R J Hill Laboratories Limited
1 Clyde Street
Private Bag 3205
Hamilton 3240, New Zealand

ANALYSISREPORT

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Client:Tel +64 7 858 2000
Fax +64 7 858 2001
Email mail@hill-labs.co.nz
Web www.hill-labs.co.nz

1108823

POPJv1Lab No:Dai company (H8560i):

1-2
1-2 Ichigayadai-machi, Shinjyuku-ku, Tokyo, Japan

2013-03-08

Date Registered:(yyyy-mm-dd)

Date Reported:(yyyy-mm-dd)

2013-03-18:

JC3007-8760

Reference:

Sample Type: Food Additives and Supplements:
GPT ANT (ant powder capsule)Sample Name::

1108823.1

Lab Number:

GC
Multiresidue GC Analysis (dried/oil Cat. C samples)

No Analytes Detected

Analyst's Comments
Sample 1 Comment:
As of 25-Feb-2013 the 13 analytes listed below have been removed from the Multiresidue GC Screen:
Bupirimate, Chlorfluazuron, Cyprodinil, Fenpropimorph, Imazalil, Pirimicarb, Prochloraz, Prometryn, Pyrifenox,Pyrimethanil, Simetryn, Terbumeton, Terbutryn.
An alternative test method for these analytes is available if required. Please contact a Client Service Manager for furtherinformation.

These samples were collected by yourselves (or your agent) and analysed as received at the laboratory. This report must not be reproduced, except in full, without
the written consent of the signatory.
Refer to the following pages for method details, list of analytes screened and detection limits.

Hisashi ItoCountry Manager
Hill Laboratories
TEL 0120-817-025
email: all@hill-labs.jp(Confirmation of Receipt)

Jason Clague BSc(Tech)
Technologist - Food & Bioanalytical Division(ILAC)(IANZ)(ILAC-MRA)
This Laboratory is accredited by International Accreditation New Zealand (IANZ), which represents New Zealand in the International Laboratory Accreditation
Cooperation (ILAC). Through the ILAC Mutual Recognition Arrangement (ILAC-MRA) this accreditation is internationally recognised.
The tests reported herein have been performed in accordance with the terms of accreditation, with the exception of tests marked *, which are not accredited.

SUMMARY OF METHODS
The following table(s) gives a brief description of the methods used to conduct the analyses for this job.

Sample Type: Food Additives and Supplements
TestMethod Description
GPCGC

Multiresidue GC Analysis (dried/oil Cat. Csamples), GC-ECD/NPD

GC-MS

Ethyl acetate extraction, GPC cleanup, GC-ECD/NPD analysis. Confirmation by GC-MS.
Note: The detection limits have been raised four fold to account for a dilution required during the analysis. Sample
types that have been refined or concentrated necessitate a smaller sub-sample (5 grams compared to 20 grams
used for fresh or raw samples) to be taken for the analysis. This ensures the amounts of interferences or coextractives that may affect the analysis are kept to a minimum.
Analysis performed at Hill Laboratories - Food & Bioanalytical Division, Waikato Innovation Park, Ruakura Lane,Hamilton.

Samples are held at the laboratory after reporting for a length of time depending on the preservation used and the stability of the analytes being tested. Once thestorage period is completed the samples are discarded unless otherwise advised by the client.

: 1108823 v 1
Lab No:Hill Laboratories

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Detection Limits
Analytes

Detection Limit

Analytes

Detection Limit

Analytes

Detection Limit

0.04 mg/kg

DDT

0.02 mg/kg

GC
Multiresidue GC Analysis (dried/oil Cat. C samples)[29] Captafol[58] 4,4'-DDE

0.04 mg/kg

0.08 mg/kg[1] Acephate[30] Captan

0.08 mg/kg[31] Carbaryl

DDT

0.02 mg/kg[60] 4,4'-DDT

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg[32] Carbofenothion[3] Alachlor0.02 mg/kg

0.04 mg/kg[61] Deltamethrin (Tralomethrin)

0.04 mg/kg[62] Demeton-S-methyl

0.02 mg/kg[63] Diazinon

0.02 mg/kg[64] Dichlobenil

0.04 mg/kg[65] Dichlofenthion

0.04 mg/kg[66] Dichlofluanid

0.04 mg/kg[67] Dichloran

0.04 mg/kg[68] Dichlorvos

0.04 mg/kg[69] Dicofol

0.04 mg/kg[70] Dicrotophos

0.04 mg/kg[71] Dieldrin

0.04 mg/kg[72] Difenoconazole

0.04 mg/kg[73] Diflufenican

0.04 mg/kg[74] Dimethenamid

0.08 mg/kg[75] Dimethoate

0.08 mg/kg[76] Dimethomorph

0.04 mg/kg[77] Dimethylvinphos

0.04 mg/kg[78] Dinocap

0.04 mg/kg[79] Dioxabenzofos

0.04 mg/kg[80] Diphenylamine

0.04 mg/kg[81] Disulfoton

0.04 mg/kg[82] Diuron

0.02 mg/kg[83] Edifenphos

0.02 mg/kg[84] Endosulfan I

0.02 mg/kg[85] Endosulfan II-S-[33] Carbofuran[4] Aldrin

0.04 mg/kg[5] Atrazine

0.12 mg/kg
0.04 mg/kg[34] Carboxin

0.04 mg/kg[6] Atrazine-desethyl

cis-0.12 mg/kg

trans-0.04 mg/kg
0.08 mg/kg
0.08 mg/kg

0.12 mg/kg[39] Chlorobenzilate

0.04 mg/kg[11] Benalaxyl

0.2 mg/kg[40] Chlorothalonil

0.04 mg/kg

0.04 mg/kg[41] Chlorpropham[12] Bendiocarb

0.04 mg/kg

0.02 mg/kg[42] Chlorpyrifos[13] Benodanil

0.04 mg/kg[14] Benoxacor

0.04 mg/kg[43] Chlorpyrifos-methyl

0.02 mg/kg[15] alpha-BHC

0.04 mg/kg[44] Chlorthal-dimethyl

0.02 mg/kg[16] beta-BHC

0.04 mg/kg[45] Chlortoluron

0.02 mg/kg

0.08 mg/kg[46] Chlozolinate[17] gamma-BHC (Lindane)

BHC

0.04 mg/kg[38] Chlorfenvinphos[10] Azoxystrobin-BHC

0.04 mg/kg[37] Chlorfenapyr[9] Azinphos-methyl

BHC

0.04 mg/kg[36] trans-chlordane[8] Azaconazole

BHC

0.04 mg/kg[35] cis-Chlordane[7] Atrazine-desisopropyl

0.02 mg/kg

0.04 mg/kg[47] Clomazone[18] delta-BHC

0.04 mg/kg[19] Bifenox

0.04 mg/kg[48] Coumaphos

0.04 mg/kg[20] Bifenthrin

0.04 mg/kg
0.04 mg/kg0.08 mg/kg[51] Cyfluthrin

0.04 mg/kg

0.2 mg/kg[52] Cyhalothrin[23] Bromophos-ethyl0.04 mg/kg[24] Bromopropylate

0.08 mg/kg[53] Cypermethrin

0.04 mg/kg[25] Buprofezin

0.04 mg/kg[54] Cyproconazole

0.04 mg/kg[26] Butachlor

DDT[55] 2,4'-DDD0.04 mg/kg

DDT[56] 4,4'-DDD[27] Butamifos

0.04 mg/kg: 1108823 v 10.04 mg/kg[50] Cyanophos[22] Bromacil[28] Cadusafos

0.2 mg/kg[49] Cyanazine[21] Bitertanol

Lab No:0.02 mg/kg[59] 2,4'-DDT0.04 mg/kg[2] Acetochlor

DDTDDTI

0.02 mg/kg

II0.02 mg/kg[57] 2,4'-DDE

Hill Laboratories

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Analytes

Detection Limit

Analytes

Detection Limit

0.02 mg/kg[86] Endosulfan sulfate[115] Flusilazole

0.02 mg/kg[87] Endrin

0.04 mg/kg
0.04 mg/kg[118] Fonofos

0.04 mg/kg[119] Furalaxyl

0.08 mg/kg[91] Epoxiconazole

EPTC

0.08 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.08 mg/kg

0.02 mg/kg

0.04 mg/kg

0.02 mg/kg

0.04 mg/kg

0.02 mg/kg

0.08 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.12 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.08 mg/kg

0.04 mg/kg

0.08 mg/kg

0.04 mg/kg

0.04 mg/kg

0.08 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.04 mg/kg

0.08 mg/kg

0.2 mg/kg

0.04 mg/kg[167] Permethrin

0.04 mg/kg

0.04 mg/kg[139] Malathion

0.04 mg/kg[111] Fluazifop-butyl

0.04 mg/kg[166] Pendimethalin[138] Linuron[110] Fenvalerate

0.04 mg/kg[165] Penconazole[137] Leptophos[109] Fenthion

0.04 mg/kg[164] Parathion-methyl[136] Kresoxim-methyl[108] Fensulfothion

0.04 mg/kg[163] Parathion-ethyl[135] Isoprocarb[107] Fenpropathrin

0.04 mg/kg[162] Paclobutrazol[134] Isofenphos[106] Fenpiclonil

0.04 mg/kg[161] Oxyfluorfen[133] Isazophos[105] Fenoxaprop-ethyl

0.02 mg/kg[160] Oxychlordane[132] Iprodione[104] Fenobucarb

0.04 mg/kg[159] Oxadixyl[131] Iprobenfos[103] Fenitrothion

0.04 mg/kg[158] Oxadiazon[130] Iodofenphos[102] Fenchlorphos

0.12 mg/kg[157] Omethoate[129] Indoxacarb[101] Fenarimol

0.04 mg/kg[156] Norflurazon[128] Hexythiazox[100] Fenamiphos

0.04 mg/kg[155] Nitrothal-isopropyl[127] Hexazinone[99] Famphur

0.04 mg/kg[154] Nitrofen[126] Hexaconazole[98] Etrimfos

0.08 mg/kg[153] Napropamide[125] Hexachlorobenzene[97] Etridiazole

0.12 mg/kg[152] Naled[124] Heptachlor epoxide[96] Ethoprophos

0.04 mg/kg[151] Myclobutanil[123] Heptachlor[95] Ethion

0.04 mg/kg[150] Monocrotophos[122] Haloxyfop-methyl[94] Esprocarb

0.04 mg/kg[149] Mevinphos[121] Halfenprox[93] Esfenvalerate

0.04 mg/kg[148] Metribuzin[120] Furathiocarb[92] EPTC

0.04 mg/kg[147] Metolachlor

0.04 mg/kg[90] EPN

0.02 mg/kg[146] Methoxychlor0.02 mg/kg

EPN

0.08 mg/kg[145] Methiocarb[117] Folpet[89] Endrin ketone

0.08 mg/kg

0.08 mg/kg

0.02 mg/kg

Detection Limit[144] Methidathion[116] Flutriafol[88] Endrin Aldehyde

Analytes

0.08 mg/kg

0.04 mg/kg[168] Phenthoate

0.08 mg/kg[140] Mepronil

0.08 mg/kg[169] Phorate

0.04 mg/kg

0.08 mg/kg[112] Flucythrinate

0.08 mg/kg[170] Phosalone

0.08 mg/kg[141] Metalaxyl (Mefenoxam)[113] Fludioxonil

0.04 mg/kg

0.04 mg/kg
0.04 mg/kg[171] Phosmet

0.08 mg/kg[172] Phosphamidon[142] Methacrifos[114] Fluometuron

0.04 mg/kg[143] Methamidophos: 1108823 v 1
Lab No:Hill Laboratories

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Analytes

Detection Limit

Analytes

Detection Limit

0.08 mg/kg[173] Piperonyl-butoxide

0.04 mg/kg[202] Terbufos

0.04 mg/kg[174] Pirimiphos-methyl0.04 mg/kg[203] Terbuthylazine

0.04 mg/kg[175] Procymidone

0.04 mg/kg[204] Terbuthylazine-desethyl0.04 mg/kg[176] Profenofos

0.04 mg/kg[205] Tetrachlorvinphos

0.08 mg/kg[177] Propachlor

0.04 mg/kg[206] Tetradifon

0.04 mg/kg[178] Propanil

0.04 mg/kg[207] Thenylchlor

0.04 mg/kg[179] Propaphos

0.04 mg/kg[208] Thiobencarb

0.2 mg/kg[180] Propargite

0.08 mg/kg[209] Thiometon

0.04 mg/kg[181] Propazine

0.04 mg/kg[210] Tolclofos-methyl0.04 mg/kg[182] Propetamphos

0.04 mg/kg[211] Tolylfluanid

0.04 mg/kg[183] Propham

0.04 mg/kg[212] Triadimefon

0.04 mg/kg[184] Propiconazole

0.08 mg/kg[213] Triallate)

0.08 mg/kg[185] Propoxur

0.04 mg/kg[214] Triazophos

0.04 mg/kg[186] Propyzamide

0.08 mg/kg[215] Trifloxystrobin

0.04 mg/kg[187] Prothiofos

0.04 mg/kg[216] Trifluralin0.08 mg/kg[188] Pyraclofos

0.08 mg/kg[217] Vinclozolin

0.04 mg/kg[189] Pyrazophos

0.08 mg/kg[190] Pyrazoxyfen

0.12 mg/kg[191] Pyrethrin

0.08 mg/kg[192] Pyriproxyfen

0.04 mg/kg[193] Quinalphos

0.04 mg/kg[194] Quintozene

0.04 mg/kg[195] Quizalofop-ethyl0.04 mg/kg[196] Simazine

0.04 mg/kg[197] Sulfentrazone

0.04 mg/kg[198] Sulfotep

0.04 mg/kg[199] Tebuconazole

0.04 mg/kg[200] Tebufenpyrad

0.04 mg/kg[201] Terbacil: 1108823 v 1
Lab No:Hill Laboratories

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