エイチ・シー・スタルク株式会社 クレビオス製品群
Clevios® P Grades
商品名

用途

導電率

粘度
mPas at 100 S-1
60~10020~100
15~30
>200

特記事項
もっとも基本的なグレードで顧客で自らフォーミュレートしないとコーティング困難。
少々導電率が高いがスタルクとしては、あまりお勧めしない(agfa社製品)。
光学特性を上げるため導電率を少し犠牲にしている。
固形分が高いという以外、基本的な導電性はClevios Pと同様。

Clevios® P
Clevios® P AG
Clevios® PH
Clevios® P HS

帯電防止の原料（全ての用途）
帯電防止の原料（全ての用途）
光学用途での帯電防止剤として高い固形分でペーストの原料として

S/cm~1 (80)~3 (200)~0.3 (65)~1

Clevios® P HC V4
Clevios® P H 500
Clevios® P H 510

高導電タイプの原料（ITOの代替）
高導電タイプの原料（ITOの代替）
高導電タイプの原料（ITOの代替）~5-10 (400)~1 (400-550)~1 (400-550)

100~350
8~25
20~100高導電材料の原料（自らフォーミュレートが必要。）
高導電材料の原料（自らフォーミュレートが必要。）
高導電材料の原料（自らフォーミュレートが必要。）PH500の固形分が高いタイプ

Clevios® P VP Al 4083
Clevios® P VP CH 8000

有機EL又は有機太陽電池
有機EL（パッシブ用）又は有機太陽電池

~10-3
-5
~10

30
20

比較的低抵抗のタイプ
クロストークを防ぐため比較的高抵抗

Clevios® P JET
Clevios® P JET HC
Clevios® P JET N
Clevios® P JET HC V2

インクジェット用途
インクジェット用途（比較的導電率が高いタイプ）
P JETの中性化タイプ
電材用途でインクジェット、高導電タイプ~10-3~50-9030-90min. 300(+5%DMSO)8-1
20 (700 S )8 - 185 - 15

インクジェット用として開発
インクジェット用として開発
インクジェット用として開発
インクジェット用として開発

Clevios® Formulations
商品名Clevios® F 141 M
Clevios® F PVA
Clevios® F CPP 105DM
Clevios® F E
Clevios® S HT
Clevios® S V3

商品名Clevios® P AI 4083 LVW 142
Clevios® P AI 4083 LVW 825
Clevios® P CH 8000 LVW 176
Clevios® P CH 8000 LVW 185
Clevios® P CH 8000 LVW 419

用途
耐溶剤タイプ、帯電防止用途
熱成型材料、帯電防止用途
導電コーティング
ITO代替用途
スクリーンペースト、無機EL用途（光学特性がよい）
スクリーンペースト、無機EL用途

用途
AI 4083の脱イオン品、有機EL並びに太陽電池
AI 4083の脱イオン品、限外ろ過品
PEDOT:PSS が1: 16 脱イオン品、有機EL並びに太陽電池
CH 8000の脱イオン品、限外ろ過品
CH 8000の脱イオン品、限外ろ過品

表面抵抗
6 µm wet 0,1 Mohm/sq.
18 µm wet 3 Kohm/sq.
18 µm wet 2 Kohm/sq.
12 µm wet 340 ohm/sq.
テストプリント < 1200ohm/sq
テストプリント< 700ohm/sq

粘度mPas at 100 S-1
20 - 60
10 - 50
10 - 30
3 - 5 dPas
15 - 200 dPas

Clevios® Special garde
導電率
粘度
S/cm
mPas at 100 S-1
-3
~10
30
-3
30
~10
-5
20
~10
-5
20
~10
~10-5
20

特記事項
レディートゥユーズ、このままコーティングが可能。
レディートゥユーズ、このままコーティングが可能。
レディートゥユーズ、このままコーティングが可能。
レディートゥユーズ、このままコーティングが可能。
レディートゥユーズ、このままコーティングが可能。〈粘度が高い）
レディートゥユーズ、このままコーティングが可能。〈粘度が高い）

特記事項
顧客の要求（指定）がない限り販売できない。（特殊品）
顧客の要求（指定）がない限り販売できない。（特殊品）
顧客の要求（指定）がない限り販売できない。（特殊品）
顧客の要求（指定）がない限り販売できない。（特殊品）
顧客の要求（指定）がない限り販売できない。（特殊品）

SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name:

CLEVIOS™ P

Use of the
Substance/Preparation:

Optical-Industry

Company:

H. C. Starck GmbHIm Schleeke 78-91
38642 Goslar / Germany

Responsible Department
Telephone
E-mail address
Emergency telephone

:
:
:
:

Central Support Services – Product Safety+49(0)5321/751-0
infoSDS@hcstarck.com+49(0)5321/751-0

2. HAZARDS IDENTIFICATIONClassification
No classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Aqueous solution

Hazardous components
Chemical Name
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

CAS-No.

EC-No.

155090-83-8

424-490-4

Symbol(s)R-phrase(s)

Xi

R41

Concentration[%]
1.3

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
If inhaled:

Remove to fresh air.
If symptoms persist, call a physician.

In case of skin contact:

Wash off with soap and water.
In the case of skin irritation or allergic reactions see a physician.

In case of eye contact:

Rinse with plenty of water.
If eye irritation persists, consult a specialist.

If swallowed:

Clean mouth with water and drink afterwards plenty of water.
Obtain medical attention.

000010001596

1/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media

:

Not combustible.
Extinguishing methods depends upon fire in vicinity poses.

Extinguishing media whichshall not be used for safety
reasons:

None known.

Special exposure hazards
arising from the substanceor preparation itself,
combustion products,
resulting gases:

None known.

Special protective
equipment for fire-fighters:

No special protective equipment required.

Additional advice:

None known.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Ventilate the area.
Use personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).
Fill into labelled, sealable containers.

:

No special precautions required.

Requirements for storage
areas and containers:

Comply with the directives governing water law

Further information on
storage conditions:

Store in original container.

7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values
Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate); CAS-No.: 155090-83-8
Basis000010001596:

EH40 (UK)2/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P
Version 2.0
Note

Revision Date 08.04.2008:

Print Date 14.04.2008

No limit value established.

Personal protective equipment
Hand protection:

Glove material: Butyl-rubber, Viton
After contamination with product change the gloves immediately andremove them according to relevant national and local regulations.

Eye protection:

Safety glasses

Body Protection:

Do not get on skin or clothing.

General protective measures:

Handle in accordance with good industrial hygiene and safety
practice.

9. PHYSICAL AND CHEMICAL PROPERTIES
AppearanceForm:liquidColour:dark blue

Odour

:

very faint:ca. 1 - 2
at 20 °C

- Pour point:

ca. 0 °C-:ca. 100 °C

Vapour pressure:

23.00 hPa
at 20 °C

Density:

1.0032 g/cm3
at 20 °C:completely miscible

Conditions to avoid:

None known.

Materials to avoid:

None known.

Thermal decomposition:

No decomposition up to 100 °C

Hazardous decomposition
products:

No decomposition if stored normally.
Formation of carbon dioxide (CO2) and carbon monoxide (CO) during
thermal decomposition.

Safety data
pH

Change in physical state

Solubility- Water solubility

10. STABILITY AND REACTIVITY

000010001596

3/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

11. TOXICOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Acute oral toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Skin irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Eye irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Sensitisation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Repeated dose toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

Genotoxicity in vitro
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

LD50 rat > 2,500 mg/kg
Method: Directive 67/548/EEC Annex V, B.1.tris.

:

rabbitNo skin irritation
Method: Directive 67/548/EEC, Annex V, B.4.

:

rabbitRisk of serious damage to eyes.
Method: Directive 67/548/EEC, Annex V, B.5.

:

Maximisation Test guinea pig
Did not cause sensitization on laboratory animals.
Method: Directive 67/548/EEC, Annex V, B.6.

:

rat OralExposure time: 28-day
NOEL: 272 mg/kg
Method: Directive 67/548/EEC, Annex V, B.7.

:

Ames test
Salmonella typhimurium
No indication of mutagenic effects.
Method: Directive 67/548/EEC, Annex V, B.14.
Chromosome aberration test in vitro
Chinese Hamster V79 cells
No indication of mutagenic effects.
Method: No information available.

12. ECOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Toxicity to fish
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Brachydanio rerio (zebra fish)
96 h NOEC >= 100 mg/l
Method: Directive 67/548/EEC, Annex V, C.1.

Toxicity to daphnia and other aquatic invertebrates.
Poly(3,4: Daphnia magna (Water flea)
ethylenedioxythiophene)48 h NOEC >= 100 mg/lpoly(styrenesulfonate)
Method: Directive 67/548/EEC, Annex V, C.2.
Toxicity to algae

000010001596

4/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P
Version 2.0

Revision Date 08.04.2008

Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Biodegradability
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Desmodesmus subspicatus
72 h ErC50 54 mg/l
Method: Directive 67/548/EEC, Annex V, C.3.

:

Not readily biodegradable.

Print Date 14.04.2008

13. DISPOSAL CONSIDERATIONS
Product:

The Federal, regional and local rules and regulations governing
disposal must be complied with.
This product is cannot be classified with disposal identification key
acc. to the EU disposal directives as a classification results from theintended utilisation purpose of the consumer

Packaging:

Packaging that is not contaminated and has been cleaned can berecycled.

14. TRANSPORT INFORMATIONLand transport ADR/RID
Not dangerous goods
Air transport ICAO-TI/IATA-DGR
Not dangerous goods
Sea transport IMDG
Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EC Directives
Directive 1999/45/EC
No labelling required

National legislation
Major Accident Hazard
Legislation:

96/82/EC
Annex I
Number: Is not subject to the Seveso II Directive.

16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R41000010001596

Risk of serious damage to eyes.
5/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid forsuch material used in combination with any other materials or in any process, unless specified in the text.
The above details do not imply any guarantee concerning composition, properties or performance.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

000010001596

6/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AG
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name:

CLEVIOS™ P AG

Use of the
Substance/Preparation:

Electrical Industry and Electronics

Company:

H. C. Starck GmbHIm Schleeke 78-91
38642 Goslar / Germany

Responsible Department
Telephone
E-mail address
Emergency telephone

:
:
:
:

Central Support Services – Product Safety+49(0)5321/751-0
infoSDS@hcstarck.com+49(0)5321/751-0

2. HAZARDS IDENTIFICATIONClassification
No classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Aqueous solution

Hazardous components
Chemical Name
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

CAS-No.

EC-No.

155090-83-8

424-490-4

Symbol(s)R-phrase(s)

Xi

R41

Concentration[%]
1.2

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
If inhaled:

Remove to fresh air.
If symptoms persist, call a physician.

In case of skin contact:

Wash off with soap and water.
In the case of skin irritation or allergic reactions see a physician.

In case of eye contact:

Rinse with plenty of water.
If eye irritation persists, consult a specialist.

If swallowed:

Clean mouth with water and drink afterwards plenty of water.
Obtain medical attention.

000010002072

1/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AG
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media

:

Not combustible.
Extinguishing methods depends upon fire in vicinity poses.

Extinguishing media whichshall not be used for safety
reasons:

None known.

Special exposure hazards
arising from the substanceor preparation itself,
combustion products,
resulting gases:

None known.

Special protective
equipment for fire-fighters:

No special protective equipment required.

Additional advice:

None known.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Ventilate the area.
Use personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).
Fill into labelled, sealable containers.

:

No special precautions required.

Requirements for storage
areas and containers:

Comply with the directives governing water law

Further information on
storage conditions:

Store in original container.

7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values
Personal protective equipment
000010002072

2/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AG
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

Hand protection:

Glove material: Butyl-rubber, Viton
After contamination with product change the gloves immediately andremove them according to relevant national and local regulations.

Eye protection:

Safety glasses

Body Protection:

Do not get on skin or clothing.

General protective measures:

Handle in accordance with good industrial hygiene and safety
practice.

9. PHYSICAL AND CHEMICAL PROPERTIES
AppearanceForm:liquidColour:dark blue

Odour

:

very faint:ca. 1 - 2
at 20 °C

- Pour point:

ca. 0 °C-:ca. 100 °C

Vapour pressure:

23.00 hPa
at 20 °C

Density:ca. 1.0028 g/cm3
at 20 °C:completely miscible

Conditions to avoid:

None known.

Materials to avoid:

None known.

Thermal decomposition:

No decomposition up to 100 °C

Hazardous decomposition
products:

No decomposition if stored normally.
Formation of carbon dioxide (CO2) and carbon monoxide (CO) during
thermal decomposition.

Safety data
pH

Change in physical state

Solubility- Water solubility

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION
000010002072

3/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AG
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

For risk assessment data of relevant ingredients:
Acute oral toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Skin irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Eye irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Sensitisation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Repeated dose toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

Genotoxicity in vitro
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

LD50 rat > 2,500 mg/kg
Method: Directive 67/548/EEC Annex V, B.1.tris.

:

rabbitNo skin irritation
Method: Directive 67/548/EEC, Annex V, B.4.

:

rabbitRisk of serious damage to eyes.
Method: Directive 67/548/EEC, Annex V, B.5.

:

Maximisation Test guinea pig
Did not cause sensitization on laboratory animals.
Method: Directive 67/548/EEC, Annex V, B.6.

:

rat OralExposure time: 28-day
NOEL: 272 mg/kg
Method: Directive 67/548/EEC, Annex V, B.7.

:

Ames test
Salmonella typhimurium
No indication of mutagenic effects.
Method: Directive 67/548/EEC, Annex V, B.14.
Chromosome aberration test in vitro
Chinese Hamster V79 cells
No indication of mutagenic effects.
Method: No information available.

12. ECOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Toxicity to fish
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Brachydanio rerio (zebra fish)
96 h NOEC >= 100 mg/l
Method: Directive 67/548/EEC, Annex V, C.1.

Toxicity to daphnia and other aquatic invertebrates.
Poly(3,4: Daphnia magna (Water flea)
ethylenedioxythiophene)48 h NOEC >= 100 mg/lpoly(styrenesulfonate)
Method: Directive 67/548/EEC, Annex V, C.2.
Toxicity to algae
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Desmodesmus subspicatus
72 h ErC50 54 mg/l
Method: Directive 67/548/EEC, Annex V, C.3.

Biodegradability

000010002072

4/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AG
Version 2.0

Revision Date 08.04.2008

Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Print Date 14.04.2008

Not readily biodegradable.

13. DISPOSAL CONSIDERATIONS
Product:

The Federal, regional and local rules and regulations governing
disposal must be complied with.
This product is cannot be classified with disposal identification key
acc. to the EU disposal directives as a classification results from theintended utilisation purpose of the consumer

Packaging:

Packaging that is not contaminated and has been cleaned can berecycled.

14. TRANSPORT INFORMATIONLand transport ADR/RID
Not dangerous goods
Air transport ICAO-TI/IATA-DGR
Not dangerous goods
Sea transport IMDG
Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EC Directives
Directive 1999/45/EC
No labelling required

National legislation
Major Accident Hazard
Legislation:

96/82/EC
Annex I
Number: Is not subject to the Seveso II Directive.

16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R41

Risk of serious damage to eyes.

Further information

000010002072

5/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AG
Version 2.0

Revision Date 08.04.2008

Print Date 14.04.2008

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid forsuch material used in combination with any other materials or in any process, unless specified in the text.
The above details do not imply any guarantee concerning composition, properties or performance.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

000010002072

6/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P HC V4
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name:

CLEVIOS™ P HC V4

Use of the
Substance/Preparation:

Electrical Industry and Electronics

Company:

H. C. Starck GmbHIm Schleeke 78-91
38642 Goslar / Germany

Responsible Department
Telephone
E-mail address
Emergency telephone

:
:
:
:

Central Support Services – Product Safety+49(0)5321/751-0
infoSDS@hcstarck.com+49(0)5321/751-0

2. HAZARDS IDENTIFICATIONClassification
No classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Aqueous solution

Hazardous components
Chemical Name
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

CAS-No.

EC-No.

155090-83-8

424-490-4

Symbol(s)R-phrase(s)

Xi

R41

Concentration[%]
1.3

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
If inhaled:

Remove to fresh air.
If symptoms persist, call a physician.

In case of skin contact:

Wash off with soap and water.
In the case of skin irritation or allergic reactions see a physician.

In case of eye contact:

Rinse with plenty of water.
If eye irritation persists, consult a specialist.

If swallowed:

Clean mouth with water and drink afterwards plenty of water.
Obtain medical attention.

000010002186

1/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P HC V4
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media

:

Not combustible.
Extinguishing methods depends upon fire in vicinity poses.

Extinguishing media whichshall not be used for safety
reasons:

None known.

Special exposure hazards
arising from the substanceor preparation itself,
combustion products,
resulting gases:

None known.

Special protective
equipment for fire-fighters:

No special protective equipment required.

Additional advice:

None known.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Ventilate the area.
Use personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).
Fill into labelled, sealable containers.

:

No special precautions required.

Requirements for storage
areas and containers:

Comply with the directives governing water law

Further information on
storage conditions:

Store in original container.

7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values
Personal protective equipment
000010002186

2/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P HC V4
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

Hand protection:

Glove material: Butyl-rubber, Viton
After contamination with product change the gloves immediately andremove them according to relevant national and local regulations.

Eye protection:

Safety glasses

Body Protection:

Do not get on skin or clothing.

General protective measures:

Handle in accordance with good industrial hygiene and safety
practice.

9. PHYSICAL AND CHEMICAL PROPERTIES
AppearanceForm:liquidColour:dark blue

Odour

:

very faint:ca. 1 - 2
at 20 °C

- Pour point:

ca. 0 °C-:ca. 100 °C

Vapour pressure:

23.00 hPa
at 20 °C

Density:ca. 1.0032 g/cm3
at 20 °C:completely miscible

Conditions to avoid:

None known.

Materials to avoid:

None known.

Thermal decomposition:

No decomposition up to 100 °C

Hazardous decomposition
products:

No decomposition if stored normally.
Formation of carbon dioxide (CO2) and carbon monoxide (CO) during
thermal decomposition.

Safety data
pH

Change in physical state

Solubility- Water solubility

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION
000010002186

3/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P HC V4
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

For risk assessment data of relevant ingredients:
Acute oral toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Skin irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Eye irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Sensitisation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Repeated dose toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

Genotoxicity in vitro
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

LD50 rat > 2,500 mg/kg
Method: Directive 67/548/EEC Annex V, B.1.tris.

:

rabbitNo skin irritation
Method: Directive 67/548/EEC, Annex V, B.4.

:

rabbitRisk of serious damage to eyes.
Method: Directive 67/548/EEC, Annex V, B.5.

:

Maximisation Test guinea pig
Did not cause sensitization on laboratory animals.
Method: Directive 67/548/EEC, Annex V, B.6.

:

rat OralExposure time: 28-day
NOEL: 272 mg/kg
Method: Directive 67/548/EEC, Annex V, B.7.

:

Ames test
Salmonella typhimurium
No indication of mutagenic effects.
Method: Directive 67/548/EEC, Annex V, B.14.
Chromosome aberration test in vitro
Chinese Hamster V79 cells
No indication of mutagenic effects.
Method: No information available.

12. ECOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Toxicity to fish
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Brachydanio rerio (zebra fish)
96 h NOEC >= 100 mg/l
Method: Directive 67/548/EEC, Annex V, C.1.

Toxicity to daphnia and other aquatic invertebrates.
Poly(3,4: Daphnia magna (Water flea)
ethylenedioxythiophene)48 h NOEC >= 100 mg/lpoly(styrenesulfonate)
Method: Directive 67/548/EEC, Annex V, C.2.
Toxicity to algae
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Desmodesmus subspicatus
72 h ErC50 54 mg/l
Method: Directive 67/548/EEC, Annex V, C.3.

Biodegradability

000010002186

4/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P HC V4
Version 2.0

Revision Date 08.04.2008

Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Print Date 07.05.2008

Not readily biodegradable.

13. DISPOSAL CONSIDERATIONS
Product:

The Federal, regional and local rules and regulations governing
disposal must be complied with.
This product is cannot be classified with disposal identification key
acc. to the EU disposal directives as a classification results from theintended utilisation purpose of the consumer

Packaging:

Packaging that is not contaminated and has been cleaned can berecycled.

14. TRANSPORT INFORMATIONLand transport ADR/RID
Not dangerous goods
Air transport ICAO-TI/IATA-DGR
Not dangerous goods
Sea transport IMDG
Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EC Directives
Directive 1999/45/EC
No labelling required

National legislation
Major Accident Hazard
Legislation:

96/82/EC
Annex I
Number: Is not subject to the Seveso II Directive.

16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R41

Risk of serious damage to eyes.

Further information

000010002186

5/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P HC V4
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid forsuch material used in combination with any other materials or in any process, unless specified in the text.
The above details do not imply any guarantee concerning composition, properties or performance.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

000010002186

6/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ PH 500
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name:

CLEVIOS™ PH 500

Use of the
Substance/Preparation:

Optical-Industry

Company:

H. C. Starck GmbHIm Schleeke 78-91
38642 Goslar / Germany

Responsible Department
Telephone
E-mail address
Emergency telephone

:
:
:
:

Central Support Services – Product Safety+49(0)5321/751-0
infoSDS@hcstarck.com+49(0)5321/751-0

2. HAZARDS IDENTIFICATIONClassification
No classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Aqueous solution

Hazardous components
Chemical Name
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

CAS-No.

EC-No.

155090-83-8

424-490-4

Symbol(s)R-phrase(s)

Xi

R41

Concentration[%]
1.3

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
If inhaled:

Remove to fresh air.
If symptoms persist, call a physician.

In case of skin contact:

Wash off with soap and water.
In the case of skin irritation or allergic reactions see a physician.

In case of eye contact:

Rinse with plenty of water.
If eye irritation persists, consult a specialist.

If swallowed:

Clean mouth with water and drink afterwards plenty of water.
Obtain medical attention.

000010002361

1/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ PH 500
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media

:

Not combustible.
Extinguishing methods depends upon fire in vicinity poses.

Extinguishing media whichshall not be used for safety
reasons:

None known.

Special exposure hazards
arising from the substanceor preparation itself,
combustion products,
resulting gases:

None known.

Special protective
equipment for fire-fighters:

No special protective equipment required.

Additional advice:

None known.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Ventilate the area.
Use personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).
Fill into labelled, sealable containers.

:

No special precautions required.

Requirements for storage
areas and containers:

Comply with the directives governing water law

Further information on
storage conditions:

Store in original container.

7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values
Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate); CAS-No.: 155090-83-8
Basis000010002361:

EH40 (UK)2/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ PH 500
Version 2.0
Note

Revision Date 08.04.2008:

Print Date 07.05.2008

No limit value established.

Personal protective equipment
Hand protection:

Glove material: Butyl-rubber, Viton
After contamination with product change the gloves immediately andremove them according to relevant national and local regulations.

Eye protection:

Safety glasses

Body Protection:

Do not get on skin or clothing.

General protective measures:

Handle in accordance with good industrial hygiene and safety
practice.

9. PHYSICAL AND CHEMICAL PROPERTIES
AppearanceForm:liquidColour:dark blue

Odour

:

odourless:ca. 1 - 2
at 20 °C-:ca. 100 °C

Density:

1.0032 g/cm3
at 20 °C:completely miscible

Conditions to avoid:

None known.

Materials to avoid:

None known.

Thermal decomposition:

No decomposition up to 100 °C

Hazardous decomposition
products:

No decomposition if stored normally.
Formation of carbon dioxide (CO2) and carbon monoxide (CO) during
thermal decomposition.

Safety data
pH

Change in physical state

Solubility- Water solubility

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION

000010002361

3/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ PH 500
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

For risk assessment data of relevant ingredients:
Acute oral toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Skin irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Eye irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Sensitisation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Repeated dose toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

Genotoxicity in vitro
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

LD50 rat > 2,500 mg/kg
Method: Directive 67/548/EEC Annex V, B.1.tris.

:

rabbitNo skin irritation
Method: Directive 67/548/EEC, Annex V, B.4.

:

rabbitRisk of serious damage to eyes.
Method: Directive 67/548/EEC, Annex V, B.5.

:

Maximisation Test guinea pig
Did not cause sensitization on laboratory animals.
Method: Directive 67/548/EEC, Annex V, B.6.

:

rat OralExposure time: 28-day
NOEL: 272 mg/kg
Method: Directive 67/548/EEC, Annex V, B.7.

:

Ames test
Salmonella typhimurium
No indication of mutagenic effects.
Method: Directive 67/548/EEC, Annex V, B.14.
Chromosome aberration test in vitro
Chinese Hamster V79 cells
No indication of mutagenic effects.
Method: No information available.

12. ECOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Toxicity to fish
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Brachydanio rerio (zebra fish)
96 h NOEC >= 100 mg/l
Method: Directive 67/548/EEC, Annex V, C.1.

Toxicity to daphnia and other aquatic invertebrates.
Poly(3,4: Daphnia magna (Water flea)
ethylenedioxythiophene)48 h NOEC >= 100 mg/lpoly(styrenesulfonate)
Method: Directive 67/548/EEC, Annex V, C.2.
Toxicity to algae
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Desmodesmus subspicatus
72 h ErC50 54 mg/l
Method: Directive 67/548/EEC, Annex V, C.3.

Biodegradability

000010002361

4/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ PH 500
Version 2.0

Revision Date 08.04.2008

Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Print Date 07.05.2008

Not readily biodegradable.

13. DISPOSAL CONSIDERATIONS
Product:

The Federal, regional and local rules and regulations governing
disposal must be complied with.
This product is cannot be classified with disposal identification key
acc. to the EU disposal directives as a classification results from theintended utilisation purpose of the consumer

Packaging:

Packaging that is not contaminated and has been cleaned can berecycled.

14. TRANSPORT INFORMATIONLand transport ADR/RID
Not dangerous goods
Air transport ICAO-TI/IATA-DGR
Not dangerous goods
Sea transport IMDG
Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EC Directives
Directive 1999/45/EC
No labelling required

National legislation
Major Accident Hazard
Legislation:

96/82/EC
Annex I
Number: Is not subject to the Seveso II Directive.

16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R41

Risk of serious damage to eyes.

Further information

000010002361

5/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ PH 500
Version 2.0

Revision Date 08.04.2008

Print Date 07.05.2008

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid forsuch material used in combination with any other materials or in any process, unless specified in the text.
The above details do not imply any guarantee concerning composition, properties or performance.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

000010002361

6/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AP.AI 4083
Version 2.0

Revision Date 08.04.2008

Print Date 04.06.2008

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name:

CLEVIOS™ P AP.AI 4083

Use of the
Substance/Preparation:

Optical-Industry

Company:

H. C. Starck GmbHIm Schleeke 78-91
38642 Goslar / Germany

Responsible Department
Telephone
E-mail address
Emergency telephone

:
:
:
:

Central Support Services – Product Safety+49(0)5321/751-0
infoSDS@hcstarck.com+49(0)5321/751-0

2. HAZARDS IDENTIFICATIONClassification
No classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Aqueous solution

Hazardous components
Chemical Name
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

CAS-No.

EC-No.

155090-83-8

424-490-4

Symbol(s)R-phrase(s)

Xi

R41

Concentration[%]<= 1.3For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
If inhaled:

Remove to fresh air.
If symptoms persist, call a physician.

In case of skin contact:

Wash off with soap and water.
In the case of skin irritation or allergic reactions see a physician.

In case of eye contact:

Rinse with plenty of water.
If eye irritation persists, consult a specialist.

If swallowed:

Clean mouth with water and drink afterwards plenty of water.
Obtain medical attention.

000010001593

1/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AP.AI 4083
Version 2.0

Revision Date 08.04.2008

Print Date 04.06.2008

5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media

:

Not combustible.
Extinguishing methods depends upon fire in vicinity poses.

Extinguishing media whichshall not be used for safety
reasons:

None known.

Special exposure hazards
arising from the substanceor preparation itself,
combustion products,
resulting gases:

None known.

Special protective
equipment for fire-fighters:

No special protective equipment required.

Additional advice:

None known.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Ventilate the area.
Use personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).
Fill into labelled, sealable containers.

:

No special precautions required.

Requirements for storage
areas and containers:

Comply with the directives governing water law

Further information on
storage conditions:

Store in original container.

7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values
Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate); CAS-No.: 155090-83-8
Basis000010001593:

EH40 (UK)2/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AP.AI 4083
Version 2.0
Note

Revision Date 08.04.2008:

Print Date 04.06.2008

No limit value established.

Personal protective equipment
Hand protection:

Glove material: Butyl-rubber, Viton
After contamination with product change the gloves immediately andremove them according to relevant national and local regulations.

Eye protection:

Safety glasses

Body Protection:

Do not get on skin or clothing.

General protective measures:

Handle in accordance with good industrial hygiene and safety
practice.

9. PHYSICAL AND CHEMICAL PROPERTIES
AppearanceForm:liquidColour

:

blue

Odour

:

odourless:

1.5 - 2.5-:

ca. 100 °C

Vapour pressure:

23.00 hPa
at 20 °C

Density:ca. 1 g/cm3
at 20 °C:completely miscible

Conditions to avoid:

None known.

Materials to avoid:

None known.

Thermal decomposition:

No decomposition up to 100 °C

Hazardous decomposition
products:

No decomposition if stored normally.
Formation of carbon dioxide (CO2) and carbon monoxide (CO) during
thermal decomposition.

Safety data
pH
Change in physical state

Solubility- Water solubility

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION
000010001593

3/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AP.AI 4083
Version 2.0

Revision Date 08.04.2008

Print Date 04.06.2008

For risk assessment data of relevant ingredients:
Acute oral toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Skin irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Eye irritation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Sensitisation
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)
Repeated dose toxicity
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

Genotoxicity in vitro
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

LD50 rat > 2,500 mg/kg
Method: Directive 67/548/EEC Annex V, B.1.tris.

:

rabbitNo skin irritation
Method: Directive 67/548/EEC, Annex V, B.4.

:

rabbitRisk of serious damage to eyes.
Method: Directive 67/548/EEC, Annex V, B.5.

:

Maximisation Test guinea pig
Did not cause sensitization on laboratory animals.
Method: Directive 67/548/EEC, Annex V, B.6.

:

rat OralExposure time: 28-day
NOEL: 272 mg/kg
Method: Directive 67/548/EEC, Annex V, B.7.

:

Ames test
Salmonella typhimurium
No indication of mutagenic effects.
Method: Directive 67/548/EEC, Annex V, B.14.
Chromosome aberration test in vitro
Chinese Hamster V79 cells
No indication of mutagenic effects.
Method: No information available.

12. ECOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Toxicity to fish
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Brachydanio rerio (zebra fish)
96 h NOEC >= 100 mg/l
Method: Directive 67/548/EEC, Annex V, C.1.

Toxicity to daphnia and other aquatic invertebrates.
Poly(3,4: Daphnia magna (Water flea)
ethylenedioxythiophene)48 h NOEC >= 100 mg/lpoly(styrenesulfonate)
Method: Directive 67/548/EEC, Annex V, C.2.
Toxicity to algae
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Desmodesmus subspicatus
72 h ErC50 54 mg/l
Method: Directive 67/548/EEC, Annex V, C.3.

Biodegradability

000010001593

4/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AP.AI 4083
Version 2.0

Revision Date 08.04.2008

Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate):

Print Date 04.06.2008

Not readily biodegradable.

13. DISPOSAL CONSIDERATIONS
Product:

The Federal, regional and local rules and regulations governing
disposal must be complied with.
This product is cannot be classified with disposal identification key
acc. to the EU disposal directives as a classification results from theintended utilisation purpose of the consumer

Packaging:

Packaging that is not contaminated and has been cleaned can berecycled.

14. TRANSPORT INFORMATIONLand transport ADR/RID
Not dangerous goods
Air transport ICAO-TI/IATA-DGR
Not dangerous goods
Sea transport IMDG
Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EC Directives
Directive 1999/45/EC
No labelling required

National legislation
Major Accident Hazard
Legislation:

96/82/EC
Annex I
Number: Is not subject to the Seveso II Directive.

16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R41

Risk of serious damage to eyes.

Further information

000010001593

5/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ P AP.AI 4083
Version 2.0

Revision Date 08.04.2008

Print Date 04.06.2008

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid forsuch material used in combination with any other materials or in any process, unless specified in the text.
The above details do not imply any guarantee concerning composition, properties or performance.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

000010001593

6/6

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

RD CLEVIOS™ S HT
Version 1.0

Revision Date 30.04.2008

Print Date 04.06.2008

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name:

RD CLEVIOS™ S HT

Use of the
Substance/Preparation:

Electrical Industry and Electronics

Company:

H.C. Starck GmbHIm Schleeke 78 - 91
38642 Goslar
Germany

Telephone
Responsible Department
E-mail address
Emergency telephone

:
:
:
:

+49(0)5321/751-0
Corporate HSEQ & SIS - Product Safety
infoSDS@hcstarck.com+49(0)5321/751-0

2. HAZARDS IDENTIFICATIONClassification
No classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Preparation

Hazardous components
Chemical Name
2,2'-Oxydiethanol
Propane-1,2-diol
1-Octanol

CAS-No.
111-46-6
57-55-6
111-87-5

EC-No.
203-872-2
200-338-0
203-917-6

Symbol(s)R-phrase(s)

Xn

R22

Xi

R36

Concentration
[%]
<= 15
70
<= 1

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
If inhaled:

Remove to fresh air.

In case of skin contact:

Wash off immediately with soap and plenty of water.

In case of eye contact:

Rinse with plenty of water.
If eye irritation persists, consult a specialist.

If swallowed:

Clean mouth with water and drink afterwards plenty of water.
Obtain medical attention.

000010003945

1/5

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

RD CLEVIOS™ S HT
Version 1.0

Revision Date 30.04.2008

Print Date 04.06.2008

5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media

:

Not combustible.
Extinguishing methods depends upon fire in vicinity poses.

Extinguishing media whichshall not be used for safety
reasons:

None known.

Special exposure hazards
arising from the substanceor preparation itself,
combustion products,
resulting gases:

In case of fire may be formed:
Carbon monoxide - Extremely flammable, Toxic
Carbon Dioxide - Gas is heavier than air. Act as an asphyxiant at highconcentrations.

Special protective
equipment for fire-fighters:

In the event of fire, wear self-contained breathing apparatus.

Additional advice:

Prevent fire extinguishing water from contaminating surface water or
the ground water system.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Ventilate the area.
Use personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).
Fill into labelled, sealable containers.

:

No special precautions required.

Requirements for storage
areas and containers:

Comply with the directives governing water law

Further information on
storage conditions:

Store in original container.
Keep containers tightly closed in a dry, cool and well-ventilated place.

7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values
2,2'-Oxydiethanol; CAS-No.: 111-46-6000010003945

2/5

SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

RD CLEVIOS™ S HT
Version 1.0
Basis
Threshold limits
TWA

Revision Date 30.04.2008:

EH40 (UK):

101 mg/m3
23 ppmPrint Date 04.06.2008

Propane-1,2-diol, Total Vapour And Particulates; CAS-No.: 57-55-6
Basis
Threshold limits
TWA:

EH40 (UK):474 mg/m3
150 ppm:

TRGS 900:

106 mg/m3
20 ml/m3
1(I)AGS

1-Octanol; CAS-No.: 111-87-5
BasisThreshold limits

Ceiling limit
Note

:
:

2,2'-Oxydiethanol; CAS-No.: 111-46-6
Basis
Note

:
:

OEL (EU)No limit value established.

Propane-1,2-diol, Total Vapour And Particulates; CAS-No.: 57-55-6
Basis
Note

:
:

OEL (EU)No limit value established.

Personal protective equipment
Hand protection:

Glove material: Butyl-rubber, Viton
After contamination with product change the gloves immediately andremove them according to relevant national and local regulations.

Eye protection:

Safety glasses

Body Protection:

Do not get on skin or clothing.

General protective measures:

Handle in accordance with good industrial hygiene and safety
practice. Wash hands before breaks and immediately after handlingthe product.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form

:

paste

Colour

:

blue

Odour

:

very faint:ca. 1.5
at 20 °C

Safety data
pH

Change in physical state

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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

RD CLEVIOS™ S HT
Version 1.0

Revision Date 30.04.2008

Print Date 04.06.2008- Boiling point/boilingrange:

ca. 100 °C

Density:

1.058 g/cm3
at 20 °C:

2,000 mPa.s
at 20 °C

Conditions to avoid:

None known.

Materials to avoid:

None known.

Thermal decomposition:

not applicable

Hazardous decomposition
products:

No hazardous decomposition products are known.

Viscosity- Viscosity, dynamic

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATIONNo toxicology information is available.

12. ECOLOGICAL INFORMATION
No information on ecology is available.

13. DISPOSAL CONSIDERATIONS
Product:

The Federal, regional and local rules and regulations governing
disposal must be complied with.
This product is cannot be classified with disposal identification key
acc. to the EU disposal directives as a classification results from theintended utilisation purpose of the consumer

Packaging:

Packaging that is not contaminated and has been cleaned can berecycled.

14. TRANSPORT INFORMATIONLand transport ADR/RID
Not dangerous goods
Air transport ICAO-TI/IATA-DGR
Not dangerous goods
Sea transport IMDG
Not dangerous goods
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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

RD CLEVIOS™ S HT
Version 1.0

Revision Date 30.04.2008

Print Date 04.06.2008

15. REGULATORY INFORMATION
Labelling according to EC Directives
Directive 1999/45/EC
No labelling required

16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R22
R36

Harmful if swallowed.
Irritating to eyes.

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid forsuch material used in combination with any other materials or in any process, unless specified in the text.
The above details do not imply any guarantee concerning composition, properties or performance.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ S V3
Version 1.0

Revision Date 29.04.2008

Print Date 04.06.2008

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name:

CLEVIOS™ S V3

Use of the
Substance/Preparation:

Electrical Industry and Electronics

Company:

H.C. Starck GmbHIm Schleeke 78 - 91
38642 Goslar
Germany

Telephone
Responsible Department
E-mail address
Emergency telephone

:
:
:
:

+49(0)5321/751-0
Corporate HSEQ & SIS - Product Safety
infoSDS@hcstarck.com+49(0)5321/751-0

2. HAZARDS IDENTIFICATIONClassification
No classification

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Preparation

Hazardous components
Chemical Name
Propane-1,2-diol
2,2'-Oxydiethanol
Poly(3,4ethylenedioxythiophene)poly(styrenesulfonate)

CAS-No.

EC-No.

57-55-6
111-46-6
155090-83-8

200-338-0
203-872-2
424-490-4

Symbol(s)R-phrase(s)

Xn
Xi

R22
R41

Concentration
[%]
65.6
<= 15
1.1

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES
If inhaled:

Remove to fresh air.

In case of skin contact:

Wash off immediately with soap and plenty of water.

In case of eye contact:

Rinse with plenty of water.
If eye irritation persists, consult a specialist.

If swallowed:

Clean mouth with water and drink afterwards plenty of water.
Obtain medical attention.

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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ S V3
Version 1.0

Revision Date 29.04.2008

Print Date 04.06.2008

5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media

:

Not combustible.
Extinguishing methods depends upon fire in vicinity poses.

Extinguishing media whichshall not be used for safety
reasons:

None known.

Special exposure hazards
arising from the substanceor preparation itself,
combustion products,
resulting gases:

In case of fire may be formed:
Carbon monoxide - Extremely flammable, Toxic
Carbon Dioxide - Gas is heavier than air. Act as an asphyxiant at highconcentrations.
sulfuric oxides (SOx) - Toxic, Corrosive

Special protective
equipment for fire-fighters:

In the event of fire, wear self-contained breathing apparatus.

Additional advice:

Prevent fire extinguishing water from contaminating surface water or
the ground water system.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Ventilate the area.
Use personal protective equipment.

Environmental precautions:

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).
Fill into labelled, sealable containers.

:

No special precautions required.

Requirements for storage
areas and containers:

Comply with the directives governing water law

Further information on
storage conditions:

Store in original container.
Keep containers tightly closed in a dry, cool and well-ventilated place.

7. HANDLING AND STORAGE
Handling
Advice on protection against
fire and explosion

Storage

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values
Propane-1,2-diol, Total Vapour And Particulates; CAS-No.: 57-55-6000010002437

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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ S V3
Version 1.0
Basis
Threshold limits
TWA

Revision Date 29.04.2008:

EH40 (UK):474 mg/m3
150 ppm

Print Date 04.06.2008

2,2'-Oxydiethanol; CAS-No.: 111-46-6
BasisThreshold limits
TWA:

EH40 (UK):

101 mg/m3
23 ppmPoly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate); CAS-No.: 155090-83-8
Basis
Note

:
:

EH40 (UK)No limit value established.

Propane-1,2-diol, Total Vapour And Particulates; CAS-No.: 57-55-6
Basis
Note

:
:

OEL (EU)No limit value established.

2,2'-Oxydiethanol; CAS-No.: 111-46-6
Basis
Note

:
:

OEL (EU)No limit value established.

Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate); CAS-No.: 155090-83-8
Basis
Note

:
:

OEL (EU)No limit value established.

Personal protective equipment
Respiratory protection:

Respiratory protection when aerosols and vapours occur. Respiratory
protective device with particle filter EN 143

Hand protection:

Glove material: Butyl-rubber, Viton
After contamination with product change the gloves immediately andremove them according to relevant national and local regulations.

Eye protection:

Safety glasses

Body Protection:

Do not get on skin or clothing.

General protective measures:

Handle in accordance with good industrial hygiene and safety
practice. Wash hands before breaks and immediately after handlingthe product.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form

:

paste

Colour

:

blue

Odour

:

slightSafety data

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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ S V3
Version 1.0
pH

Revision Date 29.04.2008

Print Date 04.06.2008:

1.5
at 20 °C

- Boiling point/boilingrange:

ca. 105 °C

Density:ca. 1.06 g/cm3
at 20 °C:completely miscible:

ca. 2,000 mPa.s
at 20 °C

Conditions to avoid:

None known.

Materials to avoid:

None known.

Thermal decomposition:

no data available

Hazardous decomposition
products:

No hazardous decomposition products are known.

Change in physical state

Solubility- Water solubility
Viscosity- Viscosity, dynamic

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Acute oral toxicity:

no data available

Skin irritation:

no data available

Eye irritation:

no data available

Sensitisation:

no data available

Genotoxicity in vitro:

no data available

12. ECOLOGICAL INFORMATION
For risk assessment data of relevant ingredients:
Toxicity to fish:

no data available

Toxicity to daphnia andother aquatic invertebrates.
Toxicity to algae:

no data available:

no data available

Biodegradability:

no data available

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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ S V3
Version 1.0

Revision Date 29.04.2008

Print Date 04.06.2008

13. DISPOSAL CONSIDERATIONS
Product

Packaging:

The Federal, regional and local rules and regulations governing
disposal must be complied with.

:This product is cannot be classified with disposal identification key
acc. to the EU disposal directives as a classification results from theintended utilisation purpose of the consumer:

Packaging that is not contaminated and has been cleaned can berecycled.

14. TRANSPORT INFORMATIONLand transport ADR/RID
Not dangerous goods
Air transport ICAO-TI/IATA-DGR
Not dangerous goods
Sea transport IMDG
Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EC Directives
Directive 1999/45/EC
No labelling required

National legislation
Major Accident Hazard
Legislation:

96/82/EC
Annex I
Number: Is not subject to the Seveso II Directive.

16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R22
R41

Harmful if swallowed.
Risk of serious damage to eyes.

Further information

000010002437

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SDB_GB (EN)SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006

CLEVIOS™ S V3
Version 1.0

Revision Date 29.04.2008

Print Date 04.06.2008

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information andbelief at the date of its publication. The information given is designed only as a guidance for safe handling,use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid forsuch material used in combination with any other materials or in any process, unless specified in the text.
The above details do not imply any guarantee concerning composition, properties or performance.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

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SDB_GB (EN)