SAFETY DATA SHEET
According to JIS Z 7253:2019

Revision date 22-Feb-2024
Revision Number 5.05

Section 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name
Product CodeBromine
020-02403,022-02402,026-02405,024-02401

Supplier

FUJIFILM Wako Pure Chemical Corporation
1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan
Phone: +81-6-6203-3741
Fax: +81-6-6203-2029+81-6-6203-3741 / +81-3-3270-8571
For research use only
Seek expert judgment when using for purposes other than those recommended.

Emergency telephone number
Recommended usesRestrictions on use

Section 2: HAZARDS IDENTIFICATIONGHS classification
Classification of the substance or mixture
Corrosive to metals
Acute toxicity - Inhalation (Vapors)
Skin corrosion/irritation
Serious eye damage/eye irritation
Specific target organ toxicity (single exposure)
Category 1 central nervous system, respiratory system
Specific target organ toxicity (repeated exposure)
Category 1 nervous system, respiratory system, endocrine system
Acute aquatic toxicity
Chronic aquatic toxicity

Category 1
Category 2
Category 1
Category 1
Category 1
Category 1
Category 1
Category 1Pictograms

Signal word

DangerHazard statements
H290 - May be corrosive to metals
H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
H330 - Fatal if inhaled
H410 - Very toxic to aquatic life with long lasting effects
H400 - Very toxic to aquatic life
H370 - Causes damage to the following organs: central nervous system, respiratory system
H372 - Causes damage to the following organs through prolonged or repeated exposure: nervous system, respiratorysystem, endocrine system
Precautionary statements-(Prevention)• Wear protective gloves/protective clothing/eye protection/face protection• Do not breathe dust/fume/gas/mist/vapors/spray

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Revision date 22-Feb-2024• Wash face, hands and any exposed skin thoroughly after handling• Do not eat, drink or smoke when using this product• Avoid release to the environment• Keep only in original container
Precautionary statements-(Response)• IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing• Immediately call a POISON CENTER or doctor/physician• IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower• Wash contaminated clothing before reuse• IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing• IF SWALLOWED: Rinse mouth. Do NOT induce vomiting• Collect spillage• Absorb spillage to prevent material damage
Precautionary statements-(Storage)• Store locked up• Store in corrosive resistant/ container with a resistant inner liner
Precautionary statements-(Disposal)• Dispose of contents/container to an approved waste disposal plant
OthersOther hazards

Not available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTSSingle Substance or Mixture

Substance

FormulaBr2

Chemical NameBromine
Note on ISHL No.:

Weight-%99.0

Molecular weight
159.808

ENCS
ISHL No.
N/A* in the table means announced chemical substances.

CAS RN
7726-95-6

Section 4: FIRST AID MEASURES
Inhalation
Remove to fresh air. If symptoms persist, call a physician.
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. Immediate medical attention is required.
Ingestion
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center
immediately. Do not induce vomiting without medical advice.
Protection of first-aiders
Use personal protective equipment as required.

Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment
Unsuitable extinguishing media
No information available
Specific hazards arising from the chemical product

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Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Special extinguishing method
No information available
Special protective actions for fire-fighters
Wear self-contained breathing apparatus and protective suit

Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
For indoor, provide adequate ventilation process until the end of working. Deny unnecessary entry other than the people
involved by, for example, using a rope. While working, wear appropriate protective equipments to avoid adhering it on skin,or inhaling the gas. Work from windward, and retract the people downwind.
Environmental precautions
To be careful not discharged to the environment without being properly handled waste water contaminated.
Methods and materials for contaminent and methods and materials for cleaning up
Absorb dry sand, earth, sawdust and the waste. Collect empty container that can be sealed.
Recoverly, neutralization
No information available
Secondary disaster prevention measures
Clean contaminated objects and areas thoroughly observing environmental regulations.

Section 7: HANDLING AND STORAGEHandlingTechnical measures
Avoids contact with acids. Avoid contact with organic substance Avoid contact with metal. To cut with care and wear
protective gloves and protective goggles to ampoule time of the opening (Cutting method to check the label). Use withlocal exhaust ventilation.
Precautions
Do not rough handling containers, such as upsetting, falling, giving a shock, and dragging. Prevent leakage, overflow, andscattering. Not to generate steam and dust in vain. Seal the container after use. After handling, wash hands and face, andthen gargle. In places other than those specified, should not be smoking or eating and drinking. Should not be brought
contaminated protective equipment and gloves to rest stops. Deny unnecessary entry of non-emergency personnel to thehandling area.
Safety handling precautions
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.

Storage
Safe storage conditions
Storage conditions

Safe packaging material
Incompatible substances

Keep container protect from light, store
in well-ventilated place at room temperature (preferably cool). Keep container tightly
closed. Store locked up.
AmpouleStrong acids, Ammonia, Organic substance, Combustible materials

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
In case of indoor workplace, seal the source or use a local exhaust system. Provide the safety shower facility, and handand eye-wash facility. And display their position clearly.
Exposure limits
Chemical Name
Bromine7726-95-6

JSOH (Japan)
TWA: 0.1 ppm OEL
TWA: 0.65 mg/m3 OEL

ISHL (Japan)
N/A

ACGIHSTEL: 0.2 ppm
TWA: 0.1 ppm

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Chemical NameBromine
7726-95-6

Concentration standard value set by Concentration standard value set by
the Minister of Health, Labor andthe Minister of Health, Labor andWelfare (8hr)
Welfare (Short-Term)
N/A
0.2 ppm

Personal protective equipment
For halogen gas mask ( JIS T 8152 )Respiratory protection
chemical protective gloves ( JIS T 8116 )Hand protection
protective eyeglasses or chemical safety goggles (JIS T 8147)
Eye protection
Long-sleeved work clothes
Skin and body protection
General hygiene considerations
Handle in accordance with good industrial hygiene and safety practice.
If this product is classified as ”Chemical Substances Hazardous to Skin, etc.”, use appropriate protective equipment tothem.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Form
Color
Appearance
Odor
Melting point/freezing point
Boiling point, initial boiling point and boiling range
Flammability
Evaporation rate:
Flammability (solid, gas):
Upper/lower flammability or explosive limits
Upper：：Lower：：Flash point
Auto-ignition temperature:
Decomposition temperature:
pH
Viscosity (coefficient of viscosity)
Dynamic viscosity
Solubilities
n-Octanol/water partition coefficient:(log Pow)
Vapour pressure
Specific Gravity / Relative density
Vapour density
Particle characteristics

dark reddish brownliquidPungent odor
-7.3 °C
59 °C
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
Ethanol : free soluble . water : soluble .
no data available
22.0 KPa
3.10 g/mL
5.5 (Air=1)
no data available

Section 10: STABILITY AND REACTIVITY
Stability
no data available
Reactivity
May be altered by light.
Chemical stability
Hazardous reactions
Reacts with acids to generate hydrogen gas.
Conditions to avoid
Extremes of temperature and direct sunlight
Incompatible materials
Strong acids, Ammonia, Organic substance, Combustible materials
Hazardous decomposition products
Halides

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Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Chemical NameBromineOral LD50
2600 mg/kg ( Rat )Chemical Name
BromineChemical Name
BromineDermal LD50
N/A

Inhalation LC50120 ppm(Mouse) 4 h

Acute toxicity -oral- source
information
Based on the NITE GHS
classification results.

Acute toxicity -dermal- source Acute toxicity -inhalation gasinformation
source information
Based on the NITE GHS
Based on the NITE GHS
classification results.
classification results.

Acute toxicity -inhalation
vapor- source information
Based on the NITE GHS
classification results.

Acute toxicity -inhalation dust- Acute toxicity -inhalation mistsource information
source information
Based on the NITE GHS
Based on the NITE GHS
classification results.
classification results.

Skin irritation/corrosion
Skin corrosion/irritation source information
Based on the NITE GHS classification results.

Chemical Name
BromineSerious eye damage/ irritation
Chemical Name
BromineRespiratory or skin sensitization
Chemical Name
BromineReproductive cell mutagenicity
Chemical Name
BromineCarcinogenicity
Chemical Name
BromineSerious eye damage/irritation source information
Based on the NITE GHS classification results.
Respiratory or Skin sensitization source information
Based on the NITE GHS classification results.
germ cell mutagencity source information
Based on the NITE GHS classification results.
Carcinogenicity source information
Based on the NITE GHS classification results.

Reproductive toxicity
Chemical Name
BromineReproductive toxicity source information
Based on the NITE GHS classification results.

Chemical Name
Bromine
STOT-repeated exposure
Chemical Name
BromineAspiration hazard
Chemical Name
Bromine

STOT -single exposure- source information
Based on the NITE GHS classification results.

STOT-single exposure

STOT -repeated exposure- source information
Based on the NITE GHS classification results.
Aspiration Hazard source information
Based on the NITE GHS classification results.

Section 12: ECOLOGICAL INFORMATION
EcotoxicityChemical Name
BromineAlgae/aquatic plants
N/AFishN/ACrustacea
LC50 : Daphnia magna
1000 µg/L 48 h

Other data
Chemical Name
BromineShort-term (acute) hazardous to theLong-term (chronic) hazardous to theaquatic environment source information aquatic environment source information
Based on the NITE GHS classification
Based on the NITE GHS classification
results.
results.

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Bromine

Revision date 22-Feb-2024

No information available
No information available
No information available
No information available

Persistence and degradability
Bioaccumulative potential
Mobility in soilHazard to the ozone layer

Section 13: DISPOSAL CONSIDERATIONS
Waste from residues
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated container and contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.

Section 14: TRANSPORT INFORMATION
ADR/RID
UN number
Proper shipping name:
UN classfication
Subsidiary hazard classPacking group
Marine pollutant

UN1744
Bromine
86.1
IYes

IMDG
UN1744UN numberBromine
Proper shipping name:
8UN classfication
6.1
Subsidiary hazard class
I
Packing group
Yes
Marine pollutant (Sea)Transport in bulk according to No information available
Annex II of MARPOL 73/78 andthe IBC CodeForbidden
IATAUN1744
UN numberBromine solution
Proper shipping name:
8UN classfication
6.1
Subsidiary hazard class
I
Packing group
Yes
Environmentally Hazardous
Substance

Section 15: REGULATORY INFORMATION
Japanese regulations
Firefighting Inhibitor
Fire Service Act
Deleterious Substances 1st. Grade
Poisonous and Deleterious
Substances Control Law
Industrial Safety and Health Act Harmful Substances Whose Names Are to be Indicated on the Label (Law Art.57)Notifiable Substances (Law Art.57-2)
Industrial Safety and Health Act (2024~)【2024.4.1~】Chemical Substances Hazardous to Skin, etc.(Regulations Article 594-2 Paragraph 1)

Corrosive Substances (Ordinance Art.3, Ministry of Transportation Ordinance Regarding
Regulations for the carriage
Transport by Ship and Storage, Attached Table 1)
and storage of dangerous
goods in ship
Forbidden (Ordinance Art.194)
Civil Aeronautics Law
Pollutant Release and Transfer Class 2
Register Law

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Revision date 22-Feb-2024(2023.4.1-)
Class 2 - No.
Water Pollution Control Act
Export Trade Control Order
Air Pollution Control Law

234

Specified substances(Law Art.2 Para.4, Enforcement Order Art.3-3)
Not applicableSpecified Substances

Chemical Name

Poisonous and Deleterious
Substances Control Law

Bromine7726-95-6 ( 99.0 )Applicable

Industrial Safety and Health Act
Substances(Law Art.57-2)
Applicable

Pollutant Release and Transfer
Register Law(2023.4.1-)
Applicable

Section 16: OTHER INFORMATIONKey literature references andsources for data etc.

NITE: National Institute of Technology and Evaluation (JAPAN)
http://www.safe.nite.go.jp/japan/db.html
IATA dangerous Goods Regulations
RTECS:Registry of Toxic Effects of Chemical Substances
Japan Industrial Safety and Health Association GHS Model SDS
Dictionary of Synthetic Oraganic Chemistry , SSOCJ, Koudansha Scientific Co.Ltd.
Chemical Dictionary, Kyouritsu Publishing Co., Ltd.
etc

The following contents were revised. Regulatory information.
Record of SDS revisions
Disclaimer
This SDS is according to JIS Z 7253: 2019. The information provided in this Safety Data Sheet is correct to the best of ourknowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the text.
GHS Classification is according to JIS Z 7252:2019. *JIS: Japanese Industrial Standards
End of Safety Data Sheet

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