
Characteristic, stimulative-20℃ or lower
77℃ (bp)
Flammable
Lower limit: 2.2vol%, upper limit: 11.5vol%(Ethyl acetate)-4℃ (Closed Method)
420℃
No data available
Not applicable
ca. 65,000（mm2/s）/20℃
Insoluble in water
No data available
No data availableca. 1.1 (20℃)
No data available
No data available
ca. 40%ca. 50,000 mPa・s

Evaporation rate:
Flash point:
Auto ignition point:
Decomposition temperature:pH:
Dynamic viscosity:Solubilities:
n-Octanol/water partition coefficient: (log Pow)
Vapor pressure:Specific gravity (density):
Vapor density:
Particle characteristics:
Non-volatile content:
Viscosity:
10. Stability and reactivity
Stability:
Chemical stability:
Possibility of hazardous reaction:
Prohibitive conditions:
Prohibitive contact:
Hazardous decomposed substances:
Other:

Stable under normal handling conditions.
Vapors may ignite and explode.
Vigorously reacts with strong oxidizing agents and ignites.
HeatOxidizing agent
Generates Aldehyde, Acid and Organic matter by thermal decomposition.
Prolonged storage may lead to the formation of volatile gases, which may increase
the pressure inside the container.

11. Hazard information
Acute toxicity:(Appended Table)
Acute toxicity(inhalation: dustand mist)
Classification notpossible

Content

Acute toxicity(oral)

Acute toxicity(dermal)Acute toxicity(inhalation: gas)

Acute toxicity(inhalation: vapor)

Ethyl acetate61%

Not classified

Not classified

Not classified

Category 4(14,600ppm)

Resin (VC-VAc
copolymer, etc.)

30～35%Classification not Classification not Classification notClassification notClassification not possible
possiblepossiblepossible
possible

Silica(Amorphous)

1～5%

Classification not Classification not Classification notClassification notClassification not possible
possiblepossiblepossiblepossible

Acute toxicity (oral):Acute toxicity (dermal):Acute toxicity (inhalation: vapor):Skin corrosion/irritation:
Eye damage/irritation:

Respiratory sensitization:
Skin sensitization:
Germ cell mutagenicity:
Carcinogenicity:
Reproductive toxicity:
Specific target organ toxicity(single exposure):
Specific target organ toxicity(repeated exposure):
Aspiration hazard:

The product, as the mixture, falls Not classified.
The product, as the mixture, falls Not classified.
The product contains substances of acute toxicity (vapor inhalation) of Categories
indicated in Appended Table. The dose is calculated for the mixture (the product)
to be ATE mix=14,600 ppm.
The product, as the mixture, falls in Category 4.
The product, as the mixture, falls Not classified.
The product contains caustically injuring and irritating substances of the following
Categories:
Category 2B: Ethyl acetate (61%).
The product, as the mixture, falls in Category 2B.
No data available
No data available
The product, as the mixture, falls Not classified.
The product, as the mixture, falls Not classified.
The product, as the mixture, falls Not classified.
The product contains single-exposure toxic substances of the following Categories:
Ethyl acetate (61%)＞1%, Category 3 (respiratory tract irritancy, narcotic effect)
The product, as the mixture, falls in Category 3 (respiratory tract irritancy, narcoticeffect).
The product, as the mixture, falls Not classified.
The product contains more than 10% in total of respiratory-harmful substances ofthe following Category, however, the kinematic viscosity at 40℃ is more than
20.5mm2/s:
The product, as the mixture, falls Not classified.

12. Ecological information
Hazard to the aquatic environment (Acute hazard):
Hazard to the aquatic environment (Long-termhazard):
Ecotoxicity:
Persistence/degradability:
Ecological accumulative property:
Mobility in soil:
Hazard to the ozone layer：
13. Notes on disposal
Residual & waste:

Contaminated containers & packages:

Not classified
Not classified
No information
No information
No information
No information
Does not contain any ingredient listed in the Annexes to the Montreal Protocol.
Classification not possible.
In the disposal of residual and other wastes, observe the relevant laws /regulations
and local government rules.
Users of the product should contract with the local government or licensed'Industrial Waste Processors' for disposal of waste.
It is important to let the contractor know well of fire and health hazards of theproduct, prior to disposal.
Clean the containers for reuse or dispose them properly in accordance withrelevant regulations and local government rules.
Completely empty containers prior to disposal.

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14. Transport information
International ruleUN number:
UN classification:
Packing group:Sea Pollution Prevention Act1325（Flammable solid , Organic , N.O.S.）
Class 4.1
Ⅱ
Harmful liquid material
The enforcement order separate table first; Z Group(Ethyl acetate)
However, it is not applicable when net weight in one container is 5L or less.

Domestic control:
Guidance Number
Onshore control info.
Offshore control info.
Air cargo control info.
Special safety measure:

15. Regulatory information
Labor Safety and Hygiene Law:

Hazardous materials to be notified to the authority (Chapter 57, Section 2)(Ethyl acetate, Tin compound)
Hazardous materials to be posted (Chapter 18 of Ordinance)(Ethyl acetate)
2nd class organic solvents (Solvent Addiction Prevention Rule, Clause 1.1.4)(Ethyl acetate)
Workers handling substances and current substances subject to special healthchecks (Article 66, paragraph 2 of the Law, Article 22, paragraph 1 of theEnforcement Order).
(Ethyl acetate)
Carcinogenicity of chemical substances(Ordinance on Industrial Safety and Health Chapter 34, Section 2-4)
(Not applicable)
Chemical substances that cause skin and other skin disorders(related to Article 22 of the Law).
(Not applicable)
Disease-causing chemicals (Article 75 (2), Ordinance for Enforcement_Article 35,
Appended Table 1-2 (iv)-1)
Class 2 Flammable solids (Hazard class III)

Labor Standards Act:
Fire Defense Law:
PRTR Law:
Poisonous & Deleterious Substance Control Law:
Sea Pollution Prevention Act

Other
16. Other information
Literature:

129
Observe the Fire Defense Law.
Observe the Marine Vessel Safety Law.
Observe the Aviation Law.
Observe the Fire Defense Law.
On-board containers of hazardous material must be piled firmly and orderly to avoid
falling, tumbling and breaking.
Cargo of hazardous material must be transported in a way the containers or thematerial itself do not suffer severe friction and vibration.
If possible cause of casualty, such as heavy leakage, is found during transportation,
try to remedy the situation and notify the fact to the nearby fire department or therelevant bureau.
The driver carrying hazardous material must hold Yellow Card.
Do not load hazardous materials together with food and feedstuff.

Not applicableNot applicable
Harmful liquid material
The enforcement order separate table first; Z Group(Ethyl acetate)
However, it is not applicable when net weight in one container is 5L or less.
Ordinance on Prevention of Dust Disorders（Silica (Amorphous))

1) Chemicals Safety Data Sheet (MSDS) Part 1: Content and Order of Items
2) Guideline for MSDS Edition (Revised Edition) by Japan Chem. Ind. Assoc.
3) GHS Classification Database, Site of National Institute of Technology and Evaluation
4) Hazard Handbook of Chemicals by Japan Industrial Safety and Health Association
5) Hazard communication of chemicals based on GHS-Labelling and Safety Data Sheet (SDS) JIS Z
7253:2019

This data sheet is edited by referring to currently available information, however, it is not intended to guarantee the data values or theprecision of contained information. The precautions mentioned above are for ordinary handling and use only therefore please handle with careby implementing appropriate safety measures for new application and usage.

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