J. Inst. Electrostat. Jpn.

, 30, 1 (2006) 14 19㜞ಽሶ☳૕⹜ᢱߩ࿕᦭ᾲೝỗ㔚ᵹࠬࡍࠢ࠻࡞ዉ಴ᳰ㦮๺↵㧖㧘᧛↰㓶ม㧖㧖㧔 ᐕ  ᦬  ᣣฃઃ㧧 ᐕ  ᦬  ᣣฃℂ㧕Derivation of Intrinsic Thermally Stimulated Current Spectraof Polymeric Powder Samples
Kazuo IKEZAKI* and Yuji MURATA**(Received August 1, 2005; Accepted October November 11, 2005)
For polymeric powder samples, we proposed a general method to obtain their intrinsic thermally stimulated current(TSC) spectra, ITSC, from which erroneous TSC component due to change in sample thickness during TSC observationwas eliminated. The method utilizes a current signal Iobs obtained experimentally from current TSD with an air gap ora voltage signal Vobs obtained from charge TSD in open-circuit, sample thickness d of powder samples and relative
dielectric constantǭr of their matrix polymers . In both cases using Iobs or Vobs, derivation of ITSC is executed by anapproximation of iteration. As a trial, we applied this method to a binder resin of toner for copiers and also to a powder
paint for electrostatic powder coating. Computed spectra for these powder samples were found to converge practicallyto their intrinsic TSC spectra within 5times iterative calculations for the resin and 2 times for the paint, respectively.
ࠆ㧘⹜ᢱߩෘߐᄌൻߩᓇ㗀ߦߟ޿ߡߪႎ๔ 2)ỊẳỜỆᾲೝỗ㔚ᵹ㧔TSC㧕ࠬࡍࠢ࠻࡞ࠬࠦࡇ࡯ߪㅢᏱࡈࠖ࡞ࡓ

ߐࠇߡ޿ࠆ߇㧘ታ㔚⩄ TSC ߢߪోߊ໧㗴ߦߐࠇߡ޿ߥ޿㧚⁁⹜ᢱߦ૶ࠊࠇࠆ㧚ߎࠇࠍ㧘ⶄ౮ᯏ↪࠻࠽࡯߿㕒㔚☳૕Ⴃ৻ᣇ㧘☳૕⹜ᢱߢߪ TSC ᷹ቯਛߩ⹜ᢱෘߐߩᄌൻ߇⪺ߒⵝ↪Ⴃᢱߥߤ㜞ಽሶ☳૕♽ߦㆡ↪ߔࠆߣ߈ߪ㧘☳૕⹜ᢱ♽ߊᄢ߈ߊ㧘ߎߩᓇ㗀ߪήⷞߢ߈ߥ޿ߣ⠨߃㧘⹜ᢱ☳૕ጀෘ․᦭ߩ໧㗴ࠍᬌ⸛ߒߡ߅ߊᔅⷐ߇޽ࠆ㧚৻ߟߪ㧘ౣ⃻ᕈߢᄌൻߩᓇ㗀ࠍ㒰ߊ TSC ࠬࡍࠢ࠻࡞ୃᱜᴺߦߟ޿ߡ৻ߟߩ

޽ࠅ㧘߽߁৻ߟߪ㧘TSC ᷹ቯਛߩ⹜ᢱ☳૕ጀᾲᄌᒻߩᓇ㗀⹜ߺ 3, 4) ࠍႎ๔ߒߚ㧚ߒ߆ߒ㧘ߘߩୃᱜᴺߪ㧘᳞߼ࠆߴ߈ߢ޽ࠆ㧚⹜ᢱ☳૕࿕᦭ TSC ࠬࡍࠢ࠻࡞߇㧘ੑߟߩୃᱜࠬࡍࠢ࠻࡞ߩ

ታ㔚⩄ TSC ߢߪ㧘࠻࡜࠶ࡊߐࠇߡ޿ߚ㔚⩄ߩ⣕࠻࡜࠶ࡊ޽޿ߛߦ޽ࠆߎߣࠍ␜ߔߛߌߩ߽ߩߢ޽ߞߚ㧚ߣߘࠇߦ⛯ߊ⣕࠻࡜࠶ࡊ㔚⩄ߩ⒖േ߇ਇนᰳߢ޽ࠆ߇㧘㔚ᧄ⎇ⓥߪ㧘ߎߩ⹜ᢱ☳૕ጀෘᄌൻߩ໧㗴ࠍࠃࠅ৻⥸⊛ߦ⩄ャㅍㆊ⒟߇☳૕ጀߩ☸ሶలႯ᭴ㅧߦଐሽߔࠆߩߢౣ⃻ᕈᛒ޿㧘᷹ⷰߐࠇߚ TSC ࠺࡯࠲߆ࠄ㧘෻ᓳ⸘▚ᴺ (iteration) ߩ߇ૐ޿ߣ⠨߃߇ߜߢ޽ࠆ㧚ߒ߆ߒ㧘⛘✼ᕈ㜞ಽሶ☳૕⹜ᢱㄭૃߦࠃࠅ৻ߟߩୃᱜࠬࡍࠢ࠻࡞ߦ෼᧤ߐߖࠆᣇᴺߦ㑐ߔߩ TSC ߢߪ㧘㔚⩄ャㅍㆊ⒟ߪᓞㅦㆊ⒟ߢߪߥߊ㧘☳૕♽ࠆ߽ߩߢ޽ࠆ㧚1)TSC ߩౣ⃻ᕈߪᭂ߼ߡࠃ޿ߎߣࠍႎ๔ ߒߚ㧚ߘߎߢ㧘ᰴߦᬌ⸛ߔߴ߈⺖㗴ߪ TSC ᷹ቯਛߦ↢ߓࠆ⹜ᢱ㧞㧚ӒࣄᚘምඥỆợỦ ᵲᵱᵡ ἋἬἁἚἽ‫ݰ‬Ј☳૕ጀෘߩᄌൻ߇ TSC ߦਈ߃ࠆᓇ㗀ߦߟ޿ߡߢ޽ࠆ㧚߹ߚ㧘㜞ಽሶ☳૕♽ߦ೑↪ߢ߈ࠆ㧘ታ㔚⩄ TSC ᷹ቯ࿁〝ߪ࿑㧝ߘߩᓇ㗀ࠍขࠅ㒰޿ߡ⹜ᢱ☳૕࿕᦭ TSC (intrinsic TSC) ࠍa ߦ␜ߔ㐿࿁〝 TSC㧔open-circuit TSC㧕ߣ㧘࿑㧝b ߩ㔚⩄ዉ಴ߔࠆߎߣߢ޽ࠆ㧚ࡈࠖ࡞ࡓ⁁⹜ᢱߩ෺ᭂሶ TSC ߦਈ߃TSD ߩ᷹ቯ࿁〝ߦ㒢ࠄࠇࠆ㧚࿑ 1b ߩ࿁〝ߢ㧘⹜ᢱ⴫㕙ߣ਄ㇱ㔚ᭂ㑆ߩ㑆㓒ࠍ๟ᦼ⊛ߦᄌൻߐߖࠆߣ㧘⹜ᢱ⴫㕙㔚૏ỿὊὁὊἛ㧦ᾲೝỗ㔚ᵹ㧘࿕᦭ࠬࡍࠢ࠻࡞㧘㜞ಽሶ☳૕㧘⹜ᢱෘߐ㧘෻ᓳ⸘▚ᴺㄭૃߣ਄ㇱ㔚ᭂ㔚૏߇⇣ߥࠆߣ߈ߪ⹜ᢱ࡮਄ㇱ㔚ᭂ㑆㔚⇇߇㔖ߢߥ޿ߚ߼㧘ᄖㇱ࿁〝ߦ੤ᵹ㔚ᵹ߇ᵹࠇࠆ㧚੤ᵹ㔚ᵹᬌ಴㧖ᘮᔕ⟵Ⴖᄢቇ (108-8345 ᧲੩ㇺ᷼඙ਃ↰ 2-15-45)
Keio University, 2-15-45, Minato-ku, Tokyo, 108-8345
Japan ikezaki@khaki.plala.or.jpᵹࠍᬌ಴ߒ㧘ߘࠇ߇㔖ߦߥࠆࠃ߁ߦ㧘⋥ᵹ㔚࿶⊒↢ེߢ૞**ࠄࠇߚࡃࠗࠕࠬ㔚࿶ࠍ㔚ᭂ㑆ߦශടߔࠆ㧚⹜ᢱ⴫㕙㔚૏ߪ

᧲੩ℂ⑼ᄢቇℂᎿቇㇱ(278-8510 ජ⪲⋵㊁↰Ꮢጊፒ 2641) Faculty of Science and Technology, Tokyo
University of Science, 2641, Yamazaki, Noda 278-8510 Japan
murata@ee.noda.tus.ac.jp࿁〝 (࿑ 1b ߦߪߎߩ࿁〝ߪ⋭⇛ߐࠇߡ޿ࠆ)ߢߎߩ੤ᵹ㔚ߘߩߣ߈ߩࡃࠗࠕࠬ㔚࿶߆ࠄ᳞߼ࠄࠇࠆ㧚㔚⩄ TSD ࠬࡍࠢ࠻࡞ߪ㧘ߎߩࠃ߁ߦߒߡ᳞߼ߚ⹜ᢱ⴫㕙㔚૏ࠍ᷷ᐲߩ㑐ᢙ

15Iobs߱ߎߣߦߔࠆ㧚☳૕☸ሶ߅ࠃ߮ⓨ᳇ߩ㧞⋧᭴ㅧߢ޽ࠆ⹜ᢱ☳૕ጀߩෘߐ

ldd ߇᷷ᐲߦࠃࠅᄌൻߔࠇ߫㧘☳૕ጀߩలႯ₸߽ᄌൻߔࠆߚ

VAITSC߼㧘⹜ᢱ☳૕ጀߩᲧ⺃㔚₸ǭ㨗߽ᄌൻߔࠆ㧚ߒߚ߇ߞߡ㧘(2)ᑼ߆ࠄࠊ߆ࠆࠃ߁ߦ㧘ᗵᐲଥᢙ J ߪ⹜ᢱ᷷ᐲ਄᣹ߦߣ߽ߥ޿ᄌൻߔࠆ㧚a. 㐿࿁〝 TSC ᷹ቯ࿁b㔚⩄ 65& ᷹ቯ࿁〝࿑㧝 ☳૕⹜ᢱ᷹ቯ↪࿁〝
Fig.1 Measuring circuit for powder samples.

⹜ᢱ☳૕࿕᦭ߩ TSC ࠍ ITSC , ࿑㧝a ߩ㐿࿁〝♽ߢ᷹ⷰߐࠇࠆ㔚ᵹࠍ Iobs ߣ߅߈㧘⹜ᢱ᣹᷷ㅦᐲࠍEߩ৻ቯㅦᐲߣߔࠇ߫㧘ߣߒߡ޽ࠄࠊߒߚ߽ߩߢ޽ࠆ㧚ࡃࠗࠕࠬ㔚࿶ߪ਄ㇱ㔚ᭂߦශടߔࠆ႐วߣਅㇱ㔚ᭂߦශടߔࠆ႐ว߇⠨߃ࠄࠇࠆ㧚ࡈࠖ࡞ࡓ⁁⹜ᢱߢߪ㧘㖸ᵄߦ

E dQ / dTITSC

dQ / dt

I obs

dQind / dt

(4)

 E dQind / dT

(5)ࠃࠅ⹜ᢱࠍ⋥ធᝄേߐߖߡ⹜ᢱ࡮਄ㇱ㔚ᭂ㑆〒㔌ࠍ๟ᦼ⊛ߢ޽ࠆ㧚(3)ᑼࠍ᷷ᐲ T ߢᓸಽߒ㧘(4), (5)ߩ㑐ଥࠍ૶߁ߣᰴߦᄌൻߐߖࠆߎߣ߇น⢻ߥߩߢ㧘ࡃࠗࠕࠬ㔚࿶ࠍ⹜ᢱਅㇱᑼ߇ᓧࠄࠇࠆ㧚㔚ᭂߦශടߒߡ㧘੤ᵹ㔚ᵹߪ਄ㇱ㔚ᭂߢᬌ಴ߔࠆߣ޿߁ᣇ5)ᴺ߇⍮ࠄࠇߡ޿ࠆ㧚߹ߚ㧘ࡃࠗࠕࠬ㔚࿶ߪ਄ㇱ㔚ᭂߦශടߒߡ㧘਄ㇱ㔚ᭂਛᄩㇱߦ㐿ߌߚዊⓣߦᝄേ㔚ᭂࠍ⟎߈੤ᵹ㔚ᵹࠍᬌ಴ߒߡࡃࠗࠕࠬ㔚࿶ࠍ೙ᓮߔࠆᣇᴺ 6)ߥߤ߇޽
ࠆ㧚☳૕⹜ᢱߦኻߒߡ㧘Ꮢ⽼ߩ㕖ធ⸅ဳ⴫㕙㔚૏⸘ࠍߘߩ߹߹೑↪ߒߚ㔚⩄ TSD ߩ⹜ⴕ଀ 7) ߽ႎ๔ߐࠇߡ޿ࠆ㧚ᧄ⎇ⓥߢߪ㧘㜞ಽሶ☳૕⹜ᢱߦኻߒߡ࿑㧝a ߅ࠃ߮࿑㧝bߩ㧘ੑߟߩ᷹ቯ♽ߢ᷹ⷰߐࠇࠆ㔚ᵹାภ߅ࠃ߮㔚࿶ାภ߆ࠄ㧘⹜ᢱ☳૕☸ሶ࿕᦭ߩ TSC ࠬࡍࠢ࠻࡞ࠍዉ಴ߔࠆᣇᴺߦId ln J obs  E QJdTI TSC(6)᷷ᐲߩ㑐ᢙߣߒߡ Iobs, J , Q߇ࠊ߆ࠇ߫㧘(6)ᑼ߆ࠄ

⹜ᢱ࿕᦭ߩ TSC ࠬࡍࠢ࠻࡞߇ᓧࠄࠇࠆ㧚(6)ᑼߩ Q ߪ᷷ᐲ T ߢ⹜ᢱߦᱷሽߔࠆ㔚⩄㊂ߥߩߢᰴᑼߢਈ߃ࠄࠇࠆ㧚

1 ª TF³QT«
E ¬ T0I TSC dT 

³TT0ºI TSC dT »

(7)¼ߟ޿ߡ⠨߃ࠆ㧚
2.1(7)ᑼฝㄝߩ T0 ߅ࠃ߮ TF ߪ㧘ߘࠇߙࠇ㧘TSC ᷹ቯ㐿ᆎ᷷ᐲ᧏‫ׅ‬ែ ᵲᵱᵡ ย‫ܭ‬ኒ߅ࠃ᷹߮ⷰߐࠇࠆ TSC ߇㔖ߦߥࠆ TSC ⚳ੌ᷷ᐲߢ޽ࠆ㧚(7)࿑㧝a ߦ␜ߔ⹜ᢱ☳૕ጀ࡮㔚ᭂ♽ߢ㧘TSC ᷹ⷰ↪㔚ᭂߦᑼࠍ(6)ᑼߦઍ౉ߔࠆߎߣߦࠃࠅ㧘⺃ዉߐࠇࠆ㔚⩄ Qind ߪᰴᑼߢ޽ߚ߃ࠄࠇࠆ㧚

QindITSC TQ>

(1)

@1  l / d  1 Hkߎߎߢ㧘d ߅ࠃ߮ǭ㨗ߪ⹜ᢱ☳૕ጀߩෘߐߣᲧ⺃㔚₸ߢ޽ࠅ㧘l ߪ㔚ᭂ㑆〒㔌ߢ޽ࠆ㧚߹ߚ㧘◲නൻߩߚ߼㧘⹜ᢱ☳૕ጀߦߪ⴫㕙㔚⩄ Q ߇޽ࠆߣߒߡ޿ࠆ㧚ߒߚ߇ߞߡ㧘Jࠍᰴᑼߩࠃ߁ߦ߅ߌ߫㧘J

1>@1  l / d  1 Hk

J Q

I obs TJ(8)Tº d ln Jª TF «
I TSC dT 
ITSC dT »
T0¼ dT¬ T0³³߇ᓧࠄࠇࠆ㧚
(8)ᑼߩฝㄝߦߪ᳞߼ࠆߴ߈⹜ᢱ࿕᦭ TSC

ITSC߇฽߹

ࠇߡ޿ࠆߚ߼㧘ߎߩᑼ߆ࠄ⋥ធ⹜ᢱ࿕᦭ߩ TSC ࠍ᳞߼ࠆߎ(2)ߣߪߢ߈ߥ޿㧚ߘߎߢ㧘෻ᓳ⸘▚ᴺࠍ೑↪ߒߡ㧘ㄭૃ⊛ߦ᳞߼ࠆߎߣߦߔࠆ㧚߹ߕ㧘г Iobs / J ࠍ෻ᓳ⸘▚ᴺߩೋᦼ୯ߣߒߡ㧘  ᑼฝ(1)ᑼߪᰴߩࠃ߁ߦ⴫ߐࠇࠆ㧚Qind

ㄝⓍಽ㗄ߩⵍⓍಽ㑐ᢙ +TSC ߦઍ౉ߒ㧘(8)ᑼฝㄝࠍ⸘▚ߔࠆ㧚
(3)ߘߩ⸘▚⚿ᨐࠍ ITSC(1)ߣ߅߈(8)ᑼᏀㄝߩ୯ߣߔࠆ㧚ߟ߉ߦ㧘(3)ᑼߩJ ߪ⹜ᢱߦሽ࿷ߔࠆ࠻࡜࠶ࡊ㔚⩄㊂ߣ᷹ቯ↪㔚ᭂ߳ߎߩ ITSC(1)ࠍౣ߮(8)ᑼฝㄝⓍಽ㗄ߩⵍⓍಽ㑐ᢙߦઍ౉ߒߡ⺃ዉߐࠇࠆ㔚⩄㊂ߩᲧࠍ⴫ߔ߽ߩߢ㧘ߎࠇࠍᗵᐲଥᢙߣࠃ

⸘▚ߒߚ⚿ᨐࠍ ITSC(2)ߣ߅߈(8)ᑼᏀㄝߩ୯ߣߔࠆ㧚ߎߩࠃ

1630

12006

߁ߥᠲ૞ࠍ n ࿁➅ࠅ㄰ߔߣᰴߩ㑐ଥ߇ᓧࠄࠇࠆ㧚nITSC



I obs

J Ic

I TSC ,Vn 1n t1(9)Tª TF n 1º d ln Jn 1IdT
ITSC dT »
«
TSCT0
¬ T0
¼ dT³Ic

³I obs߽࠺ࠖࡔࡦ࡚ࠫࡦ⊛ߦߪ㔚ᵹߢ޽ࠆ߆ࠄ㧘‛ℂ⊛ߦߪหߓ
(10)

(11)

J

ౝኈࠍ⴫ߒߡ޿ࠆ㧚(6)ᑼߪ᷹ⷰ㔚ᵹ୯߆ࠄዉ޿ߚ߽ߩߢ޽
ࠅ㧘(16)ᑼߪ᷹ⷰߒߚ⴫㕙㔚૏߆ࠄዉ޿ߚ߽ߩߢ㧘ਔᑼߪߢ޽ࠆ㧚⹜ᢱ࿕᦭ߩ TSC ITSC ߪ (9)ᑼߩ෻ᓳ⸘▚ࠍ➅ࠅ㄰หߓౝኈࠍ␜ߔߩߪᒰὼߩߎߣߢ޽ࠆ㧚ߒߚ߇ߞߡ㧘 (16)ᑼฝㄝߩ㔚⩄ Q ߽(7)ᑼߣหᒻߩᑼ㧘

1 ª TF³QT«
E ¬ T0ߒ㧘nn 1(12)ITSC # ITSC

ᩓᒵ ᵲᵱᵢ ย‫ܭ‬ኒ࿑㧝b ߩ᷹ቯ♽ߢߪ㧘᷹ⷰߐࠇࠆ‛ℂ㊂ߪ⹜ᢱߩ⴫㕙㔚૏Vs ߢ޽ࠆ㧚㐿࿁〝 TSC ᷹ቯ♽ߩ႐วߣห᭽ߦ㧘⹜ᢱ☳૕ጀߦߪ⴫㕙ߦ࠻࡜࠶ࡊ㕙㔚⩄ Q ࠍ઒ቯߔࠆ㧚 ࠤ࡞ࡆࡦᴺߦࠃࠆ⴫㕙㔚૏᷹ቯ⸘ࠍ↪޿ߚ᷹ⷰ㔚૏ Vobs ߪ ⹜ᢱ⴫㕙ߣ᷹ቯ↪ࡊࡠ࡯ࡉ㑆ߩ〒㔌ߦଐሽߖߕ

VSdQ / AH 0H k

JVQ / Aߢ޽ࠅ㧘J v ߪd / H0 HkT0TSC,V dT »dV º1 ªE A obs »«JV ¬dT ¼(18)d ln J V
 ª ³ I TSC ,V dT  ³ I TSC ,V dT º«¬ T0»¼ dTT0TFTߣߥࠅ㧘㐿࿁〝 TSC ߩ႐วߩ(8)ᑼߣౝኈ⊛ߦߪหߓߢ޽ࠆ㧚ߒߚ߇ߞߡ㧘 (18)ᑼߩ႐ว߽෻ᓳ⸘▚ᴺߦࠃࠅ⹜ᢱ☳૕☸
ߔߥࠊߜ㧘nI TSC,V(n 1)

I c,vߩ࠻࡜࠶ࡊ㔚⩄ Q ࠍ⚿߮ߟߌࠆଥᢙߢ㧘㐿࿁〝 TSC ߩ႐dV º1ªE A obs »  I Cn,V«JV ¬dT ¼n t1(19)Tª TF n 1º d ln J Vn 1IdTI TSC ,V dT »«
TSC,VT0¬ T0¼ dT³³(20)วߣหߓࠃ߁ߦ㧘ᗵᐲଥᢙߣࠃ߱ߎߣߦߔࠆ㧚⹜ᢱ⴫㕙㔚૏߆ࠄ᳞߼ࠆ⹜ᢱ☳૕࿕᦭ߩ TSCࠍ㐿࿁〝 TSC ᷹ቯ♽ߢ᳞߼ߚ߽ߩߣ඙೎ߔࠆߚ߼ߦ㧘ᷝሼ v ࠍㅊടߒߡ㧘ITSC,Vߣ⴫ߔߎߣߦߔࠆ㧚ߘ߁ߔࠆߣ㧘⹜ᢱ࿕᦭ߩ TSC

 E dQ / dT0
I TSC,VITSC,V

ߪ(4)ᑼߣหᒻߩᰴᑼߢ⴫ߐࠇࠆ㧚dQ / dt

(17)

(14)

ߢ޽ࠆ㧚߹ߚ㧘Jv ߪ᷹ⷰߐࠇࠆ⴫㕙㔚૏ Vobs ߣ⹜ᢱ☳૕ጀ

ITSC ,V¼ሶ࿕᦭ߩ TSC ࠬࡍࠢ࠻࡞ࠍㄭૃ⊛ߦ᳞߼ࠆߎߣ߇ߢ߈ࠆ㧚(13)ߢਈ߃ࠄࠇࠆ㧚ߚߛߒ㧘A ߪ⹜ᢱ㕙Ⓧ㧘H ߪ⌀ⓨߩ⺃㔚₸

Jv³Iߣߥࠆ㧚(16)߅ࠃ߮ (17)ᑼ߆ࠄ⹜ᢱ☳૕࿕᦭ߩᾲೝỗ㔚ᵹ

I TSC ,VVobsº

TI TSC,V dT 

ITSC,V ࠍ᳞߼ࠆߣ㧘ߦ෼᧤ߔࠆ߹ߢታⴕߒߡㄭૃ⸃ߣߒߡ᳞߼ࠆ㧚

2.2(16)⴫⃻ᑼߣฝㄝ╙㧝㗄ࠍ㒰߈หߓߢ޽ࠅ㧘 (16)ᑼฝㄝ╙㧝㗄n 10d ln J V
dV º1 ªE A obs »  E Q«
dTdT ¼JV ¬(16)ᑼߪ㐿࿁〝 TSC ᷹ቯ♽ߢ᳞߼ࠄࠇߚ⹜ᢱ࿕᦭ߩ TSC ߩߎߎߢ㧘

ITSC



dV º1ªE A obs »
«
dT ¼
JV ¬

(21)

ߢ޽ࠆ㧚ߎߩ႐ว߽(19)ᑼߩ෻ᓳ⸘▚ࠍ㧘
(15)

nn 1

ITSC ,V # ITSC ,V(22)㔚⩄ TSD ᷹ቯ♽ߩ႐ว߽㧘⹜ᢱ☳૕ጀߩෘߐ d ߇᷷ᐲ਄ߦ෼᧤ߔࠆ߹ߢ➅ࠅ㄰ߒߡㄭૃ⸃ࠍ᳞߼ࠆߎߣ߇ߢ߈ࠆ㧚᣹ߦࠃࠅᄌൻߔࠆߣ㧘 Hk ߽ᄌൻߔࠆߚ߼᷹ⷰ୯ Vobs ࠍᓸಽߎߎߢ㧘㔚ᵹାภߣ㔚࿶ାภߩ޿ߕࠇࠍ೑↪ߒߚ߶߁߇

ߒߡ⋥ߜߦ ITSC,V ࠍ᳞߼ࠆߎߣߪߢ߈ߥ޿㧚(13)ᑼࠍ᷷ᐲ T ߦ㑐ߒߡᓸಽߒߡ㧘(15)ߩ㑐ଥࠍ૶߁ߣ㧘⹜ᢱ☳૕ጀෘᄌൻߩᓇ㗀߇ዊߐ޿߆ᬌ⸛ߒߡߺࠆ㧚㔚ᵹାภ ߅ ࠃ ߮ 㔚࿶ ା ภ ߦኻ ߔ ࠆ⋧ ኻ ᗵ ᐲ ଥᢙJcv Tࠍᰴᑼߢቯ⟵ߔࠆ㧚Jc T ߅ ࠃ ߮

17J TJc T(23)J 0Jcv T(1) 㐿࿁〝 TSC ᷹ቯ♽ߢታ᷹ߒߚ TSC ାภIobs(2) ⹜ᢱ☳૕ጀߩෘߐ d㧦࡟࡯ࠩᄌ૏⸘ߢታ᷹Jv T(24)

Jv 0ߘ߁ߔࠆߣ㧘 (23), (24) ᑼߢ⴫ߐࠇߚ⋧ኻᗵᐲଥᢙߩᲧߪ㧘(2) ߅ࠃ߮ (14)ᑼࠍ૶ߞߡ㧘Jc TJcv Tߩዉ಴ࠍ⹜ߺߚ㧚૶↪ߒߚ࠺࡯࠲ߪᰴߩㅢࠅߢ޽ࠆ㧚

1> l / d 0 1@H k 0

1> l /d T

 1@H k T(3) ⹜ᢱ☳૕ጀߩ☸ሶలႯ₸ v(4) ⹜ᢱ☳૕☸ሶߩᲧ⺃㔚₸ Hr = 3(5) Iobs ᷹ቯᤨߩ㔚ᭂ㑆〒㔌 l = 4 mmߥ߅㧘૶↪ߒߚࡃࠗࡦ࠳࡯᮸⢽ߩࠟ࡜ࠬォ⒖᷷ᐲߪ⚂d 0d T



Hk T65Û& ߢ޽ࠅ㧘߹ߚ㧘 ࡃࠗࡦ࠳࡯᮸⢽ߩಽሶ㊂ಽᏓ߽ෳ⠨Hk 0ߩߚ߼⺞ߴߚ㧚
(25)਄⸥ߩ࠺࡯࠲ࠍ૶ߞߡㄭૃ⸘▚ࠍታⴕߔࠆߚ߼㧘᷷ᐲᄌ㔚ᵹାภߦኻߔࠆᗵᐲଥᢙߩಽᲣߩᦨೋߩ㗄㧝߇ᢙࠍ౒ㅢߦߒߚ㧚ߔߥࠊߜ㧘Iobs ߅ࠃ߮ d ߩታ᷹࠺࡯࠲ࠍ૶[( l / d) - 1] Hk ߦኻߒߡήⷞߢ߈ࠆߣ߈㧘(25)ᑼߪ◲නߦߥߞ↪ߒߡ㧘0.5͠ೞߺߩ౒ㅢ᷷ᐲߦኻߔࠆ㧘ߘࠇࠄߩ୯ࠍ⵬㑆ߡ㧘ᴺߦࠃࠅ᳞߼ߚ㧚ߎࠇࠄࠍ࿑㧞߅ࠃ߮࿑㧟ߦ␜ߒߡ߅ߊ㧚Jc Tl d 0Jcv Tld T(26)࿑㧞ߪ࠻࠽࡯↪ࡃࠗࡦ࠳࡯᮸⢽ߩ߽ߩߢ޽ࠅ㧘࿑㧟ߪ㕒㔚
0.7-8ߣߥࠆ㧚᷷ᐲ਄᣹ߣߣ߽ߦ⹜ᢱ☳૕ጀߩෘߐߪᄌൻߔࠆ߇㧘

0.65

߇ᚑࠅ┙ߟ᷷ᐲ㗔ၞߢߪ㧘(26)ߣ(27)ᑼ߆ࠄ㧘(28)-40.55
0.5-2IJc T  Jvc T

0.6d (mm)

(27)

obs

d 0 !d T(arb. unit)-60.45ߣߥࠆ㧚⋧ኻᗵᐲଥᢙ߇ 1 ߦㄭ޿߶ߤ᷷ᐲ਄᣹ߦ઻߁ᗵᐲ

00.4

ଥᢙߩᄌൻ߇ዊߐ޿ߎߣࠍᗧ๧ߔࠆ㧚ߒߚ߇ߞߡ㧘 Jcv T240߇ 1 ࠃࠅዊߐ޿႐วߪ㧘(28)ᑼ߆ࠄ Jcv T ߩ߶߁߇ Jc T60߽㧘☳૕ጀᲧ⺃㔚₸ߩ☸ሶలႯ᭴ㅧଐሽᕈߦߪ㑐ଥߥߊ㧘෻ᓳ⸘▚ࠍታⴕߒߡ㧘㔚ᵹାภ Iobs ߆ࠄ☳૕☸ሶ࿕᦭ߩ
TSC ࠬࡍࠢ࠻࡞ ITSC ࠍ᳞߼ࠆߚ߼ߦᔅⷐߥ⹜ᢱ☳૕ጀᲧ⺃Hk

1  Hr  1 v

0.6

40.55

30.5

20.45

10.4

00.35

Iobs

㔚₸ H㨗ߪᰴᑼߦࠃࠅ⸘▚ߒߚ㧚

5(29)☸ሶ♽ߩ⺃㔚₸ߪ㧘☸ሶ㑆⋧੕૞↪ࠍήⷞߔࠇ߫☸ሶỚ

-140

50

60

70

80

90

0.3
100

7HPSHUDWXUH
Temperature ǌ&(͠)ᐲߣ☸ሶߩಽᭂ₸ߩⓍߦଐሽߔࠆ㧚ߒߚ߇ߞߡ㧘☳૕☸ሶߩలႯ᭴ㅧࠍήⷞߔࠇ߫㧘లႯ₸ߩჇടߪනߦ☸ሶỚᐲߩ࿑㧟Ⴧടࠍᗧ๧ߔࠆ㧚ߔߥࠊߜ㧘 (29)ᑼߪ☸ሶలႯ᭴ㅧࠍήⷞ

Fig.3 Iobs and d for the powder paint.

ߒߚ߽ߩߢ޽ࠆ㧚
3.2d (mm)ᚾ૰ብ˳‫ޖ‬ỉᛔᩓྙ(arb. unit)

3.1

0.35
140120࿑㧞 ࡃࠗࡦ࠳࡯᮸⢽ߩ Iobs ߣ⹜ᢱෘߐ d
Fig.2 Iobs and d for the binder resin.

᣹᷷ߦࠃࠆ⹜ᢱ☳૕ጀෘᄌൻߩᓇ㗀߇ዊߐ޿ߎߣ߇ࠊ߆ࠆ㧚Ӓࣄᚘምỉܱᘍ

100

7HPSHUDWXUHTemperatureǌ& (͠)ࠃࠅ߽ 1 ߦㄭ޿㧚ߔߥࠊߜ㧘Vobs ᷹ቯߩ߶߁߇ Iobs ᷹ቯࠃࠅ3.

80ᚘምỆ̅ဇẴỦἙὊἑᧄ⎇ⓥߢߪ㧘ⶄ౮ᯏ࠻࠽࡯↪ࡃࠗࡦ࠳࡯᮸⢽߅ࠃ߮㕒㔚☳૕Ⴃⵝ↪Ⴃᢱࠍ↪޿ߡ㧘☳૕☸ሶ࿕᦭ߩ TSC ࠬࡍࠢ࠻࡞

☳૕Ⴃᢱߩ Iobs ߣ⹜ᢱෘߐ dႣⵝ↪☳૕Ⴃᢱߩ߽ߩߢ޽ࠆ㧚⹜ᢱ☳૕ጀߩෘߐ d ߩ᷹ቯߪ㧘⹜ᢱ૞ᚑ߅ࠃ߮᣹᷷ㅦᐲ
ߥߤోߡ TSC ᷹ቯߣหߓ᧦ઙߢⴕߞߚ㧚ߔߥࠊߜ㧘ห৻ᒻ⁁ߩ⹜ᢱኈེߦ㧘ࡃࠗࡦ࠳࡯᮸⢽ߢߪ 120 mg,☳૕Ⴃᢱ

1830

1

2006

ߩ߫޽޿ߪ 150 mg ߩ⹜ᢱ☳૕ࠍ 5.4 MPa ߢട࿶ᚑဳߒߡ⹜

ࠄࠇࠆߣ઒ቯߒߡ⸘▚ߒߚ⚿ᨐࠍ࿑ 4,ᢱߣߒߚ㧚ߎߩ⹜ᢱࠍ TSC ᷹ቯߣหߓ 3.5 ͠/min ߩ৻ቯ᣹࿑ 4 ߪࡃࠗࡦ࠳࡯᮸⢽ߩ⸘▚⚿ᨐߢ޽ࠅ㧘࿑ 5 ߪ㕒㔚☳૕᷷ㅦᐲߢടᾲߒߡ㧘d ߩ᷷ᐲᄌൻࠍಽ⸃⢻ 3Pm ߩ࡟࡯ࠩᄌ

Ⴃⵝ↪Ⴃᢱߩ߽ߩߢ޽ࠆ㧚ߎࠇࠄߩ࿑ߩਛߦߪ㧘ෳᾖ↪ߣ૏⸘ߢ᷹ቯߒߚ㧚ߒߡ㧘᷹ⷰ࠺࡯࠲ Iobs ߽␜ߒߡ޽ࠆ㧚ߚߛߒ㧘Iobs ߪᲧセߒ߹ߚ㗄⋡(3)ߩ㧘⹜ᢱ☳૕ጀߩ☸ሶలႯ₸ߪᰴᑼߦߒߚ߇

d /d߿ߔߊߔࠆߚ߼ߦ㧘ᭂᕈࠍ෻ォߒߘߩᒝᐲ߽࿑㧠ߢߪ ITSC(5)ߣ㧘࿑㧡ߢߪ ITSC(2)ߣ㧘ࡃࡦ࠼ߩ㕙Ⓧ߇หߓ⒟ᐲߦߥࠆࠃ

ߞߡ⸘▚ߒߚ㧚v߅ࠃ߮࿑ 5 ߦ␜ߔ㧚(30)200ࡦ࠳࡯᮸⢽߇ࠬ࠴࡟ࡦ࡮ࠕࠢ࡝࡞♽ߩ߽ߩߢ޽ࠆߎߣ߆ࠄ㧘ࡐ࡝ࠬ࠴࡟ࡦߩᲧ⺃㔚₸ 2.6 8)߅ࠃ߮ࡐ࡝ࡔ࠴࡞ࡔ࠲ࠢ࡝
8)࡟࡯࠻ߩ 3.1 ࠍ⠨ᘦߒߚ⚿ᨐߢ޽ࠆ㧚߹ߚ㧘㕒㔚Ⴃⵝ↪Ⴃᢱߦኻߒߡߪ․೎ߩℂ↱ߪߥ޿㧚☸ሶᲧ⺃㔚₸ߩ᷷ᐲଐሽ

I100

obs㗄⋡(4)ߩ☸ሶᲧ⺃㔚₸ࠍ 3 ߦߒߚᩮ᜚ߪ㧘૶↪ߒߚࡃࠗ

0150
obs

50

2
1

0

3, 4, 5I

߇㧝ߦኻᔕߒߚߣ߈ߩ⹜ᢱෘߢ޽ࠆ㧚, I (n) (arb. unit)TSCߎߎߢ㧘d*ߪ⹜ᢱ☳૕߇ṁⲢߒߡⓨ᳇⋧߇ߥߊߥࠅలႯ₸ᕈߪࡃࠗࡦ࠳࡯᮸⢽߅ࠃ߮☳૕Ⴃᢱ޿ߕࠇߩ႐ว߽⠨ᘦߒ
-50

ߡ޿ߥ޿㧚

4060

৻⥸ߦ㧘ήᭂᕈ㜞ಽሶߩಽᭂߪ㔚ሶಽᭂ߇ਥߢ޽ࠆ߆ࠄ㧘⺃㔚₸ߩ᷷ᐲଐሽᕈߪߥ޿㧚ߒ߆ߒ㧘ታ㓙ߪ᷷ᐲ਄᣹ߦ઻
߁⤘ᒛߩߚ߼ኒᐲ߇ૐਅߒ㧘ߘߩ⚿ᨐ⺃㔚₸ߪ᷷ᐲߣߣ߽
ߦᷫዋߔࠆ௑ะߦ޽ࠆ 9, 10)㧚߹ߚ㧘᦭ᭂᕈ㜞ಽሶߪ㧘ࠟ࡜ࠬォ⒖᷷ᐲએ਄ߩ᷷ᐲ㗔ၞߢߪ⛘ኻ᷷ᐲߩㅒᢙߦᲧ଀ߒߡ

80

100

120

140

7HPSHUDWXUH ǌ&(͠)࿑㧠 ࡃࠗࡦ࠳࡯᮸⢽ߩ Iobs, ITSC(n) 㧚 ࿑ਛߩᢙሼߪ෻ᓳ⸘▚ߩ࿁ᢙ nFig.4 Iobs and ITSC(n) for the binder resin. Numeralsin the figure represent the number n of iterative
calculations.

ᷫዋߔࠆߪߕߢ޽ࠆ߇㧘ߎࠇ߽㧘⃻ታߦߪ෺ᭂሶ㑆㧘޽ࠆ޿ߪ㧘෺ᭂሶߣߘߩ๟࿐ಽሶߣߩ⋧੕૞↪ߦ᷷ᐲଐሽᕈ߇(arb. unit)ߣ߽น⢻ߣ޿ࠊࠇߡ޿ࠆ 11)㧚ࠊࠇࠊࠇ߇૶↪ߒߚࡃࠗࡦ࠳࡯᮸⢽ߪᭂᕈ㜞ಽሶߣήᭂᕈ㜞ಽሶߩᷙว‛ߢ޽ࠅ㧘⺃㔚₸ߦਈ߃ࠆ᷷ᐲലᨐߪ੕޿ߦ߁ߜᶖߔ௑ะߦ޽ࠆ߽ߩߣᕁࠊࠇࠆ߇㧘ౕ૕⊛ߦߪਇ᣿ߢ޽ࠆ㧚૶↪ߒߚࡃࠗࡦ࠳࡯᮸⢽ߩಽሶ㊂ಽᏓߪ㧘3103 ⒟ᐲߩ
ಽሶ㊂ࠍࡇ࡯ࠢߣߔࠆૐಽሶ㊂ᚑಽߣ㧘3105 ⒟ᐲߩಽሶ
㊂ࠍࡇ࡯ࠢߣߔࠆ㜞ಽሶ㊂ᚑಽ߇߅ࠃߘ 3 ኻ 1 ⒟ᐲߩᲧ₸ߢᷙวߐࠇߡ޿ࠆߎߣ߇ࠊ߆ߞߚ㧚ߔߥࠊߜ㧘ߎߩࡃࠗࡦ
࠳࡯᮸⢽ߪૐ᷷ߢቯ⌕น⢻ߥૐ᷷ṁⲢ᮸⢽ߢ޽ࠆߦ߽߆߆ࠊࠄߕ㧘Ꮺ㔚㔚⩄ߪ᮸⢽߇ṁ⌕⋥೨߹ߢ⛽ᜬߢ߈ࠆࠃ߁ߦ
Ꮏᄦߐࠇߚ߽ߩߣᕁࠊࠇࠆ㧚 ᚘምኽௐểẸỉᎋ‫ݑ‬⹜ᢱ☳૕ጀᲧ⺃㔚₸ߣ☸ሶలႯ₸ߩ㑐ଥ߇(29)ᑼߢਈ߃

-40-20obs

ᭂᕈ㜞ಽሶߣ᦭ᭂᕈ㜞ಽሶࠍㆡᒰߥഀวߢᷙวߒߚ߽ߩߩ

I , I޽ࠆߚ߼ߦ㧘߻ߒࠈჇടߔࠆߎߣ߇޽ࠆ㧚ߒߚ߇ߞߡ㧘ή

TSC

Ყ⺃㔚₸ߪ޽ࠆ᷷ᐲ▸࿐ߢߪ᷷ᐲଐሽᕈࠍ߽ߚߥߊߔࠆߎ

(n)

-60

0
40

50

60

70

80

90

100

emperature (͠)
T7HPSHUDWXUH
ǌ&࿑㧡 ☳૕Ⴃᢱߩ Iobs ߣ ITSC(n) ෻ᓳ⸘▚ 2 ࿁ߩITSC(2) ߣ Iobs ߩࠬࡍࠢ࠻࡞ߩᒻߪ߶ߣࠎߤ඙೎ߢ߈ߥ޿㧚Fig.5 Iobs andITSC(n)for the powder paint.
Difference in spectral shape between ITSC(2) and Iobs
was hardly observed.

߁ߦ৻ቯ୚ߒߡ޽ࠆ㧚࿑㧠߆ࠄࠊ߆ࠆࠃ߁ߦ㧘෼᧤ߒߚ⹜
ᢱ࿕᦭ TSC ࠬࡍࠢ࠻࡞ߩਥࡃࡦ࠼ߩࡇ࡯᷷ࠢᐲߪ᷹ⷰߐ
ࠇߚࠬࡍࠢ࠻࡞ Iobs ߩ߽ߩࠃࠅ⚂ 10Û& 㜞᷷஥ߦࠪࡈ࠻ߒߡ
޿ߡ㧘⹜ᢱෘᄌൻߩᓇ㗀ࠍឃ㒰ߒߚୃᱜࠬࡍࠢ࠻࡞ߪߎߩ

19᮸⢽ߩ․ᓽࠍ෻ᤋߒߡ޿ࠆߎߣ߇ࠊ߆ࠆ㧚߹ߚ㧘ಽሶ㊂ಽ⢽߇ṁⲢ⋥೨߹ߢ㔚⩄ࠍ଻ᜬߢ߈ࠆߣ޿߁․ᓽࠍࠃߊ⺑᣿Ꮣߦ․ᓽࠍᜬߟߎߩࡃࠗࡦ࠳࡯᮸⢽ߩ႐วߢ߽㧘෻ᓳ⸘▚ߢ߈ࠆ߽ߩߢ޽ߞߚ㧚ࠍ㧡࿁߶ߤⴕ߃߫ ITSC ߪ෼᧤ߔࠆߎߣ߇࿑㧠߆ࠄࠊ߆ࠆ㧚৻ᣇ㧘TSC ߇᷹ⷰߐࠇࠆ᷷ᐲၞߢᄢ߈ߥ⹜ᢱෘᄌൻ߇ߺ৻ᣇ㧘㕒㔚☳૕Ⴃⵝ↪Ⴃᢱߩ႐วߪ㧘࿑㧡߆ࠄࠊ߆ࠆࠃ

ࠄࠇߥ߆ߞߚ☳૕Ⴃᢱߩ႐วߪ㧘᷹ⷰߐࠇߚ TSC ࠬࡍࠢ࠻߁ߦ㧘TSC ࠬࡍࠢ࠻࡞ߩ⋧ኻ⊛ᒻߪ෻ᓳ⸘▚ߩ⚿ᨐᓧࠄࠇ࡞ߣ⹜ᢱ࿕᦭ TSC ࠬࡍࠢ࠻࡞ߪ㧘ᭂᕈߣᒝᐲߩὐࠍ㒰ߌ߫ߚ෼᧤୯ߣ Iobs ߪ߶ߣࠎߤหߓߢ㧘⹜ᢱ☳૕ጀෘᄌൻߩᓇ߶ߣࠎߤหߓߢ޽ߞߚ㧚એ਄ߩߎߣ߆ࠄ㧘㜞ಽሶ☳૕⹜ᢱߢߪ㧘ታ᷹ߐࠇࠆ TSC㗀ߪዊߐߊ⏕⹺ߢ߈ߥ߆ߞߚ㧚ᦨᓟߦ㧘☳૕⹜ᢱߦኻߔࠆ TSC ᷹ቯࠍ㧘Iobs ࠍ᷹ⷰߔࠆାภߩ಴⃻᷷ᐲၞߢ⹜ᢱෘߐᄌൻ߇ᄢ߈޿ߣ߈ߪ㧘᷹ⷰߐ㔚ᵹ᷹ቯߣ㧘Vobs ࠍ᷹ቯߔࠆ㔚࿶᷹ቯߩᓧᄬࠍ⠨߃ࠆߚ߼ࠇߚ TSC ࠬࡍࠢ࠻࡞ߦਈ߃ࠆ⹜ᢱෘߐᄌൻߩᓇ㗀ߪᄢ߈ߦ㧘ࡃࠗࡦ࠳࡯᮸⢽ߩጀෘ d ߩታ᷹᷷ᐲଐሽᕈࠍ↪޿ߡ (23),ߊ㧘 ߹ߚ㧘TSC ାภߩ಴⃻᷷ᐲၞߢ⹜ᢱෘߐᄌൻ߇ዊߐ޿

(24), (25)߅ࠃ߮(26)ߩฦᑼࠍ⸘▚ߒߚ㧚ߥ߅㧘(23), (24), (25)ߣ߈ߪ㧘᷹ⷰߐࠇߚ TSC ࠬࡍࠢ࠻࡞ߦਈ߃ࠆ⹜ᢱෘߐᄌൻߩฦᑼߩᢙ୯⸘▚ߦᔅⷐߥ Hk ߩ୯ߪ(29)ᑼࠍ↪޿ߡ᳞߼ߚ㧚ߩᓇ㗀ߪዊߐ޿ߎߣ߇⏕⹺ߐࠇߚ㧚ᢙ୯⸘▚ߩ⚿ᨐࠍ࿑ 6 ߦ␜ߔ㧚(25)߅ࠃ߮(26)ᑼߩᢙ୯⸘▚߹ߚ㧘⹜ᢱ⴫㕙㔚૏ࠍ᷹ቯߔࠆ㔚࿶ᴺ㧘TSC ࠍ⋥ធ᷹ቯߩ⚿ᨐߪ㧘ࠤ࡞ࡆࡦᴺߩ⴫㕙㔚૏⸘ߦࠃࠆ⴫㕙㔚૏᷹ቯߩߔࠆ㔚ᵹᴺ㧘޿ߕࠇߩ႐ว߽᷹ⷰ⚿ᨐߪ TSC ାภ᷹ቯਛߩ߶߁߇⹜ᢱ☳૕ጀෘᄌൻߩᓇ㗀ߪࠊߕ߆ߦዊߐ޿߇㧘 (23)⹜ᢱෘߐᄌൻߩᓇ㗀ࠍหߓ⒟ᐲฃߌࠆߎߣ߇ᢙ୯⸘▚ߩ⚿

ߣ(24)ᑼߩᢙ୯⸘▚ߩ⚿ᨐࠍ⋥ធᲧセߔࠆߣ㧘ߘࠇࠄߪ߶

ᨐ᣿ࠄ߆ߦߥߞߚ㧚Results of numerical calculation ofeq.(23) ~ (26)ߣࠎߤหߓߢ޽ࠆߎߣ߇ࠊ߆ࠆ㧚ᧄ⎇ⓥࠍⴕ߁ߦ޽ߚࠅ TSC ࠬࡍࠢ࠻࡞߅ࠃ߮☳૕ጀෘ

1.2eq.(25)᷹ቯࠍߒߡ޿ߚߛ޿ߚ᪀ේ⺰ᰴำ߅ࠃ߮ࡃࠗࡦ࠳࡯᮸⢽ߩ

1DSC ߣಽሶ㊂ಽᏓߩ⺞ᩏࠍߒߡ޿ߚߛ޿ߚၳஜᔒ᳁ߦᗵ

0.8eq.(26)

0.6eq.(24)⻢ߒ߹ߔ㧚

0.4eq.(23)

0.20406080100120

140

Temperature (͠)࿑ 6 ࡃࠗࡦ࠳࡯᮸⢽ߦኻߔࠆ㔚ᵹାภߩ⋧ኻᗵᐲଥᢙߣ㔚࿶ାภߩ⋧ኻᗵᐲଥᢙ߅ࠃ߮ߘࠇࠄߩᲧ
ߩᢙ୯⸘▚
Fig.6 Numerical calculations of relative sensitivity forcurrent and voltage TSC signals, and of their ratio.

5㧚ኽ ᛯ⹜ᢱ⴫㕙㔚૏߆ࠄ TSC ࠬࡍࠢ࠻࡞ߦᄌ឵ߔࠆ㔚࿶᷹ቯ
ᴺߣ㧘TSC ࠍ⋥ធ᷹ቯߔࠆ㔚ᵹ᷹ቯᴺߦኻߒߡ㧘෻ᓳ⸘▚
ㄭૃᴺࠍ↪޿ࠆߎߣߦࠃࠅ㧘TSC ାภ᷹ቯਛߩ⹜ᢱෘᄌൻߩᓇ㗀ࠍឃ㒰ߒߚ⹜ᢱ࿕᦭ TSC ࠬࡍࠢ࠻࡞ࠍዉ಴ߔࠆ৻⥸ᑼࠍዉ޿ߚ㧚߹ߚ㧘࠻࠽࡯↪ࡃࠗࡦ࠳࡯᮸⢽߅ࠃ߮㕒㔚☳૕Ⴃⵝ↪Ⴃᢱߦߎߩᚻᴺࠍ⹜ⴕ⊛ߦㆡ↪ߒߚ⚿ᨐ㧘⹜ᢱ
ߩಽሶ㊂ಽᏓߦ․⇣ᕈࠍ߽ߟࡃࠗࡦ࠳࡯᮸⢽ߩ႐วߢ߽㧘4㨪 5 ࿁ߩ෻ᓳ⸘▚ࠍⴕ߃߫෼᧤ߒ㧘⹜ᢱ࿕᦭ TSC ࠬࡍࠢ࠻࡞߇ᓧࠄࠇߚ㧚ᓧࠄࠇߚ⹜ᢱ࿕᦭ TSC ࠬࡍࠢ࠻࡞ߪߎߩ᮸Ӌᎋ૨ྂ1) T. Hori and K. Ikezaki: J. Electrostatics, 40 & 41
(1997) 313
2) J. Vanderschueren, M. Ladang, J. Niezette and M.
Corapci: J. Appl. Phys., 58 (1985) 46543) ᪀ේ⺰ᰴ㧘ᳰ㦮๺↵㧦 2000 ᐕᐲ㕒㔚᳇ቇળ⻠Ṷ⺰ᢥ㓸,p.229 (2000)4) ᪀ේ⺰ᰴ㧘ᳰ㦮๺↵㧦2002 ᐕᐲ㕒㔚᳇ቇળᤐᦼ⻠Ṷળ⺰ᢥ㓸㧘p.7 (2004)
5) J.van Turnhout: Electrets, ed. G.M.Sessler, p.171,Springer-Verlag, Berlin, Heidelbrg, New York (1980)
6) ਄ේ೑ᄦ㧦㕒㔚᳇ቇળ⹹㧘13 (1989) 284
7) ᧖ේ㣔㓶㧘┻ౝቇ㧦2005 ᐕᐲ㕒㔚᳇ቇળᤐᦼ⻠Ṷળ⺰ᢥ㓸㧘p.47 (2005)8) ๺↰౎ਃਭ㧦㜞ಽሶߩ㔚᳇‛ᕈ㧘p.13, ⵷⪇ᚱ, ᧲੩ (1987)
9) R.Bartnikas: Elecrtical Properities of solid Insulating Materials: Molecular Structure and ElectricalBehavior, ed. R. Bartnikas and R.M.Eichhorn,p.92, ASTM, Philadelphia (1983)
10) P.J.Phillips: : Elecrtical Properities of solid Insulating
Materials: Molecular Structure and Electrical Behavior, ed.
R.Bartnikas and R.M.Eichhorn, p.205, ASTM, Philadelphia(1983)
11) C.C.Ku and R.Liepins: Electrical Properties of Polymers,
p.55, Hanser Publishers, Munich, Vienna, New York (1987)