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1 Identification. Product identifier. Trade name POLYESTER-POLYURETHANE TGIC METALLIC. Article number: 2/3/4/5/8(44)TM. Manufacturer/Supplier:
USA:
TIGER Drylac U.S.A., Inc.
3945 Swenson Ave
St. Charles, IL 60174
Phone: +1- 630-587-2918
Fax: +1-630-587-2923
Canada:TIGER Drylac Canada Inc.
110 Southgate Drive
Guelph, Ontario, N1G 4P5
Phone: +1-519-766-4781
Fax: +1-519-766-4787
MexicoTIGER Drylac Mexico S.A. de C.V.
Circuito Exportación 212, Parque Industrial Tres Naciones
San Luis Potosí, SLP, C.P. 78395
Phone +52-444-799-7243
Fax +52-444-799-7244. Informing department: Product Safety Department. Emergency telephone number: 24/7:1-800-255-3924; International:+01 or +001-813-248-0585*

2 Hazard(s) identification. Classification of the substance or mixture~d

GHS08 Health hazard

Muta. 1B
STOT RE 2


~
d

H340
H373

May cause genetic defects.
May cause damage to organs through prolonged or repeatedexposure.

H319
H317

Causes serious eye irritation.
May cause an allergic skin reaction.

GHS07

Eye Irrit. 2A
Skin Sens. 1
Combustible Dust

May form combustible dust concentrations in air.

. Label elements. GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
. Hazard pictograms

d
~
d

~
GHS07

GHS08

. Signal word Danger(Contd. on page 2)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 1). Hazard-determining components of labeling:
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione. Hazard statements
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause genetic defects.
May cause damage to organs through prolonged or repeated exposure.
May form combustible dust concentrations in air.
. Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin: Wash with plenty of water.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If exposed or concerned: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Specific treatment (see on this label).
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international
regulations.
. Classification system. NFPA ratings (scale 0-4)
Health = 2
Fire = 1
Reactivity = 1

1
2

1. HMIS-RATINGS (SCALEHEALTH

2

FIRE

1

REACTIVITY 1

0 - 4)

Health = 2
Fire = 1
Reactivity = 1. Other hazards. Results of PBT and vPvB assessment. PBT: Not applicable.
. vPvB: Not applicable.
*

3 Composition/information on ingredients. Chemical characterization: Mixtures. Description: Mixture consisting of the following components with harmless additives.
. Hazardous ingredients:
21645-51-2 aluminium hydroxide
10-25%
13463-67-7 titanium dioxide
10-25%
7727-43-7 barium sulphate, natural
10-25%
7429-90-5 aluminum powder (stabilized)<2.5%
Flam. Sol. 1, H228; Water-react. 2, H261
12001-26-2 mica
<2.5%
2451-62-9 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione<1%
Acute Tox. 3, H301; Acute Tox. 3, H331; Muta. 1B, H340; STOT RE 2,
H373; Eye Dam. 1, H318; Skin Sens. 1, H317
(Contd. on page 3)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 2)693-23-2

dodecanedioic acid<1%
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335
. Additional information For the wording of the listed hazard phrases refer to section 16.
*

4 First-aid measures. Description of first aid measures. After inhalation
Supply fresh air and call for doctor for safety reasons.
In case of unconsciousness bring patient into stable side position for transport.
. After skin contact Instantly wash with water and soap and rinse thoroughly.
. After eye contact Rinse opened eye for several minutes under running water.
. After swallowing In case of persistent symptoms consult doctor.
. Information for doctor. Most important symptoms and effects, both acute and delayed
No further relevant information available.
. Indication of any immediate medical attention and special treatment needed
No further relevant information available.

*

5 Fire Fighting Measures. Extinguishing media. Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcoholresistant foam.
. Special hazards arising from the substance or mixture
No further relevant information available.
. Advice for firefighters. Protective equipment: No special measures required.

*

6 Accidental release measures. Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Avoid causing dust.
. Environmental precautions: Do not allow product to reach sewage system or water bodies.
. Methods and material for containment and cleaning up:
Collect mechanically.
Ensure adequate ventilation.
. Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
. Protective Action Criteria for Chemicals. PAC-1:
21645-51-2 aluminium hydroxide
8.7 mg/m³
13463-67-7 titanium dioxide
30 mg/m³
7727-43-7 barium sulphate, natural
15 mg/m³
12001-26-2 mica
9 mg/m³
7631-86-9 silicon dioxide, chemically prepared
18 mg/m³
1344-28-1 aluminium oxide
15 mg/m³
112926-00-8 Silicon dioxide
18 mg/m³
105-60-2 epsilon-caprolactam
3 mg/m³
77-58-7 dibutyltin dilaurate
1.1 mg/m³
1314-23-4 zirconium dioxide
14 mg/m³
471-34-1 calcium carbonate
45 mg/m³
1309-37-1 diiron trioxide
15 mg/m³(Contd. on page 4)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 3)14808-60-7
1308-14-1
18282-10-5*

quartz (SiO2)
chromium hydroxide(III)tin dioxide

0.075 mg/m³
3 mg/m³
7.6 mg/m³. PAC-2:
21645-51-2
13463-67-7
7727-43-7
12001-26-2
7631-86-9
1344-28-1
112926-00-8
105-60-2
77-58-71314-23-4
471-34-1
1309-37-1
14808-60-7
1308-14-1
18282-10-5

aluminium hydroxidetitanium dioxidebarium sulphate, natural
mica
silicon dioxide, chemically preparedaluminium oxide
Silicon dioxide
epsilon-caprolactam
dibutyltin dilaurate
zirconium dioxide
calcium carbonate
diiron trioxide
quartz (SiO2)
chromium hydroxide(III)tin dioxide

73 mg/m³
330 mg/m³
170 mg/m³
99 mg/m³
740 mg/m³
170 mg/m³
200 mg/m³
40 mg/m³
8 mg/m³
110 mg/m³
210 mg/m³
360 mg/m³
33 mg/m³
33 mg/m³
85 mg/m³. PAC-3:
21645-51-2
13463-67-7
7727-43-7
12001-26-2
7631-86-9
1344-28-1
112926-00-8
105-60-2
77-58-71314-23-4
471-34-1
1309-37-1
14808-60-7
1308-14-1
18282-10-5

aluminium hydroxidetitanium dioxidebarium sulphate, natural
mica
silicon dioxide, chemically preparedaluminium oxide
Silicon dioxide
epsilon-caprolactam
dibutyltin dilaurate
zirconium dioxide
calcium carbonate
diiron trioxide
quartz (SiO2)
chromium hydroxide(III)tin dioxide

440 mg/m³
2,000 mg/m³
990 mg/m³
590 mg/m³
4,500 mg/m³
990 mg/m³
1,200 mg/m³
240 mg/m³
48 mg/m³
680 mg/m³
1,300 mg/m³
2,200 mg/m³
200 mg/m³
200 mg/m³
510 mg/m³

7 Handling and storage. Handling. Precautions for safe handlingNo special measures required.
Open and handle container with care.
. Information about protection against explosions and fires:

W_
b
_
V
b

Keep ignition sources away - Do not smoke.

Keep breathing equipment ready.
Dust can combine with air to form an explosive mixture.
(Contd. on page 5)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 4). Conditions for safe storage, including any incompatibilities. Storage. Requirements to be met by storerooms and containers:
Store only in the original container.
Static charges may build up in the powder. Information about storage in one common storage facility: Not required.
. Further information about storage conditions: None.
. Specific end use(s) No further relevant information available.
*

8 Exposure controls/personal protection. Additional information about design of technical systems: No further data; see item 7.
. Control parameters. Components with critical values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV
or other recommended exposure limit.
At this time, the remaining constituent has no known exposure limits.
21645-51-2 aluminium hydroxide
REL (U.S.A)
Long-term value: 2 mg/m³
as Al
TLV (U.S.A)
Long-term value: 1* mg/m³
as Al;*as respirable fraction
EL (Canada)
Long-term value: 10 mg/m³
13463-67-7 titanium dioxide
PEL (U.S.A)
Long-term value: 15* mg/m³*total dust
REL (U.S.A)
See Pocket Guide App. A
TLV (U.S.A)
Long-term value: 10 mg/m³
withdrawn from NIC
EL (Canada)
Long-term value: 10* 3** mg/m³*total dust;**respirable fraction; IARC 2B
EV (Canada)
Long-term value: 10 mg/m³
total dust
LMPE (Mexico) Long-term value: 10 mg/m³
A47727-43-7 barium sulphate, natural
PEL (U.S.A)
Long-term value: 15* 5** mg/m³*total dust **respirable fraction
REL (U.S.A)
Long-term value: 10* 5** mg/m³*total dust **respirable fraction
TLV (U.S.A)
Long-term value: 5* mg/m³*inhalable fraction; E
EL (Canada)
Long-term value: 10* 3** mg/m³*total dust, **respirable fraction
EV (Canada)
Long-term value: 10 mg/m³
total dust
LMPE (Mexico) Long-term value: 10 mg/m³
7429-90-5 aluminum powder (stabilized)
PEL (U.S.A)
Long-term value: 15*; 5** mg/m³*Total dust; ** Respirable fraction
REL (U.S.A)
Long-term value: 10* 5** mg/m³
as Al*Total dust**Respirable/pyro powd./welding f.
TLV (U.S.A)
Long-term value: 1* mg/m³
as Al; *as respirable fraction(Contd. on page 6)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 5)

EL (Canada)
LMPE (Mexico)Long-term value: 1.0 mg/m³
respirable, as AlLong-term value: 1* mg/m³
A4, *fracciòn respirable

12001-26-2 mica
PEL (U.S.A)
Long-term value: 20 mppcf ppm<1% crystalline silica
REL (U.S.A)
Long-term value: 3* mg/m³*respirable dust; containing < 1% quartz
TLV (U.S.A)
Long-term value: 3* mg/m³*as respirable fraction
EL (Canada)
Long-term value: 3 mg/m³
EV (Canada)
Long-term value: 3(D) mg/m³
respirable
LMPE (Mexico) Long-term value: 3* mg/m³*fracción respirable
2451-62-9 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
TLV (U.S.A)
Long-term value: 0.05 mg/m³
EL (Canada)
Long-term value: 0.05 mg/m³
R; S
EV (Canada)
Long-term value: 0.05 mg/m³
LMPE (Mexico) Long-term value: 0.05 mg/m³. Additional information:
The lists that were valid during the compilation were used as basis.
. Exposure controls. Personal protective equipment. General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Store protective clothing separately.
. Breathing equipment:U_

In case of brief exposure or low pollution use breathing filter apparatus. In
case of intensive or longer exposure use breathing apparatus that is independentof circulating air.

. Protection of hands:

S_

Protective gloves.

. Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product isa preparation of several substances, the resistance of the glove material can not becalculated in advance and has therefore to be checked prior to the application.
. Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective
gloves and has to be observed.
. Eye protection:

R_

Safety Glasses(Contd. on page 7)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 6). Body protection: Protective work clothing.
*

9 Physical and Chemical Properties. Information on basic physical and chemical properties. General Information. Appearance:
Form:
Solid
Colour:According to Trade Name
. Smell:
Characteristic. Odor threshold:Not determined. pH-value:

Not applicable. Change in condition
Melting point/Melting range:
Boiling point/Boiling range:> 50 C / 120F
Not applicable. Flash point:

Not applicable. Inflammability (solid, gaseous)Not determined. Ignition temperature:

390 °C (734 °F). Decomposition temperature:

Not determined. Self-inflammability:

Product is not selfigniting.

. Danger of explosion:

Product is not explosive. However,formation of explosive air/dust mixtures ispossible. Critical values for explosion:
Lower:
Upper:

Not determined.
Not determined.

. Steam pressure:

Not applicable.

. Density (Specific gravity) at 20 °C (68 °F) 1.58 g/cm³ (13.19 lbs/gal). Relative density
Not determined.
. Vapor density
Not applicable.
. Evaporation rate
Not applicable.
. Solubility in / Miscibility with
Water:

Unsoluble. Partition coefficient (n-octanol/water):Not determined.

. Viscosity:
dynamic:
kinematic:

Not applicable.
Not applicable.

. Solvent content:
Organic solvents:

0.0 %Solids content:. Other information

100.0 %
No further relevant information available.

* 10 Stability

and Reactivity. Reactivity No further relevant information available.
. Chemical stability. Conditions to be avoided: No decomposition if used according to specifications.
. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available.
. Incompatible materials: No further relevant information available.
. Hazardous decomposition products: In case of fire: CO, CO2, NOx(Contd. on page 8)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 7)* 11 Toxicological

Information. Information on toxicological effects. Acute toxicity:. LD/LC50 values that are relevant for classification:
2451-62-9 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
Oral
LD50
188-1,450 mg/kg (rat)DermalLD50>2,000 mg/kg (rat)Inhalative LC50/4 h 0.309-650 mg/l (rat). Primary irritant effect:. on the skin: No irritant effect.
. on the eye: No irritant effect.
. Sensitization: Sensitization possible by skin contact.
. Additional toxicological information:
The product shows the following dangers according to the calculation method of theGeneral EC Classification Guidelines for Preparations as issued in the latest version:
Irritant
The product can cause inheritable damage.
. Carcinogenic categories. IARC (International Agency for Research on Cancer)
13463-67-7 titanium dioxide
7631-86-9 silicon dioxide, chemically prepared112926-00-8 Silicon dioxide
105-60-2 epsilon-caprolactam
1309-37-1 diiron trioxide
14808-60-7 quartz (SiO2)

2B
3
3
4
3
1

. NTP (National Toxicology Program)
14808-60-7 quartz (SiO2)K. OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecologicalinformation. Toxicity. Aquatic toxicity: No further relevant information available.
. Persistence and degradability No further relevant information available.
. Behaviour in environmental systems:. Bioaccumulative potential No further relevant information available.
. Mobility in soil No further relevant information available.
. Additional ecological information:. General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water
bodies or sewage system.
. Results of PBT and vPvB assessment. PBT: Not applicable.
. vPvB: Not applicable.
. Other adverse effects No further relevant information available.
(Contd. on page 9)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 8)

13 Disposal considerations. Waste treatment methods. Recommendation

L?
H
@
I
?
L
J
@
K

Must not be disposed of together with household garbage. Do not allow
product to reach sewage system.

. Uncleaned packagings:. Recommendation: Disposal must be made according to official regulations.
* 14 Transport

information. UN-Number. DOT, ADR, IMDG, IATA
. UN proper shipping name
. DOT, ADR, IMDG, IATA
. Transport hazard class(es)

N/A
N/A
N/A
N/A

. DOT, IMDG, IATA
. Class
Not regulated.
. Packing group
N/A. DOT, ADR, IMDG, IATA
N/A
. Environmental hazards:. Marine pollutant:
No. Transport in bulk according to Annex II of
MARPOL73/78 and the IBC CodeNot applicable.
* 15 Regulatory

information. Safety, health and environmental regulations/legislation specific for the substance or
mixture. SARA (Superfund Amendments and Reauthorization Act):. Section 355 (Extremly hazardous substances):
None of the ingredients is listed.
. Section 313 (Specific toxic chemical listings):
7727-43-7 barium sulphate, natural
7429-90-5 aluminum powder (stabilized)
1344-28-1 aluminium oxide. TSCA (Toxic Substances Control Act):All ingredients are listed.
. TSCA new (21st Century Act) (Substances not listed)7429-90-5 aluminum powder (stabilized)
12001-26-2 mica
. Proposition 65:. Chemicals known to cause cancer:
13463-67-7 titanium dioxide. Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
. Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
(Contd. on page 10)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 9). Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
. Cancerogenity categories. EPA (Environmental Protection Agency)
7727-43-7 barium sulphate, natural

D, CBD(inh), NL(oral). TLV (Threshold Limit Value established by ACGIH)
13463-67-7 titanium dioxide1332-58-7 kaolin1344-28-1 aluminium oxide
105-60-2 epsilon-caprolactam
77-58-7 dibutyltin dilaurate1314-23-4 zirconium dioxide
1309-37-1 diiron trioxide
14808-60-7 quartz (SiO2)

A4
A4
A4
A5
A4
A4
A4
A2

. NIOSH-Ca (National Institute for Occupational Safety and Health)13463-67-7 titanium dioxide
14808-60-7 quartz (SiO2). GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
. Hazard pictograms

d
~
d

~
GHS07

GHS08

. Signal word Danger. Hazard-determining components of labeling:
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione. Hazard statements
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause genetic defects.
May cause damage to organs through prolonged or repeated exposure.
May form combustible dust concentrations in air.
. Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If on skin: Wash with plenty of water.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If exposed or concerned: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Specific treatment (see on this label).
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international
regulations.
. Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
(Contd. on page 11)US46.0.2

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Trade name POLYESTER-POLYURETHANE TGIC METALLIC(Contd. of page 10)* 16 Other

information

These data are based on our present knowledge. However, they shall not constitute a
guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
. Relevant phrases
H228 Flammable solid.
H261 In contact with water releases flammable gas.
H301 Toxic if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H340 May cause genetic defects.
H373 May cause damage to organs through prolonged or repeated exposure.
. Date of preparation / last revision 11/09/2017 / . Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flam. Sol. 1: Flammable solids – Category 1
Water-react. 2: Substances and mixtures which in contact with water emit flammable gases – Category 2
Acute Tox. 3: Acute toxicity – Category 3
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A
Skin Sens. 1: Skin sensitisation – Category 1
Muta. 1B: Germ cell mutagenicity – Category 1B
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2. * Data compared to the previous version altered.
US