SAFETY DATA SHEET
According to JIS Z 7253:2019

Revision date 13-Sep-2024
Revision Number 7.06

Section 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name
Product CodeSalicylic Acid
198-14865,194-14862,196-14861

Supplier

FUJIFILM Wako Pure Chemical Corporation
1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan
Phone: +81-6-6203-3741
Fax: +81-6-6203-2029+81-6-6203-3741 / +81-3-3270-8571
For research use only
Seek expert judgment when using for purposes other than those recommended.

Emergency telephone number
Recommended uses
Restrictions on use

Section 2: HAZARDS IDENTIFICATIONGHS classification
Classification of the substance or mixture
Acute toxicity - Oral
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Reproductive Toxicity
Specific target organ toxicity (single exposure)
Category 1 central nervous system
Specific target organ toxicity (repeated exposure)
Category 1 central nervous system
Acute aquatic toxicity

Category 4
Category 2
Category 1
Category 1
Category 2
Category 1
Category 1
Category 3

Pictograms

Signal word

DangerHazard statements
H315 - Causes skin irritation
H318 - Causes serious eye damage
H302 - Harmful if swallowed
H361 - Suspected of damaging fertility or the unborn child
H317 - May cause an allergic skin reaction
H402 - Harmful to aquatic life
H370 - Causes damage to the following organs: central nervous system
H372 - Causes damage to the following organs through prolonged or repeated exposure: central nervous system
Precautionary statements-(Prevention)• Obtain special instructions before use• Do not handle until all safety precautions have been read and understood• Use personal protective equipment as requiredPage 1 / 7
W01W0119-1486 JGHEEN

Salicylic Acid

Revision date 13-Sep-2024• Contaminated work clothing should not be allowed out of the workplace• Wear protective gloves• Do not breathe dust/fume/gas/mist/vapors/spray• Wash face, hands and any exposed skin thoroughly after handling• Do not eat, drink or smoke when using this product• Avoid release to the environment
Precautionary statements-(Response)• IF exposed: Call a POISON CENTER or doctor/physician• IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing• Immediately call a POISON CENTER or doctor/physician• Take off contaminated clothing and wash before reuse• IF ON SKIN: Wash with plenty of soap and water• If skin irritation or rash occurs: Get medical advice/attention• IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell• Rinse mouth
Precautionary statements-(Storage)• Store locked up
Precautionary statements-(Disposal)• Dispose of contents/container to an approved waste disposal plantOthers
Other hazards

Not available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTSSingle Substance or Mixture

Substance

FormulaHOC6H4COOH

Chemical Name
Salicylic acid
Note on ISHL No.:

Weight-%99.5

Molecular weight138.12ENCS
ISHL No.
(3)-1640** in the table means announced chemical substances.

CAS RN
69-72-7

Section 4: FIRST AID MEASURES
Inhalation
Remove to fresh air. If symptoms persist, call a physician.
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. Immediate medical attention is required.
Ingestion
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center
immediately. Do not induce vomiting without medical advice.
Protection of first-aiders
Use personal protective equipment as required.

Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
Water spray (fog), Carbon dioxide (CO2), Foam, Extinguishing powder, Sand
Unsuitable extinguishing media
No information available

Page 2 / 7W01W0119-1486 JGHEEN

Salicylic Acid

Revision date 13-Sep-2024

Specific hazards arising from the chemical product
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Special extinguishing method
No information available
Special protective actions for fire-fighters
Use personal protective equipment as required. Firefighters should wear self-contained breathing apparatus and full
firefighting turnout gear.

Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
For indoor, provide adequate ventilation process until the end of working. Deny unnecessary entry other than the people
involved by, for example, using a rope. While working, wear appropriate protective equipments to avoid adhering it on skin,or inhaling the gas. Work from windward, and retract the people downwind.
Environmental precautions
To be careful not discharged to the environment without being properly handled waste water contaminated.
Methods and materials for contaminent and methods and materials for cleaning up
Sweep up and gather scattered particles, and collect it in an empty airtight container.
Recoverly, neutralization
No information available
Secondary disaster prevention measures
Clean contaminated objects and areas thoroughly observing environmental regulations.

Section 7: HANDLING AND STORAGEHandlingTechnical measures
Avoid contact with strong oxidizing agents. Use with local exhaust ventilation.
Precautions
Do not rough handling containers, such as upsetting, falling, giving a shock, and dragging. Prevent leakage, overflow, andscattering. Not to generate steam and dust in vain. Seal the container after use. After handling, wash hands and face, andthen gargle. In places other than those specified, should not be smoking or eating and drinking. Should not be brought
contaminated protective equipment and gloves to rest stops. Deny unnecessary entry of non-emergency personnel to thehandling area.
Safety handling precautions
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.

Storage
Safe storage conditions
Storage conditions
Safe packaging material
Incompatible substances

Store away from sunlight in well-ventilated place at room temperature (preferably cool).
Keep container tightly closed.
Polyethylene
Strong oxidizing agents

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
In case of indoor workplace, seal the source or use a local exhaust system. Provide the safety shower facility, and handand eye-wash facility. And display their position clearly.
Exposure limits

Personal protective equipment
Respiratory protection
Hand protection
Eye protection

This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.

Dust mask ( JIS T 8151 )chemical protective gloves ( JIS T 8116 )protective eyeglasses or chemical safety goggles (JIS T 8147)

Page 3 / 7W01W0119-1486 JGHEEN

Salicylic Acid

Revision date 13-Sep-2024

Long-sleeved work clothes
Skin and body protection
General hygiene considerations
Handle in accordance with good industrial hygiene and safety practice.
If this product is classified as ”Chemical Substances Hazardous to Skin, etc.”, use appropriate protective equipment tothem.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES
FormColorAppearance
Odor
Melting point/freezing point
Boiling point, initial boiling point and boiling range
Flammability
Evaporation rate:
Flammability (solid, gas):
Upper/lower flammability or explosive limits
Upper：：
Lower：：
Flash point
Auto-ignition temperature:
Decomposition temperature:
pH
Viscosity (coefficient of viscosity)
Dynamic viscosity
Solubilities
n-Octanol/water partition coefficient:(log Pow)
Vapour pressure
Specific Gravity / Relative density
Vapour density
Particle characteristics

white
crystals - crystalline powder
no data available
158 - 161 °C
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
Ethanol , acetone : free soluble . water : slightly soluble .
2.2
no data available
1.4
no data available
no data available

Section 10: STABILITY AND REACTIVITY
Stability
no data available
Reactivity
Stable under recommended storage conditions.
Chemical stability
Hazardous reactions
None under normal processing
Conditions to avoid
Extremes of temperature and direct sunlight
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Carbon monooxide (CO), Carbon dioxide (CO2)Section 11: TOXICOLOGICAL INFORMATION*NITE: National Institute of Technology and Evaluation (JAPAN)
https://www.chem-info.nite.go.jp/en/chem/chrip/chrip_search/srhInput

Acute toxicity
Chemical Name
Salicylic acid
Chemical Name
Salicylic acid

Oral LD50
891 mg/kg ( Rat )Dermal LD50
> 2000 mg/kg ( Rat )Acute toxicity -oral- source
information
Based on the NITE GHS
classification results.

Inhalation LC50
> 0.9 mg/L ( Rat ) 1 h

Acute toxicity -dermal- source Acute toxicity -inhalation gasinformation
source information
Based on the NITE GHS
Based on the NITE GHS
classification results.
classification results.

Page 4 / 7
W01W0119-1486 JGHEEN

Salicylic AcidRevision date 13-Sep-2024

Chemical Name
Salicylic acid

Acute toxicity -inhalation
vapor- source information
Based on the NITE GHS
classification results.

Acute toxicity -inhalation dust- Acute toxicity -inhalation mistsource information
source information
Based on the NITE GHS
Based on the NITE GHS
classification results.
classification results.

Skin irritation/corrosion
Skin corrosion/irritation source information
Based on the NITE GHS classification results.

Chemical Name
Salicylic acid
Serious eye damage/ irritation
Chemical Name
Salicylic acidRespiratory or skin sensitization
Chemical Name
Salicylic acid
Reproductive cell mutagenicity
Chemical Name
Salicylic acid
Carcinogenicity
Chemical Name
Salicylic acid

Serious eye damage/irritation source information
Based on the NITE GHS classification results.
Respiratory or Skin sensitization source information
Based on the NITE GHS classification results.
germ cell mutagencity source information
Based on the NITE GHS classification results.
Carcinogenicity source information
Based on the NITE GHS classification results.

Reproductive toxicity
Chemical Name
Salicylic acid

Reproductive toxicity source information
Based on the NITE GHS classification results.

Chemical Name
Salicylic acid
STOT-repeated exposure
Chemical Name
Salicylic acidAspiration hazard
Chemical Name
Salicylic acid

STOT -single exposure- source information
Based on the NITE GHS classification results.

STOT-single exposure

STOT -repeated exposure- source information
Based on the NITE GHS classification results.
Aspiration Hazard source information
Based on the NITE GHS classification results.

Section 12: ECOLOGICAL INFORMATION*NITE: National Institute of Technology and Evaluation (JAPAN)
https://www.chem-info.nite.go.jp/en/chem/chrip/chrip_search/srhInput

Ecotoxicity
Chemical Name
Salicylic acid

Algae/aquatic plants
EC50 : Pseudokirchneriellasubcapitata
65 mg/L 96 hFish
LC50 : Oryzias latipes> 100 mg/L 96 h

Crustacea
EC50 : Daphnia magna
105 mg/L 24 h
EC50 : Daphnia magna
870 mg/L 48 h

Other data
Chemical Name
Salicylic acid

Persistence and degradability
Bioaccumulative potential
Mobility in soil
Hazard to the ozone layer

Short-term (acute) hazardous to theLong-term (chronic) hazardous to theaquatic environment source information aquatic environment source information
Based on the NITE GHS classification
Based on the NITE GHS classification
results.
results.

No information available
No information available
No information available
No information available

Page 5 / 7W01W0119-1486 JGHEEN

Salicylic Acid

Revision date 13-Sep-2024

Section 13: DISPOSAL CONSIDERATIONS
Waste from residues
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated container and contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.

Section 14: TRANSPORT INFORMATION
Not regulated-ADR/RID
UN number
Proper shipping name:
UN classfication
Subsidiary hazard classPacking group
Marine pollutant

Not applicableNot regulated
IMDG
UN number
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Not applicable
Marine pollutant (Sea)Transport in bulk according to No information available
Annex II of MARPOL 73/78 andthe IBC CodeNot regulated
IATA
UN number
Proper shipping name:
UN classfication
Subsidiary hazard class
Packing group
Not applicable
Environmentally Hazardous
Substance

Section 15: REGULATORY INFORMATION
Japanese regulations
Not applicable
Fire Service Act
Not applicable
Poisonous and Deleterious
Substances Control Law
Industrial Safety and Health Act Not applicable
Industrial Safety and Health Act (2024~)
Industrial Safety and Health Act (2025~)【2024.4.1~】Chemical Substances Hazardous to Skin, etc.(Regulations Article 594-2 Paragraph 1)【2025.4.1~】Harmful Substances Whose Names Are to be Indicated on the Label (Law Art.57)【2025.4.1~】Notifiable Substances (Law Art.57-2)

Not applicable
Regulations for the carriage
and storage of dangerous
goods in ship
Not applicable
Civil Aeronautics Law
Pollutant Release and Transfer Not applicable
Register Law(2023.4.1-)
Not applicable
Export Trade Control Order

Section 16: OTHER INFORMATION

Page 6 / 7
W01W0119-1486 JGHEEN

Salicylic AcidRevision date 13-Sep-2024

Key literature references andsources for data etc.

NITE: National Institute of Technology and Evaluation (JAPAN)
https://www.chem-info.nite.go.jp/en/chem/chrip/chrip_search/srhInput
IATA dangerous Goods Regulations
RTECS:Registry of Toxic Effects of Chemical Substances
Japan Industrial Safety and Health Association GHS Model SDS
Dictionary of Synthetic Oraganic Chemistry , SSOCJ, Koudansha Scientific Co.Ltd.
Chemical Dictionary, Kyouritsu Publishing Co., Ltd.
etc

The following contents were revised. Regulatory information.
Record of SDS revisions
Disclaimer
This SDS is according to JIS Z 7253: 2019. The information provided in this Safety Data Sheet is correct to the best of ourknowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the text.
GHS Classification is according to JIS Z 7252:2019. *JIS: Japanese Industrial Standards
End of Safety Data SheetPage 7 / 7
W01W0119-1486 JGHEEN

Salicylic Acid