Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada

PD-MSDS-00005
Issue Date: 01/30/2018

Version :SAFETY DATA SHEETOragene●ONE ON-500, ON-500.xxx, ON-600

Section 1. Identification
GHS product identifier
Other means ofidentification
Product type: Oragene●ONE ON-500, ON-500.xxx, ON-600: Not available.
: Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Identified uses

: Stabilization of DNA in collection kit.

Supplier/Manufacturer: DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc.
3000 - 500 Palladium Drive
Ottawa, ON, Canada K2V 1C2
Tel: +1-613-723-5757
Fax: +1-613-723-5057
Toll Free: +1-866-813-6354 (North America)
Toll Free: +1-613-723-5757 (all other countries)
Email: support@dnagenotek.com
Web site: www.dnagenotek.com

Emergency telephone
number (with hours ofoperation): For Emergencies involving dangerous goods call
Canutec’s 24-hour number 613-996-6666Section 2. Hazards identification
OSHA/HCS status
Classification of thesubstance or mixture: This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).
: FLAMMABLE LIQUIDS - Category 3
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

GHS label elements
Hazard pictograms:

Signal word
Hazard statements: Warning: H226 - Flammable liquid and vapor.
H319 - Causes serious eye irritation.

Precautionary statements

2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 2. Hazards identification
Prevention

Response

Storage
DisposalHazards not otherwiseclassified: P280 - Wear protective gloves. Wear eye or face protection.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 - Use explosion-proof electrical, ventilating, lighting and all material-handlingequipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P233 - Keep container tightly closed.
P264 - Wash hands thoroughly after handling.
: P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water or shower.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.
: P403 - Store in a well-ventilated place.
P235 - Keep cool.
: P501 - Dispose of contents and container in accordance with all local, regional, national
and international regulations.
: None known.

Section 3. Composition/information on ingredients
Substance/mixture
Other means ofidentification: Mixture: Not available.

Ingredient name%

CAS number

Ethanol<24

64-17-5

Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, areclassified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures
Description of necessary first aid measures
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20
minutes. Get medical attention.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If notbreathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,tie, belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Skin contact: Flush contaminated skin with plenty of water. Get medical attention if symptoms occur.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 4. First aid measures
Ingestion: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air andkeep at rest in a position comfortable for breathing. If material has been swallowed andthe exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse healtheffects persist or are severe. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact: Causes serious eye irritation.
Inhalation: No known significant effects or critical hazards.
Skin contact: No known significant effects or critical hazards.
Ingestion: No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact: Adverse symptoms may include the following:
pain or irritationwatering
redness
Inhalation: No known significant effects or critical hazards.
Skin contact: No known significant effects or critical hazards.
Ingestion: No known significant effects or critical hazards.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments: No specific treatment.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11)

Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishingmedia
Unsuitable extinguishingmedia
Specific hazards arisingfrom the chemical: Use dry chemical, CO2, water spray (fog) or foam.
: Do not use water jet or water-based fire extinguishers.

: Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In afire or if heated, a pressure increase will occur and the container may burst, with the riskof a subsequent explosion.

2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 5. Fire-fighting measures
Hazardous thermal
decomposition products: Decomposition products may include the following materials:
carbon dioxidecarbon monoxide
nitrogen oxides
metal oxide/oxides

Special protective actions
for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel frompersonnel
entering. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up
Spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place incontainer for disposal according to local regulations (see Section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage
Precautions for safe handlingProtective measures: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only withadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in theoriginal container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting andmaterial handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue and2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 7. Handling and storage
can be hazardous. Do not reuse container.
Advice on general
occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage,
including any
incompatibilities: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see Section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 forincompatible materials before handling or use.

Section 8. Exposure controls/personal protection
Control parameters
United States
Occupational exposure limits
Ingredient name

Exposure limits

Ethanol

ACGIH TLV (United States, 3/2017).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.

CanadaOccupational exposure limits
Ingredient name

Exposure limits

Ethanol

CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1000 ppm 8 hours.
8 hrs OEL: 1880 mg/m³ 8 hours.
CA British Columbia Provincial (Canada, 7/2016).
STEL: 1000 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
STEL: 1000 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 1000 ppm 8 hours.
TWAEV: 1880 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.

Appropriate engineering
controls

Environmental exposure
controls: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation.

2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 8. Exposure controls/personal protection
Individual protection measures
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unlessthe assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, theprotection time of the gloves cannot be accurately estimated.
Body protection: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothingshould include anti-static overalls, boots and gloves.
Other skin protection: Appropriate footwear and any additional skin protection measures should be selectedbased on the task being performed and the risks involved and should be approved by aspecialist before handling this product.
Respiratory protection: Based on the hazard and potential for exposure, select a respirator that meets theappropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties
Appearance
Physical state
Color
Odor
Odor threshold
pH
Melting point
Boiling point
Flash point
Evaporation rate
Flammability (solid, gas)
Lower and upper explosive(flammable) limits
Vapor pressure
Vapor density
Relative density: Liquid.
: Not available.
: Not available.
: Not available.
: 9.5: Not available.
: Not available.
: Closed cup: 32°C (89.6°F) [Pensky-Martens.]: Not available.
: Not available.
: Not available.
: Not available.
: Not available.
: Not available.

2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 9. Physical and chemical properties
Solubility
Partition coefficient: noctanol/water
Auto-ignition temperature
Decomposition temperature
Viscosity
Flow time (ISO 2431): Not available.
: Not available.
: Not available.
: Not available.
: Not available.
: Not available.

Section 10. Stability and reactivity
Reactivity: No specific test data related to reactivity available for this product or its ingredients.

Chemical stability: The product is stable.

Possibility of hazardous
reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials: Reactive or incompatible with the following materials: oxidizing materials.

Hazardous decomposition
products: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient nameResultSpecies

Dose

Exposure

Ethanol

LC50 Inhalation Vapor
LD50 Oral

Rat
Rat

124700 mg/m³
7 g/kg4 hours-

Irritation/Corrosion
Product/ingredient nameResultSpecies

Score

Exposure

Observation

Ethanol

Eyes - Mild irritantEyes - Moderate irritant

RabbitRabbit--Eyes - Moderate irritantEyes - Severe irritant
Skin - Mild irritant

RabbitRabbitRabbit-24 hours 500 mg
0.066666667
minutes 100 mg
100 µl500 mg
400 mg-Sensitization
There is no data available.
Mutagenicity
There is no data available.
Carcinogenicity
There is no data available.
Reproductive toxicity
There is no data available.
2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 11. Toxicological information
Teratogenicity
There is no data available.
Specific target organ toxicity (single exposure)
There is no data available.
Specific target organ toxicity (repeated exposure)
There is no data available.
Aspiration hazard
There is no data available.
Information on the likely
routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.

Potential acute health effects
Eye contact: Causes serious eye irritation.
Inhalation: No known significant effects or critical hazards.
Skin contact: No known significant effects or critical hazards.
Ingestion: No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact: Adverse symptoms may include the following:
pain or irritationwatering
redness
Inhalation: No known significant effects or critical hazards.
Skin contact: No known significant effects or critical hazards.
Ingestion: No known significant effects or critical hazards.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate: No known significant effects or critical hazards.
effects
Potential delayed effects: No known significant effects or critical hazards.
Long term exposure
Potential immediate: No known significant effects or critical hazards.
effects
Potential delayed effects: No known significant effects or critical hazards.
Potential chronic health effects
General: No known significant effects or critical hazards.
Carcinogenicity: No known significant effects or critical hazards.
Mutagenicity: No known significant effects or critical hazards.
Teratogenicity: No known significant effects or critical hazards.
Developmental effects: No known significant effects or critical hazards.
Fertility effects: No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Section 11. Toxicological information
There is no data available.

Section 12. Ecological information
Toxicity
Product/ingredient nameResultSpecies

Exposure

Ethanol

Acute EC50 1074 mg/L Fresh water
Acute LC50 5680 mg/L Fresh water
Acute LC50 11000000 µg/L Marine water
Chronic NOEC 4.995 mg/L Marine water
Chronic NOEC 100 ul/L Fresh water
Chronic NOEC 0.375 ul/L Fresh water

Crustaceans - Cypris subglobosa
Daphnia - Daphnia magna - Neonate
Fish - Alburnus alburnus
Algae - Ulva pertusa
Daphnia - Daphnia magna - Neonate
Fish - Gambusia holbrooki - Larvae

48 hours
48 hours
96 hours
96 hours
21 days
12 weeks

Persistence and degradability
There is no data available.
Bioaccumulative potential
Product/ingredient name

LogPow

BCF

Potential

Ethanol

-0.35

-

low

Mobility in soil
Soil/water partition
coefficient (KOC): Not available.

Other adverse effects: No known significant effects or critical hazards.

Section 13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Disposalof this product, solutions and any by-products should comply with the requirements ofenvironmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste
disposal contractor. Waste should not be disposed of untreated to the sewer unlessfully compliant with the requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Careshould be taken when handling empty containers that have not been cleaned or rinsed
out. Empty containers or liners may retain some product residues. Vapor from productresidues may create a highly flammable or explosive atmosphere inside the container.
Do not cut, weld or grind used containers unless they have been cleaned thoroughlyinternally. Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers.

2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Version :Section 14. Transport information
DOT Classification

TDG Classification

IMDG

IATA

UN number

Not regulated.

Not regulated.

Not regulated.

Not regulated.

UN proper
shipping name

-

-

-

-

Transport
hazard class(es)

-

-

-

Packing group

-

-

-

-

Environmental
hazards

No.

No.

No.

No.
AERG : Not applicable.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Section 15. Regulatory information
U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.

Clean Air Act Section 112(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602
Class I Substances: Not listed

Clean Air Act Section 602
Class II Substances: Not listed

DEA List I Chemicals(Precursor Chemicals): Not listed

DEA List II Chemicals(Essential Chemicals): Not listed: Not listed

SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ
SARA 311/312
Classification: Not applicable.

: FLAMMABLE LIQUIDS - Category 3
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2AComposition/information on ingredients2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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Version :Section 15. Regulatory information
NameClassification

Ethanol

FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

SARA 313
There is no data available.
State regulations
Massachusetts: The following components are listed: Ethanol
New York: None of the components are listed.
New Jersey: The following components are listed: Ethanol
Pennsylvania: The following components are listed: Ethanol
California Prop. 65
No products were found.
CanadaCanadian lists
Canadian NPRICEPA Toxic substances
Canada inventory (DSL
NDSL): The following components are listed: Ethanol: None of the components are listed.
: All components are listed or exempted.

Section 16. Other information
Procedure used to derive the classification
Classification
FLAMMABLE LIQUIDS - Category 3
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2AJustification
On basis of test data
Calculation method

History
Date of issue mm/dd/yyyy
Date of previous issue
VersionPrepared by: 01/30/2018: 07/15/2015: 4: KMK Regulatory Services Inc.

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

2018 DNA Genotek Inc., a subsidiary of OraSure Technologies, Inc., 3000 - 500 Palladium Drive, Ottawa, ON, Canada K2V 1C2
Emergency Tel.: 613.996.6666 ● Tel.: 613.723.5757 ● www.dnagenotek.com

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